JP4312379B2 - 参照電極 - Google Patents
参照電極 Download PDFInfo
- Publication number
- JP4312379B2 JP4312379B2 JP2000535918A JP2000535918A JP4312379B2 JP 4312379 B2 JP4312379 B2 JP 4312379B2 JP 2000535918 A JP2000535918 A JP 2000535918A JP 2000535918 A JP2000535918 A JP 2000535918A JP 4312379 B2 JP4312379 B2 JP 4312379B2
- Authority
- JP
- Japan
- Prior art keywords
- palladium
- electrode
- reference electrode
- layer
- substrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 137
- 239000010410 layer Substances 0.000 claims description 63
- 229910052763 palladium Inorganic materials 0.000 claims description 62
- 239000000758 substrate Substances 0.000 claims description 31
- 239000003792 electrolyte Substances 0.000 claims description 28
- 150000002941 palladium compounds Chemical class 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 15
- 239000004065 semiconductor Substances 0.000 claims description 15
- 150000001450 anions Chemical class 0.000 claims description 14
- 238000002848 electrochemical method Methods 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 11
- 239000012736 aqueous medium Substances 0.000 claims description 9
- 239000012528 membrane Substances 0.000 claims description 9
- 239000004020 conductor Substances 0.000 claims description 8
- 230000005669 field effect Effects 0.000 claims description 8
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 8
- 150000002500 ions Chemical class 0.000 claims description 7
- 239000000919 ceramic Substances 0.000 claims description 6
- 238000005516 engineering process Methods 0.000 claims description 6
- 239000002861 polymer material Substances 0.000 claims description 6
- 239000011247 coating layer Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 239000011521 glass Substances 0.000 claims description 4
- 239000002241 glass-ceramic Substances 0.000 claims description 4
- 239000003989 dielectric material Substances 0.000 claims description 3
- INIOZDBICVTGEO-UHFFFAOYSA-L palladium(ii) bromide Chemical compound Br[Pd]Br INIOZDBICVTGEO-UHFFFAOYSA-L 0.000 claims description 3
- 239000011230 binding agent Substances 0.000 claims description 2
- 239000011195 cermet Substances 0.000 claims description 2
- 238000009388 chemical precipitation Methods 0.000 claims description 2
- 238000011065 in-situ storage Methods 0.000 claims description 2
- 150000001768 cations Chemical class 0.000 claims 1
- 238000009396 hybridization Methods 0.000 claims 1
- 238000005259 measurement Methods 0.000 description 11
- 239000012491 analyte Substances 0.000 description 9
- 239000002609 medium Substances 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 239000000499 gel Substances 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 229910021607 Silver chloride Inorganic materials 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 5
- 239000010408 film Substances 0.000 description 4
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Substances [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 4
- 238000007650 screen-printing Methods 0.000 description 4
- 229910052709 silver Inorganic materials 0.000 description 4
- 239000004332 silver Substances 0.000 description 4
- 239000010409 thin film Substances 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 238000005229 chemical vapour deposition Methods 0.000 description 3
- 238000001465 metallisation Methods 0.000 description 3
- HBEQXAKJSGXAIQ-UHFFFAOYSA-N oxopalladium Chemical compound [Pd]=O HBEQXAKJSGXAIQ-UHFFFAOYSA-N 0.000 description 3
- 229910003445 palladium oxide Inorganic materials 0.000 description 3
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 239000000017 hydrogel Substances 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 229940071870 hydroiodic acid Drugs 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000001139 pH measurement Methods 0.000 description 2
- 150000002940 palladium Chemical class 0.000 description 2
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 2
- YJVFFLUZDVXJQI-UHFFFAOYSA-L palladium(ii) acetate Chemical compound [Pd+2].CC([O-])=O.CC([O-])=O YJVFFLUZDVXJQI-UHFFFAOYSA-L 0.000 description 2
- 238000002161 passivation Methods 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 1
- MCWMYICYUGCRDY-UHFFFAOYSA-N 2-[2-[2-(2-hydroxyethoxy)ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOCCO MCWMYICYUGCRDY-UHFFFAOYSA-N 0.000 description 1
- 102100026735 Coagulation factor VIII Human genes 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 101000911390 Homo sapiens Coagulation factor VIII Proteins 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- -1 Palladium Hydride Chemical class 0.000 description 1
- 101150003085 Pdcl gene Proteins 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical group [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 238000003869 coulometry Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- PYRZPBDTPRQYKG-UHFFFAOYSA-N cyclopentene-1-carboxylic acid Chemical compound OC(=O)C1=CCCC1 PYRZPBDTPRQYKG-UHFFFAOYSA-N 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 230000026045 iodination Effects 0.000 description 1
- 238000006192 iodination reaction Methods 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005597 polymer membrane Polymers 0.000 description 1
- 229920005591 polysilicon Polymers 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/28—Electrolytic cell components
- G01N27/30—Electrodes, e.g. test electrodes; Half-cells
- G01N27/301—Reference electrodes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Molecular Biology (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19810098 | 1998-03-10 | ||
| DE19810098.1 | 1998-03-10 | ||
| PCT/EP1999/001369 WO1999046586A1 (de) | 1998-03-10 | 1999-03-03 | Referenzelektrode |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2003515097A JP2003515097A (ja) | 2003-04-22 |
| JP2003515097A5 JP2003515097A5 (enExample) | 2006-01-26 |
| JP4312379B2 true JP4312379B2 (ja) | 2009-08-12 |
Family
ID=7860246
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000535918A Expired - Fee Related JP4312379B2 (ja) | 1998-03-10 | 1999-03-03 | 参照電極 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US6572748B1 (enExample) |
| EP (1) | EP1062501B1 (enExample) |
| JP (1) | JP4312379B2 (enExample) |
| DE (1) | DE59909242D1 (enExample) |
| WO (1) | WO1999046586A1 (enExample) |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE50015505D1 (de) * | 2000-02-10 | 2009-02-12 | Hamilton Bonaduz Ag | Polymerelektrolyt |
| EP1491519A1 (de) * | 2003-06-25 | 2004-12-29 | Mettler-Toledo GmbH | Verfahren zur Behandlung einer porösen Keramik |
| US7241500B2 (en) * | 2003-10-06 | 2007-07-10 | Certainteed Corporation | Colored roofing granules with increased solar heat reflectance, solar heat-reflective shingles, and process for producing same |
| EP1815238B1 (de) * | 2004-11-26 | 2008-07-16 | Micronas GmbH | Elektrisches Bauelement |
| FR2884111B1 (fr) | 2005-04-07 | 2007-05-18 | Saint Gobain Mat Constr Sas | Granule biocide, notamment pour la fabrication de bardeau d'asphalte |
| US20070038275A1 (en) * | 2005-07-05 | 2007-02-15 | Hee-Je Kim | High-frequency electrotherapy apparatus |
| JP2007046914A (ja) * | 2005-08-05 | 2007-02-22 | Denso Corp | 油の酸性、塩基性度検出用基準電極 |
| JP4623374B2 (ja) * | 2005-08-26 | 2011-02-02 | 国立大学法人九州大学 | 化学感覚能センサチップ |
| JP4758752B2 (ja) * | 2005-12-16 | 2011-08-31 | 日本電信電話株式会社 | pH電極 |
| US20100305420A1 (en) * | 2006-02-27 | 2010-12-02 | Edwards Lifesciences Corporation | Flexible circuit and method for forming the same |
| AU2007221292B2 (en) * | 2006-02-27 | 2012-10-04 | Edwards Lifesciences Corporation | Method and apparatus for using flex circuit technology to create a reference electrode channel |
| US7749593B2 (en) * | 2006-07-07 | 2010-07-06 | Certainteed Corporation | Solar heat responsive exterior surface covering |
| DE102006047928A1 (de) * | 2006-10-10 | 2008-04-17 | Robert Bosch Gmbh | Verfahren zur Herstellung mindestens einer porösen Schicht |
| EP2165028A4 (en) | 2007-05-24 | 2011-10-26 | Certain Teed Corp | COVER GRANULES WITH HIGH SOLAR REFLECTANCE, COVER PRODUCTS WITH HIGH SOLAR REFLECTANCE, AND METHODS OF PREPARING THE SAME |
| US8000918B2 (en) * | 2007-10-23 | 2011-08-16 | Edwards Lifesciences Corporation | Monitoring and compensating for temperature-related error in an electrochemical sensor |
| FR2923078B1 (fr) * | 2007-10-26 | 2017-09-01 | Centre Nat De La Rech Scient - Cnrs | Procede de fabrication d'un element d'interconnexion mecanique conducteur d'electricite. |
| WO2009059203A1 (en) * | 2007-11-02 | 2009-05-07 | Edwards Lifesciences Corporation | Analyte monitoring system having back-up power source for use in either transport of the system or primary power loss |
| US20090188811A1 (en) | 2007-11-28 | 2009-07-30 | Edwards Lifesciences Corporation | Preparation and maintenance of sensors |
| US8491985B2 (en) * | 2008-03-31 | 2013-07-23 | Certainteed Corporation | Coating compositions for roofing granules, dark colored roofing granules with increased solar heat reflectance, solar heat-reflective shingles, and process for producing the same |
| US20090294284A1 (en) * | 2008-05-28 | 2009-12-03 | Chung Yuan Christian University | Reference electrode |
| WO2010001277A1 (en) * | 2008-06-30 | 2010-01-07 | Nxp B.V. | Chip integrated ion sensor |
| WO2010027771A1 (en) | 2008-08-27 | 2010-03-11 | Edwards Lifesciences Corporation | Analyte sensor |
| EP2241882A1 (fr) * | 2009-04-15 | 2010-10-20 | Neroxis SA | Capteur électrochimique ampérométrique et son procédé de fabrication |
| US8119869B2 (en) * | 2009-07-17 | 2012-02-21 | Monsanto Technology Llc | Soybean variety A1016276 |
| US8342007B2 (en) | 2010-02-10 | 2013-01-01 | Dionex Corporation | Electrochemical detection cell for liquid chromatography system |
| US8636885B2 (en) * | 2010-02-26 | 2014-01-28 | Dionex Corporation | Analytic device with photovoltaic power source |
| US8833146B2 (en) | 2010-04-26 | 2014-09-16 | Southwest Research Institute | Corrosion sensor |
| DE102012111811A1 (de) * | 2012-12-05 | 2014-06-05 | Endress + Hauser Conducta Gesellschaft für Mess- und Regeltechnik mbH + Co. KG | Elektrochemischer Sensor zur Erfassung einer Analytkonzentration in einem Messmedium |
| US20150198518A1 (en) * | 2014-01-16 | 2015-07-16 | Frank William Borin | Cathodic protection reference cell article and method |
| JP6514336B2 (ja) * | 2014-12-23 | 2019-05-15 | ヘレウス センサー テクノロジー ゲゼルシャフト ミット ベシュレンクテル ハフツング | 導電性及び/又は分極性粒子を検出するセンサ、センサシステム、センサを作動させる方法、このタイプのセンサを製造する方法及びこのタイプのセンサの使用 |
| US10161897B2 (en) * | 2015-01-09 | 2018-12-25 | Xerox Corporation | Sensors incorporating palladium electrodes |
| US10730799B2 (en) | 2016-12-31 | 2020-08-04 | Certainteed Corporation | Solar reflective composite granules and method of making solar reflective composite granules |
| US20240295520A1 (en) * | 2021-06-21 | 2024-09-05 | Dominic Francis Gervasio | Palladium-hydrogen ph electrode |
| KR102685146B1 (ko) * | 2021-11-24 | 2024-07-15 | 한국생산기술연구원 | 유연성을 갖는 pH 센서 및 이를 포함하는 창상 피복재 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1158856B (it) * | 1978-06-16 | 1987-02-25 | Sclavo Inst Sieroterapeut | Sistema elettrodico con elettrodo di riferimento senza giunzione liquida per misure voltammetriche |
| US4404065A (en) | 1980-01-14 | 1983-09-13 | Enviromental Sciences Associates, Inc. | Electrochemical detection system and method of analysis |
| GB2078962A (en) * | 1980-06-11 | 1982-01-13 | Goffee Randal Antonio | Metal hydride reference electrode |
| US4536274A (en) * | 1983-04-18 | 1985-08-20 | Diamond Shamrock Chemicals Company | pH and CO2 sensing device and method of making the same |
| EP0267892A3 (en) * | 1986-11-13 | 1990-10-31 | Monsanto Company | A solid state reference electrode |
| US4933048A (en) * | 1988-02-16 | 1990-06-12 | I-Stat Corporation | Reference electrode, method of making and method of using same |
| CA2034734A1 (en) * | 1990-03-02 | 1991-09-03 | Mark L. Bowers | Amperometric detection cell |
| US5368706A (en) | 1990-03-02 | 1994-11-29 | Esa, Inc. | Amperometric detection cell |
| EP0651248B1 (en) | 1993-11-02 | 2001-01-24 | Siemens Plc | Water quality sensor apparatus |
| US5702575A (en) * | 1995-01-27 | 1997-12-30 | Chiron Diagnostics Corporation | Method of preparing an electrochemical planar metal/metal oxide electrode |
| DE19536901A1 (de) * | 1995-10-04 | 1997-04-10 | Microparts Gmbh | Verfahren zum Herstellen integrierter Elektroden in Kunststoff-Formen, Kunststoff-Formen mit integrierten Elektroden und deren Verwendung |
| DE19641777C2 (de) * | 1996-10-10 | 2001-09-27 | Micronas Gmbh | Verfahren zum Herstellen eines Sensors mit einer Metallelektrode in einer MOS-Anordnung |
-
1999
- 1999-03-03 WO PCT/EP1999/001369 patent/WO1999046586A1/de not_active Ceased
- 1999-03-03 US US09/623,839 patent/US6572748B1/en not_active Expired - Fee Related
- 1999-03-03 EP EP99911731A patent/EP1062501B1/de not_active Expired - Lifetime
- 1999-03-03 DE DE59909242T patent/DE59909242D1/de not_active Expired - Lifetime
- 1999-03-03 JP JP2000535918A patent/JP4312379B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US6572748B1 (en) | 2003-06-03 |
| JP2003515097A (ja) | 2003-04-22 |
| WO1999046586A1 (de) | 1999-09-16 |
| DE59909242D1 (de) | 2004-05-27 |
| EP1062501A1 (de) | 2000-12-27 |
| EP1062501B1 (de) | 2004-04-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4312379B2 (ja) | 参照電極 | |
| US4062750A (en) | Thin film electrochemical electrode and cell | |
| EP0185941B1 (en) | Polymer-based microelectronic pH-sensor | |
| US6419809B1 (en) | Miniature reference electrode | |
| EP0569908B1 (en) | Electrochemical detection method and apparatus therefor | |
| US3926766A (en) | Miniature probe containing multifunctional electrochemical sensing electrodes | |
| EP0299778A2 (en) | Microelectrochemical sensor and sensor array | |
| US3911901A (en) | In vivo hydrogen ion sensor | |
| JP2003515097A5 (enExample) | ||
| CA2196895A1 (en) | Chemical sensors, in particular silicon-based biosensors | |
| CN107957440B (zh) | 平面型氨选择性感测电极及其制法 | |
| JP3751026B2 (ja) | 分析セル | |
| US5384031A (en) | Reference electrode | |
| GB2237390A (en) | Liquid microelectrode | |
| WO1982000161A1 (en) | Electrochemical gas sensor,electrodes therefor and methods of making said sensor and electrodes | |
| JP3135956B2 (ja) | ソリッドコンタクトとこれを用いた電位差センサ装置およびセンサ装置による方法 | |
| EP0472398B1 (en) | Electrode for measuring pH and method for manufacturing the same | |
| US3923627A (en) | Miniature probe containing multifunctional electrochemical sensing electrodes | |
| US3794575A (en) | Oxygen sensor | |
| US3835013A (en) | Oxygen sensor and electrode device therefor | |
| JP3194090B2 (ja) | 電気化学的センサー | |
| US20130105308A1 (en) | Miniature reference electrode | |
| US4786396A (en) | Ion electrode and method of making it | |
| US10620146B2 (en) | Electrode chip | |
| US3898147A (en) | Bicarbonate ion electrode and sensor |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20051125 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20051125 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20080827 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20081120 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20081219 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20090318 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20090423 |
|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20090513 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120522 Year of fee payment: 3 |
|
| R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| LAPS | Cancellation because of no payment of annual fees |