JP2024545133A - 化合物、そのような化合物を含む遷移金属錯体ヒドロホルミル化触媒前駆体組成物、及びヒドロホルミル化プロセス - Google Patents

化合物、そのような化合物を含む遷移金属錯体ヒドロホルミル化触媒前駆体組成物、及びヒドロホルミル化プロセス Download PDF

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JP2024545133A
JP2024545133A JP2024534283A JP2024534283A JP2024545133A JP 2024545133 A JP2024545133 A JP 2024545133A JP 2024534283 A JP2024534283 A JP 2024534283A JP 2024534283 A JP2024534283 A JP 2024534283A JP 2024545133 A JP2024545133 A JP 2024545133A
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monophosphite
catalyst
ligand
hydroformylation
metal
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JP2024545133A5 (enExample
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アール． ラロシュ、クリストフ
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ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122—Metal aryl or alkyl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4053—Regeneration or reactivation of catalysts containing metals with recovery of phosphorous catalyst system constituents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4092—Regeneration or reactivation of catalysts containing metals involving a stripping step, with stripping gas or solvent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C07C45/505—Asymmetric hydroformylation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/08—Esters of oxyacids of phosphorus
    • C07F9/141—Esters of phosphorous acids
    • C07F9/145—Esters of phosphorous acids with hydroxyaryl compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/572—Five-membered rings
    • C07F9/5728—Five-membered rings condensed with carbocyclic rings or carbocyclic ring systems
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/10—Non-coordinating groups comprising only oxygen beside carbon or hydrogen

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
JP2024534283A 2021-12-16 2022-11-02 化合物、そのような化合物を含む遷移金属錯体ヒドロホルミル化触媒前駆体組成物、及びヒドロホルミル化プロセス Pending JP2024545133A (ja)

Applications Claiming Priority (3)

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US202163265512P 2021-12-16 2021-12-16
US63/265,512 2021-12-16
PCT/US2022/079127 WO2023114579A1 (en) 2021-12-16 2022-11-02 Compounds, transition metal complex hydroformylation catalyst precuror compositions comprising such compounds, and hydroformylation processes

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JP2024545133A true JP2024545133A (ja) 2024-12-05
JP2024545133A5 JP2024545133A5 (enExample) 2025-11-05

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US (1) US20250128245A1 (enExample)
EP (1) EP4448170B1 (enExample)
JP (1) JP2024545133A (enExample)
CN (1) CN118317834A (enExample)
WO (1) WO2023114579A1 (enExample)
ZA (1) ZA202405190B (enExample)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2026106685A1 (en) * 2024-11-13 2026-05-21 Dow Technology Investments Llc Hydroformylation process

Citations (9)

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JPS5817430A (ja) * 1981-07-10 1983-02-01 チバ・ガイギ−・アクチエンゲゼルシヤフト 写真感光材料
JPH04505931A (ja) * 1989-12-08 1992-10-15 ユニロイヤル　ケミカル　カンパニー　インコーポレイテッド 立体的ヒンダードアリールフォスファイトの製造法
JP2009163029A (ja) * 2008-01-08 2009-07-23 Konica Minolta Opto Inc 光学フィルム、光学フィルムの製造方法、それを用いた偏光板、及び液晶表示装置
JP2011527287A (ja) * 2008-07-03 2011-10-27 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー 循環触媒流中の重質物の制御プロセス
JP2013508274A (ja) * 2009-10-16 2013-03-07 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー 気相ヒドロホルミル化方法
JP2015218173A (ja) * 2014-05-20 2015-12-07 エボニック インダストリーズ アクチエンゲゼルシャフトＥｖｏｎｉｋ Ｉｎｄｕｓｔｒｉｅｓ ＡＧ ｔ−ブチルオキシカルボニル基を有する新規のモノホスフィット配位子
JP2015221795A (ja) * 2014-05-20 2015-12-10 エボニック インダストリーズ アクチエンゲゼルシャフトＥｖｏｎｉｋ Ｉｎｄｕｓｔｒｉｅｓ ＡＧ モノホスフィット混合物を使用したオレフィンからのアルデヒドの触媒的製造方法
JP2021501141A (ja) * 2017-10-25 2021-01-14 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化プロセス中に形成されるアルデヒド化合物を含む溶液中の重質形成を低減する方法
WO2021160448A1 (de) * 2020-02-11 2021-08-19 Basf Se Niederdruckhydroformylierung von diisobuten

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US4518809A (en) 1981-06-11 1985-05-21 Monsanto Company Preparation of pentyl nonanols
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5817430A (ja) * 1981-07-10 1983-02-01 チバ・ガイギ−・アクチエンゲゼルシヤフト 写真感光材料
JPH04505931A (ja) * 1989-12-08 1992-10-15 ユニロイヤル　ケミカル　カンパニー　インコーポレイテッド 立体的ヒンダードアリールフォスファイトの製造法
JP2009163029A (ja) * 2008-01-08 2009-07-23 Konica Minolta Opto Inc 光学フィルム、光学フィルムの製造方法、それを用いた偏光板、及び液晶表示装置
JP2011527287A (ja) * 2008-07-03 2011-10-27 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー 循環触媒流中の重質物の制御プロセス
JP2013508274A (ja) * 2009-10-16 2013-03-07 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー 気相ヒドロホルミル化方法
JP2015218173A (ja) * 2014-05-20 2015-12-07 エボニック インダストリーズ アクチエンゲゼルシャフトＥｖｏｎｉｋ Ｉｎｄｕｓｔｒｉｅｓ ＡＧ ｔ−ブチルオキシカルボニル基を有する新規のモノホスフィット配位子
JP2015221795A (ja) * 2014-05-20 2015-12-10 エボニック インダストリーズ アクチエンゲゼルシャフトＥｖｏｎｉｋ Ｉｎｄｕｓｔｒｉｅｓ ＡＧ モノホスフィット混合物を使用したオレフィンからのアルデヒドの触媒的製造方法
JP2021501141A (ja) * 2017-10-25 2021-01-14 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化プロセス中に形成されるアルデヒド化合物を含む溶液中の重質形成を低減する方法
WO2021160448A1 (de) * 2020-02-11 2021-08-19 Basf Se Niederdruckhydroformylierung von diisobuten

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EP4448170A1 (en) 2024-10-23
US20250128245A1 (en) 2025-04-24
ZA202405190B (en) 2025-10-29
CN118317834A (zh) 2024-07-09
EP4448170B1 (en) 2025-08-20
WO2023114579A1 (en) 2023-06-22

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