JP3996509B2 - 常態では液体のヒドロフルオロカーボンと二酸化炭素を含む発泡剤組成物及びポリマーフォーム - Google Patents
常態では液体のヒドロフルオロカーボンと二酸化炭素を含む発泡剤組成物及びポリマーフォーム Download PDFInfo
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- JP3996509B2 JP3996509B2 JP2002552059A JP2002552059A JP3996509B2 JP 3996509 B2 JP3996509 B2 JP 3996509B2 JP 2002552059 A JP2002552059 A JP 2002552059A JP 2002552059 A JP2002552059 A JP 2002552059A JP 3996509 B2 JP3996509 B2 JP 3996509B2
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- ZJIJAJXFLBMLCK-UHFFFAOYSA-N perfluorohexane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F ZJIJAJXFLBMLCK-UHFFFAOYSA-N 0.000 description 1
- YVBBRRALBYAZBM-UHFFFAOYSA-N perfluorooctane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YVBBRRALBYAZBM-UHFFFAOYSA-N 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000747 poly(lactic acid) Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- DUIOPKIIICUYRZ-UHFFFAOYSA-N semicarbazide Chemical compound NNC(N)=O DUIOPKIIICUYRZ-UHFFFAOYSA-N 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
- C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/122—Hydrogen, oxygen, CO2, nitrogen or noble gases
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/149—Mixtures of blowing agents covered by more than one of the groups C08J9/141 - C08J9/143
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/06—CO2, N2 or noble gases
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/12—Organic compounds only containing carbon, hydrogen and oxygen atoms, e.g. ketone or alcohol
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
- C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/18—Binary blends of expanding agents
- C08J2203/182—Binary blends of expanding agents of physical blowing agents, e.g. acetone and butane
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/20—Ternary blends of expanding agents
- C08J2203/202—Ternary blends of expanding agents of physical blowing agents
Landscapes
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
- Polyurethanes Or Polyureas (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US25748200P | 2000-12-21 | 2000-12-21 | |
| PCT/US2001/045091 WO2002050173A2 (en) | 2000-12-21 | 2001-11-29 | Blowing agent composition and polymeric foam containing a normally-liquid hydrofluorocarbon and carbon dioxide |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004516352A JP2004516352A (ja) | 2004-06-03 |
| JP2004516352A5 JP2004516352A5 (enExample) | 2007-02-15 |
| JP3996509B2 true JP3996509B2 (ja) | 2007-10-24 |
Family
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| JP2002552059A Expired - Fee Related JP3996509B2 (ja) | 2000-12-21 | 2001-11-29 | 常態では液体のヒドロフルオロカーボンと二酸化炭素を含む発泡剤組成物及びポリマーフォーム |
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| EP (1) | EP1345986B1 (enExample) |
| JP (1) | JP3996509B2 (enExample) |
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| CN (1) | CN100343314C (enExample) |
| AT (1) | ATE413428T1 (enExample) |
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| DE (1) | DE60136485D1 (enExample) |
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| NO (1) | NO20032833L (enExample) |
| RU (1) | RU2276164C2 (enExample) |
| WO (1) | WO2002050173A2 (enExample) |
Families Citing this family (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002099006A1 (en) * | 2001-06-01 | 2002-12-12 | Honeywell International, Inc. | Compositions of hydrofluorocarbons and trans-1,2-dichloroethylene |
| JP4261489B2 (ja) * | 2003-04-24 | 2009-04-30 | ナショナル リサーチ カウンシル オブ カナダ | 低損失フォーム組成物並びに低損失フォーム層を有するケーブル |
| US20060052466A1 (en) * | 2004-09-03 | 2006-03-09 | Handa Yash P | Expanded and extruded thermoplastic foams made with methyl formate-based blowing agents |
| US20060052465A1 (en) * | 2004-09-03 | 2006-03-09 | Handa Yash P | Thermoplastic foams made with methyl formate-based blowing agents |
| US7307105B2 (en) * | 2004-09-03 | 2007-12-11 | Pactiv Corporation | Thermoplastic foams made with methyl formate-based blowing agents |
| US7312253B2 (en) * | 2004-09-03 | 2007-12-25 | Pactiv Corporation | Insulating thermoplastic foams made with methyl formate-based blowing agents |
| US8309619B2 (en) | 2004-09-03 | 2012-11-13 | Pactiv LLC | Reduced-VOC and non-VOC blowing agents for making expanded and extruded thermoplastic foams |
| CA2634484A1 (en) | 2006-02-22 | 2007-09-07 | Pactiv Corporation | Expanded and extruded polyolefin foams made with methyl formate-based blowing agents |
| CN101547964B (zh) * | 2006-12-06 | 2012-05-23 | 陶氏环球技术公司 | 具有红外衰减剂的苯乙烯丙烯腈共聚物泡沫 |
| US7977397B2 (en) * | 2006-12-14 | 2011-07-12 | Pactiv Corporation | Polymer blends of biodegradable or bio-based and synthetic polymers and foams thereof |
| JP2010513604A (ja) * | 2006-12-14 | 2010-04-30 | パクティヴ・コーポレーション | ギ酸メチル系発泡剤を用いて得られた、生分解性および低排出性の膨張および押出発泡体 |
| US20080161432A1 (en) * | 2006-12-29 | 2008-07-03 | Korwin-Edson Michelle L | Room temperature crosslinked foam |
| US20100189908A1 (en) * | 2006-12-29 | 2010-07-29 | Olang Fatemeh N | Formulation method for plural component latex- foam |
| US8875472B2 (en) * | 2006-12-29 | 2014-11-04 | Owens Corning Intellectual Capital, Llc | Room temperature crosslinked foam |
| US20110123717A1 (en) * | 2006-12-29 | 2011-05-26 | O'leary Robert J | Two part spray foam using a blowing agent as a plasticizer and a room temperature crosslinking agent |
| US8779016B2 (en) * | 2006-12-29 | 2014-07-15 | Owens Corning Intellectual Capital, Llc | Spray-in latex foam for sealing and insulating |
| US9868836B2 (en) * | 2006-12-29 | 2018-01-16 | Owens Corning Intellectual Capital, Llc | Room temperature crosslinked foam |
| US20090203808A1 (en) * | 2008-02-12 | 2009-08-13 | Nova Chemicals Inc. | Expandable particulate polymer composition |
| US8324287B2 (en) * | 2008-04-25 | 2012-12-04 | Dow Global Technologies Llc | Positive skew styrene-acrylonitrile copolymer foam |
| US20110224317A1 (en) * | 2009-01-19 | 2011-09-15 | Owens Corning Intellectual Capital, Llc | Spray foams with fine particulate blowing agent |
| BRPI0924862A2 (pt) | 2009-06-12 | 2016-08-23 | Abb Technology Ag | meio de isolação dielétrica |
| DE202009009305U1 (de) | 2009-06-17 | 2009-11-05 | Ormazabal Gmbh | Schalteinrichtung für Mittel-, Hoch- oder Höchstspannung mit einem Füllmedium |
| IN2012DN02547A (enExample) * | 2009-09-25 | 2015-08-28 | Arkema Inc | |
| IT1397297B1 (it) * | 2009-11-25 | 2013-01-04 | Polymtec Trading Ag Ora Polymtec Engineering Ag | Articolo a base di polistirolo estruso, procedimento ed impianto per ottenere tale articolo |
| ES2381427T3 (es) * | 2009-12-08 | 2012-05-28 | Recticel | Procedimiento para la preparación de espuma de poliuretano flexible y espuma obtenida de ese modo |
| BR112013014849A2 (pt) | 2010-12-14 | 2016-10-18 | Abb Research Ltd | "meio de isolamento dielétrico, uso de um monoéter fluorídrico, uso do meio de isolamento dielétrico e aparelho para a geração, distribuição e uso de energia elétrica". |
| WO2012080246A1 (en) | 2010-12-14 | 2012-06-21 | Abb Technology Ag | Dielectric insulation medium |
| WO2012080269A1 (en) | 2010-12-16 | 2012-06-21 | Abb Technology Ag | Dielectric insulation medium |
| US20120286192A1 (en) * | 2011-05-12 | 2012-11-15 | 3M Innovative Properties Company | Azeotrope-like compositions with 1,1,1,3,3-pentafluorobutane |
| US8648122B2 (en) | 2011-12-01 | 2014-02-11 | Sealed Air Corporation (Us) | Method of foaming polyolefin using acrylated epoxidized fatty acid and foam produced therefrom |
| WO2013087700A1 (en) | 2011-12-13 | 2013-06-20 | Abb Technology Ag | Sealed and gas insulated high voltage converter environment for offshore platforms |
| ES2973059T3 (es) | 2013-03-15 | 2024-06-18 | Owens Corning Intellectual Capital Llc | Auxiliares de procesamiento para su uso en la fabricación de espumas de poliestireno extruidas utilizando agentes de soplado con bajo potencial en calentamiento global |
| JP6995628B2 (ja) * | 2015-05-29 | 2022-02-04 | オウェンス コーニング インテレクチュアル キャピタル リミテッド ライアビリティ カンパニー | 押出ポリスチレンフォーム |
| TW202007730A (zh) | 2018-07-31 | 2020-02-16 | 美商陶氏全球科技公司 | 組成物、形成自該組成物之經發泡聚矽氧彈性體、及形成方法 |
| CN109354820A (zh) * | 2018-09-04 | 2019-02-19 | 徐州市华天塑业有限公司 | 一种抗菌生态泡沫板 |
| EP3900502A4 (en) * | 2018-12-21 | 2022-11-02 | Honeywell International Inc. | HEAT TRANSFER PROCESSES, SYSTEMS AND FLUIDS |
| WO2020139805A1 (en) | 2018-12-28 | 2020-07-02 | Dow Brasil Sudeste Industrial Ltda. | Composite article for insulating appliance, appliance comprising composite article, and related method |
| CN112608623B (zh) * | 2020-12-11 | 2022-03-04 | 青岛黑猫新材料研究院有限公司 | 一种超高隔音性能纳米复合炭黑及其制备方法 |
| KR20240038744A (ko) | 2021-07-20 | 2024-03-25 | 다우 글로벌 테크놀로지스 엘엘씨 | 실리콘 발포 조성물 |
| KR20240038012A (ko) | 2021-07-20 | 2024-03-22 | 다우 글로벌 테크놀로지스 엘엘씨 | 실리콘 폼 조성물 |
| WO2024036233A2 (en) * | 2022-08-09 | 2024-02-15 | Solugen, Inc. | Blowing agents for foamed polymer applications |
Family Cites Families (56)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4214054A (en) | 1977-10-21 | 1980-07-22 | Asahi-Dow Limited | Expanded olefin polymer |
| JPS5481370A (en) | 1977-12-13 | 1979-06-28 | Japan Styrene Paper Corp | Method of making polyolefin foam |
| US4323528A (en) | 1980-08-07 | 1982-04-06 | Valcour Imprinted Papers, Inc. | Method and apparatus for making large size, low density, elongated thermoplastic cellular bodies |
| US4681715A (en) | 1984-11-16 | 1987-07-21 | The Dow Chemical Company | Steam expandable polymeric composition and method |
| US4663360A (en) | 1985-09-20 | 1987-05-05 | The Dow Chemical Company | Steam expandable polymeric composition and method |
| DE3903336A1 (de) | 1989-02-04 | 1990-08-09 | Bayer Ag | Verwendung von c(pfeil abwaerts)3(pfeil abwaerts)- bis c(pfeil abwaerts)5(pfeil abwaerts)-polyfluoralkanen als treibgase |
| US5266605A (en) * | 1989-08-02 | 1993-11-30 | The Dow Chemical Company | Polystyrene foam made with only carbon dioxide as a blowing agent and a process for making the same |
| DE3930847A1 (de) * | 1989-09-15 | 1991-04-04 | Berstorff Gmbh Masch Hermann | Verfahren zum herstellen eines schaumstoffes aus thermoplastischem kunststoff und extruderanlage zur durchfuehrung des verfahrens |
| US5912279A (en) | 1990-03-23 | 1999-06-15 | E. I. Du Pont De Nemours And Company | Polymer foams containing blocking agents |
| DE59104659D1 (de) * | 1990-07-04 | 1995-03-30 | Basf Ag | Verfahren zur Herstellung von Schaumstoffplatten mit hoher Druckfestigkeit. |
| JPH05247250A (ja) * | 1991-03-28 | 1993-09-24 | Hoechst Ag | 分枝ドデカフルオロヘキサンを用いたフォームの製造方法 |
| EP0557533A1 (en) | 1991-09-12 | 1993-09-01 | Daikin Industries, Ltd. | Blowing agent composition |
| DE4138388A1 (de) * | 1991-11-22 | 1993-05-27 | Basf Ag | Verfahren zur herstellung von schaumstoffplatten mit hoher druckfestigkeit |
| US5162381A (en) | 1991-12-10 | 1992-11-10 | Allied-Signal Inc. | Process for preparing thermalplastic foam |
| US5278196A (en) | 1993-03-25 | 1994-01-11 | Great Lakes Chemical Corp. | Hydrofluorocarbon compositions as blowing agents for cellular plastics |
| BE1006894A3 (fr) | 1993-03-31 | 1995-01-17 | Solvay | Compositions comprenant du pentafluorobutane et utilisation de ces compositions. |
| US5422378A (en) * | 1993-06-04 | 1995-06-06 | The Dow Chemical Company | Foamable styrenic polymer gel and resulting foam |
| US5405883A (en) | 1993-07-12 | 1995-04-11 | The Dow Chemical Company | Ethylene polymer foams blown with isobutane and 1,1-difluoroethane and a process for making |
| US5753717A (en) | 1994-03-30 | 1998-05-19 | Aci Operations Pty Ltd. | Plastics foam and method of manufacturing same |
| US5688431A (en) | 1994-09-29 | 1997-11-18 | E. I. Du Pont De Nemours And Company | Octafluorobutane compositions |
| DE69504093T2 (de) | 1994-10-19 | 1999-01-21 | Imperial Chemical Industries Plc, London | Verfahren zur herstellung von polyurethanhartschaumstoffen |
| DE4439082A1 (de) | 1994-11-02 | 1996-05-09 | Solvay Fluor & Derivate | Kohlendioxid enthaltende Treibmittel sowie deren Verwendung in Verfahren zur Herstellung geschäumter Kunststoffe |
| DE19502708C2 (de) * | 1995-01-28 | 2003-10-23 | Solvay Fluor & Derivate | Verfahren zur Herstellung von Ein- oder Mehrkomponenten-Polyurethanschaumstoffen |
| CN1071769C (zh) * | 1994-11-02 | 2001-09-26 | 索尔微氟及衍生物有限公司 | 含有液态二氧化碳的发泡剂 |
| KR0184681B1 (ko) | 1995-01-24 | 1999-05-15 | 구보타 다다시 | 탄산가스 흡착제를 가지는 발포 단열재와 그 발포 단열재의 제조방법 |
| BE1009631A3 (fr) | 1995-09-26 | 1997-06-03 | Solvay | Premelanges pour la preparation de mousses de polyurethane. |
| BE1009630A3 (fr) | 1995-09-26 | 1997-06-03 | Solvay | Premelanges pour la preparation de mousses de polyurethane ou de polyisocyanurate. |
| US5670552A (en) * | 1995-12-18 | 1997-09-23 | W. R. Grace & Co.-Conn. | Foam and process for producing foam using a carbon dioxide blowing agent |
| DE19600026A1 (de) * | 1996-01-03 | 1997-07-10 | Gefinex Jackon Gmbh | Verfahren zur Herstellung von Schaumstoffplatten, -Bahnen und Füllkörper oder Beads |
| US5672294A (en) | 1996-04-10 | 1997-09-30 | Alliedsignal Inc. | Azeotrope-like compositions of 1,1,1,3,3-pentaflurorpropane and hydrocarbons |
| US5776389A (en) * | 1996-06-20 | 1998-07-07 | The Dow Chemical Company | Process for making an alkenyl aromatic polymer foam having enlarged cell size |
| JPH1045935A (ja) | 1996-08-02 | 1998-02-17 | Kanegafuchi Chem Ind Co Ltd | アルケニル芳香族樹脂押出発泡体 |
| CA2218819A1 (en) * | 1996-11-18 | 1998-05-18 | The Celotex Corporation | Foams made with polyester polyols and hydrofluorocarbons as blowing agents |
| EP0946630B1 (de) | 1996-12-17 | 2001-05-09 | Solvay Fluor und Derivate GmbH | Gemische mit 1,1,1,3,3-pentafluorbutan |
| JP3599079B2 (ja) | 1997-01-28 | 2004-12-08 | ダイキン工業株式会社 | 合成樹脂発泡体の製造方法 |
| JPH10226730A (ja) | 1997-02-17 | 1998-08-25 | Daikin Ind Ltd | ポリオレフィン系樹脂発泡体の製造方法 |
| ATE301156T1 (de) | 1997-03-03 | 2005-08-15 | Solvay | Azeotropische oder azeotropähnliche zusammensetzungen und ihre verwendungen |
| EP0882760B1 (en) | 1997-06-03 | 2003-11-05 | Asahi Glass Company Ltd. | Method for producing foamed synthetic resin |
| US5789458A (en) | 1997-06-12 | 1998-08-04 | Celotex Corporation | Method for producing foams from high acid polyester polyols |
| JP2002510343A (ja) * | 1997-06-13 | 2002-04-02 | ハンツマン・アイシーアイ・ケミカルズ・エルエルシー | 発泡ポリウレタンフォーム用のイソシアネート組成物 |
| EP1023367B1 (en) * | 1997-07-25 | 2003-10-01 | Huntsman International Llc | Flame resistant rigid polyurethane foams blown with hydrofluorocarbons |
| CA2239950C (en) | 1997-08-11 | 2007-09-18 | Bayer Corporation | Syntactic rigid pur/pir foam boardstock |
| DE69723086T2 (de) | 1997-12-08 | 2003-12-24 | Dow Deutschland Inc. | Mehrschichtiger Schaum, Verfahren zu seiner Herstellung und Verwendung |
| EP0921148A1 (en) | 1997-12-08 | 1999-06-09 | Dow Deutschland Inc. | Low density strand foams |
| AU2115499A (en) | 1998-01-16 | 1999-08-02 | E.I. Du Pont De Nemours And Company | 1,1,1,3,3-pentafluoropropane compositions |
| DE19822944A1 (de) * | 1998-05-22 | 1999-11-25 | Solvay Fluor & Derivate | Herstellung von Polyurethanschäumen |
| DE19822945C2 (de) * | 1998-05-22 | 2001-04-26 | Solvay Fluor & Derivate | Verfahren zur Herstellung von geschäumten thermoplastischen Kunststoffen und Treibmittelzusammensetzung |
| WO1999061519A1 (de) * | 1998-05-22 | 1999-12-02 | Solvay Fluor Und Derivate Gmbh | Herstellung von polyurethanschäumen und geschäumten thermoplastischen kunststoffen |
| US6123881A (en) | 1998-09-16 | 2000-09-26 | Owens Corning Fiberglas Technology, Inc. | Process for producing extruded foam products having polystyrene blends with high levels of CO2 as a blowing agent |
| US6187831B1 (en) | 1998-09-16 | 2001-02-13 | Owens Corning Fiberglas Technology, Inc. | Process for producing extruded foam products with higher levels of CO2 as a blowing agent |
| US6022912A (en) | 1998-09-22 | 2000-02-08 | Bayer Corporation | Expansion of polymeric microspheres insitu in a rigid PUR/PIR foam formulation using a twin screw extruder |
| AU757026B2 (en) | 1998-10-21 | 2003-01-30 | Owens Corning Intellectual Capital, Llc | Process for producing extruded foam |
| US5993707A (en) | 1998-12-04 | 1999-11-30 | The Dow Chemical Company | Enlarged cell size foams made from blends of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic and/or sterically hindered aliphatic or cycloaliphatic vinyl or vinylidene interpolymers |
| DE10053524A1 (de) | 1999-10-29 | 2001-05-03 | Gefinex Jackon Gmbh | Alternatives Treibmittel mit Wasserbestandteil und Ketonen als Lösungsvermittler |
| DE19955146A1 (de) | 1999-11-17 | 2001-05-23 | Basf Ag | Verfahren zur Herstellung von Schaumstoffplatten |
| US6274640B1 (en) | 2000-08-17 | 2001-08-14 | Owens Corning Fiberglas Technology, Inc. | Extruded foam product with 134a and alcohol blowing agent |
-
2001
- 2001-11-29 EP EP01987161A patent/EP1345986B1/en not_active Expired - Lifetime
- 2001-11-29 DK DK01987161T patent/DK1345986T3/da active
- 2001-11-29 MX MXPA03005694 patent/MX235556B/es active IP Right Grant
- 2001-11-29 CA CA002432144A patent/CA2432144C/en not_active Expired - Fee Related
- 2001-11-29 DE DE60136485T patent/DE60136485D1/de not_active Expired - Lifetime
- 2001-11-29 KR KR20037008428A patent/KR20030064859A/ko not_active Withdrawn
- 2001-11-29 ES ES01987161T patent/ES2312486T3/es not_active Expired - Lifetime
- 2001-11-29 RU RU2003122203/04A patent/RU2276164C2/ru not_active IP Right Cessation
- 2001-11-29 CN CNB018211232A patent/CN100343314C/zh not_active Expired - Fee Related
- 2001-11-29 HU HU0302577A patent/HUP0302577A3/hu unknown
- 2001-11-29 AT AT01987161T patent/ATE413428T1/de active
- 2001-11-29 US US09/997,744 patent/US20020161063A1/en not_active Abandoned
- 2001-11-29 JP JP2002552059A patent/JP3996509B2/ja not_active Expired - Fee Related
- 2001-11-29 AU AU2002239402A patent/AU2002239402A1/en not_active Abandoned
- 2001-11-29 WO PCT/US2001/045091 patent/WO2002050173A2/en not_active Ceased
-
2002
- 2002-11-01 US US10/286,565 patent/US6599946B2/en not_active Expired - Lifetime
-
2003
- 2003-06-20 NO NO20032833A patent/NO20032833L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| EP1345986A2 (en) | 2003-09-24 |
| AU2002239402A1 (en) | 2002-07-01 |
| RU2276164C2 (ru) | 2006-05-10 |
| MX235556B (es) | 2006-04-06 |
| KR20030064859A (ko) | 2003-08-02 |
| ATE413428T1 (de) | 2008-11-15 |
| WO2002050173A2 (en) | 2002-06-27 |
| HUP0302577A3 (en) | 2011-04-28 |
| US20020161063A1 (en) | 2002-10-31 |
| DK1345986T3 (da) | 2009-01-12 |
| US20030119926A1 (en) | 2003-06-26 |
| EP1345986B1 (en) | 2008-11-05 |
| JP2004516352A (ja) | 2004-06-03 |
| WO2002050173A3 (en) | 2003-05-15 |
| DE60136485D1 (de) | 2008-12-18 |
| CA2432144A1 (en) | 2002-06-27 |
| NO20032833L (no) | 2003-08-20 |
| US6599946B2 (en) | 2003-07-29 |
| ES2312486T3 (es) | 2009-03-01 |
| CN100343314C (zh) | 2007-10-17 |
| CA2432144C (en) | 2009-09-29 |
| HUP0302577A2 (hu) | 2003-10-28 |
| CN1484668A (zh) | 2004-03-24 |
| NO20032833D0 (no) | 2003-06-20 |
| MXPA03005694A (es) | 2004-03-26 |
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