JP4359577B2 - 黒白熱現像感光材料 - Google Patents

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Publication number

JP4359577B2

JP4359577B2 JP2005176796A JP2005176796A JP4359577B2 JP 4359577 B2 JP4359577 B2 JP 4359577B2 JP 2005176796 A JP2005176796 A JP 2005176796A JP 2005176796 A JP2005176796 A JP 2005176796A JP 4359577 B2 JP4359577 B2 JP 4359577B2

Authority

JP

Japan

Prior art keywords

group

general formula

silver

photothermographic material

mol

Prior art date

2005-06-16

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired - Fee Related

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• 239000000463 material Substances 0.000 title claims description 137
• -1 silver halide Chemical class 0.000 claims description 303
• 150000001875 compounds Chemical class 0.000 claims description 208
• 229910052709 silver Inorganic materials 0.000 claims description 174
• 239000004332 silver Substances 0.000 claims description 174
• 125000000217 alkyl group Chemical group 0.000 claims description 129
• GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims description 89
• 125000003118 aryl group Chemical group 0.000 claims description 75
• 125000000623 heterocyclic group Chemical group 0.000 claims description 72
• 229920000126 latex Polymers 0.000 claims description 71
• 239000004816 latex Substances 0.000 claims description 71
• 125000001424 substituent group Chemical group 0.000 claims description 71
• 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 69
• 229920000642 polymer Polymers 0.000 claims description 50
• 125000004432 carbon atom Chemical group C* 0.000 claims description 48
• 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 claims description 42
• 125000005843 halogen group Chemical group 0.000 claims description 42
• 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 claims description 33
• 229910021612 Silver iodide Inorganic materials 0.000 claims description 28
• 239000011230 binding agent Substances 0.000 claims description 27
• 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 claims description 27
• JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 claims description 26
• 125000002252 acyl group Chemical group 0.000 claims description 26
• 125000004453 alkoxycarbonyl group Chemical group 0.000 claims description 26
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 26
• 229940045105 silver iodide Drugs 0.000 claims description 26
• 125000004093 cyano group Chemical group *C#N 0.000 claims description 24
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 21
• 239000000178 monomer Substances 0.000 claims description 16
• XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 14
• 150000004668 long chain fatty acids Chemical class 0.000 claims description 3
• 239000010410 layer Substances 0.000 description 152
• 238000000034 method Methods 0.000 description 105
• 239000000243 solution Substances 0.000 description 95
• 239000006185 dispersion Substances 0.000 description 82
• 238000000576 coating method Methods 0.000 description 76
• 239000011248 coating agent Substances 0.000 description 72
• 239000002245 particle Substances 0.000 description 72
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 57
• 238000011161 development Methods 0.000 description 54
• 230000018109 developmental process Effects 0.000 description 53
• 239000000839 emulsion Substances 0.000 description 52
• 238000002360 preparation method Methods 0.000 description 49
• 206010070834 Sensitisation Diseases 0.000 description 46
• 230000008313 sensitization Effects 0.000 description 46
• BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 45
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 40
• 239000003638 chemical reducing agent Substances 0.000 description 36
• 125000003545 alkoxy group Chemical group 0.000 description 35
• 229910052757 nitrogen Inorganic materials 0.000 description 35
• 239000007864 aqueous solution Substances 0.000 description 33
• 239000000975 dye Substances 0.000 description 32
• 150000003839 salts Chemical class 0.000 description 32
• 235000014113 dietary fatty acids Nutrition 0.000 description 31
• 239000000194 fatty acid Substances 0.000 description 31
• 229930195729 fatty acid Natural products 0.000 description 31
• 150000004665 fatty acids Chemical class 0.000 description 30
• 239000000126 substance Substances 0.000 description 28
• HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 27
• 125000004442 acylamino group Chemical group 0.000 description 27
• 239000000203 mixture Substances 0.000 description 26
• 239000011241 protective layer Substances 0.000 description 26
• 230000035945 sensitivity Effects 0.000 description 25
• 125000004104 aryloxy group Chemical group 0.000 description 23
• 238000003860 storage Methods 0.000 description 23
• 229920002451 polyvinyl alcohol Polymers 0.000 description 21
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 20
• 230000000274 adsorptive effect Effects 0.000 description 20
• 125000004414 alkyl thio group Chemical group 0.000 description 20
• 125000005110 aryl thio group Chemical group 0.000 description 20
• 125000004433 nitrogen atom Chemical group N* 0.000 description 20
• 108010010803 Gelatin Proteins 0.000 description 19
• OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 19
• 229920000159 gelatin Polymers 0.000 description 19
• 235000019322 gelatine Nutrition 0.000 description 19
• 235000011852 gelatine desserts Nutrition 0.000 description 19
• 125000003396 thiol group Chemical group [H]S* 0.000 description 19
• 238000002156 mixing Methods 0.000 description 18
• 230000001235 sensitizing effect Effects 0.000 description 18
• SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 18
• 125000003277 amino group Chemical group 0.000 description 17
• 239000008273 gelatin Substances 0.000 description 17
• 239000007788 liquid Substances 0.000 description 17
• 239000007787 solid Substances 0.000 description 17
• QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 16
• 239000004372 Polyvinyl alcohol Substances 0.000 description 16
• 238000006243 chemical reaction Methods 0.000 description 16
• 239000013078 crystal Substances 0.000 description 16
• 229910052739 hydrogen Inorganic materials 0.000 description 16
• 239000001257 hydrogen Substances 0.000 description 16
• 229910052751 metal Inorganic materials 0.000 description 16
• 239000002184 metal Substances 0.000 description 16
• 235000019422 polyvinyl alcohol Nutrition 0.000 description 16
• 125000004423 acyloxy group Chemical group 0.000 description 15
• 239000003795 chemical substances by application Substances 0.000 description 15
• 230000000052 comparative effect Effects 0.000 description 15
• 229940125904 compound 1 Drugs 0.000 description 15
• 229910052736 halogen Inorganic materials 0.000 description 15
• 239000004094 surface-active agent Substances 0.000 description 15
• IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
• 125000001951 carbamoylamino group Chemical group C(N)(=O)N* 0.000 description 14
• 239000010419 fine particle Substances 0.000 description 14
• 229910052714 tellurium Inorganic materials 0.000 description 14
• 239000002253 acid Substances 0.000 description 13
• 125000006575 electron-withdrawing group Chemical group 0.000 description 13
• 125000003375 sulfoxide group Chemical group 0.000 description 13
• JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 13
• RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 12
• QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 12
• 230000015572 biosynthetic process Effects 0.000 description 12
• 150000002367 halogens Chemical class 0.000 description 12
• 230000003647 oxidation Effects 0.000 description 12
• 238000007254 oxidation reaction Methods 0.000 description 12
• XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 12
• PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 12
• VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 11
• 229920001577 copolymer Polymers 0.000 description 11
• 239000012153 distilled water Substances 0.000 description 11
• 238000009826 distribution Methods 0.000 description 11
• 238000010438 heat treatment Methods 0.000 description 11
• 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 11
• 239000007800 oxidant agent Substances 0.000 description 11
• 230000036961 partial effect Effects 0.000 description 11
• 229920003048 styrene butadiene rubber Polymers 0.000 description 11
• 125000000565 sulfonamide group Chemical group 0.000 description 11
• KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 10
• ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 10
• MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 10
• 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 10
• 238000011033 desalting Methods 0.000 description 10
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 10
• 238000005755 formation reaction Methods 0.000 description 10
• 230000001590 oxidative effect Effects 0.000 description 10
• NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Substances [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 10
• 230000008569 process Effects 0.000 description 10
• 239000002002 slurry Substances 0.000 description 10
• 230000003595 spectral effect Effects 0.000 description 10
• 229910052717 sulfur Inorganic materials 0.000 description 10
• 241001061127 Thione Species 0.000 description 9
• 229910052799 carbon Inorganic materials 0.000 description 9
• 229940125782 compound 2 Drugs 0.000 description 9
• UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 9
• 239000000428 dust Substances 0.000 description 9
• 150000002500 ions Chemical class 0.000 description 9
• 125000005647 linker group Chemical group 0.000 description 9
• 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 9
• 238000012545 processing Methods 0.000 description 9
• ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 9
• 229910001961 silver nitrate Inorganic materials 0.000 description 9
• SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 8
• NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 8
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
• 229910052798 chalcogen Inorganic materials 0.000 description 8
• 150000001787 chalcogens Chemical class 0.000 description 8
• PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 8
• 229910052737 gold Inorganic materials 0.000 description 8
• 239000010931 gold Substances 0.000 description 8
• QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 8
• 230000035699 permeability Effects 0.000 description 8
• 239000004576 sand Substances 0.000 description 8
• 239000002904 solvent Substances 0.000 description 8
• 238000003756 stirring Methods 0.000 description 8
• 125000005420 sulfonamido group Chemical group S(=O)(=O)(N*)* 0.000 description 8
• 125000004434 sulfur atom Chemical group 0.000 description 8
• 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 8
• 239000004743 Polypropylene Substances 0.000 description 7
• 229910021607 Silver chloride Inorganic materials 0.000 description 7
• 239000002174 Styrene-butadiene Substances 0.000 description 7
• 239000011324 bead Substances 0.000 description 7
• 150000001721 carbon Chemical group 0.000 description 7
• 239000006224 matting agent Substances 0.000 description 7
• 229910044991 metal oxide Inorganic materials 0.000 description 7
• 150000004706 metal oxides Chemical class 0.000 description 7
• 125000005740 oxycarbonyl group Chemical group [*:1]OC([*:2])=O 0.000 description 7
• 229920001155 polypropylene Polymers 0.000 description 7
• 239000011148 porous material Substances 0.000 description 7
• 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 7
• 230000009467 reduction Effects 0.000 description 7
• 238000006722 reduction reaction Methods 0.000 description 7
• HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 7
• CVYDEWKUJFCYJO-UHFFFAOYSA-M sodium;docosanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCCCCCC([O-])=O CVYDEWKUJFCYJO-UHFFFAOYSA-M 0.000 description 7
• XSOKHXFFCGXDJZ-UHFFFAOYSA-N telluride(2-) Chemical compound [Te-2] XSOKHXFFCGXDJZ-UHFFFAOYSA-N 0.000 description 7
• QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
• KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
• KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical class C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 6
• BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 6
• 229910052771 Terbium Inorganic materials 0.000 description 6
• 239000000654 additive Substances 0.000 description 6
• 239000003125 aqueous solvent Substances 0.000 description 6
• 125000004429 atom Chemical group 0.000 description 6
• 230000008859 change Effects 0.000 description 6
• 238000005859 coupling reaction Methods 0.000 description 6
• 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 6
• 235000019441 ethanol Nutrition 0.000 description 6
• 230000009477 glass transition Effects 0.000 description 6
• 125000002887 hydroxy group Chemical group [H]O* 0.000 description 6
• 239000002667 nucleating agent Substances 0.000 description 6
• 239000003960 organic solvent Substances 0.000 description 6
• 239000005022 packaging material Substances 0.000 description 6
• 229910052711 selenium Inorganic materials 0.000 description 6
• 239000004065 semiconductor Substances 0.000 description 6
• MSFPLIAKTHOCQP-UHFFFAOYSA-M silver iodide Chemical group I[Ag] MSFPLIAKTHOCQP-UHFFFAOYSA-M 0.000 description 6
• 239000007962 solid dispersion Substances 0.000 description 6
• 230000003068 static effect Effects 0.000 description 6
• IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 5
• WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 5
• ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 5
• 238000010521 absorption reaction Methods 0.000 description 5
• 125000005161 aryl oxy carbonyl group Chemical group 0.000 description 5
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
• 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
• 150000004696 coordination complex Chemical class 0.000 description 5
• 238000001035 drying Methods 0.000 description 5
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• 238000005516 engineering process Methods 0.000 description 5
• 238000000407 epitaxy Methods 0.000 description 5
• 238000011156 evaluation Methods 0.000 description 5
• 125000001072 heteroaryl group Chemical group 0.000 description 5
• ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 5
• 238000004519 manufacturing process Methods 0.000 description 5
• 230000003287 optical effect Effects 0.000 description 5
• 229910052760 oxygen Inorganic materials 0.000 description 5
• 239000001301 oxygen Substances 0.000 description 5
• 125000004430 oxygen atom Chemical group O* 0.000 description 5
• 229910052698 phosphorus Inorganic materials 0.000 description 5
• LFSXCDWNBUNEEM-UHFFFAOYSA-N phthalazine Chemical class C1=NN=CC2=CC=CC=C21 LFSXCDWNBUNEEM-UHFFFAOYSA-N 0.000 description 5
• 229920000139 polyethylene terephthalate Polymers 0.000 description 5
• 239000005020 polyethylene terephthalate Substances 0.000 description 5
• 239000000843 powder Substances 0.000 description 5
• 150000003536 tetrazoles Chemical group 0.000 description 5
• 238000011282 treatment Methods 0.000 description 5
• 239000011701 zinc Substances 0.000 description 5
• JAAIPIWKKXCNOC-UHFFFAOYSA-N 1h-tetrazol-1-ium-5-thiolate Chemical group SC1=NN=NN1 JAAIPIWKKXCNOC-UHFFFAOYSA-N 0.000 description 4
• CWJJAFQCTXFSTA-UHFFFAOYSA-N 4-methylphthalic acid Chemical compound CC1=CC=C(C(O)=O)C(C(O)=O)=C1 CWJJAFQCTXFSTA-UHFFFAOYSA-N 0.000 description 4
• QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
• 235000021357 Behenic acid Nutrition 0.000 description 4
• WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 4
• NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
• JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
• DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 4
• FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical group C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 4
• 125000003368 amide group Chemical group 0.000 description 4
• 238000004458 analytical method Methods 0.000 description 4
• 125000006615 aromatic heterocyclic group Chemical group 0.000 description 4
• 125000004391 aryl sulfonyl group Chemical group 0.000 description 4
• 125000000656 azaniumyl group Chemical group [H][N+]([H])([H])[*] 0.000 description 4
• 229940116226 behenic acid Drugs 0.000 description 4
• 125000003785 benzimidazolyl group Chemical group N1=C(NC2=C1C=CC=C2)* 0.000 description 4
• 238000009835 boiling Methods 0.000 description 4
• CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 4
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• DZKOKXZNCDGVRY-UHFFFAOYSA-N lenthionine Chemical compound C1SSCSSS1 DZKOKXZNCDGVRY-UHFFFAOYSA-N 0.000 description 4
• 238000005259 measurement Methods 0.000 description 4
• 125000002971 oxazolyl group Chemical group 0.000 description 4
• 239000011574 phosphorus Substances 0.000 description 4
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• 235000013824 polyphenols Nutrition 0.000 description 4
• 229910052761 rare earth metal Inorganic materials 0.000 description 4
• 238000011160 research Methods 0.000 description 4
• 230000005070 ripening Effects 0.000 description 4
• 239000011669 selenium Substances 0.000 description 4
• 150000003378 silver Chemical class 0.000 description 4
• AQRYNYUOKMNDDV-UHFFFAOYSA-M silver behenate Chemical compound [Ag+].CCCCCCCCCCCCCCCCCCCCCC([O-])=O AQRYNYUOKMNDDV-UHFFFAOYSA-M 0.000 description 4
• ORYURPRSXLUCSS-UHFFFAOYSA-M silver;octadecanoate Chemical compound [Ag+].CCCCCCCCCCCCCCCCCC([O-])=O ORYURPRSXLUCSS-UHFFFAOYSA-M 0.000 description 4
• DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 4
• 150000003585 thioureas Chemical class 0.000 description 4
• 229920003169 water-soluble polymer Polymers 0.000 description 4
• 229910052725 zinc Inorganic materials 0.000 description 4
• 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 3
• MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 3
• ZGOQRUPIKZGTLQ-UHFFFAOYSA-N 1,2-benzothiazole 1-oxide;sodium Chemical compound [Na].C1=CC=C2S(=O)N=CC2=C1 ZGOQRUPIKZGTLQ-UHFFFAOYSA-N 0.000 description 3
• AFBBKYQYNPNMAT-UHFFFAOYSA-N 1h-1,2,4-triazol-1-ium-3-thiolate Chemical group SC=1N=CNN=1 AFBBKYQYNPNMAT-UHFFFAOYSA-N 0.000 description 3
• PDHFSBXFZGYBIP-UHFFFAOYSA-N 2-[2-(2-hydroxyethylsulfanyl)ethylsulfanyl]ethanol Chemical compound OCCSCCSCCO PDHFSBXFZGYBIP-UHFFFAOYSA-N 0.000 description 3
• 229920002126 Acrylic acid copolymer Polymers 0.000 description 3
• 229930185605 Bisphenol Natural products 0.000 description 3
• VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
• XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
• JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 3
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
• YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 3
• 229910052688 Gadolinium Inorganic materials 0.000 description 3
• WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
• CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
• ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
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• 239000006104 solid solution Substances 0.000 description 1
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• 239000011550 stock solution Substances 0.000 description 1
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• WSANLGASBHUYGD-UHFFFAOYSA-N sulfidophosphanium Chemical class S=[PH3] WSANLGASBHUYGD-UHFFFAOYSA-N 0.000 description 1
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• 150000003871 sulfonates Chemical class 0.000 description 1
• 229920001059 synthetic polymer Polymers 0.000 description 1
• 229910052715 tantalum Inorganic materials 0.000 description 1
• 238000010345 tape casting Methods 0.000 description 1
• 150000003498 tellurium compounds Chemical class 0.000 description 1
• 125000001302 tertiary amino group Chemical group 0.000 description 1
• 238000010998 test method Methods 0.000 description 1
• 238000004154 testing of material Methods 0.000 description 1
• AUHHYELHRWCWEZ-UHFFFAOYSA-N tetrachlorophthalic anhydride Chemical compound ClC1=C(Cl)C(Cl)=C2C(=O)OC(=O)C2=C1Cl AUHHYELHRWCWEZ-UHFFFAOYSA-N 0.000 description 1
• 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
• 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
• IKRMQEUTISXXQP-UHFFFAOYSA-N tetrasulfane Chemical compound SSSS IKRMQEUTISXXQP-UHFFFAOYSA-N 0.000 description 1
• 238000001931 thermography Methods 0.000 description 1
• 125000004149 thio group Chemical group *S* 0.000 description 1
• YUKQRDCYNOVPGJ-UHFFFAOYSA-N thioacetamide Chemical compound CC(N)=S YUKQRDCYNOVPGJ-UHFFFAOYSA-N 0.000 description 1
• DLFVBJFMPXGRIB-UHFFFAOYSA-N thioacetamide Natural products CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 1
• 125000001391 thioamide group Chemical group 0.000 description 1
• 150000003556 thioamides Chemical class 0.000 description 1
• DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
• 150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 1
• FYOWZTWVYZOZSI-UHFFFAOYSA-N thiourea dioxide Chemical class NC(=N)S(O)=O FYOWZTWVYZOZSI-UHFFFAOYSA-N 0.000 description 1
• 230000009974 thixotropic effect Effects 0.000 description 1
• FRNOGLGSGLTDKL-UHFFFAOYSA-N thulium atom Chemical compound [Tm] FRNOGLGSGLTDKL-UHFFFAOYSA-N 0.000 description 1
• DWWMSEANWMWMCB-UHFFFAOYSA-N tribromomethylsulfonylbenzene Chemical compound BrC(Br)(Br)S(=O)(=O)C1=CC=CC=C1 DWWMSEANWMWMCB-UHFFFAOYSA-N 0.000 description 1
• XTTGYFREQJCEML-UHFFFAOYSA-N tributyl phosphite Chemical compound CCCCOP(OCCCC)OCCCC XTTGYFREQJCEML-UHFFFAOYSA-N 0.000 description 1
• TUQOTMZNTHZOKS-UHFFFAOYSA-N tributylphosphine Chemical compound CCCCP(CCCC)CCCC TUQOTMZNTHZOKS-UHFFFAOYSA-N 0.000 description 1
• 125000004044 trifluoroacetyl group Chemical group FC(C(=O)*)(F)F 0.000 description 1
• KTFAZNVGJUIWJM-UHFFFAOYSA-N trimethyl(sulfanylidene)-$l^{5}-phosphane Chemical compound CP(C)(C)=S KTFAZNVGJUIWJM-UHFFFAOYSA-N 0.000 description 1
• 125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 description 1
• ZFVJLNKVUKIPPI-UHFFFAOYSA-N triphenyl(selanylidene)-$l^{5}-phosphane Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)(=[Se])C1=CC=CC=C1 ZFVJLNKVUKIPPI-UHFFFAOYSA-N 0.000 description 1
• UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 description 1
• 229940048102 triphosphoric acid Drugs 0.000 description 1
• NZKWZUOYGAKOQC-UHFFFAOYSA-H tripotassium;hexachloroiridium(3-) Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[K+].[K+].[K+].[Ir+3] NZKWZUOYGAKOQC-UHFFFAOYSA-H 0.000 description 1
• WFRMLFFVZPJQSI-UHFFFAOYSA-N tris(4-methylphenoxy)-selanylidene-$l^{5}-phosphane Chemical compound C1=CC(C)=CC=C1OP(=[Se])(OC=1C=CC(C)=CC=1)OC1=CC=C(C)C=C1 WFRMLFFVZPJQSI-UHFFFAOYSA-N 0.000 description 1
• FOEYLTKIJNXAIO-UHFFFAOYSA-N trisilver;trioxidoarsane Chemical compound [Ag+].[Ag+].[Ag+].[O-][As]([O-])[O-] FOEYLTKIJNXAIO-UHFFFAOYSA-N 0.000 description 1
• RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
• PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 description 1
• WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
• 229910052721 tungsten Inorganic materials 0.000 description 1
• 239000010937 tungsten Substances 0.000 description 1
• 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
• 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
• 230000000007 visual effect Effects 0.000 description 1
• 238000001075 voltammogram Methods 0.000 description 1
• 239000002699 waste material Substances 0.000 description 1
• 125000005023 xylyl group Chemical group 0.000 description 1
• 239000001043 yellow dye Substances 0.000 description 1