JP2021523939A - 改良型濡れ組成物 - Google Patents
改良型濡れ組成物 Download PDFInfo
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- JP2021523939A JP2021523939A JP2021512969A JP2021512969A JP2021523939A JP 2021523939 A JP2021523939 A JP 2021523939A JP 2021512969 A JP2021512969 A JP 2021512969A JP 2021512969 A JP2021512969 A JP 2021512969A JP 2021523939 A JP2021523939 A JP 2021523939A
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- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
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- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
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- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
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Abstract
Description
(a)10〜50wt%未満の1種または複数種のC10−C14アルコールと;
(b)10〜30wt%の1種または複数種のC4−C6酸素含有共溶媒と;
(c)20〜60wt%の、非イオン性、カチオン性、アニオン性および両性界面活性剤から選択される1種または複数種の界面活性剤と;
(d)0〜25wt%の水と;
(e)0〜10wt%の他の添加剤。
本発明の濡れ組成物を液体に添加する工程と;
低エネルギー表面を、濡れ組成物を含む液体と接触させる工程。
ここで、本発明の実施形態を以下の図を参照して説明するが、これらは単に例示であることを意図している。
(a)10〜50wt%未満の1種または複数種のC10−C14アルコールと;
(b)10〜30wt%の1種または複数種のC4−C6酸素含有共溶媒と;
(c)20〜60wt%の、非イオン性、カチオン性、アニオン性および両性界面活性剤から選択される1種または複数種の界面活性剤と;
(d)0〜25wt%の水と;
(e)0〜10wt%の他の添加剤。
(i)Teric BL8(50%)、2−ブトキシエタノール(25%)、ドデカノール(25%);
(ii)Teric BL8(50%)、2−ブトキシエタノール(22.5%)、ドデカノール(27.5%);
(iii)Teric BL8(50%)、2−ブトキシエタノール(20%)、ドデカノール(30%);
(iv)Teric BL8(50%)、2−ブトキシエタノール(17.5%)、ドデカノール(32.5%);
(v)Teric BL8(50%)、2−ブトキシエタノール(15%)、ドデカノール(35%);
(vi)Teric BL8(50%)、2−ブトキシエタノール(25%)、C10−C12アルカノールブレンド(25%)。
本発明の実施形態の濡れ組成物を液体に添加する工程と;
低エネルギー表面と濡れ組成物を含む液体とを接触させる工程。
濡れ組成物を形成するために、所望の量の界面活性剤と所望の量のC4−C6酸素共溶媒とを合わせて初期混合物を形成する。この初期混合物に所望の量のC10−C14アルコールを添加し、得られた組成物を混合する。必要に応じて、所望の量の水および他の添加剤をC10−C14アルコールの後に添加することもできる。
上記の一般的なプロトコルを使用して、表1に詳述されているように、様々な種類および量の成分を含む様々な濡れ組成物を調製した。
1.超純水。
2.Teric BL8(非イオン性)界面活性剤。
3.カチオン性塩化ジメチルベンジルアンモニウム界面活性剤。
4.0.1wt%の濃度で飽和。
5.アニオン性直鎖ドデカルベンジルスルホン酸界面活性剤。
6.Silwet L−77と同一の有機シリコーン系界面活性剤。
7.双性イオン性ラウラミンオキシド界面活性剤。
表1に見られるように、超純水の表面張力は、20℃で約72mN/mであった。本発明の濡れ組成物は、試験した濃度のうちの1つまたは複数で、水の表面張力を24mN/m未満の値に有意に低下させることができた。いくつかの実施例では、表面張力の低下における濡れ組成物の性能は、比較の有機シリコーン界面活性剤の性能に近似しているか、またはそれを超えている。
本発明の濡れ組成物と市販の除草剤濃縮物との相溶性を評価した。
・ GARLONタイプの製品、乳濁液濃縮物を水で希釈し、最終除草剤濃度1.7ml/lのすぐにスプレーできる組成物にした。濡れ組成物をスプレー製剤に添加した。曇っていて安定した乳濁液が形成され、5時間の貯蔵後に非相溶性は観察されなかった。
・ GRAZONタイプの製品、乳濁液濃縮物を水で希釈し、最終除草剤濃度5ml/lのすぐにスプレーできる組成物にした。濡れ組成物をスプレー製剤に添加した。曇っていて安定した乳濁液が形成され、5時間の貯蔵後に非相溶性は観察されなかった。
・ MCPA 750、水溶性濃縮物を水で希釈し、最終除草剤濃度1.4ml/lのすぐにスプレーできる溶液にした。濡れ組成物をスプレー製剤に添加した。透明で安定した溶液が形成され、5時間の貯蔵後に非相溶性は観察されなかった。
・ 2,4−D 625アミン、水溶性濃縮物を水で希釈し、最終除草剤濃度1.4ml/lのすぐにスプレーできる溶液にした。濡れ組成物をスプレー製剤に添加した。透明で安定した溶液が形成され、5時間の貯蔵後に非相溶性は観察されなかった。
・ メトスルフロン、水和剤を水で希釈し、最終除草剤濃度0.5g/lのすぐにスプレーできる溶液にした。濡れ組成物をスプレー製剤に添加した。わずかに曇った組成物が形成された。
本発明の様々な濡れ組成物と市販の除草剤濃縮物との相溶性を評価した。
・ グリホサート360g/l(Roundup(登録商標))
・ MCPA(2−メチル−4−クロロフェノキシ酢酸)広葉除草剤
・ ブトキシエチルエステル100g/lとして存在するGrazon300g/L TRICLOPYR
・ ピクロラム木質雑草除草剤
・ BrushOff(登録商標)(メトスルフロンメチル粉末)、600g/kgの木質雑草除草剤で、水和剤である。
・ 2,4D(2,4−ジクロロフェノキシ酢酸)広葉樹除草剤
本発明の濡れ組成物と、水溶液中に最大65%の固形物を含有するメラミン尿素ホルムアルデヒド樹脂との相溶性は、濡れ組成物を樹脂に添加することによって評価される。
濡れ組成物と、硫酸アンモニウム、ドロマイトおよび石膏分散液、銅塩、(カルシウム)および種々の窒素葉面肥料などの液体葉面肥料との相溶性は、濡れ組成物を肥料に添加することによって試験される。液体肥料製剤は安定である。
濡れ組成物とパーティクルボード床材樹脂との相溶性および製造プロセスを評価し、濡れ組成物の使用によって得られる改良点を判定した。
Claims (21)
- 以下を含む、濡れ組成物:
(a)10〜50wt%未満の1種または複数種のC10−C14アルコールと;
(b)10〜30wt%の1種または複数種のC4−C6酸素含有共溶媒と;
(c)20〜60wt%の、非イオン性、カチオン性、アニオン性および両性界面活性剤から選択される1種または複数種の界面活性剤と;
(d)0〜25wt%の水と;
(e)0〜10wt%の他の添加剤。 - 前記組成物が、最大で35wt%の1種または複数種のC10−C14アルコールを含む、請求項1に記載の濡れ組成物。
- 前記組成物がC12アルコールを含む、請求項1または2に記載の濡れ組成物。
- 前記組成物が、C12アルコールとC14アルコールとの混合物を含む、請求項1〜3のいずれか一項に記載の濡れ組成物。
- 前記混合物中のC12アルコールとC14アルコールとの相対比率が、50:50〜90:10の範囲内である、請求項4に記載の濡れ組成物。
- 前記組成物が、C12アルコールとC10アルコールとの混合物を含む、請求項1〜3のいずれか一項に記載の濡れ組成物。
- 前記組成物が、最大で25wt%の1種または複数種のC4−C6酸素含有共溶媒を含む、請求項1〜6のいずれか一項に記載の濡れ組成物。
- 前記組成物が、C4−C6水溶性アルコール、C4−C6水溶性エステル、C4−C6水溶性エーテル、およびそれらの混合物から選択されるC4−C6酸素含有共溶媒を含む、請求項1〜7のいずれか一項に記載の濡れ組成物。
- 前記C4−C6酸素含有共溶媒が、乳酸エチル、2−ブトキシエタノールおよびジエチレングリコールから選択される、請求項8に記載の濡れ組成物。
- 前記組成物が、アルコールアルコキシレート、アルキルベンゼンスルホン酸塩およびベンジルアルキル第四級アンモニウム界面活性剤、ならびにそれらの混合物から選択される界面活性剤を含む、請求項1〜9のいずれか一項に記載の濡れ組成物。
- 前記組成物がアルコールアルコキシレートおよびアルキルベンゼンスルホン酸塩の界面活性剤混合物を含む、請求項1〜10のいずれか一項に記載の濡れ組成物。
- 前記組成物が最大10wt%の水を含む、請求項1〜11のいずれか一項に記載の濡れ組成物。
- 請求項1〜12のいずれか一項に記載の濡れ組成物と水性液体とを含む、水性液体組成物。
- 前記水性液体が水である、請求項13に記載の水性液体組成物。
- 前記水性液体が水性ベースの樹脂である、請求項13または14に記載の水性液体組成物。
- 前記水性液体が農業用組成物からなるか、または農業用組成物を含む、請求項13または14に記載の水性液体組成物。
- 水性液体の表面張力を低下させる方法であって、請求項1〜12のいずれか一項に記載の濡れ組成物を前記水性液体に添加する工程を含む、方法。
- 低エネルギー表面を比較的高い表面エネルギーの液体で濡らす方法であって、以下の工程を含む、方法:
請求項1〜12のいずれか一項に記載の濡れ組成物を、前記液体に添加する工程と;
前記低エネルギー表面を、前記濡れ組成物を含む前記液体と接触させる工程。 - 請求項13に記載の水性液体組成物でコーティングまたは含浸された低エネルギー表面を有する製品。
- 請求項1〜12のいずれか一項に記載の濡れ組成物を含む樹脂。
- 請求項1〜12のいずれか一項に記載の濡れ組成物を含む農業用組成物。
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AU2018901548A AU2018901548A0 (en) | 2018-05-07 | Improved Wetting Composition | |
AU2018901548 | 2018-05-07 | ||
PCT/AU2018/050749 WO2019213687A1 (en) | 2018-05-07 | 2018-07-17 | Improved wetting composition |
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EP (1) | EP3790652B1 (ja) |
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CA (1) | CA3098460A1 (ja) |
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MX2022005382A (es) * | 2019-11-06 | 2022-05-19 | Advanced Wetting Tech Pty Ltd | Composicion humectante mejorada. |
KR20220094200A (ko) * | 2019-11-06 | 2022-07-05 | 어드밴스드 웨팅 테크놀로지스 피티와이 엘티디 | 신규한 습윤성 조성물 |
WO2024064267A1 (en) * | 2022-09-21 | 2024-03-28 | Championx Llc | Produced water antifoulant compositions and methods |
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US20210362109A1 (en) | 2021-11-25 |
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JP7284806B2 (ja) | 2023-05-31 |
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