JP3163227U - Natural mineral iron-based soil conditioner - Google Patents

Natural mineral iron-based soil conditioner Download PDF

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JP3163227U
JP3163227U JP2010004070U JP2010004070U JP3163227U JP 3163227 U JP3163227 U JP 3163227U JP 2010004070 U JP2010004070 U JP 2010004070U JP 2010004070 U JP2010004070 U JP 2010004070U JP 3163227 U JP3163227 U JP 3163227U
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alum
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ferrous sulfate
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井上 和裕
和裕 井上
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井上 和裕
和裕 井上
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
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    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
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Abstract

【課題】土壌の大幅な改良を可能とした、無機素材による安価で安全な土壌改良剤を提供する。【解決手段】主成分が塩化マグネシウム及び硫酸第一鉄であり、鉄ミョウバン及びカリミョウバンを加えた土壌改良剤とした。より具体的には、該土壌改良剤1000リットル中、各成分の混合割合を、塩化マグネシウム約250kg、硫酸第一鉄約150kg、鉄ミョウバン約5kg、カリミョウバン約5kgとした。また、牛糞、鶏糞、豚糞、魚粉、油粕、骨粉、おがくず、米ぬかの少なくとも2種以上をよく攪拌配合し、これに本考案の土壌改良剤を200倍に希釈した溶液をかけ、アンモニア臭がなくなるまで土壌改良剤の散布と切り返しを行い完熟堆肥・肥料を作成した。【選択図】図2The present invention provides an inexpensive and safe soil improver made of an inorganic material, which can greatly improve soil. SOLUTION: The main components are magnesium chloride and ferrous sulfate, and a soil improver is added with iron alum and potash alum. More specifically, the mixing ratio of each component in 1000 liters of the soil conditioner was about 250 kg magnesium chloride, about 150 kg ferrous sulfate, about 5 kg iron alum, and about 5 kg potash alum. In addition, cow dung, chicken dung, pork dung, fish meal, oil cake, bone meal, sawdust, rice bran, rice bran, and rice bran are mixed well with stirring. The soil conditioner was sprayed and turned over until no longer left to produce fully matured compost and fertilizer. [Selection] Figure 2

Description

本願考案は土壌の改良剤に関し、特に無機材料により土壌の大幅な改良を可能とした改良剤に関する。 The present invention relates to a soil improver, and more particularly to an improver that enables a significant soil improvement by an inorganic material.

近年、土壌において見られる障害としては、連作障害、塩類集積障害、病害虫被害、未熟有機物分解時におけるアンモニア(窒素)ガス発生による障害、など多くのものがある。
しかしこれらを改良することは容易ではなく、化学肥料の使用によっては一時的に採取量の改善が見られても、結局土がやせてしまったり、人畜に対する薬害が問題となったりと、問題点を抱えていた。また種々の土壌改良資材は存在するが、それぞれ特定の用途、pHの矯正、土壌団粒化促進、透水性の改善、保水性の向上、陽イオン交換容量の増大など限られた範囲での効果しかなく、さらには非常に高価であったりと問題があった。
In recent years, there are many troubles observed in soil, such as continuous cropping troubles, salt accumulation troubles, pest damage, troubles caused by generation of ammonia (nitrogen) gas during decomposition of immature organic matter.
However, it is not easy to improve them, and depending on the use of chemical fertilizers, even if temporary improvement in the amount of collection is seen, the soil will eventually fade or phytotoxicity against human animals will become a problem. Was holding. There are various soil improvement materials, but each has specific applications, pH correction, soil aggregation promotion, improved water permeability, improved water retention, increased cation exchange capacity, etc. However, there was a problem that it was very expensive.

本考案は用途が広範囲にわたり、安価で安全な無機素材の土壌改良剤を提供するものである。   The present invention has a wide range of uses, and provides an inexpensive and safe inorganic material soil conditioner.

特開2005−75848号JP-A-2005-75848

上記特許出願は、本願と同様な土壌改良剤であるが、主にゼオライトを用いたものであるため、基本的な構成が本願とは異なるものである。また、本願の特徴であるニ価鉄の安定化方法を用いた土壌改良剤は記載されていない。
また、土壌の改良において最も重要な土壌のpH調整は、生石灰・硫黄等を用いて行っていたが、硫黄を使用すると石灰の塊(チョーク状)ができていた。これは生石灰をpHの調整に使用するために起こる。生石灰が土壌と混ぜ合わされることで消石灰に変わり、多量の水分を吸収し、時間とともに石灰と土がしっかりと結合し、硬くなる。この状態で硫黄を使用するため、土壌中にチョーク状のものができる。また、一部の試験場では硫酸を使用しているが、一般の生産者では硫酸は危険で扱いにくい。したがって、石灰の塊が出来ず、危険でないpHの調整方法が望まれていた。
pHの調整資材は他にもあるが、本考案の土壌改良剤の土壌に対する効果はそれとは比較にならないほどのよい結果をもたらしている。
さらに本考案の土壌改良剤に含まれる二価の鉄が植物に直接働きかけるため、植物中葉緑体のリンタンパクと結合し、葉緑素の形成に大きく貢献する。さらに植物体中に適度に鉄分が吸収されると、酸化と還元(Fe2+とFe3+)とに相互変化が活発化するため、植物体も活性化される。
軟弱野菜や塩基に弱い植物の窒素過剰害が増加傾向にあるが、鉄を安定して供給することにより窒素の代謝作用を大幅に改善することができる。植物体の鉄が欠乏するとタンパクの合成反応が阻害され、植物体内にて可溶性窒素化合物が蓄積するため病気にかかりやすくなる。
さらに、リン酸肥料過多時における植物体内の鉄欠乏症も未然に防止できる。(植物中でもリン酸が過剰に吸収されると、土壌中と同じように鉄と結合する。するとリン酸だけが過剰に吸収されているため、鉄が不足する。)
また、土壌改良剤は、一般に土壌の改良にのみ作用し、農家、畜産農家にとって必要なその他の消臭作用や、防虫作用を望む場合は、別の化学薬品を購入しているのが一般であった。従って、多用途に使用可能な、天然由来成分の改良剤が望まれていた。
The above-mentioned patent application is a soil improver similar to the present application, but mainly uses zeolite, so that the basic configuration is different from the present application. Moreover, the soil improvement agent using the stabilization method of divalent iron which is the characteristics of this application is not described.
Moreover, the most important soil pH adjustment in soil improvement was performed using quick lime, sulfur or the like, but when sulfur was used, a lime lump (chalk shape) was formed. This occurs because quicklime is used to adjust the pH. When quick lime is mixed with soil, it turns into slaked lime, absorbs a large amount of moisture, and over time, lime and soil combine firmly and become hard. Since sulfur is used in this state, chalk is formed in the soil. Also, although some test sites use sulfuric acid, it is dangerous and unwieldy for general producers. Therefore, there has been a demand for a pH adjustment method that does not cause lime lump and is not dangerous.
Although there are other materials for adjusting the pH, the effect of the soil conditioner of the present invention on the soil has yielded results that are incomparable.
Furthermore, since the divalent iron contained in the soil conditioner of the present invention directly acts on the plant, it binds to the phosphoprotein of the chloroplast in the plant and greatly contributes to the formation of chlorophyll. Further, when iron is appropriately absorbed in the plant body, the mutual change is activated between oxidation and reduction (Fe2 + and Fe3 +), so that the plant body is also activated.
Nitrogen excess harm of plants that are weak to soft vegetables and bases tends to increase, but the metabolic action of nitrogen can be greatly improved by supplying iron stably. If the plant is deficient in iron, the protein synthesis reaction is inhibited, and soluble nitrogen compounds accumulate in the plant, making it more susceptible to disease.
Furthermore, iron deficiency in the plant body when phosphate fertilizer is excessive can be prevented. (If phosphoric acid is absorbed excessively in plants, it binds to iron in the same way as in the soil. Then, only phosphoric acid is absorbed excessively, so iron is insufficient.)
In addition, soil improvers generally only work on soil improvement, and other chemicals are generally purchased when other deodorizing and insect-repellent effects are required for farmers and livestock farmers. there were. Therefore, a natural component improving agent that can be used for many purposes has been desired.

本考案に係る天然ミネラル鉄分主体の土壌改良剤は、主成分が塩化マグネシウムおよび硫酸第一鉄であり、鉄ミョウバン及びカリミョウバンを加えてなることを要旨とする。   The soil improver mainly composed of natural mineral iron according to the present invention is mainly composed of magnesium chloride and ferrous sulfate, and is obtained by adding iron alum and potash alum.

また、本考案に係る天然ミネラル鉄分主体の土壌改良剤は、前記土壌改良剤において、土壌改良剤1000リットル中、各成分の混合割合が、塩化マグネシウム約250kg、硫酸第一鉄約150kg、鉄ミョウバン約5kg、カリミョウバン約5kgであることを要旨とする。   In addition, the natural mineral iron-based soil improver according to the present invention is the above-mentioned soil improver, and the mixing ratio of each component in 1000 liters of the soil improver is about 250 kg of magnesium chloride, about 150 kg of ferrous sulfate, and iron alum. The summary is about 5 kg and about 5 kg of potash alum.

また、本考案に係る土壌改良剤を用いて作成する完熟堆肥・肥料は、牛糞、鶏糞、豚糞、魚粉、油粕、骨粉、おがくず、米ぬかの少なくとも2種以上をよく攪拌配合し、小高く積み上げ、これに前記土壌改良剤を200倍に希釈した溶液を材料がしっとりと湿る程度にかけ、ビニールを表面にかぶせ、時々切り替えしを行い、アンモニア臭がなくなるまで土壌改良剤の散布と切り返しを行い作成することを要旨とする。   In addition, ripe compost and fertilizer created using the soil conditioner according to the present invention is a mixture of cow dung, chicken dung, pig dung, fish meal, oil cake, bone meal, sawdust, rice bran, and rice bran. Then, apply a solution obtained by diluting the soil conditioner 200 times to the wetness of the material, cover the surface with vinyl, switch it from time to time, and spray and turn the soil conditioner until the ammonia odor disappears. The gist is to create it.

本考案は鉄・塩化マグネシウムを主成分とした液体であるため、液体そのものも濃度に関わらず無害であり、有機農法が維持でき、液状で二価の鉄を安定させたという理由で含鉄液体土壌改良資材としての保存性がある。特に本土壌改良剤は緑色の液体であり、これは二価鉄を安定して多く含むことを意味している。二価鉄は植物に直接作用し、吸収されるため、酸素と結合している三価鉄より好ましい。
また本考案の土壌改良剤は強酸性であるため(pH1.42)、農薬や化学肥料の多投でアルカリ性に傾いた土壌(約pH7.1〜)を中和し、適正値(約PH5.0〜7.5))に保つことが可能となる。さらに、成分中に植物に必要な微量元素であり、葉緑素の構成元素であるマグネシウムを有する。そのため、光合成を高め、生育を促進し、微生物の活性化を促進する。また、マグネシウムは酵素の活性化に重要な元素であり、かんがい水や雨水に溶けて流亡しやすいため、本考案による補給が土壌にとって効果的となる。その結果、収穫物の糖度・秀品率・日持ち等が大幅に向上し土壌を保肥力の高い団粒構造にする。さらに、本考案に含まれるミョウバンの作用により、防腐効果、殺菌効果があり、水質浄化作用もある。さらには、蓄舎、蓄糞尿布、厩肥舎など悪臭の発生する場所への散布により、消臭効果がある。本願考案は、土壌の改良のほかに消臭、防虫、ハエ、蛆の発生防止などの効果も備えているため、多用途に使用可能で非常に好ましい。また、塩類集積土壌における過剰な塩基を中和し土壌水中のpHを適正に保つことが可能となる。その結果土壌は、pH依存型の特定病原菌や病害虫の増加を抑え連作が可能となり好ましい。さらに、本考案により処理した種子は、発根量が増し、秀逸な作物が生産可能となる。
Since the present invention is a liquid mainly composed of iron / magnesium chloride, the liquid itself is harmless regardless of its concentration, it can maintain organic farming, and it contains liquid liquid soil because it has stabilized liquid and divalent iron. Preservability as improved material. In particular, the soil conditioner is a green liquid, which means that it contains a stable amount of divalent iron. Since divalent iron acts directly on plants and is absorbed, it is preferable to trivalent iron combined with oxygen.
Further, since the soil conditioner of the present invention is strongly acidic (pH 1.42), the soil (about pH 7.1) inclined to alkalinity by multiple throwing of agricultural chemicals and chemical fertilizers is neutralized to an appropriate value (about PH5. 0 to 7.5)). Furthermore, it is a trace element necessary for plants in the component, and has magnesium which is a constituent element of chlorophyll. Therefore, it enhances photosynthesis, promotes growth, and promotes activation of microorganisms. Magnesium is an important element for the activation of the enzyme, and since it dissolves easily in irrigation water and rainwater, the supplementation according to the present invention is effective for the soil. As a result, the sugar content, excellent product rate, shelf life, etc. of the harvest are greatly improved, and the soil is made into a nodule structure with high fertilizer. Furthermore, the alum contained in the present invention has antiseptic and sterilizing effects and water purification. Furthermore, it has a deodorizing effect by spraying it on places where bad odors are generated, such as storage houses, feces and urine cloths, and manure houses. In addition to improving the soil, the present invention has effects such as deodorization, insect repellent, flies, and prevention of wrinkles. Moreover, it becomes possible to neutralize the excess base in salt accumulation soil and maintain pH in soil water appropriately. As a result, the soil is preferable because it suppresses the increase of pH-dependent specific pathogens and pests and enables continuous cropping. Furthermore, the seeds treated according to the present invention have an increased rooting amount and can produce excellent crops.

本考案の土壌改良剤の蛍光X線法による成分分析結果を示した図である。It is the figure which showed the component analysis result by the fluorescent X ray method of the soil improvement agent of this invention. 本考案の土壌改良剤の蛍光X線法による成分分析結果を示した図である。It is the figure which showed the component analysis result by the fluorescent X ray method of the soil improvement agent of this invention. 本考案の土壌改良剤の蛍光X線法による成分分析結果を示した図である。It is the figure which showed the component analysis result by the fluorescent X ray method of the soil improvement agent of this invention. 本考案の土壌改良剤の蛍光X線法による成分分析結果を示した図である。It is the figure which showed the component analysis result by the fluorescent X ray method of the soil improvement agent of this invention. 本考案の土壌改良剤の蛍光X線法による成分分析結果を示した図である。It is the figure which showed the component analysis result by the fluorescent X ray method of the soil improvement agent of this invention. 本考案の土壌改良剤のX線回折法における分析結果を示した図である。It is the figure which showed the analysis result in the X-ray diffraction method of the soil improvement agent of this invention. 対照の塩化マグネシウムのX線回折法における分析結果を示した図である。It is the figure which showed the analysis result in the X-ray-diffraction method of control magnesium chloride. 本考案の土壌改良剤のイオンクロマト法における分析結果を示した図である。It is the figure which showed the analysis result in the ion chromatography method of the soil improvement agent of this invention. 本考案の土壌改良剤をハウス小ねぎ栽培に使用する前の図である。It is a figure before using the soil conditioner of this invention for house onion cultivation. 本考案の土壌改良剤をハウス小ねぎ栽培に使用した結果を示した図である。It is the figure which showed the result of using the soil improvement agent of this invention for house onion cultivation. 本考案の土壌改良剤をアスパラ栽培に使用した結果を示した図面である。It is drawing which showed the result of using the soil improvement agent of this invention for asparagus cultivation. 本考案の土壌改良剤をりんご栽培に使用した結果を示した図である。It is the figure which showed the result of using the soil improvement agent of this invention for apple cultivation. 本考案の土壌改良剤をイチゴ栽培に使用した結果を示した図面である。It is drawing which showed the result of using the soil improvement agent of this invention for strawberry cultivation.

本考案は液体であり、塩化マグネシウムに硫酸アルミニウムカリウム(ミョウバン)と鉄ミョウバン、硫酸第一鉄を混合して作られる。混合割合は、以下に示す。
本考案の液体約(原料の比重が水より重いためと製造中に蒸発する水の量が多いため)1000リットル製造に必要な原料は以下の通りである。
鉄ミョウバン 約5kg
カリミョウバン 約5kg
硫酸第一鉄 約150kg
塩化マグネシウム 約250kg
水分 590kg
これらの成分はそれぞれ、鉄分として、硫酸第一鉄、鉄ミョウバンを使用し、カリミョウバンにより防腐効果、殺菌効果、水質浄化作用、アンモニア臭の中和分解、防虫効果、消臭作用、細胞の引き締めと水揚げを良くする効果を得、マグネシウムにより微生物の活性化と光合成の活発化の作用を示す。
The present invention is liquid and is made by mixing magnesium chloride with potassium aluminum sulfate (alum), iron alum, and ferrous sulfate. The mixing ratio is shown below.
About the liquid of the present invention (because the specific gravity of the raw material is heavier than that of water and the amount of water that evaporates during production is large), the raw materials necessary for 1000 liter production are as follows.
Iron alum about 5kg
Potash alum about 5kg
About 150kg ferrous sulfate
About 250kg of magnesium chloride
590kg moisture
Each of these ingredients uses ferrous sulfate and iron alum as iron, and with potash alum, antiseptic effect, bactericidal effect, water purification effect, neutralization decomposition of ammonia odor, insect repellent effect, deodorant effect, cell tightening The effect of improving the landing is obtained, and the activation of microorganisms and the activation of photosynthesis are shown by magnesium.

この混合割合が最適であるが、その理由としては、カリミョウバンがこれ以上少なすぎると硫酸第一鉄がうまく安定しない。また、2種類のミョウバンを用いた理由としては、まず、鉄ミョウバンを使用した理由としては、本考案の主な成分を鉄分にするため、硫酸第一鉄を利用するとともに鉄ミョウバンを使用した。硫酸第一鉄とカリミョウバンだけでは鉄分が少なく、さらに本考案の液体が酸化しやすいと考え、化合物である鉄ミョウバンを加えた。硫酸第1鉄については、以前より含鉄土壌改良剤として利用されていることと、植物にとって非常に重要な要素であるという点を、マグネシウムと組み合わせることによりさらに改良し、開発したものである。 This mixing ratio is optimal because, if the amount of potassium alum is too small, ferrous sulfate is not well stabilized. Moreover, as a reason for using two types of alum, first of all, as a reason for using iron alum, ferrous sulfate was used and iron alum was used in order to make the main component of the present invention iron. We thought that ferrous sulfate and potassium alum alone had less iron, and that the liquid of the present invention was likely to oxidize, so we added the compound iron alum. About ferrous sulfate, it has been further improved by combining magnesium with the fact that it has been used as an iron-containing soil improver and is a very important factor for plants.

本土壌改良資材は鉄分として硫酸第一鉄を主体として使用している。硫酸第一鉄は粉末状で薄い緑色をしている。硫酸第一鉄は、粉末状では酸素と結合しにくい(していない)二価の状態で安定している。しかし、この硫酸第一鉄を水に溶かしこむと、水中の酸素と結合して、三価の鉄に変化する(酸化する)。このような状態となると、硫酸第一鉄を溶かし込んだ溶液はすぐに鉄錆色に変化する。こうなると植物に吸収されない三価の(酸化鉄)状態となり、さらには資材としての利便性や保存性にも課題が残される。本土壌改良資材はこのような問題点を解決するものである。現在までの技術では、二価の鉄を液状で安定させるということは非常に困難とされてきた。しかし本土壌改良資材では、ミョウバンを用いることにより二価鉄の状態で安定させることが可能となる。
その根拠として、本土壌改良資材は緑色透明である。この緑色は硫酸第一鉄の緑色であり、上記の説明の通り酸素と結合してないため二価の状態(緑色)で安定しているということが言える。硫酸鉄は強い酸性(pH3以下)でよく安定する。この特性に注目し、副原料としてミョウバンを選択した。ミョウバンは水に溶かし込むと強酸性に変化する。製造段階でミョウバンを溶かし込んだ液体に硫酸第一鉄を加えることにより、液体状でも硫酸鉄は二価の状態を保ち緑色を呈している。
また、本考案の300倍希釈液を使用して種子処理も可能であり、種子の大きさによって4分〜10分間溶液に漬し、その後陰干しする。本考案の原料である硫酸第一鉄、鉄ミョウバンにより種子がコートされ帯電作用を有することにより、発芽発根を促進させる。これにより様々な病害を寄せ付けない健全な苗を作ることが可能となる。
This soil improvement material mainly uses ferrous sulfate as iron. Ferrous sulfate is powdery and light green. Ferrous sulfate is stable in a divalent state in which it is difficult (but not bonded) to oxygen in a powder form. However, when this ferrous sulfate is dissolved in water, it is combined with oxygen in the water and converted into trivalent iron (oxidized). In such a state, the solution in which ferrous sulfate is dissolved immediately changes to an iron rust color. If it becomes like this, it will be in the trivalent (iron oxide) state which is not absorbed by a plant, and also the subject also remains in the convenience and preservation nature as a material. This soil improvement material solves such problems. Until now, it has been very difficult to stabilize divalent iron in a liquid state. However, this soil improvement material can be stabilized in the state of divalent iron by using alum.
As a basis for this, the soil improvement material is transparent in green. This green color is the color of ferrous sulfate, and since it is not bonded to oxygen as described above, it can be said that it is stable in a divalent state (green). Iron sulfate is highly acidic (pH 3 or less) and well stabilized. Focusing on this characteristic, alum was selected as an auxiliary material. Alum changes to strong acidity when dissolved in water. By adding ferrous sulfate to the liquid in which alum is dissolved in the manufacturing stage, iron sulfate remains divalent and exhibits a green color even in liquid form.
In addition, seed treatment using the 300-fold diluted solution of the present invention is also possible, soaking in the solution for 4 to 10 minutes depending on the size of the seed, followed by drying in the shade. Germination rooting is promoted by coating the seeds with ferrous sulfate and iron alum which are raw materials of the present invention and having a charging effect. This makes it possible to produce healthy seedlings that are free from various diseases.

本考案の土壌改良剤は使用にあたっては100倍〜1000倍に希釈して用いる。
なお、本考案の土壌改良剤における成分分析を蛍光X線法で行った結果を図1から5に示す。この結果から、成分中には、イオウ、塩素、カリウム、カルシウム、チタニウム、マンガン、鉄、亜鉛、ストロンチウム、窒素、臭素が含まれていることがわかる。また、X線回折法によると、主成分と思われる塩化マグネシウムを検出できた(図6・7)。さらに、イオンクロマト法においては、塩素とSO4とが検出されている(図8)、他の主成分は硫酸第一鉄である。これらの成分により、防腐効果、殺菌効果、水質浄化作用、アンモニア臭の中和消臭効果(カリミョウバンに由来)がみとめられ、光合成を行う葉緑素の元になる(マグネシウムに由来)。
In use, the soil conditioner of the present invention is diluted 100 to 1000 times.
In addition, the result of having performed the component analysis in the soil improvement agent of this invention by the fluorescent X ray method is shown to FIGS. From this result, it can be seen that the component contains sulfur, chlorine, potassium, calcium, titanium, manganese, iron, zinc, strontium, nitrogen and bromine. Moreover, according to the X-ray diffraction method, magnesium chloride which seems to be a main component was detected (FIGS. 6 and 7). Furthermore, in ion chromatography, chlorine and SO4 are detected (FIG. 8), and the other main component is ferrous sulfate. By these components, antiseptic effect, bactericidal effect, water purification effect, neutralization deodorization effect of ammonia odor (derived from Potash alum) is found, and it becomes a source of chlorophyll for photosynthesis (derived from magnesium).

本実施例においては、水田を改良する場合について説明する。乾田に動力散布機などで100倍希釈溶液を散布した後、水を張る。水が張れたらロータリーにて十分攪拌する。この際に土壌中の余分な塩類等が溶け出し泡と一緒に水面に現れる。この泡は余分な塩基などが付着しているため、水田外に排出した方が良い。この際、全ての水を水田外に排出する。水が全量排出できたら、水田を3〜4日間干す。この作業を行わないと、土表面が柔らかくなりすぎて田植えができない可能性がある。
このような処理を行った水田は、根張りもよく、強風による倒伏を防ぐ。本土壌改良剤に含まれる塩素が窒素の過剰吸収を抑え、マグネシウム、カルシウム、カリ、ケイ酸などの吸収をたすけるため稔実が良くなる。
In the present embodiment, a case where paddy fields are improved will be described. After spraying a 100-fold diluted solution on a dry paddy with a power spreader, etc., add water. When the water is filled, stir well in the rotary. At this time, excess salts in the soil melt and appear on the water surface along with the bubbles. Since this foam has extra base attached to it, it is better to discharge it outside the paddy field. At this time, all water is discharged outside the paddy field. When all the water has been drained, dry the paddy field for 3-4 days. If this is not done, the soil surface may become too soft to plant rice.
Paddy fields that have undergone such treatment have good rooting and prevent lodging due to strong winds. Chlorine contained in the soil conditioner suppresses excessive absorption of nitrogen and absorbs magnesium, calcium, potash, silicic acid, and so on, resulting in better fruit.

次に、本考案を使用して、完熟堆肥の作成方法を説明する。
原料として、牛糞、鶏糞、豚糞などの動物糞尿のほかに、副資材として魚粉、油粕、骨粉、おがくずなどが使用可能である。牛糞はおがくず混入のものでもワラ混入のものでも良い。牛糞をメインにするときには牛糞10:鶏糞又は豚糞3の割りあいで配合すれば、分解促進や栄養バランスの安定になる。それらの材料をよく攪拌し、小高く積み上げる(1m以内)。本考案の土壌改良剤を200倍(pH6.5〜7に調整)に希釈した溶液を作成し、その積み上げた材料にしっとり湿る程度までたっぷりとかける。それにより、材料が黒く変色し、アンモニア臭が消える。最後に材料の上からビニールを被せ、雨に打たれるのを防ぐ。時々切り替えしを行う。2回目の切り替えしから、用途に応じて油粕、魚粉、米糠等をまぜると良い。切り替えしの度に本考案の土壌改良剤を散布すると熟成が早まりバランスの良い、優れた堆肥が出来る。アンモニア臭が消えたら「ガス障害」すなわち、有機物が微生物により分解される際にアンモニアガスの発生が抑制される。このアンモニアガスは様々な病気の原因になり、本考案の土壌改良剤の原料のひとつである、ミョウバンはアンモニア中和分解作用があるため、有機物の分解時に発生するアンモニアを中和し、使用段階でガス障害などが発生しない安全で高級な堆肥の出来上がりとなる。
また、本考案を使用して、完熟有機肥料の作成方法を説明する。
他からの水分が入ってこないように周りより高くした土の上で鶏糞、魚粉、油粕、米ぬかこれらの材料を全て同割合で混ぜ合わせる。よく混ざったら、その上から土壌改良剤を200倍に希釈したものをしっとりぬれる程度に散布する。1年に4回から5回、切り替えしを行うが、その度に本考案の土壌改良剤を200倍に希釈したものを散布する。常に水分がある状態に保ち、乾燥させないことが重要である。乾燥すると途中で分解が止まってしまう。逆に水分が多すぎても腐る。従って、材料を強く握り締めた場合に、水が垂れない程度が目安となる。肥料の臭いをかいでみて土の臭いがすれば出来上がりである。なお、出来上がり以前の強制乾燥処理はガス障害を引き起こす肥料となるため、行ってはならない。アンモニア臭が残っている間は完成していない。
使用方法としては肥料の製造段階で土壌改良剤を「肥料を作るための材料」として使用する。すなわち、本考案の土壌改良資材を利用して高級な肥料をつくり、さらにそれを施す土壌をも本考案の土壌改良資材で改善しておくと申し分ない。
肥料を施しても土壌改良資材は使用する。特にボカシ肥料などは土に施肥してから微生物の分解力を借り、植物に利用されやすい形になる。
この際には必ずガスが発生し、植物に抵抗力がない場合(幼少時や病気時)には根が焼けたり窒素が根あたりしたりと様々な弊害が発生する。しかし、ぼかし肥料(有機発酵肥料)などを施肥した後本考案の土壌改良剤希釈液で土壌ごと処理しておけば、土壌のpHを適正(6.5前後)に保ち、同時にぼかし肥料の急激な分解を防ぎます。粗大有機物(ボカシ肥料)を分解するのが得意な糸状菌は高pH下(7〜8.5付近)で盛んに活動します。土壌のpHを6.5前後に保っていれば分解型糸状菌の爆発的増殖を防ぐためボカシ肥料の分解も穏やかに進みます。ガスの発生はぼかし肥料の分解具合に比例するので、一度に大量のガスが発生し根に障害を与えることはありません。
上記のようなことから有機質肥料をいれるのであれば、先に有機質肥料を入れてから本考案の土壌改良剤処理を行うのが望ましい。
Next, a method for creating a fully-ripened compost using the present invention will be described.
In addition to animal dung such as cow dung, chicken dung, and pig dung as raw materials, fish meal, oil cake, bone meal, sawdust, etc. can be used as auxiliary materials. The cow dung may contain sawdust or straw. When the cow dung is used as the main ingredient, the decomposition of the cow dung 10: chicken dung or pig dung 3 is compounded to promote decomposition and stabilize the nutritional balance. Stir the materials well and stack them up slightly (within 1m). A solution obtained by diluting the soil conditioner of the present invention 200 times (adjusted to pH 6.5 to 7) is prepared, and it is applied to the piled material until it is moistened. As a result, the material turns black and the ammonia odor disappears. Finally, cover the material with vinyl to prevent it from being struck by rain. Switch from time to time. From the second switching, it is better to mix oil cake, fish meal, rice bran, etc. according to the application. When the soil conditioner of the present invention is sprayed every time it is switched, ripening is accelerated and a well-balanced and excellent compost can be made. When the ammonia odor disappears, “gas failure”, that is, generation of ammonia gas when organic matter is decomposed by microorganisms is suppressed. This ammonia gas causes various diseases, and alum, one of the raw materials for the soil conditioner of the present invention, has an ammonia neutralizing and decomposing action. The result is a safe and high-grade compost that does not cause gas damage.
Moreover, the preparation method of a fully-ripened organic fertilizer is demonstrated using this invention.
Mix chicken dung, fish meal, rice bran, and rice bran in the same proportions on the soil that is higher than the surroundings so that moisture from other sources does not enter. When mixed well, apply a 200-fold diluted soil conditioner so that it is moistened. Switching from 4 to 5 times a year, each time spraying a 200-fold diluted soil improver of the present invention. It is important to always keep moisture and not let it dry. Decomposition stops in the middle of drying. On the contrary, it will rot even if there is too much moisture. Therefore, the extent to which water does not drip when the material is squeezed is a standard. If you smell the soil after smelling the fertilizer, you're done. In addition, forced drying before completion is a fertilizer that causes gas damage and should not be performed. While ammonia odor remains, it is not completed.
As a method of use, a soil conditioner is used as a “material for making fertilizer” in the fertilizer manufacturing stage. That is, it is satisfactory to make high-grade fertilizer using the soil improvement material of the present invention and to improve the soil to which it is applied with the soil improvement material of the present invention.
Even if fertilizer is applied, soil improvement materials are used. Bokashi fertilizers, in particular, tend to be used by plants after fertilizing the soil and borrowing the ability to decompose microorganisms.
At this time, gas is always generated, and when the plant is not resistant (when it is young or sick), various harmful effects occur, such as burning roots or rooting nitrogen. However, if the soil is treated with the soil amendment agent dilution solution of the present invention after fertilizing with a blur fertilizer (organic fertilizer fertilizer) etc., the soil pH will be kept appropriate (around 6.5), and at the same time, the rapid degradation of the blur fertilizer To prevent. Filamentous fungi that are good at degrading coarse organic matter (bokashi fertilizer) are active at high pH (around 7 to 8.5). If the pH of the soil is maintained at around 6.5, the decomposition of Bokashi fertilizer will proceed gently to prevent the explosive growth of degradable filamentous fungi. Since the generation of gas is proportional to the degree of degradation of the blur fertilizer, a large amount of gas is generated at one time and does not damage the roots.
If organic fertilizer is added from the above, it is desirable to add the organic fertilizer first and then perform the soil improver treatment of the present invention.

本考案を畑地に使用した場合について説明する。
小ねぎ栽培ハウスに本考案の土壌改良剤を使用する場合について説明する。播種1週間ほど前に、まず200倍に希釈したものを散布する。なお、このとき、土壌改良剤の散布の偏りを無くすため、降雨中に行うか、ひと雨きそうな直前に散布するようにすると良い。
このような処理を行った畑地では、夏場の発芽が3〜4日は早くなり(従来は7日〜8日)、発芽も揃い、葉先の枯れが減少し、消毒の回数も激減する。これは本土壌改良資材が土壌の状態を大幅に改善した事で、植物が活性化し病気や虫を寄せ付けない、いっそう秀逸な小ネギが省力で収穫できたものと考えられる。
The case where this invention is used for a field is demonstrated.
The case where the soil improvement agent of this invention is used for a small onion cultivation house is demonstrated. About one week before sowing, a 200-fold diluted one is first sprayed. At this time, in order to eliminate uneven application of the soil conditioner, it may be performed during the rain or just before it seems to rain.
In the field where such treatment is performed, germination in summer is accelerated 3 to 4 days (previously 7 to 8 days), germination is complete, leaf tip wilt is reduced, and the number of disinfections is drastically reduced. This is because this soil improvement material greatly improved the condition of the soil, and it was thought that more excellent small spring onions that activated the plant and kept away diseases and insects could be harvested with labor saving.

さらに、本考案の施設園芸(グリーンアスパラガス)での使用実施例を説明する。
アスパラガスの栽培(ビニールハウス)に本考案の土壌改良剤を使用する場合について説明する。作付け時1週間ほど前にまず200倍に希釈したものを散布する。そして作付け後も4日〜7日間隔(作物の生育具合を見ながら変更可能)1000倍に希釈したものを植物体にかからないように谷間灌水もしくは灌注機にて灌注をおこなう。このような処理を行った施設園芸圃場は従来よりいっそう秀逸なアスパラガスが収穫できた(図11)。たとえば、外見は鮮やかな黄緑色で、曲がりがほとんどなく秀品率は大幅に増加し根元まで完全にやわらかい。慣行栽培アスパラガス特有のにおい・えぐみもなく、さっと水洗いして根元まで生食できるほどである。慣行栽培における収穫後のアスパラガス株の切り口は腐っていたが本考案の土壌改良剤を使用して栽培すると収穫後の切り口は腐らない。慣行栽培法での夏期アスパラガスの先端は開き気味になり、商品価値は下がる。アスパラガスは展開していく茎を食用とするため、穂先が早く開くような栽培法は都合が悪い。しかし、本土壌改良資材を使用して栽培すると、この夏季のアスパラガス先端の開きが発生しないため商品価値は春物、秋物と大差なく安定した品質のものを継続して収穫できる。窒素過多や軟弱体のものは早く枝を出し葉を繁らせようとする(徒長状態という)。しかし、本土壌改良資材で土の状態を大幅に改善することにより、植物が本来もつ性質を最大限に高め、植物本位の生長を促し、欲しいときに欲しい栄養を植物が自ら取捨選択できるため、軟弱体や窒素過多などの状態に陥らない。このとき、pHを測定したら、当初pH7.5のアルカリ性に傾いた土壌が、本考案の土壌改良剤を使用することでpH6.2となっていた。
Furthermore, the use Example in the facility gardening (green asparagus) of this invention is demonstrated.
The case where the soil improvement agent of this invention is used for cultivation (plastic greenhouse) of asparagus is demonstrated. Disperse 200 times diluted one week before planting. And even after planting, irrigation is performed with a valley irrigation or irrigator so as not to cover the plant body with a 1000-fold dilution (can be changed while observing the growth of the crop). The facility horticulture field which performed such a process was able to harvest the more excellent asparagus than before (FIG. 11). For example, the appearance is bright yellow-green, there is almost no bend, the excellence rate is greatly increased, and the base is completely soft. There is no smell and peculiar peculiarity to conventional cultivation asparagus, and it can be washed quickly with water and eaten to the root. The cut of the asparagus strain after harvest in conventional cultivation was rotten, but the crop after harvest was not rotted when cultivated using the soil conditioner of the present invention. The tip of summer asparagus in the conventional cultivation method becomes open and the value of the product decreases. Asparagus uses edible stems for food, so a cultivation method that opens the ears early is not convenient. However, when grown using this soil amendment material, the opening of the asparagus tip does not occur in this summer, so that the product value can be continuously harvested with stable quality without much difference between spring and autumn. Excessive nitrogen and weak ones tend to branch out quickly and let the leaves grow (referred to as chief state). However, by greatly improving the soil condition with this soil improvement material, the nature of the plant is maximized, the growth of the plant is promoted, and the plant can select the nutrition it wants when it wants, Does not fall into a state of weak body or excessive nitrogen. At this time, when the pH was measured, the initially inclined soil of pH 7.5 was pH 6.2 by using the soil improver of the present invention.

本考案の土壌改良剤をりんご栽培に使用した例を説明する。上記実施例4と同様に作付け時(作付け後からでもかまわない)に散布し、以後実施例4の方法で主幹部分の下部から根張り部分土壌に散布する。さらに月1回の割りあいで土壌に散布すると、軟弱果や低糖果を防ぐ。このような方法で栽培したりんごと使用していないりんごの日持ち実験を行った。日向に同時に置いて経時変化を観察した。60日経過後、図12に示すように土壌改良剤を使用して栽培したりんごは新鮮さが持続し(左側)、全くしわだらけに変化したりんご(右側)と対比して対照的な結果となった。この理由は、本考案の原料であるマグネシウムやミョウバンが土壌を活性化しその結果としてりんごの細胞を強化し保水力を高め、同時に細胞の免疫力も高くなるからと思われる。 The example which used the soil improvement agent of this invention for apple cultivation is demonstrated. It spreads at the time of planting (it does not matter even if it is after planting) similarly to the said Example 4, and is sprayed by the method of Example 4 from the lower part of a main trunk part to rooting partial soil after that. In addition, spraying the soil once a month will prevent soft and low-fruited fruits. Experiments were carried out to keep apples that were not used with apples grown in this way. The changes over time were observed by placing them simultaneously in the sun. After 60 days, as shown in FIG. 12, apples cultivated using a soil amendment maintain their freshness (left side), which is in contrast to apples that changed completely wrinkled (right side). It was. The reason for this seems to be that magnesium and alum, which are the raw materials of the present invention, activate the soil and as a result strengthen the cells of apples and increase the water retention, and at the same time increase the immunity of the cells.

本実施例では、ハウスによるイチゴ栽培について説明する。ある地域で毎年炭そ病や軟弱果に悩ませられている圃場の土壌を本考案の土壌改良剤で改良し、イチゴを栽培した。定植約1週間前に本土壌改良剤200倍液を散布する。さらにマルチングを行った後に潅水チューブより週に1回のペースで1000倍液を施用した。前年は定植から2ヶ月間ほどで3000本から4000本の数のイチゴの苗が病気で枯れたが、本考案の土壌改良剤を使用して土壌改良を行ったら2ヶ月間で200本から300本でおさまった。これは、本考案の土壌改良剤が土壌のpHを適正値に維持し、悪性の糸状菌や細菌などの活性を抑えるとともに、植物体内での窒素の代謝を促したことに起因すると考えられる。さらに塩化マグネシウム中に含まれる塩素が窒素の過剰吸収を抑え、病気に対する抵抗性を増大していると考えられる。
その結果図13に示すように、定植4〜7日ほどで、株元を揺すってもビクともしないほどの根張りを実現するとともに、新葉や花芽の展開は著しく改善し素晴らしい植物生理活性効果と成長促進効果が認められた。
In this embodiment, strawberry cultivation by a house will be described. The soil in the field, which is plagued by anthracnose and soft fruit every year in a certain area, was improved with the soil conditioner of the present invention, and strawberries were grown. Apply this soil conditioner 200 times solution about 1 week before planting. After further mulching, the 1000-fold solution was applied once a week from the irrigation tube. In the previous year, about 3000 to 4000 strawberry seedlings died of disease in about 2 months from planting, but if soil improvement was performed using the soil conditioner of the present invention, 200 to 300 in 2 months It ’s a book. This is considered to be because the soil conditioner of the present invention maintains the pH of the soil at an appropriate value, suppresses the activities of malignant filamentous fungi and bacteria, and promotes the metabolism of nitrogen in the plant body. Furthermore, it is considered that the chlorine contained in the magnesium chloride suppresses excessive absorption of nitrogen and increases resistance to diseases.
As a result, as shown in FIG. 13, the planting is about 4-7 days, and even if the plant is shaken, the rooting that does not become victorious is realized, and the development of new leaves and flower buds is remarkably improved, and a wonderful plant physiological activity effect And the growth promotion effect was recognized.

本実施例では、本考案溶液による種子の処理方法について各種の種子ごとに説明する。
1)種子が大きい場合 (かぼちゃ、とうもろこし等)
300倍希釈溶液(農業用水を用いる)に10分間、溶液に浸す。その後陰干しする。
2)種子が小さい場合 (キャベツ、ごま等)
種子が小さいため、まず種子を布袋に入れ、300倍希釈溶液(農業用水を用いる)に4〜5分間、強制的に沈める。その後布袋から取り出し、陰干しする。
3)穀物類(麦、米等)
300倍希釈溶液(農業用水を用いる)を作り、中に処理したい穀物をそのまま入れる。よくかき混ぜた後、水が落ち着くのを待つ。希釈溶液を入れた容器の下部に沈んだ種子だけを使用する。水面に浮いたものや中間部に浮いているものは発芽しないか、発芽しても生育が悪いためである。この作業を7〜8分程度で行う。希釈溶液の入った容器の下部に沈んだ種子だけを取り出し、陰干しする。
4)コート種子の場合
育苗ポットに通常の方法で播種する。上から水を掛ける代わりに300倍希釈溶液(農業用水を用いる)の入った容器に浸す。このとき、しばらく浸し、ポットの土表面まで水分が上がっていることを確認する。その後の管理は通常通りでかまわない。
以上のようにして、本考案の土壌改良剤を用いて種子処理を行うと、発根量が増し、秀逸な作物が生産可能となる。その原因としては、原料である硫酸第一鉄、鉄ミョウバンが種子に鉄の皮膜を形成し、土中に流れる電流を通し易くなったためと考えられる。さらには、原料であるカリミョウバンに由来するアンモニア中和作用により、種子自体が養分として過剰な窒素を吸収せずに済む。これにより様々な病害を寄せ付けない健全な苗が生産できる。
In the present embodiment, a seed treatment method using the inventive solution will be described for each type of seed.
1) When the seeds are large (pumpkin, corn, etc.)
Immerse in 300-fold diluted solution (using agricultural water) for 10 minutes. Then dry in the shade.
2) When the seeds are small (cabbage, sesame, etc.)
Since the seeds are small, the seeds are first put in a cloth bag and forcibly submerged in a 300-fold diluted solution (using agricultural water) for 4-5 minutes. Then remove from the cloth bag and dry in the shade.
3) Cereals (wheat, rice, etc.)
Make a 300-fold diluted solution (using agricultural water), and put the grain you want to process in it. After stirring well, wait for the water to settle down. Use only the seeds that sink to the bottom of the container containing the diluted solution. This is because those floating on the surface of the water and those floating in the middle do not germinate, or even if they germinate, they do not grow well. This operation is performed in about 7 to 8 minutes. Remove only the seeds that sink to the bottom of the container containing the diluted solution and dry in the shade.
4) In the case of coated seeds Seed seedling pots in the usual way. Instead of sprinkling water from above, immerse it in a container containing a 300-fold diluted solution (use agricultural water). At this time, it is soaked for a while and it is confirmed that the moisture has risen to the soil surface of the pot. Subsequent management may be as usual.
As described above, when seed treatment is performed using the soil conditioner of the present invention, the amount of rooting is increased and an excellent crop can be produced. The cause is considered to be that ferrous sulfate and iron alum, which are raw materials, formed an iron film on the seeds, making it easier to pass the current flowing in the soil. Furthermore, the seed itself does not need to absorb excess nitrogen as a nutrient due to the ammonia neutralization effect derived from the raw material, Kali alum. This makes it possible to produce healthy seedlings that are free from various diseases.

本実施例では、本考案の消臭方法について具体的に説明する。
厩舎や堆肥センター、処理槽などの悪臭が発生する場所に本考案の土壌改良資材を100倍に希釈したものを満遍なく散布する。すると間もなく悪臭が消える。これは本考案の土壌改良剤の原料であるミョウバンのアンモニア中和分解作用に由来するところが大きい。本考案の土壌改良剤を100倍に希釈した場合(希釈用の水がpH7.5の場合)pHが4.5〜5前後となり、この希釈液を堆肥や厩肥などにかけることにより粗大有機物分解型の糸状菌(好気的)の増殖が抑えられるため、分解は穏やかに進む。ガスの発生量は有機物の分解速度に比例するため、急激な分解による異臭や悪臭の発生を最小限に抑えることとなる。
In this embodiment, the deodorizing method of the present invention will be specifically described.
Disperse 100-fold diluted soil improvement material of the present invention evenly in places where bad odors such as stables, compost centers and treatment tanks are generated. The odor will soon disappear. This is largely due to the neutralization and decomposition of alum, which is a raw material for the soil conditioner of the present invention. When the soil conditioner of the present invention is diluted 100 times (when the water for dilution is pH 7.5), the pH becomes around 4.5 to 5, and this diluted solution is applied to compost, manure, etc. Degradation proceeds gently because the growth of filamentous fungi (aerobic) is suppressed. Since the amount of gas generated is proportional to the decomposition rate of organic matter, generation of off-flavors and odors due to rapid decomposition is minimized.

本実施例では、本考案の防虫方法について具体的に説明する。
厩舎や堆肥センターなど、ウジ虫やハエが発生する場所に本考案の土壌改良剤を100倍に希釈したものを満遍なく散布する。
本考案の土壌改良資材の原料であるミョウバンがアンモニアを中和分解するので、アンモニア臭に寄ってきていたハエの飛来を最小限に抑えることができる。
よって家畜糞尿などに飛来し産卵するハエなども比例して減少することになる。
In this embodiment, the insect-control method of the present invention will be specifically described.
Disperse the soil amendment of the present invention 100 times evenly in places where maggots and flies occur, such as stables and compost centers.
Since alum, which is a raw material for the soil improvement material of the present invention, neutralizes and decomposes ammonia, it is possible to minimize the flying of flies that have come close to the ammonia odor.
Therefore, the number of flies that fly into the livestock manure and lay eggs will also decrease in proportion.

本考案の土壌改良剤は、畑地、果樹など全てに対応可能で、簡便に良質な土壌への改良が可能となるため、産業上の利用可能性を有する。   The soil conditioner of the present invention can be applied to all fields, fruit trees, and the like, and can be easily improved into high-quality soil, and thus has industrial applicability.

Claims (3)

主成分が塩化マグネシウムおよび硫酸第一鉄であり、鉄ミョウバン及びカリミョウバンを加えてなる天然ミネラル鉄分主体の土壌改良剤。   A soil improver composed mainly of natural mineral iron, the main ingredients of which are magnesium chloride and ferrous sulfate, and iron alum and potash alum are added. 請求項1に記載の土壌改良剤において、該土壌改良剤1000リットル中、各成分の混合割合が、塩化マグネシウム約250kg、硫酸第一鉄約150kg、鉄ミョウバン約5kg、カリミョウバン約5kgであることを特徴とする土壌改良剤。   The soil improver according to claim 1, wherein the mixing ratio of each component in 1000 liters of the soil improver is about 250 kg of magnesium chloride, about 150 kg of ferrous sulfate, about 5 kg of iron alum, and about 5 kg of potash alum. A soil conditioner characterized by 牛糞、鶏糞、豚糞、魚粉、油粕、骨粉、おがくず、米ぬかの少なくとも2種以上をよく攪拌配合し、小高く積み上げ、これに請求項1又は2記載の本考案の土壌改良剤を200倍に希釈した溶液を材料がしっとりと湿る程度にかけ、ビニールを表面にかぶせ、時々切り替えしを行い、アンモニア臭がなくなるまで土壌改良剤の散布と切り返しを行い作成することを特徴とする完熟堆肥・肥料。   At least two kinds of cow dung, chicken dung, pork dung, fish meal, oil cake, bone meal, sawdust, and rice bran are mixed and mixed well, and they are piled up slightly, and the soil conditioner of the present invention according to claim 1 or 2 is increased by 200 times. Ripe compost and fertilizer characterized by applying the diluted solution to moisturize the material, covering the surface with vinyl, switching from time to time, spraying and turning over the soil conditioner until ammonia odor disappears .
JP2010004070U 2010-06-15 2010-06-15 Natural mineral iron-based soil conditioner Expired - Fee Related JP3163227U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114907863A (en) * 2022-06-29 2022-08-16 中国农业科学院烟草研究所 Chlorine-control soil conditioner special for tobacco and preparation method and application thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114907863A (en) * 2022-06-29 2022-08-16 中国农业科学院烟草研究所 Chlorine-control soil conditioner special for tobacco and preparation method and application thereof

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