JP4332380B2 - Milky type bath salt - Google Patents
Milky type bath salt Download PDFInfo
- Publication number
- JP4332380B2 JP4332380B2 JP2003272672A JP2003272672A JP4332380B2 JP 4332380 B2 JP4332380 B2 JP 4332380B2 JP 2003272672 A JP2003272672 A JP 2003272672A JP 2003272672 A JP2003272672 A JP 2003272672A JP 4332380 B2 JP4332380 B2 JP 4332380B2
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- JP
- Japan
- Prior art keywords
- weight
- acid
- agent
- polyoxyethylene
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 235000019341 magnesium sulphate Nutrition 0.000 title 1
- CSNNHWWHGAXBCP-UHFFFAOYSA-L magnesium sulphate Substances [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 title 1
- -1 polyoxyethylene Polymers 0.000 claims description 38
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 36
- 238000003287 bathing Methods 0.000 claims description 26
- 239000003795 chemical substances by application Substances 0.000 claims description 24
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 claims description 24
- 239000013040 bath agent Substances 0.000 claims description 23
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims description 16
- 239000004094 surface-active agent Substances 0.000 claims description 13
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 claims description 12
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 claims description 12
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 claims description 8
- 229960002446 octanoic acid Drugs 0.000 claims description 8
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 claims description 7
- 235000014113 dietary fatty acids Nutrition 0.000 description 19
- 239000000194 fatty acid Substances 0.000 description 19
- 229930195729 fatty acid Natural products 0.000 description 19
- 239000000839 emulsion Substances 0.000 description 14
- 239000003205 fragrance Substances 0.000 description 9
- ASKIVFGGGGIGKH-UHFFFAOYSA-N 2,3-dihydroxypropyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)CO ASKIVFGGGGIGKH-UHFFFAOYSA-N 0.000 description 8
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 8
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 7
- 229940057995 liquid paraffin Drugs 0.000 description 7
- 229960005323 phenoxyethanol Drugs 0.000 description 7
- 239000002253 acid Substances 0.000 description 6
- 150000004665 fatty acids Chemical class 0.000 description 6
- 239000001683 mentha spicata herb oil Substances 0.000 description 6
- 239000010668 rosemary oil Substances 0.000 description 6
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- 235000019721 spearmint oil Nutrition 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 239000000341 volatile oil Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000010411 cooking Methods 0.000 description 4
- 238000004945 emulsification Methods 0.000 description 4
- 125000005313 fatty acid group Chemical group 0.000 description 4
- 229940074052 glyceryl isostearate Drugs 0.000 description 4
- 229940049964 oleate Drugs 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 3
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- 239000004480 active ingredient Substances 0.000 description 3
- 239000003240 coconut oil Substances 0.000 description 3
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- 230000000052 comparative effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
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- 239000002736 nonionic surfactant Substances 0.000 description 3
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- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 238000005063 solubilization Methods 0.000 description 3
- 230000007928 solubilization Effects 0.000 description 3
- 230000000087 stabilizing effect Effects 0.000 description 3
- 150000003626 triacylglycerols Chemical class 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- JNAYPSWVMNJOPQ-UHFFFAOYSA-N 2,3-bis(16-methylheptadecanoyloxy)propyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCCCC(C)C JNAYPSWVMNJOPQ-UHFFFAOYSA-N 0.000 description 2
- LEEDMQGKBNGPDN-UHFFFAOYSA-N 2-methylnonadecane Chemical compound CCCCCCCCCCCCCCCCCC(C)C LEEDMQGKBNGPDN-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
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- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 2
- 239000011668 ascorbic acid Substances 0.000 description 2
- 235000010323 ascorbic acid Nutrition 0.000 description 2
- 229960005070 ascorbic acid Drugs 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
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- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
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- LXNHXLLTXMVWPM-UHFFFAOYSA-N pyridoxine Chemical compound CC1=NC=C(CO)C(CO)=C1O LXNHXLLTXMVWPM-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 241000894007 species Species 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
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- PROQIPRRNZUXQM-UHFFFAOYSA-N (16alpha,17betaOH)-Estra-1,3,5(10)-triene-3,16,17-triol Natural products OC1=CC=C2C3CCC(C)(C(C(O)C4)O)C4C3CCC2=C1 PROQIPRRNZUXQM-UHFFFAOYSA-N 0.000 description 1
- CUNWUEBNSZSNRX-RKGWDQTMSA-N (2r,3r,4r,5s)-hexane-1,2,3,4,5,6-hexol;(z)-octadec-9-enoic acid Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O CUNWUEBNSZSNRX-RKGWDQTMSA-N 0.000 description 1
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Landscapes
- Cosmetics (AREA)
Description
本発明は、入浴剤に関し、更に詳細には、浴槽に投入した場合に乳濁する、透明溶液の性状である、所謂ミルキータイプの入浴剤に関する。 The present invention relates to a bath agent, and more particularly to a so-called milky-type bath agent that is a property of a transparent solution that becomes milky when put in a bathtub.
古来より、入浴は種々の効果を生体に及ぼすものであり、日本には湯治という、入浴により各種疾病を治療する習慣が存するし、西欧においても「クアハウス」という制度は、治療行為の一部を負担しており、医療と密着した制度である。この様な入浴の効果を高める手段として、入浴剤を用いることも、又、世界各国で行われていることである。この様な入浴剤は、薬用植物の含有する有効成分を、一様に可溶化、乳化或いは分散させて、体表面全体及び呼気より吸収させる目的で、湯に含有させる製剤であるが、通常、生薬類の有効成分は、精油成分など、水には溶解しにくい成分が多い為、界面活性剤を用いて、可溶化或いは乳化させることが広く行われている。この様な乳化系は、バスタブに投入した際、希釈して乳化されるような設計になっており、この様な特性に適した界面活性剤として、ポリオキシエチレンオレイン酸エステルや、ポリオキシエチレンオレイルエーテルなどの不飽和炭化水素ポリオキシエチレン付加物が用いられている。（特許文献１、特許文献２、特許文献３、特許文献４を参照）しかしながら、この様な界面活性剤においては、追い炊きの際に湯垢を生じやすい欠点が存した。これは、乳化安定性がこの様な使用形態では決して良いものとは言えない為と思われる。又、可溶化の形態に於いて、香気成分のたちが悪く、しかも、香気成分の香調が経時的に変わりやすい欠点も存した。これは、乳化粒子中より、気化成分が放出されにくい為であると勘案される。この様な傾向は、精油を含有する入浴剤においては好ましくない。即ち、乳化時の安定性が高く、しかも香調の変化の少ない、浴槽に投入した場合に乳濁する、透明溶液の性状である入浴剤（ミルキータイプの入浴剤）の開発が望まれていた。 Since ancient times, bathing has various effects on the living body, and in Japan, there is a custom of treating various diseases by bathing called Yuji, and even in Western Europe, the system called `` Kurhaus '' It is a system that bears and is closely related to medical care. The use of a bathing agent as a means for enhancing the effect of such bathing is also carried out all over the world. Such bathing agents are preparations that are contained in hot water for the purpose of uniformly solubilizing, emulsifying or dispersing active ingredients contained in medicinal plants and absorbing them from the entire body surface and exhaled breath. Since active ingredients of crude drugs are many components that are difficult to dissolve in water, such as essential oil components, solubilization or emulsification using a surfactant is widely performed. Such an emulsifying system is designed to be diluted and emulsified when put into a bathtub, and polyoxyethylene oleate and polyoxyethylene are used as surfactants suitable for such characteristics. Unsaturated hydrocarbon polyoxyethylene adducts such as oleyl ether are used. (Refer to Patent Document 1, Patent Document 2, Patent Document 3, and Patent Document 4) However, such surfactants have a drawback that scales are liable to occur during additional cooking. This seems to be because the emulsion stability is never good in such a use form. Moreover, in the form of solubilization, the fragrance components were poor, and there was also a drawback that the fragrance of the fragrance components was likely to change over time. It is considered that this is because the vaporized component is less likely to be released than in the emulsified particles. Such a tendency is not preferable in a bath containing an essential oil. That is, it has been desired to develop a bathing agent (milky-type bathing agent) that has high stability during emulsification and has little change in fragrance, that becomes milky when put into a bathtub, and has a transparent solution property. .
一方、ポリオキシエチレン脂肪酸グリセリルは非イオン界面活性剤の一種であり、可溶化に優れる特性を有していることが知られている。又、該脂肪酸部分が、中鎖長の飽和直鎖の脂肪酸であるものについては、二層型の入浴剤に含有させ、刹那的なエマルジョン形成を行わせるような使用形態が知られている。又、この様な形態に於いては香調が長時間維持出来ることも知られている。（例えば、特許文献５を参照）しかしながらミルキータイプの入浴剤に含有させ、浴槽投入後に形成するエマルションを安定化させる技術については全く知られていない。 On the other hand, polyoxyethylene fatty acid glyceryl is a kind of nonionic surfactant and is known to have excellent properties for solubilization. In addition, a use form in which the fatty acid portion is a saturated straight-chain fatty acid having a medium chain length is contained in a two-layer bathing agent so as to form a decent emulsion. It is also known that incense tone can be maintained for a long time in such a form. (For example, refer to Patent Document 5) However, there is no known technique for stabilizing the emulsion that is contained in a milky-type bath agent and formed after the bath is added.
ポリオキシエチレン脂肪酸グリセリルを構成する脂肪酸残基において、該脂肪酸残基が分岐脂肪酸残基であるものは、洗浄剤に洗浄補助剤として含有させることが知られているが、入浴剤に含有させることは全く知られておらず、ミルキータイプの入浴剤に含有させ、浴槽投入後に形成するエマルションを安定化させる技術についても全く知られていない。 Of the fatty acid residues constituting the polyoxyethylene fatty acid glyceryl, those fatty acid residues that are branched fatty acid residues are known to be included in cleaning agents as cleaning aids, but should be included in bathing agents. Is not known at all, and there is also no known technique for stabilizing an emulsion formed after being put in a bath and contained in a milky type bath agent.
本発明は、この様な状況下為されたものであり、ミルキータイプの入浴剤において、浴槽投入後に形成するエマルションを安定化させる技術を提供することを課題とする。 This invention is made | formed under such a condition, and makes it a subject to provide the technique which stabilizes the emulsion formed after bathing in a milky type bath agent.
この様な状況に鑑みて、本発明者らは、ミルキータイプの入浴剤において、浴槽投入後に形成するエマルションを安定化させる技術を求めて、鋭意研究努力を重ねた結果、浴槽に投入した場合に乳濁する、透明溶液の性状である入浴剤において、界面活性剤として、ポリオキシエチレン脂肪酸グリセリルを含有させることにより、この様な課題の解決が出来ることを見出し、発明を完成させるに至った。即ち、本発明は、以下に示す技術に関するものである。
（１）浴槽に投入した場合に乳濁する、透明溶液の性状である入浴剤において、界面活性剤として、ポリオキシエチレン（７）（カプリン酸・カプリル酸）グリセリルを含有し、（カプリン酸・カプリル酸）トリグリセライドを油剤として入浴剤全量に対して１〜２０重量％含有することを特徴とする、入浴剤。
In view of such a situation, in the milky type bathing agent, the present inventors have sought for a technique for stabilizing the emulsion formed after the addition of the bath, and as a result of earnest research efforts, It has been found that such a problem can be solved by incorporating polyoxyethylene fatty acid glyceryl as a surfactant in a bathing agent that is in the form of a transparent solution that is emulsified, and has completed the invention. That is, this invention relates to the technique shown below.
(1) In a bathing agent that is a transparent solution that becomes milky when put into a bathtub, it contains polyoxyethylene (7) (capric acid / caprylic acid) glyceryl as a surfactant, A bathing agent containing 1 to 20% by weight of caprylic acid) triglyceride as an oil agent with respect to the total amount of the bathing agent.
本発明によれば、ミルキータイプの入浴剤において、浴槽投入後に形成するエマルションを安定化させることができる。 ADVANTAGE OF THE INVENTION According to this invention, in the milky type bath agent, the emulsion formed after bathing can be stabilized.
（１）本発明の入浴剤の必須成分であるポリオキシエチレン脂肪酸グリセリル
本発明の入浴剤は、浴槽に投入した場合に乳濁する、透明溶液の性状であって、界面活性剤として、ポリオキシエチレン脂肪酸グリセリルを含有することを特徴とする。かかるポリオキシエチレン脂肪酸グリセリルは、化粧料の分野に於いては非イオン界面活性剤として汎用されている成分であり、その入手は様々な市販品が存するため極めて容易である。本発明の入浴剤に使用するポリオキシエチレン脂肪酸グリセリルとしては、それを構成する脂肪酸残基が炭素数６〜１２の中鎖長の飽和直鎖のもの、或いは、炭素数が１２〜２４であって、分岐構造を有するものであることが好ましい。又、ポリオキシエチレン基の平均付加モル数は６〜３０が好ましい。特に好ましいものとしては、ポリオキシエチレン（７）（カプリン酸・カプリル酸）グリセリル、ポリオキシエチレン（２０）モノイソステアリン酸グリセリル、ポリオキシエチレン（２０）トリイソステアリン酸グリセリルなどが例示出来る。ポリオキシエチレン脂肪酸グリセリル、好ましくはポリオキシエチレン中鎖脂肪酸グリセリル乃至はポリオキシエチレン分岐脂肪酸グリセリルは、液状で乳化、再乳化性に優れる為、バスタブ中で形成した乳化物の安定性が向上する。特に本発明の乳濁系の入浴剤に精油成分を用いた場合に、油滴の分散性に優れるため、追い炊きしても、湯あかなどを生じにくい。又、精油成分の保香効果にも優れる。本発明の入浴剤に於けるポリオキシエチレン脂肪酸グリセリルの好ましい含有量は、総量で５〜２０重量％であり、更に好ましくは１０〜１５重量％である。これは、少なすぎると、バスタブに投入し形成した乳化物の安定性が損なわれる場合が存し、多すぎると精油成分などを用いた場合に、香りのたちが阻害される場合が存するためである。
(1) Polyoxyethylene fatty acid glyceryl which is an essential component of the bathing agent of the present invention The bathing agent of the present invention is a property of a transparent solution that becomes milky when put into a bath, and is used as a surfactant as a polyoxy It contains ethylene fatty acid glyceryl. Such polyoxyethylene fatty acid glyceryl is a component that is widely used as a nonionic surfactant in the cosmetics field, and its availability is very easy because there are various commercial products. As the polyoxyethylene fatty acid glyceryl used in the bathing agent of the present invention, the fatty acid residue constituting it is a saturated straight chain having a medium chain length of 6 to 12 carbon atoms, or 12 to 24 carbon atoms. Thus, it preferably has a branched structure. Further, the average added mole number of the polyoxyethylene group is preferably 6-30. Particularly preferred are polyoxyethylene (7) (capric acid caprylic acid) glyceryl, and polyoxyethylene (20) monoisostearate, glyceryl polyoxyethylene (20) glyceryl triisostearate, etc. can be exemplified. Since polyoxyethylene fatty acid glyceryl, preferably polyoxyethylene medium chain fatty acid glyceryl or polyoxyethylene branched fatty acid glyceryl is liquid and excellent in emulsification and re-emulsification, the stability of the emulsion formed in the bathtub is improved. In particular, when an essential oil component is used in the emulsion-based bathing agent of the present invention, the oil droplets are excellent in dispersibility, so that even if they are cooked, hot water is not easily generated. Moreover, it is excellent also in the aroma retaining effect of an essential oil component. The preferable content of the polyoxyethylene fatty acid glyceryl in the bath agent of the present invention is 5 to 20% by weight, more preferably 10 to 15% by weight. This is because if the amount is too small, the stability of the emulsion formed in the bathtub may be impaired, and if it is too large, the fragrance may be inhibited when using essential oil components. is there.
（２）本発明の入浴剤
本発明の入浴剤は、浴槽に投入した場合に乳濁する、透明溶液の性状であって、界面活性剤として、ポリオキシエチレン脂肪酸グリセリルを含有することを特徴とする。本発明の入浴剤においては、前記ポリオキシエチレン脂肪酸グリセリル以外に、通常入浴剤や化粧料で使用する任意の成分を含有することが出来る。かかる任意成分としては、例えば、スクワラン、流動パラフィン、軽質流動イソパラフィン、重質流動イソパラフィン、マイクロクリスタリンワックス、固形パラフィンなどの炭化水素類、ジメチコン、フェメチコン、シクロメチコン、アモジメチコン、ポリエーテル変性シリコーンなどのシリコーン類、ホホバ油、カルナウバワックス、モクロウ、ミツロウ、ゲイロウ、オレイン酸オクチルドデシル、イソプロピルミリステート、ネオペンチルグリコールジイソステアレート、リンゴ酸ジイソステアレートなどのエステル類、ステアリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、イソステアリン酸、イソパルミチン酸、ベヘン酸、オレイン酸などの脂肪酸類、ベヘニルアルコール、セタノール、オレイルアルコール、オクタデシルアルコールなどの高級アルコール類、ヒマシ油、椰子油、水添椰子油、椿油、小麦胚芽油、イソステアリン酸トリグリセライド、イソオクタン酸トリグリセライド、オリーブオイル等のトリグリセライド類、１，３−ブタンジオール、グリセリン、ジグリセリン、ジプロピレングリコール、ポリエチレングリコール、１，２−ペンタンジオール、１，２−ヘキシレングリコール、イソプレングリコールなどの多価アルコール、ソルビタンセスキオレート、ソルビタンモノオレート、ソルビタントリオレート、ソルビタンセスキステアレート、ソルビタンモノステアレート、ポリオキシエチレンソルビタンモノオレート、ポリオキシエチレンソルビタンモノステアレート、ポリオキシエチレンステアレート、ポリオキシエチレンオレート、ポリオキシエチレングリセリル脂肪酸エステル、ポリエキシエチレンアルキルエーテル、ポリオキシエチレン硬化ヒマシ油等の非イオン界面活性剤、ソジウムラウリルステアレート、ポリオキシエチレンアルキル硫酸塩、スルホコハク酸エステル塩などのアニオン界面活性剤、４級アルキルアンモニウム塩等のカチオン界面活性剤類、アルキルベタイン等の両性界面活性剤類、結晶セルロースや架橋型メチルポリシロキサン、ポリエチレン粉末、アクリル樹脂粉体等の有機粉体類、タルク、マイカ、セリサイト、炭酸マグネシウム、炭酸カルシウム、二酸化チタン、酸化鉄、紺青、群青、チタンマイカ、チタンセリサイト、シリカ等の表面処理されていても良い粉体類、アクリル酸・メタクリル酸アルキルコポリマー及び／又はその塩、カルボキシビニルポリマー及び／又はその塩、キサンタンガムやヒドロキシプロピルセルロースなどの増粘剤、レチノール、レチノイン酸、トコフェロール、リボフラビン、ピリドキシン、アスコルビン酸、アスコルビン酸リン酸エステル塩などのビタミンやグリチルリチン酸塩、グリチルレチン、ウルソール酸、オレアノール酸などのテルペン類、エストラジオール、エチニルエストラジオール、エストリオールなどのステロイド類などの有効成分、フェノキシエタノール、パラベン類、ヒビテングルコネート、塩化ベンザルコニウム等の防腐剤、ジメチルアミノ安息香酸エステル類、桂皮酸エステル類、ベンゾフェノン類などの紫外線吸収剤などが好ましく例示できる。これらの内、特に好ましいものは、中鎖長の脂肪酸のトリグリセライドである。これは、この様な成分が、油剤の中では水への分散性が良好なため、形成したエマルションの安定性が高まることと、香気成分の保持性において、経時的に香調が変わらないような保持能を有するためである。かかる中鎖長の脂肪酸トリグリセライドとしては、（カプリン酸・カプリル酸）トリグリセライドが特に好適に例示出来る。かかる中鎖長のトリグリセライドは唯一種を含有することも出来るし、二種以上を組み合わせて含有させることも出来る。本発明の入浴剤に於ける、中鎖長の脂肪酸のトリグリセライドの好ましい含有量は、総量で、１〜２０重量％であり、更に好ましくは、５〜１５重量％である。又、本発明の入浴剤においては、実質的に、オレイン酸残基又はオレイル基を有する界面活性剤を含有しないことが好ましい。オレイン酸残基或いはオレイル基を有する界面活性剤としては、例えば、ポリオキシエチレンオレイン酸エステル、ポリオキシエチレンオレイルエーテル、ポリオキシエチレンソルビタンオレイン酸エステルなどが挙げられるが、本発明の入浴剤ではこの様な界面活性剤は、実質的に含有しないことが好ましい。これは、この様な界面活性剤がバスタブで形成するエマルションが追い炊きなどによって、壊れやすく、湯垢を生じやすいためである。本発明の入浴剤は、前記必須成分と任意成分を常法に従って処理することにより、製造することが出来る。
(2) Bathing agent of the present invention The bathing agent of the present invention is a transparent solution that becomes milky when put into a bathtub, and contains polyoxyethylene fatty acid glyceryl as a surfactant. To do. In the bath agent of this invention, the arbitrary component normally used with a bath agent and cosmetics other than the said polyoxyethylene fatty-acid glyceryl can be contained. Such optional components include, for example, hydrocarbons such as squalane, liquid paraffin, light liquid isoparaffin, heavy liquid isoparaffin, microcrystalline wax, solid paraffin, dimethicone, femethicone, cyclomethicone, amodimethicone, polyether-modified silicone, etc. Silicones, jojoba oil, carnauba wax, owl, beeswax, geiwa, octyldodecyl oleate, isopropyl myristate, esters such as neopentyl glycol diisostearate, diisostearate malate, stearic acid, lauric acid, Fatty acids such as myristic acid, palmitic acid, isostearic acid, isopalmitic acid, behenic acid, oleic acid, behenyl alcohol, cetanol, oleyl alcohol, octadecyl alcohol High alcohols such as coal, castor oil, coconut oil, hydrogenated coconut oil, coconut oil, wheat germ oil, triglycerides such as isostearic acid triglyceride, isooctanoic acid triglyceride, olive oil, 1,3-butanediol, glycerin, diglycerin , Dipropylene glycol, polyethylene glycol, 1,2-pentanediol, 1,2-hexylene glycol, isoprene glycol and other polyhydric alcohols, sorbitan sesquioleate, sorbitan monooleate, sorbitan trioleate, sorbitan sesquistearate, sorbitan mono Stearate, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monostearate, polyoxyethylene stearate, polyoxyethylene oleate, polio Nonionic surfactants such as ciethylene glyceryl fatty acid ester, polyoxyethylene alkyl ether, polyoxyethylene hydrogenated castor oil, anionic surfactants such as sodium lauryl stearate, polyoxyethylene alkyl sulfate, sulfosuccinate ester salt, Cationic surfactants such as quaternary alkyl ammonium salts, amphoteric surfactants such as alkyl betaines, organic powders such as crystalline cellulose, cross-linked methylpolysiloxane, polyethylene powder, acrylic resin powder, talc, mica, Sericite, magnesium carbonate, calcium carbonate, titanium dioxide, iron oxide, bitumen, ultramarine, titanium mica, titanium sericite, silica and other surface-treated powders, acrylic acid / alkyl methacrylate copolymers and / or Its salt, carboxybi Nyl polymers and / or salts thereof, thickeners such as xanthan gum and hydroxypropyl cellulose, vitamins such as retinol, retinoic acid, tocopherol, riboflavin, pyridoxine, ascorbic acid, ascorbic acid phosphate ester, glycyrrhizinate, glycyrrhetin, ursolic acid , Terpenes such as oleanolic acid, active ingredients such as steroids such as estradiol, ethinyl estradiol, estriol, preservatives such as phenoxyethanol, parabens, hibiten gluconate, benzalkonium chloride, dimethylaminobenzoic acid esters, cinnamon Preferred examples include ultraviolet absorbers such as acid esters and benzophenones. Of these, particularly preferred is triglyceride of a medium chain length fatty acid. This is because such an ingredient has good dispersibility in water in an oil agent, so that the stability of the formed emulsion is increased and the fragrance tone does not change over time in the retention of the fragrance ingredient. This is because it has a good holding ability. As this medium chain length fatty acid triglyceride, (capric acid / caprylic acid) triglyceride can be particularly preferably exemplified. Such medium chain length triglycerides may contain only one species or may contain two or more species in combination. In the bath agent of the present invention, the total content of triglycerides of fatty acids having a medium chain length is 1 to 20% by weight, more preferably 5 to 15% by weight in total. Moreover, it is preferable that the bath agent of the present invention does not substantially contain a surfactant having an oleic acid residue or an oleyl group. Examples of the surfactant having an oleic acid residue or an oleyl group include polyoxyethylene oleate, polyoxyethylene oleyl ether, polyoxyethylene sorbitan oleate, and the like. Such a surfactant is preferably substantially not contained. This is because an emulsion formed by such a surfactant in a bathtub is easily broken and easily causes scales due to additional cooking. The bath agent of this invention can be manufactured by processing the said essential component and arbitrary components in accordance with a conventional method.
以下に、本発明について、実施例を挙げて更に詳細に説明を加えるが、本発明が、かかる実施例にのみ限定されないことは言うまでもない。 Hereinafter, the present invention will be described in more detail with reference to examples, but it is needless to say that the present invention is not limited to such examples.
＜実施例１＞
以下に示す処方に従って、本発明の入浴剤を作成した。即ち、処方成分を８０℃に加熱して、攪拌、可溶化し、攪拌冷却して本発明の入浴剤１を得た。
「センキュウエキス」（丸善製薬株式会社製） １ 重量部
「カミツレ流エキス」（丸善製薬株式会社製） ２．５重量部
スペアミント油 ０．７重量部
ローズマリー油 ０．９重量部
カプリン酸・カプリル酸トリグリセライド ５ 重量部
ＰＯＥ（７）（カプリン酸／カプリル酸）グリセリル ６ 重量部
ＰＯＥ（２０）イソステアリン酸グリセリル ７ 重量部
フェノキシエタノール ０．５重量部
流動パラフィン ７６．４重量部
<Example 1>
The bath agent of the present invention was prepared according to the formulation shown below. That is, the prescription ingredients were heated to 80 ° C., stirred and solubilized, and stirred and cooled to obtain the bath agent 1 of the present invention.
“Senkyu extract” (manufactured by Maruzen Pharmaceutical Co., Ltd.) 1 part by weight “camomile extract” (manufactured by Maruzen Pharmaceutical Co., Ltd.) 2.5 parts by weight spearmint oil 0.7 part by weight rosemary oil 0.9 part by weight capric acid / capryl Acid triglyceride 5 parts by weight POE (7) (capric / caprylic acid) glyceryl 6 parts by weight POE (20) glyceryl isostearate 7 parts by weight Phenoxyethanol 0.5 parts by weight Liquid paraffin 76.4 parts by weight
＜実施例２＞
実施例１と同様に本発明の入浴剤２を得た。このものは、バスタブに投入してからエマルションを形成するまでに、実施例１の入浴剤１に比して、時間がかかった。
「センキュウエキス」（丸善製薬株式会社製） １ 重量部
「カミツレ流エキス」（丸善製薬株式会社製） ２．５重量部
スペアミント油 ０．７重量部
ローズマリー油 ０．９重量部
カプリン酸・カプリル酸トリグリセライド ５ 重量部
ＰＯＥ（７）（カプリン酸／カプリル酸）グリセリル １３ 重量部
フェノキシエタノール ０．５重量部
流動パラフィン ７６．４重量部
<Example 2>
The bath agent 2 of the present invention was obtained in the same manner as in Example 1. Compared with the bath agent 1 of Example 1, it took time to put this in the bathtub and to form the emulsion.
“Senkyu extract” (manufactured by Maruzen Pharmaceutical Co., Ltd.) 1 part by weight “camomile extract” (manufactured by Maruzen Pharmaceutical Co., Ltd.) 2.5 parts by weight spearmint oil 0.7 part by weight rosemary oil 0.9 part by weight capric acid / capryl Acid triglyceride 5 parts by weight POE (7) (capric / caprylic acid) glyceryl 13 parts by weight Phenoxyethanol 0.5 part by weight Liquid paraffin 76.4 parts by weight
＜参考例１＞
実施例１と同様に参考例１の入浴剤３を得た。
「センキュウエキス」（丸善製薬株式会社製） １ 重量部
「カミツレ流エキス」（丸善製薬株式会社製） ２．５重量部
スペアミント油 ０．７重量部
ローズマリー油 ０．９重量部
カプリン酸・カプリル酸トリグリセライド ５ 重量部
ＰＯＥ（２０）イソステアリン酸グリセリル １３ 重量部
フェノキシエタノール ０．５重量部
流動パラフィン ７６．４重量部
< Reference Example 1 >
The bath agent 3 of Reference Example 1 was obtained in the same manner as Example 1 .
“Senkyu extract” (manufactured by Maruzen Pharmaceutical Co., Ltd.) 1 part by weight “camomile extract” (manufactured by Maruzen Pharmaceutical Co., Ltd.) 2.5 parts by weight spearmint oil 0.7 part by weight rosemary oil 0.9 part by weight capric acid / capryl Acid triglyceride 5 parts by weight POE (20) glyceryl isostearate 13 parts by weight phenoxyethanol 0.5 part by weight liquid paraffin 76.4 parts by weight
＜参考例２＞
実施例１と同様に参考例２の入浴剤４を得た。このものは、実施例１の入浴剤１に比して、バスタブでのエマルション形成に時間が必要であった。
「センキュウエキス」（丸善製薬株式会社製） １ 重量部
「カミツレ流エキス」（丸善製薬株式会社製） ２．５重量部
スペアミント油 ０．７重量部
ローズマリー油 ０．９重量部
ＰＯＥ（７）（カプリン酸／カプリル酸）グリセリル ６ 重量部
ＰＯＥ（２０）イソステアリン酸グリセリル ７ 重量部
フェノキシエタノール ０．５重量部
流動パラフィン ８１．４重量部
< Reference Example 2 >
The bath agent 4 of Reference Example 2 was obtained in the same manner as Example 1. Compared with the bath agent 1 of Example 1, this product took time to form an emulsion in the bathtub.
“Senkyu extract” (manufactured by Maruzen Pharmaceutical Co., Ltd.) 1 part by weight “camomile style extract” (manufactured by Maruzen Pharmaceutical Co., Ltd.) 2.5 parts by weight spearmint oil 0.7 part by weight rosemary oil 0.9 part by weight POE (7) (Capric acid / Caprylic acid) Glyceryl 6 parts by weight POE (20) Glyceryl isostearate 7 parts by weight Phenoxyethanol 0.5 part by weight Liquid paraffin 81.4 parts by weight
＜参考例３＞
実施例１と同様に参考例３の入浴剤５を得た。
「センキュウエキス」（丸善製薬株式会社製） １ 重量部
「カミツレ流エキス」（丸善製薬株式会社製） ２．５重量部
スペアミント油 ０．７重量部
ローズマリー油 ０．９重量部
カプリン酸・カプリル酸トリグリセライド ５ 重量部
ＰＯＥ（２０）オレイン酸エステル ６ 重量部
ＰＯＥ（２０）イソステアリン酸グリセリル ７ 重量部
フェノキシエタノール ０．５重量部
流動パラフィン ７６．４重量部
< Reference Example 3 >
The bath agent 5 of Reference Example 3 was obtained in the same manner as Example 1.
“Senkyu extract” (manufactured by Maruzen Pharmaceutical Co., Ltd.) 1 part by weight “camomile extract” (manufactured by Maruzen Pharmaceutical Co., Ltd.) 2.5 parts by weight spearmint oil 0.7 part by weight rosemary oil 0.9 part by weight capric acid / capryl Acid triglyceride 5 parts by weight POE (20) oleate 6 parts by weight POE (20) glyceryl isostearate 7 parts by weight Phenoxyethanol 0.5 part by weight Liquid paraffin 76.4 parts by weight
＜比較例１＞
実施例１と同様に比較例１を得た。
「センキュウエキス」（丸善製薬株式会社製） １ 重量部
「カミツレ流エキス」（丸善製薬株式会社製） ２．５重量部
スペアミント油 ０．７重量部
ローズマリー油 ０．９重量部
カプリン酸・カプリル酸トリグリセライド ５ 重量部
ＰＯＥ（２０）オレイン酸エステル ６ 重量部
ＰＯＥ（２０）オレイルエーテル ７ 重量部
フェノキシエタノール ０．５重量部
流動パラフィン ７６．４重量部
<Comparative Example 1>
Comparative Example 1 was obtained in the same manner as Example 1.
“Senkyu extract” (manufactured by Maruzen Pharmaceutical Co., Ltd.) 1 part by weight “camomile extract” (manufactured by Maruzen Pharmaceutical Co., Ltd.) 2.5 parts by weight spearmint oil 0.7 part by weight rosemary oil 0.9 part by weight capric acid / capryl Acid triglyceride 5 parts by weight POE (20) oleic acid ester 6 parts by weight POE (20) oleyl ether 7 parts by weight Phenoxyethanol 0.5 part by weight Liquid paraffin 76.4 parts by weight
＜試験例１＞
実施例１〜５及び比較例１の入浴剤について、８０Ｌの温水（４２℃）に１０ｍｌを加えて、香りのイメージ、溶状を専門パネラーにより評価し、３０℃まで放冷した後、追い炊きして４２℃に戻し、再び、同様の評価を行った。香りのイメージの評価は、華やかさ、すがすがしさ、香りの経時的変化をそれぞれ次に示す基準で評価した。溶状は、湯垢の出現の程度を次に示す基準で評価した。結果を表１に示す。これより、本発明の入浴剤は、香りの経時変化が少なく、追い炊きしても香りのイメージ、溶状が変化しないことが判る。又、本発明の入浴剤としては、実質的に、オレイン酸残基又はオレイル基を有する界面活性剤を含有しない形態、中鎖長の脂肪酸のトリグリセライドを含有する形態が好ましいことも判る。
（香りの評価基準）
スコア５：かなり感じる
スコア４：明確に感じる
スコア３：感じる
スコア２：やや感じる
スコア１：殆ど感じない
スコア０：感じない
（溶状の判定基準）
スコア５：全く湯垢がみられない
スコア４：殆ど湯垢がみられない
スコア３：湯垢は存在するが気にならない
スコア２：湯垢が少し気になる
スコア１：湯垢が気になる
<Test Example 1>
About the bath agents of Examples 1 to 5 and Comparative Example 1, 10 ml was added to 80 L of warm water (42 ° C.), and the image of the fragrance and the state of solution were evaluated by a specialized panelist. The temperature was returned to 42 ° C., and the same evaluation was performed again. The evaluation of the scent image was evaluated based on the following criteria for the gorgeousness, the freshness, and the change over time of the scent. The melt state was evaluated based on the following criteria for the degree of appearance of scale. The results are shown in Table 1. From this, it can be seen that the bathing agent of the present invention has little change in the scent over time, and the image and solution of the scent do not change even after additional cooking. In addition, it can be seen that the bathing agent of the present invention preferably has a form containing substantially no surfactant having an oleic acid residue or an oleyl group and a form containing a triglyceride of a medium chain length fatty acid.
(Evaluation criteria for fragrance)
Score 5: Feel quite a bit 4: Clearly feel a score 3: Feel a score 2: Slightly feel a score 1: Little feel a score 0: Feel a little (determination criteria for melt)
Score 5: No scale is seen. Score 4: Little scale is seen. Score 3: There is scale but I don't care. Score 2: I'm worried about scale. Score 1: I'm concerned about scale.
本発明は、追い炊きしても品質の変わらない入浴剤に応用出来る。 The present invention can be applied to a bathing agent whose quality does not change even after additional cooking.
Claims (1)
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| JP2003272672A JP4332380B2 (en) | 2003-07-10 | 2003-07-10 | Milky type bath salt |
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| JP2009054622A Division JP4923076B2 (en) | 2009-03-09 | 2009-03-09 | Milky type bath salt |
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| JP2010037265A (en) * | 2008-08-05 | 2010-02-18 | Tanpei Seiyaku Kk | Suspendible bath agent |
| JP7158152B2 (en) * | 2018-01-31 | 2022-10-21 | 花王株式会社 | Self-emulsifying bath agent composition |
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