JP2023146708A - Canele like confectionery and production method of the same - Google Patents

Canele like confectionery and production method of the same Download PDF

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JP2023146708A
JP2023146708A JP2022054048A JP2022054048A JP2023146708A JP 2023146708 A JP2023146708 A JP 2023146708A JP 2022054048 A JP2022054048 A JP 2022054048A JP 2022054048 A JP2022054048 A JP 2022054048A JP 2023146708 A JP2023146708 A JP 2023146708A
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confectionery
starch
canelé
layer
gelatin
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進介 北中
Shinsuke Kitanaka
亜衣 藤井
Ai Fujii
史貴 山邊
Fumitaka Yamabe
秀美 中川
Hidemi Nakagawa
潔 鈴木
Kiyoshi Suzuki
泰正 山田
Yasumasa Yamada
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Uha Mikakuto Co Ltd
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Uha Mikakuto Co Ltd
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Abstract

To provide canele like confectionery which can be preserved in a normal temperature in long term, and a production method of the same.SOLUTION: There is provided canele like confectionery having two layer structure of an outer coat layer and a center layer, where rupture stress of the outer coat layer is 1-8 N, and a fracture strain ratio is 5-30%, the canele like confectionery being mainly formed of gelatin and a water soluble saccharide. The canele like confectionery is produced by filling a water solution which is obtained by heating and dissolving the gelatin and the water soluble saccharide, in a starch mold, then, heating the water solution at 50-80°C thereby forming, the outer coat layer.SELECTED DRAWING: None

Description

本発明は、長期常温保存可能なカヌレ様菓子及びその製造方法に関する。 The present invention relates to a canelé-like confectionery that can be stored at room temperature for a long period of time and a method for producing the same.

カヌレ(カヌレ・ド・ボルドー)は、“カヌレ”=「溝がついた」という意味のフランス語の通り、縦に溝がついた王冠の形をしたフランス発祥の洋菓子である。その基本的な作り方としては、砂糖、小麦粉及び卵を含有するミックス液を王冠形状の型に流し、焼成する。そして出来上がったカヌレは、表面が焼成によって焦げて硬く、内部のゲルはしっとりもっちりとした、外部と内部との間に食感差のある菓子となる。しかし、時間の経過に伴い、外部の硬い食感は失われ、内部のもっちりとした食感は澱粉の老化によって徐々に失われていく。そして水分活性も0.8程度と高いため、市販のカヌレは冷凍品であるか、もしくは常温で消費期限2~3日のものが一般的である。 Canelé (canelé de Bordeaux) is a French confectionery that originated in France and is shaped like a crown with vertical grooves, as the French word ``canelé'' means ``grooved.'' The basic way to make it is to pour a mixture containing sugar, flour, and eggs into a crown-shaped mold and then bake it. The finished canelé has a hard, burnt surface and a moist, chewy gel inside, resulting in a confectionery with a different texture between the outside and the inside. However, as time passes, the outer hard texture is lost, and the inner chewy texture is gradually lost due to aging of the starch. The water activity is also high, around 0.8, so commercially available canelés are usually frozen or have a shelf life of 2 to 3 days at room temperature.

これまでに、焼き菓子を長期保存させる技術として、グリセリンやソルビトール、還元水あめを配合するもの等が提案されている(例えば特許文献1)。これらは水分活性を下げることにより長期保存を可能にしているが、焼き菓子の外部の硬さや、外部と内部との間の食感差を長期間維持するものではなく、実際に前記の手法では水分及び油分の移行により、外部と内部の食感差はなくなってしまう傾向がある。 So far, as a technique for preserving baked goods for a long period of time, a technique in which glycerin, sorbitol, or reduced starch syrup is blended has been proposed (for example, Patent Document 1). These methods enable long-term storage by lowering water activity, but they do not maintain the hardness of the outside of baked goods or the difference in texture between the outside and inside for a long period of time, and in fact, the above methods do not maintain the hardness of the outside of baked goods or the difference in texture between the outside and inside. Due to the transfer of moisture and oil, the difference in texture between the outside and inside tends to disappear.

特許第5132531号公報Patent No. 5132531

本発明の目的は、長期常温保存可能なカヌレ様の菓子及びその製造方法を提供することである。 An object of the present invention is to provide a canelé-like confectionery that can be stored at room temperature for a long period of time, and a method for producing the same.

前記目的を達成するため、本発明者らは鋭意研究を重ねた結果、澱粉、ゼラチン及び水溶性糖質を含有する水溶液をスターチモールドに充填し、特定の温度で乾燥させることによって、表面が固化して、カヌレのように、硬い食感を有する外皮層及びしっとりもっちりとした食感を有する中心層が形成され、しかも前記外皮層と前記中心層の食感が長期間維持された、長期常温保存可能なカヌレ様菓子となることを見出し、本発明を完成するに至った。 In order to achieve the above object, the present inventors conducted extensive research and found that by filling a starch mold with an aqueous solution containing starch, gelatin, and water-soluble carbohydrates and drying it at a specific temperature, the surface solidified. As a result, like a canelé, an outer skin layer with a hard texture and a center layer with a moist and chewy texture are formed, and the texture of the outer skin layer and the center layer is maintained for a long period of time. The present invention was completed by discovering that a canelé-like confectionery can be stored at room temperature.

即ち、本発明の要旨は、
[1]外皮層と中心層の2層構造を有するカヌレ様菓子であって、
前記外皮層の破断応力が1~8N、破断歪率が5~30%であり、
澱粉、ゼラチン及び水溶性糖質を主成分とすることを特徴とするカヌレ様菓子、
[2]前記澱粉は、酢酸澱粉、酸化、アセチル化、ヒドロキシプロピル化又はリン酸化された澱粉、及び、アジピン酸又はリン酸によって架橋された澱粉から選ばれる一種以上である、前記[1]に記載のカヌレ様菓子、
[3]前記澱粉の含有量が4~30重量%、前記ゼラチンの含有量が1~5重量%、前記水溶性糖質の含有量が40~80重量%、水分値が10~20重量%であり、かつ水分活性が0.7未満である、前記[1]又は[2]に記載のカヌレ様菓子、
[4]澱粉、ゼラチン及び水溶性糖質を加熱溶解して得られた水溶液をスターチモールドに充填し、次いで、50~80℃で加熱乾燥して、外皮層を形成させることを特徴とする、外皮層と中心層の2層構造を有するカヌレ様菓子の製造方法
に関する。
That is, the gist of the present invention is
[1] A canelé-like confectionery having a two-layer structure of an outer layer and a center layer,
The breaking stress of the outer skin layer is 1 to 8 N, and the breaking strain rate is 5 to 30%,
A canelé-like confectionery characterized by containing starch, gelatin and water-soluble carbohydrates as main ingredients,
[2] The starch according to [1] above is one or more selected from acetic acid starch, oxidized, acetylated, hydroxypropylated or phosphorylated starch, and starch crosslinked with adipic acid or phosphoric acid. Canelé-like sweets mentioned above,
[3] The starch content is 4 to 30% by weight, the gelatin content is 1 to 5% by weight, the water-soluble carbohydrate content is 40 to 80% by weight, and the moisture value is 10 to 20% by weight. and has a water activity of less than 0.7, the canelé-like confectionery according to [1] or [2] above,
[4] A starch mold is filled with an aqueous solution obtained by heating and dissolving starch, gelatin, and water-soluble carbohydrates, and then heated and dried at 50 to 80°C to form an outer skin layer. The present invention relates to a method for producing a canelé-like confectionery having a two-layer structure of an outer layer and a center layer.

本発明のカヌレ様菓子は、本来経時変化の激しいカヌレの食感を長期間維持した、常温保存可能なものである。 The canelé-like confectionery of the present invention maintains the texture of canelé, which originally changes rapidly over time, for a long period of time and can be stored at room temperature.

以下、本発明をさらに詳しく説明する。 The present invention will be explained in more detail below.

本発明のカヌレ様菓子は、外皮層で周囲を覆われた中心層からなる2層構造を有する菓子である。
前記外皮層と前記中心層は、固形分の化学組成は同じであるが、物理的状態が異なる。具体的には、表面の加熱乾燥によって、澱粉、ゼラチン及び水溶性糖質による皮膜が形成され、硬化したものが外皮層であり、表面の皮膜形成によって水分を保持し、しっとりもっちりとした食感を有したものが中心層である。
The canelé-like confectionery of the present invention is a confectionery having a two-layer structure consisting of a central layer surrounded by an outer skin layer.
The outer skin layer and the center layer have the same solid chemical composition but different physical states. Specifically, by heating and drying the surface, a film made of starch, gelatin, and water-soluble carbohydrates is formed, and the hardened layer is the outer skin layer, which retains moisture and makes food moist and chewy. The central layer is the one that has a feeling.

前記外皮層の厚みについては、0.1~4mmであればよく、食感の観点で、0.5~2mmが好ましい。 The thickness of the outer skin layer may be 0.1 to 4 mm, and preferably 0.5 to 2 mm from the viewpoint of texture.

前記外皮層は、破断応力が1~8N、破断歪率が5~30%であることで、カヌレと同等の硬さと柔軟性を有し、カヌレのような食感を再現できる。
前記破断応力及び前記破断歪率は、本発明のカヌレ様菓子に直径5mmの球形プローブで荷重をかけた際の破断時の荷重及び歪率であり、具体的には、後述の試験例1に記載の手法により測定することができる。
なお、実際の市販のカヌレを複数種類測定したところ、外皮層の破断応力は1~8N、破断歪率は5~30%の範囲に調整されている。市販のカヌレは、外皮層の硬い食感と、中心層のもっちりしっとりとした食感差を感じられるものであり、破断歪率が小さいほど、外皮層は硬くカリっとした食感を有している。ただし、時間の経過とともに表面は軟らかくなり、破断歪率が50%を超えてくると食感差はほぼ感じなくなる。また、中心層のゲルも澱粉の老化により脆い食感となり、1週間程度しかもっちりとした食感は維持できない。
The outer skin layer has a breaking stress of 1 to 8 N and a breaking strain rate of 5 to 30%, so that it has the same hardness and flexibility as a canelé, and can reproduce the texture of a canelé.
The breaking stress and breaking strain rate are the load and strain rate at break when a load is applied to the canelé-like confectionery of the present invention using a spherical probe with a diameter of 5 mm, and specifically, in Test Example 1 described below. It can be measured by the method described.
In addition, when measuring multiple types of actual cannula on the market, the breaking stress of the outer skin layer was adjusted to 1 to 8 N, and the breaking strain rate was adjusted to a range of 5 to 30%. In commercially available canelés, you can feel the difference between the hard texture of the outer skin layer and the chewy and moist texture of the center layer. are doing. However, as time passes, the surface becomes softer, and when the breaking strain rate exceeds 50%, the difference in texture becomes almost invisible. Furthermore, the gel in the center layer also has a brittle texture due to aging of the starch, and the chewy texture can only be maintained for about a week.

前記中心層の厚みについて、5~40mmであればよく、食感の観点で、8~20mmが好ましい。 The thickness of the center layer may be 5 to 40 mm, and preferably 8 to 20 mm from the viewpoint of texture.

本発明のカヌレ様菓子は、澱粉、ゼラチン及び水溶性糖質を主成分とする。
具体的には、前記外皮層及び前記中心層のいずれの主成分も、澱粉、ゼラチン及び水溶性糖質となる。
本発明において、主成分とは、固形分重量で60重量%以上であることをいう。
The canelé-like confectionery of the present invention mainly contains starch, gelatin, and water-soluble carbohydrates.
Specifically, the main components of both the outer skin layer and the center layer are starch, gelatin, and water-soluble carbohydrates.
In the present invention, the main component refers to a solid content of 60% by weight or more.

a)澱粉
本発明のカヌレ様菓子において澱粉は、外皮層の形成及び中心層の食感付与の目的で使用する。
前記澱粉としては、特に限定はないが、化学的加工が加えられた澱粉、例えば、酢酸澱粉、酸化又はアセチル化又はヒドロキシプロピル化又はリン酸化された澱粉、アジピン酸又はリン酸によって架橋された澱粉等が挙げられる。具体的には、アセチル化アジピン酸架橋澱粉、アセチル化リン酸架橋澱粉、アセチル化酸化澱粉、酢酸澱粉、酸化澱粉、ヒドロキシプロピル澱粉、ヒドロキシプロピル化リン酸架橋澱粉、リン酸モノエステル化リン酸架橋澱粉、リン酸化澱粉、リン酸架橋澱粉等が挙げられる。
前記澱粉は、単独で又は2種種以上を使用してもよい。
a) Starch In the canelé-like confectionery of the present invention, starch is used for the purpose of forming an outer skin layer and imparting texture to the center layer.
The starch is not particularly limited, but includes chemically processed starch, such as acetic acid starch, oxidized or acetylated, hydroxypropylated or phosphorylated starch, and starch cross-linked with adipic acid or phosphoric acid. etc. Specifically, acetylated adipic acid crosslinked starch, acetylated phosphoric acid crosslinked starch, acetylated oxidized starch, acetic acid starch, oxidized starch, hydroxypropyl starch, hydroxypropylated phosphoric acid crosslinked starch, phosphoric acid monoester crosslinked phosphoric acid starch Examples include starch, phosphorylated starch, phosphoric acid crosslinked starch, and the like.
The starch may be used alone or in combination of two or more.

本発明のカヌレ様菓子において、澱粉の含有量によって外皮層及び中心層の食感を適宜調整できる。求める食感によって澱粉の含有量は変わるが、例えば、全重量中の4~30重量%の範囲であることが好ましい。なお、全重量とは、前記外皮層及び前記中心層を合計したカヌレ様菓子全量をいう。 In the canelé-like confectionery of the present invention, the texture of the outer skin layer and the center layer can be adjusted as appropriate by adjusting the starch content. The starch content varies depending on the desired texture, but is preferably in the range of 4 to 30% by weight based on the total weight, for example. Note that the total weight refers to the total amount of the canelé-like confectionery, which is the sum of the outer skin layer and the center layer.

b)ゼラチン
本発明のカヌレ様菓子においてゼラチンは、外皮層及び中心層の食感付与の目的で使用する。
前記ゼラチンとしては、その由来や製法等については特に限定はなく、例えば、コラーゲンを含む物質(動物の皮・骨・結合組織等)から抽出・精製されたものであればよく、由来生物に関しては特に制限されない。例えば、牛・豚・鶏等の獣の皮や骨由来ゼラチンに加えて、水生生物(淡水・海水)由来のゼラチン等が挙げられる。また、処理方法は酸処理、アルカリ処理等の処理を施されたものでもよい。前記ゼラチンとしては、単独で又は2種以上を使用してもよい。
b) Gelatin In the canelé-like confectionery of the present invention, gelatin is used for the purpose of imparting texture to the outer skin layer and the center layer.
There are no particular limitations on the origin or manufacturing method of the gelatin, and for example, it may be extracted and purified from collagen-containing substances (animal skin, bones, connective tissue, etc.); There are no particular restrictions. Examples include gelatin derived from the skin and bones of animals such as cows, pigs, and chickens, as well as gelatin derived from aquatic organisms (freshwater and seawater). Further, the treatment method may be acid treatment, alkali treatment, or the like. The gelatin may be used alone or in combination of two or more.

また、本発明のカヌレ様菓子は、外皮層及び中心層の食感を所望のように調整する観点から、200ブルーム以下の低ゼリー強度のものを使用することが好ましく、80~200ブルームのゼラチンを使用することがより好ましい。 In addition, in the canelé-like confectionery of the present invention, from the viewpoint of adjusting the texture of the outer skin layer and the center layer as desired, it is preferable to use a low jelly strength of 200 Bloom or less, and gelatin of 80 to 200 Bloom is preferably used. It is more preferable to use

本発明のカヌレ様菓子において、ゼラチンの含有量は、全重量中の1~5重量%の範囲であることが好ましい。 In the canelé-like confectionery of the present invention, the content of gelatin is preferably in the range of 1 to 5% by weight based on the total weight.

c)水溶性糖質
本発明のカヌレ様菓子は、カヌレや他の洋菓子同様、水溶性糖質を含有するが、40~80重量%の水溶性糖質を含有することが、保存性の目的で好ましい。
本発明で使用される水溶性糖質としては、ショ糖(砂糖)、ブドウ糖、果糖、マルトース、キシリトール、エリスリトール、トレハロース、マルチトール、パラチノース、還元パラチノース等の結晶性糖質や、水飴、還元水飴、還元麦芽糖水飴、グリセリン、ソルビトール液等の液状糖質が挙げられる。
c) Water-soluble carbohydrates The canelé-like confectionery of the present invention contains water-soluble carbohydrates like caneles and other Western confectioneries, but for the purpose of preservation, it is important to contain 40 to 80% by weight of water-soluble carbohydrates. It is preferable.
The water-soluble carbohydrates used in the present invention include crystalline carbohydrates such as sucrose (sugar), glucose, fructose, maltose, xylitol, erythritol, trehalose, maltitol, palatinose, and reduced palatinose, as well as starch syrup and reduced starch syrup. , reduced maltose starch syrup, glycerin, sorbitol solution, and other liquid carbohydrates.

本発明において、結晶性糖質と液状糖質と組み合わせることで外皮層及び中心層の硬さや食感を適宜調整できるが、固形比(重量比)として結晶性糖質:液状糖質=50:50~90:10の範囲であることが好ましい。 In the present invention, by combining crystalline carbohydrates and liquid carbohydrates, the hardness and texture of the outer skin layer and center layer can be adjusted appropriately, but the solid ratio (weight ratio) of crystalline carbohydrates: liquid carbohydrates = 50: The preferred ratio is 50 to 90:10.

d)水
本発明のカヌレ様菓子の水分値は、10~20重量%の範囲であることが好ましく、より好ましくは13~18重量%である。尚、前記水分値の測定手段としては、減圧乾燥法を用いればよい。
なお、前記水分値とは、前記外皮層及び前記中心層を合計したカヌレ様菓子全体中の量をいう。
d) Water The moisture value of the canelé-like confectionery of the present invention is preferably in the range of 10 to 20% by weight, more preferably 13 to 18% by weight. Incidentally, as a means for measuring the moisture value, a reduced pressure drying method may be used.
Note that the moisture value refers to the amount in the entire canelé-like confectionery, which is the sum of the outer skin layer and the center layer.

また、本発明のカヌレ様菓子の長期常温保存を可能にするためには、前記水溶性糖質の種類や含有量および水分値を調整し、水分活性が0.7未満になるようにすることが好ましい。
前記水分活性については、水分活性測定装置を用いて測定することができる。
In addition, in order to enable long-term storage of the canelé-like confectionery of the present invention at room temperature, the type and content of the water-soluble carbohydrate and the moisture value should be adjusted so that the water activity is less than 0.7. is preferred.
The water activity can be measured using a water activity measuring device.

e)任意成分
本発明のカヌレ様菓子には、任意成分として、卵、乳製品、食物繊維、酸味料、pH調整剤、果汁、香料、着色料、油脂、乳化剤、甘味料、コーヒー、紅茶、抹茶、カカオ、小麦粉等の穀物粉、酒類、ビタミン類、ミネラル類、アミノ酸類、ゲル化剤(ゼラチンを除く)等を含有してもよい。中でも、カヌレに一般的に使用される、卵、乳製品、ラム酒、バニラ香料等を含有することが好ましい。特にカヌレの味の特徴である卵原料を含有することが好ましく、卵黄成分を含有することがより好ましい。また、糖類やたんぱく質を焦がしたシロップ、カラメル色素、キャラメルソース、コーヒー、麦芽エキス、カカオ、その他焼成品や焙煎品の粉末や液体を適宜使用することで、焼成したカヌレと同様の風味を付与することができるため好ましい。
これらの任意成分を適宜選択することで、カヌレ様菓子の嗜好性の幅を広げることができる。なお、前記任意成分は、風味や食感に悪影響を与えない範囲で使用すればよい。
e) Optional ingredients The canelé-like confectionery of the present invention includes eggs, dairy products, dietary fiber, acidulants, pH adjusters, fruit juices, fragrances, colorants, oils and fats, emulsifiers, sweeteners, coffee, black tea, It may also contain grain powders such as matcha, cacao, and wheat flour, alcoholic beverages, vitamins, minerals, amino acids, gelling agents (excluding gelatin), and the like. Among these, it is preferable to contain eggs, dairy products, rum, vanilla flavoring, etc., which are commonly used in canelés. In particular, it is preferable to contain an egg raw material, which is characteristic of the taste of canelé, and more preferably to contain an egg yolk component. In addition, by appropriately using syrup made from burnt sugars and proteins, caramel coloring, caramel sauce, coffee, malt extract, cacao, and other powders or liquids from baked or roasted products, the flavor is similar to that of baked canelés. This is preferable because it can be done.
By appropriately selecting these optional ingredients, the range of palatability of the canelé-like confectionery can be expanded. Note that the above-mentioned optional components may be used within a range that does not adversely affect flavor or texture.

本発明のカヌレ様菓子は、澱粉、ゼラチン、水溶性糖質及び必要に応じてその他任意成分を水に加熱溶解した液をスターチモールドに充填し、乾燥させて表面を固化させることによって製造することができる。 The canelé-like confectionery of the present invention can be produced by heating and dissolving starch, gelatin, water-soluble carbohydrates, and other optional ingredients in water, filling a starch mold, and drying the mixture to solidify the surface. I can do it.

具体的には、澱粉、ゼラチン、水溶性糖質及び必要に応じてその他任意成分を水に加熱溶解したミックス液を作製し、60~90℃に保ったままスターチモールドに充填する。スターチモールドとは、コーンスターチ等のスターチの粉を平らに容器に敷き詰め、石膏や樹脂で造形した型を上から押し込んで、できた凹みのことを言う。できた凹みにミックス液を流し固めることで、石膏や樹脂で造形した型と同形状のカヌレ様菓子ができあがる。
カヌレ様菓子の形状は、市販のカヌレと同様に縦に溝がついた王冠の形をしたカヌレ形状でもよいし、略円形状、略円錐形状、略立方体状等、カヌレ形状とは別の形状のものでもよい。
Specifically, a mixed solution is prepared by heating and dissolving starch, gelatin, water-soluble carbohydrates, and other arbitrary components as necessary in water, and the mixture is filled into a starch mold while being maintained at 60 to 90°C. A starch mold is a dent made by spreading starch powder such as cornstarch flat in a container and then pressing a mold made of plaster or resin into the container. By pouring the mixture into the dents and allowing it to harden, a canelé-like confectionery is created that has the same shape as the mold made of plaster or resin.
The shape of the canelé-like confectionery may be a crown-shaped canelé with vertical grooves, similar to commercially available canelés, or a shape different from the canelé shape, such as an approximately circular shape, an approximately conical shape, an approximately cubic shape, etc. It may also be from.

スターチモールドに充填したミックス液は、次いでそのまま所望の水分値まで乾燥させる。乾燥手段としては、例えば、保温庫、乾燥庫等で50~80℃の温度で加熱乾燥させる。
この工程で外皮層が形成される。前記加熱乾燥の時間は所望の水分値に達するまでの時間でよく、例えば、20~100時間程度で乾燥を行えばよい。乾燥後、前記スターチモールドから取り出して、カヌレ様菓子を得る。
The mixed liquid filled into the starch mold is then directly dried to a desired moisture content. As a drying means, for example, heating and drying is carried out at a temperature of 50 to 80° C. in a heat insulating chamber, drying chamber, etc.
This process forms the outer skin layer. The heating drying time may be the time required to reach a desired moisture content, for example, drying may be carried out for about 20 to 100 hours. After drying, the starch mold is removed to obtain a canelé-like confectionery.

得られたカヌレ様菓子には、光沢を出すために、油脂、ミツロウ、カルナウバロウ、シェラック等で表面をコーティングしてもよい。 The surface of the resulting canelé-like confectionery may be coated with oil, beeswax, carnauba wax, shellac, etc. to give it a glossy appearance.

以上のようにして得られる本発明のカヌレ様菓子は、外皮層の硬い食感と、中心層のもっちりしっとりとした軟らかい食感を長期間維持された、長期常温保存可能な菓子となる。 The canelé-like confectionery of the present invention obtained as described above is a confectionery that can be stored at room temperature for a long period of time, maintaining the hard texture of the outer skin layer and the chewy, moist, and soft texture of the center layer for a long period of time.

本発明のカヌレ様菓子において、前記外皮層と前記中心層の食感が長期間維持される理由については、水分活性を0.7未満に低く設計することと澱粉の外皮膜の形成によって前記中心層から前記外皮層への水分移行が妨げられることが考えられる。 In the canelé-like confectionery of the present invention, the reason why the texture of the outer skin layer and the center layer is maintained for a long time is that the water activity is designed to be low to less than 0.7 and the outer skin layer of starch is formed. It is believed that moisture transfer from the layer to the skin layer is hindered.

以下、本発明を実施例により具体的に説明するが、本発明はこれらによって何ら制限されるものではない。 EXAMPLES Hereinafter, the present invention will be specifically explained with reference to Examples, but the present invention is not limited thereto.

(実施例1)
砂糖、水あめ及び澱粉を水に加熱溶解し、そこに、ゼラチン(商品名:#100、新田ゼラチン株式会社製、以下同じ)を同量の60℃の水にあらかじめ溶かしておいたものを添加し、混合した。さらに卵原料等の任意成分を混合し、最終的にBx.76に調製した液を、カヌレ形状に凹みをつけておいたスターチモールドに流し込んで、60℃で60時間乾燥させた。乾燥後、型から取り出し、表面に植物油0.1重量部を塗布した。得られたカヌレ様菓子は、単重5g、外皮層の厚さ1mm、水分値14重量%、水分活性0.68であった。最終的な配合を表1に示す。
このようにして得られたカヌレ様菓子は、外皮層(表面)は硬く、中心層(中)はしっとりもっちりとした好ましい食感で、味も濃厚なカヌレのような菓子となった。
(Example 1)
Sugar, starch syrup, and starch are heated and dissolved in water, and gelatin (product name: #100, manufactured by Nitta Gelatin Co., Ltd., hereinafter the same) previously dissolved in the same amount of 60°C water is added. and mixed. Furthermore, optional ingredients such as egg raw material are mixed, and finally Bx. The solution prepared in step 76 was poured into a starch mold with a cannel-shaped depression and dried at 60°C for 60 hours. After drying, it was taken out from the mold and 0.1 part by weight of vegetable oil was applied to the surface. The obtained canelé-like confectionery had a unit weight of 5 g, a skin layer thickness of 1 mm, a moisture value of 14% by weight, and a water activity of 0.68. The final formulation is shown in Table 1.
The thus obtained canelé-like confectionery had a pleasant texture with a hard outer layer (surface) and a moist and chewy center layer (middle layer), and a rich taste.

(実施例2~4)
実施例1と同様にカヌレ様菓子を作製した。得られたカヌレ様菓子は、外皮層は硬く、中心層はしっとりもっちりとした好ましい食感で、味も濃厚な菓子であった。
(Examples 2 to 4)
A canelé-like confectionery was prepared in the same manner as in Example 1. The obtained canelé-like confectionery had a desirable texture, with a hard outer skin layer and a moist and chewy center layer, and a rich taste.

(比較例1、2)
表1に示す組成とした以外は実施例1と同様に菓子を作製した。得られた菓子は、表面が砂糖の結晶によって脆く、カヌレとは程遠いものであった。
(Comparative Examples 1 and 2)
Confectionery was produced in the same manner as in Example 1 except that the composition shown in Table 1 was used. The resulting confectionery had a brittle surface due to sugar crystals and was far from a canelé.

<試験例1>物性評価試験
実施例1~4及び比較例1、2で得られた各菓子について、テクスチャー・アナライザー(Stable Micro Systems社製「Texture Analyzer TA.XT.plus」)を用い、下記条件で測定した。その結果を表1に示す。
<Test Example 1> Physical property evaluation test Each confectionery obtained in Examples 1 to 4 and Comparative Examples 1 and 2 was subjected to the following tests using a texture analyzer ("Texture Analyzer TA.XT.plus" manufactured by Stable Micro Systems). Measured under the following conditions. The results are shown in Table 1.

[貫入試験条件]
プローブ:直径5mmの球形プローブ
測定速度:1mm/秒
貫入距離:100%
測定温度:20℃
・外皮層の破断応力;外皮層の破断点(破断時の点)の最大荷重
・外皮層の破断歪率;外皮層の破断点の歪率
[Penetration test conditions]
Probe: Spherical probe with a diameter of 5 mm Measurement speed: 1 mm/sec Penetration distance: 100%
Measurement temperature: 20℃
- Breaking stress of the outer skin layer; Maximum load at the break point (point at break) of the outer skin layer - Fracture strain rate of the outer skin layer; Strain rate at the break point of the outer skin layer

本発明におけるカヌレ様菓子において、プローブがカヌレ様菓子表面に接触してから最初に現れるピークを破断点とした。 In the canelé-like confectionery of the present invention, the peak that first appears after the probe contacts the surface of the canelé-like confectionery was defined as the breaking point.

Figure 2023146708000001
Figure 2023146708000001

表1に示す結果より、実施例1~4で得られたカヌレ様菓子は、いずれも破断応力、破断歪率が、市販のカヌレと同じ範囲に調整されたものであった。 From the results shown in Table 1, the canelé-like confectionery obtained in Examples 1 to 4 all had breaking stress and breaking strain rate adjusted to the same range as commercially available canelés.

<試験例2>長期保存性試験
実施例1~4で得られた各カヌレ様菓子をアルミパウチに封入し、3か月の室温保存試験及び37℃での虐待試験を行った。保存期間終了後のサンプルを確認したところいずれも味や食感に問題はなく、外皮層と中心層の食感は維持されていたことから、長期常温保存可能な菓子であることがわかった。
<Test Example 2> Long-term storage test Each of the canelé-like confections obtained in Examples 1 to 4 was sealed in an aluminum pouch and subjected to a room temperature storage test for 3 months and an abuse test at 37°C. When the samples were checked after the storage period, there were no problems with taste or texture, and the texture of the outer layer and center layer was maintained, indicating that the confectionery can be stored at room temperature for a long time.

Claims (4)

外皮層と中心層の2層構造を有するカヌレ様菓子であって、
前記外皮層の破断応力が1~8N、破断歪率が5~30%であり、
澱粉、ゼラチン及び水溶性糖質を主成分とすることを特徴とするカヌレ様菓子。
A canelé-like confectionery having a two-layer structure of an outer layer and a center layer,
The breaking stress of the outer skin layer is 1 to 8 N, and the breaking strain rate is 5 to 30%,
A canelé-like confectionery characterized by containing starch, gelatin, and water-soluble carbohydrates as main ingredients.
前記澱粉は、酢酸澱粉、酸化、アセチル化、ヒドロキシプロピル化又はリン酸化された澱粉、及び、アジピン酸又はリン酸によって架橋された澱粉から選ばれる一種以上である、請求項1に記載のカヌレ様菓子。 The canelé-like product according to claim 1, wherein the starch is one or more selected from acetic acid starch, oxidized, acetylated, hydroxypropylated or phosphorylated starch, and starch crosslinked with adipic acid or phosphoric acid. Confectionery. 前記澱粉の含有量が4~30重量%、前記ゼラチンの含有量が1~5重量%、前記水溶性糖質の含有量が40~80重量%、水分値が10~20重量%であり、かつ水分活性が0.7未満である、請求項1又は2に記載のカヌレ様菓子。 The content of the starch is 4 to 30% by weight, the content of the gelatin is 1 to 5% by weight, the content of the water-soluble carbohydrate is 40 to 80% by weight, and the moisture value is 10 to 20% by weight, The canelé-like confectionery according to claim 1 or 2, which has a water activity of less than 0.7. 澱粉、ゼラチン及び水溶性糖質を加熱溶解して得られた水溶液をスターチモールドに充填し、次いで、50~80℃で加熱乾燥して、外皮層を形成させることを特徴とする、外皮層と中心層の2層構造を有するカヌレ様菓子の製造方法。
An outer skin layer characterized by filling a starch mold with an aqueous solution obtained by heating and dissolving starch, gelatin and water-soluble carbohydrates, and then heating and drying at 50 to 80°C to form an outer skin layer. A method for producing a canelé-like confectionery having a two-layer structure with a central layer.
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