JP2024501217A - バガス含有グアユールゴムとシランとを組み合わせたゴム組成物及び関連する方法 - Google Patents
バガス含有グアユールゴムとシランとを組み合わせたゴム組成物及び関連する方法 Download PDFInfo
- Publication number
- JP2024501217A JP2024501217A JP2023537121A JP2023537121A JP2024501217A JP 2024501217 A JP2024501217 A JP 2024501217A JP 2023537121 A JP2023537121 A JP 2023537121A JP 2023537121 A JP2023537121 A JP 2023537121A JP 2024501217 A JP2024501217 A JP 2024501217A
- Authority
- JP
- Japan
- Prior art keywords
- rubber composition
- rubber
- tire
- phr
- bis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920001971 elastomer Polymers 0.000 title claims abstract description 319
- 239000005060 rubber Substances 0.000 title claims abstract description 313
- 239000000203 mixture Substances 0.000 title claims abstract description 184
- 241001495453 Parthenium argentatum Species 0.000 title claims abstract description 115
- LOVYCUYJRWLTSU-UHFFFAOYSA-N 2-(3,4-dichlorophenoxy)-n,n-diethylethanamine Chemical compound CCN(CC)CCOC1=CC=C(Cl)C(Cl)=C1 LOVYCUYJRWLTSU-UHFFFAOYSA-N 0.000 title claims abstract description 107
- 229910000077 silane Inorganic materials 0.000 title claims abstract description 82
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 title claims abstract description 80
- 241000609240 Ambelania acida Species 0.000 title claims abstract description 44
- 239000010905 bagasse Substances 0.000 title claims abstract description 44
- 238000000034 method Methods 0.000 title claims abstract description 35
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 58
- TXDNPSYEJHXKMK-UHFFFAOYSA-N sulfanylsilane Chemical class S[SiH3] TXDNPSYEJHXKMK-UHFFFAOYSA-N 0.000 claims abstract description 41
- 239000000945 filler Substances 0.000 claims abstract description 39
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 29
- 238000005096 rolling process Methods 0.000 claims abstract description 23
- 229910052717 sulfur Inorganic materials 0.000 claims description 46
- 239000011593 sulfur Substances 0.000 claims description 45
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 44
- 229920005989 resin Polymers 0.000 claims description 43
- 239000011347 resin Substances 0.000 claims description 43
- 244000043261 Hevea brasiliensis Species 0.000 claims description 37
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 36
- -1 trimethoxysilylpropyl Chemical group 0.000 claims description 36
- 229920001194 natural rubber Polymers 0.000 claims description 35
- 239000002174 Styrene-butadiene Substances 0.000 claims description 29
- 229920003052 natural elastomer Polymers 0.000 claims description 29
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 claims description 28
- 229920002857 polybutadiene Polymers 0.000 claims description 20
- 125000000217 alkyl group Chemical group 0.000 claims description 14
- 125000003545 alkoxy group Chemical group 0.000 claims description 12
- 125000003118 aryl group Chemical group 0.000 claims description 12
- 229920001195 polyisoprene Polymers 0.000 claims description 11
- 239000005062 Polybutadiene Substances 0.000 claims description 9
- 239000006235 reinforcing carbon black Substances 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 5
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 3
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 239000011115 styrene butadiene Substances 0.000 claims description 3
- 125000000753 cycloalkyl group Chemical group 0.000 claims 1
- 238000010586 diagram Methods 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 61
- 235000019198 oils Nutrition 0.000 description 61
- 239000006229 carbon black Substances 0.000 description 26
- 235000019241 carbon black Nutrition 0.000 description 26
- 238000004073 vulcanization Methods 0.000 description 26
- 239000004014 plasticizer Substances 0.000 description 25
- 239000003795 chemical substances by application Substances 0.000 description 22
- 239000012763 reinforcing filler Substances 0.000 description 19
- 150000002148 esters Chemical class 0.000 description 17
- 229920000642 polymer Polymers 0.000 description 17
- 239000004615 ingredient Substances 0.000 description 12
- 239000012936 vulcanization activator Substances 0.000 description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 11
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
- 239000004606 Fillers/Extenders Substances 0.000 description 8
- 239000003112 inhibitor Substances 0.000 description 8
- 150000004756 silanes Chemical class 0.000 description 8
- 125000002947 alkylene group Chemical group 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 7
- 229920002554 vinyl polymer Polymers 0.000 description 7
- 239000013032 Hydrocarbon resin Substances 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 6
- 239000003963 antioxidant agent Substances 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 239000000806 elastomer Substances 0.000 description 6
- 125000000524 functional group Chemical group 0.000 description 6
- 229920006270 hydrocarbon resin Polymers 0.000 description 6
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 5
- 238000005227 gel permeation chromatography Methods 0.000 description 5
- 229910052736 halogen Inorganic materials 0.000 description 5
- 150000002367 halogens Chemical class 0.000 description 5
- 239000003208 petroleum Substances 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 229960002447 thiram Drugs 0.000 description 5
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 5
- 239000011787 zinc oxide Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
- 235000021355 Stearic acid Nutrition 0.000 description 4
- 235000019486 Sunflower oil Nutrition 0.000 description 4
- 235000005187 Taraxacum officinale ssp. officinale Nutrition 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 125000004450 alkenylene group Chemical group 0.000 description 4
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 4
- 239000006231 channel black Substances 0.000 description 4
- 229920003211 cis-1,4-polyisoprene Polymers 0.000 description 4
- AUZONCFQVSMFAP-UHFFFAOYSA-N disulfiram Chemical compound CCN(CC)C(=S)SSC(=S)N(CC)CC AUZONCFQVSMFAP-UHFFFAOYSA-N 0.000 description 4
- 229920001519 homopolymer Polymers 0.000 description 4
- 239000003999 initiator Substances 0.000 description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 230000003014 reinforcing effect Effects 0.000 description 4
- 239000008117 stearic acid Substances 0.000 description 4
- 239000002600 sunflower oil Substances 0.000 description 4
- 150000003585 thioureas Chemical class 0.000 description 4
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 3
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 3
- 239000006236 Super Abrasion Furnace Substances 0.000 description 3
- 241000245665 Taraxacum Species 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 229920006026 co-polymeric resin Polymers 0.000 description 3
- 239000008380 degradant Substances 0.000 description 3
- 238000000113 differential scanning calorimetry Methods 0.000 description 3
- 125000005842 heteroatom Chemical group 0.000 description 3
- RLAWWYSOJDYHDC-BZSNNMDCSA-N lisinopril Chemical compound C([C@H](N[C@@H](CCCCN)C(=O)N1[C@@H](CCC1)C(O)=O)C(O)=O)CC1=CC=CC=C1 RLAWWYSOJDYHDC-BZSNNMDCSA-N 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 3
- 239000011236 particulate material Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000003549 soybean oil Substances 0.000 description 3
- 235000012424 soybean oil Nutrition 0.000 description 3
- 238000010561 standard procedure Methods 0.000 description 3
- 125000004434 sulfur atom Chemical group 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 description 3
- 239000008158 vegetable oil Substances 0.000 description 3
- 235000013311 vegetables Nutrition 0.000 description 3
- 239000003643 water by type Substances 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- JAEZSIYNWDWMMN-UHFFFAOYSA-N 1,1,3-trimethylthiourea Chemical compound CNC(=S)N(C)C JAEZSIYNWDWMMN-UHFFFAOYSA-N 0.000 description 2
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 2
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 description 2
- CPGFMWPQXUXQRX-UHFFFAOYSA-N 3-amino-3-(4-fluorophenyl)propanoic acid Chemical compound OC(=O)CC(N)C1=CC=C(F)C=C1 CPGFMWPQXUXQRX-UHFFFAOYSA-N 0.000 description 2
- BUZICZZQJDLXJN-UHFFFAOYSA-N 3-azaniumyl-4-hydroxybutanoate Chemical compound OCC(N)CC(O)=O BUZICZZQJDLXJN-UHFFFAOYSA-N 0.000 description 2
- YSRUGGVNBXSYMN-UHFFFAOYSA-N 3-dimethoxysilylbutoxy-(3-dimethoxysilylbutylsulfanyl)-methyl-sulfanylidene-lambda5-phosphane Chemical compound CO[SiH](OC)C(C)CCOP(C)(=S)SCCC(C)[SiH](OC)OC YSRUGGVNBXSYMN-UHFFFAOYSA-N 0.000 description 2
- 229910052582 BN Inorganic materials 0.000 description 2
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 2
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- 239000006238 High Abrasion Furnace Substances 0.000 description 2
- 239000005063 High cis polybutadiene Substances 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- FLVIGYVXZHLUHP-UHFFFAOYSA-N N,N'-diethylthiourea Chemical compound CCNC(=S)NCC FLVIGYVXZHLUHP-UHFFFAOYSA-N 0.000 description 2
- FCSHMCFRCYZTRQ-UHFFFAOYSA-N N,N'-diphenylthiourea Chemical compound C=1C=CC=CC=1NC(=S)NC1=CC=CC=C1 FCSHMCFRCYZTRQ-UHFFFAOYSA-N 0.000 description 2
- 238000005481 NMR spectroscopy Methods 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000006242 Semi-Reinforcing Furnace Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000010692 aromatic oil Substances 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- QOTYLQBPNZRMNL-UHFFFAOYSA-N bis(2-methylpropyl)carbamothioylsulfanyl n,n-bis(2-methylpropyl)carbamodithioate Chemical compound CC(C)CN(CC(C)C)C(=S)SSC(=S)N(CC(C)C)CC(C)C QOTYLQBPNZRMNL-UHFFFAOYSA-N 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- WITDFSFZHZYQHB-UHFFFAOYSA-N dibenzylcarbamothioylsulfanyl n,n-dibenzylcarbamodithioate Chemical compound C=1C=CC=CC=1CN(CC=1C=CC=CC=1)C(=S)SSC(=S)N(CC=1C=CC=CC=1)CC1=CC=CC=C1 WITDFSFZHZYQHB-UHFFFAOYSA-N 0.000 description 2
- VSYLGGHSEIWGJV-UHFFFAOYSA-N diethyl(dimethoxy)silane Chemical compound CC[Si](CC)(OC)OC VSYLGGHSEIWGJV-UHFFFAOYSA-N 0.000 description 2
- 238000001938 differential scanning calorimetry curve Methods 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 230000014509 gene expression Effects 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- IUJLOAKJZQBENM-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)-2-methylpropan-2-amine Chemical compound C1=CC=C2SC(SNC(C)(C)C)=NC2=C1 IUJLOAKJZQBENM-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 235000014571 nuts Nutrition 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 239000005077 polysulfide Substances 0.000 description 2
- 229920001021 polysulfide Polymers 0.000 description 2
- 150000008117 polysulfides Polymers 0.000 description 2
- 238000001542 size-exclusion chromatography Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229920003051 synthetic elastomer Polymers 0.000 description 2
- BGHCVCJVXZWKCC-UHFFFAOYSA-N tetradecane Chemical compound CCCCCCCCCCCCCC BGHCVCJVXZWKCC-UHFFFAOYSA-N 0.000 description 2
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 2
- 150000003626 triacylglycerols Chemical class 0.000 description 2
- FOQJQXVUMYLJSU-UHFFFAOYSA-N triethoxy(1-triethoxysilylethyl)silane Chemical compound CCO[Si](OCC)(OCC)C(C)[Si](OCC)(OCC)OCC FOQJQXVUMYLJSU-UHFFFAOYSA-N 0.000 description 2
- BSNAHZCVWXDRTK-UHFFFAOYSA-N trimethoxy(5-trimethoxysilylnonan-5-yl)silane Chemical compound CO[Si](OC)(OC)C(CCCC)(CCCC)[Si](OC)(OC)OC BSNAHZCVWXDRTK-UHFFFAOYSA-N 0.000 description 2
- XEUVNVNAVKZSPT-JTJYXVOQSA-N (2S,3S)-N-(6-amino-6-oxohexyl)-2-[[(2S)-2-(hexanoylamino)-3-(4-hydroxyphenyl)propanoyl]amino]-3-methylpentanamide Chemical compound CCCCCC(=O)N[C@@H](Cc1ccc(O)cc1)C(=O)N[C@@H]([C@@H](C)CC)C(=O)NCCCCCC(N)=O XEUVNVNAVKZSPT-JTJYXVOQSA-N 0.000 description 1
- VXLFMCZPFIKKDZ-UHFFFAOYSA-N (4-methylphenyl)thiourea Chemical compound CC1=CC=C(NC(N)=S)C=C1 VXLFMCZPFIKKDZ-UHFFFAOYSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- KCOYHFNCTWXETP-UHFFFAOYSA-N (carbamothioylamino)thiourea Chemical compound NC(=S)NNC(N)=S KCOYHFNCTWXETP-UHFFFAOYSA-N 0.000 description 1
- FPZXQVCYHDMIIA-UHFFFAOYSA-N 1,1-diphenylthiourea Chemical compound C=1C=CC=CC=1N(C(=S)N)C1=CC=CC=C1 FPZXQVCYHDMIIA-UHFFFAOYSA-N 0.000 description 1
- HIACAHMKXQESOV-UHFFFAOYSA-N 1,2-bis(prop-1-en-2-yl)benzene Chemical compound CC(=C)C1=CC=CC=C1C(C)=C HIACAHMKXQESOV-UHFFFAOYSA-N 0.000 description 1
- KWPNNZKRAQDVPZ-UHFFFAOYSA-N 1,3-bis(2-methylphenyl)thiourea Chemical compound CC1=CC=CC=C1NC(=S)NC1=CC=CC=C1C KWPNNZKRAQDVPZ-UHFFFAOYSA-N 0.000 description 1
- ULNVBRUIKLYGDF-UHFFFAOYSA-N 1,3-bis(4-methylphenyl)thiourea Chemical compound C1=CC(C)=CC=C1NC(=S)NC1=CC=C(C)C=C1 ULNVBRUIKLYGDF-UHFFFAOYSA-N 0.000 description 1
- KREOCUNMMFZOOS-UHFFFAOYSA-N 1,3-di(propan-2-yl)thiourea Chemical compound CC(C)NC(S)=NC(C)C KREOCUNMMFZOOS-UHFFFAOYSA-N 0.000 description 1
- KAJICSGLHKRDLN-UHFFFAOYSA-N 1,3-dicyclohexylthiourea Chemical compound C1CCCCC1NC(=S)NC1CCCCC1 KAJICSGLHKRDLN-UHFFFAOYSA-N 0.000 description 1
- DEILIWSHLDNQRR-UHFFFAOYSA-N 1-(2-triethoxysilyl-4-bicyclo[2.2.1]hept-2-enyl)ethanethione Chemical compound C1CC2C([Si](OCC)(OCC)OCC)=CC1(C(C)=S)C2 DEILIWSHLDNQRR-UHFFFAOYSA-N 0.000 description 1
- BEINZVXQFFJBGC-UHFFFAOYSA-N 1-(2-triethoxysilyl-5-bicyclo[2.2.1]hept-2-enyl)ethanethione Chemical compound C1C2C([Si](OCC)(OCC)OCC)=CC1C(C(C)=S)C2 BEINZVXQFFJBGC-UHFFFAOYSA-N 0.000 description 1
- ZVFSAUUMYMGGCR-UHFFFAOYSA-N 1-[2-(2-triethoxysilylethyl)-4-bicyclo[2.2.1]hept-2-enyl]ethanethione Chemical compound C1CC2C(CC[Si](OCC)(OCC)OCC)=CC1(C(C)=S)C2 ZVFSAUUMYMGGCR-UHFFFAOYSA-N 0.000 description 1
- RYTALXFKQSSDOL-UHFFFAOYSA-N 1-[2-(2-triethoxysilylethyl)-5-bicyclo[2.2.1]hept-2-enyl]ethanethione Chemical compound C1C2C(CC[Si](OCC)(OCC)OCC)=CC1C(C(C)=S)C2 RYTALXFKQSSDOL-UHFFFAOYSA-N 0.000 description 1
- AVLPDYQOOBNGLR-UHFFFAOYSA-N 1-[3-(2-triethoxysilylethyl)cyclohexyl]ethanethione Chemical compound CCO[Si](OCC)(OCC)CCC1CCCC(C(C)=S)C1 AVLPDYQOOBNGLR-UHFFFAOYSA-N 0.000 description 1
- FSLUHJNPNRHGBF-UHFFFAOYSA-N 1-[4-(2-triethoxysilylethyl)cyclohexyl]ethanethione Chemical compound CCO[Si](OCC)(OCC)CCC1CCC(C(C)=S)CC1 FSLUHJNPNRHGBF-UHFFFAOYSA-N 0.000 description 1
- ZJNLYGOUHDJHMG-UHFFFAOYSA-N 1-n,4-n-bis(5-methylhexan-2-yl)benzene-1,4-diamine Chemical compound CC(C)CCC(C)NC1=CC=C(NC(C)CCC(C)C)C=C1 ZJNLYGOUHDJHMG-UHFFFAOYSA-N 0.000 description 1
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- JXNPYDJBQLMKJP-UHFFFAOYSA-N 18-[chloro(diethoxy)silyl]octadecane-1-thiol Chemical compound CCO[Si](Cl)(OCC)CCCCCCCCCCCCCCCCCCS JXNPYDJBQLMKJP-UHFFFAOYSA-N 0.000 description 1
- ZNRLMGFXSPUZNR-UHFFFAOYSA-N 2,2,4-trimethyl-1h-quinoline Chemical compound C1=CC=C2C(C)=CC(C)(C)NC2=C1 ZNRLMGFXSPUZNR-UHFFFAOYSA-N 0.000 description 1
- YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 description 1
- 229940054266 2-mercaptobenzothiazole Drugs 0.000 description 1
- DVNPFNZTPMWRAX-UHFFFAOYSA-N 2-triethoxysilylethanethiol Chemical compound CCO[Si](CCS)(OCC)OCC DVNPFNZTPMWRAX-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- GNEKGOAYZYCYGD-UHFFFAOYSA-N 3-(2H-benzotriazol-4-yl)propyl-trimethoxysilane Chemical compound CO[Si](CCCC1=CC=CC=2NN=NC=21)(OC)OC GNEKGOAYZYCYGD-UHFFFAOYSA-N 0.000 description 1
- DFWCPLGXFMSUCW-UHFFFAOYSA-N 3-(dimethylamino)propyl carbamimidothioate;hydron;dichloride Chemical compound Cl.Cl.CN(C)CCCSC(N)=N DFWCPLGXFMSUCW-UHFFFAOYSA-N 0.000 description 1
- NLJVXZFCYKWXLH-DXTIXLATSA-N 3-[(3r,6s,9s,12s,15s,17s,20s,22r,25s,28s)-20-(2-amino-2-oxoethyl)-9-(3-aminopropyl)-3,22,25-tribenzyl-15-[(4-hydroxyphenyl)methyl]-6-(2-methylpropyl)-2,5,8,11,14,18,21,24,27-nonaoxo-12-propan-2-yl-1,4,7,10,13,16,19,23,26-nonazabicyclo[26.3.0]hentriacontan Chemical compound C([C@H]1C(=O)N[C@H](C(=O)N[C@@H](CCCN)C(=O)N[C@H](C(N[C@H](CC=2C=CC=CC=2)C(=O)N2CCC[C@H]2C(=O)N[C@@H](CC=2C=CC=CC=2)C(=O)N[C@H](CC=2C=CC=CC=2)C(=O)[C@H](CC(N)=O)NC(=O)[C@H](CCC(O)=O)N1)=O)CC(C)C)C(C)C)C1=CC=C(O)C=C1 NLJVXZFCYKWXLH-DXTIXLATSA-N 0.000 description 1
- MBNRBJNIYVXSQV-UHFFFAOYSA-N 3-[diethoxy(methyl)silyl]propane-1-thiol Chemical compound CCO[Si](C)(OCC)CCCS MBNRBJNIYVXSQV-UHFFFAOYSA-N 0.000 description 1
- XCOFOOGNWJLSDM-UHFFFAOYSA-N 3-dimethoxysilylbutoxy-bis(3-dimethoxysilylbutylsulfanyl)-sulfanylidene-lambda5-phosphane Chemical compound CO[SiH](OC)C(C)CCOP(=S)(SCCC(C)[SiH](OC)OC)SCCC(C)[SiH](OC)OC XCOFOOGNWJLSDM-UHFFFAOYSA-N 0.000 description 1
- CZKIATYJHXKWFK-UHFFFAOYSA-N 3-methyl-11-triethoxysilylundecanethioic S-acid Chemical compound CCO[Si](OCC)(OCC)CCCCCCCCC(C)CC(S)=O CZKIATYJHXKWFK-UHFFFAOYSA-N 0.000 description 1
- XHNGORVETGDZTH-UHFFFAOYSA-N 3-methyl-5-triethoxysilylpentanethioic s-acid Chemical compound CCO[Si](OCC)(OCC)CCC(C)CC(S)=O XHNGORVETGDZTH-UHFFFAOYSA-N 0.000 description 1
- DAYRVMQCDGKGGD-UHFFFAOYSA-N 3-methyl-7-triethoxysilylheptanethioic S-acid Chemical compound CCO[Si](OCC)(OCC)CCCCC(C)CC(S)=O DAYRVMQCDGKGGD-UHFFFAOYSA-N 0.000 description 1
- ZQFSFGBBEVOFFB-UHFFFAOYSA-N 3-methyl-9-triethoxysilylnonanethioic S-acid Chemical compound CCO[Si](OCC)(OCC)CCCCCCC(C)CC(S)=O ZQFSFGBBEVOFFB-UHFFFAOYSA-N 0.000 description 1
- RJVOFVDYOUKVJM-UHFFFAOYSA-N 3-methyl-9-trimethoxysilylnonanethioic S-acid Chemical compound CO[Si](OC)(OC)CCCCCCC(C)CC(S)=O RJVOFVDYOUKVJM-UHFFFAOYSA-N 0.000 description 1
- JPSSZFVPDCJVFL-UHFFFAOYSA-N 3-propyl-7-triethoxysilylheptanethioic S-acid Chemical compound CCCC(CC(S)=O)CCCC[Si](OCC)(OCC)OCC JPSSZFVPDCJVFL-UHFFFAOYSA-N 0.000 description 1
- DCQBZYNUSLHVJC-UHFFFAOYSA-N 3-triethoxysilylpropane-1-thiol Chemical compound CCO[Si](OCC)(OCC)CCCS DCQBZYNUSLHVJC-UHFFFAOYSA-N 0.000 description 1
- ZZMVLMVFYMGSMY-UHFFFAOYSA-N 4-n-(4-methylpentan-2-yl)-1-n-phenylbenzene-1,4-diamine Chemical compound C1=CC(NC(C)CC(C)C)=CC=C1NC1=CC=CC=C1 ZZMVLMVFYMGSMY-UHFFFAOYSA-N 0.000 description 1
- VRKQEIXDEZVPSY-UHFFFAOYSA-N 4-n-phenyl-4-n-propan-2-ylbenzene-1,4-diamine Chemical compound C=1C=C(N)C=CC=1N(C(C)C)C1=CC=CC=C1 VRKQEIXDEZVPSY-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- PIVQQUNOTICCSA-UHFFFAOYSA-N ANTU Chemical compound C1=CC=C2C(NC(=S)N)=CC=CC2=C1 PIVQQUNOTICCSA-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- VZPZIIRLVSSFPV-UHFFFAOYSA-N C(C)(=O)OSC(C)[Si](OC(C)=O)(OC(C)=O)OC(C)=O Chemical compound C(C)(=O)OSC(C)[Si](OC(C)=O)(OC(C)=O)OC(C)=O VZPZIIRLVSSFPV-UHFFFAOYSA-N 0.000 description 1
- PUWODOWHRBTFLK-UHFFFAOYSA-N C(C)O[Si](OCC)(OCC)COS(=O)(=S)CC Chemical compound C(C)O[Si](OCC)(OCC)COS(=O)(=S)CC PUWODOWHRBTFLK-UHFFFAOYSA-N 0.000 description 1
- FDJLHMMBYKZDOF-UHFFFAOYSA-N C(C)O[Si](OCC)(OCC)COS(=O)(=S)CC1=CC=CC=C1 Chemical compound C(C)O[Si](OCC)(OCC)COS(=O)(=S)CC1=CC=CC=C1 FDJLHMMBYKZDOF-UHFFFAOYSA-N 0.000 description 1
- KCIFKTPIROBBLU-UHFFFAOYSA-N C(CCCCCCCCCCCC)[Si](OC)(OC)CCCCCCCCCCCCC Chemical compound C(CCCCCCCCCCCC)[Si](OC)(OC)CCCCCCCCCCCCC KCIFKTPIROBBLU-UHFFFAOYSA-N 0.000 description 1
- UMKAENXDQKKGPE-UHFFFAOYSA-N C(CCCCCCCCCCCCCC)[Si](OC)(OC)CCCCCCCCCCCCCCC Chemical compound C(CCCCCCCCCCCCCC)[Si](OC)(OC)CCCCCCCCCCCCCCC UMKAENXDQKKGPE-UHFFFAOYSA-N 0.000 description 1
- DGKLDDMLSHZDBC-UHFFFAOYSA-N C(CCCCCCCCCCCCCCCC)[Si](OC)(OC)CCCCCCCCCCCCCCCCC Chemical compound C(CCCCCCCCCCCCCCCC)[Si](OC)(OC)CCCCCCCCCCCCCCCCC DGKLDDMLSHZDBC-UHFFFAOYSA-N 0.000 description 1
- SQCDFRZTWJYYSV-UHFFFAOYSA-N C1=CC=C2C(S(=O)(=S)OC[Si](OCC)(OCC)OCC)=CC=CC2=C1 Chemical compound C1=CC=C2C(S(=O)(=S)OC[Si](OCC)(OCC)OCC)=CC=CC2=C1 SQCDFRZTWJYYSV-UHFFFAOYSA-N 0.000 description 1
- VWOCJSYXZSVJQY-UHFFFAOYSA-N CC(C)(C[SiH2]OC)C(O)=S Chemical compound CC(C)(C[SiH2]OC)C(O)=S VWOCJSYXZSVJQY-UHFFFAOYSA-N 0.000 description 1
- XUUMUAOLWOYCKK-UHFFFAOYSA-N CC(C)O[SiH2]CC(C)(C)C(O)=S Chemical compound CC(C)O[SiH2]CC(C)(C)C(O)=S XUUMUAOLWOYCKK-UHFFFAOYSA-N 0.000 description 1
- FJNUAAGMNLHEJS-UHFFFAOYSA-N CCO[SiH2]CC(C)(C)C(O)=S Chemical compound CCO[SiH2]CC(C)(C)C(O)=S FJNUAAGMNLHEJS-UHFFFAOYSA-N 0.000 description 1
- DKTGMWVQXPAOPX-UHFFFAOYSA-N CCO[Si](CCCC[S+]=S([O-])(O)=O)(OCC)OCC Chemical compound CCO[Si](CCCC[S+]=S([O-])(O)=O)(OCC)OCC DKTGMWVQXPAOPX-UHFFFAOYSA-N 0.000 description 1
- DFVVUQQSIRKQBX-UHFFFAOYSA-N CCO[Si](CCCSP(=S)(CC)SCCC[Si](OCC)(OCC)OCC)(OCC)OCC Chemical compound CCO[Si](CCCSP(=S)(CC)SCCC[Si](OCC)(OCC)OCC)(OCC)OCC DFVVUQQSIRKQBX-UHFFFAOYSA-N 0.000 description 1
- FSPIGXNLDXWYKZ-UHFFFAOYSA-N CCO[Si](CCC[S+]=C(N(C)C)SSSSC(N(C)C)=[S+]CCC[Si](OCC)(OCC)OCC)(OCC)OCC Chemical compound CCO[Si](CCC[S+]=C(N(C)C)SSSSC(N(C)C)=[S+]CCC[Si](OCC)(OCC)OCC)(OCC)OCC FSPIGXNLDXWYKZ-UHFFFAOYSA-N 0.000 description 1
- LAIDFYFXTGQDOB-UHFFFAOYSA-N CCO[Si](OCC)(OCC)CCCOP(C)(=S)SCCC[Si](OCC)(OCC)OCC Chemical compound CCO[Si](OCC)(OCC)CCCOP(C)(=S)SCCC[Si](OCC)(OCC)OCC LAIDFYFXTGQDOB-UHFFFAOYSA-N 0.000 description 1
- BXICXWXVNPQKTM-UHFFFAOYSA-N CCO[Si](OCC)(OCC)COS(=O)(=S)C1=CC=CC=C1 Chemical compound CCO[Si](OCC)(OCC)COS(=O)(=S)C1=CC=CC=C1 BXICXWXVNPQKTM-UHFFFAOYSA-N 0.000 description 1
- SKFGZHGVWONCTD-UHFFFAOYSA-N CN(C)C(SSSSC(N(C)C)=[S+]CCC[Si](OC)(OC)OC)=[S+]CCC[Si](OC)(OC)OC Chemical compound CN(C)C(SSSSC(N(C)C)=[S+]CCC[Si](OC)(OC)OC)=[S+]CCC[Si](OC)(OC)OC SKFGZHGVWONCTD-UHFFFAOYSA-N 0.000 description 1
- ROCMTYNCIFIFHG-UHFFFAOYSA-N CO[SiH](OC)C(C)CCOC(C)=S Chemical compound CO[SiH](OC)C(C)CCOC(C)=S ROCMTYNCIFIFHG-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 235000019492 Cashew oil Nutrition 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-UHFFFAOYSA-N Dicyclopentadiene Chemical compound C1C2C3CC=CC3C1C=C2 HECLRDQVFMWTQS-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- PDQAZBWRQCGBEV-UHFFFAOYSA-N Ethylenethiourea Chemical compound S=C1NCCN1 PDQAZBWRQCGBEV-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- PWWVAXIEGOYWEE-UHFFFAOYSA-N Isophenergan Chemical compound C1=CC=C2N(CC(C)N(C)C)C3=CC=CC=C3SC2=C1 PWWVAXIEGOYWEE-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 241000208467 Macadamia Species 0.000 description 1
- SPAGIJMPHSUYSE-UHFFFAOYSA-N Magnesium peroxide Chemical compound [Mg+2].[O-][O-] SPAGIJMPHSUYSE-UHFFFAOYSA-N 0.000 description 1
- VLCDUOXHFNUCKK-UHFFFAOYSA-N N,N'-Dimethylthiourea Chemical compound CNC(=S)NC VLCDUOXHFNUCKK-UHFFFAOYSA-N 0.000 description 1
- KFFQABQEJATQAT-UHFFFAOYSA-N N,N'-dibutylthiourea Chemical compound CCCCNC(=S)NCCCC KFFQABQEJATQAT-UHFFFAOYSA-N 0.000 description 1
- 108010055280 N-hexanoic-Tyr-Ile-(6) aminohexanoic amide Proteins 0.000 description 1
- OUBMGJOQLXMSNT-UHFFFAOYSA-N N-isopropyl-N'-phenyl-p-phenylenediamine Chemical compound C1=CC(NC(C)C)=CC=C1NC1=CC=CC=C1 OUBMGJOQLXMSNT-UHFFFAOYSA-N 0.000 description 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 1
- HFWNIEFOEWMVCF-UHFFFAOYSA-N O-(3-diethoxysilylbutyl) ethanethioate Chemical compound CCO[SiH](OCC)C(C)CCOC(C)=S HFWNIEFOEWMVCF-UHFFFAOYSA-N 0.000 description 1
- COQGTXSRUFWIHS-UHFFFAOYSA-N O-methyl 3-di(propan-2-yloxy)silylpropanethioate Chemical compound COC(CC[SiH](OC(C)C)OC(C)C)=S COQGTXSRUFWIHS-UHFFFAOYSA-N 0.000 description 1
- ZIRZHZPXSOKIGF-UHFFFAOYSA-N O-methyl 3-diethoxysilylpropanethioate Chemical compound COC(CC[SiH](OCC)OCC)=S ZIRZHZPXSOKIGF-UHFFFAOYSA-N 0.000 description 1
- UYKPRDGGENWWDO-UHFFFAOYSA-N O-methyl 3-dimethoxysilylpropanethioate Chemical compound COC(CC[SiH](OC)OC)=S UYKPRDGGENWWDO-UHFFFAOYSA-N 0.000 description 1
- MPGZXMZDKUWHLK-UHFFFAOYSA-N O-silyl hexanethioate Chemical compound CCCCCC(=S)O[SiH3] MPGZXMZDKUWHLK-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 235000019485 Safflower oil Nutrition 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 240000001949 Taraxacum officinale Species 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- WAPYKDZPBOBYSR-UHFFFAOYSA-N [[dihydroxy(oxo)-lambda6-sulfanylidene]-methyl-lambda4-sulfanyl]methyl-triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CS(C)=S(O)(O)=O WAPYKDZPBOBYSR-UHFFFAOYSA-N 0.000 description 1
- 239000006230 acetylene black Substances 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical class OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 1
- 150000004705 aldimines Chemical class 0.000 description 1
- 150000001339 alkali metal compounds Chemical class 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- UFADJPZTTUWZMP-UHFFFAOYSA-N azacyclotridecane Chemical compound C1CCCCCCNCCCCC1 UFADJPZTTUWZMP-UHFFFAOYSA-N 0.000 description 1
- ZSIQJIWKELUFRJ-UHFFFAOYSA-N azepane Chemical compound C1CCCNCC1 ZSIQJIWKELUFRJ-UHFFFAOYSA-N 0.000 description 1
- HONIICLYMWZJFZ-UHFFFAOYSA-N azetidine Chemical compound C1CNC1 HONIICLYMWZJFZ-UHFFFAOYSA-N 0.000 description 1
- QXNDZONIWRINJR-UHFFFAOYSA-N azocane Chemical compound C1CCCNCCC1 QXNDZONIWRINJR-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- CPLASELWOOUNGW-UHFFFAOYSA-N benzyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)CC1=CC=CC=C1 CPLASELWOOUNGW-UHFFFAOYSA-N 0.000 description 1
- GQVVQDJHRQBZNG-UHFFFAOYSA-N benzyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)CC1=CC=CC=C1 GQVVQDJHRQBZNG-UHFFFAOYSA-N 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- XGZGKDQVCBHSGI-UHFFFAOYSA-N butyl(triethoxy)silane Chemical compound CCCC[Si](OCC)(OCC)OCC XGZGKDQVCBHSGI-UHFFFAOYSA-N 0.000 description 1
- SXPLZNMUBFBFIA-UHFFFAOYSA-N butyl(trimethoxy)silane Chemical compound CCCC[Si](OC)(OC)OC SXPLZNMUBFBFIA-UHFFFAOYSA-N 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 239000010495 camellia oil Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N carbonic acid monoamide Natural products NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 239000010467 cashew oil Substances 0.000 description 1
- 229940059459 cashew oil Drugs 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- DBOHSCMZOJCWJN-UHFFFAOYSA-N decyl(dimethoxy)silane Chemical compound C(CCCCCCCCC)[SiH](OC)OC DBOHSCMZOJCWJN-UHFFFAOYSA-N 0.000 description 1
- BAAAEEDPKUHLID-UHFFFAOYSA-N decyl(triethoxy)silane Chemical compound CCCCCCCCCC[Si](OCC)(OCC)OCC BAAAEEDPKUHLID-UHFFFAOYSA-N 0.000 description 1
- KQAHMVLQCSALSX-UHFFFAOYSA-N decyl(trimethoxy)silane Chemical compound CCCCCCCCCC[Si](OC)(OC)OC KQAHMVLQCSALSX-UHFFFAOYSA-N 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- OKGXJRGLYVRVNE-UHFFFAOYSA-N diaminomethylidenethiourea Chemical compound NC(N)=NC(N)=S OKGXJRGLYVRVNE-UHFFFAOYSA-N 0.000 description 1
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 1
- MQMBHUJAMHWBHL-UHFFFAOYSA-N dibenzyl(diethoxy)silane Chemical compound C=1C=CC=CC=1C[Si](OCC)(OCC)CC1=CC=CC=C1 MQMBHUJAMHWBHL-UHFFFAOYSA-N 0.000 description 1
- NBHLGURMXJHIOD-UHFFFAOYSA-N dibenzyl(dimethoxy)silane Chemical compound C=1C=CC=CC=1C[Si](OC)(OC)CC1=CC=CC=C1 NBHLGURMXJHIOD-UHFFFAOYSA-N 0.000 description 1
- DGPFXVBYDAVXLX-UHFFFAOYSA-N dibutyl(diethoxy)silane Chemical compound CCCC[Si](OCC)(OCC)CCCC DGPFXVBYDAVXLX-UHFFFAOYSA-N 0.000 description 1
- YPENMAABQGWRBR-UHFFFAOYSA-N dibutyl(dimethoxy)silane Chemical compound CCCC[Si](OC)(OC)CCCC YPENMAABQGWRBR-UHFFFAOYSA-N 0.000 description 1
- SOWSAZZGDGKEQC-UHFFFAOYSA-N didecyl(diethoxy)silane Chemical compound CCCCCCCCCC[Si](OCC)(OCC)CCCCCCCCCC SOWSAZZGDGKEQC-UHFFFAOYSA-N 0.000 description 1
- TWPSMOUROSROLX-UHFFFAOYSA-N didecyl(dimethoxy)silane Chemical compound CCCCCCCCCC[Si](OC)(OC)CCCCCCCCCC TWPSMOUROSROLX-UHFFFAOYSA-N 0.000 description 1
- FUEDYEAZWKUUBC-UHFFFAOYSA-N didodecyl(diethoxy)silane Chemical compound CCCCCCCCCCCC[Si](OCC)(OCC)CCCCCCCCCCCC FUEDYEAZWKUUBC-UHFFFAOYSA-N 0.000 description 1
- LNNVEWRLQMHVPM-UHFFFAOYSA-N didodecyl(dimethoxy)silane Chemical compound CCCCCCCCCCCC[Si](OC)(OC)CCCCCCCCCCCC LNNVEWRLQMHVPM-UHFFFAOYSA-N 0.000 description 1
- ZMAPKOCENOWQRE-UHFFFAOYSA-N diethoxy(diethyl)silane Chemical compound CCO[Si](CC)(CC)OCC ZMAPKOCENOWQRE-UHFFFAOYSA-N 0.000 description 1
- NRMUHDACMQEQMT-UHFFFAOYSA-N diethoxy(diheptyl)silane Chemical compound CCCCCCC[Si](OCC)(OCC)CCCCCCC NRMUHDACMQEQMT-UHFFFAOYSA-N 0.000 description 1
- KILWRTYJSVLIHF-UHFFFAOYSA-N diethoxy(dihexadecyl)silane Chemical compound CCCCCCCCCCCCCCCC[Si](OCC)(OCC)CCCCCCCCCCCCCCCC KILWRTYJSVLIHF-UHFFFAOYSA-N 0.000 description 1
- QNRQOLWFDOEZPK-UHFFFAOYSA-N diethoxy(dioctadecyl)silane Chemical compound CCCCCCCCCCCCCCCCCC[Si](OCC)(OCC)CCCCCCCCCCCCCCCCCC QNRQOLWFDOEZPK-UHFFFAOYSA-N 0.000 description 1
- YETKAVVSNLUTEQ-UHFFFAOYSA-N diethoxy(dioctyl)silane Chemical compound CCCCCCCC[Si](OCC)(OCC)CCCCCCCC YETKAVVSNLUTEQ-UHFFFAOYSA-N 0.000 description 1
- ZZNQQQWFKKTOSD-UHFFFAOYSA-N diethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OCC)(OCC)C1=CC=CC=C1 ZZNQQQWFKKTOSD-UHFFFAOYSA-N 0.000 description 1
- HZLIIKNXMLEWPA-UHFFFAOYSA-N diethoxy(dipropyl)silane Chemical compound CCC[Si](CCC)(OCC)OCC HZLIIKNXMLEWPA-UHFFFAOYSA-N 0.000 description 1
- IOTSLZNUEPNPRH-UHFFFAOYSA-N diethoxy-di(heptadecyl)silane Chemical compound CCCCCCCCCCCCCCCCC[Si](OCC)(OCC)CCCCCCCCCCCCCCCCC IOTSLZNUEPNPRH-UHFFFAOYSA-N 0.000 description 1
- ANHOEAHRWZEGKP-UHFFFAOYSA-N diethoxy-di(nonadecyl)silane Chemical compound CCCCCCCCCCCCCCCCCCC[Si](OCC)(OCC)CCCCCCCCCCCCCCCCCCC ANHOEAHRWZEGKP-UHFFFAOYSA-N 0.000 description 1
- FLXFRIBPJKRXQW-UHFFFAOYSA-N diethoxy-di(nonyl)silane Chemical compound CCCCCCCCC[Si](OCC)(OCC)CCCCCCCCC FLXFRIBPJKRXQW-UHFFFAOYSA-N 0.000 description 1
- IDUBJPPLZNKGAE-UHFFFAOYSA-N diethoxy-di(pentadecyl)silane Chemical compound CCCCCCCCCCCCCCC[Si](OCC)(OCC)CCCCCCCCCCCCCCC IDUBJPPLZNKGAE-UHFFFAOYSA-N 0.000 description 1
- LGGUSYXVECMKAL-UHFFFAOYSA-N diethoxy-di(tetradecyl)silane Chemical compound CCCCCCCCCCCCCC[Si](OCC)(OCC)CCCCCCCCCCCCCC LGGUSYXVECMKAL-UHFFFAOYSA-N 0.000 description 1
- MQTFKGKZRBBCIR-UHFFFAOYSA-N diethoxy-di(tridecyl)silane Chemical compound CCCCCCCCCCCCC[Si](OCC)(OCC)CCCCCCCCCCCCC MQTFKGKZRBBCIR-UHFFFAOYSA-N 0.000 description 1
- YUWFWYQJEXYORA-UHFFFAOYSA-N diethoxy-di(undecyl)silane Chemical compound CCCCCCCCCCC[Si](OCC)(OCC)CCCCCCCCCCC YUWFWYQJEXYORA-UHFFFAOYSA-N 0.000 description 1
- ZWPNXHXXRLYCHZ-UHFFFAOYSA-N diethyl-di(propan-2-yloxy)silane Chemical compound CC(C)O[Si](CC)(CC)OC(C)C ZWPNXHXXRLYCHZ-UHFFFAOYSA-N 0.000 description 1
- DZBCKWWFOPPOCW-UHFFFAOYSA-N diheptyl(dimethoxy)silane Chemical compound CCCCCCC[Si](OC)(OC)CCCCCCC DZBCKWWFOPPOCW-UHFFFAOYSA-N 0.000 description 1
- CYICXDQJFWXGTC-UHFFFAOYSA-N dihexyl(dimethoxy)silane Chemical compound CCCCCC[Si](OC)(OC)CCCCCC CYICXDQJFWXGTC-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- JJQZDUKDJDQPMQ-UHFFFAOYSA-N dimethoxy(dimethyl)silane Chemical compound CO[Si](C)(C)OC JJQZDUKDJDQPMQ-UHFFFAOYSA-N 0.000 description 1
- IGIHUTKDVFZAMO-UHFFFAOYSA-N dimethoxy(dioctadecyl)silane Chemical compound CCCCCCCCCCCCCCCCCC[Si](OC)(OC)CCCCCCCCCCCCCCCCCC IGIHUTKDVFZAMO-UHFFFAOYSA-N 0.000 description 1
- TYXIAHKLJMLPIP-UHFFFAOYSA-N dimethoxy(dioctyl)silane Chemical compound CCCCCCCC[Si](OC)(OC)CCCCCCCC TYXIAHKLJMLPIP-UHFFFAOYSA-N 0.000 description 1
- AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical class C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 description 1
- JVUVKQDVTIIMOD-UHFFFAOYSA-N dimethoxy(dipropyl)silane Chemical compound CCC[Si](OC)(OC)CCC JVUVKQDVTIIMOD-UHFFFAOYSA-N 0.000 description 1
- VCRICHZQAVRLMZ-UHFFFAOYSA-N dimethoxy-di(nonadecyl)silane Chemical compound CCCCCCCCCCCCCCCCCCC[Si](CCCCCCCCCCCCCCCCCCC)(OC)OC VCRICHZQAVRLMZ-UHFFFAOYSA-N 0.000 description 1
- JPGUDOGITVIWAL-UHFFFAOYSA-N dimethoxy-di(nonyl)silane Chemical compound CCCCCCCCC[Si](OC)(OC)CCCCCCCCC JPGUDOGITVIWAL-UHFFFAOYSA-N 0.000 description 1
- NOJFFNKHLVRADJ-UHFFFAOYSA-N dimethoxy-di(tetradecyl)silane Chemical compound CCCCCCCCCCCCCC[Si](OC)(OC)CCCCCCCCCCCCCC NOJFFNKHLVRADJ-UHFFFAOYSA-N 0.000 description 1
- CASFJRHEBSEPJM-UHFFFAOYSA-N dimethoxy-di(undecyl)silane Chemical compound CCCCCCCCCCC[Si](OC)(OC)CCCCCCCCCCC CASFJRHEBSEPJM-UHFFFAOYSA-N 0.000 description 1
- ZIDTUTFKRRXWTK-UHFFFAOYSA-N dimethyl(dipropoxy)silane Chemical compound CCCO[Si](C)(C)OCCC ZIDTUTFKRRXWTK-UHFFFAOYSA-N 0.000 description 1
- BPXCAJONOPIXJI-UHFFFAOYSA-N dimethyl-di(propan-2-yloxy)silane Chemical compound CC(C)O[Si](C)(C)OC(C)C BPXCAJONOPIXJI-UHFFFAOYSA-N 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
- YYLGKUPAFFKGRQ-UHFFFAOYSA-N dimethyldiethoxysilane Chemical compound CCO[Si](C)(C)OCC YYLGKUPAFFKGRQ-UHFFFAOYSA-N 0.000 description 1
- SLAYMDSSGGBWQB-UHFFFAOYSA-N diphenyl(dipropoxy)silane Chemical compound C=1C=CC=CC=1[Si](OCCC)(OCCC)C1=CC=CC=C1 SLAYMDSSGGBWQB-UHFFFAOYSA-N 0.000 description 1
- QAPWZQHBOVKNHP-UHFFFAOYSA-N diphenyl-di(propan-2-yloxy)silane Chemical compound C=1C=CC=CC=1[Si](OC(C)C)(OC(C)C)C1=CC=CC=C1 QAPWZQHBOVKNHP-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 125000002228 disulfide group Chemical group 0.000 description 1
- YGUFXEJWPRRAEK-UHFFFAOYSA-N dodecyl(triethoxy)silane Chemical compound CCCCCCCCCCCC[Si](OCC)(OCC)OCC YGUFXEJWPRRAEK-UHFFFAOYSA-N 0.000 description 1
- SCPWMSBAGXEGPW-UHFFFAOYSA-N dodecyl(trimethoxy)silane Chemical compound CCCCCCCCCCCC[Si](OC)(OC)OC SCPWMSBAGXEGPW-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- SBRXLTRZCJVAPH-UHFFFAOYSA-N ethyl(trimethoxy)silane Chemical compound CC[Si](OC)(OC)OC SBRXLTRZCJVAPH-UHFFFAOYSA-N 0.000 description 1
- KUCGHDUQOVVQED-UHFFFAOYSA-N ethyl(tripropoxy)silane Chemical compound CCCO[Si](CC)(OCCC)OCCC KUCGHDUQOVVQED-UHFFFAOYSA-N 0.000 description 1
- MYEJNNDSIXAGNK-UHFFFAOYSA-N ethyl-tri(propan-2-yloxy)silane Chemical compound CC(C)O[Si](CC)(OC(C)C)OC(C)C MYEJNNDSIXAGNK-UHFFFAOYSA-N 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000006232 furnace black Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 239000010460 hemp oil Substances 0.000 description 1
- MLNCEQPFSFGNIW-UHFFFAOYSA-N heptadecyl(trimethoxy)silane Chemical compound CCCCCCCCCCCCCCCCC[Si](OC)(OC)OC MLNCEQPFSFGNIW-UHFFFAOYSA-N 0.000 description 1
- VRINOTYEGADLMW-UHFFFAOYSA-N heptyl(trimethoxy)silane Chemical compound CCCCCCC[Si](OC)(OC)OC VRINOTYEGADLMW-UHFFFAOYSA-N 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- RSKGMYDENCAJEN-UHFFFAOYSA-N hexadecyl(trimethoxy)silane Chemical compound CCCCCCCCCCCCCCCC[Si](OC)(OC)OC RSKGMYDENCAJEN-UHFFFAOYSA-N 0.000 description 1
- CZWLNMOIEMTDJY-UHFFFAOYSA-N hexyl(trimethoxy)silane Chemical compound CCCCCC[Si](OC)(OC)OC CZWLNMOIEMTDJY-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 150000002466 imines Chemical class 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- 150000004658 ketimines Chemical class 0.000 description 1
- 239000006233 lamp black Substances 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 238000010077 mastication Methods 0.000 description 1
- 230000018984 mastication Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- RJMRIDVWCWSWFR-UHFFFAOYSA-N methyl(tripropoxy)silane Chemical compound CCCO[Si](C)(OCCC)OCCC RJMRIDVWCWSWFR-UHFFFAOYSA-N 0.000 description 1
- PXUXHQNTATUDES-UHFFFAOYSA-N methyl-sulfanylidene-bis(3-triethoxysilylpropylsulfanyl)-$l^{5}-phosphane Chemical compound CCO[Si](OCC)(OCC)CCCSP(C)(=S)SCCC[Si](OCC)(OCC)OCC PXUXHQNTATUDES-UHFFFAOYSA-N 0.000 description 1
- HLXDKGBELJJMHR-UHFFFAOYSA-N methyl-tri(propan-2-yloxy)silane Chemical compound CC(C)O[Si](C)(OC(C)C)OC(C)C HLXDKGBELJJMHR-UHFFFAOYSA-N 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- DEQZTKGFXNUBJL-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)cyclohexanamine Chemical compound C1CCCCC1NSC1=NC2=CC=CC=C2S1 DEQZTKGFXNUBJL-UHFFFAOYSA-N 0.000 description 1
- SDNJNDFHCODQDQ-UHFFFAOYSA-N n-(2-ethylphenyl)-2-[[2-[(2-ethylphenyl)carbamoyl]phenyl]disulfanyl]benzamide Chemical compound CCC1=CC=CC=C1NC(=O)C1=CC=CC=C1SSC1=CC=CC=C1C(=O)NC1=CC=CC=C1CC SDNJNDFHCODQDQ-UHFFFAOYSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- GZNRISJLOXVOSH-UHFFFAOYSA-N n-phenylaniline;propan-2-one Chemical compound CC(C)=O.C=1C=CC=CC=1NC1=CC=CC=C1 GZNRISJLOXVOSH-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000010466 nut oil Substances 0.000 description 1
- 235000019488 nut oil Nutrition 0.000 description 1
- RVZJJFTUWQGPDM-UHFFFAOYSA-N o-(3-triethoxysilylpropyl) ethanethioate Chemical compound CCO[Si](OCC)(OCC)CCCOC(C)=S RVZJJFTUWQGPDM-UHFFFAOYSA-N 0.000 description 1
- QXBLIUBAPLUCFY-UHFFFAOYSA-N o-(triethoxysilylmethyl) ethanethioate Chemical compound CCO[Si](OCC)(OCC)COC(C)=S QXBLIUBAPLUCFY-UHFFFAOYSA-N 0.000 description 1
- DUGAFPBTRVNWOH-UHFFFAOYSA-N o-(trimethoxysilylmethyl) ethanethioate Chemical compound CO[Si](OC)(OC)COC(C)=S DUGAFPBTRVNWOH-UHFFFAOYSA-N 0.000 description 1
- XLHROWYJKQZJBU-UHFFFAOYSA-N o-[2-[diethoxy(methyl)silyl]ethyl] ethanethioate Chemical compound CCO[Si](C)(OCC)CCOC(C)=S XLHROWYJKQZJBU-UHFFFAOYSA-N 0.000 description 1
- YWVJNDNHFJEYCV-UHFFFAOYSA-N o-[2-[dimethyl(propan-2-yloxy)silyl]ethyl] ethanethioate Chemical compound CC(C)O[Si](C)(C)CCOC(C)=S YWVJNDNHFJEYCV-UHFFFAOYSA-N 0.000 description 1
- XNSYTOZFTIEDHZ-UHFFFAOYSA-N o-[2-[methoxy(dimethyl)silyl]ethyl] ethanethioate Chemical compound CO[Si](C)(C)CCOC(C)=S XNSYTOZFTIEDHZ-UHFFFAOYSA-N 0.000 description 1
- BRMSZTGNZHLNDG-UHFFFAOYSA-N o-[2-[methyl-di(propan-2-yloxy)silyl]ethyl] ethanethioate Chemical compound CC(C)O[Si](C)(OC(C)C)CCOC(C)=S BRMSZTGNZHLNDG-UHFFFAOYSA-N 0.000 description 1
- KRZHJDOXWGZKTG-UHFFFAOYSA-N o-[3-tri(propan-2-yloxy)silylpropyl] ethanethioate Chemical compound CC(C)O[Si](OC(C)C)(OC(C)C)CCCOC(C)=S KRZHJDOXWGZKTG-UHFFFAOYSA-N 0.000 description 1
- ACLZYRNSDLQOIA-UHFFFAOYSA-N o-tolylthiourea Chemical compound CC1=CC=CC=C1NC(N)=S ACLZYRNSDLQOIA-UHFFFAOYSA-N 0.000 description 1
- SLYCYWCVSGPDFR-UHFFFAOYSA-N octadecyltrimethoxysilane Chemical compound CCCCCCCCCCCCCCCCCC[Si](OC)(OC)OC SLYCYWCVSGPDFR-UHFFFAOYSA-N 0.000 description 1
- QTDSLDJPJJBBLE-PFONDFGASA-N octyl (z)-octadec-9-enoate Chemical compound CCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC QTDSLDJPJJBBLE-PFONDFGASA-N 0.000 description 1
- MSRJTTSHWYDFIU-UHFFFAOYSA-N octyltriethoxysilane Chemical compound CCCCCCCC[Si](OCC)(OCC)OCC MSRJTTSHWYDFIU-UHFFFAOYSA-N 0.000 description 1
- 229960003493 octyltriethoxysilane Drugs 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000002900 organolithium compounds Chemical class 0.000 description 1
- MMMNTDFSPSQXJP-UHFFFAOYSA-N orphenadrine citrate Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O.C=1C=CC=C(C)C=1C(OCCN(C)C)C1=CC=CC=C1 MMMNTDFSPSQXJP-UHFFFAOYSA-N 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- FABOKLHQXVRECE-UHFFFAOYSA-N phenyl(tripropoxy)silane Chemical compound CCCO[Si](OCCC)(OCCC)C1=CC=CC=C1 FABOKLHQXVRECE-UHFFFAOYSA-N 0.000 description 1
- VPLNCHFJAOKWBT-UHFFFAOYSA-N phenyl-tri(propan-2-yloxy)silane Chemical compound CC(C)O[Si](OC(C)C)(OC(C)C)C1=CC=CC=C1 VPLNCHFJAOKWBT-UHFFFAOYSA-N 0.000 description 1
- 150000004986 phenylenediamines Chemical class 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical class OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- DOIRQSBPFJWKBE-UHFFFAOYSA-N phthalic acid di-n-butyl ester Natural products CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
- 239000000088 plastic resin Substances 0.000 description 1
- 229920002589 poly(vinylethylene) polymer Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- ZMYXZXUHYAGGKG-UHFFFAOYSA-N propoxysilane Chemical compound CCCO[SiH3] ZMYXZXUHYAGGKG-UHFFFAOYSA-N 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000012453 solvate Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- KHTZKHQMYLOHFT-UHFFFAOYSA-N sulfanylidene-(3-triethoxysilylpropoxy)-bis(3-triethoxysilylpropylsulfanyl)-$l^{5}-phosphane Chemical compound CCO[Si](OCC)(OCC)CCCOP(=S)(SCCC[Si](OCC)(OCC)OCC)SCCC[Si](OCC)(OCC)OCC KHTZKHQMYLOHFT-UHFFFAOYSA-N 0.000 description 1
- VGGJNLGZARHOQV-UHFFFAOYSA-N sulfanylidene-tris(3-triethoxysilylpropylsulfanyl)-$l^{5}-phosphane Chemical compound CCO[Si](OCC)(OCC)CCCSP(=S)(SCCC[Si](OCC)(OCC)OCC)SCCC[Si](OCC)(OCC)OCC VGGJNLGZARHOQV-UHFFFAOYSA-N 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- UQMOLLPKNHFRAC-UHFFFAOYSA-N tetrabutyl silicate Chemical compound CCCCO[Si](OCCCC)(OCCCC)OCCCC UQMOLLPKNHFRAC-UHFFFAOYSA-N 0.000 description 1
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 1
- ZUEKXCXHTXJYAR-UHFFFAOYSA-N tetrapropan-2-yl silicate Chemical compound CC(C)O[Si](OC(C)C)(OC(C)C)OC(C)C ZUEKXCXHTXJYAR-UHFFFAOYSA-N 0.000 description 1
- ZQZCOBSUOFHDEE-UHFFFAOYSA-N tetrapropyl silicate Chemical compound CCCO[Si](OCCC)(OCCC)OCCC ZQZCOBSUOFHDEE-UHFFFAOYSA-N 0.000 description 1
- 238000002411 thermogravimetry Methods 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- KJAMZCVTJDTESW-UHFFFAOYSA-N tiracizine Chemical compound C1CC2=CC=CC=C2N(C(=O)CN(C)C)C2=CC(NC(=O)OCC)=CC=C21 KJAMZCVTJDTESW-UHFFFAOYSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- ZMQUGUDDFAJVJH-UHFFFAOYSA-N tributoxy(1-tributoxysilyldodecyl)silane Chemical compound CCCCCCCCCCCC([Si](OCCCC)(OCCCC)OCCCC)[Si](OCCCC)(OCCCC)OCCCC ZMQUGUDDFAJVJH-UHFFFAOYSA-N 0.000 description 1
- AWPLPHSSLZXKHL-UHFFFAOYSA-N tributoxy(1-tributoxysilylethyl)silane Chemical compound CCCCO[Si](OCCCC)(OCCCC)C(C)[Si](OCCCC)(OCCCC)OCCCC AWPLPHSSLZXKHL-UHFFFAOYSA-N 0.000 description 1
- NCQCNZLBOGWBOS-UHFFFAOYSA-N tributoxy(1-tributoxysilylhexyl)silane Chemical compound CCCCO[Si](OCCCC)(OCCCC)C(CCCCC)[Si](OCCCC)(OCCCC)OCCCC NCQCNZLBOGWBOS-UHFFFAOYSA-N 0.000 description 1
- TZFUCWAQBRWXQD-UHFFFAOYSA-N tributoxy(1-tributoxysilyloctadecyl)silane Chemical compound CCCCCCCCCCCCCCCCCC([Si](OCCCC)(OCCCC)OCCCC)[Si](OCCCC)(OCCCC)OCCCC TZFUCWAQBRWXQD-UHFFFAOYSA-N 0.000 description 1
- JTPDVCUBZOBXLM-UHFFFAOYSA-N tributoxy(1-tributoxysilyloctyl)silane Chemical compound CCCCCCCC([Si](OCCCC)(OCCCC)OCCCC)[Si](OCCCC)(OCCCC)OCCCC JTPDVCUBZOBXLM-UHFFFAOYSA-N 0.000 description 1
- UWLWMBCDDGTARD-UHFFFAOYSA-N tributoxy(2-tributoxysilylpropan-2-yl)silane Chemical compound C(CCC)O[Si](OCCCC)(OCCCC)C(C)(C)[Si](OCCCC)(OCCCC)OCCCC UWLWMBCDDGTARD-UHFFFAOYSA-N 0.000 description 1
- ZGSIXKHZBGIYNB-UHFFFAOYSA-N tributoxy(3-tributoxysilylbutan-2-yl)silane Chemical compound C(CCC)O[Si](OCCCC)(OCCCC)C(C(C)[Si](OCCCC)(OCCCC)OCCCC)C ZGSIXKHZBGIYNB-UHFFFAOYSA-N 0.000 description 1
- IZEWJWAKOQTMRC-UHFFFAOYSA-N tributoxy(4-tributoxysilylheptan-4-yl)silane Chemical compound C(CCC)O[Si](OCCCC)(OCCCC)C(CCC)(CCC)[Si](OCCCC)(OCCCC)OCCCC IZEWJWAKOQTMRC-UHFFFAOYSA-N 0.000 description 1
- DLEKQYZDIPMFDN-UHFFFAOYSA-N tributoxy(5-tributoxysilylnonan-5-yl)silane Chemical compound C(CCC)O[Si](OCCCC)(OCCCC)C(CCCC)(CCCC)[Si](OCCCC)(OCCCC)OCCCC DLEKQYZDIPMFDN-UHFFFAOYSA-N 0.000 description 1
- QTMRGVPEKFBONG-UHFFFAOYSA-N tributoxy-(1-tributoxysilylcyclohexyl)silane Chemical compound CCCCO[Si](OCCCC)(OCCCC)C1([Si](OCCCC)(OCCCC)OCCCC)CCCCC1 QTMRGVPEKFBONG-UHFFFAOYSA-N 0.000 description 1
- ALZWPWTXZQHIOC-UHFFFAOYSA-N tributoxy-(2-methyl-1-tributoxysilylpropyl)silane Chemical compound CCCCO[Si](OCCCC)(OCCCC)C(C(C)C)[Si](OCCCC)(OCCCC)OCCCC ALZWPWTXZQHIOC-UHFFFAOYSA-N 0.000 description 1
- LNOCCKQRSVTOEL-UHFFFAOYSA-N triethoxy(1-triethoxysilyldecyl)silane Chemical compound CCCCCCCCCC([Si](OCC)(OCC)OCC)[Si](OCC)(OCC)OCC LNOCCKQRSVTOEL-UHFFFAOYSA-N 0.000 description 1
- ZFNAIRQZVFZTTC-UHFFFAOYSA-N triethoxy(1-triethoxysilyldodecyl)silane Chemical compound CCCCCCCCCCCC([Si](OCC)(OCC)OCC)[Si](OCC)(OCC)OCC ZFNAIRQZVFZTTC-UHFFFAOYSA-N 0.000 description 1
- PGVSPORIGRCPMG-UHFFFAOYSA-N triethoxy(1-triethoxysilylhexyl)silane Chemical compound CCCCCC([Si](OCC)(OCC)OCC)[Si](OCC)(OCC)OCC PGVSPORIGRCPMG-UHFFFAOYSA-N 0.000 description 1
- SIRUCILCCGLRQU-UHFFFAOYSA-N triethoxy(1-triethoxysilyloctadecyl)silane Chemical compound CCCCCCCCCCCCCCCCCC([Si](OCC)(OCC)OCC)[Si](OCC)(OCC)OCC SIRUCILCCGLRQU-UHFFFAOYSA-N 0.000 description 1
- FJYFPOSTNXGNNE-UHFFFAOYSA-N triethoxy(1-triethoxysilyltetradecyl)silane Chemical compound CCCCCCCCCCCCCC([Si](OCC)(OCC)OCC)[Si](OCC)(OCC)OCC FJYFPOSTNXGNNE-UHFFFAOYSA-N 0.000 description 1
- KFZYOLRKZIKUSD-UHFFFAOYSA-N triethoxy(2-hydroxysulfonothioylethyl)silane Chemical compound CCO[Si](OCC)(OCC)CCS(O)(=O)=S KFZYOLRKZIKUSD-UHFFFAOYSA-N 0.000 description 1
- LMEKMHPYJBYBEV-UHFFFAOYSA-N triethoxy(2-triethoxysilylpropan-2-yl)silane Chemical compound CCO[Si](OCC)(OCC)C(C)(C)[Si](OCC)(OCC)OCC LMEKMHPYJBYBEV-UHFFFAOYSA-N 0.000 description 1
- IDGYYGWFOFXISD-UHFFFAOYSA-N triethoxy(3-triethoxysilylbutan-2-yl)silane Chemical compound C(C)O[Si](OCC)(OCC)C(C)C(C)[Si](OCC)(OCC)OCC IDGYYGWFOFXISD-UHFFFAOYSA-N 0.000 description 1
- BRTXVSVHFSOGED-UHFFFAOYSA-N triethoxy(4-hydroxysulfonothioylbutyl)silane Chemical compound CCO[Si](OCC)(OCC)CCCCS(O)(=O)=S BRTXVSVHFSOGED-UHFFFAOYSA-N 0.000 description 1
- RBDAXWQGOZWYFH-UHFFFAOYSA-N triethoxy(4-hydroxysulfonothioylpentyl)silane Chemical compound CCO[Si](OCC)(OCC)CCCC(C)S(O)(=O)=S RBDAXWQGOZWYFH-UHFFFAOYSA-N 0.000 description 1
- REHNGZXNSDPATK-UHFFFAOYSA-N triethoxy(4-triethoxysilylheptan-4-yl)silane Chemical compound C(C)O[Si](OCC)(OCC)C(CCC)(CCC)[Si](OCC)(OCC)OCC REHNGZXNSDPATK-UHFFFAOYSA-N 0.000 description 1
- QHRPMSHTURCGJV-UHFFFAOYSA-N triethoxy(5-triethoxysilylnonan-5-yl)silane Chemical compound C(C)O[Si](OCC)(OCC)C(CCCC)(CCCC)[Si](OCC)(OCC)OCC QHRPMSHTURCGJV-UHFFFAOYSA-N 0.000 description 1
- OSAJVUUALHWJEM-UHFFFAOYSA-N triethoxy(8-triethoxysilyloctyl)silane Chemical compound CCO[Si](OCC)(OCC)CCCCCCCC[Si](OCC)(OCC)OCC OSAJVUUALHWJEM-UHFFFAOYSA-N 0.000 description 1
- DENFJSAFJTVPJR-UHFFFAOYSA-N triethoxy(ethyl)silane Chemical compound CCO[Si](CC)(OCC)OCC DENFJSAFJTVPJR-UHFFFAOYSA-N 0.000 description 1
- IJJXVFCJVQEXHZ-UHFFFAOYSA-N triethoxy(heptadecyl)silane Chemical compound CCCCCCCCCCCCCCCCC[Si](OCC)(OCC)OCC IJJXVFCJVQEXHZ-UHFFFAOYSA-N 0.000 description 1
- SAWDTKLQESXBDN-UHFFFAOYSA-N triethoxy(heptyl)silane Chemical compound CCCCCCC[Si](OCC)(OCC)OCC SAWDTKLQESXBDN-UHFFFAOYSA-N 0.000 description 1
- OYGYKEULCAINCL-UHFFFAOYSA-N triethoxy(hexadecyl)silane Chemical compound CCCCCCCCCCCCCCCC[Si](OCC)(OCC)OCC OYGYKEULCAINCL-UHFFFAOYSA-N 0.000 description 1
- WUMSTCDLAYQDNO-UHFFFAOYSA-N triethoxy(hexyl)silane Chemical compound CCCCCC[Si](OCC)(OCC)OCC WUMSTCDLAYQDNO-UHFFFAOYSA-N 0.000 description 1
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 1
- HDYOCGKYEWQGDZ-UHFFFAOYSA-N triethoxy(nonadecyl)silane Chemical compound CCCCCCCCCCCCCCCCCCC[Si](OCC)(OCC)OCC HDYOCGKYEWQGDZ-UHFFFAOYSA-N 0.000 description 1
- FZXOVEZAKDRQJC-UHFFFAOYSA-N triethoxy(nonyl)silane Chemical compound CCCCCCCCC[Si](OCC)(OCC)OCC FZXOVEZAKDRQJC-UHFFFAOYSA-N 0.000 description 1
- FZMJEGJVKFTGMU-UHFFFAOYSA-N triethoxy(octadecyl)silane Chemical compound CCCCCCCCCCCCCCCCCC[Si](OCC)(OCC)OCC FZMJEGJVKFTGMU-UHFFFAOYSA-N 0.000 description 1
- ZJLGWINGXOQWDC-UHFFFAOYSA-N triethoxy(pentadecyl)silane Chemical compound CCCCCCCCCCCCCCC[Si](OCC)(OCC)OCC ZJLGWINGXOQWDC-UHFFFAOYSA-N 0.000 description 1
- FHVAUDREWWXPRW-UHFFFAOYSA-N triethoxy(pentyl)silane Chemical compound CCCCC[Si](OCC)(OCC)OCC FHVAUDREWWXPRW-UHFFFAOYSA-N 0.000 description 1
- JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 description 1
- NBXZNTLFQLUFES-UHFFFAOYSA-N triethoxy(propyl)silane Chemical compound CCC[Si](OCC)(OCC)OCC NBXZNTLFQLUFES-UHFFFAOYSA-N 0.000 description 1
- SVKDNKCAGJVMMY-UHFFFAOYSA-N triethoxy(tetradecyl)silane Chemical compound CCCCCCCCCCCCCC[Si](OCC)(OCC)OCC SVKDNKCAGJVMMY-UHFFFAOYSA-N 0.000 description 1
- IMAMKGXMSYGEGR-UHFFFAOYSA-N triethoxy(tridecyl)silane Chemical compound CCCCCCCCCCCCC[Si](OCC)(OCC)OCC IMAMKGXMSYGEGR-UHFFFAOYSA-N 0.000 description 1
- GEUTZGDMAQBSDN-UHFFFAOYSA-N triethoxy-(1-triethoxysilylcyclohexyl)silane Chemical compound CCO[Si](OCC)(OCC)C1([Si](OCC)(OCC)OCC)CCCCC1 GEUTZGDMAQBSDN-UHFFFAOYSA-N 0.000 description 1
- KSVGRSBRXDIQCL-UHFFFAOYSA-N triethoxy-(2-methyl-1-triethoxysilylpropyl)silane Chemical compound CCO[Si](OCC)(OCC)C(C(C)C)[Si](OCC)(OCC)OCC KSVGRSBRXDIQCL-UHFFFAOYSA-N 0.000 description 1
- SHQJOFANKPSLCU-UHFFFAOYSA-N triethoxy-(4-hydroxysulfonothioyl-4-propyl-3H-naphthalen-2-yl)silane Chemical compound C1=CC=C2C(CCC)(S(O)(=O)=S)CC([Si](OCC)(OCC)OCC)=CC2=C1 SHQJOFANKPSLCU-UHFFFAOYSA-N 0.000 description 1
- XGCGZQRQPNUUPB-UHFFFAOYSA-N triethoxy-(5-hydroxysulfonothioyl-5-propylcyclohexa-1,3-dien-1-yl)silane Chemical compound CCCC1(S(O)(=O)=S)CC([Si](OCC)(OCC)OCC)=CC=C1 XGCGZQRQPNUUPB-UHFFFAOYSA-N 0.000 description 1
- ASAOXGWSIOQTDI-UHFFFAOYSA-N triethoxy-[2-(2-triethoxysilylethyltetrasulfanyl)ethyl]silane Chemical compound CCO[Si](OCC)(OCC)CCSSSSCC[Si](OCC)(OCC)OCC ASAOXGWSIOQTDI-UHFFFAOYSA-N 0.000 description 1
- VTHOKNTVYKTUPI-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltetrasulfanyl)propyl]silane Chemical group CCO[Si](OCC)(OCC)CCCSSSSCCC[Si](OCC)(OCC)OCC VTHOKNTVYKTUPI-UHFFFAOYSA-N 0.000 description 1
- XSIGLRIVXRKQRA-UHFFFAOYSA-N triethoxysilylmethanethiol Chemical compound CCO[Si](CS)(OCC)OCC XSIGLRIVXRKQRA-UHFFFAOYSA-N 0.000 description 1
- HCLYZHGNBAMPQZ-UHFFFAOYSA-N trimethoxy(1-trimethoxysilyldecyl)silane Chemical compound CCCCCCCCCC([Si](OC)(OC)OC)[Si](OC)(OC)OC HCLYZHGNBAMPQZ-UHFFFAOYSA-N 0.000 description 1
- JSOPTJTYIPIDNM-UHFFFAOYSA-N trimethoxy(1-trimethoxysilyldodecyl)silane Chemical compound CCCCCCCCCCCC([Si](OC)(OC)OC)[Si](OC)(OC)OC JSOPTJTYIPIDNM-UHFFFAOYSA-N 0.000 description 1
- JBYXACURRYATNJ-UHFFFAOYSA-N trimethoxy(1-trimethoxysilylhexyl)silane Chemical compound CCCCCC([Si](OC)(OC)OC)[Si](OC)(OC)OC JBYXACURRYATNJ-UHFFFAOYSA-N 0.000 description 1
- ZLDMJNUPPZPMBK-UHFFFAOYSA-N trimethoxy(1-trimethoxysilyloctadecyl)silane Chemical compound CCCCCCCCCCCCCCCCCC([Si](OC)(OC)OC)[Si](OC)(OC)OC ZLDMJNUPPZPMBK-UHFFFAOYSA-N 0.000 description 1
- XLUIBHBNUCWHGE-UHFFFAOYSA-N trimethoxy(1-trimethoxysilyloctyl)silane Chemical compound CCCCCCCC([Si](OC)(OC)OC)[Si](OC)(OC)OC XLUIBHBNUCWHGE-UHFFFAOYSA-N 0.000 description 1
- YOUVHODSLXMCTB-UHFFFAOYSA-N trimethoxy(1-trimethoxysilyltetradecyl)silane Chemical compound CCCCCCCCCCCCCC([Si](OC)(OC)OC)[Si](OC)(OC)OC YOUVHODSLXMCTB-UHFFFAOYSA-N 0.000 description 1
- JCGDCINCKDQXDX-UHFFFAOYSA-N trimethoxy(2-trimethoxysilylethyl)silane Chemical compound CO[Si](OC)(OC)CC[Si](OC)(OC)OC JCGDCINCKDQXDX-UHFFFAOYSA-N 0.000 description 1
- QRTOPPGMVFGMNI-UHFFFAOYSA-N trimethoxy(3-trimethoxysilylbutan-2-yl)silane Chemical compound CO[Si](OC)(OC)C(C(C)[Si](OC)(OC)OC)C QRTOPPGMVFGMNI-UHFFFAOYSA-N 0.000 description 1
- VCYIQHANEDIOMB-UHFFFAOYSA-N trimethoxy(4-trimethoxysilylheptan-4-yl)silane Chemical compound CO[Si](OC)(OC)C(CCC)(CCC)[Si](OC)(OC)OC VCYIQHANEDIOMB-UHFFFAOYSA-N 0.000 description 1
- PPUHSHGIVZSPFO-UHFFFAOYSA-N trimethoxy(nonadecyl)silane Chemical compound CCCCCCCCCCCCCCCCCCC[Si](OC)(OC)OC PPUHSHGIVZSPFO-UHFFFAOYSA-N 0.000 description 1
- JEPXSTGVAHHRBD-UHFFFAOYSA-N trimethoxy(nonyl)silane Chemical compound CCCCCCCCC[Si](OC)(OC)OC JEPXSTGVAHHRBD-UHFFFAOYSA-N 0.000 description 1
- NMEPHPOFYLLFTK-UHFFFAOYSA-N trimethoxy(octyl)silane Chemical compound CCCCCCCC[Si](OC)(OC)OC NMEPHPOFYLLFTK-UHFFFAOYSA-N 0.000 description 1
- LCXXOYOABWDYBF-UHFFFAOYSA-N trimethoxy(pentadecyl)silane Chemical compound CCCCCCCCCCCCCCC[Si](OC)(OC)OC LCXXOYOABWDYBF-UHFFFAOYSA-N 0.000 description 1
- HILHCDFHSDUYNX-UHFFFAOYSA-N trimethoxy(pentyl)silane Chemical compound CCCCC[Si](OC)(OC)OC HILHCDFHSDUYNX-UHFFFAOYSA-N 0.000 description 1
- ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 description 1
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical compound CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 description 1
- AXNJHBYHBDPTQF-UHFFFAOYSA-N trimethoxy(tetradecyl)silane Chemical compound CCCCCCCCCCCCCC[Si](OC)(OC)OC AXNJHBYHBDPTQF-UHFFFAOYSA-N 0.000 description 1
- QSYYSIXGDAAPNN-UHFFFAOYSA-N trimethoxy(tridecyl)silane Chemical compound CCCCCCCCCCCCC[Si](OC)(OC)OC QSYYSIXGDAAPNN-UHFFFAOYSA-N 0.000 description 1
- LIJFLHYUSJKHKV-UHFFFAOYSA-N trimethoxy(undecyl)silane Chemical compound CCCCCCCCCCC[Si](OC)(OC)OC LIJFLHYUSJKHKV-UHFFFAOYSA-N 0.000 description 1
- LKXYIPHHGIGPNK-UHFFFAOYSA-N trimethoxy-(1-trimethoxysilylcyclohexyl)silane Chemical compound CO[Si](OC)(OC)C1([Si](OC)(OC)OC)CCCCC1 LKXYIPHHGIGPNK-UHFFFAOYSA-N 0.000 description 1
- JTTSZDBCLAKKAY-UHFFFAOYSA-N trimethoxy-[3-(3-trimethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CO[Si](OC)(OC)CCCSSSSCCC[Si](OC)(OC)OC JTTSZDBCLAKKAY-UHFFFAOYSA-N 0.000 description 1
- PZJJKWKADRNWSW-UHFFFAOYSA-N trimethoxysilicon Chemical group CO[Si](OC)OC PZJJKWKADRNWSW-UHFFFAOYSA-N 0.000 description 1
- GBXQPDCOMJJCMJ-UHFFFAOYSA-M trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;bromide Chemical compound [Br-].C[N+](C)(C)CCCCCC[N+](C)(C)C GBXQPDCOMJJCMJ-UHFFFAOYSA-M 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0025—Compositions of the sidewalls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0041—Compositions of the carcass layers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/548—Silicon-containing compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L19/00—Compositions of rubbers not provided for in groups C08L7/00 - C08L17/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C2001/0066—Compositions of the belt layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C2200/00—Tyres specially adapted for particular applications
- B60C2200/06—Tyres specially adapted for particular applications for heavy duty vehicles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/019—Specific properties of additives the composition being defined by the absence of a certain additive
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/80—Technologies aiming to reduce greenhouse gasses emissions common to all road transportation technologies
- Y02T10/86—Optimisation of rolling resistance, e.g. weight reduction
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Tires In General (AREA)
Abstract
Description
本明細書に記載される用語は、実施形態を説明するためだけのものであり、全体として本発明を限定すると解釈すべきではない。
上述したように、第1及び第2の実施形態によれば、タイヤゴム組成物は、バガス成分を含む、過半重量(例えば、51%、55%、60%、65%、70%、75%、80%、85%、90%、95%、又は100%)のグアユールゴムを含む、ゴム成分を含む。第1及び第2の実施形態の特定の実施形態では、ゴム成分は、少なくとも60重量%(例えば、60%、65%、70%、75%、80%、85%、90%、95%、100%、60~100%、60~90%、60~80%、60~70%等)のグアユールゴムを含む。第1及び第2の実施形態の特定の実施形態では、ゴム成分は、少なくとも70重量%(例えば、70%、75%、80%、85%、90%、95%、100%、70~100%、70~90%、70~80%等)のグアユールゴムを含む。第1及び第2の実施形態の更に他の実施形態では、ゴム成分の全体(すなわち、100重量%)がグアユールゴムである。
本明細書に開示される第1及び第2の実施形態によれば、ゴム組成物のゴム成分に少なくとも1つのSBRが存在する場合、スチレン-ブタジエンゴムのMw、Mn、及び多分散度(Mw/Mn)は様々であり得る。第1の実施形態及び第2の実施形態における特定の実施形態では、SBRは、300,000~600,000グラム/モル(例えば、300,000;325,000;350,000;375,000;400,000;425,000;450,000;475,000;500,000;525,000;550,000;575,000;又は600,000グラム/モル)のMwを有する。第1の実施形態及び第2の実施形態における特定の実施形態では、SBRは、350,000~550,000、又は400,000~500,000グラム/モルのMwを有する。本明細書において言及されるMw値は、重量平均分子量であり、これは、スチレン-ブタジエン標準及び対象のポリマーに対してマルク-ハウインク定数により較正されたゲル浸透クロマトグラフィ(gel permeation chromatography、GPC)を使用することにより決定することができる。第1の実施形態及び第2の実施形態における特定の実施形態では、SBRは200,000~400,000グラム/モル(例えば、200,000;225,000;250,000;275,000;300,000;325,000;350,000;375,000;又は400,000グラム/モル)のMnを有する。第1の実施形態及び第2の実施形態における特定の実施形態では、SBRは、200,000~300,000のMnを有する。本明細書において言及されているMn値は、数平均分子量であり、これは、スチレン-ブタジエン標準及び対象のポリマーに対してマルク-ハウインク定数により較正されたゲル浸透クロマトグラフィ(GPC)を使用することにより決定することができる。本明細書に開示される第1の実施形態及び第2の実施形態における特定の実施形態では、SBRは、1.2~2.5(例えば、1.2、1.3、1.4、1.5、1.6、1.7、1.8、1.9、2、2.1、2.2、2.3、2.4、又は2.5、好ましくは、1.3~2)のMw/Mn(多分散度)を有する。第1の実施形態及び第2の実施形態における特定の実施形態では、SBRのMw、Mn、及びMw/Mnは全て、前述の範囲の1つに属し、特定のそのような実施形態では、Mw、Mn、及びMw/Mnの各々は、前述の好ましい範囲の1つに属する。第1及び第2の実施形態の他の実施形態では、利用されるSBRは、(a)350,000~600,000グラム/モル(例えば、350,000;400,000;450,000;500,000;550,000;又は600,000グラム/モル)、若しくは400,000~550,000グラム/モル(例えば、400,000;425,000;450,000;475,000;500,000;525,000;又は550,000グラム/モル)のMwを有するSBRと組み合わせて前述の範囲のうちの1つ内のMw、Mn、及び/又はMw/Mnを有する前述のSBRのうちの少なくとも1つを含むか、(b)又は350,000~600,000グラム/モル(例えば、350,000;400,000;450,000;500,000;550,000;又は600,000グラム/モル)、若しくは400,000~550,000グラム/モル(例えば、400,000;425,000;450,000;475,000;500,000;525,000;又は550,000グラム/モル)のMwを有する1つ以上のSBRのみを含む。
第1及び第2の実施形態によれば、ゴム組成物のゴム成分は、ポリブタジエンゴムを含み得る。利用されるポリブタジエンゴムの特定の種類は様々であり得る。好ましくは、第1及び第2の実施形態によれば、ゴム成分中に存在する任意のポリブタジエンゴムは、少なくとも90%(例えば、90%、91%、92%、93%、94%、95%、96%、97%、98%、99%、又はそれ以上)、好ましくは少なくとも92%(例えば、92%、93%、94%、95%、96%、97%、98%、99%、又はそれ以上)、より好ましくは少なくとも95%(例えば、95%、96%、97%、98%、99%、又はそれ以上)のシス結合含量、及び-101℃未満(例えば、-102、-103、-104、-105、-106、-107、-108、-109℃、又はそれ以下)のTgを有する。特定のそのような実施形態では、ポリブタジエンゴムのTgは、-101~-110℃である。シス結合含量は、シス1,4-結合含量を指す。本明細書で言及されるシス1,4-結合含量は、FTIR(Fourier Transform Infrared Spectroscopy、フーリエ変換赤外分光法)によって決定され、その場合、ポリマー試料は、CS2に溶解され、次いで、FTIRに供する。第1及び第2の実施形態の特定の実施形態では、ゴム成分中に存在するポリブタジエンゴムは、少なくとも98%(例えば、98%、99%、又はそれ以上)、又は少なくとも99%(例えば、99%、99.5%、又はそれ以上)のシス1,4-結合含量を有し得る。第1及び第2の実施形態の特定の実施形態では、ゴム成分中に存在する任意のポリブタジエンゴムは、-105~-110℃又は-105~-108℃等、-105℃以下(例えば、-105、-106、-107、-108、-109℃、又はそれ以下)のTgを有する。第1及び第2の実施形態における特定の実施形態では、ゴム成分中に存在する任意のポリブタジエンゴムは、3重量%未満(例えば、3%、2%、1%、0.5%、又はそれ以下)、好ましくは1重量%未満(例えば、1%、0.5%、又はそれ以下)又は0重量%のシンジオタクチック1,2-ポリブタジエンを含有する。概して、第1及び第2の実施形態によれば、少なくとも92%のシス結合含量及び-101℃未満のTgを有する1つ以上のポリブタジエンゴムをゴム成分において使用することができる。第1~第3の実施形態の特定の実施形態では、使用される唯一のポリブタジエンゴムは、少なくとも92%(例えば、92%、93%、94%、95%、96%、97%、98%、99%、又はそれ以上)のシス結合含量及び-101℃未満のTgを有する。上述したように、ポリブタジエンがゴム成分中に存在する場合、それは、上述した官能基のうちの1つ以上を用いて任意選択で官能化されてもよい。
第1及び第2の実施形態によれば、ゴム成分は、非グアユール天然ゴム、ポリイソプレン、又はそれらの組み合わせを含み得る。第1の実施形態及び第2の実施形態の特定の実施形態では、ゴム成分は、非グアユール天然ゴムを含むが、ポリイソプレンは含まない。第1及び第2の実施形態における他の実施形態では、ゴム成分は、ポリイソプレンのみを含み、天然ゴムは含まない。第1及び第2の実施形態によれば、天然ゴムがゴム成分中に存在する場合、それは、好ましくはヘベア天然ゴムである。第1及び第2の実施形態のゴム組成物において非グアユール天然ゴムが使用される場合、天然ゴムは、好ましくは、1,000,000~2,000,000グラム/モル(例えば、100万、110万、120万、130万、140万、150万、160万、170万、180万、190万、200万グラム/モル)、1,250,000~2,000,000グラム/モル、又は1,500,000~2,000,000グラム/モル(ポリスチレン標準を使用してGPCによって測定される)のMwを有する。第1及び第2の実施形態のゴム組成物において非グアユール天然ゴムが使用される場合、天然ゴムのTgは様々であり得る。好ましくは、第1及び第2の実施形態によれば、非グアユール天然ゴムが利用される場合、それは、-65~-80℃(例えば、-65、-66、-67、-68、-69、-70、-71、-72、-73、-74、-75、-76、-77、-78、-79、又は-80℃)のTg、より好ましくは-67~-77℃(例えば、-67、-68、-69、-70、-71、-72、-73、-74、-75、-76、又は-77℃)のTgを有する。第1の実施形態及び第2の実施形態のゴム組成物にポリイソプレンが利用される場合、ポリイソプレンのTgは様々であり得る。好ましくは、第1及び第2の実施形態によれば、ポリイソプレンが利用される場合、それは、-55~-75℃(例えば、-55、-56、-57、-58、-59、-60、-61、-62、-63、-64、-65、-66、-67、-68、-69、-70、-71、-72、-73、-74、又は-75℃)、より好ましくは-58~-74℃(例えば、-58、-59、-60、-61、-62、-63、-64、-65、-66、-67、-68、-69、-70、-71、-72、-73、又は-74℃)のTgを有する。
上述したように、第1及び第2の実施形態によれば、ゴム組成物は、シリカを含まない充填剤成分を含む。シリカを含まないとは、充填剤成分(ひいては、ゴム組成物全体)が0phrのシリカを含有することを意味する。理論に束縛されるものではないが、充填剤成分からシリカを排除すると、少なくとも1つのシランのバガス成分への結合(少なくとも1つのシランのシリカへの結合ではなく)が可能になる。本明細書に開示される第1及び第2の実施形態によれば、ゴム組成物の充填剤成分中に存在する充填剤の量及び種類は、様々であり得る。
上述したように、第1及び第2の実施形態によれば、ゴム組成物は、メルカプトシラン、ブロック化メルカプトシラン、及びアルコキシシランからなる群から選択される少なくとも1つのシランを含む。以下でより詳細に論じる通り、アルコキシシランは、硫黄含有アルコキシシラン並びに非硫黄含有アルコキシシランの両方を含むと理解されるべきである。
本明細書に開示される第1及び第2の実施形態の特定の実施形態では、ゴム組成物中に存在するグアユール樹脂の量は限定される。概して、グアユール樹脂は、使用されるグアユールゴムの成分としてゴム組成物に添加されてもよいが、グアユール樹脂を別個に(「遊離」樹脂として)添加することも可能である。第1及び第2の実施形態の好ましい実施形態では、ゴム組成物は、4phr以下例えば、4、3.5、3、2.5、2、1.5、1、0.5phr以下)のグアユール樹脂、より好ましくは4phr未満のグアユール樹脂(例えば、3.9、3.5、3、2.5、2、1.5、1、0.5phr以下)のグアユール樹脂、更により好ましくは1phr未満のグアユール樹脂(例えば0.9、0.8、0.7、0.6、0.5、0.4、0.3、0.2、0.1、又は0phr以下)のグアユール樹脂を含む。
第1及び第2の実施形態によれば、追加の成分がゴム組成物中に存在してもよい。これらの追加成分としては、液体可塑剤、硬化パッケージ、ワックス(場合によっては酸化防止剤である)、加工助剤、補強樹脂、素練り促進剤、及び酸化防止剤/劣化防止剤が挙げられるが、これらに限定されない。第1及び第2の実施形態の好ましい実施形態では、硬化パッケージがゴム組成物に含まれる。
上述のように、本明細書に開示される第1の実施形態は、ゴム組成物の転がり抵抗を改善する方法を対象とする。転がり抵抗の改善は、任意のシリカ及びシランを含まないことを除いて同じ成分を含有する対照ゴム組成物と比較した場合のものである。本明細書に開示される第2の実施形態によるタイヤゴム組成物はまた、(任意のシリカ及びシランを含まないことを除いて同じ成分を含有する対照ゴム組成物と比較した場合に)転がり抵抗の改善を示すことが理解されるべきである。
第1の実施形態によるゴム組成物(又は第1の実施形態の方法に従って作製されたゴム組成物)を使用して、ゴム組成物で構成される少なくとも1つの構成要素を有するタイヤを調製することができ、当該構成要素は、タイヤトレッド、タイヤサイドウォール、タイヤベルトスキム、又はタイヤカーカスから選択される。好ましい実施形態では、構成要素は、タイヤトレッドである。第1の実施形態によるゴム組成物(又は第1の実施形態の方法に従って作製されたゴム組成物)から作製されたトレッドを有する大型車用又は商用のトラック又はバスのタイヤも本明細書に開示される。
Claims (17)
- タイヤゴム組成物であって、
a.バガス成分を含む、好ましくは前記グアユールゴムの重量に基づいて1~20重量%の量のバガス成分を含む、過半重量のグアユールゴムを含む、100部のゴム成分と、
b.シリカを含まない充填剤成分と、
c.メルカプトシラン、ブロック化メルカプトシラン、及びアルコキシシランからなる群から選択される少なくとも1つのシランと、
を含む、タイヤゴム組成物。 - 前記少なくとも1つのシランが、硫黄含有アルコキシシラン、好ましくはジスルフィドアルコキシシラン又はテトラスルフィドアルコキシシランである、請求項1に記載のタイヤゴム組成物。
- 前記硫黄含有アルコキシシランが、ジスルフィドアルコキシシラン化合物であり、好ましくは、3,3’-ビス(トリエトキシシリルプロピル)ジスルフィド、3,3’-ビス(トリメトキシシリルプロピル)ジスルフィド、3,3’-ビス(トリブトキシシリル-プロピル)ジスルフィド、3,3’-ビス(トリ-m-ブトキシシリル-プロピル)ジスルフィド、3,3’-ビストリプロポキシプロピル)ジスルフィド、3,3’-ビス(トリヘキソキシシリルプロピル)ジスルフィド、2,2’-ビス(ジメチルメトキシシリルエチル)ジスルフィド、3,3’-ビス(ジフェニルシクロヘキソキシシリルプロピル)ジスルフィド、3,3’-ビス(エチル-ジ-sec-ブトキシシリルプロピル)ジスルフィド、3,3’-ビス(プロピルジエトキシシリルプロピル)ジスルフィド、3,3’-ビス(トリイソプロポキシシリルプロピル)ジスルフィド、12,12’-ビス(トリイソプロポキシシリルプロピル)ジスルフィド、3,3’-ビス(ジメトキシフェニルシリル-2-メチルプロピル)ジスルフィド、及びそれらの組み合わせからなる群から選択される、請求項2に記載のタイヤゴム組成物。
- 前記少なくとも1つのシランが、
(a)式(I)を有する非硫黄含有アルコキシシラン:
(b)4~6個のアルコキシ基を有する非硫黄含有ビスアルコキシシラン
から選択される非硫黄含有アルコキシシランである、請求項1に記載のタイヤゴム組成物。 - 前記少なくとも1つのシランが、メルカプトシランである、請求項1に記載のタイヤゴム組成物。
- 前記少なくとも1つのシランが、ブロック化メルカプトシランである、請求項1に記載のタイヤゴム組成物。
- 前記少なくとも1つのシランが、0.1~5phr、好ましくは0.2~1phrの総量で存在する、請求項1~6のいずれか一項に記載のタイヤゴム組成物。
- 前記少なくとも1つのシランが、前記ゴム組成物中に存在するバガスの量に基づいて5~20重量%の総量で存在する、請求項1~7のいずれか一項に記載のタイヤゴム組成物。
- 前記充填剤成分が、30~200phrの量で存在し、過半重量の補強カーボンブラックを含む、請求項1~8のいずれか一項に記載のタイヤゴム組成物。
- 前記バガス成分が、前記グアユールゴムの重量に基づいて1~10重量%、好ましくは5重量%未満の量で存在する、請求項1~9のいずれか一項に記載のタイヤゴム組成物。
- 前記バガス成分が、前記グアユールゴムの重量に基づいて5~20重量%、好ましくは10~20重量%の量で存在する、請求項1~10のいずれか一項に記載のタイヤゴム組成物。
- 前記ゴム成分が、非グアユール天然ゴム、ポリイソプレン、少なくとも90%のシス-1,4-結合含量を有するポリブタジエン、少なくとも90%のシス-1,4-結合含量を有する官能化ポリブタジエン、スチレン-ブタジエンゴム、及び官能化スチレン-ブタジエンゴムからなる群から選択される少なくとも1つのゴムを半重量未満含む、請求項1~11のいずれか一項に記載のタイヤゴム組成物。
- 前記ゴム組成物が、4phr未満の樹脂、好ましくは1phr未満の樹脂を含む、請求項1~12のいずれか一項に記載のタイヤゴム組成物。
- 請求項1~13のいずれか一項に記載のタイヤゴム組成物を含む少なくとも1つの構成要素を有するタイヤであって、前記構成要素が、タイヤトレッド、タイヤサイドウォール、タイヤベルトスキム、又はタイヤカーカスから選択される、タイヤ。
- 請求項1~13のいずれか一項に記載のタイヤゴム組成物から作製されたトレッドを有する、大型車用又は商用のトラック又はバス用タイヤ。
- タイヤゴム組成物の転がり抵抗を改善する方法であって、請求項1~13のいずれか一項に記載のタイヤゴム組成物を提供することを含む、方法。
- 前記タイヤゴム組成物が、タイヤトレッド、タイヤサイドウォール、タイヤベルトスキム、又はタイヤカーカスのうちの少なくとも1つに使用される、請求項16に記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US202063127534P | 2020-12-18 | 2020-12-18 | |
US63/127,534 | 2020-12-18 | ||
PCT/US2021/072972 WO2022133478A1 (en) | 2020-12-18 | 2021-12-16 | Tire rubber compositions combining bagasse-containing guayule rubber with silane and related methods |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2024501217A true JP2024501217A (ja) | 2024-01-11 |
Family
ID=79601542
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2023537121A Pending JP2024501217A (ja) | 2020-12-18 | 2021-12-16 | バガス含有グアユールゴムとシランとを組み合わせたゴム組成物及び関連する方法 |
Country Status (4)
Country | Link |
---|---|
US (1) | US20240052139A1 (ja) |
EP (1) | EP4263621A1 (ja) |
JP (1) | JP2024501217A (ja) |
WO (1) | WO2022133478A1 (ja) |
Family Cites Families (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5153159A (en) | 1990-04-09 | 1992-10-06 | Bridgestone/Firestone, Inc. | Elastomers and products having reduced hysteresis |
US5329005A (en) | 1992-10-02 | 1994-07-12 | Bridgestone Corporation | Soluble anionic polymerization initiators and preparation thereof |
US5332810A (en) | 1992-10-02 | 1994-07-26 | Bridgestone Corporation | Solubilized anionic polymerization initiator and preparation thereof |
US5393721A (en) | 1992-10-16 | 1995-02-28 | Bridgestone Corporation | Anionic polymerization initiators and reduced hysteresis products therefom |
EP0600208B1 (en) | 1992-10-30 | 1997-12-29 | Bridgestone Corporation | Soluble anionic polymerization initiators and products therefrom |
JP3202457B2 (ja) | 1993-12-16 | 2001-08-27 | 株式会社東芝 | 半導体装置の製造方法 |
US5491230A (en) | 1993-12-29 | 1996-02-13 | Bridgestone Corporation | Anionic polymerization initiators containing adducts of cyclic secondary amines and conjugated dienes, and products therefrom |
US5494955A (en) * | 1994-04-08 | 1996-02-27 | Columbian Chemicals Company | Use of silane coupling agent with carbon black to enhance the balance of reinforcement properties of rubber compounds |
US5567815A (en) | 1994-07-18 | 1996-10-22 | Bridgestone Corporation | Teritary amine containing antonic initiators used in preparing polymers and process for the preparation thereof |
US5521309A (en) | 1994-12-23 | 1996-05-28 | Bridgestone Corporation | Tertiary-amino allyl-or xylyl-lithium initiators and method of preparing same |
US5574109A (en) | 1995-02-01 | 1996-11-12 | Bridgestone Corporation | Aminoalkyllithium compounds containing cyclic amines and polymers therefrom |
US5496940A (en) | 1995-02-01 | 1996-03-05 | Bridgestone Corporation | Alkyllithium compounds containing cyclic amines and their use in polymerization |
US5786441A (en) | 1996-12-31 | 1998-07-28 | Bridgestone Corporation | Polymers, elastomeric compounds and products thereof, derived from novel amine compounds containing side-chain organolithium moieties |
CN100376585C (zh) | 1997-08-21 | 2008-03-26 | 通用电气公司 | 用于填充橡胶的封端巯基硅烷偶联剂 |
US6649684B1 (en) | 1999-08-19 | 2003-11-18 | Ppg Industries Ohio, Inc. | Chemically treated fillers and polymeric compositions containing same |
US6635700B2 (en) | 2000-12-15 | 2003-10-21 | Crompton Corporation | Mineral-filled elastomer compositions |
WO2004041870A2 (en) | 2002-10-30 | 2004-05-21 | Bridgestone Corporation | The use of sulfur containing initiators for anionic polymerization of monomers |
US7923039B2 (en) * | 2005-01-05 | 2011-04-12 | Yulex Corporation | Biopolymer extraction from plant materials |
US7256231B2 (en) | 2004-11-12 | 2007-08-14 | Bridgestone Corporation | Silica-reinforced rubber compounded with blocked mercaptosilanes and alkyl alkoxysilanes |
US7868110B2 (en) | 2005-05-20 | 2011-01-11 | Bridgestone Corporation | Anionic polymerization initiators and polymers therefrom |
US20060264590A1 (en) | 2005-05-20 | 2006-11-23 | Bridgestone Corporation | Anionic polymerization initiators and polymers therefrom |
US8329297B2 (en) * | 2008-12-01 | 2012-12-11 | Bridgestone Corporation | Rubber compositions containing non-sulfur silica coupling agents bound to diene rubbers |
WO2015054685A1 (en) * | 2013-10-11 | 2015-04-16 | Ohio State Innovation Foundation | Filler-natural rubber composites |
MX2017009165A (es) * | 2015-01-12 | 2017-10-16 | Cooper Tire & Rubber Co | Compuesto de caucho natural con silice y su uso en llantas. |
ES2745311T3 (es) * | 2015-09-29 | 2020-02-28 | Continental Reifen Deutschland Gmbh | Mezcla de cauchos y neumático de vehículo |
CN105419002A (zh) * | 2015-12-19 | 2016-03-23 | 华南理工大学 | 一种蔗渣纳米纤维素及其橡胶复合材料的制备方法 |
IT201600131325A1 (it) * | 2016-12-27 | 2018-06-27 | Pirelli | Composizioni elastomeriche comprendenti gomme naturali da Guayule per componenti di pneumatici e pneumatici che le comprendono |
EP3788103A4 (en) * | 2018-05-04 | 2022-01-12 | Bridgestone Americas Tire Operations, LLC | RUBBER COMPOSITION FOR TIRE TREAD |
-
2021
- 2021-12-16 WO PCT/US2021/072972 patent/WO2022133478A1/en active Application Filing
- 2021-12-16 JP JP2023537121A patent/JP2024501217A/ja active Pending
- 2021-12-16 EP EP21843859.6A patent/EP4263621A1/en active Pending
- 2021-12-16 US US18/257,822 patent/US20240052139A1/en active Pending
Also Published As
Publication number | Publication date |
---|---|
EP4263621A1 (en) | 2023-10-25 |
WO2022133478A1 (en) | 2022-06-23 |
US20240052139A1 (en) | 2024-02-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US10179479B2 (en) | Plant oil-containing rubber compositions, tread thereof and race tires containing the tread | |
JP2021523959A (ja) | タイヤトレッドゴム組成物 | |
WO2020243304A1 (en) | Tire tread rubber composition and related methods | |
US11203658B2 (en) | Coupled polymer products, methods of making and compositions containing | |
JP2021523260A (ja) | タイヤトレッドゴム組成物 | |
JP2021523264A (ja) | タイヤトレッドゴム組成物 | |
JP2024501217A (ja) | バガス含有グアユールゴムとシランとを組み合わせたゴム組成物及び関連する方法 | |
JP2022534568A (ja) | タイヤトレッドゴム組成物及びその関連方法 | |
JP2021523261A (ja) | タイヤトレッドゴム組成物 | |
JP7445681B2 (ja) | タイヤトレッドゴム組成物及び関連方法 | |
JP7513347B2 (ja) | タイヤトレッドゴム組成物 | |
WO2023060189A1 (en) | Tire component from rubber composition including guayule rubber and eutectic composition and related methods | |
JP2023544611A (ja) | タイヤトレッドゴム組成物及び関連方法 | |
US12006422B2 (en) | Coupled polymer products, methods of making and compositions containing | |
WO2022147464A1 (en) | Tire having tread of specified rubber composition and related methods | |
JP2024036516A (ja) | 特定のゴム組成物のトレッドを有するタイヤ及び関連方法 | |
JP2023500520A (ja) | 特定のゴム組成物のトレッドを有するタイヤ及びその関連方法 | |
US20230357543A1 (en) | Tire Having Tread Of Specified Rubber Composition And Related Methods | |
JP2016155970A (ja) | 重荷重および/または建設車両用タイヤ用ゴム組成物およびそれを用いた空気入りタイヤ |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20230725 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20230725 |
|
RD03 | Notification of appointment of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7423 Effective date: 20230809 |
|
RD04 | Notification of resignation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7424 Effective date: 20231020 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20240416 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20240604 |