JP4216036B2 - Waste treatment system - Google Patents

Waste treatment system Download PDF

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JP4216036B2
JP4216036B2 JP2002302120A JP2002302120A JP4216036B2 JP 4216036 B2 JP4216036 B2 JP 4216036B2 JP 2002302120 A JP2002302120 A JP 2002302120A JP 2002302120 A JP2002302120 A JP 2002302120A JP 4216036 B2 JP4216036 B2 JP 4216036B2
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temperature
melting furnace
treatment system
gasification
waste treatment
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JP2004136184A (en
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正一 久米
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株式会社還元溶融技術研究所
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/141Feedstock
    • Y02P20/143Feedstock the feedstock being recycled material, e.g. plastics
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/30Wastewater or sewage treatment systems using renewable energies
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/20Waste processing or separation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

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  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Processing Of Solid Wastes (AREA)
  • Treatment Of Sludge (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Coke Industry (AREA)

Description

【0001】
【発明の属する技術分野】
本発明の目的は、油化装置、メタン発酵装置および炭化装置で生成される残渣やその他の廃棄物を有効に処理して、最終的には残渣が生じない廃棄物処理システムに関するものである。
【0002】
【従来の技術】
ペットボトルやタイヤを含むプラスチック廃棄物等の石油製品や石炭製品を油化して、その油を再度、石油化学樹脂の原料や燃料用の油として有効活用する試みが従来から行われているが、この場合、油化後の残渣や、その他の廃棄物は、シュレッダー等にかけて最終処分場にて埋立てに用いるしか手段がなかった。
【0003】
また、植物、畜産物、魚貝類またはそれらの廃棄物、あるいは、畜産物等の糞などの汚物の処理は、肥料もしくはバイオマスエネルギー資源として使用する場合の他、焼却処理あるいは炭化処理のいずれかの処理を行うのが一般的である。
【0004】
前記汚物等をバイオマス資源として使用する従来技術は、農産物、植物、森林物、廃食品、畜産物、畜産物の糞または魚貝類を、重油、灯油、天然ガスあるいは電気などのエネルギーを利用して、メタンを発生しやすい雰囲気温度(70〜80℃)にして、バイオマスエネルギーとしてガス回収や油化回収を行い、それを燃料にすることが行われてきたが、この場合、残渣が発生し再び新しい廃棄物の処理が重大な問題となっていた。
【0005】
また、バイオマスエネルギー装置としてメタン発酵装置を用いた場合には、メタン発酵が生じる温度に加熱保持するため、高コストである灯油、重油、天然ガスあるいは電気などを用いる必要があった。加えて、重油を用いた場合には、窒素酸化物、硫黄酸化物、二酸化炭素などの好ましくないガスが発生し、これらのガスは、地球温暖化の原因となるため好ましくない。
【0006】
さらに、前記汚物等を炭化処理する従来法もまた、残渣が発生してバイオマス技術の場合と同様の問題を有していた。
【0007】
さらにまた、前記汚物等を肥料として使用する従来技術は、受入れが飽和状態にあることや、前記汚物等を肥料として使用すると異物が混入している場合があり、トラブルが発生する恐れがあった。
【0008】
加えて、前記汚物等を焼却処理する従来法は、焼却灰やダイオキシンを排出して、環境汚染等の問題を抱えていた。
【0009】
【発明が解決しようとする課題】
本発明の目的は、油化装置、メタン発酵装置および/または炭化装置で生成される残渣やその他の廃棄物を有効に処理する廃棄物処理システムを提供することにある。
【0012】
【発明が解決しようとする手段】
発明は、ペットボトルやタイヤを含むプラスチック廃棄物等の石油製品や石炭製品を乾留した後に加熱溶融させて燃料油と残渣を生成する油化装置と、植物、畜産物、魚貝類またはそれらの廃棄物、あるいは、畜産物等の糞などの汚物を含むバイオマス資源を、メタンを発酵させる温度に加熱保持してメタンガスと残渣を生成するメタン発酵装置と、一般廃棄物、産業廃棄物、バイオマス資源などの炭素含有物を炭化・分解させて、炭化ガスおよび炭化物を生成する炭化装置と、油化装置メタン発酵装置及び炭化装置生成した残渣を、燃料や資源として供給しかつ1000℃以上で高温溶融させて高温液状物とするとともに、炉内で発生する酸素含有ガスを還元ガス化させる還元ガス化溶融炉と、を具え高温液状物を冷却して得られたスラグおよび/またはメタルを路盤材などに活用するとともに、この還元ガス化溶融炉内で発生した還元ガスを比較的高温で回収して、高温ガスや燃料ガスのようなエネルギー資源として有効活用し、かつ、ガス化溶融炉で生成する還元ガス等のエネルギー資源や、メタン発酵装置、油化装置および炭化装置の少なくとも1つの装置で生成するエネルギー資源を、これらの炉および装置に相互に有効活用するように構成することにより、最終的な残渣発生率が0%であることを特徴とする廃棄物処理システムである。
【0014】
加えて、発明、さらに、還元ガス化溶融炉内で発生した高温ガスの熱を利用して水蒸気を発生させる蒸気発生器を具え、かつ、蒸気発生器によって発生した水蒸気の熱を、メタン発酵装置に有効活用することが好ましく、加えて、炭化装置も具える場合には、蒸気発生器によって発生した水蒸気の熱を、炭化装置またはメタン発光装置と炭化装置の少なくとも一方に有効活用することが好ましい。
【0016】
加えて、発明では、前記メタン発酵装置は、メタンを発酵させる温度に加熱保持するため、ガス化溶融炉で生成される高温排ガスを有効活用するように構成し、油化装置をさらに具える場合には、ガス化溶融炉および油化装置の少なくとも一方で生成される高温排ガスを有効活用するように構成し、炭化装置をさらに具える場合には、ガス化溶融炉および炭化装置の少なくとも一方で生成される高温排ガスを有効活用するように構成し、または、油化装置と炭化装置の双方をさらに具える場合には、ガス化溶融炉、油化装置および炭化装置の少なくとも一方で生成される高温排ガスを有効活用するように構成することがより好適である。
【0017】
【発明の実施の形態】
以下、本発明の実施形態を図面を参照しながら説明する。
図1は、発明に従う廃棄物処理システムを用いて廃棄物を処理するときのフローチャートを示したものである。
【0018】
図1に示すフローチャートは、廃棄物処理システム1が、主として油化装置2と還元ガス化溶融炉3とによって構成されている場合のものである。
【0019】
油化装置2は、ペットボトルやタイヤを含むプラスチック廃棄物等の石油製品や石炭製品を油化するための装置であり、この装置で油化する方法は、例えば、図1に示すように、前記石油製品を供給する投入口(図示せず)をもち、この投入口から供給された前記石油製品を、乾留した後に250〜500℃の温度で加熱溶融させ、揮発成分をガス化(蒸気化)したものを冷却し液体化させることによって燃料油が精製され、この燃料油を、例えば、図1に示すディーゼルエンジン4などの各種エンジンを作動させて発電するための燃料として、または、バスなどの車両の燃料として有効活用することができる。
【0020】
また、油化装置2で生成した残渣を、図2に示すように、還元ガス化溶融炉3の燃料として有効活用することができる。
【0021】
還元ガス化溶融炉3は、油化装置2で生成した残渣を、燃料として供給しかつ1000℃以上で高温溶融させて高温液状物とするとともに、炉内ガスを還元ガス化させるコークスベット式還元ガス化溶融炉である。
【0022】
なお、ここでいう「高温液状物」とは、例えば、一般廃棄物や産業廃棄物などを焼却処理または溶融処理する還元ガス化溶融炉内で生成される1000℃以上の溶融スラグや溶融メタルなどの溶融物が挙げられる。かかる溶融物の温度の上限は、炉を構成する耐火物の耐熱温度を考慮して、2600℃とすることが好ましい。特に、溶融物の温度は、1000〜1320℃であることがより好適である。
【0023】
そして、発明では、還元ガス化溶融炉3内で発生した還元ガスを比較的高温、好適には1000〜2600℃の温度のままで回収して、図1に示すような高温(排)ガスや燃料ガスのようなエネルギー資源として有効活用する。
【0024】
図1では、還元ガス化溶融炉3内で発生した還元ガスを高温排ガスとして有効活用した場合の例であり、還元ガス化溶融炉3から排出した高温排ガスをガス改質処理5とガス清浄化処理6を経て、発電機、図1では、ガスエンジン7に高温のまま供給することによって、発電することができ、この発電によって得られた電力を、例えば還元ガス化溶融炉3の運転のために供給すれば、コストの削減が図れ、経済的に有利となる。
【0025】
また、図2では、還元ガス化溶融炉3内で発生した還元ガス、例えばHガスとして回収して燃料ガスとして有効活用した場合の例であり、この燃料ガスを用いて発電システム8で発電させ、この発電によって得られた電力を、図2に示すように電力会社9に供給したり工場に供給すれば、結果的に、廃棄物処理コストの削減が図れ、経済的に有利となる。
【0026】
なお、高温(排)ガスや燃料ガスのようなエネルギー資源を用いた発電によって得られた電力だけでは足りない場合には、電力会社から供給される電力で補えばよい。
【0027】
発明に従う廃棄物処理システムは、図3に示すように、油化装置2に代えて、バイオマスエネルギー装置10を具え、バイオマスエネルギー装置10で生成した残渣を、還元ガス化溶融炉3の燃料として供給すること以外は、第1発明の廃棄物処理システムの構成とほぼ同様の構成を有する。
【0028】
バイオマスエネルギー装置10は、植物、畜産物、魚貝類またはそれらの廃棄物、あるいは、畜産物等の糞などの汚物を含むバイオマス資源からエネルギーを回収する構成を有する。
【0029】
図4は、発明の実施形態の一例を示す図であって、バイオマスエネルギー装置10としてメタン発酵装置11を用いたものである。
【0030】
図4の廃棄物処理装置は、還元ガス化溶融炉3から排出された高温排ガスを蒸気発生器のような熱交換器12を介して発電させ、この発電によって得られた電力をメタン発酵装置11でメタンを発酵させるために必要な温度に加熱保持するのに用いるとともに、メタン発酵によって生成した残渣を、還元ガス化溶融炉3に供給し高温溶融させて、スラグやメタル中に固溶するため、かかる廃棄物処理では最終的には残渣は生じない。
【0031】
また、発明では、上記構成に加えて、図2に示すように、炭化装置13をさらに具えてもよい。
【0032】
炭化装置13は、一般廃棄物、産業廃棄物、バイオマス資源などの炭素含有物を供給する投入口(図示せず)を有し、この投入口から炭素含有物を供給し、炭素含有物を炭化・分解させて、炭化ガスと炭化物とを生成させる構成をもち、図2では、炭化装置13で生成した炭化物や残渣等を、還元ガス化溶融炉3内に供給し高温溶融させて、スラグやメタル中に固溶するため、かかる廃棄物処理では最終的には残渣は生じない。
【0033】
さらに、発明では、図3に示すように、還元ガス化溶融炉3内で発生した高温ガス(1000〜2600℃)の熱を利用して水蒸気を発生させる蒸気発生器14を具え、かつ、蒸気発生器12によって発生した700〜900℃の温度の水蒸気の熱をそのまま炭化装置13に有効活用し、あるいは、蒸気発生器14によって発生した700〜900℃の温度の水蒸気の熱を利用して熱交換器12を用いて80〜100℃の高温ガス(例えば高温空気)に変換し、この高温ガスの熱をバイオマスエネルギー装置10にそれぞれ有効活用することが、コストの点で有利である。
【0034】
さらにまた、発明では、ガス化溶融炉で生成する還元ガス等のエネルギー資源や、油化装置、バイオマスエネルギー装置および炭化装置の少なくとも1つの装置で生成するエネルギー資源とを、これらの炉および装置に相互に有効活用するように構成することが、廃棄物処理コストを削減できる点で好ましい。
【0035】
加えて、図4では、バイオマスエネルギー装置は、メタンガスを生成するメタン発酵装置であり、このメタン発酵装置は、メタンを発酵させる温度に加熱保持するため、ガス化溶融炉から排出される高温排ガスを有効活用するように構成したが、これだけには限定されず、油化装置や炭化装置で生成される高温排ガスを有効活用するように構成してもよい。
【0036】
上述したところは、この発明の実施形態の一例を示したにすぎず、請求の範囲において種々の変更を加えることができる。
【0037】
本発明では、還元ガス化溶融炉で残渣等の廃棄物は、高温溶融させ冷却後に得られたスラグまたはメタルとし、これらスラグまたはメタルは路盤材などに用いることができるので、かかる廃棄物処理では最終的には残渣は生じず、よって、埋立て場所である最終処分場を不要とすることができる。
【0038】
【実施例】
本発明の廃棄物処理システム(図3)を用いて廃棄物を処理した。そのときの、残渣発生率は0%であった。
比較のため、従来のバイオマスエネルギー装置と、従来の炭化装置でそれぞれ廃棄物処理をしたところ、残渣発生率は、それぞれ41%と27%であった。
【0039】
【発明の効果】
本発明によれば、油化装置、メタン発酵装置および/または炭化装置で生成される残渣やその他の廃棄物を有効に処理する廃棄物処理システムの提供が可能になった。
【0040】
また、残渣物は、最終的には発生しないので、従来装置のように、埋立て場所である最終処分場を不要とすることができる。
【0041】
さらに、還元ガス化溶融炉、油化装置、メタン発酵装置および/または炭化装置内で生成したエネルギー資源を有効活用すれば、廃棄物処理コストが格段に向上する。
【図面の簡単な説明】
【図1】 発明に従う廃棄物処理システムのフローチャートである。
【図2】 発明に従う廃棄物処理システムの他のフローチャートである。
【図3】 発明に従う廃棄物処理システムのフローチャートである。
【図4】 発明に従う廃棄物処理システムの概略図である。
【符号の説明】
1 廃棄物処理システム
2 油化装置
3 還元ガス化溶融炉
4 ディーゼルエンジン
5 ガス改質処理
6 ガス清浄化処理
7 ガスエンジン
8 発電システム
9 電力会社
10 バイオマスエネルギー装置
11 メタン発酵装置
12 熱交換器
13 炭化装置
14 蒸気発生器
[0001]
BACKGROUND OF THE INVENTION
An object of the present invention relates to a waste treatment system that effectively treats residues and other wastes produced in an oil-producing apparatus, a methane fermentation apparatus, and a carbonization apparatus, and does not ultimately produce residues .
[0002]
[Prior art]
Attempts have been made in the past to make petroleum products and coal products such as plastic waste including plastic bottles and tires into oil, and use the oil again as a raw material for petrochemical resins and fuel oil. In this case, the residue after oiling and other wastes can only be used for landfill at a final disposal site through a shredder or the like.
[0003]
In addition, plants, livestock products, fish shellfish or their wastes, or sewage such as feces such as livestock products can be treated as either fertilizer or biomass energy resources, or incinerated or carbonized. It is common to perform processing.
[0004]
The conventional technology using the filth as a biomass resource uses agricultural products, plants, forests, waste foods, livestock products, livestock dung or fish shellfish using energy such as heavy oil, kerosene, natural gas or electricity. , Methane is easily generated at an atmospheric temperature (70 to 80 ° C), and gas and oil recovery are performed as biomass energy and used as fuel, but in this case, a residue is generated again New waste disposal has become a serious problem.
[0005]
Further, when a methane fermentation apparatus is used as a biomass energy apparatus, it is necessary to use kerosene, heavy oil, natural gas, electricity, etc., which are expensive, in order to heat and maintain the temperature at which methane fermentation occurs. In addition, when heavy oil is used, undesirable gases such as nitrogen oxides, sulfur oxides, and carbon dioxide are generated, and these gases are undesirable because they cause global warming.
[0006]
Furthermore, the conventional method of carbonizing the filth etc. also has the same problems as in the case of biomass technology due to the generation of residues.
[0007]
Furthermore, the prior art that uses the filth as a fertilizer has a possibility that trouble may occur because the receiving is in a saturated state, or when the filth or the like is used as a fertilizer, foreign matter may be mixed. .
[0008]
In addition, the conventional method for incinerating filth and the like has problems such as environmental pollution by discharging incinerated ash and dioxin.
[0009]
[Problems to be solved by the invention]
The objective of this invention is providing the waste processing system which processes effectively the residue and other waste which are produced | generated with an oil-ized apparatus, a methane fermentation apparatus, and / or a carbonization apparatus.
[0012]
Means to be Solved by the Invention
The present invention relates to an oiling device for producing fuel oil and residues by dry-melting petroleum products and coal products such as plastic wastes including plastic bottles and tires, followed by heating and melting, and plants, livestock products, fish shellfish or their A methane fermentation device that produces methane gas and residues by heating and holding biomass resources including waste or sewage such as feces such as livestock products, and general waste, industrial waste, biomass resources Carbonizers that carbonize and decompose carbon-containing materials such as carbonized gas and carbides, oil generators , methane fermentation units, and carbonized residue are supplied as fuel and resources, and are heated to 1000 ° C or higher. A slag obtained by cooling a high-temperature liquid material, comprising a reductive gasification and melting furnace that melts into a high-temperature liquid material and reductively gasifies the oxygen-containing gas generated in the furnace And / or metal is used for roadbed materials, etc., and the reducing gas generated in the reductive gasification and melting furnace is recovered at a relatively high temperature and effectively used as an energy resource such as high-temperature gas and fuel gas , and Energy resources such as reducing gas produced in gasification melting furnaces and energy resources produced in at least one of methane fermentation equipment, oil production equipment and carbonization equipment are mutually utilized effectively in these furnaces and equipment. By configuring as described above, the waste generation system is characterized in that the final residue generation rate is 0%.
[0014]
In addition, the present invention further comprises a steam generator for generating steam using heat of the hot gas generated in a reducing gasification melting furnace, and the heat of the steam generated by the steam generator, methane It is preferable to make effective use in a fermentation apparatus. In addition, when a carbonization device is also provided, the heat of water vapor generated by the steam generator should be effectively used in at least one of the carbonization device or the methane light-emitting device and the carbonization device. Is preferred.
[0016]
In addition, in the present invention, the methane fermentation apparatus is configured to effectively use the high-temperature exhaust gas generated in the gasification melting furnace in order to heat and maintain the methane fermentation temperature, and further includes an oil generation apparatus. In such a case, the high-temperature exhaust gas generated by at least one of the gasification melting furnace and the oilification apparatus is configured to be effectively used, and when further comprising a carbonization apparatus, at least one of the gasification melting furnace and the carbonization apparatus In the case where the high-temperature exhaust gas generated in the above is configured to be used effectively, or when both the oilification device and the carbonization device are further provided, it is generated at least one of the gasification melting furnace, the oilification device, and the carbonization device. It is more preferable that the high-temperature exhaust gas is effectively used.
[0017]
DETAILED DESCRIPTION OF THE INVENTION
Embodiments of the present invention will be described below with reference to the drawings.
FIG. 1 is a flowchart for processing waste using the waste processing system according to the present invention.
[0018]
The flowchart shown in FIG. 1 is for a case where the waste treatment system 1 is mainly constituted by an oil generator 2 and a reductive gasification melting furnace 3.
[0019]
The oil making apparatus 2 is an apparatus for oiling petroleum products and coal products such as plastic waste including plastic bottles and tires, and a method of oiling with this apparatus is, for example, as shown in FIG. It has an inlet (not shown) for supplying the petroleum product, and the petroleum product supplied from this inlet is dry-distilled and then heated and melted at a temperature of 250 to 500 ° C. to gasify (vaporize) volatile components. The fuel oil is refined by cooling and liquefying the product, and this fuel oil is used as fuel for generating electricity by operating various engines such as the diesel engine 4 shown in FIG. It can be effectively used as fuel for vehicles.
[0020]
Moreover, the residue produced | generated by the oilification apparatus 2 can be effectively utilized as a fuel of the reductive gasification melting furnace 3, as shown in FIG.
[0021]
The reductive gasification and melting furnace 3 is a coke bed type that supplies the residue generated in the oil generator 2 as fuel and melts it at a high temperature at 1000 ° C. or higher to form a high-temperature liquid material, and gasifies the gas in the furnace. It is a reducing gasification melting furnace.
[0022]
The “high-temperature liquid” as used herein refers to, for example, molten slag or molten metal of 1000 ° C. or higher produced in a reductive gasification melting furnace that incinerates or melts general waste, industrial waste, etc. The melt of this is mentioned. The upper limit of the temperature of the melt is preferably 2600 ° C. in consideration of the heat resistance temperature of the refractory constituting the furnace. In particular, the temperature of the melt is more preferably 1000 to 1320 ° C.
[0023]
In the present invention, the reducing gas generated in the reductive gasification melting furnace 3 is recovered at a relatively high temperature, preferably 1000 to 2600 ° C., and a high-temperature (exhaust) gas as shown in FIG. And effectively used as an energy resource such as fuel gas.
[0024]
FIG. 1 shows an example in which the reducing gas generated in the reducing gasification melting furnace 3 is effectively used as high temperature exhaust gas. The high temperature exhaust gas discharged from the reduction gasification melting furnace 3 is treated with gas reforming treatment 5 and gas purification. Through the processing 6, power can be generated by supplying a high temperature to the generator, in FIG. 1, the gas engine 7, and the electric power obtained by this power generation can be used, for example, for the operation of the reductive gasification melting furnace 3. If it supplies to, cost reduction can be achieved and it becomes economically advantageous.
[0025]
FIG. 2 shows an example of a case where the reducing gas generated in the reducing gasification melting furnace 3 is recovered as, for example, H 2 gas and effectively used as a fuel gas. If the electric power obtained by the power generation is supplied to the electric power company 9 or supplied to the factory as shown in FIG.
[0026]
In addition, when only the electric power obtained by the power generation using energy resources such as high-temperature (exhaust) gas and fuel gas is not enough, it may be supplemented with electric power supplied from an electric power company.
[0027]
As shown in FIG. 3, the waste treatment system according to the present invention includes a biomass energy device 10 instead of the oil production device 2, and uses the residue generated by the biomass energy device 10 as fuel for the reductive gasification melting furnace 3. Except for the supply, the configuration is substantially the same as the configuration of the waste treatment system of the first invention.
[0028]
The biomass energy device 10 has a configuration for recovering energy from biomass resources including vegetation such as plants, livestock products, fish shellfish or waste thereof, or feces such as livestock products.
[0029]
FIG. 4 is a diagram illustrating an example of an embodiment of the present invention, in which a methane fermentation apparatus 11 is used as the biomass energy apparatus 10.
[0030]
The waste treatment apparatus in FIG. 4 generates high-temperature exhaust gas discharged from the reductive gasification melting furnace 3 through a heat exchanger 12 such as a steam generator, and uses the power obtained by this power generation as a methane fermentation apparatus 11. Is used to heat and hold the methane at a temperature necessary for fermentation, and the residue produced by methane fermentation is supplied to the reductive gasification melting furnace 3 and melted at a high temperature to form a solid solution in slag or metal. In the waste treatment, no residue is finally generated.
[0031]
Further, in the present invention, in addition to the above-described configuration, as shown in FIG.
[0032]
The carbonization apparatus 13 has an inlet (not shown) for supplying carbon-containing materials such as general waste, industrial waste, and biomass resources. The carbon-containing material is supplied from the inlet and carbonized. -It has the structure which decomposes and produces | generates carbonized gas and a carbide | carbonized_material. In FIG. 2, the carbide | carbonized_material, residue, etc. which were produced | generated by the carbonization apparatus 13 are supplied in the reductive gasification melting furnace 3, and it is made to melt at high temperature, slag or Since it dissolves in the metal, such a waste treatment does not ultimately produce a residue.
[0033]
Furthermore, in this invention, as shown in FIG. 3, the steam generator 14 which generates water vapor | steam using the heat | fever of the high temperature gas (1000-2600 degreeC) generate | occur | produced in the reductive gasification melting furnace 3 is provided, and The heat of steam at a temperature of 700 to 900 ° C. generated by the steam generator 12 is effectively used as it is in the carbonization apparatus 13 or the heat of steam at a temperature of 700 to 900 ° C. generated by the steam generator 14 is used. It is advantageous in terms of cost to use the heat exchanger 12 to convert to a high-temperature gas (for example, high-temperature air) of 80 to 100 ° C. and to effectively use the heat of this high-temperature gas for each biomass energy device 10.
[0034]
Furthermore, in the present invention, energy resources such as a reducing gas generated in a gasification melting furnace, and energy resources generated in at least one of an oilification apparatus, a biomass energy apparatus, and a carbonization apparatus are supplied to these furnace and apparatus. In order to reduce the waste disposal cost, it is preferable to configure such that the two can be effectively used.
[0035]
In addition, in FIG. 4, the biomass energy device is a methane fermentation device that generates methane gas, and this methane fermentation device heats and maintains the temperature at which methane is fermented. Although it was configured so as to be used effectively, the present invention is not limited to this, and it may be configured so as to effectively use high-temperature exhaust gas generated by an oil generator or a carbonizer.
[0036]
The above description is merely an example of the embodiment of the present invention, and various modifications can be made within the scope of the claims.
[0037]
In the present invention, waste residues and the like in a reducing gasification melting furnace, and the resulting slag or metal after cooling to hot melt, as these slugs or metal can be used in roadbed material, in such waste disposal In the end, no residue is produced, so that the final disposal site, which is a landfill site, can be dispensed with.
[0038]
【Example】
Waste was treated using the waste treatment system of the present invention (FIG. 3). At that time, the residue generation rate was 0%.
For comparison, when waste treatment was performed with a conventional biomass energy device and a conventional carbonization device, the residue generation rates were 41% and 27%, respectively.
[0039]
【The invention's effect】
ADVANTAGE OF THE INVENTION According to this invention, the provision of the waste processing system which processes effectively the residue and other waste produced | generated with an oil-ized apparatus, a methane fermentation apparatus, and / or a carbonization apparatus was attained.
[0040]
Moreover, since a residue does not generate | occur | produce finally, the final disposal site which is a landfill place can be made unnecessary like the conventional apparatus.
[0041]
Furthermore, if the energy resources generated in the reductive gasification melting furnace, the oilification apparatus, the methane fermentation apparatus and / or the carbonization apparatus are effectively used, the waste treatment cost is remarkably improved.
[Brief description of the drawings]
FIG. 1 is a flowchart of a waste treatment system according to the present invention.
FIG. 2 is another flowchart of the waste treatment system according to the present invention.
FIG. 3 is a flowchart of a waste treatment system according to the present invention.
FIG. 4 is a schematic diagram of a waste treatment system according to the present invention.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 Waste treatment system 2 Oil refiner 3 Reductive gasification melting furnace 4 Diesel engine 5 Gas reforming process 6 Gas cleaning process 7 Gas engine 8 Power generation system 9 Electric power company
10 Biomass energy equipment
11 Methane fermentation equipment
12 Heat exchanger
13 Carbonization equipment
14 Steam generator

Claims (4)

ペットボトルやタイヤを含むプラスチック廃棄物等の石油製品や石炭製品を乾留した後に加熱溶融させて燃料油と残渣を生成する油化装置と、
植物、畜産物、魚貝類またはそれらの廃棄物、あるいは、畜産物等の糞などの汚物を含むバイオマス資源を、メタンを発酵させる温度に加熱保持してメタンガスと残渣を生成するメタン発酵装置と、
一般廃棄物、産業廃棄物、バイオマス資源などの炭素含有物を炭化・分解させて、炭化ガスおよび炭化物を生成する炭化装置と、
油化装置メタン発酵装置及び炭化装置生成した残渣を、燃料や資源として供給しかつ1000℃以上で高温溶融させて高温液状物とするとともに、炉内のガスを還元ガス化させる還元ガス化溶融炉と、
を具え、
高温液状物を冷却して得られたスラグおよび/またはメタルを路盤材などに活用するとともに、この還元ガス化溶融炉内で発生した還元ガスを比較的高温で回収して、高温ガスや燃料ガスのようなエネルギー資源として有効活用し、かつ、ガス化溶融炉で生成する還元ガス等のエネルギー資源や、メタン発酵装置、油化装置および炭化装置の少なくとも1つの装置で生成するエネルギー資源を、これらの炉および装置に相互に有効活用するように構成することにより、最終的な残渣発生率が0%であることを特徴とする廃棄物処理システム。
An oiling device for producing fuel oil and residue by dry-melting petroleum products and coal products such as plastic waste including plastic bottles and tires,
A methane fermentation apparatus that generates methane gas and residues by heating and holding biomass resources including plant, livestock products, fish and shellfish or wastes thereof, or wastes such as feces such as livestock products at a temperature at which methane is fermented;
A carbonization device that produces carbonized gas and carbide by carbonizing and decomposing carbon-containing materials such as general waste, industrial waste, and biomass resources;
Yuka device, a methane fermentation apparatus and carbonization apparatus resulting residue, as fuel and resources supplied vital 1000 ° C. or higher by hot melt with a high temperature liquid, reduced gasification melting of reducing gasification gas in the furnace A furnace,
With
The slag and / or metal obtained by cooling the high-temperature liquid material is used for roadbed materials, etc., and the reducing gas generated in this reductive gasification and melting furnace is recovered at a relatively high temperature, so that the high-temperature gas and fuel gas Energy resources such as reducing gas generated in a gasification and melting furnace and energy resources generated in at least one of a methane fermentation apparatus, an oilification apparatus, and a carbonization apparatus. The waste treatment system is characterized in that the final residue generation rate is 0% by being configured to be effectively used in each furnace and apparatus .
請求項記載の廃棄物処理システムにおいて、さらに、還元ガス化溶融炉内で発生した高温ガスの熱を利用して水蒸気を発生させる蒸気発生器を具え、かつ、蒸気発生器によって発生した水蒸気の熱を、メタン発酵装置に有効活用することを特徴とする廃棄物処理システム。2. The waste treatment system according to claim 1 , further comprising a steam generator that generates steam by using heat of the high-temperature gas generated in the reductive gasification melting furnace, and further comprising steam generated by the steam generator. A waste treatment system that effectively utilizes heat in a methane fermentation apparatus. 請求項1又は2記載の廃棄物処理システムにおいて、さらに、還元ガス化溶融炉内で発生した高温ガスの熱を利用して水蒸気を発生させる蒸気発生器を具え、かつ、蒸気発生器によって発生した水蒸気の熱をメタン発酵装置および炭化装置の少なくとも一方に有効活用することを特徴とする廃棄物処理システム。The waste treatment system according to claim 1 , further comprising a steam generator that generates steam by using heat of the high-temperature gas generated in the reduction gasification melting furnace, and generated by the steam generator. A waste treatment system characterized by effectively utilizing the heat of steam in at least one of a methane fermentation apparatus and a carbonization apparatus. 請求項1〜のいずれか1項記載の廃棄物処理システムにおいて、前記メタン発酵装置は、メタンを発酵させる温度に加熱保持するため、ガス化溶融炉で生成される高温排ガスを有効活用するように構成し、油化装置をさらに具える場合には、ガス化溶融炉および油化装置の少なくとも一方で生成される高温排ガスを有効活用するように構成し、炭化装置をさらに具える場合には、ガス化溶融炉および炭化装置の少なくとも一方で生成される高温排ガスを有効活用するように構成し、または、油化装置と炭化装置の双方をさらに具える場合には、ガス化溶融炉、油化装置および炭化装置の少なくとも一方で生成される高温排ガスを有効活用するように構成することを特徴とする廃棄物処理システム。The waste treatment system according to any one of claims 1 to 3 , wherein the methane fermentation apparatus heats and maintains the temperature at which methane is fermented, so that the high-temperature exhaust gas generated in the gasification melting furnace is effectively used. In the case of further comprising an oil generator, the high-temperature exhaust gas generated by at least one of the gasification melting furnace and the oil generator is configured to be used effectively, and when the carbonizer is further provided. The high-temperature exhaust gas generated in at least one of the gasification melting furnace and the carbonization apparatus, or when further comprising both the oilification apparatus and the carbonization apparatus, the gasification melting furnace, the oil A waste treatment system configured to effectively use high-temperature exhaust gas generated by at least one of a gasification device and a carbonization device.
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