JP2509878B2 - Composite of charcoal and polymer and method for producing the same - Google Patents
Composite of charcoal and polymer and method for producing the sameInfo
- Publication number
- JP2509878B2 JP2509878B2 JP5348820A JP34882093A JP2509878B2 JP 2509878 B2 JP2509878 B2 JP 2509878B2 JP 5348820 A JP5348820 A JP 5348820A JP 34882093 A JP34882093 A JP 34882093A JP 2509878 B2 JP2509878 B2 JP 2509878B2
- Authority
- JP
- Japan
- Prior art keywords
- charcoal
- polymer
- composite
- producing
- voids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Landscapes
- Chemical And Physical Treatments For Wood And The Like (AREA)
Description
【0001】[0001]
【産業上の利用分野】本発明は、木炭の表面及び内部の
木炭粒子をポリマーにより固定化することによって、木
炭の強度並びに切削加工性の向上を図り、新規有用な加
工素材として利用することができるようにした木炭とポ
リマーとの複合体並びにその製造方法に関するものであ
る。BACKGROUND OF THE INVENTION The present invention improves the strength and machinability of charcoal by immobilizing the charcoal particles on the surface and inside of charcoal with a polymer, and can be used as a new and useful processing material. The present invention relates to a composite of charcoal and a polymer, and a method for producing the same.
【0002】[0002]
【従来の技術】木炭は従来から手近なところで広く手軽
に使用されている。例えば、家庭用の炊事、湯沸し、焙
焼、暖房、乾燥などの燃料として、又、吸着性を利用し
て飲料水の濾過材や脱臭材として用いられたり、化粧品
のまゆ墨、絵画素描用の画材など多方面に用いられてい
る。2. Description of the Related Art Charcoal has been widely and easily used in places where it has been used. For example, it is used as a fuel for domestic cooking, boiling water, roasting, heating, drying, etc., and is also used as a filter and deodorant for drinking water by utilizing its adsorptivity. It is used in various fields such as painting materials.
【0003】しかし、木炭の物性は、一般的に物理的な
強度が脆弱であるため、折れ易く、割れ易いなどの特有
の構造体を有しているため、土木、建築、芸術などにお
いてその原形を素材として利用ことは不可能であった。However, since the physical properties of charcoal are generally weak in physical strength, they have a peculiar structure that they are easily broken and cracked, so that their original form in civil engineering, architecture, art, etc. It was impossible to use as a material.
【0004】[0004]
【発明が解決しようとする課題】本発明は、木炭の物理
的強度を飛躍的に高めて、その木炭の特性を保持しつつ
土木、建築、芸術、加工品などへの加工素材として供す
ることのできる木炭とポリマーとの複合体並びにその製
造方法を得ようとするものである。DISCLOSURE OF THE INVENTION The present invention dramatically improves the physical strength of charcoal and provides it as a processing material for civil engineering, construction, arts, processed products, etc. while maintaining the characteristics of the charcoal. The present invention is intended to obtain a charcoal-polymer composite and a method for producing the same.
【0005】[0005]
【課題を解決するための手段】本発明は上記の如き観点
に鑑みてなされたものであって、木炭の空隙内に硬化ポ
リマーの連続層を生成してなる木炭とポリマーとの複合
体、並びに、減圧−加圧法により木炭内部の空隙内空気
を吸引し、該減圧空隙にモノマー液或はポリマー液を注
入して後溶剤を発散させてから、それをラッピングして
加熱重合することにより空隙内に硬化ポリマーの連続層
を生成してなる木炭とポリマーとの複合体の製造方法を
提供しようとするものである。The present invention has been made in view of the above-mentioned viewpoints, and is a composite of charcoal and a polymer, wherein a continuous layer of a cured polymer is formed in the void of the charcoal, and The air in the void inside the charcoal is sucked by the depressurization-pressurization method, the monomer liquid or the polymer liquid is injected into the depressurized void, and the solvent is then released. Another object of the present invention is to provide a method for producing a composite of charcoal and a polymer, which is produced by forming a continuous layer of a cured polymer.
【0006】[0006]
【作用及び実施例】以下、本発明を実施例に基づいて具
体的に説明する。 実施例1 減圧−加圧法により、木炭を約1mmHg〜20mmH
gの減圧下に0.5時間〜2時間程度置き、該木炭内部
の空隙内空気を吸引し、それに引き続いて、常圧下で約
0.5%の重合開始剤、例えば、ベンゾイルパーオキサ
イド(BPO)を含有するアクリル系モノマーを、溶
剤、例えば、メタクリル酸メチル(MMA)の90%メ
チルアルコール溶液中に溶解した溶液に2時間〜20時
間程度浸漬して該溶液を木炭の空隙内に注入する。その
後、常法に則って危険予防を兼ねて溶剤を予め大気中で
発散させて除去する。その後、内部に注入された溶液が
逸失しないようにアルミ箔或は金属板等でラッピングす
る。それを約70℃以上で5時間〜10時間程度加熱し
て木炭内にポリメタクリル酸メチルのポリマーの連続層
を生成硬化して木炭とポリマーとの複合体を得た。ポリ
マー含有率は通常50%〜30%程度であるが、その含
有率は適当に選択できる。これにより製造された複合体
の縦圧縮強さは木炭の約20倍であった。OPERATION AND EXAMPLES Hereinafter, the present invention will be specifically described based on examples. Example 1 About 1 mmHg to 20 mmH of charcoal was prepared by the depressurization-pressurization method.
g under reduced pressure for about 0.5 to 2 hours to suck air in the voids inside the charcoal, and subsequently, under normal pressure, about 0.5% of a polymerization initiator such as benzoyl peroxide (BPO). ) -Containing acrylic monomer is immersed in a solvent, for example, a solution prepared by dissolving 90% methyl alcohol (MMA) in methyl alcohol for about 2 to 20 hours to inject the solution into the void of charcoal. . After that, the solvent is diffused and removed in advance in the atmosphere in accordance with a conventional method to prevent danger. After that, it is wrapped with an aluminum foil or a metal plate so that the solution injected inside is not lost. It was heated at about 70 ° C. or higher for about 5 to 10 hours to form and cure a continuous layer of polymethylmethacrylate polymer in charcoal to obtain a charcoal-polymer composite. The polymer content is usually about 50% to 30%, but the content can be appropriately selected. The longitudinal compressive strength of the composite thus produced was about 20 times that of charcoal.
【0007】実施例2 減圧−加圧法により、木炭を約1mmHg〜20mmH
gの減圧下に0.5時間〜2時間程度置き、該木炭内部
の空隙内空気を吸引し、それに引き続いて、常圧下で硬
化剤を約10%〜20%含有するポリエステル、エポキ
シ樹脂又は再生ポリマー樹脂などを、溶剤、例えば、メ
タクリル酸メチル(MMA)の90%メチルアルコール
溶液中に溶解した溶液に2時間〜20時間程度浸漬して
該溶液を木炭の空隙内に注入する。その後、常法に則っ
て危険予防を兼ねて溶剤を予め大気中で発散させて除去
する。その後、内部に注入された溶液が逸失しないよう
にアルミ箔或は金属板等でラッピングする。それを約9
0℃で1時間〜5時間程度加熱重合硬化することにより
木炭内でポリマーを樹脂化して硬化ポリマーの連続層を
生成して木炭とポリマーとの複合体を得た。ポリマー含
有率は通常50%〜30%程度であるが、その含有率は
適当に選択できる。これにより製造された複合体の縦圧
縮強さは木炭の約20倍であった。Example 2 Charcoal was applied to a pressure of about 1 mmHg to 20 mmH by a pressure-pressurization method.
g under reduced pressure for about 0.5 to 2 hours to suck air in the voids inside the charcoal, and subsequently, under normal pressure, a polyester, epoxy resin or regenerated containing about 10% to 20% of a curing agent. A polymer resin or the like is dipped in a solvent, for example, a solution of 90% methyl alcohol solution of methyl methacrylate (MMA) dissolved in the solution for about 2 to 20 hours, and the solution is injected into the voids of the charcoal. After that, the solvent is diffused and removed in advance in the atmosphere in accordance with a conventional method to prevent danger. After that, it is wrapped with an aluminum foil or a metal plate so that the solution injected inside is not lost. About 9
The polymer was resinified in the charcoal by heating and curing at 0 ° C. for about 1 to 5 hours to form a continuous layer of the cured polymer to obtain a charcoal-polymer composite. The polymer content is usually about 50% to 30%, but the content can be appropriately selected. The longitudinal compressive strength of the composite thus produced was about 20 times that of charcoal.
【0008】[0008]
【発明の効果】以上の説明により明らかなように、本発
明によれば、木炭の原形に即した状態のままで、木炭の
強度並びに切削加工性の向上が図られ、それによってそ
の原材料である木材の木目をそのまま活用できると共
に、黒体放射性、電磁波遮蔽性、高耐久性などの木炭の
特性を保持して、土木、建築、芸術、加工品などへの加
工素材として有効利用できるものである。As is apparent from the above description, according to the present invention, it is possible to improve the strength and cutting workability of charcoal while keeping the original shape of charcoal, and thus the raw material thereof. The wood grain can be used as it is, and the charcoal characteristics such as black body radiation, electromagnetic wave shielding and high durability can be retained, and it can be effectively used as a processing material for civil engineering, architecture, art, processed products, etc. .
Claims (2)
生成してなることを特徴とする木炭とポリマーとの複合
体。1. A charcoal-polymer composite comprising a continuous layer of hardened polymer formed within the voids of the charcoal.
気を吸引し、該減圧空隙にモノマー液或はポリマー液を
注入して後溶剤を発散させてから、それをラッピングし
て加熱重合することにより空隙内に硬化ポリマーの連続
層を生成してなることを特徴とする木炭とポリマーとの
複合体の製造方法。2. A vacuum-pressurization method is used to suck air in the voids inside the charcoal, and a monomer liquid or a polymer liquid is injected into the vacuum voids to diffuse the solvent, and the solvent is lapped and polymerized by heating. The method for producing a composite of charcoal and a polymer is characterized by forming a continuous layer of a cured polymer in the voids.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5348820A JP2509878B2 (en) | 1993-12-27 | 1993-12-27 | Composite of charcoal and polymer and method for producing the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5348820A JP2509878B2 (en) | 1993-12-27 | 1993-12-27 | Composite of charcoal and polymer and method for producing the same |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH07186111A JPH07186111A (en) | 1995-07-25 |
JP2509878B2 true JP2509878B2 (en) | 1996-06-26 |
Family
ID=18399598
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP5348820A Expired - Lifetime JP2509878B2 (en) | 1993-12-27 | 1993-12-27 | Composite of charcoal and polymer and method for producing the same |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2509878B2 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20020029197A (en) * | 2000-10-12 | 2002-04-18 | 조재현 | Method for fabricating solid charcoal solidified hardness, a uncolored and solid charcoal and method for fabricating thereof |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62275702A (en) * | 1986-05-26 | 1987-11-30 | 松下電工株式会社 | Improved woody material |
-
1993
- 1993-12-27 JP JP5348820A patent/JP2509878B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JPH07186111A (en) | 1995-07-25 |
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