DE69701997T2 - Verfahren zur bromierung von styrolpolymeren - Google Patents

Verfahren zur bromierung von styrolpolymeren

Info

Publication number
DE69701997T2
DE69701997T2 DE69701997T DE69701997T DE69701997T2 DE 69701997 T2 DE69701997 T2 DE 69701997T2 DE 69701997 T DE69701997 T DE 69701997T DE 69701997 T DE69701997 T DE 69701997T DE 69701997 T2 DE69701997 T2 DE 69701997T2
Authority
DE
Germany
Prior art keywords
browning
styrene polymers
styrene
polymers
browning styrene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69701997T
Other languages
English (en)
Other versions
DE69701997D1 (de
Inventor
Meng-Sheng Ao
B Dadgar
H Kolich
E Balhoff
C Lin
R Brackenridge
W Brockmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Albemarle Corp
Original Assignee
Albemarle Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/846,156 external-priority patent/US5767203A/en
Application filed by Albemarle Corp filed Critical Albemarle Corp
Application granted granted Critical
Publication of DE69701997D1 publication Critical patent/DE69701997D1/de
Publication of DE69701997T2 publication Critical patent/DE69701997T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/18Introducing halogen atoms or halogen-containing groups
    • C08F8/20Halogenation

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE69701997T 1996-09-26 1997-09-05 Verfahren zur bromierung von styrolpolymeren Expired - Lifetime DE69701997T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US72138996A 1996-09-26 1996-09-26
US08/846,156 US5767203A (en) 1996-09-26 1997-04-25 Process for brominated styrenic polymers
PCT/US1997/015622 WO1998013396A1 (en) 1996-09-26 1997-09-05 Process for brominated styrenic polymers

Publications (2)

Publication Number Publication Date
DE69701997D1 DE69701997D1 (de) 2000-06-15
DE69701997T2 true DE69701997T2 (de) 2000-11-09

Family

ID=27110422

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69701997T Expired - Lifetime DE69701997T2 (de) 1996-09-26 1997-09-05 Verfahren zur bromierung von styrolpolymeren

Country Status (7)

Country Link
US (2) US5916978A (de)
EP (1) EP0928300B1 (de)
JP (1) JP4328388B2 (de)
CA (1) CA2265642C (de)
DE (1) DE69701997T2 (de)
IL (1) IL129113A (de)
WO (1) WO1998013396A1 (de)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6518368B2 (en) 1996-06-14 2003-02-11 Albemarle Corporation Brominated polystyrene having improved thermal stability and color and process for the preparation thereof
US5637650A (en) 1996-06-14 1997-06-10 Ferro Corporation Brominated polysytrene having improved thermal stability and color and process for the preparation thereof
US6521714B2 (en) * 1996-09-26 2003-02-18 Albemarle Corporation Brominated polystyrenic resins
US6232393B1 (en) 1996-09-26 2001-05-15 Albemarle Corporation Polymers flame retarded with brominated polystyrenic resins
EP0928300B1 (de) 1996-09-26 2000-05-10 Albemarle Corporation Verfahren zur bromierung von styrolpolymeren
US6235831B1 (en) 1996-09-26 2001-05-22 Albemarle Corporation Polymer compositions containing brominated polystyrenic resins
US6326439B1 (en) 1996-09-26 2001-12-04 Albemarle Corporation Process for brominating polystyrenic resins
US6232408B1 (en) 1996-09-26 2001-05-15 Albemarle Corporation Brominated polstyrenic resins
EP1293518B1 (de) * 1997-05-07 2014-12-24 Albemarle Corporation Verfahren zur Bromierung von Polystyrolharzen
EP1115756A1 (de) * 1998-09-10 2001-07-18 Albemarle Corporation Verbesserte bromierte polystyrolharze und ihre verwendung
US6333385B1 (en) 1999-11-15 2001-12-25 Marquette University Method to produce flame retardant styrenic polymers and product produced thereby
CN100448821C (zh) * 2001-12-21 2009-01-07 帕布服务公司 生产十溴二苯基烷烃的方法与装置
US20040072929A1 (en) * 2002-06-27 2004-04-15 De Schryver Daniel A. Flame retardant compositions
US6657028B1 (en) 2002-08-01 2003-12-02 Albemarle Corporation Anionic polymerization process
US20050159552A1 (en) * 2004-01-21 2005-07-21 Reed Jon S. Flame retarded fibers and filaments and process of production therefor
US7666944B2 (en) * 2004-01-21 2010-02-23 Albemarle Corporation Flame retarded fibers and filaments and process of production therefor
EP1747089A1 (de) 2004-05-20 2007-01-31 Albemarle Corporation Granulierte bromierte anionische styrolpolymere und ihre herstellung und verwendung
ES2612575T3 (es) 2005-06-30 2017-05-17 Albemarle Corporation Polímeros estirénicos bromados y su preparación
KR101353883B1 (ko) * 2005-12-21 2014-02-18 알베마를 코포레이션 브롬화 음이온성 스티렌계 중합체 및 이의 제조
ES2351618T3 (es) * 2005-12-21 2011-02-08 Albemarle Corporation Preparación de polímeros o resinas estirénicas bromadas.
EP2650093B1 (de) 2006-07-20 2015-03-04 Albemarle Corporation Verfahrenstechnik zur Rückgewinnung bromierter Styrolpolymere aus Reaktionsmischungen, in denen sie gebildet werden, und/oder Umwandlung derartiger Mischungen in Tabletten oder Granulat oder Pastillen
TW200817447A (en) * 2006-08-22 2008-04-16 Albemarle Corp Terminating bromination of styrenic polymer in a bromination reaction mixture
MX2009005458A (es) * 2006-11-28 2009-06-01 Albemarle Corp Conversion de polimero estirenico anionico bromado en forma mas dura y larga para almacenamiento, envio y uso.
JP5543338B2 (ja) 2007-06-07 2014-07-09 アルベマール・コーポレーシヨン 付加物、または付加物とオリゴマー、または付加物とオリゴマーと低分子量ポリマー、ならびにそれらの調製
US8993684B2 (en) * 2008-06-06 2015-03-31 Albemarle Corporation Low molecular weight brominated polymers, processes for their manufacture and their use in thermoplastic formulations
EP2288628B1 (de) 2008-06-06 2018-12-19 Albemarle Corporation Niedermolekulare bromierte polymere, verfahren zu ihrer herstellung und ihre verwendung in thermoplastischen formulierungen
CN102272176A (zh) * 2008-12-02 2011-12-07 雅宝公司 支化和星形支化的苯乙烯聚合物、调聚物和加合物,其合成、其溴化及其用途
EP2373697A1 (de) * 2008-12-02 2011-10-12 Albemarle Corporation Bromierung von aus toluol und styrol gewonnenen telomergemischen
JO3423B1 (ar) * 2008-12-02 2019-10-20 Albemarle Corp مؤخرات لهب معالجة بالبروم و مواد مشتقه منها
KR20110110096A (ko) * 2008-12-02 2011-10-06 알베마를 코포레이션 톨루엔 및 스티렌 유도 텔로머 분포물 및 이로부터 생성되는 브롬화된 난연제
JO3059B1 (ar) 2009-05-01 2017-03-15 Albemarle Corp معالجة بالبروم لتراكيب بوليمرات عطرية ذات وزن جزيئي منخفض
CN102439080A (zh) 2009-05-01 2012-05-02 阿尔比马尔公司 粒状低分子量溴化芳族聚合物组合物
CN117247482B (zh) * 2023-11-17 2024-02-20 山东旭锐新材股份有限公司 一种高热稳定性溴化聚苯乙烯合成方法

Family Cites Families (67)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1890772A (en) * 1930-01-28 1932-12-13 Du Pont Chlorination of meta styrene
US2199026A (en) * 1937-04-01 1940-04-30 Du Pont Chlorinated aromatic resins
US2823201A (en) * 1952-03-10 1958-02-11 Dow Chemical Co Halogenated polymers of nuclear methylated aromatic hydrocarbons, their quaternary ammonium salts and method of making the same
US3009906A (en) * 1957-05-09 1961-11-21 Dow Chemical Co Halogenation of solid resinous polymers of alkenylaromatic compounds with gaseous halogens
US3050476A (en) * 1958-12-08 1962-08-21 Koppers Co Inc Method of making a self extinguishing expandable polymer of styrene by bromination
US3039977A (en) * 1959-12-03 1962-06-19 Koppers Co Inc Method of producing self-extinguishing foamable polystyrene by brominating foamable polystyrene in aqueous suspension
US3132045A (en) * 1961-10-26 1964-05-05 Dow Chemical Co Method of impregnating film materials with ammonium bromide
NL128916C (de) * 1965-02-18 1900-01-01
US3506741A (en) * 1966-01-10 1970-04-14 Phillips Petroleum Co Halogenated polymers and block copolymers produced therefrom
US3534012A (en) * 1969-05-01 1970-10-13 Dow Chemical Co Anionic polymerization of nuclear halogenated styrenes
CH584731A5 (de) * 1973-12-17 1977-02-15 Ciba Geigy Ag
US3959398A (en) * 1974-06-03 1976-05-25 The Goodyear Tire & Rubber Company Alpha-methyl-p-bromo-styrene and method of preparation
US4028486A (en) * 1974-06-03 1977-06-07 The Goodyear Tire & Rubber Company Alpha-methyl-p-bromo-styrene and method of preparation
US3932542A (en) * 1974-08-26 1976-01-13 Great Lakes Chemical Corporation Process for preparation of 2,5-dibromo-p-xylene
US4178327A (en) * 1974-12-19 1979-12-11 The Dow Chemical Company Ar-halo-ar(t-alkyl)styrenes and polymers thereof
DE2515473B2 (de) 1975-04-09 1978-11-23 Basf Ag, 6700 Ludwigshafen Flaminwidrige, lineare Polyester
CA1054161A (en) * 1975-08-22 1979-05-08 Herbert Naarmann Manufacture of heat-stable brominated oligomers of monovinyl-aromatic compounds
DE2645711C3 (de) * 1976-10-09 1979-06-07 Basf Ag, 6700 Ludwigshafen Halogenhaltige Flammschutzmittel enthaltende Fasern und Fäden aus linearen, thermoplastischen Polyestern
DE2651435C3 (de) * 1976-11-11 1980-11-27 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von bromierten Polymerisationsprodukten des Styrols
DE2703419B1 (de) * 1977-01-28 1978-02-02 Basf Ag Flammwidrig ausgeruestete polyamid- formmassen
FR2413409A1 (fr) * 1978-01-02 1979-07-27 Huels Chemische Werke Ag Procede pour preparer des polystyrenes resistant a la chaleur, bromes sur le noyau
EP0020294B1 (de) * 1979-05-07 1982-11-10 Ciba-Geigy Ag Verfahren zur Herstellung von bromierten Produkten des Polystyroles
DE3006448A1 (de) * 1980-02-21 1981-08-27 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von mischungen aus bromierten polystyrolen und bromierten aromatischen verbindungen
US4352909A (en) * 1980-08-20 1982-10-05 Ferro Corporation Process for the bromination of polystyrenes
US4389517A (en) * 1982-04-02 1983-06-21 The Dow Chemical Company Hydrogenation of phenylacetylene prior to styrene polymerization
US4513116A (en) * 1983-04-01 1985-04-23 Exxon Research And Engineering Co. Process for the manufacture of halogenated polymers
US4548995A (en) * 1983-04-01 1985-10-22 Exxon Research & Engineering Co. Process for the manufacture of halogenated polymers
US4554326A (en) * 1983-04-01 1985-11-19 Exxon Research & Engineering Co. Process for the manufacture of halogenated polymers
US4501859A (en) * 1983-04-01 1985-02-26 Exxon Research & Engineering Co. Process for the manufacture of halogenated polymers
JPS6060161A (ja) 1983-08-08 1985-04-06 ザ ダウ ケミカル カンパニ− 重合体の処理中に放出されたハロゲンおよび酸の中和方法
EP0150332A3 (de) * 1983-12-26 1987-08-19 Mitsubishi Kasei Corporation Verfahren zur Herstellung von chlormethylierten Polymerisaten
JPS6134723A (ja) * 1984-07-26 1986-02-19 Teijin Ltd 磁気記録媒体及びその製造法
US4650832A (en) * 1984-09-17 1987-03-17 Exxon Research & Engineering Co. Process for the manufacture of halogenated polymers
EP0201411A3 (de) * 1985-05-03 1989-02-08 The Dow Chemical Company Bromierte Polymere aus alkenylaromatischen Verbindungen
IL79499A0 (en) 1986-07-23 1986-10-31 Yeda Res & Dev Production of crystalline tribromostyrene
JP2543510B2 (ja) 1986-12-12 1996-10-16 三菱瓦斯化学株式会社 難燃性ポリアミド樹脂組成物
EP0277429B1 (de) * 1987-01-28 1992-06-10 Great Lakes Chemical Corporation Aromatische Bromierung von Polystyrol mit einer Bromverbindung als Reaktionslösungsmittel
US4879353A (en) * 1987-01-28 1989-11-07 Great Lakes Chemical Corporation Bromination of polystyrene using bromine as the reaction solvent
US4835222A (en) * 1987-02-19 1989-05-30 The Dow Chemical Company Alkylation of vinyl aromatic polymer
US4832873A (en) * 1987-10-09 1989-05-23 Great Lakes Chemical Corporation Process for producing polybrominated higher alkylbenzenes
JPH02215807A (ja) * 1989-02-17 1990-08-28 Nippon Kayaku Co Ltd 臭素化ポリスチレンの製造方法
NL8901054A (nl) 1989-04-27 1990-11-16 Gen Electric Polymeermengsel met polyester, glasvezels, vlamvertragend middel en vulmiddel; daaruit gevormde voorwerpen.
US5112896A (en) * 1989-06-06 1992-05-12 Ferro Corporation High-impact polystyrene containing low molecular weight brominated polystyrene
US5112898A (en) * 1989-06-06 1992-05-12 Ferro Corporation High impact polystyrene containing low molecular weight brominated polystyrene
US5112897A (en) * 1989-06-06 1992-05-12 Ferro Corporation High impact polystyrene containing low molecular weight brominated polystyrene
US4975496A (en) * 1989-08-10 1990-12-04 The Dow Chemical Company Process for brominating aromatic resins
EP0520007B1 (de) 1990-03-16 1998-06-03 Great Lakes Chemical Corporation Verfahren zur reinigung von bromiertem polystyrol
US5194482A (en) * 1990-08-23 1993-03-16 Ferro Corporation Flame retardant resin composition containing styrenic polymers
US5235000A (en) * 1990-12-10 1993-08-10 Ethyl Corporation Preparation, storage, and usage of bromine chloride
IL99130A (en) 1991-08-08 1998-04-05 Bromine Compounds Ltd Preparation of tribromo (B) bromoethyl (benzene in a high degree of purity)
JPH05170809A (ja) * 1991-12-24 1993-07-09 Tosoh Corp 塩素化ポリオレフィンの製造法
JP2718851B2 (ja) 1992-04-07 1998-02-25 帝人化成株式会社 ブロモ化スチレンの乳化重合法
US5326837A (en) * 1992-11-20 1994-07-05 Mobil Oil Corporation Catalyst systems for syndiospecific polymerization of styrenes
JP3359695B2 (ja) 1993-05-14 2002-12-24 帝人化成株式会社 ポリスチレン臭素化反応溶液の精製方法
JP3359698B2 (ja) 1993-06-15 2002-12-24 帝人化成株式会社 臭素化ポリスチレンの製造方法
US5304618A (en) * 1993-07-22 1994-04-19 Great Lakes Chemical Corporation Polymers of brominated styrene
JP3471086B2 (ja) * 1994-08-12 2003-11-25 帝人化成株式会社 臭素化ポリスチレンの製造方法
CA2189325A1 (en) 1995-03-10 1996-09-19 Youichi Ohara Flame-retardant polyethylene terephthalate resin compositions
JPH0977937A (ja) 1995-09-12 1997-03-25 Idemitsu Petrochem Co Ltd プリント配線板用プリプレグ及びプリント配線用基板
US5532322B1 (en) * 1995-09-26 1999-12-07 Manac Inc Process for preparing brominated polystyrene
US5723549A (en) 1996-06-14 1998-03-03 Ferro Corporation Process for the preparation of brominated polystyrene having improved color characteristics
US5637650A (en) * 1996-06-14 1997-06-10 Ferro Corporation Brominated polysytrene having improved thermal stability and color and process for the preparation thereof
EP0928300B1 (de) 1996-09-26 2000-05-10 Albemarle Corporation Verfahren zur bromierung von styrolpolymeren
US5686538A (en) 1996-09-26 1997-11-11 Albemarle Corporation Process for brominating polystyrenic resins
US5677390A (en) 1996-09-26 1997-10-14 Albemarle Corporation Process for brominating polystyrenic resins
US5767203A (en) 1996-09-26 1998-06-16 Albemarle Corporation Process for brominated styrenic polymers
JPH10130325A (ja) 1996-10-31 1998-05-19 Teijin Chem Ltd ハロゲン化されたスチレン重合物の製法

Also Published As

Publication number Publication date
EP0928300B1 (de) 2000-05-10
US6207765B1 (en) 2001-03-27
WO1998013396A1 (en) 1998-04-02
US5916978A (en) 1999-06-29
CA2265642A1 (en) 1998-04-02
EP0928300A1 (de) 1999-07-14
JP2001501237A (ja) 2001-01-30
IL129113A0 (en) 2000-02-17
IL129113A (en) 2002-08-14
JP4328388B2 (ja) 2009-09-09
DE69701997D1 (de) 2000-06-15
CA2265642C (en) 2006-03-14

Similar Documents

Publication Publication Date Title
DE69701997D1 (de) Verfahren zur bromierung von styrolpolymeren
DE69701996T2 (de) Verfahren zur bromierung von polystyrolharzen
DE69701995D1 (de) Verfahren zur bromierung von polystyrolharzen
DE69709061D1 (de) Verfahren zur umsetzung von ethylbenzol
DE69715424D1 (de) Verfahren zur halogenierung von isoolefin-para-alkylstyrol-copolymeren
DE69709648T2 (de) Verfahren zur halogenierung von isoolefincopolymeren
DE59707512D1 (de) Verfahren zur anionischen polymerisation
DE69707709T2 (de) Verfahren zur umwandlung von kohlenwasserstoffen
DE59704798D1 (de) Verfahren zur herstellung von prägeplatten
DE69603255T2 (de) Verfahren zur modifizierung von oberflächen
DE69725000D1 (de) Verfahren zur druckformung von gegenständen
DE69727395D1 (de) Verfahren zur olefinisomerisierung
DE69518550D1 (de) Verfahren zur bereitung von kohlenwasserstoffe
DE69624729D1 (de) Verfahren zur selektiven öffnung von naphtalinringen
DE69719722T2 (de) Verfahren zur identifizierung von beweglichen objekten
DE69630686D1 (de) Verfahren zur echtheitsprüfung von münzen
DE69515241T2 (de) Verfahren zur Emulsions-Polymerisation
DE69529343T2 (de) Verfahren zur isolierung von mesophasepech
DE69624494T2 (de) Verfahren zur polymerisation von tetrafluorethylen
ATE206392T1 (de) Verfahren zur alkylierug von gehinderten sulfonamiden
DE912476T1 (de) Verfahren zur abtrennung von difluormethan
DE69605269T2 (de) Verfahren zur herstellung von styrolpolymer
DE59701942D1 (de) Verfahren zur herstellung von hydrophob-hydrophilen ab-blockcopolymeren
DE69706177D1 (de) Verfahren zur gewinnung von oryzanol
DE69614477D1 (de) Verfahren zur acyclierung von aromatischen ethern