JP4003333B2 - Storage, fan device - Google Patents

Storage, fan device Download PDF

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Publication number
JP4003333B2
JP4003333B2 JP2519499A JP2519499A JP4003333B2 JP 4003333 B2 JP4003333 B2 JP 4003333B2 JP 2519499 A JP2519499 A JP 2519499A JP 2519499 A JP2519499 A JP 2519499A JP 4003333 B2 JP4003333 B2 JP 4003333B2
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Japan
Prior art keywords
iodine
sustained release
release element
fan
air
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JP2519499A
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Japanese (ja)
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JP2000227273A (en
Inventor
英文 野田
健造 高橋
尚士 横家
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Mitsubishi Electric Corp
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Mitsubishi Electric Corp
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D2317/00Details or arrangements for circulating cooling fluids; Details or arrangements for circulating gas, e.g. air, within refrigerated spaces, not provided for in other groups of this subclass
    • F25D2317/06Details or arrangements for circulating cooling fluids; Details or arrangements for circulating gas, e.g. air, within refrigerated spaces, not provided for in other groups of this subclass with forced air circulation
    • F25D2317/062Details or arrangements for circulating cooling fluids; Details or arrangements for circulating gas, e.g. air, within refrigerated spaces, not provided for in other groups of this subclass with forced air circulation along the inside of doors
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D2317/00Details or arrangements for circulating cooling fluids; Details or arrangements for circulating gas, e.g. air, within refrigerated spaces, not provided for in other groups of this subclass
    • F25D2317/06Details or arrangements for circulating cooling fluids; Details or arrangements for circulating gas, e.g. air, within refrigerated spaces, not provided for in other groups of this subclass with forced air circulation
    • F25D2317/066Details or arrangements for circulating cooling fluids; Details or arrangements for circulating gas, e.g. air, within refrigerated spaces, not provided for in other groups of this subclass with forced air circulation characterised by the air supply
    • F25D2317/0664Details or arrangements for circulating cooling fluids; Details or arrangements for circulating gas, e.g. air, within refrigerated spaces, not provided for in other groups of this subclass with forced air circulation characterised by the air supply from the side

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  • Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
  • Cold Air Circulating Systems And Constructional Details In Refrigerators (AREA)

Abstract

PROBLEM TO BE SOLVED: To sterilize or make an atmosphere in a storage cabinet antibacterial and to suppress a mildew by mounting a plurality of particles of an iodine antibacterial material on a surface of a base material in a channel of a gas circulating by a fan disposed in the cabinet and gradually exhausting iodine from this gradually discharging element into the gas. SOLUTION: In a vegetable storage cabinet 1, a blower 2 with an antibacterial function provided integrally with a gradually discharging element 3 in which an iodine resin having an antibacterial action or a mildewproofing action is fixed to a porous base material with a binder is provided. Iodine molecules discharged from the resin are diffused and supplied to the overall cabinet by a flow of the circulating air to prevent a growth of microorganisms or the like floated in the air in the cabinet, thereby holding in the cabinet clean. Thus, a corrosion or the like can be suppressed even without lowering a temperature, freshness of the vegetables can be held for a long period without cooling, and an offensive odor from a perishable material due to a growth of the microorganisms can be suppressed.

Description

【0001】
【発明の属する技術分野】
この発明は冷蔵庫や野菜貯蔵庫のように生鮮物を保存するための貯蔵庫や、黴の発生しやすい図書収納庫や地下室、押し入れのように物を貯蔵したり、貯蔵しながら作業するような貯蔵庫内の雰囲気の殺菌や黴発生を押さえるものである。
【0002】
【従来の技術】
近年、地球環境保全の一環として省エネルギーが人類の最重要課題となっている。このため居住空間等の高気密、高断熱化が進められる一方、室内空気の汚染の問題がクローズアップされてきている。また他方で大腸菌O-157のように食べ物の安全性の問題が増大する中で、生鮮野菜や食品に対する要求が増えて冷蔵やクーリングの用途が拡大しエネルギーの必要性が増えるとともにこれらの食料に対する抗菌、黴防止の需要が高まっている。
従来、輸送用コンテナ、市場などの業務用野菜の貯蔵庫等は鮮度を保つために外気温度よりも温度を下げて保存するのが普通である。また一般家庭用冷蔵庫では野菜室や冷蔵室に生鮮物を収納し、微生物が繁殖しにくい低い温度の状態で鮮度を保つ。
【0003】
倉庫型冷蔵庫の従来の例として特開昭57−16768号公報のようなものが知られている。野菜などの農作物を大量に冷却しながら保存する場合、温度を精度よく設定するばかりでなく多くの野菜を均等に冷やすため庫内の圧力差を利用してむらなく冷却する構成が記載されている。
【0004】
一方、一般家庭用冷蔵庫では野菜室や冷蔵室に生鮮物を低温で保存するが、食品の安全性を保つため微生物や黴が繁殖しにくい冷蔵庫の技術として特開昭61−228283号が知られている。この構成を図15、図16に示す。図15は冷蔵庫の構成図で、71は冷蔵庫、72は冷凍室、73は冷蔵室、74は野菜収納室、75は冷蔵庫内に冷気を循環させるファン76の冷気を冷却する冷却器、77は冷蔵庫内に設けられた冷凍食品を解凍させる特定の容器、78は防臭、防黴ユニットで、ファンから出た風を通過させて特定ユニットへ吹き込んでいる。図16は防黴ユニットの構成図で、80は防臭ユニットでハニカム状に形成した活性炭、81は防黴ユニットでポ−ラスな材質例えば多孔質に形成したセラミックなどに常用食用植物から抽出した抗菌作用のあるフィトンチッドを含浸させてある。82はフレーム、83は防臭ユニットの吸着効果を持続させるため防黴ユニットとの間に設けたポリエチレンシートのカーテンでファンが運転したときだけ両方のユニットを通過して風がながれ特定容器に入ることにより、特定容器内の食品や冷蔵庫内の壁面などに黴が発生することを防止したり、解凍食品特有の匂いを防ぐ。
【0005】
また殺菌性を有する有機高分子成形物として沃素を使用した例は特公昭60−1337号公報の技術が知られている。
【0006】
【発明が解決しようとする課題】
業務用の冷蔵倉庫は大きなスペースを冷蔵するため多大な電力を必要とし、また数の多い家庭用冷蔵庫は家庭内に於いて冷蔵庫の占める電力量は大きいので、地球温暖化防止、炭酸ガス放出量削減のためにも、これらの機器の省電力化の要求が強い。しかしながら従来の野菜貯蔵庫や冷蔵庫では単に冷やす事によってのみ鮮度を保つ方式であるため、こまめに制御して温度を維持する以外の省エネルギーを実現できなかった。悪臭対策としても多くの案が提案されているが効果が長続きしなかったり、複雑な構造や高いコストにより実用化が困難であった。更にフィトンチッドによる抗菌、防黴も効果が長続きしないという欠点があった。
また、物を貯蔵するスペースが広く取れず、居住空間等の高気密、高断熱化等から、単なる換気によっては細菌や微生物の繁殖、黴の発生を押さえることが難しくなっている。これに対しエアコンや空気清浄器を設けると家庭内や病院、工場、オフィス、市場、商店等の消費電力が大きくなり地球温暖化防止、炭酸ガス放出量削減に大きな問題が残るという課題があった。
【0007】
この発明は上記のような問題点を解消するためになされたもので、消費電力が小さい簡単な構成により、冷蔵庫や野菜貯蔵室などの生鮮物を保存するための貯蔵庫や黴の発生しやすい図書収納庫や地下室、押し入れのように物を貯蔵したり、貯蔵しながら作業するような貯蔵庫内の雰囲気の殺菌、抗菌を行うことが出来、黴発生を押さえる装置を提供しようというものである。
また冷却せずに鮮度を保つエネルギーの非常に小さな装置を提供しようというものである。また小型でどこにでも設置して庫内の雰囲気の殺菌、抗菌を行うことが出来、黴発生を押さえる装置を提供しようというものである。
【0008】
【課題を解決するための手段】
請求項1の貯蔵庫は、庫内に配置され庫内の気体を循環させるファンと、ファンにより循環する気体の流路に配置され粒体である沃素系抗菌材料と、沃素系抗菌材料の複数の粒体を基材表面に取り付けこの粒体から沃素を徐々に気体に放出する徐放エレメントと、この徐放エレメントの表面に庫内の貯蔵物が接触することを防ぐ接触防止板とを備え、徐放エレメントから徐々に放出され沃素により庫内の殺菌または防カビを行うものである。
【0009】
請求項2のファン装置は、ファンにより流れる気体の流路に配置され沃素を放出するような粒体である沃素系抗菌材料と、沃素系抗菌材料の複数の粒体を基材表面に固定手段にて固定させ、この粒体から沃素を徐々に気体に放出する徐放エレメントと、この徐放エレメントの沃素系抗菌材料を濡れた状態に維持する給水装置と、ファンと徐放エレメントを内部に収納するとともに、徐放エレメントから放出される沃素を含む気体をファンにより外部に吐出する吐出口を有するケーシングとを備えたものである。
【0021】
【発明の実施の形態】
実施の形態1.
以下、本発明の一実施例について図を用いて説明する。図1は本発明の一実施例である家庭用の野菜貯蔵庫の概念図であって、野菜や生鮮食料品を冷やさずに長期間保存する構成を示す。1は野菜貯蔵庫、2はファン4を内蔵した抗菌機能付き送風機、3は後で説明する沃素樹脂を坦持した徐放エレメント、5は野菜などの食品ケースである。この貯蔵庫には内部の空気を冷却する装置や機器の構成は存在しない。ファン1を連続的または間欠的に回転させ、これによる風速を受けて徐放エレメントから沃素分子が放出される。図2は抗菌機能付き送風機の構造図を示し、ケーシング9が貯蔵庫1の壁に固定されている。ファン4はモータ5によって駆動されるが、貯蔵庫の図示していない扉が閉鎖され、且つ、タイマーによって設定された時間間隔で運転が行われる。
【0022】
図3は徐放エレメントの構造の一部で表面に抗菌処理した繊維の拡大図であり。10は沃素系樹脂で固体粒体形状をしている。次に図4は徐放エレメント3の構造図であり、11はプラスチック性のエレメント枠15により固定された不織布である。多孔性基材である厚さ5mmの不織布11の表面にあらかじめ酢酸ビニル系エマルジョン接着剤を噴霧したバインダー材料の薄膜が形成されこのバインダー材料の薄膜を介して粒状の沃素系樹脂である固体粒子1mm以下ぐらいの径で100ミクロン以上が望ましいが多孔性基材である不織布の表面にまんべんなく被覆してある。多孔性基材として不織布や発泡ウレタンフォーム、ファイバー糸を組み合わせたもの等でよく、バインダー材料としてエアロゾルや水性エマルジョンタイプの接着剤などを使用する。
【0023】
本発明で検討した沃素系抗菌材料は、4級アンモニウムイオンを官能基とする陰イオン交換樹脂の3よう化物イオンの塩である。これは特殊な条件で沃素を陰イオン交換樹脂に接触させ含浸させ塩化物の形の陰イオン交換樹脂の塩素イオンと3よう化物イオンを交換する過程を経て製造するもので、3よう化物イオンは官能基である第4級アンモニウム基と化学的に結合しており、更に樹脂の架橋構造に支持される構造で市販されているペレット状のものでは沃素イオンはほとんど除放されない。この沃素系抗菌材料は窒素のプラスイオンを持つ樹脂で、このプラスイオンに3よう化物イオンがイオン結合しており、沃素が簡単に離脱しないものである。
【0024】
しかしながらこの沃素系抗菌材料の樹脂は5mm以上の径ではほとんど除放を起こさないが粒体が小さくなり、体積に比べ表面積の割合がある程度以上になると自然にこの表面から徐々に放出することになる。この粒体は径が小さくなるほど体積に対する表面積の割合が著しく大きくなり放出量が大きくなって寿命が短くなりすぎるのであまり細かい粒子にすると実用的でなくなる。沃素は樹脂の中でよう化物イオンとして安定するが、多価のよう化物イオンが活性のある沃素分子を樹脂から遊離する条件は原子価大きいほど重くなるので5価や7価の場合は大きなペレットでも自然に徐放することになる。しかもこの徐放量は沃素系抗菌材料に流す風量、すなわち表面に当てる風速が高ければそれだけ多くなる。なお粒体を形成する樹脂は沃素分子を通過させる樹脂であればよく例えば酢酸ビニル樹脂を使えばよい。
【0025】
しかしながら原子価の大きなよう化物イオンの大きなペレットでは空気の流れを妨げるためどこにでも設置できず使いにくい構造となる。また早く徐放してしまい、取り替える寿命上実用的でないという問題があるので、本発明では徐放が少ない3価のよう化物イオンを採用しこれを体積に比べ表面積のおおきな徐放しやすいように小さな粒体として基材にバインダーで固定することにした。これにより通風領域に様々な形で配置でき、多くの風量を全体で短い配置の距離に受けたり、少ない風量を長く分布させた配置で受けたり出来、用途に応じた構造や配置が可能になる。また寿命を考えたファンの風量で徐放させる事が出来る。
【0026】
次に本発明の特徴である動作について説明する。図1で示される野菜貯蔵庫1では抗菌作用あるいは防黴作用を有する沃素系樹脂を厚さが5mm程度多孔質基材にバインダーで固定した徐放エレメント3を一体に設けた抗菌機能付き送風機2を設けてある。この様に沃素を徐放する機能性材料を多孔質基材に坦持した徐放エレメントを用いこれに送風することにより樹脂から放出された沃素分子が循環する空気の流れにより野菜貯蔵庫全体に拡散供給され、庫内の空中を浮遊している微生物などの繁殖を防止し庫内を清潔に保つ。これにより温度を下げなくとも腐食等を押さえ野菜の鮮度を長期間保つことが出来、微生物の繁殖による生鮮物からの悪臭も押さえることが出来る。また生鮮物に付着した菌の殺菌も可能となる。
【0027】
一般に沃素の化学反応力は塩素に比べてかなり弱いが、殺菌力は強く、細菌、ウィルス、カビ、などに対し有効で即効性の殺菌作用を有する。沃素化合除菌樹脂が飲料水用浄水器に使われる等水浄化に使われてきている。
本発明では貯蔵庫内で使用することにより徐放された抗菌活性分子である沃素分子が塵埃に吸着したり反応することなく庫内の隅々まで移動し細菌などと沃素分子を交換することにより殺菌して内部を清潔に保つ。除放エレメントに流れる気体の流量を沃素が徐々に放出する流量となるように低い回転数でファン回転させることにより、徐放量を押さえ除放エレメントの寿命を長くすることが出来る。
更にこのファンの運転を貯蔵庫の扉が開放された後、扉閉の状態を検出し間欠的にモータを回転させ空気を循環させることにより、風の流れが無い状態では徐放が非常に小さくてすむため粒体からの徐放の寿命を更に延ばすことが出来る。なお扉の開放時には外部を浮遊している菌などを吸い込まないようにファンの回転を停止させておく。
【0028】
図5には図4と同様に不織布をプリーツ上に織り込んだ除放エレメント3の構造を示す。これにより図4のような平板上に比べ不織布の面積が拡大し、この不織布を通過する風圧が小さくなり、一層徐放量を少なくすることが出来寿命を延ばすことが出来る。もちろんこの徐放エレメントとして格子状に設け風の流れに平行な形で設けてもよいことは当然である。なお図1の抗菌機能付き送風機は一体として貯蔵庫の壁面に取り付けた構造を示すが、この送風機を天井や側壁だけでなく、吸気と排気を庫内の空中に開放する形で床面においておくだけでもよい。言い換えると台所の戸棚や扉のついた物入れ、収納庫の中に置いておくだけで収納庫内の生鮮物を長期に保存する効果が得られる。また図1の野菜ケースは出来るだけ食品の表面を露出させ沃素分子が接触可能な網状の棚が望ましい。これにより棚との接触面に対しても菌や黴が繁殖する余地がなくなる。
【0029】
以上のようにこの発明では温度を下げる装置、例えば冷蔵庫に使われている冷凍サイクルのように冷媒を圧縮機で加圧し膨張させて低温を得るような、圧縮機やこの圧縮機を冷やすファンを設けたり熱交換器等を設ける必要が無く、また温度を低く保つ構造も不要であり、非常な簡単な構造ですみ、地球環境に影響を与える冷媒を使う必要も無い。また、ファンを低速でまわすだけで制御も簡単なため、大幅なエネルギー削減が可能となる。これにより家庭用の小さな装置により野菜などの生鮮物を腐らせたりせずパンなどをかびたりさせずに保存したり、大きな業務用の装置でも安心して保存できる。また細菌について心配しながら生鮮物を取り扱ったり料理するなどの煩わしさから開放される。ドアの開閉に連動させドアを開けたときは運転停止するようにしておけば更に有効となる。また保冷車の場合温度を下げる装置が必要となり運搬すべき積載物の重量に制限があったがこの発明の構造ではこのような制限が不要となる。
【0030】
図6に徐放エレメントの沃素徐放量の風速依存性に関する特性図を示す。この特性図は図2で示すファン4の吸い込み側に徐放エレメント3を設けた構成で徐放面が30センチメートル角の徐放エレメントから徐放される沃素の重量を風速0.2−1.0m/sの範囲で測定した結果を表しており、風速0.5m/s以下では徐放量は少ないが0.5m/sを超えると急速に徐放量が増える。すなわち狭い庫内やファンを連続的に運転するような場合は徐放エレメントへ0.5m/s以下で有効な風速を与えればよいことになる。一方6畳相当の閉鎖された部屋の中で風速0.8m/sで運転した場合、室内の空気に含まれる沃素濃度は約0.05ppm程度であり高い防かび効果が得られた。湿度85パーセント以上の条件で部屋の中に食パンを放置したところ6日間でかびが食パン全面を覆う状況に対し徐放エレメントでの徐放により2週間以上でも問題無いことが判明した。すなわち広い室であってもこの程度の風速で十分であり、1m/s程度以上の風速にしないことが徐放エレメントの寿命上重要といえる。
【0031】
実施の形態2.
実施の形態1では冷却機能を持たないで温度を低くせずに保存する構成を示したが、冷蔵庫のように冷気で食品を冷却する構成と併用できることは当然である。図7は冷蔵庫の庫内を扉側から見た説明図である。17は庫内の空気を庫内背面に設けた冷却用熱交換器に吸い込む冷気吸込風路、18は冷却された空気を庫内へ側面から吹き出す側面冷気吹出口23の風路である側面例気風路、19は側面への冷気吹き出し量を調整する側面用ダンパ、21は冷蔵庫本体、24は天井冷気吹き出し口25への風路である天井ダクト、26は冷蔵室、28は背面用冷気通路。31は冷凍室と冷蔵室の間を仕切る断熱仕切り壁を示す。
【0032】
図8は冷蔵庫の一部を断面にて見た説明図である。27は冷蔵庫の扉22に設けられた扉ポケット、34は扉22と冷蔵庫本体21と仕切り壁31により構成される庫内の温度を維持する断熱材、36は食品を載せる棚、35は背面から冷気を吹き出す吹き出し口、40は除放エレメント3を収める凹部である。図9は扉内側のドアポケットを示す概念図であり、47はドアポケット27にならべた食品である被冷却物である。、
冷蔵庫には冷気を循環させるファンが設けられており、このファンにより空気が循環している。この循環する空気の一部を利用して除放エレメントから沃素分子を冷蔵庫に内部に拡散することが出来る。庫内の天井や側面や背面には冷気を吹き出す吹き出し口が一般に存在し、また、底面には冷気を吸い込む吸い込み口が存在しこの5面は比較的風量が多くなる。
【0033】
一方残された扉の面には冷気が循環するが、ここにはポケット部が存在し、冷気の循環には障害になるとともに、このポケットには冷却される被冷却物47がおかれ、其の後ろである扉の内面には多くの風量が流れることはない。すなわち貯蔵物により冷気の流れが妨げられる。この様にポケットの後ろの壁であってしかも図7、図8に図示されているように上のポケットの直ぐ下は庫内でもっとも風が回りにくいところであり、風量が低ければ低いほど徐放量が少なくなるので長時間の寿命が確保されるとともに、冷気は庫内を拡散して循環しているので抗菌やかび対策には効果的である。
【0034】
すなわち沃素を除放する抗菌樹脂の粒体を固定した基材を直接冷蔵庫のドアポケットに貼り付けたり、扉内板に設けた凹部に収納させて冷蔵庫内の気流により沃素を冷蔵庫内に除放し庫内の殺菌効果を高めて生鮮物の鮮度を長期間保つものである。なお家庭用の冷蔵庫の場合、庫内全体に冷気を循環させるためファンの回転数が高いが、ドアポケットの扉に近い部分は貯贓物を冷却した冷気が間接的に回り込む個所であり除放量は少なくてすむ。また一般にファンは庫内の温度が上がったときに回転させる。場合によっては熱交換器の霜取り後、起動性改善のためファンだけまわすケースもあるが短時間である。また冷蔵庫の扉が開放されているときは回転させない。以上より徐放の寿命を長くするとともに閉鎖された空間を循環させるため徐放された沃素分子を無駄にすることなく効果的な殺菌が行える。徐放エレメントを設置する場所としてドアポケットに限られず冷気の流路で、風速の小さい場所であればよく、例えば庫内に限らず冷気を冷却する冷却器の近傍に設けてもよい。
【0035】
図10は徐放エレメントの他の構造例で、13は接触防止板である。ドアポケットに取り付けた場合徐放エレメントの基材表面に固定した抗菌樹脂の粒体が貯蔵物によりあたったり、こすれたりしてとれる恐れがある。これに対し空気は流通するが食品などが当たらないように接触防止を行えばよい。図示のものだけでなく網状であっても、また貯蔵物側は閉鎖した形で扉内壁との間に風を通してもよい。
図11は徐放エレメントの別の構造で、6は上部と下部に設けたスリット、14は徐放エレメントのスリット以外を閉鎖する閉鎖板である。箱体の中に抗菌樹脂の粒体を表面に固定した基材を収納し、上端と下端に細い通風スリットを設ける。このような構成をとれば庫内のどこに設置しても除放エレメントには循環される冷気の極一部しか通らないことになる。すなわちスリットの幅を流れる風量に必要な幅に選択することにより、除放エレメントに近接して配置され徐放エレメントに流れる気体の流量を調整する調整手段を設けた事になる。但し、図の構造では徐放エレメントを交換するため閉鎖板14を取り外せるようになっている。また、抗菌樹脂の粒体は徐放によって寿命がなくなると、表面の色調が変化する。従って徐放エレメントはこの表面を見ることにより取り替えが必要かどうかを知る事が出来る。これに対し徐放エレメントを完全に閉鎖しておくと表面を点検できない。図11の閉鎖板は手がけ91により閉鎖板を上下に動かすことが出来、内部のエレメントをチェックできる。なおペレット上の沃素イオン交換樹脂は黒く、これを粉末に近づけると茶色に近くなり、沃素が抜けるとベージュ色に変化する。表面を閉鎖させる場合、沃素を透過させない透明なまたは中の見えるプラスチックフィルムやシート等で表面をカバーしてもよい。徐放エレメントの寿命を確認するため表面の点検は、この徐放エレメントを扉に設けておくと最も簡単であることは言うまでもない。
【0036】
実施の形態3.
図12は野菜を保管する冷蔵倉庫に本発明を適用した例である。41は冷却用送風機42により送風される空気を冷却する冷却器、43は差圧を発生させパレット50に乗せられた野菜7を積み上げたブロックの中を循環させる通風を行う循環用送風機、44は冷却器41に配管開閉手段45と冷媒などの熱媒体を調整する調整手段46により冷熱を供給する冷熱源である氷蓄熱槽、49は貯蔵庫48の中の冷却された風を循環させる導風板である。図13は野菜倉庫48の中の循環用送風機43に隣接して配置され沃素を徐放する徐放エレメントの構造で、ハニカム状の厚紙53の表面に抗菌樹脂の粒体が固定されている。また、図12の野菜倉庫48の床面には別の例として徐放エレメントを内蔵して抗菌機能付き送風機58がおかれている。
【0037】
図12において野菜倉庫である貯蔵庫48の中では冷却器41と送風機42により庫内の温度を貯蔵物に適した低い温度に保つ事が出来る。また、循環用送風機43により積み上げられた野菜全体にたいし均等に冷却された空気を通して鮮度を保つことが出来る。一方抗菌樹脂を表面に固定した徐エレメント3は沃素分子を除放しており、この沃素は野菜倉庫内部全体に空気の循環を通して拡散し野菜の鮮度を保っている。業務用の場合鮮度維持が生命であり、これに対し冷却に対しては熱源機側に設けられた図示されていない別の熱源と氷蓄熱の両方により熱伝達媒体が供給可能に設けられており、どのような場合にも、すなわち一方が急に停止しても他方が冷却器に冷媒を供給して冷気を供給することが出来るようにしている。また徐放エレメントはハニカム状の構成により差圧を減らさずに循環される送風の中に除放を行うことが出来る。
【0038】
もし徐放量が少ないような場合やバックアップ体制が必要であればポータブルタイプの徐放エレメントを内蔵した抗菌機能付き送風機58を床上に設置し動作させればよい。あるいは、徐放エレメント3を設けずに抗菌機能付き送風機58のみを設けてもよい。これにより冷却用ファン42と、循環用ファン43と、徐放用のファン装置58をそれぞれ独立させて運転できるようになる。貯蔵する生鮮物や他の貯蔵品の種類に応じて、あるいは庫内の温度に応じて冷却用ファンや冷熱源から冷媒の循環を止めることが出来る。これにより消費電力を大幅に減らすことが可能である。また貯蔵庫の内部で作業をしたり貯蔵品を出し入れする場合には徐放用のファン装置58を停止すればよい。沃素は人体に不可欠な物であるとともに除放される量が少なく全く問題が無いが、特有な匂いがあり不快な場合はこのファンだけ止めておけばよい。
【0039】
この貯蔵庫は、沃素を除放する徐放エレメントに気体を循環させるファンと貯蔵物に気体を循環させるファンと空気の冷却を行う装置を別個に独立して設けたものでこれにより使い勝手が良く様々な使い方が可能になり、またエネルギーを大幅に減らすことが出来る。但しこの貯蔵庫では、沃素を徐放する徐放エレメントに気体を循環させるファンと貯蔵物に気体を循環させるファンとを少なくとも所定時間同時に運転させて徐放された沃素イオンが貯蔵庫の隅々まで、あるいは貯蔵された生鮮物に十分に拡散されて行き渡る必要がある。
【0040】
図12の野菜冷蔵倉庫でも、図7の家庭用冷蔵庫でも冷媒を循環させる圧縮機やポンプなどの駆動のために電子制御回路が設けられている。この回路には交流商用電源より直流を作るトランス、制御電源整流回路、庫内の温度制御及び圧縮機を駆動する制御信号を作成するマイクロコントローラ、スイッチやトランジスタインバータ、ゲートアンプ、ファン駆動用インバータなどがあり、これらのインバータはモスフエットや還流ダイオードにより回路が構成されている。庫内に設けられた温度センサーの温度と温度調整回路に設定された温度とを比較して庫内の温度が設定より高い場合はマイクロコントローラが圧縮機の周波数を高く回転させるように指令を出す。設定温度が高い場合は圧縮機を停止させる。庫内の空気を循環させるファン用のモータに対しても圧縮機の運転とほぼ同期させてマイクロコントローラの指令で運転される。扉の開閉に連動させてファン用のモータの運転の指令をやはり同様にマイクロコントローラから出される。各ファンがそれぞれ独立して設けられている場合はマイクロコントローラに設けられたタイマーにより各ファンの運転の時間をあらかじめ設定して置くことによりそれぞれ自由に運転可能となる。
【0041】
実施の形態4.
図14は本発明の抗菌機能付き送風機の他の例を示す構造図であり、59は水を満たした水タンク、3は沃素系樹脂を坦持するとともに水タンク59の水を滴下させる徐放エレメント、64は徐放エレメント3を濡らした水を機外へ排水可能なように溜めるドレンパン、63はモータによりファン4を回転させて吸気口61から空気を吸い込み排気口62へ吐き出す送風機、58は空気清浄器である。なお吸気口61から内部を除くことにより徐放エレメントの沃素系樹脂10の表面を除くことが出来る。
【0042】
図14に示すように徐放エレメント3の上に水タンクを設けてあり、水タンク59から徐放エレメントに水を供給しこの徐放エレメントを濡れた状態にして、送風機13によってこの徐放エレメントに風を通過させる。この構造では徐放エレメントが乾燥している場合に比べ徐放エレメントから沃素が放出されにくいので空気循環式にして機外の空気を清浄する空気清浄器としている。すなわち、書庫や貯蔵庫である野菜保存室や冷蔵庫の中の空気を送風機の運転によって空気清浄器の中に取り込み、濡れた徐放エレメントと接触させて殺菌を行うものである。今までの説明のように主として空気中に沃素分子を除放させて室内や庫内に拡散させて庫内の貯蔵物を殺菌、抗菌する方法ではなく、機外である庫内の空気を送風機により取り込んで基材の中で、もしくは水を介して殺菌や抗菌を行うもので水中に存在する沃素分子を利用して空気中など機外に放出したくない条件の場所や時期に使用可能であり、すなわちいつでも、どこでも、何も気にせずに空気清浄器として使える。
【0043】
沃素を徐放する機能性材料を基材に坦持させた徐放エレメントを水で濡らして空気を循環させてこの徐放エレメントに接触させる構造にしたので、ペレットの大きさとして市販の物をそのまま使用してもよい。
徐放エレメントに給水する給水装置として除放エレメントの上方に水タンクを設け、水タンクの底部にあけた給水口から水を滴下させる構造を示したが給水管と排水管によって水を循環させる構成でもよい。空気中に浮遊する菌や黴の胞子を水に取り込んで水の中に徐放された沃素イオンにより、また沃素樹脂に菌を引き寄せて殺菌できる。この発明の構造で給気口に塵埃除去用のフィルターを設けることにより水は沃素により清浄に保てるので水を循環させるだけで良い。但し空気清浄器58のファンや徐放エレメントを収納しているケーシング9の側面に窓を設けておけば沃素系樹脂の表面を見ることが出来る。窓は開閉蓋でも透明な窓用の材料で覆ってもよい。また水の蒸発分の補充が出来るような蓋と兼用させてもよい。
【0044】
微生物で汚染されたお風呂の残り湯を用いた100ccの水に抗菌加工された不織布を5cm角に切断したものを浸漬して大腸菌による抗菌性能をATPアナライザにより評価したところ、ほぼ無菌の状態まで菌数を減少できた。また青かびを用いた防黴試験でも極めて高い効果が得られている。
【0045】
本発明は抗菌作用あるいは防黴作用を有する沃素系抗菌材料を基材に坦持させ、この徐放エレメントから空気中に沃素を放出させたり水に濡らして殺菌や防黴を行う空気清浄器をえることができる。これにより冷蔵庫や野菜貯蔵室等の生鮮物を温度を極力下げないで鮮度を保つことが出来たり、また大腸菌O−157等による食品の安全性に対する抗菌、防黴対策になり、庫内や室内の殺菌、防黴を行うことが出来る。沃素は陰イオン交換樹脂に沃素のマイナスイオンとしてイオン結合したペレット上の樹脂として市販されているが、表面近傍からの気化により沃素分子を空気中に徐放する場合、固体として製造される沃素樹脂の粒体の大きさとこれにあたる風の風速に関係するので徐放が行われるように小さく、且つ適度な風速とするがあまりに小さすぎたり、風が強すぎると徐々に放出せずに放出量が大きくなりすぎてしまい、徐放エレメントを直ぐに取り替えなければならないので都合の良い粒体の大きさと、風速を選定する必要がある。徐放量の風速依存性は図6のごとくリニアというより風速が増えることにより一層除放が増えてくる。
【0046】
人体に無害な揮発性抗菌・防黴活性分子の例としてはヒノキチオール、ワサオーロ、ナフタレン、ベイオイル、シナモンリーフォイル、クローブバドオイル、オリガナムオイル等があげられるが沃素がもっとも抗菌、防黴効果に優れている。徐放エレメントからこのような揮発性活性分子を空気中に放出することにより空中浮遊微生物の繁殖を防止し、微生物による空気汚染を軽減して悪臭をなくすことが出来、貯蔵してある貯蔵物の殺菌などにより長期保存が可能になり、また保存のために貯蔵庫や冷蔵庫などを冷やすためのエネルギーを大幅に軽減できる。
【0047】
【発明の効果】
本発明によれば、少ないエネルギーで庫内に貯蔵物を長期保存でき、接触防止板によりどこに徐放エレメントが設けられようと徐放エレメントに影響を与えない貯蔵庫が得られる
【0056】
本発明によれば、取り扱いが簡単で効果的なファン装置が得られ、汚れた空気を装置内部に取り込んで殺菌や防黴を行える
【図面の簡単な説明】
【図1】 この発明の一実施の形態による家庭用の野菜貯蔵庫の概念図である。
【図2】 この発明の一実施の形態による抗菌機能付き送風機の構造図である。
【図3】 この発明の一実施の形態による徐放エレメントの構造の一部で表面に抗菌処理した繊維の拡大図である。
【図4】 この発明の一実施の形態による徐放エレメントの構造図である。
【図5】 この発明の一実施の形態による徐放エレメントの構造図である。
【図6】 この発明の一実施の形態による徐放エレメントの特性図である。
【図7】 この発明の他の実施の形態による冷蔵庫の庫内を扉側から見た説明図である。
【図8】 この発明の他の実施の形態による冷蔵庫の構造図である。
【図9】 この発明の他の実施の形態による扉内側のドアポケットを示す概念図である。
【図10】 この発明の他の実施の形態による徐放エレメントの他の構造を説明する図である。
【図11】 この発明の他の実施の形態による徐放エレメントの別の構造を説明する図である。
【図12】 この発明の他の実施の形態による野菜を保管する冷蔵倉庫を示す説明図である。
【図13】 この発明の他の実施の形態による徐放エレメントの構造を説明する図である。
【図14】 この発明の他の実施の形態による抗菌機能付き送風機の構造図である。
【図15】 従来の冷蔵庫の構成図である。
【図16】 従来の防黴ユニットの構成図である。
【符号の説明】
1 野菜貯蔵庫、 2 抗菌機能付き送風機、 3 徐放エレメント、 4 ファン、 5 野菜ケース、 6 通風スリット、 8 モーター、9 ケーシング、 10 沃素系樹脂、 11 不織布、 12 プリーツ状の不織布、 13 接触防止板、 14 閉鎖板、 15 エレメント枠、 17 冷気吸い込み風路、 18 側面冷気風路、 19 側面用ダンパ、 21 冷蔵庫本体、 22 冷蔵庫扉、 23 側面冷気吹き出し口、 24 天井ダクト、 25 天井冷気吹き出し口、 26 冷蔵室、 27 扉ポケット、 28 背面用冷気通路、 29 庫内温度センサ、 31 冷凍室・冷蔵室断熱仕切り壁、32 背面用ダンパ、 33 内箱、 34 断熱材、 36 棚、 37 凹部、 40 除放エレメント取り付け凹部、 41 冷却器、 42 冷却用送風機、 43 循環用送風機、 44 氷蓄熱槽、 45 配管開閉手段、 46熱伝達媒体調整手段、 47 被冷却物、 48 貯蔵庫、 53 ハニカム状の厚紙、 58 空気清浄機、 59 水タンク、 61 給気口、 62 排気口、 63 送風機、 64 ドレンパン、71 冷蔵庫、 72 冷凍室、 73 冷蔵室、 74 野菜収納室、 75 冷却器、 76 ファン、 77 容器、 78 防臭防黴ユニット、 80 防臭ユニット、 81 防黴ユニット、 82 フレーム、 83 カーテン。
[0001]
BACKGROUND OF THE INVENTION
This invention is a storage for storing fresh foods such as refrigerators and vegetable storages, book storage and basements that are prone to wrinkles, and storages such as storage and storage It suppresses sterilization and generation of wrinkles in the atmosphere.
[0002]
[Prior art]
In recent years, energy conservation has become the most important issue for humanity as part of global environmental conservation. For this reason, while airtightness and high thermal insulation of a living space etc. are advanced, the problem of indoor air contamination has been highlighted. On the other hand, as food safety issues increase, such as E. coli O-157, the demand for fresh vegetables and foods has increased, the use of refrigeration and cooling has increased, the need for energy has increased, and Demand for antibacterial and anti-wrinkle is increasing.
Conventionally, in order to keep freshness, shipping containers, storages for commercial vegetables in the market, etc. are usually stored at a temperature lower than the outside air temperature. In general household refrigerators, fresh food is stored in a vegetable room or refrigerated room, and the freshness is maintained at a low temperature in which microorganisms are difficult to propagate.
[0003]
A conventional example of a warehouse refrigerator is disclosed in Japanese Patent Laid-Open No. 57-16768. When storing crops such as vegetables while cooling them in large quantities, not only the temperature is set accurately, but also a structure that cools uniformly using the pressure difference in the warehouse to cool many vegetables evenly is described .
[0004]
On the other hand, in general household refrigerators, fresh products are stored in a vegetable room or a refrigerator room at a low temperature. However, Japanese Patent Application Laid-Open No. 61-228283 is known as a refrigerator technology in which microorganisms and straws are difficult to propagate in order to maintain food safety. ing. This configuration is shown in FIGS. FIG. 15 is a configuration diagram of the refrigerator, 71 is a refrigerator, 72 is a freezing room, 73 is a refrigeration room, 74 is a vegetable storage room, 75 is a cooler that cools the cold air of a fan 76 that circulates cold air in the refrigerator, 77 A specific container 78 for thawing the frozen food provided in the refrigerator is a deodorizing and fouling unit that blows air from the fan and blows it into the specific unit. FIG. 16 is a block diagram of a fender unit, in which 80 is activated carbon formed in a honeycomb shape by a deodorant unit, 81 is an antibacterial extracted from a regular edible plant in a porous material such as a ceramic formed in a porous unit. Impregnated with active phytoncide. 82 is a frame, 83 is a polyethylene sheet curtain provided between the frame and the deodorant unit to maintain the adsorption effect of the deodorant unit. This prevents the generation of wrinkles on the food in the specific container, the wall surface in the refrigerator, and the like, and the odor peculiar to the thawed food.
[0005]
Further, as an example of using iodine as an organic polymer molded product having bactericidal properties, a technique disclosed in Japanese Patent Publication No. 60-1337 is known.
[0006]
[Problems to be solved by the invention]
Commercial refrigerated warehouses require a large amount of power to refrigerate large spaces, and many household refrigerators consume a large amount of electricity in the home, preventing global warming and carbon dioxide emissions. There is a strong demand for power saving of these devices for reduction. However, since conventional vegetable storage and refrigerators are methods that maintain freshness only by cooling, energy saving other than maintaining temperature by frequent control cannot be realized. Many proposals have been proposed as countermeasures against bad odors, but their effects have not lasted long, and their practical use has been difficult due to their complicated structure and high cost. Furthermore, antibacterial and antifungal effects due to phytoncide have a drawback that the effects do not last long.
In addition, a large space for storing objects is not available, and due to high airtightness and high heat insulation of the living space, it is difficult to suppress the growth of bacteria and microorganisms and the generation of soot by simple ventilation. On the other hand, if air conditioners and air purifiers are installed, there is a problem that power consumption in homes, hospitals, factories, offices, markets, shops, etc. will increase and there will be major problems in preventing global warming and reducing carbon dioxide emissions. .
[0007]
The present invention has been made to solve the above-mentioned problems, and with a simple configuration with low power consumption, a storage for storing fresh food such as a refrigerator and a vegetable storage room, and a book that is prone to generation of straw. It is intended to provide a device that can sterilize and antibacterial the atmosphere in a storage room such as a storage, a basement, and a closet, or store and work while storing, and suppress the generation of wrinkles.
It is also intended to provide a device with very low energy that maintains freshness without cooling. It is also intended to provide a device that is small and can be installed anywhere to sterilize and antibacterial the atmosphere inside the cabinet, and to suppress generation of wrinkles.
[0008]
[Means for Solving the Problems]
The storage of Claim 1 is arrange | positioned in the flow path of the gas which is arrange | positioned in a warehouse and circulates the gas in a warehouse, and the fan circulates. The Iodine antibacterial material and multiple particles of iodine antibacterial material are attached to the substrate surface , A sustained release element that gradually releases iodine from this grain into the gas; A contact prevention plate that prevents the stored items in the storage from coming into contact with the surface of the sustained release element; With From sustained release element Gradually released Ru It is intended to sterilize or prevent mold in the cabinet with iodine.
[0009]
Claim 2 The fan device fixes iodine-based antibacterial material, which is a particle that is disposed in a flow path of gas flowing by the fan, and releases iodine, and a plurality of particles of iodine-based antibacterial material to the substrate surface by fixing means. In addition, the sustained release element that gradually releases iodine from the particles into the gas, the water supply device that maintains the iodine antibacterial material of the sustained release element in a wet state, the fan and the sustained release element are housed inside, And a casing having a discharge port for discharging a gas containing iodine released from the sustained release element to the outside by a fan. It is a thing.
[0021]
DETAILED DESCRIPTION OF THE INVENTION
Embodiment 1 FIG.
Hereinafter, an embodiment of the present invention will be described with reference to the drawings. FIG. 1 is a conceptual diagram of a domestic vegetable storage that is an embodiment of the present invention, and shows a configuration in which vegetables and fresh food are stored for a long time without being cooled. Reference numeral 1 denotes a vegetable storage, 2 a blower with an antibacterial function incorporating a fan 4, 3 a sustained release element carrying an iodine resin, which will be described later, and 5 a food case for vegetables. This storage has no device or equipment configuration for cooling the internal air. The fan 1 is rotated continuously or intermittently, and iodine molecules are released from the sustained release element in response to the wind speed. FIG. 2 is a structural diagram of a blower with an antibacterial function, and a casing 9 is fixed to the wall of the storage 1. Although the fan 4 is driven by the motor 5, the door (not shown) of the storage is closed and the operation is performed at a time interval set by a timer.
[0022]
FIG. 3 is an enlarged view of a fiber having an antibacterial treatment on the surface in a part of the structure of the sustained release element. 10 is an iodine-based resin having a solid particle shape. Next, FIG. 4 is a structural diagram of the sustained release element 3, and 11 is a nonwoven fabric fixed by a plastic element frame 15. A thin film of binder material in which a vinyl acetate emulsion adhesive is sprayed in advance is formed on the surface of a nonwoven fabric 11 having a thickness of 5 mm, which is a porous substrate, and solid particles 1 mm in the form of granular iodine resin are formed through this thin film of binder material. Although it is desirable that the diameter is about 100 microns or more, the surface of the nonwoven fabric, which is a porous substrate, is evenly coated. The porous base material may be a combination of non-woven fabric, foamed urethane foam, fiber yarn, etc., and an aerosol or an aqueous emulsion type adhesive is used as the binder material.
[0023]
The iodine antibacterial material studied in the present invention is a salt of a triiodide ion of an anion exchange resin having a quaternary ammonium ion as a functional group. This is produced through the process of exchanging chloride ions and triiodide ions of anion exchange resin in the form of chloride by contacting and impregnating iodine with the anion exchange resin under special conditions. In the case of a pellet that is chemically bonded to a quaternary ammonium group that is a functional group and is supported by a crosslinked structure of the resin, commercially available iodine ions are hardly released. This iodine-based antibacterial material is a resin having nitrogen positive ions, and triiodide ions are ion-bonded to these positive ions, so that iodine is not easily separated.
[0024]
However, this iodine-based antibacterial material resin hardly releases at a diameter of 5 mm or more, but the particles become small, and when the surface area ratio exceeds a certain volume, it gradually releases from this surface. . As the diameter of the granule decreases, the ratio of the surface area to the volume increases remarkably, and the release amount increases and the life becomes too short. Iodine is stabilized as iodide ion in the resin, but the condition for releasing the active iodine molecule from the resin by the polyvalent iodide ion becomes heavier as the valence increases, so in the case of pentavalent or heptavalent, a large pellet However, it will be released gradually. In addition, this sustained release amount increases as the amount of air flowing through the iodine antibacterial material, that is, the wind speed applied to the surface increases. The resin that forms the particles may be a resin that allows iodine molecules to pass therethrough. For example, a vinyl acetate resin may be used.
[0025]
However the anywhere difficult to use can not be installed structure to prevent the flow of air in a large pellet large as hydride ion valence. Further, since there is a problem that it is sustainedly released quickly and is not practical for the life of replacement, the present invention employs trivalent iodide ions with a low sustained release and uses small particles so that it can be easily released with a large surface area compared to the volume. The body was fixed to the base material with a binder. As a result, it can be arranged in various forms in the ventilation area, and a large amount of airflow can be received by a short distance of the whole, or a small amount of airflow can be received by a long distribution, and the structure and arrangement according to the application is possible. . Moreover, it can be released gradually with the airflow of the fan considering the life.
[0026]
Next, the operation that characterizes the present invention will be described. The vegetable storage 1 shown in FIG. 1 has an antibacterial function blower 2 integrally provided with a sustained release element 3 in which an iodine resin having an antibacterial action or an antifungal action is fixed to a porous base material with a binder of about 5 mm in thickness. It is provided. In this way, using a sustained-release element carrying a functional material that gradually releases iodine on a porous substrate, and blowing air to this element, the iodine molecules released from the resin are diffused throughout the vegetable storage by the circulating air flow. Supplied to keep the interior clean by preventing the growth of microorganisms floating in the air. As a result, the freshness of the vegetables can be maintained for a long period of time by suppressing corrosion or the like without lowering the temperature, and it is possible to suppress bad odors from fresh products due to the propagation of microorganisms. In addition, it is possible to sterilize bacteria attached to fresh food.
[0027]
In general, the chemical reaction power of iodine is considerably weaker than that of chlorine, but the bactericidal power is strong and has an effective and immediate bactericidal action against bacteria, viruses, molds and the like. Iodized antibacterial resins have been used for water purification, such as used in drinking water purifiers.
In the present invention, iodine molecules, which are antibacterial active molecules released by use in a storage, move to every corner of the storage without adsorbing to or reacting with dust, and are exchanged with bacteria to disinfect the iodine molecules. To keep the inside clean. By rotating the fan at a low rotational speed so that the flow rate of the gas flowing through the release element becomes a flow rate at which iodine is gradually released, the sustained release amount can be suppressed and the life of the release element can be extended.
In addition, after the door of the storage is opened, the fan is operated, the closed state is detected, and the motor is intermittently rotated to circulate the air, so that the slow release is very small in the absence of wind flow. Therefore, the sustained release life from the particles can be further extended. When the door is opened, the rotation of the fan is stopped so that the germs floating outside are not sucked.
[0028]
FIG. 5 shows the structure of the release element 3 in which a nonwoven fabric is woven on a pleat as in FIG. As a result, the area of the nonwoven fabric is increased as compared with the flat plate as shown in FIG. 4, the wind pressure passing through the nonwoven fabric is reduced, the sustained release amount can be further reduced, and the life can be extended. Of course, this sustained release element may be provided in a lattice shape and in parallel with the wind flow. The blower with antibacterial function shown in FIG. 1 shows a structure in which the blower with an antibacterial function is integrally attached to the wall surface of the storage. But you can. In other words, it is possible to preserve the perishables in the storage for a long time just by placing them in a kitchen cabinet or door cabinet or storage. Further, the vegetable case of FIG. 1 is preferably a net-like shelf where the surface of the food is exposed as much as possible and iodine molecules can contact. As a result, there is no room for germs and pupae to grow on the contact surface with the shelf.
[0029]
As described above, in the present invention, a device for lowering the temperature, for example, a compressor that pressurizes and expands the refrigerant by a compressor and obtains a low temperature, such as a refrigeration cycle used in a refrigerator, and a fan that cools the compressor are provided. There is no need to install a heat exchanger or the like, and there is no need for a structure that keeps the temperature low, and there is no need to use a refrigerant that affects the global environment. In addition, since the control is simple by simply rotating the fan at a low speed, it is possible to significantly reduce energy. As a result, it is possible to store fresh products such as vegetables without rotting them without using a small device for household use, or to keep a large commercial device safe. It also frees you from the hassle of handling fresh food and cooking while worrying about bacteria. It is more effective if the operation is stopped when the door is opened in conjunction with the opening and closing of the door. In the case of a cold car, a device for lowering the temperature is required and the weight of the load to be transported is limited. However, the structure of the present invention does not require such a limitation.
[0030]
FIG. 6 is a characteristic diagram relating to the wind speed dependence of the iodine sustained release amount of the sustained release element. This characteristic diagram shows a structure in which the sustained release element 3 is provided on the suction side of the fan 4 shown in FIG. 2, and the weight of iodine released from the sustained release element having a sustained release surface of 30 centimeter square is the wind speed 0.2-1. The results of measurement in the range of 0.0 m / s are shown. The sustained release amount is small when the wind speed is 0.5 m / s or less, but the sustained release amount increases rapidly when it exceeds 0.5 m / s. That is, when the inside of a narrow warehouse or a fan is operated continuously, an effective wind speed may be given to the sustained release element at 0.5 m / s or less. On the other hand, when operated at a wind speed of 0.8 m / s in a closed room equivalent to 6 tatami mats, the concentration of iodine contained in the indoor air was about 0.05 ppm, and a high fungicidal effect was obtained. When the bread was left in the room at a humidity of 85% or more, it was found that there was no problem even after 2 weeks or more by sustained release with the sustained release element, against the situation where the mold covered the entire surface of the bread in 6 days. That is, even in a wide room, such a wind speed is sufficient, and it can be said that it is important for the life of the sustained release element not to set the wind speed to about 1 m / s or more.
[0031]
Embodiment 2. FIG.
In the first embodiment, a configuration in which the product is stored without lowering the temperature without having a cooling function is shown. However, it can be used in combination with a configuration in which food is cooled with cold air like a refrigerator. FIG. 7 is an explanatory view of the inside of the refrigerator viewed from the door side. 17 is a cold air suction air passage for sucking the air in the refrigerator into a cooling heat exchanger provided on the rear surface of the refrigerator, and 18 is a side example which is an air passage of the side cold air outlet 23 for blowing out the cooled air from the side surface into the refrigerator. The air duct, 19 is a side damper that adjusts the amount of cold air blown out to the side, 21 is a refrigerator body, 24 is a ceiling duct that is the air passage to the ceiling cold air outlet 25, 26 is a refrigerator compartment, and 28 is a cold air passage for the back. . Reference numeral 31 denotes a heat insulating partition wall that partitions the freezer compartment and the refrigerator compartment.
[0032]
FIG. 8 is an explanatory view showing a part of the refrigerator in cross section. 27 is a door pocket provided on the door 22 of the refrigerator, 34 is a heat insulating material for maintaining the temperature in the cabinet constituted by the door 22, the refrigerator main body 21 and the partition wall 31, 36 is a shelf on which food is placed, and 35 is from the back side. A blowout port 40 for blowing out cool air is a recess for accommodating the release element 3. FIG. 9 is a conceptual diagram showing a door pocket inside the door, and reference numeral 47 denotes an object to be cooled which is food arranged in the door pocket 27. ,
The refrigerator is provided with a fan for circulating cold air, and air is circulated by the fan. A part of the circulating air can be used to diffuse iodine molecules from the release element into the refrigerator. In general, there are air outlets for blowing out cool air on the ceiling, side and back of the cabinet, and there are air inlets for sucking in cold air on the bottom surface, and these five surfaces have a relatively large air volume.
[0033]
On the other hand, cold air circulates on the remaining door surface, but there is a pocket here, which obstructs the circulation of the cold air, and a cooling object 47 to be cooled is placed in this pocket. A large amount of airflow does not flow behind the door. That is, the flow of cool air is hindered by the store. In this way, the wall behind the pocket and just below the upper pocket as shown in FIG. 7 and FIG. 8 is the place where the wind is most difficult to rotate in the cabinet. Therefore, it is effective for antibacterial and antifungal measures because cold air diffuses and circulates in the cabinet.
[0034]
In other words, a base material fixed with antibacterial resin particles that release iodine is directly attached to the door pocket of the refrigerator or stored in a recess provided in the door inner plate, and iodine is released into the refrigerator by the air flow in the refrigerator. It enhances the sterilization effect in the storage and maintains the freshness of fresh food for a long time. In the case of a refrigerator for home use, the rotation speed of the fan is high to circulate cold air throughout the interior of the refrigerator, but the portion close to the door of the door pocket is the place where the cold air that cools the stored item indirectly circulates, and the release amount is Less. In general, the fan is rotated when the internal temperature rises. In some cases, after defrosting the heat exchanger, there is a case where only the fan is turned to improve the startability, but it is a short time. Also, do not rotate when the refrigerator door is open. As described above, since the extended release life is extended and the closed space is circulated, effective release can be performed without wasting the released iodine molecules. The place where the sustained release element is installed is not limited to the door pocket, but may be any place where the flow velocity of the cold air is low and the wind speed is low. For example, it may be provided near the cooler for cooling the cold air.
[0035]
FIG. 10 shows another example of the structure of the sustained release element. Reference numeral 13 denotes a contact prevention plate. When attached to the door pocket, there is a risk that the antibacterial resin particles fixed on the surface of the base material of the sustained release element may come off or be rubbed by the stored items. On the other hand, the air is circulated, but contact prevention may be performed so that food does not hit it. It is not limited to the one shown in the figure, and the storage side may be closed and the air may be passed between the inner wall of the door.
FIG. 11 shows another structure of the sustained release element, wherein 6 is a slit provided in the upper part and the lower part, and 14 is a closing plate for closing other than the slit of the sustained release element. A base material having antibacterial resin granules fixed on the surface is housed in a box, and thin ventilation slits are provided at the upper and lower ends. With such a configuration, only a very small portion of the circulated cold air passes through the release element regardless of where it is installed in the storage. That is, by selecting the width necessary for the amount of air flowing through the slit, adjustment means for adjusting the flow rate of the gas that is disposed in the vicinity of the release element and flows through the sustained release element is provided. However, in the structure shown in the figure, the closing plate 14 can be removed to replace the sustained release element. Further, when the life of the antibacterial resin particles is lost due to sustained release, the color tone of the surface changes. Thus, the sustained release element can see if it needs to be replaced by looking at this surface. On the other hand, if the sustained release element is completely closed, the surface cannot be inspected. The closing plate of FIG. 11 can be moved up and down by a handle 91 and the internal elements can be checked. The iodine ion exchange resin on the pellet is black. When it is close to powder, it becomes brown, and when iodine is removed, it changes to beige. When the surface is closed, the surface may be covered with a transparent or visible plastic film or sheet that does not allow iodine to pass therethrough. Needless to say, the surface inspection for confirming the life of the sustained-release element is easiest when the sustained-release element is provided on the door.
[0036]
Embodiment 3 FIG.
FIG. 12 shows an example in which the present invention is applied to a refrigerated warehouse for storing vegetables. 41 is a cooler that cools the air blown by the cooling fan 42, 43 is a circulation fan that generates a differential pressure and circulates through the block on which the vegetables 7 placed on the pallet 50 are stacked, and 44 An ice heat storage tank 49, which is a cold heat source for supplying cold heat to the cooler 41 by means of a pipe opening / closing means 45 and a adjusting means 46 for adjusting a heat medium such as a refrigerant, and 49 is a wind guide plate for circulating the cooled air in the storage 48 It is. FIG. 13 shows a structure of a sustained release element that is arranged adjacent to the circulation fan 43 in the vegetable warehouse 48 and releases iodine gradually, and antibacterial resin granules are fixed on the surface of the honeycomb-like cardboard 53. As another example, a blower 58 with an antibacterial function is provided on the floor of the vegetable warehouse 48 in FIG.
[0037]
In FIG. 12, in the storage 48 which is a vegetable warehouse, the cooler 41 and the blower 42 can keep the temperature in the storage at a low temperature suitable for stored items. Moreover, freshness can be maintained through the air cooled uniformly with respect to the whole vegetables piled up by the air blower 43 for circulation. On the other hand, the slow element 3 having an antibacterial resin fixed on its surface releases iodine molecules, and this iodine is diffused through the circulation of air throughout the vegetable warehouse to keep the freshness of the vegetable. Maintaining freshness is vital for business use, whereas for cooling, a heat transfer medium can be supplied by both another heat source (not shown) provided on the heat source machine side and ice heat storage. In any case, that is, even if one of them suddenly stops, the other supplies refrigerant to the cooler so that cold air can be supplied. Further, the sustained release element can be released into the circulated air without reducing the differential pressure due to the honeycomb structure.
[0038]
If the sustained release amount is small or if a backup system is required, a blower 58 with an antibacterial function incorporating a portable type sustained release element may be installed on the floor and operated. Alternatively, only the blower 58 with an antibacterial function may be provided without providing the sustained release element 3. As a result, the cooling fan 42, the circulation fan 43, and the sustained release fan device 58 can be operated independently. It is possible to stop the circulation of the refrigerant from the cooling fan or the cold heat source according to the kind of fresh food to be stored or other stored items, or according to the temperature in the warehouse. As a result, power consumption can be greatly reduced. Further, when working inside the storage room or taking in and out stored goods, the sustained release fan device 58 may be stopped. Iodine is indispensable to the human body, and the amount released is small and there is no problem at all. However, if there is a specific smell and it is unpleasant, only this fan should be stopped.
[0039]
This storage has a fan that circulates gas to the sustained release element that releases iodine, a fan that circulates gas to the storage, and a device that cools the air separately. Use is possible, and energy can be greatly reduced. However, in this storage, iodine ions that are released slowly by operating a fan that circulates gas through the sustained release element that releases iodine slowly and a fan that circulates gas through the storage at least simultaneously for a predetermined time, to every corner of the storage, Alternatively, it is necessary to spread and spread enough to the stored fresh food.
[0040]
In the vegetable refrigerated warehouse of FIG. 12 and the household refrigerator of FIG. 7, an electronic control circuit is provided for driving a compressor, a pump, and the like that circulate the refrigerant. This circuit includes a transformer that produces direct current from an AC commercial power supply, a control power rectifier circuit, a temperature controller in the cabinet, a microcontroller that creates control signals to drive the compressor, switches, transistor inverters, gate amplifiers, fan drive inverters, etc. In these inverters, a circuit is constituted by a MOS FET and a freewheeling diode. Comparing the temperature of the temperature sensor provided in the chamber with the temperature set in the temperature adjustment circuit, if the temperature in the chamber is higher than the setting, the microcontroller issues a command to rotate the compressor frequency higher . If the set temperature is high, stop the compressor. The motor for the fan that circulates the air in the refrigerator is also operated in accordance with a command from the microcontroller almost in synchronization with the operation of the compressor. Similarly, a command for operating the fan motor is issued from the microcontroller in conjunction with the opening and closing of the door. When each fan is provided independently, each fan can be freely operated by setting the operation time of each fan in advance by a timer provided in the microcontroller.
[0041]
Embodiment 4 FIG.
FIG. 14 is a structural diagram showing another example of the blower with an antibacterial function of the present invention, in which 59 is a water tank filled with water, 3 is a sustained release in which water is dropped from the water tank 59 while carrying an iodine resin. An element, 64 is a drain pan that collects water that has wetted the sustained release element 3 so that it can be drained to the outside of the machine, 63 is a blower that rotates the fan 4 by a motor and sucks air from the intake port 61 and discharges it to the exhaust port 62, 58 It is an air purifier. The surface of the iodine-based resin 10 of the sustained release element can be removed by removing the inside from the air inlet 61.
[0042]
As shown in FIG. 14, a water tank is provided on the sustained release element 3, and water is supplied from the water tank 59 to the sustained release element so that the sustained release element is wet. Let the wind pass through. In this structure, iodine is less likely to be released from the sustained release element than when the sustained release element is dry, so the air purifier is an air purifier that cleans the air outside the machine. That is, the air in the vegetable storage room or refrigerator, which is a library or storage, is taken into the air purifier by the operation of the blower, and is brought into contact with the wet controlled release element for sterilization. It is not a method of sterilizing and antibacterial storage in the warehouse by releasing iodine molecules mainly in the air and diffusing it in the room or in the warehouse as described so far. It can be used in the base material or in places and times where conditions such as disinfection and antibacterial through water are not desired to be released to the outside using the iodine molecules present in the water. Yes, you can use it as an air purifier anytime, anywhere, without worrying about anything.
[0043]
Since the sustained release element having a functional material that gradually releases iodine supported on a base material is wetted with water and air is circulated to make contact with the sustained release element, a commercially available product is used as the pellet size. It may be used as it is.
As a water supply device that supplies water to the sustained release element, a structure is shown in which a water tank is provided above the release element and water is dripped from a water supply port opened at the bottom of the water tank. But you can. Bacteria and spore spores floating in the air can be sterilized by taking them into water and attracting them to the iodine resin by iodine ions released into the water. By providing a dust removing filter at the air supply port with the structure of the present invention, the water can be kept clean by iodine, so that it is only necessary to circulate the water. However, if a window is provided on the side surface of the casing 9 accommodating the fan of the air cleaner 58 and the sustained release element, the surface of the iodine-based resin can be seen. The window may be covered with an open / close lid or a transparent window material. It may also be used as a lid that can replenish the water evaporation.
[0044]
When antibacterial performance by E. coli was evaluated with an ATP analyzer by immersing a non-woven fabric that had been antibacterial processed into 100 cc water using the remaining hot water of a bath contaminated with microorganisms, The number of bacteria could be reduced. In addition, an extremely high effect is obtained even in the antifungal test using blue mold.
[0045]
The present invention provides an air purifier that carries an antibacterial or antibacterial iodine-based antibacterial material on a base material and releases iodine from the sustained release element into the air or wets it with water for sterilization or fouling. I can. As a result, the freshness of refrigerators and vegetable storage rooms can be kept fresh without lowering the temperature as much as possible, and antibacterial and antifungal measures against food safety due to E. coli O-157, etc. Can be sterilized and protected. Iodine is commercially available as a resin on pellets that are ion-bonded to an anion exchange resin as negative ions of iodine. When iodine is gradually released into the air by vaporization from the vicinity of the surface, iodine resin is produced as a solid. Since it is related to the size of the particles and the wind speed corresponding to this, it is small so that the slow release is performed, and it is set to an appropriate wind speed, but if it is too small, or the wind is too strong, the release amount is not gradually released. Since it becomes too large and the sustained release element must be replaced immediately, it is necessary to select a convenient particle size and wind speed. The dependence of the sustained release amount on the wind speed increases as the wind speed increases rather than linear as shown in FIG.
[0046]
Examples of volatile antibacterial and antifungal active molecules that are harmless to the human body include hinokitiol, wasaolo, naphthalene, bay oil, cinnamon leaf foil, clove bud oil, and origanum oil. Iodine has the most antibacterial and antifungal effects. ing. By releasing such volatile active molecules into the air from the sustained release element, the growth of airborne microorganisms can be prevented, the air pollution caused by microorganisms can be reduced, and malodors can be eliminated. Long-term storage is possible by sterilization and the like, and energy for cooling storages and refrigerators for storage can be greatly reduced.
[0047]
【The invention's effect】
According to the present invention Small In the warehouse with no energy storage Can store things for a long time , No matter where the sustained release element is provided by the contact prevention plate, a storage that does not affect the sustained release element is obtained .
[0056]
According to the present invention, A fan device that is easy to handle and effective can be obtained, and dirty air can be taken into the device for sterilization and prevention. .
[Brief description of the drawings]
FIG. 1 is a conceptual diagram of a domestic vegetable storage according to an embodiment of the present invention.
FIG. 2 is a structural diagram of a blower with an antibacterial function according to one embodiment of the present invention.
FIG. 3 is an enlarged view of a fiber having a surface subjected to antibacterial treatment in a part of the structure of the sustained release element according to the embodiment of the present invention.
FIG. 4 is a structural diagram of a sustained release element according to an embodiment of the present invention.
FIG. 5 is a structural diagram of a sustained release element according to an embodiment of the present invention.
FIG. 6 is a characteristic diagram of a sustained release element according to an embodiment of the present invention.
FIG. 7 is an explanatory view of the interior of a refrigerator according to another embodiment of the present invention as viewed from the door side.
FIG. 8 is a structural diagram of a refrigerator according to another embodiment of the present invention.
FIG. 9 is a conceptual diagram showing a door pocket inside a door according to another embodiment of the present invention.
FIG. 10 is a view for explaining another structure of a sustained release element according to another embodiment of the present invention.
FIG. 11 is a diagram illustrating another structure of a sustained release element according to another embodiment of the present invention.
FIG. 12 is an explanatory diagram showing a refrigerated warehouse for storing vegetables according to another embodiment of the present invention.
FIG. 13 is a view for explaining the structure of a sustained release element according to another embodiment of the present invention.
FIG. 14 is a structural diagram of a blower with an antibacterial function according to another embodiment of the present invention.
FIG. 15 is a configuration diagram of a conventional refrigerator.
FIG. 16 is a configuration diagram of a conventional fender unit.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 Vegetable storage, 2 Fan with antibacterial function, 3 Sustained release element, 4 Fan, 5 Vegetable case, 6 Ventilation slit, 8 Motor, 9 Casing, 10 Iodine resin, 11 Nonwoven fabric, 12 Pleated nonwoven fabric, 13 Contact prevention plate , 14 Closing plate, 15 Element frame, 17 Cold air intake passage, 18 Side cold air passage, 19 Side damper, 21 Refrigerator body, 22 Refrigerator door, 23 Side cold air outlet, 24 Ceiling duct, 25 Ceiling cold air outlet, 26 cold room, 27 door pocket, 28 cold air passage for back side, 29 internal temperature sensor, 31 freezer compartment / refrigerated room insulation partition wall, 32 back damper, 33 inner box, 34 heat insulating material, 36 shelf, 37 recess, 40 Removable element mounting recess, 41 cooler, 42 cooling fan, 43 circulating fan, 44 ice heat storage 45 Pipe opening / closing means, 46 Heat transfer medium adjusting means, 47 Object to be cooled, 48 Storage, 53 Honeycomb cardboard, 58 Air purifier, 59 Water tank, 61 Air supply port, 62 Exhaust port, 63 Blower, 64 Drain pan 71 refrigerator, 72 freezer room, 73 refrigerator room, 74 vegetable storage room, 75 cooler, 76 fan, 77 container, 78 deodorant and fouling unit, 80 deodorant unit, 81 fouling unit, 82 frame, 83 curtain.

Claims (2)

庫内に配置され庫内の気体を循環させるファンと、前記ファンにより循環する気体の流路に配置され粒体である沃素系抗菌材料と、前記沃素系抗菌材料の複数の粒体を基材表面に取り付けこの粒体から沃素を徐々に気体に放出する徐放エレメントと、この徐放エレメントの表面に前記庫内の貯蔵物が接触することを防ぐ接触防止板とを備え、前記徐放エレメントから徐々に放出され沃素により庫内の殺菌または防カビを行うことを特徴する貯蔵庫。A fan that circulates the gas in the chamber disposed in the chamber, an iodine antibacterial material that is a particle disposed in a gas flow path circulated by the fan, and a plurality of particles of the iodine antibacterial material attached to the wood surface, comprising gradually and controlled release element which releases the gas to iodine, and a contact preventing plate to prevent the stored goods in the warehouse is in contact with the surface of the controlled release element from the granules, the sustained release reservoirs and performing sterilization or antifungal in the refrigerator by iodine gradually Ru released from release element. ファンにより流れる気体の流路に配置され沃素を放出するような粒体である沃素系抗菌材料と、前記沃素系抗菌材料の複数の粒体を基材表面に固定手段にて固定させ、この粒体から沃素を徐々に気体に放出する徐放エレメントと、この徐放エレメントの沃素系抗菌材料を濡れた状態に維持する給水装置と、前記ファンと前記徐放エレメントを内部に収納するとともに、前記徐放エレメントから放出される沃素を含む気体を前記ファンにより外部に吐出する吐出口を有するケーシングとを備えたことを特徴とするファン装置 An iodine antibacterial material that is arranged in a flow path of a gas flowing by a fan and releases iodine, and a plurality of particles of the iodine antibacterial material are fixed to a substrate surface by a fixing means. A sustained release element that gradually releases iodine from the body into a gas, a water supply device that maintains the iodine antibacterial material of the sustained release element in a wet state, the fan and the sustained release element are housed therein, and A fan device comprising: a casing having a discharge port for discharging iodine-containing gas discharged from the sustained release element to the outside by the fan .
JP2519499A 1999-02-02 1999-02-02 Storage, fan device Expired - Fee Related JP4003333B2 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102778104A (en) * 2012-07-20 2012-11-14 合肥美的荣事达电冰箱有限公司 Electronic control bear machine

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005012618A1 (en) * 2004-03-23 2005-10-13 Lg Electronics Inc. Antibacterial deodorizer kit for refrigerator, includes antibacterial agent comprising antibacterial capsules where antibacterial substance is microcapsulized and integrally formed with the deodorizing agent
US7329385B1 (en) 2004-07-08 2008-02-12 Radicone Michael C Device and method for air stream, fluid and vessel decontamination
CN109494031B (en) * 2018-10-25 2019-12-10 南京金典制冷实业有限公司 water braking air circulation anti-flashover insulator high-voltage line connecting device
CN110487012A (en) * 2019-09-11 2019-11-22 长虹美菱股份有限公司 A kind of flavor fresh-keeping refrigerator
CN114777401B (en) * 2022-04-25 2024-05-24 珠海格力电器股份有限公司 Refrigerator drawer, refrigerator and humidity control method of refrigerator drawer

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61114291U (en) * 1984-12-26 1986-07-19
JPS61228282A (en) * 1985-04-03 1986-10-11 株式会社日立製作所 Deodorant for refrigerator
JPH0479998A (en) * 1990-07-21 1992-03-13 Ito Chiyoutanpa Kk Bath room dryer
JPH0571863A (en) * 1991-09-17 1993-03-23 Matsushita Refrig Co Ltd Refrigerator
JP2989347B2 (en) * 1991-10-14 1999-12-13 シャープ株式会社 Fruit and vegetable freshness holding device and storage room simple installation type fruit and vegetable freshness holding unit
EP0797917B1 (en) * 1992-09-16 2006-12-13 Triosyn Holding Inc. Method for disinfecting of air by iodine/resin based disinfectant and systems for disinfection of air borne microorganisms
JP2904328B2 (en) * 1992-11-24 1999-06-14 三菱電機株式会社 Microbial propagation prevention device
JPH06339629A (en) * 1993-06-01 1994-12-13 Kondo Kogyo Kk Air purification agent and filter for air purification
JPH07184823A (en) * 1993-12-27 1995-07-25 Suzuki Yushi Kogyo Kk Domestic slime-removing tool
JPH07255827A (en) * 1994-03-22 1995-10-09 Dentopia:Kk Footgear deodorizing-sterilizing box
JPH07316420A (en) * 1994-05-24 1995-12-05 Sunstar Inc Thin-layer forming material and functional sheet made by utilizing the same
JP3782848B2 (en) * 1995-05-25 2006-06-07 日宝化学株式会社 Sustained release iodine complex, its production method and use
JPH0948093A (en) * 1995-05-26 1997-02-18 Hitachi Chem Co Ltd Functional sheet material and manufacture thereof
JP3477950B2 (en) * 1995-10-25 2003-12-10 三菱電機株式会社 Refrigeration and air conditioning equipment
JPH09169504A (en) * 1995-12-22 1997-06-30 Mitsubishi Heavy Ind Ltd Ozone generator
JP3768582B2 (en) * 1996-02-19 2006-04-19 日宝化学株式会社 Environmental disinfectant and anti-skid tool for sink
JPH1045609A (en) * 1996-08-05 1998-02-17 Nippo Kagaku Kk New inclusion compound, its use and resin composition
JPH1057458A (en) * 1996-08-23 1998-03-03 Sanko:Kk Sterilizing device
JPH10251101A (en) * 1997-03-07 1998-09-22 Mitsubishi Heavy Ind Ltd Device for maintaining freshness
JP3318234B2 (en) * 1997-06-06 2002-08-26 松下冷機株式会社 refrigerator

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102778104A (en) * 2012-07-20 2012-11-14 合肥美的荣事达电冰箱有限公司 Electronic control bear machine

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