JP2022032914A - 低温での改善されたエマルジョンおよび流動特性のための高分子界面活性剤 - Google Patents
低温での改善されたエマルジョンおよび流動特性のための高分子界面活性剤 Download PDFInfo
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M149/00—Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M149/00—Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
- C10M149/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M149/06—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amido or imido group
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M149/00—Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
- C10M149/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M149/10—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrogen-containing hetero ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/041—Mixtures of base-materials and additives the additives being macromolecular compounds only
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/003—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions used as base material
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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Abstract
Description
本出願は、2020年8月12日に出願された米国仮出願第63/064,777号に優先権を主張し、これは、参照によりその全体が本明細書に組み込まれる。
式中、Rは、C1-C8アルキル基を表し、
以下の実施例は、本開示のコポリマー界面活性剤および潤滑組成物の有益な特性を実証している。試験した配合物を以下の表3に示し、流体中で評価した高分子界面活性剤を表4に示す。添加剤パッケージおよび粘度調整剤は、試験したすべての配合で同じである。基油(グループIII)の処理速度は、添加したコポリマーの量に応じて調整した。
Claims (15)
- 低温安定潤滑組成物であって、
潤滑粘度の基油と、
約-30℃までの潤滑剤温度で約75%以下の測定された流動点によって証明されるような流体エマルジョンを維持するのに効果的な非極性部分および極性官能基を有する高分子界面活性剤と、
水および/または燃料汚染物と、を含む、低温安定潤滑組成物。 - 前記高分子界面活性剤が、エチレン性不飽和を有し、重合中の極性基のグラフト化または重合への極性共反応物の組み込みのいずれかによって官能化される反応物から得られるコポリマーであり、かつ/または前記高分子界面活性剤が、アルキル(メタ)アクリレート(複数可)および重合可能なエチレン性不飽和置換基を有する複素環式反応物(複数可)を含む反応物から得られるコポリマーである、請求項1に記載の低温安定潤滑組成物。
- 重合可能なエチレン性不飽和置換基を有する前記複素環式反応物(複数可)が、ビニルラクトン、ビニルラクタム、それらの組み合わせ、およびそれらの誘導体を含み、かつ/または重合可能なエチレン性不飽和置換基を有する前記複素環式反応物(複数可)が、ビニルピロリドン、ビニルピリジン、それらの組み合わせ、およびそれらの誘導体を含む、請求項2に記載の低温安定潤滑組成物。
- 前記アルキル(メタ)アクリレート反応物が、C1~C20の直鎖または分岐アルキル(メタ)アクリレート反応物から選択される反応物を含む、請求項1~3のいずれか1項に記載の低温安定潤滑組成物。
- 前記高分子界面活性剤の重量平均分子量が、約40,000以上であり、かつ/または前記高分子界面活性剤の重量平均分子量が、約800,000以上である、請求項1~4のいずれか1項に記載の低温安定潤滑組成物。
- 前記潤滑組成物が、約0.01~約3重量パーセントの前記高分子界面活性剤、好ましくは約1重量パーセント未満、より好ましくは約0.5重量パーセント未満の前記高分子界面活性剤を含む、請求項1~5のいずれか1項に記載の低温安定潤滑組成物。
- 前記極性官能基が、非極性高分子骨格に懸垂している、請求項1~6のいずれか1項に記載の低温安定潤滑組成物。
- 前記高分子界面活性剤の前記極性官能基が、1つ以上の酸素、窒素、硫黄、またはリン原子を含む、請求項1~7のいずれか1項に記載の低温安定潤滑組成物。
- 前記潤滑組成物が、水および燃料で乳化されて、約-30℃までの温度で流体エマルジョンを生成する、請求項1~8のいずれか1項に記載の低温安定潤滑組成物。
- 前記潤滑組成物が、エンジン油である、請求項1~9のいずれか1項に記載の低温安定潤滑組成物。
- 前記潤滑組成物が、乗用車用モータ油である、請求項1~10のいずれか1項に記載の低温安定潤滑組成物。
- 前記燃料が、ガソリン、アルコールベースの燃料、およびアルコールブレンド燃料からなる群から選択され、かつ/または前記燃料が、エタノールブレンドガソリンであり、かつ/または前記エタノールブレンドガソリンが、E10、E50、E85、およびE100からなる群から選択される、請求項1~11のいずれか1項に記載の低温安定潤滑組成物。
- 低温でエンジンを潤滑する方法であって、請求項1~12のいずれか1項に記載の潤滑組成物を提供することと、約-30℃までの温度で前記潤滑組成物で前記エンジンを潤滑することと、を含む、方法。
- 潤滑組成物、水、および/または燃料の流体粘度を維持するための方法であって、前記潤滑組成物が、水および/または燃料汚染物と混合されているとき、約-30℃までの潤滑剤温度で約75%以下の測定された流動点によって証明されるような非極性部分および流体エマルジョンを維持するのに有効な極性官能基を有する高分子界面活性剤を含む潤滑組成物および添加剤に添加することを含む方法。
- 前記高分子界面活性剤が、請求項2~12のいずれかに記載されている、請求項14に記載の方法。
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US202063064777P | 2020-08-12 | 2020-08-12 | |
US63/064,777 | 2020-08-12 | ||
US17/072,705 US11584898B2 (en) | 2020-08-12 | 2020-10-16 | Polymeric surfactants for improved emulsion and flow properties at low temperatures |
US17/072,705 | 2020-10-16 |
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US (1) | US11584898B2 (ja) |
EP (2) | EP4368689A1 (ja) |
JP (1) | JP2022032914A (ja) |
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-
2020
- 2020-10-16 US US17/072,705 patent/US11584898B2/en active Active
- 2020-11-16 EP EP24163903.8A patent/EP4368689A1/en active Pending
- 2020-11-16 EP EP20207933.1A patent/EP3954753B1/en active Active
- 2020-11-19 CA CA3100028A patent/CA3100028A1/en active Pending
- 2020-11-20 JP JP2020193450A patent/JP2022032914A/ja active Pending
- 2020-11-20 CN CN202011316970.4A patent/CN114075467A/zh active Pending
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US20220049180A1 (en) | 2022-02-17 |
US11584898B2 (en) | 2023-02-21 |
CN114075467A (zh) | 2022-02-22 |
EP4368689A1 (en) | 2024-05-15 |
CA3100028A1 (en) | 2022-02-12 |
EP3954753A1 (en) | 2022-02-16 |
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