JP3455820B2 - Platinum material - Google Patents

Platinum material

Info

Publication number
JP3455820B2
JP3455820B2 JP33851693A JP33851693A JP3455820B2 JP 3455820 B2 JP3455820 B2 JP 3455820B2 JP 33851693 A JP33851693 A JP 33851693A JP 33851693 A JP33851693 A JP 33851693A JP 3455820 B2 JP3455820 B2 JP 3455820B2
Authority
JP
Japan
Prior art keywords
platinum
pure
hardness
ppm
platinum material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP33851693A
Other languages
Japanese (ja)
Other versions
JPH07188808A (en
Inventor
治 渡辺
昌樹 栗田
隆司 醍醐
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tokuriki Honten Co Ltd
Original Assignee
Tokuriki Honten Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tokuriki Honten Co Ltd filed Critical Tokuriki Honten Co Ltd
Priority to JP33851693A priority Critical patent/JP3455820B2/en
Publication of JPH07188808A publication Critical patent/JPH07188808A/en
Application granted granted Critical
Publication of JP3455820B2 publication Critical patent/JP3455820B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Description

【発明の詳細な説明】 【0001】 【産業上の利用分野】本発明は、電子部品、宝飾用品、
医療分野等広い範囲で用いることができる純白金に近い
白金材料に関する。 【0002】 【従来の技術】白金は、耐蝕性、耐熱性に優れる性質か
ら電子部品をはじめ、その色彩の優雅さもあって宝飾用
品等広い範囲で使用されている。 【0003】 【発明が解決しようとする課題】しかしながら、純白金
は、非常に柔軟であり、硬さや強度が低く、ダイスによ
る細線加工では途中で断線したりし、高温度の使用にお
いては、比重が大きいために自重で線がたるんでしまう
という問題がある。また、宝飾用品として用いた場合、
高品位の高級製品は傷がつき易く、しかも変形し易いと
いう欠点があり、さらに加工過程で表面仕上げが難しい
という問題もある。 【0004】 【課題を解決するための手段】そこで本発明は、Smに
これと化合物を生成する元素Co,Ni,Sn,In,
Cuの1種以上を添加してSmを含む合計で10〜10
00ppmとし、残部がPtであることを特徴とする
Smを主添加元素とした理由は、鋳造時および加工時に
おける硬さを向上させるためであり、副添加元素である
Co,Ni,Sn,In,Cuは比較的融点の低いSm
と高融点の化合物を生成し、しかも高温における溶解時
のSmの飛散抑制や耐熱上の問題を解消すると共にSm
との相乗効果により硬さを向上させることになる。 【0005】添加量を10〜1000ppm としたのは、
10ppm 未満では硬さの向上に効果が少なく、1000
ppm を超えると電子部品については電気伝導度の低下、
医療品については添加元素の溶出、宝飾用品については
高純度としての品位の低下をきたすためである。 【0006】 【作用】以上の本発明によると、添加元素の作用によっ
て純白金に比べて鋳造後の硬さが向上し、また、板材、
線材の加工等の塑性加工においては加工硬化による硬さ
の上昇が大きく、純白金に比べ、飛躍的な硬さの向上が
みられた。さらに、加工材の熱処理においても、微量の
添加元素によって結晶粒の粗大化が抑制されるため、純
白金の細線加工時にみられた断線の発生が抑制されるよ
うになる。 【0007】 【実施例】以下に本発明の実施例を説明する。実施例と
従来例としての純Ptとを表1に示す。 【0008】 【表1】 【0009】表1に示す各試料は、まず、実施例に示す
添加元素であるSmを主元素とした合金をアーク溶解にて
鋳造して母合金とした。 【0010】つぎに、純Ptに実施例に示す組成で上記母
合金を配合し、上記同様アーク溶解を行い、厚さ10mm、
幅30mm、長さ50mmのケーキ状の鋳造体とし、この鋳造体
を、熱間鍛造で線用、板用に成形し、所定の形状まで加
工を行い、試料とした。その結果、表1で明らかなよう
に、実施例1〜6は従来例としての純Ptに比べて硬さ、
加工性共にすぐれていることがわかる。 【0011】 【発明の効果】以上詳細に説明をした本発明によると、
純Pt中にSmを主添加元素として10〜1000ppm の添
加元素を添加したことにより、純Ptに比べて硬さが高く
なり、また機械的特性にもすぐれ、しかも純白金に近い
高純度の白金材料となるもので、電子部品、宝飾用品、
医療分野等広い範囲で有用な白金となる効果を有する。
Description: BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to electronic parts, jewelry articles,
The present invention relates to a platinum material close to pure platinum that can be used in a wide range such as the medical field. 2. Description of the Related Art Platinum is used in a wide range of applications such as electronic parts due to its excellent corrosion resistance and heat resistance. [0003] However, pure platinum is very flexible, has low hardness and strength, and breaks in the course of fine wire processing with a die, and has a specific gravity when used at high temperatures. There is a problem that the line sags due to its own weight because of the large size. Also, when used as jewelry supplies,
High-grade high-grade products have the drawbacks that they are easily scratched and easily deformed, and also have the problem that surface finishing is difficult during the processing process. [0004] Accordingly, the present invention provides a method of forming a compound with Sm such as Co, Ni, Sn, In,
10 to 10 in total including Sm by adding one or more types of Cu
It is characterized by being 00 ppm and the balance being Pt .
The reason for using Sm as a main additive element is to improve hardness during casting and working, and Co, Ni, Sn, In, and Cu, which are sub-additive elements, have a relatively low melting point.
And a compound having a high melting point, and at the same time, eliminates the problem of suppression of Sm scattering at the time of melting at high temperature and the problem of heat resistance.
The hardness is improved by a synergistic effect with the above. The reason why the addition amount is set to 10 to 1000 ppm is that
If the content is less than 10 ppm, the effect of improving the hardness is small.
If it exceeds ppm, the electrical conductivity of electronic components will decrease,
This is because the elution of added elements for medical products and the deterioration of high-purity jewelry products. According to the present invention, the hardness after casting is improved as compared with pure platinum by the action of the additional element.
In plastic working such as processing of a wire rod, the increase in hardness due to work hardening was large, and a drastic improvement in hardness was observed as compared with pure platinum. Further, even in the heat treatment of the work material, the coarsening of the crystal grains is suppressed by the trace amount of the additional element, so that the occurrence of the disconnection observed in the fine wire processing of pure platinum is suppressed. An embodiment of the present invention will be described below. Table 1 shows Examples and pure Pt as a conventional example. [Table 1] Each of the samples shown in Table 1 was prepared by casting an alloy containing Sm, which is an additive element shown in Examples, as a main element by arc melting. Next, the above-mentioned mother alloy was blended with pure Pt with the composition shown in the embodiment, and arc melting was carried out in the same manner as described above, and a thickness of 10 mm was obtained.
A cake-like cast having a width of 30 mm and a length of 50 mm was formed, and the cast was formed into a wire or a plate by hot forging, processed into a predetermined shape, and used as a sample. As a result, as is clear from Table 1, Examples 1 to 6 have a higher hardness than pure Pt as a conventional example,
It can be seen that the workability is excellent. According to the present invention described in detail above,
By adding Sm as the main additive element to pure Pt and adding 10 to 1000 ppm of the additional element, the hardness becomes higher than pure Pt, the mechanical properties are excellent, and high purity platinum close to pure platinum is obtained. Materials, electronic components, jewelry supplies,
It has the effect of becoming useful platinum in a wide range such as the medical field.

───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 平7−41886(JP,A) 特開 昭64−84715(JP,A) 特開 昭56−29641(JP,A) (58)調査した分野(Int.Cl.7,DB名) C22C 5/04 ──────────────────────────────────────────────────続 き Continuation of the front page (56) References JP-A-7-41886 (JP, A) JP-A-64-84715 (JP, A) JP-A-56-29641 (JP, A) (58) Investigation Field (Int.Cl. 7 , DB name) C22C 5/04

Claims (1)

(57)【特許請求の範囲】 【請求項1】 mにこれと化合物を生成する元素C
o,Ni,Sn,In,Cuの1種以上を添加してSm
を含む合計で10〜1000ppmとし、残部がPtで
あることを特徴とする電子部品、医療品、装飾用品用の
白金材料。
(57) [Claims 1 elemental generates to as compound S m C
o, Ni, Sn, In, with the addition of one or more Cu Sm
And 10 to 1000 ppm in total, with the balance being Pt
Electronic parts, medical supplies, characterized in that there is, platinum material for decorating.
JP33851693A 1993-12-28 1993-12-28 Platinum material Expired - Fee Related JP3455820B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP33851693A JP3455820B2 (en) 1993-12-28 1993-12-28 Platinum material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP33851693A JP3455820B2 (en) 1993-12-28 1993-12-28 Platinum material

Publications (2)

Publication Number Publication Date
JPH07188808A JPH07188808A (en) 1995-07-25
JP3455820B2 true JP3455820B2 (en) 2003-10-14

Family

ID=18318900

Family Applications (1)

Application Number Title Priority Date Filing Date
JP33851693A Expired - Fee Related JP3455820B2 (en) 1993-12-28 1993-12-28 Platinum material

Country Status (1)

Country Link
JP (1) JP3455820B2 (en)

Also Published As

Publication number Publication date
JPH07188808A (en) 1995-07-25

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