JP4328388B2 - スチレン重合体の臭素化方法 - Google Patents

スチレン重合体の臭素化方法 Download PDF

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Publication number
JP4328388B2
JP4328388B2 JP51565898A JP51565898A JP4328388B2 JP 4328388 B2 JP4328388 B2 JP 4328388B2 JP 51565898 A JP51565898 A JP 51565898A JP 51565898 A JP51565898 A JP 51565898A JP 4328388 B2 JP4328388 B2 JP 4328388B2
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Prior art keywords
bromine
polystyrene
amount
mixture
styrene
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Expired - Lifetime
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JP51565898A
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Japanese (ja)
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JP2001501237A5 (OSRAM
JP2001501237A (ja
Inventor
アオ,メング―シエング
ダドガー,ビリー・ビー
コリシユ,チヤールズ・エイチ
バルホフ,ドナルド・イー
リン,ホーマー・シー
ブラツケンリツジ,デイビツド・アール
ブロツクマン,ソーステン・ダブリユー
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アルベマール・コーポレーシヨン
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Priority claimed from US08/846,156 external-priority patent/US5767203A/en
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Publication of JP2001501237A5 publication Critical patent/JP2001501237A5/ja
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/18Introducing halogen atoms or halogen-containing groups
    • C08F8/20Halogenation

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
JP51565898A 1996-09-26 1997-09-05 スチレン重合体の臭素化方法 Expired - Lifetime JP4328388B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US72138996A 1996-09-26 1996-09-26
US08/846,156 1997-04-25
US08/721,389 1997-04-25
US08/846,156 US5767203A (en) 1996-09-26 1997-04-25 Process for brominated styrenic polymers
PCT/US1997/015622 WO1998013396A1 (en) 1996-09-26 1997-09-05 Process for brominated styrenic polymers

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP2009109178A Division JP4969605B2 (ja) 1996-09-26 2009-04-28 難燃性が与えられた熱可塑材

Publications (3)

Publication Number Publication Date
JP2001501237A JP2001501237A (ja) 2001-01-30
JP2001501237A5 JP2001501237A5 (OSRAM) 2006-05-18
JP4328388B2 true JP4328388B2 (ja) 2009-09-09

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Family Applications (1)

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JP51565898A Expired - Lifetime JP4328388B2 (ja) 1996-09-26 1997-09-05 スチレン重合体の臭素化方法

Country Status (7)

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US (2) US5916978A (OSRAM)
EP (1) EP0928300B1 (OSRAM)
JP (1) JP4328388B2 (OSRAM)
CA (1) CA2265642C (OSRAM)
DE (1) DE69701997T2 (OSRAM)
IL (1) IL129113A (OSRAM)
WO (1) WO1998013396A1 (OSRAM)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5637650A (en) 1996-06-14 1997-06-10 Ferro Corporation Brominated polysytrene having improved thermal stability and color and process for the preparation thereof
US6518368B2 (en) 1996-06-14 2003-02-11 Albemarle Corporation Brominated polystyrene having improved thermal stability and color and process for the preparation thereof
US6232393B1 (en) 1996-09-26 2001-05-15 Albemarle Corporation Polymers flame retarded with brominated polystyrenic resins
US6235831B1 (en) 1996-09-26 2001-05-22 Albemarle Corporation Polymer compositions containing brominated polystyrenic resins
US6326439B1 (en) 1996-09-26 2001-12-04 Albemarle Corporation Process for brominating polystyrenic resins
US6232408B1 (en) 1996-09-26 2001-05-15 Albemarle Corporation Brominated polstyrenic resins
CA2265642C (en) 1996-09-26 2006-03-14 Albemarle Corporation Process for brominated styrenic polymers
US6521714B2 (en) * 1996-09-26 2003-02-18 Albemarle Corporation Brominated polystyrenic resins
EP2189480B1 (en) * 1997-05-07 2014-12-03 Albemarle Corporation Process for brominating polystyrenic resins
IL141905A0 (en) * 1998-09-10 2002-03-10 Albemarle Corp Improved brominated polystyrenic resins, and their use
US6333385B1 (en) 1999-11-15 2001-12-25 Marquette University Method to produce flame retardant styrenic polymers and product produced thereby
ATE462681T1 (de) 2001-12-21 2010-04-15 Chemtura Corp Verfahren und vorrichtung zur herstellung von decabromdiphenylalkanen
US20040072929A1 (en) * 2002-06-27 2004-04-15 De Schryver Daniel A. Flame retardant compositions
US6657028B1 (en) 2002-08-01 2003-12-02 Albemarle Corporation Anionic polymerization process
US20050159552A1 (en) * 2004-01-21 2005-07-21 Reed Jon S. Flame retarded fibers and filaments and process of production therefor
US7666944B2 (en) * 2004-01-21 2010-02-23 Albemarle Corporation Flame retarded fibers and filaments and process of production therefor
KR101185755B1 (ko) * 2004-05-20 2012-09-27 알베마를 코포레이션 펠렛화된 브롬화 음이온성 스티렌계 중합체 및 그의 제조 및 용도
KR101419669B1 (ko) * 2005-06-30 2014-07-15 알베마를 코포레이션 브롬화 스티렌계 중합체 및 이의 제조
CA2629736C (en) * 2005-12-21 2014-07-08 Albemarle Corporation Preparation of brominated styrenic polymers or resins
CN101341174B (zh) 2005-12-21 2011-08-31 雅宝公司 溴化阴离子苯乙烯系聚合物及其制备
HUE025498T2 (hu) 2006-07-20 2016-04-28 Albemarle Corp Eljárási technológia brómozott sztirolpolimerek visszanyerésére reakcióelegyekbõl, amelyekben képzõdtek és/vagy ezen elegyek átalakítása pelletekké vagy granulátumokká vagy pasztillákká
TW200817447A (en) * 2006-08-22 2008-04-16 Albemarle Corp Terminating bromination of styrenic polymer in a bromination reaction mixture
CN101541495A (zh) 2006-11-28 2009-09-23 雅宝公司 将溴化阴离子苯乙烯类聚合物转换成便于储存、运输和使用的更硬并更大的形态
PL2158233T3 (pl) * 2007-06-07 2019-04-30 Albemarle Corp Addukty, addukty i oligomery lub addukty, oligomery i polimery o małym ciężarze cząsteczkowym oraz ich wytwarzanie
US8993684B2 (en) * 2008-06-06 2015-03-31 Albemarle Corporation Low molecular weight brominated polymers, processes for their manufacture and their use in thermoplastic formulations
JP5498486B2 (ja) 2008-06-06 2014-05-21 アルベマール・コーポレーシヨン 低分子量臭素化ポリマー、それらの製作プロセス、および熱可塑性配合物におけるそれらの使用
SG171741A1 (en) * 2008-12-02 2011-07-28 Albemarle Corp Toluene and styrene derived telomer distributions and brominated flame retardants produced therefrom
JO3423B1 (ar) * 2008-12-02 2019-10-20 Albemarle Corp مؤخرات لهب معالجة بالبروم و مواد مشتقه منها
WO2010065464A1 (en) * 2008-12-02 2010-06-10 Albemarle Corporation Bromination of telomer mixtures derived from toluene and styrene
US8476373B2 (en) * 2008-12-02 2013-07-02 Albemarle Corporation Branched and star-branched styrene polymers, telomers, and adducts, their synthesis, their bromination, and their uses
JP2012525483A (ja) 2009-05-01 2012-10-22 アルベマール・コーポレーシヨン ペレット化された低分子量臭素化芳香族ポリマー組成物
JO3059B1 (ar) 2009-05-01 2017-03-15 Albemarle Corp معالجة بالبروم لتراكيب بوليمرات عطرية ذات وزن جزيئي منخفض
WO2022031932A1 (en) * 2020-08-07 2022-02-10 Albemarle Corporation Additives for flame retarded polyolefins
CN117247482B (zh) * 2023-11-17 2024-02-20 山东旭锐新材股份有限公司 一种高热稳定性溴化聚苯乙烯合成方法

Family Cites Families (67)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1890772A (en) * 1930-01-28 1932-12-13 Du Pont Chlorination of meta styrene
US2199026A (en) * 1937-04-01 1940-04-30 Du Pont Chlorinated aromatic resins
US2823201A (en) * 1952-03-10 1958-02-11 Dow Chemical Co Halogenated polymers of nuclear methylated aromatic hydrocarbons, their quaternary ammonium salts and method of making the same
US3009906A (en) * 1957-05-09 1961-11-21 Dow Chemical Co Halogenation of solid resinous polymers of alkenylaromatic compounds with gaseous halogens
US3050476A (en) * 1958-12-08 1962-08-21 Koppers Co Inc Method of making a self extinguishing expandable polymer of styrene by bromination
US3039977A (en) * 1959-12-03 1962-06-19 Koppers Co Inc Method of producing self-extinguishing foamable polystyrene by brominating foamable polystyrene in aqueous suspension
US3132045A (en) * 1961-10-26 1964-05-05 Dow Chemical Co Method of impregnating film materials with ammonium bromide
NL128916C (OSRAM) * 1965-02-18 1900-01-01
US3506741A (en) * 1966-01-10 1970-04-14 Phillips Petroleum Co Halogenated polymers and block copolymers produced therefrom
US3534012A (en) * 1969-05-01 1970-10-13 Dow Chemical Co Anionic polymerization of nuclear halogenated styrenes
CH584731A5 (OSRAM) * 1973-12-17 1977-02-15 Ciba Geigy Ag
US4028486A (en) * 1974-06-03 1977-06-07 The Goodyear Tire & Rubber Company Alpha-methyl-p-bromo-styrene and method of preparation
US3959398A (en) * 1974-06-03 1976-05-25 The Goodyear Tire & Rubber Company Alpha-methyl-p-bromo-styrene and method of preparation
US3932542A (en) * 1974-08-26 1976-01-13 Great Lakes Chemical Corporation Process for preparation of 2,5-dibromo-p-xylene
US4178327A (en) * 1974-12-19 1979-12-11 The Dow Chemical Company Ar-halo-ar(t-alkyl)styrenes and polymers thereof
DE2515473C3 (de) 1975-04-09 1987-01-22 Basf Ag, 6700 Ludwigshafen Flammwidrige, lineare Polyester
CA1054161A (en) * 1975-08-22 1979-05-08 Herbert Naarmann Manufacture of heat-stable brominated oligomers of monovinyl-aromatic compounds
DE2645711C3 (de) * 1976-10-09 1979-06-07 Basf Ag, 6700 Ludwigshafen Halogenhaltige Flammschutzmittel enthaltende Fasern und Fäden aus linearen, thermoplastischen Polyestern
DE2651435C3 (de) * 1976-11-11 1980-11-27 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von bromierten Polymerisationsprodukten des Styrols
DE2703419B1 (de) * 1977-01-28 1978-02-02 Basf Ag Flammwidrig ausgeruestete polyamid- formmassen
FR2413409A1 (fr) * 1978-01-02 1979-07-27 Huels Chemische Werke Ag Procede pour preparer des polystyrenes resistant a la chaleur, bromes sur le noyau
EP0020294B1 (de) * 1979-05-07 1982-11-10 Ciba-Geigy Ag Verfahren zur Herstellung von bromierten Produkten des Polystyroles
DE3006448A1 (de) * 1980-02-21 1981-08-27 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von mischungen aus bromierten polystyrolen und bromierten aromatischen verbindungen
US4352909A (en) * 1980-08-20 1982-10-05 Ferro Corporation Process for the bromination of polystyrenes
US4389517A (en) * 1982-04-02 1983-06-21 The Dow Chemical Company Hydrogenation of phenylacetylene prior to styrene polymerization
US4554326A (en) * 1983-04-01 1985-11-19 Exxon Research & Engineering Co. Process for the manufacture of halogenated polymers
US4513116A (en) * 1983-04-01 1985-04-23 Exxon Research And Engineering Co. Process for the manufacture of halogenated polymers
US4501859A (en) * 1983-04-01 1985-02-26 Exxon Research & Engineering Co. Process for the manufacture of halogenated polymers
US4548995A (en) * 1983-04-01 1985-10-22 Exxon Research & Engineering Co. Process for the manufacture of halogenated polymers
JPS6060161A (ja) 1983-08-08 1985-04-06 ザ ダウ ケミカル カンパニ− 重合体の処理中に放出されたハロゲンおよび酸の中和方法
EP0150332A3 (en) * 1983-12-26 1987-08-19 Mitsubishi Kasei Corporation Process for producing a chloromethylated polymer
JPS6134723A (ja) * 1984-07-26 1986-02-19 Teijin Ltd 磁気記録媒体及びその製造法
US4650832A (en) * 1984-09-17 1987-03-17 Exxon Research & Engineering Co. Process for the manufacture of halogenated polymers
EP0201411A3 (en) * 1985-05-03 1989-02-08 The Dow Chemical Company Brominated polymers of alkenyl aromatic compounds
IL79499A0 (en) 1986-07-23 1986-10-31 Yeda Res & Dev Production of crystalline tribromostyrene
JP2543510B2 (ja) 1986-12-12 1996-10-16 三菱瓦斯化学株式会社 難燃性ポリアミド樹脂組成物
EP0277429B1 (en) * 1987-01-28 1992-06-10 Great Lakes Chemical Corporation Aromatic bromination of polystyrene using bromine as the reaction solvent
US4879353A (en) * 1987-01-28 1989-11-07 Great Lakes Chemical Corporation Bromination of polystyrene using bromine as the reaction solvent
US4835222A (en) * 1987-02-19 1989-05-30 The Dow Chemical Company Alkylation of vinyl aromatic polymer
US4832873A (en) * 1987-10-09 1989-05-23 Great Lakes Chemical Corporation Process for producing polybrominated higher alkylbenzenes
JPH02215807A (ja) * 1989-02-17 1990-08-28 Nippon Kayaku Co Ltd 臭素化ポリスチレンの製造方法
NL8901054A (nl) 1989-04-27 1990-11-16 Gen Electric Polymeermengsel met polyester, glasvezels, vlamvertragend middel en vulmiddel; daaruit gevormde voorwerpen.
US5112898A (en) * 1989-06-06 1992-05-12 Ferro Corporation High impact polystyrene containing low molecular weight brominated polystyrene
US5112896A (en) * 1989-06-06 1992-05-12 Ferro Corporation High-impact polystyrene containing low molecular weight brominated polystyrene
US5112897A (en) * 1989-06-06 1992-05-12 Ferro Corporation High impact polystyrene containing low molecular weight brominated polystyrene
US4975496A (en) * 1989-08-10 1990-12-04 The Dow Chemical Company Process for brominating aromatic resins
WO1991013915A1 (en) 1990-03-16 1991-09-19 Great Lakes Chemical Corporation Process for purifying brominated polystyrene
US5194482A (en) * 1990-08-23 1993-03-16 Ferro Corporation Flame retardant resin composition containing styrenic polymers
US5235000A (en) * 1990-12-10 1993-08-10 Ethyl Corporation Preparation, storage, and usage of bromine chloride
IL99130A (en) 1991-08-08 1998-04-05 Bromine Compounds Ltd Preparation of tribromo (B) bromoethyl (benzene in a high degree of purity)
JPH05170809A (ja) * 1991-12-24 1993-07-09 Tosoh Corp 塩素化ポリオレフィンの製造法
JP2718851B2 (ja) 1992-04-07 1998-02-25 帝人化成株式会社 ブロモ化スチレンの乳化重合法
US5326837A (en) * 1992-11-20 1994-07-05 Mobil Oil Corporation Catalyst systems for syndiospecific polymerization of styrenes
JP3359695B2 (ja) 1993-05-14 2002-12-24 帝人化成株式会社 ポリスチレン臭素化反応溶液の精製方法
JP3359698B2 (ja) 1993-06-15 2002-12-24 帝人化成株式会社 臭素化ポリスチレンの製造方法
US5304618A (en) * 1993-07-22 1994-04-19 Great Lakes Chemical Corporation Polymers of brominated styrene
JP3471086B2 (ja) * 1994-08-12 2003-11-25 帝人化成株式会社 臭素化ポリスチレンの製造方法
WO1996028512A1 (en) 1995-03-10 1996-09-19 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Flame-retardant polyethylene terephthalate resin compositions
JPH0977937A (ja) 1995-09-12 1997-03-25 Idemitsu Petrochem Co Ltd プリント配線板用プリプレグ及びプリント配線用基板
US5532322B1 (en) * 1995-09-26 1999-12-07 Manac Inc Process for preparing brominated polystyrene
US5637650A (en) 1996-06-14 1997-06-10 Ferro Corporation Brominated polysytrene having improved thermal stability and color and process for the preparation thereof
US5723549A (en) 1996-06-14 1998-03-03 Ferro Corporation Process for the preparation of brominated polystyrene having improved color characteristics
US5686538A (en) 1996-09-26 1997-11-11 Albemarle Corporation Process for brominating polystyrenic resins
US5767203A (en) 1996-09-26 1998-06-16 Albemarle Corporation Process for brominated styrenic polymers
US5677390A (en) 1996-09-26 1997-10-14 Albemarle Corporation Process for brominating polystyrenic resins
CA2265642C (en) 1996-09-26 2006-03-14 Albemarle Corporation Process for brominated styrenic polymers
JPH10130325A (ja) 1996-10-31 1998-05-19 Teijin Chem Ltd ハロゲン化されたスチレン重合物の製法

Also Published As

Publication number Publication date
US6207765B1 (en) 2001-03-27
WO1998013396A1 (en) 1998-04-02
IL129113A0 (en) 2000-02-17
US5916978A (en) 1999-06-29
EP0928300B1 (en) 2000-05-10
CA2265642A1 (en) 1998-04-02
DE69701997T2 (de) 2000-11-09
EP0928300A1 (en) 1999-07-14
DE69701997D1 (de) 2000-06-15
IL129113A (en) 2002-08-14
JP2001501237A (ja) 2001-01-30
CA2265642C (en) 2006-03-14

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