JP4472629B2 - Inkjet recording material - Google Patents
Inkjet recording material Download PDFInfo
- Publication number
- JP4472629B2 JP4472629B2 JP2005370546A JP2005370546A JP4472629B2 JP 4472629 B2 JP4472629 B2 JP 4472629B2 JP 2005370546 A JP2005370546 A JP 2005370546A JP 2005370546 A JP2005370546 A JP 2005370546A JP 4472629 B2 JP4472629 B2 JP 4472629B2
- Authority
- JP
- Japan
- Prior art keywords
- ink
- parts
- receiving layer
- pigment
- layer coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000463 material Substances 0.000 title claims description 56
- 238000000576 coating method Methods 0.000 claims description 107
- 239000011248 coating agent Substances 0.000 claims description 104
- 239000000049 pigment Substances 0.000 claims description 89
- 239000007788 liquid Substances 0.000 claims description 68
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 46
- 229920001577 copolymer Polymers 0.000 claims description 37
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 30
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 30
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 23
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 21
- 239000004327 boric acid Substances 0.000 claims description 21
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 18
- -1 methacrylate ester Chemical class 0.000 claims description 18
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 16
- 229910017604 nitric acid Inorganic materials 0.000 claims description 16
- 239000002253 acid Substances 0.000 claims description 9
- 150000002148 esters Chemical class 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 8
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 5
- 150000007513 acids Chemical class 0.000 claims description 5
- 239000000976 ink Substances 0.000 description 188
- 239000010410 layer Substances 0.000 description 158
- 239000000243 solution Substances 0.000 description 51
- 239000007864 aqueous solution Substances 0.000 description 45
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 33
- 239000007787 solid Substances 0.000 description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 32
- 239000000123 paper Substances 0.000 description 30
- 238000006116 polymerization reaction Methods 0.000 description 24
- 238000000034 method Methods 0.000 description 23
- 235000010338 boric acid Nutrition 0.000 description 21
- 229960002645 boric acid Drugs 0.000 description 21
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 18
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 18
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 description 18
- 239000011164 primary particle Substances 0.000 description 18
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 16
- 239000003795 chemical substances by application Substances 0.000 description 16
- 238000007127 saponification reaction Methods 0.000 description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 13
- 235000019441 ethanol Nutrition 0.000 description 12
- 239000011163 secondary particle Substances 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 11
- 239000000975 dye Substances 0.000 description 11
- 239000002904 solvent Substances 0.000 description 10
- 229910000019 calcium carbonate Inorganic materials 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- 239000000178 monomer Substances 0.000 description 8
- 238000010992 reflux Methods 0.000 description 8
- 239000000377 silicon dioxide Substances 0.000 description 8
- 229910002029 synthetic silica gel Inorganic materials 0.000 description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 7
- 239000011247 coating layer Substances 0.000 description 7
- 239000006185 dispersion Substances 0.000 description 7
- 239000001023 inorganic pigment Substances 0.000 description 7
- 239000004816 latex Substances 0.000 description 7
- 229920000126 latex Polymers 0.000 description 7
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 6
- 239000011230 binding agent Substances 0.000 description 6
- 238000011161 development Methods 0.000 description 6
- 230000018109 developmental process Effects 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 229920001131 Pulp (paper) Polymers 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 5
- 239000002585 base Substances 0.000 description 5
- 239000008119 colloidal silica Substances 0.000 description 5
- 238000004040 coloring Methods 0.000 description 5
- 239000003623 enhancer Substances 0.000 description 5
- 230000001965 increasing effect Effects 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 4
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 239000011882 ultra-fine particle Substances 0.000 description 4
- 239000005995 Aluminium silicate Substances 0.000 description 3
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- 239000002518 antifoaming agent Substances 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 3
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 3
- 239000001095 magnesium carbonate Substances 0.000 description 3
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 3
- 239000003505 polymerization initiator Substances 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 description 3
- 229920003002 synthetic resin Polymers 0.000 description 3
- 239000000057 synthetic resin Substances 0.000 description 3
- 239000000454 talc Substances 0.000 description 3
- 229910052623 talc Inorganic materials 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 239000005909 Kieselgur Substances 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000005083 Zinc sulfide Substances 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 description 2
- 239000003242 anti bacterial agent Substances 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 229910001593 boehmite Inorganic materials 0.000 description 2
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 2
- 239000000378 calcium silicate Substances 0.000 description 2
- 229910052918 calcium silicate Inorganic materials 0.000 description 2
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 2
- 150000001767 cationic compounds Chemical class 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 229920006319 cationized starch Polymers 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 239000004088 foaming agent Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910052621 halloysite Inorganic materials 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 2
- 239000000347 magnesium hydroxide Substances 0.000 description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 2
- ZADYMNAVLSWLEQ-UHFFFAOYSA-N magnesium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[Mg+2].[Si+4] ZADYMNAVLSWLEQ-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 150000007522 mineralic acids Chemical class 0.000 description 2
- 239000011259 mixed solution Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000006082 mold release agent Substances 0.000 description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 239000001254 oxidized starch Substances 0.000 description 2
- 235000013808 oxidized starch Nutrition 0.000 description 2
- 230000000149 penetrating effect Effects 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 238000004513 sizing Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- 239000011667 zinc carbonate Substances 0.000 description 2
- 229910000010 zinc carbonate Inorganic materials 0.000 description 2
- 235000004416 zinc carbonate Nutrition 0.000 description 2
- 229910052984 zinc sulfide Inorganic materials 0.000 description 2
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 2
- UUGXDEDGRPYWHG-UHFFFAOYSA-N (dimethylamino)methyl 2-methylprop-2-enoate Chemical compound CN(C)COC(=O)C(C)=C UUGXDEDGRPYWHG-UHFFFAOYSA-N 0.000 description 1
- LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 description 1
- GELKGHVAFRCJNA-UHFFFAOYSA-N 2,2-Dimethyloxirane Chemical compound CC1(C)CO1 GELKGHVAFRCJNA-UHFFFAOYSA-N 0.000 description 1
- YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 1
- PQXKWPLDPFFDJP-UHFFFAOYSA-N 2,3-dimethyloxirane Chemical compound CC1OC1C PQXKWPLDPFFDJP-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- YSUQLAYJZDEMOT-UHFFFAOYSA-N 2-(butoxymethyl)oxirane Chemical compound CCCCOCC1CO1 YSUQLAYJZDEMOT-UHFFFAOYSA-N 0.000 description 1
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 1
- AGIBHMPYXXPGAX-UHFFFAOYSA-N 2-(iodomethyl)oxirane Chemical compound ICC1CO1 AGIBHMPYXXPGAX-UHFFFAOYSA-N 0.000 description 1
- LKMJVFRMDSNFRT-UHFFFAOYSA-N 2-(methoxymethyl)oxirane Chemical compound COCC1CO1 LKMJVFRMDSNFRT-UHFFFAOYSA-N 0.000 description 1
- CSUWKYOVOGHTEP-UHFFFAOYSA-N 2-(oxiran-2-yl)ethylazanium;chloride Chemical compound [Cl-].[NH3+]CCC1CO1 CSUWKYOVOGHTEP-UHFFFAOYSA-N 0.000 description 1
- LDLCZOVUSADOIV-UHFFFAOYSA-N 2-bromoethanol Chemical compound OCCBr LDLCZOVUSADOIV-UHFFFAOYSA-N 0.000 description 1
- SZIFAVKTNFCBPC-UHFFFAOYSA-N 2-chloroethanol Chemical compound OCCCl SZIFAVKTNFCBPC-UHFFFAOYSA-N 0.000 description 1
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 1
- VHSHLMUCYSAUQU-UHFFFAOYSA-N 2-hydroxypropyl methacrylate Chemical compound CC(O)COC(=O)C(C)=C VHSHLMUCYSAUQU-UHFFFAOYSA-N 0.000 description 1
- TVWBTVJBDFTVOW-UHFFFAOYSA-N 2-methyl-1-(2-methylpropylperoxy)propane Chemical compound CC(C)COOCC(C)C TVWBTVJBDFTVOW-UHFFFAOYSA-N 0.000 description 1
- RCEJCSULJQNRQQ-UHFFFAOYSA-N 2-methylbutanenitrile Chemical compound CCC(C)C#N RCEJCSULJQNRQQ-UHFFFAOYSA-N 0.000 description 1
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- BMYNFMYTOJXKLE-UHFFFAOYSA-N 3-azaniumyl-2-hydroxypropanoate Chemical compound NCC(O)C(O)=O BMYNFMYTOJXKLE-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 102100031260 Acyl-coenzyme A thioesterase THEM4 Human genes 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 108010076119 Caseins Proteins 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 1
- 101000638510 Homo sapiens Acyl-coenzyme A thioesterase THEM4 Proteins 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 229910004844 Na2B4O7.10H2O Inorganic materials 0.000 description 1
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 description 1
- 240000008881 Oenanthe javanica Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- FQYUMYWMJTYZTK-UHFFFAOYSA-N Phenyl glycidyl ether Chemical compound C1OC1COC1=CC=CC=C1 FQYUMYWMJTYZTK-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 108010073771 Soybean Proteins Proteins 0.000 description 1
- AWMVMTVKBNGEAK-UHFFFAOYSA-N Styrene oxide Chemical compound C1OC1C1=CC=CC=C1 AWMVMTVKBNGEAK-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 125000002339 acetoacetyl group Chemical group O=C([*])C([H])([H])C(=O)C([H])([H])[H] 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- HFBMWMNUJJDEQZ-UHFFFAOYSA-N acryloyl chloride Chemical compound ClC(=O)C=C HFBMWMNUJJDEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 description 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 1
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 1
- 229940073608 benzyl chloride Drugs 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000005282 brightening Methods 0.000 description 1
- PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical compound O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 229920003090 carboxymethyl hydroxyethyl cellulose Polymers 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 229910002026 crystalline silica Inorganic materials 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 229910001648 diaspore Inorganic materials 0.000 description 1
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 description 1
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010556 emulsion polymerization method Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- GKIPXFAANLTWBM-UHFFFAOYSA-N epibromohydrin Chemical compound BrCC1CO1 GKIPXFAANLTWBM-UHFFFAOYSA-N 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000006081 fluorescent whitening agent Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000011121 hardwood Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- LNCPIMCVTKXXOY-UHFFFAOYSA-N hexyl 2-methylprop-2-enoate Chemical compound CCCCCCOC(=O)C(C)=C LNCPIMCVTKXXOY-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- SKOWZLGOFVSKLB-UHFFFAOYSA-N hypodiboric acid Chemical compound OB(O)B(O)O SKOWZLGOFVSKLB-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 229940035429 isobutyl alcohol Drugs 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 229940031958 magnesium carbonate hydroxide Drugs 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 229940050176 methyl chloride Drugs 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- VGTPKLINSHNZRD-UHFFFAOYSA-N oxoborinic acid Chemical compound OB=O VGTPKLINSHNZRD-UHFFFAOYSA-N 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000010893 paper waste Substances 0.000 description 1
- GYDSPAVLTMAXHT-UHFFFAOYSA-N pentyl 2-methylprop-2-enoate Chemical compound CCCCCOC(=O)C(C)=C GYDSPAVLTMAXHT-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229960005235 piperonyl butoxide Drugs 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002250 progressing effect Effects 0.000 description 1
- OGHBATFHNDZKSO-UHFFFAOYSA-N propan-2-olate Chemical compound CC(C)[O-] OGHBATFHNDZKSO-UHFFFAOYSA-N 0.000 description 1
- 239000013055 pulp slurry Substances 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 1
- 239000011122 softwood Substances 0.000 description 1
- 235000019710 soybean protein Nutrition 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010558 suspension polymerization method Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 229920006163 vinyl copolymer Polymers 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Description
本発明は、インクジェット記録材料に関するものであり、特に顔料インクに適したインクジェット記録材料に関するものである。 The present invention relates to an ink jet recording material, and more particularly to an ink jet recording material suitable for pigment ink.
近年、インクジェットプリンターやプロッターの目ざましい進歩により、フルカラーでしかも高精細な画像が容易に得られるようになってきた。 In recent years, due to remarkable progress of inkjet printers and plotters, it has become possible to easily obtain full-color and high-definition images.
インクジェット記録方式は、種々の作動原理によりインクの微小液滴を飛翔させて紙等の記録材料に付着させ、画像・文字等の記録を行うものである。インクジェットプリンターやプロッターはコンピューターにより作成した文字や各種図形等の画像情報のハードコピー作成装置として、種々の用途において近年急速に普及している。特に多色インクジェット方式により形成されるカラー画像は製版方式による多色印刷やカラー写真方式による印画に比較しても遜色のない記録を得ることが可能であり、さらに作成部数が少ない用途においては、印刷技術や写真技術によるよりも安価で済むことから広く応用されつつある。 The ink jet recording system records images, characters, and the like by causing micro droplets of ink to fly and adhere to a recording material such as paper according to various operating principles. Inkjet printers and plotters are rapidly spreading in various applications in recent years as hard copy creation apparatuses for image information such as letters and various graphics created by a computer. In particular, color images formed by the multi-color ink jet method can obtain a recording that is comparable to multi-color printing by the plate-making method and printing by the color photographic method. It is being widely applied because it requires less cost than printing and photographic techniques.
さらに、用途の多様化に伴い、大判のポスターやＰＯＰアート、製図用途に使用されることが多くなってきている。これら用途ではインクジェットの高鮮鋭性を活かせ、色彩性も優れていることから、良好な画像を得ることが可能であり、宣伝効果が大きいものとなる。これらへの適用はパーソナルコンピュータレベルで、鮮鋭性や色彩性といった画像再現性や色再現性に優れた画像を簡単に得ることが可能であるためであり、インクジェット記録材料を多用する理由ともなっている。 Furthermore, with the diversification of uses, it is increasingly used for large-format posters, POP art, and drafting. In these applications, since the high sharpness of the ink jet is utilized and the color is excellent, a good image can be obtained and the advertising effect is great. Application to these is because it is possible to easily obtain an image with excellent image reproducibility and color reproducibility such as sharpness and color at the personal computer level, which is also a reason for using a lot of ink jet recording materials. .
これらインクジェット記録装置の高性能化や用途の多様化により、インクジェット記録に対するニーズは高まっており、その結果記録装置或いはインクジェット記録材料に求められる特性も要求もかなり高度になってきている。例えば、大判ポスターやＰＯＰアート、また写真画像を出力する用途の場合、その用途が屋内外の展示や個人の記録保存といったものであるため、従来以上に画像の耐候性、画像保存性が求められるようになっている。このような要望に対し、インク及びインクジェット記録材料の改良が進んでおり、従来よりはかなり良好な保存性が得られるようになってきている。しかしながら、特に耐光性に関しては未だ銀塩写真のレベルには到達しておらず、要求が満たされていないのが現状である。 Due to the high performance and diversification of applications of these ink jet recording apparatuses, the need for ink jet recording has increased, and as a result, the characteristics and requirements required for the recording apparatus or ink jet recording material have become considerably high. For example, in the case of applications such as large posters, POP art, and photographic image output, the applications are for indoor / outdoor exhibitions and personal record storage, and thus weather resistance and image storage stability are required more than before. It is like that. In response to such demands, improvements in ink and ink jet recording materials are progressing, and considerably better storability can be obtained than before. However, in particular, the light resistance has not yet reached the level of silver salt photography, and the current situation is that the requirements are not satisfied.
このような要求を満たすために、最近では顔料タイプのインクが使用されるようになってきている。顔料インクは光劣化も少なく、水によって再溶解しないため、染料タイプのインクよりも耐候性、画像保存性が向上することが知られている。しかし、インク中の色材顔料は染料と異なり溶媒に不溶であるため、インク中の色材顔料を安定に分散させる必要があり、インク中の色材顔料の比率を容易に上げられない。また、染料インクのように着色効率が高くなく、鮮明な発色を得にくい。 In order to satisfy such demands, pigment type inks have recently been used. It is known that the pigment ink has little light deterioration and does not re-dissolve with water, so that the weather resistance and the image storage stability are improved as compared with the dye type ink. However, since the color material pigment in the ink is insoluble in the solvent unlike the dye, it is necessary to stably disperse the color material pigment in the ink, and the ratio of the color material pigment in the ink cannot be easily increased. In addition, the coloring efficiency is not high like dye ink, and it is difficult to obtain a clear color.
そのため、インクジェット記録材料に対する要求も必然的に高まってきている。顔料インクの吸収性を向上させる方法として、支持体上に塗工するインク受理層を厚くすることが考えられる。この方法でインク吸収性は改善されるが、インクが原紙方向に深く浸透するため、発色性が低下する。前述したように顔料インクの場合、染料インクと比較して鮮明な発色を得にくいため、インクが深く浸透すると発色性は著しく低下してしまう。さらにインク受理層を有しないインクジェット記録材料ではさらにその低下は著しい。 Therefore, the demand for ink jet recording materials is inevitably increasing. As a method for improving the absorbability of the pigment ink, it is conceivable to increase the thickness of the ink receiving layer to be coated on the support. Ink absorption is improved by this method, but the color develops because the ink penetrates deeply in the direction of the base paper. As described above, in the case of the pigment ink, it is difficult to obtain a clear color compared with the dye ink, so that the color developability is significantly lowered when the ink penetrates deeply. Furthermore, the decrease is further remarkable in the ink jet recording material having no ink receiving layer.
これらインクジェット記録材料は、良好なインクジェット記録性能を得る等の目的で、無機超微粒子を含有するインクジェット記録材料が提案され、一次粒子径が３ｎｍ〜３０ｎｍである主として気相法による合成シリカを使用するインクジェット記録材料が開示されている（例えば、特許文献１、２参照）。 For these ink jet recording materials, for the purpose of obtaining good ink jet recording performance, an ink jet recording material containing inorganic ultrafine particles has been proposed, and synthetic silica mainly having a primary particle diameter of 3 nm to 30 nm is used by a gas phase method. An ink jet recording material is disclosed (for example, see Patent Documents 1 and 2).
また、非吸収性支持体上に無機超微粒子、ポリビニルアルコール及びホウ酸またはその塩を含有させた塗層を設ける方法が提案されている（例えば、特許文献３〜５参照）。この方法によれば、塗層の乾燥塗工量が少ない場合には、ひび割れを発生させずに塗層を得ることができるが、インクの吸収性が低くく、インク吸収性を向上させるために厚い塗層を設けるには、塗液を室温以上に加温した後に塗工する、もしくは塗工後に冷却する等して、塗液を支持体上でセットさせ、粘度増加剤と無機超微粒子やバインダーと強固な結合を形成させた後、乾燥を行わなければならないため、生産効率が低下するうえ、塗層を厚くしてもインク吸収性は満足のいくものではないことがある。 Moreover, the method of providing the coating layer which contained the inorganic ultrafine particle, polyvinyl alcohol, boric acid, or its salt on the non-absorbable support body is proposed (for example, refer patent documents 3-5). According to this method, when the dry coating amount of the coating layer is small, the coating layer can be obtained without causing cracks, but the ink absorbency is low and the ink absorbability is improved. In order to provide a thick coating layer, the coating solution is heated after being heated to room temperature or higher, or cooled after coating, and the coating solution is set on the support, and a viscosity increasing agent and inorganic ultrafine particles or Since it is necessary to dry after forming a strong bond with the binder, the production efficiency is lowered, and even if the coating layer is thickened, the ink absorptivity may not be satisfactory.
インクの吸収性を向上させるために下層にシリカ多孔質層を設け、上層にアルミナまたはアルミナ水和物含有層を有するインクジェット記録材料や下層に吸収性顔料含有層、最表層に擬ベーマイトを配した記録材料が提案されている（例えば、特許文献６、７参照）。 In order to improve the ink absorbency, a porous silica layer is provided in the lower layer, an ink jet recording material having an alumina or alumina hydrate-containing layer in the upper layer, an absorbent pigment-containing layer in the lower layer, and pseudoboehmite in the outermost layer. Recording materials have been proposed (see, for example, Patent Documents 6 and 7).
この様な無機超微粒子を含有する光沢発現層の塗液をシリカ多孔質からなる下層上に塗工・乾燥する方法で形成する場合、光沢発現層中のバインダー成分等が吸水性高い下層への落ち込みが発生するため、光沢発現層表面にひび割れが生じやすく、染料インクにおいては、そのひび割れが多いためにインクの吸収性の向上は見られるが、染料インクに比べ発色性の低い顔料インクにおいては、そのひび割れに顔料インクが落ち込むことにより顔料インク特性が低下することがある。 When forming a coating liquid for such a glossy layer containing inorganic ultrafine particles on the lower layer made of silica, and drying it, the binder component in the glossy layer is applied to the lower layer with high water absorption. Due to the occurrence of depression, cracks are likely to occur on the surface of the glossy layer, and in dye inks, there are many cracks, so the ink absorption is improved, but in pigment inks that have low color development compared to dye inks When the pigment ink falls into the cracks, the pigment ink characteristics may deteriorate.
一方、アルミナあるいは、アルミナとコロイダルシリカを含有するインク受理層にメタクリル酸エステル−メタクリル酸ジメチルアミノアルキルエステル−スチレン共重合物を配合するインクジェット記録材料が提案されているが、キャストコート法を用いたインクジェット紙において光沢性の改善を目的としているため、インク受理層表面のひび割れ、あるいは顔料インクの発色性の点では不十分であった（例えば、特許文献８、９参照）。
本発明の課題は、インク受理層表面にひび割れを生じさせずに顔料インクの高い吸収性と発色性を兼ね備えたインクジェット記録材料を提供することにある。 An object of the present invention is to provide an ink jet recording material that has both high absorbability and color developability of pigment ink without causing cracks on the surface of the ink receiving layer.
上記目的を達成するために鋭意研究を重ねた結果、支持体の少なくとも片面にアルミナ水和物を主成分とするインク受理層の塗液を塗工・乾燥して形成されるインクジェット記録材料において、該インク受理層中に少なくともポリビニルアルコール、メタクリル酸エステル−メタクリル酸ジメチルアミノアルキルエステル−スチレン共重合物、ホウ酸またはホウ酸塩、及び硝酸、酢酸、塩酸から選ばれる１種以上の酸を含有するインクジェット記録材料により解決した。 As a result of intensive research to achieve the above object, in an ink jet recording material formed by applying and drying a coating liquid of an ink receiving layer mainly composed of alumina hydrate on at least one side of a support, The ink-receiving layer contains at least polyvinyl alcohol, methacrylic acid ester-dimethylaminoalkyl methacrylate methacrylate-styrene copolymer, boric acid or borate , and one or more acids selected from nitric acid, acetic acid, and hydrochloric acid . Solved by inkjet recording material.
該支持体と該インク受理層の間に顔料層を設けることがより好ましい。 More preferably, a pigment layer is provided between the support and the ink receiving layer.
本発明のインクジェット記録材料は、インク受理層にひび割れが無く、高い顔料インクの吸収性と発色性を兼ね備える。 The ink jet recording material of the present invention does not have cracks in the ink receiving layer and has both high pigment ink absorbability and color developability.
以下、本発明のインクジェット記録材料を詳細に説明する。 Hereinafter, the ink jet recording material of the present invention will be described in detail.
本発明者は、顔料インク適性を向上させる方法として、顔料インク中の溶媒と色材顔料とを分離し、顔料インク中の色材顔料をインク受理層表面近傍に分布させることで、吸収性と発色性の改善が可能であると考えた。 As a method for improving the suitability of the pigment ink, the present inventor separated the solvent and the color material pigment in the pigment ink and distributed the color material pigment in the pigment ink in the vicinity of the surface of the ink receiving layer. We thought that color development could be improved.
そこで本発明者らはインク受理層表面のひび割れをなくし、顔料インク中の色材顔料成分と溶媒分を分離する手法を鋭意検討した結果、アルミナ水和物を主成分とするインク受理層中に少なくともポリビニルアルコール、メタクリル酸エステル−メタクリル酸ジメチルアミノアルキルエステル−スチレン共重合物、ホウ酸またはホウ酸塩、及び少なくとも硝酸、酢酸、塩酸から選ばれる１種以上の酸を含有するすることで、ひび割れのないインク受理層を設けることが可能となり、効果的に顔料インクを色剤顔料と溶媒分に分離し、顔料インクの吸収性と発色性を兼ね備えたインクジェット記録材料を作製できることを見いだした。 Therefore, the present inventors have intensively studied a method for removing the colorant pigment component and the solvent component in the pigment ink by eliminating cracks on the surface of the ink receiving layer, and as a result, in the ink receiving layer mainly composed of alumina hydrate. By containing at least one acid selected from polyvinyl alcohol, methacrylate ester-dimethylaminoalkyl methacrylate methacrylate-styrene copolymer, boric acid or borate , and at least nitric acid, acetic acid, hydrochloric acid , and cracking It has been found that an ink receiving layer can be provided, and the pigment ink can be effectively separated into a colorant pigment and a solvent, and an ink jet recording material having both the absorbability and color developability of the pigment ink can be produced.
本発明でいう顔料インクとは、色材顔料、分散溶媒、その他の添加剤等からなる記録液体であり、特に限定されない。また、分散溶媒は、水または各種有機溶剤のいずれを用いたものでも良い。 The pigment ink as used in the present invention is a recording liquid comprising a colorant pigment, a dispersion solvent, other additives, and the like, and is not particularly limited. Moreover, the dispersion solvent may use either water or various organic solvents.
以下に本発明に係わるインク受理層について説明する。 The ink receiving layer according to the present invention will be described below.
本発明のインク受理層には、アルミナ水和物が主成分として用いられる。 In the ink receiving layer of the present invention, alumina hydrate is used as a main component.
本発明において、主成分とは、インク受理層に含有される顔料の総量の５０質量％以上であることを表す。 In the present invention, the main component represents 50% by mass or more of the total amount of pigments contained in the ink receiving layer.
本発明に用いられるアルミナ水和物は、下記の一般式により表すことができる。Ａｌ2Ｏ3・ｎＨ2Ｏアルミナ水和物は組成や結晶形態の違いにより、ジプサイト、バイアライト、ノルストランダイト、ベーマイト、ベーマイトゲル（擬ベーマイト）、ジアスポア、無定形非晶質等に分類される。中でも、上記の式中、ｎの値が１である場合はベーマイト構造のアルミナ水和物を表し、ｎが１を越え３未満である場合は擬ベーマイト構造のアルミナ水和物を表し、ｎが３以上では非晶質構造のアルミナ水和物を表す。特に、本発明に好ましいアルミナ水和物は、少なくともｎが１を越え３未満の擬ベーマイト構造のアルミナ水和物である。 The alumina hydrate used in the present invention can be represented by the following general formula. Al 2 O 3 · nH 2 O alumina hydrate is classified into gypsite, vialite, norstrandite, boehmite, boehmite gel (pseudoboehmite), diaspore, amorphous amorphous, etc., depending on the composition and crystal form. The In particular, in the above formula, when the value of n is 1, it represents an alumina hydrate having a boehmite structure, and when n is more than 1 and less than 3, it represents an alumina hydrate having a pseudo boehmite structure, where n is 3 or more represents an amorphous alumina hydrate. In particular, the preferred alumina hydrate for the present invention is an alumina hydrate having a pseudo boehmite structure in which at least n is more than 1 and less than 3.
本発明に用いられるアルミナ水和物の形状は、平板状、繊維状、針状、球状、棒状等のいずれでもよく、インク吸収性の観点から好ましい形状は平板状である。平板状のアルミナ水和物は、平均アスペクト比３〜８であり、好ましくは平均アスペクト比が３〜６である。アスペクト比は、粒子の「厚さ」に対する「直径」の比で表される。ここで粒子の直径とは、アルミナ水和物を電子顕微鏡で観察したときの粒子の投影面積に等しい円の直径を表す。アスペクト比が上記の範囲より小さい場合は、十分なインク吸収性が得られない場合がある。一方アスペクト比が上記の範囲を超える場合は、粒子を揃えてアルミナ水和物を製造することが困難となる。 The shape of the alumina hydrate used in the present invention may be any of a flat plate shape, a fiber shape, a needle shape, a spherical shape, a rod shape, and the like, and a preferable shape is a flat shape from the viewpoint of ink absorbability. The plate-like alumina hydrate has an average aspect ratio of 3 to 8, and preferably an average aspect ratio of 3 to 6. The aspect ratio is expressed as the ratio of the “diameter” to the “thickness” of the particles. Here, the diameter of the particle represents the diameter of a circle equal to the projected area of the particle when the alumina hydrate is observed with an electron microscope. When the aspect ratio is smaller than the above range, sufficient ink absorbability may not be obtained. On the other hand, when the aspect ratio exceeds the above range, it becomes difficult to produce alumina hydrate by aligning the particles.
本発明に用いられるアルミナ水和物は、アルミニウムイソプロポキシド等のアルミニウムアルコキシドの加水分解、アルミニウム塩のアルカリによる中和、アルミン酸塩の加水分解等公知の方法によって製造することができる。また、アルミナ水和物の粒子径、細孔径、細孔容積、比表面積等の物性は、析出温度、熟成温度、熟成時間、液のｐＨ、液の濃度、共存化合物等の条件によって制御することができる。 The alumina hydrate used in the present invention can be produced by a known method such as hydrolysis of aluminum alkoxide such as aluminum isopropoxide, neutralization of aluminum salt with alkali, hydrolysis of aluminate. The physical properties of alumina hydrate, such as particle size, pore size, pore volume, and specific surface area, should be controlled by conditions such as precipitation temperature, aging temperature, aging time, solution pH, solution concentration, and coexisting compounds. Can do.
アルコキシドからアルミナ水和物を得る方法としては、特開昭５７−８８０７４号公報、同６２−５６３２１号公報、特開平４−２７５９１７号公報、同６−６４９１８号公報、同７−１０５３５号公報、同７−２６７６３３号公報、米国特許第２，６５６，３２１号明細書等にアルミニウムアルコキシドを加水分解する方法として開示されている。これらのアルミニウムアルコキシドとしてはイソプロポキシド、２−ブトキシド等が挙げられる。 As methods for obtaining alumina hydrates from alkoxides, JP-A-57-88074, JP-A-62-256321, JP-A-4-275717, JP-A-6-64918, JP-A-7-10535, JP-A-7-267633, US Pat. No. 2,656,321 and the like disclose a method for hydrolyzing aluminum alkoxide. These aluminum alkoxides include isopropoxide, 2-butoxide and the like.
本発明で使用するアルミナ水和物において平均一次粒子径が３ｎｍ〜２５ｎｍのアルミナ水和物が好ましい。特に好ましい一次粒子径は５ｎｍ〜２０ｎｍのものである。またこれらが連結した二次粒子径としては、５０ｎｍ〜２００ｎｍにするのが好ましい。 The alumina hydrate used in the present invention is preferably an alumina hydrate having an average primary particle size of 3 nm to 25 nm. A particularly preferable primary particle diameter is 5 nm to 20 nm. In addition, the secondary particle diameter in which these are linked is preferably 50 nm to 200 nm.
本発明のインク受理層には、特開平８−７２３８７公報等に記載されている気相法アルミナ、特開昭６０−２１９０８３号公報、同６１−１９３８９号公報、同６１−１８８１８３号公報、同６３−１７８０７４号公報、特開平５−５１４７０号公報等に記載されているようなコロイダルシリカ、特公平４−１９０３７号公報、特開昭６２−２８６７８７号公報に記載されているようなシリカ／アルミナハイブリッドゾル、特開平１０−１１９４２３号公報、特開平１０−２１７６０１号公報に記載されているような、気相法シリカを高速ホモジナイザーで分散したようなシリカゾル、その他にもヘクタイト、モンモリロナイト等のスメクタイト粘土（特開平７−８１２１０号公報）、ジルコニアゾル、クロミアゾル、イットリアゾル、セリアゾル、酸化鉄ゾル、ジルコンゾル、酸化アルミニウムゾル、酸化アンチモンゾル等の一次粒子径が１００ｎｍ以下の無機微粒子や軽質炭酸カルシウム、重質炭酸カルシウム、カオリン、タルク、硫酸カルシウム、硫酸バリウム、二酸化チタン、酸化亜鉛、硫化亜鉛、炭酸亜鉛、サチンホワイト、珪酸アルミニウム、ケイソウ土、珪酸カルシウム、珪酸マグネシウム、合成非晶質シリカ、コロイダルシリカ、水酸化アルミニウム、リトポン、ゼオライト、加水ハロイサイト、炭酸マグネシウム、水酸化マグネシウム等の白色無機顔料等をアルミナ水和物と併せて用いることができる。 The ink receiving layer of the present invention includes vapor phase alumina described in JP-A-8-72387, JP-A-60-219083, JP-A-61-19389, JP-A-61-188183, Colloidal silica as described in JP-A 63-178074, JP-A-5-51470, etc., silica / alumina as described in JP-B-4-19037, JP-A 62-286787 Hybrid sol, silica sol in which gas phase method silica is dispersed with a high-speed homogenizer, as described in JP-A-10-119423 and JP-A-10-217601, and other smectite clays such as hectite and montmorillonite (JP-A-7-81210), zirconia sol, chromia sol, yttria sol, seri Sol, iron oxide sol, zircon sol, aluminum oxide sol, antimony oxide sol and other inorganic fine particles with a primary particle size of 100 nm or less, light calcium carbonate, heavy calcium carbonate, kaolin, talc, calcium sulfate, barium sulfate, titanium dioxide, oxidation Zinc, zinc sulfide, zinc carbonate, satin white, aluminum silicate, diatomaceous earth, calcium silicate, magnesium silicate, synthetic amorphous silica, colloidal silica, aluminum hydroxide, lithopone, zeolite, hydrous halloysite, magnesium carbonate, magnesium hydroxide, etc. The white inorganic pigment or the like can be used in combination with alumina hydrate.
本発明のインク受理層に用いられるポリビニルアルコールとしては、アルミナ水和物との混合性、塗液粘度の調整、及び成膜性等の点で重合度２０００以上、ケン化度が８８％以上９６％未満のポリビニルアルコールが好ましい。また、シリル変性ポリビニルアルコール、アセトアセチル基変性ポリビニルアルコール等のポリビニルアルコール誘導体も用いることができる。ポリビニルアルコールの配合量は、インク受理層に用いられる顔料の総和１００質量部に対して、４〜２０質量部であることが好ましく、特に６〜１５質量部であることが好ましい。 The polyvinyl alcohol used in the ink receiving layer of the present invention has a degree of polymerization of 2000 or more and a saponification degree of 88% or more and 96 from the viewpoints of miscibility with alumina hydrate, adjustment of the coating liquid viscosity, film formability, and the like. % Of polyvinyl alcohol is preferred. Further, polyvinyl alcohol derivatives such as silyl-modified polyvinyl alcohol and acetoacetyl group-modified polyvinyl alcohol can also be used. The blending amount of the polyvinyl alcohol is preferably 4 to 20 parts by mass, particularly preferably 6 to 15 parts by mass with respect to 100 parts by mass of the total of the pigments used in the ink receiving layer.
本発明におけるメタクリル酸エステル−メタクリル酸ジメチルアミノアルキルエステル−スチレン共重合物は、メタクリル酸エステルモノマー、メタクリル酸ジメチルアミノアルキルエステルモノマー、スチレンモノマーの重合により得られる。 The methacrylic acid ester-methacrylic acid dimethylaminoalkyl ester-styrene copolymer in the present invention is obtained by polymerization of a methacrylic acid ester monomer, a methacrylic acid dimethylaminoalkyl ester monomer, and a styrene monomer.
本発明におけるメタクリル酸エステル−メタクリル酸ジメチルアミノアルキルエステル−スチレン共重合物に用いられるメタクリル酸エステルとしては、例えば、メタクリル酸メチル、メタクリル酸エチル、メタクリル酸ｎ−ブチル、メタクリル酸イソブチル、メタクリル酸ｔｅｒｔ−ブチル、メタクリル酸ｎ−アミル、メタクリル酸ｎ−ヘキシル、メタクリル酸２−エチルヘキシル、メタクリル酸２−ヒドロキシエチル、メタクリル酸２−ヒドロキシプロピル等が挙げられ、これらのモノマー成分の１種以上を使用することができる。これらのメタクリル酸エステルの中でも炭素数１〜４のアルキル基を有するメタクリル酸エステルが好ましい。 Examples of the methacrylic acid ester used in the methacrylic acid ester-dimethylaminoalkyl methacrylate-styrene copolymer in the present invention include, for example, methyl methacrylate, ethyl methacrylate, n-butyl methacrylate, isobutyl methacrylate, tert-methacrylic acid tert. -Butyl, n-amyl methacrylate, n-hexyl methacrylate, 2-ethylhexyl methacrylate, 2-hydroxyethyl methacrylate, 2-hydroxypropyl methacrylate, and the like, and one or more of these monomer components are used. be able to. Among these methacrylates, methacrylates having an alkyl group having 1 to 4 carbon atoms are preferable.
本発明におけるメタクリル酸エステル−メタクリル酸ジメチルアミノアルキルエステル−スチレン共重合物に用いられるメタクリル酸ジメチルアミノアルキルエステルとしては、メタクリル酸ジメチルアミノメチルエステル、メタクリル酸ジメチルアミノエチルエステル等が挙げられ、また、これらの有機酸もしくは無機酸の塩類、またはメタクリル酸ジメチルアミノアルキルエステルとジメチル硫酸、アクリルクロライド、ベンジルクロライド、プロピレンオキサイド、ブチレンオキサイド、スチレンオキサイド、エピクロルヒドリン、エピブロモヒドリン、エピヨードヒドリン、エチレンクロルヒドリン、エチレンブロモヒドリン、メチルグリシジルエーテル、ブチルグリシジルエーテル、フェニルグリシジルエーテル、アルキルフェニルグリシジルエーテル等のグリシジルエーテル、グリシドール、２，３−ブチレンオキサイド、イソブチレンオキサイド、プロピレンオキサイド、メチルハライド、エチルハライド、モノクロル酢酸、モノクロル酢酸エステル、グリシジルメチルアンモニウムクロライド等の４級化剤で４級化して得られるメタクリル酸ジメチルアミノアルキルエステルの第４級アンモニウム塩等の使用が可能であり、これらのモノマー成分の１種以上を使用することができる。 Examples of the methacrylic acid dimethylaminoalkyl ester used in the methacrylic acid ester-methacrylic acid dimethylaminoalkyl ester-styrene copolymer in the present invention include methacrylic acid dimethylaminomethyl ester, methacrylic acid dimethylaminoethyl ester, and the like. Salts of these organic acids or inorganic acids, or dimethylaminoalkyl methacrylate and dimethyl sulfate, acrylic chloride, benzyl chloride, propylene oxide, butylene oxide, styrene oxide, epichlorohydrin, epibromohydrin, epiiodohydrin, ethylene chloro Hydrine, ethylene bromohydrin, methyl glycidyl ether, butyl glycidyl ether, phenyl glycidyl ether, alkylpheny Quaternized with quaternizing agents such as glycidyl ether such as glycidyl ether, glycidol, 2,3-butylene oxide, isobutylene oxide, propylene oxide, methyl halide, ethyl halide, monochloroacetic acid, monochloroacetic acid ester, glycidylmethylammonium chloride The resulting quaternary ammonium salt of methacrylic acid dimethylaminoalkyl ester can be used, and one or more of these monomer components can be used.
本発明のメタクリル酸エステル−メタクリル酸ジメチルアミノアルキルエステル−スチレン共重合物において、モノマー成分の比率としては、メタクリル酸エステル２０〜９３質量％、メタクリル酸ジメチルアミノアルキルエステル５〜４０質量％、スチレンモノマー２〜５０質量％であり、好ましくはメタクリル酸エステル４０〜７０質量％、メタクリル酸ジメチルアミノアルキルエステル１５〜３５質量％、スチレンモノマー５〜４０質量％である。 In the methacrylic acid ester-methacrylic acid dimethylaminoalkyl ester-styrene copolymer of the present invention, the ratio of the monomer components is as follows: methacrylic acid ester 20-93% by mass, methacrylic acid dimethylaminoalkyl ester 5-40% by mass, styrene monomer They are 2-50 mass%, Preferably they are methacrylic acid ester 40-70 mass%, methacrylic acid dimethylaminoalkylester 15-35 mass%, and a styrene monomer 5-40 mass%.
本発明に用いるメタクリル酸エステル−メタクリル酸ジメチルアミノアルキルエステル−スチレン共重合物の重量平均分子量としては、５，０００〜５０，０００の範囲が好ましい。 The weight average molecular weight of the methacrylic ester-methacrylic acid dimethylaminoalkyl ester-styrene copolymer used in the present invention is preferably in the range of 5,000 to 50,000.
本発明において、メタクリル酸エステル−メタクリル酸ジメチルアミノアルキルエステル−スチレン共重合物の製造方法としては特に限定されず、溶液重合法、懸濁重合法、乳化重合法等、各種公知の重合法が使用できる。これらの中でも溶液重合法が好ましい。溶液重合法としては、反応容器に前記モノマー成分、溶媒及び重合開始剤を投入、十分混合し、窒素気流中で反応系内を昇温し、溶媒の還流温度以下で２〜３時間程度連続滴下した後、その温度で、４〜８時間程度重合し、重合終了後有機酸もしくは無機酸で中和し水に溶解して得られ、必要により溶媒を溜去して、メタクリル酸エステル−メタクリル酸ジメチルアミノアルキルエステル−スチレン共重合物の溶液を得る。なお、重合に際してメルカプタン、アゾチオール類、ｎ−ドデシルメルカプタン、ｔｅｒｔ−ドデシルメルカプタン、ジサルファイド等の連鎖移動剤を用いることもできる。 In the present invention, the production method of the methacrylic acid ester-dimethylmethacrylic acid dimethylaminoalkyl ester-styrene copolymer is not particularly limited, and various known polymerization methods such as a solution polymerization method, a suspension polymerization method, and an emulsion polymerization method are used. it can. Among these, the solution polymerization method is preferable. As the solution polymerization method, the monomer components, the solvent and the polymerization initiator are charged into a reaction vessel, mixed well, the reaction system is heated in a nitrogen stream, and continuously dropped for about 2 to 3 hours below the reflux temperature of the solvent. Then, polymerization is carried out at that temperature for about 4 to 8 hours, and after completion of the polymerization, it is obtained by neutralizing with an organic acid or inorganic acid and dissolving in water. If necessary, the solvent is distilled off, and a methacrylic acid ester-methacrylic acid is obtained. A solution of dimethylaminoalkyl ester-styrene copolymer is obtained. In the polymerization, a chain transfer agent such as mercaptan, azothiols, n-dodecyl mercaptan, tert-dodecyl mercaptan, disulfide and the like can also be used.
前記溶媒としては、低級アルコールまたは水と低級アルコールからなる混合溶媒を使用することが好ましい。低級アルコールとしては、エチルアルコール、ｎ−ブチルアルコール、イソブチルアルコール、ｔｅｒｔ−ブチルアルコール、ｓｅｃ−ブチルアルコール、ｎ−プロピルアルコール、イソプロピルアルコール等が例示できる。重合開始剤としては、過硫酸カリウム、過硫酸アンモニウム等の過硫酸塩、２，２’−アゾビスイソブチロニトリル、２，２’−アゾビス−２，４−ジメチルバレロニトリル、２，２’−アゾビス（２−メチルブチロニトリル）等のアゾ化合物、過酸化ベンゾイル、クメンハイドロパーオキサイド、ジクミルパーオキサイド、イソブチルパーオキサイド、ラウリルパーオキサイド等の過酸化物等、各種公知のものを使用できる。該重合開始剤の使用量は反応速度、分子量等を考慮して適宜決定できるが、通常はモノマー全量に対して０．５〜５質量％程度が好ましい。 As the solvent, it is preferable to use a lower alcohol or a mixed solvent composed of water and a lower alcohol. Examples of the lower alcohol include ethyl alcohol, n-butyl alcohol, isobutyl alcohol, tert-butyl alcohol, sec-butyl alcohol, n-propyl alcohol, isopropyl alcohol and the like. As a polymerization initiator, persulfates such as potassium persulfate and ammonium persulfate, 2,2′-azobisisobutyronitrile, 2,2′-azobis-2,4-dimethylvaleronitrile, 2,2′- Various known compounds such as azo compounds such as azobis (2-methylbutyronitrile), peroxides such as benzoyl peroxide, cumene hydroperoxide, dicumyl peroxide, isobutyl peroxide, and lauryl peroxide can be used. The amount of the polymerization initiator used can be appropriately determined in consideration of the reaction rate, molecular weight and the like, but is usually preferably about 0.5 to 5% by mass relative to the total amount of monomers.
本発明におけるメタクリル酸エステル−メタクリル酸ジメチルアミノアルキルエステル−スチレン共重合物の配合量としては、インク受理層のひび割れを防止するためには、インク受理層の顔料の総量に対して０．１〜１０質量％であり、より好ましくは０．２〜５質量％である。 The blending amount of the methacrylic acid ester-dimethylaminoalkyl methacrylate-styrene copolymer in the present invention is 0.1 to 0.1% based on the total amount of pigment in the ink receiving layer in order to prevent cracking of the ink receiving layer. It is 10 mass%, More preferably, it is 0.2-5 mass%.
本発明において用いられるホウ酸としては、オルトホウ酸だけでなくメタホウ酸、次ホウ酸等が使用できる。ホウ酸塩はこれらの可溶性塩が好ましく、具体的には、Ｎａ2Ｂ4Ｏ7・１０Ｈ2Ｏ、ＮａＢＯ2・４Ｈ2Ｏ、Ｋ2Ｂ4Ｏ7・５Ｈ2Ｏ、ＮＨ4ＨＢ4Ｏ7・３Ｈ2Ｏ、ＮＨ4ＢＯ2等が挙げられるが、本発明はこれらに限定されるものではない。 As boric acid used in the present invention, not only orthoboric acid but also metaboric acid and hypoboric acid can be used. The borate is preferably a soluble salt such as Na 2 B 4 O 7 .10H 2 O, NaBO 2 .4H 2 O, K 2 B 4 O 7 .5H 2 O, NH 4 HB 4 O. 7 · 3H 2 O, NH 4 BO 2 , and the like, but the present invention is not limited thereto.
ホウ酸またはホウ酸塩の配合量は、Ｈ3ＢＯ3換算でポリビニルアルコールに対して１〜１５質量％、好ましくは３〜１０質量％である。 The amount of boric acid or boric acid salt, 1 to 15 wt% with respect to polyvinyl alcohol in H 3 BO 3 in terms of, preferably 3 to 10 mass%.
本発明において、アルミナ水和物の分散液を安定化させるために、通常は種々の酸類が分散液に添加される。このような酸類としては、硝酸、塩酸、臭化水素酸、酢酸、蟻酸、塩化第二鉄、塩化アルミニウム等を挙げることができる。特に、硝酸、酢酸、塩酸から選ばれる１種以上の酸を含有することが好ましい。その配合量はインク受理層の顔料の総量に対して０．１〜５質量％が好ましい。より好ましくは、０．５〜３質量％である。この範囲にすることで、インク受理層表面のひび割れを抑制し、顔料インクの発色性を向上させることができる。 In the present invention, in order to stabilize the dispersion of alumina hydrate, various acids are usually added to the dispersion. Examples of such acids include nitric acid, hydrochloric acid, hydrobromic acid, acetic acid, formic acid, ferric chloride, aluminum chloride and the like. In particular, it is preferable to contain one or more acids selected from nitric acid, acetic acid and hydrochloric acid. The blending amount is preferably 0.1 to 5% by mass with respect to the total amount of pigment in the ink receiving layer. More preferably, it is 0.5-3 mass%. By setting it within this range, cracks on the surface of the ink receiving layer can be suppressed, and the color developability of the pigment ink can be improved.
さらに、本発明のインク受理層には、その他の添加剤として、カチオン系染料定着剤、顔料分散剤、増粘剤、流動性改良剤、粘度安定剤、ｐＨ調整剤、界面活性剤、消泡剤、抑泡剤、離型剤、発泡剤、浸透剤、着色染料、着色顔料、蛍光増白剤、紫外線吸収剤、酸化防止剤、レベリング剤、防腐剤、防バイ剤、耐水化剤、湿潤紙力増強剤、乾燥紙力増強剤等を本発明の目的を害しない範囲で適宜添加することもできる。 Furthermore, in the ink receiving layer of the present invention, as other additives, a cationic dye fixing agent, a pigment dispersant, a thickener, a fluidity improver, a viscosity stabilizer, a pH adjuster, a surfactant, an antifoaming agent Agent, foam suppressor, mold release agent, foaming agent, penetrating agent, coloring dye, coloring pigment, fluorescent brightening agent, ultraviolet absorber, antioxidant, leveling agent, antiseptic, antibacterial agent, waterproofing agent, wetting A paper strength enhancer, a dry paper strength enhancer, and the like can be appropriately added as long as the object of the present invention is not impaired.
本発明において、インク受理層の乾燥塗工量は特に限定されるものではないが、インク受理層表面でのひび割れと、顔料インクの発色性、インク吸収性の点から乾燥塗工量の範囲は３〜３０ｇ／ｍ2、より好ましくは５〜２０ｇ／ｍ2である。 In the present invention, the dry coating amount of the ink receiving layer is not particularly limited, but the range of the dry coating amount is from the viewpoint of cracks on the surface of the ink receiving layer, color development of the pigment ink, and ink absorption. It is 3-30 g / m < 2 >, More preferably, it is 5-20 g / m < 2 >.
本発明においては、該支持体と該インク受理層の間に顔料層を設けることが好ましい。 In the present invention, a pigment layer is preferably provided between the support and the ink receiving layer.
本発明において、顔料層に用いられる無機顔料としては、公知の白色顔料を１種以上用いることができる。例えば、軽質炭酸カルシウム、重質炭酸カルシウム、カオリン、タルク、硫酸カルシウム、硫酸バリウム、二酸化チタン、酸化亜鉛、硫化亜鉛、炭酸亜鉛、サチンホワイト、珪酸アルミニウム、ケイソウ土、珪酸カルシウム、珪酸マグネシウム、合成非晶質シリカ、コロイダルシリカ、コロイダルアルミナ、擬ベーマイト、水酸化アルミニウム、アルミナ、リトポン、ゼオライト、加水ハロイサイト、炭酸マグネシウム、水酸化マグネシウム等の白色無機顔料等を用いることができる。上記の無機顔料の中でも、多孔性無機顔料が好ましく、多孔性非晶質合成シリカ、多孔性炭酸マグネシウム、多孔性アルミナ等が挙げられ、特に細孔容積の大きい多孔性合成非晶質シリカが好ましい。 In the present invention, as the inorganic pigment used in the pigment layer, one or more known white pigments can be used. For example, light calcium carbonate, heavy calcium carbonate, kaolin, talc, calcium sulfate, barium sulfate, titanium dioxide, zinc oxide, zinc sulfide, zinc carbonate, satin white, aluminum silicate, diatomaceous earth, calcium silicate, magnesium silicate, synthetic non White inorganic pigments such as crystalline silica, colloidal silica, colloidal alumina, pseudoboehmite, aluminum hydroxide, alumina, lithopone, zeolite, hydrous halloysite, magnesium carbonate, and magnesium hydroxide can be used. Among the above inorganic pigments, porous inorganic pigments are preferable, and examples include porous amorphous synthetic silica, porous magnesium carbonate, porous alumina, and the like, and porous synthetic amorphous silica having a large pore volume is particularly preferable. .
本発明の顔料層に用いられるバインダーとしては、例えば、酸化澱粉、エーテル化澱粉、リン酸エステル化澱粉等の澱粉誘導体；カルボキシメチルセルロース、ヒドロキシエチルセルロース等のセルロース誘導体；カゼイン、ゼラチン、大豆蛋白、ポリビニルアルコール、またはシリル変性ポリビニルアルコール等のポリビニルアルコール誘導体、ポリビニルピロリドン、無水マレイン酸樹脂、スチレン−ブタジエン共重合体、メチルメタクリレート−ブタジエン共重合体等の共役ジエン系共重合体ラテックス、アクリル酸エステル及びメタクリル酸エステルの重合体または共重合体等のアクリル系共重合体ラテックス、エチレン酢酸ビニル共重合体等のビニル系共重合体ラテックス、あるいはこれらの各種共重合体のカルボキシ基等の官能基含有単量体による官能基変性共重合体ラテックス、メラミン樹脂、尿素樹脂等の熱硬化合成樹脂等の水性接着剤、ポリウレタン樹脂、不飽和ポリエステル樹脂、ポリビニルブチラール、アルキッド樹脂ラテックスが挙げられ、これらを１種以上使用できる。これらのバインダーのうち、接着力の点から、ポリビニルアルコール、またはシリル変性ポリビニルアルコール等のポリビニルアルコール誘導体が好ましい。 Examples of the binder used in the pigment layer of the present invention include starch derivatives such as oxidized starch, etherified starch, and phosphate esterified starch; cellulose derivatives such as carboxymethyl cellulose and hydroxyethyl cellulose; casein, gelatin, soybean protein, and polyvinyl alcohol. , Or polyvinyl alcohol derivatives such as silyl modified polyvinyl alcohol, polyvinyl pyrrolidone, maleic anhydride resin, conjugated diene copolymer latex such as styrene-butadiene copolymer, methyl methacrylate-butadiene copolymer, acrylic acid ester and methacrylic acid Acrylic copolymer latex such as an ester polymer or copolymer, vinyl copolymer latex such as ethylene vinyl acetate copolymer, or a functional group such as a carboxy group of these various copolymers. Examples include functional group-modified copolymer latex with monomers containing, water-based adhesives such as thermosetting synthetic resins such as melamine resins and urea resins, polyurethane resins, unsaturated polyester resins, polyvinyl butyral, and alkyd resin latex. One or more types can be used. Of these binders, polyvinyl alcohol and polyvinyl alcohol derivatives such as silyl-modified polyvinyl alcohol are preferable from the viewpoint of adhesive strength.
本発明の顔料層に使用されるバインダーの配合量としては、顔料インクの吸収性及びインク受理層の表面のひび割れの点から顔料層中の無機顔料の総和１００質量部に対して、３〜７０質量部、好ましくは、５〜５０質量部である。 The blending amount of the binder used in the pigment layer of the present invention is 3 to 70 with respect to 100 parts by mass of the sum of the inorganic pigments in the pigment layer in terms of the absorbability of the pigment ink and the cracks on the surface of the ink receiving layer. Part by mass, preferably 5 to 50 parts by mass.
本発明において、顔料層には、無機顔料の他、接着剤等、さらには顔料インクと染料インクを併用するインクジェット記録方式に適用する場合には上記の他、カチオン性化合物を含有することもできる。また、これらに添加剤として、染料定着剤、顔料分散剤、増粘剤、流動性改良剤、界面活性剤、消泡剤、抑泡剤、離型剤、発泡剤、浸透剤、着色染料、着色顔料、蛍光増白剤、紫外線吸収剤、酸化防止剤、防腐剤、防バイ剤、耐水化剤、湿潤力増強剤、乾燥紙力増強剤等を適宜配合することもできる。 In the present invention, the pigment layer may contain a cationic compound in addition to the inorganic pigment, an adhesive, and the like, as well as a cationic compound in addition to the above when applied to an ink jet recording system using both pigment ink and dye ink. . In addition, as additives, dye fixing agents, pigment dispersants, thickeners, fluidity improvers, surfactants, antifoaming agents, antifoaming agents, mold release agents, foaming agents, penetrating agents, colored dyes, Coloring pigments, fluorescent whitening agents, ultraviolet absorbers, antioxidants, preservatives, antibacterial agents, water resistance agents, wetting power enhancers, dry paper strength enhancing agents, and the like can be appropriately blended.
本発明において、顔料層の乾燥塗工量は特に限定されるものではないが、インク受理層表面でのひび割れと、顔料インクの発色性、インク吸収性の点から乾燥塗工量の範囲は３〜３０ｇ／ｍ2、より好ましくは５〜２０ｇ／ｍ2である。 In the present invention, the dry coating amount of the pigment layer is not particularly limited, but the range of the dry coating amount is 3 from the viewpoints of cracks on the surface of the ink receiving layer, coloring property of the pigment ink, and ink absorbability. to 30 g / m 2, more preferably from 5 to 20 g / m 2.
本発明において、顔料層及びインク受理層は、顔料層及びインク受理層の塗液を支持体上に塗工、乾燥して設ける。 In the present invention, the pigment layer and the ink receiving layer are provided by coating and drying the coating liquid of the pigment layer and the ink receiving layer on a support.
本発明において顔料層及びインク受理層を設ける際に、塗工する方法は、特に限定されず、公知の塗工方法を用いることができる。例えば、エアーナイフコーター、カーテンコーター、スライドリップコーター、ダイコーター、ブレードコーター、ゲートロールコーター、バーコーター、ロッドコーター、ロールコーター、ビルブレードコーター、ショートドエルブレードコーター、サイズプレス等の各種装置により塗工することができる。 In the present invention, when the pigment layer and the ink receiving layer are provided, the coating method is not particularly limited, and a known coating method can be used. For example, coating with various devices such as air knife coater, curtain coater, slide lip coater, die coater, blade coater, gate roll coater, bar coater, rod coater, roll coater, bill blade coater, short dwell blade coater, size press, etc. can do.
本発明において、塗液塗工後に乾燥する方法は、特に限定されず、公知の乾燥方法を用いることができるが、特に熱風を吹きつける方法、赤外線を照射する方法等、加熱により乾燥する方法は、生産性が良く好ましく用いられる。 In the present invention, the method of drying after coating the coating liquid is not particularly limited, and a known drying method can be used, but in particular, a method of drying by heating, such as a method of blowing hot air, a method of irradiating infrared rays, etc. The productivity is good and it is preferably used.
本発明において、顔料層またはインク受理層を塗工、乾燥後、平坦化をコントロールしたり表面光沢を高めたりする目的で、カレンダー処理により、平滑化しても良い。その際のカレンダー処理装置としては、グロスカレンダー、スーパーカレンダー、ソフトカレンダー等が挙げられる。 In the present invention, the pigment layer or the ink receiving layer may be coated and dried, and then smoothed by calendaring for the purpose of controlling flattening or increasing the surface gloss. Examples of the calendar processing device at that time include a gloss calendar, a super calendar, and a soft calendar.
本発明に用いる支持体は透明、半透明及び不透明のいずれであっても良く、紙、各種不織布、織布、合成樹脂フィルム、合成樹脂ラミネート紙、合成紙、金属箔、セラミック紙、ガラス板等、あるいはこれらを組み合わせた複合シートを目的に応じて任意に用いることが出来るが、これらに限定されるものではない。 The support used in the present invention may be any of transparent, translucent and opaque, such as paper, various nonwoven fabrics, woven fabric, synthetic resin film, synthetic resin laminated paper, synthetic paper, metal foil, ceramic paper, glass plate, etc. Alternatively, a composite sheet combining these can be arbitrarily used depending on the purpose, but is not limited thereto.
本発明において支持体として用いる紙としては、ＬＢＫＰ、ＮＢＫＰ等の化学パルプ、ＧＰ、ＰＧＷ、ＲＭＰ、ＴＭＰ、ＣＴＭＰ、ＣＭＰ、ＣＧＰ等の機械パルプ、ＤＩＰ等の古紙パルプ等の木材パルプと従来公知の顔料を主成分として、バインダー及びサイズ剤や定着剤、歩留まり向上剤、カチオン化剤、紙力増強剤等の各種添加剤を１種以上用いて混合し、長網抄紙機、円網抄紙機、ツインワイヤー抄紙機等の各種装置で製造された原紙、さらに原紙に、澱粉、ポリビニルアルコール等でのサイズプレスやアンカーコート層を設けた原紙や、それらの上にコート層を設けたアート紙、コート紙、キャストコート紙等の塗工紙も含まれる。この様な原紙及び塗工紙に、そのまま本発明における塗層を設けても良いし、平坦化をコントロールする目的で、マシンカレンダー、ＴＧカレンダー、ソフトカレンダー等のカレンダー装置を使用しても良い。 Examples of paper used as a support in the present invention include chemical pulps such as LBKP and NBKP, mechanical pulps such as GP, PGW, RMP, TMP, CTMP, CMP, and CGP, and wood pulp such as waste paper pulp such as DIP, and conventionally known pulps. The main component is a pigment, and a binder, a sizing agent, a fixing agent, a yield improver, a cationizing agent, a paper strength enhancer and the like are mixed using one or more kinds of additives, a long net paper machine, a circular net paper machine, Base paper manufactured with various devices such as twin-wire paper machines, base paper with size press or anchor coat layer with starch, polyvinyl alcohol, etc. on base paper, art paper with coat layer on top, coat Coated paper such as paper and cast coated paper is also included. Such a base paper and coated paper may be provided with the coating layer in the present invention as they are, or a calendar device such as a machine calendar, a TG calendar, and a soft calendar may be used for the purpose of controlling flattening.
以下に本発明を実施例を挙げて説明するが、本発明はこれらの例に限定されるものではない。また、実施例において示す「部」及び「％」は特に明示しない限り質量部及び質量％を示す。 EXAMPLES The present invention will be described below with reference to examples, but the present invention is not limited to these examples. Further, “parts” and “%” shown in the examples represent parts by mass and mass% unless otherwise specified.
＜支持体１＞
濾水度４５０ｍｌＣＳＦのＬＢＫＰ７０部、濾水度４５０ｍｌＣＳＦのＮＢＫＰ３０部から成る木材パルプ１００部に、軽質炭酸カルシウム／重質炭酸カルシウム／タルクの比率が３０／３５／３５の顔料５部、市販アルキルケテンダイマー０．１部、市販カチオン系アクリルアミド０．０３部、市販カチオン化澱粉１．０部、硫酸バンド０．５部添加し、水で希釈して１％スラリーとした。このスラリーを長網抄紙機を用いて坪量１０５ｇ／ｍ2で抄造し支持体１を得た。
<Support 1>
100 parts of wood pulp consisting of 70 parts of LBKP with a freeness of 450 ml CSF and 30 parts of NBKP with a freeness of 450 ml CSF, 5 parts of a pigment having a ratio of light calcium carbonate / heavy calcium carbonate / talc of 30/35/35, a commercially available alkyl ketene dimer 0.1 part, 0.03 part of commercially available cationic acrylamide, 1.0 part of commercially available cationized starch, and 0.5 part of sulfuric acid band were added and diluted with water to give a 1% slurry. This slurry was made using a long paper machine at a basis weight of 105 g / m 2 to obtain a support 1.
＜支持体２＞
広葉樹晒クラフトパルプ（ＬＢＫＰ、白色度９０％）と針葉樹晒サルファイトパルプ（ＮＢＳＰ、白色度９０％）の１：１混合物をＣＳＦで３００ｍｌになるまで叩解し、パルプスラリーを調製した。これにサイズ剤としてアルキルケテンダイマーを対パルプ０．５％、紙力増強剤としてポリアクリルアミドを対パルプ１．０％、カチオン化澱粉を対パルプ２．０％、ポリアミドエピクロロヒドリン樹脂を対パルプ０．５％添加し、水で希釈して１％スラリーとした。このスラリーを長網抄紙機で坪量１７０ｇ／ｍ2になるように抄造し、紙支持体を作製し、さらに紙支持体の表面（インク受理層が設けられる側）に、密度０．９１８ｇ／ｃｍ3の低密度ポリエチレン１００％の樹脂に対して、５％の割合でアナターゼ型チタンを均一に分散したポリエチレン樹脂組成物を３２０℃で溶融し、２００ｍ／分で２０μｍの厚さになるように押し出しコーティングし、微粗面化処理したクーリングロールを用いて光沢度６０％の樹脂被覆し、支持体２を作製した。
<Support 2>
A 1: 1 mixture of hardwood bleached kraft pulp (LBKP, whiteness 90%) and softwood bleached sulfite pulp (NBSP, whiteness 90%) was beaten to 300 ml with CSF to prepare a pulp slurry. As a sizing agent, alkylketene dimer is 0.5% for pulp, polyacrylamide is 1.0% for pulp, and cationized starch is 2.0% for pulp, and polyamide epichlorohydrin resin is used as a paper strength enhancer. 0.5% pulp was added and diluted with water to make a 1% slurry. This slurry is made with a long paper machine to a basis weight of 170 g / m 2 to prepare a paper support, and further, a density of 0.918 g / min is provided on the surface of the paper support (side on which the ink receiving layer is provided). A polyethylene resin composition in which anatase-type titanium is uniformly dispersed at a rate of 5% with respect to 100% low density polyethylene resin of cm 3 is melted at 320 ° C. to a thickness of 20 μm at 200 m / min. A support 2 was produced by coating a resin having a glossiness of 60% using a cooling roll that had been extrusion-coated and subjected to a fine-roughening treatment.
＜メタクリル酸エステル−メタクリル酸ジメチルアミノアルキルエステル−スチレン共重合物溶液の調整＞ <Preparation of methacrylic acid ester-dimethylaminoalkyl methacrylate methacrylate-styrene copolymer solution>
＜共重合物溶液１＞
攪拌機、温度計、還流冷却器、滴下ロートを取り付けた４ツ口フラスコにイソプロピルアルコール７０部を入れ、還流温度まで昇温、還流温度にて保持したイソプロピルアルコール中へメタクリル酸メチル３０部、メタクリル酸ｎ−ブチル２０部、ジメチルアミノエチルエステル−塩化メチル４級化塩３０部、スチレン２０部及び２，２´−アゾビスイソブチロニトリル０．５部からなる混合溶液を２時間かけて滴下し、さらに還流温度で５時間反応を行った。次いで３５％塩酸水溶液１６．９部及び水２００部を添加溶解させ、反応溶液中のイソプロピルアルコールを溜去して固形分濃度３３％の共重合物溶液１を得た。
<Copolymer solution 1>
70 parts of isopropyl alcohol is placed in a four-necked flask equipped with a stirrer, thermometer, reflux condenser, and dropping funnel, heated to reflux temperature, 30 parts of methyl methacrylate in isopropyl alcohol held at reflux temperature, methacrylic acid A mixed solution consisting of 20 parts of n-butyl, 30 parts of dimethylaminoethyl ester-methyl chloride quaternized salt, 20 parts of styrene and 0.5 part of 2,2′-azobisisobutyronitrile was added dropwise over 2 hours. Further, the reaction was carried out at the reflux temperature for 5 hours. Subsequently, 16.9 parts of 35% hydrochloric acid aqueous solution and 200 parts of water were added and dissolved, and isopropyl alcohol in the reaction solution was distilled off to obtain a copolymer solution 1 having a solid content concentration of 33%.
＜共重合物溶液２＞
攪拌機、温度計、還流冷却器、滴下ロートを取り付けた４ツ口フラスコにイソプロピルアルコール７０部を入れ、還流温度まで昇温し、還流温度にて保持したイソプロピルアルコール中へメタクリル酸メチル３０部、メタクリル酸ｎ−ブチル２０部、ジメチルアミノエチルエステル３０部、スチレン２０部及び２，２´−アゾビスイソブチロニトリル０．５部からなる混合溶液を２時間かけて滴下し、さらに還流温度で５時間反応を行った。次いで反応溶液中のイソプロピルアルコールを溜去してから３５％塩酸水溶液１６．９部及び水２３０部を添加溶解させ、これにエピクロルヒドリン１５部を加えて８０〜８５℃で２時間反応を行い、固形分濃度３３％の共重合物溶液２を得た。
<Copolymer solution 2>
Into a four-necked flask equipped with a stirrer, thermometer, reflux condenser, and dropping funnel, 70 parts of isopropyl alcohol was added, the temperature was raised to the reflux temperature, and 30 parts of methyl methacrylate, A mixed solution consisting of 20 parts of n-butyl acid, 30 parts of dimethylaminoethyl ester, 20 parts of styrene and 0.5 part of 2,2′-azobisisobutyronitrile was added dropwise over 2 hours, and further at reflux temperature of 5 parts. Time reaction was performed. Next, after distilling off the isopropyl alcohol in the reaction solution, 16.9 parts of 35% aqueous hydrochloric acid solution and 230 parts of water were added and dissolved, 15 parts of epichlorohydrin was added thereto, and the reaction was carried out at 80 to 85 ° C. for 2 hours to obtain a solid. A copolymer solution 2 having a partial concentration of 33% was obtained.
＜インク受理層塗液１＞
水４００部に１０％硝酸水溶液１０部、４％ホウ酸水溶液１２．５部、平均一次粒子径１４ｎｍの擬ベーマイトアルミナ水和物１００部を添加し、ホモジナイザーを用いて分散した後、８％ポリビニルアルコール（鹸化度８８％、重合度３５００）水溶液１００部、上記の３３％の共重合物溶液１を０．３部混合し、固形分濃度１７．６％のインク受理層塗液１を調製した。
<Ink-receiving layer coating solution 1>
10 parts of 10% nitric acid aqueous solution, 12.5 parts of 4% boric acid aqueous solution and 100 parts of pseudoboehmite alumina hydrate having an average primary particle size of 14 nm are added to 400 parts of water and dispersed using a homogenizer. 100 parts of an aqueous solution of alcohol (saponification degree 88%, polymerization degree 3500) and 0.3 part of the above 33% copolymer solution 1 were mixed to prepare ink receiving layer coating liquid 1 having a solid content concentration of 17.6%. .
＜インク受理層塗液２＞
水４００部に１０％硝酸水溶液１０部、４％ホウ酸水溶液１２．５部、平均一次粒子径１４ｎｍの擬ベーマイトアルミナ水和物１００部を添加し、ホモジナイザーを用いて分散した後、８％ポリビニルアルコール（鹸化度８８％、重合度３５００）水溶液１００部、上記の３３％の共重合物溶液１を３部混合し、固形分濃度１７．７％のインク受理層塗液２を調製した。
<Ink-receiving layer coating liquid 2>
10 parts of 10% nitric acid aqueous solution, 12.5 parts of 4% boric acid aqueous solution and 100 parts of pseudoboehmite alumina hydrate having an average primary particle size of 14 nm are added to 400 parts of water and dispersed using a homogenizer. 100 parts of an aqueous solution of alcohol (saponification degree 88%, polymerization degree 3500) and 3 parts of the above 33% copolymer solution 1 were mixed to prepare an ink receiving layer coating liquid 2 having a solid concentration of 17.7%.
＜インク受理層塗液３＞
水４００部に１０％塩酸水溶液１０部、４％ホウ酸水溶液１２．５部、平均一次粒子径１４ｎｍの擬ベーマイトアルミナ水和物１００部を添加し、ホモジナイザーを用いて分散した後、８％ポリビニルアルコール（鹸化度８８％、重合度３５００）水溶液１００部、上記の３３％の共重合物溶液１を３部混合し、固形分濃度１７．７％のインク受理層塗液３を調製した。
<Ink-receiving layer coating solution 3>
10 parts of 10% hydrochloric acid aqueous solution, 12.5 parts of 4% boric acid aqueous solution and 100 parts of pseudoboehmite alumina hydrate having an average primary particle size of 14 nm are added to 400 parts of water, and dispersed using a homogenizer. 100 parts of an aqueous solution of alcohol (saponification degree 88%, polymerization degree 3500) and 3 parts of the above 33% copolymer solution 1 were mixed to prepare ink receiving layer coating liquid 3 having a solid concentration of 17.7%.
＜インク受理層塗液４＞
水４００部に１０％酢酸水溶液１０部、４％ホウ酸水溶液１２．５部、平均一次粒子径１４ｎｍの擬ベーマイトアルミナ水和物１００部を添加し、ホモジナイザーを用いて分散した後、８％ポリビニルアルコール（鹸化度８８％、重合度３５００）水溶液１００部、上記の３３％の共重合物溶液１を３部混合し、固形分濃度１７．７％のインク受理層塗液４を調製した。
<Ink-receiving layer coating solution 4>
10 parts of 10% acetic acid aqueous solution, 12.5 parts of 4% boric acid aqueous solution and 100 parts of pseudo-boehmite alumina hydrate having an average primary particle size of 14 nm are added to 400 parts of water and dispersed using a homogenizer. 100 parts of an aqueous solution of alcohol (saponification degree 88%, polymerization degree 3500) and 3 parts of the above 33% copolymer solution 1 were mixed to prepare an ink receiving layer coating liquid 4 having a solid concentration of 17.7%.
＜インク受理層塗液５＞
水４００部に１０％乳酸水溶液１０部、４％ホウ酸水溶液１２．５部、平均一次粒子径１４ｎｍの擬ベーマイトアルミナ水和物１００部を添加し、ホモジナイザーを用いて分散した後、８％ポリビニルアルコール（鹸化度８８％、重合度３５００）水溶液１００部、上記の３３％の共重合物溶液１を３部混合し、固形分濃度１７．７％のインク受理層塗液５を調製した。
<Ink-receiving layer coating solution 5>
10 parts of 10% lactic acid aqueous solution, 12.5 parts of 4% boric acid aqueous solution and 100 parts of pseudoboehmite alumina hydrate having an average primary particle size of 14 nm are added to 400 parts of water, and dispersed using a homogenizer, 8% polyvinyl 100 parts of an alcohol (saponification degree 88%, polymerization degree 3500) aqueous solution 100 parts and the above 33% copolymer solution 1 were mixed to prepare an ink receiving layer coating liquid 5 having a solid content concentration of 17.7%.
＜インク受理層塗液６＞
水４００部に４％ホウ酸水溶液１２．５部、平均一次粒子径１４ｎｍの擬ベーマイトアルミナ水和物１００部を添加し、ホモジナイザーを用いて分散した後、８％ポリビニルアルコール（鹸化度８８％、重合度３５００）水溶液１００部、上記の３３％の共重合物溶液１を３部混合し、固形分濃度１７．８％のインク受理層塗液６を調製した。
<Ink-receiving layer coating liquid 6>
After adding 12.5 parts of 4% boric acid aqueous solution and 100 parts of pseudoboehmite alumina hydrate having an average primary particle diameter of 14 nm to 400 parts of water and dispersing using a homogenizer, 8% polyvinyl alcohol (saponification degree: 88%, Polymerization degree 3500) 100 parts of an aqueous solution and 3 parts of the above 33% copolymer solution 1 were mixed to prepare an ink-receiving layer coating liquid 6 having a solid content concentration of 17.8%.
＜インク受理層塗液７＞
水４００部に１０％硝酸水溶液１０部、４％ホウ酸水溶液１２．５部、平均一次粒子径１４ｎｍの擬ベーマイトアルミナ水和物１００部を添加し、ホモジナイザーを用いて分散した後、８％ポリビニルアルコール（鹸化度８８％、重合度３５００）水溶液１００部、上記の３３％の共重合物溶液１を３０部混合し、固形分濃度１８．３％のインク受理層塗液７を調製した。
<Ink-receiving layer coating liquid 7>
10 parts of 10% nitric acid aqueous solution, 12.5 parts of 4% boric acid aqueous solution and 100 parts of pseudoboehmite alumina hydrate having an average primary particle size of 14 nm are added to 400 parts of water and dispersed using a homogenizer. 100 parts of an aqueous solution of alcohol (saponification degree 88%, polymerization degree 3500) and 30 parts of the above 33% copolymer solution 1 were mixed to prepare an ink receiving layer coating liquid 7 having a solid content concentration of 18.3%.
＜インク受理層塗液８＞
水４００部に１０％硝酸水溶液１０部、４％ホウ酸水溶液１２．５部、平均一次粒子径１４ｎｍの擬ベーマイトアルミナ水和物１００部を添加し、ホモジナイザーを用いて分散した後、８％ポリビニルアルコール（鹸化度８８％、重合度３５００）水溶液１００部、上記の３３％の共重合物溶液２を３部混合し、固形分濃度１７．７％のインク受理層塗液８を調製した。
<Ink-receiving layer coating liquid 8>
10 parts of 10% nitric acid aqueous solution, 12.5 parts of 4% boric acid aqueous solution and 100 parts of pseudoboehmite alumina hydrate having an average primary particle size of 14 nm are added to 400 parts of water and dispersed using a homogenizer. 100 parts of an aqueous solution of alcohol (saponification degree 88%, polymerization degree 3500) and 3 parts of the above 33% copolymer solution 2 were mixed to prepare an ink receiving layer coating liquid 8 having a solid concentration of 17.7%.
＜インク受理層塗液９＞
水４００部に１０％硝酸水溶液１０部、４％ホウ酸水溶液１２．５部、平均一次粒子径１４ｎｍの擬ベーマイトアルミナ水和物８０部、合成非晶質シリカ（平均二次粒子径２．２μｍ）２０部を添加し、ホモジナイザーを用いて分散した後、８％ポリビニルアルコール（鹸化度８８％、重合度３５００）水溶液１２５部、上記の３３％の共重合物溶液１を３部混合し、固形分濃度１７．３％のインク受理層塗液９を調製した。
<Ink-receiving layer coating liquid 9>
400 parts of water, 10 parts of 10% nitric acid aqueous solution, 12.5 parts of 4% boric acid aqueous solution, 80 parts of pseudoboehmite alumina hydrate having an average primary particle diameter of 14 nm, synthetic amorphous silica (average secondary particle diameter of 2.2 μm ) 20 parts were added and dispersed using a homogenizer, and then 125 parts of 8% polyvinyl alcohol (saponification degree 88%, polymerization degree 3500) aqueous solution and 3 parts of the above 33% copolymer solution 1 were mixed and mixed. An ink receiving layer coating solution 9 having a partial concentration of 17.3% was prepared.
＜インク受理層塗液１０＞
水４００部に１０％硝酸水溶液１０部、４％ホウ酸水溶液１２．５部、平均一次粒子径１４ｎｍの擬ベーマイトアルミナ水和物６０部、合成非晶質シリカ（平均二次粒子径２．２μｍ）４０部を添加し、ホモジナイザーを用いて分散した後、８％ポリビニルアルコール（鹸化度８８％、重合度３５００）水溶液１４０部、上記の３３％の共重合物溶液１を３部混合し、固形分濃度１７．１％のインク受理層塗液１０を調製した。
<Ink-Receiving Layer Coating Liquid 10>
400 parts of water, 10 parts of 10% nitric acid aqueous solution, 12.5 parts of 4% boric acid aqueous solution, 60 parts of pseudoboehmite alumina hydrate having an average primary particle diameter of 14 nm, synthetic amorphous silica (average secondary particle diameter of 2.2 μm ) 40 parts were added and dispersed using a homogenizer, and then 140 parts of an 8% polyvinyl alcohol (saponification degree 88%, polymerization degree 3500) aqueous solution 140 parts and 3 parts of the above 33% copolymer solution 1 were mixed to form a solid. An ink receiving layer coating solution 10 having a partial concentration of 17.1% was prepared.
＜インク受理層塗液１１＞
２０％の表面がカチオン化されたコロイダルシリカ分散液（平均一次粒子径８０ｎｍ）５００部、４％ホウ酸水溶液１２．５部、１０％硝酸水溶液１０部を混合した後、さらに８％ポリビニルアルコール（鹸化度８８％、重合度３５００）水溶液８０部、上記の３３％の共重合物溶液１を３部混合し、固形分濃度１８．０％のインク受理層塗液１１を調製した。
<Ink-receiving layer coating solution 11>
After mixing 500 parts of a 20% surface-cationized colloidal silica dispersion (average primary particle diameter 80 nm), 42.5% boric acid aqueous solution 12.5 parts, 10% nitric acid aqueous solution 10 parts, 8% polyvinyl alcohol ( 80 parts of an aqueous solution having a saponification degree of 88% and a polymerization degree of 3500) and 3 parts of the above 33% copolymer solution 1 were mixed to prepare an ink receiving layer coating liquid 11 having a solid content concentration of 18.0%.
＜インク受理層塗液１２＞
水４００部に１０％硝酸水溶液１０部、平均一次粒子径１４ｎｍの擬ベーマイトアルミナ水和物１００部を添加し、ホモジナイザーを用いて分散した後、８％ポリビニルアルコール（鹸化度８８％、重合度３５００）水溶液１００部、上記の３３％の共重合物溶液１を３部混合し、固形分濃度１７．９％のインク受理層塗液１２を調製した。
<Ink-Receiving Layer Coating Liquid 12>
10 parts of 10% nitric acid aqueous solution and 100 parts of pseudoboehmite alumina hydrate having an average primary particle diameter of 14 nm are added to 400 parts of water and dispersed using a homogenizer, and then 8% polyvinyl alcohol (saponification degree 88%, polymerization degree 3500). ) 100 parts of an aqueous solution and 3 parts of the above 33% copolymer solution 1 were mixed to prepare an ink receiving layer coating liquid 12 having a solid content concentration of 17.9%.
＜インク受理層塗液１３＞
水４００部に１０％硝酸水溶液１０部、４％ホウ酸水溶液１２．５部、平均一次粒子径１４ｎｍの擬ベーマイトアルミナ水和物１００部を添加し、ホモジナイザーを用いて分散した後、８％ポリビニルアルコール（鹸化度８８％、重合度３５００）水溶液１００部混合し、固形分濃度１７．６％のインク受理層塗液１３を調製した。
<Ink-Receiving Layer Coating Liquid 13>
10 parts of 10% nitric acid aqueous solution, 12.5 parts of 4% boric acid aqueous solution and 100 parts of pseudoboehmite alumina hydrate having an average primary particle size of 14 nm are added to 400 parts of water and dispersed using a homogenizer. An ink receiving layer coating solution 13 having a solid content concentration of 17.6% was prepared by mixing 100 parts of an alcohol (saponification degree 88%, polymerization degree 3500) aqueous solution.
＜インク受理層塗液１４＞
水４００部に１０％硝酸水溶液１０部、平均一次粒子径１４ｎｍの擬ベーマイトアルミナ水和物１００部を添加し、ホモジナイザーを用いて分散した後、４８％スチレン−ブタジエン共重合体ラテックス４１．７部、４％ホウ酸１２．５部、上記の３３％の共重合物溶液１を３部混合し、固形分濃度２１．６％のインク受理層塗液１４を調製した。
<Ink-receiving layer coating solution 14>
10 parts of 10% nitric acid aqueous solution and 100 parts of pseudoboehmite alumina hydrate having an average primary particle diameter of 14 nm are added to 400 parts of water and dispersed using a homogenizer, and then 41.7 parts of 48% styrene-butadiene copolymer latex. 12.5 parts of 4% boric acid and 3 parts of the above 33% copolymer solution 1 were mixed to prepare an ink-receiving layer coating solution 14 having a solid content concentration of 21.6%.
＜顔料層塗液１＞
合成非晶質シリカ（平均二次粒子径４μｍ）１００部をホモジナイザーを用いて水４００部に分散し、これに１０％ポリビニルアルコール（完全鹸化、重合度１７００）水溶液２５０部を混合し、固形分濃度１６．７％の顔料層塗液１を調製した。
<Pigment layer coating solution 1>
100 parts of synthetic amorphous silica (average secondary particle diameter 4 μm) is dispersed in 400 parts of water using a homogenizer, and 250 parts of a 10% polyvinyl alcohol (completely saponified, degree of polymerization 1700) aqueous solution is mixed therewith to obtain a solid content. A pigment layer coating solution 1 having a concentration of 16.7% was prepared.
＜顔料層塗液２＞
合成非晶質シリカ（平均二次粒子径２μｍ）１００部をホモジナイザーを用いて水４００部に分散し、これに１０％ポリビニルアルコール（完全鹸化、重合度１７００）水溶液２５０部を混合し、固形分濃度１６．７％の顔料層塗液２を調製した。
<Pigment layer coating liquid 2>
100 parts of synthetic amorphous silica (average secondary particle size 2 μm) is dispersed in 400 parts of water using a homogenizer, and 250 parts of a 10% polyvinyl alcohol (completely saponified, degree of polymerization 1700) aqueous solution is mixed with the solid content. A pigment layer coating solution 2 having a concentration of 16.7% was prepared.
＜顔料層塗液３＞
合成非晶質シリカ（平均二次粒子径６μｍ）１００部をホモジナイザーを用いて水４００部に分散し、これに１０％ポリビニルアルコール（完全鹸化、重合度１７００）水溶液２５０部を混合し、固形分濃度１６．７％の顔料層塗液３を調製した。
<Pigment layer coating solution 3>
100 parts of synthetic amorphous silica (average secondary particle diameter 6 μm) is dispersed in 400 parts of water using a homogenizer, and 250 parts of a 10% polyvinyl alcohol (completely saponified, degree of polymerization 1700) aqueous solution is mixed with the solid content. A pigment layer coating solution 3 having a concentration of 16.7% was prepared.
＜顔料層塗液４＞
水２４０部に、５０％ジメチルジアリルアンモニウムクロライドホモポリマー（分子量９，０００）８部、沈降法シリカ（平均二次粒子径６μｍ）１００部を添加し、のこぎり歯状ブレード型分散機を使用して予備分散液を作製した。得られた予備分散液をビーズミルで処理して、固形分濃度２９．９％のシリカ分散液を得た。こうして得たシリカ分散液３３５部、これに１０％ポリビニルアルコール（完全鹸化、重合度１７００）水溶液２５０部、水２００部を混合し、固形分濃度１６．０％の顔料層塗液４を調製した。なお、レーザー回折／散乱式粒度分布測定装置で測定して得られたシリカ微粒子の平均二次粒子径は５００ｎｍであった。
<Pigment layer coating solution 4>
To 240 parts of water, 8 parts of 50% dimethyldiallylammonium chloride homopolymer (molecular weight 9,000) and 100 parts of precipitated silica (average secondary particle size 6 μm) are added, and a sawtooth blade type disperser is used. A preliminary dispersion was prepared. The obtained preliminary dispersion was treated with a bead mill to obtain a silica dispersion having a solid concentration of 29.9%. 335 parts of the silica dispersion thus obtained, 250 parts of a 10% polyvinyl alcohol (completely saponified, degree of polymerization 1700) aqueous solution and 200 parts of water were mixed to prepare a pigment layer coating solution 4 having a solid content concentration of 16.0%. . The average secondary particle diameter of the silica fine particles obtained by measurement with a laser diffraction / scattering particle size distribution analyzer was 500 nm.
＜顔料層塗液５＞
軽質炭酸カルシウム（平均二次粒子径２．０μｍ）１００部をホモジナイザーを用いて水１００部に分散し、４８％スチレン−ブタジエン共重合体ラテックス４２部を混合し、固形分濃度４９．７％の顔料層塗液５を調製した。
<Pigment layer coating solution 5>
100 parts of light calcium carbonate (average secondary particle size 2.0 μm) is dispersed in 100 parts of water using a homogenizer, and 42 parts of 48% styrene-butadiene copolymer latex is mixed to obtain a solid content concentration of 49.7%. A pigment layer coating solution 5 was prepared.
＜顔料層塗液６＞
高白１級カオリン（平均二次粒子径２．５μｍ）１００部をホモジナイザーを用いて水１５０部に分散し、これに８％酸化澱粉水溶液２５０部を混合し、固形分濃度２４％の顔料層塗液６を調製した。
<Pigment layer coating liquid 6>
100 parts of high-white primary kaolin (average secondary particle size 2.5 μm) is dispersed in 150 parts of water using a homogenizer, and 250 parts of 8% oxidized starch aqueous solution is mixed with this, and a pigment layer having a solid content concentration of 24% Coating liquid 6 was prepared.
＜顔料層塗液７＞
合成非晶質シリカ（平均二次粒子径４μｍ）９０部と軽質炭酸カルシウム（平均二次粒子径２．０μｍ）１０部をホモジナイザーを用いて水４００部に分散し、これに１０％ポリビニルアルコール（完全鹸化、重合度５００）水溶液２５０部を混合し、固形分濃度１６．７％の顔料層塗液７を調製した。
<Pigment layer coating liquid 7>
90 parts of synthetic amorphous silica (average secondary particle diameter 4 μm) and 10 parts of light calcium carbonate (average secondary particle diameter 2.0 μm) were dispersed in 400 parts of water using a homogenizer, and 10% polyvinyl alcohol ( Complete saponification, polymerization degree 500) 250 parts of an aqueous solution were mixed to prepare a pigment layer coating solution 7 having a solid concentration of 16.7%.
（実施例１）
上記で作製した支持体１の上に顔料層塗液１を乾燥固形分１０ｇ／ｍ2に成るように、エアーナイフコーターで塗工、乾燥した。次いでその顔料層の上にインク受理層塗液１をエアーナイフコーターにて乾燥固形分１０ｇ／ｍ2に成るように塗工、乾燥して、実施例１のインクジェット記録材料を作製した。
Example 1
The pigment layer coating solution 1 was coated on the support 1 produced above with an air knife coater so as to have a dry solid content of 10 g / m 2 and dried. Next, the ink receiving layer coating liquid 1 was applied onto the pigment layer with an air knife coater so as to have a dry solid content of 10 g / m 2 , and dried to produce the ink jet recording material of Example 1.
（実施例２）
実施例１でインク受理層塗液１を用いる代わりにインク受理層塗液２を用いた以外は実施例１と同一条件で実施例２のインクジェット記録材料を作製した。
(Example 2)
An ink jet recording material of Example 2 was produced under the same conditions as Example 1 except that the ink receiving layer coating liquid 2 was used instead of the ink receiving layer coating liquid 1 in Example 1.
（実施例３）
上記で作製した支持体１の上に顔料層塗液１を乾燥固形分１０ｇ／ｍ2に成るように、エアーナイフコーターで塗工、乾燥した。次いでその顔料層の上にインク受理層塗液１をエアーナイフコーターにて乾燥固形分１５ｇ／ｍ2に成るように塗工、乾燥して、実施例１のインクジェット記録材料を作製した。
(Example 3)
The pigment layer coating solution 1 was coated on the support 1 produced above with an air knife coater so as to have a dry solid content of 10 g / m 2 and dried. Next, the ink receiving layer coating liquid 1 was applied onto the pigment layer with an air knife coater so as to have a dry solid content of 15 g / m 2 , and dried to produce the ink jet recording material of Example 1.
（実施例４）
実施例１でインク受理層塗液１を用いる代わりにインク受理層塗液３を用いた以外は実施例１と同一条件で実施例４のインクジェット記録材料を作製した。
Example 4
An ink jet recording material of Example 4 was produced under the same conditions as Example 1 except that the ink receiving layer coating liquid 3 was used instead of the ink receiving layer coating liquid 1 in Example 1.
（実施例５）
実施例１でインク受理層塗液１を用いる代わりにインク受理層塗液４を用いた以外は実施例１と同一条件で実施例５のインクジェット記録材料を作製した。
(Example 5)
An ink jet recording material of Example 5 was produced under the same conditions as in Example 1 except that the ink receiving layer coating liquid 4 was used instead of the ink receiving layer coating liquid 1 in Example 1.
（実施例６）
実施例１でインク受理層塗液１を用いる代わりにインク受理層塗液７を用いた以外は実施例１と同一条件で実施例６のインクジェット記録材料を作製した。
(Example 6)
An ink jet recording material of Example 6 was produced under the same conditions as Example 1 except that the ink receiving layer coating liquid 7 was used instead of the ink receiving layer coating liquid 1 in Example 1.
（実施例７）
実施例１でインク受理層塗液１を用いる代わりにインク受理層塗液８を用いた以外は実施例１と同一条件で実施例７のインクジェット記録材料を作製した。
(Example 7)
An ink jet recording material of Example 7 was produced under the same conditions as Example 1 except that the ink receiving layer coating liquid 8 was used instead of the ink receiving layer coating liquid 1 in Example 1.
（実施例８）
実施例１でインク受理層塗液１を用いる代わりにインク受理層塗液９を用いた以外は実施例１と同一条件で実施例８のインクジェット記録材料を作製した。
(Example 8)
An ink jet recording material of Example 8 was produced under the same conditions as Example 1 except that the ink receiving layer coating liquid 9 was used instead of the ink receiving layer coating liquid 1 in Example 1.
（実施例９）
実施例１でインク受理層塗液１を用いる代わりにインク受理層塗液１０を用いた以外は実施例１と同一条件で実施例９のインクジェット記録材料を作製した。
Example 9
An ink jet recording material of Example 9 was produced under the same conditions as in Example 1 except that the ink receiving layer coating liquid 10 was used instead of the ink receiving layer coating liquid 1 in Example 1.
（実施例１０）
実施例２で顔料層塗液１を用いる代わりに顔料層塗液２を用いた以外は実施例２と同一条件で実施例１０のインクジェット記録材料を作製した。
(Example 10)
An ink jet recording material of Example 10 was produced under the same conditions as in Example 2 except that the pigment layer coating liquid 2 was used instead of the pigment layer coating liquid 1 in Example 2.
（実施例１１）
実施例２で顔料層塗液１を用いる代わりに顔料層塗液３を用いた以外は実施例２と同一条件で実施例１１のインクジェット記録材料を作製した。
Example 11
An ink jet recording material of Example 11 was produced under the same conditions as Example 2 except that the pigment layer coating liquid 3 was used instead of the pigment layer coating liquid 1 in Example 2.
（実施例１２）
実施例２で顔料層塗液１を用いる代わりに顔料層塗液４を用いた以外は実施例２と同一条件で実施例１２のインクジェット記録材料を作製した。
(Example 12)
An ink jet recording material of Example 12 was produced under the same conditions as in Example 2 except that the pigment layer coating liquid 4 was used instead of the pigment layer coating liquid 1 in Example 2.
（実施例１３）
実施例２で顔料層塗液１を用いる代わりに顔料層塗液５を用いた以外は実施例２と同一条件で実施例１３のインクジェット記録材料を作製した。
(Example 13)
An ink jet recording material of Example 13 was produced under the same conditions as Example 2 except that the pigment layer coating solution 5 was used instead of the pigment layer coating solution 1 in Example 2.
（実施例１４）
実施例２で顔料層塗液１を用いる代わりに顔料層塗液６を用いた以外は実施例２と同一条件で実施例１４のインクジェット記録材料を作製した。
(Example 14)
An ink jet recording material of Example 14 was produced under the same conditions as in Example 2 except that the pigment layer coating liquid 6 was used instead of the pigment layer coating liquid 1 in Example 2.
（実施例１５）
実施例２で顔料層塗液１を用いる代わりに顔料層塗液７を用いた以外は実施例２と同一条件で実施例１５のインクジェット記録材料を作製した。
(Example 15)
An ink jet recording material of Example 15 was produced under the same conditions as in Example 2 except that the pigment layer coating liquid 7 was used instead of the pigment layer coating liquid 1 in Example 2.
（実施例１６）
上記で作製した支持体２の上にインク受理層塗液２をエアーナイフコーターにて乾燥固形分２０ｇ／ｍ2に成るように塗工、乾燥して、実施例１６のインクジェット記録材料を作製した。
(Example 16)
The ink receiving layer coating liquid 2 was applied onto the support 2 prepared above with an air knife coater so as to have a dry solid content of 20 g / m 2 and dried to prepare an ink jet recording material of Example 16. .
（参考例１）
実施例１でインク受理層塗液１を用いる代わりにインク受理層塗液５を用いた以外は実施例１と同一条件で参考例１のインクジェット記録材料を作製した。
(Reference Example 1)
An ink jet recording material of Reference Example 1 was produced under the same conditions as in Example 1 except that the ink receiving layer coating liquid 5 was used instead of the ink receiving layer coating liquid 1 in Example 1 .
（参考例２）
実施例１でインク受理層塗液１を用いる代わりにインク受理層塗液６を用いた以外は実施例１と同一条件で参考例２のインクジェット記録材料を作製した。
(Reference Example 2)
An ink jet recording material of Reference Example 2 was produced under the same conditions as in Example 1 except that the ink receiving layer coating liquid 6 was used instead of the ink receiving layer coating liquid 1 in Example 1.
（比較例１）
実施例１でインク受理層塗液１を用いる代わりにインク受理層塗液１１を用いた以外は実施例１と同一条件で比較例１のインクジェット記録材料を作製した。
(Comparative Example 1)
An ink jet recording material of Comparative Example 1 was produced under the same conditions as in Example 1 except that the ink receiving layer coating liquid 11 was used instead of the ink receiving layer coating liquid 1 in Example 1.
（比較例２）
実施例１でインク受理層塗液１を用いる代わりにインク受理層塗液１２を用いた以外は実施例１と同一条件で比較例２のインクジェット記録材料を作製した。
(Comparative Example 2)
An ink jet recording material of Comparative Example 2 was prepared under the same conditions as in Example 1 except that the ink receiving layer coating liquid 12 was used instead of the ink receiving layer coating liquid 1 in Example 1.
（比較例３）
実施例１でインク受理層塗液１を用いる代わりにインク受理層塗液１３を用いた以外は実施例１と同一条件で比較例３のインクジェット記録材料を作製した。
(Comparative Example 3)
An ink jet recording material of Comparative Example 3 was prepared under the same conditions as in Example 1 except that the ink receiving layer coating liquid 13 was used instead of the ink receiving layer coating liquid 1 in Example 1.
（比較例４）
実施例１でインク受理層塗液１を用いる代わりにインク受理層塗液１４を用いた以外は実施例１と同一条件で比較例４のインクジェット記録材料を作製した。
(Comparative Example 4)
An ink jet recording material of Comparative Example 4 was produced under the same conditions as in Example 1 except that the ink receiving layer coating liquid 14 was used instead of the ink receiving layer coating liquid 1 in Example 1.
＜評価＞
実施例１〜１６、参考例１及び２，比較例１〜４で作製したインクジェット記録材料にセイコーエプソン（株）製「ＭＣ−１００００（プリンタ設定：ＭＣ光沢用紙、きれい）」を用いて画像を印刷し、インク受理層表面のひび割れの有無、インク吸収性について評価を行った。評価に用いた画像は黒、シアン、マゼンタ、イエロー、ブルー、レッド、グリーン各色のベタ印字及びその中に白抜き文字を設けたパターン等からなる。
<Evaluation>
Images were prepared using “MC-10000 (printer setting: MC glossy paper, clean)” manufactured by Seiko Epson Corporation on the inkjet recording materials prepared in Examples 1 to 16, Reference Examples 1 and 2 , and Comparative Examples 1 to 4. Were printed and evaluated for the presence or absence of cracks on the surface of the ink receiving layer and ink absorbability. The image used for evaluation is composed of solid prints of black, cyan, magenta, yellow, blue, red, green, and a pattern in which white characters are provided.
インク受理層表面のひび割れの有無は、作製したインクジェット記録材料の表面を目視で観察して評価した。「◎」は全くひび割れが観察されない。「○」は極めて少数の細かいひび割れが観察される。「△」は細かいひび割れが観察されるが実用上問題ない。「×」は大きいひび割れが多数発生して実用不可の状態である。結果を表１の「塗層のひび割れ」に示した。 The presence or absence of cracks on the surface of the ink receiving layer was evaluated by visually observing the surface of the produced inkjet recording material. In “◎”, no cracks are observed. “○” indicates very few fine cracks. In “Δ”, fine cracks are observed, but there is no practical problem. “X” is a state in which many large cracks are generated and impractical. The results are shown in “Crack of coating layer” in Table 1.
インク吸収性は、ベタ印字部分の均一性、隣り合ったベタ印字部の境界部や白抜き文字の鮮鋭性等を目視で観察して評価し、１〜１０の数値で表した。１は最もインクの吸収性が悪いことを表し、数値が大きくなるほどインクの吸収性が良好で、１０は最もインクの吸収性が良好なことを示す。６以上であれば実用上問題ない。結果を表１の「インク吸収性」に示した。 The ink absorptivity was evaluated by visually observing the uniformity of solid print portions, the boundary between adjacent solid print portions, the sharpness of white characters, and the like, and was represented by a numerical value of 1 to 10. 1 indicates that the ink absorbability is the worst, and the larger the numerical value, the better the ink absorbency, and 10 indicates the most ink absorbability. If it is 6 or more, there is no practical problem. The results are shown in “ink absorbability” in Table 1.
インク発色性は、黒ベタ印字部分の濃度を濃度計（マクベスＲＤ９１８）を用いて測定した。数値が高い方がインクの発色性が良好で、１．９以上であれば実用上問題なく、１．９よりも低い場合には、印字部分にむらが発生し、実用が不可の状態である。結果を表１の「インク発色性」に示した。 Ink color development was measured by using a densitometer (Macbeth RD918) for the density of the black solid print portion. The higher the numerical value, the better the color developability of the ink. When the value is 1.9 or more, there is no practical problem. When the value is lower than 1.9, unevenness occurs in the printed portion, and the practical use is not possible. . The results are shown in “Ink color development” in Table 1.
表１中、実施例１〜１６に示す様に支持体上にアルミナ水和物を主成分とし、少なくともポリビニルアルコール、メタクリル酸エステル−メタクリル酸ジメチルアミノアルキルエステル−スチレン共重合物、ホウ酸またはホウ酸塩、及び硝酸、酢酸、塩酸から選ばれる１種以上の酸を含有するインク受理層の塗液を塗工・乾燥して形成されるインクジェット記録材料により、熱による乾燥を行ってもインク受理層表面にひび割れを生じさせずに顔料インクの吸収性と発色性を兼ね備えたインクジェット記録材料を得ることができた。また、該支持体と該インク受理層の間に顔料層を設けたことで、インク受理層表面にひび割れを生じさせずにインク吸収性の良好なインクジェット記録材料を得ることができた。 In Table 1, as shown in Examples 1 to 16 , alumina hydrate was a main component on the support, and at least polyvinyl alcohol, methacrylate ester-dimethylaminoalkyl ester methacrylate-styrene copolymer, boric acid or An ink-jet recording material formed by applying and drying a coating solution for an ink-receiving layer containing at least one acid selected from borate , nitric acid, acetic acid, and hydrochloric acid. It was possible to obtain an ink jet recording material having both pigment ink absorptivity and color developability without causing cracks on the surface of the receiving layer. Further, by providing a pigment layer between the support and the ink receiving layer, an ink jet recording material having good ink absorbability could be obtained without causing cracks on the surface of the ink receiving layer.
実施例１、１６の比較により、該支持体と該インク受理層の間に顔料層を設けることにより、インク受理層表面にひび割れを生じさせずにインク吸収性が良化し、好ましい。 By comparing Examples 1 and 16, it is preferable to provide a pigment layer between the support and the ink receiving layer, since the ink absorption is improved without causing cracks on the surface of the ink receiving layer.
比較例１においては、アルミナ水和物を含有しないため、インクの吸収性及び発色性が低下した。また、比較例２、３及び４においてはインク受理層にホウ酸もしくはポリビニルアルコール、メタクリル酸エステル−メタクリル酸ジメチルアミノアルキルエステル−スチレン共重合物を含有していないため、ひび割れを防止することができなかった。 In Comparative Example 1, since no alumina hydrate was contained, the ink absorptivity and color developability were lowered. In Comparative Examples 2, 3 and 4, since the ink receiving layer does not contain boric acid or polyvinyl alcohol, and a methacrylic acid ester-dimethylaminoalkyl ester methacrylate-styrene copolymer, it is possible to prevent cracking. There wasn't.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2005370546A JP4472629B2 (en) | 2005-12-22 | 2005-12-22 | Inkjet recording material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2005370546A JP4472629B2 (en) | 2005-12-22 | 2005-12-22 | Inkjet recording material |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2007168324A JP2007168324A (en) | 2007-07-05 |
| JP2007168324A5 JP2007168324A5 (en) | 2008-09-18 |
| JP4472629B2 true JP4472629B2 (en) | 2010-06-02 |
Family
ID=38295515
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2005370546A Active JP4472629B2 (en) | 2005-12-22 | 2005-12-22 | Inkjet recording material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4472629B2 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6827872B2 (en) * | 2017-03-31 | 2021-02-10 | トッパン・フォームズ株式会社 | Recording sheet for inkjet |
| JP6827871B2 (en) * | 2017-03-31 | 2021-02-10 | トッパン・フォームズ株式会社 | Recording sheet for inkjet |
| JP6827873B2 (en) * | 2017-03-31 | 2021-02-10 | トッパン・フォームズ株式会社 | Recording sheet for inkjet |
-
2005
- 2005-12-22 JP JP2005370546A patent/JP4472629B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP2007168324A (en) | 2007-07-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP3876146B2 (en) | Inkjet recording medium and method of manufacturing | |
| KR20060041973A (en) | Ink jet recording sheet | |
| JP4472629B2 (en) | Inkjet recording material | |
| JP3699859B2 (en) | Ink jet recording sheet and manufacturing method thereof | |
| JP3810229B2 (en) | Inkjet recording sheet | |
| JP2004175113A (en) | Ink jet recording medium and method for manufacturing the same | |
| JP3991489B2 (en) | Inkjet recording paper | |
| JP4050475B2 (en) | Inkjet recording paper | |
| JP3895574B2 (en) | Inkjet recording medium and method of manufacturing | |
| JP2005001373A (en) | Inkjet recording material | |
| JP2004230759A (en) | Ink jet recording medium for non-aqueous pigmented ink | |
| JP4504296B2 (en) | Method for producing ink jet recording material | |
| JP2005271444A (en) | Inkjet medium to be recorded | |
| JP4243260B2 (en) | Inkjet recording medium and method for producing the same | |
| JP2003285533A (en) | Method for manufacturing ink jet recording sheet | |
| JP4279182B2 (en) | Inkjet recording material | |
| JP4420837B2 (en) | Inkjet recording material | |
| JP4068328B2 (en) | Inkjet recording medium and method for producing the same | |
| JP3699104B2 (en) | Ink jet recording medium and manufacturing method thereof | |
| JP4014387B2 (en) | Method for manufacturing inkjet recording medium | |
| JP3911260B2 (en) | Inkjet recording sheet | |
| JP4504205B2 (en) | Inkjet recording material | |
| JP2006256157A (en) | Gloss ink jet recording sheet | |
| JP2005119217A (en) | Inkjet recording material and inkjet imaging method using inkjet recording material | |
| JP2001096908A (en) | Ink jet recording sheet |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20080801 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20080801 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20091127 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20091201 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20100126 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20100223 |
|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20100303 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130312 Year of fee payment: 3 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 4472629 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130312 Year of fee payment: 3 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140312 Year of fee payment: 4 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |