JP4538452B2 - 戦争兵器を中和するための活性化蒸着処理 - Google Patents
戦争兵器を中和するための活性化蒸着処理 Download PDFInfo
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- JP4538452B2 JP4538452B2 JP2006513306A JP2006513306A JP4538452B2 JP 4538452 B2 JP4538452 B2 JP 4538452B2 JP 2006513306 A JP2006513306 A JP 2006513306A JP 2006513306 A JP2006513306 A JP 2006513306A JP 4538452 B2 JP4538452 B2 JP 4538452B2
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- Prior art keywords
- peroxide
- ammonia
- hydrogen peroxide
- nitrogen
- concentration
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
- A62D3/30—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
- A62D3/30—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents
- A62D3/38—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents by oxidation; by combustion
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
- A61L2/20—Gaseous substances, e.g. vapours
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
- A61L2/20—Gaseous substances, e.g. vapours
- A61L2/208—Hydrogen peroxide
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
- A62D3/30—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents
- A62D3/36—Detoxification by using acid or alkaline reagents
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2202/00—Aspects relating to methods or apparatus for disinfecting or sterilising materials or objects
- A61L2202/20—Targets to be treated
- A61L2202/23—Containers, e.g. vials, bottles, syringes, mail
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/02—Chemical warfare substances, e.g. cholinesterase inhibitors
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- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Toxicology (AREA)
- Emergency Management (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Business, Economics & Management (AREA)
- Animal Behavior & Ethology (AREA)
- Apparatus For Disinfection Or Sterilisation (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Treating Waste Gases (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Medicines Containing Plant Substances (AREA)
- Preparation Of Fruits And Vegetables (AREA)
Description
本明細書中に記載される本発明は、米国政府によって、または米国政府のために製造、認可、そして使用され得る。
本出願は、生物兵器および化学兵器を不活性化する技術に関する。本発明は、G型、V型およびH型の神経剤、ならびに生物兵器に関連する特定の適用を見出す。
本発明の1つの局面に従って、病原性化学因子を不活性化する方法が提供される。その方法は、その病原性化学因子を、蒸気形態の過酸化物および気体形態の窒素含有化合物に供する工程を包含し、その過酸化物のその窒素含有化合物に対する比は、1:1と1:0.0001との間である。その窒素含有化合物は、以下の一般式:
図1を参照すると、処理囲い10は、生物学的に活性な物質(特に、生物兵器もしくは化学兵器)で潜在的に汚染された構造体を受容するか、またはこの囲い自体が、この構造体の一部分である。代表的に、生物学的に活性な物質としては、病原体、生体毒素、プリオン、胞子、化学因子などが挙げられる。代表的な化学因子としては、H型水疱剤(例えば、マスタードガス)、ならびにV型神経剤およびG型神経剤が挙げられる。
によって記載され得る。ここで、R1、R2、およびR3は、独立して、Hおよびアルキル基から選択される。このアルキル基は、置換されていても置換されていなくてもよい。適切な置換基は、窒素含有化合物の触媒活性に過度に影響を与えない置換基である。この窒素含有化合物は、好ましくは、過酸化水素蒸気相において、または生物学的に活性な物質と接触して、この因子の過酸化物分解のための促進剤として働くために充分な時間にわたって残存し得る化合物である。適切なアルキルアミンとしては、メチルアミン、エチルアミン、プロピルアミン、ブチルアミン、ジメチルアミン、メチルエチルアミン、ジエチルアミン、これらの組み合わせなどが挙げられる。
Claims (11)
- 請求項1に記載の方法であって、前記病原性化学因子が、ジ(2−クロロエチル)スルフィド、メチルホスホノフルオリド酸 1,2,2−トリメチルプロピルエステル、およびo−エチル−S−(2−ジイソプロピルアミノエチル)メチルホスホノ−チオレートからなる群より選択される、方法。
- 請求項1に記載の方法であって、前記過酸化物が、過酸化水素を含むことによってさらに特徴付けられる、方法。
- 請求項1に記載の方法であって、前記窒素含有化合物が、アンモニアを含むことによってさらに特徴付けられる、方法。
- 請求項1に記載の方法であって、前記窒素含有化合物が、アルキルアミンを含むことによってさらに特徴付けられる、方法。
- 請求項1〜5のいずれか1項に記載の方法であって、前記窒素含有化合物および過酸化物が、気体混合物の形態にあることによってさらに特徴付けられる、方法。
- 請求項6に記載の方法であって、前記窒素含有化合物が、前記気体混合物中で少なくとも1ppmで100ppm未満の濃度であることによってさらに特徴付けられる、方法。
- 請求項6または7に記載の方法であって、前記過酸化物が、前記気体混合物中で少なくとも50ppmで1000ppm未満の濃度であることによってさらに特徴付けられる、方法。
- 請求項6〜8のいずれか1項に記載の方法であって、前記気体混合物が、キャリアガスをさらに含有することによってさらに特徴付けられる、方法。
- 請求項1〜9のいずれか1項に記載の方法であって、供する工程の間、15℃〜30℃に温度を維持することによってさらに特徴付けられる、方法。
- メチルホスホノフルオリド酸 1,2,2−トリメチルプロピルエステルにより汚染された部材の除染のための方法であって、該方法は、
囲い(10)中の該部材と、過酸化物およびアンモニアを含有する蒸気とを、メチルホスホノフルオリド酸 1,2,2−トリメチルプロピルエステルの濃度をその最初の濃度の1%未満に減少するために充分な時間、接触させる工程
によってさらに特徴付けられ、該濃度がその最初の濃度の1%に達する時間は、6時間未満である、方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/422,472 US7102052B2 (en) | 2003-04-24 | 2003-04-24 | Activated vapor treatment for neutralizing warfare agents |
US51986803P | 2003-11-13 | 2003-11-13 | |
PCT/US2004/012744 WO2005035067A2 (en) | 2003-04-24 | 2004-04-23 | Activated vapor treatment for neutralizing warfare agents |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2006524551A JP2006524551A (ja) | 2006-11-02 |
JP4538452B2 true JP4538452B2 (ja) | 2010-09-08 |
JP2006524551A5 JP2006524551A5 (ja) | 2011-02-24 |
Family
ID=34437231
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2006513306A Expired - Fee Related JP4538452B2 (ja) | 2003-04-24 | 2004-04-23 | 戦争兵器を中和するための活性化蒸着処理 |
Country Status (10)
Country | Link |
---|---|
US (2) | US7629500B2 (ja) |
EP (1) | EP1615703B1 (ja) |
JP (1) | JP4538452B2 (ja) |
KR (1) | KR20060017758A (ja) |
AT (1) | ATE465787T1 (ja) |
AU (1) | AU2004279294B2 (ja) |
CA (1) | CA2523604C (ja) |
DE (1) | DE602004026852D1 (ja) |
ES (1) | ES2341010T3 (ja) |
WO (1) | WO2005035067A2 (ja) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
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JP4255385B2 (ja) * | 2002-04-24 | 2009-04-15 | ステリス インコーポレイテッド | 活性化酸化蒸気処理システムおよび方法 |
US7629500B2 (en) * | 2003-04-24 | 2009-12-08 | Steris Inc | Activated vapor treatment for neutralizing warfare agents |
WO2008118564A2 (en) | 2007-03-06 | 2008-10-02 | Steris Inc. | Decontamination unit and process |
GB0710340D0 (en) * | 2007-05-30 | 2007-07-11 | Bioquell Uk Ltd | Decontamination of biological and chemical agents |
AU2011213782B2 (en) * | 2007-06-15 | 2012-05-10 | American Sterilizer Company | Method and apparatus for removal of vaporized hydrogen peroxide from a region |
US7850925B2 (en) * | 2007-06-15 | 2010-12-14 | American Sterilizer Company | Apparatus for removal of vaporized hydrogen peroxide from a region |
US20110171064A1 (en) * | 2009-04-30 | 2011-07-14 | Teledyne Brown Engineering, Inc. | Hydrogen peroxide and ammonia decontamination of a foreign agent |
JP2010269032A (ja) * | 2009-05-22 | 2010-12-02 | Asahi Kasei Chemicals Corp | 新規除染方法及び装置 |
US8357331B2 (en) * | 2009-09-30 | 2013-01-22 | American Sterilizer Company | Feed back and dose control of distributed decontamination systems |
WO2011047127A1 (en) | 2009-10-15 | 2011-04-21 | Minntech Corporation | Room fogging disinfection system |
JP2013512080A (ja) | 2009-12-03 | 2013-04-11 | ミンテック コーポレーション | 医療装置を噴霧によって浄化する容器及びシステム |
US20110183598A1 (en) * | 2010-01-26 | 2011-07-28 | Holt Alton R | Method and System for Controlling Microbiological Contamination in Buildings |
KR20120140238A (ko) | 2010-02-24 | 2012-12-28 | 바이오? 유케이 리미티드 | 화학/생물학 병기제의 처리 |
JP5735761B2 (ja) * | 2010-07-26 | 2015-06-17 | 株式会社Ihi | 有毒物質の除染装置 |
US9017607B2 (en) | 2011-05-27 | 2015-04-28 | Medivators Inc. | Decontamination system including environmental control using a decontaminating substance |
GB2492819A (en) * | 2011-07-13 | 2013-01-16 | Bioquell Uk Ltd | Indicators for confirming decontamination treatment of chemical/biological warfare agents |
US10039850B2 (en) | 2016-01-13 | 2018-08-07 | Sterio3, Llc | Sterilization device and methods |
US9849204B2 (en) | 2016-01-13 | 2017-12-26 | Sterio3, Llc | Sterilization device and methods |
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-
2004
- 2004-04-23 US US10/554,223 patent/US7629500B2/en active Active
- 2004-04-23 DE DE602004026852T patent/DE602004026852D1/de not_active Expired - Lifetime
- 2004-04-23 JP JP2006513306A patent/JP4538452B2/ja not_active Expired - Fee Related
- 2004-04-23 KR KR1020057020159A patent/KR20060017758A/ko not_active Application Discontinuation
- 2004-04-23 EP EP04809340A patent/EP1615703B1/en not_active Expired - Lifetime
- 2004-04-23 AT AT04809340T patent/ATE465787T1/de not_active IP Right Cessation
- 2004-04-23 WO PCT/US2004/012744 patent/WO2005035067A2/en active Search and Examination
- 2004-04-23 ES ES04809340T patent/ES2341010T3/es not_active Expired - Lifetime
- 2004-04-23 AU AU2004279294A patent/AU2004279294B2/en not_active Expired
- 2004-04-23 CA CA2523604A patent/CA2523604C/en not_active Expired - Lifetime
-
2009
- 2009-07-08 US US12/499,353 patent/US8025848B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
ES2341010T3 (es) | 2010-06-14 |
CA2523604C (en) | 2012-09-11 |
KR20060017758A (ko) | 2006-02-27 |
WO2005035067A3 (en) | 2005-11-24 |
WO2005035067A2 (en) | 2005-04-21 |
CA2523604A1 (en) | 2005-04-21 |
EP1615703A2 (en) | 2006-01-18 |
ATE465787T1 (de) | 2010-05-15 |
AU2004279294A1 (en) | 2005-04-21 |
US8025848B2 (en) | 2011-09-27 |
AU2004279294B2 (en) | 2009-01-08 |
JP2006524551A (ja) | 2006-11-02 |
US7629500B2 (en) | 2009-12-08 |
US20100074804A1 (en) | 2010-03-25 |
EP1615703B1 (en) | 2010-04-28 |
DE602004026852D1 (de) | 2010-06-10 |
US20060205991A1 (en) | 2006-09-14 |
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