DE69701995D1 - Verfahren zur bromierung von polystyrolharzen - Google Patents
Verfahren zur bromierung von polystyrolharzenInfo
- Publication number
- DE69701995D1 DE69701995D1 DE69701995T DE69701995T DE69701995D1 DE 69701995 D1 DE69701995 D1 DE 69701995D1 DE 69701995 T DE69701995 T DE 69701995T DE 69701995 T DE69701995 T DE 69701995T DE 69701995 D1 DE69701995 D1 DE 69701995D1
- Authority
- DE
- Germany
- Prior art keywords
- browning
- polystyrene resins
- polystyrene
- resins
- browning polystyrene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/18—Introducing halogen atoms or halogen-containing groups
- C08F8/20—Halogenation
- C08F8/22—Halogenation by reaction with free halogens
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/721,398 US5686538A (en) | 1996-09-26 | 1996-09-26 | Process for brominating polystyrenic resins |
PCT/US1997/015615 WO1998013395A1 (en) | 1996-09-26 | 1997-09-05 | Process for brominating polystyrenic resins |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69701995D1 true DE69701995D1 (de) | 2000-06-15 |
DE69701995T2 DE69701995T2 (de) | 2000-11-09 |
Family
ID=24897828
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69701995T Expired - Lifetime DE69701995T2 (de) | 1996-09-26 | 1997-09-05 | Verfahren zur bromierung von polystyrolharzen |
Country Status (7)
Country | Link |
---|---|
US (2) | US5686538A (de) |
EP (1) | EP0928298B1 (de) |
JP (2) | JP2001501236A (de) |
CA (1) | CA2265646C (de) |
DE (1) | DE69701995T2 (de) |
IL (1) | IL129114A (de) |
WO (1) | WO1998013395A1 (de) |
Families Citing this family (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6518368B2 (en) | 1996-06-14 | 2003-02-11 | Albemarle Corporation | Brominated polystyrene having improved thermal stability and color and process for the preparation thereof |
US5637650A (en) | 1996-06-14 | 1997-06-10 | Ferro Corporation | Brominated polysytrene having improved thermal stability and color and process for the preparation thereof |
US6235844B1 (en) | 1996-09-26 | 2001-05-22 | Albemarle Corporation | Brominated polystyrenic resins |
US6232408B1 (en) | 1996-09-26 | 2001-05-15 | Albemarle Corporation | Brominated polstyrenic resins |
US6521714B2 (en) | 1996-09-26 | 2003-02-18 | Albemarle Corporation | Brominated polystyrenic resins |
US6232393B1 (en) | 1996-09-26 | 2001-05-15 | Albemarle Corporation | Polymers flame retarded with brominated polystyrenic resins |
US6235831B1 (en) | 1996-09-26 | 2001-05-22 | Albemarle Corporation | Polymer compositions containing brominated polystyrenic resins |
DE69701997T2 (de) | 1996-09-26 | 2000-11-09 | Albemarle Corp | Verfahren zur bromierung von styrolpolymeren |
US6133381A (en) * | 1996-09-26 | 2000-10-17 | Albelmarle Corporation | Brominated polystyrenic flame retardants |
US6326439B1 (en) | 1996-09-26 | 2001-12-04 | Albemarle Corporation | Process for brominating polystyrenic resins |
US6146555A (en) * | 1998-01-19 | 2000-11-14 | Ferro Corporation | Brominated copolymer flame retardant additives having improved color characteristics and related method |
IL141905A0 (en) * | 1998-09-10 | 2002-03-10 | Albemarle Corp | Improved brominated polystyrenic resins, and their use |
DE60235833D1 (de) | 2001-12-21 | 2010-05-12 | Chemtura Corp | Verfahren und vorrichtung zur herstellung von decabromdiphenylalkanen |
US6657028B1 (en) | 2002-08-01 | 2003-12-02 | Albemarle Corporation | Anionic polymerization process |
US7666944B2 (en) * | 2004-01-21 | 2010-02-23 | Albemarle Corporation | Flame retarded fibers and filaments and process of production therefor |
US20050159552A1 (en) * | 2004-01-21 | 2005-07-21 | Reed Jon S. | Flame retarded fibers and filaments and process of production therefor |
KR101185755B1 (ko) * | 2004-05-20 | 2012-09-27 | 알베마를 코포레이션 | 펠렛화된 브롬화 음이온성 스티렌계 중합체 및 그의 제조 및 용도 |
HUE031115T2 (en) * | 2005-06-30 | 2017-06-28 | Albemarle Corp | Brominated styrene polymers and their preparation |
US7638583B2 (en) * | 2005-12-21 | 2009-12-29 | Albemarle Corporation | Brominated anionic styrenic polymers and their preparation |
ES2351618T3 (es) * | 2005-12-21 | 2011-02-08 | Albemarle Corporation | Preparación de polímeros o resinas estirénicas bromadas. |
JP5591536B2 (ja) * | 2006-07-20 | 2014-09-17 | アルベマール・コーポレーシヨン | 臭素化されたスチレン系重合体をそれらが中で生成される反応混合物から回収しおよび/またはそのような混合物をペレットまたは顆粒もしくは小球に転化させるための工程技術 |
TW200817447A (en) | 2006-08-22 | 2008-04-16 | Albemarle Corp | Terminating bromination of styrenic polymer in a bromination reaction mixture |
US20100047577A1 (en) * | 2006-11-28 | 2010-02-25 | Albemarle Corporation | Converting Brominated Anionic Styrenic Polymer Into Harder and Larger Form for Storage, Shipment, and Use |
PL2158233T3 (pl) * | 2007-06-07 | 2019-04-30 | Albemarle Corp | Addukty, addukty i oligomery lub addukty, oligomery i polimery o małym ciężarze cząsteczkowym oraz ich wytwarzanie |
US8993684B2 (en) * | 2008-06-06 | 2015-03-31 | Albemarle Corporation | Low molecular weight brominated polymers, processes for their manufacture and their use in thermoplastic formulations |
CA2740945C (en) | 2008-06-06 | 2017-07-11 | Albemarle Corporation | Low molecular weight brominated polymers, processes for their manufacture and their use in thermoplastic formulations |
CN102232089B (zh) * | 2008-12-02 | 2013-11-13 | 雅宝公司 | 衍生自甲苯和苯乙烯的调聚物混合物的溴化 |
JO3423B1 (ar) * | 2008-12-02 | 2019-10-20 | Albemarle Corp | مؤخرات لهب معالجة بالبروم و مواد مشتقه منها |
EP2361269A1 (de) * | 2008-12-02 | 2011-08-31 | Albemarle Corporation | Verzweigte und sternverzweigte styrolpolymere, telomere und addukte, ihre synthese, bromierung und verwendung |
KR20110110096A (ko) * | 2008-12-02 | 2011-10-06 | 알베마를 코포레이션 | 톨루엔 및 스티렌 유도 텔로머 분포물 및 이로부터 생성되는 브롬화된 난연제 |
PL2424930T3 (pl) | 2009-05-01 | 2014-01-31 | Albemarle Corp | Kompozycje bromowanych polimerów aromatycznych o niskim ciężarze cząsteczkowym w postaci peletek |
JO3059B1 (ar) | 2009-05-01 | 2017-03-15 | Albemarle Corp | معالجة بالبروم لتراكيب بوليمرات عطرية ذات وزن جزيئي منخفض |
CN117106109B (zh) * | 2023-10-25 | 2024-06-04 | 山东海化集团有限公司 | 一种连续化制备溴化聚苯乙烯的方法 |
Family Cites Families (47)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1890772A (en) * | 1930-01-28 | 1932-12-13 | Du Pont | Chlorination of meta styrene |
US2199026A (en) * | 1937-04-01 | 1940-04-30 | Du Pont | Chlorinated aromatic resins |
US2823201A (en) * | 1952-03-10 | 1958-02-11 | Dow Chemical Co | Halogenated polymers of nuclear methylated aromatic hydrocarbons, their quaternary ammonium salts and method of making the same |
US3009906A (en) * | 1957-05-09 | 1961-11-21 | Dow Chemical Co | Halogenation of solid resinous polymers of alkenylaromatic compounds with gaseous halogens |
US3050476A (en) * | 1958-12-08 | 1962-08-21 | Koppers Co Inc | Method of making a self extinguishing expandable polymer of styrene by bromination |
US3039977A (en) * | 1959-12-03 | 1962-06-19 | Koppers Co Inc | Method of producing self-extinguishing foamable polystyrene by brominating foamable polystyrene in aqueous suspension |
US3132045A (en) * | 1961-10-26 | 1964-05-05 | Dow Chemical Co | Method of impregnating film materials with ammonium bromide |
NL128916C (de) * | 1965-02-18 | 1900-01-01 | ||
US3506741A (en) * | 1966-01-10 | 1970-04-14 | Phillips Petroleum Co | Halogenated polymers and block copolymers produced therefrom |
US3534012A (en) * | 1969-05-01 | 1970-10-13 | Dow Chemical Co | Anionic polymerization of nuclear halogenated styrenes |
CH584731A5 (de) * | 1973-12-17 | 1977-02-15 | Ciba Geigy Ag | |
US4028486A (en) * | 1974-06-03 | 1977-06-07 | The Goodyear Tire & Rubber Company | Alpha-methyl-p-bromo-styrene and method of preparation |
US3959398A (en) * | 1974-06-03 | 1976-05-25 | The Goodyear Tire & Rubber Company | Alpha-methyl-p-bromo-styrene and method of preparation |
US3932542A (en) * | 1974-08-26 | 1976-01-13 | Great Lakes Chemical Corporation | Process for preparation of 2,5-dibromo-p-xylene |
US4178327A (en) * | 1974-12-19 | 1979-12-11 | The Dow Chemical Company | Ar-halo-ar(t-alkyl)styrenes and polymers thereof |
CA1054161A (en) * | 1975-08-22 | 1979-05-08 | Herbert Naarmann | Manufacture of heat-stable brominated oligomers of monovinyl-aromatic compounds |
DE2645711C3 (de) * | 1976-10-09 | 1979-06-07 | Basf Ag, 6700 Ludwigshafen | Halogenhaltige Flammschutzmittel enthaltende Fasern und Fäden aus linearen, thermoplastischen Polyestern |
DE2651435C3 (de) * | 1976-11-11 | 1980-11-27 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von bromierten Polymerisationsprodukten des Styrols |
DE2703419B1 (de) * | 1977-01-28 | 1978-02-02 | Basf Ag | Flammwidrig ausgeruestete polyamid- formmassen |
FR2413409A1 (fr) * | 1978-01-02 | 1979-07-27 | Huels Chemische Werke Ag | Procede pour preparer des polystyrenes resistant a la chaleur, bromes sur le noyau |
DE3006448A1 (de) * | 1980-02-21 | 1981-08-27 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von mischungen aus bromierten polystyrolen und bromierten aromatischen verbindungen |
US4352909A (en) * | 1980-08-20 | 1982-10-05 | Ferro Corporation | Process for the bromination of polystyrenes |
US4389517A (en) * | 1982-04-02 | 1983-06-21 | The Dow Chemical Company | Hydrogenation of phenylacetylene prior to styrene polymerization |
US4554326A (en) * | 1983-04-01 | 1985-11-19 | Exxon Research & Engineering Co. | Process for the manufacture of halogenated polymers |
US4548995A (en) * | 1983-04-01 | 1985-10-22 | Exxon Research & Engineering Co. | Process for the manufacture of halogenated polymers |
US4513116A (en) * | 1983-04-01 | 1985-04-23 | Exxon Research And Engineering Co. | Process for the manufacture of halogenated polymers |
US4501859A (en) * | 1983-04-01 | 1985-02-26 | Exxon Research & Engineering Co. | Process for the manufacture of halogenated polymers |
EP0150332A3 (de) * | 1983-12-26 | 1987-08-19 | Mitsubishi Kasei Corporation | Verfahren zur Herstellung von chlormethylierten Polymerisaten |
JPS6134723A (ja) * | 1984-07-26 | 1986-02-19 | Teijin Ltd | 磁気記録媒体及びその製造法 |
US4650832A (en) * | 1984-09-17 | 1987-03-17 | Exxon Research & Engineering Co. | Process for the manufacture of halogenated polymers |
EP0201411A3 (de) * | 1985-05-03 | 1989-02-08 | The Dow Chemical Company | Bromierte Polymere aus alkenylaromatischen Verbindungen |
US4879353A (en) * | 1987-01-28 | 1989-11-07 | Great Lakes Chemical Corporation | Bromination of polystyrene using bromine as the reaction solvent |
US4835222A (en) * | 1987-02-19 | 1989-05-30 | The Dow Chemical Company | Alkylation of vinyl aromatic polymer |
US4832873A (en) * | 1987-10-09 | 1989-05-23 | Great Lakes Chemical Corporation | Process for producing polybrominated higher alkylbenzenes |
JPH02215807A (ja) * | 1989-02-17 | 1990-08-28 | Nippon Kayaku Co Ltd | 臭素化ポリスチレンの製造方法 |
US5112897A (en) * | 1989-06-06 | 1992-05-12 | Ferro Corporation | High impact polystyrene containing low molecular weight brominated polystyrene |
US5112898A (en) * | 1989-06-06 | 1992-05-12 | Ferro Corporation | High impact polystyrene containing low molecular weight brominated polystyrene |
US5112896A (en) * | 1989-06-06 | 1992-05-12 | Ferro Corporation | High-impact polystyrene containing low molecular weight brominated polystyrene |
US4975496A (en) * | 1989-08-10 | 1990-12-04 | The Dow Chemical Company | Process for brominating aromatic resins |
DE69129533T2 (de) * | 1990-03-16 | 1998-10-29 | Great Lakes Chemical Corp | Verfahren zur reinigung von bromiertem polystyrol |
US5194482A (en) * | 1990-08-23 | 1993-03-16 | Ferro Corporation | Flame retardant resin composition containing styrenic polymers |
JPH0639491B2 (ja) * | 1990-11-29 | 1994-05-25 | ダイソー株式会社 | 塩素化ポリオレフィンの製造法及びそれに用いられる装置 |
US5235000A (en) * | 1990-12-10 | 1993-08-10 | Ethyl Corporation | Preparation, storage, and usage of bromine chloride |
US5326837A (en) * | 1992-11-20 | 1994-07-05 | Mobil Oil Corporation | Catalyst systems for syndiospecific polymerization of styrenes |
US5304618A (en) * | 1993-07-22 | 1994-04-19 | Great Lakes Chemical Corporation | Polymers of brominated styrene |
JP3471086B2 (ja) * | 1994-08-12 | 2003-11-25 | 帝人化成株式会社 | 臭素化ポリスチレンの製造方法 |
US5532322B1 (en) * | 1995-09-26 | 1999-12-07 | Manac Inc | Process for preparing brominated polystyrene |
-
1996
- 1996-09-26 US US08/721,398 patent/US5686538A/en not_active Expired - Lifetime
-
1997
- 1997-06-11 US US08/872,718 patent/US5852131A/en not_active Expired - Lifetime
- 1997-09-05 IL IL12911497A patent/IL129114A/en not_active IP Right Cessation
- 1997-09-05 EP EP97939806A patent/EP0928298B1/de not_active Expired - Lifetime
- 1997-09-05 CA CA002265646A patent/CA2265646C/en not_active Expired - Fee Related
- 1997-09-05 JP JP10515657A patent/JP2001501236A/ja active Pending
- 1997-09-05 DE DE69701995T patent/DE69701995T2/de not_active Expired - Lifetime
- 1997-09-05 WO PCT/US1997/015615 patent/WO1998013395A1/en active IP Right Grant
-
2008
- 2008-09-24 JP JP2008244012A patent/JP5066043B2/ja not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CA2265646A1 (en) | 1998-04-02 |
IL129114A (en) | 2002-08-14 |
IL129114A0 (en) | 2000-02-17 |
DE69701995T2 (de) | 2000-11-09 |
EP0928298B1 (de) | 2000-05-10 |
EP0928298A1 (de) | 1999-07-14 |
JP2008303401A (ja) | 2008-12-18 |
US5852131A (en) | 1998-12-22 |
WO1998013395A1 (en) | 1998-04-02 |
US5686538A (en) | 1997-11-11 |
JP2001501236A (ja) | 2001-01-30 |
CA2265646C (en) | 2006-06-06 |
JP5066043B2 (ja) | 2012-11-07 |
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