JPS62176909A - Active carbon product and its preparation - Google Patents
Active carbon product and its preparationInfo
- Publication number
- JPS62176909A JPS62176909A JP61019304A JP1930486A JPS62176909A JP S62176909 A JPS62176909 A JP S62176909A JP 61019304 A JP61019304 A JP 61019304A JP 1930486 A JP1930486 A JP 1930486A JP S62176909 A JPS62176909 A JP S62176909A
- Authority
- JP
- Japan
- Prior art keywords
- active carbon
- pores
- activated carbon
- monomer
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 63
- 229910052799 carbon Inorganic materials 0.000 title abstract description 12
- 229920000642 polymer Polymers 0.000 claims abstract description 16
- 239000011148 porous material Substances 0.000 claims abstract description 13
- 239000000178 monomer Substances 0.000 claims abstract description 9
- 230000000379 polymerizing effect Effects 0.000 claims abstract 3
- 238000004519 manufacturing process Methods 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 9
- 239000000463 material Substances 0.000 abstract description 7
- 238000010438 heat treatment Methods 0.000 abstract description 6
- 238000001179 sorption measurement Methods 0.000 abstract description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract description 3
- 230000002401 inhibitory effect Effects 0.000 abstract 1
- 238000004321 preservation Methods 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- 230000003014 reinforcing effect Effects 0.000 abstract 1
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- -1 polyethylene Polymers 0.000 description 5
- 238000000465 moulding Methods 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004342 Benzoyl peroxide Substances 0.000 description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000002964 rayon Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 235000018262 Arachis monticola Nutrition 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 235000012438 extruded product Nutrition 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- CXKWCBBOMKCUKX-UHFFFAOYSA-M methylene blue Chemical compound [Cl-].C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 CXKWCBBOMKCUKX-UHFFFAOYSA-M 0.000 description 1
- 229960000907 methylthioninium chloride Drugs 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001483 poly(ethyl methacrylate) polymer Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
活性炭製品およびその製造方法に関する。樹脂などの結
合材とともに混練したものを射出成形や押出成形などに
よって成形し、また、結合材による骨格を形成するだめ
の熱処理を施して得られる活性体成形物として使用され
るものなど、その使用にあたって熱処理を施されるもの
には特に好適である。DETAILED DESCRIPTION OF THE INVENTION (Industrial Field of Application) The present invention relates to activated carbon products and methods for producing the same. The use of active materials, such as those that are kneaded with a binder such as a resin and molded by injection molding or extrusion molding, and then subjected to heat treatment to form a skeleton of the binder. It is particularly suitable for those that are subjected to heat treatment.
（従来の技術）
そのまま使用される場合は勿論、上記したような活性炭
成形物などとする場合に使用される活性炭も１通常は格
別の処理を施されたものではなく、単に活性炭として得
られたものをそのまま使用していた。また、中には、結
合材による骨格より大きな連通気孔を形成するようなも
ので表面を被覆した活性炭を使うことについて開示して
いるものもある。例えば、特開昭６０−９６５１６号公
報には比較的炭素収率の小さなもので表面を被覆した活
性炭の使用について開示されている。(Prior art) Activated carbon used not only as it is, but also when making activated carbon molded products as described above, is usually not subjected to any special treatment, but is simply obtained as activated carbon. I was using things as they were. Some also disclose the use of activated carbon whose surface is coated with something that forms communicating pores that are larger than the binding material skeleton. For example, JP-A-60-96516 discloses the use of activated carbon whose surface is coated with a material having a relatively low carbon yield.
（発明が解決しようとする問題点）
保存上の問題と、前記したような活性炭成形物を成形す
る際などの成形性が悪い間項である。(Problems to be Solved by the Invention) There are storage problems and poor moldability when molding activated carbon molded articles as described above.
即ち、活性炭の気孔には種々物質が吸着されて経時的な
性能劣化を生じ、ｔた２強度的に活性炭は崩れ易いのが
一般的であり、更に、成形に際しては、可塑剤、溶剤な
どの成形助材が気孔に含浸することによって成形性が悪
くなる。ここで、成形性を良くするためにこれら成形助
材を多量に使おうとすると、成形物の形状安定性が悪く
なり、また、成形物の強度も大きく低下してしまうこと
になる。この点について、炭素収率の比較的小さなもの
で表面を被覆した活性炭を使う場合も同様である。なぜ
ならば、活性炭表面を完全に被覆することができたとし
ても。In other words, various substances are adsorbed into the pores of activated carbon, causing performance deterioration over time, and activated carbon is generally easy to crumble due to its strength.Furthermore, during molding, it is difficult to use plasticizers, solvents, etc. The moldability deteriorates due to impregnation of the molding aid into the pores. If a large amount of these molding aids is used in order to improve moldability, the shape stability of the molded product will deteriorate and the strength of the molded product will also be significantly reduced. Regarding this point, the same applies when using activated carbon whose surface is coated with a material having a relatively low carbon yield. This is because even if the activated carbon surface could be completely covered.
混練時の力などによってその被覆の完全性がいつまでも
継続するとは限らない。The integrity of the coating may not last forever due to factors such as the force during kneading.
（問題点を解決するための手段）
気孔中に解重合型ポリマーを充填させる。解重合型ポリ
マーの一例としては、ポリエチレンポリプロピレン、ポ
リブタジェン、ポリイノブチレン、ポリスチレン、ナイ
ロン、ポリメタメチルスチレン、ポリメタクリル酸メチ
ル、ポリメタクリル酸エチル、ポリ−α−トイテロスチ
レンなどであり、ポリメタクリル酸メチルは特に好まし
いものの一つである。解重合の程度が極めて高い。(Means for solving the problem) Fill the pores with a depolymerizable polymer. Examples of depolymerizable polymers include polyethylene polypropylene, polybutadiene, polyinobutylene, polystyrene, nylon, polymethacrystyrene, polymethyl methacrylate, polyethyl methacrylate, poly-alpha-toiterostyrene, etc. Methyl acid is one of the particularly preferred. The degree of depolymerization is extremely high.
また、解重合型ポリマーを気孔中に含浸させるにあたっ
ては、解重合型ポリマーの溶剤による希釈液に活性炭を
浸漬し、乾燥させるような方法でも可能ではあるが、充
填量は大きい程好ましく、望ましくは２０％（体積）以
上とするのがよく、その点で、このような方法では繰シ
返して処理しなければならないとか、それでも大して充
填できないなどの面倒さがあるので。In addition, in order to impregnate the pores with the depolymerizable polymer, it is possible to immerse activated carbon in a diluted solution of the depolymerizable polymer with a solvent and dry it, but the filling amount is preferably larger. It is best to set the amount to 20% (volume) or more, since this method is troublesome, such as having to process repeatedly and even then not being able to fill much.
好ましくは、解重合型ポリマーを形成するモノマーを活
性炭の気孔中に含浸させた後、このモノマーを重合させ
てポリマーとするのが良い。Preferably, a monomer forming a depolymerizable polymer is impregnated into the pores of activated carbon, and then this monomer is polymerized to form a polymer.
重合方法は一般的に知られているものをそのまま活用で
きる。即ち、単に加熱したシ、過酸化水素、過硫酸アン
モン、過酸化ベンゾイル、クメンヒドロパーオキサイド
、アゾイソピスズチロニトリル、ジメチルアニリン、金
属錯塩などの重合用触媒を使用したり、紫外線などの光
エネルギーを利用したシと、含浸モノマーの種類に応じ
て種々である。また、含浸にあたって超音波による微振
動とか加熱や減圧などによる強制手段も利用してよい。Generally known polymerization methods can be used as they are. That is, simply heated polymerization catalysts such as hydrogen peroxide, ammonium persulfate, benzoyl peroxide, cumene hydroperoxide, azoisopistintyronitrile, dimethylaniline, metal complex salts, etc., or the use of light such as ultraviolet rays. There are various methods depending on the method using energy and the type of impregnating monomer. In addition, for impregnation, microvibration by ultrasonic waves, forced means such as heating or reduced pressure may be used.
尚１本発明で使用する活性炭としては、ヤシ殻、ビーナ
ツツ殻、木炭１石油１石炭、樹脂などから得られたもの
を例示でき、その形状も微粉末状２粒状、繊維状と適宜
である。The activated carbon used in the present invention can be exemplified by those obtained from coconut shells, peanut shells, charcoal, petroleum, coal, resin, etc., and its shape may be appropriate, such as fine powder, two grains, or fibrous.
（作用）
解重合型ポリマーは活性炭使用時には熱処理などで除去
されてしまうが、それまでの保存時には気孔の栓材とな
って物質吸着を抑え、また。(Function) When activated carbon is used, the depolymerized polymer is removed by heat treatment, etc., but during storage, it acts as a plug material for pores and suppresses material adsorption.
補強体となって崩れを抑える。It acts as a reinforcement and prevents collapse.
また、前記した成形物の場合のように、製品を得る過程
で熱処理をなすものの場合には、この熱処理によって解
重合型ポリマーを除去することができるので工程数が維
持される。Further, in the case of a product that is heat treated during the process of obtaining the product, as in the case of the molded product described above, the number of steps can be maintained because the depolymerized polymer can be removed by this heat treatment.
（実施例）
〈実施例１〉
市販のヤシ殻活性炭（粒径４０〜１００メツシユ）５０
重量部を減圧状態とし、そこへアクリエステルＭ（三菱
レイヨン■製メタクリル酸メチルモノマー）１００重量
部を加え、攪拌後。(Example) <Example 1> Commercially available coconut shell activated carbon (particle size 40-100 mesh) 50
The pressure in the weight part was reduced, and 100 parts by weight of Acryester M (methyl methacrylate monomer manufactured by Mitsubishi Rayon ■) was added thereto, followed by stirring.
濾過し、これを９０℃の湯の中へ入れ、攪拌しながら窒
素気流中で４時間維持後、濾過、乾燥させた。The mixture was filtered, placed in hot water at 90°C, maintained in a nitrogen stream for 4 hours with stirring, and then filtered and dried.
〈実施例２〉
実施例１で使用したのと同じ活性炭５０重量部ヲ、ベン
ゾイルパーオキサイド２重量部とパフセン１００重景部
とよシなる溶液中に浸漬し。<Example 2> 50 parts by weight of the same activated carbon used in Example 1 was immersed in a solution containing 2 parts by weight of benzoyl peroxide and 100 parts by weight of Pafusen.
濾過、乾燥後、減圧下でスチレンモノマー１００重量部
を加え、攪拌後、濾過し、これを７０℃の湯の中へ入れ
、攪拌しながら２時間維持後。After filtration and drying, 100 parts by weight of styrene monomer was added under reduced pressure, stirred, filtered, poured into hot water at 70° C., and maintained with stirring for 2 hours.
さらに９５℃にして攪拌しながら２時間維持し。Further, the temperature was raised to 95°C and maintained for 2 hours while stirring.
その後、濾過、乾燥させた。Thereafter, it was filtered and dried.
く比較例１〉
アクリシラツブ５Ｙ−１０３（三菱レイヨン■製のポリ
メタクリル酸メチル）２０ｆｉ量部をメチルエチルケト
ン１００重量部で希釈した溶液に実施例１で使用したの
と同じ活性炭５０重量部を加え、開放型ニーダ−で６０
分間混練した０
く比較例２〉
比較例１において、アクリシラツブ５Ｙ−１０３に替え
てＧＰスタイロン６６６（旭化成工業■製のポリスチレ
ン）２０重量部を使用した以外はすべて比較例２と同様
にした。Comparative Example 1 50 parts by weight of the same activated carbon as used in Example 1 was added to a solution prepared by diluting 20 parts of Acrysilub 5Y-103 (polymethyl methacrylate manufactured by Mitsubishi Rayon ■) with 100 parts by weight of methyl ethyl ketone, and the mixture was opened. 60 with mold kneader
Comparative Example 2 The procedure was the same as in Comparative Example 2, except that 20 parts by weight of GP Stylon 666 (polystyrene manufactured by Asahi Kasei Kogyo ■) was used in place of Acrylic Slub 5Y-103.
〈比較例３〉
実施例１〜比較例２で使用した活性炭（そのまま）を比
較例５とする。<Comparative Example 3> Comparative Example 5 is the activated carbon (as is) used in Examples 1 to 2.
（発明の効果）
各側の活性炭製品を手で押しつぶしたときの感触、並び
に、各側の活性炭製品（活性炭そのものの量はいずれも
５０重量部分）それぞれを。(Effects of the invention) The feel of the activated carbon products on each side when crushed by hand, and the activated carbon products on each side (the amount of activated carbon itself is 50 parts by weight in each case).
ポリ塩化ビニル樹脂３０重量部、ジオクチルフタレート
１０重量部、ステアリン酸塩（滑剤）２重量部、メチル
エチルケトン５０重量部とともに３本ロールで十分に混
練後、押出成形して直径約１咽の棒状物とし、更にポリ
塩化ビニル樹脂を炭素骨格とするために、空気雰囲気中
で３００°Ｃまで熱処理した後、最高温度８５０℃まで
の焼成処理を施して得たものの評価結果を表−１に示す
。After thorough kneading with 3 rolls with 30 parts by weight of polyvinyl chloride resin, 10 parts by weight of dioctyl phthalate, 2 parts by weight of stearate (lubricant), and 50 parts by weight of methyl ethyl ketone, it was extruded into a rod-shaped product with a diameter of about 1 mm. Furthermore, in order to make the polyvinyl chloride resin a carbon skeleton, it was heat-treated to 300°C in an air atmosphere and then fired to a maximum temperature of 850°C. The evaluation results are shown in Table 1.
表−１
（注１） 強度測定はＪＩＳ Ｓ ６００５に準じ
た。Table 1 (Note 1) Strength measurements were conducted in accordance with JIS S 6005.
（注２） 吸着能測定はＪＩＳ Ｋ １４７０に準じ
た（メチレンブルー脱色能）。また、上段の値が各側で
得た直後（但し、比較例３については購入直後）、下段
の値が各側で得たものを３０℃炭酸ガス雰囲気中に１２
時間放置後、それぞれ使用したものの場合を示す。(Note 2) Adsorption ability measurement was based on JIS K 1470 (methylene blue decolorization ability). Immediately after the values in the upper row were obtained on each side (however, immediately after purchase for Comparative Example 3), the values in the lower row were obtained on each side at 12
The results are shown after each product was used after being left for a certain period of time.
表−１よシ１本発明によれば、経時的性能劣化が少なく
（吸着能の欄）２強度もあり（押しつぶしたときの感触
の欄）、また、成形性に優れる（押出成形物に対する観
察の欄）とともに得られる成形物の強度も優れたものと
なることが判る。According to Table 1, the present invention exhibits little deterioration in performance over time (adsorption capacity column), 2 strength (feel when crushed), and excellent moldability (observations on extruded products). It can be seen that the strength of the molded product obtained is also excellent.
Claims (1)
。 ２、解重合型ポリマーを形成するモノマーを活性炭の気
孔中に含浸させた後、このモノマーを重合させてポリマ
ーとすることを特徴とする活性炭製品の製造方法。[Claims] 1. An activated carbon product whose pores are filled with a depolymerized polymer. 2. A method for producing an activated carbon product, which comprises impregnating the pores of activated carbon with a monomer that forms a depolymerizable polymer, and then polymerizing the monomer to form a polymer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61019304A JPS62176909A (en) | 1986-01-31 | 1986-01-31 | Active carbon product and its preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61019304A JPS62176909A (en) | 1986-01-31 | 1986-01-31 | Active carbon product and its preparation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62176909A true JPS62176909A (en) | 1987-08-03 |
Family
ID=11995676
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61019304A Pending JPS62176909A (en) | 1986-01-31 | 1986-01-31 | Active carbon product and its preparation |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62176909A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100764613B1 (en) | 2006-12-15 | 2007-10-08 | 재단법인서울대학교산학협력재단 | Fabrication of mesoporous carbon/conducting polymer nanocomposite and application to electrode of electro-double layer capacitor |
| JP2009525258A (en) * | 2006-01-30 | 2009-07-09 | アドバンスド テクノロジー マテリアルズ，インコーポレイテッド | Nanoporous carbon material and system and method using the same |
| US9468901B2 (en) | 2011-01-19 | 2016-10-18 | Entegris, Inc. | PVDF pyrolyzate adsorbent and gas storage and dispensing system utilizing same |
-
1986
- 1986-01-31 JP JP61019304A patent/JPS62176909A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009525258A (en) * | 2006-01-30 | 2009-07-09 | アドバンスド テクノロジー マテリアルズ，インコーポレイテッド | Nanoporous carbon material and system and method using the same |
| KR100764613B1 (en) | 2006-12-15 | 2007-10-08 | 재단법인서울대학교산학협력재단 | Fabrication of mesoporous carbon/conducting polymer nanocomposite and application to electrode of electro-double layer capacitor |
| US9468901B2 (en) | 2011-01-19 | 2016-10-18 | Entegris, Inc. | PVDF pyrolyzate adsorbent and gas storage and dispensing system utilizing same |
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