JP3987108B2 - 多層殺菌フィルム組成物 - Google Patents
多層殺菌フィルム組成物 Download PDFInfo
- Publication number
- JP3987108B2 JP3987108B2 JP50157897A JP50157897A JP3987108B2 JP 3987108 B2 JP3987108 B2 JP 3987108B2 JP 50157897 A JP50157897 A JP 50157897A JP 50157897 A JP50157897 A JP 50157897A JP 3987108 B2 JP3987108 B2 JP 3987108B2
- Authority
- JP
- Japan
- Prior art keywords
- layer
- chlorine dioxide
- hydrophilic
- composite material
- chlorite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title description 24
- 230000002070 germicidal effect Effects 0.000 title 1
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 claims description 428
- 239000004155 Chlorine dioxide Substances 0.000 claims description 215
- 235000019398 chlorine dioxide Nutrition 0.000 claims description 210
- 239000002131 composite material Substances 0.000 claims description 133
- 229910001919 chlorite Inorganic materials 0.000 claims description 106
- 229910052619 chlorite group Inorganic materials 0.000 claims description 106
- 230000002209 hydrophobic effect Effects 0.000 claims description 96
- -1 hydronium ions Chemical class 0.000 claims description 70
- 239000002253 acid Substances 0.000 claims description 67
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 58
- 239000003795 chemical substances by application Substances 0.000 claims description 48
- QBWCMBCROVPCKQ-UHFFFAOYSA-M chlorite Chemical compound [O-]Cl=O QBWCMBCROVPCKQ-UHFFFAOYSA-M 0.000 claims description 24
- 238000009792 diffusion process Methods 0.000 claims description 24
- 230000007062 hydrolysis Effects 0.000 claims description 17
- 238000006460 hydrolysis reaction Methods 0.000 claims description 17
- 239000011185 multilayer composite material Substances 0.000 claims description 13
- 230000004888 barrier function Effects 0.000 claims description 8
- 239000002274 desiccant Substances 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- 239000010410 layer Substances 0.000 description 159
- 239000000463 material Substances 0.000 description 100
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 description 99
- 150000001412 amines Chemical class 0.000 description 60
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 54
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 54
- 239000010408 film Substances 0.000 description 51
- 239000012071 phase Substances 0.000 description 45
- 239000001993 wax Substances 0.000 description 41
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 30
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 30
- 239000004202 carbamide Substances 0.000 description 27
- 239000007789 gas Substances 0.000 description 27
- 239000002245 particle Substances 0.000 description 27
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 25
- 238000006243 chemical reaction Methods 0.000 description 25
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 24
- 230000012010 growth Effects 0.000 description 24
- 235000013372 meat Nutrition 0.000 description 24
- 239000000123 paper Substances 0.000 description 24
- 239000000843 powder Substances 0.000 description 24
- 239000002904 solvent Substances 0.000 description 23
- UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 description 22
- 238000013270 controlled release Methods 0.000 description 21
- 229960002218 sodium chlorite Drugs 0.000 description 21
- 150000002500 ions Chemical class 0.000 description 20
- 239000000243 solution Substances 0.000 description 20
- 239000012298 atmosphere Substances 0.000 description 19
- 238000000576 coating method Methods 0.000 description 18
- 238000000034 method Methods 0.000 description 18
- 229920001577 copolymer Polymers 0.000 description 16
- 239000001257 hydrogen Substances 0.000 description 16
- 229910052739 hydrogen Inorganic materials 0.000 description 16
- FHHSDJDNHUGWRI-UHFFFAOYSA-N 3-methyl-2-methylidenebutanamide;prop-2-enamide Chemical compound NC(=O)C=C.CC(C)C(=C)C(N)=O FHHSDJDNHUGWRI-UHFFFAOYSA-N 0.000 description 15
- OHLUUHNLEMFGTQ-UHFFFAOYSA-N N-methylacetamide Chemical compound CNC(C)=O OHLUUHNLEMFGTQ-UHFFFAOYSA-N 0.000 description 15
- 150000008064 anhydrides Chemical class 0.000 description 15
- 230000001580 bacterial effect Effects 0.000 description 15
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 14
- 241000894006 Bacteria Species 0.000 description 14
- 239000011248 coating agent Substances 0.000 description 14
- 229910052757 nitrogen Inorganic materials 0.000 description 14
- 239000000523 sample Substances 0.000 description 14
- 239000004014 plasticizer Substances 0.000 description 13
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 12
- 150000001336 alkenes Chemical class 0.000 description 12
- 229920000642 polymer Polymers 0.000 description 12
- 239000006185 dispersion Substances 0.000 description 11
- 230000002538 fungal effect Effects 0.000 description 11
- 150000003335 secondary amines Chemical class 0.000 description 11
- 238000012360 testing method Methods 0.000 description 11
- 229910019142 PO4 Inorganic materials 0.000 description 10
- 239000004698 Polyethylene Substances 0.000 description 10
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 10
- 150000001408 amides Chemical class 0.000 description 10
- 235000011187 glycerol Nutrition 0.000 description 10
- 235000021317 phosphate Nutrition 0.000 description 10
- 229920000573 polyethylene Polymers 0.000 description 10
- 230000001954 sterilising effect Effects 0.000 description 10
- 238000003860 storage Methods 0.000 description 10
- 239000004215 Carbon black (E152) Substances 0.000 description 9
- 241000233866 Fungi Species 0.000 description 9
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 9
- 239000004743 Polypropylene Substances 0.000 description 9
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 9
- 230000006870 function Effects 0.000 description 9
- 229930195733 hydrocarbon Natural products 0.000 description 9
- 150000002430 hydrocarbons Chemical class 0.000 description 9
- 229920001155 polypropylene Polymers 0.000 description 9
- 150000003141 primary amines Chemical class 0.000 description 9
- 238000004659 sterilization and disinfection Methods 0.000 description 9
- 150000003512 tertiary amines Chemical class 0.000 description 9
- 150000004703 alkoxides Chemical class 0.000 description 8
- 239000002775 capsule Substances 0.000 description 8
- 239000000499 gel Substances 0.000 description 8
- 150000007524 organic acids Chemical class 0.000 description 8
- 238000004806 packaging method and process Methods 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 230000002829 reductive effect Effects 0.000 description 8
- 229920001817 Agar Polymers 0.000 description 7
- 239000008272 agar Substances 0.000 description 7
- 125000000217 alkyl group Chemical group 0.000 description 7
- 238000004364 calculation method Methods 0.000 description 7
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 7
- 239000003085 diluting agent Substances 0.000 description 7
- 150000002148 esters Chemical class 0.000 description 7
- 235000013305 food Nutrition 0.000 description 7
- 238000002844 melting Methods 0.000 description 7
- 230000008018 melting Effects 0.000 description 7
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 7
- 239000011087 paperboard Substances 0.000 description 7
- 239000010452 phosphate Substances 0.000 description 7
- 239000013641 positive control Substances 0.000 description 7
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 6
- 241000588724 Escherichia coli Species 0.000 description 6
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- 230000000844 anti-bacterial effect Effects 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 238000011109 contamination Methods 0.000 description 6
- 230000007423 decrease Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 150000007522 mineralic acids Chemical class 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-O oxonium Chemical compound [OH3+] XLYOFNOQVPJJNP-UHFFFAOYSA-O 0.000 description 6
- 229920003023 plastic Polymers 0.000 description 6
- 239000004033 plastic Substances 0.000 description 6
- 229920000098 polyolefin Polymers 0.000 description 6
- 238000013268 sustained release Methods 0.000 description 6
- 239000012730 sustained-release form Substances 0.000 description 6
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 6
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 5
- 125000005647 linker group Chemical group 0.000 description 5
- 239000011159 matrix material Substances 0.000 description 5
- 230000007246 mechanism Effects 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 230000001105 regulatory effect Effects 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 4
- VHYFNPMBLIVWCW-UHFFFAOYSA-N 4-Dimethylaminopyridine Chemical compound CN(C)C1=CC=NC=C1 VHYFNPMBLIVWCW-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 239000011837 N,N-methylenebisacrylamide Substances 0.000 description 4
- ATHHXGZTWNVVOU-UHFFFAOYSA-N N-methylformamide Chemical compound CNC=O ATHHXGZTWNVVOU-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 239000004793 Polystyrene Substances 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 4
- 238000005266 casting Methods 0.000 description 4
- 125000000753 cycloalkyl group Chemical group 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 4
- 239000002054 inoculum Substances 0.000 description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 4
- 239000002609 medium Substances 0.000 description 4
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 4
- 230000020477 pH reduction Effects 0.000 description 4
- 229920002223 polystyrene Polymers 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000001632 sodium acetate Substances 0.000 description 4
- 235000017281 sodium acetate Nutrition 0.000 description 4
- 241000894007 species Species 0.000 description 4
- 230000006641 stabilisation Effects 0.000 description 4
- 238000011105 stabilization Methods 0.000 description 4
- 238000012546 transfer Methods 0.000 description 4
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 4
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 3
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 3
- 229910004852 P—O—Si Inorganic materials 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 241000700605 Viruses Species 0.000 description 3
- 150000001266 acyl halides Chemical class 0.000 description 3
- 235000015278 beef Nutrition 0.000 description 3
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- 150000001768 cations Chemical class 0.000 description 3
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- 229940005993 chlorite ion Drugs 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
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- 239000004310 lactic acid Substances 0.000 description 3
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- ASMUSBIQKPGHMD-UHFFFAOYSA-N oxido-oxo-silylphosphanium Chemical class P(=O)(=O)[SiH3] ASMUSBIQKPGHMD-UHFFFAOYSA-N 0.000 description 3
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- 239000002699 waste material Substances 0.000 description 3
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- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/02—Oxides of chlorine
- C01B11/022—Chlorine dioxide (ClO2)
- C01B11/023—Preparation from chlorites or chlorates
- C01B11/024—Preparation from chlorites or chlorates from chlorites
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
- A23B2/00—Preservation of foods or foodstuffs, in general
- A23B2/70—Preservation of foods or foodstuffs, in general by treatment with chemicals
- A23B2/704—Preservation of foods or foodstuffs, in general by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
- A23B2/00—Preservation of foods or foodstuffs, in general
- A23B2/70—Preservation of foods or foodstuffs, in general by treatment with chemicals
- A23B2/725—Preservation of foods or foodstuffs, in general by treatment with chemicals in the form of liquids or solids
- A23B2/788—Inorganic compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
- A23B9/00—Preservation of edible seeds, e.g. cereals
- A23B9/14—Coating with a protective layer; Compositions or apparatus therefor
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
- A23B9/00—Preservation of edible seeds, e.g. cereals
- A23B9/16—Preserving with chemicals
- A23B9/24—Preserving with chemicals in the form of liquids or solids
- A23B9/30—Inorganic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K47/00—Medicinal preparations characterised by the non-active ingredients used, e.g. carriers or inert additives; Targeting or modifying agents chemically bound to the active ingredient
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/02—Oxides of chlorine
- C01B11/022—Chlorine dioxide (ClO2)
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Food Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Environmental Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
- Pharmacology & Pharmacy (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dispersion Chemistry (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Medicinal Preparation (AREA)
- Laminated Bodies (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Materials For Medical Uses (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/461,304 | 1995-06-05 | ||
| US08/461,304 US5705092A (en) | 1995-06-05 | 1995-06-05 | Multilayered biocidal film compositions |
| PCT/US1996/009199 WO1996039028A1 (en) | 1995-06-05 | 1996-06-04 | Multilayered biocidal film compositions |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JPH11501938A JPH11501938A (ja) | 1999-02-16 |
| JPH11501938A5 JPH11501938A5 (enExample) | 2004-07-22 |
| JP3987108B2 true JP3987108B2 (ja) | 2007-10-03 |
Family
ID=23832035
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP50157897A Expired - Lifetime JP3987108B2 (ja) | 1995-06-05 | 1996-06-04 | 多層殺菌フィルム組成物 |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US5705092A (enExample) |
| EP (1) | EP0774897B1 (enExample) |
| JP (1) | JP3987108B2 (enExample) |
| KR (1) | KR100428229B1 (enExample) |
| AR (1) | AR003684A1 (enExample) |
| AU (1) | AU700406B2 (enExample) |
| BR (1) | BR9606419A (enExample) |
| CA (1) | CA2196781C (enExample) |
| DE (1) | DE69629891T2 (enExample) |
| MX (1) | MX9700956A (enExample) |
| MY (1) | MY115463A (enExample) |
| NZ (1) | NZ311875A (enExample) |
| TW (1) | TW371257B (enExample) |
| WO (1) | WO1996039028A1 (enExample) |
Families Citing this family (59)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6585843B2 (en) * | 1992-01-10 | 2003-07-01 | Super Sack Mfg. Corp. | Anti-static, anti-corrosion, and/or anti-microbial films, fabrics, and articles |
| US6046243A (en) * | 1993-02-12 | 2000-04-04 | Bernard Technologies, Inc. | Compositions for sustained release of a gas |
| AU713284B2 (en) * | 1995-06-12 | 1999-11-25 | Bernard Technologies, Inc. | Sustained release, transparent biocidal compositions |
| WO1998011776A1 (en) * | 1996-09-18 | 1998-03-26 | Bernard Technologies, Inc. | Powders providing controlled sustained release of a gas |
| US6174508B1 (en) | 1997-02-11 | 2001-01-16 | Fred Klatte | Method of producing chlorine dioxide using sodium chlorite and a water-retaining substance impregnated in zeolite or in aqueous solution |
| EP1027280B1 (en) | 1997-11-07 | 2003-04-23 | Engelhard Corporation | Method and device for the production of an aqueous solution containing chlorine dioxide |
| US6277408B1 (en) | 1998-02-09 | 2001-08-21 | Southwest Research Institute | Silicate-containing powders providing controlled, sustained gas release |
| US6605304B1 (en) | 1998-02-09 | 2003-08-12 | Bernard Technologies, Inc. | Silicate-containing powders providing controlled, sustained gas release |
| WO2000021879A1 (en) * | 1998-10-09 | 2000-04-20 | Dennis Charles Clemes | Chlorine dioxide generators |
| AU1745500A (en) * | 1998-11-25 | 2000-06-19 | Engelhard Corporation | Methods and systems for reducing microbial populations |
| US6039979A (en) * | 1999-01-13 | 2000-03-21 | Laboratoires Prographarm | Multiparticulate pharmaceutical form with programmed and pulsed release and process for its preparation |
| CA2373333C (en) * | 1999-05-18 | 2009-09-29 | Southwest Research Institute | Energy-activated compositions for controlled sustained release of a gas |
| US7273567B1 (en) | 1999-11-24 | 2007-09-25 | Microactive Corp. | Energy-activated compositions for controlled sustained release of a gas |
| US6767509B1 (en) | 1999-06-16 | 2004-07-27 | Kimberly-Clark Worldwide, Inc. | Self-sterilizing packaging |
| MXPA02007993A (es) * | 2000-02-18 | 2004-04-05 | Selective Micro Technologies L | Aparato y metodo para entrega controlada de un gas. |
| US6607696B1 (en) * | 2000-02-18 | 2003-08-19 | Selective Micro Technologies, Llc | Apparatus and method for controlled delivery of a gas |
| US7922984B2 (en) * | 2000-02-18 | 2011-04-12 | Selective Micro Technologies, Llc | Apparatus and method for controlled delivery of a gas |
| US6764661B1 (en) | 2000-06-27 | 2004-07-20 | Avantec Technologies, Inc. | Device for producing an aqueous chlorine dioxide solution |
| WO2002058748A1 (en) * | 2001-01-26 | 2002-08-01 | Camelot Technologies Limited | Absorbent pad for rendering hazardous liquids non-hazardous |
| US6589591B1 (en) | 2001-07-10 | 2003-07-08 | Baylor College Of Medicine | Method for treating medical devices using glycerol and an antimicrobial agent |
| US7195744B2 (en) * | 2001-08-28 | 2007-03-27 | Ecolab, Inc. | Device for holding a container for a composition that produces an antimicrobially active gas |
| US6620380B2 (en) | 2001-09-14 | 2003-09-16 | Ecolab, Inc. | Method, device and composition for the sustained release of an antimicrobial gas |
| WO2003051407A1 (en) * | 2001-12-17 | 2003-06-26 | Selective Micro Technologies, Llc | Apparatus and methods for delivery of a gas |
| AU2003205058A1 (en) * | 2002-01-08 | 2003-07-24 | Bernard Techologies, Inc. | Antimicrobial body covering articles |
| US7150854B2 (en) * | 2002-03-19 | 2006-12-19 | Engelhard Corporation | Device for generating aqueous chlorine dioxide solutions |
| US20030190273A1 (en) * | 2002-04-09 | 2003-10-09 | Bernard Technologies, Inc. | Container liner for inhibiting decay of perishable items |
| AU2003235188A1 (en) * | 2002-04-29 | 2003-11-17 | Sk Aquatech Co., Ltd. | Simple apparatus for producing chlorine dioxide gas |
| US6619051B1 (en) | 2002-07-12 | 2003-09-16 | Ecolab Inc. | Integrated cleaning and sanitizing system and method for ice machines |
| US20040137039A1 (en) * | 2002-07-22 | 2004-07-15 | Trustees Of Stevens Institute Of Technology | Methods for controlled release of molecules from layered polymer films |
| US7922992B2 (en) * | 2002-09-13 | 2011-04-12 | Ica Trinova, Llc | Composition and method for producing carbon dioxide |
| GB0228870D0 (en) * | 2002-12-10 | 2003-01-15 | Ace Three Uk Ltd | Sulphur dioxide release coastings |
| US7285255B2 (en) * | 2002-12-10 | 2007-10-23 | Ecolab Inc. | Deodorizing and sanitizing employing a wicking device |
| US20040170671A1 (en) * | 2003-03-05 | 2004-09-02 | Jian Tao | Thin wall gloves that release chlorine dioxide |
| US20040256561A1 (en) * | 2003-06-17 | 2004-12-23 | Allyson Beuhler | Wide band light sensing pixel array |
| US7243788B2 (en) * | 2003-10-22 | 2007-07-17 | Kimberly-Clark Worldwide, Inc. | Package for segregating and mixing substances |
| US20060216496A2 (en) * | 2003-11-13 | 2006-09-28 | Bernard Technologies, Inc. | Gas Generating Polymers |
| EP1737378A2 (en) * | 2004-04-02 | 2007-01-03 | Baylor College of Medicine | Novel modification of medical prostheses |
| US8900610B2 (en) * | 2004-08-30 | 2014-12-02 | Southwest Research Institute | Biocidal fibrous and film materials comprising silver and chlorite ions |
| WO2006026573A2 (en) * | 2004-08-30 | 2006-03-09 | Southwest Research Institute | Biocidal fibrous and film materials utilizing silver ion |
| US20060178445A1 (en) * | 2004-12-16 | 2006-08-10 | Mcintyre Patrick F | Composition for controlled sustained release of a gas |
| US20100062220A1 (en) * | 2005-05-30 | 2010-03-11 | Yasushi Nishikawa | Process for producing graphite film and graphite film produced thereby |
| US8673297B2 (en) * | 2006-02-28 | 2014-03-18 | Basf Corporation | Chlorine dioxide based cleaner/sanitizer |
| JP2010511097A (ja) * | 2006-11-27 | 2010-04-08 | マイクロアクティブ・コーポレイション | 気体を徐放するための溶融加工可能な相溶性ポリマーブレンド |
| US8129327B2 (en) | 2006-12-01 | 2012-03-06 | The Procter & Gamble Company | Packaging for high moisture bar soap |
| US8383549B2 (en) * | 2007-07-20 | 2013-02-26 | Bayer Cropscience Lp | Methods of increasing crop yield and controlling the growth of weeds using a polymer composite film |
| PT2170602E (pt) | 2007-07-20 | 2012-01-16 | Bayer Innovation Gmbh | Película de polímero compósito com funcionalidade de barreira |
| PT2170044E (pt) | 2007-07-20 | 2014-04-02 | Bayer Innovation Gmbh | Material compósito polimérico com uma funcionalidade biocida |
| US8741325B2 (en) * | 2008-12-18 | 2014-06-03 | The Hong Kong University Of Science And Technology | Material for forming a multi-level antimicrobial surface coating and its preparation |
| US20100183785A1 (en) * | 2009-01-21 | 2010-07-22 | Manuel Ii Zuniga | Method for doing business to retard bacterial, fungal, and viral contamination and mold growth in fruits |
| US9382116B2 (en) | 2013-01-10 | 2016-07-05 | Ica Trinova, Llc | Mixtures for producing chlorine dioxide gas in enclosures and methods of making the same |
| US9517934B2 (en) | 2013-03-14 | 2016-12-13 | The United States Of America As Represented By The Secretary Of The Army | Process for the generation of chlorine dioxide |
| WO2015130992A1 (en) * | 2014-02-28 | 2015-09-03 | Biovation Ii, Llc | Biocidal sachet for food safety |
| CN112389060B (zh) * | 2015-08-18 | 2023-04-18 | 威斯康星校友研究基金会 | ClO2气体从医疗器械包装膜的释放 |
| WO2017192717A1 (en) | 2016-05-05 | 2017-11-09 | Southwest Research Institute | Three-dimensional bioreactor for cell expansion and related applications |
| US11149244B2 (en) | 2018-04-04 | 2021-10-19 | Southwest Research Institute | Three-dimensional bioreactor for T-cell activation and expansion for immunotherapy |
| CN108690625B (zh) * | 2018-04-28 | 2020-12-15 | 上海市环境科学研究院 | 一种用于处理土壤中持久性卤代烃的缓释复合修复药剂及其制备方法 |
| WO2020068840A1 (en) | 2018-09-24 | 2020-04-02 | Southwest Research Institute | Three-dimensional bioreactors |
| US11492580B2 (en) | 2020-05-12 | 2022-11-08 | Southwest Research Institute | Method using a three-dimensional bioprocessor |
| US12036525B2 (en) | 2020-10-27 | 2024-07-16 | Selective Micro Technologies, Llc | Gas micro reactor utilizing membrane packaging |
Family Cites Families (44)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2071625A (en) * | 1931-06-03 | 1937-02-23 | W E Long Co | Preservation of packaged food products |
| US2546568A (en) * | 1945-01-11 | 1951-03-27 | Olin Mathieson | Process for the preservation of comestible materials |
| US2482891A (en) * | 1945-03-16 | 1949-09-27 | Olin Mathieson | Solid, stable chlorine dioxide generating compositions |
| US2558942A (en) * | 1947-02-03 | 1951-07-03 | Eagleson Craig | Sanitizing composition |
| US3183057A (en) * | 1958-11-03 | 1965-05-11 | Wallace & Tiernan Inc | Products and procedures for effecting treatiment with chlorinous gas |
| US3591515A (en) * | 1968-04-16 | 1971-07-06 | Int Dioxide Inc | Pulverulent chlorine dioxide compositions |
| US3585147A (en) * | 1969-10-01 | 1971-06-15 | Int Dioxcide Inc | Stabilized chlorine dioxide solutions containing a chloride and processes of making and using same |
| US3767787A (en) * | 1971-10-07 | 1973-10-23 | H Segal | Retarded vaporization compositions and method for making |
| GB1579431A (en) * | 1976-03-23 | 1980-11-19 | Minnesota Mining & Mfg | Disinfecting and/or sterilising |
| US4330531A (en) * | 1976-03-26 | 1982-05-18 | Howard Alliger | Germ-killing materials |
| US4499077A (en) * | 1981-02-03 | 1985-02-12 | Stockel Richard F | Anti-microbial compositions and associated methods for preparing the same and for the disinfecting of various objects |
| JPS57198775A (en) * | 1981-06-01 | 1982-12-06 | Nasa:Kk | Molding material having deodorizing function, etc. |
| US4728498A (en) * | 1981-11-02 | 1988-03-01 | Alza Corporation | Process for disinfecting article with device dispensing chlorine donor and chlorine acceptor |
| US4504442A (en) * | 1982-10-19 | 1985-03-12 | Scopas Technology Corporation | Use of chlorine dioxide gas as a chemosterilizing agent |
| US4681739A (en) * | 1982-10-19 | 1987-07-21 | The Scopas Technology Co., Inc. | Use of chlorine dioxide gas as a chemosterilizing agent |
| JPS6092759A (ja) * | 1983-10-26 | 1985-05-24 | 土倉 満 | 合成樹脂素材の成型に係る物品に消臭浄化剤の含浸装置 |
| US4547381A (en) * | 1983-11-10 | 1985-10-15 | Rio Linda Chemical Co., Inc. | Dry compositions for the production of chlorine dioxide |
| US4689169A (en) * | 1983-11-10 | 1987-08-25 | Rio Linda Chemical Company, Inc. | Dry compositions for the production of chlorine dioxide |
| US4533691A (en) * | 1983-12-12 | 1985-08-06 | Polysar Limited | Chlorine dioxide antimicrobial agent for latex |
| IN160430B (enExample) * | 1984-03-18 | 1987-07-11 | Alcide Corp | |
| US4986990A (en) * | 1984-03-21 | 1991-01-22 | Alcide Corporation | Disinfection method and composition therefor |
| US4585482A (en) * | 1984-05-25 | 1986-04-29 | Southern Research Institute | Long-acting biocidal compositions and method therefor |
| US4889654A (en) * | 1984-07-31 | 1989-12-26 | Rio Linda Chemical Company, Inc. | Aqueous foam disinfectant containing chlorine dixoide and preparation and use thereof |
| US4748904A (en) * | 1986-07-01 | 1988-06-07 | Razeto Andres V R | Chlorine generator for preservation of fruits and vegetables |
| US4891216A (en) * | 1987-04-14 | 1990-01-02 | Alcide Corporation | Disinfecting compositions and methods therefor |
| US4829129A (en) * | 1987-05-29 | 1989-05-09 | International Dioxcide, Inc. | Reaction product of polymer with chlorine dioxide |
| US4975109A (en) * | 1988-05-02 | 1990-12-04 | Lester Technologies Corp. | Microbiocidal combinations of materials and their use |
| US4956184A (en) * | 1988-05-06 | 1990-09-11 | Alcide Corporation | Topical treatment of genital herpes lesions |
| US4880638A (en) * | 1988-08-23 | 1989-11-14 | Bioxy International, Ltd. | Biocidal composition and method for disinfecting articles |
| US4925645A (en) * | 1988-10-05 | 1990-05-15 | Mason James A | Method of preparing a mixture of chlorine containing substances including chlorine dioxide |
| CN1023205C (zh) * | 1989-06-23 | 1993-12-22 | 栾和林 | 二氧化氯的制备方法及控制盒 |
| US5078908A (en) * | 1989-10-02 | 1992-01-07 | Allergan, Inc. | Methods for generating chlorine dioxide and compositions for disinfecting |
| US5126070A (en) * | 1989-10-20 | 1992-06-30 | The Drackett Company | Chlorine dioxide generator |
| US5387350A (en) * | 1989-11-20 | 1995-02-07 | George L. Williamson | Method and apparatus for treating and disinfecting infectious wastes |
| US5104660A (en) * | 1989-11-21 | 1992-04-14 | Bruce A. Barber | Method of preparing an antimicrobial wound dressing |
| JPH04164005A (ja) * | 1990-10-26 | 1992-06-09 | Takasugi Seiyaku Kk | 環境浄化組成物 |
| AU640053B2 (en) * | 1991-06-17 | 1993-08-12 | Rio Linda Chemical Co., Inc. | Generation of chlorine dioxide in a non-aqueous medium |
| US5252343A (en) * | 1992-03-20 | 1993-10-12 | Alcide Corporation | Method and composition for prevention and treatment of bacterial infections |
| IL102627A (en) * | 1992-07-23 | 1996-05-14 | Abic Ltd | Solid composition releasing chlorine dioxide |
| JPH06107971A (ja) * | 1992-09-25 | 1994-04-19 | Honny Chem Ind Co Ltd | 被覆用組成物 |
| US5360609A (en) * | 1993-02-12 | 1994-11-01 | Southwest Research Institute | Chlorine dioxide generating polymer packaging films |
| US5631300A (en) * | 1993-02-12 | 1997-05-20 | Southwest Research Institute | Method of making a sustained release biocidal composition |
| PT611163E (pt) * | 1993-02-12 | 2000-04-28 | Southwest Res Inst | Composicao biocida polimerica e metodo para a sua preparacao |
| ES2138764T3 (es) * | 1994-12-14 | 2000-01-16 | Alcide Corp | Composiciones desinfectantes adherentes y metodos relacionados. |
-
1995
- 1995-06-05 US US08/461,304 patent/US5705092A/en not_active Expired - Lifetime
-
1996
- 1996-06-03 MY MYPI96002145A patent/MY115463A/en unknown
- 1996-06-04 JP JP50157897A patent/JP3987108B2/ja not_active Expired - Lifetime
- 1996-06-04 DE DE69629891T patent/DE69629891T2/de not_active Expired - Fee Related
- 1996-06-04 MX MX9700956A patent/MX9700956A/es unknown
- 1996-06-04 BR BR9606419A patent/BR9606419A/pt unknown
- 1996-06-04 KR KR1019970700792A patent/KR100428229B1/ko not_active Expired - Fee Related
- 1996-06-04 AU AU63280/96A patent/AU700406B2/en not_active Ceased
- 1996-06-04 NZ NZ311875A patent/NZ311875A/en unknown
- 1996-06-04 EP EP96922397A patent/EP0774897B1/en not_active Expired - Lifetime
- 1996-06-04 CA CA002196781A patent/CA2196781C/en not_active Expired - Fee Related
- 1996-06-04 WO PCT/US1996/009199 patent/WO1996039028A1/en not_active Ceased
- 1996-06-05 AR ARP960102937A patent/AR003684A1/es unknown
- 1996-07-23 TW TW085108997A patent/TW371257B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| BR9606419A (pt) | 1997-09-30 |
| EP0774897A4 (en) | 2000-08-09 |
| KR970704338A (ko) | 1997-09-06 |
| US5705092A (en) | 1998-01-06 |
| MY115463A (en) | 2003-06-30 |
| MX9700956A (es) | 1998-01-31 |
| NZ311875A (en) | 1998-11-25 |
| HK1013212A1 (en) | 1999-08-20 |
| AU700406B2 (en) | 1999-01-07 |
| TW371257B (en) | 1999-10-01 |
| JPH11501938A (ja) | 1999-02-16 |
| DE69629891D1 (de) | 2003-10-16 |
| WO1996039028A1 (en) | 1996-12-12 |
| EP0774897B1 (en) | 2003-09-10 |
| AU6328096A (en) | 1996-12-24 |
| DE69629891T2 (de) | 2004-07-15 |
| CA2196781A1 (en) | 1996-12-12 |
| KR100428229B1 (ko) | 2004-06-16 |
| EP0774897A1 (en) | 1997-05-28 |
| CA2196781C (en) | 2005-11-29 |
| AR003684A1 (es) | 1998-09-09 |
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