JP4350087B2 - フッ素含有ターフェニルジヒドロキシ単量体とこの単量体を利用して製造されたフッ素含有ポリ(アリレンエーテルスルフィド) - Google Patents
フッ素含有ターフェニルジヒドロキシ単量体とこの単量体を利用して製造されたフッ素含有ポリ(アリレンエーテルスルフィド) Download PDFInfo
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- JP4350087B2 JP4350087B2 JP2005358801A JP2005358801A JP4350087B2 JP 4350087 B2 JP4350087 B2 JP 4350087B2 JP 2005358801 A JP2005358801 A JP 2005358801A JP 2005358801 A JP2005358801 A JP 2005358801A JP 4350087 B2 JP4350087 B2 JP 4350087B2
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- 0 *c1ccc(*=C)cc1 Chemical compound *c1ccc(*=C)cc1 0.000 description 1
- GORITXRMBHTBBL-UHFFFAOYSA-N CC(C)(c(c(F)c(c(Sc(c([I]=C)c(c(F)c1F)F)c1F)c1F)F)c1F)Oc(cc(-c1ccc(C(F)(F)F)cc1)c(Oc(c(F)c(c(Sc(c(F)c(c1c2F)[F]CC1(C)F)c2F)c1F)F)c1F)c1)c1-c1ccc(C(F)(F)F)cc1 Chemical compound CC(C)(c(c(F)c(c(Sc(c([I]=C)c(c(F)c1F)F)c1F)c1F)F)c1F)Oc(cc(-c1ccc(C(F)(F)F)cc1)c(Oc(c(F)c(c(Sc(c(F)c(c1c2F)[F]CC1(C)F)c2F)c1F)F)c1F)c1)c1-c1ccc(C(F)(F)F)cc1 GORITXRMBHTBBL-UHFFFAOYSA-N 0.000 description 1
- FATAYOGWFJUREC-UHFFFAOYSA-N Oc(cc(C1=CCC(C(F)(F)F)C=C1)c(O)c1)c1-c1ccc(C(F)(F)F)cc1 Chemical compound Oc(cc(C1=CCC(C(F)(F)F)C=C1)c(O)c1)c1-c1ccc(C(F)(F)F)cc1 FATAYOGWFJUREC-UHFFFAOYSA-N 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
- C08G65/38—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols
- C08G65/40—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols from phenols (I) and other compounds (II), e.g. OH-Ar-OH + X-Ar-X, where X is halogen atom, i.e. leaving group
- C08G65/4012—Other compound (II) containing a ketone group, e.g. X-Ar-C(=O)-Ar-X for polyetherketones
- C08G65/4018—(I) or (II) containing halogens other than as leaving group (X)
- C08G65/4025—(I) or (II) containing fluorine other than as leaving group (X)
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Optical Integrated Circuits (AREA)
Description
a)次の化学式1で表されるターフェニルジヒドロキシ化合物と次の化学式7で表されるスルフィド化合物を縮合反応して、次の化学式6aで表される高分子(D=F)を合成する過程、及び、
b)次の化学式6aで表される高分子とZ−OHで表される架橋結合性化合物とを反応して、次の化学式6bで表される高分子(D=−O−Z)を合成する過程が含まれる。
以上説明したような本発明は、次の製造例及び実施例によりさらに詳細に説明するが、本発明がこれに限定されるものではない。
製造例1:1,4−ジブロモ−2,5−ジメトキシベンゼンの製造
実施例1:フッ素含有ポリ(アリレンエーテルスルフィド)−TP(FPAESI−TP)の製造
Claims (9)
- 前記化学式1で表される化合物が
2’,5’−ジメトキシ−4,4”−ビス−トリフルオロメチル−[1,1’;4’,1”]ターフェニル、
4,4”−ビス−トリフルオロメチル−[1,1’,4’,1”]ターフェニル−2’,5’−ジオール、
2’,5’−ジメトキシ−3,5,3”,5”−テトラキス−トリフルオロメチル−[1,1’,4’,1”]ターフェニル、
3,5,3”,5”−テトラキス−トリフルオロメチル−[1,1’,4’,1”]ターフェニル−2’,5’−ジオール、
2,3,5,6,2”,3”,5”,6”−オクタフルオロ−2’,5’−ジメトキシ−4,4”−ビス−トリフルオロメチル−[1,1’,4’,1”]ターフェニル、及び
2,3,5,6,2”,3”,5”,6”−オクタフルオロ−4,4”−ビス−トリフルオロメチル−[1,1’,4’,1”]ターフェニル−2’,5’−ジオール
の中から選択されたものであることを特徴とする、請求項1に記載のフッ素含有ターフェニル単量体。 - 次の化学式2で表される1,4−ジアルコキシベンゼンを臭化反応させて、次の化学式3で表される1,4−ジブロモ−2,5−ジアルコキシベンゼンを製造する過程と、
次の化学式3で表される1,4−ジブロモ−2,5−ジアルコキシベンゼンの臭素(Br)置換基をボロン酸に転換し、次の化学式4で表される2,5−ジアルコキシ−1,4−ベンゼンジボロン酸を製造する過程と、
次の化学式4で表される2,5−ジアルコキシ−1,4−ベンゼンジボロン酸と次の化学式5で表されるフッ素含有ブロモベンゼンとをスズキクロスカップリング反応し、次の化学式1で表されるフッ素含有ターフェニル単量体を製造する過程と、
からなることを特徴とするフッ素含有ターフェニル単量体の製造方法:
- 前記スズキクロスカップリング反応により生成された前記化学式1で表される化合物のRがC1〜C6のアルキル基である化合物は、酸溶液により加水分解し、Rが水素原子である化合物に転換する過程がさらに含まれることを特徴とする、請求項3に記載の製造方法。
- a)次の化学式1で表されるターフェニルジヒドロキシ単量体と次の化学式7で表されるスルフィド化合物とを縮合反応して、次の化学式6aで表される高分子を合成する過程、及び、
b)次の化学式6aで表される高分子とZ−OHで表される架橋結合性化合物とを反応して、次の化学式6bで表される高分子を合成する過程
からなることを特徴とする、フッ素含有ポリ(アリレンエーテルスルフィド)の製造方法:
- 前記化学式1で表されるターフェニルジヒドロキシ単量体は、
4,4”−ビス−トリフルオロメチル−[1,1’,4’,1”]ターフェニル−2’,5’−ジオール、
3,5,3”,5”−テトラキス−トリフルオロメチル−[1,1’,4’,1”]ターフェニル−2’,5’−ジオール、及び
2,3,5,6,2”,3”,5”,6”−オクタフルオロ−4,4”−ビス−トリフルオロメチル−[1,1’,4’,1”]ターフェニル−2’,5’−ジオール
の中から選択して使用することを特徴とする、請求項7に記載の製造方法。 - 前記a)及びb)の反応は、それぞれ塩基と非プロトン性極性溶媒の存在下で、100〜200℃の温度範囲の条件で行うことを特徴とする、請求項7に記載の製造方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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KR1020040105085A KR100583016B1 (ko) | 2004-12-13 | 2004-12-13 | 플루오린 함유 터페닐 디하이드록시 단량체와 이의 제조방법 |
KR1020050086575A KR100641866B1 (ko) | 2005-09-16 | 2005-09-16 | 플루오린을 함유한 폴리(아릴렌 에테르 설파이드) |
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JP2006176507A JP2006176507A (ja) | 2006-07-06 |
JP4350087B2 true JP4350087B2 (ja) | 2009-10-21 |
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JP2005358801A Expired - Fee Related JP4350087B2 (ja) | 2004-12-13 | 2005-12-13 | フッ素含有ターフェニルジヒドロキシ単量体とこの単量体を利用して製造されたフッ素含有ポリ(アリレンエーテルスルフィド) |
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US (2) | US20060183878A1 (ja) |
JP (1) | JP4350087B2 (ja) |
DE (1) | DE102005058722A1 (ja) |
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US8247142B1 (en) * | 2011-06-30 | 2012-08-21 | Xerox Corporation | Fluorinated structured organic film compositions |
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KR100399018B1 (ko) * | 2000-12-19 | 2003-09-19 | 광주과학기술원 | 플로린을 함유한 광소자용 폴리아릴렌에테르설폰 또는 폴리아릴렌에테르설파이드 및 그 제조방법 |
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2005
- 2005-12-08 DE DE102005058722A patent/DE102005058722A1/de not_active Withdrawn
- 2005-12-12 US US11/301,144 patent/US20060183878A1/en not_active Abandoned
- 2005-12-13 JP JP2005358801A patent/JP4350087B2/ja not_active Expired - Fee Related
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2009
- 2009-05-04 US US12/435,112 patent/US7732560B2/en not_active Expired - Fee Related
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Publication number | Publication date |
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JP2006176507A (ja) | 2006-07-06 |
US20090259017A1 (en) | 2009-10-15 |
DE102005058722A1 (de) | 2006-09-07 |
US7732560B2 (en) | 2010-06-08 |
US20060183878A1 (en) | 2006-08-17 |
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