JP3232514B2 - Transfer paper for electrophotography - Google Patents
Transfer paper for electrophotographyInfo
- Publication number
- JP3232514B2 JP3232514B2 JP09612792A JP9612792A JP3232514B2 JP 3232514 B2 JP3232514 B2 JP 3232514B2 JP 09612792 A JP09612792 A JP 09612792A JP 9612792 A JP9612792 A JP 9612792A JP 3232514 B2 JP3232514 B2 JP 3232514B2
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- JP
- Japan
- Prior art keywords
- paper
- transfer
- coating
- electrophotographic
- transfer paper
- Prior art date
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Description
【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION
【0001】[0001]
【産業上の利用分野】本発明は、電子写真用転写紙、及
び、その転写紙を用い、写真印刷並みの高画質画像を再
現できるカラー若しくはモノクローム電子写真複写方法
に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a transfer paper for electrophotography and a color or monochrome electrophotography copying method capable of reproducing a high-quality image comparable to a photographic print using the transfer paper.
【0002】[0002]
【従来の技術】平板オフセット印刷を主流とする精巧な
印刷や多色印刷において、アート紙、コート紙等の塗工
紙が使用されている。これは、塗工紙の表面が平滑なた
めに、印刷時にインキ皮膜との接触が良く、画像が忠実
に再現されるとともに、画像の光沢が高く、色再現が良
いことなどによる。しかし、この印刷用塗工紙をそのま
ま電子写真用転写紙に用いると、画像乱れ、給紙時の重
送や紙詰まり、定着時のブリスター(水ぼうそう状のふ
くれ)等の不都合が生ずるため、印刷用塗工紙は電子写
真用転写紙として従来ほとんど使用されなかった。2. Description of the Related Art Coated paper such as art paper and coated paper is used in elaborate printing and multicolor printing mainly using flat plate offset printing. This is due to the fact that the coated paper has a smooth surface, so that it has good contact with the ink film during printing, and the image is faithfully reproduced, and the image has high gloss and good color reproduction. However, if this coated printing paper is used as it is for electrophotographic transfer paper, problems such as image disturbance, double feeding and paper jam at the time of paper feeding, and blisters at the time of fixing occur (fizzle-like blisters). Conventionally, coated paper has rarely been used as transfer paper for electrophotography.
【0003】一方、電子写真の高画質化は、近年トナー
の小粒径化及び転写トナーの薄層化が進み、平滑な塗工
紙の使用が画質向上に有利であると考えられるようにな
ってきた(塚谷,太田著『ノンインパクトプリンタ用
紙』「紙パルプ技術タイムス,27,No.3(198
4)p.45〜49」)。また、画像の光沢や色再現を
重視した定着には、印刷と同様に電子写真でも平滑な塗
工紙の方が良いところから、電子写真法における印刷用
塗工紙の問題を解決すべく、特にカラー複写における塗
工紙の利点を生かすべく種々の検討が行われてきた。On the other hand, in recent years, in order to improve the image quality of electrophotography, the use of smooth coated paper has been considered to be advantageous for improving the image quality, as the particle size of the toner and the thickness of the transfer toner have been advanced in recent years. (Tokutani, Ota, "Non-impact Printer Paper", "Paper Pulp Technology Times, 27, No. 3 (198
4) p. 45-49 "). Also, for fixing with emphasis on image gloss and color reproduction, smooth coated paper is better in electrophotography as well as printing, so in order to solve the problem of coated paper for printing in electrophotography, In particular, various studies have been made to take advantage of the coated paper in color copying.
【0004】特開昭62─198877号公報では、転
写層の表面電気抵抗を温度20℃、相対湿度85%で
8.0×108 Ω以上に調整することにより、高温高湿
時の画像乱れを改善した塗工紙タイプの電子写真用転写
紙が提案された。また、特開昭62─198876号公
報では、透気度を4000秒以下に調整することによ
り、塗工紙におけるトナーの熱定着時、転写紙のブリス
ターを改善した塗工紙タイプの電子写真用転写紙が提案
された。しかしながら、上記の電子写真用転写紙をカラ
ー複写機に使用し、感光体上の現像像を複数回転写して
熱加圧定着すると、上記の転写層表面電気抵抗でかつ透
気度の塗工紙でも、転写時に画像のべた部分が粒子状の
ムラとなる転写不良(以下、転写ムラという)や定着時
にトナーが十分に溶融しないことによる画像のグロス・
ムラが生ずるという問題がある。Japanese Patent Application Laid-Open No. Sho 62-1988877 discloses that the surface electric resistance of a transfer layer is adjusted to 8.0 × 10 8 Ω or more at a temperature of 20 ° C. and a relative humidity of 85% so that image distortion at high temperature and high humidity is obtained. An electrophotographic transfer paper of a coated paper type in which the above is improved has been proposed. Japanese Patent Application Laid-Open No. 62-1988876 discloses a coated paper type electrophotographic apparatus in which the air permeability is adjusted to 4000 seconds or less to improve the transfer paper blister during thermal fixing of the toner on the coated paper. Transfer paper was proposed. However, when the electrophotographic transfer paper is used in a color copier, and the developed image on the photoreceptor is transferred a plurality of times and fixed by heat and pressure, the coated paper having the above-described transfer layer surface electric resistance and air permeability is obtained. However, transfer failure (hereinafter referred to as transfer unevenness) in which the solid portion of the image becomes particulate unevenness during transfer, and image gloss and gloss due to insufficient melting of the toner during fixing.
There is a problem that unevenness occurs.
【0005】[0005]
【発明が解決しようとする課題】そこで、本発明は、上
記の欠点を解消し、転写時の転写ムラや定着時のグロス
・ムラを発生させず、写真印刷並の高画質画像を得るこ
とができ、しかも走行性にも優れたカラー及び、モノク
ローム電子写真用転写紙、さらには、その転写紙を用い
た電子写真複写方法を提供しようとするものである。SUMMARY OF THE INVENTION Accordingly, the present invention has been made to solve the above-mentioned drawbacks and to provide a high-quality image comparable to a photographic print without causing transfer unevenness at the time of transfer and gloss unevenness at the time of fixing. It is an object of the present invention to provide a color and monochrome electrophotographic transfer paper which is excellent in running property and further has an electrophotographic copying method using the transfer paper.
【0006】[0006]
【課題を解決するための手段】本発明は、原反の少なく
とも一方の面に、顔料及び接着剤からなる片面当たりの
塗布量4g/m2 以上の塗工層を備えた、坪量85〜1
00g/m2 の塗工紙からなる電子写真用転写紙におい
て、JISP8111の方法で前処理した上記塗工紙の
表面電気抵抗値が6×109 〜1×1011Ωの範囲にあ
り、かつ、J.TAPPI No.48に準じた水銀圧
入法による塗工紙の空隙直径の大きい方のピークの値が
2.0〜3.0μmの範囲にあることを特徴とする電子
写真用転写紙、及び、この転写紙を転写フィルム上に保
持し、感光体上の現像像を複数回転写し、熱加圧定着法
で定着することを特徴とする電子写真複写方法である。
なお、上記の転写紙において、JISP8111の方法
で前処理する理由は以下のとおりである。用紙は、環境
条件によりその含有水分が大きく異なり、そのため用紙
の表面電気抵抗値も大きく異なる。それ故、転写紙の表
面電気抵抗値を規定するためには、ある一定環境での前
処理、試験が必要であり、ここではJISP8111の
標準条件、すなわち温度20℃±2℃,湿度65±2%
で前処理した。According to the present invention, a raw material is provided with a coating layer comprising a pigment and an adhesive and having a coating amount of 4 g / m 2 or more per side on at least one surface of the raw material. 1
In an electrophotographic transfer paper made of a coated paper of 00 g / m 2 , the surface electric resistance of the coated paper pretreated by the method of JISP8111 is in a range of 6 × 10 9 to 1 × 10 11 Ω, and J. TAPPI No. An electrophotographic transfer paper, characterized in that the peak value of the larger pore diameter of the coated paper obtained by the mercury intrusion method according to No. 48 is in the range of 2.0 to 3.0 μm, and this transfer paper An electrophotographic copying method characterized by holding the image on a transfer film, transferring the developed image on the photoreceptor a plurality of times, and fixing the image by a heat and pressure fixing method.
The reason why the above-described transfer paper is pre-processed by the method of JISP8111 is as follows. The moisture content of paper varies greatly depending on the environmental conditions, and therefore the surface electrical resistance of the paper also varies greatly. Therefore, in order to define the surface electric resistance value of the transfer paper, it is necessary to perform a pretreatment and a test in a certain environment, and here, the standard conditions of JISP8111, namely, a temperature of 20 ° C. ± 2 ° C. and a humidity of 65 ± 2. %
Pre-processed.
【0007】[0007]
【作用】電子写真複写法で良好な転写を行うためには、
感光体と転写紙の間に転写に必要で十分の電界強度を与
える必要があり、具体的には、転写コロトロン・ワイヤ
ーに流れる電流値(It)を調節して転写フィルムへの
電流値(Id)を一定に保つことにより達成される。特
に、乾式カラー電子写真方式の複写機及びプリンターで
は、感光体上の現像像を複数回転写するために、第1色
目の転写時と比較して最終色転写時の転写フィルム電位
は高くなる。したがって、最終色目の転写を行うために
感光体と転写紙との間の電界強度を第1色目の転写時電
界強度に等しくするためには、最終色目の転写時のIt
は、第1色目の転写時のItと比較して大きな値とな
る。それ故、転写紙は幅広いItに対して転写ムラが発
生しないよう検討する必要があった。[Function] In order to perform good transfer by the electrophotographic copying method,
It is necessary to provide a sufficient electric field intensity necessary for transfer between the photoreceptor and the transfer paper. Specifically, the current value (It) flowing through the transfer corotron wire is adjusted to adjust the current value (Id) to the transfer film. Is kept constant. In particular, in a copying machine and a printer of a dry color electrophotographic system, since the developed image on the photosensitive member is transferred a plurality of times, the transfer film potential in the final color transfer is higher than that in the transfer of the first color. Therefore, in order to make the electric field intensity between the photosensitive member and the transfer paper equal to the electric field intensity at the time of the transfer of the first color in order to perform the transfer of the final color, it is necessary to set the It at the time of the transfer of the final color.
Is a large value compared to It at the time of transfer of the first color. Therefore, the transfer paper needs to be examined so that transfer unevenness does not occur for a wide range of It.
【0008】本発明者等は、上記転写ムラとグロス・ム
ラを抑制するために鋭意検討したところ、J.TAPP
I No.48に準じた水銀圧入法による塗工紙の空隙
直径の大きい方のピーク値が2.0〜3.0μm、好ま
しくは2.0〜2.7μmの範囲にある電子写真用塗工
紙を用いることにより、上記の幅広い範囲のItに対し
て、転写ムラを改善できることを見い出した。このピー
ク値が3.0μmを越える場合、より厳密には2.7μ
mを越える場合には、Itを高くして行くと転写ムラが
発生するようになる。これは、塗工紙内部で放電が起こ
っているためと考えられる。したがって、このような転
写ムラを改善するためには、このピーク値を3.0μm
以下、好ましくは2.7μm以下の小さな値にして塗工
紙の電気破壊強度を高める必要がある。しかし、このピ
ーク値を小さくし過ぎると、紙の腰が弱くなり、通紙時
にトラブルを生ずるなどの欠点があるため、このピーク
値の下限値は、2.0μm以上であることが好ましい。
なお、塗工紙の空隙直径の大きい方のピーク値とは、以
下の様な意味をもつ。通常、塗工紙の空隙直径に関する
空隙量分布曲線は2つのピークをもつ。このうち、空隙
直径の大きい方のピークは、原反層の空隙に由来するも
のであり、また空隙直径の小さい方のピークは、塗工層
の空隙に由来するものである。本発明では、塗工紙の原
反層の空隙直径に由来する空隙直径の大きい方のピーク
の値を一定値内に定めることにより、転写ムラを抑えら
れることを見い出したものである。The present inventors have conducted intensive studies to suppress the transfer unevenness and the gloss unevenness. TAPP
I No. Use a coated paper for electrophotography in which the peak value of the larger void diameter of the coated paper by the mercury intrusion method according to No. 48 is in the range of 2.0 to 3.0 μm, preferably 2.0 to 2.7 μm. As a result, it has been found that transfer unevenness can be improved for the above-mentioned wide range of It. If this peak value exceeds 3.0 μm, more precisely, 2.7 μm
When m exceeds m, transfer unevenness occurs as the value of It is increased. This is considered to be due to discharge occurring inside the coated paper. Therefore, in order to improve such transfer unevenness, this peak value should be 3.0 μm
Hereinafter, it is necessary to increase the electric breakdown strength of the coated paper by setting a small value, preferably 2.7 μm or less. However, if the peak value is too small, there is a drawback that the stiffness of the paper becomes weak and a trouble occurs when the paper is passed. Therefore, the lower limit of the peak value is preferably 2.0 μm or more.
In addition, the peak value of the larger void diameter of the coated paper has the following meaning. Usually, the void volume distribution curve relating to the void diameter of the coated paper has two peaks. Among them, the peak with the larger void diameter is derived from the void in the raw material layer, and the peak with the smaller void diameter is derived from the void in the coating layer. In the present invention, it has been found that transfer unevenness can be suppressed by setting a value of a peak having a larger void diameter derived from a void diameter of a raw layer of a coated paper within a certain value.
【0009】また、定着時のグロス・ムラについては、
少なくとも片面当たりの塗布量4g/m2 以上の塗工層
を備え、坪量85〜100g/m2 の電子写真用塗工紙
を用いることにより、改善されることを見いだした。塗
工紙の坪量が100g/m2を越えると、定着時のグロ
ス・ムラが生じたり、極端な場合にはトナーが剥がれて
しまうことがある。これは定着の際に、熱伝導率の悪い
塗工紙に対しては十分にトナーを溶融定着させることが
できないためと考えられる。また、塗工紙の坪量が85
g/m2 を下回ると、定着は十分であるが、定着の際
に、定着ロールに巻き付いたりする。したがって、これ
らの欠点をなくして上記のグロス・ムラを改善するため
には、片面当たりの塗布量4g/m2 以上の塗工層を備
え、坪量85〜100g/m2 の電子写真用塗工紙を用
いることにより、熱伝導率を良くして定着が十分に行わ
れるようにする必要がある。なお、塗布量が4g/m2
未満では原反の繊維が十分に覆えないために、定着画像
が乱れる等の欠点があるため、高画質画像を得ることが
できない。また、塗工紙の坪量が85〜100g/m 2
の範囲で塗布量が30g/m2 を越えると、紙の腰が弱
くなり、通紙時にトラブルを生ずるなどの欠点があるRegarding the gloss and unevenness at the time of fixing,
At least 4 g / m coating amount per sideTwoCoating layer above
With a basis weight of 85 to 100 g / mTwoElectrophotographic coated paper
Have been found to be improved by using. Paint
100g / m basis weight of industrial paperTwoExceeds the gross
Unevenness or in extreme cases the toner may come off
Sometimes. This is due to poor thermal conductivity during fixing
It is possible to fuse and fix toner sufficiently on coated paper
Probably because it cannot. In addition, the basis weight of the coated paper is 85
g / mTwoIf it is less than, fixing is sufficient, but when fixing
And then wrap around the fixing roll. So this
To improve the above gross unevenness by eliminating these disadvantages
Has a coating amount of 4 g / m per side.TwoWith the above coating layer
E, basis weight 85-100g / mTwoUsing electrophotographic coated paper
Improves thermal conductivity and ensures sufficient fixing
Need to be In addition, the coating amount is 4 g / mTwo
If less, the fiber of the raw fabric cannot be covered sufficiently, so the fixed image
It is difficult to obtain high quality images
Can not. The basis weight of the coated paper is 85 to 100 g / m. Two
30g / m in the range ofTwoOver, the waist of the paper is weak
Disadvantages, such as trouble with paper passing
【0010】本発明にかかる転写紙の構成について、さ
らに詳細に説明する。この転写紙の原反に使用するパル
プは、化学パルプ、機械パルプ、古紙パルプ、その他従
来公知の全てのパルプを使用することができる。また、
中性紙処方、酸性紙処方のいずれでも構わない。また、
使用する填料は、従来公知のタルク、カオリン、炭酸カ
ルシウム、二酸化チタン等の填料を全て使用することが
できる。The configuration of the transfer paper according to the present invention will be described in more detail. As the pulp used as the raw material of the transfer paper, chemical pulp, mechanical pulp, waste paper pulp and all other conventionally known pulp can be used. Also,
Either a neutral paper formulation or an acidic paper formulation may be used. Also,
As the filler to be used, all known fillers such as talc, kaolin, calcium carbonate, titanium dioxide and the like can be used.
【0011】塗工紙の空隙直径の大きい方のピーク値
は、原反層の空隙に由来するので、原反層中の空隙直径
を2.0〜3.0μm、好ましくは2.0〜2.7μm
に調整する必要がある。なお、塗工紙の空隙直径の測定
は、J.TAPPI No.48に準じた水銀圧入法に
よる。この方法の概略を以下に説明する。測定法の原理
は、試料の細孔(空隙)に圧入される水銀の容積を膨張
計(ディラトメータ)で測定し、自動的に圧力の関数と
して記録するものである。測定の原理は、細孔半径と水
銀の表面張力、接触角および圧力に関するKelvin
の式に基づいている。加えた圧力と細孔半径とは反比例
の関係にあり、この式から圧力を細孔半径に換算し、細
孔半径に関する細孔量の累積曲線および細孔量分布曲線
が求められる。塗工紙の空隙直径の調整法としては、原
反中の空隙を繊維以外の物質で埋めることにより、目的
の空隙直径を得ることができる。充填には、クレー、タ
ルク、チタンホワイト、炭酸カルシウム等を使用するこ
とができるが、定着時のブリスター発生、紙の腰の低下
等を考慮して十分な注意の下でその配合量を決定する必
要である。Since the peak value of the larger gap diameter of the coated paper is derived from the gap of the raw layer, the gap diameter in the raw layer is 2.0 to 3.0 μm, preferably 2.0 to 3.0 μm. 0.7 μm
Need to be adjusted. The measurement of the pore diameter of the coated paper is described in J. Org. TAPPI No. According to the mercury intrusion method according to No.48. The outline of this method will be described below. The principle of the measurement method is that the volume of mercury injected into the pores (voids) of the sample is measured with a dilatometer and automatically recorded as a function of pressure. The principle of measurement is Kelvin with respect to pore radius and mercury surface tension, contact angle and pressure.
Based on the formula. The applied pressure and the pore radius are in inverse proportion, and the pressure is converted into the pore radius from this formula, and the cumulative curve of the pore volume and the pore volume distribution curve with respect to the pore radius are obtained. As a method for adjusting the gap diameter of the coated paper, a desired gap diameter can be obtained by filling gaps in the raw material with a substance other than fibers. For filling, clay, talc, titanium white, calcium carbonate, etc. can be used, but the amount of the mixture is determined with sufficient care in consideration of blistering during fixing, lowering of paper stiffness, etc. is necessary.
【0012】また、繊維を叩解することにより、繊維を
毛羽立たせたり、微細繊維(単繊維)化させることによ
り、原反中の空隙を埋めて目的の空隙直径を得ることも
できる。しかし、繊維を強く叩解し過ぎると、抄紙後の
カールが大きくなり、紙の腰が弱くなり、かつ、不透明
度が低下するため、電子写真複写機適性が悪くなる。し
たがって、この方法を適用する場合は、叩解の程度に注
意するか、あるいは、通常の叩解を施した繊維に、叩解
を強く進めた繊維を配合して原紙を抄紙するなどの工夫
が必要となる。また、プレスロール間の圧力を強くし、
原反の密度を高めることもできる。Also, by beating the fibers to make them fluffy or to make them into fine fibers (single fibers), the voids in the raw material can be filled to obtain the desired void diameter. However, if the fibers are beaten too hard, the curl after papermaking becomes large, the paper becomes stiff, and the opacity is reduced, thereby deteriorating the suitability for an electrophotographic copying machine. Therefore, when applying this method, it is necessary to pay attention to the degree of beating, or to devise a method such as blending fibers that have been strongly beaten with fibers that have been subjected to regular beating to make base paper. . Also, increase the pressure between the press rolls,
The density of the raw material can be increased.
【0013】さらに、スーパー・カレンダーあるいはグ
ロス・カレンダーなどの剛性ロールと弾性ニップの間を
多数回通すことにより、平滑化処理を施し、原反中の空
隙を押しつぶして目的の空隙直径を得ることもできる。
この方法は、塗工後の用紙にも適用することができる
が、塗工後のカレンダー処理を過度に行うと、いわゆる
「カレンダー焼け」を生じ、塗工層のグロスが低下する
ため、高画質画像が得られなくなる。また、紙の腰を弱
くする欠点もあり、適度のカレンダー処理を施すことが
望ましい。なお、本発明の原反中の空隙直径調整法は、
上記の方法に限定されるものではない。[0013] Further, by passing between a rigid roll such as a super calender or a gloss calender many times and an elastic nip, a smoothing treatment is performed, and a gap in the raw material is crushed to obtain a desired gap diameter. it can.
This method can be applied to the coated paper, but if the calendering after the coating is performed excessively, so-called “calendar burn” occurs, and the gloss of the coated layer is reduced. Images cannot be obtained. Further, there is a disadvantage that the stiffness of the paper is weakened, and it is desirable to perform an appropriate calendering process. In addition, the method of adjusting the gap diameter in the raw material of the present invention,
It is not limited to the above method.
【0014】塗工層の材料は、表面電気抵抗値が6×1
09 〜1×1011Ωの範囲にあり、かつ、電子写真に適
用できるものであればその種類を問わず、自由に使用す
ることができる。表面電気抵抗値が6×109 Ωを下回
ると、特に高湿時に転写抜けが生じ、1×1011Ωを上
回ると、特に低湿時に感材との剥離放電による画像の乱
れや転写時のムラが発生しやすく好ましくない。塗料の
主体である顔料は、塗工後スーパー・カレンダー等によ
り塗工面を平滑化処理するため、平均粒子径が1.5μ
m以下、好ましくは1.0μm以下の微粒子であり、ト
ナー層の転写の際にトナーの転写率が高く、画像の乱れ
を防止するために、電気抵抗を高くし、かつ、定着時の
ブリスターを防止するために、透気性を与えることが望
ましい。平均粒子径が1.5μmを越えると平滑化処理
を行っても白紙グロスが高くならず、平滑化の効果が十
分に得られなかったり、透気性が低下する傾向があるの
で望ましくない。使用できる顔料としては、重質炭酸カ
ルシウム、軽質炭酸カルシウム、焼成クレー、リトポ
ン、酸化亜鉛、二酸化チタン、硫酸バリウム、尿素樹
脂、カオリンクレー、セリサイト、ジークライト、タル
ク等いずれも公知の顔料は一種または二種以上の組み合
わせで使用できるが、結晶水を持つ顔料、または平板状
の結晶構造を持つ顔料は、電気抵抗値を下げ過ぎたり、
透気性を低下させブリスターを発生させる懸念があるた
め単独での使用は避けた方がよい。The material of the coating layer has a surface electric resistance value of 6 × 1.
As long as it is in the range of 09 to 1 × 10 11 Ω and is applicable to electrophotography, it can be used irrespective of its type. When the surface electric resistance value is lower than 6 × 10 9 Ω, transfer loss occurs particularly at high humidity, and when the surface electric resistance value exceeds 1 × 10 11 Ω, image disturbance due to peeling discharge from the photosensitive material especially at low humidity and unevenness during transfer. Is likely to occur, which is not preferable. The pigment, which is the main component of the coating, has an average particle size of 1.5 μm for smoothing the coated surface by using a super calendar after coating.
m or less, preferably 1.0 μm or less, the transfer rate of the toner is high at the time of transfer of the toner layer, the electrical resistance is high in order to prevent the disturbance of the image, and the blister at the time of fixing is reduced. To prevent this, it is desirable to provide air permeability. If the average particle diameter exceeds 1.5 μm, the white paper gloss does not increase even if the smoothing treatment is performed, and the smoothing effect cannot be sufficiently obtained, or the air permeability tends to decrease. Known pigments include heavy calcium carbonate, light calcium carbonate, calcined clay, lithopone, zinc oxide, titanium dioxide, barium sulfate, urea resin, kaolin clay, sericite, siegrite, talc, and other known pigments. Or a combination of two or more, but pigments with water of crystallization, or pigments with a flat crystal structure,
It is better to avoid using alone because there is a concern that air permeability may be reduced and blisters may be generated.
【0015】接着剤は、顔料と原反との接着力が強く、
ブロッキング性が少ない水溶性接着剤あるいはエマルジ
ョン、ラテックスを使用することができるが、トナー層
の転写を良好にするためには、紙表面の電気抵抗の微小
部分での変動を小さく抑え、かつ、高湿度下での電気抵
抗の低下を防ぐために乳化剤等の電気抵抗の低い成分を
使用しないか、使用量をなるべく少なくすることが望ま
しい。例えば、樹脂成分が自己架橋型アクリル樹脂系
で、アクリル系樹脂に対して5モル%未満のカルボン酸
を含有させることにより、乳化剤なしでエマルジョン化
したソープレス自己架橋型アクリルエマルジョンを使用
することができる。カルボン酸は、アクリル酸、メタク
リル酸、イタコン酸、無水マレイン酸が好適であるが、
5モル%を越えて使用すると電気抵抗値が低下するので
好ましくない。また、架橋反応には、カルボキシル基と
エポキシ樹脂との架橋反応、アミド自己架橋型反応、カ
ルボキシル基とメラミン樹脂との架橋反応、ヒドロキシ
ル基とメラミン樹脂との架橋反応など各種の型がある
が、いずれの型でもよい。The adhesive has a strong adhesion between the pigment and the raw material,
A water-soluble adhesive, emulsion, or latex having low blocking properties can be used.However, in order to improve the transfer of the toner layer, the fluctuation of the electric resistance on the paper surface in a small portion should be small and high. In order to prevent a decrease in electric resistance under humidity, it is desirable not to use a component having a low electric resistance such as an emulsifier or to reduce the amount of use as much as possible. For example, it is possible to use a soapless self-crosslinking acrylic emulsion that is emulsified without an emulsifier by containing a resin component of a self-crosslinking acrylic resin system and containing less than 5 mol% of a carboxylic acid with respect to the acrylic resin. it can. Carboxylic acid, acrylic acid, methacrylic acid, itaconic acid, maleic anhydride is preferred,
If it is used in an amount exceeding 5 mol%, the electric resistance value is undesirably reduced. There are various types of crosslinking reactions, such as a crosslinking reaction between a carboxyl group and an epoxy resin, an amide self-crosslinking reaction, a crosslinking reaction between a carboxyl group and a melamine resin, and a crosslinking reaction between a hydroxyl group and a melamine resin. Any type may be used.
【0016】また、両性ラテックスで乳化剤の使用量の
少ないものは接着剤として使用することができる。例え
ば、1,3−ブタジエン、2−メチル−1,3−ブタジ
エン、2−クロロ−1,3ブタジエン等の脂肪族共役ジ
オレフィンモノマー;スチレン、α−メチルスチレン、
モノクロルスチレン、アクリル酸エステル、メタクリル
酸エステル、アクリルニトリル等のモノオレフィン系モ
ノマー;アクリル酸、メタクリル酸、イタコン酸、フマ
ル酸、クロトン酸、ケイ皮酸等のエチレン系不飽和酸モ
ノマー;及び、メチルアミノエチル(メタ)アクリレー
ト、t−ブチルアミノエチル(メタ)アクリレート、ジ
メチルアミノエチル(メタ)アクリレート、ジエチルア
ミノエチル(メタ)アクリレート、ジブチルアミノエチ
ル(メタ)アクリレート等のエチレン系不飽和アミンモ
ノマーからなるモノマーを、全モノマーに対して1重量
%以下の乳化剤を使用して重合する際に不飽和酸モノマ
ーと不飽和アミンモノマーが同時には重合系内に存在し
ない条件で重合して得られるラテックスで、アンモニア
等の揮発性のアルカリ物質により安定化され、pH3.
5〜8.5でゲル化を起こすものがある。この両性ラテ
ックスと顔料を混合し、紙に塗布、乾燥するとアルカリ
性物質が揮発してゲル化を起こすため、顔料との接着性
が良くなり、得られた塗膜の電気抵抗が向上するものと
考えられる。In addition, an amphoteric latex which uses a small amount of an emulsifier can be used as an adhesive. For example, aliphatic conjugated diolefin monomers such as 1,3-butadiene, 2-methyl-1,3-butadiene, 2-chloro-1,3 butadiene; styrene, α-methylstyrene,
Monoolefinic monomers such as monochlorostyrene, acrylic acid ester, methacrylic acid ester, and acrylonitrile; ethylenically unsaturated acid monomers such as acrylic acid, methacrylic acid, itaconic acid, fumaric acid, crotonic acid, and cinnamic acid; and methyl Monomer composed of ethylenically unsaturated amine monomers such as aminoethyl (meth) acrylate, t-butylaminoethyl (meth) acrylate, dimethylaminoethyl (meth) acrylate, diethylaminoethyl (meth) acrylate, and dibutylaminoethyl (meth) acrylate Is a latex obtained by polymerizing under the condition that the unsaturated acid monomer and the unsaturated amine monomer are not simultaneously present in the polymerization system when the polymerization is carried out using 1% by weight or less of an emulsifier with respect to all the monomers. Volatile al Stabilized by Li substances, pH 3.
Some of them cause gelation at 5 to 8.5. When this amphoteric latex and pigment are mixed, applied to paper, and dried, the alkaline substance is volatilized and gels, so that the adhesion with the pigment is improved and the electrical resistance of the obtained coating film is considered to be improved. Can be
【0017】また、これらのソープレス自己架橋型アク
リルエマルジョンや両性ラテックスは、それぞれ単独で
使用するだけでなく、混合して使用することも可能であ
り、電気抵抗を低下させ過ぎない範囲で水溶性樹脂、例
えば、ポリビニルアルコール、デンプン、メチルセルロ
ース、ヒドロキシエチルセルロース、スチレン−アクリ
ル樹脂などと混合して使用することもできる。なお、こ
の他、塗料には色調を調整するために染料や有色顔料を
添加したり、視感的白さを増すため、蛍光染料を添加す
ることもできる。さらに、塗料調製を容易にするため、
分散剤や消泡剤を添加することもできる。These soapless self-crosslinking acrylic emulsions and amphoteric latexes can be used not only alone but also in a mixture, and can be used in a water-soluble manner as long as the electric resistance is not excessively reduced. Resins, for example, polyvinyl alcohol, starch, methylcellulose, hydroxyethylcellulose, styrene-acrylic resin, and the like can be used as a mixture. In addition, a dye or a colored pigment may be added to the paint to adjust the color tone, or a fluorescent dye may be added to increase the visual whiteness. Furthermore, to facilitate paint preparation,
Dispersants and defoamers can also be added.
【0018】塗料中の顔料と接着剤の重量配合比は、9
5/5〜60/40の範囲が望ましいが、特に、95/
5〜70/30の範囲が望ましい。顔料の配合比が95
重量%を越えると、塗膜強度が弱くなり、画像グロスが
低下するだけでなく、製造工程でもトラブルを起こす可
能性がある。顔料の配合比が60重量%未満の場合、平
滑化仕上げをしても十分な白紙グロスを得ることができ
ない。塗工方法としては、一般の塗工法、例えば、ブレ
ード塗工法、エアナイフ塗工法、ロール塗工法、バー塗
工法などを使用することができる。The weight ratio of the pigment to the adhesive in the paint is 9
The range of 5/5 to 60/40 is desirable, but in particular, 95/60/40.
A range of 5 to 70/30 is desirable. Pigment ratio is 95
If the amount exceeds 10% by weight, the strength of the coating film is weakened, and not only the image gloss is reduced, but also a trouble may be caused in the manufacturing process. When the compounding ratio of the pigment is less than 60% by weight, sufficient white paper gloss cannot be obtained even with a smoothing finish. As a coating method, a general coating method, for example, a blade coating method, an air knife coating method, a roll coating method, a bar coating method, or the like can be used.
【0019】[0019]
【実施例】以下、実施例及び比較例によって、本発明を
更に具体的に説明する。以下の例中、部は重量部を表
す。 (実施例1)坪量81g/m2 の原反に、スーパー・カ
レンダー処理を施し、スチレンブタジエンラバー(SB
R)とポリビニルアルコール(PVA)の配合比が69
部/31部の接着剤と、カオリンと炭カルの配合比が7
1部/29部の顔料からなり、顔料と接着剤の配合比が
87部/13部である塗布材料を乾燥後の塗布量が原反
のフェルト面に15g/m2 、ワイヤー面に3.5g/
m2 となるように、ラボ・コーターで塗工した後、スー
パー・カレンダー処理を行い電子写真用転写紙を得た。The present invention will be described more specifically with reference to the following examples and comparative examples. In the following examples, parts represent parts by weight. (Example 1) A raw material having a basis weight of 81 g / m 2 was subjected to a super calender treatment, and styrene butadiene rubber (SB
R) and polyvinyl alcohol (PVA) at a compounding ratio of 69
Parts / 31 parts of adhesive and 7 parts by weight of kaolin and charcoal
The coating amount after drying of a coating material composed of 1 part / 29 parts of a pigment and having a mixing ratio of the pigment and the adhesive of 87 parts / 13 parts is 15 g / m 2 on the felt surface of the raw material, and 3. 5g /
After coating with a lab coater so as to obtain m 2 , a transfer paper for electrophotography was obtained by performing a super calender treatment.
【0020】(実施例2)坪量66.5g/m2 の原反
にスーパーカレンダー処理を施し、実施例1と同様の方
法で塗工・スーパー・カレンダー処理を行い電子写真用
転写紙を得た。(Example 2) A raw material having a basis weight of 66.5 g / m 2 was subjected to a super calendering treatment, and was coated and super calendered in the same manner as in Example 1 to obtain an electrophotographic transfer paper. Was.
【0021】(実施例3)実施例1の条件のうち、フェ
ルト面への乾燥後の塗布量を15g/m2 から10g/
m2 に少なくして電子写真用転写紙を得た。(Embodiment 3) Under the conditions of Embodiment 1, the coating amount after drying on the felt surface is from 15 g / m 2 to 10 g / m 2.
The transfer paper for electrophotography was obtained with a reduction in m 2 .
【0022】(実施例4)実施例1の条件のうち、フェ
ルト面への乾燥後の塗布量を15g/m2 から4g/m
2 に少なくして電子写真用転写紙を得た。(Embodiment 4) Under the conditions of Embodiment 1, the coating amount after drying on the felt surface is from 15 g / m 2 to 4 g / m 2.
The transfer paper for electrophotography was obtained by reducing it to 2 .
【0023】(実施例5)実施例1の条件のうち、接着
剤SBRとPVAの配合比を69部/31部から85部
/15部に代えて電子写真用転写紙を得た。Example 5 Transfer paper for electrophotography was obtained by changing the blending ratio of the adhesive SBR and PVA from 69 parts / 31 parts to 85 parts / 15 parts in the conditions of Example 1.
【0024】(実施例6)坪量82.4g/m2 の原反
にスーパーカレンダー処理を施し、実施例1の条件のう
ち、炭カルをすべてカオリンで置換した顔料を用い、他
は実施例1と同様の方法で電子写真用転写紙を得た。(Example 6) A raw calender having a basis weight of 82.4 g / m 2 was subjected to a super calendering treatment, and the conditions of Example 1 were changed to a pigment obtained by replacing all of the charcoal with kaolin. In the same manner as in Example 1, an electrophotographic transfer paper was obtained.
【0025】(実施例7)市販の富士ゼロックス社製M
紙用の原反にスーパーカレンダー処理を施し、実施例1
と同様の条件で塗工、スーパ・カレンダー処理を行い電
子写真用転写紙を得た。(Example 7) Commercially available Fuji Xerox M
Example 1 Super-calendering of paper stock
Coating and supercalendering were performed under the same conditions as in Example 1 to obtain an electrophotographic transfer paper.
【0026】(実施例8)市販の富士ゼロックス社製M
紙用の原反に実施例1と同様の条件で塗工、スーパー・
カレンダー処理を行い電子写真用転写紙を得た。Example 8 Commercially available Fuji Xerox M
Coating on a raw paper for paper under the same conditions as in Example 1,
A calendering process was performed to obtain an electrophotographic transfer paper.
【0027】(比較例1)坪量82.4g/m2 の原反
にSBRとPVAの配合比が69部/31部の接着剤
と、カオリンと炭カルの配合比が71部/29部の顔料
からなり、顔料と接着剤の配合比が87部/13部であ
る塗布材料を乾燥後の塗布量が、原反のフェルト面に1
5g/m2 、ワイヤー面に3.5g/m2 となるよう
に、ラボ・コーターで塗工し、その後、スーパー・カレ
ンダー処理を行わずに電子写真用転写紙を得た。(Comparative Example 1) An adhesive having a blending ratio of SBR and PVA of 69 parts / 31 parts and a blending ratio of kaolin and charcoal of 71 parts / 29 parts in a raw material having a basis weight of 82.4 g / m 2. Of the coating material having a mixing ratio of 87 parts / 13 parts of the pigment and the adhesive, and the coating amount after drying is 1% on the felt surface of the raw material.
The coating was performed by a lab coater so as to be 5 g / m 2 and 3.5 g / m 2 on the wire surface, and thereafter, a transfer paper for electrophotography was obtained without performing super calendar treatment.
【0028】(比較例2)市販の王子製紙社製印刷用紙
サンフラワー用の原反に比較例1と同様の方法で塗工を
行い、その後、スーパー・カレンダー処理を行って電子
写真用転写紙を得た。(Comparative Example 2) An original paper for printing paper sunflower commercially available from Oji Paper Co., Ltd. was coated in the same manner as in Comparative Example 1, and then subjected to a super calender treatment to obtain an electrophotographic transfer paper. I got
【0029】(比較例3)市販の富士ゼロックス社製L
紙用の原反に比較例1で用いた塗布材料を乾燥後の塗布
量が、原反のフェルト面に30g/m2 、ワイヤー面に
3.5g/m2 となるようにラボ・コーターで塗工し、
その後、スーパー・カレンダー処理を行い電子写真用転
写紙を得た。Comparative Example 3 Commercially available L manufactured by Fuji Xerox Co., Ltd.
Coating amount after drying a coating material used in Comparative Example 1 to raw for paper, 30 g / m 2 on the felt surface of the raw, lab coater so that 3.5 g / m 2 on the wire surface Coating,
Thereafter, a super calendar treatment was performed to obtain an electrophotographic transfer paper.
【0030】(比較例4)市販の富士ゼロックス社製L
紙用の原反に比較例1で用いた塗布材料を乾燥後の塗布
量が、原反のフェルト面に3g/m2 、ワイヤー面に
3.5g/m2 となるようにラボ・コーターで塗工し、
その後、スーパー・カレンダー処理を行い電子写真用転
写紙を得た。Comparative Example 4 Commercially available L manufactured by Fuji Xerox Co., Ltd.
Coating amount after drying a coating material used in Comparative Example 1 to raw for paper, 3 g / m 2 on the felt surface of the raw, lab coater so that 3.5 g / m 2 on the wire surface Coating,
Thereafter, a super calendar treatment was performed to obtain an electrophotographic transfer paper.
【0031】(比較例5)比較例1で用いた原反に、接
着剤としてSBRを、顔料として炭カルを用い、顔料と
接着剤の配合比が87部/13部である塗布材料を乾燥
後の塗布量が、原反のフェルト面に15g/m2 、ワイ
ヤー面に3.5g/m2 となるようにラボ・コーターで
塗工し、その後、スーパー・カレンダー処理を行い電子
写真用転写紙を得た。(Comparative Example 5) The raw material used in Comparative Example 1 was dried using SBR as an adhesive, charcoal char as a pigment, and a coating material having a mixing ratio of 87 parts / 13 parts of the pigment and the adhesive. the coating amount of later, 15 g / m 2 on the felt surface of the raw, and coated in a laboratory coater so that 3.5 g / m 2 on the wire surface, then, for electrophotographic transfer performs super calendar treatment I got the paper.
【0032】(比較例6)比較例1で用いた原反に、比
較例1の塗布材料にアニオン系導電性樹脂を0.6g/
m2 添加して比較例1と同様に塗工を行い、その後、ス
ーパー・カレンダー処理を行って電子写真用転写紙を得
た。(Comparative Example 6) The raw material used in Comparative Example 1 was replaced with the coating material of Comparative Example 1 containing 0.6 g / anionic conductive resin.
Coating was performed in the same manner as in Comparative Example 1 with the addition of m 2 , and then a super calendar treatment was performed to obtain an electrophotographic transfer paper.
【0033】(比較例7)比較例1で用いた原反に、比
較例1の塗布材料にアニオン系導電性樹脂を1.4g/
m2 添加して比較例1と同様に塗工を行い、その後、ス
ーパー・カレンダー処理を行って電子写真用転写紙を得
た。(Comparative Example 7) The raw material used in Comparative Example 1 was replaced with the coating material of Comparative Example 1 containing 1.4 g / anionic conductive resin.
Coating was performed in the same manner as in Comparative Example 1 with the addition of m 2 , and then a super calendar treatment was performed to obtain an electrophotographic transfer paper.
【0034】(比較例8)市販の富士ゼロックス社製M
紙用の原反を用い、比較例1と同様の方法で塗工を行い
電子写真用転写紙を得た。(Comparative Example 8) Commercially available Fuji Xerox M
Coating was carried out in the same manner as in Comparative Example 1 using a paper web to obtain an electrophotographic transfer paper.
【0035】(比較例9)市販の富士ゼロックス社製共
用紙(厚口)用の原反を用い、比較例1と同様の方法で
塗工を行い電子写真用転写紙を得た。(Comparative Example 9) Coating paper (thick mouth) manufactured by Fuji Xerox Co., Ltd. was used and coated in the same manner as in Comparative Example 1 to obtain an electrophotographic transfer paper.
【0036】(比較例10)市販の王子製紙社製印刷用
塗工紙OK特アートを電子写真用転写紙として用いた。(Comparative Example 10) A commercial printing coated paper OK special art manufactured by Oji Paper Co., Ltd. was used as an electrophotographic transfer paper.
【0037】(比較例11) 市販のキャノン販売社製カラー電子写真用塗工紙ピクセ
ル用ペーパー・コートタイプを用いた。[0037] was used (Comparative Example 11), commercially available Canon Sales Co., Ltd. color electrophotographic coating paper coat type for the paper pixel.
【0038】実施例1〜8及び比較例1〜11に挙げた
用紙について、坪量(g/m2 )、厚さ(μm)、
J.TAPPI No.48に準じた水銀圧入法によ
る塗工紙の空隙直径の大きい方のピーク値(μm)、
転写面表面電気抵抗値(Ω)、各転写電流値(Itμ
A)での画質、シリコン被覆ゴムロール温度でのグロ
ス・ムラ、走行性の各特性を下記の方法で測定、評価
し、その結果を表1及び表2に示した。For the papers listed in Examples 1 to 8 and Comparative Examples 1 to 11, the basis weight (g / m 2 ), the thickness (μm),
J. TAPPI No. Peak value (μm) of the larger pore diameter of the coated paper by the mercury intrusion method according to No. 48,
Transfer surface electric resistance (Ω), transfer current (Itμ)
The image quality, gloss / unevenness at the temperature of the silicone-coated rubber roll, and running properties in A) were measured and evaluated by the following methods, and the results are shown in Tables 1 and 2.
【0039】[0039]
【表1】 [Table 1]
【0040】[0040]
【表2】 [Table 2]
【0041】坪量:JISP8124の方法で測定し
た。 厚さ:JISP8118の方法で測定した。 原反空隙直径最頻値:測定器としてCARLO ER
BA INSTRUMENTS社製のPOROSIME
TER 2000,MACRO PORE 120を使
用し、J.TAPPI No.48に準じた水銀圧入法
で空隙直径最頻値を測定した。 表面電気抵抗値:(株)川口電機製作所製の常温測定
箱(RC−02)及び超絶縁計(R−503)を使用
し、印加電圧を100Vに設定し、JISP8111の
方法により試験片を前処理し、各々前処理と同じ条件で
JISC2122の表面抵抗率に準じた方法により転写
面について測定した。 各転写電流値の画質:カラー電子写真複写機(キャノ
ン(株)社製CLC500)を用いて、外部電源により
転写コントロン・ワイヤーに流れる転写電流値(It)
を変化させ、マジェンタ色トナーを使用して200線万
線(200本/インチ)画像から成る転写像を転写面に
形成した後、定着像を得た。得られた画像のうち入力濃
度がX−Rite404A(X−Rite社製)で1.
31〜1.87のべた部分を目視により評価した。な
お、試験用紙はJISP8111の方法で前処理を行っ
た。表中の記号の意味は下記のとおりである。 ◎:転写ムラ、その他画像ディフェクトがほとんどな
い。 ○:転写ムラ、その他画像ディフェクトが多少あるが、
目視では目立たない。 △:転写ムラ、その他画像ディフェクトがあり、目視で
やや目立つ。 ×:転写ムラ、その他画像ディフェクトが非常に大き
く、目視でもはっきり認められる。 ××:転写不良、その他画像ディフェクトが認められ
る。 グロス・ムラ:カラー電子写真複写機(キャノン
(株)社製CLC500)を用い、カラー200線万線
転写像を転写面に得た後、熱加圧方式の定着器のシリコ
ンゴム被覆ロールの温度を150℃と160℃の条件に
して定着像を得た。この定着像の全体を目視により評価
した。なお、試験用紙はJISP8111の方法で前処
理を行った。表中の記号の意味は下記のとおりである。 ○:グロス・ムラがない。 △:グロス・ムラがあり、目視でやや目立つ。 ×:グロス・ムラが非常に大きく、目視でもはっきり認
められる。 走行性: ○:フェーザー巻き付きジャム発生せず。 △:全走行枚数の約1/10フェーザー巻き付きジャム
発生。 ×:全走行枚数の約1/2フェーザー巻き付きジャム発
生。 ××:全走行枚数フェーザー巻き付きジャム発生。Basis weight: Measured according to the method of JISP8124. Thickness: Measured by the method of JISP8118. Material void diameter mode: CARLO ER as measuring instrument
POROSIME manufactured by BA INSTRUMENTS
Using TER 2000, MACRO PORE 120, TAPPI No. The mode value of the pore diameter was measured by a mercury intrusion method according to No.48. Surface electric resistance value: Using a room temperature measurement box (RC-02) and a super insulation meter (R-503) manufactured by Kawaguchi Electric Works, set the applied voltage to 100 V, and place the test piece in front of the specimen by the method of JISP8111. The transfer surface was measured by the method according to the surface resistivity of JISC2122 under the same conditions as in the pretreatment. Image quality of each transfer current value: Using a color electrophotographic copying machine (CLC500 manufactured by Canon Inc.), the transfer current value (It) flowing through the transfer contron wire by an external power supply
Was changed to form a transfer image composed of 200 lines and 200 lines (200 lines / inch) on the transfer surface using a magenta toner, and then a fixed image was obtained. In the obtained image, the input density is X-Rite404A (manufactured by X-Rite).
Solid portions of 31 to 1.87 were visually evaluated. The test paper was pretreated by the method of JISP8111. The meanings of the symbols in the table are as follows. A: Transfer unevenness and other image defects are almost nonexistent. :: There are some transfer unevenness and other image defects,
It is not noticeable visually. Δ: There are uneven transfer and other image defects, which are slightly noticeable visually. X: Transfer unevenness and other image defects are extremely large, and are clearly recognized visually. XX: Poor transfer and other image defects are observed. Gross / Mura: Using a color electrophotographic copier (CLC500, manufactured by Canon Inc.), a color 200-line parallel transfer image was obtained on the transfer surface, and then the temperature of the silicon rubber-coated roll of the heat-pressing type fixing device was measured. At 150 ° C. and 160 ° C. to obtain a fixed image. The whole of the fixed image was visually evaluated. The test paper was pretreated by the method of JISP8111. The meanings of the symbols in the table are as follows. :: No gloss or unevenness. Δ: There is unevenness in gloss, and it is slightly noticeable visually. X: The gloss unevenness is very large, and is clearly recognized visually. Runnability: :: No phasor-wrapped jam occurs. Δ: Jam occurred due to phasor winding about 1/10 of the total running number. ×: Jam occurred with 巻 き phasor winding of the total running number. XX: The total number of running sheets.
【0042】[0042]
【発明の効果】本発明は、上記の構成を採用することに
より、転写時の転写ムラ及び定着時のグロス・ムラのな
い、写真印刷並のカラー及びモノクローム高画質画像を
電子写真複写方法で得ることができるようになった。According to the present invention, by adopting the above-mentioned structure, a color and monochrome high-quality image comparable to that of a photographic print can be obtained by an electrophotographic copying method without transfer unevenness at the time of transfer and gloss unevenness at the time of fixing. Now you can do it.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 牧山 皓一 神奈川県海老名市本郷2274番地 富士ゼ ロックス株式会社海老名事業所内 (72)発明者 長沢 伸一 東京都江東区東雲一丁目10番6号 王子 製紙株式会社商品研究所内 (72)発明者 植地 勢作 東京都中央区銀座四丁目7番5号 王子 製紙株式会社内 (56)参考文献 特開 平4−88354(JP,A) 特開 平1−245265(JP,A) 特開 平3−294600(JP,A) (58)調査した分野(Int.Cl.7,DB名) G03G 7/00 101 ──────────────────────────────────────────────────の Continuing from the front page (72) Inventor Koichi Makiyama 2274 Hongo, Ebina-shi, Kanagawa Fuji Xerox Co., Ltd.Ebina Office (72) Inventor Shinichi Nagasawa 1-10-6 Shinonome, Koto-ku, Tokyo Oji Paper Stock (72) Inventor Shigesaku Uechi 4-57-5 Ginza, Chuo-ku, Tokyo Oji Paper Co., Ltd. (56) References JP-A-4-88354 (JP, A) JP-A-1-245265 (JP, A) JP-A-3-294600 (JP, A) (58) Fields investigated (Int. Cl. 7 , DB name) G03G 7/00 101
Claims (2)
接着剤からなる片面当たりの塗布量4g/m2 以上の塗
工層を備えた、坪量85〜100g/m2 の塗工紙から
なる電子写真用転写紙において、JISP8111の方
法で前処理した上記塗工紙の表面電気抵抗値が6×10
9 〜1×1011Ωの範囲にあり、かつ、J.TAPPI
No.48に準じた水銀圧入法による塗工紙の空隙直
径の大きい方のピークの値が2.0〜3.0μmの範囲
にあることを特徴とする電子写真用転写紙。On at least one surface of 1. A raw, with a coating weight 4g / m 2 or more coating layers per surface consisting of a pigment and an adhesive, basis weight 85~100g / m 2 of coated paper In the electrophotographic transfer paper, the coated paper pretreated by the method of JISP8111 has a surface electric resistance value of 6 × 10
9 to 1 × 10 11 Ω. TAPPI
No. 48. A transfer paper for electrophotography, wherein the peak value of the larger pore diameter of the coated paper by mercury intrusion method according to No. 48 is in the range of 2.0 to 3.0 μm.
フィルム上に保持し、感光体上の現像像を複数回転写
し、熱加圧定着法で定着することを特徴とする電子写真
複写方法。2. The electrophotographic copying method according to claim 1, wherein the transfer paper for electrophotography according to claim 1 is held on a transfer film, a developed image on a photoreceptor is transferred a plurality of times, and is fixed by a heat and pressure fixing method. Method.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP09612792A JP3232514B2 (en) | 1992-04-16 | 1992-04-16 | Transfer paper for electrophotography |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP09612792A JP3232514B2 (en) | 1992-04-16 | 1992-04-16 | Transfer paper for electrophotography |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH05297621A JPH05297621A (en) | 1993-11-12 |
JP3232514B2 true JP3232514B2 (en) | 2001-11-26 |
Family
ID=14156724
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP09612792A Expired - Lifetime JP3232514B2 (en) | 1992-04-16 | 1992-04-16 | Transfer paper for electrophotography |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3232514B2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI704954B (en) | 2019-02-27 | 2020-09-21 | 潘彥儒 | Wet scrubber for capturing solid particles by using microbubbles |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3816120B2 (en) * | 1994-12-20 | 2006-08-30 | 富士ゼロックス株式会社 | Electrophotographic transfer paper |
-
1992
- 1992-04-16 JP JP09612792A patent/JP3232514B2/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI704954B (en) | 2019-02-27 | 2020-09-21 | 潘彥儒 | Wet scrubber for capturing solid particles by using microbubbles |
Also Published As
Publication number | Publication date |
---|---|
JPH05297621A (en) | 1993-11-12 |
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