JP4302519B2 - 親油性流体処理方法 - Google Patents
親油性流体処理方法 Download PDFInfo
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- JP4302519B2 JP4302519B2 JP2003526517A JP2003526517A JP4302519B2 JP 4302519 B2 JP4302519 B2 JP 4302519B2 JP 2003526517 A JP2003526517 A JP 2003526517A JP 2003526517 A JP2003526517 A JP 2003526517A JP 4302519 B2 JP4302519 B2 JP 4302519B2
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- lipophilic fluid
- emulsion
- lipophilic
- water
- membrane
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- 125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
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- GSANOGQCVHBHIF-UHFFFAOYSA-N tetradecamethylcycloheptasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 GSANOGQCVHBHIF-UHFFFAOYSA-N 0.000 description 1
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- 239000002562 thickening agent Substances 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-M toluene-4-sulfonate Chemical compound CC1=CC=C(S([O-])(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-M 0.000 description 1
- GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
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- OEIXGLMQZVLOQX-UHFFFAOYSA-N trimethyl-[3-(prop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCCNC(=O)C=C OEIXGLMQZVLOQX-UHFFFAOYSA-N 0.000 description 1
- 238000010977 unit operation Methods 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/02—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using organic solvents
- D06L1/10—Regeneration of used chemical baths
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D17/00—Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D17/00—Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
- B01D17/02—Separation of non-miscible liquids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D17/00—Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
- B01D17/02—Separation of non-miscible liquids
- B01D17/04—Breaking emulsions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D17/00—Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
- B01D17/08—Thickening liquid suspensions by filtration
- B01D17/085—Thickening liquid suspensions by filtration with membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D17/00—Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
- B01D17/12—Auxiliary equipment particularly adapted for use with liquid-separating apparatus, e.g. control circuits
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Textile Engineering (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Detergent Compositions (AREA)
- Water Treatment By Sorption (AREA)
- Treatment Of Fiber Materials (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Heat Treatment Of Water, Waste Water Or Sewage (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Description
本明細書で使用される「親油性流体」という用語は、後述の試験によって限定されるように、皮脂を除去する能力がある任意の非水性流体又は蒸気を包含することを意味している。
本明細書の親油性流体は、布地/皮革物品処理機器の運転条件下、換言すれば、本発明による布地物品の処理中に、液相が存在するものである。一般にこうした親油性流体は、周囲温度及び周囲圧力で完全に液体である可能性もあり、容易に融解する固体である可能性もあり、例えば約0℃〜約60℃の範囲の温度で液体になるか、又は周囲温度及び周囲圧力、例えば約25℃、1気圧で、液相と気相の混合物を含むことができる。従って、親油性流体は、二酸化炭素のような圧縮性気体ではない。
ドライクリーニング流体に対する既知の要求(例えば、引火点など)を満たすことができると共に、下記の試験法に示されるように少なくとも部分的に皮脂を溶解することができるいかなる非水性流体も、本明細書の親油性流体として適している。一般指針としてパーフルオロブチルアミン(フロリナート(Fluorinert)FC−43(登録商標))はそれ自体(補助剤と共に、又は補助剤無しで)が標準物質であり、定義上は本明細書で使用される親油性流体として適していない(本質的に非溶媒である)が、一方でシクロペンタシロキサンは好適な皮脂溶解特性を有し、皮脂を溶解させる。
補助剤物質は、大きく異なる可能性があり、広範囲の濃度で使用することができる。例えば、プロテアーゼ類、アミラーゼ類、セルラーゼ類、リパーゼ類などの洗浄性酵素、並びにマンガン又は類似の遷移金属を有する大環状型を含む漂白触媒は、すべて洗濯製品及び洗浄製品に有用であり、本発明で標準的又は特殊な濃度で使用できる。触媒作用を有する補助剤物質、例えば酵素は、本発明から独立して有用であると発見された「順方向」又は「逆方向」モードで使用することができる。例えば、リポラーゼ又は他の加水分解酵素を補助剤としてアルコール類の存在下で任意選択的に使用してもよく、脂肪酸をエステルに転化し、それにより親油性流体の溶解度を増大させる。これは「逆方向」操作であって、水に対する溶解度がより小さい脂肪酸エステルを、水に対する溶解度がより大きい物質に転換するために、水中における加水分解酵素の通常の使用法とは対照的である。いずれにしても、任意の添加剤成分は親油性流体との組み合わせで使用するのに適していなければならない。
a)ノニルフェノール及びミリスチルアルコールのポリエチレンオキシド縮合物であり、米国特許第4,685,930号(カスプルザーク(Kasprzak))におけるものなど、及び
b)脂肪族アルコールエトキシレート、R−(OCH2CH2)aOH、a=1〜100、典型的には12〜40、R=炭化水素残基8〜20C原子、典型的には直鎖アルキル。例として、4又は23のオキシエチレン基を有するポリオキシエチレンラウリルエーテル;2、10、又は20のオキシエチレン基を有するポリオキシエチレンセチルエーテル;2、10、20、21、又は100のオキシエチレン基を有するポリオキシエチレンステアリルエーテル;2、又は10のオキシエチレン基を有するポリオキシエチレン(2),(10)オレイルエーテルがある。市販されている例として、アルフォニック(ALFONIC)、ブリジ(BRIJ)、ゲナポール(GENAPOL)、ネオドール(NEODOL)、サーフォニック(SURFONIC)、トリコール(TRYCOL)が挙げられるが、これらに限定されない。米国特許第6,013,683号(ヒル(Hill)らに発行)も参照のこと。
MaDbD’cD”dM’2〜a
式中、aは0〜2であり;bは0〜1000であり;cは0〜50であり;dは0〜50であり、但しa+c+dは少なくとも1である;
MはR1 3〜eXeSiO1/2であり、式中、R1は独立して、H、又は一価の炭化水素基であり、Xはヒドロキシル基であり、eは0又は1である;
M’はR2 3SiO1/2であり、式中、R2は独立して、H、一価の炭化水素基、又は(CH2)f−(C6H4)gO−(C2H4O)h−(C3H6O)i−(CkH2kO)j−R3であり、但し少なくとも1つのR2が(CH2)f−(C6H4)gO−(C2H4O)h−(C3H6O)i−(CkH2kO)j−R3であり、式中、R3は独立して、H、一価の炭化水素基、又はアルコキシ基であり、fは1〜10であり、gは0又は1であり、hは1〜50であり、iは0〜50であり、jは0〜50であり、kは4〜8である;
DはR4 2SiO2/2であり、式中、R4は独立して、H又は一価の炭化水素基であり;
D’はR5 2SiO2/2であり、式中、R5は独立してR2であり、但し少なくとも1つのR5が(CH2)f−(C6H4)gO−(C2H4O)h−(C3H6O)i−(CkH2kO)j−R3であり、式中、R3は独立して、H、一価の炭化水素基、又はアルコキシ基であり、fは1〜10であり、gは0又は1であり、hは1〜50であり、iは0〜50であり、jは0〜50であり、kは4〜8であり、
D”はR6 2SiO2/2であり、式中、R6は独立して、H、一価の炭化水素基又は(CH2)l(C6H4)m(A)n−[(L)o−(A’)p−]q−(L’)rZ(G)sであり、式中、lは1〜10であり;mは0又は1であり;nは0〜5であり;oは0〜3であり;pは0又は1であり;qは0〜10であり;rは0〜3であり;sは0〜3であり;C6H4はC1〜10アルキル又はアルケニルで置換されていないか又は置換されており;A及びA’はそれぞれ独立して連結部分であって、エステル、ケト、エーテル、チオ、アミド、アミノ、C1〜4フルオロアルキル、C1〜4フルオロアルケニル、分枝又は直鎖ポリアルキレンオキシド、ホスフェート、スルホニル、サルフェート、アンモニウム、及びこれらの混合物を表し;L及びL’はそれぞれ独立して、非置換又は置換の、C1〜30直鎖又は分枝アルキル又はアルケニル又はアリールであり;Zは水素、カルボン酸、ヒドロキシ、ホスフェート、ホスフェートエステル、スルホニル、スルホネート、サルフェート、分枝又は直鎖ポリアルキレンオキシド、ニトリル、グリセリル、C1〜30アルキル又はアルケニルで置換されていない又は置換されているアリール、C1〜10アルキル又はアルケニル又はアンモニウムで置換されていない又は置換されている炭水化物であり;GはH+、Na+、Li+、K+、NH4 +、Ca+2、Mg+2、Cl−、Br−、I−、メシラート又はトシラートなどの陰イオン又は陽イオンである。
R’R”N+(CH3)2X−
式中、各R’R”は独立して、12〜30炭素原子から成る群から選択されるか、又はタロー、ココヤシ油又は大豆から誘導され、X=塩素又は臭素である。例として、ジドデシルジメチルアンモニウムブロミド(DDAB)、ジヘキサデシルジメチルアンモニウムクロリド、ジヘキサデシルジメチルアンモニウムブロミド、ジオクタデシルジメチルアンモニウムクロリド、ジエイコシルジメチルアンモニウムクロリド、ジドコシルジメチルアンモニウムクロリド、ジココナッツジメチルアンモニウムクロリド、ジタロージメチルアンモニウムブロミド(DTAB)が挙げられる。市販の例として、アドゲン(ADOGEN)、アークワッド(ARQUAD)、トマー(TOMAH)、バリクワット(VARIQUAT)が挙げられるが、これらに限定されない。米国特許第6,013,683号(ヒル(Hill)らに発行)も参照のこと。
R1―(CH3)2SiO―[(CH3)2SiO]a―[(CH3)(R1)SiO]b―Si(CH3)2―R1
式中、a+bは約1〜約50、好ましくは約3〜約30、更に好ましくは約10〜約25であり、各R1は同一であるか又は異なり、メチル及び次の一般式を有するポリ(エチレンオキシド/プロピレンオキシド)コポリマー基から成る群から選択され、
−(CH2)nO(C2H4O)c(C3H6O)dR2
少なくとも1個のR1はポリ(エチレンオキシド/プロピレンオキシド)コポリマー基であり、その際、nは3又は4、好ましくは3であり;(すべてのポリアルキレン側基の)cの合計は1〜約100、好ましくは約6〜約100の値を有し;dの合計は0〜約14、好ましくは0〜約3であり;更に好ましくはdは0であり;c+dの合計の値は約5〜約150、好ましくは約9〜約100の値を有し、各R2は同一であるか又は異なり、水素、1〜4個の炭素原子を有するアルキル基、及びアセチル基、好ましくは水素及びメチル基から成る群から選択される。これらの界面活性剤の例は、米国特許第5,705,562号及び第5,707,613号(いずれもヒル(Hill)に発行)に見出すことができる。
本発明の吸収性材料は1又はそれ以上の吸水剤を含む。好適な吸水剤及び/又は本発明の吸水剤を含む吸収性材料を、本明細書の以下に記載する。
本発明の吸収性ポリマーは、好ましくは少なくとも1つのヒドロゲル形成吸収性ポリマー(ヒドロゲル形成ポリマーともいう)を含む。本発明で有用なヒドロゲル形成ポリマーには、水性液流体を吸収することが可能な種々の水不溶であるが水で膨潤可能なポリマーを含む。こうしたヒドロゲル形成ポリマーは、当該技術分野では既知であり、これらのポリマーのいずれも本発明に有用である。
アクリルアミドをベースにするゲルも、本発明での使用に適している。具体的に好適なものは、アクリルアミド、2−(アクリロイルオキシ)エチル酸ホスフェート、2−アクリルアミド(acyrlamido)−2−メチルプロパンスルホン酸、2−ジメチルアミノエチルアクリレート、2,2’−ビス(アクリルアミド)酢酸、3−(メタクリルアミド)プロピルトリメチルアンモニウムクロリド、アクリルアミドメチルプロパンジメチルアンモニウムクロリド、アクリレート、アクリロニトリル、アクリル酸、ジアリルジメチルアンモニウムクロリド、ジアリルアンモニウムクロリド、ジメチルアミノエチルアクリレート、ジメチルアミノエチルメタクリレート、エチレングリコール、ジメタクリレート、エチレングリコールモノメタクリレート、メタクリルアミド、メチルアクリルアミドプロピルトリメチルアンモニウムクロリド、N,N−ジメチルアクリルアミド、N−[2[[5−(ジメチルアミノ)1−ナフタレニル(naphthaleny)]スルホニル]アミノ[エチル]−2−アクリルアミド、N−[3−ジメチルアミノ)プロピル]アクリルアミド塩酸塩、N−[3−(ジメチルアミノ)プロピル)メタクリルアミド塩酸塩、ポリ(ジアリルジメチルアンモニウムクロリド)、2−(2−カルボキシベンゾイルオキシ)エチルメタクリル酸ナトリウム、アクリル酸ナトリウム、アリル酢酸ナトリウム、メタクリル酸ナトリウム、スチレンスルホン酸ナトリウム、ビニル酢酸ナトリウム、トリアリルアミン、トリメチル(N−アクリロイル−3−アミノプロピル)アンモニウムクロリド、トリフェニルメタン−ロイコ誘導体、ビニル末端ポリメチルシロキサン、N−(2−エトキシエチル)アクリルアミド、N−3−(メトキシプロピル)アクリルアミド、N−(3−エトキシプロピル)アクリルアミド、N−シクロプロピルアクリルアミド、N−n−プロピルアクリルアミド、及びN−(テトラヒドロフルフリル)アクリルアミドである。
浸透吸収剤(例えば、ヒドロゲル形成吸収性ポリマー)に加えて、本発明は高表面積物質を含むことができる。単独又はヒドロゲル形成吸収性ポリマーと組み合わせて、分別装置又は容器に高い毛管吸着吸収能力を与えるのがこの高表面積物質である。本明細書で論じるように、高表面積物質を、1つの点において、その毛管吸着吸収能力(ヒドロゲル形成ポリマー又はその他のいかなる物質も分別装置又は容器に含有されていない状態で測定される)という観点から記述する。高表面積を有する物質は、極めて高い吸引力の高さ(例えば、100cm以上)で取り込み能力を有する可能性があることが認識される。このことによって高表面積物質は、i)浸透吸収剤への液体の毛管経路、ii)追加の吸収能力、の1つ又は両方を提供することができる。従って、高表面積物質は、重量又は容積当りのその表面積に関して記載されてもよいが、本明細書の出願者らは別の方法として、高表面積物質を記載するのに毛管吸着吸収能力を用いる。それは毛管吸着吸収能力が、一般に本発明で使用される分別装置又は容器に改善された吸収製品を提供するために、必要な吸引能力を提供する性能のパラメータであるからである。特定の高表面積物質、例えば、ガラス微小繊維はそれ自体、あらゆる高さ、特に極めて高い高さ(例えば、100cm以上)では特に高い毛管吸着吸収能力を示さないことが認識される。それにも関わらず、こうした物質は、ヒドロゲル形成ポリマー又はその他の浸透吸収剤と組み合わせた場合、相対的に高い高さでさえ必要な毛管吸着吸収能力を備えるために、ヒドロゲル形成吸収性ポリマー又はその他の浸透吸収剤への液体の望ましい毛管経路を提供する可能性がある。
スペーサー物質が本発明の吸収性材料に用いられてもよい。本発明での使用に好適なスペーサー物質は、水及び/又は親油性流体内において、あってもわずかしか可溶性がない任意の繊維状又は粒子状物質を含む。吸収性材料単独で作られたマトリックスの浸透性以上に、その浸透性を改善するために、スペーサーを吸収性材料のマトリックス全体に分散することができ、又は吸収性材料が水に接触する際に膨張及び/又はゲル化した後でも浸透性を維持するためにスペーサーを使用することができる。従って、スペーサーは、含水流体が吸収性材料マトリックスを通過した時に当該マトリックス前後での圧力損失を減少する作用がある。加えて、吸収性材料が水にさらされてから壊れた後で凝固する傾向がある場合、スペーサーは、壊れる時のゲル凝固の減少又は防止に役立つことができる。
「乾燥した」吸収性マトリックスの透過性を増大するため、又は湿潤時に吸収性マトリックスの透過性を維持するためには、スペーサー、及び、任意選択的に高表面積物質に対して吸収性材料の比を十分にすることが重要である。考えられるスペーサーの重量は吸収性材料の重量に対して大きく変動する可能性があるので、この比率を「乾燥」容積を基準として定量化しなければならない。「正味マトリックス容積」は、吸収性材料、スペーサー、及び、任意選択的に、任意の高表面積物質の容積であって、これら自体が含有する可能性のある物質間容積又は物質内の空隙に起因するいかなる容積も含まない。「物質内の空隙容積」は、物質粒子及び/又は繊維が特定の空間を占めた時に、典型的及び自然に発生する物質粒子及び/又は繊維間の空隙の累積体積である。「乾燥原体マトリックス容積」は、乾燥量を基準として正味マトリックス容積と物質内空隙容積を合わせたものに等しい。本発明に関しては、吸収性材料は乾燥原体マトリックス容積の約50体積%〜100体積%、より好ましくは75体積%〜95体積%であることが好ましい。スペーサーは、乾燥原体マトリックス容積の1体積%〜50体積%、より好ましくは5体積%〜25体積%であることが好ましい。任意の高表面積物質は、乾燥原体マトリックス容積の1体積%〜50体積%、より好ましくは5体積%〜25体積%であることが好ましい。
本発明は、流体を精製する数種類の既知の方法と必要に応じて組み合わせることができる。これらの方法で、水−親油性流体分離操作の補助のための使用、及び/又は使用後の親油性流体からの不純物除去のための使用が可能である。
本発明は、少なくとも水及び親油性流体から成るエマルションに含有される親油性流体の処理方法を対象とする。本方法は、エマルションの前処理工程と、エマルションからの親油性流体の回収工程と、親油性流体の精製の工程とを含む。本方法は更に、布地を親油性流体及び水にさらす第一の工程と、エマルション形態における親油性流体及び水を回収する工程とを含む。本方法は、親油性流体の少なくとも一部分及び水の少なくとも一部分を混合して、布地を水にさらす前にエマルションを形成する混合工程を任意に含んでもよい。乳化剤をも混合工程中に加えてよい。
Claims (11)
- 水及び親油性流体を含むエマルションに含有された前記親油性流体の処理方法であって、前記方法は、
a.前記エマルションの前処理工程、但し、該前処理工程は、沈降分離、遠心分離、サ
イクロン作用の暴露、デカンテーション、濾過、温度変更、液体の少なくとも一つ
の物理化学的特性を変えるための化学薬品添加、及びこれらの組み合わせから成る
群から選択される;
b.前記エマルションからの前記親油性流体の回収工程;及び
c.膜濾過法による前記親油性流体の精製工程、但し、該膜濾過法は、ポリフッ化ビニ
リデン膜、ポリスルホン中空繊維膜又はシラン処理セルロース膜を含む;
を含む方法であって、前記親油性流体は、直鎖シロキサン、環状シロキサン、又はこれらの混合物を含む、上記方法。 - 前記前処理工程が、1ミクロン以上の粒子及び粒子集合体を除去するように、前記エマルションをフィルターに通すことを含む、請求項1に記載の方法。
- 前記回収工程が、機械的な凝集、電気的な凝集、液体の少なくとも一つの物理化学的特性を変えるための化学薬品添加、膜濾過、温度変更、エアストリッピング、微生物添加、吸収性材料暴露、遠心分離、蒸留、吸着、吸収、結晶化、沈殿、ダイアフィルトレーション、電気分解、抽出、pH変更、イオン強度変更、及びこれらの組み合わせから成る群から選択される、請求項1に記載の方法。
- 回収工程が、前記エマルションを活性炭にさらすことを含む吸着である、請求項3に記載の方法。
- 前記エマルションが、該エマルションの10重量%までの乳化剤を含む、請求項1に記載の方法。
- 前記エマルションが、前記エマルションの重量において、1/98.9/0.1〜40/55/5の比で、水/親油性流体と凝縮親油性流体蒸気を合わせたもの/乳化剤、を含む、請求項5に記載の方法。
- 前記乳化剤が界面活性剤を含む、請求項5に記載の方法。
- 前記親油性流体が、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロペンタシロキサン、及びこれらの混合物から成る群から選択される、請求項1に記載の方法。
- 前記親油性流体が、デカメチルシクロペンタシロキサンを含む、請求項1に記載の方法。
- 前記親油性流体が、デカメチルシクロペンタシロキサンを含むが、オクタメチルシクロテトラシロキサンを含まない、請求項1に記載の方法。
- 親油性流体及び親油性流体蒸気の精製方法であって、前記方法は、
a.前記親油性流体蒸気と水及び前記親油性流体を含有する第一エマルションの回収工
程;
b.凝縮された親油性流体蒸気を形成するための前記親油性流体蒸気の凝縮工程;
c.第二エマルションを形成するための凝縮された親油性流体蒸気と第一エマルション
の結合工程;
d.第二エマルションの前処理工程、該前処理工程は、沈降分離、遠心分離、サイクロ
ン作用の暴露、デカンテーション、濾過、温度変更、液体の少なくとも一つの物理
化学的特性を変えるための化学薬品添加、及びこれらの組み合わせから成る群から
選択される;
e.第二エマルションからの前記親油性流体及び前記凝縮親油性流体蒸気の回収工程;
及び
f.膜濾過法による親油性流体及び前記凝縮親油性流体蒸気の精製工程、但し、該膜濾
過法は、ポリフッ化ビニリデン膜、ポリスルホン中空繊維膜又はシラン処理セルロ
ース膜を含む;
を含む方法であって、前記親油性流体は、直鎖シロキサン、環状シロキサン、又はこれらの混合物を含む、上記方法。
Applications Claiming Priority (2)
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US31838301P | 2001-09-10 | 2001-09-10 | |
PCT/US2002/028671 WO2003022394A2 (en) | 2001-09-10 | 2002-09-10 | Process for treating a lipophilic fluid |
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JP2005507761A JP2005507761A (ja) | 2005-03-24 |
JP4302519B2 true JP4302519B2 (ja) | 2009-07-29 |
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JP (1) | JP4302519B2 (ja) |
KR (1) | KR100637014B1 (ja) |
CN (1) | CN100497800C (ja) |
AU (1) | AU2002333531B2 (ja) |
BR (1) | BR0212360A (ja) |
CA (1) | CA2455839C (ja) |
CZ (1) | CZ2004322A3 (ja) |
MX (1) | MXPA04002241A (ja) |
WO (1) | WO2003022394A2 (ja) |
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CN102079603B (zh) * | 2010-12-20 | 2012-01-04 | 大连理工大学 | 一种高浓度的有机和无机混合废水处理回收方法 |
CN102877279B (zh) * | 2012-10-09 | 2016-02-24 | 深圳市佳能宝节能环保科技有限公司 | 一种干衣机 |
CN106957126B (zh) * | 2016-01-12 | 2020-03-31 | 绍兴鑫杰环保科技有限公司 | 一种切削废水的处理工艺 |
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US4108599A (en) * | 1976-01-09 | 1978-08-22 | Stauffer Chemical Company | High water content emulsion cleaning |
US4604205A (en) * | 1982-09-02 | 1986-08-05 | Central Illinois Manufacturing Company | Water removing filter media |
FI84621C (fi) * | 1983-12-29 | 1991-12-27 | Daicel Chem | Dehydraticeringsfoerfarande. |
US4664754A (en) * | 1985-07-18 | 1987-05-12 | General Electric Company | Spent liquid organic solvent recovery system |
JPH0780250A (ja) * | 1993-09-09 | 1995-03-28 | Kuraray Co Ltd | ドライクリーニング溶剤の浄化装置およびドライクリーニングシステム |
US6086635A (en) * | 1997-08-22 | 2000-07-11 | Greenearth Cleaning, Llc | System and method for extracting water in a dry cleaning process involving a siloxane solvent |
CA2410192C (en) * | 2000-06-05 | 2007-09-11 | The Procter & Gamble Company | Use of absorbent materials to separate water from lipophilic fluid |
ATE480660T1 (de) * | 2000-06-05 | 2010-09-15 | Procter & Gamble | Verfahren zur behandlung einer lipophilen flüssigkeit |
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2002
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- 2002-09-10 AU AU2002333531A patent/AU2002333531B2/en not_active Ceased
- 2002-09-10 WO PCT/US2002/028671 patent/WO2003022394A2/en active Application Filing
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JP2005507761A (ja) | 2005-03-24 |
AU2002333531B2 (en) | 2006-04-06 |
WO2003022394A3 (en) | 2004-05-06 |
CA2455839A1 (en) | 2003-03-20 |
KR20040044890A (ko) | 2004-05-31 |
CN1612960A (zh) | 2005-05-04 |
CN100497800C (zh) | 2009-06-10 |
WO2003022394A2 (en) | 2003-03-20 |
CZ2004322A3 (cs) | 2004-12-15 |
KR100637014B1 (ko) | 2006-10-23 |
BR0212360A (pt) | 2004-12-14 |
MXPA04002241A (es) | 2004-06-29 |
CA2455839C (en) | 2009-06-23 |
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