JP4568465B2 - Semiconductor wafer protection sheet - Google Patents

Semiconductor wafer protection sheet Download PDF

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Publication number
JP4568465B2
JP4568465B2 JP2001378066A JP2001378066A JP4568465B2 JP 4568465 B2 JP4568465 B2 JP 4568465B2 JP 2001378066 A JP2001378066 A JP 2001378066A JP 2001378066 A JP2001378066 A JP 2001378066A JP 4568465 B2 JP4568465 B2 JP 4568465B2
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Prior art keywords
semiconductor wafer
heat
protection sheet
support
layer
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JP2003176464A (en
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正信 九津見
弘之 内田
知道 高津
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Denka Co Ltd
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Denki Kagaku Kogyo KK
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/683Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
    • H01L21/6835Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using temporarily an auxiliary support
    • H01L21/6836Wafer tapes, e.g. grinding or dicing support tapes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2221/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof covered by H01L21/00
    • H01L2221/67Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere
    • H01L2221/683Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere for supporting or gripping
    • H01L2221/68304Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere for supporting or gripping using temporarily an auxiliary support
    • H01L2221/68327Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere for supporting or gripping using temporarily an auxiliary support used during dicing or grinding

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  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
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  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
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Description

【0001】
【発明の属する技術分野】
本発明は、半導体ウエハ保護用シートに係り、特に、半導体ウエハを100μm以下の厚さまで研磨でき、半導体ウエハを研磨した後にダイボンディングフィルムを融着させても半導体ウエハが破損しない半導体ウエハ保護用シートに関する。
【0002】
【従来の技術】
半導体チップの製造に用いられるウエハにはシリコンウエハ、ガリウム−砒素等があり、中でもシリコンウエハが多用されている。シリコンウエハは高純度の単結晶シリコンを厚さ500〜1000μm程度に薄くスライスすることにより製造されているが、近年ICカード(インテグレーテッド サーキット カード)の普及やスタックドCSP(チップ サイズ パッケージ)の多層化により、さらなる薄肉化が望まれており、厚さが350μm程度であった半導体ウエハを100μm以下まで研磨することが必要とされてきた。
【0003】
また、半導体チップを基板へ実装させる際に、半導体チップと基板を安定的に固定するための接着剤として、ダイボンディングフィルムが使用されている。ダイボンディングフィルムは、半導体ウエハに熱融着されるものであり、厚さが350μm程度の半導体ウエハでは、半導体ウエハ保護用シートを剥離させた後に融着させることができる。しかし、厚さが100μm以下の半導体ウエハにあっては、半導体ウエハ保護用シートを剥離させてしまうと半導体ウエハが自重によって破損してしまうため、半導体ウエハ保護用シートを貼り付けたままダイボンディングフィルムを融着させることが必要とされてきた。
【0004】
ここで、半導体ウエハを研磨する際に半導体ウエハを保持するための半導体ウエハ保護用シートとしては、例えば、特開2001−123139号の手段が知られている。この手段は、特定の粘着剤を軟質の支持体上に積層させたものであり、半導体ウエハの裏面へ粘着剤が移行することを防止するというものである。
【0005】
【発明が解決しようとする課題】
しかしながら、この手段のような半導体ウエハ保護用シートでは、ダイボンディングフィルムを融着させる際に、半導体ウエハ保護用シートの支持体が融着熱によって軟化し、半導体ウエハが安定的に保持されなくなって破損してしまうという課題があった。
【0006】
この課題を解決するために、支持体として硬質のものを採用する手段が考えられるが、単に支持体を硬質のものに変更しただけでは、半導体ウエハを研磨する際に半導体ウエハにかかる応力を緩和することができず、研磨中に半導体ウエハが破損してしまうという新たな課題が発生した。
【0007】
したがって、本発明の目的は、半導体ウエハを100μm以下の厚さまで研磨できるとともに、半導体ウエハを研磨した後にダイボンディングフィルムを融着させても半導体ウエハが破損しない半導体ウエハ保護用シートを提供することにある。
【0008】
【課題を解決するための手段】
本発明者は、上記に鑑み鋭意検討を行った結果、単層又は複数層からなる支持体と、支持体上に積層された粘着剤層を有する半導体ウエハ保護用シートであって、支持体が、融点160〜300℃で、引張弾性率0.1〜1.5GPaである耐熱支持層を少なくとも1層有することにより、上記課題を解決できることを見出し本発明を完成した。
【0009】
【発明の実施の形態】
本発明の半導体ウエハ保護用シートにおける耐熱支持層の融点は、あまりに低いと、ダイボンディングフィルムを融着させる際の融着熱によって支持体が軟化し半導体ウエハが破損してしまい、あまりに高いと、支持体が硬くなってしまい半導体ウエハを研磨する際に発生する応力を緩和できなくなり半導体ウエハが破損してしまう。このため、耐熱支持層の融点にあっては、160〜300℃の範囲が良く、好ましくは、180〜300℃の範囲が良い。ここで融点とは、JIS K 7121に準じて測定して得られた値であり、示差走査熱量計による融解熱量測定で得られた融解曲線における吸熱ピークの頂点の温度をいう。
【0010】
本発明の半導体ウエハ保護用シートにおける耐熱支持層の引張弾性率は、あまりに低いと、研磨時に発生する応力によって半導体ウエハが変形して破損してしまい、あまりに高いと半導体ウエハを研磨する際に発生する応力を緩和できなくなり半導体ウエハが破損してしまう。このため、耐熱支持層の引張弾性率にあっては、0.1〜1.5GPaの範囲が良く、好ましくは、0.1〜1.0GPaの範囲が良い。ここで引張弾性率とは、JIS K 7121に準じて測定して得られた値であり、幅10mmの短冊状の試料を、雰囲気温度23℃、引張速度100%/minで引張試験をして得られた応力−ひずみ曲線から求められる初期弾性率をいう。
【0011】
本発明の半導体ウエハ保護用シートにおける耐熱支持層は、単層で使用する際は何ら問題がない。しかし、耐熱支持層と粘着剤層の間に介在層を設ける際には、介在層の総厚が75μm以下のものが良い。これは、介在層の厚さがあまりに厚いと、耐熱支持層の上記効果が得られなくなってしまうからである。なお、耐熱支持層の粘着剤層を積層させない面に積層させる層については特に限定するものではない。
【0012】
本発明の半導体ウエハ保護用シートの耐熱支持層として採用できる材料としては、融点及び引張弾性率が上記値であれば適宜選択して採用でき、具体的にはポリブチレンテレフタレート、ポリ−1、4−シクロヘキサンジメチレンテレフタレート、ポリブチレンナフタレート、ナイロン等がある。
【0013】
本発明の半導体ウエハ保護用シートの支持体は、後述する粘着剤層が紫外線硬化型粘着剤の場合には、支持体側から照射される紫外線を粘着剤層にまで届かせる必要があるため、紫外線透過性のものでなければならない。また、支持体は、後述する粘着剤層が加熱硬化型粘着剤や加熱発泡型粘着剤の場合には、加熱時に使用される温度より高い温度の融点を有していなければならない。なお、支持体の厚さにあっては、特に限定するものではないが、一般的な半導体ウエハ保護用シートで採用されている5〜500μmの範囲から適宜選択して採用すれば良い。
【0014】
本発明の半導体ウエハ保護用シートの粘着剤層は、一般的な感圧型粘着剤、紫外線硬化型粘着剤、加熱硬化型粘着剤等を用いることができる。感圧型粘着剤としてはアクリル系、ゴム系、シリコン系等従来公知の粘着剤が用いられる。また、紫外線硬化型粘着剤としてはベースポリマ、紫外線硬化性化合物、紫外線硬化開始剤等を配合したものが採用され、加熱硬化型粘着剤としてはベースポリマ、加熱硬化性化合物、加熱硬化開始剤等を配合したものが採用される。ここで、紫外線硬化型粘着剤及び加熱硬化型粘着剤のベースポリマとしては、一般的なアクリル系粘着剤、ゴム系粘着剤等を用いることができる。
【0015】
なお、紫外線硬化型粘着剤の硬化を開始するためには、紫外線の照射が必要になる。また、熱硬化型粘着剤及び加熱発泡型粘着剤については剥離時に加熱が必要となる。紫外線照射及び加熱のタイミングとしては、半導体ウエハを研磨し、搬送した後に行われる。なお、粘着剤層の厚さにあっては、特に限定するものではないが、一般的な半導体ウエハ保護用シートで採用されている5〜200μmの範囲から適宜選択して採用すれば良い。
【0016】
本発明にかかる半導体ウエハ保護用シートは、必要に応じて、粘着剤層の粘着面にポリエチレンラミネート紙、剥離処理プラスチックフィルム等の剥離紙又は剥離シートを密着させて保存される。
【0017】
本発明にあっては、単層又は複数層からなる支持体と、支持体上に積層された粘着剤層を有する半導体ウエハ保護用シートであって、支持体が、融点160〜300℃で、引張弾性率0.1〜1.5GPaである耐熱支持層を少なくとも1層有することにより、半導体ウエハを100μm以下の厚さまで研磨できるとともに、半導体ウエハを研磨した後にダイボンディングフィルムを融着させても半導体ウエハが破損しない半導体ウエハ保護用シートが得られた。
【0018】
【実施例】
本発明にかかる半導体ウエハ保護用シートの実施例1を、比較例と比較しつつ、表1及び図1を用いて説明する。ここで、表1は、本実施例及び比較例の半導体ウエハ保護用シートの配合及び特性を示したものであり、図1は、本実施例及び比較例の半導体ウエハ保護用シートを模式的に示した断面図である。
【0019】
【表1】

Figure 0004568465
【0020】
ここで、表1の特性値における「研磨性」は、半導体ウエハ保護用シート上に直径8インチ、厚さ700μmの半導体ウエハを貼り付けてから研磨機(株式会社ディスコ製バックグラインダーDFG−850)を用いて半導体ウエハの厚みが25μmになるまで研磨した後、目視にて半導体ウエハの状態を観察したものである。研磨性にあっては、半導体ウエハが破損していなかったものを○、破損が確認されたものを×として評価した。なお、試験のサンプル数は30とした。
【0021】
また、表1の特性値における「耐熱性」は、研磨性試験に合格したサンプルについてダイボンディングフィルムを融着させる際の条件(140℃、10秒)で熱処理した後、目視にて半導体ウエハの状態を観察したものである。耐熱性にあっては、半導体ウエハが破損していなかったものを○、破損が確認されたものを×として評価した。なお、試験のサンプル数は研磨性と同様に30とした。
【0022】
本実施例の半導体ウエハ保護用シートは、図1に示すように、単層の耐熱支持層3からなる支持体1と、支持体1上に積層された粘着剤層2を有するものである。ここで、耐熱支持層3は、融点220℃、引張弾性率0.3GPa、厚さ150μmのポリブチレンテレフタレート製である。また、粘着剤層2は、厚さ20μmの紫外線硬化型粘着剤であり、ベースポリマとしてのアクリル酸エチル−アクリル酸2−エチルヘキシルの共重合体100重量部、紫外線硬化性化合物としての6官能性ウレタンアクリレートオリゴマ120重量部、紫外線硬化開始剤としてのベンゾインイソプロピルエーテル8重量部、架橋剤としての2,4−トルイレンジイソシアナート3重量部を配合して得られたものである。なお、特に記載しない限り、以下の実施例及び比較例は本実施例と同様なものである。
【0023】
本実施例にあっては、研磨性及び耐熱性が良く、目標とする半導体ウエハ保護用シートが得られた。
【0024】
比較例1及び比較例2について説明する。比較例1は、実施例1の耐熱支持層3を融点90℃のポリエチレンに変更したものであり、比較例2は、実施例1の耐熱支持層3を融点330℃のポリテトラフルオロエチレンに変更したものである。
【0025】
比較例1にあっては耐熱性が悪く、比較例2にあっては研磨性が悪かった。
【0026】
比較例3及び比較例4について説明する。比較例3は、実施例1の耐熱支持層3を引張弾性率0.07GPaのエチレンビニルアセテートに変更したものであり、比較例4は、実施例1の耐熱支持層3を引張弾性率3.0GPaのポリエチレンテレフタレートに変更したものである。
【0027】
比較例3及び比較例4にあっては研磨性が悪かった。
【0028】
本発明における実施例2及び実施例3について、図2及び図3を参照しつつ説明する。実施例2は、図2に示すように、実施例1の耐熱支持層3と粘着剤層2の間に、厚さ70μmのポリエチレンテレフタレート層4を介在させたものであり、実施例3は、図3に示すように、実施例1における耐熱支持層3の粘着剤層2を積層していない面に、厚さ70μmのポリエチレンテレフタレート層4を積層させたものである。
【0029】
これら図2及び図3に示した実施例についても、研磨性及び耐熱性が良く、目標とする半導体ウエハ保護用シートが得られた。
【0030】
【発明の効果】
本発明にあっては、単層又は複数層からなる支持体と、支持体上に積層された粘着剤層を有する半導体ウエハ保護用シートであって、支持体が、融点160〜300℃で、引張弾性率0.1〜1.5GPaである耐熱支持層を少なくとも1層有することにより、半導体ウエハを100μm以下の厚さまで研磨できるとともに、半導体ウエハを研磨した後にダイボンディングフィルムを融着させても半導体ウエハが破損しない半導体ウエハ保護用シートが得られた。
【図面の簡単な説明】
【図1】実施例1及び比較例の半導体ウエハ保護用シートを模式的に示した断面図である。
【図2】実施例2の半導体ウエハ保護用シートを模式的に示した断面図である。
【図3】実施例3の半導体ウエハ保護用シートを模式的に示した断面図である。
【符号の説明】
1 支持体
2 粘着剤層
3 耐熱支持層[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a semiconductor wafer protection sheet, and more particularly, a semiconductor wafer protection sheet that can polish a semiconductor wafer to a thickness of 100 μm or less and that does not break even if a die bonding film is fused after polishing the semiconductor wafer. About.
[0002]
[Prior art]
There are silicon wafers, gallium arsenide, and the like as wafers used for manufacturing semiconductor chips, and among these, silicon wafers are frequently used. Silicon wafers are manufactured by thinly slicing high-purity single crystal silicon to a thickness of about 500 to 1000 μm. Recently, IC cards (integrated circuit cards) have become popular and stacked CSPs (chip size packages) have become multilayered. Therefore, further thinning has been desired, and it has been necessary to polish a semiconductor wafer having a thickness of about 350 μm to 100 μm or less.
[0003]
In addition, when the semiconductor chip is mounted on the substrate, a die bonding film is used as an adhesive for stably fixing the semiconductor chip and the substrate. The die bonding film is heat-sealed to a semiconductor wafer. For a semiconductor wafer having a thickness of about 350 μm, the die-bonding film can be fused after the semiconductor wafer protection sheet is peeled off. However, in the case of a semiconductor wafer having a thickness of 100 μm or less, if the semiconductor wafer protection sheet is peeled off, the semiconductor wafer will be damaged by its own weight. Therefore, the die bonding film remains attached with the semiconductor wafer protection sheet attached. It has been required to fuse.
[0004]
Here, as a semiconductor wafer protection sheet for holding a semiconductor wafer when polishing the semiconductor wafer, for example, means of JP-A-2001-123139 is known. This means is that a specific pressure-sensitive adhesive is laminated on a soft support and prevents the pressure-sensitive adhesive from moving to the back surface of the semiconductor wafer.
[0005]
[Problems to be solved by the invention]
However, in the semiconductor wafer protection sheet like this means, when the die bonding film is fused, the support of the semiconductor wafer protection sheet is softened by the heat of fusion, and the semiconductor wafer is not stably held. There was a problem of being damaged.
[0006]
In order to solve this problem, it is conceivable to adopt a hard support as a support. However, simply changing the support to a hard support will alleviate the stress applied to the semiconductor wafer when polishing the semiconductor wafer. A new problem has arisen that the semiconductor wafer is damaged during polishing.
[0007]
Accordingly, an object of the present invention is to provide a semiconductor wafer protection sheet that can polish a semiconductor wafer to a thickness of 100 μm or less and that does not break the semiconductor wafer even if the die bonding film is fused after polishing the semiconductor wafer. is there.
[0008]
[Means for Solving the Problems]
As a result of intensive studies in view of the above, the present inventor is a semiconductor wafer protection sheet having a support composed of a single layer or a plurality of layers and an adhesive layer laminated on the support, wherein the support is The inventors have found that the above-mentioned problems can be solved by having at least one heat-resistant support layer having a melting point of 160 to 300 ° C. and a tensile elastic modulus of 0.1 to 1.5 GPa, thereby completing the present invention.
[0009]
DETAILED DESCRIPTION OF THE INVENTION
If the melting point of the heat-resistant support layer in the sheet for protecting a semiconductor wafer of the present invention is too low, the support is softened by the heat of fusion at the time of fusing the die bonding film, and the semiconductor wafer is damaged. The support becomes hard and the stress generated when the semiconductor wafer is polished cannot be relaxed, and the semiconductor wafer is damaged. For this reason, the melting point of the heat-resistant support layer is preferably in the range of 160 to 300 ° C, and preferably in the range of 180 to 300 ° C. Here, the melting point is a value obtained by measurement according to JIS K 7121, and refers to the temperature at the top of the endothermic peak in the melting curve obtained by the measurement of heat of fusion using a differential scanning calorimeter.
[0010]
If the tensile elastic modulus of the heat-resistant support layer in the sheet for protecting a semiconductor wafer of the present invention is too low, the semiconductor wafer is deformed and damaged by the stress generated during polishing, and if it is too high, it occurs when polishing the semiconductor wafer. As a result, the semiconductor wafer cannot be relieved and the semiconductor wafer is damaged. For this reason, in the tensile elasticity modulus of a heat-resistant support layer, the range of 0.1-1.5 GPa is good, Preferably, the range of 0.1-1.0 GPa is good. Here, the tensile modulus is a value obtained by measurement according to JIS K 7121. A strip-like sample having a width of 10 mm is subjected to a tensile test at an ambient temperature of 23 ° C. and a tensile speed of 100% / min. It refers to the initial elastic modulus obtained from the obtained stress-strain curve.
[0011]
The heat-resistant support layer in the semiconductor wafer protection sheet of the present invention has no problem when used as a single layer. However, when an intervening layer is provided between the heat-resistant support layer and the pressure-sensitive adhesive layer, it is preferable that the intervening layer has a total thickness of 75 μm or less. This is because if the intervening layer is too thick, the above-mentioned effect of the heat-resistant support layer cannot be obtained. In addition, it does not specifically limit about the layer laminated | stacked on the surface which does not laminate | stack the adhesive layer of a heat-resistant support layer.
[0012]
As a material that can be used as the heat-resistant support layer of the semiconductor wafer protection sheet of the present invention, any material can be selected and used as long as the melting point and the tensile modulus are the above values. Specifically, polybutylene terephthalate, poly-1, 4 -Cyclohexane dimethylene terephthalate, polybutylene naphthalate, nylon and the like.
[0013]
The support for the semiconductor wafer protection sheet of the present invention requires that the ultraviolet ray irradiated from the support side reaches the pressure-sensitive adhesive layer when the pressure-sensitive adhesive layer described later is an ultraviolet-curable pressure-sensitive adhesive. Must be permeable. Moreover, the support body must have melting | fusing point of temperature higher than the temperature used at the time of heating, when the adhesive layer mentioned later is a thermosetting adhesive or a heating foaming adhesive. In addition, although it does not specifically limit in the thickness of a support body, What is necessary is just to select suitably from the range of 5-500 micrometers employ | adopted with the sheet | seat for general semiconductor wafer protection.
[0014]
For the pressure-sensitive adhesive layer of the semiconductor wafer protection sheet of the present invention, a general pressure-sensitive pressure-sensitive adhesive, ultraviolet curable pressure-sensitive adhesive, heat-curable pressure-sensitive adhesive, or the like can be used. As the pressure-sensitive adhesive, conventionally known adhesives such as acrylic, rubber, and silicon are used. In addition, as a UV curable pressure sensitive adhesive, a base polymer, a UV curable compound, a UV curable initiator, etc. are used. As a heat curable pressure sensitive adhesive, a base polymer, a heat curable compound, a heat curable initiator, etc. Is used. Here, as the base polymer of the ultraviolet curable adhesive and the heat curable adhesive, a general acrylic adhesive, rubber adhesive, or the like can be used.
[0015]
In order to start the curing of the ultraviolet curable adhesive, it is necessary to irradiate with ultraviolet rays. Moreover, about a thermosetting adhesive and a heat-foaming adhesive, heating is needed at the time of peeling. The timing of ultraviolet irradiation and heating is performed after polishing and transporting the semiconductor wafer. The thickness of the pressure-sensitive adhesive layer is not particularly limited, but may be appropriately selected from a range of 5 to 200 μm that is employed in a general semiconductor wafer protection sheet.
[0016]
The sheet for protecting a semiconductor wafer according to the present invention is stored with a release paper or release sheet such as a polyethylene laminated paper or a release-treated plastic film in close contact with the adhesive surface of the adhesive layer as necessary.
[0017]
In the present invention, it is a sheet for protecting a semiconductor wafer having a support composed of a single layer or a plurality of layers and an adhesive layer laminated on the support, and the support has a melting point of 160 to 300 ° C. By having at least one heat-resistant support layer having a tensile modulus of 0.1 to 1.5 GPa, the semiconductor wafer can be polished to a thickness of 100 μm or less, and the die bonding film can be fused after polishing the semiconductor wafer. A semiconductor wafer protection sheet was obtained in which the semiconductor wafer was not damaged.
[0018]
【Example】
Example 1 of the semiconductor wafer protection sheet according to the present invention will be described with reference to Table 1 and FIG. Here, Table 1 shows the composition and characteristics of the semiconductor wafer protection sheets of the present example and the comparative example, and FIG. 1 schematically shows the semiconductor wafer protection sheets of the present example and the comparative example. It is sectional drawing shown.
[0019]
[Table 1]
Figure 0004568465
[0020]
Here, the “abrasiveness” in the characteristic values in Table 1 is a polishing machine (back grinder DFG-850 manufactured by DISCO Corporation) after a semiconductor wafer having a diameter of 8 inches and a thickness of 700 μm is pasted on a semiconductor wafer protection sheet. After polishing until the thickness of the semiconductor wafer becomes 25 μm, the state of the semiconductor wafer is visually observed. In terms of abrasiveness, the case where the semiconductor wafer was not damaged was evaluated as ◯, and the case where damage was confirmed was evaluated as X. The number of test samples was 30.
[0021]
Further, the “heat resistance” in the characteristic values of Table 1 indicates that the sample that passed the abrasiveness test was heat-treated under the conditions (140 ° C., 10 seconds) for fusing the die bonding film, and then visually observed on the semiconductor wafer. The state is observed. In terms of heat resistance, the semiconductor wafers that were not damaged were evaluated as ◯, and those that were confirmed to be damaged were evaluated as X. Note that the number of samples in the test was 30 as in the case of abrasiveness.
[0022]
As shown in FIG. 1, the sheet for protecting a semiconductor wafer of this example has a support 1 composed of a single heat-resistant support layer 3 and an adhesive layer 2 laminated on the support 1. Here, the heat-resistant support layer 3 is made of polybutylene terephthalate having a melting point of 220 ° C., a tensile elastic modulus of 0.3 GPa, and a thickness of 150 μm. The pressure-sensitive adhesive layer 2 is an ultraviolet curable pressure-sensitive adhesive having a thickness of 20 μm, 100 parts by weight of a copolymer of ethyl acrylate / 2-ethylhexyl acrylate as a base polymer, and hexafunctionality as an ultraviolet curable compound. 120 parts by weight of urethane acrylate oligomer, 8 parts by weight of benzoin isopropyl ether as an ultraviolet curing initiator, and 3 parts by weight of 2,4-toluylene diisocyanate as a crosslinking agent were obtained. Unless otherwise specified, the following examples and comparative examples are the same as the present examples.
[0023]
In this example, the polishing property and heat resistance were good, and the target semiconductor wafer protection sheet was obtained.
[0024]
Comparative Example 1 and Comparative Example 2 will be described. In Comparative Example 1, the heat-resistant support layer 3 of Example 1 was changed to polyethylene having a melting point of 90 ° C., and in Comparative Example 2, the heat-resistant support layer 3 of Example 1 was changed to polytetrafluoroethylene having a melting point of 330 ° C. It is a thing.
[0025]
In Comparative Example 1, the heat resistance was poor, and in Comparative Example 2, the polishing property was poor.
[0026]
Comparative Example 3 and Comparative Example 4 will be described. In Comparative Example 3, the heat-resistant support layer 3 of Example 1 was changed to ethylene vinyl acetate having a tensile elastic modulus of 0.07 GPa, and in Comparative Example 4, the heat-resistant support layer 3 of Example 1 was changed to a tensile elastic modulus of 3. It is changed to polyethylene terephthalate of 0 GPa.
[0027]
In Comparative Example 3 and Comparative Example 4, the abrasiveness was poor.
[0028]
Examples 2 and 3 according to the present invention will be described with reference to FIGS. In Example 2, as shown in FIG. 2, a polyethylene terephthalate layer 4 having a thickness of 70 μm is interposed between the heat-resistant support layer 3 and the pressure-sensitive adhesive layer 2 in Example 1, and Example 3 As shown in FIG. 3, a polyethylene terephthalate layer 4 having a thickness of 70 μm is laminated on the surface of the heat-resistant support layer 3 in Example 1 on which the pressure-sensitive adhesive layer 2 is not laminated.
[0029]
2 and 3 also had good polishing properties and heat resistance, and a target semiconductor wafer protection sheet was obtained.
[0030]
【The invention's effect】
In the present invention, it is a sheet for protecting a semiconductor wafer having a support composed of a single layer or a plurality of layers and an adhesive layer laminated on the support, and the support has a melting point of 160 to 300 ° C. By having at least one heat-resistant support layer having a tensile modulus of 0.1 to 1.5 GPa, the semiconductor wafer can be polished to a thickness of 100 μm or less, and the die bonding film can be fused after polishing the semiconductor wafer. A semiconductor wafer protection sheet was obtained in which the semiconductor wafer was not damaged.
[Brief description of the drawings]
FIG. 1 is a cross-sectional view schematically showing a semiconductor wafer protection sheet of Example 1 and a comparative example.
2 is a cross-sectional view schematically showing a semiconductor wafer protection sheet of Example 2. FIG.
3 is a cross-sectional view schematically showing a semiconductor wafer protection sheet of Example 3. FIG.
[Explanation of symbols]
1 Support 2 Adhesive Layer 3 Heat-resistant Support Layer

Claims (3)

単層又は複数層からなる支持体と、該支持体上に積層された粘着剤層を有し、支持体が、融点160〜300℃で、引張弾性率0.1〜1.5GPaの耐熱支持層を少なくとも1層有する半導体ウエハ保護用シートを用い、半導体ウエハ保護用シートにウエハを貼り付けた状態で半導体ウエハを100μm以下(但し100μmを除く)に研磨することを特徴とする半導体ウエハの研磨方法。A heat-resistant support having a support composed of a single layer or a plurality of layers and an adhesive layer laminated on the support, the support having a melting point of 160 to 300 ° C. and a tensile elastic modulus of 0.1 to 1.5 GPa Polishing a semiconductor wafer characterized by using a semiconductor wafer protection sheet having at least one layer and polishing the semiconductor wafer to 100 μm or less (excluding 100 μm) in a state where the wafer is attached to the semiconductor wafer protection sheet Method. ポリブチレンテレフタレートを含有する耐熱支持層を用いた請求項1に記載の半導体ウエハの研磨方法。 The method for polishing a semiconductor wafer according to claim 1, wherein a heat-resistant support layer containing polybutylene terephthalate is used . 請求項1又は請求項2に記載の半導体ウエハ保護用シート。The semiconductor wafer protection sheet according to claim 1 or 2.
JP2001378066A 2001-12-12 2001-12-12 Semiconductor wafer protection sheet Expired - Fee Related JP4568465B2 (en)

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JP4519409B2 (en) * 2003-02-24 2010-08-04 リンテック株式会社 Adhesive sheet and method of using the same
JP4511840B2 (en) * 2004-01-13 2010-07-28 三井化学株式会社 Adhesive film and method for protecting semiconductor wafer using the same
JP5006015B2 (en) * 2006-12-05 2012-08-22 古河電気工業株式会社 Semiconductor wafer surface protective tape and semiconductor chip manufacturing method using the same
JP6195839B2 (en) * 2012-10-19 2017-09-13 リンテック株式会社 Adhesive sheet for processing electronic parts and method for manufacturing semiconductor device
JP7311284B2 (en) * 2019-03-22 2023-07-19 日東電工株式会社 back grind tape

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