JP3150779B2 - Neutral detergent - Google Patents
Neutral detergentInfo
- Publication number
- JP3150779B2 JP3150779B2 JP25202392A JP25202392A JP3150779B2 JP 3150779 B2 JP3150779 B2 JP 3150779B2 JP 25202392 A JP25202392 A JP 25202392A JP 25202392 A JP25202392 A JP 25202392A JP 3150779 B2 JP3150779 B2 JP 3150779B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- degreasing
- cleaning
- acid
- amount
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Description
【０００１】[0001]
【産業上の利用分野】本発明は、金属、セラミックス、
ガラス、プラスチック等の脱脂洗浄に用いる水系の洗浄
剤に関するものである。The present invention relates to metal, ceramics,
The present invention relates to an aqueous cleaning agent used for degreasing cleaning of glass, plastic, and the like.
【０００２】[0002]
【従来の技術】従来、金属、セラミックス、ガラス、プ
ラスチック等の工業用の脱脂洗浄剤としては、アルカリ
洗浄剤を代表とする水系洗浄剤、および１、１、１−ト
リクロロエタンを代表とする溶剤系洗浄剤が用いられて
いる。アルカリ洗浄剤は、ポリオキシエチレンアルキル
フェニルエーテルを代表とする非イオン界面活性剤、ア
ルキルベンゼンスルホン酸ナトリウムを代表とするアニ
オン界面活性剤等の界面活性剤、炭酸ナトリウム、ケイ
酸ナトリウム、ホウ酸ナトリウム、リン酸ナトリウム、
水酸化ナトリウム、水酸化カリウム等のアルカリ塩、ト
リポリリン酸ナトリウム、ＥＤＴＡ、ＮＴＡ、グルコン
酸塩等のキレート剤、ベンゾトリアゾール、アミン類、
アルカノールアミン類、亜硝酸ナトリウム等の防錆剤等
を適宜配合したものである。その配合組成は、たとえ
ば、辻薦著「精密洗浄技術」工学図書ｐ１１７−１２
０、辻薦編著「精密洗浄技術マニュアル」新技術開発セ
ンターｐ５０−５６に記載されているように、洗浄する
物品、金属、汚れに応じて種々のものが提案されてい
る。しかし、脱脂力、浸透力は、１、１、１−トリクロ
ロエタン等の塩素系溶剤に比べて劣るため、実際の適用
分野としては、簡単な構造を有する物品の洗浄や洗浄後
の残存油分量をあまり気にしない分野が主体である。2. Description of the Related Art Conventionally, as industrial degreasing agents for metals, ceramics, glass, plastics, etc., aqueous detergents represented by alkali detergents and solvent detergents represented by 1,1,1-trichloroethane have been used. Cleaning agents are used. Alkaline detergents, non-ionic surfactants represented by polyoxyethylene alkyl phenyl ether, surfactants such as anionic surfactants represented by sodium alkylbenzene sulfonate, sodium carbonate, sodium silicate, sodium borate, Sodium phosphate,
Sodium hydroxide, alkali salts such as potassium hydroxide, sodium tripolyphosphate, EDTA, NTA, chelating agents such as gluconate, benzotriazole, amines,
It contains alkanolamines, rust preventives such as sodium nitrite and the like as appropriate. Its composition is described, for example, in "Precision Cleaning Technology" by Kotsuji Engineering, p. 117-12.
As described in "Precision Cleaning Technology Manual", New Technology Development Center, p. However, since the degreasing power and the osmotic power are inferior to chlorine solvents such as 1,1,1-trichloroethane and the like, as an actual field of application, the cleaning of articles having a simple structure and the amount of residual oil after cleaning are required. Mainly in fields that do not care much.
【０００３】一方、１、１、１−トリクロロエタン等の
塩素系溶剤は、脱脂力、浸透力に優れ、切削油、引き抜
き油、プレス油等あらゆる脱脂に適用でき、主として、
複雑な構造を有する物品や、高い清浄度を要求する精密
部品の洗浄分野で用いられている。On the other hand, chlorinated solvents such as 1,1,1-trichloroethane have excellent degreasing power and penetrating power, and can be applied to all kinds of degreasing such as cutting oil, drawing oil, and press oil.
It is used in the field of cleaning articles having a complicated structure and precision parts requiring high cleanliness.
【０００４】ところが、近年、塩素系溶剤による地下水
汚染、大気汚染、オゾン層破壊等の環境問題が顕著に現
れるようになり、産業界では、これを代替するための洗
浄剤として、従来の水系洗浄剤を適用しつつある。In recent years, however, environmental problems such as groundwater pollution, air pollution, and ozone layer destruction due to chlorine-based solvents have become prominent. In the industry, conventional water-based cleaning agents have been used as a cleaning agent to replace these. The agent is being applied.
【０００５】[0005]
【発明が解決しようとする課題】しかしながら、従来の
水系洗浄剤は、塩素系溶剤に比べ、脱脂力、浸透力が劣
り、特に、切削油、引き抜き油や粘度の高いプレス油等
が狭い隙間や細部に付着しているような場合や、部品表
面のごく微量の残留油分量を問題にする場合に適用する
ことが難しい。However, the conventional water-based cleaning agent is inferior in the degreasing power and the penetrating power as compared with the chlorine-based solvent. It is difficult to apply this method when it is attached to details or when a very small amount of residual oil on the surface of a part is a problem.
【０００６】脱脂力、浸透力を上げるために、多量の非
イオン界面活性剤を使用することが考えられるが、製品
として安定な液体状とすることが難しくなる等の問題が
あった。また、脱脂力を高めるためにアルカリ塩を増量
してｐＨを高めることが考えられるが、これも、製品と
して安定な液体状とすることを困難とし、さらに、非鉄
金属への影響、作業者への安全性の配慮から好ましくな
い。It is conceivable to use a large amount of a nonionic surfactant in order to increase the degreasing power and the penetrating power. However, there are problems such as difficulty in obtaining a stable liquid state as a product. In addition, it is conceivable to increase the pH by increasing the amount of alkali salt in order to increase the degreasing power. However, this also makes it difficult to obtain a stable liquid state as a product. Is not preferred due to safety concerns.
【０００７】安定な液体状とする方法としては、たとえ
ば、特公昭６３−１３４８０に示されるような、芳香族
カルボン酸ナトリウムを使用する方法があるが、芳香族
カルボン酸ナトリウムの代表として用いられるパラター
シャリーブチル安息香酸ナトリウムは、腎臓、肝臓に対
する毒性が強いという問題がある。As a method for preparing a stable liquid, for example, there is a method using sodium aromatic carboxylate as disclosed in JP-B-63-13480. Sodium tert-butyl benzoate has a problem that it is highly toxic to kidneys and liver.
【０００８】[0008]
【課題を解決するための手段】本発明者らは、鋭意検討
した結果、アルカノールアミン、水酸化カリウム、特定
の非イオン界面活性剤、ブロックポリマーおよび脂肪族
カルボン酸を組み合わせることにより、前記問題が解決
できることを見いだし、本発明を完成するに至った。Means for Solving the Problems As a result of diligent studies, the present inventors have found that the above problems can be solved by combining alkanolamine, potassium hydroxide, a specific nonionic surfactant, a block polymer and an aliphatic carboxylic acid. They have found that they can be solved and have completed the present invention.
【０００９】すなわち、本発明は、少なくとも （１）アルカノールアミンおよび／または水酸化カリウ
ム １〜２５重量％ （２）ポリオキシエチレンアルキルフェニルエーテル非
イオン界面活性剤 １〜２０重量％ （３）ポリオキシエチレンポリオキシプロピレンブロッ
クポリマー １〜１０重量％ （４）炭素数６〜１２の脂肪族カルボン酸 １〜２０重
量％ （５）水 からなり、ｐＨが７〜９．５であることを特徴とする洗
浄剤である。That is, the present invention provides at least (1) 1 to 25% by weight of alkanolamine and / or potassium hydroxide (2) 1 to 20% by weight of a polyoxyethylene alkylphenyl ether nonionic surfactant (3) Polyoxyethylene Ethylene polyoxypropylene block polymer 1 to 10% by weight (4) aliphatic carboxylic acid having 6 to 12 carbon atoms 1 to 20% by weight (5) water, pH is 7 to 9.5 It is a cleaning agent.
【００１０】アルカノールアミンとしては、モノエタノ
ールアミン、ジエタノールアミン、トリエタノールアミ
ンおよびこれらのアルキル化物等のエタノールアミン類
が挙げられる。水酸化カリウムは、アルカノールアミン
で中和しきれない脂肪族カルボン酸を中和し、ｐＨを調
整するために用いる。アルカノールアミンと水酸化カリ
ウムの合計量が１重量％より少ないと洗浄力が低下し、
２５重量％より多いと非鉄金属、特にアルミニウムに対
する腐食性が出て好ましくない。Examples of the alkanolamine include ethanolamines such as monoethanolamine, diethanolamine, triethanolamine and alkylated products thereof. Potassium hydroxide is used to neutralize aliphatic carboxylic acids that cannot be completely neutralized with alkanolamines and adjust the pH. When the total amount of alkanolamine and potassium hydroxide is less than 1% by weight, the detergency decreases,
If it is more than 25% by weight, non-ferrous metals, particularly aluminum, are corroded, which is not preferable.
【００１１】ポリオキシエチレンアルキルフェニルエー
テル非イオン界面活性剤としては、ポリオキシエチレン
オクチルフェニルエーテル、ポリオキシエチレンノニル
フェニルエーテル等が挙げられる。その配合量が１重量
％より少ないと洗浄力が低下し、２０重量％より多い
と、安定な液体になりにくくなり好ましくない。[0011] Examples of the polyoxyethylene alkylphenyl ether nonionic surfactant include polyoxyethylene octyl phenyl ether, polyoxyethylene nonyl phenyl ether and the like. If the amount is less than 1% by weight, the detergency decreases, and if it is more than 20% by weight, it becomes difficult to obtain a stable liquid, which is not preferable.
【００１２】ポリオキシエチレンポリオキシプロピレン
ブロックポリマーとしては、ポリオキシプロピレン部分
の平均分子量が６００〜２０００、エチレンオキシドの
割合が１０〜４０重量％のものが好適に用いられる。こ
の配合量が１重量％より少ないか、１０重量％より多い
と浸透力が劣るようになり好ましくない。この配合量に
て、ブロックポリマー単独またはポリオキシエチレンア
ルキルフェニルエーテル非イオン界面活性剤単独より
も、浸透力が高くなるという予想外の相乗効果が得られ
る。As the polyoxyethylene polyoxypropylene block polymer, those having an average molecular weight of the polyoxypropylene portion of 600 to 2,000 and an ethylene oxide ratio of 10 to 40% by weight are suitably used. If the amount is less than 1% by weight or more than 10% by weight, the penetrating power becomes inferior, which is not preferable. With this blending amount, an unexpected synergistic effect of higher penetrating power than the block polymer alone or the polyoxyethylene alkylphenyl ether nonionic surfactant alone can be obtained.
【００１３】炭素数６〜１２の脂肪族カルボン酸は、本
発明の洗浄剤を、０℃以下の低温から５０℃以上の高温
まで幅広い温度範囲で安定な液体状として保つために必
要な成分で、具体的には、ヘキサン酸、ヘプタン酸、オ
クタン酸、２−エチルヘキサン酸、ノナン酸、３、５、
５−トリメチルヘキサン酸、デカン酸、ウンデカン酸、
ドデカン酸等が挙げられる。炭素数が６より少ないと、
不快な臭気が強くなり、１２より大きいと、泡立ちが大
きくなり好ましくない。この添加量が１重量％より少な
いと、安定な液体状に保つことが困難になり、２０重量
％より多いと、脱脂力が低下するようになり好ましくな
い。The aliphatic carboxylic acid having 6 to 12 carbon atoms is a component necessary for keeping the detergent of the present invention as a stable liquid in a wide temperature range from a low temperature of 0 ° C. or lower to a high temperature of 50 ° C. or higher. Specifically, hexanoic acid, heptanoic acid, octanoic acid, 2-ethylhexanoic acid, nonanoic acid, 3, 5,
5-trimethylhexanoic acid, decanoic acid, undecanoic acid,
Dodecanoic acid and the like. If the carbon number is less than 6,
Unpleasant odor becomes strong, and if it is more than 12, foaming becomes large, which is not preferable. If the amount is less than 1% by weight, it is difficult to maintain a stable liquid state. If the amount is more than 20% by weight, the degreasing power is undesirably reduced.
【００１４】水は、アルカノールアミン、水酸化カリウ
ム、界面活性剤、脂肪族カルボン酸等、洗浄剤有効成分
を均一な液体製品とするための溶媒として用いる。その
量は、前記洗浄剤有効成分および後述の公知の添加剤等
の量と水の総量が１００重量％になるように決められ
る。Water is used as a solvent for making the active ingredients of the detergent such as alkanolamine, potassium hydroxide, surfactant and aliphatic carboxylic acid into a uniform liquid product. The amount is determined so that the total amount of water and the amount of the above-mentioned cleaning agent active ingredient and known additives and the like will be 100% by weight.
【００１５】洗浄剤のｐＨは７〜９．５、好ましくは７
〜９、より好ましくは７〜８．５に調整される。７より
低いと鉄に対する安定性が劣るようになり、９．５より
高いとアルミに対する安定性が劣るようになり、また、
皮膚に対する刺激が強くなり好ましくない。The pH of the cleaning agent is 7 to 9.5, preferably 7
-9, more preferably 7-8.5. If it is lower than 7, the stability to iron will be inferior, if it is higher than 9.5, the stability to aluminum will be inferior,
It is not preferable because irritation to skin becomes strong.
【００１６】本発明の洗浄剤を実際の洗浄工程に用いる
場合は、水によりさらに希釈して用いる。その時の洗浄
剤有効成分濃度は、通常０．０５〜５重量％である。こ
の洗浄剤有効成分濃度は、洗浄方法、洗浄物品、汚れ等
の条件により、適宜調整される。When the cleaning agent of the present invention is used in an actual cleaning step, it is used after further diluting with water. The concentration of the detergent active ingredient at that time is usually 0.05 to 5% by weight. The concentration of the detergent active ingredient is appropriately adjusted depending on conditions such as a cleaning method, a cleaning article, and a stain.
【００１７】なお、本発明では、その他の界面活性剤、
公知の添加剤、たとえば、グルコン酸ナトリウム、ＥＤ
ＴＡ、ＮＴＡ等のキレート剤、ベンゾトリアゾール、ア
ミン類、亜硝酸塩等の腐食防止剤、消泡剤、アルコー
ル、グリコール、グリコールエーテル等の溶剤を適宜配
合して用いることも可能である。In the present invention, other surfactants,
Known additives such as sodium gluconate, ED
A chelating agent such as TA and NTA, a corrosion inhibitor such as benzotriazole, amines and nitrite, an antifoaming agent, and a solvent such as alcohol, glycol and glycol ether can be appropriately blended and used.
【００１８】[0018]
【実施例】以下、実施例により本発明を説明する。 実施例１〜５および比較例１〜３ 表１に示す洗浄剤を配合し、以下の試験を行った。その
結果を表２に示す。The present invention will be described below with reference to examples. Examples 1 to 5 and Comparative Examples 1 to 3 The cleaning agents shown in Table 1 were blended, and the following tests were performed. Table 2 shows the results.
【００１９】（１）脱脂力、浸透力試験 ３０メッシュのステンレス金網（６０×３０ｍｍ）に下
記金属加工油を含浸させ、１００℃で３０分加熱した。
これを、表１の洗浄剤の５重量％水溶液で洗浄し、洗浄
前後の付着油分量から下記数１で脱脂率を計算し、１、
１、１−トリクロロエタンによる脱脂と比較評価した。 試験に用いた金属加工油 切削油 ：ユニカットＧＨ３５（商品名、日本石油株式
会社製） プレス油：ユニプレスＤＰ１２０（商品名、日本石油株
式会社製） （２）安定性試験 洗浄剤を−５℃、３０℃、６０℃に保ち、洗浄剤有効成
分の分離、沈澱がないか観察した。 （３）浸透性試験 洗浄剤を水で１重量％に希釈した水溶液に１ｃｍ四方の
キャンバス生地を浮かべ、これが沈降するまでの時間を
測定した。(1) Degreasing and Penetration Tests A 30-mesh stainless steel mesh (60 × 30 mm) was impregnated with the following metal working oil and heated at 100 ° C. for 30 minutes.
This was washed with a 5% by weight aqueous solution of the detergent shown in Table 1, and the degreasing rate was calculated from the amount of oil adhering before and after washing according to the following equation (1).
Comparative evaluation was performed with degreasing with 1,1-trichloroethane. Metal working oil used for the test Cutting oil: Unicut GH35 (trade name, manufactured by Nippon Oil Co., Ltd.) Press oil: Unipres DP120 (trade name, manufactured by Nippon Oil Co., Ltd.) (2) Stability test The cleaning agent was -5 ° C. While maintaining the temperature at 30 ° C. and 60 ° C., it was observed whether the active ingredient of the detergent was separated or precipitated. (3) Permeability test A 1 cm square canvas cloth was floated on an aqueous solution obtained by diluting a detergent to 1% by weight with water, and the time required for the cloth to settle was measured.
【００２０】[0020]
【数１】 (Equation 1)
【００２１】[0021]
【表１】 [Table 1]
【００２２】表中の各成分の数字は重量％を示す。 １）アルカノールアミン ａ１：モノエタノールアミン 〃 ａ２：ジエタノールアミン 〃 ａ３：トリエタノールアミン ２）非イオン界面活性剤 ｂ１：ポリオキシエチレンオクチルフェニルエーテル （エチレンオキシド平均８モル付加） 〃 ｂ２：ポリオキシエチレンノニルフェニルエーテル （エチレンオキシド平均９モル付加） ３）ブロックポリマー ｃ１：プルロニックＬ３１（商品名、旭電化工業株式 会社製） 〃 ｃ２：ペポールＢ１０１（商品名、東邦化学工業株式 会社製） ４）脂肪酸 ｄ１：ノナン酸 〃 ｄ２：３、５、５−トリメチルヘキサン酸The number of each component in the table indicates% by weight. 1) Alkanolamine a1: Monoethanolamine 〃 a2: Diethanolamine 〃 a3: Triethanolamine 2) Nonionic surfactant b1: Polyoxyethylene octyl phenyl ether (addition of 8 mol of ethylene oxide on average) 〃 b2: Polyoxyethylene nonyl phenyl ether (Ethylene oxide added 9 mol on average) 3) Block polymer c1: Pluronic L31 (trade name, manufactured by Asahi Denka Kogyo Co., Ltd.) 〃 c2: Pepol B101 (trade name, manufactured by Toho Chemical Industry Co., Ltd.) 4) Fatty acid d1: nonanoic acid d2: 3,5,5-trimethylhexanoic acid
【００２３】[0023]
【表２】 １）脱脂率が１、１、１−トリクロロエタンによる脱脂
と同等である場合；〇 劣る場合；× ２）変化がない場合；〇 沈澱、分離が見られる場
合；× ３）数字が小さい程浸透性が良いことを示す １００
秒以上；×[Table 2] 1) When the degreasing rate is equivalent to degreasing with 1,1,1-trichloroethane; 劣 Inferior; × 2) When there is no change; 場合 When precipitation or separation is observed; × 3) The smaller the number, the more permeable Is good 100
Seconds or more; ×
【００２４】[0024]
【発明の効果】本発明は、塩素系溶剤に匹敵する脱脂
力、浸透力を有し、安定な液体状の優れた中性洗浄剤で
ある。Industrial Applicability The present invention is an excellent neutral detergent which has a degreasing power and a penetrating power comparable to that of a chlorinated solvent and is stable in a liquid state.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 ＦＩ Ｃ１１Ｄ 3/37 Ｃ１１Ｄ 3/37 Ｃ２３Ｇ 5/036 Ｃ２３Ｇ 5/036 (72)発明者 金田 亮二 神奈川県藤沢市善行坂１−14−25 (72)発明者 徳植 孝 神奈川県横浜市旭区市沢町97−６ (56)参考文献 特開 昭54−46207（ＪＰ，Ａ) 特開 平１−215893（ＪＰ，Ａ) 特開 平１−301799（ＪＰ，Ａ) 特公 昭48−17527（ＪＰ，Ｂ１) (58)調査した分野(Int.Cl.7，ＤＢ名) C11D 1/00 - 3/60 C23G 1/00 - 5/04 ────────────────────────────────────────────────── ─── Continued on the front page (51) Int.Cl. 7 Identification symbol FI C11D 3/37 C11D 3/37 C23G 5/036 C23G 5/036 (72) Inventor Ryoji Kanada 1-14 Yoshiyukizaka, Fujisawa-shi, Kanagawa -25 (72) Inventor Takashi Tokuvei 97-6 Ichizawa, Asahi-ku, Yokohama-shi, Kanagawa Prefecture (56) References JP-A-54-46207 (JP, A) JP-A-1-215893 (JP, A) Hei 1-301799 (JP, A) JP 48-17527 (JP, B1) (58) Fields investigated (Int. Cl. 7 , DB name) C11D 1/00-3/60 C23G 1/00-5 / 04
Claims (1)
ム １〜２５重量％ （２）ポリオキシエチレンアルキルフェニルエーテル非
イオン界面活性剤 １〜２０重量％ （３）ポリオキシエチレンポリオキシプロピレンブロッ
クポリマー １〜１０重量％ （４）炭素数６〜１２の脂肪族カルボン酸 １〜２０重
量％ （５）水 からなり、ｐＨが７〜９．５であることを特徴とする洗
浄剤。1. At least (1) 1 to 25% by weight of an alkanolamine and / or potassium hydroxide (2) 1 to 20% by weight of a polyoxyethylene alkylphenyl ether nonionic surfactant (3) Polyoxyethylene polyoxypropylene A cleaning agent comprising a block polymer 1 to 10% by weight (4) an aliphatic carboxylic acid having 6 to 12 carbon atoms 1 to 20% by weight (5) water and a pH of 7 to 9.5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25202392A JP3150779B2 (en) | 1992-08-28 | 1992-08-28 | Neutral detergent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25202392A JP3150779B2 (en) | 1992-08-28 | 1992-08-28 | Neutral detergent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0680993A JPH0680993A (en) | 1994-03-22 |
| JP3150779B2 true JP3150779B2 (en) | 2001-03-26 |
Family
ID=17231514
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP25202392A Expired - Lifetime JP3150779B2 (en) | 1992-08-28 | 1992-08-28 | Neutral detergent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3150779B2 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3596912B2 (en) * | 1994-07-25 | 2004-12-02 | 旭化成ケミカルズ株式会社 | Rinse-free cleaning agent |
| JP3558375B2 (en) * | 1994-07-25 | 2004-08-25 | 旭化成ケミカルズ株式会社 | Rinse-free low residue cleaning agent |
| US6247478B1 (en) * | 1996-11-15 | 2001-06-19 | Ecolab Inc. | Cleaning method for polyethylene terephthalate containers |
| JP5284609B2 (en) * | 2007-08-09 | 2013-09-11 | 花王株式会社 | Non-electrolytically cleaned cold-rolled steel sheet detergent composition |
| JP5841883B2 (en) * | 2012-04-03 | 2016-01-13 | 第一工業製薬株式会社 | Cleaning composition for ferrous and non-ferrous metal parts, and cleaning method using the same |
-
1992
- 1992-08-28 JP JP25202392A patent/JP3150779B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0680993A (en) | 1994-03-22 |
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