JP2022546182A - 水性ポリマー配合物 - Google Patents
水性ポリマー配合物 Download PDFInfo
- Publication number
- JP2022546182A JP2022546182A JP2022500745A JP2022500745A JP2022546182A JP 2022546182 A JP2022546182 A JP 2022546182A JP 2022500745 A JP2022500745 A JP 2022500745A JP 2022500745 A JP2022500745 A JP 2022500745A JP 2022546182 A JP2022546182 A JP 2022546182A
- Authority
- JP
- Japan
- Prior art keywords
- acrylic
- monomer
- composition
- monomers
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 66
- 229920000642 polymer Polymers 0.000 title description 45
- 238000009472 formulation Methods 0.000 title 1
- 239000000178 monomer Substances 0.000 claims abstract description 108
- 229920000098 polyolefin Polymers 0.000 claims abstract description 43
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 41
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 36
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000002245 particle Substances 0.000 claims abstract description 27
- 239000000835 fiber Substances 0.000 claims abstract description 26
- 238000000034 method Methods 0.000 claims abstract description 24
- 239000007787 solid Substances 0.000 claims abstract description 18
- 239000012736 aqueous medium Substances 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 49
- 239000011230 binding agent Substances 0.000 claims description 22
- -1 polypropylene Polymers 0.000 claims description 5
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract description 7
- 239000000839 emulsion Substances 0.000 description 23
- 239000004816 latex Substances 0.000 description 17
- 229920000126 latex Polymers 0.000 description 17
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 15
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 15
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 14
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 12
- 239000000126 substance Substances 0.000 description 10
- 239000006185 dispersion Substances 0.000 description 9
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 8
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 8
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 8
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 7
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 7
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 239000008367 deionised water Substances 0.000 description 7
- 229910021641 deionized water Inorganic materials 0.000 description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 125000005907 alkyl ester group Chemical group 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 6
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 6
- 102100026735 Coagulation factor VIII Human genes 0.000 description 5
- 101000911390 Homo sapiens Coagulation factor VIII Proteins 0.000 description 5
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 238000007720 emulsion polymerization reaction Methods 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000004745 nonwoven fabric Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical group OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 3
- 150000003926 acrylamides Chemical class 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 150000003440 styrenes Chemical class 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 2
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000010526 radical polymerization reaction Methods 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 239000013504 Triton X-100 Substances 0.000 description 1
- 229920004890 Triton X-100 Polymers 0.000 description 1
- 229920005822 acrylic binder Polymers 0.000 description 1
- 229920006397 acrylic thermoplastic Polymers 0.000 description 1
- 238000012644 addition polymerization Methods 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 238000000937 dynamic scanning calorimetry Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000002557 mineral fiber Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000002491 polymer binding agent Substances 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 150000003254 radicals Chemical group 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/062—Copolymers with monomers not covered by C08L33/06
- C08L33/066—Copolymers with monomers not covered by C08L33/06 containing -OH groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/062—Copolymers with monomers not covered by C09J133/06
- C09J133/066—Copolymers with monomers not covered by C09J133/06 containing -OH groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
(a)マレイン化ポリオレフィン(a)を含む粒子(a)と、
(b)アクリルポリマー(b)を含む粒子(b)と、をさらに含む組成物であって、アクリルポリマー(b)が、アクリルポリマー(b)の固体重量に基づく重量で、
(i)ヒドロキシル官能性アクリルモノマーの0.1%~10%の重合単位、
(ii)カルボキシル官能性モノマーの1%~20%の重合単位、および
(iii)アクリルモノマー、スチレンモノマー、およびそれらの混合物からなる群から選択される1つ以上の追加のモノマー(iii)の70%~98.9%の重合単位、を含み、
マレイン化ポリオレフィン(a)が、マレイン化ポリオレフィン(a)およびアクリルポリマー(b)の固体重量の合計に基づいて、1重量%~19重量%の量で存在する、組成物である。
DI=脱イオン化
SBS=亜硫酸水素ナトリウム
APS=過硫酸アンモニウム
t-BHP=t-ブチルヒドロペルオキシド
FF6=Bruggemann ChemicalからのBRUGGELITE(商標)還元剤
DS-4=Solvayからのドデシルベンゼンスルホン酸ナトリウム
BA=n-ブチルアクリレート
Sty=スチレン
IA=イタコン酸
AA=アクリル酸
HEMA=ヒドロキシエチルメタクリレート
HEA=ヒドロキシエチルアクリレート
FA2D=カプロラクトン修飾アクリルモノマー(上記の構造(I)、式中、Rは水素であり、nは2である。
AC-597P=無水マレイン酸修飾ポリプロピレン分散液(39重量%の固体ポリマー、酸価63mgKOH/g、Honeywellから供給。
TRITON(商標)X-100=Dow ChemicalCompanyからの界面活性剤
IPA=イソプロパノール
紙=Whatman Ltd.からのWHATMAN(商標)#4紙
コポリマーの乾燥重量に基づいて、81重量%のBA、13重量%のSty、2.5重量%のAA、2.5重量%のIA、1重量%のHEMAを含む一段階アクリルラテックス(ラテックスB-1と表記)を以下のプロセスに従って調製した。
ブレンドされたバインダーは、以下のように作製した:11.5重量部の水性分散液AC-579Pを、100重量部の上記の水性ラテックスのうちの1つと15分間撹拌しながら混合した。得られた各混合物において、マレイン化ポリオレフィンおよびアクリルポリマーの固体重量の合計に基づく固体マレイン化ポリオレフィンの重量パーセントは、9.1%であった。
Claims (5)
- 組成物であって、水性媒体を含み、かつ前記水性媒体中に分散された、
(a)マレイン化ポリオレフィン(a)を含む粒子(a)と、
(b)アクリルポリマー(b)を含む粒子(b)と、をさらに含み、前記アクリルポリマー(b)が、前記アクリルポリマー(b)の固体重量に基づく重量で、
(i)ヒドロキシル官能性アクリルモノマーの0.1%~10%の重合単位、
(ii)カルボキシル官能性モノマーの1%~20%の重合単位、および
(iii)アクリルモノマー、スチレンモノマー、およびそれらの混合物からなる群から選択される1つ以上の追加のモノマー(iii)の70%~98.9%の重合単位、を含み、
前記マレイン化ポリオレフィン(a)が、マレイン化ポリオレフィン(a)およびアクリルポリマー(b)の固体重量の合計に基づいて、1重量%~19重量%の量で存在する、組成物。 - 前記マレイン化ポリオレフィン(a)が、マレイン化ポリプロピレンである、請求項1に記載の組成物。
- 前記追加のモノマー(iii)が、0℃以下のTgを有する1つ以上のアクリルモノマーを含む、請求項1に記載の組成物。
- 前記追加のモノマー(iii)が、1つ以上のスチレンモノマーを含む、請求項1に記載の組成物。
- 繊維を結合する方法であって、水性バインダー組成物を前記繊維と接触させ、次いで、前記水性バインダー組成物から水を蒸発させる、または水の蒸発を可能にすることを含み、前記水性バインダー組成物が、請求項1に記載の組成物である、方法。
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/CN2019/095739 WO2021007692A1 (en) | 2019-07-12 | 2019-07-12 | Aqueous polymer formulation |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2022546182A true JP2022546182A (ja) | 2022-11-04 |
Family
ID=74210085
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2022500745A Pending JP2022546182A (ja) | 2019-07-12 | 2019-07-12 | 水性ポリマー配合物 |
Country Status (9)
Country | Link |
---|---|
US (1) | US20220282081A1 (ja) |
EP (1) | EP3997186A4 (ja) |
JP (1) | JP2022546182A (ja) |
CN (1) | CN114072479B (ja) |
AR (1) | AR119215A1 (ja) |
BR (1) | BR112021026784A2 (ja) |
MX (1) | MX2022000013A (ja) |
TW (1) | TW202111064A (ja) |
WO (1) | WO2021007692A1 (ja) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114380938B (zh) * | 2021-12-30 | 2022-08-16 | 江苏艾科赛特新材料有限公司 | 一种提高耐水性能的矿物棉专用无甲醛定型剂 |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6262159B1 (en) * | 1999-01-08 | 2001-07-17 | Basf Aktiengesellschaft | Polymer dispersion containing dispersed particles, a dissolved polymer, and an amine |
JP2006036920A (ja) * | 2004-07-27 | 2006-02-09 | Toyo Kasei Kogyo Co Ltd | 水性樹脂組成物およびその製造方法 |
JP2011508006A (ja) * | 2007-12-19 | 2011-03-10 | イーストマン ケミカル カンパニー | 接着促進剤の水性分散体 |
JP2011174056A (ja) * | 2010-01-29 | 2011-09-08 | Toray Ind Inc | 繊維強化熱可塑性樹脂組成物および強化繊維束 |
JP2015511260A (ja) * | 2012-02-08 | 2015-04-16 | ハネウェル・インターナショナル・インコーポレーテッド | 高性能水性粘着性アクリル酸系感圧接着剤 |
JP2015117382A (ja) * | 2010-03-26 | 2015-06-25 | ユーエムジー・エービーエス株式会社 | プロピレン系水性分散体及び、それを用いた水性塗料組成物、その製造方法 |
WO2018176298A1 (en) * | 2017-03-30 | 2018-10-04 | Rohm And Haas Company | Formaldehyde-free curable composition |
EP3486295A1 (en) * | 2016-12-21 | 2019-05-22 | LG Chem, Ltd. | Adhesive composition having excellent kisstack characteristics |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2012176677A1 (ja) * | 2011-06-23 | 2012-12-27 | ユニチカ株式会社 | 水性分散体、ならびにそれを用いてなる積層体、履物用接着剤および履物 |
FR3030557B1 (fr) * | 2014-12-17 | 2016-12-23 | Bostik Sa | Composition adhesive de fixation a base aqueuse presentant une tenue au fluage amelioree |
-
2019
- 2019-07-12 BR BR112021026784A patent/BR112021026784A2/pt unknown
- 2019-07-12 EP EP19937990.0A patent/EP3997186A4/en active Pending
- 2019-07-12 MX MX2022000013A patent/MX2022000013A/es unknown
- 2019-07-12 JP JP2022500745A patent/JP2022546182A/ja active Pending
- 2019-07-12 CN CN201980098173.2A patent/CN114072479B/zh active Active
- 2019-07-12 US US17/597,414 patent/US20220282081A1/en active Pending
- 2019-07-12 WO PCT/CN2019/095739 patent/WO2021007692A1/en unknown
-
2020
- 2020-06-15 TW TW109120082A patent/TW202111064A/zh unknown
- 2020-06-19 AR ARP200101754A patent/AR119215A1/es active IP Right Grant
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6262159B1 (en) * | 1999-01-08 | 2001-07-17 | Basf Aktiengesellschaft | Polymer dispersion containing dispersed particles, a dissolved polymer, and an amine |
JP2006036920A (ja) * | 2004-07-27 | 2006-02-09 | Toyo Kasei Kogyo Co Ltd | 水性樹脂組成物およびその製造方法 |
JP2011508006A (ja) * | 2007-12-19 | 2011-03-10 | イーストマン ケミカル カンパニー | 接着促進剤の水性分散体 |
JP2011174056A (ja) * | 2010-01-29 | 2011-09-08 | Toray Ind Inc | 繊維強化熱可塑性樹脂組成物および強化繊維束 |
JP2015117382A (ja) * | 2010-03-26 | 2015-06-25 | ユーエムジー・エービーエス株式会社 | プロピレン系水性分散体及び、それを用いた水性塗料組成物、その製造方法 |
JP2015511260A (ja) * | 2012-02-08 | 2015-04-16 | ハネウェル・インターナショナル・インコーポレーテッド | 高性能水性粘着性アクリル酸系感圧接着剤 |
EP3486295A1 (en) * | 2016-12-21 | 2019-05-22 | LG Chem, Ltd. | Adhesive composition having excellent kisstack characteristics |
WO2018176298A1 (en) * | 2017-03-30 | 2018-10-04 | Rohm And Haas Company | Formaldehyde-free curable composition |
Also Published As
Publication number | Publication date |
---|---|
CN114072479B (zh) | 2024-01-05 |
US20220282081A1 (en) | 2022-09-08 |
MX2022000013A (es) | 2022-02-24 |
AR119215A1 (es) | 2021-12-01 |
WO2021007692A1 (en) | 2021-01-21 |
TW202111064A (zh) | 2021-03-16 |
CN114072479A (zh) | 2022-02-18 |
EP3997186A4 (en) | 2023-03-29 |
EP3997186A1 (en) | 2022-05-18 |
BR112021026784A2 (pt) | 2022-02-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US5451432A (en) | Treating flexible, porous substrates with formaldehyde free binder | |
JPH10204302A (ja) | ホルムアルデヒド非含有硬化性水性組成物 | |
JPH11106437A (ja) | ポリマー組成物 | |
JP2022546182A (ja) | 水性ポリマー配合物 | |
JPS603411B2 (ja) | グラフト化鉱油で増量されたラテックス | |
JPH07216164A (ja) | ホルムアルデヒドを含有しない合成樹脂水分散液 | |
TWI713498B (zh) | 核-殼水性乳膠 | |
TW202128927A (zh) | 黏著劑組成物 | |
TWI700327B (zh) | 含有寡聚物之組合物 | |
JP5150707B2 (ja) | 硬化性水性組成物 | |
JPH02294334A (ja) | 水性プラスチツク分散液 | |
JPS63175151A (ja) | 耐溶剤性に優れる不織布用結合剤 | |
JPH0328212A (ja) | 水性樹脂組成物 | |
JPS6328086B2 (ja) | ||
JPH0374416A (ja) | 不織布または紙含浸用水分散性樹脂組成物 | |
EP0434388A2 (en) | Emulsion polymerisation |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
RD03 | Notification of appointment of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7423 Effective date: 20220112 |
|
RD04 | Notification of resignation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7424 Effective date: 20220506 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20220629 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20230620 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20230621 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20230915 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20231120 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20240123 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20240422 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20240619 |