JP2021503532A - エアロゲル前駆体およびそれを用いて製造したエアロゲル - Google Patents
エアロゲル前駆体およびそれを用いて製造したエアロゲル Download PDFInfo
- Publication number
- JP2021503532A JP2021503532A JP2020527782A JP2020527782A JP2021503532A JP 2021503532 A JP2021503532 A JP 2021503532A JP 2020527782 A JP2020527782 A JP 2020527782A JP 2020527782 A JP2020527782 A JP 2020527782A JP 2021503532 A JP2021503532 A JP 2021503532A
- Authority
- JP
- Japan
- Prior art keywords
- hydrophobic
- airgel
- airgel precursor
- precursor
- producing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/18—Polysiloxanes containing silicon bound to oxygen-containing groups to alkoxy or aryloxy groups
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
- C01B33/14—Colloidal silica, e.g. dispersions, gels, sols
- C01B33/157—After-treatment of gels
- C01B33/158—Purification; Drying; Dehydrating
- C01B33/1585—Dehydration into aerogels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/0091—Preparation of aerogels, e.g. xerogels
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
- C01B33/14—Colloidal silica, e.g. dispersions, gels, sols
- C01B33/157—After-treatment of gels
- C01B33/158—Purification; Drying; Dehydrating
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
- C01B33/14—Colloidal silica, e.g. dispersions, gels, sols
- C01B33/157—After-treatment of gels
- C01B33/159—Coating or hydrophobisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/32—Polymers modified by chemical after-treatment
- C08G65/329—Polymers modified by chemical after-treatment with organic compounds
- C08G65/333—Polymers modified by chemical after-treatment with organic compounds containing nitrogen
- C08G65/33348—Polymers modified by chemical after-treatment with organic compounds containing nitrogen containing isocyanate group
- C08G65/33351—Polymers modified by chemical after-treatment with organic compounds containing nitrogen containing isocyanate group acyclic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/32—Polymers modified by chemical after-treatment
- C08G65/329—Polymers modified by chemical after-treatment with organic compounds
- C08G65/336—Polymers modified by chemical after-treatment with organic compounds containing silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/46—Block-or graft-polymers containing polysiloxane sequences containing polyether sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0025—Crosslinking or vulcanising agents; including accelerators
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/544—Silicon-containing compounds containing nitrogen
- C08K5/5455—Silicon-containing compounds containing nitrogen containing at least one group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/02—Polysilicates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/90—Other properties not specified above
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Silicon Polymers (AREA)
- Silicon Compounds (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
線状シラン架橋剤を添加して重合させるステップと、を含み、
前記線状シラン架橋剤がPEG由来単位を含むものである、疎水性エアロゲル前駆体の製造方法を提供する。
線状シラン架橋剤を添加して重合させるステップと、を含み、
前記線状シラン架橋剤がPEG由来単位を含むものである、疎水性エアロゲル前駆体の製造方法を提供する。
Si(OC2H5)4+nH2O−>PEDS−Px+溶媒(C2H5OH)
(前記反応式1中、nは、使用される水のモル数であって、n<2である。)
500mLの反応器に、TEOS150g、エタノール51g、および35%のHCl水溶液0.04gを投入してから撹拌し、70℃まで反応温度を上げた。反応温度が70℃に維持されると、35%の塩酸水溶液0.02gを投入した、酸性化された蒸留水19.4gを、1時間かけてゆっくりと滴下した後、8時間反応を実施した。
前記製造例1で製造したプレポリマー溶液を0℃に冷却させた後、製造例2の線状シラン架橋剤3.5g(製造例1で製造したプレポリマーの0.5モル%)をエタノール40gに希釈させ、1時間かけてゆっくりと滴下した後、4時間激しく撹拌して反応させた。反応終結後、反応器の温度を室温まで冷却させ、疎水性エアロゲル前駆体を製造した。
500mLの反応器に、TEOS150g、エタノール51g、製造例2の線状シラン架橋剤3.5g(TEOSの0.5モル%)、および35%のHCl水溶液0.04gを投入してから撹拌し、70℃まで反応温度を上げた。反応温度が70℃に維持されると、35%の塩酸水溶液0.02gを投入した、酸性化された蒸留水19.4gを、1時間かけてゆっくりと滴下した後、8時間反応を実施した。反応終結後、反応器の温度を室温まで冷却した。冷却された反応物をフィルターで減圧濾過して不純物を除去し、疎水性エアロゲル前駆体を製造した。
前記実施例1において、製造例2の線状シラン架橋剤を0.35g(製造例1で製造したプレポリマーの0.05モル%)使用したことを除き、実施例1と同様の方法により疎水性エアロゲル前駆体および疎水性エアロゲルを製造した。
前記実施例1において、製造例2の線状シラン架橋剤を175g(製造例1で製造したプレポリマーの25モル%)使用したことを除き、実施例1と同様の方法により疎水性エアロゲル前駆体および疎水性エアロゲルを製造した。
前記製造例1で製造したプレポリマー溶液を0℃に冷却させた後、クロロトリメチルシラン3.9g(TEOSの5モル%)をエタノール40gに希釈させ、1時間かけてゆっくりと滴下した後、4時間激しく撹拌して反応させた。反応終結後、反応器の温度を室温まで冷却させ、疎水性エアロゲル前駆体を製造した。
前記実施例および比較例で製造したそれぞれのシリカエアロゲルに対して下記物性を測定し、その結果を下記表2に示した。
タップ密度は、タップ密度測定機(TAP−2S、Logan Instruments co.製)を用いて分析した。
比表面積、平均気孔直径、および気孔体積は、MicrometricsのASAP 2010機器を用いて、部分圧(0.11<p/po<1)による、窒素の吸着/脱着量から分析した。
炭素含量は、EltraのCarbon/Sulfur Analyzer(CS−800)を用いて測定した。
UTM(H10K−C、Hounsfield、U.K)を用いて、等しい高さ(12mm)に表面を研磨した円筒状試験片に対して、5mm/minのクロスヘッド速度(down cross head Speed)で一軸加圧(uniaxial pressing)することによる変形程度から評価した。
UTM(H10K−C、Hounsfield、U.K)を用いて、等しい高さ(12mm)に表面を研磨した円筒状試験片に対して、5mm/minのクロスヘッド速度(down cross head Speed)で一軸加圧(uniaxial pressing)することによる変形程度から評価した。
Claims (13)
- アルコキシシラン化合物、または前加水分解されたアルコキシシラン化合物を準備するステップと、
線状シラン架橋剤を添加して重合させるステップと、を含み、
前記線状シラン架橋剤は、PEG(ポリエチレングリコール;polyethylene glycol)由来単位を含むものである、疎水性エアロゲル前駆体の製造方法。 - 前記線状シラン架橋剤は、前記アルコキシシラン化合物、または前加水分解されたアルコキシシラン化合物の総モル数に対して、0.5〜20モル%で添加することを特徴とする、請求項1に記載の疎水性エアロゲル前駆体の製造方法。
- 前記疎水性エアロゲル前駆体の重量平均分子量(Mw)が500〜6,500g/molであることを特徴とする、請求項1に記載の疎水性エアロゲル前駆体の製造方法。
- 前記疎水性エアロゲル前駆体は、PEG由来単位を0.2〜10重量%で含むことを特徴とする、請求項1に記載の疎水性エアロゲル前駆体の製造方法。
- 前記疎水性エアロゲル前駆体は、炭素含量が20重量%以上であることを特徴とする、請求項1に記載の疎水性エアロゲル前駆体の製造方法。
- 前記前加水分解されたアルコキシシラン化合物の水和度が50〜80%であることを特徴とする、請求項1に記載の疎水性エアロゲル前駆体の製造方法。
- アルコキシシラン化合物由来単位と、PEG由来単位と、を含む疎水性エアロゲル前駆体。
- PEG由来単位を0.2〜10重量%で含むことを特徴とする、請求項1に記載の疎水性エアロゲル前駆体。
- 炭素含量が20重量%以上であることを特徴とする、請求項8に記載の疎水性エアロゲル前駆体。
- 請求項1から7に記載の方法により製造された疎水性エアロゲル前駆体を用いて製造する、疎水性シリカエアロゲルの製造方法。
- 表面改質ステップを行わないことを特徴とする、請求項11に記載の疎水性シリカエアロゲルの製造方法。
- 請求項8から10の何れか一項に記載の疎水性エアロゲル前駆体由来単位を含む疎水性シリカエアロゲル。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR10-2017-0167918 | 2017-12-08 | ||
KR1020170167918A KR102176632B1 (ko) | 2017-12-08 | 2017-12-08 | 에어로겔 전구체 및 이를 이용하여 제조한 에어로겔 |
PCT/KR2018/015571 WO2019112393A1 (ko) | 2017-12-08 | 2018-12-07 | 에어로겔 전구체 및 이를 이용하여 제조한 에어로겔 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2021503532A true JP2021503532A (ja) | 2021-02-12 |
JP7127934B2 JP7127934B2 (ja) | 2022-08-30 |
Family
ID=66751617
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2020527782A Active JP7127934B2 (ja) | 2017-12-08 | 2018-12-07 | エアロゲル前駆体およびそれを用いて製造したエアロゲル |
Country Status (6)
Country | Link |
---|---|
US (1) | US11760647B2 (ja) |
EP (1) | EP3722349A4 (ja) |
JP (1) | JP7127934B2 (ja) |
KR (1) | KR102176632B1 (ja) |
CN (1) | CN111372973A (ja) |
WO (1) | WO2019112393A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2024117202A1 (ja) * | 2022-12-02 | 2024-06-06 | 東洋製罐グループホールディングス株式会社 | 多孔質体および多孔質体の製造方法 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102160555B1 (ko) * | 2017-11-13 | 2020-09-28 | 주식회사 엘지화학 | 폐용매 정제방법 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007524739A (ja) * | 2004-01-06 | 2007-08-30 | アスペン エアロゲルズ,インコーポレイティド | ケイ素結合線状ポリマーを含有するオルモシルエーロゲル |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0775669B1 (en) | 1995-11-16 | 2001-05-02 | Texas Instruments Incorporated | Low volatility solvent-based precursors for nanoporous aerogels |
US20050192366A1 (en) | 2004-01-06 | 2005-09-01 | Aspen Aerogels, Inc. | Ormosil aerogels containing silicon bonded polymethacrylate |
KR20070022004A (ko) * | 2004-01-06 | 2007-02-23 | 아스펜 에어로겔, 인코포레이티드 | 규소 결합된 폴리메타크릴레이트를 함유하는 오르모실에어로겔 |
US20100155644A1 (en) | 2005-01-05 | 2010-06-24 | Aspen Aerogels, Inc. | Aerogels containing silicon bonded polymers |
FR2969313B1 (fr) | 2010-12-16 | 2012-12-21 | Essilor Int | Element optique comprenant un aerogel sans fissure |
KR20120070948A (ko) | 2010-12-22 | 2012-07-02 | 주식회사 화인텍 | 단열 성능을 지닌 소수성 실리카 에어로젤 분말의 제조방법 |
US10350576B2 (en) | 2013-10-29 | 2019-07-16 | Wisconsin Alumni Research Foundation | Sustainable aerogels and uses thereof |
CN103951966B (zh) * | 2014-04-23 | 2016-04-20 | 江苏绿源新材料有限公司 | 硬质聚氨酯-气凝胶二氧化硅复合泡沫塑料及制备方法 |
KR101748527B1 (ko) | 2015-04-14 | 2017-06-19 | 주식회사 엘지화학 | 실리카 에어로겔 포함 블랑켓의 제조방법 및 이에 따라 제조된 실리카 에어로겔 포함 블랑켓 |
KR102024140B1 (ko) * | 2016-03-16 | 2019-09-23 | 주식회사 엘지화학 | 에어로겔 전구체 및 이를 이용하여 제조한 에어로겔 |
-
2017
- 2017-12-08 KR KR1020170167918A patent/KR102176632B1/ko active IP Right Grant
-
2018
- 2018-12-07 CN CN201880074908.3A patent/CN111372973A/zh active Pending
- 2018-12-07 JP JP2020527782A patent/JP7127934B2/ja active Active
- 2018-12-07 WO PCT/KR2018/015571 patent/WO2019112393A1/ko unknown
- 2018-12-07 EP EP18885470.7A patent/EP3722349A4/en active Pending
- 2018-12-07 US US16/767,303 patent/US11760647B2/en active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007524739A (ja) * | 2004-01-06 | 2007-08-30 | アスペン エアロゲルズ,インコーポレイティド | ケイ素結合線状ポリマーを含有するオルモシルエーロゲル |
Non-Patent Citations (4)
Title |
---|
D. FISCHER ET AL.: "Monitoring of the Sol-Gel Synthesis of Organic-inorganic Hybrids by FTIR Transmission, FTIR/ATR, NIR", MACROMOL. SYMP., vol. 265, JPN6021024172, 2008, pages 134 - 143, ISSN: 0004537295 * |
XIAOFEI QIAO ET AL.: "Molecular construction and photophysics of luminescent covalently bonded hybrids by grafting the lan", JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A: CHEMISTRY, vol. 199, JPN6021024175, 2008, pages 188 - 196, ISSN: 0004537297 * |
YING LI ET AL.: "Coordination assembly and characterization of europium(III) complexes covalently bonded to SBA-15 di", RSC ADV., vol. 3, JPN6021024174, 2013, pages 14057 - 14065, ISSN: 0004537296 * |
ZHIGANG MA ET AL.: "Preparation and characterization of inorganic-organic hybrid proton exchange membranes based on phos", J SOL-GEL SCI TECHNOL, vol. 48, JPN6021024176, 2008, pages 267 - 271, XP019646215, ISSN: 0004537298, DOI: 10.1007/s10971-008-1813-1 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2024117202A1 (ja) * | 2022-12-02 | 2024-06-06 | 東洋製罐グループホールディングス株式会社 | 多孔質体および多孔質体の製造方法 |
Also Published As
Publication number | Publication date |
---|---|
JP7127934B2 (ja) | 2022-08-30 |
KR20190067984A (ko) | 2019-06-18 |
US20200407231A1 (en) | 2020-12-31 |
EP3722349A1 (en) | 2020-10-14 |
WO2019112393A1 (ko) | 2019-06-13 |
CN111372973A (zh) | 2020-07-03 |
US11760647B2 (en) | 2023-09-19 |
KR102176632B1 (ko) | 2020-11-09 |
EP3722349A4 (en) | 2021-01-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN111501335B (zh) | 气凝胶毡的制备方法和由其制备的气凝胶毡 | |
US20110240907A1 (en) | Hydropohobic aerogels | |
KR100785521B1 (ko) | 표면개질된 에어로겔 제조 방법 및 이로부터 제조된 표면개질된 에어로겔 | |
Kurahashi et al. | Role of block copolymer surfactant on the pore formation in methylsilsesquioxane aerogel systems | |
Weinberger et al. | Sol− Gel Processing of a glycolated cyclic organosilane and its pyrolysis to silicon oxycarbide monoliths with multiscale porosity and large surface areas | |
CN108602681B (zh) | 二氧化硅气凝胶的制备方法以及由其制备的二氧化硅气凝胶 | |
CN112135860B (zh) | 预水解的聚硅酸酯的合成方法 | |
WO2016178560A1 (en) | Hydrophobic silica aerogel and method for the preparation thereof | |
CA2747385A1 (en) | Telechelic hybrid aerogels | |
EP3312185B1 (en) | Aerogel precursor and aerogel prepared using the same | |
JP2001518835A (ja) | 低密度ゲル構造体の製造方法 | |
JP2021503532A (ja) | エアロゲル前駆体およびそれを用いて製造したエアロゲル | |
JP6955700B2 (ja) | Co2吸着材 | |
US10773964B2 (en) | Aerogel precursor, method for preparing the same, aerogel prepared therewith, and method for preparing aerogel using the same | |
CN107758674B (zh) | 气凝胶颗粒制备方法 | |
KR101227065B1 (ko) | 에어로겔과 그의 제조 방법 | |
Meti et al. | Sorbitol cross-linked silica aerogels with improved textural and mechanical properties | |
CN108463486B (zh) | 预水解的聚硅酸烷基酯的合成方法 | |
Shajesh et al. | Synthesis, structure and properties of cross-linked R (SiO1. 5)/SiO2 (R= 3-glycidoxypropyl) porous organic inorganic hybrid networks dried at ambient pressure | |
JP5141948B2 (ja) | バイモダルな細孔構造を有する球状シリカ系メソ多孔体及びその製造方法 | |
JP2003267719A (ja) | 多孔体、多孔体膜を有する基体およびこれらの製造方法 | |
JP4128363B2 (ja) | 多孔質ゲルの製造方法 | |
Pirzada et al. | Potential of PVA templated Silica Xerogels as Adsorbents for Rhodamine 6G | |
KR20220165663A (ko) | 실리카 에어로겔 및 실리카 에어로겔 블랭킷의 제조 방법 | |
JPWO2020084670A1 (ja) | エアロゲル粒子、分散体及び塗膜 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20200518 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20200518 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20210628 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20210922 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20220221 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20220523 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20220719 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20220812 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 7127934 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |