JP4398521B2 - Wrapping material and manufacturing method thereof - Google Patents

Wrapping material and manufacturing method thereof Download PDF

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Publication number
JP4398521B2
JP4398521B2 JP03552298A JP3552298A JP4398521B2 JP 4398521 B2 JP4398521 B2 JP 4398521B2 JP 03552298 A JP03552298 A JP 03552298A JP 3552298 A JP3552298 A JP 3552298A JP 4398521 B2 JP4398521 B2 JP 4398521B2
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Japan
Prior art keywords
fiber
wrapping material
polishing
fibers
inorganic long
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JPH11216677A (en
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俊 松下
賢二 菊澤
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Xebec Technology Co Ltd
Taimei Chemicals Co Ltd
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Xebec Technology Co Ltd
Taimei Chemicals Co Ltd
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Description

【0001】
【発明の属する技術分野】
本発明はバリ取りや研磨加工に適した研磨用ラッピング材に関する。さらに具体的には、鉄または鉄合金、アルミニウムまたはアルミニウム合金、銅または銅合金、マグネシウム合金、あるいはニッケルまたはニッケル合金等のバリ取りや研磨加工、さらにはこれらの金型の研磨加工を行うのに適した研磨用ラッピング材に関する。
【0002】
【従来の技術】
たとえば、実公昭51−12796号公報、特開平1−222865号公報等に開示されているように、無機長繊維を熱硬化性樹脂で固めた成形体はラッピング材として極めて有用であり、特に、繊維径が揃っていることから金型等の研磨面に線状傷を生ぜず、金型等の仕上げが素人でも可能になつたことはよく知られた事実である。
【0003】
【発明が解決しようとする課題】
前記従来技術によれば、仕上げ面の仕上げ効率(加工効率)は繊維径に依存せざるを得ず、まず、繊維径の太い40μm等の繊維からなるラッピング材で粗磨きを行い、ついで繊維径15μm程度の繊維からなるラッピング材で研磨を行い、最後は繊維径10μm程度の繊維からなるラッピング材で研磨を行って、最終的には研磨粉によるバフ仕上げを行っていた。
しかし、上記に示した特開平1−222865号公報に開示のラッピング材におけるように繊維を一方向に引き揃えて作成した成形板から切り出して作ったスティック状のラッピング材は、研磨方向に糸が引き揃えられているため、厚みが0.5〜1mmの薄板状のスティックにした場合、スティックにひねりが加わった際に一方向に引き揃えられた糸の方向に沿って割れが生じ易く、いわゆる縦割れを起こすという欠点を有していた。また、このスティックを使って研磨する際、一方向に糸が引き揃えられているため研磨方向が定まらず、どうしても、わずかであるが研磨方向が左右にずれて磨かれ、いわゆる横スベリを起こすという現象が見られた。
また、一方向に引き揃えられた繊維の先端面で研削、研磨を行うため、繊維径が40μm以上の粗磨きの領域での効率を上げるためには繊維径を太くせざるを得ないという欠点を有し、繊維径が太いと製造の困難な糸の製作の検討が必要とされていた。
そこで、本発明は金型のリブ等の細い溝の研磨に適した厚みが0.5〜1mmのスティック状においても縦割れを起こし難く、なおかつ研削、研磨面に対して研削、研磨の際にも横すべりを起こさず、研削、研磨面に対して食いつき性がよく、研削、研磨効率の上がるラッピング材を提供しようとするものである。すなわち、本発明は前記各工程における研削、研磨の効率を上げる手段を提供するものである。
【0004】
【課題を解決するための手段】
繊維径が一定の繊維を使って研削、研磨効率を上げる方法として、本発明者等は鋭意研究を行った結果、研削、研磨の方向と繊維の引き揃え方向との間に一定の角度を設け、しかも一方向ではなく、研削、研磨方向に対して、左右の双方向に綾を振ることにより得られた板から、この綾を振られた面に対して平行にスライス切りして得たスティックをラッピング材として用いることにより、研磨の際にもスティックが片方向にねじれることもなく研削、研磨効率を飛躍的に上げることに成功したものである。
すなわち、請求項1記載の本発明のラッピング材は、無機長繊維に熱硬化性樹脂を含浸させ表裏に平坦面を備える平板状の成形体とし、前記無機長繊維を研磨方向に対して左右対称な二方向に配向させ、前記成形体の長手方向前端面に現れる前記各長繊維の繊維端面で研削、研磨するラッピング材であって、前記各長繊維が研磨方向に対して直交する方向であってかつ前記成形体の平坦面に対して平行方向に長軸を有する楕円形状の繊維端面を備えることを特徴とする。
また、請求項2記載のラッピング材は、前記無機長繊維を研磨方向に対して10〜45度の角度で左右対称な二方向に配向させてなることを特徴とする。
また、請求項3記載のラッピング材は、前記無機長繊維を研磨方向に対して12.5〜45度の角度で左右対称な二方向に配向させてなることを特徴とする。
また、請求項4記載のラッピング材は、前記無機長繊維を綾振りによって研磨方向に対して左右対称な二方向に配向させてなることを特徴とする。
また、請求項5記載のラッピング材は、前記無機長繊維はガラス繊維、アルミナ質繊維、炭化珪素質繊維、ボロン質繊維及び窒化珪素質繊維からなる群から選ばれた無機長繊維であることを特徴とする。
また、請求項6記載のラッピング材は、前記無機長繊維を70〜85重量%としたことを特徴とする。
また、請求項7記載の本発明のラッピング材の製造方法は、熱硬化性樹脂を含浸させた無機長繊維を回転体の回転方向に沿ってその外周に綾振りさせつつ巻き取り、この回転体上に巻き取った成形材料を回転体の軸方向にカットして切り開き、シート状に広げ、これを必要ならば複数枚積層し、加熱加圧プレスすることにより硬化させてラッピング材ブロックを作成し、このブロックの綾振りした面がラッピング時の平坦面側になるように平板状にスライス切りすることを特徴とする。
また、請求項8記載にラッピング材の製造方法は、前記綾振りをパラレル巻きとしたことを特徴とする。
また、請求項9記載のラッピング材の製造方法は、前記綾振りをヘリカル巻きとしたことを特徴とする。
【0005】
【発明の実施の形態】
繊維を一方向に引き揃えずに、研削、研磨方向に対して左右対称な二方向に配向させて作成されたスティック状のラッピング材は次のような特徴を持つ。
まず、繊維が研削、研磨方向に対して二方向に配向していることにより、スティックが研削、研磨の際に一方向にねじれることがない。
また、繊維を一方向にだけ配向したスティックに比べ、スティックをひねった際に縦割れを起こしにくい。特に、厚みが0.5〜1mmの厚みの薄いスティックにおいてそのことが顕著である。
【0006】
また、繊維を研削、研磨方向に対して左右対称な二方向に配向することで、図2に示すように、各長繊維1は研磨方向に対して直交する方向に長軸を有する楕円形状の繊維端面を備えることになり、被研磨材に対して作用する繊維端面の前端側の外周縁1aが長くなり、研削、研磨効率が上がる。このように図3に示す、通常の円形の繊維端を有する長繊維1の研削、研磨用ラッピング材と繊維コンテントは同一にもかかわらず、研磨面における、被研磨材に対して作用する繊維端面の前端側の外周縁1aが長くなり、研削、研磨効率が上がることになり、あたかも、もっと太い繊維を使用したのと同じような効率のアップが可能となる。
【0007】
また、研削、研磨方向に対し左右対称な二方向に繊維が向いているので、研削、研磨の際に横すべりせず、精密研磨での効率が上がる。すなわち、繊維をこのように左右双方向に綾を振ることにより、研削、研磨の際のワークに対する食い付きがよくなり、研削、研磨効率が上がる。
【0008】
前記無機質繊維としては、ガラス繊維、アルミナ質繊維、炭化珪素質繊維、ボロン質繊維、窒化珪素質繊維などがあげられるが、本発明者等の実験によれば、アルミナ質繊維あるいは炭化珪素質繊維が鉄、ニッケルおよびそれらの合金材料の磨きに特に適しており、アルミニウム、銅、マグネシウム合金にはガラス繊維が特に適している。
【0009】
前記無機長繊維を一方向に引き揃えたUDプリプレグを左右双方向に一定の角度になるように何層か積層しプレス成形したものを繊維が研削、研磨方向に対して左右等しい角度に向くように切り出して前記のようなラッピング材を得ることができる。
また、前記無機長繊維の繊維束を樹脂の中を通して樹脂を含浸させフィラメントワインディング法によりいわゆるヘリカル巻きといわれる方法で円筒に円周方向に対して角度θで綾を振って巻き付けた後、これを円筒の軸方向に切り開いてシート状にして加熱プレス成形し、図1に示すように、無機長繊維1の繊維束11を二方向に配向させたブロック材20を得、これからプレス面と平行にスティック21を切り出して前記ラッピング材を得ることができる。
また、いわゆるパラレル巻きで円周方向に対して角度が10〜45度になるような幅に円筒に右方向に巻き付け、次の層を左方向に巻き付けることを繰り返すことにより、一層毎に右、左の方向に角度を持った層を作成して加熱プレスしてブロックを作成してもよい。
【0010】
前記無機長繊維を含浸させる熱硬化性樹脂としては、特に限定されるものではないが、エポキシ樹脂、フェノール樹脂等の熱硬化性樹脂が好ましい。特に耐熱性を必要とする場合はポリイミド、ポリアミド、ポリマレイミド樹脂等も使われる。
前記ラッピング材の繊維含有量は60〜87重量%の範囲が望ましい。なお、60重量%未満では研磨性が低下し、また87重量%を超えると無機長繊維の接着が悪くなり強度低下が生じる。従って70〜85重量%の範囲が最適である。
【0011】
また、前記無機長繊維の削り方向に対する配向角度に関しては、研磨方向に対して10度未満では被研磨材に作用する繊維端面の前端側の外周長さの増加率が少なく、12.5度以上が望ましい。縦方向の弾性率、折れにくさを維持し、なおかつ研磨面への食いつき効果を得るには17.5度〜45度の範囲が最適である。なお、45度を超える角度では研磨方向に対する強度と弾性率の低下が大きく実用に向かない。
【0012】
【実施例】
次に、本発明ラッピング材の実施例を説明する。
(実施例1)
先ず、樹脂組成として下記の樹脂組成物を作成した
エポキシ樹脂(DER383J ダウケミカルジャパン) 100部
テトラヒドロメチル無水フタル酸(HN2200 日立化成) 80部
イミダゾール(2E4MZ−CN 四国化成 ) 2部
上記の樹脂組成物を入れた樹脂槽の中を繊維径40μmのアルミナ繊維を500本引き揃えた2000TEXからなるアルミナ繊維を24本通して樹脂組成物を含浸させ、これを繊維径106mmからなる円筒に円周方向に一周に対して70.5mmづつずらして282mmの幅に平行巻(パラレル巻)に6往復した後、これを軸方向に切り開いてシートを作成した。このシートは円周方向に対して右方向に12.5度傾斜したアルミナ繊維層と左方向に12.5度傾斜したアルミナ繊維層が交互に重なり合ったシートを形成していた。
【0013】
このようにして作成したシート2枚を円周方向に320mmの長さにカットし、この2枚を同方向に積み重ね、120度に加熱した330mm×300mmのポジティブ金型にいれ、100Kg/cm2 の圧力で加圧し、1時間後に取り出し、10.1mmの厚みの板を作成した。
この板より試験片を切り出し、繊維のコンテントを測定したところ82.5重量%であった。
【0014】
また、前記板から円周方向に10mmの幅に角棒を切り出し、これを横に倒して1mmの幅にカットし、幅10mm、厚み1mm、長さ100mmのスティックを作成した。
このスティックは幅10mmの面に平行に長さ方向に対して右方向に12.5度に引き揃えられた繊維の層と左方向に12.5度に引き揃えられた繊維の層とが交互に重なり二方向に繊維が向いたスティックを形成している。
このスティックと、長さ方向に実施例と同じ繊維径40μmの繊維を用い一方向にだけ繊維が引き揃えられたスティック(繊維のコンテントが83重量%)とを用い、S45Cの鋼製の金型を研磨したところ、この実施例の二方向に綾を振ったスティックは一方向に引き揃えられた繊維のスティックにくらべ、被研磨面に対する食い付き性、削り性が格段に優れ、研磨の際に横滑りを生ぜず、しかも線状きずのない良好な研磨面が得られた。
これに対して一方向にだけ繊維が引き揃えられているスティックはひねりに弱く、ひねると簡単に縦割れを生じた。
また、前記実施例のスティックと、実施例の繊維径40μmの繊維の代わりに繊維径50μmの繊維を用い一方向にだけ繊維が引き揃えられたスティック(繊維コンテント84重量%)とを用い、S45Cの鋼製金型での研磨性を比較したところ、被研磨面に対する食い付き性において実施例の繊維径40μmの繊維を用いて綾を振って作成したスティックは繊維径50μmの繊維を一方向にだけ引き揃えて作成したスティックとほぼ同等の金型への食い付き性を有していた。すなわち、綾を振ることにより、繊維径50μmの繊維を一方向にだけ引き揃えて作成しスティックと同等の食い付き性を繊維径40μmの繊維で得ることができた。
【0015】
(実施例2)
実施例1と同じ樹脂組成物を入れた樹脂槽の中を繊維径40μmのアルミナ繊維を500本引き揃えた2000TEXからなるアルミナ繊維を1本通して樹脂組成物を含浸させこれを繊維径106mmからなる円筒に円周方向に対して21.6度の角度にヘリカル巻でフィラメントワインディングマシーンによりワインディングを行った。一往復で5.875mmずれるようにし一往復で先に巻かれた繊維束のとなりにつぎの繊維束が巻かれるように設計した。このようにして282mmの幅に392往復させて巻いた成形材料を円筒の軸方向に切り開いてシートを作成した。
【0016】
このようにして作成したシート2枚を円周方向に320mmの長さにカットし、この2枚を同方向に積み重ね120度に加熱した330mm×300mmのポジティブ金型にいれ、100Kg/cm2 の圧力で加圧し、1時間後に取り出し、6.5mmの厚みの板を作成した。
この板より試験片を切り出し、繊維のコンテントを測定したところ82.0重量%であった。
【0017】
また、前記板から円周方向に10mmの幅に角棒を切り出し、これを横に倒して1mmの幅にカットし、幅10mm、厚み1mm、長さ100mmのスティックを作成した。
このスティックは長さ方向に対して幅10mmの面に平行に長さ方向に対して右方向に21.6度に向いた繊維束と左方向に21.6度に向いた繊維束が綾を振って重なり二方向に繊維が向いたスティックを形成していた。
このスティックと、長さ方向に一方向にだけ繊維が引き揃えられたスティックとを用い、S45Cの鋼製の金型を研磨したところ、実施例1と同様、この二方向に綾を振ったスティックも一方向に引き揃えられた繊維のスティックにくらべ被研磨面に対する食い付き性、削り性が格段に優れ、実施例1のスティックと比較しても、この実施例2のスティックの食い付き性は優れていた。これは実施例2の綾振り角度が大きいことによるものと考えられる。また、ひねったときに縦割れを生じず、しかも線状きずのない良好な研磨面が得られた。
これに対して一方向にだけ繊維が引き揃えられているスティックはひねりに弱く、ひねると簡単に縦割れを生じた。
【0018】
【発明の効果】
本発明のラッピング材によれば、研削、研磨方向に対して二方向に繊維が配向していることにより、スティックが研削、研磨の際に一方向にねじれることがない。また、繊維が一方向にだけ配向しているスティックに比べ、スティックをひねった際に縦割れを起こしにくい。また、繊維を研削、研磨方向に対して左右対称な二方向に配向することで、各繊維は研磨方向に対して直交する方向に長軸を有する楕円形状の繊維端面を備えることになり、被研磨材に対して作用する繊維端面の前端側の外周縁が長くなり、研削、研磨効率が上がる。しかも、研削、研磨の際に横すべりせず、精密研磨での効率が上がり、研削、研磨の際のワークに対する食い付きがよくなり、研削、研磨効率が上がる。
また、本発明のラッピング材の製造方法によれば、無機長繊維を円筒に対して任意の角度で、任意の巻き方で円筒に巻き付けるだけで、所望の楕円状の繊維端を有するラッピング材を簡単に製造することができる。
【図面の簡単な説明】
【図1】 本発明ラッピング材の製造行程を示す斜視図
【図2】 本発明ラッピング材の端面の模式図
【図3】 従来のラッピング材の端面の模式図
【符号の説明】
1 無機長繊維(単繊維)
1a 外周縁
11 繊維束
20 ブロック材
21 スティック
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a lapping material for polishing suitable for deburring and polishing. More specifically, for deburring and polishing of iron or iron alloy, aluminum or aluminum alloy, copper or copper alloy, magnesium alloy, nickel or nickel alloy, and further polishing these molds. The present invention relates to a suitable lapping material for polishing.
[0002]
[Prior art]
For example, as disclosed in Japanese Utility Model Publication No. 51-12796, Japanese Patent Application Laid-Open No. 1-222865, etc., a molded body in which inorganic long fibers are hardened with a thermosetting resin is extremely useful as a wrapping material. It is a well-known fact that since the fiber diameters are uniform, linear scratches do not occur on the polished surface of the mold or the like, and the finishing of the mold or the like is possible even for an amateur.
[0003]
[Problems to be solved by the invention]
According to the prior art, the finishing efficiency (processing efficiency) of the finished surface has to depend on the fiber diameter. First, rough polishing is performed with a lapping material made of fibers having a large fiber diameter, such as 40 μm, and then the fiber diameter. Polishing was performed with a wrapping material made of fibers of about 15 μm, and finally polishing was performed with a wrapping material made of fibers having a fiber diameter of about 10 μm, and finally buffing with polishing powder was performed.
However, the stick-shaped wrapping material cut out from the molded plate prepared by aligning the fibers in one direction as in the wrapping material disclosed in Japanese Patent Laid-Open No. 1-222865 shown above has a thread in the polishing direction. When the stick is made into a thin plate having a thickness of 0.5 to 1 mm, cracks are likely to occur along the direction of the yarn aligned in one direction when the stick is twisted. It had the disadvantage of causing vertical cracks. Also, when polishing with this stick, because the yarn is aligned in one direction, the polishing direction is not fixed, and the polishing direction is inevitably slightly shifted from side to side, causing so-called lateral sliding. The phenomenon was seen.
In addition, since grinding and polishing are performed on the fiber end face aligned in one direction, the fiber diameter must be increased in order to increase the efficiency in the rough polishing region where the fiber diameter is 40 μm or more. It has been necessary to study the production of yarns that are difficult to manufacture when the fiber diameter is large.
Therefore, the present invention is less likely to cause vertical cracking even in a stick shape having a thickness of 0.5 to 1 mm suitable for polishing a thin groove such as a rib of a mold. Therefore, the present invention intends to provide a lapping material that does not cause side slip, has good biting property on the ground surface, and has improved grinding and polishing efficiency. That is, the present invention provides means for increasing the efficiency of grinding and polishing in each of the above steps.
[0004]
[Means for Solving the Problems]
As a method of increasing the grinding and polishing efficiency using fibers with a constant fiber diameter, the present inventors have conducted intensive research, and as a result, established a certain angle between the direction of grinding and polishing and the direction of fiber alignment. In addition, a stick obtained by slicing the twill parallel to the swirled surface from a plate obtained by tapping the twill in both the left and right directions in the grinding and polishing directions, not in one direction By using as a wrapping material, the stick was not twisted in one direction during polishing, and the grinding and polishing efficiency was successfully increased.
That is, the wrapping material of the present invention according to claim 1 is a flat molded body in which inorganic long fibers are impregnated with a thermosetting resin and have flat surfaces on the front and back, and the inorganic long fibers are symmetrical with respect to the polishing direction. Wrapping material that is oriented in two directions and is ground and polished at the fiber end surface of each long fiber appearing on the front end surface in the longitudinal direction of the molded body, wherein each long fiber is in a direction perpendicular to the polishing direction. In addition, an elliptical fiber end surface having a major axis in a direction parallel to the flat surface of the molded body is provided.
The wrapping material according to claim 2 is characterized in that the inorganic long fibers are oriented in two symmetrical directions at an angle of 10 to 45 degrees with respect to the polishing direction.
The wrapping material according to claim 3 is characterized in that the inorganic long fibers are oriented in two symmetrical directions at an angle of 12.5 to 45 degrees with respect to the polishing direction.
The wrapping material according to claim 4 is characterized in that the inorganic long fibers are oriented in two directions symmetrical to the polishing direction by traversing.
The wrapping material according to claim 5, wherein the inorganic long fiber is an inorganic long fiber selected from the group consisting of glass fiber, alumina fiber, silicon carbide fiber, boron fiber and silicon nitride fiber. Features.
The wrapping material according to claim 6 is characterized in that the inorganic long fibers are 70 to 85% by weight.
According to a seventh aspect of the present invention, there is provided a method for producing a wrapping material according to the present invention, in which an inorganic long fiber impregnated with a thermosetting resin is wound while traversing the outer circumference along the rotating direction of the rotating body. Cut the molding material wound up in the axial direction of the rotating body, cut it open, spread it into a sheet, and if necessary, stack multiple sheets and cure by heating and pressing to create a wrapping material block The block is sliced into flat plates so that the traversed surface of the block is on the flat surface side during lapping.
Moreover, the manufacturing method of the wrapping material according to claim 8 is characterized in that the traverse is parallel winding.
The wrapping material manufacturing method according to claim 9 is characterized in that the traverse is helically wound.
[0005]
DETAILED DESCRIPTION OF THE INVENTION
A stick-shaped lapping material produced by aligning fibers in two directions symmetrical to the grinding and polishing directions without aligning the fibers in one direction has the following characteristics.
First, since the fibers are oriented in two directions with respect to the grinding and polishing directions, the stick is not twisted in one direction during the grinding and polishing.
Also, compared to a stick in which fibers are oriented in only one direction, vertical cracks are less likely to occur when the stick is twisted. This is particularly noticeable in thin sticks having a thickness of 0.5 to 1 mm.
[0006]
Further, by grinding the fibers and orienting the fibers in two directions symmetrical to the polishing direction, each long fiber 1 has an elliptical shape having a long axis in a direction orthogonal to the polishing direction, as shown in FIG. Since the fiber end face is provided, the outer peripheral edge 1a on the front end side of the fiber end face acting on the material to be polished becomes longer, and the grinding and polishing efficiency increases. In this way, the fiber end surface acting on the material to be polished on the polishing surface, although the normal lapping fiber 1 having a circular fiber end and the lapping material for polishing and the fiber content shown in FIG. 3 are the same. As a result, the outer peripheral edge 1a on the front end side becomes longer and the grinding and polishing efficiency increases, and it is possible to increase the efficiency as if using thicker fibers.
[0007]
In addition, since the fibers are oriented in two directions that are bilaterally symmetrical with respect to the grinding and polishing directions, the fibers do not slip sideways during the grinding and polishing, and the efficiency in precision polishing increases. That is, by wobbling the fibers in this way in both the left and right directions, the biting of the workpiece during grinding and polishing is improved, and the grinding and polishing efficiency is improved.
[0008]
Examples of the inorganic fibers include glass fibers, alumina fibers, silicon carbide fibers, boron fibers, and silicon nitride fibers. According to experiments by the present inventors, alumina fibers or silicon carbide fibers. Are particularly suitable for polishing iron, nickel and their alloy materials, and glass fibers are particularly suitable for aluminum, copper and magnesium alloys.
[0009]
The UD prepreg in which the inorganic long fibers are aligned in one direction is laminated in several layers so as to have a constant angle in both the left and right directions, and press-molded so that the fibers are oriented at the same angle on the left and right with respect to the grinding and polishing directions. And the wrapping material as described above can be obtained.
Further, after the fiber bundle of the inorganic long fibers is impregnated with the resin through the resin and wound around the cylinder at an angle θ with respect to the circumferential direction by a method called so-called helical winding by the filament winding method, As shown in FIG. 1, a block material 20 in which the fiber bundles 11 of the inorganic long fibers 1 are oriented in two directions is obtained, which is parallel to the press surface. The lapping material can be obtained by cutting out the stick 21.
In addition, by winding the cylinder to the right so that the angle is 10 to 45 degrees with respect to the circumferential direction by so-called parallel winding, and repeating winding the next layer to the left, A block having an angle in the left direction may be formed and heated and pressed to form a block.
[0010]
The thermosetting resin impregnated with the inorganic long fibers is not particularly limited, but is preferably a thermosetting resin such as an epoxy resin or a phenol resin. Especially when heat resistance is required, polyimide, polyamide, polymaleimide resin and the like are also used.
The fiber content of the wrapping material is preferably in the range of 60 to 87% by weight. In addition, if it is less than 60% by weight, the abrasiveness is lowered, and if it exceeds 87% by weight, the adhesion of inorganic long fibers is deteriorated and the strength is reduced. Therefore, the range of 70 to 85% by weight is optimal.
[0011]
The orientation angle of the inorganic long fiber with respect to the shaving direction is less than 10 degrees with respect to the polishing direction, and the increase rate of the outer peripheral length on the front end side of the fiber end surface acting on the material to be polished is small. Is desirable. The range of 17.5 ° to 45 ° is optimal for maintaining the elastic modulus in the vertical direction and the resistance to bending and obtaining the biting effect on the polished surface. Note that at an angle exceeding 45 degrees, the strength and elastic modulus in the polishing direction are greatly reduced, which is not suitable for practical use.
[0012]
【Example】
Next, examples of the wrapping material of the present invention will be described.
Example 1
First, an epoxy resin (DER 383J Dow Chemical Japan) in which the following resin composition was prepared as a resin composition 100 parts tetrahydromethyl phthalic anhydride (HN2200 Hitachi Chemical) 80 parts imidazole (2E4MZ-CN Shikoku Chemicals) 2 parts The above resin composition 24 resin fibers are impregnated with 24 alumina fibers made of 2000 TEX, in which 500 alumina fibers having a fiber diameter of 40 μm are aligned, and are impregnated in a circumferential direction into a cylinder having a fiber diameter of 106 mm. The sheet was shifted by 70.5 mm with respect to one rotation and reciprocated 6 times in parallel winding (parallel winding) to a width of 282 mm, and then cut in the axial direction to create a sheet. This sheet formed a sheet in which alumina fiber layers inclined 12.5 degrees to the right with respect to the circumferential direction and alumina fiber layers inclined 12.5 degrees to the left alternately overlapped.
[0013]
Two sheets thus prepared were cut into a length of 320 mm in the circumferential direction, the two sheets were stacked in the same direction, and placed in a 330 mm × 300 mm positive mold heated at 120 ° C., and 100 kg / cm 2 And a plate having a thickness of 10.1 mm was prepared.
A test piece was cut out from this plate and the content of the fiber was measured and found to be 82.5% by weight.
[0014]
Further, a square bar was cut out from the plate to a width of 10 mm in the circumferential direction, and this was tilted sideways and cut into a width of 1 mm to produce a stick having a width of 10 mm, a thickness of 1 mm, and a length of 100 mm.
This stick is parallel to a 10 mm wide surface with alternating layers of fibers aligned 12.5 degrees to the right and 12.5 degrees to the left. It forms a stick with fibers facing in two directions.
S45C steel mold using this stick and a stick (fiber content is 83% by weight) in which the fibers are aligned in one direction using fibers having the same fiber diameter of 40 μm as in the embodiment in the length direction. In this example, the stick with the twilling in two directions is much better in biting and sharpening on the surface to be polished than the fiber stick aligned in one direction. A good polished surface with no side slip and no linear flaws was obtained.
On the other hand, the stick in which the fibers were aligned in only one direction was weak to twist, and when it was twisted, a vertical crack was easily generated.
Also, using the stick of the above example and the stick (fiber content 84% by weight) in which the fiber is aligned in only one direction using the fiber of 50 μm instead of the fiber of 40 μm of the example, S45C As a result, the stick made by shaking the twill using the fiber having the fiber diameter of 40 μm in the example in the biting property to the polished surface was unidirectionally arranged with the fiber having the fiber diameter of 50 μm in one direction. It had almost the same bite to the mold as the sticks made by pulling them together. That is, by shaking the twill, fibers with a fiber diameter of 50 μm were drawn in only one direction, and the biting property equivalent to that of a stick could be obtained with a fiber with a fiber diameter of 40 μm.
[0015]
(Example 2)
The resin composition containing the same resin composition as in Example 1 was impregnated with a resin composition by passing one alumina fiber composed of 2000 TEX, in which 500 alumina fibers having a fiber diameter of 40 μm were aligned, and the fiber composition was impregnated with a fiber diameter of 106 mm. The resulting cylinder was wound by a filament winding machine with a helical winding at an angle of 21.6 degrees with respect to the circumferential direction. The design was such that the next fiber bundle was wound next to the fiber bundle wound earlier in one reciprocation so as to be displaced by 5.875 mm in one reciprocation. Thus, the molding material wound by reciprocating 392 to the width of 282 mm was cut open in the axial direction of the cylinder, and the sheet | seat was created.
[0016]
Two sheets thus prepared were cut into a length of 320 mm in the circumferential direction, and the two sheets were stacked in the same direction and placed in a 330 mm × 300 mm positive mold heated at 120 ° C., and 100 Kg / cm 2 The plate was pressed with pressure and taken out after 1 hour to prepare a plate having a thickness of 6.5 mm.
A test piece was cut out from this plate and the fiber content was measured and found to be 82.0% by weight.
[0017]
Further, a square bar was cut out from the plate to a width of 10 mm in the circumferential direction, and this was tilted sideways and cut into a width of 1 mm to produce a stick having a width of 10 mm, a thickness of 1 mm, and a length of 100 mm.
This stick is parallel to a surface having a width of 10 mm with respect to the length direction, and a fiber bundle facing 21.6 degrees to the right and 21.6 degrees to the left with respect to the length direction. It was shaken and formed a stick with fibers facing in two directions.
Using this stick and a stick in which fibers are aligned in only one direction in the length direction, an S45C steel mold was polished. Compared with the stick of Example 1, the bite of the stick of Example 2 is much better than the stick of Example 1. It was excellent. This is thought to be due to the large traverse angle of Example 2. Further, a good polished surface free from vertical cracks when twisted and free from linear flaws was obtained.
On the other hand, the stick in which the fibers were aligned in only one direction was weak to twist, and when it was twisted, a vertical crack was easily generated.
[0018]
【The invention's effect】
According to the wrapping material of the present invention, since the fibers are oriented in two directions with respect to the grinding and polishing directions, the stick is not twisted in one direction during the grinding and polishing. Further, compared to a stick in which fibers are oriented in only one direction, vertical cracks are less likely to occur when the stick is twisted. Also, by grinding the fibers and orienting the fibers in two directions symmetrical to the polishing direction, each fiber has an elliptical fiber end surface having a major axis in a direction orthogonal to the polishing direction. The outer peripheral edge on the front end side of the fiber end surface acting on the abrasive becomes longer, and the grinding and polishing efficiency is improved. In addition, it does not slide sideways during grinding and polishing, so that the efficiency in precision polishing is improved, the biting of the workpiece during grinding and polishing is improved, and the grinding and polishing efficiency is improved.
Further, according to the method for producing a wrapping material of the present invention, a wrapping material having a desired elliptical fiber end can be obtained by simply winding an inorganic long fiber around a cylinder at an arbitrary angle and in an arbitrary winding manner. Easy to manufacture.
[Brief description of the drawings]
FIG. 1 is a perspective view showing a manufacturing process of a wrapping material of the present invention. FIG. 2 is a schematic diagram of an end surface of the wrapping material of the present invention. FIG. 3 is a schematic diagram of an end surface of a conventional wrapping material.
1 Inorganic long fibers (single fibers)
1a Outer peripheral edge 11 Fiber bundle 20 Block material 21 Stick

Claims (9)

無機長繊維に熱硬化性樹脂を含浸させ表裏に平坦面を備える平板状の成形体とし、前記無機長繊維を研磨方向に対して左右対称な二方向に配向させ、前記成形体の長手方向前端面に現れる前記各長繊維の繊維端面で研削、研磨するラッピング材であって、前記各長繊維が研磨方向に対して直交する方向であってかつ前記成形体の平坦面に対して平行方向に長軸を有する楕円形状の繊維端面を備えることを特徴とするラッピング材。The inorganic long fiber is impregnated with a thermosetting resin to form a flat molded body having flat surfaces on the front and back, the inorganic long fiber is oriented in two directions symmetrical to the polishing direction, and the longitudinal front end of the molded body A wrapping material that is ground and polished at the fiber end surface of each long fiber that appears on the surface, wherein each long fiber is in a direction perpendicular to the polishing direction and parallel to the flat surface of the molded body. A wrapping material comprising an elliptical fiber end face having a long axis . 前記無機長繊維を研磨方向に対して10〜45度の角度で左右対称な二方向に配向させてなることを特徴とする請求項1に記載のラッピング材。  The wrapping material according to claim 1, wherein the inorganic long fibers are oriented in two symmetrical directions at an angle of 10 to 45 degrees with respect to the polishing direction. 前記無機長繊維を研磨方向に対して12.5〜45度の角度で左右対称な二方向に配向させてなることを特徴とする請求項2に記載のラッピング材。  The wrapping material according to claim 2, wherein the inorganic long fibers are oriented in two symmetrical directions at an angle of 12.5 to 45 degrees with respect to the polishing direction. 前記無機長繊維を綾振りによって研磨方向に対して左右対称な二方向に配向させてなることを特徴とする請求項1乃至3の何れかに記載のラッピング材。  The wrapping material according to any one of claims 1 to 3, wherein the inorganic long fibers are oriented in two directions symmetrical to the polishing direction by traversing. 前記無機長繊維はガラス繊維、アルミナ質繊維、炭化珪素質繊維、ボロン質繊維及び窒化珪素質繊維からなる群から選ばれた無機長繊維であることを特徴とする請求項1乃至4の何れかに記載のラッピング材。  The inorganic long fiber is an inorganic long fiber selected from the group consisting of glass fiber, alumina fiber, silicon carbide fiber, boron fiber, and silicon nitride fiber. Wrapping material described in 1. 前記無機長繊維を70〜85重量%としたことを特徴とする請求項1乃至5の何れかに記載のラッピング材。 The wrapping material according to any one of claims 1 to 5, wherein the inorganic long fiber is 70 to 85% by weight . 熱硬化性樹脂を含浸させた無機長繊維を回転体の回転方向に沿ってその外周に綾振りさせつつ巻き取り、この回転体上に巻き取った成形材料を回転体の軸方向にカットして切り開き、シート状に広げ、これを必要ならば複数枚積層し、加熱加圧プレスすることにより硬化させてラッピング材ブロックを作成し、このブロックの綾振りした面側がラッピング時の平坦面側になるように平板状にスライス切りすることを特徴とするラッピング材の製造方法。  The inorganic long fiber impregnated with the thermosetting resin is wound while traversing the outer circumference along the rotation direction of the rotating body, and the molding material wound on the rotating body is cut in the axial direction of the rotating body. Cut and spread it into sheets, if necessary, stack multiple sheets and cure by heating and pressing to create a wrapping material block, and the traversed surface side of this block will be the flat surface side during wrapping A method for producing a wrapping material, characterized in that it is sliced into a flat plate shape. 前記綾振りをパラレル巻きとしたことを特徴とする請求項7記載のラッピング材の製造方法。  8. The method for manufacturing a wrapping material according to claim 7, wherein the traversing is parallel winding. 前記綾振りをヘリカル巻きとしたことを特徴とする請求項7記載のラッピング材の製造方法。  The method for producing a wrapping material according to claim 7, wherein the traverse is helically wound.
JP03552298A 1998-02-02 1998-02-02 Wrapping material and manufacturing method thereof Expired - Lifetime JP4398521B2 (en)

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