JP4489015B2 - 毛髪洗浄剤 - Google Patents
毛髪洗浄剤 Download PDFInfo
- Publication number
- JP4489015B2 JP4489015B2 JP2005380390A JP2005380390A JP4489015B2 JP 4489015 B2 JP4489015 B2 JP 4489015B2 JP 2005380390 A JP2005380390 A JP 2005380390A JP 2005380390 A JP2005380390 A JP 2005380390A JP 4489015 B2 JP4489015 B2 JP 4489015B2
- Authority
- JP
- Japan
- Prior art keywords
- hair
- acid
- weight
- alkyl
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 210000004209 hair Anatomy 0.000 title claims description 89
- -1 halide ion Chemical class 0.000 claims description 56
- 150000003839 salts Chemical class 0.000 claims description 34
- 239000003599 detergent Substances 0.000 claims description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- 125000004432 carbon atom Chemical group C* 0.000 claims description 18
- 125000000217 alkyl group Chemical group 0.000 claims description 16
- 239000002253 acid Substances 0.000 claims description 12
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 7
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 6
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 6
- 239000003945 anionic surfactant Substances 0.000 claims description 5
- 150000007524 organic acids Chemical class 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- 125000003342 alkenyl group Chemical group 0.000 claims description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 3
- 229920006395 saturated elastomer Polymers 0.000 claims description 3
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 2
- 125000005362 aryl sulfone group Chemical group 0.000 claims description 2
- 150000002500 ions Chemical class 0.000 claims description 2
- 229930195734 saturated hydrocarbon Natural products 0.000 claims description 2
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 31
- 239000000194 fatty acid Substances 0.000 description 31
- 229930195729 fatty acid Natural products 0.000 description 31
- 229920001296 polysiloxane Polymers 0.000 description 28
- 150000004665 fatty acids Chemical class 0.000 description 20
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
- 238000005406 washing Methods 0.000 description 18
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 17
- 239000003795 chemical substances by application Substances 0.000 description 14
- 239000006260 foam Substances 0.000 description 12
- 229920003171 Poly (ethylene oxide) Chemical group 0.000 description 11
- 229920001577 copolymer Polymers 0.000 description 11
- 238000001035 drying Methods 0.000 description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- 239000000284 extract Substances 0.000 description 10
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
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- 239000012459 cleaning agent Substances 0.000 description 8
- 238000011156 evaluation Methods 0.000 description 8
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 7
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 7
- 239000004166 Lanolin Substances 0.000 description 7
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 7
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 7
- 229960003237 betaine Drugs 0.000 description 7
- 229920006317 cationic polymer Polymers 0.000 description 7
- 235000019388 lanolin Nutrition 0.000 description 7
- 229940039717 lanolin Drugs 0.000 description 7
- 239000001630 malic acid Substances 0.000 description 7
- 235000011090 malic acid Nutrition 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
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- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 6
- 230000037308 hair color Effects 0.000 description 6
- 150000002430 hydrocarbons Chemical group 0.000 description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 6
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 6
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 6
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 5
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 5
- 238000009825 accumulation Methods 0.000 description 5
- 239000003093 cationic surfactant Substances 0.000 description 5
- 239000003240 coconut oil Substances 0.000 description 5
- 235000019864 coconut oil Nutrition 0.000 description 5
- 230000003750 conditioning effect Effects 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 5
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 5
- 239000011049 pearl Substances 0.000 description 5
- 239000002453 shampoo Substances 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- KIWBPDUYBMNFTB-UHFFFAOYSA-N Ethyl hydrogen sulfate Chemical compound CCOS(O)(=O)=O KIWBPDUYBMNFTB-UHFFFAOYSA-N 0.000 description 4
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- JBFHTYHTHYHCDJ-UHFFFAOYSA-N gamma-caprolactone Chemical compound CCC1CCC(=O)O1 JBFHTYHTHYHCDJ-UHFFFAOYSA-N 0.000 description 4
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 239000003002 pH adjusting agent Substances 0.000 description 4
- 229920001451 polypropylene glycol Polymers 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- 230000008961 swelling Effects 0.000 description 4
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 3
- WGVGLSURTKMQQC-UHFFFAOYSA-N 3-aminopropyl-ethyl-dimethylazanium Chemical compound CC[N+](C)(C)CCCN WGVGLSURTKMQQC-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 3
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 229920002907 Guar gum Polymers 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 239000005639 Lauric acid Substances 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 229920006322 acrylamide copolymer Polymers 0.000 description 3
- 125000002252 acyl group Chemical group 0.000 description 3
- 239000001361 adipic acid Substances 0.000 description 3
- 235000011037 adipic acid Nutrition 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 3
- 239000002280 amphoteric surfactant Substances 0.000 description 3
- 235000019445 benzyl alcohol Nutrition 0.000 description 3
- 239000004359 castor oil Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 239000000665 guar gum Substances 0.000 description 3
- 235000010417 guar gum Nutrition 0.000 description 3
- 229960002154 guar gum Drugs 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 230000001965 increasing effect Effects 0.000 description 3
- 239000004310 lactic acid Substances 0.000 description 3
- 235000014655 lactic acid Nutrition 0.000 description 3
- 150000002596 lactones Chemical class 0.000 description 3
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 3
- 229940043348 myristyl alcohol Drugs 0.000 description 3
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- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 3
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- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
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- 102000004169 proteins and genes Human genes 0.000 description 3
- 229960004889 salicylic acid Drugs 0.000 description 3
- 239000004034 viscosity adjusting agent Substances 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- OOCCDEMITAIZTP-QPJJXVBHSA-N (E)-cinnamyl alcohol Chemical compound OC\C=C\C1=CC=CC=C1 OOCCDEMITAIZTP-QPJJXVBHSA-N 0.000 description 2
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- UBHINGQGGSTHQT-UHFFFAOYSA-N 3-(8-methylnonoxy)propane-1,2-diol Chemical compound CC(C)CCCCCCCOCC(O)CO UBHINGQGGSTHQT-UHFFFAOYSA-N 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- SNPLKNRPJHDVJA-ZETCQYMHSA-N D-panthenol Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCCO SNPLKNRPJHDVJA-ZETCQYMHSA-N 0.000 description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
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- HBXWUCXDUUJDRB-UHFFFAOYSA-N 1-octadecoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC HBXWUCXDUUJDRB-UHFFFAOYSA-N 0.000 description 1
- ZONJATNKKGGVSU-UHFFFAOYSA-N 14-methylpentadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCC(O)=O ZONJATNKKGGVSU-UHFFFAOYSA-N 0.000 description 1
- XFOQWQKDSMIPHT-UHFFFAOYSA-N 2,3-dichloro-6-(trifluoromethyl)pyridine Chemical compound FC(F)(F)C1=CC=C(Cl)C(Cl)=N1 XFOQWQKDSMIPHT-UHFFFAOYSA-N 0.000 description 1
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- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 125000004964 sulfoalkyl group Chemical group 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 125000001302 tertiary amino group Chemical group 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- NRLLZRJXDKUVHM-UHFFFAOYSA-N tridecyl 7-methyloctanoate Chemical compound CCCCCCCCCCCCCOC(=O)CCCCCC(C)C NRLLZRJXDKUVHM-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
(A) アニオン界面活性剤、
(B) 一般式(1)で表されるアミドベンザルコニウム塩
R2OSO3M (3)
また、R1が7から11であるものが好ましい。具体的には、ペンチルアミドエチルベンザルコニウム塩、ヘプチルアミドエチルベンザルコニウム塩、1-エチルペンチルアミドエチルベンザルコニウム塩、2,4,4-トリメチルペンチルアミドエチルベンザルコニウム塩、ノニルアミドエチルベンザルコニウム塩、ウンデシルアミドエチルベンザルコニウム塩(以上、n=2)、ペンチルアミドプロピルベンザルコニウム塩、ヘプチルアミドプロピルベンザルコニウム塩、1-エチルペンチルアミドプロピルベンザルコニウム塩、2,4,4-トリメチルペンチルアミドプロピルベンザルコニウム塩、ノニルアミドプロピルベンザルコニウム塩、ウンデシルアミドプロピルベンザルコニウム塩(以上、n=3)、ペンチルアミドブチルベンザルコニウム塩、ヘプチルアミドブチルベンザルコニウム塩、1-エチルペンチルアミドブチルアンモニウム塩、2,4,4-トリメチルペンチルアミドブチルベンザルコニウム塩、ノニルアミドブチルベンザルコニウム塩、ウンデシルアミドブチルベンザルコニウム塩(以上、n=4)が挙げられる。
例えば下記一般式で表されるものが挙げられる。
R8-N+(CH3)3 X-
〔式中、R8は炭素数12〜22のアルキル基を示し、X-はハロゲン化物イオン(特に塩化物イオン、臭化物イオン)を示す。〕
例えば下記一般式で表されるものが挙げられる。
R8-O-R9-N+(CH3)3 X-
〔式中、R9はエチレン基又はプロピレン基を示し、R8及びX-は前記と同じ意味を示す。〕
例えば下記一般式で表されるものが挙げられる。
(R10)2N+(CH3)2 X-
〔式中、R10は炭素数12〜22のアルキル基又はベンジル基を示し、X-は前記と同じ意味を示す。〕
例えば下記一般式で表されるもの及びその塩が挙げられる。
R8-N(CH3)2
〔式中、R8は前記と同じ意味を示す。〕
例えば下記一般式で表されるもの及びその塩が挙げられる。
R8-O-R9-N(CH3)2
〔式中、R8及びR9は前記と同じ意味を示す。〕
例えば下記一般式で表されるもの及びその塩が挙げられる。
R11-C(=O)NH-R9-N(CH3)2
〔式中、R11は炭素数11〜21のアルキル基を示し、R9は前記と同じ意味を示す。〕
例えば下記一般式で表されるものが挙げられる。
(CH3)3SiO-[(CH3)2SiO]g-Si(CH3)3
〔式中、gは3〜20000の数を示す。〕
各種のアミノ変性シリコーンが使用できるが、特に平均分子量が約3000〜100000の、アモジメチコーン(Amodimethicone)の名称でCTFA辞典(米国,Cosmetic Ingredient Dictionary)第3版中に記載されているものが好ましい。このアミノ変性シリコーンは水性乳濁液として用いるのが好ましく、市販品としては、SM 8704C〔東レ・ダウコーニング・シリコーン(株)〕、DC 929〔ダウ・コーニング社〕、KT 1989〔GE東芝シリコーン(株)〕等が挙げられる。
上記以外に、ポリエーテル変性シリコーン、メチルフェニルポリシロキサン、脂肪酸変性シリコーン、アルコール変性シリコーン、アルコキシ変性シリコーン、エポキシ変性シリコーン、フッ素変性シリコーン、環状シリコーン、アルキル変性シリコーン等が挙げられる。
表1に示す各基剤5.0重量%、エタノール15重量%、ベンジルアルコール2.5重量%及びリンゴ酸5.0重量%を含有する水溶液を作り、水酸化ナトリウムでpH3.7に調整した。この水溶液のダメージ毛のうねりに対する作用について試験を行った。
あらかじめブリーチ処理を8回、洗髪と乾燥を720回繰り返したダメージ毛から、「うねった部分(以降カールと呼ぶ)」を切り取り、試験片とする(中心角約90度以上、カール径が約7〜12mm)。試験片は5個で一組とする。
水に完全に浸した後、軽く水を拭き取り、毛髪本来の形が出てくるように軽く振動させながら乾燥させる。乾燥後、形状が円の一部となっているカールだけを集め、カールの半径を測定(処理前半径)した。
試験片(切り取ったカール部)は、35℃、1時間、十分な量の処理剤に浸した後、1分間水で洗い、水分を軽く拭いた後、毛髪本来の形が出てくるように軽く振動させながら乾燥させる。乾燥後、カールの半径を測定した(処理後半径)。処理前後の変化(カール径比)を下記式に基づいて求め、試験片5個の平均を表1に示す。カール径比が大きくなるほど、うねりの取れる効果が多くなる。
表2に示す毛髪洗浄剤を調製し、洗髪時・すすぎ時の滑り感、乾燥後の毛髪(毛先)のうねりの取れる度合いを評価した。なお、pHは水で20重量倍に希釈したときの25℃における値である。
あらかじめブリーチ処理を8回、洗髪と乾燥を720回繰り返したダメージ毛を用いて作製した、長さ20cm、幅5.5cm、重さ10.0gの毛束を40℃の温水で軽く濯いだ後、余分な水分を取り去り、0.5gの毛髪洗浄剤を用いて約30秒間十分に泡立てた。泡の付いた毛束の滑り感を官能評価し、続いて毛束を40℃のお湯ですすぎ流しながら滑り感を官能評価した。評価は5人で行い、その評価の合計値を示した。
4:よく滑る
3:やや滑る
2:あまり滑らない
1:滑らない
あらかじめブリーチ処理を8回、洗髪と乾燥を720回繰り返したダメージ毛を用いて作成した、長さ20cm、幅1.5cm、重さ1.0gの毛束を40℃の温水で軽くすすいだ後、余分な水分を取り去り、0.1gの毛髪洗浄剤を用いて約30秒間泡立て、40℃の流水(2L/min)で30秒間濯いだ後、タオルで水気を十分に拭き取りドライヤーで櫛を通しながら乾燥した。これを30回繰り返した。その後、目視により毛先のうねりの取れ具合を評価した。評価は5人のパネラーで行い、その評価の合計値を示した。
4:うねりが取れている
3:ややうねりが取れている
2:あまりうねりが取れてない
1:うねりが取れてない
(重量%)
ポリオキシエチレン(2)ラウリルエーテル硫酸アンモニウム 13.0
化合物(B1) 0.5
ココアンホ酢酸ナトリウム 1.0
ココイルモノエタノールアミド 0.3
ポリオキシエチレン(14)ラウリルエーテル 0.5
高重合メチルポリシロキサンエマルション*1 3.0
ベンジルアルコール 0.5
エチレングリコールジステアレート 2.0
カチオン化ヒドロキシエチルセルロース*2 0.4
アミノ変性シリコーン誘導体*3 0.7
パンテノール 0.05
シルクエキス 0.05
塩化ナトリウム 0.5
乳酸 0.5
pH調整剤(水酸化ナトリウム) pH5.0になる量
イオン交換水 残量
*2:Polymer JR-400〔Amerchol社〕
*3:8500 CONDITIONING AGENT〔ダウ・コーニング社〕
B:75%は基−CH2CH(OH)CH2OH、25%は水素原子
(重量%)
ポリオキシエチレン(1.0)ラウリルエーテル硫酸アンモニウム 13.0
化合物(B1) 0.5
イソデシルグリセリルエーテル 0.7
ラウリルアミドプロピルベタイン 3.0
ココイルモノエタノールアミド 0.5
ミリスチルアルコール 1.0
ポリオキシエチレン(16)ラウリルエーテル 0.5
エチレングリコールジステアレート 2.0
カチオン化ヒドロキシエチルセルロース*4 0.5
ジアリル四級アンモニウム塩/アクリルアミド共重合物*5 0.3
アミノ変性シリコーン誘導体*3 0.4
高重合メチルポリシロキサンエマルション*1 2.0
ベンジルアルコール 0.4
ポリプロピレングリコール(Mw=400) 0.2
加水分解コンキオリン液(乾燥分3重量%) 0.05
オタネニンジンエキス(乾燥分3重量%) 0.05
ダイズエキス(乾燥分0.4重量%) 0.05
ユーカリエキス(乾燥分0.2重量%) 0.05
ツバキ油 0.05
米胚芽油 0.05
リンゴ酸 0.5
pH調整剤(水酸化ナトリウム) pH3.9になる量
イオン交換水 残量
*5:マーコート550〔ONDEO NALCO社〕
(重量%)
ポリオキシエチレン(1)ラウリルエーテル硫酸ナトリウム 12.0
化合物(B1) 0.5
ラウリルアミドプロピルベタイン 3.0
ポリオキシエチレン(16)ラウリルエーテル 2.0
カチオン化グアーガム*6 0.3
ポリプロピレングリコール(Mw=400) 0.5
アミノ変性シリコーン誘導体*3 0.3
塩化ナトリウム 0.5
アルギニン 0.5
リンゴ酸 0.2
アジピン酸 0.5
グリコール酸 0.2
pH調整剤(水酸化ナトリウム) pH5.0になる量
イオン交換水 残量
(重量%)
ポリオキシエチレン(2.5)ラウリルエーテル硫酸ナトリウム 12.0
化合物(B1) 0.2
イソデシルグリセリルエーテル 1.5
ココイルアミドプロピルベタイン 1.0
ラウリルヒドロキシスルホベタイン 1.0
ラウリン酸 0.5
ミリスチン酸 0.7
ジステアリルエーテル 2.0
ココイルベンザルコニウムクロライド 0.5
カチオン化ヒドロキシエチルセルロース*2 0.4
エタノール 0.5
アミノ変性シリコーン誘導体*3 0.4
高重合メチルポリシロキサンエマルション*1 2.0
セラミドII〔クローダジャパン(株)〕 0.05
ヒバマタエキス 0.05
ツバキ油 0.05
リンゴ酸 0.7
pH調整剤(水酸化ナトリウム) pH5.0になる量
イオン交換水 残量
Claims (3)
- (A)アニオン界面活性剤が一般式(2)で表されるポリオキシアルキレンアルキルエーテル硫酸塩又は一般式(3)で表されるアルキル硫酸塩である請求項1記載の毛髪洗浄剤。
R2O(CH2CH2O)aSO3M (2)
R2OSO3M (3)
〔式中、R2は炭素数8〜18のアルキル基又はアルケニル基を示し、Mはアルカリ金属、アルカリ土類金属又はアンモニウムを示し、aは重量平均で1〜5の数を示す。〕 - 更に、(C)ヒドロキシカルボン酸、ジカルボン酸及び芳香族カルボン酸から選ばれる少なくとも1種の有機酸を含む請求項1又は2記載の毛髪洗浄剤。
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4275055A (en) * | 1979-06-22 | 1981-06-23 | Conair Corporation | Hair conditioner having a stabilized, pearlescent effect |
JPH0680539A (ja) * | 1992-04-15 | 1994-03-22 | Helene Curtis Inc | コンディショニングシャンプー組成物およびその製造方法 |
JP2000053540A (ja) * | 1998-08-04 | 2000-02-22 | Nof Corp | シャンプー組成物 |
JP2000169886A (ja) * | 1998-12-11 | 2000-06-20 | Kao Corp | 増泡剤 |
JP2005068051A (ja) * | 2003-08-22 | 2005-03-17 | Kao Corp | 洗浄料 |
JP2005534644A (ja) * | 2002-06-04 | 2005-11-17 | ザ プロクター アンド ギャンブル カンパニー | ゲル網状組織を含有するシャンプー |
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2005
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Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4275055A (en) * | 1979-06-22 | 1981-06-23 | Conair Corporation | Hair conditioner having a stabilized, pearlescent effect |
JPH0680539A (ja) * | 1992-04-15 | 1994-03-22 | Helene Curtis Inc | コンディショニングシャンプー組成物およびその製造方法 |
JP2000053540A (ja) * | 1998-08-04 | 2000-02-22 | Nof Corp | シャンプー組成物 |
JP2000169886A (ja) * | 1998-12-11 | 2000-06-20 | Kao Corp | 増泡剤 |
JP2005534644A (ja) * | 2002-06-04 | 2005-11-17 | ザ プロクター アンド ギャンブル カンパニー | ゲル網状組織を含有するシャンプー |
JP2005068051A (ja) * | 2003-08-22 | 2005-03-17 | Kao Corp | 洗浄料 |
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