JP2022036169A - Paint material made of cosmetic material, diluent for paint material, paint material and paint set - Google Patents
Paint material made of cosmetic material, diluent for paint material, paint material and paint set Download PDFInfo
- Publication number
- JP2022036169A JP2022036169A JP2021213226A JP2021213226A JP2022036169A JP 2022036169 A JP2022036169 A JP 2022036169A JP 2021213226 A JP2021213226 A JP 2021213226A JP 2021213226 A JP2021213226 A JP 2021213226A JP 2022036169 A JP2022036169 A JP 2022036169A
- Authority
- JP
- Japan
- Prior art keywords
- paint
- diluent
- powder
- cosmetic
- cosmetics
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000002537 cosmetic Substances 0.000 title claims abstract description 230
- 239000000463 material Substances 0.000 title claims abstract description 154
- 239000003085 diluting agent Substances 0.000 title claims abstract description 101
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000000843 powder Substances 0.000 claims description 148
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 48
- 239000010445 mica Substances 0.000 claims description 29
- 229910052618 mica group Inorganic materials 0.000 claims description 29
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- 229920000620 organic polymer Polymers 0.000 description 1
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 229940098695 palmitic acid Drugs 0.000 description 1
- 229940056211 paraffin Drugs 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229960000969 phenyl salicylate Drugs 0.000 description 1
- 229940057874 phenyl trimethicone Drugs 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 235000009991 pite Nutrition 0.000 description 1
- 244000293655 pite Species 0.000 description 1
- 229920003216 poly(methylphenylsiloxane) Polymers 0.000 description 1
- 229920003217 poly(methylsilsesquioxane) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229940062000 polyglyceryl-2 triisostearate Drugs 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000004405 propyl p-hydroxybenzoate Substances 0.000 description 1
- 229940116422 propylene glycol dicaprate Drugs 0.000 description 1
- 229960003415 propylparaben Drugs 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 239000001057 purple pigment Substances 0.000 description 1
- KXXXUIKPSVVSAW-UHFFFAOYSA-K pyranine Chemical compound [Na+].[Na+].[Na+].C1=C2C(O)=CC(S([O-])(=O)=O)=C(C=C3)C2=C2C3=C(S([O-])(=O)=O)C=C(S([O-])(=O)=O)C2=C1 KXXXUIKPSVVSAW-UHFFFAOYSA-K 0.000 description 1
- WPPDXAHGCGPUPK-UHFFFAOYSA-N red 2 Chemical compound C1=CC=CC=C1C(C1=CC=CC=C11)=C(C=2C=3C4=CC=C5C6=CC=C7C8=C(C=9C=CC=CC=9)C9=CC=CC=C9C(C=9C=CC=CC=9)=C8C8=CC=C(C6=C87)C(C=35)=CC=2)C4=C1C1=CC=CC=C1 WPPDXAHGCGPUPK-UHFFFAOYSA-N 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 239000002151 riboflavin Substances 0.000 description 1
- 235000019192 riboflavin Nutrition 0.000 description 1
- 229960002477 riboflavin Drugs 0.000 description 1
- 239000008165 rice bran oil Substances 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 235000019512 sardine Nutrition 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 229940057910 shea butter Drugs 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- LLELVHKMCSBMCX-UHFFFAOYSA-M sodium 1-[(4-chloro-5-methyl-2-sulfophenyl)diazenyl]naphthalen-2-olate Chemical compound [Na+].Cc1cc(N=Nc2c(O)ccc3ccccc23)c(cc1Cl)S([O-])(=O)=O LLELVHKMCSBMCX-UHFFFAOYSA-M 0.000 description 1
- AZLXCBPKSXFMET-UHFFFAOYSA-M sodium 4-[(4-sulfophenyl)diazenyl]naphthalen-1-olate Chemical compound [Na+].C12=CC=CC=C2C(O)=CC=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 AZLXCBPKSXFMET-UHFFFAOYSA-M 0.000 description 1
- JAOZKJMVYIWLKU-UHFFFAOYSA-N sodium 7-hydroxy-8-[(4-sulfonaphthalen-1-yl)diazenyl]naphthalene-1,3-disulfonic acid Chemical compound C1=CC=C2C(=C1)C(=CC=C2S(=O)(=O)O)N=NC3=C(C=CC4=CC(=CC(=C43)S(=O)(=O)O)S(=O)(=O)O)O.[Na+] JAOZKJMVYIWLKU-UHFFFAOYSA-N 0.000 description 1
- 235000019259 sodium dehydroacetate Nutrition 0.000 description 1
- 229940079839 sodium dehydroacetate Drugs 0.000 description 1
- DSOWAKKSGYUMTF-GZOLSCHFSA-M sodium;(1e)-1-(6-methyl-2,4-dioxopyran-3-ylidene)ethanolate Chemical compound [Na+].C\C([O-])=C1/C(=O)OC(C)=CC1=O DSOWAKKSGYUMTF-GZOLSCHFSA-M 0.000 description 1
- NOJQBSUJVLPAQO-UHFFFAOYSA-L sodium;zinc;hexadecyl phosphate Chemical compound [Na+].[Zn+2].CCCCCCCCCCCCCCCCOP([O-])([O-])=O NOJQBSUJVLPAQO-UHFFFAOYSA-L 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002195 soluble material Substances 0.000 description 1
- 229950011392 sorbitan stearate Drugs 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 229960004274 stearic acid Drugs 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910052917 strontium silicate Inorganic materials 0.000 description 1
- QSQXISIULMTHLV-UHFFFAOYSA-N strontium;dioxido(oxo)silane Chemical compound [Sr+2].[O-][Si]([O-])=O QSQXISIULMTHLV-UHFFFAOYSA-N 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- BORJONZPSTVSFP-UHFFFAOYSA-N tetradecyl 2-hydroxypropanoate Chemical compound CCCCCCCCCCCCCCOC(=O)C(C)O BORJONZPSTVSFP-UHFFFAOYSA-N 0.000 description 1
- DZKXJUASMGQEMA-UHFFFAOYSA-N tetradecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC DZKXJUASMGQEMA-UHFFFAOYSA-N 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- 235000010384 tocopherol Nutrition 0.000 description 1
- 229960001295 tocopherol Drugs 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 229940042585 tocopherol acetate Drugs 0.000 description 1
- 239000001069 triethyl citrate Substances 0.000 description 1
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 description 1
- 235000013769 triethyl citrate Nutrition 0.000 description 1
- QPQANCNBWQXGTQ-UHFFFAOYSA-N trihydroxy(trimethylsilylperoxy)silane Chemical compound C[Si](C)(C)OO[Si](O)(O)O QPQANCNBWQXGTQ-UHFFFAOYSA-N 0.000 description 1
- LINXHFKHZLOLEI-UHFFFAOYSA-N trimethyl-[phenyl-bis(trimethylsilyloxy)silyl]oxysilane Chemical compound C[Si](C)(C)O[Si](O[Si](C)(C)C)(O[Si](C)(C)C)C1=CC=CC=C1 LINXHFKHZLOLEI-UHFFFAOYSA-N 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 description 1
- 229960002703 undecylenic acid Drugs 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000010497 wheat germ oil Substances 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229940105125 zinc myristate Drugs 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- 229940057977 zinc stearate Drugs 0.000 description 1
- KUPGJMJHAFGISS-UHFFFAOYSA-L zinc;hexadecyl phosphate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCOP([O-])([O-])=O KUPGJMJHAFGISS-UHFFFAOYSA-L 0.000 description 1
- GBFLQPIIIRJQLU-UHFFFAOYSA-L zinc;tetradecanoate Chemical compound [Zn+2].CCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCC([O-])=O GBFLQPIIIRJQLU-UHFFFAOYSA-L 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
- OENHQHLEOONYIE-JLTXGRSLSA-N β-Carotene Chemical compound CC=1CCCC(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C OENHQHLEOONYIE-JLTXGRSLSA-N 0.000 description 1
Images
Abstract
Description
本発明は、化粧料からなる絵の具材料、絵の具材料用希釈剤、絵の具及び絵の具セットに関する。さらに詳しくは、廃棄対象の化粧料等を利用可能な化粧料からなる絵の具材料、絵の具材料用希釈剤、絵の具及び絵の具セットに関する。 The present invention relates to paint materials made of cosmetics, diluents for paint materials, paints and paint sets. More specifically, the present invention relates to a paint material composed of a cosmetic that can be used as a cosmetic to be discarded, a diluent for the paint material, a paint, and a paint set.
粉末状化粧料をはじめとした化粧料が流通され、女性を中心に使用されている。一般的な粉末状化粧料は、ファンデーション、フェイスパウダー等のベースメイクやアイシャドウ、チーク等のポイントメイクがあり、これらはいずれも人の肌への塗抹等を目的として使用されるものである。また、粉末状化粧料を構成する体質粉体等の粉体は鉱物を由来とするものが大半であるが(例えば、特許文献1等を参照。)、一部の鉱物においては枯渇が叫ばれている。
Cosmetics such as powdered cosmetics are distributed and used mainly by women. General powdered cosmetics include base makeup such as foundation and face powder, and point makeup such as eye shadow and cheek, all of which are used for the purpose of smearing on human skin. In addition, most of the powders such as constitutional powders constituting powdered cosmetics are derived from minerals (see, for example,
これに対して、個人消費者は粉末状化粧料を使い切らずに廃棄することが多く、また、化粧料を製造・販売する企業においてもある一定の品質をクリアしなかった粉末状化粧料のバルク(中身)を年間に大量廃棄している。持続可能的な社会を目指すべき近年の情勢を鑑みても、廃棄対象となる粉末状化粧料の有効利用を考えていくべきであり、それに対応する技術の確立が望まれている。 On the other hand, individual consumers often dispose of powdered cosmetics without using them up, and even companies that manufacture and sell cosmetics do not meet a certain level of quality in bulk powdered cosmetics. (Contents) are discarded in large quantities annually. Considering the recent situation in which we should aim for a sustainable society, we should consider the effective use of powdered cosmetics to be discarded, and it is desired to establish the technology to deal with them.
ここで、粉末状化粧料等の化粧料には、顔料や光輝性のある粉体が配合されている場合が多く、その場合は視覚で多彩な色彩を楽しめるという特性がある。かかる特性を有したまま、廃棄対象となる粉末状化粧料を、例えば絵の具へと転化させることができれば、廃棄対象となる粉末状化粧料の新たな使用方法をもたらすことが可能となる。 Here, cosmetics such as powdered cosmetics often contain pigments or brilliant powders, and in that case, there is a characteristic that various colors can be visually enjoyed. If the powdered cosmetics to be discarded can be converted into, for example, paints while maintaining such characteristics, it is possible to bring about a new method of using the powdered cosmetics to be discarded.
粉末状化粧料には、一般に、シリコーン油、炭化水素油等の油性成分(油剤)とマイカ、タルク、シリカ、硫酸バリウム、合成金雲母等の体質粉体や、酸化チタン等の色材等や必要により界面活性剤等が配合されており、これらを金皿等の容器に詰めてプレスされているものが多い。 In general, powdered cosmetics include oily components (oil agents) such as silicone oil and hydrocarbon oil, constitutional powders such as mica, talc, silica, barium sulfate and synthetic gold mica, and coloring materials such as titanium oxide. If necessary, a surfactant or the like is blended, and in many cases, these are packed in a container such as a gold plate and pressed.
このため、粉末状化粧料中の粉体は部分的にある一定量の油性成分で被覆されている場合があり、粉末状化粧料を粉砕し、市販される水系の液体と混練しても、濡れが進まずに分離してしまうため、絵の具様のスラリー状にすることは困難であった。 Therefore, the powder in the powdered cosmetic may be partially covered with a certain amount of oily component, and even if the powdered cosmetic is crushed and kneaded with a commercially available water-based liquid, it may be mixed. It was difficult to make a paint-like slurry because the wetness did not proceed and the powder separated.
本発明は、前記に鑑みてなされたものであって、市販される一般の水彩絵の具と同等に使用することができる化粧料からなる絵の具材料、絵の具材料用希釈剤、絵の具及び絵の具セットを提供することにある。 The present invention is made in view of the above, and provides a paint material made of a cosmetic, a diluent for the paint material, a paint, and a paint set, which can be used in the same manner as general watercolor paints on the market. There is something in it.
前記の課題を解決するために、本発明に係る化粧料からなる絵の具材料は、
体質粉体及び色材を含み、かつ、
含有される成分を含有量が多い順に並べた場合に、上から5番目までに、油性成分が3種以下となる化粧料を含むことを特徴とする。
In order to solve the above-mentioned problems, the paint material made of the cosmetic according to the present invention is used.
Contains constitutional powder and coloring material, and
When the contained components are arranged in descending order of content, the fifth from the top is characterized by containing cosmetics having 3 or less oily components.
本発明に係る化粧料からなる絵の具材料は、前記した本発明において、含有される成分を含有量が多い順に並べた場合に、上から3番目までに体質粉体を1種以上含むことを特徴とする。 The paint material made of the cosmetic according to the present invention is characterized in that, in the above-mentioned invention, when the contained components are arranged in descending order of content, one or more constitutional powders are contained in the third order from the top. And.
本発明に係る化粧料からなる絵の具材料は、前記した本発明において、前記上から3番目までに含まれる体質粉体が、マイカ、タルク、合成金雲母、シリカ及び硫酸バリウムよりなる群から選ばれた少なくとも1種であることを特徴とする。 In the above-mentioned invention, the constitutional powder contained in the third item from the top is selected from the group consisting of mica, talc, synthetic phlogopite, silica and barium sulfate. It is characterized by being at least one species.
本発明に係る化粧料からなる絵の具材料は、前記した本発明において、含有される成分を含有量が多い順に並べた場合に、上から3番目までにパール粉体を含まないことを特徴とする。 The paint material made of the cosmetic according to the present invention is characterized in that, in the above-mentioned invention, when the contained components are arranged in descending order of content, the pearl powder is not contained in the third order from the top. ..
本発明に係る化粧料からなる絵の具材料は、前記した本発明において、前記化粧料が、アイシャドウ、チーク、ボディパウダー、フェイスパウダー、美白パウダー、スキンケアパウダー、ルースパウダー、プレストパウダー及びファンデーションよりなる群から選ばれた少なくとも1種であることを特徴とする。 The paint material comprising the cosmetic according to the present invention is the group in which the cosmetic comprises eye shadow, teak, body powder, face powder, whitening powder, skin care powder, loose powder, pressed powder and foundation in the present invention. It is characterized by being at least one selected from.
本発明に係る絵の具材料用希釈剤は、化粧料からなる絵の具材料を希釈するための希釈剤であって、下記の成分;
水:希釈剤全体に対して49.5~89.0質量%、
低級アルコール:希釈剤全体に対して10.0~35.0質量%、
ポリビニルアルコール:希釈剤全体に対して0.5~15.0質量%、
を含有することを特徴とする。
The diluent for paint materials according to the present invention is a diluent for diluting paint materials made of cosmetics, and has the following components;
Water: 49.5-89.0% by weight based on the total diluent,
Lower alcohol: 10.0 to 35.0% by mass based on the total diluent,
Polyvinyl alcohol: 0.5 to 15.0% by mass based on the total diluent,
It is characterized by containing.
本発明に係る絵の具材料用希釈剤は、前記した本発明において、前記低級アルコールがエタノールであることを特徴とする。 The diluent for paint materials according to the present invention is characterized in that, in the above-mentioned invention, the lower alcohol is ethanol.
本発明に係る絵の具は、
前記した本発明の化粧料からなる絵の具材料と、
前記した本発明の絵の具材料用希釈剤と、
を混合した混合体を含むことを特徴とする。
The paint according to the present invention is
The above-mentioned paint material made of the cosmetic of the present invention and
The above-mentioned diluent for paint materials of the present invention and
It is characterized by containing a mixture of the above.
本発明に係る絵の具セットは、
前記した本発明の化粧料からなる絵の具材料と、
前記した本発明の絵の具材料用希釈剤と、
を含むことを特徴とする。
The paint set according to the present invention is
The above-mentioned paint material made of the cosmetic of the present invention and
The above-mentioned diluent for paint materials of the present invention and
It is characterized by including.
本発明に係る化粧料からなる絵の具材料は、絵の具材料用希釈剤と併用することにより、絵の具としての最低限の特性を有することとなり、一般の絵の具と同様に使用することができ、廃棄対象となる化粧料の有効利用を図ることを可能とする。特に、かかる希釈剤と併用することで、一般の絵の具よりも画用紙へ伸び広げたときの膜の透明感、速乾性、香り等において、化粧料をベースとした絵の具材料特有の良好な特性を期待することができる。 The paint material made of the cosmetic according to the present invention has the minimum characteristics as a paint when used in combination with a diluent for the paint material, and can be used in the same manner as general paints, and is subject to disposal. It makes it possible to make effective use of cosmetics. In particular, when used in combination with such a diluent, it is expected to have better properties peculiar to paint materials based on cosmetics, such as transparency, quick-drying, and fragrance of the film when spread on drawing paper compared to general paints. can do.
本発明に係る絵の具材料用希釈剤は、化粧料からなる絵の具材料と併用することにより、絵の具材料用化粧料に対して絵の具材料として不足している成分を補う役割を果たすことができる。 The diluent for paint materials according to the present invention can play a role of supplementing the components lacking as paint materials with respect to the paint materials for paint materials when used in combination with the paint materials made of cosmetics.
本発明に係る絵の具、及び絵の具セットは、本発明に係る化粧料からなる絵の具材料及び本発明に係る絵の具材料用希釈剤よりなり、一般の絵の具と同様に使用することができる絵の具、及び絵の具材料を専用の希釈剤とセットとした絵の具セットとして提供することができる。 The paint and the paint set according to the present invention consist of a paint material made of the cosmetic according to the present invention and a diluent for the paint material according to the present invention, and can be used in the same manner as general paints, and paint materials. Can be provided as a paint set with a special diluent.
以下、本発明の一態様について説明する。 Hereinafter, one aspect of the present invention will be described.
(I)化粧料からなる絵の具材料:
本発明は、化粧料からなる絵の具材料であるが、市販される化粧料のうち、本発明に適用が可能と考えられる化粧料としては、例えば、パウダーアイシャドウ(アイカラー)等の各種アイシャドウ(アイカラー)、パウダーチーク等の各種チーク(チークカラー)、ボディパウダー、フェイスパウダー、美白パウダー、スキンケアパウダー、ルースパウダー、プレストパウダー、ファンデーション等のメイクアップ(メークアップ)化粧料等の粉末状化粧料を含む化粧料や、化粧下地等のメイクアップ化粧料の下地等となる下地化粧料等の粉末状化粧料を含む化粧料が挙げられる。
(I) Paint material consisting of cosmetics:
The present invention is a paint material made of cosmetics, and among commercially available cosmetics, various eye shadows such as powder eye shadows (eye colors) are considered to be applicable to the present invention. (Eye color), various teaks such as powder teak (cheek color), body powder, face powder, whitening powder, skin care powder, loose powder, pressed powder, foundation and other make-up (makeup) cosmetics and other powdered makeup Examples thereof include cosmetics containing a material and cosmetics containing powdered cosmetics such as a base cosmetic that serves as a base for make-up cosmetics such as a makeup base.
これらの化粧料は、その1種を単独で使用してもよく、2種以上を組み合わせて使用してもよい。また、これらの化粧料は、廃棄対象となるものを使用しても問題はなく、本来廃棄する予定であった化粧料を使用することで、廃棄対象となる化粧料の有効利用を図ることができる。 These cosmetics may be used alone or in combination of two or more. In addition, there is no problem with using these cosmetics that are to be discarded, and by using the cosmetics that were originally planned to be discarded, it is possible to make effective use of the cosmetics that are to be discarded. can.
このうち、アイシャドウ(アイカラー)は、例えば、まぶた側のアイホールと、下まぶた、目尻といった目の周囲に、異なるトーンのカラーを付けて陰影を形成するために順に塗られる化粧料である。 Of these, eye shadow (eye color) is a cosmetic that is applied in order to form shadows by applying different tones of color to the eye holes on the eyelid side and around the eyes such as the lower eyelid and the outer corner of the eye. ..
チーク(チークカラー)とは、いわゆる頬紅(ほおべに)のことであり、頬に塗布して顔色を明るく見せたり、頬に陰影をつけて 立体感をだすために用いられる化粧料である。剤型は固形状、粉末状、クリーム状、液状、スティック状などがあるが、本発明には粉末状が適する。 Cheek (cheek color) is so-called blusher, which is a cosmetic that is applied to the cheeks to make the complexion look brighter, or to add shadows to the cheeks to give a three-dimensional effect. The dosage form may be solid, powder, cream, liquid, stick or the like, but the powder is suitable for the present invention.
ボディパウダーとは、油のぎらつきを抑え、マットで自然な仕上がりを与えるために用 いられる化粧料である。 Body powder is a cosmetic that is used to suppress oil glare and give a matte, natural finish.
フェイスパウダーとは、化粧の仕上げに使用し、皮脂やファンデーションのいわゆるてかり(テカリ)やべたつきを抑えるための化粧料である。美白効果を有する美白パウダー、スキンケア効果を有するスキンケアパウダー、ルースパウダーもフェイスパウダーやボディパウダーの一種と考えられる。 Face powder is a cosmetic that is used to finish makeup and suppresses the so-called shine and stickiness of sebum and foundation. Whitening powder with whitening effect, skin care powder with skin care effect, and loose powder are also considered to be a kind of face powder and body powder.
ブレストパウダーは、前記したフェイスパウダーの一種で、基本的には後記するファンデーションを用いた後に使用され。ファンデーションを整えコーティングし、より綺麗な肌に見せるための化粧料である。 Breast powder is a kind of face powder mentioned above, and is basically used after using the foundation described later. It is a cosmetic that prepares and coats the foundation to make the skin look more beautiful.
ファンデーションとは、肌のカラーを整えたり、肌のそばかすやしみ等を被覆して、紫外線から保護等をするためになされる化粧料である。後記する化粧下地を肌上に塗布した後、塗布されるメイクアップ化粧料である。 Foundation is a cosmetic that is used to adjust the color of the skin, cover freckles and age spots on the skin, and protect it from ultraviolet rays. It is a make-up cosmetic that is applied after applying the makeup base described later on the skin.
化粧下地とは、ファンデーション等のメイクアップ化粧料を塗布する前に下地として用いるものであり、かかるメイクアップ化粧料の発色性を付着力(つき)、被覆力(のり)を良好にして、化粧仕上がりの美しさや、化粧くずれを防ぎメイクアップ効果の持続等を目的として使用されるベース材となる化粧料である。 The makeup base is used as a base before applying make-up cosmetics such as foundation, and the color-developing property of the make-up cosmetics is improved in adhesion (attachment) and covering power (glue) to make up. It is a cosmetic that is used as a base material for the purpose of beautiful finish, prevention of makeup breakage, and maintenance of makeup effect.
なお、本発明に係る絵の具材料に適する粉末状化粧料とは、一般に、粉体(粉体成分)を主成分(概ね、化粧料全体の60質量%以上と考えられており、60~95質量%であることが好ましいが、これには限定されない。)とし、必要により適宜水性成分や油性成分等を混合した化粧料を指し、概ね粒径1.0mm以下の粉体粒子からなり、常温、常圧下で各粒子が自由に流動できるものをいうものと解されるが、特にこれには限定されず、化粧業界で一般的に粉末状化粧料と呼ばれる化粧料を広く使用することができる。 The powdered cosmetics suitable for the paint material according to the present invention are generally considered to contain powder (powder component) as a main component (generally 60% by mass or more of the total amount of the cosmetics), and have a mass of 60 to 95%. %, But is not limited to this), and refers to cosmetics mixed with water-based components, oil-based components, etc. as appropriate. It is understood that each particle can freely flow under normal pressure, but the present invention is not particularly limited to this, and cosmetics generally called powdered cosmetics in the cosmetic industry can be widely used.
前記に代表される対象となる化粧料に含まれる成分としては、例えば、体質粉体(例えば、無機粉体、有機粉体、界面活性剤金属塩粉体(金属石鹸)等。)、色材(例えば、無機顔料、有機顔料、天然色素、パール粉体等。)、油性成分(例えば、天然由来の植物油や動物油等、炭化水素油、エステル油(グリセライド油を含む。)、高級脂肪酸、高級アルコール、シリコーン油、ワックス、油性増粘剤、有機溶剤等。)、その他の成分(例えば、水性防腐剤、粉末状防腐剤、防腐剤、界面活性剤、表面処理剤、酸化防止剤、美容剤、紫外線吸収剤、被膜形成剤、エモリエント成分、水性成分等。)が挙げられる。これらの成分は、その1種を単独で使用してもよく、2種以上を組み合わせて使用してもよい。また、下記に挙げる成分の個々についても、同様に、その1種を単独で使用してもよく、2種以上を組み合わせて使用してもよい。このうち、体質粉体及び色材については、化粧料を絵の具材料として適用するために必須の成分となるが、油性成分、その他の成分にあっては、特にそのようなことはない。また、油性成分については、後記するように、化粧料に含有される成分を含有量が多い順に並べた場合に、上から5番目までに、油性成分が3種以下となるようにしている。 Examples of the components contained in the target cosmetics represented by the above include constitutional powders (for example, inorganic powders, organic powders, surfactant metal salt powders (metal soaps), etc.), and coloring materials. (For example, inorganic pigments, organic pigments, natural pigments, pearl powders, etc.), oily components (for example, naturally derived vegetable oils, animal oils, etc., hydrocarbon oils, ester oils (including glyceride oil), higher fatty acids, higher grades, etc.) Alcohol, silicone oil, wax, oily thickener, organic solvent, etc.) and other ingredients (eg, aqueous preservatives, powdered preservatives, preservatives, surfactants, surface treatments, antioxidants, beauty agents , Ultraviolet absorber, film forming agent, emollient component, aqueous component, etc.). One of these components may be used alone, or two or more thereof may be used in combination. Similarly, for each of the components listed below, one of them may be used alone, or two or more of them may be used in combination. Of these, constitutional powders and coloring materials are essential components for applying cosmetics as paint materials, but oily components and other components are not particularly such. As for the oily components, as will be described later, when the components contained in the cosmetics are arranged in descending order of content, the number of oily components is 3 or less from the top to the 5th.
一般に、粉末状化粧料に含まれる粉体としては、無機粉体、有機粉体、界面活性剤金属塩粉体(金属石鹸)等が例に挙げられる体質粉体と、無機顔料(白色顔料含む。)、有機顔料、天然色素、パール粉体等が例に挙げられる色材等が考えられる。ここで、以下に挙げる粉体は、各種の表面処理が行われていてもいなくても構わない。 In general, powders contained in powdered cosmetics include constitutional powders such as inorganic powders, organic powders, and surfactant metal salt powders (metal soaps), and inorganic pigments (including white pigments). ), Organic pigments, natural pigments, pearl powders and the like can be considered. Here, the powders listed below may or may not be subjected to various surface treatments.
体質粉体(体質顔料とも呼ばれる。)とは、化粧料の剤形を保つための増量剤的な役割として用いられ、加えて化粧料の伸展性や付着性、光沢等を調節や、色調の調整のための調整剤的な役割で用いるものと解される。 Constitution powder (also called constitution pigment) is used as a bulking agent to maintain the dosage form of cosmetics, and in addition, it adjusts the extensibility, adhesion, gloss, etc. of cosmetics, and adjusts the color tone. It is understood that it is used as a regulator for regulation.
体質粉体として用いられる成分は、無機粉体や、天然に産出する粘土鉱物の粉砕品である。それ以外には、例えば、二酸化ケイ素(シリカ)などの合成無機粉体等や、無機顔料ではないが、有機高分子粉体等の有機粉体や、界面活性剤金属塩粉体(金属石鹸)等も個々に分類される場合もある。 The components used as the constitutional powder are inorganic powders and crushed products of naturally occurring clay minerals. Other than that, for example, synthetic inorganic powder such as silicon dioxide (silica), organic powder such as organic polymer powder which is not an inorganic pigment, and surfactant metal salt powder (metal soap). Etc. may also be classified individually.
体質粉体は、化粧料にあっては汗や皮脂の吸収による化粧くずれの防止、粉体形状、粒子径、硬度、表面状態の調整による使用感触の向上、化粧料の伸展性や付着性、白度、色調の調整、透明度の制御による化粧料の光沢の調整などの目的でも使用され、例えば、ファンデーション等のベース用成分として不可欠な成分である。 For cosmetics, constitutional powder prevents makeup from breaking due to absorption of sweat and sebum, improves the feel of use by adjusting the powder shape, particle size, hardness, and surface condition, and the extensibility and adhesiveness of cosmetics. It is also used for the purpose of adjusting the whiteness and color tone, adjusting the gloss of cosmetics by controlling the transparency, and is an indispensable ingredient as a base ingredient for, for example, foundations.
体質粉体として、無機粉体としては、例えば、酸化ジルコニウム、酸化セリウム、酸化マグネシウム、硫酸バリウム(硫酸Ba)、硫酸カルシウム、硫酸マグネシウム、炭酸カルシウム、炭酸マグネシウム、タルク、マイカ、カオリン、セリサイト、白雲母、合成雲母、合成金雲母(合成フルオロフロゴパイト)、金雲母、紅雲母、黒雲母、リチア雲母、ケイ酸、無水ケイ酸、ケイ酸アルミニウム、ケイ酸マグネシウム、ケイ酸アルミニウムマグネシウム、ケイ酸カルシウム、ケイ酸バリウム、ケイ酸ストロンチウム、ケイ酸(Na/K/Al)、タングステン酸金属塩、ヒドロキシアパタイト、バーミキュライト、ハイジライト、ベントナイト、モンモリロナイト、ヘクトライト、ジステアルジモニウムヘクトライト、ゼオライト、セラミックスパウダー、第二リン酸カルシウム、アルミナ、水酸化アルミニウム、窒化ホウ素、窒化ボロン、シリカ、微粒子酸化セリウム、ジメチルシリル化シリカ、オクテニルコハク酸トウモロコシデンプンアルミニウム(オクテニルコハク酸トウモロコシデンプンAl)、オクテニルコハク酸デンプンアルミニウム(オクテニルコハク酸デンプンAl)等が挙げられる。 As the constitutional powder, as the inorganic powder, for example, zirconium oxide, cerium oxide, magnesium oxide, barium sulfate (Ba sulfate), calcium sulfate, magnesium sulfate, calcium carbonate, magnesium carbonate, talc, mica, kaolin, silicite, etc. White mica, synthetic mica, synthetic gold mica (synthetic fluorofrogo pite), gold mica, red mica, black mica, Lithia mica, silicic acid, anhydrous silicic acid, aluminum silicate, magnesium silicate, aluminum magnesium silicate, silicic acid Calcium acid, barium silicate, strontium silicate, silicic acid (Na / K / Al), metal tungstate, hydroxyapatite, vermiculite, hygilite, bentonite, montmorillonite, hectrite, disteardimonium hectrite, zeolite, Ceramic powder, dicalcium phosphate, alumina, aluminum hydroxide, boron nitride, boron nitride, silica, fine particle cerium oxide, dimethylsilylated silica, octenyl succinate corn starch aluminum (octenyl succinate corn starch Al), octenyl succinate starch aluminum (octenyl succinic acid) Distillate Al) and the like can be mentioned.
有機粉体としては、例えば、ポリアミドパウダー、ポリエステルパウダー、ポリエチレンパウダー(ワックスにもなる。)、ポリプロピレンパウダー、ポリスチレンパウダー、ポリウレタンパウダー、ベンゾグアナミンパウダー、ポリメチルベンゾグアナミンパウダー、ポリテトラフルオロエチレンパウダー、ポリメチルメタクリレートパウダー、セルロースパウダー、シルクパウダー、ナイロンパウダー(12ナイロン、6ナイロン等)等が挙げられる。なお、これらの「~パウダー」の記載は便宜上のものであり、「パウダー」の記載がつけられていないもの(例えば、「ポリエチレン」、「ポリプロピレン」等。)も含む。 Examples of the organic powder include polyamide powder, polyester powder, polyethylene powder (which can also be wax), polypropylene powder, polystyrene powder, polyurethane powder, benzoguanamine powder, polymethylbenzoguanamine powder, polytetrafluoroethylene powder, and polymethylmethacrylate. Examples thereof include powder, cellulose powder, silk powder, nylon powder (12 nylon, 6 nylon, etc.). It should be noted that the description of these "-powder" is for convenience, and includes those without the description of "powder" (for example, "polyethylene", "polypropylene", etc.).
その他の有機粉体としては、例えば、スチレン・アクリル酸共重合体、ジビニルベンゼン・スチレン共重合体、ビニル樹脂、尿素樹脂、フェノール樹脂、フッ素樹脂、ケイ素樹脂、アクリル樹脂、メラミン樹脂、エポキシ樹脂、ポリカーボネイト樹脂、微結晶繊維粉体、デンプン末、ラウロイルリジン(表面処理剤にもなる。)、ポリメチルシルセスキオキサン、(ビニルジメチコン/メチコンシルセスキオキサン)クロスポリマー、(ジメチコン/ビニルジメチコン)クロスポリマー、(ジフェニルジメチコン/ビニルジフェニルジメチコン/シルセスキオキサン)クロスポリマー、ポリメタクリル酸メチル、メタクリル酸メチルクロスポリマー、コーンスターチ、加水分解水添デンプン等が挙げられる。 Examples of other organic powders include styrene / acrylic acid copolymer, divinylbenzene / styrene copolymer, vinyl resin, urea resin, phenol resin, fluororesin, silicon resin, acrylic resin, melamine resin, and epoxy resin. Polycarbonate resin, microcrystalline fiber powder, starch powder, lauroyl lysine (also a surface treatment agent), polymethylsilsesquioxane, (vinyldimethicone / methicone silsesquioxane) crosspolymer, (dimethicone / vinyldimethicone) Examples thereof include cross-polymers, (diphenyldimethicone / vinyldiphenyldimethicone / silsesquioxane) cross-polymers, polymethyl methacrylate, methyl methacrylate cross-polymers, corn starch, hydrolyzed hydrogenated starch and the like.
界面活性剤金属塩粉体(金属石鹸)としては、例えば、ステアリン酸亜鉛、ステアリン酸アルミニウム、ジステアリン酸アルミニウム(ジステアリン酸Al)、ステアリン酸カルシウム、ステアリン酸マグネシウム(ステアリン酸Mg)、ミリスチン酸亜鉛、ミリスチン酸マグネシウム(ミリスチン酸Mg)、セチルリン酸亜鉛、セチルリン酸カルシウム、セチルリン酸亜鉛ナトリウム等が挙げられる。 Examples of the surfactant metal salt powder (metal soap) include zinc stearate, aluminum stearate, aluminum distearate (Al distearate), calcium stearate, magnesium stearate (Mg stearate), zinc myristate, and myristin. Examples thereof include magnesium acid (Mg myristate), zinc cetyl phosphate, calcium cetyl phosphate, sodium zinc cetyl phosphate and the like.
色材は、化粧料を所望の色に着色し、発色させるための粉体等であり、色材として、顔料である無機顔料としては、例えば、微粒子及び顔料級の(酸化チタン(ルチル)、酸化チタン(アナターゼ)等の)酸化チタン(白色顔料であり、パール粉体にもなる。)、微粒子及び顔料級の酸化亜鉛(白色顔料であり、粉末状防腐剤にもなる。)等の無機白色顔料、酸化鉄、水酸化鉄、チタン酸鉄の無機赤色顔料、γ-酸化鉄等の無機褐色系顔料、黄酸化鉄、黄土等の無機黄色系顔料、黒酸化鉄、カーボンブラック等の無機黒色顔料、マンガンバイオレット、コバルトバイオレット等の無機紫色顔料、水酸化クロム、酸化クロム、酸化コバルト、チタン酸コバルト等の無機緑色顔料、コンジョウ(紺青)、グンジョウ(群青)等の無機青色系顔料等が挙げられる。 The coloring material is a powder or the like for coloring a cosmetic into a desired color and developing a color. As a coloring material, examples of the inorganic pigment which is a pigment include fine particles and a pigment grade (titanium oxide (rutyl)). Inorganic substances such as titanium oxide (white pigment, which can also be a pearl powder), fine particles and pigment-grade zinc oxide (white pigment, which can also be a powder preservative), such as titanium oxide (anathase). Inorganic red pigments such as white pigments, iron oxide, iron hydroxide, iron titanate, inorganic brown pigments such as γ-iron oxide, inorganic yellow pigments such as yellow iron oxide and ocher, and inorganic substances such as black iron oxide and carbon black. Inorganic purple pigments such as black pigments, manganese violet and cobalt violet, inorganic green pigments such as chromium hydroxide, chromium oxide, cobalt oxide and cobalt titanate, and inorganic blue pigments such as konjo (dark blue) and gunjo (ultra blue). Can be mentioned.
顔料である有機顔料としては、例えば、タール系色素をレーキ化したもの、天然色素をレーキ化したもの、及びこれらの粉体を複合化した合成樹脂粉体等を使用することができ、例えば、赤2、赤3、赤102、赤104、赤105、赤106、黄4、黄5、緑3、青1、青2、赤201、赤202、赤203、赤204、赤205、赤206、赤207、赤208、赤213、赤214、赤215、赤218、赤219、赤220、赤221、赤223、赤225、赤226、赤227、赤228、赤230(1)、赤230(2)、赤231、赤232、橙201、橙203、橙204、橙205、橙206、橙207、黄201、黄202(1)、黄202(2)、黄203、黄204、黄205、緑201、緑202、緑204、緑205、青201、青202、青203、青204、青205、褐201、紫201、赤401、赤404、赤405、赤501、赤502、赤504、赤505、赤506、橙401、橙402、橙403、黄401、黄402、黄403、黄404、黄405、黄406、黄407、緑401、緑402、青403、青404、紫401、黒401等が挙げられる。 As the organic pigment which is a pigment, for example, a raked tar-based dye, a raked natural dye, a synthetic resin powder in which these powders are combined, and the like can be used, for example. Red 2, Red 3, Red 102, Red 104, Red 105, Red 106, Yellow 4, Yellow 5, Green 3, Blue 1, Blue 2, Red 201, Red 202, Red 203, Red 204, Red 205, Red 206 , Red 207, Red 208, Red 213, Red 214, Red 215, Red 218, Red 219, Red 220, Red 221, Red 223, Red 225, Red 226, Red 227, Red 228, Red 230 (1), Red 230 (2), red 231 and red 232, orange 201, orange 203, orange 204, orange 205, orange 206, orange 207, yellow 201, yellow 202 (1), yellow 202 (2), yellow 203, yellow 204, Yellow 205, Green 201, Green 202, Green 204, Green 205, Blue 201, Blue 202, Blue 203, Blue 204, Blue 205, Brown 201, Purple 201, Red 401, Red 404, Red 405, Red 501, Red 502 , Red 504, Red 505, Red 506, Orange 401, Orange 402, Orange 403, Yellow 401, Yellow 402, Yellow 403, Yellow 404, Yellow 405, Yellow 406, Yellow 407, Green 401, Green 402, Blue 403, Blue Examples thereof include 404, purple 401, and black 401.
色材である天然色素としては、例えば、カルミン、カルミン酸、ラッカイン酸、カルサミン、ブラジリン、クロシン、サロールイエロー、β-カロチン、ハイビスカス色素、カプサインチン、ラッカイ酸、グルクミン、リボフラビン、シコニン等が挙げられる。 Examples of the natural pigment as a coloring material include carmine, carmic acid, laccinic acid, carthamin, brazilin, crocin, salol yellow, β-carotene, hibiscus pigment, capsinetin, laccinic acid, glucmin, riboflavin, ciconin and the like. ..
色材であるパール粉体とは、一般に汎用されているパール光沢を有する粉体であれば良く、例えば、真珠光沢を有する通常の雲母チタンの他に、酸化鉄被覆雲母チタン、酸化鉄被覆雲母、黒酸化鉄被覆雲母チタン、酸化鉄・黒酸化鉄被覆雲母チタン、カルミン被覆雲母チタン、カルミン・コンジョウ被覆雲母チタン、酸化鉄・カルミン処理雲母チタン、コンジョウ処理雲母チタン、酸化鉄・コンジョウ処理雲母チタン、酸化クロム処理雲母チタン、黒酸化チタン処理雲母チタン、合成金雲母、酸化チタン被覆合成金雲母、ガラス末、酸化チタン被覆ガラス末、ポリエチレンテレフタレート・ポリエステルフィルム積層末、雲母片、アクリル樹脂被覆アルミニウム末(色材を含有してもよい)、酸化チタン被覆マイカ、酸化チタン被覆オキシ塩化ビスマス、酸化チタン被覆タルク、着色酸化チタン被覆マイカ、オキシ塩化ビスマス、魚鱗箔、アルミニウムフレーク、ステンレスフレーク、酸化チタン被覆板状アルミナ、酸化錫(スズ)、真珠殻、金箔、金蒸着樹脂フィルム、金属蒸着樹脂フィルム等が挙げられる。 The pearl powder as a coloring material may be any powder having a pearl luster that is generally used. For example, in addition to ordinary mica titanium having a pearl luster, iron oxide-coated mica titanium and iron oxide-coated mica , Black Iron Oxide Coated Mica Titanium, Iron Oxide / Black Iron Oxide Coated Mica Titanium, Carmine Coated Mica Titanium, Carmine / Conjo Coated Mica Titanium, Iron Oxide / Carmine Treated Mica Titanium, Conjo Treated Mica Titanium, Iron Oxide / Conjo Treated Mica Titanium , Chromium oxide treated mica titanium, black titanium oxide treated mica titanium, synthetic gold mica, titanium oxide coated synthetic gold mica, glass powder, titanium oxide coated glass powder, polyethylene terephthalate / polyester film laminated powder, mica piece, acrylic resin coated aluminum powder (May contain coloring material), iron oxide coated mica, iron oxide coated bismuth oxide, titanium oxide coated talc, colored titanium oxide coated mica, bismuth oxychloride, fish scale foil, aluminum flakes, stainless flakes, titanium oxide coating Examples thereof include plate-shaped alumina, iron oxide (tin), pearl husks, gold foil, gold-deposited resin film, and metal-deposited resin film.
また、これ以外のパール粉体としては、例えば、酸化チタン(白色顔料にもなる。)、ホウケイ酸(Ca/Al)、ホウケイ酸(Ca/Na)、(PET/ポリメタクリル酸メチル)ラミネート、(PET/Al)ラミネート、(PET/Al/エポキシ樹脂)ラミネート等が挙げられる。 Other pearl powders include, for example, titanium oxide (which can also be a white pigment), borosilicate (Ca / Al), borosilicate (Ca / Na), (PET / polymethyl methacrylate) laminate, and the like. Examples thereof include (PET / Al) laminating and (PET / Al / epoxy resin) laminating.
油性成分(油剤とも呼ばれる。)としては、油分を含み、剤型を滑らかなものとすることに役立ち、例えば、天然由来の植物油や動物油等、炭化水素油、エステル油(グリセライド油を含む。)、高級脂肪酸、高級アルコール、シリコーン油、ワックス、油性増粘剤、有機溶剤等が挙げられる。 The oily component (also called an oil agent) contains an oil content and is useful for smoothing the formulation. For example, naturally derived vegetable oils, animal oils and the like, hydrocarbon oils and ester oils (including glyceride oils). , Higher fatty acids, higher alcohols, silicone oils, waxes, oily thickeners, organic solvents and the like.
油性成分として、天然由来の植物油や動物油等としては、例えば、アボガド油、アマニ油、アーモンド油、イボタロウ、エノ油、オリーブ油、カカオ脂、カポックロウ、カヤ油、カルナウバロウ、肝油、キャンデリラロウ、キョウニン油、硬化油、小麦胚芽油、ゴマ油、コメ胚芽油、コメヌカ油、サトウキビロウ、サザンカ油、サフラワー油、シアバター、シナギリ油、シナモン油、ジョジョバロウ、セラックロウ、タートル油、大豆油、茶実油、ツバキ油、月見草油、トウモロコシ油、ナタネ油、日本キリ油、ヌカロウ、胚芽油、パーシック油、パーム油、パーム核油、ヒマシ油、硬化ヒマシ油、ヒマシ油脂肪酸メチルエステル、ヒマワリ油、ブドウ油、ベイベリーロウ、ホホバ油、マカデミアナッツ油、ミンク油、綿実油、綿ロウ、モクロウ、モクロウ核油、モンタンロウ、ヤシ油、硬化ヤシ油、トリヤシ油脂肪酸グリセライド、落花生油、ラノリン、液状ラノリン、還元ラノリン、ラノリンアルコール、硬質ラノリン、酢酸ラノリン、ラノリン脂肪酸イソプロピル、POEラノリンアルコールエーテル、POEラノリンアルコールアセテート、ラノリン脂肪酸ポリエチレングリコール、POE水素添加ラノリンアルコールエーテル、水添野菜油、卵黄油等が挙げられる。 As oily components, naturally derived vegetable oils, animal oils and the like include, for example, avocado oil, flaxseed oil, almond oil, sardine oil, eno oil, olive oil, cacao butter, capoc wax, kaya oil, carnauba wax, liver oil, candelilla wax and kyonin oil. , Hardened oil, wheat germ oil, sesame oil, rice germ oil, rice bran oil, sugar cane, southern ka oil, safflower oil, shea butter, cinnamon oil, cinnamon oil, jojobaro, celaclow, turtle oil, soybean oil, brown seed oil , Camellia oil, evening primrose oil, corn oil, rapeseed oil, Japanese millet oil, nukarou, germ oil, persic oil, palm oil, palm kernel oil, sunflower oil, hardened sunflower oil, sunflower oil fatty acid methyl ester, sunflower oil, grape oil , Bayberry wax, jojoba oil, macadamia nut oil, mink oil, cotton seed oil, cotton wax, mokuro, mokuro kernel oil, montan wax, palm oil, hardened palm oil, tri-palm oil fatty acid glyceride, peanut oil, lanolin, liquid lanolin, reduced lanolin, lanolin alcohol , Hard lanolin, lanolin acetate, lanolin fatty acid isopropyl, POE lanolin alcohol ether, POE lanolin alcohol acetate, lanolin fatty acid polyethylene glycol, POE hydrogenated lanolin alcohol ether, hydrogenated vegetable oil, egg yolk oil and the like.
炭化水素油としては、例えば、スクワラン、スクワレン、パラフィン、パラフィンワックス、流動パラフィン(ミネラルオイル)、プリスタン、ポリイソブチレン、ワセリン、ポリイソブテン、ポリブテン等が挙げられる。 Examples of the hydrocarbon oil include squalane, squalane, paraffin, paraffin wax, liquid paraffin (mineral oil), pristane, polyisobutylene, petrolatum, polyisobutene, polybutene and the like.
エステル油(グリセライド油を含む。)としては、例えば、アジピン酸ジイソブチル、アジピン酸2-ヘキシルデシル、アジピン酸ジ-2-ヘプチルウンデシル、モノイソステアリン酸N-アルキルグリコール、イソステアリン酸イソセチル、トリイソステアリン酸トリメチロールプロパン、ジ-2-エチルヘキサン酸エチレングリコール、2-エチルヘキサン酸セチル、トリ-2-エチルヘキサン酸グリセリル(トリエチルヘキサノイン)、トリ-2-エチルヘキサン酸トリメチロールプロパン、テトラ-2-エチルヘキサン酸ペンタエリスリトール、オクタン酸セチル、オクチルドデシルガムエステル、オレイン酸オレイル、オレイン酸オクチルドデシル、オレイン酸デシル、ジカプリン酸ネオペンチルグリコール、クエン酸トリエチル、コハク酸2-エチルヘキシル、酢酸アミル、酢酸エチル、酢酸ブチル、ステアリン酸イソセチル、ステアリン酸ブチル、セバシン酸ジイソプロピル、セバシン酸ジ-2-エチルヘキシル、乳酸セチル、乳酸ミリスチル、パルミチン酸イソプロピル、パルミチン酸2-エチルヘキシル(パルミチン酸エチルヘキシル)、パルミチン酸2-ヘキシルデシル、パルミチン酸2-ヘプチルウンデシル、12-ヒドロキシステアリル酸コレステリル(ヒドロキシステアリン酸コレステリル)、ジペンタエリスリトール脂肪酸エステル、ミリスチン酸イソプロピル、ミリスチン酸オクチルドデシル、ミリスチン酸2-ヘキシルデシル、ミリスチン酸ミリスチル、ジメチルオクタン酸ヘキシルデシル、ラウリン酸エチル、ラウリン酸ヘキシル、N-ラウロイル-L-グルタミン酸-2-オクチルドデシルエステル、リンゴ酸ジイソステアリル、アセトグリセリル、トリイソオクタン酸グリセリル、トリイソステアリン酸ポリグリセリル-2(トリイソステアリン酸グリセリル)(界面活性剤としても用いられる。)、トリイソパルミチン酸グリセリル、モノステアリン酸グリセリル、ジ-2-ヘプチルウンデカン酸グリセリル、トリミリスチン酸グリセリル、ミリスチン酸イソステアリン酸ジグリセリル、トリメリト酸トリトリデシル、ヘキサ(ヒドロキシステアリン酸/ステアリン酸/ロジン酸)ジペンタエリスリチル、ジカプリン酸プロピレングリコール(ジカプリン酸PG)、イソノナン酸イソトリデシル、トリ(カプリル酸/カプリン酸)グリセリル、イソノナン酸イソノニル、ビスジグリセリルポリアシルアジペート-2、ジエチルヘキサン酸ネオペンチルグリコール、ステアロイルオキシステアリン酸オクチルドデシル、ネオペンタン酸イソステアリル、イソステアリン酸水添ヒマシ油、水添トリ脂肪酸(C12-18)グリセリル等が挙げられる。 Examples of the ester oil (including glyceride oil) include diisobutyl adipate, 2-hexyldecyl adipate, di-2-heptylundecyl adipate, N-alkylglycol monoisostearate, isosetyl isostearate, and triisostearic acid. Trimethylol propane, di-2-ethylhexanoate ethylene glycol, 2-ethylhexanoate cetyl, tri-2-ethylhexanoate glyceryl (triethylhexanoin), tri-2-ethylhexanoate trimethylolpropane, tetra-2- Pentaerythritol ethylhexanate, cetyl octanate, octyldodecyl gum ester, oleyl oleate, octyldodecyl oleate, decyl oleate, neopentyl glycol dicaprate, triethyl citrate, 2-ethylhexyl succinate, amyl acetate, ethyl acetate, Butyl acetate, isocetyl stearate, butyl stearate, diisopropyl sebacate, di-2-ethylhexyl sebacate, cetyl lactate, myristyl lactate, isopropyl palmitate, 2-ethylhexyl palmitate (ethylhexyl palmitate), 2-hexyldecyl palmitate , 2-Heptylundecyl palmitate, Cholesteryl 12-hydroxystearyl (cholesteryl hydroxystearate), Dipentaerythritol fatty acid ester, isopropyl myristate, octyldodecyl myristate, 2-hexyldecyl myristate, myristyl myristate, dimethyloctane Hexyldecyl acid, ethyl laurate, hexyl laurate, N-lauroyl-L-glutamate-2-octyldodecyl ester, diisostearyl malate, acetoglyceryl, glyceryl triisooctanoate, polyglyceryl-2 triisostearate-2 (triisostearic acid) Glyceryl) (also used as a surface active agent), glyceryl triisopalmitate, glyceryl monostearate, glyceryl di-2-heptylundecanoate, glyceryl trimyristate, diglyceryl triisostearate, tridecyltricate trimeritate, Hexa (hydroxystearic acid / stearic acid / logonic acid) dipentaerythrityl, propylene glycol dicaprate (PG dicapric acid), isotridecyl isononanoate, tri (capric acid / capric acid) glyceryl, isononyl isononanoate, bisdig Examples thereof include lyceryl polyacyl adipate-2, neopentyl glycol diethylhexanate, octyldodecyl stearoyloxystearate, isostearyl neopentate, hydrogenated castor oil isostearate, hydrogenated trifatty acid (C12-18) glyceryl and the like.
高級脂肪酸としては、例えば、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘン酸、ウンデシレン酸、オレイン酸、リノール酸、リノレン酸、アラキドン酸、エイコサペンタエン酸(EPA)、ドコサヘキサエン酸(DHA)、イソステアリン酸、12-ヒドロキシステアリン酸(ヒドロキシステアリン酸)が挙げられる。 Examples of higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, undecylenic acid, oleic acid, linoleic acid, linolenic acid, arachidonic acid, eicosapentaenoic acid (EPA), docosahexaenoic acid (DHA), and the like. Examples thereof include isostearic acid and 12-hydroxystearic acid (hydroxystearic acid).
高級アルコールとしては、例えば、ラウリルアルコール、ミリスチルアルコール、パルミチルアルコール、ステアリルアルコール、ベヘニルアルコール、ヘキサデシルアルコール、オレイルアルコール、イソステアリルアルコール、ヘキシルドデカノール、オクチルドデカノール、セトステアリルアルコール、2-デシルテトラデシノール、コレステロール、フィトステロール、POEコレステロールエーテル、モノステアリルグリセリンエーテル(バチルアルコール)、モノオレイルグリセリルエーテル(セラキルアルコール)等が挙げられる。 Examples of higher alcohols include lauryl alcohol, myristyl alcohol, palmityl alcohol, stearyl alcohol, behenyl alcohol, hexadecyl alcohol, oleyl alcohol, isostearyl alcohol, hexyldodecanol, octyldodecanol, cetostearyl alcohol and 2-decyltetradecy. Examples thereof include noll, cholesterol, phytosterol, POE cholesterol ether, monostearyl glycerin ether (bacyl alcohol), monooleyl glyceryl ether (ceracyl alcohol) and the like.
シリコーン油としては、例えば、ジメチルシリコーンオイル、環状ジメチルシリコーンオイル、メチルハイドロジェンシリコーンオイル、ポリエーテル変性シリコーンオイル、メチルフェニルシリコーンオイル、フッ素変性シリコーンオイル、ジメチコン、ハイドロゲンジメチコン、シクロペンタシロキサン、メチコン、ジフェニルシロキシフェニルトリメチコン、フェニルトリメチコン等が挙げられる。 Examples of the silicone oil include dimethylsilicone oil, cyclic dimethylsilicone oil, methylhydrogen silicone oil, polyether-modified silicone oil, methylphenylsilicone oil, fluorine-modified silicone oil, dimethicone, hydrogendimethicone, cyclopentasiloxane, methicone, and diphenyl. Examples thereof include siloxyphenyltrimethicone and phenyltrimethicone.
ワックスとしては、例えば、キャンデリラロウ、マイクロクリスタリンワックス、ポリエチレン(体質粉体にもなる。)、セレシン、オゾケライト、ミツロウ、合成ワックス、水添パーム油脂肪酸、ステアリン酸ステアリル等が挙げられる。 Examples of the wax include candelilla wax, microcrystalline wax, polyethylene (which can also be an constitutional powder), selecin, zokerite, beeswax, synthetic wax, hydrogenated palm oil fatty acid, stearyl stearate and the like.
油性増粘剤としては、例えば、(エチレン/プロピレン/スチレン)コポリマー、(ブチレン/エチレン/スチレン)コポリマー、(エチレン/プロピレン)コポリマー、パルミチン酸デキストリン等が挙げられる。 Examples of the oil-based thickener include (ethylene / propylene / styrene) copolymer, (butylene / ethylene / styrene) copolymer, (ethylene / propylene) copolymer, dextrin palmitate and the like.
有機溶剤としては、例えば、イソドデカン等が挙げられる。 Examples of the organic solvent include isododecane and the like.
その他の成分について、水性防腐剤としては、例えば、フェノキシエタノール、カプリリルグリコール等が挙げられる。粉末状防腐剤としては、例えば、酸化亜鉛(白色顔料にもなる。)等が挙げられる。防腐剤としては、例えば、ブチレングリコール(BG。水性成分にもなる。)メチルパラベン、エチルパラベン、プロピルパラベン、ブチルパラベン、カプリリルグリコール、エチルヘキシルグリセリン、プロパンジオール、デヒドロ酢酸ナトリウム(デヒドロ酢酸Na)、銀等が挙げられる。 Regarding other components, examples of the aqueous preservative include phenoxyethanol and caprylyl glycol. Examples of the powdered preservative include zinc oxide (which can also be a white pigment). Examples of preservatives include butylene glycol (BG, which is also an aqueous component) methylparaben, ethylparaben, propylparaben, butylparaben, caprylyl glycol, ethylhexylglycerin, propanediol, sodium dehydroacetate (Na dehydroacetate), and silver. And so on.
界面活性剤としては、例えば、セスキイソステアリン酸ソルビタン、トリイソステアリン酸ポリグリセリル-2(油性成分としても用いられる。)、ステアリン酸ソルビタン、ポリヒドロキシステアリン酸、ポリリシノレイン酸ポリグリセリル-3(油性成分としても用いられる。)等が挙げられる。 Examples of the surfactant include sorbitan sesquiisostearate, polyglyceryl-2 triisostearate (also used as an oily component), sorbitan stearate, polyhydroxystearic acid, and polyglyceryl-3 polylysinoreate (also used as an oily component). ), Etc. can be mentioned.
表面処理剤としては、例えば、パーフルオロヘキシルエチルトリエトキシシラン、イソステアリン酸、ステアリン酸、水酸化アルミニウム(水酸化Al)、トリエトキシカプリリルシラン、パルミチン酸、ラウロイルリシン(体質粉体にもなる。)等が挙げられる。 Examples of the surface treatment agent include perfluorohexylethyltriethoxysilane, isostearic acid, stearic acid, aluminum hydroxide (Al hydroxide), triethoxycaprylylsilane, palmitic acid, and lauroylricin (which can also be constitutional powders). ) Etc. can be mentioned.
酸化防止剤としては、例えば、ジブチルヒドロキシトルエン(BHT)、トコフェロール、酢酸トコフェロール、マロン酸ジエチルヘキシルシリンギリデン等が挙げられる。 Examples of the antioxidant include dibutylhydroxytoluene (BHT), tocopherol, tocopherol acetate, diethylhexylcyringidene malonic acid and the like.
美容剤としては、例えば、レシチン、カミツレエキス、イチゴ果実エキス、ラベンダー花エキス、マグワ根皮エキス、水溶性コラーゲン、キトサン、乳酸桿菌/ハイビスカス花発酵液、テンニンカ果実エキス、ツバキ種子油、加水分解コンキオリン、ラウロイルグルタミン酸ジ(フィトステリル/オクチルドデシル)(セラミドのこと。)等が挙げられる。 Examples of beauty agents include lecithin, chamomile extract, strawberry fruit extract, lavender flower extract, magwa root bark extract, water-soluble collagen, chitosan, lactic acid rod fungus / hibiscus flower fermented liquid, tenninka fruit extract, camellia seed oil, and hydrolyzed conchiolin. , Di (phytosteryl / octyldodecyl) lauroyl glutamate (ceramide) and the like.
紫外線吸収剤としては、例えば、メトキシケイヒ酸エチルヘキシル、t-ブチルメトキシジベンゾイルメタン、メトキシケイヒ酸エチルヘキシル等が挙げられる。 Examples of the ultraviolet absorber include ethylhexyl methoxycinnamate, t-butylmethoxydibenzoylmethane, ethylhexyl methoxycinnamate and the like.
被膜形成剤としては、例えば、トリメチルシロキシケイ酸等が挙げられる。 Examples of the film forming agent include trimethylsiloxysilicic acid and the like.
エモリエント成分としては、例えば、トリ(カプリル酸/カプリン酸)グリセリル等が挙げられる。 Examples of the emollient component include tri (caprylic acid / capric acid) glyceryl and the like.
水性成分としては、例えば、ブチレングリコール(BG。防腐剤にもなる。)、水等が挙げられる。 Examples of the aqueous component include butylene glycol (BG, which also serves as a preservative), water and the like.
本発明に適用可能な前記の化粧料は、色材を含み、かつ、含有される成分を含有量が多い順に並べた場合に、上から3番目までに体質粉体を1種以上含むことが好ましい。化粧料に含まれる色材は光輝性を備えていることが多く、また、体質粉体も絵の具材料のベース材料となるほか、発色を助ける場合が多いので、必須の成分とすることより視覚で多彩な色を楽しめ、絵の具材料として使用するのに適するものである。また、体質粉体は、絵の具として画用紙上へ塗り広げた際の隠ぺい力、着色力、被覆力、延展性、付着性等を調節する機能を有する。 The cosmetics applicable to the present invention may contain one or more constitutional powders in the third order from the top when they contain a coloring material and the contained components are arranged in descending order of content. preferable. Coloring materials contained in cosmetics often have brilliant properties, and constitutional powder is also a base material for paint materials and often helps color development, so it is more visually appealing than making it an essential ingredient. You can enjoy a variety of colors and it is suitable for use as a paint material. In addition, the constitutional powder has a function of adjusting the hiding power, coloring power, covering power, ductility, adhesiveness, etc. when spread on drawing paper as a paint.
なお、色材は、概ね、化粧料全体に対して、0.05質量%以上含有することが好ましく、2.0~30.0質量%の範囲で含有することが特に好ましいが、絵の具材料として使用するに適するだけの発色を備えたものであれば、特にこの範囲には限定されない。また、化粧料を絵の具材料として適用するに際して発色の不足等を感じた場合に、色材を別途添加して、前記した含有量とすることも構わない。 The coloring material is generally preferably contained in an amount of 0.05% by mass or more, particularly preferably in the range of 2.0 to 30.0% by mass, as a paint material. The range is not particularly limited as long as it has enough color to be used. Further, when the cosmetic material is applied as a paint material and a lack of color development is felt, a coloring material may be added separately to obtain the above-mentioned content.
化粧料に含まれる体質粉体はこのように絵の具材料として適する一方、含有される成分を含有量が多い順に並べた場合に、上から3番目までに体質粉体が1種以上含まれていれば、化粧料中に体質粉体が適度に含まれることが期待でき、化粧料全体として絵の具材料として有効に使用することができると考えられる。 While the constitutional powder contained in cosmetics is suitable as a paint material in this way, when the contained components are arranged in descending order of content, one or more constitutional powders should be contained from the top to the third. For example, it can be expected that the constitutional powder is appropriately contained in the cosmetics, and it is considered that the cosmetics as a whole can be effectively used as a paint material.
また、体質粉体は、含有される成分を含有量が多い順に並べた場合に、上から3番目までの成分のうち2種を占めることがさらに好ましく、上から3番目のうち3種全てを占めることが特に好ましい。また、体質粉体は、含有される成分を含有量が多い順に並べた場合に、上から2番目までに体質粉体が含まれることを含むことがさらに好ましく、上から1番目の体質粉体を含むことが特に好ましい。 Further, it is more preferable that the constitutional powder occupies two kinds of the third component from the top when the contained components are arranged in descending order of the content, and all three of the third from the top are included. It is especially preferable to occupy. Further, it is more preferable that the constitutional powder contains the constitutional powder from the top to the second when the contained components are arranged in descending order of the content, and the constitutional powder is the first from the top. Is particularly preferable.
また、含有される成分を含有量が多い順に並べた場合に、上から3番目までに含まれる体質粉体としては、マイカ、タルク、シリカ、合成金雲母(合成フルオロフロゴパイト)、硫酸バリウム(硫酸Ba)によりなる群より選ばれた少なくとも1種であることが好ましい。これらの体質粉体は、給油量の多い嵩高い粉体であり、絵の具材料として適するとともに、絵の具材料として使用した場合には、紙上へ塗り広げた際の隠ぺい力、着色力、被覆力、延展性、付着性等を調節できる。すなわち、紙表面への付着の均一性、仕上がった絵の具膜の平滑性、視覚的透明性等を付与することが可能となる。 In addition, when the contained components are arranged in descending order of content, the constitutional powders contained in the third order from the top include mica, talc, silica, synthetic phlogopite (synthetic fluorophlogopite), and barium sulfate. It is preferably at least one selected from the group consisting of (sulfate Ba). These constitutional powders are bulky powders with a large amount of refueling, and are suitable as paint materials. When used as paint materials, they have hiding power, coloring power, covering power, and spreading power when spread on paper. The sex, adhesiveness, etc. can be adjusted. That is, it is possible to impart uniformity of adhesion to the paper surface, smoothness of the finished paint film, visual transparency, and the like.
対象となる化粧料は、含有される成分を含有量が多い順に並べた場合に、上から5番目までに、油性成分が3種以下となるようにしている。上から5番目までに油性成分が4種以上含まれる場合にあっては、化粧料に対して油性成分が占める割合が高くなると考えられ、併用する絵の具材料用希釈剤(後記する(II)で説明する。)と混合しても、化粧料に希釈剤がなじまず分離してしまい、市販される一般の水彩絵の具と同様な状態とすることができないため好ましくない。また、化粧料と希釈剤が混合できそうな場合でも、希釈剤との軽度な分離が認められ、水に溶いて画用紙に塗抹させた場合にあっては絵の具として使用することが難しい場合があり好ましくない。油性成分は、化粧料に含有される成分を含有量が多い順に並べた場合に、上から5番目までに、油性成分が2種以下となることが好ましく、1種以下となることがさらに好ましく、油性成分を含有しない(0種となる)ことが特に好ましい。 In the target cosmetics, when the contained components are arranged in descending order of content, the number of oily components is 3 or less from the top to the 5th. When four or more oily ingredients are contained in the fifth from the top, it is considered that the ratio of the oily ingredients to the cosmetics is high, and the diluent for paint materials to be used together ((II) described later). Even if it is mixed with (explained), the diluent will not be compatible with the cosmetics and will separate, and it will not be possible to obtain the same state as general watercolor paints on the market, which is not preferable. In addition, even if the cosmetic and the diluent are likely to be mixed, slight separation from the diluent is observed, and it may be difficult to use it as a paint if it is dissolved in water and smeared on drawing paper. Not preferred. As for the oily components, when the components contained in the cosmetics are arranged in descending order of content, the number of oily components is preferably 2 or less, and more preferably 1 or less, from the top to the 5th. , It is particularly preferable that it does not contain an oily component (it becomes 0 kinds).
また、含有される成分を含有量が多い順に並べた場合に、上から3番目までにパール粉体を含まないことが好ましい。真珠光沢顔料(パール剤)や光輝性顔料(ラメ剤)等のパール粉体は、比較的大きな粒径の粉体から形成されるため、上から3番目までに色材としてパール粉体が含まれると、化粧料に対してパール粉体の占める割合が高くなる可能性があり、絵の具化した場合に、画用紙への伸び広がり、画用紙への重ね塗り、画用紙上でできた膜の滑らかさ、画用紙上でできた膜の定着性において悪影響を与える場合があり、また、二次付着性を低下させる可能性もある。含有される成分を含有量が多い順に並べた場合に、上から2番目までにパール粉体を含まないことがさらに好ましく、パール粉体が1番多い成分とならないことが特に好ましい。なお、本発明に関し、「二次付着性」とは現象ではなく評価項目という認識であり、評価項目上の高低及び優劣を記載する。つまり、二次付着性が低くなる及び二次付着性が劣ることは、事象として捉えたとき、二次付着しやすいことを指す。 Further, when the contained components are arranged in descending order of content, it is preferable that the pearl powder is not contained in the third order from the top. Since pearl powders such as pearl luster pigments (pearl agents) and brilliant pigments (lame agents) are formed from powders with a relatively large particle size, the third from the top contains pearl powder as a coloring material. Then, the ratio of pearl powder to cosmetics may increase, and when it is made into a paint, it spreads and spreads on the drawing paper, is overcoated on the drawing paper, and the smoothness of the film formed on the drawing paper. It may adversely affect the fixability of the film formed on the drawing paper, and may also reduce the secondary adhesion. When the contained components are arranged in descending order of content, it is more preferable that the pearl powder is not contained in the second order from the top, and it is particularly preferable that the pearl powder is not the most abundant component. Regarding the present invention, "secondary adhesion" is not a phenomenon but an evaluation item, and the high and low levels and superiority or inferiority of the evaluation items are described. In other words, low secondary adhesion and inferior secondary adhesion mean that secondary adhesion is likely to occur when viewed as an event.
含有される成分には、酸化チタン、酸化亜鉛及び窒化ホウ素よりなる群から選ばれた少なくとも1種を含むことが好ましい。これらの成分は、通常、メイクアップ化粧料等に配合されている成分であるため、汎用成分であると考えられる。 The contained component preferably contains at least one selected from the group consisting of titanium oxide, zinc oxide and boron nitride. Since these ingredients are usually blended in make-up cosmetics and the like, they are considered to be general-purpose ingredients.
本発明で使用される化粧料には、前記の成分のほかに、本発明の目的及び効果を損なわない範囲で、化粧料に一般的に使用される成分、例えば、薬剤、保湿剤、殺菌剤、樹脂等、一般的に化粧料に使用される所望の成分を添加することができる。 In addition to the above-mentioned ingredients, the cosmetics used in the present invention include ingredients generally used in cosmetics, such as drugs, moisturizers, and bactericides, as long as the purpose and effect of the present invention are not impaired. , Resins and the like, desired ingredients generally used in cosmetics can be added.
本発明に係る化粧料からなる絵の具材料を水彩絵の具として用いるには、例えば、後記する絵の具材料用希釈剤と混合して(混合体として)絵の具化される。ここで、絵の具化とは、市販される一般の水彩絵の具と同様な状態(絵の具様)とされることを指す(以下同じ。)。また、絵の具様とされた後、市販される一般の水彩絵の具(以下、単に、「一般の絵の具」とする場合もある。)と同様、適量の水に溶かれて、筆により画用紙上に塗抹されて使用される。 In order to use the paint material made of the cosmetic according to the present invention as a watercolor paint, for example, it is mixed (as a mixture) with a diluent for the paint material described later to be made into a paint. Here, "painting" means that the state (paint-like) is similar to that of general watercolor paints on the market (the same applies hereinafter). In addition, after being made into a paint, it is dissolved in an appropriate amount of water and smeared on drawing paper with a brush, similar to general watercolor paints on the market (hereinafter, may be simply referred to as "general paints"). Will be used.
このような本発明に係る化粧料からなる絵の具材料は、絵の具材料用希釈剤と併用することにより、絵の具材料としての最低限の特性を有することとなり、一般の絵の具と同様に使用することができ、廃棄対象となる化粧料の有効利用を図ることを可能とする。特に、かかる希釈剤と併用することで、一般の絵の具よりも画用紙へ伸び広げたときの膜の透明感、速乾性、香り等において、化粧料をベースとした絵の具材料特有の良好な特性を期待することができる。 When such a paint material made of a cosmetic according to the present invention is used in combination with a diluent for paint materials, it has the minimum characteristics as a paint material and can be used in the same manner as general paints. , It is possible to make effective use of cosmetics to be discarded. In particular, when used in combination with such a diluent, it is expected to have better properties peculiar to paint materials based on cosmetics, such as transparency, quick-drying, and fragrance of the film when spread on drawing paper compared to general paints. can do.
なお、本発明のように化粧料を絵の具化した(以下、便宜上「化粧料絵の具」とする場合もある。)場合には、発色(色の出やすさ)において、化粧料絵の具は一般の絵の具より若干劣る場合もある。これは、人の肌へ塗抹する目的で製造された粉末状化粧料自体に配合されている顔料の濃度が一般の絵の具よりも低いためである。 When the cosmetic is made into a paint as in the present invention (hereinafter, may be referred to as "cosmetic paint" for convenience), the cosmetic paint is a general paint in terms of color development (easiness of color appearance). It may be slightly inferior to that. This is because the concentration of the pigment contained in the powdered cosmetic itself produced for the purpose of smearing on human skin is lower than that of general paints.
また、絵の具化する化粧料の種類によっては、二次付着性(例えば、画用紙へ塗抹して乾いた軌跡を手でなぞり、手に付着しないかどうかで確認できる。)においても、市販される一般の水彩絵の具よりも若干の低下が見られる場合がある。これは、化粧料に配合されている体質粉体等の粉体が、ほぼ顔料級粒径の粉体で構成された一般の絵の具と比較して、比較的大きいことに起因すると考えられる。 In addition, depending on the type of cosmetic used as a paint, it is also generally available on the market in terms of secondary adhesiveness (for example, it can be confirmed by tracing a dry locus on drawing paper with a hand and checking whether it adheres to the hand). May be slightly lower than the watercolor paints in. It is considered that this is because the powder such as the constitutional powder contained in the cosmetic is relatively large as compared with the general paint composed of the powder having a pigment-grade particle size.
一方、例えば、化粧料絵の具により仕上がった描写跡の膜には、化粧料絵の具独特の透明感があり、また、一般の絵の具にはない化粧料絵の具独特の透明感のあるタッチ感を備える場合もある。また、元来が化粧料であることから、香りもよく、後記する希釈剤と混合することにより、速乾性等も良好であると考えられる。 On the other hand, for example, the film of the depiction mark finished by the cosmetic paint has a transparent feeling peculiar to the cosmetic paint, and may also have a transparent touch feeling peculiar to the cosmetic paint which is not found in general paint. be. In addition, since it is originally a cosmetic, it has a good scent, and it is considered that quick-drying and the like are also good by mixing it with a diluent described later.
(II)絵の具材料用希釈剤:
次に、化粧料からなる絵の具材料と併用して使用される絵の具材料用希釈剤(以下、単に「希釈剤」とする場合もある。)について説明する。希釈剤は、前記した本発明に係る化粧料からなる絵の具材料等と併用するのに適し、含有量と特定範囲とした水、低級アルコール、ポリビニルアルコールを含む。かかる絵の具材料用希釈剤は、前記した化粧料等を絵の具材料(絵の具のベース材料)として適用するに際して、かかる化粧料と混合して使用されることにより、化粧料に対して絵の具材料として不足している成分を補う役割を果たす。
(II) Diluent for paint materials:
Next, a diluent for paint materials used in combination with paint materials made of cosmetics (hereinafter, may be simply referred to as “diluent”) will be described. The diluent is suitable for use in combination with the above-mentioned paint material made of the cosmetic according to the present invention, and contains water, lower alcohol, and polyvinyl alcohol having a specific content and a specific range. When the above-mentioned cosmetics and the like are applied as paint materials (base materials for paints), the diluents for paint materials are insufficient as paint materials for cosmetics because they are used in combination with such paints. It plays a role of supplementing the ingredients.
すなわち、粉末状化粧料等の化粧料は、もともと絵の具材料を想定して製造されているわけではないので、一般の絵の具に対して不足する成分があるのは当然である。前記の成分により構成される絵の具材料等をそのまま水に溶いて使用した場合には、水への分散性や、水への濡れ特性等が不足し、また、仮に水に溶けたとしても、紙への付着性、被膜性、速乾性等が不足することが予想される。絵の具材料用希釈剤は、前記の成分を特定量含有することで、かかる不足する特性を補充することができる。 That is, since cosmetics such as powdered cosmetics are not originally manufactured assuming paint materials, it is natural that there are components that are insufficient for general paints. When the paint material composed of the above components is used by dissolving it in water as it is, the dispersibility in water and the wettability in water are insufficient, and even if it is dissolved in water, the paper It is expected that there will be insufficient adhesion to water, film properties, quick-drying properties, etc. Diluents for paint materials can supplement such deficient properties by containing the above-mentioned components in a specific amount.
水は、希釈剤を構成する各成分を分散させる溶媒となり、水道水、精製水、イオン交換水等といった、一般的に使用される水を使用することができる。かかる水の含有量は、例えば、希釈剤中の必須成分及び任意成分を除いた残部(希釈剤において、必須成分及び任意成分以外の部分を指す。)とすればよいが、概ね、希釈剤全体に対して、49.5~89.0質量%とし、60.5~86.0質量%とすることがさらに好ましく、66.5~83.5質量%であることが好ましい。 The water serves as a solvent for dispersing each component constituting the diluent, and commonly used water such as tap water, purified water, ion-exchanged water and the like can be used. The content of such water may be, for example, the balance excluding the essential component and the optional component in the diluent (referring to the portion other than the essential component and the optional component in the diluent), but is generally the entire diluent. On the other hand, it is preferably 49.5 to 89.0% by mass, more preferably 60.5 to 86.0% by mass, and more preferably 66.5 to 83.5% by mass.
低級アルコールは、化粧料と併用された場合に揮発剤的な役割を果たし、揮発性、速乾性を付与することができる。低級アルコールとしては、例えば、メタノール(メチルアルコール)、エタノール(エチルアルコール)、プロパノール(プロピルアルコール)、イソプロピルアルコール、ブタノール、プロパノール等の低級アルコール(炭素数5以下の1価アルコール。)を使用することができ、汎用性、安全性、化粧料との相性等という点で、エタノールを使用することが好ましい。 The lower alcohol plays a role of a volatile agent when used in combination with cosmetics, and can impart volatility and quick-drying property. As the lower alcohol, for example, lower alcohols (monohydric alcohols having 5 or less carbon atoms) such as methanol (methyl alcohol), ethanol (ethyl alcohol), propanol (propyl alcohol), isopropyl alcohol, butanol, and propanol shall be used. It is preferable to use ethanol in terms of versatility, safety, compatibility with cosmetics, and the like.
低級アルコールの含有量は、総量で、希釈剤全体に対して、10.0~35.0質量%とする。低級アルコールの含有量が10.0質量%より少ないと、速乾性が損なわれ、紙への膜形成が遅延し、色むらができる場合がある。一方、含有量が35.0質量%を超えると、速乾性が強すぎ、伸ばし切らないまま膜形成がなされることで、これもまた色むらの原因となる場合がある。さらに、低級アルコールをエタノールとした場合、エタノール過多は顔料凝集の原因となる場合がある。低級アルコールの含有量は、総量で、希釈剤全体に対して、12.5~30.0質量%とすることがさらに好ましく、15.0~30.0質量%とすることが好ましい。 The total content of the lower alcohol is 10.0 to 35.0% by mass with respect to the total amount of the diluent. If the content of the lower alcohol is less than 10.0% by mass, the quick-drying property is impaired, the film formation on the paper is delayed, and color unevenness may occur. On the other hand, if the content exceeds 35.0% by mass, the quick-drying property is too strong, and the film is formed without being fully stretched, which may also cause color unevenness. Furthermore, when the lower alcohol is ethanol, excess ethanol may cause pigment aggregation. The total content of the lower alcohol is preferably 12.5 to 30.0% by mass, more preferably 15.0 to 30.0% by mass, based on the total amount of the diluent.
ポリビニルアルコールは、化粧料と併用された場合の膜形成に役立ち(膜成分となる。)、形成される膜に対して、画用紙に対する乗り(のり)のよさ、膜に滑らかさ等を付与することができる。 Polyvinyl alcohol is useful for film formation when used in combination with cosmetics (it becomes a film component), and imparts good riding (glue) to drawing paper, smoothness, etc. to the formed film. Can be done.
ポリビニルアルコールの含有量は、希釈剤全体に対して、0.5~15.0質量%とする。ポリビニルアルコールの含有量が0.5質量%より少ないと、形成される膜が薄くなり、膜の滑らかさや膜の均一性が失われる。一方、含有量が15.0質量%を超えると、膜が厚くなり、均一膜を損ない、摩擦による仕上がり膜の欠損を生じる場合がある。すなわち、含有量が少ないと、画用紙上にできる形成膜が薄くなることで粉体の凹凸が目立ち膜の均一性が失われる場合があり、また、ポリビニルアルコールは顔料分散作用があるので、少ないと絵の具自体や描写時の画用紙上での顔料分散性が落ち、色むらが生じる場合がある。一方、含有量が多いと、画用紙上にできる形成膜が厚くなりすぎることで膜の均一性が失われる場合がある。ポリビニルアルコールの含有量は、希釈剤全体に対して、1.0~9.0質量%とすることがさらに好ましく、1.0~3.0質量%とすることが特に好ましい。 The content of polyvinyl alcohol is 0.5 to 15.0% by mass with respect to the total amount of the diluent. When the content of polyvinyl alcohol is less than 0.5% by mass, the formed film becomes thin, and the smoothness of the film and the uniformity of the film are lost. On the other hand, if the content exceeds 15.0% by mass, the film becomes thick, the uniform film is damaged, and the finished film may be damaged due to friction. That is, if the content is low, the forming film formed on the drawing paper becomes thin, and the unevenness of the powder becomes conspicuous, and the uniformity of the film may be lost. Pigment dispersibility on the paint itself or on the drawing paper at the time of drawing may deteriorate, resulting in color unevenness. On the other hand, if the content is high, the film formed on the drawing paper becomes too thick, and the uniformity of the film may be lost. The content of polyvinyl alcohol is more preferably 1.0 to 9.0% by mass, and particularly preferably 1.0 to 3.0% by mass, based on the total amount of the diluent.
絵の具材料用希釈剤には、前記の必須成分のほか、本発明の目的及び効果を妨げない範囲で、例えば、フェノキシエタノール、トリエタノールアミン、多価アルコール、アクリル酸重合体(カルボマー)等の水溶性高分子、水酸化ナトリウム(NaOH)、水酸化カリウム(KOH)(前記したトリエタノールアミン、水酸化ナトリウム、水酸化カリウムはアクリル酸重合体の中和剤となる。)、ノニオン性合成樹脂、ノニオン性合成高分子、アクリル酸系水溶性高分子、多糖類、界面活性剤等、水溶性の被膜形成剤やその他の水溶性の材料等の任意成分を適宜添加することができる。 In addition to the above-mentioned essential components, the diluent for paint materials is water-soluble, for example, phenoxyethanol, triethanolamine, polyhydric alcohol, acrylic acid polymer (carbomer), etc., as long as it does not interfere with the object and effect of the present invention. Polymer, sodium hydroxide (NaOH), potassium hydroxide (KOH) (the above-mentioned triethanolamine, sodium hydroxide, potassium hydroxide serve as a neutralizing agent for the acrylic acid polymer), nonionic synthetic resin, nonion. Arbitrary components such as a water-soluble film-forming agent and other water-soluble materials such as a sex-synthesized polymer, an acrylic acid-based water-soluble polymer, a polysaccharide, and a surfactant can be appropriately added.
ここで、化粧料からなる絵の具材料に対して、分散性と濡れ(ぬれ)等を補うために界面活性剤を用いることで解決することが好ましいが、絵の具材料の対象と考えている粉末状化粧料等の化粧料には、界面活性剤が配合されている場合も多いため、絵の具として用いたときの環境に対する影響や人の肌へ付着したときの安全性を考えた場合を考慮し、希釈剤としては任意成分として挙げている。前記の任意成分は、添加する場合は、例えば、希釈剤全体に対して、例えば1.0質量%以下程度を含有するようにしてもよいが、これには限定されない。 Here, it is preferable to solve the problem by using a surfactant to supplement the dispersibility and wetness (wetting) of the paint material made of cosmetics, but powdered makeup which is considered to be the target of the paint material. Since cosmetics such as cosmetics often contain a surfactant, they are diluted in consideration of the environmental impact when used as a paint and the safety when they adhere to human skin. As an agent, it is listed as an optional ingredient. When added, the optional component may be contained, for example, in an amount of, for example, about 1.0% by mass or less with respect to the entire diluent, but the present invention is not limited thereto.
絵の具材料用希釈剤は、前記の必須成分及び任意成分(必須成分等)を混合、攪拌することにより調製することができる。一例としては、溶媒となる水に対して各成分を添加し、混合、攪拌して必須成分等を水の中に分散させるようにすればよい。 The diluent for paint materials can be prepared by mixing and stirring the above-mentioned essential components and optional components (essential components and the like). As an example, each component may be added to water as a solvent, mixed and stirred to disperse the essential components and the like in the water.
以上説明した本発明に係る絵の具材料用希釈剤は、化粧料からなる絵の具材料と併用することにより、絵の具材料用化粧料に対して絵の具材料として不足している成分を補う役割を果たすことができる。 The diluent for paint materials according to the present invention described above can play a role of supplementing the components lacking as paint materials in the paint materials for paint materials when used in combination with the paint materials made of cosmetics. ..
(III)絵の具及び絵の具セット:
本発明に係る絵の具は、(I)で説明した化粧料からなる絵の具材料及び(II)で説明した絵の具材料用希釈剤を混合した混合体を含み、同様に、本発明に係る絵の具セットは、(I)で説明した化粧料からなる絵の具材料及び(II)で説明した絵の具材料用希釈剤を含むものである。絵の具セットとしては、化粧料からなる絵の具材料及び希釈剤は、それぞれ1種をその構成としてもよく、また、それぞれ2種以上をその構成としてもよい。
(III) Paints and paint sets:
The paint according to the present invention comprises a mixture of a paint material consisting of the cosmetics described in (I) and a diluent for the paint material described in (II), and similarly, the paint set according to the present invention is: It contains a paint material consisting of the cosmetics described in (I) and a diluent for the paint material described in (II). As the paint set, the paint material and the diluent made of cosmetics may each have one kind of composition, or two or more kinds of each may have its composition.
化粧料からなる絵の具材料は、絵の具材料用希釈剤により希釈されて混合体とされることにより、一般に市販される一般の水彩絵の具と同様な状態(一般の絵の具様)とされる(これが本発明の絵の具となる。)。絵の具材料と希釈剤の配合割合としては、特に制限はなく、化粧料の種類、希釈剤を構成する成分の配合比、使用者が最終的に求める色彩等により適宜決定することができるが、概ね、質量比として、化粧料1に対して希釈剤を0.5~2として混合することが好ましく、0.7~1.5として混合することが特に好ましいが、特にこの範囲は限定されない。 The paint material composed of cosmetics is diluted with a diluent for the paint material to form a mixture, so that the paint material is in the same state as general watercolor paints on the market (this is the present invention). It will be the paint of.). The mixing ratio of the paint material and the diluent is not particularly limited, and can be appropriately determined depending on the type of cosmetic, the mixing ratio of the components constituting the diluent, the color finally desired by the user, and the like. As a mass ratio, it is preferable to mix the diluent as 0.5 to 2 with respect to the cosmetic 1, and it is particularly preferable to mix the diluent as 0.7 to 1.5, but this range is not particularly limited.
希釈剤により希釈化された絵の具材料(混合体である絵の具)は、例えば、市販される一般の水彩絵の具と同様、パレット上等で水に溶かれて使用される。使用される水の量については、概ね、質量比として、希釈化された絵の具材料(化粧料と希釈剤の混合体からなる、絵の具化された化粧料のこと。)を1に対して、水を0.5~3として混合して溶くようにして使用すればよいが、かかる混合比には限定されず、使用者の好み等により適宜決定すればよい。 The paint material diluted with the diluent (paint which is a mixture) is used by being dissolved in water on a palette or the like, for example, like a general watercolor paint on the market. As for the amount of water used, as a mass ratio, 1 is a diluted paint material (a paint-ized cosmetic made of a mixture of a cosmetic and a diluent), and water is used. However, the mixing ratio is not limited to 0.5 to 3, and the mixture may be appropriately determined according to the preference of the user and the like.
以上説明した本発明に係る絵の具、及び絵の具セットは、本発明に係る化粧料からなる絵の具材料及び本発明に係る絵の具材料用希釈剤よりなり、一般の絵の具と同様に使用することができる絵の具、及び絵の具材料を専用の希釈剤とセットとした絵の具セットとして提供することができる。 The paint according to the present invention and the paint set described above are made of a paint material made of the cosmetic according to the present invention and a diluent for the paint material according to the present invention, and can be used in the same manner as general paints. And can be provided as a paint set in which the paint material is set with a special diluent.
(V)実施形態の変形:
なお、以上説明した態様は、本発明の一態様を示したものであって、本発明は、前記した実施形態に限定されるものではなく、本発明の構成を備え、目的及び効果を達成できる範囲内での変形や改良が、本発明の内容に含まれるものであることはいうまでもない。また、本発明を実施する際における具体的な構造及び形状等は、本発明の目的及び効果を達成できる範囲内において、他の構造や形状等としても問題はない。本発明は前記した各実施形態に限定されるものではなく、本発明の目的を達成できる範囲での変形や改良は、本発明に含まれるものである。
(V) Modification of embodiment:
It should be noted that the embodiments described above show one aspect of the present invention, and the present invention is not limited to the above-described embodiment, but includes the configuration of the present invention and can achieve the object and the effect. Needless to say, modifications and improvements within the scope are included in the content of the present invention. Further, the specific structure, shape, etc. in carrying out the present invention may be any other structure, shape, etc. within the range in which the object and effect of the present invention can be achieved. The present invention is not limited to the above-described embodiments, and modifications and improvements to the extent that the object of the present invention can be achieved are included in the present invention.
例えば、前記した実施形態では、絵の具材料となり得る化粧料の種類として一定のものを例として挙げているが、絵の具材料となり得る化粧料についてはこれには限定されず、例として挙げた以外の粉末状化粧料等の化粧料を適用することを制限するものではない。同様に、前記した実施形態では、各成分の具体例を挙げているが、これらはあくまでも一例であり、挙げられていない成分が化粧料からなる絵の具材料に配合されていても問題はない。
その他、本発明の実施の際の具体的な構造及び形状等は、本発明の目的を達成できる範囲で他の構造等としてもよい。
For example, in the above-described embodiment, certain types of cosmetics that can be used as paint materials are given as an example, but the cosmetics that can be used as paint materials are not limited to this, and powders other than those mentioned as examples are given. It does not limit the application of cosmetics such as cosmetics. Similarly, in the above-described embodiment, specific examples of each component are given, but these are merely examples, and there is no problem even if the components not listed are blended in the paint material made of cosmetics.
In addition, the specific structure, shape, etc. at the time of carrying out the present invention may be other structures, etc. as long as the object of the present invention can be achieved.
以下、本発明を試験例等に基づいてさらに詳細に説明するが、本発明はこれらに限定されるものではない。 Hereinafter, the present invention will be described in more detail based on test examples and the like, but the present invention is not limited thereto.
表1~表9に示した組成からなる市販される化粧料A~化粧料Pの16種類の化粧料を用意した(表1に品名と種類等、表2~表9に組成等全成分情報を示す。)。化粧料A~化粧料Pは、成分として色材を、絵の具材料として使用するに適するだけの発色を備えたものである(後記する試験例2(4)でも評価している。)。 16 kinds of commercially available cosmetics A to P having the compositions shown in Tables 1 to 9 were prepared (Table 1 shows the product name and type, etc., and Tables 2 to 9 show all the ingredient information such as the composition, etc.). Shows.). Cosmetics A to P have a coloring material as an ingredient and have sufficient color development to be suitable for use as a paint material (also evaluated in Test Example 2 (4) described later).
また、化粧料A~化粧料Pは、体質粉体、油性成分等を含み、化粧料A~化粧料G、化粧料M~化粧料Pはアイシャドウ、化粧料Hはチーク、化粧料I~化粧料Kはフェイスパウダー、化粧料Lはファンデーション、にそれぞれ分類される。また、化粧料A、化粧料B、化粧料D、化粧料H~化粧料Pはいわゆる粉末状化粧料として一般に流通、販売されているものである。 Further, cosmetics A to P contain constitutional powder, oily components, etc., cosmetics A to cosmetics G, cosmetics M to cosmetics P are eye shadows, cosmetics H are teak, and cosmetics I to. Cosmetic K is classified into face powder, and cosmetic L is classified into foundation. Further, the cosmetic A, the cosmetic B, the cosmetic D, and the cosmetics H to P are generally distributed and sold as so-called powdered cosmetics.
(品名及び製造販売元)
(組成等全成分情報:化粧料A、化粧料B)
(組成等全成分情報:化粧料C、化粧料D)
(組成等全成分情報:化粧料E、化粧料F)
(組成等全成分情報:化粧料G、化粧料H)
(組成等全成分情報:化粧料I、化粧料J)
(組成等全成分情報:化粧料K、化粧料L)
(組成等全成分情報:化粧料M、化粧料N)
(組成等全成分情報:化粧料O、化粧料P)
ここで、表2等の組成は、化粧料全体に対する成分量が多い順に並べて載せられている。また、表2等の組成において、「+/-」の表示は、メイクアップ用の化粧料等の色違いの多いシリーズ商品で使用される表示であり、その後に表示されている成分(色材等)が、そのシリーズ品に用いられていることを示す。よって、記載された品名の化粧料には必ずしも配合されていない成分が表示されている場合もある(ただし、「+/-」以下に示される少なくとも1種の色材は使用されている。)。 Here, the compositions shown in Table 2 and the like are listed in descending order of the amount of ingredients with respect to the total cosmetics. Further, in the composition of Table 2 and the like, the indication of "+/-" is an indication used in series products having many different colors such as cosmetics for make-up, and the components (coloring materials) displayed after that. Etc.) indicates that it is used in the series products. Therefore, there are cases where ingredients that are not necessarily blended are displayed in the cosmetics with the listed product names (however, at least one kind of coloring material shown below "+/-" is used). ..
そして、かかる16種類の化粧料について、下記の[試験例1]で選定した絵の具材料用希釈剤を用いて、[試験例2]に載せた方法により、絵の具材料としての諸特性を比較・評価した。 Then, with respect to these 16 types of cosmetics, various properties as paint materials are compared and evaluated by the method described in [Test Example 2] using the diluent for paint materials selected in [Test Example 1] below. did.
[試験例1]
絵の具材料用希釈剤の評価:
下記の方法で得られた絵の具材料用希釈剤(希釈剤)について、化粧料Aを対照として用いて、絵の具材料用希釈剤としての適性を評価した。
[Test Example 1]
Evaluation of Diluents for Paint Materials:
With respect to the diluent (diluent) for paint materials obtained by the following method, the suitability as a diluent for paint materials was evaluated using Cosmetic A as a control.
(絵の具材料用希釈剤の製造)
絵の具材料用希釈剤の成分として、水、低級アルコールであるエタノール、ポリビニルアルコール及びフェノキシエタノールをそれぞれ表10に示した含有量(希釈剤全体に対する質量%)として、溶媒となる水に他の成分を添加し、混合、攪拌して水の中に分散させて、希釈剤1~希釈剤3を製造した。
(Manufacturing of diluent for paint materials)
Water, ethanol as a lower alcohol, polyvinyl alcohol and phenoxyethanol are added as the components of the diluent for the paint material as the contents shown in Table 10 (% by mass with respect to the total amount of the diluent), and other components are added to the solvent water. Then, the mixture was mixed and stirred and dispersed in water to produce
(希釈剤の組成)
このようにして得られた希釈剤1~希釈剤3について、表1及び表2に載せた化粧料Aを用いて、下記の方法で絵の具化(市販される一般の水彩絵の具と同様の状態(一般の絵の具様)とすること。)した上で、評価サンプルを作製するとともに、下記の方法で絵の具材料用希釈剤としての適性を評価した。
The
(絵の具化及び評価サンプルの作製)
化粧料3gと希釈剤3gを5分間ヘラで混練して混合体として、化粧料を絵の具化した。そして、絵の具化された化粧料0.2gと水(水道水)0.2gをパレット上で溶いて、評価サンプルとした。
(Painting and preparation of evaluation samples)
3 g of the cosmetic and 3 g of the diluent were kneaded with a spatula for 5 minutes to form a mixture, and the cosmetic was made into a paint. Then, 0.2 g of the paint-made cosmetic and 0.2 g of water (tap water) were dissolved on a palette to prepare an evaluation sample.
(評価方法)
かかる評価サンプルについて、下記(1)~(14)の14つの評価項目のうち、(1)(紙への)伸び広がり、(2)(紙への)乗りの良さ、(3)速乾性、(5)透明感、(8)(紙上でできた)膜の滑らかさ、の5項目を用いて、12人のパネラーにより図1に示した基準(市販される一般の水彩絵の具を3点(普通)とした時の5、4、3,2及び1点の5段階の基準であり、5点が一番良く、1点が一番悪い。)で評価してもらい、かかる12人のパネラーの平均点(平均値)を算出した。図1は、試験例1及び試験例2で用いた評価基準を示した図であり、後記する試験例2でもこの基準を用いている。
(Evaluation methods)
Of the 14 evaluation items (1) to (14) below, (1) spreading and spreading (on paper), (2) good riding (on paper), (3) quick-drying, etc. Using the five items of (5) transparency and (8) smoothness of the film (made on paper), the criteria shown in FIG. 1 by 12 panelists (3 points of general watercolor paints on the market (commercially available watercolor paints) It is a standard of 5 grades of 5, 4, 3, 2 and 1 point when it is normal), and 5 points are the best and 1 point is the worst.) The average score (average value) of was calculated. FIG. 1 is a diagram showing the evaluation criteria used in Test Example 1 and Test Example 2, and this criterion is also used in Test Example 2 described later.
そして、算出された平均点について下記の評価基準を用いて比較・評価した。結果を表11に示す(表11及び後記する表12には、結果の平均点及び下記の「◎」、「〇」、「△」、及び「×」の評価を載せている。)。なお、図1や下記の内容には、塗沫対象である「画用紙」については、単に「紙」と記載するところもある。また、表11及び後記する表12の平均値は、小数点第3位を四捨五入したところもある。 Then, the calculated average score was compared and evaluated using the following evaluation criteria. The results are shown in Table 11 (Table 11 and Table 12 below show the average score of the results and the evaluations of "◎", "○", "Δ", and "×" below). In addition, in FIG. 1 and the following contents, the "drawing paper" to be smeared may be simply described as "paper". In addition, the average values in Table 11 and Table 12 to be described later are rounded off to the third decimal place.
(評価基準)
評 価 内 容
◎ : 平均点が3.5点以上
〇 : 平均点が2.5点以上3.5点未満
△ : 平均点が1.5点以上2.5点未満
× : 平均点が1.5点未満
(Evaluation criteria)
Rating contents ◎: Average score is 3.5 points or more 〇: Average score is 2.5 points or more and less than 3.5 points △: Average score is 1.5 points or more and less than 2.5 points ×: Average score is 1 . Less than 5 points
(評価項目)
(1)(紙への)伸び広がり:
筆で画用紙に塗った時の紙への伸び広がりやすさを確認した。
(Evaluation item)
(1) Spread (on paper):
We confirmed how easy it is to spread on the paper when it is applied to the drawing paper with a brush.
(2)(紙への)乗りの良さ:
かすれたりせず、一般の絵の具と同じように紙に塗抹できるかどうかを確認した。
(2) Good ride (on paper):
I checked whether it could be smeared on paper in the same way as ordinary paints without fading.
(3)速乾性:
乾く速さを確認した。
(3) Quick-drying:
I confirmed how fast it dries.
(4)発色:
色の出やすさを確認した。
(4) Color development:
I confirmed the ease of color appearance.
(5)透明感:
画用紙が透けて見える度合いを確認した。
(5) Transparency:
We confirmed the degree to which the drawing paper can be seen through.
(6)(紙への)重ね塗り:
塗抹直後に再度上から塗抹し、最初に塗ったものがよれたり二度目の塗抹に持っていかれたりしないか確認した。
(6) Overcoating (on paper):
Immediately after smearing, it was smeared again from above, and it was confirmed that the first smear was not twisted or taken to the second smear.
(7)乾燥後の剥離性:
パレットに絵の具を出して数日固めた後にパレットから落ちたり剥がれたりするかどうかを確認した。
(7) Detachability after drying:
After putting the paint on the palette and letting it harden for a few days, I checked if it fell off or peeled off the palette.
(8)(紙上でできた)膜の滑らかさ:
画用紙に塗抹して乾いた軌跡を手でなぞり、ざらざらしたり、凹凸があったりしないかを確認した。
(8) Smoothness of film (made of paper):
I smeared it on drawing paper and traced the dry trajectory by hand to check if it was rough or uneven.
(9)二次付着性:
画用紙へ塗抹して乾いた軌跡を手でなぞり、手に付着しないかどうかを確認した。
(9) Secondary adhesion:
I smeared it on drawing paper and traced the dry trajectory with my hand to check if it adhered to my hand.
(10)(紙上でできた)膜の定着性:
塗抹し乾燥後、手でなぞった時に膜がよれたりしないかどうかを確認した。
(10) Film fixability (made of paper):
After smearing and drying, it was confirmed whether the film was twisted when traced by hand.
(11)香り:
一般の絵の具の独特な香りに対して、よい香りがするかどうかを確認した。
(11) Fragrance:
It was confirmed whether or not it had a good scent against the unique scent of general paints.
(12)調色:
パレット上で他の化粧料絵の具を混ぜた時に予想どおりの色となるかどうかを確認した(例えば、赤と青を混ぜた時に紫となる予想で、そのとおりになるか。)。
(12) Toning:
I checked if the color was as expected when I mixed other cosmetic paints on the palette (for example, if I expected it to be purple when red and blue were mixed, would it be so?).
(13)水への溶解性:
パレット上で水と混ぜる時に混ざりやすいかどうかを確認した。
(13) Solubility in water:
It was confirmed whether it was easy to mix when mixing with water on the pallet.
(14)固形化後の水での溶解性:
(7)と同じように絵の具をパレット上に載せ、乾燥させ固形化させた後に、水で再溶解できるかどうかを確認した。
(14) Solubility in water after solidification:
As in (7), the paint was placed on a palette, dried and solidified, and then it was confirmed whether it could be redissolved with water.
(結果)
表11に示すように、揮発剤となると考えられる低級アルコール(エタノール)の含有量及び膜成分となると考えられるポリビニルアルコール(PVA)の含有量に応じて、(2)(紙への)乗りの良さ、(3)速乾性、(8)膜の滑らかさの評価点数が高くなる(希釈剤3が一番高い。)という結果であった。また、(5)透明感については、3つの希釈剤いずれも、平均点が5点(満点)という結果であった。
As shown in Table 11, depending on the content of lower alcohol (ethanol) considered to be a volatile agent and the content of polyvinyl alcohol (PVA) considered to be a membrane component, (2) riding (on paper) The results showed that the evaluation scores of goodness, (3) quick-drying property, and (8) film smoothness were high (
なお、その一方で、(1)伸び広がりの評価については、一般の絵の具の標準点数(3点)以上となるものの、エタノール及びポリビニルアルコールの含有量が一番多い希釈剤3の平均点が一番低かった。この点、揮発性と膜形成性を合わせた観点で考えると、希釈剤3を使用した場合にあっては、一般の絵の具程度に程よく伸び広がり、綺麗で均一な膜が素早くできるという利点があるとも考えられる。
On the other hand, regarding (1) the evaluation of elongation and spread, the average score of the
以上の結果を総合して、希釈剤1~希釈剤3は、いずれも、画用紙へ塗抹した際に絵の具の膜が伸び広がりすぎず、一般の絵の具と同等に伸び広がること、一般絵の具よりもかすれたりせずに綺麗にのっていくこと、仕上がった絵の具の膜が均一で凹凸が少ないこと、を相対評価し、一般の絵の具と同等以上の良好な特性を備えていることが確認できた。
Based on the above results, in each of
そして、3つの希釈剤の中では、これらの特性をバランスよく兼ね備えた希釈剤3が一番好ましいと判断し、下記の[試験例2]においては、希釈剤3を希釈剤として用いるようにした。
Then, among the three diluents, it was judged that the
[試験例2]
化粧料の絵の具材料としての評価:
前記の表1~表9に示した化粧料A~化粧料Pについて、希釈剤として試験例1で選定した希釈剤3を用いて、絵の具材料の諸特性を比較・評価した。
[Test Example 2]
Evaluation as a paint material for cosmetics:
With respect to the cosmetics A to P shown in Tables 1 to 9 above, various properties of the paint material were compared and evaluated using the
まず、試験例1と同様、化粧料3gと希釈剤3gを5分間ヘラで混練して混合体として、化粧料を絵の具化するようにした。また、絵の具化された化粧料0.2gと水(水道水)0.2gをパレット上で溶いて評価サンプルとした。 First, as in Test Example 1, 3 g of the cosmetic and 3 g of the diluent were kneaded with a spatula for 5 minutes to form a mixture, and the cosmetic was made into a paint. Further, 0.2 g of paint-based cosmetics and 0.2 g of water (tap water) were dissolved on a palette to prepare an evaluation sample.
前記の操作を行った結果、化粧料C、化粧料E及び化粧料Fについては、希釈剤と分離してしまい、化粧料に希釈剤がなじまず、絵の具化することができなかった(そのため、水に溶いて画用紙に塗布することができなかった。)。また、化粧料Gも、希釈剤との軽度な分離が認められ、水に溶いて画用紙に塗抹させた場合にあっては絵の具として使用することが難しかった。よって、これらの化粧料C、化粧料E、化粧料F及び化粧料Gについては、絵の具材料としては不適合と判断し、以降の評価を行わないようにした。 As a result of performing the above operation, the cosmetic C, the cosmetic E, and the cosmetic F were separated from the diluent, and the diluent did not fit into the cosmetic and could not be made into a paint (hence,). It dissolved in water and could not be applied to drawing paper.) In addition, the cosmetic G was also found to be slightly separated from the diluent, and it was difficult to use it as a paint when it was dissolved in water and smeared on drawing paper. Therefore, these cosmetics C, cosmetics E, cosmetics F, and cosmetics G were judged to be unsuitable as paint materials, and subsequent evaluations were not performed.
なお、絵の具化の可否に関しては、表2~表9に示した化粧料の全成分情報より、上から5番目までに、油性成分を4種以上含む場合には、油性成分により体質粉体等の粉体の表面積全体が被覆されるほどの多くの油性成分を含有していると考えられ、絵の具化が困難となると考えられる。また、絵の具化が困難であった化粧料は、全てクリーム状の剤型となっており、指で触れたときにスラリー状であると認識できるくらい柔らかいものであった。 Regarding the possibility of making paints, from the information on all the ingredients of the cosmetics shown in Tables 2 to 9, if 4 or more oily ingredients are contained from the top to the 5th, the constitutional powder etc. may be determined by the oily ingredients. It is considered that the powder contains so many oily components that the entire surface area of the powder is covered, which makes it difficult to make a paint. In addition, all the cosmetics that were difficult to paint were in a creamy dosage form, and were soft enough to be recognized as a slurry when touched with a finger.
これに対して、含有される成分を含有量が多い順に並べた場合に、上から5番目までに、油性成分が3種以下であり、かつ、上から3番目までに体質粉体を1種以上含む化粧料である化粧料A、化粧料B、化粧料D、化粧料H~化粧料Pについては、絵の具化等について問題がなかった。以上より、化粧料A、化粧料B、化粧料D、化粧料H~化粧料Pの評価サンプルについて下記(1)~(14)の14評価項目(評価項目の内容は前記参照。)を、図1に示した基準(一般の絵の具を3点とした場合)で評価した。結果を表12に示す(化粧料Aについては、希釈剤1及び希釈剤2を使用した場合の結果も参考として載せた。)。
On the other hand, when the contained components are arranged in descending order of content, the oily component is 3 or less from the top, and the constitutional powder is 1 from the top. Regarding the cosmetics A, B, D, H to P, which are the cosmetics including the above, there was no problem in making them into paints. Based on the above, the 14 evaluation items (see above for the contents of the evaluation items) of the following (1) to (14) for the evaluation samples of cosmetic A, cosmetic B, cosmetic D, and cosmetic H to cosmetic P. The evaluation was made according to the criteria shown in FIG. 1 (when 3 points were used for general paints). The results are shown in Table 12 (for cosmetic A, the results when Diluent 1 and
(評価項目)
(1)(紙への)伸び広がり
(2)(紙への)乗りの良さ
(3)速乾性
(4)発色
(5)透明感
(6)(紙への)重ね塗り
(7)乾燥後の剥離性
(8)(紙上でできた)膜の滑らかさ
(9)二次付着性
(10)(紙上でできた)膜の定着性
(11)香り
(12)調色
(13)水への溶解性
(14)固形化後の水での溶解性
(Evaluation item)
(1) Spreading (on paper) (2) Good riding (on paper) (3) Quick-drying (4) Color development (5) Transparency (6) Overcoating (on paper) (7) After drying (8) Smoothness of the film (made on paper) (9) Secondary adhesion (10) Fixability of the film (made on paper) (11) Fragrance (12) Toning (13) To water Solubility (14) Solubility in water after solidification
(結果)
表12に示すように、評価した化粧料については、一部の化粧料について(4)発色及び(9)二次付着性について「△」の評価となるものが見られたものの((1)(紙への)伸び広がり、(6)(紙への)重ね塗り、(8)(紙上でできた)膜の滑らかさ、(10)(紙上でできた)膜の定着性が「△」であり、(9)「二次付着性」に「×」があった化粧料Nについては後記する。)、全体的に概ね良好な評価結果であり、これにより、本化粧料絵の具は、一般水彩絵の具と大差のない特性を有していると判断できる。 As shown in Table 12, some of the evaluated cosmetics were evaluated as "△" for (4) color development and (9) secondary adhesion ((1)). Spreading (on paper), (6) recoating (on paper), (8) smoothness of film (made on paper), (10) fixability of film (made on paper) are "△" (9) Cosmetic N with "x" in "secondary adhesiveness" will be described later), and the overall evaluation results are generally good. As a result, this cosmetic paint is generally used. It can be judged that it has characteristics that are not much different from those of watercolor paints.
なお、(1)~(14)の項目は、絵の具としての必須の特性というわけではなく、一般の絵の具に対して相対的に優れる点及び劣る点を確認したに過ぎず、(4)発色や(9)二次付着性等の項目も含め、これらの項目の評価結果が一般の絵の具に対して劣るからといって、絵の具として適用できないというわけではない。 It should be noted that the items (1) to (14) are not essential characteristics as paints, but merely confirm the points that are relatively superior and inferior to general paints, and (4) color development and (9) Just because the evaluation results of these items, including items such as secondary adhesion, are inferior to those of general paints does not mean that they cannot be applied as paints.
ここで、(4)発色において、今回絵の具化して評価した化粧料(化粧料絵の具)は、市販される一般の水彩絵の具(一般の絵の具)と比較して若干劣る結果のものがいくつかあるが、これは、人の肌への塗抹目的で製造された粉末状化粧料自体に配合されている顔料の含有量が一般の絵の具よりも低い場合があるためである。 Here, in (4) color development, some of the cosmetics (cosmetic paints) evaluated as paints this time are slightly inferior to the general watercolor paints (general paints) on the market. This is because the content of the pigment contained in the powdered cosmetic itself produced for the purpose of smearing on human skin may be lower than that of general paints.
しかしながら、(3)速乾性及び(5)透明感について、化粧料絵の具により仕上がった描写跡の膜には化粧料絵の具独特の透明感があり、パネラーのコメントを総合すると一般の絵の具にはない化粧料絵の具独特のタッチ感があって好ましい印象を持っているということであった。以上より、発色において若干の劣りはあるものの、絵の具として捉えられる程度であり、また、発色の代わりに透明感のあるタッチで独自の描写感を演出できると考える。 However, regarding (3) quick-drying and (5) transparency, the film of the depiction trace finished with the cosmetic paint has the transparency peculiar to the cosmetic paint, and when the panelists' comments are put together, the makeup that is not found in general paints. It was said that it had a favorable impression because it had a touch feeling peculiar to paints. From the above, it is considered that although there is some inferiority in color development, it can be regarded as a paint, and it is possible to produce a unique depiction feeling with a transparent touch instead of color development.
また、(9)二次付着性において、一般の絵の具よりも若干劣るものもあった。これは、化粧料に配合されている体質粉体等の粉体が、ほぼ顔料級粒径の粉体で構成された一般の絵の具と比較して比較的大きいことに起因すると考えられる。 In addition, (9) some of them were slightly inferior to general paints in secondary adhesiveness. It is considered that this is because the powder such as the constitutional powder contained in the cosmetic is relatively large as compared with the general paint composed of the powder having a pigment-grade particle size.
これは、画用紙表面の凹凸に染み込むように入り込んでいく一般の絵の具とは異なり、化粧料絵の具の中に含まれる大きな粉体は紙表面の凹凸に入り込むことができず、画用紙の表面に付着し膜成分によって固着している状態であると予想される。これにより、物理的摩擦力で絡めとられやすく、二次付着性が低下すると考えられる。 This is different from general paints that penetrate into the unevenness of the drawing paper surface, and the large powder contained in the cosmetic paint cannot penetrate the unevenness of the paper surface and adheres to the surface of the drawing paper. It is expected to be in a state of being fixed by the membrane component. As a result, it is easy to be entangled by the physical frictional force, and it is considered that the secondary adhesiveness is lowered.
加えて、前記したように(3)速乾性及び(5)透明感において一般の絵の具よりも良好な評価であり、透明感があることで淡いタッチで繊細なデザインを表現することができるというメリットや、アクリル絵の具の様な速乾性があることで描きやすく、乾燥までの時間を待たずして描写を継続できるメリットを有していることも確認できた。 In addition, as mentioned above, it has a better evaluation than general paints in (3) quick-drying and (5) transparency, and the transparency makes it possible to express a delicate design with a light touch. It was also confirmed that it is easy to draw because it dries quickly like acrylic paint, and has the advantage of being able to continue drawing without waiting for the time to dry.
さらには、(11)香り、においても、一般の絵の具よりも概ね良好な評価であった。これは、化粧料には無賦香と賦香の製品があるが、希釈剤そのものに水彩絵の具独特の匂いは無く、更には、賦香された化粧料により形成される化粧料絵の具には、化粧料由来の香りが付与されており、不快感を与えない化粧料ならではの良好な香りがあるというメリットも確認できた。 Furthermore, the (11) scent was also generally better than that of general paints. This is because there are unscented and scented products in cosmetics, but the diluent itself does not have the odor peculiar to watercolor paints, and moreover, the cosmetic paints formed by the scented cosmetics have no scent. It was confirmed that the scent derived from cosmetics was given, and that there was a merit that there was a good scent unique to cosmetics that did not cause discomfort.
なお、パール粉体が全成分のうち1番含有量が多い化粧料Nは、(1)(紙への)伸び広がり、(6)(紙への)重ね塗り、(8)(紙上でできた)膜の滑らかさ、(10)(紙上でできた)膜の定着性、の各項目において比較的点数が低く、(9)二次付着性についても平均点が1点と、点数が低かった。 Cosmetic N, which has the highest content of pearl powder among all the components, can be spread and spread (1) (on paper), (6) overcoated (on paper), and (8) (on paper). The score was relatively low in each of the items of () smoothness of the film and (10) film fixability (made on paper), and (9) the average score of the secondary adhesion was 1 point, which was low. rice field.
この結果は、大粒径のパール粉体が、化粧料を構成する成分のうち1番多く含有されていることに起因する筆先への粉体の引っ掛かりが原因であると考えられる。筆先が紙へ触れた時に筆先の外表面についた大きな粉体が紙へ付着し、伸び広げていく初期段階で大きな粉体が筆毛先間に詰まり、それにからめとられるように小さな粉体も毛先に詰まるようになる。 It is considered that this result is caused by the fact that the pearl powder having a large particle size is contained in the largest amount among the components constituting the cosmetic, and the powder is caught on the brush tip. When the brush tip touches the paper, the large powder attached to the outer surface of the brush tip adheres to the paper, and in the initial stage of spreading and spreading, the large powder gets stuck between the brush tips, and the small powder is also entangled with it. It becomes clogged at the ends of the hair.
その後、液状成分のみが画用紙へ吸われるように伸び広がっていき、筆先の液状成分の流動性も落ちているため、伸び広がりが低下したように感じると考えられる。以上より、画用紙の上へと伸び広げた描写跡には粉体の局在性に偏りがみられ、(6)(紙への)重ね塗りが困難となり、乾燥後の描写跡の膜の凹凸も生じると考える。その結果、(8)(紙上でできた)膜の滑らかさにも影響し、乾燥後の描写跡の局在した紛体のダマにより、(9)二次付着性が低下し、(10)(紙上でできた)膜の定着性も落ちてしまうと考えられる。 After that, only the liquid component spreads and spreads so as to be sucked into the drawing paper, and the fluidity of the liquid component of the brush tip also decreases, so that it is considered that the spread and spread seems to have decreased. From the above, there is a bias in the localization of the powder in the depiction trace that spreads on the drawing paper, making it difficult to recoat (6) (on paper), and the unevenness of the film of the depiction trace after drying. I think that will also occur. As a result, (8) it also affects the smoothness of the film (made on paper), and (9) secondary adhesion is reduced due to the localized powder lumps of the depiction trace after drying, and (10) ( It is thought that the fixability of the film (made of paper) is also reduced.
なお、一般の絵の具は、通常、パレットに絵の具を出した後、乾燥させ、固形化させて使用するものである。このように一般の絵の具と同じような使用方法を化粧料絵の具においても可能かどうかを検証するため、(7)乾燥後の剥離性及び(14)固形化後の水での溶解性の評価を行った。その結果、表12に示すように、一般の絵の具と同等程度であり、パレットからの剥がれ落ちや水への難溶性は確認されず、同等のレベルで使用することが可能であると確認できた。 In addition, general paints are usually used by putting the paints on a palette, drying them, and solidifying them. In order to verify whether it is possible to use cosmetic paints in the same way as general paints, (7) exfoliation after drying and (14) solubility in water after solidification were evaluated. went. As a result, as shown in Table 12, it was confirmed that it was comparable to general paints, and that it could be used at the same level without peeling off from the palette or being sparingly soluble in water. ..
本発明は、廃棄対象となる化粧料を絵の具材料ないしは絵の具として適用する手段として有利に利用することができ、産業上の利用可能性は高い。 INDUSTRIAL APPLICABILITY The present invention can be advantageously used as a paint material or a means for applying a cosmetic to be discarded as a paint material, and has high industrial applicability.
Claims (9)
含有される成分を含有量が多い順に並べた場合に、上から5番目までに、油性成分が3種以下となる化粧料を含むことを特徴とする化粧料からなる絵の具材料。 Contains constitutional powder and coloring material, and
A paint material comprising cosmetics, characterized in that, when the contained components are arranged in descending order of content, the fifth from the top contains cosmetics having three or less oily components.
水:希釈剤全体に対して49.5~89.0質量%、
低級アルコール:希釈剤全体に対して10.0~35.0質量%、
ポリビニルアルコール:希釈剤全体に対して0.5~15.0質量%、
を含有することを特徴とする絵の具材料用希釈剤。 A diluent for diluting paint materials consisting of cosmetics, and the following components;
Water: 49.5-89.0% by weight based on the total diluent,
Lower alcohol: 10.0 to 35.0% by mass based on the total diluent,
Polyvinyl alcohol: 0.5 to 15.0% by mass based on the total diluent,
Diluent for paint materials, characterized by containing.
請求項6または請求項7に記載の絵の具材料用希釈剤と、
を混合した混合体を含むことを特徴とする絵の具。 The paint material comprising the cosmetic according to any one of claims 1 to 5.
The diluent for paint material according to claim 6 or 7.
A paint characterized by containing a mixture of.
請求項6または請求項7に記載の絵の具材料用希釈剤と、
を含むことを特徴とする絵の具セット。 The paint material comprising the cosmetic according to any one of claims 1 to 5.
The diluent for paint material according to claim 6 or 7.
A set of paints characterized by including.
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"IV.処方設計とその評価法", パーソナルケアハンドブック, JPN6021041552, 7 June 2016 (2016-06-07), pages 839 - 855, ISSN: 0005045424 * |
坂口翠: "PLUS COSME PROJECT(プラスコスメプロジェクト)-未使用化粧品や不要になって余った化", 廃棄物資源循環学会誌, vol. 25, no. 3, JPN6021041551, 2014, pages 201 - 206, ISSN: 0005045423 * |
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