JP4537638B2 - 高レジリエンスフォームを製造するための方法 - Google Patents
高レジリエンスフォームを製造するための方法 Download PDFInfo
- Publication number
- JP4537638B2 JP4537638B2 JP2001535433A JP2001535433A JP4537638B2 JP 4537638 B2 JP4537638 B2 JP 4537638B2 JP 2001535433 A JP2001535433 A JP 2001535433A JP 2001535433 A JP2001535433 A JP 2001535433A JP 4537638 B2 JP4537638 B2 JP 4537638B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- polyol
- polyols
- content
- functionality
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000006260 foam Substances 0.000 title description 22
- 238000004519 manufacturing process Methods 0.000 title description 6
- 229920005862 polyol Polymers 0.000 claims description 89
- 150000003077 polyols Chemical class 0.000 claims description 89
- 238000000034 method Methods 0.000 claims description 26
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 18
- 229920001228 polyisocyanate Polymers 0.000 claims description 18
- 239000005056 polyisocyanate Substances 0.000 claims description 18
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 14
- 238000009472 formulation Methods 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 6
- 229920005830 Polyurethane Foam Polymers 0.000 claims description 5
- 239000011496 polyurethane foam Substances 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 3
- 239000012948 isocyanate Substances 0.000 description 18
- 150000002513 isocyanates Chemical class 0.000 description 17
- 238000006243 chemical reaction Methods 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- -1 that of water Chemical compound 0.000 description 4
- 239000004604 Blowing Agent Substances 0.000 description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 125000005702 oxyalkylene group Chemical group 0.000 description 3
- 125000006353 oxyethylene group Chemical group 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 150000001718 carbodiimides Chemical class 0.000 description 2
- 210000004027 cell Anatomy 0.000 description 2
- 230000001413 cellular effect Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229920000768 polyamine Chemical class 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- JIABEENURMZTTI-UHFFFAOYSA-N 1-isocyanato-2-[(2-isocyanatophenyl)methyl]benzene Chemical compound O=C=NC1=CC=CC=C1CC1=CC=CC=C1N=C=O JIABEENURMZTTI-UHFFFAOYSA-N 0.000 description 1
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000004970 Chain extender Substances 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 241001425800 Pipa Species 0.000 description 1
- 229920002396 Polyurea Polymers 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical group NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 210000000497 foam cell Anatomy 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 150000003335 secondary amines Chemical group 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 150000004072 triols Chemical class 0.000 description 1
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical compound NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S521/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S521/904—Polyurethane cellular product having high resiliency or cold cure property
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP99121697 | 1999-11-02 | ||
| EP99121697.9 | 1999-11-02 | ||
| PCT/EP2000/009731 WO2001032735A1 (en) | 1999-11-02 | 2000-10-05 | Process for making high resilience foams |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2003514040A JP2003514040A (ja) | 2003-04-15 |
| JP2003514040A5 JP2003514040A5 (enExample) | 2005-04-21 |
| JP4537638B2 true JP4537638B2 (ja) | 2010-09-01 |
Family
ID=8239315
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001535433A Expired - Fee Related JP4537638B2 (ja) | 1999-11-02 | 2000-10-05 | 高レジリエンスフォームを製造するための方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US6593387B2 (enExample) |
| EP (1) | EP1240227B1 (enExample) |
| JP (1) | JP4537638B2 (enExample) |
| CN (1) | CN1174014C (enExample) |
| AR (1) | AR026316A1 (enExample) |
| AU (1) | AU7662100A (enExample) |
| WO (1) | WO2001032735A1 (enExample) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001032736A1 (en) * | 1999-11-02 | 2001-05-10 | Huntsman International Llc | Process for making visco-elastic foams, polyols blend and reaction system useful therefor |
| BR0107571B1 (pt) | 2000-02-14 | 2010-10-19 | processo para preparar uma espuma de poliuretano flexìvel, e, espuma de poliuretano flexìvel moldada. | |
| ITMI20010357A1 (it) * | 2001-02-22 | 2002-08-22 | Enichem Spa | Composizioni isocianiche e loro impiego nella preparazione di espansipoliuretanici a migliorate caratteristiche fisico-meccaniche |
| EP1234843A1 (en) | 2001-02-26 | 2002-08-28 | Huntsman International Llc | Process for preparing a flexible polyurethane foam |
| WO2004014976A1 (en) | 2002-08-02 | 2004-02-19 | Huntsman International Llc | Prepolymer, polyol composition and process for making a flexible foam |
| US20050131095A1 (en) * | 2002-08-02 | 2005-06-16 | Jianming Yu | Novel polyols |
| US6784218B1 (en) * | 2003-03-19 | 2004-08-31 | Basf Corporation | Method of forming high resilience slabstock polyurethane foam displaying latex-like characteristics |
| US6797736B1 (en) * | 2003-03-19 | 2004-09-28 | Basf Corporation | Method of forming high resilience slabstock polyurethane foam |
| US20050038132A1 (en) * | 2003-03-19 | 2005-02-17 | Raghuram Gummaraju | Composition for forming a foamed article and an article of furniture having the foamed article disposed therein |
| US7326738B2 (en) | 2004-07-29 | 2008-02-05 | Basf Corporation | Composition and process for forming a flexible polyurethane foam sealing device |
| FR2899230B1 (fr) * | 2006-03-29 | 2008-06-20 | Faurecia Sieges Automobile | Procede de preparation de mousse de polyurethanne flexible de haute resilience |
| US20090012195A1 (en) | 2007-07-05 | 2009-01-08 | Neff Raymond A | Resin composition for use in forming a polyurethane article with increased comfort |
| EP2172501A1 (en) * | 2008-09-24 | 2010-04-07 | Recticel | Process for the preparation of flexible, resilient polyurethane foam and the resulting foam |
| US8901187B1 (en) | 2008-12-19 | 2014-12-02 | Hickory Springs Manufacturing Company | High resilience flexible polyurethane foam using MDI |
| US8604094B2 (en) | 2008-12-23 | 2013-12-10 | Basf Se | Flexible polyurethane foam and method of producing same |
| US8906975B1 (en) | 2009-02-09 | 2014-12-09 | Hickory Springs Manufacturing Company | Conventional flexible polyurethane foam using MDI |
| JP4920051B2 (ja) * | 2009-02-25 | 2012-04-18 | 株式会社日立製作所 | 酸素燃焼ボイラプラント及び酸素燃焼ボイラプラントの運転方法 |
| AU2014318648B2 (en) * | 2013-09-13 | 2017-09-07 | Dow Global Technologies Llc | PIPA polyol based viscoelastic foams |
| CN108137773B (zh) * | 2015-10-08 | 2021-10-15 | 陶氏环球技术有限责任公司 | 由具有主要仲羟基的高官能度、高当量多元醇制备的高弹性聚氨基甲酸酯泡沫 |
| WO2018022368A1 (en) | 2016-07-29 | 2018-02-01 | Resinate Materials Group, Inc. | Sustainable polyester polyol compositions |
| US10155837B2 (en) | 2016-07-29 | 2018-12-18 | Resinate Materials Group, Inc. | Sustainable polyester polyol compositions |
| CN110753710B (zh) | 2017-06-27 | 2022-07-26 | 巴斯夫欧洲公司 | 具有改善的透气性的软质聚氨酯泡沫 |
| WO2020126586A1 (de) | 2018-12-19 | 2020-06-25 | Basf Se | Polyurethan-weichschäume mit verbesserten dauergebrauchseigenschaften |
| CN110283293B (zh) * | 2019-06-24 | 2021-12-24 | 红宝丽集团股份有限公司 | 采用端异氰酸酯基预聚体制备的仿乳胶聚氨酯软质泡沫 |
| CN113583205B (zh) * | 2021-06-29 | 2023-05-09 | 佳化化学科技发展（上海）有限公司 | 一种慢回弹海绵及其制备方法和应用 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3721058A1 (de) * | 1987-06-26 | 1989-01-05 | Bayer Ag | Verfahren zur herstellung von kalthaertenden polyurethan-weichformschaumstoffen |
| DE3806476A1 (de) | 1988-03-01 | 1989-09-14 | Bayer Ag | Verfahren zur herstellung von kalthaertenden polyurethan-weichformschaumstoffen mit hervorragenden daempfungseigenschaften |
| GB9126741D0 (en) * | 1991-12-17 | 1992-02-12 | Ici Plc | Polyurethane foams |
| GB9126740D0 (en) * | 1991-12-17 | 1992-02-12 | Ici Plc | Polyol compositions |
| DE4205934A1 (de) * | 1992-02-27 | 1993-09-02 | Basf Ag | Verfahren zur herstellung von fluorchlorkohlenwasserstoff freien, niedrigdichten polyurethan-weichschaumstoffen und weichelastischen polyurethan-formschaumstoffen sowie hierfuer verwendbare, mit urethangruppen modifizierte polyisocyanatmischungen auf diphenylmethan-diisocyanatbasis |
| GB9216631D0 (en) * | 1992-08-05 | 1992-09-16 | Ici Plc | Reaction system for preparing microcellular elastomers |
| GB9301995D0 (en) * | 1993-02-02 | 1993-03-17 | Ici Plc | Process for making flexible foams |
| US5565498A (en) | 1993-02-02 | 1996-10-15 | Imperial Chemical Industries Plc | Process for making flexible foams |
| US5459170A (en) * | 1993-04-13 | 1995-10-17 | Imperial Chemical Industries Plc | Polyurethane foams |
| GB9307565D0 (en) * | 1993-04-13 | 1993-06-02 | Ici Plc | Polyurethane foams |
| GB9311838D0 (en) * | 1993-06-08 | 1993-07-28 | Ici Plc | Process for making flexible foams |
| ATE182341T1 (de) * | 1994-11-22 | 1999-08-15 | Ici Plc | Verfahren zur herstellung von weichschäumen |
| US6031010A (en) * | 1997-08-11 | 2000-02-29 | Imperial Chemical Industries Plc | Polyurethane foam composition having improved flex fatigue |
-
2000
- 2000-10-05 CN CNB008149836A patent/CN1174014C/zh not_active Expired - Lifetime
- 2000-10-05 EP EP00966115A patent/EP1240227B1/en not_active Expired - Lifetime
- 2000-10-05 AU AU76621/00A patent/AU7662100A/en not_active Abandoned
- 2000-10-05 JP JP2001535433A patent/JP4537638B2/ja not_active Expired - Fee Related
- 2000-10-05 WO PCT/EP2000/009731 patent/WO2001032735A1/en not_active Ceased
- 2000-10-31 AR ARP000105752A patent/AR026316A1/es unknown
-
2002
- 2002-04-12 US US10/122,454 patent/US6593387B2/en not_active Expired - Lifetime
-
2003
- 2003-06-11 US US10/458,901 patent/US6784217B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| WO2001032735A1 (en) | 2001-05-10 |
| EP1240227A1 (en) | 2002-09-18 |
| US6784217B2 (en) | 2004-08-31 |
| AR026316A1 (es) | 2003-02-05 |
| JP2003514040A (ja) | 2003-04-15 |
| AU7662100A (en) | 2001-05-14 |
| US20030087977A1 (en) | 2003-05-08 |
| CN1384846A (zh) | 2002-12-11 |
| CN1174014C (zh) | 2004-11-03 |
| US6593387B2 (en) | 2003-07-15 |
| EP1240227B1 (en) | 2012-05-09 |
| US20030212155A1 (en) | 2003-11-13 |
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