JP4106087B2 - 無定形シリカ及び口腔用組成物 - Google Patents
無定形シリカ及び口腔用組成物 Download PDFInfo
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- JP4106087B2 JP4106087B2 JP50474597A JP50474597A JP4106087B2 JP 4106087 B2 JP4106087 B2 JP 4106087B2 JP 50474597 A JP50474597 A JP 50474597A JP 50474597 A JP50474597 A JP 50474597A JP 4106087 B2 JP4106087 B2 JP 4106087B2
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- Prior art keywords
- silica
- amorphous silica
- solution
- weight
- toothpaste
- Prior art date
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims description 147
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- 210000000214 mouth Anatomy 0.000 title claims 2
- 239000000606 toothpaste Substances 0.000 claims description 43
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- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 17
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- 238000000034 method Methods 0.000 claims description 12
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- 229910019142 PO4 Inorganic materials 0.000 description 2
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- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 1
- QLOKJRIVRGCVIM-UHFFFAOYSA-N 1-[(4-methylsulfanylphenyl)methyl]piperazine Chemical compound C1=CC(SC)=CC=C1CN1CCNCC1 QLOKJRIVRGCVIM-UHFFFAOYSA-N 0.000 description 1
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- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
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- 235000014749 Mentha crispa Nutrition 0.000 description 1
- 244000246386 Mentha pulegium Species 0.000 description 1
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- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
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- 229910052749 magnesium Inorganic materials 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
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- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 229940097886 phosphorus 32 Drugs 0.000 description 1
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- 229920005862 polyol Polymers 0.000 description 1
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- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 229960003500 triclosan Drugs 0.000 description 1
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- WGIWBXUNRXCYRA-UHFFFAOYSA-H trizinc;2-hydroxypropane-1,2,3-tricarboxylate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O WGIWBXUNRXCYRA-UHFFFAOYSA-H 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
- C01B33/18—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof
- C01B33/187—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates
- C01B33/193—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates of aqueous solutions of silicates
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/02—Amorphous compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/11—Powder tap density
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/16—Pore diameter
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/19—Oil-absorption capacity, e.g. DBP values
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
- C01P2006/82—Compositional purity water content
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/90—Other properties not specified above
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Cosmetics (AREA)
- Silicon Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP95304614.1 | 1995-06-30 | ||
| EP95304614 | 1995-06-30 | ||
| PCT/EP1996/002535 WO1997002211A1 (en) | 1995-06-30 | 1996-06-10 | Amorphous silicas and oral compositions |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JPH11508533A JPH11508533A (ja) | 1999-07-27 |
| JPH11508533A5 JPH11508533A5 (enExample) | 2004-08-05 |
| JP4106087B2 true JP4106087B2 (ja) | 2008-06-25 |
Family
ID=8221243
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP50474597A Expired - Fee Related JP4106087B2 (ja) | 1995-06-30 | 1996-06-10 | 無定形シリカ及び口腔用組成物 |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US5964937A (enExample) |
| EP (1) | EP0835223B1 (enExample) |
| JP (1) | JP4106087B2 (enExample) |
| KR (1) | KR100449132B1 (enExample) |
| CN (1) | CN1108274C (enExample) |
| AU (1) | AU718059B2 (enExample) |
| BR (1) | BR9609526A (enExample) |
| DE (1) | DE69612977T2 (enExample) |
| ES (1) | ES2158318T3 (enExample) |
| MX (1) | MX9800022A (enExample) |
| PL (1) | PL184365B1 (enExample) |
| RU (1) | RU2171781C2 (enExample) |
| TW (1) | TW460291B (enExample) |
| WO (1) | WO1997002211A1 (enExample) |
| ZA (1) | ZA965373B (enExample) |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9601084D0 (en) * | 1996-01-19 | 1996-03-20 | Unilever Plc | Amorphous silicas and oral compositions |
| FR2749576B1 (fr) * | 1996-06-06 | 1998-09-04 | Rhone Poulenc Chimie | Procede de preparation de silice susceptible d'etre utilisee dans les compositions dentifrices |
| FR2750692B1 (fr) * | 1996-07-05 | 1998-10-16 | Rhone Poulenc Chimie | Nouvelle silice abrasive, utilisable dans les dentifrices, son procede de preparation et compositions dentifrices la contenant |
| US6290933B1 (en) * | 2000-05-09 | 2001-09-18 | Colgate-Palmolive Company | High cleaning dentifrice |
| AU1029901A (en) * | 2000-10-16 | 2002-04-29 | Biocosmetics Sl | Use of olive oil in the preparation of a product for oral hygiene for eliminating or reducing bacterial plaque and/or bacteria in the mouth |
| EP1399121B1 (en) * | 2001-06-25 | 2008-11-05 | The Procter & Gamble Company | Oral care compositions |
| US6616916B1 (en) * | 2001-12-10 | 2003-09-09 | J. M. Huber Corporation | Transparent dentifrices |
| US7008617B1 (en) | 2001-12-10 | 2006-03-07 | J.M. Huber Corporation | Precipitated silicas |
| US6869595B2 (en) * | 2001-12-21 | 2005-03-22 | J.M. Huber Corporation | Abrasive compositions for clear toothpaste |
| US20030131536A1 (en) * | 2001-12-21 | 2003-07-17 | Kostinko John A. | Precipitated silica |
| GB0130907D0 (en) | 2001-12-22 | 2002-02-13 | Ineos Silicas Ltd | Amorphous silica |
| US8128911B2 (en) * | 2002-05-10 | 2012-03-06 | Colgate-Palmolive Company | Antibacterial dentifrice exhibiting enhanced antiplaque and breath freshening properties |
| EP1577263A4 (en) * | 2002-07-10 | 2010-04-14 | Tokuyama Corp | BLOCK OF EASILY DISPOSABLE FLEECE SKINIC ACID AND ITS MANUFACTURING PROCESS |
| JP2005053728A (ja) * | 2003-08-01 | 2005-03-03 | Dsl Japan Co Ltd | 高吸油性および高い構造性を有する非晶質シリカ粒子 |
| JP2005053744A (ja) * | 2003-08-05 | 2005-03-03 | Dsl Japan Co Ltd | 高吸油性非晶質シリカ粒子 |
| GB0322296D0 (en) * | 2003-09-23 | 2003-10-22 | Glaxo Group Ltd | Novel compositions |
| GB0400447D0 (en) * | 2004-01-09 | 2004-02-11 | Glaxo Group Ltd | Dentifrice compositions |
| US7267814B2 (en) * | 2004-11-24 | 2007-09-11 | J.M. Huber Corporation | High-cleaning/low abrasive silica and materials and dentifrice containing such materials |
| EP1868689B1 (en) * | 2005-03-21 | 2015-05-27 | Glaxo Group Limited | Alkyl sulfate free and orthophosphate free dentifrice composition comprising a fluoride source and a silica dental abrasive |
| RU2298399C2 (ru) * | 2005-04-25 | 2007-05-10 | Закрытое акционерное общество "Троя" | Состав для повышения функциональных резервов организма |
| GB0525369D0 (en) * | 2005-12-14 | 2006-01-18 | Ineos Silicas Ltd | Silicas |
| JP5756946B2 (ja) * | 2007-02-27 | 2015-07-29 | 熊野油脂株式会社 | 皮膚用洗浄剤 |
| GB0706787D0 (en) * | 2007-04-05 | 2007-05-16 | Glaxo Group Ltd | Novel use |
| US8551457B2 (en) | 2008-11-25 | 2013-10-08 | The Procter & Gamble Company | Oral care compositions comprising spherical fused silica |
| US8795637B2 (en) * | 2008-11-25 | 2014-08-05 | The Procter & Gamble Company | Oral care compositions with fused silica |
| WO2011130009A1 (en) * | 2010-04-14 | 2011-10-20 | Isp Investments Inc. | Oral care compositions |
| CN101830474B (zh) * | 2010-05-17 | 2012-01-11 | 浙江建业化工股份有限公司 | 白炭黑的制备方法 |
| WO2011150004A2 (en) | 2010-05-25 | 2011-12-01 | The Procter & Gamble Company | Oral care compositions and methods of making oral care compositions comprising silica from plant materials |
| MX344227B (es) * | 2011-06-17 | 2016-12-07 | Colgate Palmolive Co | Composiciones para el cuidado oral. |
| BR112015010146A2 (pt) | 2012-11-05 | 2017-07-11 | Procter & Gamble | sílica precipitada tratada com calor |
| ES2889579T3 (es) * | 2017-02-17 | 2022-01-12 | Imertech Sas | Uso de un mineral particulado para reducir la contaminación |
| EP3595626B1 (en) * | 2017-03-13 | 2021-10-13 | Unilever IP Holdings B.V. | Oral care compositions |
| US20230125516A1 (en) * | 2020-04-24 | 2023-04-27 | Tokuyama Corporation | Method for producing surface-treated silica powder, resin composition, and slurry |
| KR20230123986A (ko) | 2020-12-11 | 2023-08-24 | 피큐 실리카스 유케이 리미티드 | 연마 실리카 입자 |
| CN113336234B (zh) * | 2021-07-02 | 2023-10-27 | 确成硅化学股份有限公司 | 一种牙膏用低磨损摩擦型二氧化硅的制备方法 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3428425A (en) * | 1966-04-04 | 1969-02-18 | Monsanto Co | Method of preparing silica materials |
| US4191742A (en) * | 1974-05-22 | 1980-03-04 | J. M. Huber Corporation | Amorphous precipitated siliceous pigments and methods for their production |
| SE420596B (sv) * | 1975-03-25 | 1981-10-19 | Osaka Packing | Formad kropp av amorf kiseldioxid, eventuellt innehallande kalciumkarbonat, sett att framstella en formad kropp av amorf kiseldioxid samt partikel av amorf kiseldioxid for framstellning av en formad kropp |
| GR68943B (enExample) * | 1977-12-20 | 1982-03-29 | Huber Corp J M | |
| US4244707A (en) * | 1978-09-28 | 1981-01-13 | J. M. Huber Corporation | Abrasive composition for use in toothpaste |
| US4243428A (en) * | 1979-01-24 | 1981-01-06 | Donnet Jean Baptise | Processes for the manufacturing of precipitated silica |
| US4312845A (en) * | 1979-09-10 | 1982-01-26 | J. M. Huber Corporation | Method of producing amorphous silica of controlled oil absorption |
| US4435380A (en) * | 1982-01-29 | 1984-03-06 | Lever Brothers Company | Humectants for clear gel dentifrice compositions |
| JPS59163306A (ja) * | 1983-03-08 | 1984-09-14 | Taki Chem Co Ltd | 歯磨用シリカ基剤及びその製法 |
| GB8604985D0 (en) * | 1986-02-28 | 1986-04-09 | Unilever Plc | Precipitated silicas |
| DE3639845A1 (de) * | 1986-11-21 | 1988-06-01 | Degussa | Faellungskieselsaeuren, verfahren zu ihrer herstellung und verwendung |
| GB8721644D0 (en) * | 1987-09-15 | 1987-10-21 | Unilever Plc | Silicas |
| EP0368130B1 (en) * | 1988-11-09 | 1994-05-04 | The Procter & Gamble Company | Oral compositions |
| FR2649089B1 (fr) * | 1989-07-03 | 1991-12-13 | Rhone Poulenc Chimie | Silice a porosite controlee et son procede d'obtention |
| US5225177A (en) * | 1990-01-19 | 1993-07-06 | J. M. Huber Corporation | Dentifrice abrasives and compositions |
| EP0495039B2 (en) * | 1990-08-06 | 2003-10-08 | INEOS Silicas Limited | Silicas |
| US5120528A (en) * | 1991-06-12 | 1992-06-09 | Block Drug Company, Inc. | Taste preserving, mild oral hygiene compositions |
| US5108734A (en) * | 1991-07-01 | 1992-04-28 | Colgate-Palmolive Company | Prophy mouthfeel dentifrice having low RDA value |
| KR960010781B1 (ko) * | 1991-10-02 | 1996-08-08 | 유니레버 엔브이 | 실리카 |
| ATE142170T1 (de) * | 1992-10-28 | 1996-09-15 | Crosfield Joseph & Sons | Kieselsäuren |
| US5651958A (en) * | 1995-05-02 | 1997-07-29 | The Procter & Gamble Company | Dentifrice compositions |
| US5647903A (en) * | 1995-10-03 | 1997-07-15 | Mcgill; Patrick D. | Microporous high structure precipitated silicas and methods |
-
1996
- 1996-06-10 RU RU98101722/12A patent/RU2171781C2/ru not_active IP Right Cessation
- 1996-06-10 PL PL96324311A patent/PL184365B1/pl unknown
- 1996-06-10 KR KR10-1997-0709859A patent/KR100449132B1/ko not_active Expired - Fee Related
- 1996-06-10 JP JP50474597A patent/JP4106087B2/ja not_active Expired - Fee Related
- 1996-06-10 ES ES96918686T patent/ES2158318T3/es not_active Expired - Lifetime
- 1996-06-10 WO PCT/EP1996/002535 patent/WO1997002211A1/en not_active Ceased
- 1996-06-10 DE DE69612977T patent/DE69612977T2/de not_active Revoked
- 1996-06-10 MX MX9800022A patent/MX9800022A/es not_active IP Right Cessation
- 1996-06-10 AU AU61262/96A patent/AU718059B2/en not_active Ceased
- 1996-06-10 BR BR9609526A patent/BR9609526A/pt not_active IP Right Cessation
- 1996-06-10 CN CN96195114A patent/CN1108274C/zh not_active Expired - Fee Related
- 1996-06-10 EP EP96918686A patent/EP0835223B1/en not_active Revoked
- 1996-06-18 TW TW085107375A patent/TW460291B/zh not_active IP Right Cessation
- 1996-06-25 ZA ZA9605373A patent/ZA965373B/xx unknown
-
1997
- 1997-12-23 US US08/996,867 patent/US5964937A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| AU6126296A (en) | 1997-02-05 |
| KR100449132B1 (ko) | 2004-11-16 |
| CN1189142A (zh) | 1998-07-29 |
| EP0835223A1 (en) | 1998-04-15 |
| JPH11508533A (ja) | 1999-07-27 |
| AU718059B2 (en) | 2000-04-06 |
| ZA965373B (en) | 1997-12-25 |
| PL324311A1 (en) | 1998-05-25 |
| PL184365B1 (pl) | 2002-10-31 |
| EP0835223B1 (en) | 2001-05-23 |
| ES2158318T3 (es) | 2001-09-01 |
| WO1997002211A1 (en) | 1997-01-23 |
| US5964937A (en) | 1999-10-12 |
| BR9609526A (pt) | 1999-02-23 |
| CN1108274C (zh) | 2003-05-14 |
| DE69612977T2 (de) | 2001-09-06 |
| TW460291B (en) | 2001-10-21 |
| MX9800022A (es) | 1998-03-31 |
| KR19990028541A (ko) | 1999-04-15 |
| DE69612977D1 (de) | 2001-06-28 |
| RU2171781C2 (ru) | 2001-08-10 |
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