JP2002201302A - Modified product of wood tar - Google Patents

Modified product of wood tar

Info

Publication number
JP2002201302A
JP2002201302A JP2001312310A JP2001312310A JP2002201302A JP 2002201302 A JP2002201302 A JP 2002201302A JP 2001312310 A JP2001312310 A JP 2001312310A JP 2001312310 A JP2001312310 A JP 2001312310A JP 2002201302 A JP2002201302 A JP 2002201302A
Authority
JP
Japan
Prior art keywords
wood tar
wood
tar
modified product
foamed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2001312310A
Other languages
Japanese (ja)
Other versions
JP3663581B2 (en
Inventor
Akira Shibata
晃 柴田
Yuji Enomoto
雄司 榎本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Taiko Tec Co Ltd
Original Assignee
Taiko Tec Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Taiko Tec Co Ltd filed Critical Taiko Tec Co Ltd
Priority to JP2001312310A priority Critical patent/JP3663581B2/en
Publication of JP2002201302A publication Critical patent/JP2002201302A/en
Application granted granted Critical
Publication of JP3663581B2 publication Critical patent/JP3663581B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Landscapes

  • Chemical And Physical Treatments For Wood And The Like (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide an effectively utilizable, modified product of a wood tar. SOLUTION: The wood tar is heated and foamed to provide a porous structure. The modified product of the wood tar is obtained by heating the wood tar to foam the wood tar, and the foamed product has a composition resembled to that of a charcoal and nearly composed of carbon, and the structure is a porous structure to provide excellent adsorptivity (hydroscopicity) and heat insulation. The modified product can be heated and formed so as to provide a desired shape. As a result, the wood tar can be effectively utilized as same as charcoal, e.g. by heating and forming the wood tar into a wall material, a humidity-controlling material, a flooring material or the like. The foamed product has a light weight, can be freely formed, and can be used by forming the wood tar into a powdery body.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】この発明は有効利用すること
ができる木タール変成物に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a modified wood tar which can be effectively used.

【0002】[0002]

【従来の技術】木質成分を熱分解すると、木炭、木酢
液、木タール等が得られる。このうち、木炭、木酢液は
現在多様な用途がある。
2. Description of the Prior Art Pyrolysis of woody components yields charcoal, wood vinegar, wood tar and the like. Among them, charcoal and wood vinegar have various uses at present.

【0003】しかし、木タールはそれを蒸留精製して得
られる木クレオソートが医薬品に使われているなどの特
殊な用途を除けば、ほとんど利用されることがなく、不
要残渣として焼却処分していることが多く、何らかの有
効利用ができないかと模索していた。
However, wood tar is hardly used except for special uses such as the use of wood creosote obtained by distilling and refining wood tar, and is incinerated as unnecessary residue. In many cases, they were looking for ways to use them effectively.

【0004】[0004]

【発明が解決しようとする課題】そこでこの発明は、有
効利用することができる木タール変成物を提供しようと
するものである。
SUMMARY OF THE INVENTION Accordingly, an object of the present invention is to provide a modified wood tar which can be effectively used.

【0005】[0005]

【課題を解決するための手段】前記課題を解決するため
この発明では次のような技術的手段を講じている。 この発明の木タール変成物は、木タールを加熱して
発泡させ、ポーラス構造としたことを特徴とする。
In order to solve the above-mentioned problems, the present invention employs the following technical means. The modified wood tar is characterized in that the wood tar is heated and foamed to have a porous structure.

【0006】この木タール変成物では、木タールを加熱
して発泡させており、この発泡物の組成は木炭の組成と
近似していて殆どが炭素から成るが、その構造はポーラ
ス(多孔)構造であり、吸着性(吸湿性等)や断熱性に
優れる。
In this modified wood tar, the wood tar is foamed by heating, and the composition of the foam is similar to the composition of charcoal and is mostly composed of carbon, but its structure is porous (porous). And is excellent in adsorptivity (such as moisture absorption) and heat insulation.

【0007】このようにポーラス(多孔)構造であり高
い吸着性(吸湿性等)その他の特性を有し、例えば土壌
改良材、水質浄化資材、消臭剤として好適に用いること
ができ、忌避剤としても好適に用いることができる。ま
た高い炭素含有量を有するので、コークス等の代替とし
て炭素繊維原料として好適に用いることができ、同様に
石炭・石油資源等の代替としてバイオマスエネルギー燃
料として好適に用いることができる。 所望の形状になるように加熱成形してもよい。
[0007] As described above, it has a porous structure and has high adsorptivity (hygroscopicity, etc.) and other characteristics, and can be suitably used as, for example, a soil improvement material, a water purification material, a deodorant, and a repellent. Can also be suitably used. Further, since it has a high carbon content, it can be suitably used as a carbon fiber raw material as a substitute for coke and the like, and similarly can be suitably used as a biomass energy fuel as a substitute for coal and petroleum resources. Heat molding may be performed to obtain a desired shape.

【0008】このように構成すると、例えば壁材や調湿
材、床下材などの形状に加熱成形して、木炭と同様に有
効利用を図ることができる。また軽くて自由に成型可能
であり、粉体等に成形して使用することもできる。 前記発泡物を焼成して成ることとしてもよい。
[0008] With this configuration, for example, it can be formed into a shape such as a wall material, a humidity control material, or a material under the floor, and can be effectively used similarly to charcoal. It is light and freely moldable, and can be used after being molded into powder or the like. The foam may be fired.

【0009】このように発泡物を焼成すると、元素の配
列が変化してより密度の高い炭素系材料になるので、電
磁波遮蔽材などとしても適用できる。 この木タール変成物は、木材という天然由来材料を
原料としており環境保全にも非常に好ましくエコ資材と
して多岐にわたって活用することができる。
When the foam is baked in this manner, the arrangement of elements changes to produce a carbon-based material having a higher density. Therefore, the foam can be used as an electromagnetic wave shielding material. This wood tar metamorphic product is made of a natural material called wood as a raw material, is very preferable for environmental protection, and can be widely used as an eco-material.

【0010】[0010]

【発明の実施の形態】以下、この発明の実施の形態を図
面を参照して説明する。
Embodiments of the present invention will be described below with reference to the drawings.

【0011】先ず、木タールを次のようにして得た。す
なわち図1に示すように、窯内で木材を約1000℃で
乾留して生じた煙を液化冷却し、原料タールを得た。こ
の原料タールを減圧蒸留し、粗木酢液を取り除いて、木
タール(沈降タール)を得た。この木タールを釜に入
れ、約300℃で約4時間、板状もしくは適当な形状に
なるように加熱成形して発泡させてポーラス(多孔)構
造の木タール変成物を得た。
First, wood tar was obtained as follows. That is, as shown in FIG. 1, wood was carbonized in a kiln at about 1000 ° C., and the resulting smoke was liquefied and cooled to obtain a raw material tar. This raw material tar was distilled under reduced pressure, and the crude wood vinegar was removed to obtain a wood tar (settled tar). The wood tar was placed in a kettle, heated at about 300 ° C. for about 4 hours to form a plate or an appropriate shape, and foamed to obtain a modified wood tar of a porous structure.

【0012】この発泡物はウエハース状で、組成は殆ど
が炭素からなる。即ち前記木タール変成物の元素分析を
行った結果、炭素が80.57%、水素が4.64%、
窒素が1.48%であり、高い炭素含有量を有すること
が明らかとなった。また、この木タール変成物の電子顕
微鏡写真(撮影条件は40倍)を撮った。図2は、前記
電子顕微鏡写真を図面化したものである。この顕微鏡写
真には幾つもの空洞部1が写っており、ポーラス構造を
有することが明確に把握できる。
This foam is in the form of a wafer, and is mostly composed of carbon. That is, as a result of performing an elemental analysis of the wood tar modified product, carbon was 80.57%, hydrogen was 4.64%,
Nitrogen was 1.48% and was found to have a high carbon content. An electron micrograph (photographing conditions: 40 times) of this wood tar metamorphic product was taken. FIG. 2 is a drawing of the electron micrograph. In this micrograph, several cavities 1 are shown, and it can be clearly grasped that it has a porous structure.

【0013】ところで、木タールを減圧蒸留した際に蒸
留されずに釜に残った黒い粘ちょうな物質が木ピッチで
あるが、これは木タールから木タールオイルを除いたも
ので、これからも同様の変成物が得られた。
[0013] By the way, when wood tar is distilled under reduced pressure, the black viscous substance which remains in the kettle without being distilled is wood pitch, which is obtained by removing wood tar oil from wood tar. The modified product was obtained.

【0014】さらに前記発泡物を1500℃前後以上で
焼成して木タール変成物を得た。
Further, the foam was calcined at about 1500 ° C. or higher to obtain a modified wood tar.

【0015】次に、この実施形態の木タール変成物の使
用状態を説明する。
Next, the state of use of the modified wood tar of this embodiment will be described.

【0016】この木タール変成物では、木タールを加熱
して発泡させており、この発泡物の組成は木炭の組成と
近似していて殆どが炭素から成るが、その構造はポーラ
ス構造であり、吸着性(吸湿性等)や断熱性に優れ、こ
の特性を生かして有効利用をすることができるという利
点がある。
In this modified wood tar, the wood tar is foamed by heating, and the composition of the foam is similar to the composition of charcoal and is mostly composed of carbon, but its structure is a porous structure. It is excellent in adsorptivity (hygroscopicity etc.) and heat insulation, and has the advantage that it can be used effectively by taking advantage of this property.

【0017】また、発泡ができ、条件により色々な成形
が可能であり、所望の形状となるように加熱成形し発泡
させると、例えば壁材や調湿材、床下材などの形状に加
熱成形して、木炭と同様に有効利用を図ることができる
という利点がある。
In addition, foaming can be performed, and various moldings can be performed depending on conditions. When the composition is heated and formed into a desired shape and then foamed, for example, the material is formed into a shape such as a wall material, a humidity control material, and a floor material by heating. Therefore, there is an advantage that effective utilization can be achieved similarly to charcoal.

【0018】さらに、前記発泡物を高温(例えば150
0℃前後以上)で焼成すると、元素の配列が変化してよ
り密度の高い炭素系材料になるので、例えばその通電性
の高さを利用して電磁波遮蔽材などとしても適用できる
という利点がある。
Further, the foam is heated to a high temperature (for example, 150
When calcined at about 0 ° C. or higher), the arrangement of elements changes and the carbon-based material becomes denser. Therefore, there is an advantage that the carbon-based material can be used as an electromagnetic wave shielding material or the like by utilizing its high conductivity. .

【0019】[0019]

【発明の効果】この発明は上記のような構成であり、次
の効果を有する。
The present invention is configured as described above and has the following effects.

【0020】この発泡物は吸着性や断熱性に優れ、この
特性を生かして有効利用をすることができる木タール変
成物を提供することができる。
This foam is excellent in adsorptive properties and heat insulating properties, and can provide a modified wood tar which can be effectively used by taking advantage of these properties.

【0021】また、焼成することにより炭素系材料に変
換すると、この特性を生かして更に有効利用を図ること
ができる。
Further, when the material is converted into a carbon-based material by firing, this property can be utilized to achieve more effective use.

【図面の簡単な説明】[Brief description of the drawings]

【図1】この発明の木タールの製造方法を説明する図。FIG. 1 is a diagram illustrating a method for producing wood tar of the present invention.

【図2】得られた木タール変成物の電子顕微鏡写真を図
面化したもの。
FIG. 2 is a drawing of an electron micrograph of the obtained wood tar modified product.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) C08L 97:02 C08L 97:02 Fターム(参考) 2B230 AA21 BA01 CB26 4F074 AA02 CC04Y CC12Y CC12Z 4F212 AA02 AE02 AG20 AH48 UA17 UN08 UW05 ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 7 Identification code FI Theme coat ゛ (Reference) C08L 97:02 C08L 97:02 F term (Reference) 2B230 AA21 BA01 CB26 4F074 AA02 CC04Y CC12Y CC12Z 4F212 AA02 AE02 AG20 AH48 UA17 UN08 UW05

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 木タールを加熱して発泡させ、ポーラス
構造としたことを特徴とする木タール変成物。
1. A modified wood tar, wherein the wood tar is heated and foamed to have a porous structure.
【請求項2】 所望の形状となるように加熱成形した請
求項1記載の木タール変成物。
2. The modified wood tar product according to claim 1, which is formed by heating to a desired shape.
【請求項3】 前記発泡物を焼成して成る請求項1又は
2記載の木タール変成物。
3. The modified wood tar product according to claim 1, wherein the foamed product is fired.
JP2001312310A 2000-10-13 2001-10-10 Wood tar metamorphosis Expired - Fee Related JP3663581B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2001312310A JP3663581B2 (en) 2000-10-13 2001-10-10 Wood tar metamorphosis

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2000313058 2000-10-13
JP2000-313058 2000-10-13
JP2001312310A JP3663581B2 (en) 2000-10-13 2001-10-10 Wood tar metamorphosis

Publications (2)

Publication Number Publication Date
JP2002201302A true JP2002201302A (en) 2002-07-19
JP3663581B2 JP3663581B2 (en) 2005-06-22

Family

ID=26602024

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2001312310A Expired - Fee Related JP3663581B2 (en) 2000-10-13 2001-10-10 Wood tar metamorphosis

Country Status (1)

Country Link
JP (1) JP3663581B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100746359B1 (en) 2006-02-28 2007-08-10 대한민국 Manufacturing method of carbon powder using wood tar

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100746359B1 (en) 2006-02-28 2007-08-10 대한민국 Manufacturing method of carbon powder using wood tar

Also Published As

Publication number Publication date
JP3663581B2 (en) 2005-06-22

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