JPS62198877A - Electrophotographic transfer paper - Google Patents
Electrophotographic transfer paperInfo
- Publication number
- JPS62198877A JPS62198877A JP3897686A JP3897686A JPS62198877A JP S62198877 A JPS62198877 A JP S62198877A JP 3897686 A JP3897686 A JP 3897686A JP 3897686 A JP3897686 A JP 3897686A JP S62198877 A JPS62198877 A JP S62198877A
- Authority
- JP
- Japan
- Prior art keywords
- paper
- parts
- manufactured
- image
- coated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000012546 transfer Methods 0.000 title claims abstract description 32
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract description 40
- 238000000576 coating method Methods 0.000 abstract description 37
- 239000011248 coating agent Substances 0.000 abstract description 34
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract description 17
- 239000000049 pigment Substances 0.000 abstract description 17
- 238000009499 grossing Methods 0.000 abstract description 16
- 239000000853 adhesive Substances 0.000 abstract description 5
- 239000000123 paper Substances 0.000 description 112
- 238000000034 method Methods 0.000 description 23
- 238000007639 printing Methods 0.000 description 18
- 239000002245 particle Substances 0.000 description 17
- 239000003973 paint Substances 0.000 description 16
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 12
- 238000004132 cross linking Methods 0.000 description 12
- 238000001035 drying Methods 0.000 description 12
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 10
- 239000004816 latex Substances 0.000 description 10
- 229920000126 latex Polymers 0.000 description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- 239000000839 emulsion Substances 0.000 description 8
- 239000000178 monomer Substances 0.000 description 8
- 239000010410 layer Substances 0.000 description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 5
- 229920002261 Corn starch Polymers 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 229940099112 cornstarch Drugs 0.000 description 5
- 239000001254 oxidized starch Substances 0.000 description 5
- 235000013808 oxidized starch Nutrition 0.000 description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 230000006866 deterioration Effects 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- -1 lithopone Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 235000010724 Wisteria floribunda Nutrition 0.000 description 3
- 230000000903 blocking effect Effects 0.000 description 3
- 239000004927 clay Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- SJIXRGNQPBQWMK-UHFFFAOYSA-N 2-(diethylamino)ethyl 2-methylprop-2-enoate Chemical compound CCN(CC)CCOC(=O)C(C)=C SJIXRGNQPBQWMK-UHFFFAOYSA-N 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- 239000004640 Melamine resin Substances 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- 239000011121 hardwood Substances 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000002655 kraft paper Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 125000005395 methacrylic acid group Chemical group 0.000 description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 108091008695 photoreceptors Proteins 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229920002379 silicone rubber Polymers 0.000 description 2
- 239000004945 silicone rubber Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 229920003051 synthetic elastomer Polymers 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 1
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 1
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 238000007754 air knife coating Methods 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 238000010009 beating Methods 0.000 description 1
- 238000009529 body temperature measurement Methods 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229930016911 cinnamic acid Natural products 0.000 description 1
- 235000013985 cinnamic acid Nutrition 0.000 description 1
- 238000004737 colorimetric analysis Methods 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- BXKDSDJJOVIHMX-UHFFFAOYSA-N edrophonium chloride Chemical compound [Cl-].CC[N+](C)(C)C1=CC=CC(O)=C1 BXKDSDJJOVIHMX-UHFFFAOYSA-N 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 150000005673 monoalkenes Chemical class 0.000 description 1
- UXJXCZLHRLBCLF-UHFFFAOYSA-N n-ethylethanamine;ethyl 2-methylprop-2-enoate Chemical compound CCNCC.CCOC(=O)C(C)=C UXJXCZLHRLBCLF-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 229920005792 styrene-acrylic resin Polymers 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
- D21H25/08—Rearranging applied substances, e.g. metering, smoothing; Removing excess material
- D21H25/12—Rearranging applied substances, e.g. metering, smoothing; Removing excess material with an essentially cylindrical body, e.g. roll or rod
- D21H25/14—Rearranging applied substances, e.g. metering, smoothing; Removing excess material with an essentially cylindrical body, e.g. roll or rod the body being a casting drum, a heated roll or a calender
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H5/00—Special paper or cardboard not otherwise provided for
- D21H5/0075—Anti-friction, anti-abrasive or release paper
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G7/00—Selection of materials for use in image-receiving members, i.e. for reversal by physical contact; Manufacture thereof
- G03G7/0006—Cover layers for image-receiving members; Strippable coversheets
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/02—Chemical or chemomechanical or chemothermomechanical pulp
- D21H11/04—Kraft or sulfate pulp
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/28—Starch
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/62—Rosin; Derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/66—Salts, e.g. alums
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/68—Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/28—Colorants ; Pigments or opacifying agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/30—Luminescent or fluorescent substances, e.g. for optical bleaching
Abstract
Description
【発明の詳細な説明】
[産業上の利用分野]
本発明は電子写真用転写紙に関するものであり、特に写
真や印刷並の画質を再現するモノクロームおよびカラー
電子写真複写機において、高画質コピーを得るのに好適
な電子写真用転写紙に関するものである。Detailed Description of the Invention [Field of Industrial Application] The present invention relates to electrophotographic transfer paper, and is particularly useful for high-quality copies in monochrome and color electrophotographic copying machines that reproduce image quality comparable to photographs and printing. The present invention relates to an electrophotographic transfer paper suitable for obtaining.
[従来の技術]
平板オフセット印刷を主流とする精巧な印刷や多色印刷
においては、アート紙、コート紙等の塗工紙が使用され
ている。これは塗工紙の表面が平滑なために、印刷時に
インキ皮膜との接触が良く、画像が忠実に再現されるこ
と、画像の光沢が高く、色再現が良いことなどによる。[Prior Art] Coated papers such as art paper and coated paper are used in elaborate printing and multicolor printing, where planar offset printing is the mainstream. This is because the coated paper has a smooth surface, which allows for good contact with the ink film during printing, resulting in faithful reproduction of images, high gloss, and good color reproduction.
塗工紙の電子写真適性については、塚谷等の検討がある
。彼等は、物理的には塗工紙は平滑で感光体に一様に密
着するので、理論的にはきれいなトナー転写像が得られ
るはずであるとしているが、実際に現存の装置に適用し
た場合には、画像が荒れると述べている(塚谷、太田:
ノンインパクトプリンタ用紙、紙パルプ技術タイムス2
7、NO64(19B4>31−36>。事実、印刷用
塗工紙を電子写真に用いても画質上の利点はなく、はと
んど使用されていない。Regarding the suitability of coated paper for electrophotography, there is a study by Tsukatani et al. They argue that coated paper is physically smooth and adheres uniformly to the photoreceptor, so theoretically it should be possible to obtain a clean toner transfer image, but they have not actually applied it to existing equipment. In some cases, the image becomes rough (Tsukatani, Ota:
Non-impact printer paper, paper pulp technology times 2
7, No. 64 (19B4>31-36>. In fact, even if coated printing paper is used for electrophotography, there is no advantage in image quality, and it is rarely used.
本発明者らの検討では、印刷用塗工紙の電子写真におけ
る画質上の大きな欠点は、感光体から用紙にトナー像を
転写する際の乱れが、非塗工上質紙系の電子写真標準紙
より大きいことにあり、この現象は温度20℃、湿度(
RH)85%を一例とする高湿条件で特に顕著であった
。この原因は主に塗工紙表面の塗工材料の電気特性にあ
り(紙の表面抵抗が低いためであることが判明した。The inventors have found that a major drawback in terms of image quality in electrophotography using coated paper for printing is that disturbances during the transfer of toner images from the photoreceptor to the paper are This phenomenon is caused by a temperature of 20℃ and humidity (
This was particularly noticeable under high humidity conditions, with an example of RH) of 85%. The cause of this is mainly due to the electrical properties of the coating material on the surface of the coated paper (it turned out that this is because the surface resistance of the paper is low).
一方、電子写真の高画質化の方法について、塚谷等は印
刷プロセスとの比較で、トナーの小粒径化、転写トナー
の薄層化を示唆している(塚谷。On the other hand, regarding methods for improving image quality in electrophotography, Tsukatani et al. suggest reducing the toner particle size and thinning the transferred toner layer in comparison with the printing process (Tsukatani et al.).
太田:ノンインパクトプリンタ用紙、紙パルプ技術タイ
ムス、27.No、3 (1984)45−49)。Ota: Non-impact printer paper, Paper and Pulp Technology Times, 27. No. 3 (1984) 45-49).
これらの技術面において、電子写真での印刷用塗工紙の
問題を解決できれば平滑な塗工紙の使用は画質上有利と
考えられる。また画像の光沢や色再現を重視した定着に
おいては、印刷と同様に電子写真でも平滑な塗工紙の方
が良いことが確認されている。In these technical aspects, if the problems of coated paper for printing in electrophotography can be solved, the use of smooth coated paper is considered to be advantageous in terms of image quality. Furthermore, it has been confirmed that smooth coated paper is better for electrophotography as well as for printing when fixing images with emphasis on gloss and color reproduction.
塗工紙に最も近い電子写真用転写紙として、磁性−成分
現像方式用の転写紙がある(特公昭58−26026号
、特公昭57−24716号、特公昭57−53592
号、特公昭57−55139号)。Transfer paper for electrophotography that is closest to coated paper is transfer paper for magnetic component development (Japanese Patent Publication No. 58-26026, Japanese Patent Publication No. 57-24716, Japanese Patent Publication No. 57-53592).
No., Special Publication No. 57-55139).
この転写紙は磁性−成分現像剤の電気抵抗が低いことに
より生じる転写時の像の乱れを改善する目的で、原紙に
高電気抵抗樹脂を主体とする塗料を塗工したものである
が、普通紙に似せるために塗工量が少なく、低平滑であ
り、前記の高画質用途には不適である。また印刷用塗工
紙の塗料に使用されているものと同じ顔料が、この転写
紙用の塗料にも配合されている。This transfer paper is made by coating a base paper with a paint mainly consisting of a high electrical resistance resin in order to improve the image disturbance caused by the low electrical resistance of the magnetic component developer. In order to resemble paper, the amount of coating is small and the surface is low and smooth, making it unsuitable for the above-mentioned high image quality applications. The same pigments used in the coating for coated printing paper are also included in the coating for this transfer paper.
しかし印刷用塗工紙の場合には、主に平滑化の目的で顔
料が多量に配合されるのに対し、普通紙に似せるように
配合されること、多量に配合すると高電気抵抗樹脂の効
果を低下させること等のため、塗料中の顔料配合量は印
刷用塗工紙より大幅に少ない。従って、この転写紙の塗
料の塗工量を増加しただけでは、印刷用塗工紙並の平滑
性は得られず、また、紙間のブロッキング等の問題を生
じ、電子写真用転写紙としては使用できない。However, in the case of coated paper for printing, large amounts of pigment are blended mainly for the purpose of smoothing, whereas pigments are blended to resemble plain paper, and when blended in large amounts, the effect of high electrical resistance resin The amount of pigment added in the paint is significantly lower than that of coated paper for printing, in order to reduce the Therefore, simply increasing the coating amount of paint on this transfer paper does not provide the same level of smoothness as coated paper for printing, and also causes problems such as blocking between the sheets, making it unsuitable for use as transfer paper for electrophotography. I can not use it.
[発明が解決しようとする問題点]
本発明の目的は、前記した従来技術の欠点を改善し、電
子写真における転写時の像の乱れがなく、高画質なコピ
ーが得られる電子写真転写用塗工紙を提供することにあ
る。[Problems to be Solved by the Invention] An object of the present invention is to improve the drawbacks of the prior art described above, and to provide a coating for electrophotographic transfer that eliminates image disturbance during transfer in electrophotography and provides high-quality copies. Our goal is to provide paper.
[問題点を解決するための手段]
本発明は前記の問題点を達成するために、表面の中心線
平均粗さが2.0μm以下の受像層を原紙の少なくとも
片面に設け、かつ転写層の表面電気抵抗を温度20 ’
C、相対湿度(RH>85%で8.0X108Ω以上に
調整したことを特徴とする電子写真用転写紙である。[Means for Solving the Problems] In order to achieve the above-mentioned problems, the present invention provides an image receiving layer having a surface center line average roughness of 2.0 μm or less on at least one side of a base paper, and a transfer layer. Surface electrical resistance at temperature 20'
C. An electrophotographic transfer paper characterized in that the relative humidity (RH>85%) is adjusted to 8.0×10 8 Ω or more.
印刷のカラー再現性に対する紙の影響については、J、
A、C,Yu Ieが紙表面のクロスが高く、インク吸
収性が小さいほどインクの色の劣化がないこと、および
非塗工紙に比較し、塗工紙の方がシャープな画像を得ら
れることを述べている(J、A、C,YuIe:pri
nciplesof QOIOr Reprodu
ction。Regarding the influence of paper on the color reproduction of printing, see J.
A, C, Yu Ie has a higher paper surface cross and a lower ink absorption, the less the ink color will deteriorate, and compared to uncoated paper, coated paper can produce sharper images. (J, A, C, YuIe: pri
nciplesofQOIOrReprodu
ction.
JOHN WILEY & 5ONS、INC,
。JOHN WILEY & 5ONS, INC.
.
1967)。1967).
本発明者らは電子写真用カラートナーの色の劣化につい
て、市販の印刷用塗工紙、上質紙および試作塗工紙を用
いて評価し、印刷と同様に塗工紙の方が上質紙より色の
劣化が少ないことを確認した。これらの紙についてクロ
スをGARDNER社の光沢度計GARDNERGLO
3SGARDIIを使用して測定した。また中心線平均
粗さを、株式会社小坂研究所製の万能表面形状測定機5
urfcorder 5E−3Cを使用して、JIS
BO601の方法に従い、カットオフ値0.8m、測定
長さ871!I11で測定し、第1図に示すようなりロ
スと中心線平均粗さの関係を得た。この結果からクロス
については色の劣化の少ない塗工紙と上質紙の境界は1
0%であるが、この付近にマット仕上げの塗工紙と上質
紙が存在し両者が識別しにくいのに対し、中心線平均粗
さでは境界値2μmを取ると両者を明確に区別し得るこ
とがわかった。The present inventors evaluated the color deterioration of color toner for electrophotography using commercially available coated printing paper, high-quality paper, and prototype coated paper.As with printing, coated paper was superior to high-quality paper. It was confirmed that there was little color deterioration. For these papers, use the GARDNER gloss meter GARDNER GLO.
Measured using 3SGARDII. In addition, the center line average roughness was measured using a universal surface profile measuring device 5 manufactured by Kosaka Laboratory Co., Ltd.
JIS using urfcorder 5E-3C
According to the method of BO601, the cutoff value is 0.8m and the measured length is 871! I11 was measured, and the relationship between loss and center line average roughness was obtained as shown in FIG. From this result, for cloth, the boundary between coated paper and high-quality paper with less color deterioration is 1
0%, but matte-finish coated paper and high-quality paper exist near this area, making it difficult to distinguish between the two, whereas the two can be clearly distinguished by taking the boundary value of 2 μm for the center line average roughness. I understand.
またカラートナーを十分発色させるためには、トナーを
定着時十分に溶融させる必要があり、そのため画像クロ
スが高くなるので、紙自体のクロスが低すぎるとコピー
内のクロスのムラが大きくなり好ましくない。In addition, in order for the color toner to develop sufficiently, the toner must be sufficiently melted during fixing, which will result in a high image cross, so if the cross of the paper itself is too low, the uneven cross in the copy will become undesirable. .
この点からは紙表面の中心線平均粗さはグロスが20%
以上となる1、5μm以下が望ましい。From this point of view, the center line average roughness of the paper surface is 20% for gloss.
The thickness is preferably 1.5 μm or less.
本発明の電子写真用転写紙は、原紙の少なくとも片面に
主に電気抵抗の高い顔料を主体とし、接着剤を配合した
塗料を塗工して表面を平滑し、転写層の表面電気抵抗を
温度20℃、湿度(R)−1>85%で8.0×108
Ω以上になるように調整して得られる。In the electrophotographic transfer paper of the present invention, a paint containing a pigment with high electrical resistance as a main ingredient and an adhesive is coated on at least one side of the base paper to smooth the surface, and the surface electrical resistance of the transfer layer is adjusted by temperature. 8.0×108 at 20℃, humidity (R)-1>85%
It can be obtained by adjusting it so that it is Ω or more.
塗料の主体である顔料は、塗工後スーパーカレンダー等
により塗工面を平滑化処理するため、平均粒径が1.5
μ准以下、望ましくは1.0μm以下の微粒子であり、
かつトナ一層の転写の際に、トナーの転写率が高く、画
像の乱れを生じさせないようにするため電気抵抗の高い
ものが望ましい。The pigment, which is the main component of the paint, has an average particle size of 1.5 because the coated surface is smoothed using a super calender etc. after coating.
Fine particles of less than μm, preferably less than 1.0 μm,
In addition, it is desirable to have a high electrical resistance in order to have a high toner transfer rate and prevent image disturbance when transferring a single layer of toner.
平均粒径が1.5μmを越えると平滑化処理を行なって
も中心線平均粗さが小さくならない傾向があり望ましく
ない。また電気抵抗の高い顔料は、例えば、重質炭酸カ
ルシウム、軽質炭酸カルシウム、焼成りレー、リトポン
、酸化亜鉛、二酸化チタン、硫酸バリウム、尿素樹脂顔
料等から選択で・きる。結晶水を含有するカオリンクレ
ー、セリサイト、ジ−クライト、タルク等は電気抵抗が
低く好ましくない。If the average grain size exceeds 1.5 μm, the center line average roughness tends not to be reduced even after smoothing treatment, which is undesirable. Pigments with high electrical resistance can be selected from, for example, heavy calcium carbonate, light calcium carbonate, calcined clay, lithopone, zinc oxide, titanium dioxide, barium sulfate, urea resin pigments, and the like. Kaolin clay, sericite, gicrite, talc, etc. containing crystal water have low electrical resistance and are not preferred.
接着剤は顔料、原紙との接着力が強く、ブロッキング性
が少ない水溶性接着剤あるいはエマルジョン、ラテック
スが使用できるが、トナ一層の転写を良好にするため、
紙表面の電気抵抗の微小部分での変動を小さく抑えるた
め、および高湿度下での電気抵抗の低下を防ぐため、乳
化剤等電気抵抗の低い成分は使用しないか、使用量をな
るべく少なくすることが望ましい。例えば、樹脂成分が
自己架橋型アクリル系樹脂で、アクリル系樹脂に対して
5モル%未満のカルボン酸を含有させることにより、乳
化剤なしでエマルジョン化したソープレス自己架橋型ア
クリルエマルジョンが使用できる。カルボン酸はアクリ
ル酸、メタクリル酸、イタコン酸、無水マレイン酸が好
適であるが、5モル%以上使用すると電気抵抗値が低下
して好ましくない。架橋反応にはカルボキシル基とエポ
キシ樹脂との架橋反応、アミド自己架橋反応、カルボキ
シル基とメラミン樹脂、ヒドロキシル基とメラミン樹脂
との架橋反応など各種の型があるが、いずれの型でもよ
い。Water-soluble adhesives, emulsions, and latexes that have strong adhesion to pigments and base paper and have low blocking properties can be used, but in order to improve the transfer of the toner layer,
In order to suppress small fluctuations in electrical resistance on the paper surface and to prevent a decrease in electrical resistance under high humidity, components with low electrical resistance such as emulsifiers should not be used or should be used in as little amount as possible. desirable. For example, a soapless self-crosslinking acrylic emulsion can be used in which the resin component is a self-crosslinking acrylic resin and the emulsion is made without an emulsifier by containing less than 5 mol % of carboxylic acid based on the acrylic resin. Preferred carboxylic acids are acrylic acid, methacrylic acid, itaconic acid, and maleic anhydride, but if they are used in excess of 5 mol %, the electrical resistance value decreases, which is not preferred. There are various types of crosslinking reactions, such as a crosslinking reaction between a carboxyl group and an epoxy resin, an amide self-crosslinking reaction, a crosslinking reaction between a carboxyl group and a melamine resin, and a crosslinking reaction between a hydroxyl group and a melamine resin, and any type may be used.
また両性ラテックスで乳化剤の使用量の少ないものを接
着剤として使用できる。例えば、1.3−ブタジェン、
2−メチル−1,3−ブタジェン、2−クロロ−1,3
−ブタジェン等の脂肪族共役ジオレフィンモノマー、ス
チレン、α−メチルスチレン、モノクロルスチレン、ア
クリル酸エステル、メタクリル酸エステル、アクリルニ
トリル等のモノオレフィン系モノマー、アクリル酸、メ
タクリル酸、イタコン酸、フマル酸、クロトン酸、ケイ
皮酸等のエチレン系不飽和酸モノマーおよびメチルアミ
ノエチル(メタ)アクリレート、t−プチルアミノエチ
ル(メタ)アクリレート、ジメチルアミノエチル(メタ
)アクリレート、ジブチルアミノエチル(メタ)アクリ
レート、ジブチルアミノエチル(メタ)アクリレート等
のエチレン系不飽和アミンモノマーからなる七ツマ−を
、全モノマーに対し1重量%以下の乳化剤を使用して重
合する際に不飽和酸上ツマ−と不飽和アミンモノマーが
同時には重合系内に存在しない条件で重合して得られた
ラテックスで、アンモニア等の揮発性アルカリ物質によ
り安定化され、113.5〜8.5でゲル化を起こすも
のがある。Also, amphoteric latex with a small amount of emulsifier can be used as an adhesive. For example, 1,3-butadiene,
2-methyl-1,3-butadiene, 2-chloro-1,3
- Aliphatic conjugated diolefin monomers such as butadiene, monoolefin monomers such as styrene, α-methylstyrene, monochlorostyrene, acrylic esters, methacrylic esters, acrylonitrile, acrylic acid, methacrylic acid, itaconic acid, fumaric acid, Ethylenically unsaturated acid monomers such as crotonic acid and cinnamic acid, and methylaminoethyl (meth)acrylate, t-butylaminoethyl (meth)acrylate, dimethylaminoethyl (meth)acrylate, dibutylaminoethyl (meth)acrylate, dibutyl When a monomer consisting of an ethylenically unsaturated amine monomer such as aminoethyl (meth)acrylate is polymerized using an emulsifier of 1% by weight or less based on the total monomer, the unsaturated acid monomer and the unsaturated amine monomer are polymerized. There are latexes obtained by polymerization under conditions that do not simultaneously exist in the polymerization system, are stabilized by volatile alkaline substances such as ammonia, and cause gelation at 113.5 to 8.5.
この両性ラテックスと顔料を混合し、紙に塗布、乾燥す
るとアルカリ性物質が揮発する際ゲル化を起こすため、
顔料との接着性が良く、得られた塗膜の電気抵抗が向上
するものと考えられる。When this amphoteric latex and pigment are mixed, applied to paper, and dried, gelation occurs when the alkaline substance evaporates.
It is thought that it has good adhesion with pigments and improves the electrical resistance of the resulting coating film.
また、これらソープレス自己架橋型アクリルエマルジョ
ンや両性ラテックスはそれぞれ単独で使用するだけでな
く、混合して使用するとか、高電気抵抗性を阻害しない
範囲で水溶性樹脂、例えば、ポリビニルアルコール、デ
ンプン、メチルセルロース、ヒドロキエチルセルロース
、スチレン−アクリル樹脂などと混合して使用すること
ができる。In addition, these soapless self-crosslinking acrylic emulsions and amphoteric latexes can be used not only individually, but also in combination, or with water-soluble resins such as polyvinyl alcohol, starch, etc., as long as they do not inhibit high electrical resistance. It can be used in combination with methylcellulose, hydroxyethylcellulose, styrene-acrylic resin, etc.
また、この他塗料には色調を調整するため染料や有色顔
料を添加したり、視感的白さを向上させるため蛍光染料
を添加することもできる。塗料調成を容易にするため分
散剤や消泡剤を添加することもできる。In addition, dyes and colored pigments may be added to the paint to adjust the color tone, and fluorescent dyes may be added to improve visual whiteness. Dispersants and antifoaming agents can also be added to facilitate paint preparation.
塗料中の顔料と接着剤の配合比は9515〜60/40
が望ましく平滑化仕上により、中心線平均粗さを2μm
(白紙クロス10%以上)にすることができる。とりわ
け9515〜70/30では中心線平均粗さを1.5μ
TrL(白紙クロス20%以上)にすることができるの
でさらに望ましい。The blending ratio of pigment and adhesive in the paint is 9515 to 60/40
The average roughness of the center line is preferably 2 μm by smoothing the finish.
(blank paper cloth 10% or more). In particular, for 9515-70/30, the center line average roughness is 1.5μ
It is more desirable because it can be made TrL (20% or more blank paper cloth).
顔料配合比が95%を越えると塗膜強度が低下し、製造
上トラブルを発生したり、記録後のトナーの定着性が低
下する欠点がある。また60%未満では平滑化仕上をし
ても十分な中心線平均粗さ、白紙クロスを得ることがで
きない欠点がある。When the pigment blending ratio exceeds 95%, the strength of the coating film decreases, causing problems in production and the toner fixing properties after recording are reduced. Moreover, if it is less than 60%, there is a drawback that even if a smooth finish is applied, sufficient center line average roughness and blank paper cannot be obtained.
ざらに40%未満では紙間のブロッキングを起こすとか
、筆記性が低下する等の問題が生じる欠点がある。If it is less than 40%, there are drawbacks such as blocking between sheets and deterioration of writability.
塗布量は片面当り5〜30g/Tdが望ましい。The coating amount is preferably 5 to 30 g/Td per side.
塗布量が5 g/m未満では目標とする電気抵抗、中心
線平均粗さおよび白紙クロスを得ることができないし、
30g/Triを越えると紙の腰が弱くなり通紙性にト
ラブルを生じたり、カール性が太きくなる欠点がある。If the coating amount is less than 5 g/m, it will not be possible to obtain the target electrical resistance, center line average roughness and white paper cross.
If it exceeds 30 g/Tri, the stiffness of the paper becomes weak, causing problems in paper passing properties, and there are disadvantages in that the curling property becomes thick.
塗工方法としては、一般の塗工方法、例えばブレード塗
工、エアナイフ塗工、ロール塗工、バー塗工などの塗工
方式を使用することができる。As the coating method, general coating methods such as blade coating, air knife coating, roll coating, bar coating, etc. can be used.
平滑化処理はスーパーカレンダーあるいはクロスカレン
ダーなど剛性ロールと弾性ロールのニップ間を多数回通
すことにより行うことができる。The smoothing treatment can be performed by passing the material through the nip between a rigid roll and an elastic roll many times using a super calender or a cross calender.
平滑化処理は十分な画像光沢度を得るためにJISBO
601による表面の中心線平均粗さが2.0μm以下、
望ましくは1.5μm以下となるように調整する必要が
ある。The smoothing process is performed using JISBO to obtain sufficient image glossiness.
601, the center line average roughness of the surface is 2.0 μm or less,
Desirably, it is necessary to adjust the thickness to 1.5 μm or less.
この必要な中心線平均粗さを得るためには平滑化処理工
程だけでコントロールできるものではなく、顔料の粒径
、配合比、塗工量、塗布方法をも考慮する必要がある。In order to obtain the required center line average roughness, it is not possible to control it only by the smoothing process, but it is also necessary to consider the pigment particle size, blending ratio, coating amount, and coating method.
原紙としては、酸性および中性の上質紙や中質紙等が使
用できるが、走行性、カール性等の電子写真複写機適性
を付与するために原料の配合、調成、製造条件を公知の
方法(特公昭55−47385号、特公昭57−812
70号)でコントロールした用紙が好ましい。As the base paper, acidic or neutral high-quality paper or medium-quality paper can be used. However, in order to provide suitability for electrophotographic copying machines such as runnability and curling properties, the blending, preparation, and manufacturing conditions of the raw materials must be adjusted according to known methods. Method (Special Publication No. 55-47385, Special Publication No. 57-812)
Paper controlled by No. 70) is preferable.
[実施例]
以下実施例および比較例によって本発明をざらに具体的
に説明する。以下の例中、部は重量部を表わす。[Examples] The present invention will be explained in detail below using Examples and Comparative Examples. In the following examples, parts represent parts by weight.
°実施例1
叩解度が460ccの広葉樹晒クラフトパルプ(LBK
P)100部にタルク12部、澱粉2°部、ロジンサイ
ズ剤1.5部および硫酸バンド1部を添加して抄紙した
6 5 g/mの上質紙の両面に軽質炭酸゛カルシウム
(ブリリアント1500゜平均粒径0.15μm、白石
工業社製>90部、スチレン:ブタジェン:メタクリル
酸=60部:37部:3部のラテックスを重合後、ジエ
チルアミノエチルメタクリレート2部を共重合して得た
両性ラテックス8部および酸化澱粉(、エースA。°Example 1 Hardwood bleached kraft pulp (LBK) with a freeness of 460cc
P) Light calcium carbonate (Brilliant 1500゜Average particle size 0.15 μm, manufactured by Shiraishi Kogyo Co., Ltd.>90 parts, ampholytic obtained by polymerizing latex of styrene:butadiene:methacrylic acid=60 parts:37 parts:3 parts, and then copolymerizing 2 parts of diethylaminoethyl methacrylate. 8 parts latex and oxidized starch (Ace A.
玉子コーンスターチ社製)2部からなる塗料を乾燥後の
塗布量がフェルト面(F面)/ワイヤー面(W面)=1
5/15g/mとなるようにブレードコーターで塗布し
た(麦、スーパーカレンダーで平滑化処理を行って複写
用紙を得た。The coating amount after drying of the paint consisting of 2 parts (manufactured by Tamago Cornstarch Co., Ltd.) is felt side (F side) / wire side (W side) = 1
Coating paper was coated with a blade coater at a concentration of 5/15 g/m (mugi) and smoothed with a super calendar to obtain copy paper.
実施例2
叩解度が460ccの広葉樹晒クラフトパルプ(LBK
P)100部にタルク12部、澱粉2部、ロジンサイズ
剤1.5部および硫酸バンド1部を添加して抄紙した6
5g/Tdの上質紙の両面に軽質炭酸カルシウム(ブリ
リアント’l 500゜平均粒径0.15μm、白石工
業社製)85部、スチレン:ブタジェン:メタクリル酸
=60部:37部:3部のラテックスを重合後、ジエチ
ルアミンエチルメタクリレート2部を共重合して得た両
性ラテックス13部および酸化澱粉(エースA。Example 2 Hardwood bleached kraft pulp (LBK) with a beating degree of 460cc
P) Paper was made by adding 12 parts of talc, 2 parts of starch, 1.5 parts of rosin sizing agent and 1 part of sulfuric acid to 100 parts 6
85 parts of light calcium carbonate (Brilliant'l 500° average particle size 0.15 μm, manufactured by Shiraishi Kogyo Co., Ltd.), styrene:butadiene:methacrylic acid = 60 parts: 37 parts: 3 parts latex on both sides of 5g/Td high-quality paper. and 13 parts of an amphoteric latex obtained by copolymerizing 2 parts of diethylamine ethyl methacrylate and oxidized starch (Ace A).
玉子コーンスターチ社製)2部からなる塗料を乾燥後の
塗布IがF面/W面一15/15g/mとなるようにエ
アーナイフコーターで塗布した後、スーパーカレンダー
で平滑化処理を行って複写用紙を得た゛。After applying the paint consisting of 2 parts (manufactured by Tamago Corn Starch Co., Ltd.) using an air knife coater so that the coating I after drying is 15/15 g/m on the F side/W side, smoothing it with a super calender and copying. I got the paper.
実施例3
実施例1で使用した上質紙の両面に重質炭酸カルシウム
(NS−1000,平均粒径1.17μm2日東粉化社
製)58部、湿式粉砕炭酸カルシウム(カー上タル90
.平均粒径0.6μ雇。Example 3 Both sides of the high-quality paper used in Example 1 were coated with 58 parts of heavy calcium carbonate (NS-1000, average particle size 1.17 μm, manufactured by Nitto Funka Co., Ltd.) and wet-pulverized calcium carbonate (car-top 90 parts).
.. Average particle size is 0.6μ.
富士カオリン社製)29部、ソープレス自己架橋型アク
リルエマルジョン(ジュリマ−3EKIO1、日本紬薬
社製)8部およびポリビニルアルシール(ポバール11
7.クラレ社製)5部からなる塗料を乾燥後の塗布量が
F面/W面=13/13g/TItとなるようにエアー
ナイフコーターで塗布した後、スーパーカレンダーで平
滑化処理を行なって複写用紙を得た。29 parts (manufactured by Fuji Kaolin Co., Ltd.), 8 parts of Soapless self-crosslinking acrylic emulsion (Jurimar-3EKIO1, manufactured by Nippon Tsumugi Co., Ltd.), and polyvinyl alsil (Poval 11)
7. After applying the paint consisting of 5 parts (manufactured by Kuraray Co., Ltd.) using an air knife coater so that the coating amount after drying is F side/W side = 13/13g/TIt, smoothing treatment was performed using a super calender and the copy paper was coated. I got it.
実施例4
実施例1で使用した上質紙の両面に軽質炭酸カルシウム
(ブリリアント1500.平均粒径0.15μm、白石
工業社製)58部、湿式粉砕炭酸カルシウム(カーごタ
ル90.平均粒径0.6μm、富士カオリン社製)29
部、ソープレス自己架橋型アクリルエマルジョン(ジ1
リマー3EK101.日本純薬社製)8部およびポリビ
ニルアルコール(ポバール117.クラレ社製)5部か
らなる塗料を乾燥後の塗布量がF面/W面=13/13
g/mとなるようにエアーナイフコーターで塗布した後
、スーパーカレンダーで平滑化処理を行なって複写用紙
を1qた。Example 4 On both sides of the high-quality paper used in Example 1, 58 parts of light calcium carbonate (Brilliant 1500, average particle size 0.15 μm, manufactured by Shiraishi Kogyo Co., Ltd.) and wet-pulverized calcium carbonate (Cargotal 90, average particle size 0) were added. .6 μm, manufactured by Fuji Kaolin Co., Ltd.) 29
Section, Soapless self-crosslinking acrylic emulsion (Di1
Rimmer 3EK101. The coating amount after drying of the paint consisting of 8 parts (manufactured by Nippon Pure Chemical Industries) and 5 parts of polyvinyl alcohol (Poval 117. manufactured by Kuraray Co., Ltd.) is F side / W side = 13 / 13
After coating with an air knife coater so as to give a coating weight of 1 q/m, copying paper was smoothed using a super calender to obtain 1 q of copy paper.
実施例5
実施例1で使用した上質紙の両面に軽質炭酸カルシウム
(ブリリアント1500.平均粒径0.15μm、白石
工業社製)45部、湿式粉砕炭酸カルシウム(カービク
ル90.平均粒径0.6μm、富士カオリン社製)20
部、ソープレス自己架橋型アクリルエマルジョン(ジュ
リマー3EK101.日本純薬社製)30部およびポリ
ビニルアルコール(ポバール117.クラレ社製)5部
からなる塗料を乾燥後の塗布量がF面/W面=7/l/
Tdとなるようにエアーナイフコーターで塗布した後、
スーパーカレンダーで平滑化処理を行なって複写用紙を
得た。Example 5 45 parts of light calcium carbonate (Brilliant 1500, average particle size 0.15 μm, manufactured by Shiraishi Kogyo Co., Ltd.) and wet-pulverized calcium carbonate (Carbicle 90, average particle size 0.6 μm) were coated on both sides of the high-quality paper used in Example 1. , manufactured by Fuji Kaolin Co., Ltd.) 20
After drying a paint consisting of 30 parts of Soapless self-crosslinking acrylic emulsion (Jurimar 3EK101, manufactured by Nippon Pure Chemical Industries, Ltd.) and 5 parts of polyvinyl alcohol (Poval 117, manufactured by Kuraray Co., Ltd.), the amount of coating after drying is F side / W side = 7/l/
After applying with an air knife coater to achieve Td,
Copy paper was obtained by smoothing with a super calendar.
実施例6
実施例1で使用した上質紙の両面に焼成りレー(アンシ
レックス93.平均粒径0.6μm。Example 6 Both sides of the high-quality paper used in Example 1 were coated with a baking tray (Ansilex 93. Average particle size: 0.6 μm).
EMC社製>60部、重質炭酸カルシウム(NS−10
00,平均粒径1.17μm、日東粉化社製)20部、
ソープレス自己架橋型アクリルエマルジョン(ジュラマ
ー5EK3O1,日本純薬社製)15部およびポリビニ
ルアルコール(ポバール117.クラレ社製)5部から
なる塗料を乾燥後の塗布量がF面/W面=15/15g
/Tdとなるようにエアーナイフコーターで塗布した後
、スーパーカレンダーで平滑化処理を行なって複写用紙
を得た。Manufactured by EMC > 60 parts, heavy calcium carbonate (NS-10
00, average particle size 1.17 μm, manufactured by Nitto Funka Co., Ltd.) 20 parts,
After drying a paint consisting of 15 parts of Soapless self-crosslinking acrylic emulsion (Duramar 5EK3O1, manufactured by Nippon Pure Chemical Industries, Ltd.) and 5 parts of polyvinyl alcohol (Poval 117, manufactured by Kuraray Co., Ltd.), the coating amount was F side / W side = 15 / 15g
/Td using an air knife coater, and smoothing was performed using a super calendar to obtain copy paper.
実施例7
実施例1で使用した上質紙の両面に軽質炭酸カルシウム
(ブリリアント1500.平均粒径0.15μm、白石
工業社製)85部、スチレン:ブタジェン:メタクリル
酸=60部:37部:3部のラテックスを重合後、ジエ
チルアミノエチルメタクリレート2部を共重合して1q
た両性ラテックス13部および酸化澱粉(エースA、玉
子コーンスターチ社製)2部および潤滑剤としてステア
リン酸カルシウム(ノブコートC−104,サンノプコ
社製)2部からなる塗料を乾燥後の塗布量がF面/W面
=15/1 !M/mとなるようにブレードコーターで
塗布した後、スーパーカレンダーで平滑化処理を行って
複写用紙を得た。Example 7 Both sides of the high-quality paper used in Example 1 were coated with 85 parts of light calcium carbonate (Brilliant 1500, average particle size 0.15 μm, manufactured by Shiraishi Kogyo Co., Ltd.), styrene:butadiene:methacrylic acid = 60 parts:37 parts:3 After polymerizing 1 q of latex, 2 parts of diethylaminoethyl methacrylate were copolymerized to give 1 q.
After drying a paint consisting of 13 parts of amphoteric latex, 2 parts of oxidized starch (Ace A, manufactured by Tamago Cornstarch Co., Ltd.) and 2 parts of calcium stearate (Nobu Coat C-104, manufactured by San Nopco Co., Ltd.) as a lubricant, the amount of coating after drying was W side = 15/1! After coating with a blade coater to give M/m, smoothing treatment was performed with a super calendar to obtain copy paper.
実施例8
実施例1で使用した上質紙の両面に重質炭酸カルシウム
(NS−2500,平均粒径0.89μm1日東粉化社
製>20部、軽質炭酸カルシウム(白艶華PZ、平均粒
径0.20°μm、白石工業社製)70部、実施例1で
使用した両性ラテックス8部およびポリビニルアルコー
ル(Nl−1−170、日本合成化学社製)2部からな
る塗料を乾燥後の塗布量がF面/W面=12/12g/
Tdとなるようにブレードコーターで塗布した後、クロ
スカレンダーで平滑化処理を行って複写用紙を得た。Example 8 Both sides of the high-quality paper used in Example 1 were coated with heavy calcium carbonate (NS-2500, average particle size 0.89 μm, manufactured by Nitto Funka Co., Ltd. > 20 parts) and light calcium carbonate (Shiroenka PZ, average particle size 0.89 μm). After drying, the coating amount was as follows: F side/W side=12/12g/
After coating with a blade coater to achieve Td, smoothing treatment was performed with a cross calender to obtain copy paper.
実施例9
実施例1で使用した原紙の表面に軽質炭酸カルシウム(
ブリリアント1500.平均粒径0.15μm、白石工
業社製)85部、SBRラテックス(JSRO662,
日本合成ゴム社製)13部、酸化澱粉(エースA、玉子
コーンスターチ社製)2部からなる塗料を乾燥後の塗布
量がF面/W面=12/12g/7Ffとなるようにブ
レードコーターで塗布した後、スーパーカレンダーで平
滑化処理を行って複写用紙を得た。Example 9 Light calcium carbonate (
Brilliant 1500. Average particle size 0.15 μm, Shiraishi Kogyo Co., Ltd.) 85 parts, SBR latex (JSRO662,
A coating consisting of 13 parts (manufactured by Japan Synthetic Rubber Co., Ltd.) and 2 parts of oxidized starch (Ace A, manufactured by Tamago Cornstarch Co., Ltd.) was coated with a blade coater so that the coating amount after drying was F side/W side = 12/12g/7Ff. After coating, smoothing treatment was performed using a super calendar to obtain copy paper.
比較例1
実施例1で使用した上質紙の両面にカオリンクレー(ウ
ルトラホワイト90.EMC社製)87部、スチレン−
ブタジェンラテックス(JSRO6・322日本合成ゴ
ム社製>10部および酸化澱粉(エースA、玉子コーン
スターチ社製)3部からなる塗料を、乾燥後の塗布量が
F面/W面=15/159/rdとなるようにブレード
コーターで塗布した後、スーパーカレンダーで平滑化処
理を行い複写用紙を得た。Comparative Example 1 87 parts of kaolin clay (Ultra White 90, manufactured by EMC) and styrene were applied to both sides of the high-quality paper used in Example 1.
A paint consisting of 10 parts of butadiene latex (JSRO6/322 manufactured by Japan Synthetic Rubber Co., Ltd.) and 3 parts of oxidized starch (Ace A, manufactured by Tamago Cornstarch Co., Ltd.) was applied in an amount after drying of F side/W side = 15/159/ After coating with a blade coater so as to give a RD, smoothing treatment was performed with a super calender to obtain copy paper.
比較例2
市販の印刷用塗工紙OK特アート(玉子製紙社製)84
.99部m。Comparative Example 2 Commercially available coated printing paper OK special art (manufactured by Tamako Paper Co., Ltd.) 84
.. 99 parts m.
比較例3
市販の印刷用塗工紙ニュー金e、<神崎製紙社製>84
.9g/尻。Comparative Example 3 Commercially available coated printing paper New Gold e, <manufactured by Kanzaki Paper Co., Ltd.> 84
.. 9g/butt.
比較例4
市販の一成分磁性トナー現像方式の三田工業ミタDC−
131複写機用のPPC用紙。Comparative Example 4 Commercially available one-component magnetic toner development system Mita Kogyo Mita DC-
131 PPC paper for copying machines.
比較例5 市販の富士ゼロックス社製ゼロックスL紙。Comparative example 5 Commercially available Xerox L paper manufactured by Fuji Xerox.
実施例1〜9および比較例1〜4にあげた用紙について
、(1)坪量、(2)厚さ、(3)中心線平均粗さ、(
4)表面電気抵抗、(5)透気度、(6)静摩擦係数、
(7)ハイライトクロマ、(8)白紙クロス、(9)ソ
リッド画像クロス、(10)画像乱れ、(11)定着時
ブリスターおよび(12)走行トラブル数の各特性を下
記の方法で測定、評価し、その結果を表1−1.1−2
.2−1および2−2に示した。Regarding the papers listed in Examples 1 to 9 and Comparative Examples 1 to 4, (1) basis weight, (2) thickness, (3) center line average roughness, (
4) Surface electrical resistance, (5) Air permeability, (6) Static friction coefficient,
(7) Highlight chroma, (8) Blank paper cross, (9) Solid image cross, (10) Image disturbance, (11) Blisters during fixing, and (12) Number of running troubles were measured and evaluated using the following methods. The results are shown in Table 1-1.1-2.
.. Shown in 2-1 and 2-2.
(1)坪量:JISP8124の方法により測定した。(1) Basis weight: Measured by the method of JISP8124.
(2)厚さ:JISP8118の方法により測定した。(2) Thickness: Measured by the method of JISP8118.
(3)中心線平均粗さ:JIsP8111(7)方法で
試験片を前処置し、J l5BO601の方法により1
面について測定した。(3) Center line average roughness: Pre-treated the test piece according to JIsP8111 (7) method, and
The surface was measured.
使用測定器;株式会社小坂研究所製。Measuring instrument used: Manufactured by Kosaka Laboratory Co., Ltd.
万能表面形状測定器
5urfcorder 5E−3C
カツトオフ(直 0.8an
測定長さ 8al11
(4)表面電気抵抗:
JISP8111の方法および条件が温度20±2℃、
湿度85±2%でJISP8111に準じる方法で試験
片を前処置し、各々前処置と同じ条件で、JISC21
22の表面抵抗率に準じる方法により1面について測定
した。Universal surface shape measuring instrument 5urfcorder 5E-3C Cut-off (direct 0.8an, measurement length 8al11 (4) Surface electrical resistance: JISP8111 method and conditions are temperature 20±2℃,
The test piece was pretreated in accordance with JISP8111 at a humidity of 85 ± 2%, and each test piece was subjected to JISC21 under the same conditions as the pretreatment.
The surface resistivity was measured on one side by a method similar to that of No. 22.
使用測定器;株式会社川口電機製作所製。Measuring instrument used: Manufactured by Kawaguchi Electric Manufacturing Co., Ltd.
常温測定箱 P−601
横河ヒューレットパッカード社
製HIGHRESISTA
NCE METER
329A
印加電圧; 100V
(5)透気度:JISP8117の方法により測定した
。Room temperature measurement box P-601 HIGHRESISTA NCE METER 329A manufactured by Yokogawa Hewlett-Packard Co., Ltd. Applied voltage: 100V (5) Air permeability: Measured by the method of JISP8117.
(6)静摩擦係数:
実施例および比較例の用紙については平滑化処理後、ギ
ロチン断裁機で500枚ずつA4サイズに断裁し、その
最上部の数十枚を除いた堆積状態の連続約100枚を試
験サンプルとした。(6) Static friction coefficient: After smoothing the papers of Examples and Comparative Examples, they were cut into A4 size sheets of 500 sheets each using a guillotine cutting machine, and approximately 100 consecutive sheets in a stacked state, excluding the top few dozen sheets, were cut into A4 size sheets. was used as the test sample.
市販紙については開封して、上と同様に堆積状態の連続
約100枚を試験サンプルとした。Regarding commercially available paper, the package was opened and about 100 consecutive sheets in the same stacked state as above were used as test samples.
J、TAPPI No、30に準じる方法により、試
験サンプルを84サイズ大の水平板の上に固定し、試験
サンプルの最上部一枚とおもりの底部を両面接着テープ
で固定し、順次10枚目まで測定した。J, TAPPI No. 30, fix the test sample on a horizontal plate of size 84, fix the top one of the test sample and the bottom of the weight with double-sided adhesive tape, and apply it sequentially up to the 10th plate. It was measured.
使用測定器:東洋ボールドウィン社製。Measuring instrument used: Manufactured by Toyo Baldwin.
テンシロンUTM−III−100
(7)ハイライトクロマ:
富士ゼロックス社製3890複写機でマゼンタ色トj−
を使用して175線5〜85%の網点階調画像の未定着
の転写像を1面に形成した。その後シリコーンゴム被覆
ロールから構成される両面加熱定着器で画像を定着した
。Tensilon UTM-III-100 (7) Highlight chroma: Magenta color toner with Fuji Xerox 3890 copier
An unfixed transfer image of a halftone gradation image of 5 to 85% of 175 lines was formed on one surface using the . Thereafter, the image was fixed using a double-sided heat fixing device consisting of a silicone rubber coated roll.
各網点階調毎にJ l5Z8722の方法により分光測
色し、X、’1/、Yを計算し、その値からJISZ8
721の方法により彩度Cを定めた。また同じ網点の網
点面積比を測定し、彩度Cと網点面積比の関係式を最小
二乗法で求めた。この関係式により網点面積比0.4の
時の彩度Cを計算しハイライトクロマとした。Spectral colorimetry is performed using the method of Jl5Z8722 for each halftone gradation, X, '1/, Y are calculated, and from the values JISZ8
The saturation C was determined by the method of 721. Further, the halftone dot area ratio of the same halftone dot was measured, and the relational expression between the saturation C and the halftone dot area ratio was determined by the least squares method. Using this relational expression, the saturation C when the dot area ratio is 0.4 was calculated and used as a highlight chroma.
使用測定器;日立製作所社製。Measuring instrument used: Manufactured by Hitachi, Ltd.
spectrophotome
ter H330
東洋インク社製、BEUVAC
(8)白紙グロス:JISP8142に準じる方法によ
りF面について測定した。Spectrophotometer H330 manufactured by Toyo Ink Co., Ltd., BEUVAC (8) Blank paper gloss: Measured on the F side by a method according to JISP8142.
使用測定器:GARDNER社製。Measuring instrument used: Manufactured by GARDNER.
GARDNERGLO3
SGARDIII
(9)ソリッド画像グロス:
ハイライトクロマと同様の方法により、F面にマゼンタ
色のソリッド画像を得た。このソリッド画像のグロスを
白紙クロスと同様の方法により測定した。GARDNERGLO3 SGARDIII (9) Solid image gloss: A magenta solid image was obtained on the F side by the same method as the highlight chroma. The gloss of this solid image was measured in the same manner as the white paper cloth.
(10)画像乱れ:
ハイライトクロマと同様の方法により、マゼンタ色のラ
イン像の未定着の転写像を形成した。(10) Image disturbance: An unfixed transfer image of a magenta line image was formed by the same method as the highlight chroma.
この転写像を光学顕微鏡で50倍の顕微鏡写真を撮影し
、限度見本と比較し評価した。A photomicrograph of this transferred image was taken with an optical microscope at a magnification of 50 times, and compared with a limit sample for evaluation.
なお、試験用紙はJISP8111の方法および条件が
温度20℃±2℃、湿度85±2%でJISP8111
に準じる方法で前処置した。The test paper is JISP8111 method and conditions: temperature 20℃±2℃, humidity 85±2%.
Pretreatment was performed in a manner similar to that described in .
表中の記号の意味は下記の通りである。The meanings of the symbols in the table are as follows.
0:画像乱れがほとんどない。0: Almost no image disturbance.
△;多少画像乱れがあるが、目視では目立たない。Δ: There is some image disturbance, but it is not noticeable visually.
X:画像乱れが大きく、目視でもはっきり認められる。X: Image disturbance is large and clearly visible even when visually observed.
(11)定着時ブリスタm:
ハイライトクロマと同様の方法により、加熱定着器のシ
リゴム被覆ロールの温度を180℃と200℃の条件で
マゼンタ色の網点階調画像を形成した。この定着器を目
視でブリスターを評価した。(11) Blister m during fixing: A magenta halftone gradation image was formed using the same method as Highlight Chroma, with the temperature of the silicone rubber coated roll of the heat fixing device set at 180° C. and 200° C. This fixing device was visually evaluated for blisters.
なお、試験用紙は温度20℃±2℃、湿度85±2%で
JISP8111に準じる方法で前処置した。The test paper was pretreated at a temperature of 20°C±2°C and a humidity of 85±2% in accordance with JISP8111.
表中の記号の意味は下記の通りである。The meanings of the symbols in the table are as follows.
○;ブリスターが認められない。○: No blisters observed.
62紙の面積の1/10以下の部分にだけブリスターが
認められる。。62 Blisters are observed only in an area less than 1/10 of the area of the paper. .
X:紙の面積の1/10以上の部分にブリスターが認め
られる。X: Blisters are observed over 1/10 or more of the paper area.
(12)走行トラブル数:
静摩擦係数と同様の方法で採取した堆積状態の用紙を5
00枚ずつ、富士ゼロックス社製5870複写機の給紙
トレイにセットし、各用紙1000枚(但し実施例8,
9.比較例1,2.3については100枚)コピーを取
り、紙詰り、重送等のトラブルの合計回数を走行トラブ
ル数とした、表1−1.1−2.2−1および2−2に
示した結果から、温度20’C,湿度85%の条件で調
湿した用紙の画像乱れを実用上問題のないレベルにする
ためには前記条件での紙の表面電気抵抗が8.0XIO
8Ω以上、望ましくは1.0X109Ω以上必要である
ことが明らかである。(12) Number of running troubles: 5 sheets of accumulated paper collected using the same method as the static friction coefficient.
00 sheets each, set in the paper feed tray of a Fuji Xerox 5870 copier, and 1000 sheets of each sheet (Example 8,
9. For Comparative Examples 1 and 2.3, 100 copies were made, and the total number of troubles such as paper jams and double feeding was taken as the number of running troubles. Tables 1-1.1-2.2-1 and 2-2 From the results shown in , in order to bring the image distortion of paper conditioned under conditions of temperature 20'C and humidity 85% to a level that does not pose a practical problem, the surface electrical resistance of paper under the above conditions must be 8.0XIO.
It is clear that 8Ω or more, preferably 1.0×10 9 Ω or more is required.
また、評価した定着システム、紙送りシステムではブリ
スターが紙の面積の1/10以上に発生しないこと、1
000枚で5回以下のトラブル数が望ましい。In addition, in the evaluated fixing system and paper feeding system, blisters should not occur on more than 1/10 of the paper area;
It is desirable to have no more than 5 troubles per 1,000 sheets.
[発明の効果]
本発明は表面の中心線平均粗さが2.0μm以下の転写
層を原紙の少なくとも片面に設け、転写層の表面電気抵
抗を温度20℃、相対湿度85%で8.0XIO8Ω以
上に調整した電子写真用転写紙を提供したものであり、
転写時に像の乱れがなくクロスの高い高画質のコピーが
得られるという特長を有する。[Effects of the Invention] The present invention provides a transfer layer with a surface center line average roughness of 2.0 μm or less on at least one side of a base paper, and the surface electrical resistance of the transfer layer is 8.0XIO8Ω at a temperature of 20°C and a relative humidity of 85%. Provides electrophotographic transfer paper adjusted as described above,
It has the advantage of being able to produce high-quality copies with high cross-sections without image disturbance during transfer.
第1図は各種用紙のクロスと中心線平均粗さとの関係を
示すグラフである。FIG. 1 is a graph showing the relationship between the cross and center line average roughness of various types of paper.
Claims (1)
の少なくとも片面に設け、かつ転写層の表面電気抵抗を
温度20℃、相対湿度85%で8.0×10^8Ω以上
に調整したことを特徴とする電子写真用転写紙。A transfer layer with a surface centerline average roughness of 2.0 μm or less is provided on at least one side of the base paper, and the surface electrical resistance of the transfer layer is adjusted to 8.0 × 10^8 Ω or more at a temperature of 20 ° C. and a relative humidity of 85%. An electrophotographic transfer paper that is characterized by:
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61038976A JPH0769628B2 (en) | 1986-02-26 | 1986-02-26 | Electrophotographic transfer paper |
US07/018,473 US4778711A (en) | 1986-02-26 | 1987-02-25 | Paper for receiving toner images in electrophotography |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61038976A JPH0769628B2 (en) | 1986-02-26 | 1986-02-26 | Electrophotographic transfer paper |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS62198877A true JPS62198877A (en) | 1987-09-02 |
JPH0769628B2 JPH0769628B2 (en) | 1995-07-31 |
Family
ID=12540181
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP61038976A Expired - Lifetime JPH0769628B2 (en) | 1986-02-26 | 1986-02-26 | Electrophotographic transfer paper |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0769628B2 (en) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62198875A (en) * | 1986-02-26 | 1987-09-02 | Fuji Xerox Co Ltd | Transfer paper for electrophotography |
JPH03294600A (en) * | 1990-03-05 | 1991-12-25 | Sanyo Kokusaku Pulp Co Ltd | Transfer paper for electrophotography |
EP0718702A2 (en) | 1994-12-20 | 1996-06-26 | Fuji Xerox Co., Ltd. | Electrophotographic transfer paper |
EP0718701A2 (en) | 1994-12-20 | 1996-06-26 | Fuji Xerox Co., Ltd. | Electrophotographic transfer paper and color image forming method |
EP0770927A1 (en) | 1995-10-20 | 1997-05-02 | Oji Paper Company Limited | Transfer sheet for electrophotography |
US5662995A (en) * | 1994-07-04 | 1997-09-02 | Fuji Xerox Co., Ltd. | Transfer paper for electrophotography and process for producing the same |
JPH11160905A (en) * | 1997-11-27 | 1999-06-18 | Oji Paper Co Ltd | Electrophotographic transfer sheet |
JP2008089981A (en) * | 2006-10-02 | 2008-04-17 | Bridgestone Corp | Conductive endless belt |
JP2009216820A (en) * | 2008-03-07 | 2009-09-24 | Fuji Xerox Co Ltd | Electrophotographic coated paper |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5540809A (en) * | 1978-09-08 | 1980-03-22 | Sanyo Chemical Ind Ltd | High electrresistant imparting agent for paper |
-
1986
- 1986-02-26 JP JP61038976A patent/JPH0769628B2/en not_active Expired - Lifetime
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5540809A (en) * | 1978-09-08 | 1980-03-22 | Sanyo Chemical Ind Ltd | High electrresistant imparting agent for paper |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62198875A (en) * | 1986-02-26 | 1987-09-02 | Fuji Xerox Co Ltd | Transfer paper for electrophotography |
JPH0582939B2 (en) * | 1986-02-26 | 1993-11-24 | Fuji Zerotsukusu Kk | |
JPH03294600A (en) * | 1990-03-05 | 1991-12-25 | Sanyo Kokusaku Pulp Co Ltd | Transfer paper for electrophotography |
US5662995A (en) * | 1994-07-04 | 1997-09-02 | Fuji Xerox Co., Ltd. | Transfer paper for electrophotography and process for producing the same |
US5637383A (en) * | 1994-12-20 | 1997-06-10 | Fuji Xerox Co., Ltd. | Electrophotographic transfer paper |
EP0718701A2 (en) | 1994-12-20 | 1996-06-26 | Fuji Xerox Co., Ltd. | Electrophotographic transfer paper and color image forming method |
EP0718702A2 (en) | 1994-12-20 | 1996-06-26 | Fuji Xerox Co., Ltd. | Electrophotographic transfer paper |
US5925446A (en) * | 1994-12-20 | 1999-07-20 | Fuji Xerox Co., Ltd. | Electrophotographic transfer paper and color image forming method |
US6120954A (en) * | 1994-12-20 | 2000-09-19 | Fuji Xerox Co., Ltd. | Electrophotographic transfer paper and color image forming method |
EP0770927A1 (en) | 1995-10-20 | 1997-05-02 | Oji Paper Company Limited | Transfer sheet for electrophotography |
JPH11160905A (en) * | 1997-11-27 | 1999-06-18 | Oji Paper Co Ltd | Electrophotographic transfer sheet |
JP2008089981A (en) * | 2006-10-02 | 2008-04-17 | Bridgestone Corp | Conductive endless belt |
JP2009216820A (en) * | 2008-03-07 | 2009-09-24 | Fuji Xerox Co Ltd | Electrophotographic coated paper |
Also Published As
Publication number | Publication date |
---|---|
JPH0769628B2 (en) | 1995-07-31 |
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