JP3663581B2 - Wood tar metamorphosis - Google Patents
Wood tar metamorphosis Download PDFInfo
- Publication number
- JP3663581B2 JP3663581B2 JP2001312310A JP2001312310A JP3663581B2 JP 3663581 B2 JP3663581 B2 JP 3663581B2 JP 2001312310 A JP2001312310 A JP 2001312310A JP 2001312310 A JP2001312310 A JP 2001312310A JP 3663581 B2 JP3663581 B2 JP 3663581B2
- Authority
- JP
- Japan
- Prior art keywords
- wood tar
- wood
- tar
- modified product
- foamed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Description
【0001】
【発明の属する技術分野】
この発明は有効利用することができる木タール変成物に関するものである。
【0002】
【従来の技術】
木質成分を熱分解すると、木炭、木酢液、木タール等が得られる。このうち、木炭、木酢液は現在多様な用途がある。
【0003】
しかし、木タールはそれを蒸留精製して得られる木クレオソートが医薬品に使われているなどの特殊な用途を除けば、ほとんど利用されることがなく、不要残渣として焼却処分していることが多く、何らかの有効利用ができないかと模索していた。
【0004】
【発明が解決しようとする課題】
そこでこの発明は、有効利用することができる木タール変成物を提供しようとするものである。
【0005】
【課題を解決するための手段】
前記課題を解決するためこの発明では次のような技術的手段を講じている。
(1)この発明の木タール変成物は、木タールを加熱して発泡させ、ポーラス構造としたことを特徴とする。
【0006】
この木タール変成物では、木タールを加熱して発泡させており、この発泡物の組成は木炭の組成と近似していて殆どが炭素から成るが、その構造はポーラス(多孔)構造であり、吸着性(吸湿性等)や断熱性に優れる。
【0007】
このようにポーラス(多孔)構造であり高い吸着性(吸湿性等)その他の特性を有し、例えば土壌改良材、水質浄化資材、消臭剤として好適に用いることができ、忌避剤としても好適に用いることができる。また高い炭素含有量を有するので、コークス等の代替として炭素繊維原料として好適に用いることができ、同様に石炭・石油資源等の代替としてバイオマスエネルギー燃料として好適に用いることができる。
(2)所望の形状になるように加熱成形してもよい。
【0008】
このように構成すると、例えば壁材や調湿材、床下材などの形状に加熱成形して、木炭と同様に有効利用を図ることができる。また軽くて自由に成型可能であり、粉体等に成形して使用することもできる。
(3)前記発泡させた木タールを焼成して成ることとしてもよい。
【0009】
このように発泡させた木タールを焼成すると、元素の配列が変化してより密度の高い炭素系材料になるので、電磁波遮蔽材などとしても適用できる。
(4)この木タール変成物は、木材という天然由来材料を原料としており環境保全にも非常に好ましくエコ資材として多岐にわたって活用することができる。
【0010】
【発明の実施の形態】
以下、この発明の実施の形態を図面を参照して説明する。
【0011】
先ず、木タールを次のようにして得た。すなわち図1に示すように、窯内で木材を約1000℃で乾留して生じた煙を液化冷却し、原料タールを得た。この原料タールを減圧蒸留し、粗木酢液を取り除いて、木タール(沈降タール)を得た。この木タールを釜に入れ、約300℃で約4時間、板状もしくは適当な形状になるように加熱成形して発泡させてポーラス(多孔)構造の木タール変成物を得た。
【0012】
この発泡物はウエハース状で、組成は殆どが炭素からなる。即ち前記木タール変成物の元素分析を行った結果、炭素が80.57%、水素が4.64%、窒素が1.48%であり、高い炭素含有量を有することが明らかとなった。また、この木タール変成物の電子顕微鏡写真(撮影条件は40倍)を撮った。図2は、前記電子顕微鏡写真を図面化したものである。この顕微鏡写真には幾つもの空洞部1が写っており、ポーラス構造を有することが明確に把握できる。
【0013】
ところで、木タールを減圧蒸留した際に蒸留されずに釜に残った黒い粘ちょうな物質が木ピッチであるが、これは木タールから木タールオイルを除いたもので、これからも同様の変成物が得られた。
【0014】
さらに前記発泡物を1500℃前後以上で焼成して木タール変成物を得た。
【0015】
次に、この実施形態の木タール変成物の使用状態を説明する。
【0016】
この木タール変成物では、木タールを加熱して発泡させており、この発泡物の組成は木炭の組成と近似していて殆どが炭素から成るが、その構造はポーラス構造であり、吸着性(吸湿性等)や断熱性に優れ、この特性を生かして有効利用をすることができるという利点がある。
【0017】
また、発泡ができ、条件により色々な成形が可能であり、所望の形状となるように加熱成形し発泡させると、例えば壁材や調湿材、床下材などの形状に加熱成形して、木炭と同様に有効利用を図ることができるという利点がある。
【0018】
さらに、前記発泡物を高温(例えば1500℃前後以上)で焼成すると、元素の配列が変化してより密度の高い炭素系材料になるので、例えばその通電性の高さを利用して電磁波遮蔽材などとしても適用できるという利点がある。
【0019】
【発明の効果】
この発明は上記のような構成であり、次の効果を有する。
【0020】
この発泡物は吸着性や断熱性に優れ、この特性を生かして有効利用をすることができる木タール変成物を提供することができる。
【0021】
また、焼成することにより炭素系材料に変換すると、この特性を生かして更に有効利用を図ることができる。
【図面の簡単な説明】
【図1】 この発明の木タールの製造方法を説明する図。
【図2】 得られた木タール変成物の電子顕微鏡写真を図面化したもの。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a wood tar modified product which can be used effectively.
[0002]
[Prior art]
When the wood component is pyrolyzed, charcoal, wood vinegar, wood tar and the like are obtained. Of these, charcoal and wood vinegar have a variety of uses.
[0003]
However, wood tar is rarely used except for special uses such as wood creosote obtained by distillation purification and used for pharmaceuticals, and it is incinerated as an unnecessary residue. Many were looking for some kind of effective use.
[0004]
[Problems to be solved by the invention]
Therefore, the present invention intends to provide a wood tar modified product that can be used effectively.
[0005]
[Means for Solving the Problems]
In order to solve the above problems, the present invention takes the following technical means.
(1) The wood tar modified product of the present invention is characterized in that wood tar is heated and foamed to have a porous structure.
[0006]
In this wood tar modified product, wood tar is heated and foamed, and the composition of this foam is similar to that of charcoal and is mostly composed of carbon, but its structure is a porous structure. Excellent adsorptivity (hygroscopicity) and heat insulation.
[0007]
Thus, it has a porous (porous) structure and has high adsorptive properties (such as hygroscopicity) and other characteristics. For example, it can be suitably used as a soil conditioner, water purification material, deodorant, and also suitable as a repellent. Can be used. Moreover, since it has a high carbon content, it can be suitably used as a carbon fiber raw material as an alternative to coke and the like, and can also be suitably used as a biomass energy fuel as an alternative to coal and petroleum resources.
(2) You may heat-mold so that it may become a desired shape.
[0008]
If comprised in this way, it can heat-mold, for example in shapes, such as a wall material, a humidity control material, and an underfloor material, and can aim at effective utilization similarly to charcoal. Further, it is light and can be freely molded, and can be molded into a powder or the like.
(3) The foamed wood tar may be fired.
[0009]
When the wood tar thus foamed is fired, the arrangement of the elements changes and the carbon-based material has a higher density. Therefore, it can also be applied as an electromagnetic shielding material.
(4) This wood tar modified product is made from a naturally-derived material called wood, which is very preferable for environmental conservation and can be used in various ways as an eco-material.
[0010]
DETAILED DESCRIPTION OF THE INVENTION
Embodiments of the present invention will be described below with reference to the drawings.
[0011]
First, wood tar was obtained as follows. That is, as shown in FIG. 1, smoke generated by dry distillation of wood at about 1000 ° C. in a kiln was liquefied and cooled to obtain raw material tar. This raw material tar was distilled under reduced pressure, and the crude wood vinegar was removed to obtain wood tar (precipitated tar). This wood tar was put in a kettle, and was molded by heating to form a plate or a suitable shape at about 300 ° C. for about 4 hours, and foamed to obtain a porous (porous) wood tar modified product.
[0012]
This foam is in the form of a wafer and is composed mostly of carbon. That is, as a result of elemental analysis of the wood tar modification, it was revealed that carbon had a high carbon content of 80.57%, hydrogen of 4.64%, and nitrogen of 1.48%. In addition, an electron micrograph (40.times. Photographing condition) of this wood tar modified was taken. FIG. 2 is a drawing of the electron micrograph. In this micrograph, a number of
[0013]
By the way, when the wooden tar is distilled under reduced pressure, the black sticky substance that remains in the kettle without being distilled is the wooden pitch. This is the wooden tar excluding the wooden tar oil. was gotten.
[0014]
Furthermore, the foam was fired at about 1500 ° C. or higher to obtain a wood tar modified product.
[0015]
Next, the use state of the wood tar modified product of this embodiment will be described.
[0016]
In this wood tar modified product, wood tar is heated and foamed, and the composition of this foam is similar to that of charcoal and is mostly composed of carbon. It has excellent hygroscopicity and heat insulation properties, and has the advantage that it can be used effectively by taking advantage of this property.
[0017]
In addition, it can be foamed and can be molded in various ways depending on conditions. When it is molded and foamed to a desired shape, it is thermoformed into a shape such as a wall material, humidity control material, or underfloor material. There is an advantage that it can be used effectively in the same way.
[0018]
Furthermore, when the foam is fired at a high temperature (for example, around 1500 ° C. or more), the arrangement of the elements changes to become a higher-density carbon-based material. There is an advantage that it can be applied.
[0019]
【The invention's effect】
The present invention is configured as described above and has the following effects.
[0020]
This foam is excellent in adsorptivity and heat insulation, and can provide a wood tar modified product that can be effectively utilized by taking advantage of this property.
[0021]
Further, when converted into a carbon-based material by firing, it is possible to further effectively utilize the characteristics.
[Brief description of the drawings]
FIG. 1 is a diagram for explaining a method for producing wood tar according to the present invention.
FIG. 2 is an electron micrograph of the obtained wood tar modification.
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2001312310A JP3663581B2 (en) | 2000-10-13 | 2001-10-10 | Wood tar metamorphosis |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000313058 | 2000-10-13 | ||
JP2000-313058 | 2000-10-13 | ||
JP2001312310A JP3663581B2 (en) | 2000-10-13 | 2001-10-10 | Wood tar metamorphosis |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2002201302A JP2002201302A (en) | 2002-07-19 |
JP3663581B2 true JP3663581B2 (en) | 2005-06-22 |
Family
ID=26602024
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2001312310A Expired - Fee Related JP3663581B2 (en) | 2000-10-13 | 2001-10-10 | Wood tar metamorphosis |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3663581B2 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100746359B1 (en) | 2006-02-28 | 2007-08-10 | 대한민국 | Manufacturing method of carbon powder using wood tar |
-
2001
- 2001-10-10 JP JP2001312310A patent/JP3663581B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
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JP2002201302A (en) | 2002-07-19 |
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