JP2563051B2 - Oil inclusion method - Google Patents
Oil inclusion methodInfo
- Publication number
- JP2563051B2 JP2563051B2 JP4314282A JP31428292A JP2563051B2 JP 2563051 B2 JP2563051 B2 JP 2563051B2 JP 4314282 A JP4314282 A JP 4314282A JP 31428292 A JP31428292 A JP 31428292A JP 2563051 B2 JP2563051 B2 JP 2563051B2
- Authority
- JP
- Japan
- Prior art keywords
- oil
- resin
- emulsion
- solidified body
- cured
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Description
【０００１】[0001]
【産業上の利用分野】本発明は、油分の封入処理方法に
係り、特に廃油等の油分を樹脂中に封入させて固形状に
する封入処理方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for encapsulating an oil component, and more particularly to an encapsulating method for encapsulating an oil component such as waste oil in a resin to make it solid.
【０００２】[0002]
【従来の技術】従来、産業上の廃油処理は、ほとんど焼
却によって行っている。固形化処理による方法では、廃
油の温度を上げて、その中にパラフィンのような比較的
低い融点の物質を混合し液体状にしたのち、融点以下に
まで冷却して全体を固形化する方法がある。2. Description of the Related Art Conventionally, most industrial waste oil treatment is performed by incineration. In the method by solidification treatment, there is a method in which the temperature of waste oil is raised, a substance having a relatively low melting point such as paraffin is mixed therein to form a liquid, and then cooled to below the melting point to solidify the whole. is there.
【０００３】[0003]
【発明が解決しようとする課題】上記において、焼却処
理方法は、油分中に不燃成分を多く含むシリコーン油や
リン酸油では、廃ガス中にこれらの固形分が多量に含ま
れるため、フィルターの目詰りが激しく不適当である。
また、ＰＣＢのような難燃性油についても応用すること
はできない。In the above incineration treatment method, in the case of silicone oil or phosphoric acid oil in which the oil content contains a large amount of non-combustible components, a large amount of these solids is contained in the waste gas. Clogging is severe and inappropriate.
Also, it cannot be applied to flame-retardant oils such as PCB.
【０００４】低融点物質による固形化処理では、融点が
１００℃以下（通常６０〜８０℃）のものが使用されて
いるため、高温になると再度液状になり、完全な固形化
処理とは云えない。本発明は、上記問題点を解決するも
ので、廃油等の油分を樹脂中に封入させて固形状とし、
再溶融せず汚染拡散の防止ができる油分の封入処理方法
を提供することを課題とする。In the solidification treatment with a low melting point substance, a material having a melting point of 100 ° C. or lower (usually 60 to 80 ° C.) is used, so that it becomes liquid again at a high temperature and cannot be said to be a complete solidification treatment. . The present invention is to solve the above problems, by encapsulating an oil component such as waste oil in a resin to give a solid state,
An object of the present invention is to provide a method for encapsulating and treating oil that can prevent the diffusion of contamination without remelting.
【０００５】[0005]
【課題を解決するための手段】上記課題を解決するため
に、本発明では、植物油、動物油、鉱物油等の油分を、
ビニルエステル樹脂、不飽和ポリエステル樹脂又はエポ
キシ樹脂から選ばれた熱硬化性樹脂と混合して、樹脂相
を連続相とするエマルジョンを形成し、得られたエマル
ジョンを硬化させて、前記油分を熱硬化性樹脂中に封入
することを特徴とする油分の処理方法としたものであ
る。In order to solve the above-mentioned problems, in the present invention, an oil component such as vegetable oil, animal oil, mineral oil,
It is mixed with a thermosetting resin selected from vinyl ester resin, unsaturated polyester resin or epoxy resin to form an emulsion having a resin phase as a continuous phase, and the obtained emulsion is cured to thermoset the oil component. It is a method for treating an oil content, which is characterized in that it is encapsulated in a resin.
【０００６】上記方法において、処理すべき油分は、混
合物全体に対して３０〜７０容量％とするのがよい。本
発明の処理方法によれば、シリコン油、リン酸油等の不
燃成分を多く含む油分や、ＰＣＢ等の難燃性油について
も、固化可能である上に、硬化した固化体は固定した油
分を安定に保持するプラスチック固化体となるので、油
分が流出することがない。In the above method, the oil content to be treated is preferably 30 to 70% by volume based on the whole mixture. According to the treatment method of the present invention, an oil component containing a large amount of non-combustible components such as silicone oil and phosphoric acid oil, and a flame-retardant oil such as PCB can be solidified, and a cured solidified product is a fixed oil component Since it becomes a plastic solidified body that stably holds, oil does not flow out.
【０００７】[0007]
【実施例】以下、本発明を実施例により具体的に説明す
るが、本発明はこれらの実施例に限定されるものではな
い。 実施例１ ビニルエステル樹脂（ダウ社製バインダー１０１Ｊ：ビ
スフェノールＡのジグリシジルエーテルとビスフェノー
ルＡの混合物と、無水マレイン酸とメタクリル酸の混合
物とを、反応させスチレンに溶解したもの）５０ｍｌ
と、ビニルエステル樹脂に対して１．５容量％の重合開
始剤（日本化薬ヌーリー製カドックスＢ−５０Ｎ）を加
えて混合したものに、シリコーン油５０ｍｌを攪拌しな
がら徐々に添加し、エマルジョンを形成させた。形成さ
れたエマルジョンに、硬化促進剤Ｎ，Ｎ−ジメチル−ｐ
−トルイジンを樹脂量の０．２容量％添加し、硬化させ
た。そのものはシリコーン油を安定に保持した均一な固
化体（ショア硬度：７８〜８０）となった。EXAMPLES The present invention will be specifically described below with reference to examples, but the present invention is not limited to these examples. Example 1 Vinyl ester resin (Binder 101J manufactured by Dow Co., Ltd .: a mixture of a diglycidyl ether of bisphenol A and a bisphenol A, and a mixture of maleic anhydride and methacrylic acid reacted to dissolve in styrene) 50 ml
And 1.5% by volume of a polymerization initiator (Cadox B-50N manufactured by Nippon Kayaku Nouri Co., Ltd.) with respect to the vinyl ester resin, and mixed, 50 ml of silicone oil is gradually added with stirring to form an emulsion. Formed. The formed emulsion contains a curing accelerator N, N-dimethyl-p.
-Toluidine was added at 0.2% by volume of the resin amount and cured. The substance itself became a uniform solidified body (Shore hardness: 78 to 80) in which silicone oil was stably retained.
【０００８】実施例２ エポキシ樹脂（アデカレジンＥＰ４４００：ビスフェノ
ールＡとエピクロルヒドリンから合成されたもの）５０
ｍｌと、硬化剤２０ｍｌを混合し、タービン油５０ｍｌ
を攪拌しながら徐々に添加し、エマルジョンを形成させ
た。その後、混合物を３０〜４０℃になる迄攪拌を続け
硬化させた。そのものはタービン油を安定に保持した均
一な固化体（ショア硬度：８０〜８５）となった。Example 2 Epoxy resin (Adekaresin EP4400: synthesized from bisphenol A and epichlorohydrin) 50
ml and hardener 20 ml, turbine oil 50 ml
Was slowly added with stirring to form an emulsion. Then, the mixture was continuously stirred and cured until the temperature reached 30 to 40 ° C. The material itself became a uniform solidified body (Shore hardness: 80 to 85) that stably held turbine oil.
【０００９】実施例３ 実施例２と同じ方法で、リン酸油を用いて固化体を作成
した。そのものはリン酸油を安定に保持した均一な固化
体（ショア硬度：７５〜８０）となった。Example 3 A solidified body was prepared using phosphoric acid oil in the same manner as in Example 2. The substance itself became a uniform solidified body (Shore hardness: 75 to 80) that stably held the phosphate oil.
【００１０】[0010]
【発明の効果】本発明によれば、油分を樹脂中に封入
し、安定な固化体にすることができるため、廃油を流出
せず固定化でき、しかも生成した固化体は難燃性であ
り、廃油を固化体として安全に貯蔵することができるよ
うになった。EFFECTS OF THE INVENTION According to the present invention, since oil can be encapsulated in a resin to form a stable solidified body, waste oil can be fixed without flowing out, and the solidified body produced is flame-retardant. , Now waste oil can be safely stored as a solidified body.
Claims (2)
ニルエステル樹脂、不飽和ポリエステル樹脂又はエポキ
シ樹脂から選ばれた熱硬化性樹脂と混合して、樹脂相を
連続相とするエマルジョンを形成し、得られたエマルジ
ョンを硬化させて、前記油分を熱硬化性樹脂中に封入す
ることを特徴とする油分の処理方法。1. An oil component such as vegetable oil, animal oil or mineral oil is mixed with a thermosetting resin selected from vinyl ester resin, unsaturated polyester resin or epoxy resin to form an emulsion having a resin phase as a continuous phase. Then, the obtained emulsion is cured, and the oil is encapsulated in a thermosetting resin.
７０容量％を含むことを特徴とする請求項１記載の油分
の処理方法。2. The oil content is 30 to 30% with respect to the entire mixture.
70% by volume is contained, The processing method of the oil content of Claim 1 characterized by the above-mentioned.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4314282A JP2563051B2 (en) | 1992-10-30 | 1992-10-30 | Oil inclusion method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4314282A JP2563051B2 (en) | 1992-10-30 | 1992-10-30 | Oil inclusion method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH06145691A JPH06145691A (en) | 1994-05-27 |
| JP2563051B2 true JP2563051B2 (en) | 1996-12-11 |
Family
ID=18051493
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4314282A Expired - Fee Related JP2563051B2 (en) | 1992-10-30 | 1992-10-30 | Oil inclusion method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2563051B2 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012074675A2 (en) * | 2010-11-30 | 2012-06-07 | Palmese Giuseppe R | Toughening cross-linked thermosets |
| EP3194465B1 (en) | 2014-09-12 | 2023-11-01 | Drexel University | Toughening of epoxy thermosets |
| US11729493B2 (en) | 2019-03-28 | 2023-08-15 | Sony Group Corporation | Image capture apparatus and image capture method |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0765030B2 (en) * | 1990-05-09 | 1995-07-12 | 三洋化成工業株式会社 | Oil coagulant |
| JPH05230435A (en) * | 1992-02-20 | 1993-09-07 | Ricoh Co Ltd | Gelling agent for oily liquid and for substance containing oily liquid, and method for gelling |
-
1992
- 1992-10-30 JP JP4314282A patent/JP2563051B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH06145691A (en) | 1994-05-27 |
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