JP2021155749A - Coloring composition and compound - Google Patents

Abstract

To solve the problem in which a color filter formed from a colored curable resin composition containing C.I. Pigment Yellow 185 has a large phase difference value.SOLUTION: The coloring composition comprises a compound represented by formula (IZ6-B), and an alkali-soluble resin.SELECTED DRAWING: None

Description

The present invention relates to coloring compositions and compounds.

The color curable composition is used in the manufacture of color filters used in display devices such as liquid crystal displays and electroluminescence display devices. Examples of the colorant contained in such a color curable composition include C.I. I. Pigment Yellow 185 is known (Patent Document 1).

Japanese Unexamined Patent Publication No. 2016-66020

Conventionally known C.I. I. In the color filter formed from the color curable resin composition containing Pigment Yellow 185, there is a problem that the phase difference value is large.

［式（ＩＺ１）中、
Ｒ^O1Z1は、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^1Z1、Ｒ^2Z1、Ｒ^3Z1、Ｒ^4Z1、Ｒ^5Z1、Ｒ^6Z1、及びＲ^7Z1は、互いに独立に、水素原子、−ＣＯ−Ｒ^102Z1、−ＣＯＯ−Ｒ^101Z1、−ＯＣＯ−Ｒ^102Z1、−ＣＯＣＯ−Ｒ^102Z1、−Ｏ−Ｒ^102Z1、−ＳＯ₂−Ｒ^101Z1、−ＳＯ₂Ｎ（Ｒ^102Z1）₂、−ＣＯＮ（Ｒ^102Z1）₂、−Ｎ（Ｒ^102Z1）₂、−ＮＨＣＯ−Ｒ^102Z1、−ＮＨＣＯ−Ｎ（Ｒ^102Z1）₂、−ＮＨＣＯＯＲ^102Z1、−ＯＣＯＮ（Ｒ^102Z1）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^2Z1とＲ^3Z1、Ｒ^3Z1とＲ^4Z1、及びＲ^4Z1とＲ^5Z1は、それぞれ互いに結合して環を形成してもよい。
Ｒ^101Z1は、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102Z1は、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、水素原子又はアルカリ金属原子を表す。
Ｒ^101Z1、Ｒ^102Z1及びＭが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
波線は、Ｅ体又はＺ体を表す。］

［式（ＩＺ２）中、
Ｒ^CO1Z2及びＲ^CO2Z2は、互いに独立に、−Ｏ−Ｒ^O1Z2又は−ＮＲ^N1Z2Ｒ^N2Z2を表す。
Ｒ^N1Z2、Ｒ^N2Z2、Ｒ^1Z2、Ｒ^2Z2、Ｒ^3Z2、Ｒ^4Z2、及びＲ^5Z2は、互いに独立に、水素原子、−ＣＯ−Ｒ^102Z2、−ＣＯＯ−Ｒ^101Z2、−ＯＣＯ−Ｒ^102Z2、−ＣＯＣＯ−Ｒ^102Z2、−Ｏ−Ｒ^102Z2、−ＳＯ₂−Ｒ^101Z2、−ＳＯ₂Ｎ（Ｒ^102Z2）₂、−ＣＯＮ（Ｒ^102Z2）₂、−Ｎ（Ｒ^102Z2）₂、−ＮＨＣＯ−Ｒ^102Z2、−ＮＨＣＯ−Ｎ（Ｒ^102Z2）₂、−ＮＨＣＯＯＲ^102Z2、−ＯＣＯＮ（Ｒ^102Z2）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^2Z2とＲ^3Z2、Ｒ^3Z2とＲ^4Z2、及びＲ^4Z2とＲ^5Z2は、それぞれ互いに結合して環を形成してもよい。
Ｒ^101Z2は、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^O1Z2及びＲ^102Z2は、互いに独立に、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、水素原子又はアルカリ金属原子を表す。
Ｒ^O1Z2、Ｒ^N1Z2、Ｒ^N2Z2、Ｒ^101Z2、Ｒ^102Z2及びＭが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
波線は、Ｅ体又はＺ体を表す。］

［式（ＩＺ３）中、
Ｒ^1Z3、Ｒ^2Z3、Ｒ^3Z3、Ｒ^4Z3、Ｒ^5Z3、Ｒ^6Z3、及びＲ^7Z3は、互いに独立に、水素原子、−ＣＯ−Ｒ^102Z3、−ＣＯＯ−Ｒ^101Z3、−ＯＣＯ−Ｒ^102Z3、−ＣＯＣＯ−Ｒ^102Z3、−Ｏ−Ｒ^102Z3、−ＳＯ₂−Ｒ^101Z3、−ＳＯ₂Ｎ（Ｒ^102Z3）₂、−ＣＯＮ（Ｒ^102Z3）₂、−Ｎ（Ｒ^102Z3）₂、−ＮＨＣＯ−Ｒ^102Z3、−ＮＨＣＯ−Ｎ（Ｒ^102Z3）₂、−ＮＨＣＯＯＲ^102Z3、−ＯＣＯＮ（Ｒ^102Z3）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^2Z3とＲ^3Z3、Ｒ^3Z3とＲ^4Z3、及びＲ^4Z3とＲ^5Z3は、それぞれ互いに結合して環を形成してもよい。
Ｒ^101Z3は、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102Z3は、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、水素原子又はアルカリ金属原子を表す。
Ｒ^101Z3、Ｒ^102Z3及びＭが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
波線は、Ｅ体又はＺ体を表す。］

［式（ＩＺ４）中、
Ｒ^N1Z4及びＲ^N2Z4は、互いに独立に、−ＣＯ−Ｒ^102Z4、−ＣＯＯ−Ｒ^101Z4、−ＯＣＯ−Ｒ^102Z4、−ＣＯＣＯ−Ｒ^102Z4、−Ｏ−Ｒ^102Z4、−ＳＯ₂−Ｒ^101Z4、−ＳＯ₂Ｎ（Ｒ^102Z4）₂、−ＣＯＮ（Ｒ^102Z4）₂、−Ｎ（Ｒ^102Z4）₂、−ＮＨＣＯ−Ｒ^102Z4、−ＮＨＣＯ−Ｎ（Ｒ^102Z4）₂、−ＮＨＣＯＯＲ^102Z4、−ＯＣＯＮ（Ｒ^102Z4）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^1Z4、Ｒ^2Z4、Ｒ^3Z4、Ｒ^4Z4、Ｒ^5Z4、Ｒ^6Z4、及びＲ^7Z4は、互いに独立に、水素原子、−ＣＯ−Ｒ^102Z4、−ＣＯＯ−Ｒ^101Z4、−ＯＣＯ−Ｒ^102Z4、−ＣＯＣＯ−Ｒ^102Z4、−Ｏ−Ｒ^102Z4、−ＳＯ₂−Ｒ^101Z4、−ＳＯ₂Ｎ（Ｒ^102Z4）₂、−ＣＯＮ（Ｒ^102Z4）₂、−Ｎ（Ｒ^102Z4）₂、−ＮＨＣＯ−Ｒ^102Z4、−ＮＨＣＯ−Ｎ（Ｒ^102Z4）₂、−ＮＨＣＯＯＲ^102Z4、−ＯＣＯＮ（Ｒ^102Z4）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^2Z4とＲ^3Z4、Ｒ^3Z4とＲ^4Z4、及びＲ^4Z4とＲ^5Z4は、それぞれ互いに結合して環を形成してもよい。
Ｒ^101Z4は、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102Z4は、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、水素原子又はアルカリ金属原子を表す。
Ｒ^101Z4、Ｒ^102Z4及びＭが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
波線は、Ｅ体又はＺ体を表す。］

［式（ＩＺ５）中、
Ｒ^N1Z5は、−ＣＯ−Ｒ^102Z5、−ＣＯＯ−Ｒ^101Z5、−ＯＣＯ−Ｒ^102Z5、−ＣＯＣＯ−Ｒ^102Z5、−Ｏ−Ｒ^102Z5、−ＳＯ₂−Ｒ^101Z5、−ＳＯ₂Ｎ（Ｒ^102Z5）₂、−ＣＯＮ（Ｒ^102Z5）₂、−Ｎ（Ｒ^102Z5）₂、−ＮＨＣＯ−Ｒ^102Z5、−ＮＨＣＯ−Ｎ（Ｒ^102Z5）₂、−ＮＨＣＯＯＲ^102Z5、−ＯＣＯＮ（Ｒ^102Z5）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^1Z5、Ｒ^2Z5、Ｒ^3Z5、Ｒ^4Z5、Ｒ^5Z5、Ｒ^6Z5、及びＲ^7Z5は、互いに独立に、水素原子、−ＣＯ−Ｒ^102Z5、−ＣＯＯ−Ｒ^101Z5、−ＯＣＯ−Ｒ^102Z5、−ＣＯＣＯ−Ｒ^102Z5、−Ｏ−Ｒ^102Z5、−ＳＯ₂−Ｒ^101Z5、−ＳＯ₂Ｎ（Ｒ^102Z5）₂、−ＣＯＮ（Ｒ^102Z5）₂、−Ｎ（Ｒ^102Z5）₂、−ＮＨＣＯ−Ｒ^102Z5、−ＮＨＣＯ−Ｎ（Ｒ^102Z5）₂、−ＮＨＣＯＯＲ^102Z5、−ＯＣＯＮ（Ｒ^102Z5）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表し、Ｒ^2Z5とＲ^3Z5、Ｒ^3Z5とＲ^4Z5、及びＲ^4Z5とＲ^5Z5は、それぞれ互いに結合して環を形成してもよく、Ｒ^2Z5、Ｒ^3Z5、Ｒ^4Z5及びＲ^5Z5の少なくとも一つは、−ＣＯ−Ｒ^102Z5、−ＣＯＯ−Ｒ^101Z5、−ＯＣＯ−Ｒ^102Z5、−ＣＯＣＯ−Ｒ^102Z5、−Ｏ−Ｒ^102Z5、−ＳＯ₂−Ｒ^101Z5、−ＳＯ₂Ｎ（Ｒ^102Z5）₂、−ＣＯＮ（Ｒ^102Z5）₂、−Ｎ（Ｒ^102Z5）₂、−ＮＨＣＯ−Ｒ^102Z5、−ＮＨＣＯ−Ｎ（Ｒ^102Z5）₂、−ＮＨＣＯＯＲ^102Z5、−ＯＣＯＮ（Ｒ^102Z5）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基若しくは置換基を有していてもよい複素環基であるか、又はＲ^2Z5とＲ^3Z5、Ｒ^3Z5とＲ^4Z5、及びＲ^4Z5とＲ^5Z5の少なくとも一組が、結合して環を形成している。
Ｒ^101Z5は、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102Z5は、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置
換基を有していてもよい複素環基を表す。
Ｍは、水素原子又はアルカリ金属原子を表す。
Ｒ^101Z5、Ｒ^102Z5及びＭが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
波線は、Ｅ体又はＺ体を表す。］

［式（ＩＺ６）中、
Ｄは、イソインドリン骨格を有する構造を表す。
Ｚは、−ＳＯ₃ ^-又は−ＣＯ₂ ^-を表す。
Ａ^c+は、ｃ価の金属陽イオンを表す。
ａは、１〜１０の整数を表す。
ｂは、１以上の整数を表す。
ｃは、２〜１０の整数を表す。
ｄは、１以上の整数を表す。
Ｄ、Ｚ、ａ又はＡ^c+が複数存在する場合、それらはそれぞれ同一であってもよく、異なっていてもよい。
式（Ｉ’Ｚ６）及び式（Ｉ’’Ｚ６）は、それぞれ、式（ＩＺ６）の部分構造を表し、Ｄ、Ｚ、Ａ^c+、ａ、ｂ、ｃ及びｄは、式（ＩＺ６）におけるものと同じものを表す。
ただし、式（Ｉ’Ｚ６）で表される部分構造が有する負の価数と、式（Ｉ’’Ｚ６）で表される部分構造が有する正の価数の絶対値は同じである。］
［２］
式（ＩＺ１）で表される化合物、式（ＩＺ２）で表される化合物、又は式（ＩＺ３）で表される化合物と、樹脂とを含む［１］に記載の着色組成物。
［３］
式（ＩＺ４）で表される化合物、式（ＩＺ５）で表される化合物、又は式（ＩＺ６）で表される化合物と、溶剤とを含む［１］に記載の着色組成物。
［４］
式（ＩＺ１）で表される化合物を含み、Ｒ^1Z1、Ｒ^6Z1及びＲ^7Z1が、水素原子である［１］又は［２］に記載の着色組成物。
［５］
式（ＩＺ１）で表される化合物を含み、Ｒ^O1Z1が、水素原子或いは置換基を有していてもよい炭素数１〜１０の炭化水素基である［１］〜［２］又は［４］記載の着色組成物。
［６］
式（ＩＺ１）で表される化合物を含み、Ｒ^2Z1、Ｒ^3Z1、Ｒ^4Z1、及びＲ^5Z1の少なくとも一つが、−ＣＯ−Ｒ^102Z1、−ＣＯＯ−Ｒ^101Z1、−ＯＣＯ−Ｒ^102Z1、−ＣＯＣＯ−Ｒ^102Z1、−Ｏ−Ｒ^102Z1、−ＳＯ₂−Ｒ^101Z1、−ＳＯ₂Ｎ（Ｒ^102Z1）₂、−ＣＯＮ（Ｒ^102Z1）₂、−Ｎ（Ｒ^102Z1）₂、−ＮＨＣＯ−Ｒ^102Z1、−ＮＨＣＯ−Ｎ（Ｒ^102Z1）₂、−ＮＨＣＯＯＲ^102Z1、−ＯＣＯＮ（Ｒ^102Z1）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基であるか、又はＲ^2Z1とＲ^3Z1、Ｒ^3Z1とＲ^4Z1、及びＲ^4Z1とＲ^5Z1の少なくとも一組が結合して環を形成している［１］〜［２］、［４］又は［５］に記載の着色組成物。
［７］
式（ＩＺ１）で表される化合物を含み、Ｒ^2Z1、Ｒ^3Z1、Ｒ^4Z1、及びＲ^5Z1の少なくとも一つが、ニトロ基又はｔｅｒｔ−ブチル基である［１］〜［２］又は［４］〜［６］のいずれかに記載の着色組成物。
［８］
式（ＩＺ２）で表される化合物を含み、Ｒ^O1Z2、Ｒ^N1Z2及びＲ^N2Z2が、互いに独立に、水素原子又は置換基を有していてもよい炭素数１〜１０の炭化水素基である［１］又は［２］に記載の着色組成物。
［９］
式（ＩＺ２）で表される化合物を含み、Ｒ^1Z2が水素原子である［１］〜［２］又は［８］に記載の着色組成物。
［１０］
式（ＩＺ２）で表される化合物を含み、Ｒ^2Z2、Ｒ^3Z2、Ｒ^4Z2、及びＲ^5Z2の少なくとも一つが、−ＣＯ−Ｒ^102Z2、−ＣＯＯ−Ｒ^101Z2、−ＯＣＯ−Ｒ^102Z2、−ＣＯＣＯ−Ｒ^102Z2、−Ｏ−Ｒ^102Z2、−ＳＯ₂−Ｒ^101Z2、−ＳＯ₂Ｎ（Ｒ^102Z2）₂、−ＣＯＮ（Ｒ^102Z2）₂、−Ｎ（Ｒ^102Z2）₂、−ＮＨＣＯ−Ｒ^102Z2、−ＮＨＣＯ−Ｎ（Ｒ^102Z2）₂、−ＮＨＣＯＯＲ^102Z2、−ＯＣＯＮ（Ｒ^102Z2）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基であるか、又はＲ^2Z2とＲ^3Z2、Ｒ^3Z2とＲ^4Z2、及びＲ^4Z2とＲ^5Z2の少なくとも一組が結合して環を形成している［１］〜［２］、［８］又は［９］に記載の着色組成物。
［１１］
式（ＩＺ２）で表される化合物を含み、Ｒ^2Z2、Ｒ^3Z2、Ｒ^4Z2、及びＲ^5Z2の少なくとも一つが、ニトロ基又はｔｅｒｔ−ブチル基である［１］〜［２］又は［８］〜［１０］のいずれかに記載の着色組成物。
［１２］
式（ＩＺ３）で表される化合物を含み、Ｒ^1Z3、Ｒ^6Z3及びＲ^7Z3が、水素原子である［１］又は［２］に記載の着色組成物。
［１３］
式（ＩＺ３）で表される化合物を含み、Ｒ^2Z3、Ｒ^3Z3、Ｒ^4Z3、及びＲ^5Z3の少なくとも一つが、−ＣＯ−Ｒ^102Z3、−ＣＯＯ−Ｒ^101Z3、−ＯＣＯ−Ｒ^102Z3、−ＣＯＣＯ−Ｒ^102Z3、−Ｏ−Ｒ^102Z3、−ＳＯ₂−Ｒ^101Z3、−ＳＯ₂Ｎ（Ｒ^102Z3）₂、−ＣＯＮ（Ｒ^102Z3）₂、−Ｎ（Ｒ^102Z3）₂、−ＮＨＣＯ−Ｒ^102Z3、−ＮＨＣＯ−Ｎ（Ｒ^102Z3）₂、−ＮＨＣＯＯＲ^102Z3、−ＯＣＯＮ（Ｒ^102Z3）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基或いは置換基を有していてもよい複素環基であるか、又はＲ^2Z3とＲ^3Z3、Ｒ^3Z3とＲ^4Z3、及びＲ^4Z3とＲ^5Z3の少なくとも一組が結合して環を形成している［１］〜［２］又は［１２］に記載の着色組成物。
［１４］
式（ＩＺ３）で表される化合物を含み、Ｒ^2Z3、Ｒ^3Z3、Ｒ^4Z3、及びＲ^5Z3の少なくとも一つが、ニトロ基又はｔｅｒｔ−ブチル基である［１］〜［２］、［１２］又は［１３］に記載の着色組成物。
［１５］
樹脂と溶剤の両方を含む［１］〜［１４］のいずれかに記載の着色組成物。
［１６］
さらに、黄色着色剤又は緑色着色剤を含む［１］〜［１５］のいずれかに記載の着色組成物。
［１７］
［１］〜［１６］のいずれか記載の着色組成物、及び重合性化合物を含む着色硬化性組成物。
［１８］
さらに、重合開始剤を含む［１７］に記載の着色硬化性組成物。
［１９］
［１］〜［１６］のいずれかに記載の着色組成物又は［１７］或いは［１８］に記載の着色硬化性組成物から形成されたカラーフィルタ。
［２０］
［１９］に記載のカラーフィルタを含む液晶表示装置。
［２１］
式（ＩＺ１−Ｂ）で表される化合物。

［式（ＩＺ１−Ｂ）中、
Ｒ^O11Z1は、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^1Z1、Ｒ^21Z1、Ｒ^31Z1、Ｒ^41Z1、Ｒ^51Z1、Ｒ^61Z1、及びＲ^71Z1は、互いに独立に、水素原子、−ＣＯ−Ｒ^102Z1、−ＣＯＯ−Ｒ^101Z1、−ＯＣＯ−Ｒ^102Z1、−ＣＯＣＯ−Ｒ^102Z1、−Ｏ−Ｒ^102Z1、−ＳＯ₂−Ｒ^101Z1、−ＳＯ₂Ｎ（Ｒ^102Z1）₂、−ＣＯＮ（Ｒ^102Z1）₂、−Ｎ（Ｒ^102Z1）₂、−ＮＨＣＯ−Ｒ^102Z1、−ＮＨＣＯ−Ｎ（Ｒ^102Z1）₂、−ＮＨＣＯＯＲ^102Z1、−ＯＣＯＮ（Ｒ^102Z1）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^21Z1とＲ^31Z1、Ｒ^31Z1とＲ^41Z1、及びＲ^41Z1とＲ^51Z1は、それぞれ互いに結合して環を形成してもよい。
ただし、Ｒ^21Z1、Ｒ^31Z1、Ｒ^41Z1、及びＲ^51Z1の少なくとも一つは、−ＣＯ−Ｒ^102Z1、−ＣＯＯ−Ｒ^101Z1、−ＯＣＯ−Ｒ^102Z1、−ＣＯＣＯ−Ｒ^102Z1、−Ｏ−Ｒ^102Z1、−ＳＯ₂−Ｒ^101Z1、−ＳＯ₂Ｎ（Ｒ^102Z1）₂、−ＣＯＮ（Ｒ^102Z1）₂、−Ｎ（Ｒ^102Z1）₂、−ＮＨＣＯ−Ｒ^102Z1、−ＮＨＣＯ−Ｎ（Ｒ^102Z1）₂、−ＮＨＣＯＯＲ^102Z1、−ＯＣＯＮ（Ｒ^102Z1）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基であるか、又はＲ^21Z1とＲ^31Z1、Ｒ^31Z1とＲ^41Z1、及びＲ^41Z1とＲ^51Z1の少なくとも一組が結合して環を形成している。
Ｒ^101Z1は、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102Z1は、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、水素原子又はアルカリ金属原子を表す。
Ｒ^101Z1、Ｒ^102Z1及びＭが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
波線は、Ｅ体又はＺ体を表す。］
［２２］
Ｒ^1Z1、Ｒ^61Z1及びＲ^71Z1が、水素原子である［２１］に記載の化合物。
［２３］
Ｒ^O11Z1が、水素原子或いは置換基を有していてもよい炭素数１〜１０の炭化水素基である［２１］又は［２２］に記載の化合物。
［２４］
Ｒ^21Z1、Ｒ^31Z1、Ｒ^41Z1、及びＲ^51Z1の少なくとも一つが、ニトロ基又はｔｅｒｔ−ブチル基である［２１］〜［２３］のいずれかに記載の化合物。
［２５］
式（ＩＺ２−Ｂ）で表される化合物。

［式（ＩＺ２−Ｂ）中、
Ｒ^CO11Z2及びＲ^CO21Z2は、互いに独立に、−Ｏ−Ｒ^O1Z2又は−ＮＲ^N1Z2Ｒ^N2Z2を表し、Ｒ^CO11Z2及びＲ^CO21Z2の少なくとも一つは、−ＮＲ^N1Z2Ｒ^N2Z2である。
Ｒ^N1Z2、Ｒ^N2Z2、Ｒ^1Z2、Ｒ^21Z2、Ｒ^31Z2、Ｒ^41Z2及びＲ^51Z2は、互いに独立に、水素原子、−ＣＯ−Ｒ^102Z2、−ＣＯＯ−Ｒ^101Z2、−ＯＣＯ−Ｒ^102Z2、−ＣＯＣＯ−Ｒ^102Z2、−Ｏ−Ｒ^102Z2、−ＳＯ₂−Ｒ^101Z2、−ＳＯ₂Ｎ（Ｒ^102Z2）₂、−ＣＯＮ（Ｒ^102Z2）₂、−Ｎ（Ｒ^102Z2）₂、−ＮＨＣＯ−Ｒ^102Z2、−ＮＨＣＯ−Ｎ（Ｒ^102Z2）₂、−ＮＨＣＯＯＲ^102Z2、−ＯＣＯＮ（Ｒ^102Z2）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表し、Ｒ^21Z2とＲ^31Z2、Ｒ^31Z2とＲ^41Z2、及びＲ^41Z2とＲ^51Z2は、それぞれ互いに結合して環を形成してもよく、
Ｒ^21Z2、Ｒ^31Z2、Ｒ^41Z2及びＲ^51Z2の少なくとも一つは、−ＣＯ−Ｒ^102Z2、−ＣＯＯ−Ｒ^101Z2、−ＯＣＯ−Ｒ^102Z2、−ＣＯＣＯ−Ｒ^102Z2、−Ｏ−Ｒ^102Z2、−ＳＯ₂−Ｒ^101Z2、−ＳＯ₂Ｎ（Ｒ^102Z2）₂、−ＣＯＮ（Ｒ^102Z2）₂、−Ｎ（Ｒ^102Z2）₂、−ＮＨＣＯ−Ｒ^102Z2、−ＮＨＣＯ−Ｎ（Ｒ^102Z2）₂、−ＮＨＣＯＯＲ^102Z2、−ＯＣＯＮ（Ｒ^102Z2）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基であるか、又はＲ^21Z2とＲ^31Z2、Ｒ^31Z2とＲ^41Z2、及びＲ^41Z2とＲ^51Z2の少なくとも一組が、結合して環を形成している。
Ｒ^101Z2は、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^O1Z2及びＲ^102Z2は、互いに独立に、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、水素原子又はアルカリ金属原子を表す。
Ｒ^O1Z2、Ｒ^N1Z2、Ｒ^N2Z2、Ｒ^101Z2、Ｒ^102Z2及びＭが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
波線は、Ｅ体又はＺ体を表す。］
［２６］
Ｒ^O1Z2、Ｒ^N1Z2及びＲ^N2Z2が、水素原子又は置換基を有していてもよい炭素数１〜１０の炭化水素基である［２５］に記載の化合物。
［２７］
Ｒ^1Z2が、水素原子である［２５］又は［２６］に記載の化合物。
［２８］
Ｒ^21Z2、Ｒ^31Z2、Ｒ^41Z2及びＲ^51Z2の少なくとも一つが、ニトロ基又はｔｅｒｔ−ブチル基である［２５］〜［２７］のいずれかに記載の化合物。
［２９］
式（ＩＺ３−Ｂ）で表される化合物。

［式（ＩＺ３−Ｂ）中、
Ｒ^1Z3、Ｒ^21Z3、Ｒ^31Z3、Ｒ^41Z3、Ｒ^51Z3、Ｒ^61Z3、及びＲ^71Z3は、互いに独立に、水素原子、−ＣＯ−Ｒ^102Z3、−ＣＯＯ−Ｒ^101Z3、−ＯＣＯ−Ｒ^102Z3、−ＣＯＣＯ−Ｒ^102Z3、−Ｏ−Ｒ^102Z3、−ＳＯ₂−Ｒ^101Z3、−ＳＯ₂Ｎ（Ｒ^102Z3）₂、−ＣＯＮ（Ｒ^102Z3）₂、−Ｎ（Ｒ^102Z3）₂、−ＮＨＣＯ−Ｒ^102Z3、−ＮＨＣＯ−Ｎ（Ｒ^102Z3）₂、−ＮＨＣＯＯＲ^102Z3、−ＯＣＯＮ（Ｒ^102Z3）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^21Z3とＲ^31Z3、Ｒ^31Z3とＲ^41Z3、及びＲ^41Z3とＲ^51Z3は、それぞれ互いに結合して環を形成してもよい。
ただし、Ｒ^21Z3、Ｒ^31Z3、Ｒ^41Z3、及びＲ^51Z3の少なくとも一つは、−ＣＯ−Ｒ^102Z3、−ＣＯＯ−Ｒ^101Z3、−ＯＣＯ−Ｒ^102Z3、−ＣＯＣＯ−Ｒ^102Z3、−Ｏ−Ｒ^102Z3、−ＳＯ₂−Ｒ^101Z3、−ＳＯ₂Ｎ（Ｒ^102Z3）₂、−ＣＯＮ（Ｒ^102Z3）₂、−Ｎ（Ｒ^102Z3）₂、−ＮＨＣＯ−Ｒ^102Z3、−ＮＨＣＯ−Ｎ（Ｒ^102Z3）₂、−ＮＨＣＯＯＲ^102Z3、−ＯＣＯＮ（Ｒ^102Z3）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基或いは置換基を有していてもよい複素環基であるか、又はＲ^21Z3とＲ^31Z3、Ｒ^31Z3とＲ^41Z3、及びＲ^41Z3とＲ^51Z3の少なくとも一組が結合して環を形成している。
Ｒ^101Z3は、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102Z3は、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、水素原子又はアルカリ金属原子を表す。
Ｒ^101Z3、Ｒ^102Z3及びＭが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
波線は、Ｅ体又はＺ体を表す。］
［３０］
Ｒ^1Z3、Ｒ^61Z3及びＲ^71Z3が、水素原子である［２９］に記載の化合物。
［３１］
Ｒ^21Z3、Ｒ^31Z3、Ｒ^41Z3、及びＲ^51Z3の少なくとも一つが、ニトロ基又はｔｅｒｔ−ブチル基である［２９］又は［３０］に記載の化合物。
［３２］
式（ＩＺ４）で表される化合物。

［式（ＩＺ４）中、
Ｒ^N1Z4及びＲ^N2Z4は、互いに独立に、−ＣＯ−Ｒ^102Z4、−ＣＯＯ−Ｒ^101Z4、−ＯＣＯ−Ｒ^102Z4、−ＣＯＣＯ−Ｒ^102Z4、−Ｏ−Ｒ^102Z4、−ＳＯ₂−Ｒ^101Z4、−ＳＯ₂Ｎ（Ｒ^102Z4）₂、−ＣＯＮ（Ｒ^102Z4）₂、−Ｎ（Ｒ^102Z4）₂、−ＮＨＣＯ−Ｒ^102Z4、−ＮＨＣＯ−Ｎ（Ｒ^102Z4）₂、−ＮＨＣＯＯＲ^102Z4、−ＯＣＯＮ（Ｒ^102Z4）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^1Z4、Ｒ^2Z4、Ｒ^3Z4、Ｒ^4Z4、Ｒ^5Z4、Ｒ^6Z4、及びＲ^7Z4は、互いに独立に、水素原子、−ＣＯ−Ｒ^102Z4、−ＣＯＯ−Ｒ^101Z4、−ＯＣＯ−Ｒ^102Z4、−ＣＯＣＯ−Ｒ^102Z4、−Ｏ−Ｒ^102Z4、−ＳＯ₂−Ｒ^101Z4、−ＳＯ₂Ｎ（Ｒ^102Z4）₂、−ＣＯＮ（Ｒ^102Z4）₂、−Ｎ（Ｒ^102Z4）₂、−ＮＨＣＯ−Ｒ^102Z4、−ＮＨＣＯ−Ｎ（Ｒ^102Z4）₂、−ＮＨＣＯＯＲ^102Z4、−ＯＣＯＮ（Ｒ^102Z4）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^2Z4とＲ^3Z4、Ｒ^3Z4とＲ^4Z4、及びＲ^4Z4とＲ^5Z4は、それぞれ互いに結合して環を形成してもよい。
Ｒ^101Z4は、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102Z4は、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、水素原子又はアルカリ金属原子を表す。
Ｒ^101Z4、Ｒ^102Z4及びＭが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
波線は、Ｅ体又はＺ体を表す。］
［３３］
Ｒ^1Z4、Ｒ^6Z4及びＲ^7Z4が、水素原子である［３２］に記載の化合物。
［３４］
Ｒ^N1Z4及びＲ^N2Z4が、互いに独立に、置換基を有していてもよい炭素数１〜１０の炭化水素基である［３２］又は［３３］に記載の化合物。
［３５］
Ｒ^2Z4、Ｒ^3Z4、Ｒ^4Z4、及びＲ^5Z4の少なくとも一つが、−ＣＯ−Ｒ^102Z4、−ＣＯＯ−Ｒ^101Z4、−ＯＣＯ−Ｒ^102Z4、ＣＯＣＯ−Ｒ^102Z4、−Ｏ−Ｒ^102Z4、−ＳＯ₂−Ｒ^101Z4、−ＳＯ₂Ｎ（Ｒ^102Z4）₂、−ＣＯＮ（Ｒ^102Z4）₂、−Ｎ（Ｒ^102Z4）₂、−ＮＨＣＯ−Ｒ^102Z4、−ＮＨＣＯ−Ｎ（Ｒ^102Z4）₂、−ＮＨＣＯＯＲ^102Z4、−ＯＣＯＮ（Ｒ^102Z4）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基或いは置換基を有していてもよい複素環基であるか、又はＲ^2Z4とＲ^3Z4、Ｒ^3Z4とＲ^4Z4、及びＲ^4Z4とＲ^5Z4の少なくとも一組が結合して環を形成している［３２］〜［３４］のいずれかに記載の化合物。
［３６］
Ｒ^2Z4、Ｒ^3Z4、Ｒ^4Z4、及びＲ^5Z4の少なくとも一つが、ニトロ基又はｔｅｒｔ−ブチル基である［３２］〜［３５］のいずれかに記載の化合物。
［３７］
式（ＩＺ５）で表される化合物。

［式（ＩＺ５）中、
Ｒ^N1Z5は、−ＣＯ−Ｒ^102Z5、−ＣＯＯ−Ｒ^101Z5、−ＯＣＯ−Ｒ^102Z5、−ＣＯＣＯ−Ｒ^102Z5、−Ｏ−Ｒ^102Z5、−ＳＯ₂−Ｒ^101Z5、−ＳＯ₂Ｎ（Ｒ^102Z5）₂、−ＣＯＮ（Ｒ^102Z5）₂、−Ｎ（Ｒ^102Z5）₂、−ＮＨＣＯ−Ｒ^102Z5、−ＮＨＣＯ−Ｎ（Ｒ^102Z5）₂、−ＮＨＣＯＯＲ^102Z5、−ＯＣＯＮ（Ｒ^102Z5）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^1Z5、Ｒ^2Z5、Ｒ^3Z5、Ｒ^4Z5、Ｒ^5Z5、Ｒ^6Z5、及びＲ^7Z5は、互いに独立に、水素原子、−ＣＯ−Ｒ^102Z5、−ＣＯＯ−Ｒ^101Z5、−ＯＣＯ−Ｒ^102Z5、−ＣＯＣＯ−Ｒ^102Z5、−Ｏ−Ｒ^102Z5、−ＳＯ₂−Ｒ^101Z5、−ＳＯ₂Ｎ（Ｒ^102Z5）₂、−ＣＯＮ（Ｒ^102Z5）₂、−Ｎ（Ｒ^102Z5）₂、−ＮＨＣＯ−Ｒ^102Z5、−ＮＨＣＯ−Ｎ（Ｒ^102Z5）₂、−ＮＨＣＯＯＲ^102Z5、−ＯＣＯＮ（Ｒ^102Z5）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表し、Ｒ^2Z5とＲ^3Z5、Ｒ^3Z5とＲ^4Z5、及びＲ^4Z5とＲ^5Z5は、それぞれ互いに結合して環を形成してもよく、Ｒ^2Z5、Ｒ^3Z5、Ｒ^4Z5及びＲ^5Z5の少なくとも一つは、−ＣＯ−Ｒ^102Z5、−ＣＯＯ−Ｒ^101Z5、−ＯＣＯ−Ｒ^102Z5、−ＣＯＣＯ−Ｒ^102Z5、−Ｏ−Ｒ^102Z5、−ＳＯ₂−Ｒ^101Z5、−ＳＯ₂Ｎ（Ｒ^102Z5）₂、−ＣＯＮ（Ｒ^102Z5）₂、−Ｎ（Ｒ^102Z5）₂、−ＮＨＣＯ−Ｒ^102Z5、−ＮＨＣＯ−Ｎ（Ｒ^102Z5）₂、−ＮＨＣＯＯＲ^102Z5、−ＯＣＯＮ（Ｒ^102Z5）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基若しくは置換基を有していてもよい複素環基であるか、又はＲ^2Z5とＲ^3Z5、Ｒ^3Z5とＲ^4Z5、及びＲ^4Z5とＲ^5Z5の少なくとも一組が、結合して環を形成している。
Ｒ^101Z5は、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102Z5は、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、水素原子又はアルカリ金属原子を表す。
Ｒ^101Z5、Ｒ^102Z5及びＭが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
波線は、Ｅ体又はＺ体を表す。］
［３８］
Ｒ^N1Z5が、置換基を有していてもよい炭素数１〜１０の炭化水素基である［３７］に記載の化合物。
［３９］
Ｒ^1Z5、Ｒ^6Z5及びＲ^7Z5が、水素原子である［３７］又は［３８］に記載の化合物。
［４０］
Ｒ^2Z5、Ｒ^3Z5、Ｒ^4Z5、及びＲ^5Z5の少なくとも一つが、ニトロ基又はｔｅｒｔ−ブチル基である［３７］〜［３９］のいずれかに記載の化合物。
［４１］
式（ＩＺ６）で表される化合物。

［式（ＩＺ６）中、
Ｄは、イソインドリン骨格を有する構造を表す。
Ｚは、−ＳＯ₃ ^-又は−ＣＯ₂ ^-を表す。
Ａ^c+は、ｃ価の金属陽イオンを表す。
ａは、１〜１０の整数を表す。
ｂは、１以上の整数を表す。
ｃは、２〜１０の整数を表す。
ｄは、１以上の整数を表す。
Ｄ、Ｚ、ａ又はＡ^c+が複数存在する場合、それらはそれぞれ同一であってもよく、異なっていてもよい。
式（Ｉ’Ｚ６）及び式（Ｉ’’Ｚ６）は、それぞれ、式（ＩＺ６）の部分構造を表し、Ｄ、Ｚ、Ａ^c+、ａ、ｂ、ｃ及びｄは、式（ＩＺ６）におけるものと同じものを表す。
ただし、式（Ｉ’Ｚ６）で表される部分構造が有する負の価数と、式（Ｉ’’Ｚ６）で表される部分構造が有する正の価数の絶対値は同じである。］
［４２］
式（ＩＺ６）で表される化合物が、式（ＩＺ６−Ａ）で表される化合物である［４１］に記載の化合物。

［式（ＩＺ６−Ａ）中、
Ａ^c+、ｂ、ｃ及びｄは、前記と同じ意味を表す。
Ｒ^1AZ6、Ｒ^2AZ6、Ｒ^3AZ6、Ｒ^4AZ6、Ｒ^5AZ6、Ｒ^AA1Z6、Ｒ^AA2Z6、Ｒ^12AZ6及びＲ^13AZ6は、互いに独立に、水素原子、−ＣＯ−Ｒ^102AZ6、−ＣＯＯ−Ｒ^101AZ6、−ＯＣＯ−Ｒ^102AZ6、−ＣＯＣＯ−Ｒ^102AZ6、−Ｏ−Ｒ^102AZ6、−ＳＯ₂−Ｒ^101AZ6、−ＳＯ₂Ｎ（Ｒ^102AZ6）₂、−ＣＯＮ（Ｒ^102AZ6）₂、−Ｎ（Ｒ^102AZ6）₂、−ＮＨＣＯ−Ｒ^102AZ6、−ＮＨＣＯ−Ｎ（Ｒ^102AZ6）₂、−ＮＨＣＯＯＲ^102AZ6、−ＯＣＯＮ（Ｒ^102AZ6）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、−ＳＯ₃ ^-、−ＣＯ₂ ^-、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^2AZ6とＲ^3AZ6、Ｒ^3AZ6とＲ^4AZ6、Ｒ^4AZ6とＲ^5AZ6、Ｒ^AA1Z6とＲ^AA2Z6及びＲ^12AZ6とＲ^13AZ6は、それぞれ互いに結合して環を形成してもよい。
Ｒ^101AZ6は、互いに独立に、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102AZ6は、互いに独立に、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、水素原子又はアルカリ金属原子を表す。
式（ＩＺ６−Ａ’）及び式（ＩＺ６−Ａ’’）は、それぞれ、式（ＩＺ６−Ａ）の部分構造を表し、Ａ^c+、ｂ、ｃ、ｄ、Ｒ^1AZ6、Ｒ^2AZ6、Ｒ^3AZ6、Ｒ^4AZ6、Ｒ^5AZ6、Ｒ^AA1Z6、
Ｒ^AA2Z6、Ｒ^12AZ6及びＲ^13AZ6は、式（ＩＺ６−Ａ）におけるものと同じものを表す。
Ｒ^1AZ6、Ｒ^2AZ6、Ｒ^3AZ6、Ｒ^4AZ6、Ｒ^5AZ6、Ｒ^AA1Z6、Ｒ^AA2Z6、Ｒ^12AZ6、Ｒ^13AZ6、Ｒ^101AZ6、Ｒ^102AZ6、Ｍ、ｃ又はＡ^c+が複数存在する場合、それらはそれぞれ同一であってもよく、異なっていてもよい。
Ｒ^1AZ6、Ｒ^2AZ6、Ｒ^3AZ6、Ｒ^4AZ6、Ｒ^5AZ6、Ｒ^AA1Z6、Ｒ^AA2Z6、Ｒ^12AZ6、Ｒ^13AZ6、Ｒ^101AZ6及びＲ^102AZ6は、（ｒａ−ｉ）〜（ｒａ−ｉｉｉ）のうち少なくとも１つを充足しており、Ｒ^1AZ6、Ｒ^2AZ6、Ｒ^3AZ6、Ｒ^4AZ6、Ｒ^5AZ6、Ｒ^AA1Z6、Ｒ^AA2Z6、Ｒ^12AZ6、Ｒ^13AZ6、Ｒ^101AZ6及びＲ^102AZ6が有する−ＳＯ₃ ^-又は−ＣＯ₂ ^-の合計個数はａである。
（ｒａ−ｉ）Ｒ^1AZ6、Ｒ^2AZ6、Ｒ^3AZ6、Ｒ^4AZ6、Ｒ^5AZ6、Ｒ^AA1Z6、Ｒ^AA2Z6、Ｒ^12AZ6及びＲ^13AZ6の少なくとも一つが、−ＳＯ₃ ^-又は−ＣＯ₂ ^-である。
（ｒａ−ｉｉ）Ｒ^1AZ6、Ｒ^2AZ6、Ｒ^3AZ6、Ｒ^4AZ6、Ｒ^5AZ6、Ｒ^AA1Z6、Ｒ^AA2Z6、Ｒ^12AZ6及びＲ^13AZ6の少なくとも一つが、−ＣＯ−Ｒ^102AZ6、−ＣＯＯ−Ｒ^101AZ6、−ＯＣＯ−Ｒ^102AZ6、−ＣＯＣＯ−Ｒ^102AZ6、−Ｏ−Ｒ^102AZ6、−ＳＯ₂−Ｒ^101AZ6、−ＳＯ₂Ｎ（Ｒ^102AZ6）₂、−ＣＯＮ（Ｒ^102AZ6）₂、−Ｎ（Ｒ^102AZ6）₂、−ＮＨＣＯ−Ｒ^102AZ6、−ＮＨＣＯ−Ｎ（Ｒ^102AZ6）₂、−ＮＨＣＯＯＲ^102AZ6、又は−ＯＣＯＮ（Ｒ^102AZ6）₂であって、該Ｒ^101AZ6及びＲ^102AZ6が、−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する炭素数１〜４０の炭化水素基又は−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する複素環基である。ただし該炭化水素基又は該複素環基は、−ＳＯ₃ ^-及び−ＣＯ₂ ^-以外の置換基を有していてもよい。
（ｒａ−ｉｉｉ）Ｒ^1AZ6、Ｒ^2AZ6、Ｒ^3AZ6、Ｒ^4AZ6、Ｒ^5AZ6、Ｒ^AA1Z6、Ｒ^AA2Z6、Ｒ^12AZ6及びＲ^13AZ6の少なくとも一つが、−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する炭素数１〜４０の炭化水素基又は−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する複素環基である。ただし該炭化水素基及び該複素環基は、−ＳＯ₃ ^-又は−ＣＯ₂ ^-以外の置換基を有していてもよい。
ａは、式（ＩＺ６）におけるものと同じ意味を表す。ａが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
式（ＩＺ６−Ａ’）で表される部分構造が有する負の価数と、式（ＩＺ６−Ａ’’）で表される部分構造が有する正の価数の絶対値は同じである。
波線は、Ｅ体又はＺ体を表す。］
［４３］
式（ＩＺ６−Ａ）で表される化合物が、式（ＩＺ６−Ｂ）で表される化合物である［４２］に記載の化合物。

［式（ＩＺ６−Ｂ）中、
Ａ^c+、ｂ、ｃ、ｄ及び波線は、前記と同じ意味を表す。
Ｌ¹は、−ＣＯ−又は−ＳＯ₂−を表す。
Ｒ^1BZ6、Ｒ^2BZ6、Ｒ^3BZ6、Ｒ^4BZ6、Ｒ^5BZ6、Ｒ^11BZ6、Ｒ^12BZ6及びＲ^13BZ6は、互いに独立に、水素原子、−ＣＯ−Ｒ^102BZ6、−ＣＯＯ−Ｒ^101BZ6、−ＯＣＯ−Ｒ^102BZ6、−ＣＯＣＯ−Ｒ^102BZ6、−Ｏ−Ｒ^102BZ6、−ＳＯ₂−Ｒ^101BZ6、−ＳＯ₂Ｎ（Ｒ^102BZ6）₂、−ＣＯＮ（Ｒ^102BZ6）₂、−Ｎ（Ｒ^102BZ6）₂、−ＮＨＣＯ−Ｒ^102BZ6、−ＮＨＣＯ−Ｎ（Ｒ^102BZ6）₂、−ＮＨＣＯＯＲ^102BZ6、−ＯＣＯＮ（Ｒ^102BZ6）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、−ＳＯ₃ ^-、−ＣＯ₂ ^-、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^2BZ6とＲ^3BZ6、Ｒ^3BZ6とＲ^4BZ6、Ｒ^4BZ6とＲ^5BZ6、及びＲ^12BZ6とＲ^13BZ6は、それぞれ互いに結合して環を形成してもよい。
Ｒ^101BZ6は、互いに独立に、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102BZ6は、互いに独立に、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
式（ＩＺ６−Ｂ’）及び式（ＩＺ６−Ｂ’’）は、それぞれ、式（ＩＺ６−Ｂ）の部分構造を表し、Ａ^c+、ｂ、ｃ、ｄ、Ｒ^1BZ6、Ｒ^2BZ6、Ｒ^3BZ6、Ｒ^4BZ6、Ｒ^5BZ6、Ｒ^11BZ6、Ｒ^12BZ6、Ｒ^13BZ6及びＬ¹は、式（ＩＺ６−Ｂ）におけるものと同じものを表す。
Ｍは、前記と同じ意味を表す。
Ｒ^1BZ6、Ｒ^2BZ6、Ｒ^3BZ6、Ｒ^4BZ6、Ｒ^5BZ6、Ｒ^11BZ6、Ｒ^12BZ6、Ｒ^13BZ6、Ｒ^101BZ6、Ｒ^102BZ6、Ｌ¹、Ｍ、ｃ又はＡ^c+が複数存在する場合、それらはそれぞれ同一であってもよく、異なっていてもよい。
Ｒ^1BZ6、Ｒ^2BZ6、Ｒ^3BZ6、Ｒ^4BZ6、Ｒ^5BZ6、Ｒ^11BZ6、Ｒ^12BZ6、Ｒ^13BZ6、Ｒ^101BZ6及びＲ^102BZ6は、（ｒｂ−ｉ）〜（ｒｂ−ｉｉｉ）のうち少なくとも１つを充足しており、Ｒ^1BZ6、Ｒ^2BZ6、Ｒ^3BZ6、Ｒ^4BZ6、Ｒ^5BZ6、Ｒ^11BZ6、Ｒ^12BZ6、Ｒ^13BZ6、Ｒ^101BZ6及びＲ^102BZ6が有する−ＳＯ₃ ^-又は−ＣＯ₂ ^-の合計個数はａである。
（ｒｂ−ｉ）Ｒ^1BZ6、Ｒ^2BZ6、Ｒ^3BZ6、Ｒ^4BZ6、Ｒ^5BZ6、Ｒ^11BZ6、Ｒ^12BZ6及びＲ^13BZ6の少なくとも一つが、−ＳＯ₃ ^-又は−ＣＯ₂ ^-である。
（ｒｂ−ｉｉ）Ｒ^1BZ6、Ｒ^2BZ6、Ｒ^3BZ6、Ｒ^4BZ6、Ｒ^5BZ6、Ｒ^11BZ6、Ｒ^12BZ6及びＲ^13BZ6の少なくとも一つが、−ＣＯ−Ｒ^102BZ6、−ＣＯＯ−Ｒ^101BZ6、−ＯＣＯ−Ｒ^102BZ6、−ＣＯＣＯ−Ｒ^102BZ6、−Ｏ−Ｒ^102BZ6、−ＳＯ₂−Ｒ^101BZ6、−ＳＯ₂Ｎ（Ｒ^102BZ6）₂、又は−ＣＯＮ（Ｒ^102BZ6）₂、−Ｎ（Ｒ^102BZ6）₂、−ＮＨＣＯ−Ｒ^102BZ6、−ＮＨＣＯ−Ｎ（Ｒ^102BZ6）₂、−ＮＨＣＯＯＲ^102BZ6、又は−ＯＣＯＮ（Ｒ^102BZ6）₂であって、
該Ｒ^101BZ6及びＲ^102BZ6が、−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する炭素数１〜４０の炭化水素基又は−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する複素環基である。ただし該炭化水素基又は該複素環基は、−ＳＯ₃ ^-及び−ＣＯ₂ ^-以外の置換基を有していてもよい。
（ｒｂ−ｉｉｉ）Ｒ^1BZ6、Ｒ^2BZ6、Ｒ^3BZ6、Ｒ^4BZ6、Ｒ^5BZ6、Ｒ^11BZ6、Ｒ^12BZ6及びＲ^13BZ6の少なくとも一つが、−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する炭素数１〜４０の炭化水素基又は−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する複素環基である。ただし該炭化水素基又は該複素環基は、−ＳＯ₃ ^-及び−ＣＯ₂ ^-以外の置換基を有していてもよい。
ａは、式（ＩＺ６−Ａ）におけるものと同じ意味を表す。ａが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
式（ＩＺ６−Ｂ’）で表される部分構造が有する負の価数と、式（ＩＺ６−Ｂ’’）で表される部分構造が有する正の価数の絶対値は同じである。］
［４４］
Ｌ¹が、−ＣＯ−である［４３］に記載の化合物。
［４５］
Ｒ^11BZ6が、置換基を有していてもよい炭素数１〜４０の脂肪族炭化水素基、置換基を有していてもよいフェニル基、置換基を有していてもよいナフチル基、置換基を有していてもよいテトラヒドロナフチル基、置換基を有していてもよいチエニル基、置換基を有していてもよいフリル基又は置換基を有していてもよいピリジニル基である［４３］又は［４４］に記載の化合物。
［４６］
式（ＩＺ６−Ｂ）で表される化合物が、式（ＩＺ６−Ｃ）で表される化合物である［４３］に記載の化合物。

［式（ＩＺ６−Ｃ）中、
Ａ^c+、ｂ、ｃ、ｄ、Ｌ¹及び波線は、前記と同じ意味を表す。
Ｌ²は、−ＣＯ−又は−ＳＯ₂−を表す。
Ｒ^1CZ6、Ｒ^2CZ6、Ｒ^3CZ6、Ｒ^4CZ6、Ｒ^5CZ6、Ｒ^11CZ6及びＲ^14CZ6は、互いに独立に、水素原子、−ＣＯ−Ｒ^102CZ6、−ＣＯＯ−Ｒ^101CZ6、−ＯＣＯ−Ｒ^102CZ6、−ＣＯＣＯ−Ｒ^102CZ6、−Ｏ−Ｒ^102CZ6、−ＳＯ₂−Ｒ^101CZ6、−ＳＯ₂Ｎ（Ｒ^102CZ6）₂、−ＣＯＮ（Ｒ^102CZ6）₂、−Ｎ（Ｒ^102CZ6）₂、−ＮＨＣＯ−Ｒ^102CZ6、−ＮＨＣＯ−Ｎ（Ｒ^102CZ6）₂、−ＮＨＣＯＯＲ^102CZ6、−ＯＣＯＮ（Ｒ^102CZ6）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、−ＳＯ₃ ^-、−ＣＯ₂ ^-、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^2CZ6とＲ^3CZ6、Ｒ^3CZ6とＲ^4CZ6、及びＲ^4CZ6とＲ^5CZ6は、それぞれ互いに結合して環を形成してもよい。
Ｒ^101CZ6は、互いに独立に、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102CZ6は、互いに独立に、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、前記と同じ意味を表す。
式（ＩＺ６−Ｃ’）及び式（ＩＺ６−Ｃ’’）は、それぞれ、式（ＩＺ６−Ｃ）の部分構造を表し、Ａ^c+、ｂ、ｃ、ｄ、Ｒ^1CZ6、Ｒ^2CZ6、Ｒ^3CZ6、Ｒ^4CZ6、Ｒ^5CZ6、Ｒ^11CZ6、Ｒ^14CZ6、Ｌ¹及びＬ²は、式（ＩＺ６−Ｃ）におけるものと同じものを表す。
Ｒ^1CZ6、Ｒ^2CZ6、Ｒ^3CZ6、Ｒ^4CZ6、Ｒ^5CZ6、Ｒ^11CZ6、Ｒ^14CZ6、Ｒ^101CZ6、Ｒ^102CZ6、Ｌ¹、Ｌ²、Ｍ、ｃ又はＡ^c+が複数存在する場合、それらはそれぞれ同一であってもよく、異なっていてもよい。
Ｒ^1CZ6、Ｒ^2CZ6、Ｒ^3CZ6、Ｒ^4CZ6、Ｒ^5CZ6、Ｒ^11CZ6、Ｒ^14CZ6、Ｒ^101CZ6及びＲ^102CZ6は、（ｒｃ−ｉ）〜（ｒｃ−ｉｉｉ）のうち少なくとも１つを充足しており、Ｒ^1CZ6、Ｒ^2CZ6、Ｒ^3CZ6、Ｒ^4CZ6、Ｒ^5CZ6、Ｒ^11CZ6、Ｒ^14CZ6、Ｒ^101CZ6及びＲ^102CZ6が有する−ＳＯ₃ ^-又は−ＣＯ₂ ^-の合計個数はａである。
（ｒｃ−ｉ）Ｒ^1CZ6、Ｒ^2CZ6、Ｒ^3CZ6、Ｒ^4CZ6、Ｒ^5CZ6、Ｒ^11CZ6及びＲ^14CZ6の少なくとも一つが、−ＳＯ₃ ^-又は−ＣＯ₂ ^-である。
（ｒｃ−ｉｉ）Ｒ^1CZ6、Ｒ^2CZ6、Ｒ^3CZ6、Ｒ^4CZ6、Ｒ^5CZ6、Ｒ^11CZ6及びＲ^14CZ6の少なくとも一つが、−ＣＯ−Ｒ^102CZ6、−ＣＯＯ−Ｒ^101CZ6、−ＯＣＯ−Ｒ^102CZ6、−ＣＯＣＯ−Ｒ^102CZ6、−Ｏ−Ｒ^102CZ6、−ＳＯ₂−Ｒ^101CZ6、−ＳＯ₂Ｎ（Ｒ^102CZ6）₂、−ＣＯＮ（Ｒ^102CZ6）₂、−Ｎ（Ｒ^102CZ6）₂、−ＮＨＣＯ−Ｒ^102CZ6、−ＮＨＣＯ−Ｎ（Ｒ^102CZ6）₂、−ＮＨＣＯＯＲ^102CZ6、又は−ＯＣＯＮ（Ｒ^102CZ6）₂であって、該Ｒ^101CZ6及びＲ^102CZ6が、−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する炭素数１〜４０の炭化水素基又は−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する複素環基である。ただし該炭化水素基又は該複素環基は、−ＳＯ₃ ^-及び−ＣＯ₂ ^-以外の置換基を有していてもよい。
（ｒｃ−ｉｉｉ）Ｒ^1CZ6、Ｒ^2CZ6、Ｒ^3CZ6、Ｒ^4CZ6、Ｒ^5CZ6、Ｒ^11CZ6及びＲ^14CZ6の少なくとも一つが、−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する炭素数１〜４０の炭化水素基又は−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する複素環基である。ただし該炭化水素基又は該複素環基は、−ＳＯ₃ ^-及び−ＣＯ₂ ^-以外の置換基を有していてもよい。
ａは、式（ＩＺ６−Ｂ）におけるものと同じ意味を表す。ａが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
式（ＩＺ６−Ｃ’）で表される部分構造が有する負の価数と、式（ＩＺ６−Ｃ’’）で表される部分構造が有する正の価数の絶対値は同じである。］
［４７］
Ｒ^11CZ6とＲ^14CZ6とが同じ基であり、Ｌ¹とＬ²とが同じ基である［４６］に記載の化合物。
［４８］
Ｌ¹及びＬ²が、−ＣＯ−である［４６］又は［４７］に記載の化合物。
［４９］
Ｒ^11CZ6及びＲ^14CZ6が、置換基を有していてもよい炭素数１〜４０の脂肪族炭化水素基、置換基を有していてもよいフェニル基、置換基を有していてもよいナフチル基、置換基を有していてもよいテトラヒドロナフチル基、置換基を有していてもよいチエニル基、置換基を有していてもよいフリル基又は置換基を有していてもよいピリジニル基である［４６］〜［４８］のいずれかに記載の化合物。
［５０］
式（ＩＺ６−Ｂ）で表される化合物が、式（ＩＺ６−Ｄ）で表される化合物である［４３］に記載の化合物。

［式（ＩＺ６−Ｄ）中、
Ａ^c+、ｂ、ｃ、ｄ、Ｌ¹及び波線は、前記と同じ意味を表す。
Ｒ^20DZ6及びＲ^30DZ6は結合して環Ｑを形成する。
環Ｑは、置換基を有していてもよく、環の構成員数が５〜７の環であり、該環Ｑは、炭化水素環でもよく複素環でもよい。環Ｑには、炭化水素環及び複素環から選ばれる、環の構成員数が５〜７の置換基を有していてもよい単環又は該単環の２つ以上が縮合した縮環が縮合してもよい。
Ｒ^1DZ6、Ｒ^2DZ6、Ｒ^3DZ6、Ｒ^4DZ6、Ｒ^5DZ6及びＲ^11DZ6は、互いに独立に、水素原子、−ＣＯ−Ｒ^102DZ6、−ＣＯＯ−Ｒ^101DZ6、−ＯＣＯ−Ｒ^102DZ6、−ＣＯＣＯ−Ｒ^102DZ6、−Ｏ−Ｒ^102DZ6、−ＳＯ₂−Ｒ^101DZ6、−ＳＯ₂Ｎ（Ｒ^102DZ6）₂、−ＣＯＮ（Ｒ^102DZ6）₂、−Ｎ（Ｒ^102DZ6）₂、−ＮＨＣＯ−Ｒ^102DZ6、−ＮＨＣＯ−Ｎ（Ｒ^102DZ6）₂、−ＮＨＣＯＯＲ^102DZ6、−ＯＣＯＮ（Ｒ^102DZ6）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、−ＳＯ₃ ^-、−ＣＯ₂ ^-、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^2DZ6とＲ^3DZ6、Ｒ^3DZ6とＲ^4DZ6、及びＲ^4DZ6とＲ^5DZ6は、それぞれ互いに結合して環を形成してもよい。
Ｒ^101DZ6は、互いに独立に、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102DZ6は、互いに独立に、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、前記と同じ意味を表す。
式（ＩＺ６−Ｄ’）及び式（ＩＺ６−Ｄ’’）は、それぞれ、式（ＩＺ６−Ｄ）の部分構造を表し、Ａ^c+、ｂ、ｃ、ｄ、Ｒ^1DZ6、Ｒ^2DZ6、Ｒ^3DZ6、Ｒ^4DZ6、Ｒ^5DZ6、Ｒ^11DZ6、Ｒ^20DZ6、Ｒ^30DZ6及びＬ¹は、式（ＩＺ６−Ｄ）におけるものと同じものを表す。
Ｒ^1DZ6、Ｒ^2DZ6、Ｒ^3DZ6、Ｒ^4DZ6、Ｒ^5DZ6、Ｒ^11DZ6、Ｒ^101DZ6、Ｒ^102DZ6、Ｌ¹、Ｍ、Ｒ^20DZ6、Ｒ^30DZ6、環Ｑ、ｃ又はＡ^c+が複数存在する場合、それらはそれぞれ同一であってもよく、異なっていてもよい。
Ｒ^1DZ6、Ｒ^2DZ6、Ｒ^3DZ6、Ｒ^4DZ6、Ｒ^5DZ6、Ｒ^11DZ6、Ｒ^101DZ6、Ｒ^102DZ6及び環Ｑは、（ｒｄ−ｉ）〜（ｒｄ−ｉｖ）のうち少なくとも１つを充足しており、Ｒ^1DZ6、Ｒ^2DZ6、Ｒ^3DZ6、Ｒ^4DZ6、Ｒ^5DZ6、Ｒ^11DZ6、Ｒ^101DZ6、Ｒ^102DZ6及び環Ｑが有する−ＳＯ₃ ^-又は−ＣＯ₂ ^-の合計個数はａである。
（ｒｄ−ｉ）Ｒ^1DZ6、Ｒ^2DZ6、Ｒ^3DZ6、Ｒ^4DZ6、Ｒ^5DZ6及びＲ^11DZ6の少なくとも一つが、−ＳＯ₃ ^-又は−ＣＯ₂ ^-である。
（ｒｄ−ｉｉ）Ｒ^1DZ6、Ｒ^2DZ6、Ｒ^3DZ6、Ｒ^4DZ6、Ｒ^5DZ6及びＲ^11DZ6の少なくとも一つが、−ＣＯ−Ｒ^102DZ6、−ＣＯＯ−Ｒ^101DZ6、−ＯＣＯ−Ｒ^102DZ6、−ＣＯＣＯ−Ｒ^102DZ6、−Ｏ−Ｒ^102DZ6、−ＳＯ₂−Ｒ^101DZ6、−ＳＯ₂Ｎ（Ｒ^102DZ6）₂、−ＣＯＮ（Ｒ^102DZ6）₂、−Ｎ（Ｒ^102DZ6）₂、−ＮＨＣＯ−Ｒ^102DZ6、−ＮＨＣＯ−Ｎ（Ｒ^102DZ6）₂、−ＮＨＣＯＯＲ^102DZ6、又は−ＯＣＯＮ（Ｒ^102DZ6）₂であって、該Ｒ^101DZ6及びＲ^102DZ6が、−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する炭素数１〜４０の炭化水素基又は−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する複素環基である。ただし該炭化水素基又は該複素環基は、−ＳＯ₃ ^-及び−ＣＯ₂ ^-以外の置換基を有していてもよい。
（ｒｄ−ｉｉｉ）Ｒ^1DZ6、Ｒ^2DZ6、Ｒ^3DZ6、Ｒ^4DZ6、Ｒ^5DZ6及びＲ^11DZ6の少なくとも一つが、−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する炭素数１〜４０の炭化水素基又は−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する複素環基である。ただし該炭化水素基又は該複素環基は、−ＳＯ₃ ^-及び−ＣＯ₂ ^-以外の置換基を有していてもよい。
（ｒｄ−ｉｖ）環Ｑが、−ＳＯ₃ ^-又は−ＣＯ₂ ^-を有する
ａは、式（ＩＺ６−Ｂ）におけるものと同じ意味を表す。ａが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
式（ＩＺ６−Ｄ’）で表される部分構造が有する負の価数と、式（ＩＺ６−Ｄ’’）で表される部分構造が有する正の価数の絶対値は同じである。］
［５１］
Ｌ¹が、−ＣＯ−である［５０］に記載の化合物。
［５２］
Ｒ^11DZ6が、置換基を有していてもよい炭素数１〜４０の脂肪族炭化水素基、置換基を有していてもよいフェニル基、置換基を有していてもよいナフチル基、置換基を有していてもよいテトラヒドロナフチル基、置換基を有していてもよいチエニル基、置換基を有していてもよいフリル基又は置換基を有していてもよいピリジニル基である［５０］又は［５１］に記載の化合物。
［５３］
式（ＩＺ６−Ｄ）で表される化合物が、式（ＩＺ６−Ｅ）で表される化合物である［５０］に記載の化合物。

［式（ＩＺ６−Ｅ）中、
Ａ^c+、ｂ、ｃ、ｄ、Ｌ¹及び波線は、前記と同じ意味を表す。
Ｒ^1EZ6、Ｒ^2EZ6、Ｒ^3EZ6、Ｒ^4EZ6、Ｒ^5EZ6、Ｒ^6EZ6、Ｒ^7EZ6及びＲ^11EZ6は、互いに独立に、水素原子、−ＣＯ−Ｒ^102EZ6、−ＣＯＯ−Ｒ^101EZ6、−ＯＣＯ−Ｒ^102EZ6、−ＣＯＣＯ−Ｒ^102EZ6、−Ｏ−Ｒ^102EZ6、−ＳＯ₂−Ｒ^101EZ6、−ＳＯ₂Ｎ（Ｒ^102EZ6）₂、−ＣＯＮ（Ｒ^102EZ6）₂、−Ｎ（Ｒ^102EZ6）₂、−ＮＨＣＯ−Ｒ^102EZ6、−ＮＨＣＯ−Ｎ（Ｒ^102EZ6）₂、−ＮＨＣＯＯＲ^102EZ6、−ＯＣＯＮ（Ｒ^102EZ6）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、−ＳＯ₃ ^-、−ＣＯ₂ ^-、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^2EZ6とＲ^3EZ6、Ｒ^3EZ6とＲ^4EZ6、及びＲ^4EZ6とＲ^5EZ6は、それぞれ互いに結合して環を形成してもよい。
Ｒ^101EZ6は、互いに独立に、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102EZ6は、互いに独立に、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、前記と同じ意味を表す。
式（ＩＺ６−Ｅ’）及び式（ＩＺ６−Ｅ’’）は、それぞれ、式（ＩＺ６−Ｅ）の部分構造を表し、Ａ^c+、ｂ、ｃ、ｄ、Ｒ^1EZ6、Ｒ^2EZ6、Ｒ^3EZ6、Ｒ^4EZ6、Ｒ^5EZ6、Ｒ^6EZ6、Ｒ^7EZ6、Ｒ^11EZ6及びＬ¹は、式（ＩＺ６−Ｅ）におけるものと同じものを表す。
Ｒ^1EZ6、Ｒ^2EZ6、Ｒ^3EZ6、Ｒ^4EZ6、Ｒ^5EZ6、Ｒ^6EZ6、Ｒ^7EZ6、Ｒ^11EZ6、Ｒ^101EZ6、Ｒ^102EZ6、Ｌ¹、Ｍ、ｃ又はＡ^c+が複数存在する場合、それらはそれぞれ同一であってもよく、異なっていてもよい。
Ｒ^1EZ6、Ｒ^2EZ6、Ｒ^3EZ6、Ｒ^4EZ6、Ｒ^5EZ6、Ｒ^6EZ6、Ｒ^7EZ6、Ｒ^11EZ6、Ｒ^101EZ6及びＲ^102EZ6は、（ｒｅ−ｉ）〜（ｒｅ−ｉｉｉ）のうち少なくとも１つを充足しており、Ｒ^1EZ6、Ｒ^2EZ6、Ｒ^3EZ6、Ｒ^4EZ6、Ｒ^5EZ6、Ｒ^6EZ6、Ｒ^7EZ6、Ｒ^11EZ6、Ｒ^101EZ6及びＲ^102EZ6が有する−ＳＯ₃ ^-又は−ＣＯ₂ ^-の合計個数はａである。
（ｒｅ−ｉ）Ｒ^1EZ6、Ｒ^2EZ6、Ｒ^3EZ6、Ｒ^4EZ6、Ｒ^5EZ6、Ｒ^6EZ6、Ｒ^7EZ6及びＲ^11EZ6の少なくとも一つが、−ＳＯ₃ ^-又は−ＣＯ₂ ^-である。
（ｒｅ−ｉｉ）Ｒ^1EZ6、Ｒ^2EZ6、Ｒ^3EZ6、Ｒ^4EZ6、Ｒ^5EZ6、Ｒ^6EZ6、Ｒ^7EZ6及びＲ^11EZ6の少なくとも一つが、−ＣＯ−Ｒ^102EZ6、−ＣＯＯ−Ｒ^101EZ6、−ＯＣＯ−Ｒ^102EZ6、−ＣＯＣＯ−Ｒ^102EZ6、−Ｏ−Ｒ^102EZ6、−ＳＯ₂−Ｒ^101EZ6、−ＳＯ₂Ｎ（Ｒ^102EZ6）₂、−ＣＯＮ（Ｒ^102EZ6）₂、−Ｎ（Ｒ^102EZ6）₂、−ＮＨＣＯ−Ｒ^102EZ6、−ＮＨＣＯ−Ｎ（Ｒ^102EZ6）₂、−ＮＨＣＯＯＲ^102EZ6、又は−ＯＣＯＮ（Ｒ^102EZ6）₂であって、該Ｒ^101EZ6及びＲ^102EZ6が、−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する炭素数１〜４０の炭化水素基又は−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する複素環基である。ただし該炭化水素基又は該複素環基は、−ＳＯ₃ ^-及び−ＣＯ₂ ^-以外の置換基を有していてもよい。
（ｒｅ−ｉｉｉ）Ｒ^1EZ6、Ｒ^2EZ6、Ｒ^3EZ6、Ｒ^4EZ6、Ｒ^5EZ6、Ｒ^6EZ6、Ｒ^7EZ6及びＲ^11EZ6の少なくとも一つが、−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する炭素数１〜４０の炭化水素基又は−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する複素環基である。ただし該炭化水素基又は該複素環基は、−ＳＯ₃ ^-及び−ＣＯ₂ ^-以外の置換基を有していてもよい。
ａは、式（ＩＺ６−Ｄ）におけるものと同じ意味を表す。ａが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
式（ＩＺ６−Ｅ’）で表される部分構造が有する負の価数と、式（ＩＺ６−Ｅ’’）で表される部分構造が有する正の価数の絶対値は同じである。］
［５４］
Ｌ¹が、−ＣＯ−である［５３］に記載の化合物。
［５５］
Ｒ^11EZ6が、置換基を有していてもよい炭素数１〜４０の脂肪族炭化水素基、置換基を有していてもよいフェニル基、置換基を有していてもよいナフチル基、置換基を有していてもよいテトラヒドロナフチル基、置換基を有していてもよいチエニル基、置換基を有していてもよいフリル基又は置換基を有していてもよいピリジニル基である［５３］又は［５４］に記載の化合物。 The present invention includes the following inventions.
[1]
A compound represented by the formula (IZ1), a compound represented by the formula (IZ2), a compound represented by the formula (IZ3), a compound represented by the formula (IZ4), a compound represented by the formula (IZ5), And one or more selected from the compounds represented by the formula (IZ6),
A coloring composition containing at least one of a resin and a solvent.

[In formula (IZ1),
^RO1Z1 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
R ^1Z1 , R ^2Z1 , R ^3Z1 , R ^4Z1 , R ^5Z1 , R ^6Z1 , and R ^7Z1 are independent of each other, hydrogen atom, -CO-R ^102Z1 , -COO-R ^101Z1 , -OCO-R ^102Z1 , -COCO. -R ^102Z1 , -O-R ^102Z1 , -SO ₂ -R ^101Z1 , -SO ₂ N (R ^102Z1 ) ₂ ^{, -CON} (R 102Z1) ₂ , -N (R ^102Z1 ) ₂ , -NHCO-R ^102Z1 ,- NHCO-N (R ^102Z1 ) ₂ , -NHCOOR ^102Z1 , -OCON (R ^102Z1 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, carbon which may have a substituent. Represents a heterocyclic group which may have a hydrocarbon group or a substituent of the number 1 to 40.
R ^{2Z 1} and R ^{3Z 1} , R ^{3Z 1} and R ^{4Z 1} , and R ^{4Z 1} and R 5 ^{Z 1} , respectively, may be coupled to each other to form a ring.
R ^101Z1 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102Z1 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
M represents a hydrogen atom or an alkali metal atom.
When a ^{plurality of R 101Z1} , R ^{102 Z1} and M exist, they may be the same or different.
The wavy line represents an E-form or a Z-form. ]

[In formula (IZ2),
R ^CO1Z2 and R ^CO2Z2 represent ^{-OR O1Z2} or -NR N1Z2 R ^N2Z2 independently of each other.
^{R N1Z2, R N2Z2, R 1Z2} , R 2Z2, R 3Z2, R 4Z2, and R ^5Z2, independently of each other, hydrogen ^{atom, -CO-R 102Z2, -COO-} R 101Z2, -OCO-R 102Z2, -COCO -R ^102Z2 , -O-R ^102Z2 , -SO ₂ -R ^101Z2 , -SO ₂ N (R ^102Z2 ) ₂ ^{, -CON} (R 102Z2) ₂ , -N (R ^102Z2 ) ₂ , -NHCO-R ^102Z2 ,- NHCO-N (R ^102Z2 ) ₂ , -NHCOOR ^102Z2 , -OCON (R ^102Z2 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, carbon which may have a substituent Represents a heterocyclic group which may have a hydrocarbon group or a substituent of the number 1 to 40.
R ^2Z2 and R ^3Z2, R ^3Z2 and R ^4Z2, and R ^4Z2 and R ^5Z2 may each be bonded to each other to form a ring.
R ^101Z2 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
^RO1Z2 and ^R102Z2 represent a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent, independently of each other.
M represents a hydrogen atom or an alkali metal atom.
When a ^{plurality of} R O1Z2, R ^N1Z2 , R ^N2Z2 , R ^101Z2 , R ^102Z2 and M exist, they may be the same or different.
The wavy line represents an E-form or a Z-form. ]

[In formula (IZ3),
R ^1Z3 , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , and R ^7Z3 are independent of each other, hydrogen atom, -CO-R ^102Z3 , -COO-R ^101Z3 , -OCO-R ^102Z3 , -COCO. -R ^102Z3 , -O-R ^102Z3 , -SO ₂ -R ^101Z3 , -SO ₂ N (R ^102Z3 ) ₂ ^{, -CON} (R 102Z3) ₂ , -N (R ^102Z3 ) ₂ , -NHCO-R ^102Z3 ,- NHCO-N (R ^102Z3 ) ₂ , -NHCOOR ^102Z3 , -OCON (R ^102Z3 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, carbon which may have a substituent Represents a heterocyclic group which may have a hydrocarbon group or a substituent of the number 1 to 40.
R ^2Z3 and R ^3Z3 , R ^3Z3 and R ^4Z3 , and R ^4Z3 and R ^5Z3 may be coupled to each other to form a ring, respectively.
R ^101Z3 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102Z3 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
M represents a hydrogen atom or an alkali metal atom.
When a ^{plurality of R 101Z3} , R ^102Z3 and M are present, they may be the same or different.
The wavy line represents an E-form or a Z-form. ]

[In formula (IZ4),
R ^N1Z4 and R ^N2Z4 are independent of each other, -CO-R ^102Z4 , -COO-R ^101Z4 , -OCO-R ^102Z4 , -COCO-R ^102Z4 , ^{-OR 102Z4} , -SO _2- R ^101Z4 , -SO. ₂ N (R ^102Z4 ) ₂ ^{, -CON} (R 102Z4) ₂ , -N (R ^102Z4 ) ₂ , -NHCO-R ^102Z4 , -NHCO-N (R ^102Z4 ) ₂ , -NHCOOR ^102Z4 , -OCON (R ^102Z4 ) ₂ , Halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, may have a substituent or a hydrocarbon group having 1 to 40 carbon atoms or a complex which may have a substituent. Represents a ring group.
R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , and R ^7Z4 are independent of each other, hydrogen atom, -CO-R ^102Z4 , -COO-R ^101Z4 , -OCO-R ^102Z4 , -COCO. -R ^102Z4 , -O-R ^102Z4 , -SO ₂ -R ^101Z4 , -SO ₂ N (R ^102Z4 ) ₂ ^{, -CON} (R 102Z4) ₂ , -N (R ^102Z4 ) ₂ , -NHCO-R ^102Z4 ,- NHCO-N (R ^102Z4 ) ₂ , -NHCOOR ^102Z4 , -OCON (R ^102Z4 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, carbon which may have a substituent Represents a heterocyclic group which may have a hydrocarbon group or a substituent of the number 1 to 40.
R ^{2Z 4} and R ^{3Z 4} , R ^{3Z 4} and R ^{4Z 4} , and R 4 ^{Z 4} and R 5 ^{Z 4} may be coupled to each other to form a ring, respectively.
R ^101Z4 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102Z4 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
M represents a hydrogen atom or an alkali metal atom.
When a ^{plurality of R 101Z4} , R ^102Z4 and M are present, they may be the same or different.
The wavy line represents an E-form or a Z-form. ]

[In formula (IZ5),
R ^N1Z5 is -CO-R ^102Z5 , -COO-R ^101Z5 , -OCO-R ^102Z5 , -COCO-R ^102Z5 , -O-R ^102Z5 , -SO _2- R ^101Z5 , -SO ₂ N (R ^102Z5 ) ₂ ^{, -CON} (R 102Z5) ₂ , -N (R ^102Z5 ) ₂ , -NHCO-R ^102Z5 , -NHCO-N (R ^102Z5 ) ₂ , -NHCOOR ^102Z5 , -OCON (R ^102Z5 ) ₂ , halogen atom, cyano group , Nitro group, -SO ₃ M, -CO ₂ M, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
^{R 1Z5, R 2Z5, R 3Z5} , R 4Z5, R 5Z5, R 6Z5, and R ^7Z5, independently of each other, hydrogen ^{atom, -CO-R 102Z5, -COO-} R 101Z5, -OCO-R 102Z5, -COCO -R ^102Z5 , -O-R ^102Z5 , -SO ₂ -R ^101Z5 , -SO ₂ N (R ^102Z5 ) ₂ ^{, -CON} (R 102Z5) ₂ , -N (R ^102Z5 ) ₂ , -NHCO-R ^102Z5 ,- NHCO-N (R ^102Z5 ) ₂ , -NHCOOR ^102Z5 , -OCON (R ^102Z5 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, carbon which may have a substituent ^{Represents a} heterocyclic group which may have a hydrocarbon group or a substituent of the number 1 to 40, and R 2Z5 and R ^3Z5 , R ^3Z5 and R ^4Z5 , and R ^4Z5 and R ^5Z5 are bonded to each other and ring, respectively. , ^And at least one of ^{R 2Z5} , R ^3Z5 , R ^4Z5 and R ^{5Z5 is -CO-R 102Z5} , -COO-R ^101Z5 , -OCO-R ^102Z5 , -COCO-R ^102Z5 , -O. -R ^102Z5 , -SO ₂ -R ^101Z5 , -SO ₂ N (R ^102Z5 ) ₂ ^{, -CON} (R 102Z5) ₂ , -N (R ^102Z5 ) ₂ , -NHCO-R ^102Z5 , -NHCO-N (R ^102Z5) ) ₂ , -NHCOOR ^102Z5 , -OCON (R ^102Z5 ) ₂ , Halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, hydrocarbon with 1 to 40 carbon atoms which may have a substituent It is a heterocyclic group that may have a hydrogen group or a substituent, or ^{at least one set of R 2Z5} and R ^3Z5 , R ^3Z5 and R ^4Z5 , and R ^4Z5 and R ^5Z5 are bonded to form a ring. doing.
R ^101Z5 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102Z5 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
M represents a hydrogen atom or an alkali metal atom.
When a ^{plurality of R 101Z5} , R ^102Z5 and M are present, they may be the same or different.
The wavy line represents an E-form or a Z-form. ]

[In formula (IZ6),
D represents a structure having an isoindoline skeleton.
Z is, -SO ₃ ^- represents a ^- or -CO _2.
A ^{c +} represents a c-valent metal cation.
a represents an integer of 1 to 10.
b represents an integer of 1 or more.
c represents an integer of 2 to 10.
d represents an integer of 1 or more.
When a plurality of D, Z, a or ^{Ac +} exist, they may be the same or different from each other.
The formula (I'Z6) and the formula (I''Z6) represent the partial structure of the formula (IZ6), respectively, and D, Z, Ac ⁺ , a, b, c and d are those in the formula (IZ6). Represents the same thing as.
However, the absolute value of the negative valence of the substructure represented by the formula (I'Z6) and the positive valence of the substructure represented by the formula (I ″ Z6) are the same. ]
[2]
The coloring composition according to [1], which comprises a compound represented by the formula (IZ1), a compound represented by the formula (IZ2), or a compound represented by the formula (IZ3), and a resin.
[3]
The coloring composition according to [1], which comprises a compound represented by the formula (IZ4), a compound represented by the formula (IZ5), or a compound represented by the formula (IZ6), and a solvent.
[4]
The coloring composition according to [1] or [2], which comprises a compound represented by the formula (IZ1) and in which R ^1Z1 , R ^{6Z 1} and R ^{7Z 1 are hydrogen atoms.}
[5]
[1] to [2] or [4], which comprises a compound represented by the formula (IZ1), and ^RO1Z1 is a hydrocarbon group having 1 to 10 carbon atoms which may have a hydrogen atom or a substituent. The colored composition described.
[6]
Including the compound represented by the formula (IZ1), at least one of ^{R 2Z1} , R ^3Z1 , R ^4Z1 and R ^{5Z1 is -CO-R 102Z1} , -COO-R ^101Z1 , -OCO-R ^102Z1 , -COCO-. R ^102Z1 , ^{-OR 102Z1} , -SO ₂ -R ^101Z1 , -SO ₂ N (R ^102Z1 ) ₂ ^{, -CON} (R 102Z1) ₂ , -N (R ^102Z1 ) ₂ , -NHCO-R ^102Z1 , -NHCO -N (R ^102Z1 ) ₂ , -NHCOOR ^102Z1 , -OCON (R ^102Z1 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, number of carbon atoms which may have a substituent 1-40 hydrocarbon group or have a substituent is also heterocyclic group, or R ^2Z1 and R ^3Z1, R ^3Z1 and R ^4Z1, and at least one pair binding of R ^4Z1 and R ^5Z1 The coloring composition according to [1] to [2], [4] or [5] forming a ring.
[7]
[1] to [2] or [4] to include a compound represented by the formula (IZ1) in which ^{at least one of R 2Z1} , R ^{3Z 1} , R ^{4Z 1} , and R ^{5Z 1 is a nitro group or a tert-butyl group.} The coloring composition according to any one of [6].
[8]
Includes the compound represented by the formula (IZ2), ^RO1Z2 , ^RN1Z2 and ^RN2Z2 are hydrocarbon groups having 1 to 10 carbon atoms which may have hydrogen atoms or substituents independently of each other [ The coloring composition according to 1] or [2].
[9]
The coloring composition according to [1] to [2] or [8], which comprises a compound represented by the formula (IZ2) and in which R ^{1Z2 is a hydrogen atom.}
[10]
Comprise a compound represented by formula ^{(IZ2), R 2Z2, R} 3Z2, R 4Z2, and at least one of R ^{5Z2 is, -CO-R 102Z2, -COO-} R 101Z2, -OCO-R 102Z2, -COCO- R ^102Z2 , ^{-OR 102Z2} , -SO ₂ -R ^101Z2 , -SO ₂ N (R ^102Z2 ) ₂ ^{, -CON} (R 102Z2) ₂ , -N (R ^102Z2 ) ₂ , -NHCO-R ^102Z2 , -NHCO -N (R ^102Z2 ) ₂ , -NHCOOR ^102Z2 , -OCON (R ^102Z2 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, number of carbon atoms which may have a substituent 1-40 hydrocarbon group or have a substituent is also heterocyclic group, or R ^2Z2 and R ^3Z2, R ^3Z2 and R ^4Z2, and at least one pair binding of R ^4Z2 and R ^5Z2 The coloring composition according to [1] to [2], [8] or [9] forming a ring.
[11]
Includes a compound represented by a formula ^{(IZ2), R 2Z2, R} 3Z2, R 4Z2, and at least one of R ^5Z2 is a nitro group or a tert- butyl group [1] to [2] or [8] to The coloring composition according to any one of [10].
[12]
The coloring composition according to [1] or [2], which comprises a compound represented by the formula (IZ3) and in which R ^1Z3 , R ^6Z3 and R ^{7Z3 are hydrogen atoms.}
[13]
Including the compound represented by the formula (IZ3), at least one of ^{R 2Z3} , R ^3Z3 , R ^4Z3 , and R ^{5Z3 is -CO-R 102Z3} , -COO-R ^101Z3 , -OCO-R ^102Z3 , -COCO-. R ^102Z3 , ^{-OR 102Z3} , -SO ₂ -R ^101Z3 , -SO ₂ N (R ^102Z3 ) ₂ ^{, -CON} (R 102Z3) ₂ , -N (R ^102Z3 ) ₂ , -NHCO-R ^102Z3 , -NHCO -N (R ^102Z3 ) ₂ , -NHCOOR ^102Z3 , -OCON (R ^102Z3 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, number of carbon atoms which may have a substituent It is a heterocyclic group that may have 1 to 40 hydrocarbon groups or substituents, or at least one set of ^{R 2Z3} and R ^3Z3 , R ^3Z3 and R ^4Z3 , and R ^4Z3 and R ^{5Z3 is bonded.} The coloring composition according to [1] to [2] or [12], which forms a ring.
[14]
It contains the compound represented by the formula (IZ3) ^{, and at least one of R 2Z3} , R ^3Z3 , R ^4Z3 , and R ^5Z3 is a nitro group or a tert-butyl group [1] to [2], [12] or The coloring composition according to [13].
[15]
The coloring composition according to any one of [1] to [14], which comprises both a resin and a solvent.
[16]
The coloring composition according to any one of [1] to [15], further comprising a yellow colorant or a green colorant.
[17]
The coloring composition according to any one of [1] to [16], and a coloring curable composition containing a polymerizable compound.
[18]
The color-curable composition according to [17], which further comprises a polymerization initiator.
[19]
A color filter formed from the coloring composition according to any one of [1] to [16] or the coloring curable composition according to [17] or [18].
[20]
A liquid crystal display device including the color filter according to [19].
[21]
A compound represented by the formula (IZ1-B).

[In the formula (IZ1-B),
^RO11Z1 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
R ^1Z1 , R ^21Z1 , R ^31Z1 , R ^41Z1 , R ^51Z1 , R ^61Z1 , and R ^71Z1 are independent of each other, hydrogen atom, -CO-R ^102Z1 , -COO-R ^101Z1 , -OCO-R ^102Z1 , -COCO. -R ^102Z1 , -O-R ^102Z1 , -SO ₂ -R ^101Z1 , -SO ₂ N (R ^102Z1 ) ₂ ^{, -CON} (R 102Z1) ₂ , -N (R ^102Z1 ) ₂ , -NHCO-R ^102Z1 ,- NHCO-N (R ^102Z1 ) ₂ , -NHCOOR ^102Z1 , -OCON (R ^102Z1 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, carbon which may have a substituent. Represents a heterocyclic group which may have a hydrocarbon group or a substituent of the number 1 to 40.
R ^21Z1 and R ^31Z1 , R ^31Z1 and R ^41Z1 , and R ^41Z1 and R ^51Z1 may be coupled to each other to form a ring, respectively.
However, at least one of ^{R 21Z1} , R ^31Z1 , R ^41Z1 , and R ^{51Z1 is -CO-R 102Z1} , -COO-R ^101Z1 , -OCO-R ^102Z1 , -COCO-R ^102Z1 , -O-R ^102Z1 , -SO ₂ -R ^101Z1 , -SO ₂ N (R ^102Z1 ) ₂ ^{, -CON} (R 102Z1) ₂ , -N (R ^102Z1 ) ₂ , -NHCO-R ^102Z1 , -NHCO-N (R ^102Z1 ) ₂ ,- NHCOOR ^102Z1 , -OCON (R ^102Z1 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, hydrocarbon group or substitution having 1 to 40 carbon atoms which may have a substituent. It is a heterocyclic group which may have a group, or ^{at least one set of R 21Z1} and R ^31Z1 , R ^31Z1 and R ^41Z1 , and R ^41Z1 and R ^51Z1 are bonded to form a ring.
R ^101Z1 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102Z1 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
M represents a hydrogen atom or an alkali metal atom.
When a ^{plurality of R 101Z1} , R ^{102 Z1} and M exist, they may be the same or different.
The wavy line represents an E-form or a Z-form. ]
[22]
The compound according to [21], wherein R ^1Z1 , R ^{61Z 1} and R ^{71Z 1 are hydrogen atoms.}
[23]
^{The compound according to [21] or [22], wherein RO11Z1} is a hydrocarbon group having 1 to 10 carbon atoms which may have a hydrogen atom or a substituent.
[24]
The compound according to any one of [21] to [23], wherein at least one of R ^21Z1 , R ^31Z1 , R ^41Z1 , and R ^{51Z1 is a nitro group or a tert-butyl group.}
[25]
A compound represented by the formula (IZ2-B).

[In the formula (IZ2-B),
R ^CO11Z2 and R ^CO21Z2 independently represent -O-R ^O1Z2 or -NR ^N1Z2 R ^N2Z2 , and at least one of ^{R CO11Z2} and R ^{CO21Z2 is -NR N1Z2} R ^N2Z2 .
R ^N1Z2 , R ^N2Z2 , R ^1Z2 , R ^21Z2 , R ^31Z2 , R ^41Z2 and R ^51Z2 are independent of each other, hydrogen atom, -CO-R ^102Z2 , -COO-R ^101Z2 , -OCO-R ^102Z2 , -COCO- R ^102Z2 , ^{-OR 102Z2} , -SO ₂ -R ^101Z2 , -SO ₂ N (R ^102Z2 ) ₂ ^{, -CON} (R 102Z2) ₂ , -N (R ^102Z2 ) ₂ , -NHCO-R ^102Z2 , -NHCO -N (R ^102Z2 ) ₂ , -NHCOOR ^102Z2 , -OCON (R ^102Z2 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, number of carbon atoms which may have a substituent ^{Represents a} heterocyclic group that may have 1 to 40 hydrocarbon groups or substituents, R 21Z2 and R ^31Z2 , R ^31Z2 and R ^41Z2 , and R ^41Z2 and R ^51Z2 , respectively, bonded to each other to form a ring. May be formed,
At ^{least one of R 21Z2} , R ^31Z2 , R ^41Z2 and R ^51Z2 is -CO-R ^102Z2 , -COO-R ^101Z2 , -OCO-R ^102Z2 , -COCO-R ^102Z2 , -O-R ^102Z2 , -SO ₂ -R ^101Z2 , -SO ₂ N (R ^102Z2 ) ₂ ^{, -CON} (R 102Z2) ₂ , -N (R ^102Z2 ) ₂ , -NHCO-R ^102Z2 , -NHCO-N (R ^102Z2 ) ₂ , -NHCOOR ^102Z2 , -OCON (R ^102Z2 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, having a hydrocarbon group or substituent having 1 to 40 carbon atoms which may have a substituent. It may be a heterocyclic group, or ^{at least one set of R 21Z2} and R ^31Z2 , R ^31Z2 and R ^41Z2 , and R ^41Z2 and R ^51Z2 are bonded to form a ring.
R ^101Z2 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
^RO1Z2 and ^R102Z2 represent a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent, independently of each other.
M represents a hydrogen atom or an alkali metal atom.
When a ^{plurality of} R O1Z2, R ^N1Z2 , R ^N2Z2 , R ^101Z2 , R ^102Z2 and M exist, they may be the same or different.
The wavy line represents an E-form or a Z-form. ]
[26]
^{The compound according to [25], wherein RO1Z2} , ^RN1Z2 and ^RN2Z2 are hydrocarbon groups having 1 to 10 carbon atoms which may have a hydrogen atom or a substituent.
[27]
The compound according to [25] or [26], wherein R ^{1Z2 is a hydrogen atom.}
[28]
The compound according to any one of [25] to [27], wherein at least one of R ^21Z2 , R ^31Z2 , R ^41Z2 and R ^{51Z2 is a nitro group or a tert-butyl group.}
[29]
A compound represented by the formula (IZ3-B).

[In the formula (IZ3-B),
R ^1Z3 , R ^21Z3 , R ^31Z3 , R ^41Z3 , R ^51Z3 , R ^61Z3 , and R ^71Z3 are independent of each other, hydrogen atom, -CO-R ^102Z3 , -COO-R ^101Z3 , -OCO-R ^102Z3 , -COCO. -R ^102Z3 , -O-R ^102Z3 , -SO ₂ -R ^101Z3 , -SO ₂ N (R ^102Z3 ) ₂ ^{, -CON} (R 102Z3) ₂ , -N (R ^102Z3 ) ₂ , -NHCO-R ^102Z3 ,- NHCO-N (R ^102Z3 ) ₂ , -NHCOOR ^102Z3 , -OCON (R ^102Z3 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, carbon which may have a substituent Represents a heterocyclic group which may have a hydrocarbon group or a substituent of the number 1 to 40.
R ^21Z3 and R ^31Z3 , R ^31Z3 and R ^41Z3 , and R ^41Z3 and R ^51Z3 may be combined with each other to form a ring, respectively.
However, at least one of ^{R 21Z3} , R ^31Z3 , R ^41Z3 , and R ^{51Z3 is -CO-R 102Z3} , -COO-R ^101Z3 , -OCO-R ^102Z3 , -COCO-R ^102Z3 , -O-R ^102Z3 , −SO ₂ −R ^101Z3 , −SO ₂ N (R ^102Z3 ) ₂ ^{, −CON} (R 102Z3) ₂ , −N (R ^102Z3 ) ₂ , −NHCO-R ^102Z3 , −NHCO-N (R ^102Z3 ) ₂ , − NHCOOR ^102Z3 , -OCON (R ^102Z3 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, hydrocarbon group or substitution having 1 to 40 carbon atoms which may have a substituent. It is a heterocyclic group which may have a group, or ^{at least one set of R 21Z3} and R ^31Z3 , R ^31Z3 and R ^41Z3 , and R ^41Z3 and R ^51Z3 are bonded to form a ring.
R ^101Z3 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102Z3 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
M represents a hydrogen atom or an alkali metal atom.
When a ^{plurality of R 101Z3} , R ^102Z3 and M are present, they may be the same or different.
The wavy line represents an E-form or a Z-form. ]
[30]
The compound according to [29], wherein R ^1Z3 , R ^61Z3 and R ^{71Z3 are hydrogen atoms.}
[31]
The compound according to [29] or [30], wherein at least one of R ^21Z3 , R ^31Z3 , R ^41Z3 , and R ^{51Z3 is a nitro group or a tert-butyl group.}
[32]
A compound represented by the formula (IZ4).

[In formula (IZ4),
R ^N1Z4 and R ^N2Z4 are independent of each other, -CO-R ^102Z4 , -COO-R ^101Z4 , -OCO-R ^102Z4 , -COCO-R ^102Z4 , ^{-OR 102Z4} , -SO _2- R ^101Z4 , -SO. ₂ N (R ^102Z4 ) ₂ ^{, -CON} (R 102Z4) ₂ , -N (R ^102Z4 ) ₂ , -NHCO-R ^102Z4 , -NHCO-N (R ^102Z4 ) ₂ , -NHCOOR ^102Z4 , -OCON (R ^102Z4 ) ₂ , Halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, may have a substituent or a hydrocarbon group having 1 to 40 carbon atoms or a complex which may have a substituent. Represents a ring group.
R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , and R ^7Z4 are independent of each other, hydrogen atom, -CO-R ^102Z4 , -COO-R ^101Z4 , -OCO-R ^102Z4 , -COCO. -R ^102Z4 , -O-R ^102Z4 , -SO ₂ -R ^101Z4 , -SO ₂ N (R ^102Z4 ) ₂ ^{, -CON} (R 102Z4) ₂ , -N (R ^102Z4 ) ₂ , -NHCO-R ^102Z4 ,- NHCO-N (R ^102Z4 ) ₂ , -NHCOOR ^102Z4 , -OCON (R ^102Z4 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, carbon which may have a substituent Represents a heterocyclic group which may have a hydrocarbon group or a substituent of the number 1 to 40.
R ^{2Z 4} and R ^{3Z 4} , R ^{3Z 4} and R ^{4Z 4} , and R 4 ^{Z 4} and R 5 ^{Z 4} may be coupled to each other to form a ring, respectively.
R ^101Z4 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102Z4 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
M represents a hydrogen atom or an alkali metal atom.
When a ^{plurality of R 101Z4} , R ^102Z4 and M are present, they may be the same or different.
The wavy line represents an E-form or a Z-form. ]
[33]
The compound according to [32], wherein R ^1Z4 , R ^6Z4 and R ^{7Z4 are hydrogen atoms.}
[34]
^{The compound according to [32] or [33], wherein RN1Z4} and ^RN2Z4 are hydrocarbon groups having 1 to 10 carbon atoms which may have substituents independently of each other.
[35]
At ^{least one of R 2Z4} , R ^3Z4 , R ^4Z4 , and R ^5Z4 is -CO-R ^102Z4 , -COO-R ^101Z4 , -OCO-R ^102Z4 , COCO-R ^102Z4 , -O-R ^102Z4 , -SO _2- R ^101Z4 , -SO ₂ N (R ^102Z4 ) ₂ ^{, -CON} (R 102Z4) ₂ , -N (R ^102Z4 ) ₂ , -NHCO-R ^102Z4 , -NHCO-N (R ^102Z4 ) ₂ , -NHCOOR ^102Z4 ,- OCON (R ^102Z4 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, having a hydrocarbon group or substituent having 1 to 40 carbon atoms which may have a substituent. It is a heterocyclic group that may be present, or ^{at least one set of R 2Z4} and R ^3Z4 , R ^3Z4 and R ^4Z4 , and R ^4Z4 and R ^5Z4 are bonded to form a ring [32] to [34]. ] The compound according to any one of.
[36]
The compound according to any one of [32] to [35], wherein at least one of R ^2Z4 , R ^3Z4 , R ^4Z4 , and R ^{5Z4 is a nitro group or a tert-butyl group.}
[37]
A compound represented by the formula (IZ5).

[In formula (IZ5),
R ^N1Z5 is -CO-R ^102Z5 , -COO-R ^101Z5 , -OCO-R ^102Z5 , -COCO-R ^102Z5 , -O-R ^102Z5 , -SO _2- R ^101Z5 , -SO ₂ N (R ^102Z5 ) ₂ ^{, -CON} (R 102Z5) ₂ , -N (R ^102Z5 ) ₂ , -NHCO-R ^102Z5 , -NHCO-N (R ^102Z5 ) ₂ , -NHCOOR ^102Z5 , -OCON (R ^102Z5 ) ₂ , halogen atom, cyano group , Nitro group, -SO ₃ M, -CO ₂ M, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
^{R 1Z5, R 2Z5, R 3Z5} , R 4Z5, R 5Z5, R 6Z5, and R ^7Z5, independently of each other, hydrogen ^{atom, -CO-R 102Z5, -COO-} R 101Z5, -OCO-R 102Z5, -COCO -R ^102Z5 , -O-R ^102Z5 , -SO ₂ -R ^101Z5 , -SO ₂ N (R ^102Z5 ) ₂ ^{, -CON} (R 102Z5) ₂ , -N (R ^102Z5 ) ₂ , -NHCO-R ^102Z5 ,- NHCO-N (R ^102Z5 ) ₂ , -NHCOOR ^102Z5 , -OCON (R ^102Z5 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, carbon which may have a substituent ^{Represents a} heterocyclic group which may have a hydrocarbon group or a substituent of the number 1 to 40, and R 2Z5 and R ^3Z5 , R ^3Z5 and R ^4Z5 , and R ^4Z5 and R ^5Z5 are bonded to each other and ring, respectively. , ^And at least one of ^{R 2Z5} , R ^3Z5 , R ^4Z5 and R ^{5Z5 is -CO-R 102Z5} , -COO-R ^101Z5 , -OCO-R ^102Z5 , -COCO-R ^102Z5 , -O. -R ^102Z5 , -SO ₂ -R ^101Z5 , -SO ₂ N (R ^102Z5 ) ₂ ^{, -CON} (R 102Z5) ₂ , -N (R ^102Z5 ) ₂ , -NHCO-R ^102Z5 , -NHCO-N (R ^102Z5) ) ₂ , -NHCOOR ^102Z5 , -OCON (R ^102Z5 ) ₂ , Halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, hydrocarbon with 1 to 40 carbon atoms which may have a substituent It is a heterocyclic group that may have a hydrogen group or a substituent, or ^{at least one set of R 2Z5} and R ^3Z5 , R ^3Z5 and R ^4Z5 , and R ^4Z5 and R ^5Z5 are bonded to form a ring. doing.
R ^101Z5 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102Z5 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
M represents a hydrogen atom or an alkali metal atom.
When a ^{plurality of R 101Z5} , R ^102Z5 and M are present, they may be the same or different.
The wavy line represents an E-form or a Z-form. ]
[38]
^{The compound according to [37], wherein RN1Z5} is a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent.
[39]
R ^1Z5, R ^6Z5 and R ^7Z5 A compound according to a hydrogen atom [37] or [38].
[40]
The compound according to any one of [37] to [39], wherein at least one of R ^2Z5 , R ^3Z5 , R ^4Z5 , and R ^{5Z5 is a nitro group or a tert-butyl group.}
[41]
A compound represented by the formula (IZ6).

[In formula (IZ6),
D represents a structure having an isoindoline skeleton.
Z is, -SO ₃ ^- represents a ^- or -CO _2.
A ^{c +} represents a c-valent metal cation.
a represents an integer of 1 to 10.
b represents an integer of 1 or more.
c represents an integer of 2 to 10.
d represents an integer of 1 or more.
When a plurality of D, Z, a or ^{Ac +} exist, they may be the same or different from each other.
The formula (I'Z6) and the formula (I''Z6) represent the partial structure of the formula (IZ6), respectively, and D, Z, Ac ⁺ , a, b, c and d are those in the formula (IZ6). Represents the same thing as.
However, the absolute value of the negative valence of the substructure represented by the formula (I'Z6) and the positive valence of the substructure represented by the formula (I ″ Z6) are the same. ]
[42]
The compound according to [41], wherein the compound represented by the formula (IZ6) is a compound represented by the formula (IZ6-A).

[In the formula (IZ6-A),
A ^{c +} , b, c and d have the same meanings as described above.
R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 and R ^13AZ6 are independent of each other, hydrogen atom, -CO-R ^102AZ6 , -COO-R ^101AZ6 , -OCO- R ^102AZ6 , -COCO-R ^102AZ6 , ^{-OR 102AZ6} , -SO _2- R ^101AZ6 , -SO ₂ N (R ^102AZ6 ) ₂ ^{, -CON} (R 102AZ6) ₂ , -N (R ^102AZ6 ) ₂ , -NHCO ^{-R 102AZ6, -NHCO-N (R} 102AZ6) 2, -NHCOOR 102AZ6, -OCON (R 102AZ6) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , -SO 3 -, -CO ₂ ^-, a hydrocarbon group or optionally substituted heterocyclic group having carbon atoms of 1 to 40 which may have a substituent.
R ^2AZ6 and R ^3AZ6 , R ^3AZ6 and R ^4AZ6 , R ^4AZ6 and R ^5AZ6 , ^RAA1Z6 and ^RAA2Z6 and R ^12AZ6 and R ^13AZ6 may be bonded to each other to form a ring, respectively.
R ^101AZ6 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent independently of each other.
R ^102AZ6 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent, independently of each other.
M represents a hydrogen atom or an alkali metal atom.
Formulas (IZ6-A') and formulas (IZ6-A'') represent substructures of formula (IZ6-A), respectively, Ac ⁺ , b, c, d, R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 ,
R ^AA2Z6 , R ^12AZ6 and R ^13AZ6 represent the same as in formula (IZ6-A).
If there are multiple R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 , R ^102AZ6 , M, c or ^{Ac +} , they are the same. It may be present or different.
R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6 are at least one of (ra-i) to (ra-iii). and fulfill ^{the, R 1AZ6, R 2AZ6, R} 3AZ6, R 4AZ6, R 5AZ6, R AA1Z6, R AA2Z6, R 12AZ6, R 13AZ6, R 101AZ6 and -SO ₃ R ^102AZ6 has ^- or -CO ₂ ^- of The total number is a.
At least one ^{(ra-i) R 1AZ6,} R 2AZ6, R 3AZ6, R 4AZ6, R 5AZ6, R AA1Z6, R AA2Z6, R 12AZ6 and R ^13AZ6 is, -SO ₃ ^- or -CO ₂ ^- a.
^(Ra -ii) At least one of R 1AZ6, R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 and R ^13AZ6 is -CO-R ^102AZ6 , -COO-R ^101AZ6 , -OCO. -R ^102AZ6 , -COCO-R ^102AZ6 , -O-R ^102AZ6 , -SO ₂ -R ^101AZ6 , -SO ₂ N (R ^102AZ6 ) ₂ ^{, -CON} (R 102AZ6) ₂ , -N (R ^102AZ6 ) ₂ ,- ^{NHCO-R 102AZ6, -NHCO-N} (R 102AZ6) 2, -NHCOOR 102AZ6, or -OCON (R ^102AZ6) a _2, wherein R ^101AZ6 and R ^102AZ6 is, -SO ₃ ^- having ^- or -CO ₂ hydrocarbon group or a -SO ₃ having 1 to 40 carbon atoms ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
^{(Ra-iii) R 1AZ6,} R 2AZ6, R 3AZ6, R 4AZ6, R 5AZ6, at least one of R ^AA1Z6, R ^AA2Z6, R ^12AZ6 and R ^13AZ6 is, -SO ₃ ^- or -CO ₂ ^- carbons having 1 40 hydrocarbon group or -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group and heterocyclic group, -SO ₃ ^- or -CO ₂ ^- may have other substituents.
a represents the same meaning as in the equation (IZ6). When a plurality of a exist, they may be the same or different.
The absolute value of the negative valence of the substructure represented by the formula (IZ6-A') and the positive valence of the substructure represented by the formula (IZ6-A'') are the same.
The wavy line represents an E-form or a Z-form. ]
[43]
The compound according to [42], wherein the compound represented by the formula (IZ6-A) is a compound represented by the formula (IZ6-B).

[In the formula (IZ6-B),
A ^{c +} , b, c, d and wavy lines have the same meanings as described above.
L ¹ is, -CO- or -SO ₂ - represents a.
R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 and R ^13BZ6 are independent of each other, hydrogen atom, -CO-R ^102BZ6 , -COO-R ^101BZ6 , -OCO-R ^102BZ6 , -COCO-R ^102BZ6 , -O-R ^102BZ6 , -SO _2- R ^101BZ6 , -SO ₂ N (R ^102BZ6 ) ₂ ^{, -CON} (R 102BZ6) ₂ , -N (R ^102BZ6 ) ₂ , -NHCO-R ^{102BZ6 , -NHCO-N (R 102BZ6)} 2, -NHCOOR 102BZ6, -OCON (R 102BZ6) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , -SO 3 -, -CO 2 ^—— Represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^2BZ6 and R ^3BZ6 , R ^3BZ6 and R ^4BZ6 , R ^4BZ6 and R ^5BZ6 , and R ^12BZ6 and R ^13BZ6 may be coupled to each other to form a ring, respectively.
R ^101BZ6 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent independently of each other.
R ^102BZ6 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent, independently of each other.
Formulas (IZ6-B') and formulas (IZ6-B'') represent the substructures of formula (IZ6-B), respectively, Ac ⁺ , b, c, d, R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 , R ^13BZ6 and L ¹ represent the same as those in the equation (IZ6-B).
M represents the same meaning as described above.
If there are multiple R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 , R ^13BZ6 , R ^101BZ6 , R ^102BZ6 , L ¹ , M, c or ^{Ac +} , they are the same. It may be present or different.
R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 , R ^13BZ6 , R ^101BZ6 and R ^102BZ6 satisfy at least one of (rb-i) to (rb-iii). ^{and, R 1BZ6, R 2BZ6, R} 3BZ6, R 4BZ6, R 5BZ6, R 11BZ6, R 12BZ6, R 13BZ6, R 101BZ6 and -SO ₃ R ^102BZ6 has ^- or -CO ₂ ^- total number of is a ..
At least one ^{(rb-i) R 1BZ6,} R 2BZ6, R 3BZ6, R 4BZ6, R 5BZ6, R 11BZ6, R 12BZ6 and R ^13BZ6 is, -SO ₃ ^- or -CO ₂ ^- a.
^(Rb -ii) At least one of R 1BZ6, R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 and R ^13BZ6 is -CO-R ^102BZ6 , -COO-R ^101BZ6 , -OCO-R ^102BZ6. , -COCO-R ^102BZ6 , -O-R ^102BZ6 , -SO _2- R ^101BZ6 , -SO ₂ N (R ^102BZ6 ) ₂ , or ^-CON (R 102BZ6) ₂ , -N (R ^102BZ6 ) ₂ , -NHCO- R ^102BZ6 , -NHCO-N (R ^102BZ6 ) ₂ , -NHCOOR ^102BZ6 , or -OCON (R ^102BZ6 ) ₂ .
The R ^101BZ6 and R ^102BZ6 is, -SO ₃ ^- or -CO ₂ ^- 1 to 40 carbon atoms having a hydrocarbon group or a -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
At least one ^{(rb-iii) R 1BZ6,} R 2BZ6, R 3BZ6, R 4BZ6, R 5BZ6, R 11BZ6, R 12BZ6 and R ^13BZ6 is, -SO ₃ ^- 1 to 40 carbon atoms having a ^- or -CO ₂ hydrocarbon group or a -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
a represents the same meaning as in the formula (IZ6-A). When a plurality of a exist, they may be the same or different.
The absolute value of the negative valence of the substructure represented by the formula (IZ6-B') and the positive valence of the substructure represented by the formula (IZ6-B ″) are the same. ]
[44]
The compound according to [43], wherein L ^{1 is −CO−.}
[45]
R ^11BZ6 is an aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a phenyl group which may have a substituent, a naphthyl group which may have a substituent, and a substituent. A tetrahydronaphthyl group which may have a group, a thienyl group which may have a substituent, a frill group which may have a substituent, or a pyridinyl group which may have a substituent [. 43] or the compound according to [44].
[46]
The compound according to [43], wherein the compound represented by the formula (IZ6-B) is a compound represented by the formula (IZ6-C).

[In the formula (IZ6-C),
A ^{c +} , b, c, d, L ¹ and wavy lines have the same meanings as described above.
L ² is, -CO- or -SO ₂ - represents a.
R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 and R ^14CZ6 are independent of each other, hydrogen atom, -CO-R ^102CZ6 , -COO-R ^101CZ6 , -OCO-R ^102CZ6 , -COCO- R ^102CZ6 , ^{-OR 102CZ6} , -SO ₂ -R ^101CZ6 , -SO ₂ N (R ^102CZ6 ) ₂ ^{, -CON} (R 102CZ6) ₂ , -N (R ^102CZ6 ) ₂ , -NHCO-R ^102CZ6 , -NHCO _{^{-N (R 102CZ6) 2, -NHCOOR}} 102CZ6, -OCON (R 102CZ6) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , -SO 3 -, -CO 2 -, substituted It represents a hydrocarbon group having 1 to 40 carbon atoms which may have a group or a heterocyclic group which may have a substituent.
R ^2CZ6 and R ^3CZ6 , R ^3CZ6 and R ^4CZ6 , and R ^4CZ6 and R ^5CZ6 may be bonded to each other to form a ring, respectively.
R ^101CZ6 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent independently of each other.
R ^102CZ6 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent, independently of each other.
M represents the same meaning as described above.
Formulas (IZ6-C') and formulas (IZ6-C'') represent the substructures of formula (IZ6-C), respectively, Ac ⁺ , b, c, d, R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 , R ^14CZ6 , L ¹ and L ² represent the same as those in the equation (IZ6-C).
If there are multiple R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 , R ^14CZ6 , R ^101CZ6 , R ^102CZ6 , L ¹ , L ² , M, c or ^{Ac +} , they are the same. It may be present or different.
R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 , R ^14CZ6 , R ^101CZ6 and R ^102CZ6 satisfy at least one of (rc-i) to (rc-iii). ^{R 1CZ6, R 2CZ6, R 3CZ6} , R 4CZ6, R 5CZ6, R 11CZ6, R 14CZ6, R 101CZ6 and -SO ₃ R ^102CZ6 has ^- or -CO ₂ ^- total number of is a.
At least one ^{(rc-i) R 1CZ6,} R 2CZ6, R 3CZ6, R 4CZ6, R 5CZ6, R 11CZ6 and R ^14CZ6 is, -SO ₃ ^- or -CO ₂ ^- a.
(Rc-ii) At ^{least one of R 1CZ6} , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 and R ^14CZ6 is -CO-R ^102CZ6 , -COO-R ^101CZ6 , -OCO-R ^102CZ6 , -COCO -R ^102CZ6 , -O-R ^102CZ6 , -SO ₂ -R ^101CZ6 , -SO ₂ N (R ^102CZ6 ) ₂ ^{, -CON} (R 102CZ6) ₂ , -N (R ^102CZ6 ) ₂ , -NHCO-R ^102CZ6 ,- _{^{NHCO-N (R 102CZ6) 2}} , -NHCOOR 102CZ6, or -OCON (R ^102CZ6) a _2, wherein R ^101CZ6 and R ^102CZ6 is, -SO ₃ ^- 1 to 40 carbon atoms having a ^- or -CO ₂ hydrocarbon group or a -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
^{(Rc-iii) R 1CZ6,} R 2CZ6, R 3CZ6, R 4CZ6, at least one of R ^5CZ6, R ^11CZ6 and R ^14CZ6 is, -SO ₃ ^- or -CO ₂ ^- Number 1-40 hydrocarbon group having a carbon having or -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
a represents the same meaning as in the formula (IZ6-B). When a plurality of a exist, they may be the same or different.
The absolute value of the negative valence of the substructure represented by the formula (IZ6-C') and the positive valence of the substructure represented by the formula (IZ6-C ″) are the same. ]
[47]
The compound according to [46], wherein R ^11CZ6 and R ^14CZ6 are the same group, and L ¹ and L ^{2 are the same group.}
[48]
The compound according to [46] or [47], wherein L ¹ and L ^{2 are −CO−.}
[49]
R ^11CZ6 and R ^14CZ6 have an aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a phenyl group which may have a substituent, and a naphthyl which may have a substituent. A group, a tetrahydronaphthyl group which may have a substituent, a thienyl group which may have a substituent, a frill group which may have a substituent or a pyridinyl group which may have a substituent. The compound according to any one of [46] to [48].
[50]
The compound according to [43], wherein the compound represented by the formula (IZ6-B) is a compound represented by the formula (IZ6-D).

[In the formula (IZ6-D),
A ^{c +} , b, c, d, L ¹ and wavy lines have the same meanings as described above.
R ^20DZ6 and R ^30DZ6 combine to form ring Q.
Ring Q may have a substituent and has 5 to 7 ring members, and the ring Q may be a hydrocarbon ring or a heterocycle. Ring Q is condensed with a monocycle selected from a hydrocarbon ring and a heterocycle, which may have a substituent having 5 to 7 ring members, or a condensed ring obtained by condensing two or more of the monocycles. You may.
R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 and R ^11DZ6 are independent of each other, hydrogen atom, -CO-R ^102DZ6 , -COO-R ^101DZ6 , -OCO-R ^102DZ6 , -COCO-R ^102DZ6 , -O-R ^102DZ6 , -SO ₂ -R ^101DZ6 , -SO ₂ N (R ^102DZ6 ) ₂ ^{, -CON} (R 102DZ6) ₂ , -N (R ^102DZ6 ) ₂ , -NHCO-R ^102DZ6 , -NHCO-N ( _{^{R 102DZ6) 2, -NHCOOR 102DZ6,}} -OCON (R 102DZ6) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , -SO 3 -, -CO 2 -, have a substituent It represents a hydrocarbon group having 1 to 40 carbon atoms or a heterocyclic group which may have a substituent.
R ^2DZ6 and R ^3DZ6 , R ^3DZ6 and R ^4DZ6 , and R ^4DZ6 and R ^5DZ6 may be coupled to each other to form a ring, respectively.
R ^101DZ6 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent independently of each other.
R ^102DZ6 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent, independently of each other.
M represents the same meaning as described above.
Formulas (IZ6-D') and formulas (IZ6-D'') represent the substructures of formula (IZ6-D), respectively, Ac ⁺ , b, c, d, R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 , R ^11DZ6 , R ^20DZ6 , R ^30DZ6 and L ¹ represent the same as those in the equation (IZ6-D).
If there are multiple R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 , R ^11DZ6 , R ^101DZ6 , R ^102DZ6 , L ¹ , M, R ^20DZ6 , R ^30DZ6 , ring Q, c or ^{Ac +, they are} They may be the same or different.
R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 , R ^11DZ6 , R ^101DZ6 , R ^102DZ6 and ring Q satisfy at least one of (rd-i) to (rd-iv). ^{R 1DZ6, R 2DZ6, R 3DZ6} , R 4DZ6, R 5DZ6, R 11DZ6, R 101DZ6, R 102DZ6 and -SO ₃ having the ring Q ^- or -CO ₂ ^- total number of is a.
At least one ^{(rd-i) R 1DZ6,} R 2DZ6, R 3DZ6, R 4DZ6, R 5DZ6 and R ^11DZ6 is, -SO ₃ ^- or -CO ₂ ^- a.
^(Rd -ii) At least one of R 1DZ6, R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 and R ^11DZ6 is -CO-R ^102DZ6 , -COO-R ^101DZ6 , -OCO-R ^102DZ6 , -COCO-R ^102DZ6. , ^{-OR 102DZ6} , -SO ₂ -R ^101DZ6 , -SO ₂ N (R ^102DZ6 ) ₂ ^{, -CON} (R 102DZ6) ₂ , -N (R ^102DZ6 ) ₂ , -NHCO-R ^102DZ6 , -NHCO-N _{^{(R 102DZ6) 2, -NHCOOR 102DZ6}} , or -OCON (R ^102DZ6) a _2, wherein R ^101DZ6 and R ^102DZ6 is, -SO ₃ ^- or -CO ₂ ^- number 1-40 hydrocarbon group having a carbon having or -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
^{(Rd-iii) R 1DZ6,} R 2DZ6, R 3DZ6, R 4DZ6, at least one of R ^5DZ6 and R ^11DZ6 is, -SO ₃ ^- or -CO ₂ ^- hydrocarbon radical or -SO having 1 to 40 carbon atoms having a ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
(Rd-iv) ring Q is, -SO ₃ ^- or -CO ₂ ^- a with represents the same meaning as in formula (IZ6-B). When a plurality of a exist, they may be the same or different.
The absolute value of the negative valence of the substructure represented by the formula (IZ6-D') and the positive valence of the substructure represented by the formula (IZ6-D ″) are the same. ]
[51]
The compound according to [50], wherein L ^{1 is −CO−.}
[52]
R ^11DZ6 is an aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a phenyl group which may have a substituent, a naphthyl group which may have a substituent, and a substituent. A tetrahydronaphthyl group which may have a group, a thienyl group which may have a substituent, a frill group which may have a substituent, or a pyridinyl group which may have a substituent [. 50] or the compound according to [51].
[53]
The compound according to [50], wherein the compound represented by the formula (IZ6-D) is a compound represented by the formula (IZ6-E).

[In the formula (IZ6-E),
A ^{c +} , b, c, d, L ¹ and wavy lines have the same meanings as described above.
R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 and R ^11EZ6 are independent of each other, hydrogen atom, -CO-R ^102EZ6 , -COO-R ^101EZ6 , -OCO-R ^102EZ6 , -COCO-R ^102EZ6 , -O-R ^102EZ6 , -SO _2- R ^101EZ6 , -SO ₂ N (R ^102EZ6 ) ₂ ^{, -CON} (R 102EZ6) ₂ , -N (R ^102EZ6 ) ₂ , -NHCO-R ^{102EZ6 , -NHCO-N (R 102EZ6)} 2, -NHCOOR 102EZ6, -OCON (R 102EZ6) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , -SO 3 -, -CO 2 ^—— Represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^2EZ6 and R ^3EZ6 , R ^3EZ6 and R ^4EZ6 , and R ^4EZ6 and R ^5EZ6 may be bonded to each other to form a ring, respectively.
R ^101EZ6 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent independently of each other.
R ^102EZ6 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent, independently of each other.
M represents the same meaning as described above.
Formulas (IZ6-E') and formulas (IZ6-E'') represent the substructures of formula (IZ6-E), respectively, Ac ⁺ , b, c, d, R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 , R ^11EZ6 and L ¹ represent the same as those in the equation (IZ6-E).
If there are multiple R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 , R ^11EZ6 , R ^101EZ6 , R ^102EZ6 , L ¹ , M, c or ^{Ac +} , they are the same. It may be present or different.
R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 , R ^11EZ6 , R ^101EZ6 and R ^102EZ6 satisfy at least one of (re-i) to (re-iii). ^{and, R 1EZ6, R 2EZ6, R} 3EZ6, R 4EZ6, R 5EZ6, R 6EZ6, R 7EZ6, R 11EZ6, R 101EZ6 and -SO ₃ R ^102EZ6 has ^- or -CO ₂ ^- total number of is a in ..
At least one of ^{(re-i) R 1EZ6,} R 2EZ6, R 3EZ6, R 4EZ6, R 5EZ6, R 6EZ6, R 7EZ6 and R ^11EZ6 is, -SO ₃ ^- or -CO ₂ ^- a.
(Re-ii) At ^{least one of R 1EZ6} , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 and R ^11EZ6 is -CO-R ^102EZ6 , -COO-R ^101EZ6 , -OCO-R ^102EZ6. , -COCO-R ^102EZ6 , -O-R ^102EZ6 , -SO ₂ -R ^101EZ6 , -SO ₂ N (R ^102EZ6 ) ₂ ^{, -CON} (R 102EZ6) ₂ , -N (R ^102EZ6 ) ₂ , -NHCO-R ^{102EZ6, -NHCO-N (R 102EZ6} ) 2, -NHCOOR 102EZ6, or -OCON a (R ^102EZ6) _2, wherein R ^101EZ6 and R ^102EZ6 is, -SO ₃ ^- or -CO ₂ ^- carbons having 1 40 hydrocarbon group or -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
At least one of ^{(re-iii) R 1EZ6,} R 2EZ6, R 3EZ6, R 4EZ6, R 5EZ6, R 6EZ6, R 7EZ6 and R ^11EZ6 is, -SO ₃ ^- 1 to 40 carbon atoms having a ^- or -CO ₂ hydrocarbon group or a -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
a represents the same meaning as in the formula (IZ6-D). When a plurality of a exist, they may be the same or different.
The absolute value of the negative valence of the substructure represented by the formula (IZ6-E') and the positive valence of the substructure represented by the formula (IZ6-E ″) are the same. ]
[54]
The compound according to [53], wherein L ^{1 is −CO−.}
[55]
R ^11EZ6 is an aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a phenyl group which may have a substituent, a naphthyl group which may have a substituent, and a substituent. A tetrahydronaphthyl group which may have a group, a thienyl group which may have a substituent, a frill group which may have a substituent, or a pyridinyl group which may have a substituent [. 53] or the compound according to [54].

According to the present invention, there are provided coloring compositions and compounds that can be used for forming color filters having a small retardation value.

The coloring composition of the present invention may be a compound represented by the formula (IZ1) (hereinafter, may be referred to as a compound (IZ1)) or a compound represented by the formula (IZ2) (hereinafter, may be referred to as a compound (IZ2)). (Yes), a compound represented by the formula (IZ3) (hereinafter, may be referred to as a compound (IZ3)), a compound represented by the formula (IZ4) (hereinafter, may be referred to as a compound (IZ4)), a formula (hereinafter, may be referred to as a compound (IZ4)). One or more selected from a compound represented by IZ5) (hereinafter, may be referred to as compound (IZ5)) and a compound represented by the formula (IZ6) (hereinafter, may be referred to as compound (IZ6)). , Compound (Z)), and at least one of a resin (hereinafter, may be referred to as resin (B)) and a solvent (hereinafter, may be referred to as solvent (E)).

The compound (IZ1), compound (IZ2), compound (IZ3), compound (IZ4), compound (IZ5), and compound (IZ6) also include their tautomers and salts thereof, respectively.
The compound (IZ1), the compound (IZ2), the compound (IZ3), the compound (IZ4), the compound (IZ5), and the compound (IZ6) can be used as colorants, respectively.
The coloring composition of the present invention may contain one or more compounds (IZ1), or may contain one or more compounds (IZ2). Two or more kinds of compounds (IZ3) may be contained, one kind or two or more kinds of compounds (IZ4) may be contained, and one kind or two or more kinds of compounds (IZ5) are contained. It may contain one kind or two or more kinds of compounds (IZ6).
When the coloring composition of the present invention contains one or more selected from the compound (IZ1), the compound (IZ2), and the compound (IZ3), it is preferable that the coloring composition contains the resin (B).
When the coloring composition of the present invention contains one or more selected from the compound (IZ4), the compound (IZ5), and the compound (IZ6), it is preferable that the solvent (E) is always contained.
When the coloring composition of the present invention contains a solvent, the compound (IZ1), the compound (IZ2), the compound (IZ3), the compound (IZ4), the compound (IZ5), and the compound (IZ6) are dispersed in the solvent (E). Is preferable.

When the coloring composition of the present invention contains a compound (IZ1), the coloring composition may be referred to as a colorant other than the compound (IZ1) (hereinafter, a colorant (A1Z1). In the following, the compound (IZ1) and The colorant (A1Z1) may be generically referred to as "colorant (AZ1)"). The colorant (A1Z1) may contain one or more colorants.
When the coloring composition of the present invention contains a compound (IZ2), the coloring composition may be referred to as a colorant other than the compound (IZ2) (hereinafter, a colorant (A1Z2). In the following, the compound (IZ2) and The colorant (A1Z2) may be generically referred to as "colorant (AZ2)"). The colorant (A1Z2) may contain one or more colorants.
When the coloring composition of the present invention contains a compound (IZ3), the coloring composition may be referred to as a colorant other than the compound (IZ3) (hereinafter, a colorant (A1Z3). In the following, the compound (IZ3) and The colorant (A1Z3) may be generically referred to as "colorant (AZ3)"). The colorant (A1Z3) may contain one or more colorants.
When the coloring composition of the present invention contains a compound (IZ4), the coloring composition may be referred to as a colorant other than the compound (IZ4) (hereinafter, a colorant (A1Z4). In the following, the compound (IZ4) and The colorant (A1Z4) may be generically referred to as "colorant (AZ4)"). The colorant (A1Z4) may contain one or more colorants.
When the coloring composition of the present invention contains a compound (IZ5), the coloring composition may be referred to as a colorant other than the compound (IZ5) (hereinafter, a colorant (A1Z5). In the following, the compound (IZ5) and The colorant (A1Z5) may be generically referred to as "colorant (AZ5)"). The colorant (A1Z5) may contain one or more colorants.
When the coloring composition of the present invention contains a compound (IZ6), the coloring composition may be referred to as a colorant other than the compound (IZ6) (hereinafter, a colorant (A1Z6). In the following, the compound (IZ6) and The colorant (A1Z6) may be generically referred to as "colorant (AZ6)"). The colorant (A1Z6) may contain one or more colorants.
One or more selected from a colorant (A1Z1), a colorant (A1Z2), a colorant (A1Z3), a colorant (A1Z4), a colorant (A1Z5), and a colorant (A1Z6) are hereinafter referred to as colorants (ZZ). ). The colorant (ZZ) preferably contains a yellow colorant or a green colorant.
One or more selected from a colorant (AZ1), a colorant (AZ2), a colorant (AZ3), a colorant (AZ4), a colorant (AZ5), and a colorant (AZ6) are hereinafter referred to as colorants (ZZZ). ).

The coloring composition of the present invention preferably contains both the resin (B) and the solvent (E).
Moreover, the color curable composition of the present invention is
A compound represented by the formula (IZ1), a compound represented by the formula (IZ2), a compound represented by the formula (IZ3), a compound represented by the formula (IZ4), a compound represented by the formula (IZ5), And one or more selected from the compounds represented by the formula (IZ6),
It contains at least one of the resin (B) and the solvent (E) and the polymerizable compound (C).
In other words, the color curable composition of the present invention contains the color composition and the polymerizable compound (C).
The color curable composition of the present invention may contain a polymerization initiator (D).
The color curable composition of the present invention may contain a polymerization initiation aid (D1).
The coloring composition of the present invention may further contain a leveling agent (F) and an antioxidant.

<Compound (IZ1)>
The compound (IZ1) is a compound represented by the formula (IZ1).

[In formula (IZ1),
^RO1Z1 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
R ^1Z1 , R ^2Z1 , R ^3Z1 , R ^4Z1 , R ^5Z1 , R ^6Z1 , and R ^7Z1 are independent of each other, hydrogen atom, -CO-R ^102Z1 , -COO-R ^101Z1 , -OCO-R ^102Z1 , -COCO. -R ^102Z1 , -O-R ^102Z1 , -SO ₂ -R ^101Z1 , -SO ₂ N (R ^102Z1 ) ₂ ^{, -CON} (R 102Z1) ₂ , -N (R ^102Z1 ) ₂ , -NHCO-R ^102Z1 ,- NHCO-N (R ^102Z1 ) ₂ , -NHCOOR ^102Z1 , -OCON (R ^102Z1 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, carbon which may have a substituent. Represents a heterocyclic group which may have a hydrocarbon group or a substituent of the number 1 to 40.
R ^{2Z 1} and R ^{3Z 1} , R ^{3Z 1} and R ^{4Z 1} , and R ^{4Z 1} and R 5 ^{Z 1} , respectively, may be coupled to each other to form a ring.
R ^101Z1 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102Z1 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
M represents a hydrogen atom or an alkali metal atom.
When a ^{plurality of R 101Z1} , R ^{102 Z1} and M exist, they may be the same or different.
The wavy line represents an E-form or a Z-form. ]

The carbon number of the hydrocarbon group represented by ^RO1Z1 , ^R1Z1 , ^R2Z1 , ^R3Z1 , ^R4Z1 , ^R5Z1 , ^R6Z1 , ^R7Z1 , ^R101Z1 and ^{R102Z1 is 1 to 40, preferably 1.} It is ~ 30, more preferably 1 to 20, still more preferably 1 to 15, and particularly preferably 1 to 10.

The hydrocarbon groups having 1 to 40 carbon atoms represented by ^RO1Z1 , ^R1Z1 , ^R2Z1 , ^R3Z1 , ^R4Z1 , ^R5Z1 , ^R6Z1 , ^R7Z1 , ^R101Z1 and ^{R102Z1 are aliphatic hydrocarbon groups and} It may be an aromatic hydrocarbon group, and the aliphatic hydrocarbon group may be saturated or unsaturated, or may be a chain or an alicyclic.

Saturated or unsaturated chain hydrocarbon groups represented by ^RO1Z1 , ^R1Z1 , ^R2Z1 , ^R3Z1 , ^R4Z1 , ^R5Z1 , ^R6Z1 , ^R7Z1 , ^R101Z1 and ^{R102Z1 include methyl group and ethyl group.} , Propyl group, butyl group, pentyl group, hexyl group, heptyl group, octyl group, nonyl group, decyl group, undecyl group, dodecyl group, heptadecyl group, octadecyl group, linear alkyl group such as icosyl group; isopropyl Group, isobutyl group, sec-butyl group, tert-butyl group, (2-ethyl) butyl group, isopentyl group, neopentyl group, tert-pentyl group, (1-methyl) pentyl group, (2-methyl) pentyl group, Branched chain alkyl groups such as (1-ethyl) pentyl group, (3-ethyl) pentyl group, isohexyl group, (5-methyl) hexyl group, (2-ethyl) hexyl group and (3-ethyl) heptyl group. Etc; Vinyl group, 1-propenyl group, 2-propenyl group (allyl group), (1-methyl) ethenyl group, 2-butenyl group, 3-butenyl group, 1,3-butadienyl group, (1- (2-) Propenyl)) alkenyl groups such as (1,2-dimethyl) propenyl group and 2-pentenyl group; and the like. The saturated or unsaturated chain hydrocarbon group preferably has 1 to 30 carbon atoms, more preferably 1 to 20 carbon atoms, still more preferably 1 to 15 carbon atoms, and particularly preferably 1 to 10 carbon atoms. It is more preferably 1 to 8, and even more preferably 1 to 5. Of these, a linear or branched alkyl group having 1 to 10 carbon atoms, more preferably 1 to 8 carbon atoms is particularly preferable, and a methyl group, an ethyl group, and a tert-butyl group are particularly preferable.

The saturated or unsaturated alicyclic hydrocarbon groups represented by ^RO1Z1 , ^R1Z1 , ^R2Z1 , ^R3Z1 , ^R4Z1 , ^R5Z1 , ^R6Z1 , ^R7Z1 , ^R101Z1 and ^{R102Z1 include cyclopropyl groups.} 1-methylcyclopropyl group, cyclobutyl group, cyclopentyl group, cyclohexyl group, cycloheptyl group, 1-methylcyclohexyl group, 2-methylcyclohexyl group, 3-methylcyclohexyl group, 4-methylcyclohexyl group, 1,2-dimethylcyclohexyl Group, 1,3-dimethylcyclohexyl group, 1,4-dimethylcyclohexyl group, 2,3-dimethylcyclohexyl group, 2,4-dimethylcyclohexyl group, 2,5-dimethylcyclohexyl group, 2,6-dimethylcyclohexyl group, 3,4-Dimethylcyclohexyl group, 3,5-dimethylcyclohexyl group, 2,2-dimethylcyclohexyl group, 3,3-dimethylcyclohexyl group, 4,4-dimethylcyclohexyl group, cyclooctyl group, 2,4,6- Cyclo such as trimethylcyclohexyl group, 2,2,6,6-tetramethylcyclohexyl group and 3,3,5,5-tetramethylcyclohexyl group, 4-pentylcyclohexyl group, 4-octylcyclohexyl group, 4-cyclohexylcyclohexyl group Alkyl group; cycloalkenyl group such as cyclohexenyl group (for example, cyclohex-2-ene, cyclohex-3-ene), cycloheptenyl group, cyclooctenyl group; norbornan group, adamantyl group, bicyclo [2.2.2] octane and the like. Be done. The saturated or unsaturated alicyclic hydrocarbon group preferably has 3 to 30, more preferably 3 to 20, even more preferably 4 to 20, and even more preferably 4 to 15. Yes, more particularly preferably 5 to 15, and most preferably 5 to 10. Of these, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, and a cyclooctyl group are particularly preferable.

The ^{aromatic hydrocarbon groups represented by RO1Z1} , ^R1Z1 , ^R2Z1 , ^R3Z1 , ^R4Z1 , ^R5Z1 , ^R6Z1 , and ^R7Z1 , ^R101Z1 and ^R102Z1 include phenyl group, o-tolyl group, m-tolyl group, p-tolyl group, 2-ethylphenyl group, 3-ethylphenyl group, 4-ethylphenyl group, 2,3-dimethylphenyl group, 2,4-dimethylphenyl group, 2,5-dimethylphenyl Group, 2,6-dimethylphenyl group, 3,4-dimethylphenyl group, 3,5-dimethylphenyl group, 4-vinylphenyl group, o-isopropylphenyl group, m-isopropylphenyl group, p-isopropylphenyl group, o-tert-butylphenyl group, m-tert-butylphenyl group, p-tert-butylphenyl group, mesityl group, 4-ethylphenyl group, 4-butylphenyl group, 4-pentylphenyl group, 2,6-bis (2-propyl) phenyl group, 4-cyclohexylphenyl group, 2,4,6-trimethylphenyl group, 4-octylphenyl group, 1-naphthyl group, 2-naphthyl group, 5,6,7,8-tetrahydro- Examples thereof include 1-naphthyl group, 5,6,7,8-tetrahydro-2-naphthyl group, fluorenyl group, phenyl group and aromatic hydrocarbon group such as anthryl group and pyrenyl group; and the like. The number of carbon atoms of the aromatic hydrocarbon group is preferably 6 to 30, more preferably 6 to 20, and even more preferably 6 to 15.

The ^{hydrocarbon groups represented by RO1Z1} , ^R1Z1 , ^R2Z1 , ^R3Z1 , ^R4Z1 , ^R5Z1 , ^R6Z1 , ^R7Z1 , ^R101Z1 and ^R102Z1 are the above-mentioned hydrocarbon groups (for example, aromatic carbides). It may be a group in which a hydrogen group is combined with at least one of a chain hydrocarbon group and an alicyclic hydrocarbon group), and an aralkyl group such as a benzyl group, a phenethyl group, or a 1-methyl-1-phenylethyl group. An arylalkenyl group such as a phenylethenyl group (phenylvinyl group); an arylalkynyl group such as a phenylethynyl group; a phenyl group to which one or more phenyl groups such as a biphenylyl group and a terphenylyl group are bonded; a cyclohexylmethylphenyl group and a benzyl Examples thereof include a phenyl group and a (dimethyl (phenyl) methyl) phenyl group.
The ^{groups represented by RO1Z1} , ^R1Z1 , ^R2Z1 , ^R3Z1 , ^R4Z1 , ^R5Z1 , ^R6Z1 , ^R7Z1 , ^R101Z1 and ^R102Z1 are the hydrocarbon groups listed above (for example, chain hydrocarbon groups). And alicyclic hydrocarbon group), for example, cyclopropylmethyl group, cyclopropylethyl group, cyclobutylmethyl group, cyclobutylethyl group, cyclopentylmethyl group, cyclopentylethyl group, cyclohexylmethyl group, 2- It may be an alkyl group to which one or more alicyclic hydrocarbon groups such as methylcyclohexylmethyl group, cyclohexylethyl group and adamantylmethyl group are bonded.
These carbon numbers are preferably 4 to 30, more preferably 6 to 30, even more preferably 6 to 20, still preferably 4 to 20, and even more preferably 4 to 15. , Particularly preferably 6 to 15.

The hydrocarbon groups represented by ^RO1Z1 , ^R1Z1 , ^R2Z1 , ^R3Z1 , ^R4Z1 , ^R5Z1 , ^R6Z1 , ^R7Z1 , ^R101Z1 and ^{R102Z1 may have substituents.} The substituent may be monovalent or divalent. For the divalent substituent, it is preferable that two bonds are bonded to the same carbon atom to form a double bond.
As the monovalent substituent,
Methoxy group, ethoxy group, propoxy group, isopropoxy group, butoxy group, isobutoxy group, sec-butoxy group, tert-butoxy group, pentyloxy group, hexyloxy group, (2-ethyl) hexyloxy group, heptyloxy group, Octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, dodecyloxy group, (2-ethyl) hexyloxy group, icosyloxy group, 1-phenylethoxy group, 1-methyl-1-phenylethoxy group, phenyloxy group , O-Trilloxy group, 2,3-dimethylphenyloxy group, 2,4-dimethylphenyloxy group, 2,5-dimethylphenyloxy group, 2,6-dimethylphenyloxy group, 3,4-dimethylphenyloxy group , 3,5-dimethylphenyloxy group, 2,2-dicyanophenyloxy group, 2,3-dicyanophenyloxy group, 2,4-dicyanophenyloxy group, 2,5-dicyanophenyloxy group, 2,6- Dicyanophenyloxy group, 3,4-dicyanophenyloxy group, 3,5-dicyanophenyloxy group, 4-methoxyphenyloxy group, 2-methoxyphenyloxy group, 3-methoxyphenyloxy group, 4-ethoxyphenyloxy group , 2-ethoxyphenyloxy group, 3-ethoxyphenyloxy group, etc., and groups represented by the following formulas, etc., which have 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or a derivatizing group thereof. (For example, a group derivatized with a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), or the like). Is an oxy group bonded to one side;

Methylthio group, ethylthio group, propylthio group, butylthio group, tert-butylthio group, pentylthio group, hexylthio group, (2-ethyl) hexylthio group, heptylthio group, octylthio group, nonylthio group, decylthio group, undecylthio group, dodecylthio group, icosylthio group. A sulfanyl group to which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group, a phenylthio group and an o-tolylthio group is bonded;

Epoxy group, oxetanyl group, tetrahydrofuryl group, tetrahydropyranyl group;
Holmil group;
Acetyl group, propanoyl group, butanoyl group, 2,2-dimethylpropanoyl group, pentanoyl group, hexanoyl group, (2-ethyl) hexanoyl group, heptanoil group, octanoyl group, nonanoyl group, decanoyl group, undecanoyl group, dodecanoyl group, A hydrocarbon group having a carbon number of 1 to 20 (preferably having a carbon number of 1 to 11) or an inducible group thereof (for example, a carboxy group or a sulfo group) such as a henicosanoyl group, a benzoyl group, and a group represented by the following formula. , A carbonyl group to which a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. are bonded. When the carbonyl group is an alkanoyl group, the number of carbon atoms is preferably 2 to 12);

Methoxycarbonyl group, ethoxycarbonyl group, propoxycarbonyl group, butoxycarbonyl group, tert-butoxycarbonyl group, pentyloxycarbonyl group, hexyloxycarbonyl group, (2-ethyl) hexyloxycarbonyl group, heptyloxycarbonyl group, octyloxycarbonyl group Group, nonyloxycarbonyl group, decyloxycarbonyl group, undecyloxycarbonyl group, dodecyloxycarbonyl group, icosyloxycarbonyl group, phenyloxycarbonyl group, o-tolyloxycarbonyl group, etc., and represented by the following formula A hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), a carbon number of carbon atoms). An oxycarbonyl group to which 1 to 10 alkylsulfamoyl groups (preferably groups derivatized with an octylsulfamoyl group) or the like are attached;

Amino group;
N-methylamino group, N, N-dimethylamino group, N-ethylamino group, N, N-diethylamino group, N-propylamino group, N, N-dipropylamino group, N-isopropylamino group, N, N-diisopropylamino group, N-butylamino group, N, N-dibutylamino group, N-isobutylamino group, N, N-diisobutylamino group, N-sec-butylamino group, N, N-disec-butyl Amino group, N-tert-butylamino group, N, N-ditert-butylamino group, N-pentylamino group, N, N-dipentylamino group, N- (1-ethylpropyl) amino group, N, N -Di (1-ethylpropyl) amino group, N-hexylamino group, N, N-dihexylamino group, N- (2-ethyl) hexylamino group, N, N-di (2-ethyl) hexylamino group, N-Heptylamino Group, N, N-Diheptylamino Group, N-octylamino Group, N, N-Dioctylamino Group, N-Nonylamino Group, N, N-Dinonylamino Group, N-Phenylamino Group, N, N -Diphenylamino group, N, N-ethylmethylamino group, N, N-propylmethylamino group, N, N-isopropylmethylamino group, N, N-butylmethylamino group, N-decylamino group, N, N- Decylmethylamino Group, N-Undecylamino Group, N, N-Undecylmethylamino Group, N-Dodecylamino Group, N, N-Dodecylmethylamino Group, N-Icosylamino Group, N, N-Icosylmethylamino One or two carbon atoms 1 to 20 (preferably 1 carbon atom) such as a group, an N, N-tert-butylmethylamino group, an N, N-phenylmethylamino group, etc., and a group represented by the following formula. A hydrocarbon group of 10) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), and an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsul). Amino group substituted with a famoyl group) or a derivatized group);

Sulfamoyl group;
N-methylsulfamoyl group, N, N-dimethylsulfamoyl group, N-ethylsulfamoyl group, N, N-diethylsulfamoyl group, N-propylsulfamoyl group, N, N-dipropyls Rufamoyl group, N-isopropylsulfamoyl group, N, N-diisopropylsulfamoyl group, N-butylsulfamoyl group, N, N-dibutylsulfamoyl group, N-isobutylsulfamoyl group, N, N-diisobutylsulfamoyl group, N-sec-butylsulfamoyl group, N, N-disec-butylsulfamoyl group, N-tert-butylsulfamoyl group, N, N-ditert-butylsul Famoyl group, N-pentyl sulfamoyl group, N, N-dipentyl sulfamoyl group, N- (1-ethylpropyl) sulfamoyl group, N, N-di (1-ethylpropyl) sulfamoyl group, N-hexyl Sulfamoyl group, N, N-dihexyl sulfamoyl group, N- (2-ethyl) hexyl sulfamoyl group, N, N-di (2-ethyl) hexyl sulfamoyl group, N-heptyl sulfamoyl Group, N, N-diheptyl sulfamoyl group, N-octyl sulfamoyl group, N, N-dioctyl sulfamoyl group, N, N-octylmethyl sulfamoyl group, N-nonyl sulfamoyl group, N, N-Dinonyl sulfamoyl group, N-phenyl sulfamoyl group, N, N-diphenyl sulfamoyl group, N, N-ethylmethyl sulfamoyl group, N, N-propylmethyl sulfamoyl group, N, N-isopropylmethylsulfamoyl group, N, N-butylmethylsulfamoyl group, N-decylsulfamoyl group, N, N-decylmethylsulfamoyl group, N-undecylsulfamoyl group, N , N-Undecylmethyl Sulfamoyl Group, N-Dodecyl Sulfamoyl Group, N, N-Dodecyl Methyl Sulfamoyl Group, N-Icosyl Sulfamoyl Group, N, N-Icosyl Methyl Sulfamoyl Group, N, N-tert-butylmethylsulfamoyl group, N, N-phenylmethylsulfamoyl group, etc., and one or two groups represented by the following formula, etc., having 1 or 2 carbon atoms (preferably carbons) A hydrocarbon group having a number of 1 to 10 or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), and an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably). Induced by octylsulfamoyl group) etc. Sulfamoyl group substituted with (ta group);

Formylamino group; acetylamino group, propanoylamino group, butanoylamino group, 2,2-dimethylpropanoylamino group, pentanoylamino group, hexanoylamino group, (2-ethyl) hexanoylamino group, heptanoil Amino group, octanoylamino group, nonanoylamino group, decanoyylamino group, undecanoylamino group, dodecanoylamino group, henicosanoylamino group, benzoylamino group, etc., and groups represented by the following formulas. Etc., a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 12 carbon atoms) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), 1 carbon atom). A carbonylamino group to which 10 to 10 alkylsulfamoyl groups (preferably groups derivatized with an octylsulfamoyl group) or the like are bonded (when the carbonylamino group is an alkanoylamino group, the number of carbon atoms is preferably 1. ~ 12);

Hydroxy group;
Halogen atoms such as fluorine atom, chlorine atom, bromine atom and iodine atom;
Carboxy group, -CO ₂ M ² (M ² is alkali metal, preferably lithium, sodium, potassium); sulfo group, -SO ₃ M ² (M ² is alkali metal, preferably lithium, sodium, potassium); nitro group Cyan group;

Formyloxy group; acetoxy group, propanoyloxy group, butanoyloxy group, 2,2-dimethylpropanoyloxy group, pentanoyloxy group, hexanoyloxy group, (2-ethyl) hexanoyloxy group, heptanoyloxy group Carbons such as groups, octanoyloxy groups, nonanoyloxy groups, decanoyloxy groups, undecanoyloxy groups, dodecanoyloxy groups, henicosanoyloxy groups, benzoyloxy groups, etc., and groups represented by the following formulas. A hydrocarbon group having a number of 1 to 20 (preferably 1 to 10 carbon atoms) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), and a group having 1 to 10 carbon atoms. A carbonyloxy group to which an alkylsulfamoyl group (preferably a group derivatized with an octylsulfamoyl group) or the like is bonded (when the carbonyloxy group is an alkanoyloxy group, the number of carbon atoms is preferably 1 to 10). be);

Methylsulfonyl group, ethylsulfonyl group, propylsulfonyl group, butylsulfonyl group, pentylsulfonyl group, hexylsulfonyl group, (2-ethyl) hexylsulfonyl group, heptylsulfonyl group, octylsulfonyl group, nonylsulfonyl group, decylsulfonyl group, un Decylsulfonyl group, dodecylsulfonyl group, icosylsulfonyl group, phenylsulfonyl group, p-tolylsulfonyl group and the like, and groups represented by the following formulas having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms). A hydrocarbon group or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group)). Sulfonyl group to which (groups derivatized by etc.) are bound;

Carbamic group;
N-Methylcarbamoyl group, N, N-dimethylcarbamoyl group, N-ethylcarbamoyl group, N, N-diethylcarbamoyl group, N-propylcarbamoyl group, N, N-dipropylcarbamoyl group, N-isopropylcarbamoyl group, N , N-diisopropylcarbamoyl group, N-butylcarbamoyl group, N, N-dibutylcarbamoyl group, N-isobutylcarbamoyl group, N, N-diisobutylcarbamoyl group, N-sec-butylcarbamoyl group, N, N-disec- Butylcarbamoyl group, N-tert-butylcarbamoyl group, N, N-ditert-butylcarbamoyl group, N-pentylcarbamoyl group, N, N-dipentylcarbamoyl group, N- (1-ethylpropyl) carbamoyl group, N, N-di (1-ethylpropyl) carbamoyl group, N-hexyl carbamoyl group, N, N-dihexyl carbamoyl group, N- (2-ethyl) hexyl carbamoyl group, N, N-di (2-ethyl) hexyl carbamoyl group , N-Heptylcarbamoyl group, N, N-diheptylcarbamoyl group, N-octylcarbamoyl group, N, N-dioctylcarbamoyl group, N-nonylcarbamoyl group, N, N-octylmethylcarbamoyl group, N, N-octyl Butylcarbamoyl group, N, N-dinonylcarbamoyl group, N-phenylcarbamoyl group, N, N-diphenylcarbamoyl group, N, N-ethylmethylcarbamoyl group, N, N-propylmethylcarbamoyl group, N, N-isopropyl Methylcarbamoyl group, N, N-butylmethylcarbamoyl group, N-decylcarbamoyl group, N, N-decylmethylcarbamoyl group, N-undecylcarbamoyl group, N, N-undecylmethylcarbamoyl group, N-dodecylcarbamoyl group , N, N-dodecylmethylcarbamoyl group, N-icosylcarbamoyl group, N, N-icosylmethylcarbamoyl group, N, N-tert-butylmethylcarbamoyl group, N, N-phenylmethylcarbamoyl group, etc. A hydrocarbon group having 1 or 2 carbon atoms (preferably 1 to 10 carbon atoms) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group) such as a group represented by the above formula. , A carbamoyl group substituted with halogen (preferably a chlorine atom), a group derivatized with an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc.;

Trifluoromethyl group, perfluoroethyl group, perfluoropropyl group, perfluoroisopropyl group, perfluorobutyl group, perfluoropentyl group, perfluorohexyl group, perfluoroheptyl group, perfluorooctyl group, perfluorononyl group, Carbonation of 1 to 20 carbon atoms in which all hydrogen atoms such as perfluorodecyl group, perfluoroundecyl group, perfluorododecyl group, perfluoroicosyl group, perfluorocyclohexyl group and perfluorophenyl group are substituted with fluorine atom. Hydrogen group;
Perfluoroethylmethyl group, perfluoropropylmethyl group, perfluoroisopropylmethyl group, perfluorobutylmethyl group, perfluoropentylmethyl group, perfluorohexylmethyl group, perfluoroheptylmethyl group, perfluorooctylmethyl group, perfluoro A linear chain having 1 to 20 carbon atoms in which all hydrogen atoms such as nonylmethyl group, perfluorodecylmethyl group, perfluoroundecylmethyl group, perfluorododecylmethyl group, and perfluoroicosylmethyl group are substituted with fluorine atoms. Alternatively, a hydrocarbon group having 1 to 20 carbon atoms substituted with an alkyl group in the branched chain;

1 to 20 carbon atoms (preferably carbon number) in which a part of hydrogen atoms such as 2-fluorophenyl group, 3-fluorophenyl group, 4-fluorophenyl group and 2,4,6-trifluorophenyl group are replaced with fluorine. 1-10) hydrocarbon groups;

-CO-SH, -CO-S-CH ₃ , -CO-S-CH ₂ CH ₃ , -CO-S-CH ₂ -CH ₂ -CH ₃ , -CO-S-CH ₂ -CH ₂ -CH ₂ carbon atoms -CH _3, etc. 20 (preferably having 1 to 10 carbon atoms) bound to an alkyl group as bonded to a thiocarbonyl _{group, -CO-S-C 6 H} 5 aryl group having 6 to 20 carbon atoms, such as the Thiocarbonyl group;

* -COCO-R as represented by the following formula (in the formula, R is a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms (for example, among the hydrocarbon groups listed above, it satisfies 1 to 20 carbon atoms). , Or its inducing group (eg, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group). Group) (group derived by etc.);

_{* -NRCONR 2} as represented by the following formula (in the formula, R is a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms (for example, among the hydrocarbon groups listed above, those satisfying 1 to 20 carbon atoms). ), Or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), etc. Groups derived from), the Rs of which may be the same or different from each other, or bonded to each other to form a ring);

_{* -OCONR 2} as represented by the following formula (in the formula, R is a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms (for example, among the hydrocarbon groups listed above, those satisfying 1 to 20 carbon atoms). ), Or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), etc. Groups derived from), the Rs of which may be the same or different from each other, or bonded to each other to form a ring);

* -NRCOOR as represented by the following formula (in the formula, R is a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms (for example, among the hydrocarbon groups listed above, those satisfying 1 to 20 carbon atoms)). , Or its inducing group (eg, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group), etc. Derivatized groups), the Rs of which may be the same or different from each other, or bonded to each other to form a ring) groups;

* -OP (O) (OCH ₃ ) ₂ such as * -OP (O) (OR) ₂ (In the formula, R is a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms (for example, the hydrocarbon group listed above). Of these, those satisfying 1 to 20 carbon atoms), or their inducible groups (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms). (Preferably a group derivatized with an octylsulfamoyl group) or the like), and the Rs may be the same or different from each other, or may be bonded to each other to form a ring).
* -Si (CH ₃ ) ₃ , _{* -Si (CH 2} CH ₃ ) ₃ , _{* -Si (C 6} H ₅ ) ₃ and * -Si (CH (CH ₃ ) ₂ ) _3, etc. * -SiR ₃ ( In the formula, R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, one of the above-mentioned hydrocarbon groups satisfying 1 to 20 carbon atoms), or an inducing group thereof (for example, a carboxy group or a sulfo group). A group derived from a group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), etc.), and the R is Groups of (may be the same or different from each other and may be bonded to each other to form a ring);
And so on.

As the divalent substituent, an oxo group, a thioxo group, an imino group, an imino group substituted with an alkyl group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) and an aryl group having 6 to 20 carbon atoms are substituted. Examples include the imino group. Examples of the imino group substituted with the alkyl group include CH _3- N =, CH _3- CH _2- N =, CH _3- (CH ₂ ) _2- N = and CH _3- (CH ₂ ) _3- N =. Can be mentioned. Examples of the imino group substituted with the aryl group include C ₆ H _5- N = and the like.

Preferred examples of the substituent of the hydrocarbon group having 1 to 40 carbon atoms include the substituent of the group s1. The inducible groups shown below are carboxy groups, sulfo groups, nitro groups, hydroxy groups, halogens (preferably chlorine atoms), alkylsulfamoyl groups having 1 to 10 carbon atoms (preferably octylsulfamoyl groups) and the like. It is preferably an derivatized group.
[Group s1]
An oxy group in which a hydrocarbon group having 1 to 20 carbon atoms or an inducible group thereof is bonded to one side;
A carbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
An oxycarbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
Amino group;
An amino group substituted with one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
Sulfamoyl group;
A sulfamoyl group substituted with one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
A carbonylamino group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
Hydroxy group;
Halogen atom;
-CO ₂ M (preferably a carboxy group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom);
-SO ₃ M (preferably a sulfo group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom);
Nitro group;
Cyano group;
A carbonyloxy group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
A sulfonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or an inducible group thereof is bonded;
Carbamic group;
A carbamoyl group substituted with one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
A hydrocarbon group having 1 to 20 carbon atoms in which all hydrogen atoms are replaced by fluorine atoms;
A hydrocarbon group having 1 to 20 carbon atoms in which all of the hydrogen atoms are substituted with fluorine atoms;
A hydrocarbon group having 1 to 20 carbon atoms in which a part of a hydrogen atom is replaced by fluorine;
Oxo group

As the substituent of the hydrocarbon group having 1 to 40 carbon atoms, a substituent of group s2 is more preferable.
[Group s2]
An oxy group in which a hydrocarbon group having 1 to 10 carbon atoms or an inducible group thereof is bonded to one side;
A carbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
An oxycarbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
Amino group;
An amino group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or an inducible group thereof;
Sulfamoyl group;
A sulfamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof;
A carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
Hydroxy group;
Fluorine atom, chlorine atom, bromine atom;
-CO ₂ M (preferably a carboxy group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom);
-SO ₃ M (preferably a sulfo group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom);
Nitro group;
Cyano group;
A carbonyloxy group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
A sulfonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or an inducible group thereof is bonded;
Carbamic group;
A carbamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof;
A hydrocarbon group having 1 to 10 carbon atoms in which all hydrogen atoms are replaced by fluorine atoms;
A hydrocarbon group having 1 to 10 carbon atoms in which all of the hydrogen atoms are substituted with fluorine atoms;
A hydrocarbon group having 1 to 10 carbon atoms in which a part of a hydrogen atom is replaced by fluorine;
Oxo group

As a hydrocarbon group having 1 to 40 carbon atoms having a substituent represented by ^RO1Z1 , ^R1Z1 , ^R2Z1 , ^R3Z1 , ^R4Z1 , ^R5Z1 , ^R6Z1 , ^R7Z1 , ^R101Z1 and ^{R102Z1, 1} Hydrocarbon groups having 1 to 40 carbon atoms having a valent or divalent substituent can be mentioned, preferably saturated or unsaturated chain hydrocarbon groups having 1 to 30 carbon atoms having a monovalent or divalent substituent. A saturated or unsaturated alicyclic hydrocarbon group having 3 to 30 carbon atoms having a monovalent or divalent substituent or an aromatic hydrocarbon group having 6 to 30 carbon atoms having a monovalent or divalent substituent or Groups having a combination of hydrocarbon groups and having a monovalent or divalent substituent and having 1 to 30 carbon atoms can be mentioned.
More preferably, a saturated or unsaturated chain hydrocarbon group having 1 to 20 carbon atoms having a substituent in group s1 and a saturated or unsaturated alicyclic hydrocarbon group having 3 to 20 carbon atoms having a substituent in group s1. , A group having a substituent of group s1 and having 6 to 20 carbon atoms or a combination of hydrocarbon groups and a group having a substituent of group s1 and having 1 to 20 carbon atoms.
Particularly preferably, a saturated or unsaturated chain hydrocarbon group having 1 to 15 carbon atoms having a substituent in group s2 and a saturated or unsaturated alicyclic hydrocarbon group having 3 to 15 carbon atoms having a substituent in group s2. , A group having a substituent of group s2 and having 6 to 15 carbon atoms or a combination of hydrocarbon groups and a group having a substituent of group s2 and having 1 to 15 carbon atoms.

The ^{heterocyclic group represented by RO1Z1} , ^R1Z1 , ^R2Z1 , ^R3Z1 , ^R4Z1 , ^R5Z1 , ^R6Z1 , ^R7Z1 , ^R101Z1 and ^R102Z1 may be monocyclic or polycyclic. It may be a heterocycle, preferably a heterocycle containing a heteroatom as a component of the ring. Examples of the hetero atom include a nitrogen atom, an oxygen atom and a sulfur atom.
The number of carbon atoms of the heterocyclic group is preferably 3 to 30, more preferably 3 to 22, still more preferably 3 to 20, even more preferably 3 to 18, and even more preferably 3 to 3. It is 15, particularly preferably 3 to 14.

As a heterocycle containing a nitrogen atom,
Monocyclic saturated heterocycles such as aziridine, azetidine, pyrrolidine, piperidine and piperazine;
Pyrrole such as 2,5-dimethylpyrrole, pyrazole such as 2-methylpyrazole and 3-methylpyrazole, imidazole, 1,2,3-triazole and 5-membered ring-based unsaturated heterocycle such as 1,2,4-triazole ;
Pyrimidines such as pyridine, pyridazine, 6-methylpyrimidine, pyrazines and 6-membered ring unsaturated heterocycles such as 1,3,5-triazine;
Quinoxaline such as indazole, indolin, isoindolin, indole, indoline, benzimidazole, quinoline, isoquinoline, 5,6,7,8-tetrahydro (3-methyl) quinoxaline, 3-methylquinoxaline, quinazoline, cinnoline, phthalazine, diazanaphthalene. , Purine, pteridine, benzopyrazole, benzopiperidine and other fused bicyclic heterocycles;
Condensed tricyclic heterocycles such as carbazole, acridine and phenazine; and the like.

As a heterocycle containing an oxygen atom,
Monocyclic saturated heterocycles such as oxylan, oxetane, tetrahydrofuran, tetrahydropyran, 1,3-dioxane and 1,4-dioxane, 1-cyclopentyl dioxolane;
Bicyclic saturated heterocycles such as 1,4-dioxaspiro [4.5] decane and 1,4-dioxaspiro [4.5] nonane;
Lactone-based heterocycles such as α-acetolactone, β-propiolactone, γ-butyrolactone, γ-valerolactone and δ-valerolactone;
A 5-membered ring-based unsaturated heterocycle such as furan such as 2,3-dimethylfuran and 2,5-dimethylfuran;
6-membered ring-based unsaturated heterocycles such as 2H-pyran and 4H-pyran;
Benzopyrans such as 1-benzofuran and 4-methylbenzopyran, condensed bicyclic heterocycles such as benzodioxol, chroman and isochroman;
Condensed tricyclic heterocycles such as xanthene and dibenzofuran; and the like.

As a heterocycle containing a sulfur atom,
5-membered ring-based saturated heterocycle such as dithiolane;
6-membered ring-based saturated heterocycles such as thiane, 1,3-dithiane, 2-methyl 1,3-dithiane;
5-membered ring-based unsaturated heterocycles such as thiophenes such as 3-methylthiophene and 2-carboxythiophene, 4H-thiopyran, benzothiopyran such as benzotetrahydrothiopyran;
Condensation bicyclic heterocycles such as benzothiophene;
Condensed tricyclic heterocycles such as thianthrene and dibenzothiophene; and the like.

As a heterocycle containing a nitrogen atom and an oxygen atom,
Monocyclic saturated heterocycles such as morpholine, 2-pyrrolidone, 2-methyl-2-pyrrolidone, 2-piperidone and 2-methyl-2-piperidone;
Monocyclic unsaturated heterocycles such as oxazoles such as 4-methyloxazole, 2-methylisoxazoles, and isooxazoles such as 3-methylisoxazole;
Condensed bicyclic heterocycles such as benzoxazole, benzoisoxazole, benzoxazine, benzodioxan, benzoimidazoline;
Condensed tricyclic heterocycles such as phenoxazine; and the like.

As a heterocycle containing a nitrogen atom and a sulfur atom,
Monocyclic heterocycles such as thiazoles such as 3-methylthiazole and 2,4-dimethylthiazole;
Condensation bicyclic heterocycles such as benzothiazole;
Condensation tricyclic heterocycles such as phenothiazine; and the like.

The heterocycle may be a group in which the above-mentioned hydrocarbon groups are combined, and examples thereof include a tetrahydrofurylmethyl group.

Further, the heterocycle may be represented by the following formula.

Further, the heterocyclic group may be a heterocyclic group formed by bonding two or more of ^{R 1Z1 to} R ^5Z1. Such a heterocyclic group has a ring structure of two or more rings together with a benzene ring to which ^{R 1Z1 to} R ^{5Z1 are bonded.} Examples of the ring structure having two or more rings include the structure of the following formula.

The bond position of the above heterocycle is a portion where an arbitrary hydrogen atom contained in each ring is eliminated.

The ^{heterocyclic group represented by RO1Z1} , ^R1Z1 , ^R2Z1 , ^R3Z1 , ^R4Z1 , ^R5Z1 , ^R6Z1 , ^R7Z1 , ^R101Z1 and ^R102Z1 may have a substituent. As the substituent, the hydrocarbon group represented by ^RO1Z1 , ^R1Z1 , ^R2Z1 , ^R3Z1 , ^R4Z1 , ^R5Z1 , ^R6Z1 , ^R7Z1 , ^R101Z1 and ^R102Z1 may have a substituent. The same as the group can be mentioned. When the heterocycle contains a nitrogen atom as a constituent element thereof, the hydrocarbon group mentioned above may be bonded to the nitrogen atom as a substituent.
Preferred examples of the substituent, and ^{R O1Z1, R 1Z1, R 2Z1} , R 3Z1, R 4Z1, R 5Z1, R 6Z1, R 7Z1, have a hydrocarbon group represented by R ^101Z1 and R ^102Z1 The same preferred substituents may be mentioned.
Heterocyclic groups having substituents represented by ^RO1Z1 , ^R1Z1 , ^R2Z1 , ^R3Z1 , ^R4Z1 , ^R5Z1 , ^R6Z1 , ^R7Z1 , ^R101Z1 and ^{R102Z1 are monovalent or divalent substitutions.} A heterocyclic group having a group is mentioned, preferably a heterocyclic group having a substituent of the group s1 is mentioned, and more preferably a heterocyclic group having a substituent of the group s2 is mentioned.
The above-mentioned hydrocarbon group or heterocyclic group may have one or more substituents (first substituents), and the two or more substituents are independent of each other. It may be the same or different. Further, the first substituent may have another substituent (second substituent) bonded to the hydrocarbon group contained in a part thereof. The second substituent can be selected from the same groups as the first substituent.

Below, R ^1Z1 , R ^2Z1 , R ^3Z1 , R ^4Z1 , R ^5Z1 , R ^6Z1 , R ^7Z1 -CO-R ^102Z1 , -COO-R ^101Z1 , -OCO-R ^102Z1 , -COCO-R ^102Z1 , -O- R ^102Z1 , -SO ₂ -R ^101Z1 , -SO ₂ N (R ^102Z1 ) ₂ ^{, -CON} (R 102Z1) ₂ , -N (R ^102Z1 ) ₂ , -NHCO-R ^102Z1 , -NHCO-N (R ^102Z1 ) ₂ , -NHCOOR ^102Z1 , -OCON (R ^102Z1 ) ₂ , halogen atom, -SO ₃ M, -CO ₂ M will be described.

-CO-R ^102Z1 includes formyl group; acetyl group, propanoyl group, butanoyl group, 2,2-dimethylpropanoyl group, pentanoyl group, hexanoyl group, (2-ethyl) hexanoyl group, heptanoil group, octanoyl group, nonanoyl. Derivation of a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group, a decanoyl group, an undecanoyl group, a dodecanoyl group, a henicosanoyl group, a benzoyl group, etc., and a group represented by the above formula. It was derivatized with a chemical group (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), or the like. A group corresponding to -CO-R 102Z1 in the carbonyl group to which the group) is bonded (when the carbonyl group is an acyl group, the number of carbon atoms is 2 to 41) and the compounds shown in Tables 1Z1 to ^{14Z1 and a special application.} In the compounds shown in Tables 1 to 966 of No. ^2017-016290 , a group corresponding to −CO-R 102Z1 and the like can be mentioned, preferably a hydrocarbon group having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms) or a hydrocarbon group. ^{Corresponds to -CO-R 102Z1} in the carbonyl group to which the derivatizing group is bonded (when the carbonyl group is an alkanoyl group, the number of carbon atoms is more preferably 2 to 12) and the compounds shown in Tables 1Z1 to 14Z1. Examples include the groups to be used.

-COO-R ^101Z1 includes methoxycarbonyl group, ethoxycarbonyl group, propoxycarbonyl group, tert-butoxycarbonyl group, butoxycarbonyl group, pentyloxycarbonyl group, hexyloxycarbonyl group, (2-ethyl) hexyloxycarbonyl group, Heptyloxycarbonyl group, octyloxycarbonyl group, nonyloxycarbonyl group, decyloxycarbonyl group, undecyloxycarbonyl group, dodecyloxycarbonyl group, phenyloxycarbonyl group, icosyloxycarbonyl group, etc., and represented by the above formula. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or an inducing group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon In the oxycarbonyl group to which an alkylsulfamoyl group (preferably a group derivatized with an octylsulfamoyl group) of several 1 to 10 is bonded and the compounds shown in Tables 1Z1 to 14Z1, -COO-R ^{101Z1 Examples of the relevant group and the group corresponding to -COO-R 101Z1} in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290 include a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof. Examples thereof include an oxycarbonyl group to which is bonded and a group corresponding to ^{-COO-R 101Z1 in the compounds shown in Tables 1Z1 to 14Z1.}

-OCO-R ^102Z1 includes formyloxy group; acetoxy group, propanoyloxy group, butanoyloxy group, 2,2-dimethylpropanoyloxy group, pentanoyloxy group, hexanoyloxy group, (2-ethyl). Hexanoyloxy group, heptanoiloxy group, octanoyloxy group, nonanoyloxy group, decanoyloxy group, undecanoyloxy group, dodecanoyloxy group, henikosanoyloxy group, benzoyloxy group, etc., and the above formula. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or an inducible group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, or a halogen (preferably a chlorine atom). ), A carbonyloxy group to which an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably a group derived from an octylsulfamoyl group) or the like is bonded (when the carbonyloxy group is an acyloxy group, the number of carbon atoms is 2 to 41), ^{and the groups corresponding to -OCO-R 102Z1} in the compounds shown in Tables 1Z1 to 14Z1 and -OCO-R 102Z1 in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. ^2017-016290. Examples of the group corresponding to the above, preferably a hydrocarbon group having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms) or a carbonyloxy group to which an inducible group thereof is bonded (the carbonyloxy group is referred to as an acyloxy group). In this case, the number of carbon atoms is more preferably 2 to 12), and in the compounds shown in Tables 1Z1 to ^14Z1 , groups corresponding to -OCO-R 102Z1 and the like can be mentioned.

-COCO-R ^102Z1 includes methyloxalyl group, ethyloxalyl group, propyloxalyl group, butyloxalyl group, pentyloxalyl group, hexyloxalyl group, (2-ethyl) hexyloxalyl group, heptyloxalyl group, octyloxalyl group and nonyl. Oxalyl group, decyl oxalyl group, undecyl oxalyl group, dodecyl oxalyl group, icosyl oxalyl group, cyclopentyl oxalyl group, cyclohexyl oxalyl group, phenyl oxalyl group, p-tolyl oxalyl group and the like, and groups represented by the above formulas and the like. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), 1 to 1 carbon atoms. Oxalyl groups to which 10 alkylsulfamoyl groups (preferably groups derivatized with octylsulfamoyl groups) and the like are bonded, and groups corresponding to ^{-COCO-R 102Z1 in the compounds shown in Tables 1Z1 to 14Z1 and} Examples of the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290 include groups corresponding to ^{-COCO-R 102Z1.}

-O-R ^102Z1 includes hydroxy group; methoxy group, ethoxy group, propoxy group, isopropoxy group, butoxy group, isobutoxy group, sec-butoxy group, tert-butoxy group, pentyloxy group, hexyloxy group, heptyloxy. Group, octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, dodecyloxy group, (2-ethyl) hexyloxy group, icosyloxy group, 1-phenylethoxy group, 1-methyl-1-phenylethoxy group, phenyl Oxy group, 2,3-dimethylphenyloxy group, 2,4-dimethylphenyloxy group, 2,5-dimethylphenyloxy group, 2,6-dimethylphenyloxy group, 3,4-dimethylphenyloxy group, 3, 5-Dimethylphenyloxy group, 2,2-dicyanophenyloxy group, 2,3-dicyanophenyloxy group, 2,4-dicyanophenyloxy group, 2,5-dicyanophenyloxy group, 2,6-dicyanophenyloxy Group, 3,4-dicyanophenyloxy group, 3,5-dicyanophenyloxy group, 4-methoxyphenyloxy group, 2-methoxyphenyloxy group, 3-methoxyphenyloxy group, 4-ethoxyphenyloxy group, 2- A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as an ethoxyphenyloxy group, a 3-ethoxyphenyloxy group, etc., and a group represented by the above formula, or an inducing group thereof (for example, carboxy). A group derived from a group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), or the like is bonded. group corresponding to the -O-R ^102Z1 in group and compounds shown in Table 1Z1~ Table 14Z1 -O-R ^102Z1 Table 1-966 of the relevant group and Japanese Patent Application No. 2017-016290 to the compounds shown in the Examples thereof include an oxy group to which a hydrocarbon group having 1 to 10 carbon atoms or an inducible group thereof is bonded, and a group corresponding to ^{-OR 102Z1 in the compounds shown in Tables 1Z1 to 14Z1.}

-SO _2- R ^101Z1 includes methyl sulfonyl group, ethyl sulfonyl group, propyl sulfonyl group, butyl sulfonyl group, pentyl sulfonyl group, hexyl sulfonyl group, (2-ethyl) hexyl sulfonyl group, heptyl sulfonyl group, octyl sulfonyl group, Nonylsulfonyl group, decylsulfonyl group, undecylsulfonyl group, dodecylsulfonyl group, icosylsulfonyl group, phenylsulfonyl group, p-tolylsulfonyl group, etc., and groups represented by the above formula, etc. have 1 to 40 carbon atoms (1 to 40 carbon atoms). A hydrocarbon group having 1 to 20 carbon atoms or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms). (preferably octyl sulfamoyl group) derivatized group) bonded to a sulfonyl group and tables 1Z1~ Table 14Z1 group and Japanese Patent Application No. 2017-016290 corresponding to -SO ₂ -R ^101Z1 in the compound represented in the like -SO ₂ in the compounds shown in Table 1~966 -R ^101Z1 relevant group and the like in, preferably a sulfonyl group and tables 1Z1~ bonded hydrocarbon radical or a derivatized group having 1 to 10 carbon atoms group corresponding to -SO ₂ -R ^101Z1 in the compounds shown in Table 14Z1 and the like.

-SO ₂ N (R ^102Z1 ) ₂ is a sulfamoyl group;
N-methylsulfamoyl group, N-ethylsulfamoyl group, N-propylsulfamoyl group, N-isopropylsulfamoyl group, N-butylsulfamoyl group, N-isobutylsulfamoyl group, N- sec-butyl sulfamoyl group, N-tert-butyl sulfamoyl group, N-pentyl sulfamoyl group, N- (1-ethylpropyl) sulfamoyl group, N-hexyl sulfamoyl group, N- (2-) Ethyl) Hexyl sulfamoyl group, N-heptyl sulfamoyl group, N-octyl sulfamoyl group, N-nonyl sulfamoyl group, N-decyl sulfamoyl group, N-undecyl sulfamoyl group, N- One carbon number 1 to 40 (preferably 1 to 20) of one group such as dodecylsulfamoyl group, N-icosylsulfamoyl group, N-phenylsulfamoyl group, and a group represented by the above formula. (For example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably octyl sulfamoyl group). ^{_{) -SO 2 NH (R 102Z1X)}} ( provided that the sulfamoyl group and tables 1Z1~ Table 14Z1 compounds shown in substituted with derivatized groups) in such, except that R ^102Z1X is not a hydrogen atom, R ^102Z1 -SO ₂ NH (R ^102Z1X) (provided that the compounds shown in Table 1 to 966 of the corresponding group and Japanese Patent Application No. 2017-016290 the same as is) and, except that R ^102Z1X is not a hydrogen atom, R ^102Z1 (Same as))

N, N-dimethylsulfamoyl group, N, N-ethylmethylsulfamoyl group, N, N-diethylsulfamoyl group, N, N-propylmethylsulfamoyl group, N, N-dipropylsulfamoyl Group, N, N-isopropylmethylsulfamoyl group, N, N-diisopropylsulfamoyl group, N, N-tert-butylmethylsulfamoyl group, N, N-diisobutylsulfamoyl group, N, N- Disec-butyl sulfamoyl group, N, N-ditert-butyl sulfamoyl group, N, N-butylmethyl sulfamoyl group, N, N-dibutyl sulfamoyl group, N, N-dipentyl sulfa Moyl group, N, N-di (1-ethylpropyl) sulfamoyl group, N, N-dihexyl sulfamoyl group, N, N-di (2-ethyl) hexyl sulfamoyl group, N, N-diheptylsul Famoyl group, N, N-octylmethylsulfamoyl group, N, N-dioctylsulfamoyl group, N, N-dinonyl sulfamoyl group, N, N-decylmethylsulfamoyl group, N, N- Undecylmethyl sulfamoyl group, N, N-dodecylmethyl sulfamoyl group, N, N-icosylmethyl sulfamoyl group, N, N-phenylmethyl sulfamoyl group, N, N-diphenyl sulfamoyl Two hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group and a group represented by the above formula or a derivatizing group thereof (for example, a carboxy group, a sulfo group, a nitro group, etc. Sulfamoyl groups substituted with hydroxy groups, halogens (preferably chlorine atoms), alkylsulfamoyl groups having 1 to 10 carbon atoms (preferably octylsulfamoyl groups) and the like, and sulfamoyl groups in Tables 1Z1 to Tables 1Z1 to Table. _{Group corresponding to -SO 2} N (R ^102Z1X ) ₂ (however, R ^{102Z1X is the same as R 102Z1} except that it does not become a hydrogen atom) in the compound shown in 14Z1 and Table 1 of Japanese Patent Application No. 2017-016290. Among the compounds shown in ~ 966, groups corresponding to −SO ₂ N (R ^102Z1X ) ₂ (however, R ^{102Z1X is the same as R 102Z1} except that it does not become a hydrogen atom) can be mentioned.
Preferably, it corresponds to _{−SO 2} N (R 102Z1) ₂ in the sulfamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or an inducible group thereof and the compounds shown in Tables 1Z1 to ^14Z1. The group etc. can be mentioned.

^-CON (R 102Z1) ₂ is a carbamoyl group;
N-methylcarbamoyl group, N-ethylcarbamoyl group, N-propylcarbamoyl group, N-isopropylcarbamoyl group, N-butylcarbamoyl group, N-isobutylcarbamoyl group, N-sec-butylcarbamoyl group, N-tert-butylcarbamoyl group. Group, N-pentylcarbamoyl group, N- (1-ethylpropyl) carbamoyl group, N-hexylcarbamoyl group, N- (2-ethyl) hexylcarbamoyl group, N-heptylcarbamoyl group, N-octylcarbamoyl group, N- One of nonylcarbamoyl group, N-decylcarbamoyl group, N-undecylcarbamoyl group, N-dodecylcarbamoyl group, N-icosylcarbamoyl group, N-phenylcarbamoyl group and the like, and a group represented by the above formula. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), and 1 to 10 carbon atoms. -CONH (R ^102Z1X ) (where R ^{102Z1X is the same as R 102Z1} except that it does not become a hydrogen atom), and in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290, -CONH (R ^102Z1X ) (however, R ^102Z1X is It is the same as ^{R 102 Z1} except that it does not become a hydrogen atom).

N, N-dimethylcarbamoyl group, N, N-ethylmethylcarbamoyl group, N, N-diethylcarbamoyl group, N, N-propylmethylcarbamoyl group, N, N-dipropylcarbamoyl group, N, N-isopropylmethylcarbamoyl Group, N, N-diisopropylcarbamoyl group, N, N-tert-butylmethylcarbamoyl group, N, N-diisobutylcarbamoyl group, N, N-disec-butylcarbamoyl group, N, N-ditert-butylcarbamoyl group , N, N-butylmethylcarbamoyl group, N, N-dibutylcarbamoyl group, N, N-butyloctylcarbamoyl group, N, N-dipentylcarbamoyl group, N, N-di (1-ethylpropyl) carbamoyl group, N , N-dihexylcarbamoyl group, N, N-di (2-ethyl) hexylcarbamoyl group, N, N-diheptylcarbamoyl group, N, N-octylmethylcarbamoyl group, N, N-dioctylcarbamoyl group, N, N -Dinonylcarbamoyl group, N, N-decylmethylcarbamoyl group, N, N-undecylmethylcarbamoyl group, N, N-dodecylmethylcarbamoyl group, N, N-icosylmethylcarbamoyl group, N, N-phenylmethyl Two hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a carbamoyl group and an N, N-diphenylcarbamoyl group, and a group represented by the above formula, or an inducing group thereof (for example, 1 to 20 carbon atoms). Substituted with a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably a group derived with an octyl sulfamoyl group), or the like). ^{Group corresponding to -CON} (R 102Z1X) ₂ (however, R ^102Z1X is the same as R 102Z1 except that it does not become a hydrogen atom) in the carbamoyl group and the compounds shown in Tables 1Z1 to ^14Z1. In the compounds shown in Tables 1 to 966 of No. 2017-016290, ^{groups corresponding to −CON} (R 102Z1X) ₂ (however, R ^{102Z1X is the same as R 102Z1} except that it does not become a hydrogen atom) can be mentioned. ,
Preferably, a carbamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or an inducible group thereof, and a group corresponding to ^-CON (R 102Z1) _{2 in the compounds shown in Tables 1Z1 to 14Z1 and the like.} Can be mentioned.

−N (R ^102Z1 ) ₂ is an amino group;
N-methylamino group, N-ethylamino group, N-propylamino group, N-isopropylamino group, N-butylamino group, N-isobutylamino group, N-sec-butylamino group, N-tert-butylamino Group, N-pentylamino group, N-hexylamino group, N- (2-ethyl) hexylamino group, N-heptylamino group, N-octylamino group, N-nonylamino group, N-decylamino group, N-un A decylamino group, an N-dodecylamino group, an N-icosylamino group, an N-phenylamino group, etc., and a group represented by the above formula, etc., which have 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms). A hydrocarbon group or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group)). ^{-NH (R 102Z1X} ) in the amino groups substituted with (groups induced by etc.) and the compounds shown in Tables 1Z1 to 14Z1 (however, R ^102Z1X is the same as ^{R 102Z1} except that it does not become a hydrogen atom. ^{-NH (R 102Z1X} ) in the groups corresponding to (there is) and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290 (however, R ^102Z1X is the same as ^{R 102Z1} except that it does not become a hydrogen atom). Group corresponding to;

N, N-dimethylamino group, N, N-ethylmethylamino group, N, N-diethylamino group, N, N-propylmethylamino group, N, N-dipropylamino group, N, N-isopropylmethylamino group , N, N-diisopropylamino group, N, N-tert-butylmethylamino group, N, N-diisobutylamino group, N, N-disec-butylamino group, N, N-ditert-butylamino group, N, N-butylmethylamino group, N, N-dibutylamino group, N, N-dipentylamino group, N, N-di (1-ethylpropyl) amino group, N, N-dihexylamino group, N, N -Di (2-ethyl) hexylamino group, N, N-diheptylamino group, N, N-dioctylamino group, N, N-dinonylamino group, N, N-decylmethylamino group, N, N-undecyl Methylamino group, N, N-dodecylmethylamino group, N, N-icosylmethylamino group, N, N-phenylmethylamino group, N, N-diphenylamino group, etc., and groups represented by the above formulas. 2 hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or derivatizing groups thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon ^{-N (R 102Z1X} ) in amino groups substituted with an alkyl sulfamoyl group (preferably a group derivatized with an octyl sulfamoyl group) of numbers 1 to 10 and the compounds shown in Tables 1Z1 to 14Z1. ^{-N (R 102Z1X} ) _{2 in the groups corresponding to 2} (however, R ^{102Z1X is the same as R 102Z1} except that it does not become a hydrogen atom) and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290. (However, R ^102Z1X is the same as ^{R 102Z1} except that it does not become a hydrogen atom.)
Preferably, an amino group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or an inducible group thereof, and a group corresponding to ^{-N (R 102Z1} ) _{2 in the compounds shown in Tables 1Z1 to 14Z1 and the like.} Can be mentioned.

-NHCO-R ^102Z1 includes formylamino groups; acetylamino groups, propanoylamino groups, butanoylamino groups, 2,2-dimethylpropanoylamino groups, pentanoylamino groups, hexanoylamino groups, (2-ethyl). ) Hexanoylamino group, Heptanoylamino group, Octanoylamino group, Nonanoylamino group, Decanoylamino group, Undecanoylamino group, Dodecanoylamino group, Henikosanoylamino group, Bencoylamino group, etc. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group represented by the above formula or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, or a halogen (preferably). Is a chlorine atom), a carbonylamino group (a group derivatized with an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc.) is bonded (when the carbonylamino group is an acylamino group). , The number of carbon atoms is 1 to 40), and in the compounds shown in Tables 1Z1 to ^14Z1 , the group corresponding to -NHCO-R 102Z1 and in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290-NHCO- The groups corresponding to ^{R 102Z1 are listed.}
Preferably, a carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or an inducible group thereof is bonded (when the carbonylamino group is an alkanoylamino group, the carbon number is more preferably 1 to 10) and Table 1Z1. In the compounds shown in Table 14Z1, ^{groups corresponding to -NHCO-R 102Z1} and the like can be mentioned.

-NHCON (R ^102Z1 ) ₂ ^{includes the groups listed above and the groups corresponding to -NHCON (R 102Z1} ) ₂ in the compounds shown in Tables 1Z1 to 14Z1, Tables 1 to 966 of Japanese Patent Application No. 2017-016290. Examples of the compounds shown in (1) include groups corresponding to ^{−NHCON (R 102Z1} _{) 2.}

-NHCOOR ^{102Z1 includes the groups listed above, the groups corresponding to -NHCOOR 102Z1} in the compounds shown in Tables 1Z1 to 14Z1, and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. ^2017-016290. Examples of the group corresponding to.

-OCON (R ^102Z1 ) ₂ ^{includes the groups listed above and the groups corresponding to -OCON (R 102Z1} ) ₂ in the compounds shown in Tables 1Z1 to 14Z1, Tables 1 to 966 of Japanese Patent Application No. 2017-016290. ^{Examples of the} compounds shown in (1) include groups corresponding to _{−OCON (R 102Z1) 2.}

As the halogen atom, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom and the like are preferable.
Examples of _{M of −SO 3} M and −CO ₂ M include hydrogen atom; alkali metal atom such as lithium atom, sodium atom and potassium atom, and preferably hydrogen atom, sodium atom and potassium atom.

-CO-R ^102Z1 , -COO-R ^102Z1 , -OCO-R ^102Z1 , -COCO-R ^102Z1 , -O-R ^102Z1 , -SO _2- R ^102Z1 , -SO ₂ N (R ^102Z1 ) ₂ , -CON Substituents (first substituents) contained in (R ^102Z1 ) ₂ , -N (R ^102Z1 ) ₂ , -NHCO-R ^102Z1 , -NHCON (R ^102Z1 ) ₂ , -NHCOOR ^102Z1 , -OCON (R ^102Z1 ) _2. May be one or more, and the two or more substituents may be the same or different independently of each other.
Further, the first substituent may have another substituent (second substituent) bonded to the hydrocarbon group contained in a part thereof. The second substituent can be selected from the same groups as the first substituent.

The ^{rings formed by R 2Z1} and R ^3Z1 , R ^3Z1 and R ^4Z1 , and R ^4Z1 and R ^5Z1 are condensed with the benzene ring of the isoindoline skeleton of the compound represented by the formula (IZ1). The fused ring structures of the ring formed by R ^2Z1 and R ^3Z1 , R ^3Z1 and R ^4Z1 , and R ^4Z1 and R ^5Z1 and the benzene ring include inden, naphthalene, biphenylene, indacene, ashenanthrene, fluorene, phenanthrene, and phenanthrene. Hydrocyclic condensed ring structures such as anthracene, fluorantene, acephenanthrene, aceanthrene, triphenylene, pyrene, chrysene, N-methylphthalimide, N- (1-phenylethyl) phthalimide and tetracene, and their partial reductions ( For example, 9,10-dihydroanthracene, 1,2,3,4-tetrahydronaphthalene); indol, isoindole, indazole, quinoline, isoquinoline, phthalazine, quinoxaline, quinazoline, cinnoline, carbazole, carboline, phenanthrene, aclysine. , Perimidine, phenanthrene, phenazine and the like, nitrogen-containing fused heterocycles and their partial reductions; oxygen-containing condensed heterocycles such as 3-hydrobenzofuran 2-one and their partial reductions.

When R ^2Z1 and R ^3Z1 , R ^{3Z 1} and R ^{4Z 1} , and R ^{4Z 1} and R 5 ^{Z 1} form a ring, the ring may have a substituent. As the substituent, the hydrocarbon group represented by ^RO1Z1 , ^R1Z1 , ^R2Z1 , ^R3Z1 , ^R4Z1 , ^R5Z1 , ^R6Z1 , ^R7Z1 , ^R101Z1 and ^R102Z1 may have a substituent. The same as the group can be mentioned. Preferred examples of the substituent, and ^{R O1Z1, R 1Z1, R 2Z1} , R 3Z1, R 4Z1, R 5Z1, R 6Z1, R 7Z1, have a hydrocarbon group represented by R ^101Z1 and R ^102Z1 The same preferred substituents may be mentioned.

When R ^{3Z 1} and R 4 ^{Z 1} form a ring, ^{it is preferable that R 2Z 1} and R 5 ^{Z 1} are hydrogen atoms, amino groups and hydroxy groups independently of each other.
If R ^2Z1 and R ^3Z1 form a ring, it is preferable that the R ^4Z1 and R ^5Z1 do not form a ring, and more preferably R ^4Z1 and R ^5Z1 is a hydrogen atom.
In the case where R ^4Z1 and R ^5Z1 form a ring, it is preferable that the R ^2Z1 and R ^3Z1 do not form a ring, and more preferably R ^2Z1 and R ^3Z1 is a hydrogen atom.

In the present invention, R ^1Z1 , R ^{6Z 1} and R ⁷ Z 1 are preferably hydrogen atoms.

In the present invention, ^RO1Z1 is preferably a hydrocarbon group having 1 to 30 carbon atoms which may have a hydrogen atom or a substituent, and may have a hydrogen atom or a substituent. It is more preferably a hydrogen group of ~ 20, and further preferably a hydrogen group having 1 to 15 carbon atoms which may have a hydrogen atom or a substituent, and has a hydrogen atom or a substituent. It is particularly preferable that the hydrocarbon group has 1 to 10 carbon atoms, and may have a hydrogen atom or a substituent and may have a hydrocarbon group or a substituent having 1 to 6 carbon atoms. It is even more preferably a hydrocarbon group having 1 to 5 carbon atoms, particularly preferably a hydrogen atom, a methyl group, or an ethyl group, or a phenyl group, and most preferably a hydrogen atom, a methyl group, or an ethyl group. preferable.

At ^{least one of R 2Z1} , R ^3Z1 , R ^4Z1 and R ^5Z1 is −CO-R ^102Z1 , −COO-R ^101Z1 , − OCO-R ^102Z1 , -COCO-R ^102Z1 , -O-R ^102Z1 , -SO _2- R ^101Z1 , -SO ₂ N (R ^102Z1 ) ₂ ^{, -CON} (R 102Z1) ₂ , -N (R ^102Z1 ) ₂ , -NHCO-R ^102Z1 , -NHCO-N (R ^102Z1 ) ₂ , -NHCOOR ^102Z1 , -OCON (R ^102Z1 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, substituent It is preferably a hydrocarbon group having 1 to 40 carbon atoms or a heterocyclic group which may have a substituent.
A hydrocarbon group having 1 to 40 carbon atoms, which may have a substituent, a halogen atom, -N (R ^102Z1 ) ₂ , a nitro group, and a hydrogen atom in which all or a part of the hydrocarbon atom is substituted with a fluorine atom has 1 to 1 carbon atoms. More preferably, there are 20 hydrocarbon groups, -NHCO-R ^102Z1 , ^{-OR 102Z1} , -SO ₃ M or -CO _{2 M.}
It is more preferably a hydrocarbon group having 1 to 40 carbon atoms which may have a nitro group or a substituent.
Even more preferably, it is a nitro group or a tert-butyl group. Or, R ^2Z1 and R ^3Z1, R ^3Z1 and R ^4Z1, or R ^4Z1 and at least one pair of R ^5Z1 is, it is preferable to form a ring.

At least one of ^{R 2Z1} , R ^3Z1 , R ^4Z1 and R ^5Z1 of the compound (IZ1) is ^{-CO-R 102Z1} , -COO-R ^101Z1 , -OCO-R ^102Z1 , -COCO-R ^102Z1 , -O-. R ^102Z1 , -SO ₂ -R ^101Z1 , -SO ₂ N (R ^102Z1 ) ₂ ^{, -CON} (R 102Z1) ₂ , -N (R ^102Z1 ) ₂ , -NHCO-R ^102Z1 , -NHCO-N (R ^102Z1 ) ₂ , -NHCOOR ^102Z1 , -OCON (R ^102Z1 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, hydrocarbon having 1 to 40 carbon atoms which may have a substituent. is a group or an optionally substituted heterocyclic group, or R ^2Z1 and R ^3Z1, R ^3Z1 and R ^4Z1, and to form a ring, at least one pair binding of R ^4Z1 and R ^5Z1 The compound is preferable (hereinafter, the compound may be referred to as "compound (IZ1-B)"). When the compound (IZ1) is the compound (IZ1-B), the phase difference value of the color filter produced from the coloring composition becomes small.

From the viewpoint of reducing the phase difference value of the color filter prepared from the coloring composition ^{, at least one of R 2Z1} , R ^3Z1 , R ^{4Z 1} , and R ^5Z 1 may have a substituent and has 1 to 40 carbon atoms. Hydrocarbon group, halogen atom, -N (R ^102Z1 ) ₂ , nitro group, hydrocarbon group with 1 to 20 carbon atoms in which all or part of the hydrogen atom is replaced by a fluorine atom, -NHCO-R ^102Z1 , -O It is preferably −R ^102Z1 , −SO ₃ M or −CO ₂ M, more preferably a hydrocarbon group having 1 to 40 carbon atoms which may have a nitro group or a substituent, and a nitro group or It is more preferably a tert-butyl group. Particularly preferably, R ^3Z1 is a nitro group or a tert-butyl group and R ^2Z1 , R ^4Z1 and R ^5Z1 are hydrogen atoms, or R ^2Z1 , R ^3Z1 and R ^5Z1 are hydrogen atoms and R ^4Z1. Is a nitro group or a tert-butyl group.

［式（ＩＺ１−Ｂ）中、
Ｒ^O11Z1は、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^1Z1、Ｒ^21Z1、Ｒ^31Z1、Ｒ^41Z1、Ｒ^51Z1、Ｒ^61Z1、及びＲ^71Z1は、互いに独立に、水素原子、−ＣＯ−Ｒ^102Z1、−ＣＯＯ−Ｒ^101Z1、−ＯＣＯ−Ｒ^102Z1、−ＣＯＣＯ−Ｒ^102Z1、−Ｏ−Ｒ^102Z1、−ＳＯ₂−Ｒ^101Z1、−ＳＯ₂Ｎ（Ｒ^102Z1）₂、−ＣＯＮ（Ｒ^102Z1）₂、−Ｎ（Ｒ^102Z1）₂、−ＮＨＣＯ−Ｒ^102Z1、−ＮＨＣＯ−Ｎ（Ｒ^102Z1）₂、−ＮＨＣＯＯＲ^102Z1、−ＯＣＯＮ（Ｒ^102Z1）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^21Z1とＲ^31Z1、Ｒ^31Z1とＲ^41Z1、及びＲ^41Z1とＲ^51Z1は、それぞれ互いに結合して環を形成してもよい。
ただし、Ｒ^21Z1、Ｒ^31Z1、Ｒ^41Z1、及びＲ^51Z1の少なくとも一つは、−ＣＯ−Ｒ^102Z1、−ＣＯＯ−Ｒ^101Z1、−ＯＣＯ−Ｒ^102Z1、−ＣＯＣＯ−Ｒ^102Z1、−Ｏ−Ｒ^102Z1、−ＳＯ₂−Ｒ^101Z1、−ＳＯ₂Ｎ（Ｒ^102Z1）₂、−ＣＯＮ（Ｒ^102Z1）₂、−Ｎ（Ｒ^102Z1）₂、−ＮＨＣＯ−Ｒ^102Z1、−ＮＨＣＯ−Ｎ（Ｒ^102Z1）₂、−ＮＨＣＯＯＲ^102Z1、−ＯＣＯＮ（Ｒ^102Z1）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基或いは置換基を有していてもよい複素環基であるか、又はＲ^21Z1とＲ^31Z1、Ｒ^31Z1とＲ^41Z1、及びＲ^41Z1とＲ^51Z1の少なくとも一組が結合して環を形成している。
Ｒ^101Z1は、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102Z1は、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、水素原子又はアルカリ金属原子を表す。
Ｒ^101Z1、Ｒ^102Z1及びＭが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
波線は、Ｅ体又はＺ体を表す。］ The compound (IZ1-B) is defined by the formula as follows.

[In the formula (IZ1-B),
^RO11Z1 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
R ^1Z1 , R ^21Z1 , R ^31Z1 , R ^41Z1 , R ^51Z1 , R ^61Z1 , and R ^71Z1 are independent of each other, hydrogen atom, -CO-R ^102Z1 , -COO-R ^101Z1 , -OCO-R ^102Z1 , -COCO. -R ^102Z1 , -O-R ^102Z1 , -SO ₂ -R ^101Z1 , -SO ₂ N (R ^102Z1 ) ₂ ^{, -CON} (R 102Z1) ₂ , -N (R ^102Z1 ) ₂ , -NHCO-R ^102Z1 ,- NHCO-N (R ^102Z1 ) ₂ , -NHCOOR ^102Z1 , -OCON (R ^102Z1 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, carbon which may have a substituent. Represents a heterocyclic group which may have a hydrocarbon group or a substituent of the number 1 to 40.
R ^21Z1 and R ^31Z1 , R ^31Z1 and R ^41Z1 , and R ^41Z1 and R ^51Z1 may be coupled to each other to form a ring, respectively.
However, at least one of ^{R 21Z1} , R ^31Z1 , R ^41Z1 and R ^{51Z1 is -CO-R 102Z1} , -COO-R ^101Z1 , -OCO-R ^102Z1 , -COCO-R ^102Z1 , -O-R ^102Z1 , -SO ₂ -R ^101Z1 , -SO ₂ N (R ^102Z1 ) ₂ ^{, -CON} (R 102Z1) ₂ , -N (R ^102Z1 ) ₂ , -NHCO-R ^102Z1 , -NHCO-N (R ^102Z1 ) ₂ ,- NHCOOR ^102Z1 , -OCON (R ^102Z1 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, hydrocarbon group or substitution having 1 to 40 carbon atoms which may have a substituent. It is a heterocyclic group which may have a group, or ^{at least one set of R 21Z1} and R ^31Z1 , R ^31Z1 and R ^41Z1 , and R ^41Z1 and R ^51Z1 are bonded to form a ring.
R ^101Z1 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102Z1 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
M represents a hydrogen atom or an alkali metal atom.
When a ^{plurality of R 101Z1} , R ^{102 Z1} and M exist, they may be the same or different.
The wavy line represents an E-form or a Z-form. ]

Wherein ^{(IZ1-B), R O11Z1} , R 21Z1, R 31Z1, R 41Z1, R 51Z1, R 61Z1, and R ^71Z1 are each, R ^O1Z1 in formula ^{(IZ1), R 2Z1, R} 3Z1, R 4Z1 , R ^5Z1 , R ^6Z1 , and the same as ^{R 7Z1.}

In the formula (IZ1-B), the preferred ^RO11Z1 , ^R21Z1 , ^R31Z1 , ^R41Z1 , ^R51Z1 , ^R61Z1 , and ^{R71Z1 are R O1Z1} , R ^2Z1 , R ^3Z1 , R in the formula (IZ1), respectively. ^The same as the preferred ones of 4Z1, R ^5Z1 , R ^6Z1 and R ^{7Z1 can be mentioned.}

In the formula (IZI-B), ^{it is preferable that (Aspect 1) R 1Z1} , R ^{61Z 1} and R ^{71Z 1} are hydrogen atoms. It is also preferable that (Aspect 2) ^RO11Z1 is a hydrocarbon group having 1 to 10 carbon atoms which may have a hydrogen atom or a substituent. Further (Aspect 3) ^{It is also preferable that at least one of R 21Z1} , R ^31Z1 , R ^41Z1 and R ^51Z1 is a nitro group or a tert-butyl group. The above-mentioned aspects 1 to 3 may be adopted alone or in combination as appropriate.

Specific examples of the compound (IZ1) include, for example, in the formula (IZ1-aa), Table 1Z1, Table 2Z1, Table 3Z1, Table 4Z1, Table 5Z1, Table 6Z1, Table 7Z1, Table 8Z1, Table 9Z1, Table 10Z1, Examples thereof include compounds (IZ1-1) to compounds (IZ1-529) having substituents shown in Tables 11Z1, Table 12Z1, Table 13Z1, and Table 14Z1 or alkali metal salts thereof.
B ^a1Z1 B ^a2Z1 is a formula (BB1) to a formula (BB60), a formula (BBK2), a formula (BBK3), a formula (BBK4), a formula (BBK14), a formula (BBI1), a formula (BBO8), a formula (BBO10). , Represents any of the partial structures represented by the formula (BBD1) and the formula (BBJ2). B ^a1Z1 B ^a2Z1 includes the formula (BB1), the formula (BB6), the formula (BB8), the formula (BB11), the formula (BB14), the formula (BB19), the formula (BB37), the formula (BB58), and the formula (BBJ2). ), The formula (BBO8) and the formula (BBO10) are preferable, and the formula (BB1), the formula (BB6), and the formula (BB19) are more preferable.

The symbols in Table 1Z1, Table 2Z1, Table 3Z1, Table 4Z1, Table 5Z1, Table 6Z1, Table 7Z1, Table 8Z1, Table 9Z1, Table 10Z1, Table 11Z1, Table 12Z1, Table 13Z1, and Table 14Z1 are as follows. Represents a partial structure. In addition, in the partial structure
"Me" represents a methyl group
"Et" represents an ethyl group
"Bu" represents a butyl group
"TBu" represents a tert-butyl group and represents
"Hex" represents a hexyl group
"Oct" represents an octyl group
"2EH" represents a 2-ethylhexyl group and represents
"CHM" represents a cyclohexylmethyl group
"CH" represents a cyclohexyl group
"PH" represents a phenyl group
"BZ" represents a benzyl group
"NPR" represents a propyl group
"IPR" represents an isopropyl group
"IBu" represents an isobutyl group and represents
"EOE" stands for −CH ₂ CH ₂ OCH ₂ CH ₃
"ALL" represents an allyl group
"HYE" represents a 2-hydroxyethyl group
"COM" stands for -CO-CH ₃
"COE" stands for -COO-CH ₂ CH ₃
"OCM" stands for -OCO-CH ₃
"OME" stands for -O-CH ₃ and represents
"SOT" represents a tosyl group
“SNH” stands for −SO ₂ NH-CH ₂ CH (CH ₂ CH ₃ ) ((CH ₂ ) ₃ CH ₃ ).
“SN2” stands for −SO ₂ N (CH ₃ ) ((CH ₂ ) ₇ CH ₃ ).
"CNM" stands for -CONHCH ₃
"CN2" stands for -CON (CH ₃ ) C ₆ H ₅ and represents
"NPH" stands for -NHC ₆ H ₅ and represents
"NOT" stands for -N ((CH ₂ ) ₇ CH ₃ ) ₂
"NCO" stands for -NHCO ((CH ₂ ) ₄ CH ₃ )
"F" represents a fluorine atom
"Cl" represents a chlorine atom
"Br" represents a bromine atom
"CN" represents a cyano group
"NO2" represents a nitro group
"SUA" stands for -SO ₃ H
"CBA" stands for -CO ₂ H and represents
"CHO" stands for -CHO
"OCH" stands for -OCOH
"OH" stands for -OH
"SFM" stands for -SO ₂ NH ₂
"CBM" stands for -CONH _{2
"NH 2} " stands for -NH 2
"NCH" is -NHCOH
Represents.
In the partial structure shown by the following formula, * represents a bond.

Also, B ^A1Z1 and B ^A2Z1 each represent a bond, bond B ^A2Z1 becomes less bond B ^2, B ^A1Z1 is less than B ² when B ^A1Z1 is a bond of the B ¹ or less When is, B ^{a2 Z1} becomes a bond of B ^{1 below.}

For example, the compound (IZ1-1) is a compound represented by the formula (IZ1-1).

As a compound (IZ1),
Compound (IZ1-1) to compound (IZ1-171) and compound (IZ1-258) to compound (IZ1-529) are preferable.
Compound (IZ1-1) to compound (IZ1-171) and compound (IZ1-258) to compound (IZ1-471) are more preferable.
Compounds (IZ1-1) to compounds (IZ1-171) are even more preferred, compounds (IZ1-1) to compounds (IZ1-111) are even more preferred, and compounds (IZ1-1) to compounds (IZ1-54) are particularly preferred. Preferably, compound (IZ1-2) to compound (IZ1-3), compound (IZ1-20) to compound (IZ1-21), and compound (IZ1-38) to compound (IZ1-39) are particularly preferable.

Specific examples of the compound (IZ1) include Table 1Z1, Table 2Z1, Table 3Z1, Table 4Z1, Table 5Z1, Table 6Z1, Table 7Z1, Table 8Z1, Table 9Z1, Table 10Z1, Table 11Z1, Table 12Z1, Table 13Z1, and. _{Examples thereof include compounds in which -SO 3} M or -CO ₂ M is substituted for 1 to 3 hydrogen atoms contained in the compounds shown in Table 14Z1. For example, a compound in which 1 to 3 sulfo groups are bonded to the compound (IZ1-1) in Table 1Z1 is represented by the following structure. However, in the formula, − (SO ₃ H) means that any hydrogen atom of the compound (IZ1-1) in Table 1Z1 is substituted.

In the present invention
Compound (IZ1-1) to compound (IZ1-171), compound (IZ1-258) to compound (IZ1-529) to which 1 to 3 -SO ₃ M or -CO ₂ M are bound. Is preferable
Compound (IZ1-1) to compound (IZ1-171), compound (IZ1-258) to compound (IZ1-431) to which 1 to 3 -SO ₃ M or -CO ₂ M are bound. Is more preferable
More preferably, it is a compound in which _{1 to 3 -SO 3} M or -CO ₂ M are bound to the compound (IZ1-1) to the compound (IZ1-171).
Even more preferably, it is a compound in which _{1 to 3 -SO 3} M or -CO ₂ M are bound to compound (IZ1-1) to compound (IZ1-111).
Particularly preferably, it is a compound in which _{1 to 3 -SO 3} M or -CO ₂ M are bound to the compound (IZ1-1) to the compound (IZ1-54).
Compound (IZ1-2) to compound (IZ1-3), compound (IZ1-20) to compound (IZ1-21), and compound (IZ1-38) to compound (IZ1-39) have 1 to 3 − It is particularly preferably a compound to which SO ₃ M or -CO _{2 M is bound.}

As the compound (IZ1), in the formula (IZ1),
^RO1Z1 is a hydrocarbon group having 1 to 20 carbon atoms which may have a hydrogen atom or _{a substituent selected from the group consisting of -SO 3} M and -CO _{2 M.}
R ^1Z 1 is a hydrocarbon group having 1 to 20 carbon atoms, which may have a substituent selected from the group consisting of a hydrogen atom, -SO ₃ M and -CO _{2 M, -SO 3} M or -CO ₂ M and
Each of R ^{2Z1 to} R ^5Z1 has a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogen atom, -N (R ^102Z1 ) ₂ , a nitro group, and a fluorine atom in all or part of the hydrogen atom. Substituted hydrocarbon groups with 1 to 20 carbon atoms, -NHCO-R ^102Z1 , ^{-OR 102Z1} , -SO ₃ M or -CO ₂ M.
R ^6Z1 and R ^7Z1 are independent of each other and may have a substituent selected from the group consisting of a hydrogen atom, −SO ₃ M and −CO ₂ M, a hydrocarbon group having 1 to 20 carbon atoms, −. SO ₃ M or -CO ₂ M,
R ^102Z1 is a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent selected from the group consisting of _{-SO 3} M and -CO _{2 M.}
M is preferably a compound which is a hydrogen atom or an alkali metal atom.
^RO1Z1 is a hydrocarbon group having 1 to 10 carbon atoms which may have a hydrogen atom or _{a substituent selected from the group consisting of -SO 3} M and -CO _{2 M.}
R ^1Z1 is a hydrogen atom
Each of R ^{2Z1 to} R ^5Z1 has a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, -N (R ^102Z1 ) ₂ , a nitro group, and a fluorine atom in all or part of the hydrogen atom. Substituted hydrocarbon groups with 1 to 10 carbon atoms, -NHCO-R ^102Z1 , ^{-OR 102Z1} , -SO ₃ M or -CO ₂ M.
R ^6Z1 and R ^7Z1 are hydrocarbons having 1 to 10 carbon atoms which are the same group and may have a hydrogen atom or a substituent selected from the group consisting of _{-SO 3} M and -CO _{2 M.} Is the basis and
R ^102Z1 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of _{-SO 3} M and -CO _{2 M.}
M is more preferably a compound which is a hydrogen atom or an alkali metal atom.
^RO1Z1 is a hydrocarbon group having 1 to 10 carbon atoms which may have a hydrogen atom or _{a substituent selected from the group consisting of -SO 3} M and -CO _{2 M.}
R ^1Z1 is a hydrogen atom
R ^{2Z1 to} R ^5Z1 are independently hydrogen atom, hydrocarbon group having 1 to 10 carbon atoms, halogen atom, -N (R ^102Z1 ) ₂ , nitro group, trifluoromethyl group, ^{-OR 102Z1} , -SO ₃ M or -CO ₂ M,
R ^6Z1 and R ^7Z1 are the same group, a hydrogen atom, or a hydrocarbon group having 1 to 10 carbon atoms.
R ^102Z1 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of _{-SO 3} M and -CO _{2 M.}
M is more preferably a compound which is a hydrogen atom or an alkali metal atom.

As for the compound (IZ1), when R ^1Z1 is a hydrogen atom, a compound represented by the formula (pt1Z1) (hereinafter, may be referred to as a phthalonitrile compound) is referred to as a compound represented by the formula (pt2Z1) (hereinafter, referred to as an alkoxide compound). It can be produced by further reacting the compound represented by the formula (pt3Z1) with the compound represented by the formula (pt4Z1) in the presence of an acid. When R ^1Z1 is other than a hydrogen atom, the compound (IZ1) can be produced by further reacting with a compound represented by the formula (pt5Z1).

[In the formula (pt1Z1), formula (pt2Z1), formula (pt3Z1), formula (pt4Z1), formula (pt5Z1) and formula (IZ1), ^RO1Z1 , ^R1Z1 , ^R2Z1 , ^R3Z1 , ^R4Z1 , ^R5Z1 , R ^6Z1 and R ^7Z1 have the same meanings as described above.
R ^14Z1 represents an alkyl group having 1 to 20 carbon atoms.
M ^1Z1 represents an alkali metal atom.
LG represents a halogen atom, a methanesulfonyloxy group, a toluenesulfonyloxy group or a trifluoromethanesulfonyloxy group. ]

^Examples of the alkyl group having 1 to 20 carbon atoms represented by R 14Z1 include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, a sec-butyl group and a tert-butyl group, which are preferable. Examples include alkyl groups having 1 to 6 carbon atoms.
Examples of the alkali metal atom represented by M ^{1Z 1} include a lithium atom, a sodium atom and a potassium atom.

The amount of the alkoxide compound used is usually 0.1 to 10 mol, preferably 0.2 to 5 mol, and more preferably 0.3 to 3 mol, based on 1 mol of the phthalonitrile compound. More preferably, it is 0.4 to 2 mol.

The amount of the compound (pt3Z1) used is usually 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, still more preferably 1 mol, relative to 1 mol of the phthalonitrile compound. ~ 2 mol.
The amount of the compound (pt4Z1) used is usually 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, still more preferably 1 mol, relative to 1 mol of the phthalonitrile compound. ~ 2 mol.

Examples of the acid include inorganic acids such as hydrochloric acid, hydrobromic acid, hydroiodic acid, sulfuric acid, nitric acid, fluorosulfonic acid and phosphoric acid; sulfonic acids such as methanesulfonic acid, trifluoromethanesulfonic acid and p-toluenesulfonic acid; Examples thereof include carboxylic acids such as acetic acid, citric acid, formic acid, gluconic acid, lactic acid, oxalic acid and tartrate acid, preferably hydrochloric acid, hydrobromic acid, sulfuric acid, methanesulfonic acid, trifluoromethanesulfonic acid, p-toluenesulfonic acid and Examples include carboxylic acids, more preferably acetic acids.
The amount of the acid used is usually 1 to 20 mol, preferably 1 to 10 mol, more preferably 1 to 8 mol, still more preferably 1 to 6 mol, based on 1 mol of the phthalonitrile compound. be.

The reaction of the phthalonitrile compound, the alkoxide compound, the compound (pt3Z1) and the compound (pt4Z1) is usually carried out in the presence of a solvent.
As the solvent, water; a nitrile solvent such as acetonitrile; an alcohol solvent such as methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol and 1-octanol; an ether solvent such as tetrahydrofuran; a ketone solvent such as acetone; acetic acid. Ester solvents such as ethyl; aliphatic hydrocarbon solvents such as hexane; aromatic hydrocarbon solvents such as toluene; halogenated hydrocarbon solvents such as methylene chloride and chloroform; amides such as N, N-dimethylformaldehyde and N-methylpyrrolidone. Solvents: Sulfoxide solvents such as dimethylsulfoxide, preferably water, nitrile solvents, alcohol solvents, ether solvents, ketone solvents, ester solvents, aromatic hydrocarbon solvents, halogenated hydrocarbon solvents, amide solvents and sulfoxide solvents. More preferably, water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, tetrahydrofuran, acetone, ethyl acetate, toluene, methylene chloride, chloroform, N, N-dimethylformaldehyde. , N-Methylpyrrolidone and dimethylsulfoxide, more preferably water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, acetone, methylene chloride, chloroform, N, N. -Dimethylformaldehyde, N-methylpyrrolidone and dimethylsulfoxide are mentioned, and water, acetonitrile, methanol, ethanol and 2-propanol are particularly preferable.
The amount of the solvent used is usually 1 to 1000 parts by mass with respect to 1 part by mass of the phthalonitrile compound.

The reaction temperature is usually 0 to 200 ° C, preferably 0 to 100 ° C, more preferably 0 to 70 ° C, still more preferably 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

The amount of the compound (pt5Z1) used is usually 1 to 10 mol, preferably 1 to 5 mol, and more preferably 1 to 3 mol, relative to 1 mol of the compound (IZ1) in which ^{R 1Z1 is a hydrogen atom.} It is more preferably 1 to 2 mol.

When the compound (pt5Z1) is reacted, it is preferable that a base coexists. Bases include organic bases such as triethylamine, 4- (N, N-dimethylamino) pyridine, pyridine and piperidine; metal alkoxides such as sodium methoxide, sodium ethoxide, sodium tert-butoxide and potassium tert-butoxide; butyl lithium. , Tert-Organic metal compounds such as butyllithium and phenyllithium; and inorganic bases such as lithium hydroxide, sodium hydroxide and potassium hydroxide.

The amount of the base used is usually 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, and further, with respect to 1 mol of the compound (IZ1) in which ^{R 1Z1 is a hydrogen atom.} It is preferably 1 to 2 mol.

The reaction of compound (pt5Z1) is usually carried out in the presence of a solvent. The solvent can be selected from the same range as described above.
The amount of the solvent used is usually 1 to 1000 parts by mass with respect to 1 part by mass of the compound (IZ1) in which ^{R 1Z1 is a hydrogen atom.} The reaction temperature of the compound (pt5) is usually −90 to 200 ° C., preferably −80 to 100 ° C., and more preferably 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

If compound (IZ1) _{does not have a sulfo group or -SO 3} M ²² , the compound (IZ1) is reacted with a sulphonizing agent such as fuming sulfuric acid or chlorosulfuric acid to cause a sulfo group or -SO ₃ M ^22. Can be introduced.
M ²² represents an alkali metal atom.
Examples ^{of the alkali metal atom represented by M 22} include a lithium atom, a sodium atom and a potassium atom.

_{The amount of SO 3} used in fuming sulfuric acid is usually 1 to 50 mol, preferably 5 to 40 mol, more preferably 5 to 30 mol, still more preferably 5 to 30 mol, per 1 mol of compound (IZ1). It is 5 to 25 mol.
The amount of sulfuric acid used in fuming sulfuric acid is usually 1 to 200 mol, preferably 10 to 100 mol, more preferably 10 to 75 mol, and further preferably 10 to 1 mol of compound (IZ1). ~ 50 mol.

The amount of chlorosulfonic acid used is usually 1 to 500 mol, preferably 10 to 300 mol, more preferably 10 to 200 mol, still more preferably 10 to 150 mol, relative to 1 mol of compound (IZ1). It is a mole.

The reaction temperature for sulfonation is usually -20 to 200 ° C, preferably -10 to 100 ° C, and more preferably 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

The method for extracting the compound (IZ1) from the reaction mixture is not particularly limited, and the compound (IZ1) can be extracted by various known methods. For example, after completion of the reaction, the compound (IZ1) can be taken out by filtering the reaction mixture. Further, after filtration, the obtained residue may be subjected to column chromatography, recrystallization or the like. Further, after completion of the reaction, the solvent of the reaction mixture may be distilled off and then purified by column chromatography.

<Compound (IZ2)>
The compound (IZ2) is a compound represented by the formula (IZ2).

[In formula (IZ2),
R ^CO1Z2 and R ^CO2Z2 represent ^{-OR O1Z2} or -NR N1Z2 R ^N2Z2 independently of each other.
^{R N1Z2, R N2Z2, R 1Z2} , R 2Z2, R 3Z2, R 4Z2, and R ^5Z2, independently of each other, hydrogen ^{atom, -CO-R 102Z2, -COO-} R 101Z2, -OCO-R 102Z2, -COCO -R ^102Z2 , -O-R ^102Z2 , -SO ₂ -R ^101Z2 , -SO ₂ N (R ^102Z2 ) ₂ ^{, -CON} (R 102Z2) ₂ , -N (R ^102Z2 ) ₂ , -NHCO-R ^102Z2 ,- NHCO-N (R ^102Z2 ) ₂ , -NHCOOR ^102Z2 , -OCON (R ^102Z2 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, carbon which may have a substituent Represents a heterocyclic group which may have a hydrocarbon group or a substituent of the number 1 to 40.
R ^2Z2 and R ^3Z2, R ^3Z2 and R ^4Z2, and R ^4Z2 and R ^5Z2 may each be bonded to each other to form a ring.
R ^101Z2 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
^RO1Z2 and ^R102Z2 represent a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent, independently of each other.
M represents a hydrogen atom or an alkali metal atom.
When a ^{plurality of} R O1Z2, R ^N1Z2 , R ^N2Z2 , R ^101Z2 , R ^102Z2 and M exist, they may be the same or different.
The wavy line represents an E-form or a Z-form. ]

^{R O1Z2, R N1Z2, R N2Z2} , R 1Z2, R 2Z2, R 3Z2, R 4Z2, R 5Z2, R 101Z2 and the carbon number of the hydrocarbon group which may have a substituent represented by R ^102Z2 is It is 1 to 40, preferably 1 to 30, more preferably 1 to 20, still more preferably 1 to 15, particularly preferably 1 to 10, and even more preferably 1 to 5.

^{R O1Z2, R N1Z2, R N2Z2} , R 1Z2, R 2Z2, R 3Z2, R 4Z2, a hydrocarbon group of R ^5Z2, R ^101Z2 and C1-40 represented by R ^102Z2 is an aliphatic hydrocarbon group and It may be an aromatic hydrocarbon group, and the aliphatic hydrocarbon group may be saturated or unsaturated, or may be a chain or an alicyclic.

The ^{R O1Z2, R N1Z2, R N2Z2} , R 1Z2, R 2Z2, R 3Z2, R 4Z2, R 5Z2, saturated or unsaturated chain hydrocarbon group represented by R ^101Z2 and R ^102Z2, a methyl group, an ethyl group , Propyl group, butyl group, pentyl group, hexyl group, heptyl group, octyl group, nonyl group, decyl group, undecyl group, dodecyl group, heptadecyl group, octadecyl group, linear alkyl group such as icosyl group; isopropyl Group, isobutyl group, sec-butyl group, tert-butyl group, (2-ethyl) butyl group, isopentyl group, neopentyl group, tert-pentyl group, (1-methyl) pentyl group, (2-methyl) pentyl group, Branched chain alkyl groups such as (1-ethyl) pentyl group, (3-ethyl) pentyl group, isohexyl group, (5-methyl) hexyl group, (2-ethyl) hexyl group and (3-ethyl) heptyl group. Etc; Vinyl group, 1-propenyl group, 2-propenyl group (allyl group), (1-methyl) ethenyl group, 2-butenyl group, 3-butenyl group, 1,3-butadienyl group, (1- (2-) Propenyl)) alkenyl groups such as (1,2-dimethyl) propenyl group and 2-pentenyl group; and the like. The saturated or unsaturated chain hydrocarbon group preferably has 1 to 30 carbon atoms, more preferably 1 to 20 carbon atoms, still more preferably 1 to 15 carbon atoms, and particularly preferably 1 to 10 carbon atoms. It is more preferably 1 to 8, and even more preferably 1 to 5. Of these, a linear or branched alkyl group having 1 to 10 carbon atoms, more preferably 1 to 8 carbon atoms is particularly preferable, and a methyl group, an ethyl group, and a tert-butyl group are particularly preferable.

R ^O1Z2, as the ^{R N1Z2, R N2Z2, R 1Z2} , R 2Z2, R 3Z2, R 4Z2, R 5Z2, saturated or unsaturated alicyclic hydrocarbon group represented by R ^101Z2 and R ^102Z2, cyclopropyl group, 1-methylcyclopropyl group, cyclobutyl group, cyclopentyl group, cyclohexyl group, cycloheptyl group, 1-methylcyclohexyl group, 2-methylcyclohexyl group, 3-methylcyclohexyl group, 4-methylcyclohexyl group, 1,2-dimethylcyclohexyl Group, 1,3-dimethylcyclohexyl group, 1,4-dimethylcyclohexyl group, 2,3-dimethylcyclohexyl group, 2,4-dimethylcyclohexyl group, 2,5-dimethylcyclohexyl group, 2,6-dimethylcyclohexyl group, 3,4-Dimethylcyclohexyl group, 3,5-dimethylcyclohexyl group, 2,2-dimethylcyclohexyl group, 3,3-dimethylcyclohexyl group, 4,4-dimethylcyclohexyl group, cyclooctyl group, 2,4,6- Cyclo such as trimethylcyclohexyl group, 2,2,6,6-tetramethylcyclohexyl group and 3,3,5,5-tetramethylcyclohexyl group, 4-pentylcyclohexyl group, 4-octylcyclohexyl group, 4-cyclohexylcyclohexyl group Alkyl group; cycloalkenyl group such as cyclohexenyl group (for example, cyclohex-2-ene, cyclohex-3-ene), cycloheptenyl group, cyclooctenyl group; norbornan group, adamantyl group, bicyclo [2.2.2] octane and the like. Be done. The saturated or unsaturated alicyclic hydrocarbon group preferably has 3 to 30, more preferably 3 to 20, even more preferably 4 to 20, and even more preferably 4 to 15. Yes, more particularly preferably 5 to 15, and most preferably 5 to 10. Of these, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, and a cyclooctyl group are particularly preferable.

The ^{R O1Z2, R N1Z2, R N2Z2} , R 1Z2, R 2Z2, R 3Z2, R 4Z2, R 5Z2, aromatic hydrocarbon groups represented by R ^101Z2 and R ^102Z2, phenyl, o- tolyl group, m -Trill group, p-tolyl group, 2-ethylphenyl group, 3-ethylphenyl group, 4-ethylphenyl group, 2,3-dimethylphenyl group, 2,4-dimethylphenyl group, 2,5-dimethylphenyl group , 2,6-dimethylphenyl group, 3,4-dimethylphenyl group, 3,5-dimethylphenyl group, 4-vinylphenyl group, o-isopropylphenyl group, m-isopropylphenyl group, p-isopropylphenyl group, o -Tert-butylphenyl group, m-tert-butylphenyl group, p-tert-butylphenyl group, mesityl group, 4-ethylphenyl group, 4-butylphenyl group, 4-pentylphenyl group, 2,6-bis ( 2-propyl) phenyl group, 4-cyclohexylphenyl group, 2,4,6-trimethylphenyl group, 4-octylphenyl group, 1-naphthyl group, 2-naphthyl group, 5,6,7,8-tetrahydro-1 Examples thereof include −naphthyl group, 5,6,7,8-tetrahydro-2-naphthyl group, fluorenyl group, phenyl group and aromatic hydrocarbon group such as anthryl group and pyrenyl group; and the like. The number of carbon atoms of the aromatic hydrocarbon group is preferably 6 to 30, more preferably 6 to 20, and even more preferably 6 to 15.

^{R O1Z2, R N1Z2, R N2Z2} , R 1Z2, R 2Z2, R 3Z2, R 4Z2, R 5Z2, hydrocarbon groups represented by R ^101Z2 and R ^102Z2 is a hydrocarbon group (e.g. an aromatic listed above carbonized It may be a group in which a hydrogen group is combined with at least one of a chain hydrocarbon group and an alicyclic hydrocarbon group), and an aralkyl group such as a benzyl group, a phenethyl group, or a 1-methyl-1-phenylethyl group. An arylalkenyl group such as a phenylethenyl group (phenylvinyl group); an arylalkynyl group such as a phenylethynyl group; a phenyl group to which one or more phenyl groups such as a biphenylyl group and a terphenylyl group are bonded; a cyclohexylmethylphenyl group and a benzyl Examples thereof include a phenyl group and a (dimethyl (phenyl) methyl) phenyl group.
^{R O1Z2, R N1Z2, R N2Z2} , R 1Z2, R 2Z2, R 3Z2, R 4Z2, R 5Z2, groups represented by R ^101Z2 and R ^102Z2 is a hydrocarbon group (e.g., a chain hydrocarbon group listed above And alicyclic hydrocarbon group), for example, cyclopropylmethyl group, cyclopropylethyl group, cyclobutylmethyl group, cyclobutylethyl group, cyclopentylmethyl group, cyclopentylethyl group, cyclohexylmethyl group, 2- It may be an alkyl group to which one or more alicyclic hydrocarbon groups such as methylcyclohexylmethyl group, cyclohexylethyl group and adamantylmethyl group are bonded.
These carbon numbers are preferably 4 to 30, more preferably 6 to 30, even more preferably 6 to 20, still preferably 4 to 20, and even more preferably 4 to 15. , Particularly preferably 6 to 15.

^{R O1Z2, R N1Z2, R N2Z2} , R 1Z2, R 2Z2, R 3Z2, R 4Z2, hydrocarbon groups represented by R ^5Z2, R ^101Z2 and R ^102Z2 may have a substituent. The substituent may be monovalent or divalent. For the divalent substituent, it is preferable that two bonds are bonded to the same carbon atom to form a double bond.
As the monovalent substituent,
Methoxy group, ethoxy group, propoxy group, isopropoxy group, butoxy group, isobutoxy group, sec-butoxy group, tert-butoxy group, pentyloxy group, hexyloxy group, (2-ethyl) hexyloxy group, heptyloxy group, Octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, dodecyloxy group, (2-ethyl) hexyloxy group, icosyloxy group, 1-phenylethoxy group, 1-methyl-1-phenylethoxy group, phenyloxy group , O-Trilloxy group, 2,3-dimethylphenyloxy group, 2,4-dimethylphenyloxy group, 2,5-dimethylphenyloxy group, 2,6-dimethylphenyloxy group, 3,4-dimethylphenyloxy group , 3,5-dimethylphenyloxy group, 2,2-dicyanophenyloxy group, 2,3-dicyanophenyloxy group, 2,4-dicyanophenyloxy group, 2,5-dicyanophenyloxy group, 2,6- Dicyanophenyloxy group, 3,4-dicyanophenyloxy group, 3,5-dicyanophenyloxy group, 4-methoxyphenyloxy group, 2-methoxyphenyloxy group, 3-methoxyphenyloxy group, 4-ethoxyphenyloxy group , 2-ethoxyphenyloxy group, 3-ethoxyphenyloxy group, etc., and a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group represented by the following formula, or a derivatizing group thereof. (For example, a group derivatized with a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), or the like). Is an oxy group bonded to one side;

Methylthio group, ethylthio group, propylthio group, butylthio group, tert-butylthio group, pentylthio group, hexylthio group, (2-ethyl) hexylthio group, heptylthio group, octylthio group, nonylthio group, decylthio group, undecylthio group, dodecylthio group, icosylthio group. A sulfanyl group to which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group, a phenylthio group and an o-tolylthio group is bonded;

Epoxy group, oxetanyl group, tetrahydrofuryl group, tetrahydropyranyl group;
Holmil group;
Acetyl group, propanoyl group, butanoyl group, 2,2-dimethylpropanoyl group, pentanoyl group, hexanoyl group, (2-ethyl) hexanoyl group, heptanoil group, octanoyl group, nonanoyl group, decanoyl group, undecanoyl group, dodecanoyl group, A hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 11 carbon atoms) or an inducible group thereof (for example, a carboxy group or a sulfo group) such as a henicosanoyl group and a benzoyl group and a group represented by the following formula. , A carbonyl group to which a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. are bonded. When the carbonyl group is an alkanoyl group, the number of carbon atoms is preferably 2 to 12);

Methoxycarbonyl group, ethoxycarbonyl group, propoxycarbonyl group, butoxycarbonyl group, tert-butoxycarbonyl group, pentyloxycarbonyl group, hexyloxycarbonyl group, (2-ethyl) hexyloxycarbonyl group, heptyloxycarbonyl group, octyloxycarbonyl group Group, nonyloxycarbonyl group, decyloxycarbonyl group, undecyloxycarbonyl group, dodecyloxycarbonyl group, icosyloxycarbonyl group, phenyloxycarbonyl group, o-tolyloxycarbonyl group, etc., and represented by the following formula A hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), a carbon number of carbon atoms). An oxycarbonyl group to which 1 to 10 alkylsulfamoyl groups (preferably groups derivatized with an octylsulfamoyl group) or the like are attached;

アミノ基；
Ｎ−メチルアミノ基、Ｎ，Ｎ−ジメチルアミノ基、Ｎ−エチルアミノ基、Ｎ，Ｎ−ジエチルアミノ基、Ｎ−プロピルアミノ基、Ｎ，Ｎ−ジプロピルアミノ基、Ｎ−イソプロピルアミノ基、Ｎ，Ｎ−ジイソプロピルアミノ基、Ｎ−ブチルアミノ基、Ｎ，Ｎ−ジブチルアミノ基、Ｎ−イソブチルアミノ基、Ｎ，Ｎ−ジイソブチルアミノ基、Ｎ−ｓｅｃ−ブチルアミノ基、Ｎ，Ｎ−ジｓｅｃ−ブチルアミノ基、Ｎ−ｔｅｒｔ−ブチルアミノ基、Ｎ，Ｎ−ジｔｅｒｔ−ブチルアミノ基、Ｎ−ペンチルアミノ基、Ｎ，Ｎ−ジペンチルアミノ基、Ｎ−（１−エチルプロピル）アミノ基、Ｎ，Ｎ−ジ（１−エチルプロピル）アミノ基、Ｎ−ヘキシルアミノ基、Ｎ，Ｎ−ジヘキシルアミノ基、Ｎ−（２−エチル）ヘキシルアミノ基、Ｎ，Ｎ−ジ（２−エチル）ヘキシルアミノ基、Ｎ−ヘプチルアミノ基、Ｎ，Ｎ−ジヘプチルアミノ基、Ｎ−オクチルアミノ基、Ｎ，Ｎ−ジオクチルアミノ基、Ｎ−ノニルアミノ基、Ｎ，Ｎ−ジノニルアミノ基、Ｎ−フェニルアミノ基、Ｎ，Ｎ−ジフェニルアミノ基、Ｎ，Ｎ−エチルメチルアミノ基、Ｎ，Ｎ−プロピルメチルアミノ基、Ｎ，Ｎ−イソプロピルメチルアミノ基、Ｎ，Ｎ−ブチルメチルアミノ基、Ｎ−デシルアミノ基、Ｎ，Ｎ−デシルメチルアミノ基、Ｎ−ウンデシルアミノ基、Ｎ，Ｎ−ウンデシルメチルアミノ基、Ｎ−ドデシルアミノ基、Ｎ，Ｎ−ドデシルメチルアミノ基、Ｎ−イコシルアミノ基、Ｎ，Ｎ−イコシルメチルアミノ基、Ｎ，Ｎ−ｔｅｒｔ−ブチルメチルアミノ基及びＮ，Ｎ−フェニルメチルアミノ基等、及び以下の式で表される基等の１つ又は２つの炭素数１〜２０（好ましくは炭素数１〜１０）の炭化水素基又はその誘導化基（例えばカルボキシ基、スルホ基、ニトロ基、ヒドロキシ基、ハロゲン（好ましくは塩素原子）、炭素数１〜１０のアルキルスルファモイル基（好ましくはオクチルスルファモイル基）等で誘導化された基）で置換されたアミノ基；

Amino group;
N-methylamino group, N, N-dimethylamino group, N-ethylamino group, N, N-diethylamino group, N-propylamino group, N, N-dipropylamino group, N-isopropylamino group, N, N-diisopropylamino group, N-butylamino group, N, N-dibutylamino group, N-isobutylamino group, N, N-diisobutylamino group, N-sec-butylamino group, N, N-disec-butyl Amino group, N-tert-butylamino group, N, N-ditert-butylamino group, N-pentylamino group, N, N-dipentylamino group, N- (1-ethylpropyl) amino group, N, N -Di (1-ethylpropyl) amino group, N-hexylamino group, N, N-dihexylamino group, N- (2-ethyl) hexylamino group, N, N-di (2-ethyl) hexylamino group, N-Heptylamino Group, N, N-Diheptylamino Group, N-octylamino Group, N, N-Dioctylamino Group, N-Nonylamino Group, N, N-Dinonylamino Group, N-Phenylamino Group, N, N -Diphenylamino group, N, N-ethylmethylamino group, N, N-propylmethylamino group, N, N-isopropylmethylamino group, N, N-butylmethylamino group, N-decylamino group, N, N- Decylmethylamino Group, N-Undecylamino Group, N, N-Undecylmethylamino Group, N-Dodecylamino Group, N, N-Dodecylmethylamino Group, N-Icosylamino Group, N, N-Icosylmethylamino One or two carbon atoms 1 to 20 (preferably 1 carbon atom) such as a group, an N, N-tert-butylmethylamino group, an N, N-phenylmethylamino group, etc., and a group represented by the following formula. A hydrocarbon group of 10) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), and an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsul). Amino group substituted with a famoyl group) or a derivatized group);

スルファモイル基；
Ｎ−メチルスルファモイル基、Ｎ，Ｎ−ジメチルスルファモイル基、Ｎ−エチルスルファモイル基、Ｎ，Ｎ−ジエチルスルファモイル基、Ｎ−プロピルスルファモイル基、Ｎ，Ｎ−ジプロピルスルファモイル基、Ｎ−イソプロピルスルファモイル基、Ｎ，Ｎ−ジイソプロピルスルファモイル基、Ｎ−ブチルスルファモイル基、Ｎ，Ｎ−ジブチルスルファモイル基、Ｎ−イソブチルスルファモイル基、Ｎ，Ｎ−ジイソブチルスルファモイル基、Ｎ−ｓｅｃ−ブチルスルファモイル基、Ｎ，Ｎ−ジｓｅｃ−ブチルスルファモイル基、Ｎ−ｔｅｒｔ−ブチルスルファモイル基、Ｎ，Ｎ−ジｔｅｒｔ−ブチルスルファモイル基、Ｎ−ペンチルスルファモイル基、Ｎ，Ｎ−ジペンチルスルファモイル基、Ｎ−（１−エチルプロピル）スルファモイル基、Ｎ，Ｎ−ジ（１−エチルプロピル）スルファモイル基、Ｎ−ヘキシルスルファモイル基、Ｎ，Ｎ−ジヘキシルスルファモイル基、Ｎ−（２−エチル）ヘキシルスルファモイル基、Ｎ，Ｎ−ジ（２−エチル）ヘキシルスルファモイル基、Ｎ−ヘプチルスルファモイル基、Ｎ，Ｎ−ジヘプチルスルファモイル基、Ｎ−オクチルスルファモイル基、Ｎ，Ｎ−ジオクチルスルファモイル基、Ｎ，Ｎ−オクチルメチルスルファモイル基、Ｎ−ノニルスルファモイル基、Ｎ，Ｎ−ジノニルスルファモイル基、Ｎ−フェニルスルファモイル基、Ｎ，Ｎ−ジフェニルスルファモイル基、Ｎ，Ｎ−エチルメチルスルファモイル基、Ｎ，Ｎ−プロピルメチルスルファモイル基、Ｎ，Ｎ−イソプロピルメチルスルファモイル基、Ｎ，Ｎ−ブチルメチルスルファモイル基、Ｎ−デシルスルファモイル基、Ｎ，Ｎ−デシルメチルスルファモイル基、Ｎ−ウンデシルスルファモイル基、Ｎ，Ｎ−ウンデシルメチルスルファモイル基、Ｎ−ドデシルスルファモイル基、Ｎ，Ｎ−ドデシルメチルスルファモイル基、Ｎ−イコシルスルファモイル基、Ｎ，Ｎ−イコシルメチルスルファモイル基、Ｎ，Ｎ−ｔｅｒｔ−ブチルメチルスルファモイル基及びＮ，Ｎ−フェニルメチルスルファモイル基等、及び以下の式で表される基等の１つ又は２つの炭素数１〜２０（好ましくは炭素数１〜１０）の炭化水素基またはその誘導化基（例えばカルボキシ基、スルホ基、ニトロ基、ヒドロキシ基、ハロゲン（好ましくは塩素原子）、炭素数１〜１０のアルキルスルファモイル基（好ましくはオクチルスルファモイル基）等で誘導化された基）で置換されたスルファモイル基；

Sulfamoyl group;
N-methylsulfamoyl group, N, N-dimethylsulfamoyl group, N-ethylsulfamoyl group, N, N-diethylsulfamoyl group, N-propylsulfamoyl group, N, N-dipropyls Rufamoyl group, N-isopropylsulfamoyl group, N, N-diisopropylsulfamoyl group, N-butylsulfamoyl group, N, N-dibutylsulfamoyl group, N-isobutylsulfamoyl group, N, N-diisobutylsulfamoyl group, N-sec-butylsulfamoyl group, N, N-disec-butylsulfamoyl group, N-tert-butylsulfamoyl group, N, N-ditert-butylsul Famoyl group, N-pentyl sulfamoyl group, N, N-dipentyl sulfamoyl group, N- (1-ethylpropyl) sulfamoyl group, N, N-di (1-ethylpropyl) sulfamoyl group, N-hexyl Sulfamoyl group, N, N-dihexyl sulfamoyl group, N- (2-ethyl) hexyl sulfamoyl group, N, N-di (2-ethyl) hexyl sulfamoyl group, N-heptyl sulfamoyl Group, N, N-diheptyl sulfamoyl group, N-octyl sulfamoyl group, N, N-dioctyl sulfamoyl group, N, N-octylmethyl sulfamoyl group, N-nonyl sulfamoyl group, N, N-Dinonyl sulfamoyl group, N-phenyl sulfamoyl group, N, N-diphenyl sulfamoyl group, N, N-ethylmethyl sulfamoyl group, N, N-propylmethyl sulfamoyl group, N, N-isopropylmethylsulfamoyl group, N, N-butylmethylsulfamoyl group, N-decylsulfamoyl group, N, N-decylmethylsulfamoyl group, N-undecylsulfamoyl group, N , N-Undecylmethyl Sulfamoyl Group, N-Dodecyl Sulfamoyl Group, N, N-Dodecyl Methyl Sulfamoyl Group, N-Icosyl Sulfamoyl Group, N, N-Icosyl Methyl Sulfamoyl Group, N, N-tert-butylmethylsulfamoyl group, N, N-phenylmethylsulfamoyl group, etc., and one or two groups represented by the following formula, etc., having 1 or 2 carbon atoms (preferably carbons) A hydrocarbon group having a number of 1 to 10 or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), and an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably). Induced with octylsulfamoyl group) etc. Sulfamoyl group substituted with (done group);

Formylamino group; acetylamino group, propanoylamino group, butanoylamino group, 2,2-dimethylpropanoylamino group, pentanoylamino group, hexanoylamino group, (2-ethyl) hexanoylamino group, heptanoil Amino group, octanoylamino group, nonanoylamino group, decanoyylamino group, undecanoylamino group, dodecanoylamino group, henicosanoylamino group, benzoylamino group, etc., and groups represented by the following formulas. Etc., a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 12 carbon atoms) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), 1 carbon atom). A carbonylamino group to which 10 to 10 alkylsulfamoyl groups (preferably groups derivatized with an octylsulfamoyl group) or the like are bonded (when the carbonylamino group is an alkanoylamino group, the number of carbon atoms is preferably 1. ~ 12);

ヒドロキシ基；
フッ素原子、塩素原子、臭素原子及びヨウ素原子等のハロゲン原子；
カルボキシ基、−ＣＯ₂Ｍ²（Ｍ²はアルカリ金属、好ましくはリチウム、ナトリウム、
カリウム）；スルホ基、−ＳＯ₃Ｍ²（Ｍ²はアルカリ金属、好ましくはリチウム、ナトリウム、カリウム）；ニトロ基；シアノ基；
ホルミルオキシ基；アセトキシ基、プロパノイルオキシ基、ブタノイルオキシ基、２，２−ジメチルプロパノイルオキシ基、ペンタノイルオキシ基、ヘキサノイルオキシ基、（２−エチル）ヘキサノイルオキシ基、ヘプタノイルオキシ基、オクタノイルオキシ基、ノナノイルオキシ基、デカノイルオキシ基、ウンデカノイルオキシ基、ドデカノイルオキシ基、ヘンイコサノイルオキシ基、ベンゾイルオキシ基等、及び以下の式で表される基等の炭素数１〜２０（好ましくは炭素数１〜１０）の炭化水素基又はその誘導化基（例えばカルボキシ基、スルホ基、ニトロ基、ヒドロキシ基、ハロゲン（好ましくは塩素原子）、炭素数１〜１０のアルキルスルファモイル基（好ましくはオクチルスルファモイル基）等で誘導化された基）が結合したカルボニルオキシ基（該カルボニルオキシ基をアルカノイルオキシ基とする場合、炭素数は好ましくは１〜１０である）；

Hydroxy group;
Halogen atoms such as fluorine atom, chlorine atom, bromine atom and iodine atom;
Carboxy group, -CO ₂ M ² (M ² is an alkali metal, preferably lithium, sodium,
Potassium); sulfo group, -SO ₃ M ² (M ² is alkali metal, preferably lithium, sodium, potassium); nitro group; cyano group;
Formyloxy group; acetoxy group, propanoyloxy group, butanoyloxy group, 2,2-dimethylpropanoyloxy group, pentanoyloxy group, hexanoyloxy group, (2-ethyl) hexanoyloxy group, heptanoyloxy group Carbons such as groups, octanoyloxy groups, nonanoyloxy groups, decanoyloxy groups, undecanoyloxy groups, dodecanoyloxy groups, henicosanoyloxy groups, benzoyloxy groups, etc., and groups represented by the following formulas. A hydrocarbon group having a number of 1 to 20 (preferably 1 to 10 carbon atoms) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), and a group having 1 to 10 carbon atoms. A carbonyloxy group to which an alkylsulfamoyl group (preferably a group derivatized with an octylsulfamoyl group) or the like is bonded (when the carbonyloxy group is an alkanoyloxy group, the number of carbon atoms is preferably 1 to 10). be);

メチルスルホニル基、エチルスルホニル基、プロピルスルホニル基、ブチルスルホニル基、ペンチルスルホニル基、ヘキシルスルホニル基、（２−エチル）ヘキシルスルホニル基、ヘプチルスルホニル基、オクチルスルホニル基、ノニルスルホニル基、デシルスルホニル基、ウンデシルスルホニル基、ドデシルスルホニル基、イコシルスルホニル基、フェニルスルホニル基、ｐ−トリルスルホニル基等、及び以下の式で表される基等の炭素数１〜２０（好ましくは炭素数１〜１０）の炭化水素基又はその誘導化基（例えばカルボキシ基、スルホ基、ニトロ基、ヒドロキシ基、ハロゲン（好ましくは塩素原子）、炭素数１〜１０のアルキルスルファモイル基（好ましくはオクチルスルファモイル基）等で誘導化された基）が結合したスルホニル基；

Methylsulfonyl group, ethylsulfonyl group, propylsulfonyl group, butylsulfonyl group, pentylsulfonyl group, hexylsulfonyl group, (2-ethyl) hexylsulfonyl group, heptylsulfonyl group, octylsulfonyl group, nonylsulfonyl group, decylsulfonyl group, un Decylsulfonyl group, dodecylsulfonyl group, icosylsulfonyl group, phenylsulfonyl group, p-tolylsulfonyl group and the like, and groups represented by the following formulas having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms). A hydrocarbon group or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group)). Sulfonyl group to which (groups derivatized by etc.) are bound;

Carbamic group;
N-Methylcarbamoyl group, N, N-dimethylcarbamoyl group, N-ethylcarbamoyl group, N, N-diethylcarbamoyl group, N-propylcarbamoyl group, N, N-dipropylcarbamoyl group, N-isopropylcarbamoyl group, N , N-diisopropylcarbamoyl group, N-butylcarbamoyl group, N, N-dibutylcarbamoyl group, N-isobutylcarbamoyl group, N, N-diisobutylcarbamoyl group, N-sec-butylcarbamoyl group, N, N-disec- Butylcarbamoyl group, N-tert-butylcarbamoyl group, N, N-ditert-butylcarbamoyl group, N-pentylcarbamoyl group, N, N-dipentylcarbamoyl group, N- (1-ethylpropyl) carbamoyl group, N, N-di (1-ethylpropyl) carbamoyl group, N-hexyl carbamoyl group, N, N-dihexyl carbamoyl group, N- (2-ethyl) hexyl carbamoyl group, N, N-di (2-ethyl) hexyl carbamoyl group , N-Heptylcarbamoyl group, N, N-diheptylcarbamoyl group, N-octylcarbamoyl group, N, N-dioctylcarbamoyl group, N-nonylcarbamoyl group, N, N-octylmethylcarbamoyl group, N, N-octyl Butylcarbamoyl group, N, N-dinonylcarbamoyl group, N-phenylcarbamoyl group, N, N-diphenylcarbamoyl group, N, N-ethylmethylcarbamoyl group, N, N-propylmethylcarbamoyl group, N, N-isopropyl Methylcarbamoyl group, N, N-butylmethylcarbamoyl group, N-decylcarbamoyl group, N, N-decylmethylcarbamoyl group, N-undecylcarbamoyl group, N, N-undecylmethylcarbamoyl group, N-dodecylcarbamoyl group , N, N-dodecylmethylcarbamoyl group, N-icosylcarbamoyl group, N, N-icosylmethylcarbamoyl group, N, N-tert-butylmethylcarbamoyl group, N, N-phenylmethylcarbamoyl group, etc. A hydrocarbon group having 1 or 2 carbon atoms (preferably 1 to 10 carbon atoms) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group) such as a group represented by the above formula. , A carbamoyl group substituted with halogen (preferably a chlorine atom), a group derivatized with an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc.;

Trifluoromethyl group, perfluoroethyl group, perfluoropropyl group, perfluoroisopropyl group, perfluorobutyl group, perfluoropentyl group, perfluorohexyl group, perfluoroheptyl group, perfluorooctyl group, perfluorononyl group, Carbonation of 1 to 20 carbon atoms in which all hydrogen atoms such as perfluorodecyl group, perfluoroundecyl group, perfluorododecyl group, perfluoroicosyl group, perfluorocyclohexyl group and perfluorophenyl group are substituted with fluorine atom. Hydrogen group;
Perfluoroethylmethyl group, perfluoropropylmethyl group, perfluoroisopropylmethyl group, perfluorobutylmethyl group, perfluoropentylmethyl group, perfluorohexylmethyl group, perfluoroheptylmethyl group, perfluorooctylmethyl group, perfluoro A linear chain having 1 to 20 carbon atoms in which all hydrogen atoms such as nonylmethyl group, perfluorodecylmethyl group, perfluoroundecylmethyl group, perfluorododecylmethyl group and perfluoroicosylmethyl group are substituted with fluorine atoms. Alternatively, a hydrocarbon group having 1 to 20 carbon atoms substituted with an alkyl group in the branched chain;
1 to 20 carbon atoms (preferably carbon number) in which a part of hydrogen atoms such as 2-fluorophenyl group, 3-fluorophenyl group, 4-fluorophenyl group and 2,4,6-trifluorophenyl group are replaced with fluorine. 1-10) hydrocarbon groups;
-CO-SH, -CO-S-CH ₃ , -CO-S-CH ₂ CH ₃ , -CO-S-CH ₂ -CH ₂ -CH ₃ and -CO-S-CH ₂ -CH ₂ -CH ₂ carbon atoms -CH _3, etc. 20 (preferably having 1 to 10 carbon atoms) bound to an alkyl group as bonded to a thiocarbonyl _{group, -CO-S-C 6 H} 5 aryl group having 6 to 20 carbon atoms, such as the Thiocarbonyl group;

* -COCO-R as represented by the following formula (in the formula, R is a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms (for example, among the hydrocarbon groups listed above, it satisfies 1 to 20 carbon atoms). , Or its inducing group (eg, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group). Group) (group derived by etc.);

_{* -NRCONR 2} as represented by the following formula (in the formula, R is a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms (for example, among the hydrocarbon groups listed above, those satisfying 1 to 20 carbon atoms). ), Or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), etc. Groups derived from), the Rs of which may be the same or different from each other, or bonded to each other to form a ring);

_{* -OCONR 2} as represented by the following formula (in the formula, R is a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms (for example, among the hydrocarbon groups listed above, those satisfying 1 to 20 carbon atoms). ), Or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), etc. Groups derived from), the Rs of which may be the same or different from each other, or bonded to each other to form a ring);

* -NRCOOR as represented by the following formula (in the formula, R is a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms (for example, among the hydrocarbon groups listed above, those satisfying 1 to 20 carbon atoms)). , Or its inducing group (eg, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group), etc. Derivatized groups), the Rs of which may be the same or different from each other, or bonded to each other to form a ring) groups;

* -OP (O) (OCH ₃ ) ₂ such as * -OP (O) (OR) ₂ (In the formula, R is a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms (for example, the hydrocarbon group listed above). Of these, those satisfying 1 to 20 carbon atoms), or their inducible groups (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms). (Preferably a group derivatized with an octylsulfamoyl group) or the like), and the Rs may be the same or different from each other, or may be bonded to each other to form a ring).
* -Si (CH ₃ ) ₃ , _{* -Si (CH 2} CH ₃ ) ₃ , _{* -Si (C 6} H ₅ ) ₃ and * -Si (CH (CH ₃ ) ₂ ) _3, etc. * -SiR ₃ ( In the formula, R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, one of the above-mentioned hydrocarbon groups satisfying 1 to 20 carbon atoms), or an inducing group thereof (for example, a carboxy group or a sulfo group). A group derived from a group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), etc.), and the R is Groups of (may be the same or different from each other and may be bonded to each other to form a ring);
And so on.

As the divalent substituent, an oxo group, a thioxo group, an imino group, an imino group substituted with an alkyl group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) and an aryl group having 6 to 20 carbon atoms are substituted. Examples include the imino group. Examples of the imino group substituted with the alkyl group include CH _3- N =, CH _3- CH _2- N =, CH _3- (CH ₂ ) _2- N = and CH _3- (CH ₂ ) _3- N =. Can be mentioned. Examples of the imino group substituted with the aryl group include C ₆ H _5- N = and the like.

Preferred examples of the substituent of the hydrocarbon group having 1 to 40 carbon atoms include the substituent of the group s1. The inducible groups shown below are carboxy groups, sulfo groups, nitro groups, hydroxy groups, halogens (preferably chlorine atoms), alkylsulfamoyl groups having 1 to 10 carbon atoms (preferably octylsulfamoyl groups) and the like. It is preferably an derivatized group.
[Group s1]
An oxy group in which a hydrocarbon group having 1 to 20 carbon atoms or an inducible group thereof is bonded to one side;
A carbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
An oxycarbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
Amino group;
An amino group substituted with one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
Sulfamoyl group;
A sulfamoyl group substituted with one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
A carbonylamino group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
Hydroxy group;
Halogen atom;
-CO ₂ M (preferably a carboxy group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom);
-SO ₃ M (preferably a sulfo group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom);
Nitro group;
Cyano group;
A carbonyloxy group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
A sulfonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or an inducible group thereof is bonded;
Carbamic group;
A carbamoyl group substituted with one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
A hydrocarbon group having 1 to 20 carbon atoms in which all hydrogen atoms are replaced by fluorine atoms;
A hydrocarbon group having 1 to 20 carbon atoms in which all of the hydrogen atoms are substituted with fluorine atoms;
A hydrocarbon group having 1 to 20 carbon atoms in which a part of a hydrogen atom is replaced by fluorine;
Oxo group

As the substituent of the hydrocarbon group having 1 to 40 carbon atoms, a substituent of group s2 is more preferable.
[Group s2]
An oxy group in which a hydrocarbon group having 1 to 10 carbon atoms or an inducible group thereof is bonded to one side;
A carbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
An oxycarbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
Amino group;
An amino group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or an inducible group thereof;
Sulfamoyl group;
A sulfamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof;
A carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
Hydroxy group;
Fluorine atom, chlorine atom, bromine atom;
-CO ₂ M (preferably a carboxy group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom);
-SO ₃ M (preferably a sulfo group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom);
Nitro group;
Cyano group;
A carbonyloxy group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
A sulfonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or an inducible group thereof is bonded;
Carbamic group;
A carbamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof;
A hydrocarbon group having 1 to 10 carbon atoms in which all hydrogen atoms are replaced by fluorine atoms;
A hydrocarbon group having 1 to 10 carbon atoms in which all of the hydrogen atoms are substituted with fluorine atoms;
A hydrocarbon group having 1 to 10 carbon atoms in which a part of a hydrogen atom is replaced by fluorine;
Oxo group

Examples of the hydrocarbon group ^{R O1Z2, R N1Z2, R N2Z2} , R 1Z2, R 2Z2, R 3Z2, R 4Z2, R 5Z2, carbon atoms having a substituent represented by R ^101Z2 and R ^102Z2 1~40, 1 Hydrocarbon groups having 1 to 40 carbon atoms having a valent or divalent substituent can be mentioned, preferably saturated or unsaturated chain hydrocarbon groups having 1 to 30 carbon atoms having a monovalent or divalent substituent. A saturated or unsaturated alicyclic hydrocarbon group having 3 to 30 carbon atoms having a monovalent or divalent substituent or an aromatic hydrocarbon group having 6 to 30 carbon atoms having a monovalent or divalent substituent or Groups having a combination of hydrocarbon groups and having a monovalent or divalent substituent and having 1 to 30 carbon atoms can be mentioned.
More preferably, a saturated or unsaturated chain hydrocarbon group having 1 to 20 carbon atoms having a substituent in group s1 and a saturated or unsaturated alicyclic hydrocarbon group having 3 to 20 carbon atoms having a substituent in group s1. , A group having a substituent of group s1 and having 6 to 20 carbon atoms or a combination of hydrocarbon groups and a group having a substituent of group s1 and having 1 to 20 carbon atoms.
Particularly preferably, a saturated or unsaturated chain hydrocarbon group having 1 to 15 carbon atoms having a substituent in group s2 and a saturated or unsaturated alicyclic hydrocarbon group having 3 to 15 carbon atoms having a substituent in group s2. , A group having a substituent of group s2 and having 6 to 15 carbon atoms or a combination of hydrocarbon groups and a group having a substituent of group s2 and having 1 to 15 carbon atoms.

In Examples ^{R O1Z2, R N1Z2, R N2Z2} , R 1Z2, R 2Z2, R 3Z2, R 4Z2, heterocyclic group represented by R ^5Z2, R ^101Z2 and R ^102Z2, it may be monocyclic polycyclic It may be a heterocycle, preferably a heterocycle containing a heteroatom as a component of the ring. Examples of the hetero atom include a nitrogen atom, an oxygen atom and a sulfur atom.
The heterocyclic group preferably has 3 to 30, more preferably 3 to 22, still more preferably 3 to 20, even more preferably 3 to 18, and even more preferably 3. It is ~ 15, and particularly preferably 3 ~ 14.

As a heterocycle containing a nitrogen atom,
Monocyclic saturated heterocycles such as aziridine, azetidine, pyrrolidine, piperidine and piperazine;
Pyrrole such as 2,5-dimethylpyrrole, pyrazole such as 2-methylpyrazole and 3-methylpyrazole, imidazole, 1,2,3-triazole and 5-membered ring-based unsaturated heterocycle such as 1,2,4-triazole ;
Pyrimidines such as pyridine, pyridazine, 6-methylpyrimidine, pyrazines and 6-membered ring unsaturated heterocycles such as 1,3,5-triazine;
Quinoxaline such as indazole, indolin, isoindolin, indole, indoline, benzimidazole, quinoline, isoquinoline, 5,6,7,8-tetrahydro (3-methyl) quinoxaline, 3-methylquinoxaline, quinazoline, cinnoline, phthalazine, diazanaphthalene. , Purine, pteridine, benzopyrazole, benzopiperidine and other fused bicyclic heterocycles;
Condensed tricyclic heterocycles such as carbazole, acridine and phenazine; and the like.

As a heterocycle containing an oxygen atom,
Monocyclic saturated heterocycles such as oxylan, oxetane, tetrahydrofuran, tetrahydropyran, 1,3-dioxane and 1,4-dioxane, 1-cyclopentyl dioxolane;
Bicyclic saturated heterocycles such as 1,4-dioxaspiro [4.5] decane and 1,4-dioxaspiro [4.5] nonane;
Lactone-based heterocycles such as α-acetolactone, β-propiolactone, γ-butyrolactone, γ-valerolactone and δ-valerolactone;
A 5-membered ring-based unsaturated heterocycle such as furan such as 2,3-dimethylfuran and 2,5-dimethylfuran;
6-membered ring-based unsaturated heterocycles such as 2H-pyran and 4H-pyran;
Benzopyrans such as 1-benzofuran and 4-methylbenzopyran, condensed bicyclic heterocycles such as benzodioxol, chroman and isochroman;
Condensed tricyclic heterocycles such as xanthene and dibenzofuran; and the like.

As a heterocycle containing a sulfur atom,
5-membered ring-based saturated heterocycle such as dithiolane;
6-membered ring-based saturated heterocycles such as thiane, 1,3-dithiane, 2-methyl 1,3-dithiane;
5-membered ring-based unsaturated heterocycles such as thiophenes such as 3-methylthiophene and 2-carboxythiophene, 4H-thiopyran, benzothiopyran such as benzotetrahydrothiopyran;
Condensation bicyclic heterocycles such as benzothiophene;
Condensed tricyclic heterocycles such as thianthrene and dibenzothiophene; and the like.

As a heterocycle containing a nitrogen atom and an oxygen atom,
Monocyclic saturated heterocycles such as morpholine, 2-pyrrolidone, 2-methyl-2-pyrrolidone, 2-piperidone and 2-methyl-2-piperidone;
Monocyclic unsaturated heterocycles such as oxazoles such as 4-methyloxazole, 2-methylisoxazoles, and isooxazoles such as 3-methylisoxazole;
Condensed bicyclic heterocycles such as benzoxazole, benzoisoxazole, benzoxazine, benzodioxan, benzoimidazoline;
Condensed tricyclic heterocycles such as phenoxazine; and the like.

As a heterocycle containing a nitrogen atom and a sulfur atom,
Monocyclic heterocycles such as thiazoles such as 3-methylthiazole and 2,4-dimethylthiazole;
Condensation bicyclic heterocycles such as benzothiazole;
Condensation tricyclic heterocycles such as phenothiazine; and the like.

The heterocycle may be a group in which the above-mentioned hydrocarbon groups are combined, and examples thereof include a tetrahydrofurylmethyl group.

Further, the heterocycle may be represented by the following formula.

Further, the heterocyclic group may be a heterocyclic group formed by bonding two or more of ^{R 1Z2 to} R ^{5Z 2.} Such a heterocyclic group has a ring structure of two or more rings together with a benzene ring to which ^{R 1Z2 to} R ^{5Z2 are bonded.} Examples of the ring structure having two or more rings include the structure of the following formula.

The bond position of the above heterocycle is a portion where an arbitrary hydrogen atom contained in each ring is eliminated.

^{R O1Z2, R N1Z2, R N2Z2} , R 1Z2, R 2Z2, R 3Z2, R 4Z2, heterocyclic group represented by R ^5Z2, R ^101Z2 and R ^102Z2 may have a substituent. Examples of the ^{substituent, R O1Z2, R N1Z2, R} N2Z2, R 1Z2, R 2Z2, R 3Z2, R 4Z2, R 5Z2, which may have a hydrocarbon group represented by R ^101Z2 and R ^102Z2 substituted The same thing as the group can be mentioned. When the heterocycle contains a nitrogen atom as a constituent element thereof, the hydrocarbon group mentioned above may be bonded to the nitrogen atom as a substituent.
Preferred examples of the substituent, and ^{R O1Z2, R N1Z2, R N2Z2} , R 1Z2, R 2Z2, R 3Z2, R 4Z2, R 5Z2, have a hydrocarbon group represented by R ^101Z2 and R ^102Z2 The same preferred substituents may be mentioned.
Examples of the heterocyclic group having a ^{R O1Z2, R N1Z2, R N2Z2} , R 1Z2, R 2Z2, R 3Z2, R 4Z2, R 5Z2, substituents represented by R ^101Z2 and R ^102Z2, 1 monovalent or divalent substituent A heterocyclic group having a group is mentioned, preferably a heterocyclic group having a substituent of the group s1 is mentioned, and more preferably a heterocyclic group having a substituent of the group s2 is mentioned.
The above-mentioned hydrocarbon group or heterocyclic group may have one or more substituents (first substituents), and the two or more substituents are independent of each other. It may be the same or different. Further, the first substituent may have another substituent (second substituent) bonded to the hydrocarbon group contained in a part thereof. The second substituent can be selected from the same groups as the first substituent.

^{Hereinafter, R N1Z2, R N2Z2, R} 1Z2, R 2Z2, R 3Z2, R 4Z2, -CO-R 102Z2 of ^{R 5Z2, -COO-R 101Z2,} -OCO-R 102Z2, -COCO-R 102Z2, -O- R ^102Z2 , -SO ₂ -R ^101Z2 , -SO ₂ N (R ^102Z2 ) ₂ ^{, -CON} (R 102Z2) ₂ , -N (R ^102Z2 ) ₂ , -NHCO-R ^102Z2 , -NHCO-N (R ^102Z2 ) ₂ , -NHCOOR ^102Z2 , -OCON (R ^102Z2 ) ₂ , halogen atom, -SO ₃ M, -CO ₂ M will be described.
-CO-R ^102Z2 includes formyl group; acetyl group, propanoyl group, butanoyl group, 2,2-dimethylpropanoyl group, pentanoyl group, hexanoyl group, (2-ethyl) hexanoyl group, heptanoil group, octanoyl group, nonanoyl. Derivation of a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group, a decanoyl group, an undecanoyl group, a dodecanoyl group, a henicosanoyl group, a benzoyl group, etc., and a group represented by the above formula. It was derivatized with a chemical group (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), or the like. A group corresponding to -CO-R 102Z2 in the carbonyl group to which the group) is bonded (when the carbonyl group is an acyl group, the number of carbon atoms is 2 to 41) and the compounds shown in Tables 1Z2 to 43Z2, and a ^{special application.} In the compounds shown in Tables 1 to 966 of No. ^2017-016290 , a group corresponding to −CO-R 102Z2 and the like can be mentioned, preferably a hydrocarbon group having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms) or a hydrocarbon group. ^{Corresponds to -CO-R 102Z2} in the carbonyl group to which the derivatizing group is bonded (when the carbonyl group is an alkanoyl group, the number of carbon atoms is more preferably 2 to 12) and the compounds shown in Tables 1Z2 to 43Z2. Examples include the groups to be used.

-COO-R ^101Z2 includes methoxycarbonyl group, ethoxycarbonyl group, propoxycarbonyl group, tert-butoxycarbonyl group, butoxycarbonyl group, pentyloxycarbonyl group, hexyloxycarbonyl group, (2-ethyl) hexyloxycarbonyl group, Heptyloxycarbonyl group, octyloxycarbonyl group, nonyloxycarbonyl group, decyloxycarbonyl group, undecyloxycarbonyl group, dodecyloxycarbonyl group, phenyloxycarbonyl group, icosyloxycarbonyl group, etc., and represented by the above formula. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or an inducing group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon In the oxycarbonyl group to which an alkylsulfamoyl group (preferably a group derivatized with an octylsulfamoyl group) of numbers 1 to 10 (preferably a group derivatized by an octylsulfamoyl group) or the like is bonded, and in the compounds shown in Tables 1Z2 to 43Z2, -COO-R ^101Z2 Examples of the relevant group and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. ^2017-016290 include the group corresponding to -COO-R 101Z2, and preferably a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof. Examples thereof include an oxycarbonyl group to which is bonded and a group corresponding to ^{-COO-R 101Z2 in the compounds shown in Tables 1Z2 to 43Z2.}

-OCO-R ^102Z2 includes formyloxy group; acetoxy group, propanoyloxy group, butanoyloxy group, 2,2-dimethylpropanoyloxy group, pentanoyloxy group, hexanoyloxy group, (2-ethyl). Hexanoyloxy group, heptanoiloxy group, octanoyloxy group, nonanoyloxy group, decanoyloxy group, undecanoyloxy group, dodecanoyloxy group, henikosanoyloxy group, benzoyloxy group, etc., and the above formula. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or an inducible group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, or a halogen (preferably a chlorine atom). ), A carbonyloxy group to which an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably a group derived from an octylsulfamoyl group) or the like is bonded (when the carbonyloxy group is an acyloxy group, the number of carbon atoms is 2 to 41), ^{and the groups corresponding to -OCO-R 102Z2} in the compounds shown in Tables 1Z2 to 43Z2 and -OCO-R 102Z2 in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. ^2017-016290. Examples of the group corresponding to the above, preferably a hydrocarbon group having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms) or a carbonyloxy group to which an inducible group thereof is bonded (the carbonyloxy group is referred to as an acyloxy group). If so, the number of carbon atoms is more preferably 2 to 12), and ^{groups corresponding to -OCO-R 102Z2} in the compounds shown in Tables 1Z2 to 43Z2 can be mentioned.

-COCO-R ^102Z2 includes methyloxalyl group, ethyloxalyl group, propyloxalyl group, butyloxalyl group, pentyloxalyl group, hexyloxalyl group, (2-ethyl) hexyloxalyl group, heptyloxalyl group, octyloxalyl group and nonyl. Oxalyl group, decyl oxalyl group, undecyl oxalyl group, dodecyl oxalyl group, icosyl oxalyl group, cyclopentyl oxalyl group, cyclohexyl oxalyl group, phenyl oxalyl group, p-tolyl oxalyl group and the like, and groups represented by the above formulas and the like. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), 1 to 1 carbon atoms. Oxalyl groups to which 10 alkylsulfamoyl groups (preferably groups derivatized with octylsulfamoyl groups) and the like are bonded, and groups corresponding to ^{-COCO-R 102Z2 in the compounds shown in Tables 1Z2 to 43Z2 and} Examples of the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290 include groups corresponding to ^{-COCO-R 102Z2.}

^{-OR 102Z 2} groups include hydroxy group; methoxy group, ethoxy group, propoxy group, isopropoxy group, butoxy group, isobutoxy group, sec-butoxy group, tert-butoxy group, pentyloxy group, hexyloxy group, heptyl. Oxy group, octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, dodecyloxy group, (2-ethyl) hexyloxy group, icosyloxy group, 1-phenylethoxy group, 1-methyl-1-phenylethoxy group, Phenyloxy group, 2,3-dimethylphenyloxy group, 2,4-dimethylphenyloxy group, 2,5-dimethylphenyloxy group, 2,6-dimethylphenyloxy group, 3,4-dimethylphenyloxy group, 3 , 5-Dimethylphenyloxy group, 2,2-dicyanophenyloxy group, 2,3-dicyanophenyloxy group, 2,4-dicyanophenyloxy group, 2,5-dicyanophenyloxy group, 2,6-dicyanophenyl Oxy group, 3,4-dicyanophenyloxy group, 3,5-dicyanophenyloxy group, 4-methoxyphenyloxy group, 2-methoxyphenyloxy group, 3-methoxyphenyloxy group, 4-ethoxyphenyloxy group, 2 A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a −ethoxyphenyloxy group, a 3-ethoxyphenyloxy group, etc., and a group represented by the above formula, or a derivatizing group thereof (for example, 1 to 20 carbon atoms). A group derived from a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), or the like is bonded. group corresponding to the -O-R ^102Z2 in the group as well as compounds shown in Table 1Z2~ Table 43Z2 -O-R ^102Z2 Table 1-966 of the relevant group and Japanese Patent Application No. 2017-016290 to the compounds shown in Examples thereof include an oxy group to which a hydrocarbon group having 1 to 10 carbon atoms or an inducible group thereof is bonded, and a group corresponding to ^{-OR 102Z2 in the compounds shown in Tables 1Z2 to 43Z2.}

-SO _2- R ^101Z2 includes methyl sulfonyl group, ethyl sulfonyl group, propyl sulfonyl group, butyl sulfonyl group, pentyl sulfonyl group, hexyl sulfonyl group, (2-ethyl) hexyl sulfonyl group, heptyl sulfonyl group, octyl sulfonyl group, Nonylsulfonyl group, decylsulfonyl group, undecylsulfonyl group, dodecylsulfonyl group, icosylsulfonyl group, phenylsulfonyl group, p-tolylsulfonyl group, etc., and groups represented by the above formula, etc. have 1 to 40 carbon atoms (1 to 40 carbon atoms). A hydrocarbon group having 1 to 20 carbon atoms or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms). (preferably octyl sulfamoyl group) derivatized group) bonded to a sulfonyl group and tables 1Z2~ Table 43Z2 group and Japanese Patent Application No. 2017-016290 corresponding to -SO ₂ -R ^101Z2 in the compound represented in the like -SO ₂ in the compounds shown in Table 1~966 -R ^101Z2 relevant group and the like in, preferably a sulfonyl group and tables 1Z2~ bonded hydrocarbon radical or a derivatized group having 1 to 10 carbon atoms group corresponding to -SO ₂ -R ^101Z2 in the compounds shown in Table 43Z2 and the like.

-SO ₂ N (R ^102Z2 ) ₂ is a sulfamoyl group;
N-methylsulfamoyl group, N-ethylsulfamoyl group, N-propylsulfamoyl group, N-isopropylsulfamoyl group, N-butylsulfamoyl group, N-isobutylsulfamoyl group, N- sec-butyl sulfamoyl group, N-tert-butyl sulfamoyl group, N-pentyl sulfamoyl group, N- (1-ethylpropyl) sulfamoyl group, N-hexyl sulfamoyl group, N- (2-) Ethyl) Hexyl sulfamoyl group, N-heptyl sulfamoyl group, N-octyl sulfamoyl group, N-nonyl sulfamoyl group, N-decyl sulfamoyl group, N-undecyl sulfamoyl group, N- One carbon number 1 to 40 (preferably 1 to 20) of one group such as dodecylsulfamoyl group, N-icosylsulfamoyl group, N-phenylsulfamoyl group, and a group represented by the above formula. (For example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably octyl sulfamoyl group). _{-SO 2} NH (R ^102Z2X ) (however, R ^102Z2X does not become a hydrogen atom, except that the sulfamoyl group substituted with) etc.) and the compounds shown in Tables 1Z2 to ^{43Z2 do not become R 102Z2.} -SO ₂ NH (R ^102Z2X) (provided that the compounds shown in Table 1 to 966 of the corresponding group and Japanese Patent Application No. 2017-016290 the same as is) and, except that R ^102Z2X is not a hydrogen atom, R ^102Z2 (Same as))
N, N-dimethylsulfamoyl group, N, N-ethylmethylsulfamoyl group, N, N-diethylsulfamoyl group, N, N-propylmethylsulfamoyl group, N, N-dipropylsulfamoyl Group, N, N-isopropylmethylsulfamoyl group, N, N-diisopropylsulfamoyl group, N, N-tert-butylmethylsulfamoyl group, N, N-diisobutylsulfamoyl group, N, N- Disec-butyl sulfamoyl group, N, N-ditert-butyl sulfamoyl group, N, N-butylmethyl sulfamoyl group, N, N-dibutyl sulfamoyl group, N, N-dipentyl sulfa Moyl group, N, N-di (1-ethylpropyl) sulfamoyl group, N, N-dihexyl sulfamoyl group, N, N-di (2-ethyl) hexyl sulfamoyl group, N, N-diheptylsul Famoyl group, N, N-octylmethylsulfamoyl group, N, N-dioctylsulfamoyl group, N, N-dinonyl sulfamoyl group, N, N-decylmethylsulfamoyl group, N, N- Undecylmethyl sulfamoyl group, N, N-dodecylmethyl sulfamoyl group, N, N-icosylmethyl sulfamoyl group, N, N-phenylmethyl sulfamoyl group, N, N-diphenyl sulfamoyl Two hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group and a group represented by the above formula or a derivatizing group thereof (for example, a carboxy group, a sulfo group, a nitro group, etc. Sulfamoyl groups substituted with hydroxy groups, halogens (preferably chlorine atoms), alkylsulfamoyl groups having 1 to 10 carbon atoms (preferably octylsulfamoyl groups), etc.) and Tables 1Z2 to Table 1Z2. In the compound shown in 43Z2, the group corresponding to -SO ₂ N (R ^102Z2X ) ₂ (however, R ^{102Z2X is the same as R 102Z2} except that it does not become a hydrogen atom) and Table 1 of Japanese Patent Application No. 2017-016290. Among the compounds shown in ~ 966, groups corresponding to −SO ₂ N (R ^102Z2X ) ₂ (however, R ^{102Z2X is the same as R 102Z2} except that it does not become a hydrogen atom) can be mentioned.
Preferably, it corresponds to _{−SO 2} N (R 102Z2) ₂ in the sulfamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or an inducible group thereof and the compounds shown in Tables 1Z2 to ^43Z2. The group etc. can be mentioned.

^-CON (R 102Z2) ₂ is a carbamoyl group;
N-methylcarbamoyl group, N-ethylcarbamoyl group, N-propylcarbamoyl group, N-isopropylcarbamoyl group, N-butylcarbamoyl group, N-isobutylcarbamoyl group, N-sec-butylcarbamoyl group, N-tert-butylcarbamoyl group. Group, N-pentylcarbamoyl group, N- (1-ethylpropyl) carbamoyl group, N-hexylcarbamoyl group, N- (2-ethyl) hexylcarbamoyl group, N-heptylcarbamoyl group, N-octylcarbamoyl group, N- One of nonylcarbamoyl group, N-decylcarbamoyl group, N-undecylcarbamoyl group, N-dodecylcarbamoyl group, N-icosylcarbamoyl group, N-phenylcarbamoyl group and the like, and a group represented by the above formula. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), and 1 to 10 carbon atoms. -CONH (R ^102Z2X ) (where R ^{102Z2X is the same as R 102Z2} except that it does not become a hydrogen atom), and in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290, -CONH (R ^102Z2X ) (however, R ^102Z2X is It is the same as ^{R 102 Z2} except that it does not become a hydrogen atom).
N, N-dimethylcarbamoyl group, N, N-ethylmethylcarbamoyl group, N, N-diethylcarbamoyl group, N, N-propylmethylcarbamoyl group, N, N-dipropylcarbamoyl group, N, N-isopropylmethylcarbamoyl Group, N, N-diisopropylcarbamoyl group, N, N-tert-butylmethylcarbamoyl group, N, N-diisobutylcarbamoyl group, N, N-disec-butylcarbamoyl group, N, N-ditert-butylcarbamoyl group , N, N-butylmethylcarbamoyl group, N, N-dibutylcarbamoyl group, N, N-butyloctylcarbamoyl group, N, N-dipentylcarbamoyl group, N, N-di (1-ethylpropyl) carbamoyl group, N , N-dihexylcarbamoyl group, N, N-di (2-ethyl) hexylcarbamoyl group, N, N-diheptylcarbamoyl group, N, N-octylmethylcarbamoyl group, N, N-dioctylcarbamoyl group, N, N -Dinonylcarbamoyl group, N, N-decylmethylcarbamoyl group, N, N-undecylmethylcarbamoyl group, N, N-dodecylmethylcarbamoyl group, N, N-icosylmethylcarbamoyl group, N, N-phenylmethyl Two hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a carbamoyl group, an N, N-diphenylcarbamoyl group, etc., and a group represented by the above formula, or an inducible group thereof (for example, 1 to 20 carbon atoms). Substituted with a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably a group derivatized with an octylsulfamoyl group), or the like). -CON (R 102Z2X) ₂ in the carbamoyl groups and the compounds shown in Tables 1Z2 to ^43Z2.
(However, R ^{102Z2X is the same as R 102Z2} except that it does not become a hydrogen atom.)- ^CON _{(R 102Z2X) 2} (However, in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290) However, R ^102Z2X is the same as ^{R 102Z2} except that it does not become a hydrogen atom).
Preferably, a carbamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or an inducible group thereof, and a group corresponding to ^-CON (R 102Z2) _{2 in the compounds shown in Tables 1Z2 to 43Z2 and the like.} Can be mentioned.

−N (R ^102Z2 ) ₂ is an amino group;
N-methylamino group, N-ethylamino group, N-propylamino group, N-isopropylamino group, N-butylamino group, N-isobutylamino group, N-sec-butylamino group, N-tert-butylamino Group, N-pentylamino group, N-hexylamino group, N- (2-ethyl) hexylamino group, N-heptylamino group, N-octylamino group, N-nonylamino group, N-decylamino group, N-un A decylamino group, an N-dodecylamino group, an N-icosylamino group, an N-phenylamino group, etc., and a group represented by the above formula, etc., which have 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms). A hydrocarbon group or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group)). ^{-NH (R 102Z2X} ) (however, R ^102Z2X is the same as ^{R 102Z2} except that it does not become a hydrogen atom in the amino groups substituted with (groups induced by etc.) and the compounds shown in Tables 1Z2 to 43Z2. ^{-NH (R 102Z2X} ) in the groups corresponding to (there is) and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290 (however, R ^102Z2X is the same as ^{R 102Z2} except that it does not become a hydrogen atom). Group corresponding to;

N, N-dimethylamino group, N, N-ethylmethylamino group, N, N-diethylamino group, N, N-propylmethylamino group, N, N-dipropylamino group, N, N-isopropylmethylamino group , N, N-diisopropylamino group, N, N-tert-butylmethylamino group, N, N-diisobutylamino group, N, N-disec-butylamino group, N, N-ditert-butylamino group, N, N-butylmethylamino group, N, N-dibutylamino group, N, N-dipentylamino group, N, N-di (1-ethylpropyl) amino group, N, N-dihexylamino group, N, N -Di (2-ethyl) hexylamino group, N, N-diheptylamino group, N, N-dioctylamino group, N, N-dinonylamino group, N, N-decylmethylamino group, N, N-undecyl Methylamino group, N, N-dodecylmethylamino group, N, N-icosylmethylamino group, N, N-phenylmethylamino group, N, N-diphenylamino group, etc., and groups represented by the above formulas. 2 hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or derivatizing groups thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon ^{-N (R 102Z2X} ) in the amino group substituted with an alkyl sulfamoyl group (preferably a group derivatized by an octyl sulfamoyl group) of the number 1 to 10 and the compounds shown in Tables 1Z2 to 43Z2. ^{-N (R 102Z2X} ) _{2 in the groups corresponding to 2} (however, R ^{102Z2X is the same as R 102Z2} except that it does not become a hydrogen atom) and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290. (However, R ^102Z2X is the same as ^{R 102Z2} except that it does not become a hydrogen atom.)
Preferably, an amino group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or an inducible group thereof, and a group corresponding to ^{-N (R 102Z2} ) _{2 in the compounds shown in Tables 1Z2 to 43Z2 and the like.} Can be mentioned.

-NHCO-R ^102Z2 includes formylamino groups; acetylamino groups, propanoylamino groups, butanoylamino groups, 2,2-dimethylpropanoylamino groups, pentanoylamino groups, hexanoylamino groups, (2-ethyl). ) Hexanoylamino group, Heptanoylamino group, Octanoylamino group, Nonanoylamino group, Decanoylamino group, Undecanoylamino group, Dodecanoylamino group, Henikosanoylamino group, Bencoylamino group, etc. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group represented by the above formula or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, or a halogen (preferably). Is a chlorine atom), a carbonylamino group (a group derivatized with an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc.) is bonded (when the carbonylamino group is an acylamino group). , The number of carbon atoms is 1 to 40), and in the compounds shown in Tables 1Z2 to ^43Z2 , the group corresponding to -NHCO-R 102Z2 and in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290-NHCO- The groups corresponding to ^{R 102Z2 are listed.}
Preferably, a carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or an inducible group thereof is bonded (when the carbonylamino group is an alkanoylamino group, the carbon number is more preferably 1 to 10) and Table 1Z2. In the compounds shown in Table 43Z2, ^{groups corresponding to -NHCO-R 102Z2} and the like can be mentioned.

-NHCON (R ^102Z2) The _2, table -NHCON (R ^102Z2) ₂ into the appropriate group, Japanese Patent Application No. 2017-016290 In the compounds shown in group and tables 1Z2~ table 43Z2 listed above 1-966 Examples of the compounds shown in (1) include groups corresponding to ^{−NHCON (R 102Z2} _{) 2.}

-NHCOOR ^{102Z2 includes the groups listed above, the groups corresponding to -NHCOOR 102Z2} in the compounds shown in Tables 1Z2 to 43Z2, and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. ^2017-016290. Examples of the group corresponding to.

-OCON (R ^102Z2 ) ₂ ^{includes the groups listed above and the groups corresponding to -OCON (R 102Z2} ) ₂ in the compounds shown in Tables 1Z2 to 43Z2, and Tables 1 to 966 of Japanese Patent Application No. 2017-016290. ^{Examples of the} compounds shown in (1) include groups corresponding to _{−OCON (R 102Z2) 2.}

As the halogen atom, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom and the like are preferable.
Examples of _{M of −SO 3} M and −CO ₂ M include hydrogen atom; alkali metal atom such as lithium atom, sodium atom and potassium atom, and preferably hydrogen atom, sodium atom and potassium atom.

-CO-R ^102Z2 , -COO-R ^102Z2 , -OCO-R ^102Z2 , -COCO-R ^102Z2 , -O-R ^102Z2 , -SO _2- R ^102Z2 , -SO ₂ N (R ^102Z2 ) ₂ , -CON Substituents (first substituents) contained in (R ^102Z2 ) ₂ , -N (R ^102Z2 ) ₂ , -NHCO-R ^102Z2 , -NHCON (R ^102Z2 ) ₂ , -NHCOOR ^102Z2 , -OCON (R ^102Z2 ) _2. May be one or more, and the two or more substituents may be the same or different independently of each other.
Further, the first substituent may have another substituent (second substituent) bonded to the hydrocarbon group contained in a part thereof. The second substituent can be selected from the same groups as the first substituent.

Ring R ^2Z2 and R ^3Z2, R ^3Z2 and R ^4Z2, and the R ^4Z2 and R ^5Z2 form is condensed with the benzene ring of the isoindoline skeleton of the compound represented by the formula (Iz2). The fused ring structure of R ^2Z2 and R ^3Z2, R ^3Z2 and R ^4Z2, and the ring R ^4Z2 and R ^5Z2 form said benzene ring, indene, naphthalene, biphenylene, indacene, acenaphthylene, fluorene, phenalene, phenanthrene, Hydrocyclic condensed ring structures such as anthracene, fluorantene, acephenanthrene, aceanthrene, triphenylene, pyrene, chrysene, N-methylphthalimide, N- (1-phenylethyl) phthalimide and tetracene, and their partial reductions ( For example, 9,10-dihydroanthracene, 1,2,3,4-tetrahydronaphthalene); indol, isoindole, indazole, quinoline, isoquinoline, phthalazine, quinoxaline, quinazoline, cinnoline, carbazole, carboline, phenanthrene, aclysine. , Perimidine, phenanthrene, phenazine and the like, nitrogen-containing fused heterocycles and their partial reductions; oxygen-containing condensed heterocycles such as 3-hydrobenzofuran 2-one and their partial reductions.

If R ^2Z2 and R ^3Z2, R ^3Z2 and R ^4Z2, and the R ^4Z2 and R ^5Z2 form a ring, the ring may have a substituent. Examples of the ^{substituent, R O1Z2, R N1Z2, R} N2Z2, R 1Z2, R 2Z2, R 3Z2, R 4Z2, R 5Z2, which may have a hydrocarbon group represented by R ^101Z2 and R ^102Z2 substituted The same thing as the group can be mentioned. Preferred examples of the substituent, and ^{R O1Z2, R N1Z2, R N2Z2} , R 1Z2, R 2Z2, R 3Z2, R 4Z2, R 5Z2, have a hydrocarbon group represented by R ^101Z2 and R ^102Z2 The same preferred substituents may be mentioned.

If R ^3Z2 and R ^4Z2 form a ring, the R ^2Z2 and R ^5Z2, independently of one another, a hydrogen atom is preferably an amino group and hydroxy group.
If R ^2Z2 and R ^3Z2 form a ring, R ^4Z2 and R ^5Z2 is preferably not form a ring, and more preferably R ^4Z2 and R ^5Z2 is a hydrogen atom.
In the case where R ^4Z2 and R ^5Z2 form a ring, R ^2Z2 and R ^3Z2 is preferably not form a ring, and more preferably R ^2Z2 and R ^3Z2 is a hydrogen atom.

R ^1Z2 is preferably a hydrogen atom.

^RO1Z2 is preferably a hydrocarbon group having 1 to 30 carbon atoms which may have a hydrogen atom or a substituent, and carbon dioxide having 1 to 20 carbon atoms which may have a hydrogen atom or a substituent. It is more preferably a hydrogen group, further preferably a hydrocarbon group having 1 to 15 carbon atoms which may have a hydrogen atom or a substituent, and a carbon which may have a hydrogen atom or a substituent. It is particularly preferable that it is a hydrocarbon group having a number of 1 to 10, and may have a hydrogen atom or a substituent and may have a hydrogen atom or a substituent having 1 to 6 carbon atoms. The hydrocarbon group of 5 is even more preferable, a hydrogen atom, a methyl group, an ethyl group or a phenyl group is particularly preferable, and a hydrogen atom, a methyl group or an ethyl group is most preferable.
^RN1Z2 and ^RN2Z2 have a hydrogen atom, -CO-R ^102Z2 , -COO-R ^101Z2 , -CON (R ^102Z2 ) ₂ , -N (R ^102Z2 ) ₂ , -CO ₂ M or a substituent. It is preferably a hydrocarbon group having 1 to 40 carbon atoms, and more preferably a hydrogen atom or a hydrocarbon group having 1 to 30 carbon atoms which may have a substituent. It is more preferably a hydrocarbon group having 1 to 20 carbon atoms which may have a hydrogen atom or a substituent, and particularly preferably a hydrocarbon group having 1 to 15 carbon atoms which may have a hydrogen atom or a substituent. , A hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent is more preferable, and a hydrocarbon having 1 to 6 carbon atoms which may have a hydrogen atom or a substituent may be used. It is particularly preferably a hydrocarbon group having 1 to 5 carbon atoms which may have a group or a substituent, and even more preferably a hydrogen atom, a methyl group, an ethyl group, or a phenyl group. Most preferably, it is a methyl group or an ethyl group. Further, ^RN1Z2 and ^RN2Z2 may be the same group or different groups, but are preferably the same group.

From the viewpoint of the phase difference value of the color filter formed from the colored composition is ^{reduced, R 2Z2, R 2Z2, R} 3Z2, at least one of R ^4Z2, R ^{5Z2 is, -CO-R 102Z2, -COO-} R ^101Z2 , -OCO-R ^102Z2 , -COCO-R ^102Z2 , -O-R ^102Z2 , -SO _2- R ^101Z2 , -SO ₂ N (R ^102Z2 ) ₂ ^{, -CON} (R 102Z2) ₂ , -N (R ^102Z2) ) ₂ , -NHCO-R ^102Z2 , -NHCO-N (R ^102Z2 ) ₂ , -NHCOOR ^102Z2 , -OCON (R ^102Z2 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, It is preferably a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
A hydrocarbon group having 1 to 40 carbon atoms, which may have a substituent, a halogen atom, -N (R ^102Z2 ) ₂ , a nitro group, and a hydrogen atom in which all or a part of the hydrocarbon atom is substituted with a fluorine atom has 1 to 1 carbon atoms. More preferably, there are 20 hydrocarbon groups, -NHCO-R ^102Z2 , ^{-OR 102Z2} , -SO ₃ M or -CO _{2 M.}
It is more preferably a hydrocarbon group having 1 to 40 carbon atoms which may have a nitro group or a substituent, and even more preferably a nitro group or a tert-butyl group. Or, R ^2Z2 and R ^3Z2, R ^3Z2 and R ^4Z2, or R ^4Z2 and at least one pair of R ^5Z2 is, it is preferable to form a ring.

From the viewpoint of the phase difference value of the color filter formed from the colored composition is ^{reduced, R 2Z2, R 2Z2, R} 3Z2, R 4Z2, at least one of R ^5Z2 is carbon atoms, which may have a substituent 1 to 40 hydrocarbon groups, halogen atoms, -N (R ^102Z2 ) ₂ , nitro groups, hydrocarbon groups with 1 to 20 carbon atoms in which all or part of the hydrogen atoms are replaced by fluorine atoms, -NHCO-R ^102Z2 , ^{-OR 102Z2} , -SO ₃ M or -CO ₂ M, more preferably a hydrocarbon group having 1 to 40 carbon atoms which may have a nitro group or a substituent. It is more preferably a nitro group or a tert-butyl group. Among them, either R ^2Z2 R ^3Z2 is a nitro group or a tert- butyl group, R ^4Z2 and R ^5Z2 is a hydrogen atom, or an R ^2Z2, R ^3Z2 and R ^5Z2 is a hydrogen atom R ^4Z2 nitro It is even more preferably a group or a tert-butyl group.

The compound (IZ2) is preferably a compound represented by the formula (IZ2-B) (hereinafter, may be referred to as a compound (IZ2-B)). When the compound (IZ2) is the compound (IZ2-B), the phase difference value of the color filter formed from the coloring composition containing the compound (IZ2-B) becomes smaller.

[In the formula (IZ2-B),
R ^CO11Z2 and R ^CO21Z2 independently represent -O-R ^O1Z2 or -NR ^N1Z2 R ^N2Z2 , and at least one of ^{R CO11Z2} and R ^{CO21Z2 is -NR N1Z2} R ^N2Z2 .
R ^N1Z2 , R ^N2Z2 , R ^1Z2 , R ^21Z2 , R ^31Z2 , R ^41Z2 , R ^51Z2 are independent of each other, hydrogen atom, -CO-R ^102Z2 , -COO-R ^101Z2 , -OCO-R ^102Z2 , -COCO- R ^102Z2 , ^{-OR 102Z2} , -SO ₂ -R ^101Z2 , -SO ₂ N (R ^102Z2 ) ₂ ^{, -CON} (R 102Z2) ₂ , -N (R ^102Z2 ) ₂ , -NHCO-R ^102Z2 , -NHCO -N (R ^102Z2 ) ₂ , -NHCOOR ^102Z2 , -OCON (R ^102Z2 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, number of carbon atoms which may have a substituent ^{Represents a} heterocyclic group that may have 1 to 40 hydrocarbon groups or substituents, R 21Z2 and R ^31Z2 , R ^31Z2 and R ^41Z2 , and R ^41Z2 and R ^51Z2 , respectively, bonded to each other to form a ring. ^May be formed and at least one of R 21Z2, R ^31Z2 , R ^41Z2 and R ^{51Z2 is -CO-R 102Z2} , -COO-R ^101Z2 , -OCO-R ^102Z2 , -COCO-R ^102Z2 , -O- R ^102Z2 , -SO ₂ -R ^101Z2 , -SO ₂ N (R ^102Z2 ) ₂ ^{, -CON} (R 102Z2) ₂ , -N (R ^102Z2 ) ₂ , -NHCO-R ^102Z2 , -NHCO-N (R ^102Z2 ) ₂ , -NHCOOR ^102Z2 , -OCON (R ^102Z2 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, hydrocarbon having 1 to 40 carbon atoms which may have a substituent. It is a heterocyclic group that may have a group or a substituent, or ^{at least one set of R 21Z2} and R ^31Z2 , R ^31Z2 and R ^41Z2 , and R ^41Z2 and R ^51Z2 are bonded to form a ring. ing.
R ^101Z2 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
^RO1Z2 and ^R102Z2 represent a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent, independently of each other.
M represents a hydrogen atom or an alkali metal atom.
When a ^{plurality of} R O1Z2, R ^N1Z2 , R ^N2Z2 , R ^101Z2 , R ^102Z2 and M exist, they may be the same or different.
The wavy line represents an E-form or a Z-form. ]

Wherein ^{(IZ2-B), R CO11Z2} , CO21Z2, R 21Z2, R 31Z2, as the R ^41Z2 and R ^51Z2, R ^CO1Z2 in formula ^{(IZ2), CO2Z2, R 2Z2} , R 3Z2, R 4Z2, and R ^5Z2 The same thing can be mentioned.

Wherein (IZ2-B), preferred ^{R CO11Z2, CO21Z2, R 21Z2,} R 31Z2, as the R ^41Z2 and R ^51Z2, R ^CO1Z2 in formula ^{(IZ2), CO2Z2, R 2Z2} , R 3Z2, R 4Z2, and R ^The same as the preferred one of 5Z2 can be mentioned.

From the viewpoint of ease of synthesis, it is preferable that ^{R 1Z 2 is a hydrogen atom in the formula (IZ2-B).}

In formula (IZ2-B),
^RO1Z2 is preferably a hydrocarbon group having 1 to 30 carbon atoms which may have a hydrogen atom or a substituent, and carbon dioxide having 1 to 20 carbon atoms which may have a hydrogen atom or a substituent. It is more preferably a hydrogen group, further preferably a hydrocarbon group having 1 to 15 carbon atoms which may have a hydrogen atom or a substituent, and a carbon which may have a hydrogen atom or a substituent. It is particularly preferable that it is a hydrocarbon group having a number of 1 to 10, and may have a hydrogen atom or a substituent and may have a hydrogen atom or a substituent having 1 to 6 carbon atoms. The hydrocarbon group of 5 is even more preferable, a hydrogen atom, a methyl group, an ethyl group, or a phenyl group is particularly preferable, and a hydrogen atom, a methyl group, or an ethyl group is most preferable.
^RN1Z2 and ^RN2Z2 have a hydrogen atom, -CO-R ^102Z2 , -COO-R ^101Z2 , -CON (R ^102Z2 ) ₂ , -N (R ^102Z2 ) ₂ , -CO ₂ M or a substituent. It is preferably a hydrocarbon group having 1 to 40 carbon atoms, and more preferably a hydrogen atom or a hydrocarbon group having 1 to 30 carbon atoms which may have a substituent. It is more preferably a hydrocarbon group having 1 to 20 carbon atoms which may have a hydrogen atom or a substituent, and particularly preferably a hydrocarbon group having 1 to 15 carbon atoms which may have a hydrogen atom or a substituent. , A hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent is more preferable, and a hydrocarbon having 1 to 6 carbon atoms which may have a hydrogen atom or a substituent may be used. It is particularly preferably a hydrocarbon group having 1 to 5 carbon atoms which may have a group or a substituent, and even more preferably a hydrogen atom, a methyl group, an ethyl group, or a phenyl group. Most preferably, it is a methyl group or an ethyl group. Further, ^RN1Z2 and ^RN2Z2 may be the same group or different groups, but are preferably the same group.

From the viewpoint of reducing the phase difference value of the color filter formed from the coloring composition, at least one of ^{R 21Z2} , R ^31Z2 , R ^41Z2 and R ^{51Z2 in the formula (IZ2-B) has a substituent.} A hydrocarbon group having 1 to 40 carbon atoms, a halogen atom, -N (R ^102Z2 ) ₂ , a nitro group, a hydrocarbon group having 1 to 20 carbon atoms in which all or a part of the hydrogen atom is replaced with a fluorine atom, It is preferably a -NHCO-R ^102Z2 , -O-R ^102Z2 , -SO ₃ M or -CO ₂ M, and is a hydrocarbon group having 1 to 40 carbon atoms which may have a nitro group or a substituent. More preferably, it is a nitro group or a tert-butyl group. Among them, R ^31Z2 is a nitro group or a tert-butyl group and R ^21Z2 , R ^41Z2 and R ^51Z2 are hydrogen atoms, or R ^21Z2 , R ^31Z2 and R ^51Z2 are hydrogen atoms and R ^41Z2 is a nitro. It is even more preferably a group or a tert-butyl group.

Specific examples of the compound (IZ2) include, for example,
In the formula (IaZ2), compounds (IaZ2-1) to compounds (IaZ2-494) having substituents shown in Tables 1Z2 to 13Z2 or alkali metal salts thereof;
In formula (IbZ2), compounds (IbZ2-1) to compounds (IbZ2-840) having substituents shown in Tables 14Z2 to 35Z2 or alkali metal salts thereof;
In the formula (IcZ2), compounds (IcZ2-1) to compounds (IcZ2-296) having substituents shown in Tables 36Z2 to 43Z2 or alkali metal salts thereof are mentioned, respectively.
B ^a1Z2 B ^a2Z2 is a formula (BB1) to a formula (BB60), a formula (BBK2), a formula (BBK3), a formula (BBK4), a formula (BBK14), a formula (BBI1), a formula (BBO8), a formula (BBO10). , Represents any of the partial structures represented by the formula (BBD1) and the formula (BBJ2). Formulas (BB1) to formulas (BB60), formulas (BBK2), formulas (BBK3), formulas (BBK4), formulas (BBK14), formulas (BBI1), formulas (BBO8), formulas (BBO10), formulas (BBD1) and ^{The formula (BBJ2) represents B a1Z1} B ^a2Z1 of the formula (IZ1-aa) (BB1) to (BB60), the formula (BBK2), the formula (BBK3), the formula (BBK4), the formula (BBK14), the formula (BBI1). ), Equation (BBO8), Equation (BBO10), Equation (BBD1) and Equation (BBJ2). B ^a1Z2 and B ^a2Z2 represent a bond, respectively, and B ^a1Z2 is a formula (BB1) to a formula (BB60), a formula (BBK2), a formula (BBK3), a formula (BBK4), a formula (BBK14), a formula (BBI1). , formula (BBO8), formula (BBO10), formula (BBD1) and becomes a bond B ^A2Z2 is B ² when a bond of B ¹ of formula ^(BBJ2), B a1Z2 the expression (BB1) ~ formula (BB60 ), Formula (BBK2), Formula (BBK3), Formula (BBK4), Formula (BBK14), Formula (BBI1), Formula (BBO8), Formula (BBO10), Formula (BBD1) and Formula (BBJ2) B ^{2
B a2 Z2} is the bond of ^{B 1} when it is the bond of B 1.
B ^a1Z2 B ^a2Z2 includes the formula (BB1), the formula (BB6), the formula (BB8), the formula (BB11), the formula (BB14), the formula (BB19), the formula (BB37), the formula (BB58), and the formula (BBJ2). ), Formula (BBO8) and formula (BBO10) are preferable, and formula (BB1), formula (BB6) and formula (BB19) are more preferable.

Each symbol in Tables 1Z2 to 43Z2 represents the following partial structure. In addition, in the partial structure
"Me" represents a methyl group
"Et" represents an ethyl group
"Bu" represents a butyl group
"TBu" represents a tert-butyl group and represents
"Hex" represents a hexyl group
"Oct" represents an octyl group
"2EH" represents a 2-ethylhexyl group and represents
"CHM" represents a cyclohexylmethyl group
"CH" represents a cyclohexyl group
"PH" represents a phenyl group
"BZ" represents a benzyl group
"NPR" represents a propyl group
"IPR" represents an isopropyl group
"IBu" represents an isobutyl group and represents
"EOE" stands for −CH ₂ CH ₂ OCH ₂ CH ₃
"ALL" represents an allyl group
"HYE" represents a 2-hydroxyethyl group
"COM" stands for -CO-CH ₃
"COE" stands for -COO-CH ₂ CH ₃
"CBA" stands for -CO ₂ H and represents
"CBM" stands for -CONH ₂
"NH ₂ " represents -NH 2.
In the partial structure shown by the following formula, * represents a bond.

For example, the compound (IaZ2-1) is a compound represented by the formula (IaZ2-1).

Compound (IaZ2-1) -Compound (IaZ2-165), (IaZ2-223) -Compound (IaZ2-494), Compound (IbZ2-1) -Compound (IbZ2-248), Compound (IbZ2-3-11) -Compound ( IbZ2-840), compounds (IcZ2-1) to compounds (IcZ2-234) are preferred.
Compound (IaZ2-1) -Compound (IaZ2-165), (IaZ2-223) -Compound (IaZ2-436), Compound (IbZ2-1) -Compound (IbZ2-248), Compound (IbZ2-3-11) -Compound ( IbZ2-782), compounds (IcZ2-1) to compounds (IcZ2-234) are more preferred.
Compounds (IaZ2-1) to compounds (IaZ2-165), compounds (IbZ2-1) to compounds (IbZ2-248), and compounds (IcZ2-1) to compounds (IcZ2-234) are more preferred.
Compounds (IaZ2-1) to compounds (IaZ2-111), compounds (IbZ2-1) to compounds (IbZ2-248), and compounds (IcZ2-1) to compounds (IcZ2-234) are even more preferred.
Compounds (IaZ2-1) to compounds (IaZ2-54) and compounds (IbZ2-1) to compounds (IbZ2-186) are particularly preferred.

_{Specific examples of the compound (IZ2) include compounds in which -SO 3} M or -CO ₂ M is substituted for 1 to 3 hydrogen atoms contained in the compounds shown in Tables 1Z2 to 43Z2. Be done. For example, a compound in which 1 to 3 sulfo groups are bonded to the compound (IaZ2-1) in Table 1Z2 is represented by the following structure. However, in the formula, − (SO ₃ H) means that any hydrogen atom of the compound (IaZ2-1) in Table 1Z2 is substituted.

Compound (IaZ2-1) -Compound (IaZ2-165), (IaZ2-223) -Compound (IaZ2-494), Compound (IbZ2-1) -Compound (IbZ2-248), Compound (IbZ2-3-11) -Compound ( IbZ2-840), compounds (IcZ2-1) to compounds (IcZ2-234) to which 1 to 3 -SO ₃ M or -CO ₂ M are bound are preferable.
Compound (IaZ2-1) -Compound (IaZ2-165), (IaZ2-223) -Compound (IaZ2-436), Compound (IbZ2-1) -Compound (IbZ2-248), Compound (IbZ2-3-11) -Compound ( IbZ2-782), compounds (IcZ2-1) to compounds (IcZ2-234) to which 1 to 3 -SO ₃ M or -CO ₂ M are bound are more preferable.
Compound (IaZ2-1) -Compound (IaZ2-165), Compound (IbZ2-1) -Compound (IbZ2-248) and Compound (IcZ2-1) -Compound (IcZ2-234) with 1 to 3 -SOs. _{Compounds to which 3} M or -CO ₂ M are attached are more preferred.
Compound (IaZ2-1) to compound (IaZ2-111), compound (IbZ2-1) to compound (IbZ2-248) and compound (IcZ2-1) to compound (IcZ2-234) with 1 to 3 -SOs. _{Compounds to which 3} M or -CO ₂ M are attached are even more preferred.
Compounds (IaZ2-1) to compound (IaZ2-54) and compounds (IbZ2-1) to compound (IbZ2-186) to which 1 to 3 -SO ₃ M or -CO ₂ M are bound are particularly preferable. preferable.

Examples of the compound to which −CO ₂ M is bound include compound (IbZ2-2), compound (IbZ2-3), compound (IbZ2-4), compound (IbZ2-12), compound (IbZ2-126), and compound (IbZ2). -127), compound (IbZ2-687), compound (IbZ2-370) and the like to which two -CO ₂ H are bound, particularly compound (IbZ2-317), compound (IbZ2-318), compound (IbZ2). -319), compound (IbZ2-320), compound (IbZ2-515), compound (IbZ2-516), compound (IbZ2-706), compound (IbZ2-389) and the like are particularly preferable.

As the compound (IZ2), in the formula (IZ2),
R ^CO1Z2 and R ^CO1Z2 are the same group and
^RO1Z2 is a hydrocarbon group having 1 to 20 carbon atoms which may have a hydrogen atom or _{a substituent selected from the group consisting of -SO 3} M and -CO _{2 M.}
R ^N1Z2 and R ^N2Z2 are independently selected from the group consisting of hydrogen atom, -CO-R ^102Z2 , -COO-R ^101Z2 , -CON (R ^102Z2 ) ₂ , or -SO ₃ M and -CO _{2 M.} It is a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent (s).
R ^{1Z 2} is a hydrocarbon group having 1 to 20 carbon atoms, which may have a substituent selected from the group consisting of a hydrogen atom, -SO ₃ M and -CO _{2 M, -SO 3} M or -CO ₂ M and
In R ^{2Z2 to} R ^5Z2 , hydrogen atom, hydrocarbon group having 1 to 20 carbon atoms, halogen atom, -N (R 102Z2) ₂ , nitro group, and all or part of hydrogen atom are independently ^{composed of hydrogen atom.} Substituted hydrocarbon groups with 1 to 20 carbon atoms, -NHCO-R ^102Z2 , ^{-OR 102Z2} , -SO ₃ M or -CO ₂ M.
R ^102Z2 is a hydrocarbon group having 1 to 20 carbon atoms which may have a hydrogen atom or _{a substituent selected from the group consisting of -SO 3} M and -CO _{2 M.}
R ^101Z2 is a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent selected from the group consisting of _{-SO 3} M and -CO _{2 M.}
M is preferably a compound which is a hydrogen atom or an alkali metal atom.
R ^CO1Z2 and R ^CO1Z2 are the same group and
^RO1Z2 is a hydrocarbon group having 1 to 10 carbon atoms which may have a hydrogen atom or _{a substituent selected from the group consisting of -SO 3} M and -CO _{2 M.}
R ^N1Z2 and R ^N2Z2 have substituents independently of each other selected from the group consisting of hydrogen atom, -CO-R ^102Z2 , -CON (R ^102Z2 ) ₂ , or -SO ₃ M and -CO _{2 M.} It is a hydrocarbon group having 1 to 10 carbon atoms which may be present.
R ^1Z2 is a hydrogen atom
In R ^{2Z2 to} R ^5Z2 , hydrogen atom, hydrocarbon group having 1 to 10 carbon atoms, halogen atom, -N (R 102Z2) ₂ , nitro group, and all or part of hydrogen atom are independently ^{composed of hydrogen atom.} Substituted hydrocarbon groups with 1 to 10 carbon atoms, -NHCO-R ^102Z2 , ^{-OR 102Z2} , -SO ₃ M or -CO ₂ M.
R ^102Z2 is a hydrocarbon group having 1 to 10 carbon atoms which may have a hydrogen atom or _{a substituent selected from the group consisting of -SO 3} M and -CO _{2 M.}
R ^101Z2 is a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of _{-SO 3} M and -CO _{2 M.}
M is more preferably a compound which is a hydrogen atom or an alkali metal atom.
R ^CO1Z2 and R ^CO1Z2 are the same group and
^RO1Z2 is a hydrocarbon group having 1 to 10 carbon atoms which may have a hydrogen atom or _{a substituent selected from the group consisting of -SO 3} M and -CO _{2 M.}
R ^N1Z2 and R ^N2Z2 have substituents independently of each other selected from the group consisting of hydrogen atom, -CO-R ^102Z2 , -CON (R ^102Z2 ) ₂ , or -SO ₃ M and -CO _{2 M.} It is a hydrocarbon group having 1 to 10 carbon atoms which may be present.
R ^1Z2 is a hydrogen atom
R ^{2Z2 to} R ^5Z2 are independently hydrogen atom, hydrocarbon group having 1 to 10 carbon atoms, halogen atom, -N (R ^102Z2 ) ₂ , nitro group, trifluoromethyl group, ^{-OR 102Z2} , respectively. -SO ₃ M or -CO ₂ M,
R ^102Z2 is a hydrocarbon group having 1 to 10 carbon atoms which may have a hydrogen atom or _{a substituent selected from the group consisting of -SO 3} M and -CO _{2 M.}
R ^101Z2 is a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of _{-SO 3} M and -CO _{2 M.}
M is more preferably a compound which is a hydrogen atom or an alkali metal atom.

As for the compound (IZ2), when R ^1Z2 is a hydrogen atom, a compound represented by the formula (pt1Z2) (hereinafter, may be referred to as a phthalonitrile compound) is referred to as a compound represented by the formula (pt2Z2) (hereinafter, referred to as an alkoxide compound). It can be produced by further reacting the compound represented by the formula (pt3Z2) with the compound represented by the formula (pt4Z2) in the presence of an acid. When R ^1Z2 is other than a hydrogen atom, the compound (IZ2) can be produced by further reacting with a compound represented by the formula (pt5Z2).

Expression (pt1Z2), formula (pt2Z2), formula (pt3Z2), formula (pt4Z2), wherein (pt5Z2) and formula ^{(IZ2), R CO1Z2, R} CO2Z2, R 1Z2, R 2Z2, R 3Z2, R 4Z2, And R ^{5Z 2} have the same meaning as described above.
R ^14Z2 represents an alkyl group having 1 to 20 carbon atoms.
M ^{1Z 2} represents an alkali metal atom.
LG represents a halogen atom, a methanesulfonyloxy group, a toluenesulfonyloxy group or a trifluoromethanesulfonyloxy group. ]

^Examples of the alkyl group having 1 to 20 carbon atoms represented by R 14Z2 include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, a sec-butyl group and a tert-butyl group, which are preferable. Examples include alkyl groups having 1 to 6 carbon atoms.
Examples of the alkali metal atom represented by M ^{1Z 2} include a lithium atom, a sodium atom and a potassium atom.

The amount of the alkoxide compound used is usually 0.1 to 10 mol, preferably 0.2 to 5 mol, and more preferably 0.3 to 3 mol, based on 1 mol of the phthalonitrile compound. More preferably, it is 0.4 to 2 mol.

The amount of the compound (pt3Z2) used is usually 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, still more preferably 1 mol, relative to 1 mol of the phthalonitrile compound. ~ 2 mol.
The amount of the compound (pt4Z2) used is usually 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, still more preferably 1 mol, relative to 1 mol of the phthalonitrile compound. ~ 2 mol.

Examples of the acid include inorganic acids such as hydrochloric acid, hydrobromic acid, hydroiodic acid, sulfuric acid, nitric acid, fluorosulfonic acid and phosphoric acid; sulfonic acids such as methanesulfonic acid, trifluoromethanesulfonic acid and p-toluenesulfonic acid; Examples thereof include carboxylic acids such as acetic acid, citric acid, formic acid, gluconic acid, lactic acid, oxalic acid and tartrate acid, preferably hydrochloric acid, hydrobromic acid, sulfuric acid, methanesulfonic acid, trifluoromethanesulfonic acid, p-toluenesulfonic acid and Examples include carboxylic acids, more preferably acetic acids.
The amount of the acid used is usually 1 to 20 mol, preferably 1 to 10 mol, more preferably 1 to 8 mol, still more preferably 1 to 6 mol, based on 1 mol of the phthalonitrile compound. be.

The reaction of the phthalonitrile compound, the alkoxide compound, the compound (pt3Z2) and the compound (pt4Z2) is usually carried out in the presence of a solvent.
As the solvent, water; a nitrile solvent such as acetonitrile; an alcohol solvent such as methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol and 1-octanol; an ether solvent such as tetrahydrofuran; a ketone solvent such as acetone; acetic acid. Ester solvents such as ethyl; aliphatic hydrocarbon solvents such as hexane; aromatic hydrocarbon solvents such as toluene; halogenated hydrocarbon solvents such as methylene chloride and chloroform; amides such as N, N-dimethylformaldehyde and N-methylpyrrolidone. Solvents: Sulfoxide solvents such as dimethylsulfoxide, preferably water, nitrile solvents, alcohol solvents, ether solvents, ketone solvents, ester solvents, aromatic hydrocarbon solvents, halogenated hydrocarbon solvents, amide solvents and sulfoxide solvents. More preferably, water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, tetrahydrofuran, acetone, ethyl acetate, toluene, methylene chloride, chloroform, N, N-dimethylformaldehyde. , N-Methylpyrrolidone and dimethylsulfoxide, more preferably water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, acetone, methylene chloride, chloroform, N, N. -Dimethylformaldehyde, N-methylpyrrolidone and dimethylsulfoxide are mentioned, and water, acetonitrile, methanol, ethanol and 2-propanol are particularly preferable.
The amount of the solvent used is usually 1 to 1000 parts by mass with respect to 1 part by mass of the phthalonitrile compound.

The reaction temperature is usually 0 to 200 ° C, preferably 0 to 100 ° C, more preferably 0 to 70 ° C, still more preferably 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

The amount of the compound (pt5Z2) used is usually 1 to 10 mol, preferably 1 to 5 mol, and more preferably 1 to 3 mol, relative to 1 mol of the compound (IZ2) in which ^{R 1Z2 is a hydrogen atom.} It is more preferably 1 to 2 mol.

When the compound (pt5Z2) is reacted, it is preferable that a base coexists. Bases include organic bases such as triethylamine, 4- (N, N-dimethylamino) pyridine, pyridine and piperidine; metal alkoxides such as sodium methoxide, sodium ethoxide, sodium tert-butoxide and potassium tert-butoxide; butyl lithium. , Tert-Organic metal compounds such as butyllithium and phenyllithium; and inorganic bases such as lithium hydroxide, sodium hydroxide and potassium hydroxide.

The amount of the base used is usually 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, and further, with respect to 1 mol of the compound (IZ2) in which ^{R 1Z2 is a hydrogen atom.} It is preferably 1 to 2 mol.

The reaction of compound (pt5Z2) is usually carried out in the presence of a solvent. The solvent can be selected from the same range as described above.
The amount of the solvent used is usually 1 to 1000 parts by mass with respect to 1 part by mass of the compound (IZ2) in which ^{R 1Z2 is a hydrogen atom.} The reaction temperature of the compound (pt5Z2) is usually −90 to 200 ° C., preferably −80 to 100 ° C., and more preferably 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

If compound (IZ2) _{does not have a sulfo group or -SO 3} M ²² , the compound (IZ 2) is reacted with a sulphonizing agent such as fuming sulfuric acid or chlorosulfuric acid to cause a sulfo group or -SO ₃ M ^22. Can be introduced.
M ²² represents an alkali metal atom.
Examples ^{of the alkali metal atom represented by M 22} include a lithium atom, a sodium atom and a potassium atom.

_{The amount of SO 3} used in fuming sulfuric acid is usually 1 to 50 mol, preferably 5 to 40 mol, more preferably 5 to 30 mol, still more preferably 5 to 30 mol, per 1 mol of compound (IZ2). It is 5 to 25 mol.
The amount of sulfuric acid used in fuming sulfuric acid is usually 1 to 200 mol, preferably 10 to 100 mol, more preferably 10 to 75 mol, and further preferably 10 to 1 mol of compound (IZ2). ~ 50 mol.

The amount of chlorosulfonic acid used is usually 1 to 500 mol, preferably 10 to 300 mol, more preferably 10 to 200 mol, still more preferably 10 to 150 mol, relative to 1 mol of compound (IZ2). It is a mole.

The reaction temperature for sulfonation is usually -20 to 200 ° C, preferably -10 to 100 ° C, and more preferably 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

The method for extracting the compound (IZ2) from the reaction mixture is not particularly limited, and the compound (IZ2) can be extracted by various known methods. For example, after completion of the reaction, the compound (IZ2) can be taken out by filtering the reaction mixture. Further, after filtration, the obtained residue may be subjected to column chromatography, recrystallization or the like. Further, after completion of the reaction, the solvent of the reaction mixture may be distilled off and then purified by column chromatography.

<Compound (IZ3)>
The compound (IZ3) is a compound represented by the formula (IZ3).

[In formula (IZ3),
R ^1Z3 , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , and R ^7Z3 are independent of each other, hydrogen atom, -CO-R ^102Z3 , -COO-R ^101Z3 , -OCO-R ^102Z3 , -COCO. -R ^102Z3 , -O-R ^102Z3 , -SO ₂ -R ^101Z3 , -SO ₂ N (R ^102Z3 ) ₂ ^{, -CON} (R 102Z3) ₂ , -N (R ^102Z3 ) ₂ , -NHCO-R ^102Z3 ,- NHCO-N (R ^102Z3 ) ₂ , -NHCOOR ^102Z3 , -OCON (R ^102Z3 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, carbon which may have a substituent Represents a heterocyclic group which may have a hydrocarbon group or a substituent of the number 1 to 40.
R ^2Z3 and R ^3Z3 , R ^3Z3 and R ^4Z3 , and R ^4Z3 and R ^5Z3 may be coupled to each other to form a ring, respectively.
R ^101Z3 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102Z3 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
M represents a hydrogen atom or an alkali metal atom.
When a ^{plurality of R 101Z3} , R ^102Z3 and M are present, they may be the same or different.
The wavy line represents an E-form or a Z-form. ]

The ^{hydrocarbon groups represented by R 1Z3} , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^102Z3 have 1 to 40 carbon atoms, preferably 1 to 30 carbon atoms. Yes, more preferably 1 to 20, still more preferably 1 to 15, and particularly preferably 1 to 10.

The hydrocarbon groups having 1 to 40 carbon atoms represented by R ^1Z3 , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^{102Z3 are aliphatic hydrocarbon groups and aromatic hydrocarbons.} It may be a hydrogen group, and the aliphatic hydrocarbon group may be saturated or unsaturated, or may be a chain or an alicyclic.

Saturated or unsaturated chain hydrocarbon groups represented by R ^1Z3 , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^102Z3 include methyl group, ethyl group and propyl group. , Butyl group, pentyl group, hexyl group, heptyl group, octyl group, nonyl group, decyl group, undecyl group, dodecyl group, heptadecyl group, octadecyl group, linear alkyl group such as icosyl group; isopropyl group, isobutyl Group, sec-butyl group, tert-butyl group, (2-ethyl) butyl group, isopentyl group, neopentyl group, tert-pentyl group, (1-methyl) pentyl group, (2-methyl) pentyl group, (1-methyl) pentyl group Branched alkyl groups such as ethyl) pentyl group, (3-ethyl) pentyl group, isohexyl group, (5-methyl) hexyl group, (2-ethyl) hexyl group and (3-ethyl) heptyl group; vinyl Group, 1-propenyl group, 2-propenyl group (allyl group), (1-methyl) ethenyl group, 2-butenyl group, 3-butenyl group, 1,3-butadienyl group, (1- (2-propenyl)) Examples thereof include alkenyl groups such as an ethenyl group, a (1,2-dimethyl) propenyl group and a 2-pentenyl group; and the like. The saturated or unsaturated chain hydrocarbon group preferably has 1 to 30 carbon atoms, more preferably 1 to 20 carbon atoms, still more preferably 1 to 15 carbon atoms, and particularly preferably 1 to 10 carbon atoms. It is more preferably 1 to 8, and even more preferably 1 to 5. Of these, a linear or branched alkyl group having 1 to 10 carbon atoms, more preferably 1 to 8 carbon atoms is particularly preferable, and a methyl group, an ethyl group, and a tert-butyl group are particularly preferable.

The saturated or unsaturated alicyclic hydrocarbon groups represented by ^{R 1Z3} , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^{102Z3 include cyclopropyl group and 1-methyl.} Cyclopropyl group, cyclobutyl group, cyclopentyl group, cyclohexyl group, cycloheptyl group, 1-methylcyclohexyl group, 2-methylcyclohexyl group, 3-methylcyclohexyl group, 4-methylcyclohexyl group, 1,2-dimethylcyclohexyl group, 1 , 3-Dimethylcyclohexyl group, 1,4-dimethylcyclohexyl group, 2,3-dimethylcyclohexyl group, 2,4-dimethylcyclohexyl group, 2,5-dimethylcyclohexyl group, 2,6-dimethylcyclohexyl group, 3,4 -Dimethylcyclohexyl group, 3,5-dimethylcyclohexyl group, 2,2-dimethylcyclohexyl group, 3,3-dimethylcyclohexyl group, 4,4-dimethylcyclohexyl group, cyclooctyl group, 2,4,6-trimethylcyclohexyl group , 2,2,6,6-tetramethylcyclohexyl group and 3,3,5,5-tetramethylcyclohexyl group, 4-pentylcyclohexyl group, 4-octylcyclohexyl group, 4-cyclohexylcyclohexyl group and other cycloalkyl groups; Cycloalkenyl groups such as cyclohexenyl group (eg, cyclohex-2-ene, cyclohex-3-ene), cycloheptenyl group, cyclooctenyl group; norbornan group, adamantyl group, bicyclo [2.2.2] octane and the like can be mentioned. The saturated or unsaturated alicyclic hydrocarbon group preferably has 3 to 30, more preferably 3 to 20, even more preferably 4 to 20, and even more preferably 4 to 15. Yes, more particularly preferably 5 to 15, and most preferably 5 to 10. Of these, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, and a cyclooctyl group are particularly preferable.

The ^{aromatic hydrocarbon groups represented by R 1Z3} , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^102Z3 include phenyl group, o-tryl group and m-trill group. , P-tryl group, 2-ethylphenyl group, 3-ethylphenyl group, 4-ethylphenyl group, 2,3-dimethylphenyl group, 2,4-dimethylphenyl group, 2,5-dimethylphenyl group, 2, 6-Dimethylphenyl group, 3,4-dimethylphenyl group, 3,5-dimethylphenyl group, 4-vinylphenyl group, o-isopropylphenyl group, m-isopropylphenyl group, p-isopropylphenyl group, o-tert- Butylphenyl group, m-tert-butylphenyl group, p-tert-butylphenyl group, mesityl group, 4-ethylphenyl group, 4-butylphenyl group, 4-pentylphenyl group, 2,6-bis (2-propyl) ) Phenyl group, 4-cyclohexylphenyl group, 2,4,6-trimethylphenyl group, 4-octylphenyl group, 1-naphthyl group, 2-naphthyl group, 5,6,7,8-tetrahydro-1-naphthyl group , 5,6,7,8-Tetrahydro-2-naphthyl group, fluorenyl group, phenyl tril group and aromatic hydrocarbon group such as anthryl group, pyrenyl group; and the like. The number of carbon atoms of the aromatic hydrocarbon group is preferably 6 to 30, more preferably 6 to 20, and even more preferably 6 to 15.

The ^{hydrocarbon groups represented by R 1Z3} , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^102Z3 are the above-mentioned hydrocarbon groups (for example, aromatic hydrocarbon groups). , At least one of a chain hydrocarbon group and an alicyclic hydrocarbon group) may be combined, and an aralkyl group such as a benzyl group, a phenethyl group, a 1-methyl-1-phenylethyl group; Arylalkenyl group such as tenyl group (phenylvinyl group); arylalkynyl group such as phenylethynyl group; phenyl group to which one or more phenyl groups such as biphenylyl group and terphenylyl group are bonded; cyclohexylmethylphenyl group, benzylphenyl group, (Dimethyl (phenyl) methyl) Phenyl group and the like can be mentioned.
The ^{groups represented by R 1Z3} , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^102Z3 are the hydrocarbon groups listed above (for example, chain hydrocarbon groups and alicyclics). (Formula hydrocarbon group), for example, cyclopropylmethyl group, cyclopropylethyl group, cyclobutylmethyl group, cyclobutylethyl group, cyclopentylmethyl group, cyclopentylethyl group, cyclohexylmethyl group, 2-methylcyclohexylmethyl It may be an alkyl group to which one or more alicyclic hydrocarbon groups such as a group, a cyclohexylethyl group and an adamantylmethyl group are bonded.
These carbon numbers are preferably 4 to 30, more preferably 6 to 30, even more preferably 6 to 20, still preferably 4 to 20, and even more preferably 4 to 15. , Particularly preferably 6 to 15.

The ^{hydrocarbon groups represented by R 1Z3} , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^102Z3 may have a substituent. The substituent may be monovalent or divalent. For the divalent substituent, it is preferable that two bonds are bonded to the same carbon atom to form a double bond.
As the monovalent substituent,
Methoxy group, ethoxy group, propoxy group, isopropoxy group, butoxy group, isobutoxy group, sec-butoxy group, tert-butoxy group, pentyloxy group, hexyloxy group, (2-ethyl) hexyloxy group, heptyloxy group, Octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, dodecyloxy group, (2-ethyl) hexyloxy group, icosyloxy group, 1-phenylethoxy group, 1-methyl-1-phenylethoxy group, phenyloxy group , O-Trilloxy group, 2,3-dimethylphenyloxy group, 2,4-dimethylphenyloxy group, 2,5-dimethylphenyloxy group, 2,6-dimethylphenyloxy group, 3,4-dimethylphenyloxy group , 3,5-dimethylphenyloxy group, 2,2-dicyanophenyloxy group, 2,3-dicyanophenyloxy group, 2,4-dicyanophenyloxy group, 2,5-dicyanophenyloxy group, 2,6- Dicyanophenyloxy group, 3,4-dicyanophenyloxy group, 3,5-dicyanophenyloxy group, 4-methoxyphenyloxy group, 2-methoxyphenyloxy group, 3-methoxyphenyloxy group, 4-ethoxyphenyloxy group , 2-ethoxyphenyloxy group, 3-ethoxyphenyloxy group, etc., and groups represented by the following formulas, etc., which have 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or a derivatizing group thereof. (For example, a group derivatized with a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), or the like). Is an oxy group bonded to one side;

Methylthio group, ethylthio group, propylthio group, butylthio group, tert-butylthio group, pentylthio group, hexylthio group, (2-ethyl) hexylthio group, heptylthio group, octylthio group, nonylthio group, decylthio group, undecylthio group, dodecylthio group, icosylthio group. A sulfanyl group to which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group, a phenylthio group and an o-tolylthio group is bonded;

Epoxy group, oxetanyl group, tetrahydrofuryl group, tetrahydropyranyl group;
Holmil group;
Acetyl group, propanoyl group, butanoyl group, 2,2-dimethylpropanoyl group, pentanoyl group, hexanoyl group, (2-ethyl) hexanoyl group, heptanoil group, octanoyl group, nonanoyl group, decanoyl group, undecanoyl group, dodecanoyl group, A hydrocarbon group having a carbon number of 1 to 20 (preferably having a carbon number of 1 to 11) or an inducible group thereof (for example, a carboxy group or a sulfo group) such as a henicosanoyl group, a benzoyl group, and a group represented by the following formula. , A carbonyl group to which a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. are bonded. When the carbonyl group is an alkanoyl group, the number of carbon atoms is preferably 2 to 12);

Methoxycarbonyl group, ethoxycarbonyl group, propoxycarbonyl group, butoxycarbonyl group, tert-butoxycarbonyl group, pentyloxycarbonyl group, hexyloxycarbonyl group, (2-ethyl) hexyloxycarbonyl group, heptyloxycarbonyl group, octyloxycarbonyl group Group, nonyloxycarbonyl group, decyloxycarbonyl group, undecyloxycarbonyl group, dodecyloxycarbonyl group, icosyloxycarbonyl group, phenyloxycarbonyl group, o-tolyloxycarbonyl group, etc., and represented by the following formula A hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), a carbon number of carbon atoms). An oxycarbonyl group to which 1 to 10 alkylsulfamoyl groups (preferably groups derivatized with an octylsulfamoyl group) or the like are attached;

Amino group;
N-methylamino group, N, N-dimethylamino group, N-ethylamino group, N, N-diethylamino group, N-propylamino group, N, N-dipropylamino group, N-isopropylamino group, N, N-diisopropylamino group, N-butylamino group, N, N-dibutylamino group, N-isobutylamino group, N, N-diisobutylamino group, N-sec-butylamino group, N, N-disec-butyl Amino group, N-tert-butylamino group, N, N-ditert-butylamino group, N-pentylamino group, N, N-dipentylamino group, N- (1-ethylpropyl) amino group, N, N -Di (1-ethylpropyl) amino group, N-hexylamino group, N, N-dihexylamino group, N- (2-ethyl) hexylamino group, N, N-di (2-ethyl) hexylamino group, N-Heptylamino Group, N, N-Diheptylamino Group, N-octylamino Group, N, N-Dioctylamino Group, N-Nonylamino Group, N, N-Dinonylamino Group, N-Phenylamino Group, N, N -Diphenylamino group, N, N-ethylmethylamino group, N, N-propylmethylamino group, N, N-isopropylmethylamino group, N, N-butylmethylamino group, N-decylamino group, N, N- Decylmethylamino Group, N-Undecylamino Group, N, N-Undecylmethylamino Group, N-Dodecylamino Group, N, N-Dodecylmethylamino Group, N-Icosylamino Group, N, N-Icosylmethylamino One or two carbon atoms 1 to 20 (preferably 1 carbon atom) such as a group, an N, N-tert-butylmethylamino group, an N, N-phenylmethylamino group, etc., and a group represented by the following formula. A hydrocarbon group of 10) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), and an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsul). Amino group substituted with a famoyl group) or a derivatized group);

Sulfamoyl group;
N-methylsulfamoyl group, N, N-dimethylsulfamoyl group, N-ethylsulfamoyl group, N, N-diethylsulfamoyl group, N-propylsulfamoyl group, N, N-dipropyls Rufamoyl group, N-isopropylsulfamoyl group, N, N-diisopropylsulfamoyl group, N-butylsulfamoyl group, N, N-dibutylsulfamoyl group, N-isobutylsulfamoyl group, N, N-diisobutylsulfamoyl group, N-sec-butylsulfamoyl group, N, N-disec-butylsulfamoyl group, N-tert-butylsulfamoyl group, N, N-ditert-butylsul Famoyl group, N-pentyl sulfamoyl group, N, N-dipentyl sulfamoyl group, N- (1-ethylpropyl) sulfamoyl group, N, N-di (1-ethylpropyl) sulfamoyl group, N-hexyl Sulfamoyl group, N, N-dihexyl sulfamoyl group, N- (2-ethyl) hexyl sulfamoyl group, N, N-di (2-ethyl) hexyl sulfamoyl group, N-heptyl sulfamoyl Group, N, N-diheptyl sulfamoyl group, N-octyl sulfamoyl group, N, N-dioctyl sulfamoyl group, N, N-octylmethyl sulfamoyl group, N-nonyl sulfamoyl group, N, N-Dinonyl sulfamoyl group, N-phenyl sulfamoyl group, N, N-diphenyl sulfamoyl group, N, N-ethylmethyl sulfamoyl group, N, N-propylmethyl sulfamoyl group, N, N-isopropylmethylsulfamoyl group, N, N-butylmethylsulfamoyl group, N-decylsulfamoyl group, N, N-decylmethylsulfamoyl group, N-undecylsulfamoyl group, N , N-Undecylmethyl Sulfamoyl Group, N-Dodecyl Sulfamoyl Group, N, N-Dodecyl Methyl Sulfamoyl Group, N-Icosyl Sulfamoyl Group, N, N-Icosyl Methyl Sulfamoyl Group, N, N-tert-butylmethylsulfamoyl group, N, N-phenylmethylsulfamoyl group, etc., and one or two groups represented by the following formula, etc., having 1 or 2 carbon atoms (preferably carbons) A hydrocarbon group having a number of 1 to 10 or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), and an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably). Induced by octylsulfamoyl group) etc. Sulfamoyl group substituted with (ta group);

Formylamino group; acetylamino group, propanoylamino group, butanoylamino group, 2,2-dimethylpropanoylamino group, pentanoylamino group, hexanoylamino group, (2-ethyl) hexanoylamino group, heptanoil Amino group, octanoylamino group, nonanoylamino group, decanoyylamino group, undecanoylamino group, dodecanoylamino group, henicosanoylamino group, benzoylamino group, etc., and groups represented by the following formulas. Etc., a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 12 carbon atoms) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), 1 carbon atom). A carbonylamino group to which 10 to 10 alkylsulfamoyl groups (preferably groups derivatized with an octylsulfamoyl group) or the like are bonded (when the carbonylamino group is an alkanoylamino group, the number of carbon atoms is preferably 1. ~ 12);

Hydroxy group;
Halogen atoms such as fluorine atom, chlorine atom, bromine atom and iodine atom;
Carboxy group, -CO ₂ M ² (M ² is alkali metal, preferably lithium, sodium, potassium); sulfo group, -SO ₃ M ² (M ² is alkali metal, preferably lithium, sodium, potassium); nitro group Cyan group;

Formyloxy group; acetoxy group, propanoyloxy group, butanoyloxy group, 2,2-dimethylpropanoyloxy group, pentanoyloxy group, hexanoyloxy group, (2-ethyl) hexanoyloxy group, heptanoyloxy group Carbons such as groups, octanoyloxy groups, nonanoyloxy groups, decanoyloxy groups, undecanoyloxy groups, dodecanoyloxy groups, henicosanoyloxy groups, benzoyloxy groups, etc., and groups represented by the following formulas. A hydrocarbon group having a number of 1 to 20 (preferably 1 to 10 carbon atoms) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), and a group having 1 to 10 carbon atoms. A carbonyloxy group to which an alkylsulfamoyl group (preferably a group derivatized with an octylsulfamoyl group) or the like is bonded (when the carbonyloxy group is an alkanoyloxy group, the number of carbon atoms is preferably 1 to 10). be);

Methylsulfonyl group, ethylsulfonyl group, propylsulfonyl group, butylsulfonyl group, pentylsulfonyl group, hexylsulfonyl group, (2-ethyl) hexylsulfonyl group, heptylsulfonyl group, octylsulfonyl group, nonylsulfonyl group, decylsulfonyl group, un Decylsulfonyl group, dodecylsulfonyl group, icosylsulfonyl group, phenylsulfonyl group, p-tolylsulfonyl group and the like, and groups represented by the following formulas having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms). A hydrocarbon group or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group)). Sulfonyl group to which (groups derivatized by etc.) are bound;

Carbamic group;
N-Methylcarbamoyl group, N, N-dimethylcarbamoyl group, N-ethylcarbamoyl group, N, N-diethylcarbamoyl group, N-propylcarbamoyl group, N, N-dipropylcarbamoyl group, N-isopropylcarbamoyl group, N , N-diisopropylcarbamoyl group, N-butylcarbamoyl group, N, N-dibutylcarbamoyl group, N-isobutylcarbamoyl group, N, N-diisobutylcarbamoyl group, N-sec-butylcarbamoyl group, N, N-disec- Butylcarbamoyl group, N-tert-butylcarbamoyl group, N, N-ditert-butylcarbamoyl group, N-pentylcarbamoyl group, N, N-dipentylcarbamoyl group, N- (1-ethylpropyl) carbamoyl group, N, N-di (1-ethylpropyl) carbamoyl group, N-hexyl carbamoyl group, N, N-dihexyl carbamoyl group, N- (2-ethyl) hexyl carbamoyl group, N, N-di (2-ethyl) hexyl carbamoyl group , N-Heptylcarbamoyl group, N, N-diheptylcarbamoyl group, N-octylcarbamoyl group, N, N-dioctylcarbamoyl group, N-nonylcarbamoyl group, N, N-octylmethylcarbamoyl group, N, N-octyl Butylcarbamoyl group, N, N-dinonylcarbamoyl group, N-phenylcarbamoyl group, N, N-diphenylcarbamoyl group, N, N-ethylmethylcarbamoyl group, N, N-propylmethylcarbamoyl group, N, N-isopropyl Methylcarbamoyl group, N, N-butylmethylcarbamoyl group, N-decylcarbamoyl group, N, N-decylmethylcarbamoyl group, N-undecylcarbamoyl group, N, N-undecylmethylcarbamoyl group, N-dodecylcarbamoyl group , N, N-dodecylmethylcarbamoyl group, N-icosylcarbamoyl group, N, N-icosylmethylcarbamoyl group, N, N-tert-butylmethylcarbamoyl group, N, N-phenylmethylcarbamoyl group, etc. A hydrocarbon group having 1 or 2 carbon atoms (preferably 1 to 10 carbon atoms) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group) such as a group represented by the above formula. , A carbamoyl group substituted with halogen (preferably a chlorine atom), a group derivatized with an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc.;

Trifluoromethyl group, perfluoroethyl group, perfluoropropyl group, perfluoroisopropyl group, perfluorobutyl group, perfluoropentyl group, perfluorohexyl group, perfluoroheptyl group, perfluorooctyl group, perfluorononyl group, Carbonation of 1 to 20 carbon atoms in which all hydrogen atoms such as perfluorodecyl group, perfluoroundecyl group, perfluorododecyl group, perfluoroicosyl group, perfluorocyclohexyl group and perfluorophenyl group are substituted with fluorine atom. Hydrogen group;
Perfluoroethylmethyl group, perfluoropropylmethyl group, perfluoroisopropylmethyl group, perfluorobutylmethyl group, perfluoropentylmethyl group, perfluorohexylmethyl group, perfluoroheptylmethyl group, perfluorooctylmethyl group, perfluoro A linear chain having 1 to 20 carbon atoms in which all hydrogen atoms such as nonylmethyl group, perfluorodecylmethyl group, perfluoroundecylmethyl group, perfluorododecylmethyl group, and perfluoroicosylmethyl group are substituted with fluorine atoms. Alternatively, a hydrocarbon group having 1 to 20 carbon atoms substituted with an alkyl group in the branched chain;

1 to 20 carbon atoms (preferably carbon number) in which a part of hydrogen atoms such as 2-fluorophenyl group, 3-fluorophenyl group, 4-fluorophenyl group and 2,4,6-trifluorophenyl group are replaced with fluorine. 1-10) hydrocarbon groups;

-CO-SH, -CO-S-CH ₃ , -CO-S-CH ₂ CH ₃ , -CO-S-CH ₂ -CH ₂ -CH ₃ , -CO-S-CH ₂ -CH ₂ -CH ₂ carbon atoms -CH _3, etc. 20 (preferably having 1 to 10 carbon atoms) bound to an alkyl group as bonded to a thiocarbonyl _{group, -CO-S-C 6 H} 5 aryl group having 6 to 20 carbon atoms, such as the Thiocarbonyl group;

* -COCO-R as represented by the following formula (in the formula, R is a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms (for example, among the hydrocarbon groups listed above, it satisfies 1 to 20 carbon atoms). , Or its inducing group (eg, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group). Group) (group derived by etc.);

_{* -NRCONR 2} as represented by the following formula (in the formula, R is a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms (for example, among the hydrocarbon groups listed above, those satisfying 1 to 20 carbon atoms). ), Or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), etc. Groups derived from), the Rs of which may be the same or different from each other, or bonded to each other to form a ring);

_{* -OCONR 2} as represented by the following formula (in the formula, R is a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms (for example, among the hydrocarbon groups listed above, those satisfying 1 to 20 carbon atoms). ), Or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), etc. Groups derived from), the Rs of which may be the same or different from each other, or bonded to each other to form a ring);

* -NRCOOR as represented by the following formula (in the formula, R is a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms (for example, among the hydrocarbon groups listed above, those satisfying 1 to 20 carbon atoms)). , Or its inducing group (eg, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group), etc. Derivatized groups), the Rs of which may be the same or different from each other, or bonded to each other to form a ring) groups;

* -OP (O) (OCH ₃ ) ₂ such as * -OP (O) (OR) ₂ (In the formula, R is a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms (for example, the hydrocarbon group listed above). Of these, those satisfying 1 to 20 carbon atoms), or their inducible groups (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms). (Preferably a group derivatized with an octylsulfamoyl group) or the like), and the Rs may be the same or different from each other, or may be bonded to each other to form a ring).
* -Si (CH ₃ ) ₃ , _{* -Si (CH 2} CH ₃ ) ₃ , _{* -Si (C 6} H ₅ ) ₃ and * -Si (CH (CH ₃ ) ₂ ) _3, etc. * -SiR ₃ ( In the formula, R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, one of the above-mentioned hydrocarbon groups satisfying 1 to 20 carbon atoms), or an inducing group thereof (for example, a carboxy group or a sulfo group). A group derived from a group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), etc.), and the R is Groups of (may be the same or different from each other and may be bonded to each other to form a ring);
And so on.

As the divalent substituent, an oxo group, a thioxo group, an imino group, an imino group substituted with an alkyl group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) and an aryl group having 6 to 20 carbon atoms are substituted. Examples include the imino group. _{CH 3-} N is an imino group substituted with an alkyl group.
=, CH ₃ −CH ₂ −N =, CH ₃ − (CH ₂ ) ₂ −N =, CH ₃ − (CH ₂ ) ₃ −N =, and the like. Examples of the imino group substituted with the aryl group include C ₆ H _5- N = and the like.

Preferred examples of the substituent of the hydrocarbon group having 1 to 40 carbon atoms include the substituent of the group s1. The inducible groups shown below are carboxy groups, sulfo groups, nitro groups, hydroxy groups, halogens (preferably chlorine atoms), alkylsulfamoyl groups having 1 to 10 carbon atoms (preferably octylsulfamoyl groups) and the like. It is preferably an derivatized group.
[Group s1]
An oxy group in which a hydrocarbon group having 1 to 20 carbon atoms or an inducible group thereof is bonded to one side;
A carbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
An oxycarbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
Amino group;
An amino group substituted with one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
Sulfamoyl group;
A sulfamoyl group substituted with one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
A carbonylamino group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
Hydroxy group;
Halogen atom;
-CO ₂ M (preferably a carboxy group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom);
-SO ₃ M (preferably a sulfo group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom);
Nitro group;
Cyano group;
A carbonyloxy group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
A sulfonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or an inducible group thereof is bonded;
Carbamic group;
A carbamoyl group substituted with one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
A hydrocarbon group having 1 to 20 carbon atoms in which all hydrogen atoms are replaced by fluorine atoms;
A hydrocarbon group having 1 to 20 carbon atoms in which all of the hydrogen atoms are substituted with fluorine atoms;
A hydrocarbon group having 1 to 20 carbon atoms in which a part of a hydrogen atom is replaced by fluorine;
Oxo group

As the substituent of the hydrocarbon group having 1 to 40 carbon atoms, a substituent of group s2 is more preferable.
[Group s2]
An oxy group in which a hydrocarbon group having 1 to 10 carbon atoms or an inducible group thereof is bonded to one side;
A carbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
An oxycarbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
Amino group;
An amino group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or an inducible group thereof;
Sulfamoyl group;
A sulfamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof;
A carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
Hydroxy group;
Fluorine atom, chlorine atom, bromine atom;
-CO ₂ M (preferably a carboxy group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom);
-SO ₃ M (preferably a sulfo group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom);
Nitro group;
Cyano group;
A carbonyloxy group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
A sulfonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or an inducible group thereof is bonded;
Carbamic group;
A carbamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof;
A hydrocarbon group having 1 to 10 carbon atoms in which all hydrogen atoms are replaced by fluorine atoms;
A hydrocarbon group having 1 to 10 carbon atoms in which all of the hydrogen atoms are substituted with fluorine atoms;
A hydrocarbon group having 1 to 10 carbon atoms in which a part of a hydrogen atom is replaced by fluorine;
Oxo group

As a hydrocarbon group having 1 to 40 carbon atoms having a substituent represented by ^{R 1Z3} , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^{102Z3, monovalent or 2} Hydrocarbon groups having 1 to 40 carbon atoms having a valent substituent can be mentioned, preferably saturated or unsaturated chain hydrocarbon groups having 1 to 30 carbon atoms having a monovalent or divalent substituent and monovalent. Alternatively, a saturated or unsaturated alicyclic hydrocarbon group having 3 to 30 carbon atoms having a divalent substituent and an aromatic hydrocarbon group or hydrocarbon group having 6 to 30 carbon atoms having a monovalent or divalent substituent. A group having 1 to 30 carbon atoms having a monovalent or divalent substituent can be mentioned.
More preferably, a saturated or unsaturated chain hydrocarbon group having 1 to 20 carbon atoms having a substituent in group s1 and a saturated or unsaturated alicyclic hydrocarbon group having 3 to 20 carbon atoms having a substituent in group s1. , A group having a substituent of group s1 and having 6 to 20 carbon atoms or a combination of hydrocarbon groups and a group having a substituent of group s1 and having 1 to 20 carbon atoms.
Particularly preferably, a saturated or unsaturated chain hydrocarbon group having 1 to 15 carbon atoms having a substituent in group s2 and a saturated or unsaturated alicyclic hydrocarbon group having 3 to 15 carbon atoms having a substituent in group s2. , A group having a substituent of group s2 and having 6 to 15 carbon atoms or a combination of hydrocarbon groups and a group having a substituent of group s2 and having 1 to 15 carbon atoms.

The ^{heterocyclic group represented by R 1Z3} , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^102Z3 may be monocyclic or polycyclic. Often, it is preferably a heterocycle containing a heteroatom as a component of the ring. Examples of the hetero atom include a nitrogen atom, an oxygen atom and a sulfur atom.
The number of carbon atoms of the heterocyclic group is preferably 3 to 30, more preferably 3 to 22, still more preferably 3 to 20, even more preferably 3 to 18, and even more preferably 3 to 3. It is 15, particularly preferably 3 to 14.

As a heterocycle containing a nitrogen atom,
Monocyclic saturated heterocycles such as aziridine, azetidine, pyrrolidine, piperidine and piperazine;
Pyrrole such as 2,5-dimethylpyrrole, pyrazole such as 2-methylpyrazole and 3-methylpyrazole, imidazole, 1,2,3-triazole and 5-membered ring-based unsaturated heterocycle such as 1,2,4-triazole ;
Pyrimidines such as pyridine, pyridazine, 6-methylpyrimidine, pyrazines and 6-membered ring unsaturated heterocycles such as 1,3,5-triazine;
Quinoxaline such as indazole, indolin, isoindolin, indole, indoline, benzimidazole, quinoline, isoquinoline, 5,6,7,8-tetrahydro (3-methyl) quinoxaline, 3-methylquinoxaline, quinazoline, cinnoline, phthalazine, diazanaphthalene. , Purine, pteridine, benzopyrazole, benzopiperidine and other fused bicyclic heterocycles;
Condensed tricyclic heterocycles such as carbazole, acridine and phenazine; and the like.

As a heterocycle containing an oxygen atom,
Monocyclic saturated heterocycles such as oxylan, oxetane, tetrahydrofuran, tetrahydropyran, 1,3-dioxane and 1,4-dioxane, 1-cyclopentyl dioxolane;
Bicyclic saturated heterocycles such as 1,4-dioxaspiro [4.5] decane and 1,4-dioxaspiro [4.5] nonane;
Lactone-based heterocycles such as α-acetolactone, β-propiolactone, γ-butyrolactone, γ-valerolactone and δ-valerolactone;
A 5-membered ring-based unsaturated heterocycle such as furan such as 2,3-dimethylfuran and 2,5-dimethylfuran;
6-membered ring-based unsaturated heterocycles such as 2H-pyran and 4H-pyran;
Benzopyrans such as 1-benzofuran and 4-methylbenzopyran, condensed bicyclic heterocycles such as benzodioxol, chroman and isochroman;
Condensed tricyclic heterocycles such as xanthene and dibenzofuran; and the like.

As a heterocycle containing a sulfur atom,
5-membered ring-based saturated heterocycle such as dithiolane;
6-membered ring-based saturated heterocycles such as thiane, 1,3-dithiane, 2-methyl 1,3-dithiane;
5-membered ring-based unsaturated heterocycles such as thiophenes such as 3-methylthiophene and 2-carboxythiophene, 4H-thiopyran, benzothiopyran such as benzotetrahydrothiopyran;
Condensation bicyclic heterocycles such as benzothiophene;
Condensed tricyclic heterocycles such as thianthrene and dibenzothiophene; and the like.

As a heterocycle containing a nitrogen atom and an oxygen atom,
Monocyclic saturated heterocycles such as morpholine, 2-pyrrolidone, 2-methyl-2-pyrrolidone, 2-piperidone and 2-methyl-2-piperidone;
Monocyclic unsaturated heterocycles such as oxazoles such as 4-methyloxazole, 2-methylisoxazoles, and isooxazoles such as 3-methylisoxazole;
Condensed bicyclic heterocycles such as benzoxazole, benzoisoxazole, benzoxazine, benzodioxan, benzoimidazoline;
Condensed tricyclic heterocycles such as phenoxazine; and the like.

As a heterocycle containing a nitrogen atom and a sulfur atom,
Monocyclic heterocycles such as thiazoles such as 3-methylthiazole and 2,4-dimethylthiazole;
Condensation bicyclic heterocycles such as benzothiazole;
Condensation tricyclic heterocycles such as phenothiazine; and the like.

The heterocycle may be a group in which the above-mentioned hydrocarbon groups are combined, and examples thereof include a tetrahydrofurylmethyl group.

Further, the heterocycle may be represented by the following formula.

Further, the heterocyclic group may be a heterocyclic group formed by bonding two or more of ^{R 1Z3 to} R ^5Z3. Such a heterocyclic group has a ring structure of two or more rings together with a benzene ring to which ^{R 1Z3 to} R ^{5Z3 are bonded.} Examples of the ring structure having two or more rings include the structure of the following formula.

The bond position of the above heterocycle is a portion where an arbitrary hydrogen atom contained in each ring is eliminated.

The ^{heterocyclic group represented by R 1Z3} , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^102Z3 may have a substituent. The substituent is the same as the substituent that the hydrocarbon group represented by ^{R 1Z3} , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^{102Z3 may have.} Things can be mentioned. When the heterocycle contains a nitrogen atom as a constituent element thereof, the hydrocarbon group mentioned above may be bonded to the nitrogen atom as a substituent.
Preferred substituents are those represented by the hydrocarbon groups represented by ^{R 1Z3} , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^102Z3. The same as the preferred ones of the group can be mentioned.
The heterocyclic group having a substituent represented by ^{R 1Z3} , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^{102Z3 has a monovalent or divalent substituent.} Heterocyclic groups are mentioned, preferably a heterocyclic group having a substituent of group s1, and more preferably a heterocyclic group having a substituent of group s2.
The above-mentioned hydrocarbon group or heterocyclic group may have one or more substituents (first substituents), and the two or more substituents are independent of each other. It may be the same or different. Further, the first substituent may have another substituent (second substituent) bonded to the hydrocarbon group contained in a part thereof. The second substituent can be selected from the same groups as the first substituent.

Below, R ^1Z3 , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , and R ^7Z3 -CO-R ^102Z3 , -COO-R ^101Z3 , -OCO-R ^102Z3 , -COCO-R ^102Z3 , -O -R ^102Z3 , -SO ₂ -R ^101Z3 , -SO ₂ N (R ^102Z3 ) ₂ ^{, -CON} (R 102Z3) ₂ , -N (R ^102Z3 ) ₂ , -NHCO-R ^102Z3 , -NHCO-N (R ^102Z3) ) ₂ , -NHCOOR ^102Z3 , -OCON (R ^102Z3 ) ₂ , halogen atom, -SO ₃ M, -CO ₂ M will be described.
-CO-R ^102Z3 includes formyl group; acetyl group, propanoyl group, butanoyl group, 2,2-dimethylpropanoyl group, pentanoyl group, hexanoyl group, (2-ethyl) hexanoyl group, heptanoil group, octanoyl group, nonanoyl. Derivation of a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group, a decanoyl group, an undecanoyl group, a dodecanoyl group, a henicosanoyl group, a benzoyl group, etc., and a group represented by the above formula. It was derivatized with a chemical group (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), or the like. A group corresponding to -CO-R 102Z3 in the carbonyl group to which the group) is bonded (when the carbonyl group is an acyl group, the number of carbon atoms is 2 to 41) and the compounds shown in Tables 1Z3 to 6Z3, and a ^{special application.} In the compounds shown in Tables 1 to 966 of No. ^2017-016290 , a group corresponding to −CO-R 102Z3 and the like can be mentioned, preferably a hydrocarbon group having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms) or a hydrocarbon group. In the carbonyl group to which the derivatizing group is attached (when the carbonyl group is an alkanoyl group, the number of carbon atoms is more preferably 2 to 12), and in the compounds shown in Tables 1Z3 to 6Z3, -CO-R ^102Z3 Applicable groups and the like can be mentioned.

-COO-R ^101Z3 includes methoxycarbonyl group, ethoxycarbonyl group, propoxycarbonyl group, tert-butoxycarbonyl group, butoxycarbonyl group, pentyloxycarbonyl group, hexyloxycarbonyl group, (2-ethyl) hexyloxycarbonyl group, Heptyloxycarbonyl group, octyloxycarbonyl group, nonyloxycarbonyl group, decyloxycarbonyl group, undecyloxycarbonyl group, dodecyloxycarbonyl group, phenyloxycarbonyl group, icosyloxycarbonyl group, etc., and represented by the above formula. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or an inducing group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon In the oxycarbonyl group to which an alkylsulfamoyl group (preferably a group derivatized with an octylsulfamoyl group) of numbers 1 to 10 (preferably a group derivatized by an octylsulfamoyl group) or the like is bonded, and in the compounds shown in Tables 1Z3 to 6Z3, -COO-R ^102Z3 Examples of the relevant group and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. ^2017-016290 include the group corresponding to -COO-R 102Z3, and preferably a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof. Examples thereof include an oxycarbonyl group to which is bonded and a group corresponding to ^{-COO-R 102Z3 in the compounds shown in Tables 1Z3 to 6Z3.}

-OCO-R ^102Z3 includes formyloxy group; acetoxy group, propanoyloxy group, butanoyloxy group, 2,2-dimethylpropanoyloxy group, pentanoyloxy group, hexanoyloxy group, (2-ethyl). Hexanoyloxy group, heptanoiloxy group, octanoyloxy group, nonanoyloxy group, decanoyloxy group, undecanoyloxy group, dodecanoyloxy group, henikosanoyloxy group, benzoyloxy group, etc., and the above formula. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or an inducible group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, or a halogen (preferably a chlorine atom). ), A carbonyloxy group to which an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably a group derived from an octylsulfamoyl group) or the like is bonded (when the carbonyloxy group is an acyloxy group, the number of carbon atoms is 2 to 41), and in the compounds shown in Tables 1Z3 to ^6Z3 , the group corresponding to -OCO-R 102Z3 and in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290- ^{OCO-R 102Z3.} Examples of the group corresponding to the above, preferably a hydrocarbon group having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms) or a carbonyloxy group to which an inducible group thereof is bonded (the carbonyloxy group is referred to as an acyloxy group). In this case, the number of carbon atoms is more preferably 2 to 12), and in the compounds shown in Tables 1Z3 to ^6Z3 , groups corresponding to -OCO-R 102Z3 and the like can be mentioned.

-COCO-R ^102Z3 includes methyloxalyl group, ethyloxalyl group, propyloxalyl group, butyloxalyl group, pentyloxalyl group, hexyloxalyl group, (2-ethyl) hexyloxalyl group, heptyloxalyl group, octyloxalyl group and nonyl. Oxalyl group, decyl oxalyl group, undecyl oxalyl group, dodecyl oxalyl group, icosyl oxalyl group, cyclopentyl oxalyl group, cyclohexyl oxalyl group, phenyl oxalyl group, p-tolyl oxalyl group and the like, and groups represented by the above formulas and the like. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), 1 to 1 carbon atoms. Oxalyl groups to which 10 alkylsulfamoyl groups (preferably groups derivatized with octylsulfamoyl groups) and the like are bonded, and groups corresponding to ^{-COCO-R 102Z3 in the compounds shown in Tables 1Z3 to 6Z3 and} Examples of the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290 include groups corresponding to ^{-COCO-R 102Z3.}

-O-R ^102Z3 includes hydroxy groups; methoxy group, ethoxy group, propoxy group, isopropoxy group, butoxy group, isobutoxy group, sec-butoxy group, tert-butoxy group, pentyloxy group, hexyloxy group, heptyloxy. Group, octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, dodecyloxy group, (2-ethyl) hexyloxy group, icosyloxy group, 1-phenylethoxy group, 1-methyl-1-phenylethoxy group, phenyl Oxy group, 2,3-dimethylphenyloxy group, 2,4-dimethylphenyloxy group, 2,5-dimethylphenyloxy group, 2,6-dimethylphenyloxy group, 3,4-dimethylphenyloxy group, 3, 5-Dimethylphenyloxy group, 2,2-dicyanophenyloxy group, 2,3-dicyanophenyloxy group, 2,4-dicyanophenyloxy group, 2,5-dicyanophenyloxy group, 2,6-dicyanophenyloxy Group, 3,4-dicyanophenyloxy group, 3,5-dicyanophenyloxy group, 4-methoxyphenyloxy group, 2-methoxyphenyloxy group, 3-methoxyphenyloxy group, 4-ethoxyphenyloxy group, 2- A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as an ethoxyphenyloxy group, a 3-ethoxyphenyloxy group, etc., and a group represented by the above formula, or an inducing group thereof (for example, carboxy). A group derived from a group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), or the like is bonded. group corresponding to the -O-R ^102Z3 in group and compounds shown in Table 1Z3~ Table 6Z3 -O-R ^102Z3 Table 1-966 of the relevant group and Japanese Patent Application No. 2017-016290 to the compounds shown in the Examples thereof include an oxy group to which a hydrocarbon group having 1 to 10 carbon atoms or an inducible group thereof is bonded, and a group corresponding to ^{-OR 102Z3 in the compounds shown in Tables 1Z3 to 6Z3.}

-SO _2- R ^101Z3 includes methyl sulfonyl group, ethyl sulfonyl group, propyl sulfonyl group, butyl sulfonyl group, pentyl sulfonyl group, hexyl sulfonyl group, (2-ethyl) hexyl sulfonyl group, heptyl sulfonyl group, octyl sulfonyl group, Nonylsulfonyl group, decylsulfonyl group, undecylsulfonyl group, dodecylsulfonyl group, icosylsulfonyl group, phenylsulfonyl group, p-tolylsulfonyl group, etc., and groups represented by the above formula, etc. have 1 to 40 carbon atoms (1 to 40 carbon atoms). A hydrocarbon group having 1 to 20 carbon atoms or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms). Sulfonyl groups to which (preferably octylsulfamoyl groups) and the like (preferably octylsulfamoyl groups) and the compounds shown in Tables 1Z3 to ^6Z3 _{correspond to -SO 2-} R 102Z3 and Japanese Patent Application No. 2017-016290. -SO ₂ in the compounds shown in Table 1~966 -R ^102Z3 relevant group and the like in, preferably a sulfonyl group and tables 1Z3~ bonded hydrocarbon radical or a derivatized group having 1 to 10 carbon atoms group corresponding to -SO ₂ -R ^102Z3 in the compounds shown in Table 6Z3 like.

-SO ₂ N (R ^102Z3 ) ₂ is a sulfamoyl group;
N-methylsulfamoyl group, N-ethylsulfamoyl group, N-propylsulfamoyl group, N-isopropylsulfamoyl group, N-butylsulfamoyl group, N-isobutylsulfamoyl group, N- sec-butyl sulfamoyl group, N-tert-butyl sulfamoyl group, N-pentyl sulfamoyl group, N- (1-ethylpropyl) sulfamoyl group, N-hexyl sulfamoyl group, N- (2-) Ethyl) Hexyl sulfamoyl group, N-heptyl sulfamoyl group, N-octyl sulfamoyl group, N-nonyl sulfamoyl group, N-decyl sulfamoyl group, N-undecyl sulfamoyl group, N- One carbon number 1 to 40 (preferably 1 to 20) of one group such as dodecylsulfamoyl group, N-icosylsulfamoyl group, N-phenylsulfamoyl group, and a group represented by the above formula. (For example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably octyl sulfamoyl group). ^{_{) -SO 2 NH (R 102Z3X)}} ( provided that the sulfamoyl group and tables 1Z3~ Table 6Z3 compounds shown in substituted with derivatized groups) in such, except that R ^102Z3X is not a hydrogen atom, R ^102Z3 -SO ₂ NH (R ^102Z3X) (provided that the compounds shown in Table 1 to 966 of the corresponding group and Japanese Patent Application No. 2017-016290 the same as is) and, except that R ^102Z3X is not a hydrogen atom, R ^102Z3 The group corresponding to the group corresponding to);

N, N-dimethylsulfamoyl group, N, N-ethylmethylsulfamoyl group, N, N-diethylsulfamoyl group, N, N-propylmethylsulfamoyl group, N, N-dipropylsulfamoyl Group, N, N-isopropylmethylsulfamoyl group, N, N-diisopropylsulfamoyl group, N, N-tert-butylmethylsulfamoyl group, N, N-diisobutylsulfamoyl group, N, N- Disec-butyl sulfamoyl group, N, N-ditert-butyl sulfamoyl group, N, N-butylmethyl sulfamoyl group, N, N-dibutyl sulfamoyl group, N, N-dipentyl sulfa Moyl group, N, N-di (1-ethylpropyl) sulfamoyl group, N, N-dihexyl sulfamoyl group, N, N-di (2-ethyl) hexyl sulfamoyl group, N, N-diheptylsul Famoyl group, N, N-octylmethylsulfamoyl group, N, N-dioctylsulfamoyl group, N, N-dinonyl sulfamoyl group, N, N-decylmethylsulfamoyl group, N, N- Undecylmethyl sulfamoyl group, N, N-dodecylmethyl sulfamoyl group, N, N-icosylmethyl sulfamoyl group, N, N-phenylmethyl sulfamoyl group, N, N-diphenyl sulfamoyl Two hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group and a group represented by the above formula or a derivatizing group thereof (for example, a carboxy group, a sulfo group, a nitro group, etc. Sulfamoyl groups substituted with hydroxy groups, halogens (preferably chlorine atoms), alkylsulfamoyl groups having 1 to 10 carbon atoms (preferably octylsulfamoyl groups) and the like, and sulfamoyl groups and Tables 1Z3 to Tables 1Z3. In the compound shown in 6Z3, the group corresponding to -SO ₂ N (R ^102Z3X ) ₂ (however, R ^{102Z3X is the same as R 102Z3} except that it does not become a hydrogen atom) and Table 1 of Japanese Patent Application No. 2017-016290. Among the compounds shown in ~ 966, groups corresponding to −SO ₂ N (R ^102Z3X ) ₂ (however, R ^{102Z3X is the same as R 102Z3} except that it does not become a hydrogen atom) can be mentioned.
Preferably, it corresponds to _{-SO 2} N (R 102Z3) ₂ in the sulfamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or an inducible group thereof and the compounds shown in Tables 1Z3 to ^6Z3. The group etc. can be mentioned.

^-CON (R 102Z3) ₂ is a carbamoyl group;
N-methylcarbamoyl group, N-ethylcarbamoyl group, N-propylcarbamoyl group, N-isopropylcarbamoyl group, N-butylcarbamoyl group, N-isobutylcarbamoyl group, N-sec-butylcarbamoyl group, N-tert-butylcarbamoyl group. Group, N-pentylcarbamoyl group, N- (1-ethylpropyl) carbamoyl group, N-hexylcarbamoyl group, N- (2-ethyl) hexylcarbamoyl group, N-heptylcarbamoyl group, N-octylcarbamoyl group, N- One of nonylcarbamoyl group, N-decylcarbamoyl group, N-undecylcarbamoyl group, N-dodecylcarbamoyl group, N-icosylcarbamoyl group, N-phenylcarbamoyl group and the like, and a group represented by the above formula. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), and 1 to 10 carbon atoms. -CONH (R ^102Z3X ) (where R ^{102Z3X is the same as R 102Z3} except that it does not become a hydrogen atom), and in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290, -CONH (R ^102Z3X ) (however, R ^102Z3X is It is the same as ^{R 102 Z3} except that it does not become a hydrogen atom).

N, N-dimethylcarbamoyl group, N, N-ethylmethylcarbamoyl group, N, N-diethylcarbamoyl group, N, N-propylmethylcarbamoyl group, N, N-dipropylcarbamoyl group, N, N-isopropylmethylcarbamoyl Group, N, N-diisopropylcarbamoyl group, N, N-tert-butylmethylcarbamoyl group, N, N-diisobutylcarbamoyl group, N, N-disec-butylcarbamoyl group, N, N-ditert-butylcarbamoyl group , N, N-butylmethylcarbamoyl group, N, N-dibutylcarbamoyl group, N, N-butyloctylcarbamoyl group, N, N-dipentylcarbamoyl group, N, N-di (1-ethylpropyl) carbamoyl group, N , N-dihexylcarbamoyl group, N, N-di (2-ethyl) hexylcarbamoyl group, N, N-diheptylcarbamoyl group, N, N-octylmethylcarbamoyl group, N, N-dioctylcarbamoyl group, N, N -Dinonylcarbamoyl group, N, N-decylmethylcarbamoyl group, N, N-undecylmethylcarbamoyl group, N, N-dodecylmethylcarbamoyl group, N, N-icosylmethylcarbamoyl group, N, N-phenylmethyl Two hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a carbamoyl group, an N, N-diphenylcarbamoyl group, etc., and a group represented by the above formula, or an inducing group thereof (for example, 1 to 20 carbon atoms). Substituted with a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably a group derived with an octyl sulfamoyl group), or the like). ^{Carbamoyl groups and the compounds corresponding to -CON} (R 102Z3X) ₂ (however, R ^102Z3X is the same as R 102Z3 except that it does not become a hydrogen atom) in the compounds shown in Tables 1Z3 to ^{6Z3, and the special application.} In the compounds shown in Tables 1 to 966 of No. 2017-016290, ^{groups corresponding to −CON} (R 102Z3X) ₂ (however, R ^{102Z3X is the same as R 102Z3} except that it does not become a hydrogen atom) can be mentioned. ,
Preferably, a carbamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or an inducible group thereof, and a group corresponding to ^-CON (R 102Z3) _{2 in the compounds shown in Tables 1Z3 to 6Z3 and the like.} Can be mentioned.

−N (R ^102Z3 ) ₂ is an amino group;
N-methylamino group, N-ethylamino group, N-propylamino group, N-isopropylamino group, N-butylamino group, N-isobutylamino group, N-sec-butylamino group, N-tert-butylamino Group, N-pentylamino group, N-hexylamino group, N- (2-ethyl) hexylamino group, N-heptylamino group, N-octylamino group, N-nonylamino group, N-decylamino group, N-un A decylamino group, an N-dodecylamino group, an N-icosylamino group, an N-phenylamino group, etc., and a group represented by the above formula, etc., which have 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms). A hydrocarbon group or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group)). ^{-NH (R 102Z3X} ) (however, R ^102Z3X is the same as ^{R 102Z3} except that it does not become a hydrogen atom in the amino groups substituted with (groups induced by etc.) and the compounds shown in Tables 1Z3 to 6Z3. ^{-NH (R 102Z3X} ) in the groups corresponding to (there is) and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290 (however, R ^102Z3X is the same as ^{R 102Z3} except that it does not become a hydrogen atom). Group corresponding to;

N, N-dimethylamino group, N, N-ethylmethylamino group, N, N-diethylamino group, N, N-propylmethylamino group, N, N-dipropylamino group, N, N-isopropylmethylamino group , N, N-diisopropylamino group, N, N-tert-butylmethylamino group, N, N-diisobutylamino group, N, N-disec-butylamino group, N, N-ditert-butylamino group, N, N-butylmethylamino group, N, N-dibutylamino group, N, N-dipentylamino group, N, N-di (1-ethylpropyl) amino group, N, N-dihexylamino group, N, N -Di (2-ethyl) hexylamino group, N, N-diheptylamino group, N, N-dioctylamino group, N, N-dinonylamino group, N, N-decylmethylamino group, N, N-undecyl Methylamino group, N, N-dodecylmethylamino group, N, N-icosylmethylamino group, N, N-phenylmethylamino group, N, N-diphenylamino group, etc., and groups represented by the above formulas. 2 hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or derivatizing groups thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon ^{-N (R 102Z3X} ) in the amino group substituted with an alkyl sulfamoyl group (preferably a group derivatized by an octyl sulfamoyl group) of the number 1 to 10 and the compounds shown in Tables 1Z3 to 6Z3. ^{-N (R 102Z3X} ) _{2 in the groups corresponding to 2} (however, R ^{102Z3X is the same as R 102Z3} except that it does not become a hydrogen atom) and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290. (However, R ^102Z3X is the same as ^{R 102Z3} except that it does not become a hydrogen atom.)
Preferably, an amino group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or an inducible group thereof, and a group corresponding to ^{-N (R 102Z3} ) _{2 in the compounds shown in Tables 1Z3 to 6Z3 and the like.} Can be mentioned.

-NHCO-R ^102Z3 includes formylamino groups; acetylamino groups, propanoylamino groups, butanoylamino groups, 2,2-dimethylpropanoylamino groups, pentanoylamino groups, hexanoylamino groups, (2-ethyl). ) Hexanoylamino group, Heptanoylamino group, Octanoylamino group, Nonanoylamino group, Decanoylamino group, Undecanoylamino group, Dodecanoylamino group, Henikosanoylamino group, Bencoylamino group, etc. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group represented by the above formula or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, or a halogen (preferably). Is a chlorine atom), a carbonylamino group (a group derivatized with an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc.) is bonded (when the carbonylamino group is an acylamino group). , The number of carbon atoms is 1 to 40), and in the compounds shown in Tables 1Z3 to ^6Z3 , the group corresponding to -NHCO-R 102Z3 and in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290-NHCO- The groups corresponding to ^{R 102Z3 are listed.}
Preferably, a carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or an inducible group thereof is bonded (when the carbonylamino group is an alkanoylamino group, the carbon number is more preferably 1 to 10) and Table 1Z3. In the compounds shown in Table 6Z3, ^{groups corresponding to -NHCO-R 102Z3} and the like can be mentioned.

-NHCON (R ^102Z3 ) ₂ ^{includes the groups listed above and the groups corresponding to -NHCON (R 102Z3} ) ₂ in the compounds shown in Tables 1Z3 to 6Z3, Tables 1 to 966 of Japanese Patent Application No. 2017-016290. Examples of the compounds shown in (1) include groups corresponding to ^{−NHCON (R 102Z3} _{) 2.}

-NHCOOR ^{102Z3 includes the groups listed above, the groups corresponding to -NHCOOR 102Z3} in the compounds shown in Tables 1Z3 to 6Z3, and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. ^2017-016290. Examples of the group corresponding to.

-OCON (R ^102Z3 ) ₂ ^{includes the groups listed above and the groups corresponding to -OCON (R 102Z3} ) ₂ in the compounds shown in Tables 1Z3 to 6Z3, and Tables 1 to 966 of Japanese Patent Application No. 2017-016290. ^{Examples of the} compounds shown in (1) include groups corresponding to _{−OCON (R 102Z3) 2.}

As the halogen atom, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom and the like are preferable.
Examples of _{M of −SO 3} M and −CO ₂ M include hydrogen atom; alkali metal atom such as lithium atom, sodium atom and potassium atom, and preferably hydrogen atom, sodium atom and potassium atom.

-CO-R ^102Z3 , -COO-R ^102Z3 , -OCO-R ^102Z3 , -COCO-R ^102Z3 , -O-R ^102Z3 , -SO _2- R ^102Z3 , -SO ₂ N (R ^102Z3 ) ₂ , -CON Substituents (first substituents) contained in (R ^102Z3 ) ₂ , -N (R ^102Z3 ) ₂ , -NHCO-R ^102Z3 , -NHCON (R ^102Z3 ) ₂ , -NHCOOR ^102Z3 , -OCON (R ^102Z3 ) _2. May be one or more, and the two or more substituents may be the same or different independently of each other.
Further, the first substituent may have another substituent (second substituent) bonded to the hydrocarbon group contained in a part thereof. The second substituent can be selected from the same groups as the first substituent.

The ^{rings formed by R 2Z3} and R ^3Z3 , R ^3Z3 and R ^4Z3 , and R ^4Z3 and R ^5Z3 are condensed with the benzene ring of the isoindoline skeleton of the compound represented by the formula (IZ3). The fused ring structures of the ring formed by R ^2Z3 and R ^3Z3 , R ^3Z3 and R ^4Z3 , and R ^4Z3 and R ^5Z3 and the benzene ring include inden, naphthalene, biphenylene, indacene, ashenanthrene, fluorene, phenanthrene, and phenanthrene. Hydrocyclic condensed ring structures such as anthracene, fluorantene, acephenanthrene, aceanthrene, triphenylene, pyrene, chrysene, N-methylphthalimide, N- (1-phenylethyl) phthalimide and tetracene, and their partial reductions ( For example, 9,10-dihydroanthracene, 1,2,3,4-tetrahydronaphthalene); indol, isoindole, indazole, quinoline, isoquinoline, phthalazine, quinoxaline, quinazoline, cinnoline, carbazole, carboline, phenanthrene, aclysine. , Perimidine, phenanthrene, phenazine and the like, nitrogen-containing fused heterocycles and their partial reductions; oxygen-containing condensed heterocycles such as 3-hydrobenzofuran 2-one and their partial reductions.

When R ^2Z3 and R ^3Z3 , R ^3Z3 and R ^4Z3 , and R ^4Z3 and R ^5Z3 form a ring, the ring may have a substituent. The substituent is the same as the substituent that the hydrocarbon group represented by ^{R 1Z3} , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^{102Z3 may have.} Things can be mentioned. Preferred substituents are those represented by the hydrocarbon groups represented by ^{R 1Z3} , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^102Z3. The same as the preferred ones of the group can be mentioned.

When R ^{3Z 3} and R 4 ^{Z 3} form a ring, ^{it is preferable that R 2Z 3} and R 5 ^{Z 3} are hydrogen atoms, amino groups and hydroxy groups independently of each other.
If R ^2Z3 and R ^3Z3 form a ring, it is preferable that the R ^4Z3 and R ^5Z3 do not form a ring, and more preferably R ^4Z3 and R ^5Z3 is a hydrogen atom.
In the case where R ^4Z3 and R ^5Z3 form a ring, it is preferable that the R ^2Z3 and R ^3Z3 do not form a ring, and more preferably R ^2Z3 and R ^3Z3 is a hydrogen atom.

In the present invention, R ^1Z3 , R ^6Z3 and R ^7Z3 are preferably hydrogen atoms.

^{At least one of R 2Z3} , R ^3Z3 , R ^4Z3 , and R ^5Z3 is -CO-R ^102Z3 , -COO-R ^101Z3 , -from the viewpoint of reducing the phase difference value of the color filter prepared from the coloring composition. OCO-R ^102Z3 , -COCO-R ^102Z3 , -O-R ^102Z3 , -SO _2- R ^101Z3 , -SO ₂ N (R ^102Z3 ) ₂ ^{, -CON} (R 102Z3) ₂ , -N (R ^102Z3 ) ₂ , -NHCO-R ^102Z3 , -NHCO-N (R ^102Z3 ) ₂ , -NHCOOR ^102Z3 , -OCON (R ^102Z3 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, substituent It is preferably a hydrocarbon group having 1 to 40 carbon atoms or a heterocyclic group which may have a substituent.
A hydrocarbon group having 1 to 40 carbon atoms, which may have a substituent, a halogen atom, -N (R ^102Z3 ) ₂ , a nitro group, and a hydrogen atom in which all or a part of the hydrocarbon atom is substituted with a fluorine atom has 1 to 1 carbon atoms. 20 hydrocarbon groups, -NHCO-R ^102Z3 , ^{-OR 102Z3} , -SO ₃ M or -CO ₂ M are more preferred.
It is more preferably a hydrocarbon group having 1 to 40 carbon atoms which may have a nitro group or a substituent, and even more preferably a nitro group or a tert-butyl group. Alternatively, at least one set of ^{R 2Z 3} and R ^{3Z 3} , R ^{3Z 3} and R ^{4Z 3} , or R ^{4Z 3} and R 5 ^{Z 3 preferably forms a ring.}

At least one of ^{R 2Z3} , R ^3Z3 , R ^4Z3 , and R ^5Z3 of the compound (IZ3) is ^{-CO-R 102Z3} , -COO-R ^101Z3 , -OCO-R ^102Z3 , -COCO-R ^102Z3 , -O- R ^102Z3 , -SO ₂ -R ^101Z3 , -SO ₂ N (R ^102Z3 ) ₂ ^{, -CON} (R 102Z3) ₂ , -N (R ^102Z3 ) ₂ , -NHCO-R ^102Z3 , -NHCO-N (R ^102Z3 ) ₂ , -NHCOOR ^102Z3 , -OCON (R ^102Z3 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, hydrocarbon having 1 to 40 carbon atoms which may have a substituent. It is a heterocyclic group which may have a group or a substituent, or ^{at least one set of R 2Z3} and R ^3Z3 , R ^3Z3 and R ^4Z3 , and R ^4Z3 and R ^5Z3 are bonded to form a ring. The compound is preferable (hereinafter, the compound may be referred to as "compound (IZ3-B)"). When the compound (IZ3) is the compound (IZ3-B), the phase difference value of the color filter produced from the coloring composition becomes small.

［式（ＩＺ３−Ｂ）中、
Ｒ^1Z3、Ｒ^21Z3、Ｒ^31Z3、Ｒ^41Z3、Ｒ^51Z3、Ｒ^61Z3、及びＲ^71Z3は、互いに独立に、水素原子、−ＣＯ−Ｒ^102Z3、−ＣＯＯ−Ｒ^101Z3、−ＯＣＯ−Ｒ^102Z3、−ＣＯＣＯ−Ｒ^102Z3、−Ｏ−Ｒ^102Z3、−ＳＯ₂−Ｒ^101Z3、−ＳＯ₂Ｎ（Ｒ^102Z3）₂、−ＣＯＮ（Ｒ^102Z3）₂、−Ｎ（Ｒ^102Z3）₂、−ＮＨＣＯ−Ｒ^102Z3、−ＮＨＣＯ−Ｎ（Ｒ^102Z3）₂、−ＮＨＣＯＯＲ^102Z3、−ＯＣＯＮ（Ｒ^102Z3）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^21Z3とＲ^31Z3、Ｒ^31Z3とＲ^41Z3、及びＲ^41Z3とＲ^51Z3は、それぞれ互いに結合して環を形成してもよい。
ただし、Ｒ^21Z3、Ｒ^31Z3、Ｒ^41Z3、及びＲ^51Z3の少なくとも一つは、−ＣＯ−Ｒ^102Z3、−ＣＯＯ−Ｒ^101Z3、−ＯＣＯ−Ｒ^102Z3、−ＣＯＣＯ−Ｒ^102Z3、−Ｏ−Ｒ^102Z3、−ＳＯ₂−Ｒ^101Z3、−ＳＯ₂Ｎ（Ｒ^102Z3）₂、−ＣＯＮ（Ｒ^102Z3）₂、−Ｎ（Ｒ^102Z3）₂、−ＮＨＣＯ−Ｒ^102Z3、−ＮＨＣＯ−Ｎ（Ｒ^102Z3）₂、−ＮＨＣＯＯＲ^102Z3、−ＯＣＯＮ（Ｒ^102Z3）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基或いは置換基を有していてもよい複素環基であるか、又はＲ^21Z3とＲ^31Z3、Ｒ^31Z3とＲ^41Z3、及びＲ^41Z3とＲ^51Z3の少なくとも一組が結合して環を形成している。
Ｒ^101Z3は、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102Z3は、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、水素原子又はアルカリ金属原子を表す。
Ｒ^101Z3、Ｒ^102Z3及びＭが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
波線は、Ｅ体又はＺ体を表す。］ The compound (IZ3-B) is defined by the formula as follows.

[In the formula (IZ3-B),
R ^1Z3 , R ^21Z3 , R ^31Z3 , R ^41Z3 , R ^51Z3 , R ^61Z3 , and R ^71Z3 are independent of each other, hydrogen atom, -CO-R ^102Z3 , -COO-R ^101Z3 , -OCO-R ^102Z3 , -COCO. -R ^102Z3 , -O-R ^102Z3 , -SO ₂ -R ^101Z3 , -SO ₂ N (R ^102Z3 ) ₂ ^{, -CON} (R 102Z3) ₂ , -N (R ^102Z3 ) ₂ , -NHCO-R ^102Z3 ,- NHCO-N (R ^102Z3 ) ₂ , -NHCOOR ^102Z3 , -OCON (R ^102Z3 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, carbon which may have a substituent Represents a heterocyclic group which may have a hydrocarbon group or a substituent of the number 1 to 40.
R ^21Z3 and R ^31Z3 , R ^31Z3 and R ^41Z3 , and R ^41Z3 and R ^51Z3 may be combined with each other to form a ring, respectively.
However, at least one of ^{R 21Z3} , R ^31Z3 , R ^41Z3 , and R ^{51Z3 is -CO-R 102Z3} , -COO-R ^101Z3 , -OCO-R ^102Z3 , -COCO-R ^102Z3 , -O-R ^102Z3 , −SO ₂ −R ^101Z3 , −SO ₂ N (R ^102Z3 ) ₂ ^{, −CON} (R 102Z3) ₂ , −N (R ^102Z3 ) ₂ , −NHCO-R ^102Z3 , −NHCO-N (R ^102Z3 ) ₂ , − NHCOOR ^102Z3 , -OCON (R ^102Z3 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, hydrocarbon group or substitution having 1 to 40 carbon atoms which may have a substituent. It is a heterocyclic group which may have a group, or ^{at least one set of R 21Z3} and R ^31Z3 , R ^31Z3 and R ^41Z3 , and R ^41Z3 and R ^51Z3 are bonded to form a ring.
R ^101Z3 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102Z3 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
M represents a hydrogen atom or an alkali metal atom.
When a ^{plurality of R 101Z3} , R ^102Z3 and M are present, they may be the same or different.
The wavy line represents an E-form or a Z-form. ]

In formula (IZ3-B), R ^21Z3 , R ^31Z3 , R ^41Z3 , R ^51Z3 , R ^61Z3 , and R ^{71Z3 are R 2Z3} , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^{6Z3 in} formula (IZ3), respectively. , And the same as ^{R 7Z3.}

In the formula (IZ3-B), the preferred R ^21Z3 , R ^31Z3 , R ^41Z3 , R ^51Z3 , R ^61Z3 , and R ^{71Z3 are R 2Z3} , R ^3Z3 , R ^4Z3 , R ^5Z3 , R in the formula (IZ3), respectively. ^The same as the preferred ones of ^6Z3 and R7Z3 can be mentioned.

In the formula (IZ3-B), ^{it is preferable that (Aspect 1) R 1Z3} , R ^61Z3 and R ^71Z3 are hydrogen atoms. (Aspect 2) At ^{least one of R 21Z3} , R ^31Z3 , R ^41Z3 , and R ^51Z3 is preferably a nitro group or a tert-butyl group. One of aspects 1 and 2 may be adopted, or both may be adopted.

From the viewpoint of reducing the phase difference value of the color filter prepared from the coloring composition ^{, at least one of R 2Z3} , R ^3Z3 , R ^4Z3 , and R ^5Z3 may have a substituent and has 1 to 40 carbon atoms. Hydrocarbon group, halogen atom, -N (R ^102Z3 ) ₂ , nitro group, hydrocarbon group with 1 to 20 carbon atoms in which all or part of the hydrogen atom is replaced by a fluorine atom, -NHCO-R ^102Z3 , -O It is preferably −R ^102Z3 , −SO ₃ M or −CO ₂ M, more preferably a hydrocarbon group having 1 to 40 carbon atoms which may have a nitro group or a substituent, and more preferably a nitro group or a hydrocarbon group. It is more preferably a tert-butyl group. Particularly preferably, R ^3Z3 is a nitro group or a tert-butyl group and R ^2Z3 , R ^4Z3 and R ^5Z3 are hydrogen atoms, or R ^2Z3 , R ^3Z3 and R ^5Z3 are hydrogen atoms and R ^4Z3. Is a nitro group or a tert-butyl group.

Specific examples of the compound (IZ3) include, for example, a compound (IZ3-1) having a substituent shown in Table 1Z3, Table 2Z3, Table 3Z3, Table 4Z3, Table 5Z3, and Table 6Z3 in the formula (IZ3-aa). ~ Compound (IZ3-212) or an alkali metal salt thereof can be mentioned.
B ^a1Z3 B ^a2Z3 is a formula (BB1) to a formula (BB60), a formula (BBK2), a formula (BBK3), a formula (BBK4), a formula (BBK14), a formula (BBI1), a formula (BBO8), a formula (BBO10). , Represents any of the partial structures represented by the formula (BBD1) and the formula (BBJ2). Formulas (BB1) to formulas (BB60), formulas (BBK2), formulas (BBK3), formulas (BBK4), formulas (BBK14), formulas (BBI1), formulas (BBO8), formulas (BBO10), formulas (BBD1) and ^{The formula (BBJ2) represents B a1Z1} B ^a2Z1 of the formula (IZ1-aa) (BB1) to (BB60), the formula (BBK2), the formula (BBK3), the formula (BBK4), the formula (BBK14), the formula (BBI1). ), Equation (BBO8), Equation (BBO10), Equation (BBD1) and Equation (BBJ2). B ^a1Z3 and B ^a2Z3 represent a bond, respectively, and B ^a1Z3 is a formula (BB1) to a formula (BB60), a formula (BBK2), a formula (BBK3), a formula (BBK4), a formula (BBK14), a formula (BBI1). , formula (BBO8), formula (BBO10), formula (BBD1) and becomes a bond B ^A2Z3 is B ² when a bond of B ¹ of formula ^(BBJ2), B a1Z3 the expression (BB1) ~ formula (BB60 ), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1), formula (BBO8), formula (BBO10), formula (BBD1) and formula B ² of (BBJ2) When it is a bond, ^{B a2 Z3} is ^{a bond of B 1.}
B ^a1Z3 B ^a2Z3 includes the formula (BB1), the formula (BB6), the formula (BB8), the formula (BB11), the formula (BB14), the formula (BB19), the formula (BB37), the formula (BB58), and the formula (BBJ2). ), Formula (BBO8) and formula (BBO10) are preferable, and formula (BB1), formula (BB6) and formula (BB19) are more preferable.

Each symbol in Table 1Z3, Table 2Z3, Table 3Z3, Table 4Z3, Table 5Z3, and Table 6Z3 represents the following substructure. In addition, in the partial structure
"Me" represents a methyl group
"Et" represents an ethyl group
"Bu" represents a butyl group
"TBu" represents a tert-butyl group and represents
"Hex" represents a hexyl group
"Oct" represents an octyl group
"2EH" represents a 2-ethylhexyl group and represents
"CHM" represents a cyclohexylmethyl group
"CH" represents a cyclohexyl group
"PH" represents a phenyl group
"BZ" represents a benzyl group
"NPR" represents a propyl group
"IPR" represents an isopropyl group
"IBu" represents an isobutyl group and represents
"EOE" stands for −CH ₂ CH ₂ OCH ₂ CH ₃
"ALL" represents an allyl group
"HYE" represents a 2-hydroxyethyl group
"COM" stands for -CO-CH ₃
"COE" stands for -COO-CH ₂ CH ₃
"OCM" stands for -OCO-CH ₃
"OME" stands for -O-CH ₃ and represents
"SOT" represents a tosyl group
“SNH” stands for −SO ₂ NH-CH ₂ CH (CH ₂ CH ₃ ) ((CH ₂ ) ₃ CH ₃ ).
“SN2” stands for −SO ₂ N (CH ₃ ) ((CH ₂ ) ₇ CH ₃ ).
"CNM" stands for -CONHCH ₃
"CN2" stands for -CON (CH ₃ ) C ₆ H ₅ and represents
"NPH" stands for -NHC ₆ H ₅ and represents
"NOT" stands for -N ((CH ₂ ) ₇ CH ₃ ) ₂
"NCO" stands for -NHCO ((CH ₂ ) ₄ CH ₃ )
"F" represents a fluorine atom
"Cl" represents a chlorine atom
"Br" represents a bromine atom
"CN" represents a cyano group
"NO2" represents a nitro group
"SUA" stands for -SO ₃ H
"CBA" stands for -CO ₂ H and represents
"CHO" stands for -CHO
"OCH" stands for -OCOH
"OH" stands for -OH
"SFM" stands for -SO ₂ NH ₂
"CBM" stands for -CONH _{2
"NH 2} " stands for -NH 2
"NCH" represents -NHCOH.

For example, the compound (IZ3-1) is a compound represented by the formula (IZ3-1).

As a compound (IZ3),
Compound (IZ3-1) to compound (IZ3-120) and (IZ3-207) to compound (IZ3-212) are preferable.
Compounds (IZ3-1) to compounds (IZ3-120) are more preferred.
Compounds (IZ3-1) to compounds (IZ3-60) are more preferred.
Compounds (IZ3-1) to compounds (IZ3-36), compounds (IZ3-37) and compounds (IZ3-58) are even more preferred.
Compounds (IZ3-1) to compounds (IZ3-36) are particularly preferred, compound (IZ3-1), compound (IZ3-6), compound (IZ3-8), compound (IZ3-11), compound (IZ3-14). ) And compound (IZ3-19) are even more preferred.
Compound (IZ3-1), compound (IZ3-6), and compound (IZ3-19) are particularly preferred.

Specific examples of the compound (IZ3) include compounds in which 1 to 3 hydrogen atoms contained in the compounds shown in Tables 1Z3 to 6Z3 are substituted with _{-SO 3} M or -CO _{2 M.} For example, a compound in which 1 to 3 sulfo groups are bonded to the compound (IZ3-1) in Table 1Z3 is represented by the following structure. However, in the formula, − (SO ₃ H) means that any hydrogen atom of the compound (IZ3-1) in Table 1Z3 is substituted.

In the present invention
Compounds (IZ3-1) to (IZ3-120) and (IZ3-207) to compound (IZ3-212) to which 1 to 3 -SO ₃ M or -CO ₂ M are bound are preferable.
More preferably, compounds in which _{1 to 3 -SO 3} M or -CO ₂ M are bound to compound (IZ3-1) to compound (IZ3-120).
_{Compounds in which 1 to 3 -SO 3} M or -CO ₂ M are bound to compound (IZ3-1) to compound (IZ3-60) are more preferable.
Compound (IZ3-1) to compound (IZ3-36), compound (IZ3-37) and compound (IZ3-58) to which 1 to 3 -SO ₃ M or -CO ₂ M are bound are further added. More preferred
_{Compounds in which 1 to 3 -SO 3} M or -CO ₂ M are bound to compound (IZ3-1) to compound (IZ3-36) are particularly preferable.
1 to 3 -SOs in compound (IZ3-1), compound (IZ3-6), compound (IZ3-8), compound (IZ3-11), compound (IZ3-14) and compound (IZ3-19). _{Compounds to which 3} M or -CO ₂ M are attached are even more preferred.
_{A compound in which 1 to 3 -SO 3} M or -CO ₂ M is bound to compound (IZ3-1), compound (IZ3-6) or compound (IZ3-19) is particularly preferable.

As the compound (IZ3), in the formula (IZ3),
R ^1Z ₃ is a hydrocarbon group having 1 to 20 carbon atoms, which may have a substituent selected from the group consisting of a hydrogen atom, -SO 3 M and -CO _{2 M, -SO 3} M or -CO ₂ M and
R ^{2Z3 to} R ^5Z3 independently have a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogen atom, -N (R ^102Z3 ) ₂ , a nitro group, and a fluorine atom in all or part of the hydrogen atom. Substituted hydrocarbon groups with 1 to 20 carbon atoms, -NHCO-R ^102Z3 , ^{-OR 102Z3} , -SO ₃ M or -CO ₂ M.
R ^6Z3 and R ^7Z3 are independent of each other _{and may have a substituent selected from the group consisting of hydrogen atom, −SO 3} M and −CO ₂ M, a hydrocarbon group having 1 to 20 carbon atoms, −. SO ₃ M or -CO ₂ M,
R ^102Z3 is a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent selected from the group consisting of _{-SO 3} M and -CO _{2 M.}
M is preferably a compound which is a hydrogen atom or an alkali metal atom.
R ^1Z3 is a hydrogen atom
In R ^{2Z3 to} R ^5Z3 , hydrogen atom, hydrocarbon group having 1 to 10 carbon atoms, halogen atom, -N (R 102Z3) ₂ , nitro group, and all or part of hydrogen atom are independently ^{composed of hydrogen atom.} Substituted hydrocarbon groups with 1 to 10 carbon atoms, -NHCO-R ^102Z3 , ^{-OR 102Z3} , -SO ₃ M or -CO ₂ M.
R ^6Z3 and R ^7Z3 are hydrocarbons having 1 to 10 carbon atoms which are the same group and may have a hydrogen atom or a substituent selected from the group consisting of _{-SO 3} M and -CO _{2 M.} Is the basis and
R ^102Z3 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of _{-SO 3} M and -CO _{2 M.}
M is more preferably a compound which is a hydrogen atom or an alkali metal atom.
R ^1Z3 is a hydrogen atom
R ^{2Z3 to} R ^5Z3 are independently hydrogen atom, hydrocarbon group having 1 to 10 carbon atoms, halogen atom, -N (R ^102Z3 ) ₂ , nitro group, trifluoromethyl group, ^{-OR 102Z3} , respectively. -SO ₃ M or -CO ₂ M,
R ^6Z3 and R ^7Z3 are the same group, a hydrogen atom, or a hydrocarbon group having 1 to 10 carbon atoms.
R ^102Z3 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of _{-SO 3} M and -CO _{2 M.}
M is more preferably a compound which is a hydrogen atom or an alkali metal atom.

As for the compound (IZ3), when R ^1Z3 is a hydrogen atom, a compound represented by the formula (pt1Z3) (hereinafter, may be referred to as a phthalonitrile compound) is referred to as a compound represented by the formula (pt2Z3) (hereinafter, referred to as an alkoxide compound). It can be produced by further reacting the compound represented by the formula (pt3Z3) with the compound represented by the formula (pt4Z3) in the presence of an acid. When R ^1Z3 is other than a hydrogen atom, the compound (IZ3) can be produced by further reacting with a compound represented by the formula (pt5Z3).

[In the formula (pt1Z3), the formula (pt2Z3), the formula (pt3Z3), the formula (pt4Z3), the formula (pt5Z3) and the formula (IZ3), R ^{1Z3 to} R ^7Z3 have the same meanings as described above.
R ^14Z3 represents an alkyl group having 1 to 20 carbon atoms.
M ^1Z3 represents an alkali metal atom.
LG represents a halogen atom, a methanesulfonyloxy group, a toluenesulfonyloxy group or a trifluoromethanesulfonyloxy group. ]

^Examples of the alkyl group having 1 to 20 carbon atoms represented by R 14Z3 include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, a sec-butyl group and a tert-butyl group, which are preferable. Examples include alkyl groups having 1 to 6 carbon atoms.
Examples of the alkali metal atom represented by M ^{1Z 3} include a lithium atom, a sodium atom and a potassium atom.

The amount of the alkoxide compound used is usually 0.1 to 10 mol, preferably 0.2 to 5 mol, and more preferably 0.3 to 3 mol, based on 1 mol of the phthalonitrile compound. More preferably, it is 0.4 to 2 mol.

The amount of the compound (pt3Z3) used is usually 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, still more preferably 1 mol, relative to 1 mol of the phthalonitrile compound. ~ 2 mol.
The amount of the compound (pt4Z3) used is usually 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, still more preferably 1 mol, relative to 1 mol of the phthalonitrile compound. ~ 2 mol.

Examples of the acid include inorganic acids such as hydrochloric acid, hydrobromic acid, hydroiodic acid, sulfuric acid, nitric acid, fluorosulfonic acid and phosphoric acid; sulfonic acids such as methanesulfonic acid, trifluoromethanesulfonic acid and p-toluenesulfonic acid; Examples thereof include carboxylic acids such as acetic acid, citric acid, formic acid, gluconic acid, lactic acid, oxalic acid and tartrate acid, preferably hydrochloric acid, hydrobromic acid, sulfuric acid, methanesulfonic acid, trifluoromethanesulfonic acid, p-toluenesulfonic acid and Examples include carboxylic acids, more preferably acetic acids.
The amount of the acid used is usually 1 to 20 mol, preferably 1 to 10 mol, more preferably 1 to 8 mol, still more preferably 1 to 6 mol, based on 1 mol of the phthalonitrile compound. be.

The reaction of the phthalonitrile compound, the alkoxide compound, the compound (pt3Z3) and the compound (pt4Z3) is usually carried out in the presence of a solvent.
As the solvent, water; a nitrile solvent such as acetonitrile; an alcohol solvent such as methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol and 1-octanol; an ether solvent such as tetrahydrofuran; a ketone solvent such as acetone; acetic acid. Ester solvents such as ethyl; aliphatic hydrocarbon solvents such as hexane; aromatic hydrocarbon solvents such as toluene; halogenated hydrocarbon solvents such as methylene chloride and chloroform; amides such as N, N-dimethylformaldehyde and N-methylpyrrolidone. Solvents: Sulfoxide solvents such as dimethylsulfoxide, preferably water, nitrile solvents, alcohol solvents, ether solvents, ketone solvents, ester solvents, aromatic hydrocarbon solvents, halogenated hydrocarbon solvents, amide solvents and sulfoxide solvents. More preferably, water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, tetrahydrofuran, acetone, ethyl acetate, toluene, methylene chloride, chloroform, N, N-dimethylformaldehyde. , N-Methylpyrrolidone and dimethylsulfoxide, more preferably water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, acetone, methylene chloride, chloroform, N, N. -Dimethylformaldehyde, N-methylpyrrolidone and dimethylsulfoxide are mentioned, and water, acetonitrile, methanol, ethanol and 2-propanol are particularly preferable.
The amount of the solvent used is usually 1 to 1000 parts by mass with respect to 1 part by mass of the phthalonitrile compound.

The reaction temperature is usually 0 to 200 ° C, preferably 0 to 100 ° C, more preferably 0 to 70 ° C, still more preferably 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

The amount of the compound (pt5Z3) used is usually 1 to 10 mol, preferably 1 to 5 mol, and more preferably 1 to 3 mol, relative to 1 mol of the compound (IZ3) in which ^{R 1Z3 is a hydrogen atom.} It is more preferably 1 to 2 mol.

When the compound (pt5Z3) is reacted, it is preferable that a base coexists. Bases include organic bases such as triethylamine, 4- (N, N-dimethylamino) pyridine, pyridine and piperidine; metal alkoxides such as sodium methoxide, sodium ethoxide, sodium tert-butoxide and potassium tert-butoxide; butyl lithium. , Tert-Organic metal compounds such as butyllithium and phenyllithium; and inorganic bases such as lithium hydroxide, sodium hydroxide and potassium hydroxide.

The amount of the base used is usually 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, and further, with respect to 1 mol of the compound (IZ3) in which ^{R 1Z3 is a hydrogen atom.} It is preferably 1 to 2 mol.

The reaction of compound (pt5Z3) is usually carried out in the presence of a solvent. The solvent can be selected from the same range as described above.
The amount of the solvent used is usually 1 to 1000 parts by mass with respect to 1 part by mass of the compound (IZ3) in which ^{R 1Z3 is a hydrogen atom.} The reaction temperature of the compound (pt5Z3) is usually −90 to 200 ° C., preferably −80 to 100 ° C., and more preferably 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

If compound (IZ3) _{does not have a sulfo group or -SO 3} M ²² , the compound (IZ 3) is reacted with a sulphonizing agent such as fuming sulfuric acid or chlorosulfuric acid to cause a sulfo group or -SO ₃ M ^22. Can be introduced.
M ²² represents an alkali metal atom.
Examples ^{of the alkali metal atom represented by M 22} include a lithium atom, a sodium atom and a potassium atom.

_{The amount of SO 3} used in fuming sulfuric acid is usually 1 to 50 mol, preferably 5 to 40 mol, more preferably 5 to 30 mol, still more preferably 5 to 30 mol, per 1 mol of compound (IZ3). It is 5 to 25 mol.
The amount of sulfuric acid used in fuming sulfuric acid is usually 1 to 200 mol, preferably 10 to 100 mol, more preferably 10 to 75 mol, and further preferably 10 to 1 mol of compound (IZ3). ~ 50 mol.

The amount of chlorosulfonic acid used is usually 1 to 500 mol, preferably 10 to 300 mol, more preferably 10 to 200 mol, still more preferably 10 to 150 mol, relative to 1 mol of compound (IZ3). It is a mole.

The reaction temperature for sulfonation is usually -20 to 200 ° C, preferably -10 to 100 ° C, and more preferably 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

The method for extracting the compound (IZ3) from the reaction mixture is not particularly limited, and the compound (IZ3) can be extracted by various known methods. For example, after completion of the reaction, the compound (IZ3) can be taken out by filtering the reaction mixture. Further, after filtration, the obtained residue may be subjected to column chromatography, recrystallization or the like. Further, after completion of the reaction, the solvent of the reaction mixture may be distilled off and then purified by column chromatography.

<Compound (IZ4)>
The compound (IZ4) is a compound represented by the formula (IZ4).

[In formula (IZ4),
R ^N1Z4 and R ^N2Z4 are independent of each other, -CO-R ^102Z4 , -COO-R ^101Z4 , -OCO-R ^102Z4 , -COCO-R ^102Z4 , ^{-OR 102Z4} , -SO _2- R ^101Z4 , -SO. ₂ N (R ^102Z4 ) ₂ ^{, -CON} (R 102Z4) ₂ , -N (R ^102Z4 ) ₂ , -NHCO-R ^102Z4 , -NHCO-N (R ^102Z4 ) ₂ , -NHCOOR ^102Z4 , -OCON (R ^102Z4 ) ₂ , Halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, may have a substituent or a hydrocarbon group having 1 to 40 carbon atoms or a complex which may have a substituent. Represents a ring group.
R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , and R ^7Z4 are independent of each other, hydrogen atom, -CO-R ^102Z4 , -COO-R ^101Z4 , -OCO-R ^102Z4 , -COCO. -R ^102Z4 , -O-R ^102Z4 , -SO ₂ -R ^101Z4 , -SO ₂ N (R ^102Z4 ) ₂ ^{, -CON} (R 102Z4) ₂ , -N (R ^102Z4 ) ₂ , -NHCO-R ^102Z4 ,- NHCO-N (R ^102Z4 ) ₂ , -NHCOOR ^102Z4 , -OCON (R ^102Z4 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, carbon which may have a substituent Represents a heterocyclic group which may have a hydrocarbon group or a substituent of the number 1 to 40.
R ^{2Z 4} and R ^{3Z 4} , R ^{3Z 4} and R ^{4Z 4} , and R 4 ^{Z 4} and R 5 ^{Z 4} may be coupled to each other to form a ring, respectively.
R ^101Z4 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102Z4 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
M represents a hydrogen atom or an alkali metal atom.
When a ^{plurality of R 101Z4} , R ^102Z4 and M are present, they may be the same or different.
The wavy line represents an E-form or a Z-form. ]

The number of carbon atoms of the hydrocarbon groups represented by ^{R N1Z4} , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^101Z4 and R ^{102Z4 is 1 to 40.} It is preferably 1 to 30.
It is more preferably 1 to 20, still more preferably 1 to 15, and particularly preferably 1 to 10.

The hydrocarbon groups having 1 to 40 carbon atoms represented by R ^N1Z4 , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^101Z4 and R ^{102Z4 are aliphatic hydrocarbons.} It may be a hydrogen group and an aromatic hydrocarbon group, and the aliphatic hydrocarbon group may be saturated or unsaturated, or may be a chain or an alicyclic.

The saturated or unsaturated chain hydrocarbon group represented by ^{R N1Z4} , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^101Z4 and R ^{102Z4 is a methyl group.} , Ethyl group, propyl group, butyl group, pentyl group, hexyl group, heptyl group, octyl group, nonyl group, decyl group, undecyl group, dodecyl group, heptadecyl group, octadecyl group, and linear alkyl group such as icosyl group. Etc .; isopropyl group, isobutyl group, sec-butyl group, tert-butyl group, (2-ethyl) butyl group, isopentyl group, neopentyl group, tert-pentyl group, (1-methyl) pentyl group, (2-methyl) Branch chains of pentyl group, (1-ethyl) pentyl group, (3-ethyl) pentyl group, isohexyl group, (5-methyl) hexyl group, (2-ethyl) hexyl group, (3-ethyl) heptyl group, etc. Alkyl group, etc .; vinyl group, 1-propenyl group, 2-propenyl group (allyl group), (1-methyl) ethenyl group, 2-butenyl group, 3-butenyl group, 1,3-butadienyl group, (1- (2-Propenyl)) Ethenyl groups, alkenyl groups such as (1,2-dimethyl) propenyl groups and 2-pentenyl groups; and the like. The saturated or unsaturated chain hydrocarbon group preferably has 1 to 30 carbon atoms, more preferably 1 to 20 carbon atoms, still more preferably 1 to 15 carbon atoms, and particularly preferably 1 to 10 carbon atoms. It is more preferably 1 to 8, and even more preferably 1 to 5. Of these, a linear or branched alkyl group having 1 to 10 carbon atoms, more preferably 1 to 8 carbon atoms is particularly preferable, and a methyl group, an ethyl group, and a tert-butyl group are particularly preferable.

The ^{R N1Z4, R N2Z4, R 1Z4} , R 2Z4, R 3Z4, R 4Z4, R 5Z4, R 6Z4, R 7Z4, saturated or unsaturated alicyclic hydrocarbon group represented by R ^101Z4 and R ^102Z4, cyclo Propyl group, 1-methylcyclopropyl group, cyclobutyl group, cyclopentyl group, cyclohexyl group, cycloheptyl group, 1-methylcyclohexyl group, 2-methylcyclohexyl group, 3-methylcyclohexyl group, 4-methylcyclohexyl group, 1,2 -Dimethylcyclohexyl group, 1,3-dimethylcyclohexyl group, 1,4-dimethylcyclohexyl group, 2,3-dimethylcyclohexyl group, 2,4-dimethylcyclohexyl group, 2,5-dimethylcyclohexyl group, 2,6-dimethyl Cyclohexyl group, 3,4-dimethylcyclohexyl group, 3,5-dimethylcyclohexyl group, 2,2-dimethylcyclohexyl group, 3,3-dimethylcyclohexyl group, 4,4-dimethylcyclohexyl group, cyclooctyl group, 2,4 , 6-trimethylcyclohexyl group, 2,2,6,6-tetramethylcyclohexyl group and 3,3,5,5-tetramethylcyclohexyl group, 4-pentylcyclohexyl group, 4-octylcyclohexyl group, 4-cyclohexylcyclohexyl group Cycloalkyl groups such as: cyclohexenyl groups (eg, cyclohex-2-ene, cyclohexa-3-ene), cycloheptenyl groups, cyclooctenyl groups such as cycloalkenyl groups; norbornan group, adamantyl group, bicyclo [2.2.2] octane And so on. The saturated or unsaturated alicyclic hydrocarbon group preferably has 3 to 30, more preferably 3 to 20, even more preferably 4 to 20, and even more preferably 4 to 15. Yes, more particularly preferably 5 to 15, and most preferably 5 to 10. Of these, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, and a cyclooctyl group are particularly preferable.

The ^{aromatic hydrocarbon groups represented by R N1Z4} , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^101Z4 and R ^102Z4 include phenyl group and o-trill. Group, m-tolyl group, p-tolyl group, 2-ethylphenyl group, 3-ethylphenyl group, 4-ethylphenyl group, 2,3-dimethylphenyl group, 2,4-dimethylphenyl group, 2,5- Dimethylphenyl group, 2,6-dimethylphenyl group, 3,4-dimethylphenyl group, 3,5-dimethylphenyl group, 4-vinylphenyl group, o-isopropylphenyl group, m-isopropylphenyl group, p-isopropylphenyl Group, o-tert-butylphenyl group, m-tert-butylphenyl group, p-tert-butylphenyl group, mesityl group, 4-ethylphenyl group, 4-butylphenyl group, 4-pentylphenyl group, 2,6 -Bis (2-propyl) phenyl group, 4-cyclohexylphenyl group, 2,4,6-trimethylphenyl group, 4-octylphenyl group, 1-naphthyl group, 2-naphthyl group, 5,6,7,8- Examples thereof include tetrahydro-1-naphthyl group, 5,6,7,8-tetrahydro-2-naphthyl group, fluorenyl group, phenyl group and aromatic hydrocarbon group such as anthryl group and pyrenyl group; and the like. The number of carbon atoms of the aromatic hydrocarbon group is preferably 6 to 30, more preferably 6 to 20, and even more preferably 6 to 15.

The ^{hydrocarbon groups represented by R N1Z4} , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^101Z4 and R ^102Z4 are the above-mentioned hydrocarbon groups (for example, It may be a group in which an aromatic hydrocarbon group is combined with at least one of a chain hydrocarbon group and an alicyclic hydrocarbon group), such as a benzyl group, a phenethyl group, a 1-methyl-1-phenylethyl group and the like. Aralkyl group; arylalkenyl group such as phenylethenyl group (phenylvinyl group); arylalkynyl group such as phenylethynyl group; phenyl group to which one or more phenyl groups such as biphenylyl group and terphenylyl group are bonded; cyclohexylmethylphenyl Examples include a group, a benzyl phenyl group, a (dimethyl (phenyl) methyl) phenyl group and the like.
The ^{groups represented} by R N1Z4, R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^101Z4 and R ^102Z4 are the hydrocarbon groups listed above (for example, chain). As a group combining a hydrocarbon group and an alicyclic hydrocarbon group, for example, a cyclopropylmethyl group, a cyclopropylethyl group, a cyclobutylmethyl group, a cyclobutylethyl group, a cyclopentylmethyl group, a cyclopentylethyl group, a cyclohexylmethyl group. , 2-Methylcyclohexylmethyl group, cyclohexylethyl group, adamantylmethyl group and the like may be an alkyl group to which one or more alicyclic hydrocarbon groups are bonded.
These carbon numbers are preferably 4 to 30, more preferably 6 to 30, even more preferably 6 to 20, still preferably 4 to 20, and even more preferably 4 to 15. , Particularly preferably 6 to 15.

The hydrocarbon groups represented by ^{R N1Z4} , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^{101 Z4} and R ^{102 Z4 may have substituents.} .. The substituent may be monovalent or divalent. For the divalent substituent, it is preferable that two bonds are bonded to the same carbon atom to form a double bond.
As the monovalent substituent,
Methoxy group, ethoxy group, propoxy group, isopropoxy group, butoxy group, isobutoxy group, sec-butoxy group, tert-butoxy group, pentyloxy group, hexyloxy group, (2-ethyl) hexyloxy group, heptyloxy group, Octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, dodecyloxy group, (2-ethyl) hexyloxy group, icosyloxy group, 1-phenylethoxy group, 1-methyl-1-phenylethoxy group, phenyloxy group , O-Trilloxy group, 2,3-dimethylphenyloxy group, 2,4-dimethylphenyloxy group, 2,5-dimethylphenyloxy group, 2,6-dimethylphenyloxy group, 3,4-dimethylphenyloxy group , 3,5-dimethylphenyloxy group, 2,2-dicyanophenyloxy group, 2,3-dicyanophenyloxy group, 2,4-dicyanophenyloxy group, 2,5-dicyanophenyloxy group, 2,6- Dicyanophenyloxy group, 3,4-dicyanophenyloxy group, 3,5-dicyanophenyloxy group, 4-methoxyphenyloxy group, 2-methoxyphenyloxy group, 3-methoxyphenyloxy group, 4-ethoxyphenyloxy group , 2-ethoxyphenyloxy group, 3-ethoxyphenyloxy group, etc., and groups represented by the following formulas, etc., which have 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or a derivatizing group thereof. (For example, a group derivatized with a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), or the like). Is an oxy group bonded to one side;

Methylthio group, ethylthio group, propylthio group, butylthio group, tert-butylthio group, pentylthio group, hexylthio group, (2-ethyl) hexylthio group, heptylthio group, octylthio group, nonylthio group, decylthio group, undecylthio group, dodecylthio group, icosylthio group. A sulfanyl group to which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group, a phenylthio group and an o-tolylthio group is bonded;

Epoxy group, oxetanyl group, tetrahydrofuryl group, tetrahydropyranyl group;
Holmil group;
Acetyl group, propanoyl group, butanoyl group, 2,2-dimethylpropanoyl group, pentanoyl group, hexanoyl group, (2-ethyl) hexanoyl group, heptanoil group, octanoyl group, nonanoyl group, decanoyl group, undecanoyl group, dodecanoyl group, A hydrocarbon group having a carbon number of 1 to 20 (preferably having a carbon number of 1 to 11) or an inducible group thereof (for example, a carboxy group or a sulfo group) such as a henicosanoyl group, a benzoyl group, and a group represented by the following formula. , A carbonyl group to which a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. are bonded. When the carbonyl group is an alkanoyl group, the number of carbon atoms is preferably 2 to 12);

Methoxycarbonyl group, ethoxycarbonyl group, propoxycarbonyl group, butoxycarbonyl group, tert-butoxycarbonyl group, pentyloxycarbonyl group, hexyloxycarbonyl group, (2-ethyl) hexyloxycarbonyl group, heptyloxycarbonyl group, octyloxycarbonyl group Group, nonyloxycarbonyl group, decyloxycarbonyl group, undecyloxycarbonyl group, dodecyloxycarbonyl group, icosyloxycarbonyl group, phenyloxycarbonyl group, o-tolyloxycarbonyl group, etc., and represented by the following formula A hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), a carbon number of carbon atoms). An oxycarbonyl group to which 1 to 10 alkylsulfamoyl groups (preferably groups derivatized with an octylsulfamoyl group) or the like are attached;

Amino group;
N-methylamino group, N, N-dimethylamino group, N-ethylamino group, N, N-diethylamino group, N-propylamino group, N, N-dipropylamino group, N-isopropylamino group, N, N-diisopropylamino group, N-butylamino group, N, N-dibutylamino group, N-isobutylamino group, N, N-diisobutylamino group, N-sec-butylamino group, N, N-disec-butyl Amino group, N-tert-butylamino group, N, N-ditert-butylamino group, N-pentylamino group, N, N-dipentylamino group, N- (1-ethylpropyl) amino group, N, N -Di (1-ethylpropyl) amino group, N-hexylamino group, N, N-dihexylamino group, N- (2-ethyl) hexylamino group, N, N-di (2-ethyl) hexylamino group, N-Heptylamino Group, N, N-Diheptylamino Group, N-octylamino Group, N, N-Dioctylamino Group, N-Nonylamino Group, N, N-Dinonylamino Group, N-Phenylamino Group, N, N -Diphenylamino group, N, N-ethylmethylamino group, N, N-propylmethylamino group, N, N-isopropylmethylamino group, N, N-butylmethylamino group, N-decylamino group, N, N- Decylmethylamino Group, N-Undecylamino Group, N, N-Undecylmethylamino Group, N-Dodecylamino Group, N, N-Dodecylmethylamino Group, N-Icosylamino Group, N, N-Icosylmethylamino One or two carbon atoms 1 to 20 (preferably 1 carbon atom) such as a group, an N, N-tert-butylmethylamino group, an N, N-phenylmethylamino group, etc., and a group represented by the following formula. A hydrocarbon group of 10) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), and an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsul). Amino group substituted with a famoyl group) or a derivatized group);

Sulfamoyl group;
N-methylsulfamoyl group, N, N-dimethylsulfamoyl group, N-ethylsulfamoyl group, N, N-diethylsulfamoyl group, N-propylsulfamoyl group, N, N-dipropyls Rufamoyl group, N-isopropylsulfamoyl group, N, N-diisopropylsulfamoyl group, N-butylsulfamoyl group, N, N-dibutylsulfamoyl group, N-isobutylsulfamoyl group, N, N-diisobutylsulfamoyl group, N-sec-butylsulfamoyl group, N, N-disec-butylsulfamoyl group, N-tert-butylsulfamoyl group, N, N-ditert-butylsul Famoyl group, N-pentyl sulfamoyl group, N, N-dipentyl sulfamoyl group, N- (1-ethylpropyl) sulfamoyl group, N, N-di (1-ethylpropyl) sulfamoyl group, N-hexyl Sulfamoyl group, N, N-dihexyl sulfamoyl group, N- (2-ethyl) hexyl sulfamoyl group, N, N-di (2-ethyl) hexyl sulfamoyl group, N-heptyl sulfamoyl Group, N, N-diheptyl sulfamoyl group, N-octyl sulfamoyl group, N, N-dioctyl sulfamoyl group, N, N-octylmethyl sulfamoyl group, N-nonyl sulfamoyl group, N, N-Dinonyl sulfamoyl group, N-phenyl sulfamoyl group, N, N-diphenyl sulfamoyl group, N, N-ethylmethyl sulfamoyl group, N, N-propylmethyl sulfamoyl group, N, N-isopropylmethylsulfamoyl group, N, N-butylmethylsulfamoyl group, N-decylsulfamoyl group, N, N-decylmethylsulfamoyl group, N-undecylsulfamoyl group, N , N-Undecylmethyl Sulfamoyl Group, N-Dodecyl Sulfamoyl Group, N, N-Dodecyl Methyl Sulfamoyl Group, N-Icosyl Sulfamoyl Group, N, N-Icosyl Methyl Sulfamoyl Group, N, N-tert-butylmethylsulfamoyl group, N, N-phenylmethylsulfamoyl group, etc., and one or two groups represented by the following formula, etc., having 1 or 2 carbon atoms (preferably carbons) A hydrocarbon group having a number of 1 to 10 or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), and an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably). Induced by octylsulfamoyl group) etc. Sulfamoyl group substituted with (ta group);

Formylamino group; acetylamino group, propanoylamino group, butanoylamino group, 2,2-dimethylpropanoylamino group, pentanoylamino group, hexanoylamino group, (2-ethyl) hexanoylamino group, heptanoil Amino group, octanoylamino group, nonanoylamino group, decanoyylamino group, undecanoylamino group, dodecanoylamino group, henicosanoylamino group, benzoylamino group, etc., and groups represented by the following formulas. Etc., a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 12 carbon atoms) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), 1 carbon atom). A carbonylamino group to which 10 to 10 alkylsulfamoyl groups (preferably groups derivatized with an octylsulfamoyl group) or the like are bonded (when the carbonylamino group is an alkanoylamino group, the number of carbon atoms is preferably 1. ~ 12);

Hydroxy group;
Halogen atoms such as fluorine atom, chlorine atom, bromine atom and iodine atom;
Carboxy group, -CO ₂ M ² (M ² is an alkali metal, preferably lithium, sodium,
Potassium); sulfo group, -SO ₃ M ² (M ² is alkali metal, preferably lithium, sodium, potassium); nitro group; cyano group;

Formyloxy group; acetoxy group, propanoyloxy group, butanoyloxy group, 2,2-dimethylpropanoyloxy group, pentanoyloxy group, hexanoyloxy group, (2-ethyl) hexanoyloxy group, heptanoyloxy group Carbons such as groups, octanoyloxy groups, nonanoyloxy groups, decanoyloxy groups, undecanoyloxy groups, dodecanoyloxy groups, henicosanoyloxy groups, benzoyloxy groups, etc., and groups represented by the following formulas. A hydrocarbon group having a number of 1 to 20 (preferably 1 to 10 carbon atoms) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), and a group having 1 to 10 carbon atoms. A carbonyloxy group to which an alkylsulfamoyl group (preferably a group derivatized with an octylsulfamoyl group) or the like is bonded (when the carbonyloxy group is an alkanoyloxy group, the number of carbon atoms is preferably 1 to 10). be);

Methylsulfonyl group, ethylsulfonyl group, propylsulfonyl group, butylsulfonyl group, pentylsulfonyl group, hexylsulfonyl group, (2-ethyl) hexylsulfonyl group, heptylsulfonyl group, octylsulfonyl group, nonylsulfonyl group, decylsulfonyl group, un Decylsulfonyl group, dodecylsulfonyl group, icosylsulfonyl group, phenylsulfonyl group, p-tolylsulfonyl group and the like, and groups represented by the following formulas having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms). A hydrocarbon group or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group)). Sulfonyl group to which (groups derivatized by etc.) are bound;

Carbamic group;
N-Methylcarbamoyl group, N, N-dimethylcarbamoyl group, N-ethylcarbamoyl group, N, N-diethylcarbamoyl group, N-propylcarbamoyl group, N, N-dipropylcarbamoyl group, N-isopropylcarbamoyl group, N , N-diisopropylcarbamoyl group, N-butylcarbamoyl group, N, N-dibutylcarbamoyl group, N-isobutylcarbamoyl group, N, N-diisobutylcarbamoyl group, N-sec-butylcarbamoyl group, N, N-disec- Butylcarbamoyl group, N-tert-butylcarbamoyl group, N, N-ditert-butylcarbamoyl group, N-pentylcarbamoyl group, N, N-dipentylcarbamoyl group, N- (1-ethylpropyl) carbamoyl group, N, N-di (1-ethylpropyl) carbamoyl group, N-hexyl carbamoyl group, N, N-dihexyl carbamoyl group, N- (2-ethyl) hexyl carbamoyl group, N, N-di (2-ethyl) hexyl carbamoyl group , N-Heptylcarbamoyl group, N, N-diheptylcarbamoyl group, N-octylcarbamoyl group, N, N-dioctylcarbamoyl group, N-nonylcarbamoyl group, N, N-octylmethylcarbamoyl group, N, N-octyl Butylcarbamoyl group, N, N-dinonylcarbamoyl group, N-phenylcarbamoyl group, N, N-diphenylcarbamoyl group, N, N-ethylmethylcarbamoyl group, N, N-propylmethylcarbamoyl group, N, N-isopropyl Methylcarbamoyl group, N, N-butylmethylcarbamoyl group, N-decylcarbamoyl group, N, N-decylmethylcarbamoyl group, N-undecylcarbamoyl group, N, N-undecylmethylcarbamoyl group, N-dodecylcarbamoyl group , N, N-dodecylmethylcarbamoyl group, N-icosylcarbamoyl group, N, N-icosylmethylcarbamoyl group, N, N-tert-butylmethylcarbamoyl group, N, N-phenylmethylcarbamoyl group, etc. A hydrocarbon group having 1 or 2 carbon atoms (preferably 1 to 10 carbon atoms) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group) such as a group represented by the above formula. , A carbamoyl group substituted with halogen (preferably a chlorine atom), a group derivatized with an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc.;

Trifluoromethyl group, perfluoroethyl group, perfluoropropyl group, perfluoroisopropyl group, perfluorobutyl group, perfluoropentyl group, perfluorohexyl group, perfluoroheptyl group, perfluorooctyl group, perfluorononyl group, Carbonation of 1 to 20 carbon atoms in which all hydrogen atoms such as perfluorodecyl group, perfluoroundecyl group, perfluorododecyl group, perfluoroicosyl group, perfluorocyclohexyl group and perfluorophenyl group are substituted with fluorine atom. Hydrogen group;

Perfluoroethylmethyl group, perfluoropropylmethyl group, perfluoroisopropylmethyl group, perfluorobutylmethyl group, perfluoropentylmethyl group, perfluorohexylmethyl group, perfluoroheptylmethyl group, perfluorooctylmethyl group, perfluoro A linear chain having 1 to 20 carbon atoms in which all hydrogen atoms such as nonylmethyl group, perfluorodecylmethyl group, perfluoroundecylmethyl group, perfluorododecylmethyl group, and perfluoroicosylmethyl group are substituted with fluorine atoms. Alternatively, a hydrocarbon group having 1 to 20 carbon atoms substituted with an alkyl group in the branched chain;

1 to 20 carbon atoms (preferably carbon number) in which a part of hydrogen atoms such as 2-fluorophenyl group, 3-fluorophenyl group, 4-fluorophenyl group and 2,4,6-trifluorophenyl group are replaced with fluorine. 1-10) hydrocarbon groups;

-CO-SH, -CO-S-CH ₃ , -CO-S-CH ₂ CH ₃ , -CO-S-CH ₂ -CH ₂ -CH ₃ , -CO-S-CH ₂ -CH ₂ -CH ₂ carbon atoms -CH _3, etc. 20 (preferably having 1 to 10 carbon atoms) bound to an alkyl group as bonded to a thiocarbonyl _{group, -CO-S-C 6 H} 5 aryl group having 6 to 20 carbon atoms, such as the Thiocarbonyl group;

* -COCO-R as represented by the following formula (in the formula, R is a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms (for example, among the hydrocarbon groups listed above, it satisfies 1 to 20 carbon atoms). , Or its inducing group (eg, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group). Group) (group derived by etc.);

_{* -NRCONR 2} as represented by the following formula (in the formula, R is a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms (for example, among the hydrocarbon groups listed above, those satisfying 1 to 20 carbon atoms). ), Or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), etc. Groups derived from), the Rs of which may be the same or different from each other, or bonded to each other to form a ring);

_{* -OCONR 2} as represented by the following formula (in the formula, R is a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms (for example, among the hydrocarbon groups listed above, those satisfying 1 to 20 carbon atoms). ), Or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), etc. Groups derived from), the Rs of which may be the same or different from each other, or bonded to each other to form a ring);

* -NRCOOR as represented by the following formula (in the formula, R is a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms (for example, among the hydrocarbon groups listed above, those satisfying 1 to 20 carbon atoms)). , Or its inducing group (eg, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group), etc. Derivatized groups), the Rs of which may be the same or different from each other, or bonded to each other to form a ring) groups;

* -OP (O) (OCH ₃ ) ₂ such as * -OP (O) (OR) ₂ (In the formula, R is a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms (for example, the hydrocarbon group listed above). Of these, those satisfying 1 to 20 carbon atoms), or their inducible groups (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms). (Preferably a group derivatized with an octylsulfamoyl group) or the like), and the Rs may be the same or different from each other, or may be bonded to each other to form a ring).
* -Si (CH ₃ ) ₃ , _{* -Si (CH 2} CH ₃ ) ₃ , _{* -Si (C 6} H ₅ ) ₃ and * -Si (CH (CH ₃ ) ₂ ) _3, etc. * -SiR ₃ ( In the formula, R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, one of the above-mentioned hydrocarbon groups satisfying 1 to 20 carbon atoms), or an inducing group thereof (for example, a carboxy group or a sulfo group). A group derived from a group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), etc.), and the R is Groups of (may be the same or different from each other and may be bonded to each other to form a ring);
And so on.

As the divalent substituent, an oxo group, a thioxo group, an imino group, an imino group substituted with an alkyl group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) and an aryl group having 6 to 20 carbon atoms are substituted. Examples include the imino group. Examples of the imino group substituted with the alkyl group include CH _3- N =, CH _3- CH _2- N =, CH _3- (CH ₂ ) _2- N = and CH _3- (CH ₂ ) _3- N =. Can be mentioned. Examples of the imino group substituted with the aryl group include C ₆ H _5- N = and the like.

Preferred examples of the substituent of the hydrocarbon group having 1 to 40 carbon atoms include the substituent of the group s1. The inducible groups shown below are carboxy groups, sulfo groups, nitro groups, hydroxy groups, halogens (preferably chlorine atoms), alkylsulfamoyl groups having 1 to 10 carbon atoms (preferably octylsulfamoyl groups) and the like. It is preferably an derivatized group.
[Group s1]
An oxy group in which a hydrocarbon group having 1 to 20 carbon atoms or an inducible group thereof is bonded to one side;
A carbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
An oxycarbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
Amino group;
An amino group substituted with one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
Sulfamoyl group;
A sulfamoyl group substituted with one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
A carbonylamino group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
Hydroxy group;
Halogen atom;
-CO ₂ M (preferably a carboxy group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom);
-SO ₃ M (preferably a sulfo group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom);
Nitro group;
Cyano group;
A carbonyloxy group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
A sulfonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or an inducible group thereof is bonded;
Carbamic group;
A carbamoyl group substituted with one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
A hydrocarbon group having 1 to 20 carbon atoms in which all hydrogen atoms are replaced by fluorine atoms;
A hydrocarbon group having 1 to 20 carbon atoms in which all of the hydrogen atoms are substituted with fluorine atoms;
A hydrocarbon group having 1 to 20 carbon atoms in which a part of a hydrogen atom is replaced by fluorine;
Oxo group

As the substituent of the hydrocarbon group having 1 to 40 carbon atoms, a substituent of group s2 is more preferable.
[Group s2]
An oxy group in which a hydrocarbon group having 1 to 10 carbon atoms or an inducible group thereof is bonded to one side;
A carbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
An oxycarbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
Amino group;
An amino group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or an inducible group thereof;
Sulfamoyl group;
A sulfamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof;
A carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
Hydroxy group;
Fluorine atom, chlorine atom, bromine atom;
-CO ₂ M (preferably a carboxy group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom);
-SO ₃ M (preferably a sulfo group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom);
Nitro group;
Cyano group;
A carbonyloxy group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
A sulfonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or an inducible group thereof is bonded;
Carbamic group;
A carbamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof;
A hydrocarbon group having 1 to 10 carbon atoms in which all hydrogen atoms are replaced by fluorine atoms;
A hydrocarbon group having 1 to 10 carbon atoms in which all of the hydrogen atoms are substituted with fluorine atoms;
A hydrocarbon group having 1 to 10 carbon atoms in which a part of a hydrogen atom is replaced by fluorine;
Oxo group

As a hydrocarbon group having 1 to 40 carbon atoms having a substituent represented by ^{R N1Z4} , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^{101 Z4} and R ^{102 Z4.} Is a hydrocarbon group having 1 to 40 carbon atoms having a monovalent or divalent substituent, preferably a saturated or unsaturated chain having 1 to 30 carbon atoms having a monovalent or divalent substituent. Saturated or unsaturated alicyclic hydrocarbon groups with 3 to 30 carbon atoms having monovalent or divalent substituents, aromatic hydrocarbons with 6 to 30 carbon atoms having monovalent or divalent substituents A group having a monovalent or divalent substituent and having 1 to 30 carbon atoms, which is a combination of a hydrogen group or a hydrocarbon group, can be mentioned.
More preferably, a saturated or unsaturated chain hydrocarbon group having 1 to 20 carbon atoms having a substituent in group s1 and a saturated or unsaturated alicyclic hydrocarbon group having 3 to 20 carbon atoms having a substituent in group s1. , A group having a substituent of group s1 and having 6 to 20 carbon atoms or a combination of hydrocarbon groups and a group having a substituent of group s1 and having 1 to 20 carbon atoms.
Particularly preferably, a saturated or unsaturated chain hydrocarbon group having 1 to 15 carbon atoms having a substituent in group s2 and a saturated or unsaturated alicyclic hydrocarbon group having 3 to 15 carbon atoms having a substituent in group s2. , A group having a substituent of group s2 and having 6 to 15 carbon atoms or a combination of hydrocarbon groups and a group having a substituent of group s2 and having 1 to 15 carbon atoms.

The ^{heterocyclic group represented by R N1Z4} , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^{101 Z4} and R ^{102 Z4} may be a single ring. It may be polycyclic, and is preferably a heterocycle containing a heteroatom as a component of the ring. Examples of the hetero atom include a nitrogen atom, an oxygen atom and a sulfur atom.
The number of carbon atoms of the heterocyclic group is preferably 3 to 30, more preferably 3 to 22, still more preferably 3 to 20, even more preferably 3 to 18, and even more preferably 3 to 3. It is 15, particularly preferably 3 to 14.

As a heterocycle containing a nitrogen atom,
Monocyclic saturated heterocycles such as aziridine, azetidine, pyrrolidine, piperidine and piperazine;
Pyrrole such as 2,5-dimethylpyrrole, pyrazole such as 2-methylpyrazole and 3-methylpyrazole, imidazole, 1,2,3-triazole and 5-membered ring-based unsaturated heterocycle such as 1,2,4-triazole ;
Pyrimidines such as pyridine, pyridazine, 6-methylpyrimidine, pyrazines and 6-membered ring unsaturated heterocycles such as 1,3,5-triazine;
Quinoxaline such as indazole, indolin, isoindolin, indole, indoline, benzimidazole, quinoline, isoquinoline, 5,6,7,8-tetrahydro (3-methyl) quinoxaline, 3-methylquinoxaline, quinazoline, cinnoline, phthalazine, diazanaphthalene. , Purine, pteridine, benzopyrazole, benzopiperidine and other fused bicyclic heterocycles;
Condensed tricyclic heterocycles such as carbazole, acridine and phenazine; and the like.

As a heterocycle containing an oxygen atom,
Monocyclic saturated heterocycles such as oxylan, oxetane, tetrahydrofuran, tetrahydropyran, 1,3-dioxane and 1,4-dioxane, 1-cyclopentyl dioxolane;
Bicyclic saturated heterocycles such as 1,4-dioxaspiro [4.5] decane and 1,4-dioxaspiro [4.5] nonane;
Lactone-based heterocycles such as α-acetolactone, β-propiolactone, γ-butyrolactone, γ-valerolactone and δ-valerolactone;
A 5-membered ring-based unsaturated heterocycle such as furan such as 2,3-dimethylfuran and 2,5-dimethylfuran;
6-membered ring-based unsaturated heterocycles such as 2H-pyran and 4H-pyran;
Benzopyrans such as 1-benzofuran and 4-methylbenzopyran, condensed bicyclic heterocycles such as benzodioxol, chroman and isochroman;
Condensed tricyclic heterocycles such as xanthene and dibenzofuran; and the like.

As a heterocycle containing a sulfur atom,
5-membered ring-based saturated heterocycle such as dithiolane;
6-membered ring-based saturated heterocycles such as thiane, 1,3-dithiane, 2-methyl 1,3-dithiane;
5-membered ring-based unsaturated heterocycles such as thiophenes such as 3-methylthiophene and 2-carboxythiophene, 4H-thiopyran, benzothiopyran such as benzotetrahydrothiopyran;
Condensation bicyclic heterocycles such as benzothiophene;
Condensed tricyclic heterocycles such as thianthrene and dibenzothiophene; and the like.

As a heterocycle containing a nitrogen atom and an oxygen atom,
Monocyclic saturated heterocycles such as morpholine, 2-pyrrolidone, 2-methyl-2-pyrrolidone, 2-piperidone and 2-methyl-2-piperidone;
Monocyclic unsaturated heterocycles such as oxazoles such as 4-methyloxazole, 2-methylisoxazoles, and isooxazoles such as 3-methylisoxazole;
Condensed bicyclic heterocycles such as benzoxazole, benzoisoxazole, benzoxazine, benzodioxan, benzoimidazoline;
Condensed tricyclic heterocycles such as phenoxazine; and the like.

As a heterocycle containing a nitrogen atom and a sulfur atom,
Monocyclic heterocycles such as thiazoles such as 3-methylthiazole and 2,4-dimethylthiazole;
Condensation bicyclic heterocycles such as benzothiazole;
Condensation tricyclic heterocycles such as phenothiazine; and the like.

The heterocycle may be a group in which the above-mentioned hydrocarbon groups are combined, and examples thereof include a tetrahydrofurylmethyl group.

Further, the heterocycle may be represented by the following formula.

Further, the heterocyclic group may be a heterocyclic group formed by bonding two or more of ^{R 1Z4 to} R ^5Z4. Such a heterocyclic group has a ring structure of two or more rings together with a benzene ring to which ^{R 1Z4 to} R ^{5Z4 are bonded.} Examples of the ring structure having two or more rings include the structure of the following formula.

The bond position of the above heterocycle is a portion where an arbitrary hydrogen atom contained in each ring is eliminated.

The heterocyclic groups represented by ^{R N1Z4} , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^{101 Z4} and R ^{102 Z4 may have substituents.} .. As the substituent, the hydrocarbon groups represented by R ^N1Z4 , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^{101 Z4} and R ^{102 Z4} are contained. The same as a good substituent can be mentioned. When the heterocycle contains a nitrogen atom as a constituent element thereof, the hydrocarbon group mentioned above may be bonded to the nitrogen atom as a substituent.
Preferred substituents include hydrocarbon groups represented by ^{R N1Z4} , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^{101 Z4} and R ^{102 Z4.} Examples include the same preferred substituents that may be used.
Heterocyclic groups having substituents represented by R ^N1Z4 , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^101Z4 and R ^{102Z4 are monovalent or 2} A heterocyclic group having a valence substituent can be mentioned, preferably a heterocyclic group having a substituent of group s1, and more preferably a heterocyclic group having a substituent of group s2.
The above-mentioned hydrocarbon group or heterocyclic group may have one or more substituents (first substituents), and the two or more substituents are independent of each other. It may be the same or different. Further, the first substituent may have another substituent (second substituent) bonded to the hydrocarbon group contained in a part thereof. The second substituent can be selected from the same groups as the first substituent.

Below, R ^N1Z4 , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 -CO-R ^102Z4 , -COO-R ^101Z4 , -OCO-R ^102Z4 , -COCO- R ^102Z4 , ^{-OR 102Z4} , -SO ₂ -R ^101Z4 , -SO ₂ N (R ^102Z4 ) ₂ ^{, -CON} (R 102Z4) ₂ , -N (R ^102Z4 ) ₂ , -NHCO-R ^102Z4 , -NHCO -N (R ^102Z4 ) ₂ , -NHCOOR ^102Z4 , -OCON (R ^102Z4 ) ₂ , halogen atom, -SO ₃ M, -CO ₂ M will be described.

-CO-R ^102Z4 includes formyl group; acetyl group, propanoyl group, butanoyl group, 2,2-dimethylpropanoyl group, pentanoyl group, hexanoyl group, (2-ethyl) hexanoyl group, heptanoil group, octanoyl group, nonanoyl. Derivation of a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group, a decanoyl group, an undecanoyl group, a dodecanoyl group, a henicosanoyl group, a benzoyl group, etc., and a group represented by the above formula. It was derivatized with a chemical group (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), or the like. A group corresponding to -CO-R 102Z4 in the carbonyl group to which the group) is bonded (when the carbonyl group is an acyl group, the number of carbon atoms is 2 to 41) and the compounds shown in Tables 1Z4 to 20Z4, and a ^{special application.} In the compounds shown in Tables 1 to 966 of No. ^2017-016290 , a group corresponding to −CO-R 102Z4 and the like can be mentioned, preferably a hydrocarbon group having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms) or a hydrocarbon group. ^{Corresponds to -CO-R 102Z4} in the carbonyl group to which the derivatizing group is bonded (when the carbonyl group is an alkanoyl group, the number of carbon atoms is more preferably 2 to 12) and the compounds shown in Tables 1Z4 to 20Z4. Examples include the groups to be used.

-COO-R ^101Z4 includes methoxycarbonyl group, ethoxycarbonyl group, propoxycarbonyl group, tert-butoxycarbonyl group, butoxycarbonyl group, pentyloxycarbonyl group, hexyloxycarbonyl group, (2-ethyl) hexyloxycarbonyl group, Heptyloxycarbonyl group, octyloxycarbonyl group, nonyloxycarbonyl group, decyloxycarbonyl group, undecyloxycarbonyl group, dodecyloxycarbonyl group, phenyloxycarbonyl group, icosyloxycarbonyl group, etc., and represented by the above formula. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or an inducing group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon In the oxycarbonyl group to which an alkylsulfamoyl group (preferably a group derivatized with an octylsulfamoyl group) of numbers 1 to 10 (preferably a group derivatized by an octylsulfamoyl group) or the like is bonded, and in the compounds shown in Tables 1Z4 to 20Z4, -COO-R ^102Z4 Examples of the relevant group and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. ^2017-016290 include the group corresponding to -COO-R 102Z4, and preferably a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof. Examples thereof include an oxycarbonyl group to which is bonded and a group corresponding to ^{-COO-R 102Z4 in the compounds shown in Tables 1Z4 to 20Z4.}

-OCO-R ^102Z4 includes formyloxy group; acetoxy group, propanoyloxy group, butanoyloxy group, 2,2-dimethylpropanoyloxy group, pentanoyloxy group, hexanoyloxy group, (2-ethyl). Hexanoyloxy group, heptanoiloxy group, octanoyloxy group, nonanoyloxy group, decanoyloxy group, undecanoyloxy group, dodecanoyloxy group, henikosanoyloxy group, benzoyloxy group, etc., and the above formula. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or an inducible group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, or a halogen (preferably a chlorine atom). ), A carbonyloxy group to which an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably a group derived from an octylsulfamoyl group) or the like is bonded (when the carbonyloxy group is an acyloxy group, the number of carbon atoms is 2 to 41), ^{and the groups corresponding to -OCO-R 102Z4} in the compounds shown in Tables 1Z4 to 20Z4 and -OCO-R 102Z4 in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. ^2017-016290. Examples of the group corresponding to the above, preferably a hydrocarbon group having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms) or a carbonyloxy group to which an inducible group thereof is bonded (the carbonyloxy group is referred to as an acyloxy group). In this case, the number of carbon atoms is more preferably 2 to 12), and in the compounds shown in Tables 1Z4 to ^20Z4 , groups corresponding to -OCO-R 102Z4 and the like can be mentioned.

-COCO-R ^102Z4 includes methyloxalyl group, ethyloxalyl group, propyloxalyl group, butyloxalyl group, pentyloxalyl group, hexyloxalyl group, (2-ethyl) hexyloxalyl group, heptyloxalyl group, octyloxalyl group and nonyl. Oxalyl group, decyl oxalyl group, undecyl oxalyl group, dodecyl oxalyl group, icosyl oxalyl group, cyclopentyl oxalyl group, cyclohexyl oxalyl group, phenyl oxalyl group, p-tolyl oxalyl group and the like, and groups represented by the above formulas and the like. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), 1 to 1 carbon atoms. Oxalyl groups to which 10 alkylsulfamoyl groups (preferably groups derivatized with octylsulfamoyl groups) and the like are bonded, and groups corresponding to ^{-COCO-R 102Z4 in the compounds shown in Tables 1Z4 to 20Z4 and} Examples of the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290 include groups corresponding to ^{-COCO-R 102Z4.}

^{-OR 102Z4} includes hydroxy group; methoxy group, ethoxy group, propoxy group, isopropoxy group, butoxy group, isobutoxy group, sec-butoxy group, tert-butoxy group, pentyloxy group, hexyloxy group, heptyloxy. Group, octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, dodecyloxy group, (2-ethyl) hexyloxy group, icosyloxy group, 1-phenylethoxy group, 1-methyl-1-phenylethoxy group, phenyl Oxy group, 2,3-dimethylphenyloxy group, 2,4-dimethylphenyloxy group, 2,5-dimethylphenyloxy group, 2,6-dimethylphenyloxy group, 3,4-dimethylphenyloxy group, 3, 5-Dimethylphenyloxy group, 2,2-dicyanophenyloxy group, 2,3-dicyanophenyloxy group, 2,4-dicyanophenyloxy group, 2,5-dicyanophenyloxy group, 2,6-dicyanophenyloxy Group, 3,4-dicyanophenyloxy group, 3,5-dicyanophenyloxy group, 4-methoxyphenyloxy group, 2-methoxyphenyloxy group, 3-methoxyphenyloxy group, 4-ethoxyphenyloxy group, 2- A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as an ethoxyphenyloxy group, a 3-ethoxyphenyloxy group, etc., and a group represented by the above formula, or an inducing group thereof (for example, carboxy). A group derived from a group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), or the like is bonded. group corresponding to the -O-R ^102Z4 in group and compounds shown in Table 1Z4~ Table 20Z4 -O-R ^102Z4 Table 1-966 of the relevant group and Japanese Patent Application No. 2017-016290 to the compounds shown in the Examples thereof include an oxy group to which a hydrocarbon group having 1 to 10 carbon atoms or an inducible group thereof is bonded, and a group corresponding to ^{-OR 102Z4 in the compounds shown in Tables 1Z4 to 20Z4.}

-SO _2- R ^101Z4 includes methyl sulfonyl group, ethyl sulfonyl group, propyl sulfonyl group, butyl sulfonyl group, pentyl sulfonyl group, hexyl sulfonyl group, (2-ethyl) hexyl sulfonyl group, heptyl sulfonyl group, octyl sulfonyl group, Nonylsulfonyl group, decylsulfonyl group, undecylsulfonyl group, dodecylsulfonyl group, icosylsulfonyl group, phenylsulfonyl group, p-tolylsulfonyl group, etc., and groups represented by the above formula, etc. have 1 to 40 carbon atoms (1 to 40 carbon atoms). A hydrocarbon group having 1 to 20 carbon atoms or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms). Sulfonyl groups to which (preferably octylsulfamoyl groups) and the like (preferably octylsulfamoyl groups) and the compounds shown in Tables 1Z4 to ^20Z4 _{correspond to -SO 2-} R 102Z4 and Japanese Patent Application No. 2017-016290. -SO ₂ in the compounds shown in Table 1~966 -R ^102Z4 relevant group and the like in, preferably a sulfonyl group and tables 1Z4~ bonded hydrocarbon radical or a derivatized group having 1 to 10 carbon atoms group corresponding to -SO ₂ -R ^102Z4 in the compounds shown in Table 20Z4 and the like.

-SO ₂ N (R ^102Z4 ) ₂ is a sulfamoyl group;
N-methylsulfamoyl group, N-ethylsulfamoyl group, N-propylsulfamoyl group, N-isopropylsulfamoyl group, N-butylsulfamoyl group, N-isobutylsulfamoyl group, N- sec-butyl sulfamoyl group, N-tert-butyl sulfamoyl group, N-pentyl sulfamoyl group, N- (1-ethylpropyl) sulfamoyl group, N-hexyl sulfamoyl group, N- (2-) Ethyl) Hexyl sulfamoyl group, N-heptyl sulfamoyl group, N-octyl sulfamoyl group, N-nonyl sulfamoyl group, N-decyl sulfamoyl group, N-undecyl sulfamoyl group, N- One carbon number 1 to 40 (preferably 1 to 20) of one group such as dodecylsulfamoyl group, N-icosylsulfamoyl group, N-phenylsulfamoyl group, and a group represented by the above formula. (For example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably octyl sulfamoyl group). ) Etc.) substituted sulfamoyl groups and the compounds shown in Tables 1Z4 to 20Z4 -SO ₂ NH (R ^102Z4X ) (where R ^102Z4X does not become a hydrogen atom, except that R ^102Z4 -SO ₂ NH (R ^102Z4X) (provided that the compounds shown in Table 1 to 966 of the corresponding group and Japanese Patent Application No. 2017-016290 the same as is) and, except that R ^102Z4X is not a hydrogen atom, R ^102Z4 (Same as))

N, N-dimethylsulfamoyl group, N, N-ethylmethylsulfamoyl group, N, N-diethylsulfamoyl group, N, N-propylmethylsulfamoyl group, N, N-dipropylsulfamoyl Group, N, N-isopropylmethylsulfamoyl group, N, N-diisopropylsulfamoyl group, N, N-tert-butylmethylsulfamoyl group, N, N-diisobutylsulfamoyl group, N, N- Disec-butyl sulfamoyl group, N, N-ditert-butyl sulfamoyl group, N, N-butylmethyl sulfamoyl group, N, N-dibutyl sulfamoyl group, N, N-dipentyl sulfa Moyl group, N, N-di (1-ethylpropyl) sulfamoyl group, N, N-dihexyl sulfamoyl group, N, N-di (2-ethyl) hexyl sulfamoyl group, N, N-diheptylsul Famoyl group, N, N-octylmethylsulfamoyl group, N, N-dioctylsulfamoyl group, N, N-dinonyl sulfamoyl group, N, N-decylmethylsulfamoyl group, N, N- Undecylmethyl sulfamoyl group, N, N-dodecylmethyl sulfamoyl group, N, N-icosylmethyl sulfamoyl group, N, N-phenylmethyl sulfamoyl group, N, N-diphenyl sulfamoyl Two hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group and a group represented by the above formula or a derivatizing group thereof (for example, a carboxy group, a sulfo group, a nitro group, etc. Sulfamoyl groups substituted with hydroxy groups, halogens (preferably chlorine atoms), alkylsulfamoyl groups having 1 to 10 carbon atoms (preferably octylsulfamoyl groups), etc.) and sulfamoyl groups and Tables 1Z4 to Tables 1Z4. In the compounds shown in 20Z4, _{the groups corresponding to -SO 2} N (R ^102Z4X ) ₂ (however, R ^{102Z4X is the same as R 102Z4} except that it does not become a hydrogen atom) and Table 1 of Japanese Patent Application No. 2017-016290. Among the compounds shown in ~ 966, groups corresponding to −SO ₂ N (R ^102Z4X ) ₂ (however, R ^{102Z4X is the same as R 102Z4} except that it does not become a hydrogen atom) can be mentioned.
Preferably, it corresponds to _{-SO 2} N (R 102Z4) ₂ in the sulfamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or an inducible group thereof and the compounds shown in Tables 1Z4 to ^20Z4. The group etc. can be mentioned.

^-CON (R 102Z4) ₂ is a carbamoyl group;
N-methylcarbamoyl group, N-ethylcarbamoyl group, N-propylcarbamoyl group, N-isopropylcarbamoyl group, N-butylcarbamoyl group, N-isobutylcarbamoyl group, N-sec-butylcarbamoyl group, N-tert-butylcarbamoyl group. Group, N-pentylcarbamoyl group, N- (1-ethylpropyl) carbamoyl group, N-hexylcarbamoyl group, N- (2-ethyl) hexylcarbamoyl group, N-heptylcarbamoyl group, N-octylcarbamoyl group and N- One of nonylcarbamoyl group, N-decylcarbamoyl group, N-undecylcarbamoyl group, N-dodecylcarbamoyl group, N-icosylcarbamoyl group, N-phenylcarbamoyl group and the like, and a group represented by the above formula. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), and 1 to 10 carbon atoms. -CONH (R ^102Z4X ) (where R ^{102Z4X is the same as R 102Z4} except that it does not become a hydrogen atom), and in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290, -CONH (R ^102Z4X ) (however, R ^102Z4X is It is the same as ^{R 102 Z4} except that it does not become a hydrogen atom).

N, N-dimethylcarbamoyl group, N, N-ethylmethylcarbamoyl group, N, N-diethylcarbamoyl group, N, N-propylmethylcarbamoyl group, N, N-dipropylcarbamoyl group, N, N-isopropylmethylcarbamoyl Group, N, N-diisopropylcarbamoyl group, N, N-tert-butylmethylcarbamoyl group, N, N-diisobutylcarbamoyl group, N, N-disec-butylcarbamoyl group, N, N-ditert-butylcarbamoyl group , N, N-butylmethylcarbamoyl group, N, N-dibutylcarbamoyl group, N, N-butyloctylcarbamoyl group, N, N-dipentylcarbamoyl group, N, N-di (1-ethylpropyl) carbamoyl group, N , N-dihexylcarbamoyl group, N, N-di (2-ethyl) hexylcarbamoyl group, N, N-diheptylcarbamoyl group, N, N-octylmethylcarbamoyl group, N, N-dioctylcarbamoyl group, N, N -Dinonylcarbamoyl group, N, N-decylmethylcarbamoyl group, N, N-undecylmethylcarbamoyl group, N, N-dodecylmethylcarbamoyl group, N, N-icosylmethylcarbamoyl group, N, N-phenylmethyl Two hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a carbamoyl group, an N, N-diphenylcarbamoyl group, etc., and a group represented by the above formula, or an inducing group thereof (for example, 1 to 20 carbon atoms). Substituted with a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably a group derived with an octyl sulfamoyl group), or the like). ^{Carbamoyl groups and the groups corresponding to -CON} (R 102Z4X) ₂ in the compounds shown in Tables 1Z4 to 20Z4 (however, R ^102Z4X is the same as R 102Z4 except that it does not become a hydrogen atom) and the ^{special application.} In the compounds shown in Tables 1 to 966 of No. 2017-016290, ^{groups corresponding to −CON} (R 102Z4X) ₂ (however, R ^{102Z4X is the same as R 102Z4} except that it does not become a hydrogen atom) can be mentioned. ,
Preferably, a carbamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or an inducible group thereof, and a group corresponding to ^-CON (R 102Z4) _{2 in the compounds shown in Tables 1Z4 to 20Z4 and the like.} Can be mentioned.

-N (R ^102Z4 ) ₂ is an amino group;
N-methylamino group, N-ethylamino group, N-propylamino group, N-isopropylamino group, N-butylamino group, N-isobutylamino group, N-sec-butylamino group, N-tert-butylamino Group, N-pentylamino group, N-hexylamino group, N- (2-ethyl) hexylamino group, N-heptylamino group, N-octylamino group, N-nonylamino group, N-decylamino group, N-un A decylamino group, an N-dodecylamino group, an N-icosylamino group, an N-phenylamino group, etc., and a group represented by the above formula, etc., which have 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms). A hydrocarbon group or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group)). ^{-NH (R 102Z4X} ) (however, R ^102Z4X is the same as ^{R 102Z4} except that it does not become a hydrogen atom in the amino groups substituted with (groups induced by etc.) and the compounds shown in Tables 1Z4 to 20Z4. ^{-NH (R 102Z4X} ) in the groups corresponding to (there is) and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290 (however, R ^102Z4X is the same as ^{R 102Z4} except that it does not become a hydrogen atom). Group corresponding to;

N, N-dimethylamino group, N, N-ethylmethylamino group, N, N-diethylamino group, N, N-propylmethylamino group, N, N-dipropylamino group, N, N-isopropylmethylamino group , N, N-diisopropylamino group, N, N-tert-butylmethylamino group, N, N-diisobutylamino group, N, N-disec-butylamino group, N, N-ditert-butylamino group, N, N-butylmethylamino group, N, N-dibutylamino group, N, N-dipentylamino group, N, N-di (1-ethylpropyl) amino group, N, N-dihexylamino group, N, N -Di (2-ethyl) hexylamino group, N, N-diheptylamino group, N, N-dioctylamino group, N, N-dinonylamino group, N, N-decylmethylamino group, N, N-undecyl Methylamino group, N, N-dodecylmethylamino group, N, N-icosylmethylamino group, N, N-phenylmethylamino group, N, N-diphenylamino group, etc., and groups represented by the above formulas. 2 hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or derivatizing groups thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon ^{-N (R 102Z4X} ) in amino groups substituted with an alkyl sulfamoyl group (preferably a group derivatized with an octyl sulfamoyl group) of numbers 1 to 10 and the compounds shown in Tables 1Z4 to 20Z4. ^{-N (R 102Z4X} ) _{2 in the groups corresponding to 2} (however, R ^{102Z4X is the same as R 102Z4} except that it does not become a hydrogen atom) and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290. (However, R ^102Z4X is the same as ^{R 102Z4} except that it does not become a hydrogen atom.)
Preferably, an amino group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or an inducible group thereof, and a group corresponding to ^{-N (R 102Z4} ) _{2 in the compounds shown in Tables 1Z4 to 20Z4 and the like.} Can be mentioned.

-NHCO-R ^102Z4 includes formylamino groups; acetylamino groups, propanoylamino groups, butanoylamino groups, 2,2-dimethylpropanoylamino groups, pentanoylamino groups, hexanoylamino groups, (2-ethyl). ) Hexanoylamino group, Heptanoylamino group, Octanoylamino group, Nonanoylamino group, Decanoylamino group, Undecanoylamino group, Dodecanoylamino group, Henikosanoylamino group, Bencoylamino group, etc. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group represented by the above formula or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, or a halogen (preferably). Is a chlorine atom), a carbonylamino group (a group derivatized with an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc.) is bonded (when the carbonylamino group is an acylamino group). , The number of carbon atoms is 1 to 40), and in the compounds shown in Tables 1Z4 to ^20Z4 , the group corresponding to -NHCO-R 102Z4 and in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290-NHCO- The groups corresponding to ^{R 102Z4 are listed.}
Preferably, a carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or an inducible group thereof is bonded (when the carbonylamino group is an alkanoylamino group, the carbon number is more preferably 1 to 10) and Table 1Z4. In the compounds shown in Table 20Z4, ^{groups corresponding to -NHCO-R 102Z4} and the like can be mentioned.

-NHCON (R ^102Z4 ) ₂ includes the groups listed above, the groups ^{corresponding to -NHCON (R 102Z4} ) ₂ in the compounds shown in Tables 1Z4 to 20Z4, and Tables 1 to 1 of Japanese Patent Application No. 2017-016290. Examples of the compound shown in 966 include a group corresponding to ^{-NHCON (R 102Z4} ) _2.

-NHCOOR ^102Z4 includes the groups listed above, the groups ^{corresponding to -NHCOOR 102Z4} in the compounds shown in Tables 1Z4 to 20Z4, and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290. ^Examples include groups corresponding to 102Z4.

-OCON (R ^102Z4 ) ₂ includes the groups listed above, the groups ^{corresponding to -OCON (R 102Z4} ) ₂ in the compounds shown in Tables 1Z4 to 20Z4, and Tables 1 to 1 of Japanese Patent Application No. 2017-016290. ^{Examples of the} compound shown in 966 include a group corresponding to -OCON (R 102Z4) _2.

As the halogen atom, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom and the like are preferable.
Examples of _{M of −SO 3} M and −CO ₂ M include hydrogen atom; alkali metal atom such as lithium atom, sodium atom and potassium atom, and preferably hydrogen atom, sodium atom and potassium atom.

-CO-R ^102Z4 , -COO-R ^102Z4 , -OCO-R ^102Z4 , -COCO-R ^102Z4 , -O-R ^102Z4 , -SO _2- R ^102Z4 , -SO ₂ N (R ^102Z4 ) ₂ , -CON Substituents (first substituents) contained in (R ^102Z4 ) ₂ , -N (R ^102Z4 ) ₂ , -NHCO-R ^102Z4 , -NHCON (R ^102Z4 ) ₂ , -NHCOOR ^102Z4 , -OCON (R ^102Z4 ) _2. May be one or more, and the two or more substituents may be the same or different independently of each other.
Further, the first substituent may have another substituent (second substituent) bonded to the hydrocarbon group contained in a part thereof. The second substituent can be selected from the same groups as the first substituent.

The ^{rings formed by R 2Z4} and R ^3Z4 , R ^3Z4 and R ^4Z4 , and R ^4Z4 and R ^5Z4 are condensed with the benzene ring of the isoindoline skeleton of the compound represented by the formula (IZ4). The fused ring structures of the ring formed by R ^2Z4 and R ^3Z4 , R ^3Z4 and R ^4Z4 , and R ^4Z4 and R ^5Z4 and the benzene ring include inden, naphthalene, biphenylene, indacene, ashenanthrene, fluorene, phenanthrene, and phenanthrene. Hydrocyclic condensed ring structures such as anthracene, fluorantene, acephenanthrene, aceanthrene, triphenylene, pyrene, chrysene, N-methylphthalimide, N- (1-phenylethyl) phthalimide and tetracene, and their partial reductions ( For example, 9,10-dihydroanthracene, 1,2,3,4-tetrahydronaphthalene); indol, isoindole, indazole, quinoline, isoquinoline, phthalazine, quinoxaline, quinazoline, cinnoline, carbazole, carboline, phenanthrene, aclysine. , Perimidine, phenanthrene, phenazine and the like nitrogen-containing condensed heterocycles and their partial reductions; oxygen-containing condensation heterocycles such as 3-hydrobenzofuran 2-one and their partial reductions.

When R ^2Z4 and R ^3Z4 , R ^3Z4 and R ^4Z4 , and R ^4Z4 and R ^5Z4 form a ring, the ring may have a substituent. As the substituent, the hydrocarbon groups represented by R ^N1Z4 , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^{101 Z4} and R ^{102 Z4} are contained. The same as a good substituent can be mentioned. Preferred substituents include hydrocarbon groups represented by ^{R N1Z4} , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^{101 Z4} and R ^{102 Z4.} Examples include the same preferred substituents that may be used.

When R ^{3Z 4} and R 4 ^{Z 4} form a ring, R ^{2Z 4} and R ^{5Z 4} are preferably hydrogen atoms, amino groups and hydroxy groups independently of each other.
If R ^2Z4 and R ^3Z4 form a ring, it is preferable that the R ^4Z4 and R ^5Z4 do not form a ring, and more preferably R ^4Z4 and R ^5Z4 is a hydrogen atom.
In the case where R ^4Z4 and R ^5Z4 form a ring, it is preferable that the R ^2Z4 and R ^3Z4 do not form a ring, and more preferably R ^2Z4 and R ^3Z4 is a hydrogen atom.

In the present invention, R ^1Z4 , R ^6Z4 and R ^7Z4 are preferably hydrogen atoms.

In the present invention, ^RN1Z4 and ^RN2Z4 are independent of each other, -CO-R ^102Z4 , -COO-R ^101Z4 , -CON (R ^102Z4 ) ₂ , -N (R ^102Z4 ) ₂ , -CO ₂ M or substituents. It is preferably a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, and more preferably a hydrocarbon group having 1 to 30 carbon atoms which may have a substituent. A hydrocarbon group having 1 to 20 carbon atoms which may have a substituent is more preferable, and a hydrocarbon group having 1 to 15 carbon atoms which may have a substituent is particularly preferable, and may have a substituent. A hydrocarbon group having 1 to 10 carbon atoms is even more preferable, and a hydrocarbon group having 1 to 6 carbon atoms which may have a substituent or a hydrocarbon having 1 to 5 carbon atoms which may have a substituent may be used. A group is particularly preferable, a methyl group, an ethyl group, or a phenyl group is particularly preferable, and a methyl group or an ethyl group is most preferable. Further, ^RN1Z4 and ^RN2Z4 may be the same group or different groups, but are preferably the same group.

^{At least one of R 2Z4} , R ^3Z4 , R ^4Z4 , and R ^5Z4 is -CO-R ^102Z4 , -COO-R ^101Z4 , -from the viewpoint of reducing the phase difference value of the color filter prepared from the coloring composition. OCO-R ^102Z4 , -COCO-R ^102Z4 , -O-R ^102Z4 , -SO _2- R ^101Z4 , -SO ₂ N (R ^102Z4 ) ₂ ^{, -CON} (R 102Z4) ₂ , -N (R ^102Z4 ) ₂ , -NHCO-R ^102Z4 , -NHCO-N (R ^102Z4 ) ₂ , -NHCOOR ^102Z4 , -OCON (R ^102Z4 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, substituent It is preferably a hydrocarbon group having 1 to 40 carbon atoms or a heterocyclic group which may have a substituent.
A hydrocarbon group having 1 to 40 carbon atoms, which may have a substituent, a halogen atom, -N (R ^102Z4 ) ₂ , a nitro group, and a hydrogen atom in which all or a part of the hydrocarbon atom is substituted with a fluorine atom has 1 to 1 carbon atoms. More preferably, there are 20 hydrocarbon groups, -NHCO-R ^102Z4 , ^{-OR 102Z4} , -SO ₃ M or -CO _{2 M.}
It is more preferably a hydrocarbon group having 1 to 40 carbon atoms which may have a nitro group or a substituent, and even more preferably a nitro group or a tert-butyl group. Alternatively, at least one set of ^{R 2Z 4} and R ^{3Z 4} , R ^{3Z 4} and R ^{4Z 4} , or R 4 ^{Z 4} and R 5 ^{Z 4 preferably forms a ring.}

From the viewpoint of reducing the phase difference value of the color filter prepared from the coloring composition ^{, at least one of R 2Z4} , R ^3Z4 , R ^4Z4 , and R ^5Z4 may have a substituent and has 1 to 40 carbon atoms. Hydrocarbon group, halogen atom, -N (R ^102Z4 ) ₂ , nitro group, hydrocarbon group with 1 to 20 carbon atoms in which all or part of the hydrogen atom is replaced by a fluorine atom, -NHCO-R ^102Z4 , -O It is preferably −R ^102Z4 , −SO ₃ M or −CO ₂ M, more preferably a hydrocarbon group having 1 to 40 carbon atoms which may have a nitro group or a substituent, and a nitro group or Even more preferably, it is a tert-butyl group. Particularly preferably, R ^3Z4 is a nitro group or a tert-butyl group and R ^2Z4 , R ^4Z4 and R ^5Z4 are hydrogen atoms, or R ^2Z4 , R ^3Z4 and R ^5Z4 are hydrogen atoms and R ^4Z4. Is a nitro group or a tert-butyl group.

Specific examples of the compound (IZ4) include compounds (IZ4-1) to compounds (IZ4-769) having substituents shown in Tables 1Z4 to 20Z4 or alkali metal salts thereof in the formula (IZ4-aa). Can be mentioned.
B ^a1Z4 B ^a2Z4 is a formula (BB1) to a formula (BB60), a formula (BBK2), a formula (BBK3), a formula (BBK4), a formula (BBK14), a formula (BBI1), a formula (BBO8), a formula (BBO10). , Represents any of the partial structures represented by the formula (BBD1) and the formula (BBJ2). Formulas (BB1) to formulas (BB60), formulas (BBK2), formulas (BBK3), formulas (BBK4), formulas (BBK14), formulas (BBI1), formulas (BBO8), formulas (BBO10), formulas (BBD1) and ^{The formula (BBJ2) represents B a1Z1} B ^a2Z1 of the formula (IZ1-aa) (BB1) to (BB60), the formula (BBK2), the formula (BBK3), the formula (BBK4), the formula (BBK14), the formula (BBI1). ), Equation (BBO8), Equation (BBO10), Equation (BBD1) and Equation (BBJ2). B ^a1Z4 and B ^a2Z4 represent a bond, respectively, and B ^a1Z4 is a formula (BB1) to a formula (BB60), a formula (BBK2), a formula (BBK3), a formula (BBK4), a formula (BBK14), a formula (BBI1). , formula (BBO8), formula (BBO10), formula (BBD1) and becomes a bond B ^A2Z4 is B ² when a bond of B ¹ of formula ^(BBJ2), B a1Z4 the expression (BB1) ~ formula (BB6
0), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1), formula (BBO8), formula (BBO10), formula (BBD1) and formula (BBJ2) B ^{2 B a2 Z4} is the bond of ^{B 1} when it is the bond of B 1.
B ^a1Z4 B ^a2Z4 includes the formula (BB1), the formula (BB6), the formula (BB8), the formula (BB11), the formula (BB14), the formula (BB19), the formula (BB37), the formula (BB58), and the formula (BBJ2). ), Formula (BBO8) and formula (BBO10) are preferable, and formula (BB1), formula (BB6) and formula (BB19) are more preferable.

Each symbol in Tables 1Z4 to 20Z4 represents the following partial structure. In addition, in the partial structure
"Me" represents a methyl group
"Et" represents an ethyl group
"Bu" represents a butyl group
"TBu" represents a tert-butyl group and represents
"Hex" represents a hexyl group
"Oct" represents an octyl group
"2EH" represents a 2-ethylhexyl group and represents
"CHM" represents a cyclohexylmethyl group
"CH" represents a cyclohexyl group
"PH" represents a phenyl group
"BZ" represents a benzyl group
"NPR" represents a propyl group
"IPR" represents an isopropyl group
"IBu" represents an isobutyl group and represents
"EOE" stands for −CH ₂ CH ₂ OCH ₂ CH ₃
"ALL" represents an allyl group
"HYE" represents a 2-hydroxyethyl group
"COM" stands for -CO-CH ₃
"COE" stands for -COO-CH ₂ CH ₃
"OCM" stands for -OCO-CH ₃
"OME" stands for -O-CH ₃ and represents
"SOT" represents a tosyl group
“SNH” stands for −SO ₂ NH-CH ₂ CH (CH ₂ CH ₃ ) ((CH ₂ ) ₃ CH ₃ ).
“SN2” stands for −SO ₂ N (CH ₃ ) ((CH ₂ ) ₇ CH ₃ ).
"CNM" stands for -CONHCH ₃
"CN2" stands for -CON (CH ₃ ) C ₆ H ₅ and represents
"NPH" stands for -NHC ₆ H ₅ and represents
"NOT" stands for -N ((CH ₂ ) ₇ CH ₃ ) ₂
"NCO" stands for -NHCO ((CH ₂ ) ₄ CH ₃ )
"F" represents a fluorine atom
"Cl" represents a chlorine atom
"Br" represents a bromine atom
"CN" represents a cyano group
"NO2" represents a nitro group
"SUA" stands for -SO ₃ H
"CBA" stands for -CO ₂ H and represents
"CHO" stands for -CHO
"OCH" stands for -OCOH
"OH" stands for -OH
"SFM" stands for -SO ₂ NH ₂
"CBM" stands for -CONH _{2
"NH 2} " stands for -NH 2
"NCH" represents -NHCOH.
In the partial structure shown by the following formula, * represents a bond.

For example, the compound (IZ4-1) is a compound represented by the formula (IZ4-1).

As a compound (IZ4),
Compound (IZ4-1) to compound (IZ4-234) and compound (IZ4-321) to compound (IZ4-769) are preferable.
Compound (IZ4-1) to compound (IZ4-234) and compound (IZ4-321) to compound (IZ4-711) are more preferable.
Compounds (IZ4-1) to compounds (IZ4-234) are more preferred.
Compounds (IZ4-1) to compounds (IZ4-174) are even more preferred.
Compounds (IZ4-1) to compounds (IZ4-117) are particularly preferred.
Compound (IZ4-1) to compound (IZ4-2), compound (IZ4-40) to compound (IZ4-41), and compound (IZ4-79) to compound (IZ4-80) are particularly preferable.

Specific examples of the compound (IZ4) include compounds in which 1 to 3 hydrogen atoms contained in the compounds shown in Tables 1Z4 to 20Z4 are substituted with _{-SO 3} M or -CO _{2 M.} For example, a compound in which 1 to 3 sulfo groups are bonded to the compound (IZ4-1) in Table 1Z4 is represented by the following structure. However, in the formula, − (SO ₃ H) means that any hydrogen atom of the compound (IZ4-1) in Table 1Z4 is substituted.

In the present invention
Compounds (IZ4-1) to compound (IZ4-234) and compounds (IZ4-321) to compound (IZ4-769) to which 1 to 3 -SO ₃ M or -CO ₂ M are bound are preferable. ,
Compound (IZ4-1) to compound (IZ4-234) and compound (IZ4-321) to compound (IZ4-711) to which 1 to 3 -SO ₃ M or -CO ₂ M are bound are more. Preferably
_{Compounds in which 1 to 3 -SO 3} M or -CO ₂ M are bound to compound (IZ4-1) to compound (IZ4-234) are more preferable.
Compounds (IZ4-1) to compounds (IZ4-174) to which 1 to 3 -SO ₃ M or -CO ₂ M are bound are even more preferable.
_{Compounds in which 1 to 3 -SO 3} M or -CO ₂ M are bound to compound (IZ4-1) to compound (IZ4-117) are particularly preferable.
Compound (IZ4-1) to compound (IZ4-2), compound (IZ4-40) to compound (IZ4-41), and compound (IZ4-79) to compound (IZ4-80) have 1 to 3 − Compounds to which SO ₃ M or -CO ₂ M are bound are particularly preferred.

As the compound (IZ4), in the formula (IZ4),
R ^N1Z4 and R ^N2Z4 are substituents selected independently of each other from ^{the group consisting of} -CO-R 102Z4, -COO-R ^101Z4 , -CON (R ^102Z4 ) ₂ , or -SO ₃ M and -CO ₂ M. It is a hydrocarbon group having 1 to 20 carbon atoms which may have.
R ^1Z4 is a hydrocarbon group having 1 to 20 carbon atoms, which may have a substituent selected from the group consisting of a hydrogen atom, -SO ₃ M and -CO _{2 M, -SO 3} M or -CO ₂ M and
In R ^{2Z4 to} R ^5Z4 , hydrogen atom, hydrocarbon group having 1 to 20 carbon atoms, halogen atom, -N (R 102Z4) ₂ , nitro group, and all or part of hydrogen atom are independently ^{composed of hydrogen atom.} Substituted hydrocarbon groups with 1 to 20 carbon atoms, -NHCO-R ^102Z4 , ^{-OR 102Z4} , -SO ₃ M or -CO ₂ M.
R ^6Z4 and R ^7Z4 are independent of each other and may have a substituent selected from the group consisting of a hydrogen atom, −SO ₃ M and −CO ₂ M, a hydrocarbon group having 1 to 20 carbon atoms, −. SO ₃ M or -CO ₂ M,
R ^102Z4 is a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent selected from the group consisting of _{-SO 3} M and -CO _{2 M.}
R ^101Z4 is a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent selected from the group consisting of _{-SO 3} M and -CO _{2 M.}
M is preferably a compound which is a hydrogen atom or an alkali metal atom.
Even if ^RN1Z4 and ^RN2Z4 independently have substituents selected from the group consisting of -CO-R ^102Z4 , -CON (R ^102Z4 ) ₂ , or -SO ₃ M and -CO _{2 M.} It is a good hydrocarbon group with 1 to 10 carbon atoms.
R ^1Z4 is a hydrogen atom
In R ^{2Z4 to} R ^5Z4 , hydrogen atom, hydrocarbon group having 1 to 10 carbon atoms, halogen atom, -N (R 102Z4) ₂ , nitro group, and all or part of hydrogen atom are independently ^{composed of hydrogen atom.} Substituted hydrocarbon groups with 1 to 10 carbon atoms, -NHCO-R ^102Z4 , ^{-OR 102Z4} , -SO ₃ M or -CO ₂ M.
R ^6Z4 and R ^7Z4 are hydrocarbons with 1 to 10 carbon atoms that are the same group and may have a hydrogen atom or a substituent selected from the group consisting of _{-SO 3} M and -CO _{2 M.} Is the basis and
R ^102Z4 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of _{-SO 3} M and -CO _{2 M.}
R ^101Z4 is a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of _{-SO 3} M and -CO _{2 M.}
M is more preferably a compound which is a hydrogen atom or an alkali metal atom.
Even if ^RN1Z4 and ^RN2Z4 independently have substituents selected from the group consisting of -CO-R ^102Z4 , -CON (R ^102Z4 ) ₂ , or -SO ₃ M and -CO _{2 M.} It is a good hydrocarbon group with 1 to 10 carbon atoms.
R ^1Z4 is a hydrogen atom
R ^{2Z4 to} R ^5Z4 are independently hydrogen atom, hydrocarbon group having 1 to 10 carbon atoms, halogen atom, -N (R ^102Z4 ) ₂ , nitro group, trifluoromethyl group, ^{-OR 102Z4} , respectively. -SO ₃ M or -CO ₂ M,
R ^6Z4 and R ^7Z4 are the same group, a hydrogen atom, or a hydrocarbon group having 1 to 10 carbon atoms.
R ^102Z4 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of _{-SO 3} M and -CO _{2 M.}
R ^101Z4 is a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of _{-SO 3} M and -CO _{2 M.}
M is more preferably a compound which is a hydrogen atom or an alkali metal atom.

As for the compound (IZ4), when R ^1Z4 is a hydrogen atom, a compound represented by the formula (pt1Z4) (hereinafter, may be referred to as a phthalonitrile compound) is referred to as a compound represented by the formula (pt2Z4) (hereinafter, referred to as an alkoxide compound). After reacting with (in some cases), the compound represented by the formula (pt3Z4) and the compound represented by the formula (pt4Z4) can be further reacted in the presence of an acid to produce the compound. When R ^1Z4 is other than a hydrogen atom, the compound (IZ4) can be produced by further reacting with a compound represented by the formula (pt5Z4).

[In formula (pt1Z4), formula (pt2Z4), formula (pt3Z4), formula (pt4Z4), formula (pt5Z4) and formula (IZ4), R ^N1Z4 , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , and R ^7Z4 have the same meanings as described above.
R ^14Z4 represents an alkyl group having 1 to 20 carbon atoms.
M ^1Z4 represents an alkali metal atom.
LG represents a halogen atom, a methanesulfonyloxy group, a toluenesulfonyloxy group or a trifluoromethanesulfonyloxy group. ]

^Examples of the alkyl group having 1 to 20 carbon atoms represented by R 14Z4 include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, a sec-butyl group and a tert-butyl group, which are preferable. Examples include alkyl groups having 1 to 6 carbon atoms.
Examples of the alkali metal atom represented by M ^{1Z 4} include a lithium atom, a sodium atom and a potassium atom.

The amount of the alkoxide compound used is usually 0.1 to 10 mol, preferably 0.2 to 5 mol, and more preferably 0.3 to 3 mol, based on 1 mol of the phthalonitrile compound. More preferably, it is 0.4 to 2 mol.

The amount of the compound (pt3Z4) used is usually 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, still more preferably 1 mol, relative to 1 mol of the phthalonitrile compound. ~ 2 mol.
The amount of the compound (pt4Z4) used is usually 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, still more preferably 1 mol, relative to 1 mol of the phthalonitrile compound. ~ 2 mol.

Examples of the acid include inorganic acids such as hydrochloric acid, hydrobromic acid, hydroiodic acid, sulfuric acid, nitric acid, fluorosulfonic acid and phosphoric acid; sulfonic acids such as methanesulfonic acid, trifluoromethanesulfonic acid and p-toluenesulfonic acid; Examples thereof include carboxylic acids such as acetic acid, citric acid, formic acid, gluconic acid, lactic acid, oxalic acid and tartrate acid, preferably hydrochloric acid, hydrobromic acid, sulfuric acid, methanesulfonic acid, trifluoromethanesulfonic acid, p-toluenesulfonic acid and Examples include carboxylic acids, more preferably acetic acids.
The amount of the acid used is usually 1 to 20 mol, preferably 1 to 10 mol, more preferably 1 to 8 mol, still more preferably 1 to 6 mol, based on 1 mol of the phthalonitrile compound. be.

The reaction of the phthalonitrile compound, the alkoxide compound, the compound (pt3Z4) and the compound (pt4Z4) is usually carried out in the presence of a solvent.
As the solvent, water; a nitrile solvent such as acetonitrile; an alcohol solvent such as methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol and 1-octanol; an ether solvent such as tetrahydrofuran; a ketone solvent such as acetone; acetic acid. Ester solvents such as ethyl; aliphatic hydrocarbon solvents such as hexane; aromatic hydrocarbon solvents such as toluene; halogenated hydrocarbon solvents such as methylene chloride and chloroform; amides such as N, N-dimethylformaldehyde and N-methylpyrrolidone. Solvents: Sulfoxide solvents such as dimethylsulfoxide, preferably water, nitrile solvents, alcohol solvents, ether solvents, ketone solvents, ester solvents, aromatic hydrocarbon solvents, halogenated hydrocarbon solvents, amide solvents and sulfoxide solvents. More preferably, water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, tetrahydrofuran, acetone, ethyl acetate, toluene, methylene chloride, chloroform, N, N-dimethylformaldehyde. , N-Methylpyrrolidone and dimethylsulfoxide, more preferably water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, acetone, methylene chloride, chloroform, N, N. -Dimethylformaldehyde, N-methylpyrrolidone and dimethylsulfoxide are mentioned, and water, acetonitrile, methanol, ethanol and 2-propanol are particularly preferable.
The amount of the solvent used is usually 1 to 1000 parts by mass with respect to 1 part by mass of the phthalonitrile compound.

The reaction temperature is usually 0 to 200 ° C, preferably 0 to 100 ° C, more preferably 0 to 70 ° C, still more preferably 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

The amount of the compound (pt5Z4) used is usually 1 to 10 mol, preferably 1 to 5 mol, and more preferably 1 to 3 mol, relative to 1 mol of the compound (IZ4) in which ^{R 1Z4 is a hydrogen atom.} It is more preferably 1 to 2 mol.

When the compound (pt5Z4) is reacted, it is preferable that a base coexists. Bases include organic bases such as triethylamine, 4- (N, N-dimethylamino) pyridine, pyridine and piperidine; metal alkoxides such as sodium methoxide, sodium ethoxide, sodium tert-butoxide and potassium tert-butoxide; butyl lithium. , Tert-Organic metal compounds such as butyllithium and phenyllithium; and inorganic bases such as lithium hydroxide, sodium hydroxide and potassium hydroxide.

The amount of the base used is usually 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, and further, with respect to 1 mol of the compound (IZ4) in which ^{R 1Z4 is a hydrogen atom.} It is preferably 1 to 2 mol.

The reaction of compound (pt5Z4) is usually carried out in the presence of a solvent. The solvent can be selected from the same range as described above.
The amount of the solvent used is usually 1 to 1000 parts by mass with respect to 1 part by mass of the compound (IZ4) in which ^{R 1Z4 is a hydrogen atom.} The reaction temperature of the compound (pt5Z4) is usually −90 to 200 ° C., preferably −80 to 100 ° C., and more preferably 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

If compound (IZ4) _{does not have a sulfo group or -SO 3} M ²² , the compound (IZ 4) is reacted with a sulphonizing agent such as fuming sulfuric acid or chlorosulfuric acid to cause a sulfo group or -SO ₃ M ^22. Can be introduced.
M ²² represents an alkali metal atom.
Examples ^{of the alkali metal atom represented by M 22} include a lithium atom, a sodium atom and a potassium atom.

_{The amount of SO 3} used in fuming sulfuric acid is usually 1 to 50 mol, preferably 5 to 40 mol, more preferably 5 to 30 mol, still more preferably 5 to 30 mol, per 1 mol of compound (IZ4). It is 5 to 25 mol.
The amount of sulfuric acid used in fuming sulfuric acid is usually 1 to 200 mol, preferably 10 to 100 mol, more preferably 10 to 75 mol, and further preferably 10 to 1 mol of compound (IZ4). ~ 50 mol.

The amount of chlorosulfonic acid used is usually 1 to 500 mol, preferably 10 to 300 mol, more preferably 10 to 200 mol, still more preferably 10 to 150 mol, relative to 1 mol of compound (IZ4). It is a mole.

The reaction temperature for sulfonation is usually -20 to 200 ° C, preferably -10 to 100 ° C, and more preferably 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

The method for extracting the compound (IZ4) from the reaction mixture is not particularly limited, and the compound (IZ4) can be extracted by various known methods. For example, after completion of the reaction, the compound (IZ4) can be taken out by filtering the reaction mixture. Further, after filtration, the obtained residue may be subjected to column chromatography, recrystallization or the like. Further, after completion of the reaction, the solvent of the reaction mixture may be distilled off and then purified by column chromatography.

<Compound (IZ5)>
Compound (IZ5) is represented by the formula (IZ5).

[In formula (IZ5),
R ^N1Z5 is -CO-R ^102Z5 , -COO-R ^101Z5 , -OCO-R ^102Z5 , -COCO-R ^102Z5 , -O-R ^102Z5 , -SO _2- R ^101Z5 , -SO ₂ N (R ^102Z5 ) ₂ ^{, -CON} (R 102Z5) ₂ , -N (R ^102Z5 ) ₂ , -NHCO-R ^102Z5 , -NHCO-N (R ^102Z5 ) ₂ , -NHCOOR ^102Z5 , -OCON (R ^102Z5 ) ₂ , halogen atom, cyano group , Nitro group, -SO ₃ M, -CO ₂ M, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
^{R 1Z5, R 2Z5, R 3Z5} , R 4Z5, R 5Z5, R 6Z5, and R ^7Z5, independently of each other, hydrogen ^{atom, -CO-R 102Z5, -COO-} R 101Z5, -OCO-R 102Z5, -COCO -R ^102Z5 , -O-R ^102Z5 , -SO ₂ -R ^101Z5 , -SO ₂ N (R ^102Z5 ) ₂ ^{, -CON} (R 102Z5) ₂ , -N (R ^102Z5 ) ₂ , -NHCO-R ^102Z5 ,- NHCO-N (R ^102Z5 ) ₂ , -NHCOOR ^102Z5 , -OCON (R ^102Z5 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, carbon which may have a substituent ^{Represents a} heterocyclic group which may have a hydrocarbon group or a substituent of the number 1 to 40, and R 2Z5 and R ^3Z5 , R ^3Z5 and R ^4Z5 , and R ^4Z5 and R ^5Z5 are bonded to each other and ring, respectively. , ^And at least one of ^{R 2Z5} , R ^3Z5 , R ^4Z5 and R ^{5Z5 is -CO-R 102Z5} , -COO-R ^101Z5 , -OCO-R ^102Z5 , -COCO-R ^102Z5 , -O. -R ^102Z5 , -SO ₂ -R ^101Z5 , -SO ₂ N (R ^102Z5 ) ₂ ^{, -CON} (R 102Z5) ₂ , -N (R ^102Z5 ) ₂ , -NHCO-R ^102Z5 , -NHCO-N (R ^102Z5) ) ₂ , -NHCOOR ^102Z5 , -OCON (R ^102Z5 ) ₂ , Halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, hydrocarbon with 1 to 40 carbon atoms which may have a substituent It is a heterocyclic group that may have a hydrogen group or a substituent, or ^{at least one set of R 2Z5} and R ^3Z5 , R ^3Z5 and R ^4Z5 , and R ^4Z5 and R ^5Z5 are bonded to form a ring. doing.
R ^101Z5 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102Z5 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
M represents a hydrogen atom or an alkali metal atom.
When a ^{plurality of R 101Z5} , R ^102Z5 and M are present, they may be the same or different.
The wavy line represents an E-form or a Z-form. ]

^{R N1Z5, R 1Z5, R 2Z5} , R 3Z5, R 4Z5, R 5Z5, R 6Z5, R 7Z5, R 101Z5 and the carbon number of the hydrocarbon group which may have a substituent represented by R ^102Z5 is It is 1 to 40, preferably 1 to 30, more preferably 1 to 20, still more preferably 1 to 15, particularly preferably 1 to 10, and even more preferably 1 to 5.

^{R N1Z5, R 1Z5, R 2Z5} , R 3Z5, R 4Z5, R 5Z5, R 6Z5, a hydrocarbon group of R ^7Z5, R ^101Z5 and C1-40 represented by R ^102Z5 is an aliphatic hydrocarbon group and It may be an aromatic hydrocarbon group, and the aliphatic hydrocarbon group may be saturated or unsaturated, or may be a chain or an alicyclic.

The ^{R N1Z5, R 1Z5, R 2Z5} , R 3Z5, R 4Z5, R 5Z5, R 6Z5, R 7Z5, saturated or unsaturated chain hydrocarbon group represented by R ^101Z5 and R ^102Z5, a methyl group, an ethyl group , Propyl group, butyl group, pentyl group, hexyl group, heptyl group, octyl group, nonyl group, decyl group, undecyl group, dodecyl group, heptadecyl group, octadecyl group, icosyl group and other linear alkyl groups; isopropyl group , Isobutyl group, sec-butyl group, tert-butyl group, (2-ethyl) butyl group, isopentyl group, neopentyl group, tert-pentyl group, (1-methyl) pentyl group, (2-methyl) pentyl group, ( Branched chain alkyl groups such as 1-ethyl) pentyl group, (3-ethyl) pentyl group, isohexyl group, (5-methyl) hexyl group, (2-ethyl) hexyl group and (3-ethyl) heptyl group, etc. Vinyl group, 1-propenyl group, 2-propenyl group (allyl group), (1-methyl) ethenyl group, 2-butenyl group, 3-butenyl group, 1,3-butadienyl group, (1- (2-propenyl) )) An alkenyl group such as an ethenyl group, a (1,2-dimethyl) propenyl group and a 2-pentenyl group; and the like. The saturated or unsaturated chain hydrocarbon group preferably has 1 to 30 carbon atoms, more preferably 1 to 20 carbon atoms, still more preferably 1 to 15 carbon atoms, and particularly preferably 1 to 10 carbon atoms. It is more preferably 1 to 8, and even more preferably 1 to 5. Of these, a linear or branched alkyl group having 1 to 10 carbon atoms, more preferably 1 to 8 carbon atoms is particularly preferable, and a methyl group, an ethyl group, and a tert-butyl group are particularly preferable.

R ^N1Z5, as the ^{R 1Z5, R 2Z5, R 3Z5} , R 4Z5, R 5Z5, R 6Z5, R 7Z5, saturated or unsaturated alicyclic hydrocarbon group represented by R ^101Z5 and R ^102Z5, cyclopropyl group, 1-methylcyclopropyl group, cyclobutyl group, cyclopentyl group, cyclohexyl group, cycloheptyl group, 1-methylcyclohexyl group, 2-methylcyclohexyl group, 3-methylcyclohexyl group, 4-methylcyclohexyl group, 1,2-dimethylcyclohexyl Group, 1,3-dimethylcyclohexyl group, 1,4-dimethylcyclohexyl group, 2,3-dimethylcyclohexyl group, 2,4-dimethylcyclohexyl group, 2,5-dimethylcyclohexyl group, 2,6-dimethylcyclohexyl group, 3,4-Dimethylcyclohexyl group, 3,5-dimethylcyclohexyl group, 2,2-dimethylcyclohexyl group, 3,3-dimethylcyclohexyl group, 4,4-dimethylcyclohexyl group, cyclooctyl group, 2,4,6- Cyclo such as trimethylcyclohexyl group, 2,2,6,6-tetramethylcyclohexyl group and 3,3,5,5-tetramethylcyclohexyl group, 4-pentylcyclohexyl group, 4-octylcyclohexyl group, 4-cyclohexylcyclohexyl group Alkyl group; cycloalkenyl group such as cyclohexenyl group (for example, cyclohex-2-ene, cyclohex-3-ene), cycloheptenyl group and cyclooctenyl group; norbornan group, adamantyl group, bicyclo [2.2.2] octane and the like. Be done. The saturated or unsaturated alicyclic hydrocarbon group preferably has 3 to 30, more preferably 3 to 20, even more preferably 4 to 20, and even more preferably 4 to 15. Yes, more particularly preferably 5 to 15, and most preferably 5 to 10. Of these, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, and a cyclooctyl group are particularly preferable.

The ^{R N1Z5, R 1Z5, R 2Z5} , R 3Z5, R 4Z5, R 5Z5, R 6Z5, R 7Z5, aromatic hydrocarbon groups represented by R ^101Z5 and R ^102Z5, phenyl, o- tolyl group, m -Trill group, p-tolyl group, 2-ethylphenyl group, 3-ethylphenyl group, 4-ethylphenyl group, 2,3-dimethylphenyl group, 2,4-dimethylphenyl group, 2,5-dimethylphenyl group , 2,6-dimethylphenyl group, 3,4-dimethylphenyl group, 3,5-dimethylphenyl group, 4-vinylphenyl group, o-isopropylphenyl group, m-isopropylphenyl group, p-isopropylphenyl group, o -Tert-butylphenyl group, m-tert-butylphenyl group, p-tert-butylphenyl group, mesityl group, 4-ethylphenyl group, 4-butylphenyl group, 4-pentylphenyl group, 2,6-bis ( 2-propyl) phenyl group, 4-cyclohexylphenyl group, 2,4,6-trimethylphenyl group, 4-octylphenyl group, 1-naphthyl group, 2-naphthyl group, 5,6,7,8-tetrahydro-1 Examples thereof include −naphthyl group, 5,6,7,8-tetrahydro-2-naphthyl group, fluorenyl group, phenyl group and aromatic hydrocarbon group such as anthryl group and pyrenyl group; and the like. The number of carbon atoms of the aromatic hydrocarbon group is preferably 6 to 30, more preferably 6 to 20, and even more preferably 6 to 15.

^{R N1Z5, R 1Z5, R 2Z5} , R 3Z5, R 4Z5, R 5Z5, R 6Z5, R 7Z5, hydrocarbon groups represented by R ^101Z5 and R ^102Z5 is a hydrocarbon group (e.g. an aromatic listed above carbonized It may be a group in which a hydrogen group is combined with at least one of a chain hydrocarbon group and an alicyclic hydrocarbon group), and an aralkyl group such as a benzyl group, a phenethyl group, or a 1-methyl-1-phenylethyl group. An arylalkenyl group such as a phenylethenyl group (phenylvinyl group); an arylalkynyl group such as a phenylethynyl group; a phenyl group to which one or more phenyl groups such as a biphenylyl group and a terphenylyl group are bonded; a cyclohexylmethylphenyl group and a benzyl Examples thereof include a phenyl group and a (dimethyl (phenyl) methyl) phenyl group.
^{R N1Z5, R 1Z5, R 2Z5} , R 3Z5, R 4Z5, R 5Z5, R 6Z5, R 7Z5, groups represented by R ^101Z5 and R ^102Z5 is a hydrocarbon group (e.g., a chain hydrocarbon group listed above And alicyclic hydrocarbon group), for example, cyclopropylmethyl group, cyclopropylethyl group, cyclobutylmethyl group, cyclobutylethyl group, cyclopentylmethyl group, cyclopentylethyl group, cyclohexylmethyl group, 2- It may be an alkyl group to which one or more alicyclic hydrocarbon groups such as methylcyclohexylmethyl group, cyclohexylethyl group and adamantylmethyl group are bonded.
These carbon numbers are preferably 4 to 30, more preferably 6 to 30, even more preferably 6 to 20, still preferably 4 to 20, and even more preferably 4 to 15. , Particularly preferably 6 to 15.

^{R N1Z5, R 1Z5, R 2Z5} , R 3Z5, R 4Z5, R 5Z5, R 6Z5, hydrocarbon groups represented by R ^7Z5, R ^101Z5 and R ^102Z5 may have a substituent. The substituent may be monovalent or divalent. For the divalent substituent, it is preferable that two bonds are bonded to the same carbon atom to form a double bond.
As the monovalent substituent,
Methoxy group, ethoxy group, propoxy group, isopropoxy group, butoxy group, isobutoxy group, sec-butoxy group, tert-butoxy group, pentyloxy group, hexyloxy group, (2-ethyl) hexyloxy group, heptyloxy group, Octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, dodecyloxy group, (2-ethyl) hexyloxy group, icosyloxy group, 1-phenylethoxy group, 1-methyl-1-phenylethoxy group, phenyloxy group , O-Trilloxy group, 2,3-dimethylphenyloxy group, 2,4-dimethylphenyloxy group, 2,5-dimethylphenyloxy group, 2,6-dimethylphenyloxy group, 3,4-dimethylphenyloxy group , 3,5-dimethylphenyloxy group, 2,2-dicyanophenyloxy group, 2,3-dicyanophenyloxy group, 2,4-dicyanophenyloxy group, 2,5-dicyanophenyloxy group, 2,6- Dicyanophenyloxy group, 3,4-dicyanophenyloxy group, 3,5-dicyanophenyloxy group, 4-methoxyphenyloxy group, 2-methoxyphenyloxy group, 3-methoxyphenyloxy group, 4-ethoxyphenyloxy group , 2-ethoxyphenyloxy group, 3-ethoxyphenyloxy group, etc., and groups represented by the following formulas, etc., which have 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or a derivatizing group thereof. (For example, a group derivatized with a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), or the like). Is an oxy group bonded to one side;

Methylthio group, ethylthio group, propylthio group, butylthio group, tert-butylthio group, pentylthio group, hexylthio group, (2-ethyl) hexylthio group, heptylthio group, octylthio group, nonylthio group, decylthio group, undecylthio group, dodecylthio group, icosylthio group. A sulfanyl group to which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group, a phenylthio group and an o-tolylthio group is bonded;

Epoxy group, oxetanyl group, tetrahydrofuryl group, tetrahydropyranyl group;
Holmil group;
Acetyl group, propanoyl group, butanoyl group, 2,2-dimethylpropanoyl group, pentanoyl group, hexanoyl group, (2-ethyl) hexanoyl group, heptanoil group, octanoyl group, nonanoyl group, decanoyl group, undecanoyl group, dodecanoyl group, A hydrocarbon group having a carbon number of 1 to 20 (preferably having a carbon number of 1 to 11) or an inducible group thereof (for example, a carboxy group or a sulfo group) such as a henicosanoyl group, a benzoyl group, and a group represented by the following formula. , A carbonyl group to which a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. are bonded. When the carbonyl group is an alkanoyl group, the number of carbon atoms is preferably 2 to 12);

Methoxycarbonyl group, ethoxycarbonyl group, propoxycarbonyl group, butoxycarbonyl group, tert-butoxycarbonyl group, pentyloxycarbonyl group, hexyloxycarbonyl group, (2-ethyl) hexyloxycarbonyl group, heptyloxycarbonyl group, octyloxycarbonyl group Group, nonyloxycarbonyl group, decyloxycarbonyl group, undecyloxycarbonyl group, dodecyloxycarbonyl group, icosyloxycarbonyl group, phenyloxycarbonyl group, o-tolyloxycarbonyl group, etc., and represented by the following formula A hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), a carbon number of carbon atoms). An oxycarbonyl group to which 1 to 10 alkylsulfamoyl groups (preferably groups derivatized with an octylsulfamoyl group) or the like are attached;

Amino group;
N-methylamino group, N, N-dimethylamino group, N-ethylamino group, N, N-diethylamino group, N-propylamino group, N, N-dipropylamino group, N-isopropylamino group, N, N-diisopropylamino group, N-butylamino group, N, N-dibutylamino group, N-isobutylamino group, N, N-diisobutylamino group, N-sec-butylamino group, N, N-disec-butyl Amino group, N-tert-butylamino group, N, N-ditert-butylamino group, N-pentylamino group, N, N-dipentylamino group, N- (1-ethylpropyl) amino group, N, N -Di (1-ethylpropyl) amino group, N-hexylamino group, N, N-dihexylamino group, N- (2-ethyl) hexylamino group, N, N-di (2-ethyl) hexylamino group, N-Heptylamino Group, N, N-Diheptylamino Group, N-octylamino Group, N, N-Dioctylamino Group, N-Nonylamino Group, N, N-Dinonylamino Group, N-Phenylamino Group, N, N -Diphenylamino group, N, N-ethylmethylamino group, N, N-propylmethylamino group, N, N-isopropylmethylamino group, N, N-butylmethylamino group, N-decylamino group, N, N- Decylmethylamino Group, N-Undecylamino Group, N, N-Undecylmethylamino Group, N-Dodecylamino Group, N, N-Dodecylmethylamino Group, N-Icosylamino Group, N, N-Icosylmethylamino One or two carbon atoms 1 to 20 (preferably 1 carbon atom) such as a group, an N, N-tert-butylmethylamino group, an N, N-phenylmethylamino group, etc., and a group represented by the following formula. A hydrocarbon group of 10) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), and an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsul). Amino group substituted with a famoyl group) or a derivatized group);

Sulfamoyl group;
N-methylsulfamoyl group, N, N-dimethylsulfamoyl group, N-ethylsulfamoyl group, N, N-diethylsulfamoyl group, N-propylsulfamoyl group, N, N-dipropyls Rufamoyl group, N-isopropylsulfamoyl group, N, N-diisopropylsulfamoyl group, N-butylsulfamoyl group, N, N-dibutylsulfamoyl group, N-isobutylsulfamoyl group, N, N-diisobutylsulfamoyl group, N-sec-butylsulfamoyl group, N, N-disec-butylsulfamoyl group, N-tert-butylsulfamoyl group, N, N-ditert-butylsul Famoyl group, N-pentyl sulfamoyl group, N, N-dipentyl sulfamoyl group, N- (1-ethylpropyl) sulfamoyl group, N, N-di (1-ethylpropyl) sulfamoyl group, N-hexyl Sulfamoyl group, N, N-dihexyl sulfamoyl group, N- (2-ethyl) hexyl sulfamoyl group, N, N-di (2-ethyl) hexyl sulfamoyl group, N-heptyl sulfamoyl Group, N, N-diheptyl sulfamoyl group, N-octyl sulfamoyl group, N, N-dioctyl sulfamoyl group, N, N-octylmethyl sulfamoyl group, N-nonyl sulfamoyl group, N, N-Dinonyl sulfamoyl group, N-phenyl sulfamoyl group, N, N-diphenyl sulfamoyl group, N, N-ethylmethyl sulfamoyl group, N, N-propylmethyl sulfamoyl group, N, N-isopropylmethylsulfamoyl group, N, N-butylmethylsulfamoyl group, N-decylsulfamoyl group, N, N-decylmethylsulfamoyl group, N-undecylsulfamoyl group, N , N-Undecylmethyl Sulfamoyl Group, N-Dodecyl Sulfamoyl Group, N, N-Dodecyl Methyl Sulfamoyl Group, N-Icosyl Sulfamoyl Group, N, N-Icosyl Methyl Sulfamoyl Group, N, N-tert-butylmethylsulfamoyl group, N, N-phenylmethylsulfamoyl group, etc., and one or two groups represented by the following formula, etc., having 1 or 2 carbon atoms (preferably carbons) A hydrocarbon group having a number of 1 to 10 or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), and an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably). Induced by octylsulfamoyl group) etc. Sulfamoyl group substituted with (ta group);

Formylamino group; acetylamino group, propanoylamino group, butanoylamino group, 2,2-dimethylpropanoylamino group, pentanoylamino group, hexanoylamino group, (2-ethyl) hexanoylamino group, heptanoil Amino group, octanoylamino group, nonanoylamino group, decanoyylamino group, undecanoylamino group, dodecanoylamino group, henicosanoylamino group, benzoylamino group, etc., and groups represented by the following formulas. Etc., a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 12 carbon atoms) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), 1 carbon atom). A carbonylamino group to which 10 to 10 alkylsulfamoyl groups (preferably groups derivatized with an octylsulfamoyl group) or the like are bonded (when the carbonylamino group is an alkanoylamino group, the number of carbon atoms is preferably 1. ~ 12);

Hydroxy group;
Halogen atoms such as fluorine atom, chlorine atom, bromine atom and iodine atom;
Carboxy group, -CO ₂ M ² (M ² is alkali metal, preferably lithium, sodium, potassium); sulfo group, -SO ₃ M ² (M ² is alkali metal, preferably lithium, sodium, potassium); nitro group Cyan group;

Formyloxy group; acetoxy group, propanoyloxy group, butanoyloxy group, 2,2-dimethylpropanoyloxy group, pentanoyloxy group, hexanoyloxy group, (2-ethyl) hexanoyloxy group, heptanoyloxy group Carbons such as groups, octanoyloxy groups, nonanoyloxy groups, decanoyloxy groups, undecanoyloxy groups, dodecanoyloxy groups, henicosanoyloxy groups, benzoyloxy groups, etc., and groups represented by the following formulas. A hydrocarbon group having a number of 1 to 20 (preferably 1 to 10 carbon atoms) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), and a group having 1 to 10 carbon atoms. A carbonyloxy group to which an alkylsulfamoyl group (preferably a group derivatized with an octylsulfamoyl group) or the like is bonded (when the carbonyloxy group is an alkanoyloxy group, the number of carbon atoms is preferably 1 to 10). be);

Methylsulfonyl group, ethylsulfonyl group, propylsulfonyl group, butylsulfonyl group, pentylsulfonyl group, hexylsulfonyl group, (2-ethyl) hexylsulfonyl group, heptylsulfonyl group, octylsulfonyl group, nonylsulfonyl group, decylsulfonyl group, un Decylsulfonyl group, dodecylsulfonyl group, icosylsulfonyl group, phenylsulfonyl group, p-tolylsulfonyl group and the like, and groups represented by the following formulas having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms). A hydrocarbon group or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group)). Sulfonyl group to which (groups derivatized by etc.) are bound;

Carbamic group;
N-Methylcarbamoyl group, N, N-dimethylcarbamoyl group, N-ethylcarbamoyl group, N, N-diethylcarbamoyl group, N-propylcarbamoyl group, N, N-dipropylcarbamoyl group, N-isopropylcarbamoyl group, N , N-diisopropylcarbamoyl group, N-butylcarbamoyl group, N, N-dibutylcarbamoyl group, N-isobutylcarbamoyl group, N, N-diisobutylcarbamoyl group, N-sec-butylcarbamoyl group, N, N-disec- Butylcarbamoyl group, N-tert-butylcarbamoyl group, N, N-ditert-butylcarbamoyl group, N-pentylcarbamoyl group, N, N-dipentylcarbamoyl group, N- (1-ethylpropyl) carbamoyl group, N, N-di (1-ethylpropyl) carbamoyl group, N-hexyl carbamoyl group, N, N-dihexyl carbamoyl group, N- (2-ethyl) hexyl carbamoyl group, N, N-di (2-ethyl) hexyl carbamoyl group , N-Heptylcarbamoyl group, N, N-diheptylcarbamoyl group, N-octylcarbamoyl group, N, N-dioctylcarbamoyl group, N-nonylcarbamoyl group, N, N-octylmethylcarbamoyl group, N, N-octyl Butylcarbamoyl group, N, N-dinonylcarbamoyl group, N-phenylcarbamoyl group, N, N-diphenylcarbamoyl group, N, N-ethylmethylcarbamoyl group, N, N-propylmethylcarbamoyl group, N, N-isopropyl Methylcarbamoyl group, N, N-butylmethylcarbamoyl group, N-decylcarbamoyl group, N, N-decylmethylcarbamoyl group, N-undecylcarbamoyl group, N, N-undecylmethylcarbamoyl group, N-dodecylcarbamoyl group , N, N-dodecylmethylcarbamoyl group, N-icosylcarbamoyl group, N, N-icosylmethylcarbamoyl group, N, N-tert-butylmethylcarbamoyl group, N, N-phenylmethylcarbamoyl group, etc. A hydrocarbon group having 1 or 2 carbon atoms (preferably 1 to 10 carbon atoms) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group) such as a group represented by the above formula. , A carbamoyl group substituted with halogen (preferably a chlorine atom), a group derivatized with an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc.;

Trifluoromethyl group, perfluoroethyl group, perfluoropropyl group, perfluoroisopropyl group, perfluorobutyl group, perfluoropentyl group, perfluorohexyl group, perfluoroheptyl group, perfluorooctyl group, perfluorononyl group, Carbonation of 1 to 20 carbon atoms in which all hydrogen atoms such as perfluorodecyl group, perfluoroundecyl group, perfluorododecyl group, perfluoroicosyl group, perfluorocyclohexyl group and perfluorophenyl group are substituted with fluorine atom. Hydrogen group;
Perfluoroethylmethyl group, perfluoropropylmethyl group, perfluoroisopropylmethyl group, perfluorobutylmethyl group, perfluoropentylmethyl group, perfluorohexylmethyl group, perfluoroheptylmethyl group, perfluorooctylmethyl group, perfluoro A linear chain having 1 to 20 carbon atoms in which all hydrogen atoms such as nonylmethyl group, perfluorodecylmethyl group, perfluoroundecylmethyl group, perfluorododecylmethyl group and perfluoroicosylmethyl group are substituted with fluorine atoms. Alternatively, a hydrocarbon group having 1 to 20 carbon atoms substituted with an alkyl group in the branched chain;

1 to 20 carbon atoms (preferably carbon number) in which a part of hydrogen atoms such as 2-fluorophenyl group, 3-fluorophenyl group, 4-fluorophenyl group and 2,4,6-trifluorophenyl group are replaced with fluorine. 1-10) hydrocarbon groups;

-CO-SH, -CO-S-CH ₃ , -CO-S-CH ₂ CH ₃ , -CO-S-CH ₂ -CH ₂ -CH ₃ and -CO-S-CH ₂ -CH ₂ -CH ₂ carbon atoms -CH _3, etc. 20 (preferably having 1 to 10 carbon atoms) bound to an alkyl group as bonded to a thiocarbonyl _{group, -CO-S-C 6 H} 5 aryl group having 6 to 20 carbon atoms, such as the Thiocarbonyl group;

* -COCO-R as represented by the following formula (in the formula, R is a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms (for example, among the hydrocarbon groups listed above, it satisfies 1 to 20 carbon atoms). , Or its inducing group (eg, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group). Group) (group derived by etc.);

_{* -NRCONR 2} as represented by the following formula (in the formula, R is a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms (for example, among the hydrocarbon groups listed above, those satisfying 1 to 20 carbon atoms). ), Or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), etc. Groups derived from), the Rs of which may be the same or different from each other, or bonded to each other to form a ring);

_{* -OCONR 2} as represented by the following formula (in the formula, R is a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms (for example, among the hydrocarbon groups listed above, those satisfying 1 to 20 carbon atoms). ), Or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), etc. Groups derived from), the Rs of which may be the same or different from each other, or bonded to each other to form a ring);

* -NRCOOR as represented by the following formula (in the formula, R is a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms (for example, among the hydrocarbon groups listed above, those satisfying 1 to 20 carbon atoms)). , Or its inducing group (eg, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group), etc. Derivatized groups), the Rs of which may be the same or different from each other, or bonded to each other to form a ring) groups;

* -OP (O) (OCH ₃ ) ₂ such as * -OP (O) (OR) ₂ (In the formula, R is a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms (for example, the hydrocarbon group listed above). Of these, those satisfying 1 to 20 carbon atoms), or their inducible groups (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms). (Preferably a group derivatized with an octylsulfamoyl group) or the like), and the Rs may be the same or different from each other, or may be bonded to each other to form a ring).
* -Si (CH ₃ ) ₃ , _{* -Si (CH 2} CH ₃ ) ₃ , _{* -Si (C 6} H ₅ ) ₃ and * -Si (CH (CH ₃ ) ₂ ) _3, etc. * -SiR ₃ ( In the formula, R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, one of the above-mentioned hydrocarbon groups satisfying 1 to 20 carbon atoms), or an inducing group thereof (for example, a carboxy group or a sulfo group). A group derived from a group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), etc.), and the R is Groups of (may be the same or different from each other and may be bonded to each other to form a ring);
And so on.

As the divalent substituent, an oxo group, a thioxo group, an imino group, an imino group substituted with an alkyl group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) and an aryl group having 6 to 20 carbon atoms are substituted. Examples include the imino group. _{CH 3-} N is an imino group substituted with an alkyl group.
=, CH ₃ −CH ₂ −N =, CH ₃ − (CH ₂ ) ₂ −N =, CH ₃ − (CH ₂ ) ₃ −N =, and the like. Examples of the imino group substituted with the aryl group include C ₆ H _5- N = and the like.

Preferred examples of the substituent of the hydrocarbon group having 1 to 40 carbon atoms include the substituent of the group s1. The inducible groups shown below are carboxy groups, sulfo groups, nitro groups, hydroxy groups, halogens (preferably chlorine atoms), alkylsulfamoyl groups having 1 to 10 carbon atoms (preferably octylsulfamoyl groups) and the like. It is preferably an derivatized group.
[Group s1]
An oxy group in which a hydrocarbon group having 1 to 20 carbon atoms or an inducible group thereof is bonded to one side;
A carbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
An oxycarbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
Amino group;
An amino group substituted with one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
Sulfamoyl group;
A sulfamoyl group substituted with one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
A carbonylamino group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
Hydroxy group;
Halogen atom;
-CO ₂ M (preferably a carboxy group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom);
-SO ₃ M (preferably a sulfo group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom);
Nitro group;
Cyano group;
A carbonyloxy group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
A sulfonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or an inducible group thereof is bonded;
Carbamic group;
A carbamoyl group substituted with one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
A hydrocarbon group having 1 to 20 carbon atoms in which all hydrogen atoms are replaced by fluorine atoms;
A hydrocarbon group having 1 to 20 carbon atoms in which all of the hydrogen atoms are substituted with fluorine atoms;
A hydrocarbon group having 1 to 20 carbon atoms in which a part of a hydrogen atom is replaced by fluorine;
Oxo group

As the substituent of the hydrocarbon group having 1 to 40 carbon atoms, a substituent of group s2 is more preferable.
[Group s2]
An oxy group in which a hydrocarbon group having 1 to 10 carbon atoms or an inducible group thereof is bonded to one side;
A carbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
An oxycarbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
Amino group;
An amino group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or an inducible group thereof;
Sulfamoyl group;
A sulfamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof;
A carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
Hydroxy group;
Fluorine atom, chlorine atom, bromine atom;
-CO ₂ M (preferably a carboxy group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom);
-SO ₃ M (preferably a sulfo group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom);
Nitro group;
Cyano group;
A carbonyloxy group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
A sulfonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or an inducible group thereof is bonded;
Carbamic group;
A carbamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof;
A hydrocarbon group having 1 to 10 carbon atoms in which all hydrogen atoms are replaced by fluorine atoms;
A hydrocarbon group having 1 to 10 carbon atoms in which all of the hydrogen atoms are substituted with fluorine atoms;
A hydrocarbon group having 1 to 10 carbon atoms in which a part of a hydrogen atom is replaced by fluorine;
Oxo group

Examples of the hydrocarbon group ^{R N1Z5, R 1Z5, R 2Z5} , R 3Z5, R 4Z5, R 5Z5, R 6Z5, R 7Z5, carbon atoms having a substituent represented by R ^101Z5 and R ^102Z5 1~40, 1 Hydrocarbon groups having 1 to 40 carbon atoms having a valent or divalent substituent can be mentioned, preferably saturated or unsaturated chain hydrocarbon groups having 1 to 30 carbon atoms having a monovalent or divalent substituent. A saturated or unsaturated alicyclic hydrocarbon group having 3 to 30 carbon atoms having a monovalent or divalent substituent or an aromatic hydrocarbon group having 6 to 30 carbon atoms having a monovalent or divalent substituent or Groups having a combination of hydrocarbon groups and having a monovalent or divalent substituent and having 1 to 30 carbon atoms can be mentioned.
More preferably, a saturated or unsaturated chain hydrocarbon group having 1 to 20 carbon atoms having a substituent in group s1 and a saturated or unsaturated alicyclic hydrocarbon group having 3 to 20 carbon atoms having a substituent in group s1. , A group having a substituent of group s1 and having 6 to 20 carbon atoms or a combination of hydrocarbon groups and a group having a substituent of group s1 and having 1 to 20 carbon atoms.
Particularly preferably, a saturated or unsaturated chain hydrocarbon group having 1 to 15 carbon atoms having a substituent in group s2 and a saturated or unsaturated alicyclic hydrocarbon group having 3 to 15 carbon atoms having a substituent in group s2. , A group having a substituent of group s2 and having 6 to 15 carbon atoms or a combination of hydrocarbon groups and a group having a substituent of group s2 and having 1 to 15 carbon atoms.

In Examples ^{R N1Z5, R 1Z5, R 2Z5} , R 3Z5, R 4Z5, R 5Z5, R 6Z5, heterocyclic group represented by R ^7Z5, R ^101Z5 and R ^102Z5, it may be monocyclic polycyclic It may be a heterocycle, preferably a heterocycle containing a heteroatom as a component of the ring. Examples of the hetero atom include a nitrogen atom, an oxygen atom and a sulfur atom.
The number of carbon atoms of the heterocyclic group is preferably 3 to 30, more preferably 3 to 22, still more preferably 3 to 20, even more preferably 3 to 18, and even more preferably 3 to 3. It is 15, particularly preferably 3 to 14.

As a heterocycle containing a nitrogen atom,
Monocyclic saturated heterocycles such as aziridine, azetidine, pyrrolidine, piperidine and piperazine;
Pyrrole such as 2,5-dimethylpyrrole, pyrazole such as 2-methylpyrazole and 3-methylpyrazole, imidazole, 1,2,3-triazole and 5-membered ring-based unsaturated heterocycle such as 1,2,4-triazole ;
Pyrimidines such as pyridine, pyridazine, 6-methylpyrimidine, pyrazines and 6-membered ring unsaturated heterocycles such as 1,3,5-triazine;
Quinoxaline such as indazole, indolin, isoindolin, indole, indoline, benzimidazole, quinoline, isoquinoline, 5,6,7,8-tetrahydro (3-methyl) quinoxaline, 3-methylquinoxaline, quinazoline, cinnoline, phthalazine, diazanaphthalene. , Purine, pteridine, benzopyrazole, benzopiperidine and other fused bicyclic heterocycles;
Condensed tricyclic heterocycles such as carbazole, acridine and phenazine; and the like.

As a heterocycle containing an oxygen atom,
Monocyclic saturated heterocycles such as oxylan, oxetane, tetrahydrofuran, tetrahydropyran, 1,3-dioxane and 1,4-dioxane, 1-cyclopentyl dioxolane;
Bicyclic saturated heterocycles such as 1,4-dioxaspiro [4.5] decane and 1,4-dioxaspiro [4.5] nonane;
Lactone-based heterocycles such as α-acetolactone, β-propiolactone, γ-butyrolactone, γ-valerolactone and δ-valerolactone;
A 5-membered ring-based unsaturated heterocycle such as furan such as 2,3-dimethylfuran and 2,5-dimethylfuran;
6-membered ring-based unsaturated heterocycles such as 2H-pyran and 4H-pyran;
Benzopyrans such as 1-benzofuran and 4-methylbenzopyran, condensed bicyclic heterocycles such as benzodioxol, chroman and isochroman;
Condensed tricyclic heterocycles such as xanthene and dibenzofuran; and the like.

As a heterocycle containing a sulfur atom,
5-membered ring-based saturated heterocycle such as dithiolane;
6-membered ring-based saturated heterocycles such as thiane, 1,3-dithiane, 2-methyl 1,3-dithiane;
5-membered ring-based unsaturated heterocycles such as thiophenes such as 3-methylthiophene and 2-carboxythiophene, 4H-thiopyran, benzothiopyran such as benzotetrahydrothiopyran;
Condensation bicyclic heterocycles such as benzothiophene;
Condensed tricyclic heterocycles such as thianthrene and dibenzothiophene; and the like.

As a heterocycle containing a nitrogen atom and an oxygen atom,
Monocyclic saturated heterocycles such as morpholine, 2-pyrrolidone, 2-methyl-2-pyrrolidone, 2-piperidone and 2-methyl-2-piperidone;
Monocyclic unsaturated heterocycles such as oxazoles such as 4-methyloxazole, 2-methylisoxazoles, and isooxazoles such as 3-methylisoxazole;
Condensed bicyclic heterocycles such as benzoxazole, benzoisoxazole, benzoxazine, benzodioxan, benzoimidazoline;
Condensed tricyclic heterocycles such as phenoxazine; and the like.

As a heterocycle containing a nitrogen atom and a sulfur atom,
Monocyclic heterocycles such as thiazoles such as 3-methylthiazole and 2,4-dimethylthiazole;
Condensation bicyclic heterocycles such as benzothiazole;
Condensation tricyclic heterocycles such as phenothiazine; and the like.

The heterocycle may be a group in which the above-mentioned hydrocarbon groups are combined, and examples thereof include a tetrahydrofurylmethyl group.

Further, the heterocycle may be represented by the following formula.

The above heterocyclic group may be heterocyclic group or two of R ^1Z5 ~R ^5Z5 formed by bonding. Such heterocyclic groups can have two or more rings ring structure with the benzene ring to which R ^1Z5 ~R ^5Z5 binds. Examples of the ring structure having two or more rings include the structure of the following formula.

The bond position of the above heterocycle is a portion where an arbitrary hydrogen atom contained in each ring is eliminated.

^{R N1Z5, R 1Z5, R 2Z5} , R 3Z5, R 4Z5, R 5Z5, R 6Z5, heterocyclic group represented by R ^7Z5, R ^101Z5 and R ^102Z5 may have a substituent. Examples of the ^{substituent, R N1Z5, R 1Z5, R} 2Z5, R 3Z5, R 4Z5, R 5Z5, R 6Z5, R 7Z5, which may have a hydrocarbon group represented by R ^101Z5 and R ^102Z5 substituted The same thing as the group can be mentioned. When the heterocycle contains a nitrogen atom as a constituent element thereof, the hydrocarbon group mentioned above may be bonded to the nitrogen atom as a substituent.
Preferred examples of the substituent, and ^{R N1Z5, R 1Z5, R 2Z5} , R 3Z5, R 4Z5, R 5Z5, R 6Z5, R 7Z5, have a hydrocarbon group represented by R ^101Z5 and R ^102Z5 The same preferred substituents may be mentioned.
Examples of the heterocyclic group having a ^{R N1Z5, R 1Z5, R 2Z5} , R 3Z5, R 4Z5, R 5Z5, R 6Z5, R 7Z5, substituents represented by R ^101Z5 and R ^102Z5, 1 monovalent or divalent substituent A heterocyclic group having a group is mentioned, preferably a heterocyclic group having a substituent of the group s1 is mentioned, and more preferably a heterocyclic group having a substituent of the group s2 is mentioned.
The above-mentioned hydrocarbon group or heterocyclic group may have one or more substituents (first substituents), and the two or more substituents are independent of each other. It may be the same or different. Further, the first substituent may have another substituent (second substituent) bonded to the hydrocarbon group contained in a part thereof. The second substituent can be selected from the same groups as the first substituent.

^{Hereinafter, R N1Z5, R 1Z5, R} 2Z5, R 3Z5, R 4Z5, R 5Z5, R 6Z5, and -CO-R ^102Z5 of ^{R 7Z5, -COO-R 101Z5,} -OCO-R 102Z5, -COCO-R 102Z5 , ^{-OR 102Z5} , -SO ₂ -R ^101Z5 , -SO ₂ N (R ^102Z5 ) ₂ ^{, -CON} (R 102Z5) ₂ , -N (R ^102Z5 ) ₂ , -NHCO-R ^102Z5 , -NHCO-N (R ^102Z5 ) ₂ , -NHCOOR ^102Z5 , -OCON (R ^102Z5 ) ₂ , halogen atom, -SO ₃ M, -CO ₂ M will be described.

-CO-R ^102Z5 includes formyl group; acetyl group, propanoyl group, butanoyl group, 2,2-dimethylpropanoyl group, pentanoyl group, hexanoyl group, (2-ethyl) hexanoyl group, heptanoil group, octanoyl group, nonanoyl. Derivation of a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group, a decanoyl group, an undecanoyl group, a dodecanoyl group, a henicosanoyl group, a benzoyl group, etc., and a group represented by the above formula. It was derivatized with a chemical group (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), or the like. A group corresponding to -CO-R 102Z5 in the carbonyl group to which the group) is bonded (when the carbonyl group is an acyl group, the number of carbon atoms is 2-41) and the compounds shown in Tables 1Z5 to 15Z5, and a ^{special application.} In the compounds shown in Tables 1 to 966 of No. ^2017-016290 , a group corresponding to −CO-R 102Z5 and the like can be mentioned, preferably a hydrocarbon group having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms) or a hydrocarbon group. In the carbonyl group to which the derivatizing group is attached (when the carbonyl group is an alkanoyl group, the number of carbon atoms is more preferably 2 to 12), and in the compounds shown in Tables 1Z5 to 15Z5, -CO-R ^102Z5 . Applicable groups and the like can be mentioned.

-COO-R ^101Z5 includes methoxycarbonyl group, ethoxycarbonyl group, propoxycarbonyl group, tert-butoxycarbonyl group, butoxycarbonyl group, pentyloxycarbonyl group, hexyloxycarbonyl group, (2-ethyl) hexyloxycarbonyl group, Heptyloxycarbonyl group, octyloxycarbonyl group, nonyloxycarbonyl group, decyloxycarbonyl group, undecyloxycarbonyl group, dodecyloxycarbonyl group, phenyloxycarbonyl group, icosyloxycarbonyl group, etc., and represented by the above formula. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or an inducing group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon In the oxycarbonyl group to which an alkylsulfamoyl group (preferably a group derivatized with an octylsulfamoyl group) of numbers 1 to 10 (preferably a group derivatized by an octylsulfamoyl group) or the like is bonded, and in the compounds shown in Tables 1Z5 to 15Z5, -COO-R ^{102Z5 Examples of the relevant group and the group corresponding to -COO-R 102Z5} in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290 include a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof. Examples thereof include an oxycarbonyl group to which is bonded and a group corresponding to ^{-COO-R 102Z5 in the compounds shown in Tables 1Z5 to 15Z5.}

-OCO-R ^102Z5 includes formyloxy group; acetoxy group, propanoyloxy group, butanoyloxy group, 2,2-dimethylpropanoyloxy group, pentanoyloxy group, hexanoyloxy group, (2-ethyl). Hexanoyloxy group, heptanoiloxy group, octanoyloxy group, nonanoyloxy group, decanoyloxy group, undecanoyloxy group, dodecanoyloxy group, henikosanoyloxy group, benzoyloxy group, etc., and the above formula. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or an inducible group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, or a halogen (preferably a chlorine atom). ), A carbonyloxy group to which an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably a group derived from an octylsulfamoyl group) or the like is bonded (when the carbonyloxy group is an acyloxy group, the number of carbon atoms is 2 to 41), and in the compounds shown in Tables 1Z5 to ^15Z5 , the groups corresponding to -OCO-R 102Z5 and in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290- ^{OCO-R 102Z5.} Examples of the group corresponding to the above, preferably a hydrocarbon group having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms) or a carbonyloxy group to which an inducible group thereof is bonded (the carbonyloxy group is referred to as an acyloxy group). In this case, the number of carbon atoms is more preferably 2 to 12), and in the compounds shown in Tables 1Z5 to ^15Z5 , groups corresponding to -OCO-R 102Z5 and the like can be mentioned.

-COCO-R ^102Z5 includes methyloxalyl group, ethyloxalyl group, propyloxalyl group, butyloxalyl group, pentyloxalyl group, hexyloxalyl group, (2-ethyl) hexyloxalyl group, heptyloxalyl group, octyloxalyl group and nonyl. Oxalyl group, decyl oxalyl group, undecyl oxalyl group, dodecyl oxalyl group, icosyl oxalyl group, cyclopentyl oxalyl group, cyclohexyl oxalyl group, phenyl oxalyl group, p-tolyl oxalyl group and the like, and groups represented by the above formulas and the like. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), 1 to 1 carbon atoms. Oxalyl groups to which 10 alkylsulfamoyl groups (preferably groups derivatized with octylsulfamoyl groups) and the like are bonded, and groups corresponding to ^{-COCO-R 102Z5 in the compounds shown in Tables 1Z5 to 15Z5 and} Examples of the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290 include groups corresponding to ^{-COCO-R 102Z5.}

^{-OR 102Z 5} groups include hydroxy group; methoxy group, ethoxy group, propoxy group, isopropoxy group, butoxy group, isobutoxy group, sec-butoxy group, tert-butoxy group, pentyloxy group, hexyloxy group, heptyl. Oxy group, octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, dodecyloxy group, (2-ethyl) hexyloxy group, icosyloxy group, 1-phenylethoxy group, 1-methyl-1-phenylethoxy group, Phenyloxy group, 2,3-dimethylphenyloxy group, 2,4-dimethylphenyloxy group, 2,5-dimethylphenyloxy group, 2,6-dimethylphenyloxy group, 3,4-dimethylphenyloxy group, 3 , 5-Dimethylphenyloxy group, 2,2-dicyanophenyloxy group, 2,3-dicyanophenyloxy group, 2,4-dicyanophenyloxy group, 2,5-dicyanophenyloxy group, 2,6-dicyanophenyl Oxy group, 3,4-dicyanophenyloxy group, 3,5-dicyanophenyloxy group, 4-methoxyphenyloxy group, 2-methoxyphenyloxy group, 3-methoxyphenyloxy group, 4-ethoxyphenyloxy group, 2 A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a −ethoxyphenyloxy group, a 3-ethoxyphenyloxy group, etc., and a group represented by the above formula, or a derivatizing group thereof (for example, 1 to 20 carbon atoms). A group derived from a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), or the like is bonded. group corresponding to the -O-R ^102Z5 in the group as well as compounds shown in Table 1Z5~ Table 15Z5 -O-R ^102Z5 Table 1-966 of the relevant group and Japanese Patent Application No. 2017-016290 to the compounds shown in Examples thereof include an oxy group to which a hydrocarbon group having 1 to 10 carbon atoms or an inducible group thereof is bonded, and a group corresponding to ^{-OR 102Z5 in the compounds shown in Tables 1Z5 to 15Z5.}

−SO ₂ −R ^101Z5 includes methylsulfonyl group, ethylsulfonyl group, propylsulfonyl group, butylsulfonyl group, pentylsulfonyl group, hexylsulfonyl group, (2-ethyl) hexylsulfonyl group, heptylsulfonyl group, octylsulfonyl group, Nonylsulfonyl group, decylsulfonyl group, undecylsulfonyl group, dodecylsulfonyl group, icosylsulfonyl group, phenylsulfonyl group, p-tolylsulfonyl group, etc., and groups represented by the above formula, etc. have 1 to 40 carbon atoms (1 to 40 carbon atoms). A hydrocarbon group having 1 to 20 carbon atoms or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms). (preferably octyl sulfamoyl group) groups and, and Japanese Patent Application No. corresponding to -SO ₂ -R ^102Z5 in the compound represented by sulfonyl groups and Table 1Z5~ table 15Z5 groups derivatized with like) bound 2017-016290 Examples of the compounds shown in Tables 1 to 966 of No. ₂ include groups corresponding to −SO2-R ^102Z5 , preferably a sulfonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or an inducible group thereof is bonded, and Table 1Z5. group corresponding to -SO ₂ -R ^102Z5 are mentioned in the compounds shown in to table 15Z5.

-SO ₂ N (R ^102Z5 ) ₂ is a sulfamoyl group;
N-methylsulfamoyl group, N-ethylsulfamoyl group, N-propylsulfamoyl group, N-isopropylsulfamoyl group, N-butylsulfamoyl group, N-isobutylsulfamoyl group, N- sec-butyl sulfamoyl group, N-tert-butyl sulfamoyl group, N-pentyl sulfamoyl group, N- (1-ethylpropyl) sulfamoyl group, N-hexyl sulfamoyl group, N- (2-) Ethyl) Hexyl sulfamoyl group, N-heptyl sulfamoyl group, N-octyl sulfamoyl group, N-nonyl sulfamoyl group, N-decyl sulfamoyl group, N-undecyl sulfamoyl group, N- One carbon number 1 to 40 (preferably 1 to 20) of one group such as dodecylsulfamoyl group, N-icosylsulfamoyl group, N-phenylsulfamoyl group, and a group represented by the above formula. (For example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably octyl sulfamoyl group). ^{_{) -SO 2 NH (R 102Z5X)}} ( provided that the sulfamoyl group and tables 1Z5~ Table 15Z5 compounds shown in substituted with derivatized groups) in such, except that R ^102Z5X is not a hydrogen atom, R ^102Z5 -SO ₂ NH (R ^102Z5X) (provided that the compounds shown in Table 1 to 966 of the corresponding group and Japanese Patent Application No. 2017-016290 the same as is) and, except that R ^102Z5X is not a hydrogen atom, R ^102Z5 (Same as))

N, N-dimethylsulfamoyl group, N, N-ethylmethylsulfamoyl group, N, N-diethylsulfamoyl group, N, N-propylmethylsulfamoyl group, N, N-dipropylsulfamoyl Group, N, N-isopropylmethylsulfamoyl group, N, N-diisopropylsulfamoyl group, N, N-tert-butylmethylsulfamoyl group, N, N-diisobutylsulfamoyl group, N, N- Disec-butyl sulfamoyl group, N, N-ditert-butyl sulfamoyl group, N, N-butylmethyl sulfamoyl group, N, N-dibutyl sulfamoyl group, N, N-dipentyl sulfa Moyl group, N, N-di (1-ethylpropyl) sulfamoyl group, N, N-dihexyl sulfamoyl group, N, N-di (2-ethyl) hexyl sulfamoyl group, N, N-diheptylsul Famoyl group, N, N-octylmethylsulfamoyl group, N, N-dioctylsulfamoyl group, N, N-dinonyl sulfamoyl group, N, N-decylmethylsulfamoyl group, N, N- Undecylmethyl sulfamoyl group, N, N-dodecylmethyl sulfamoyl group, N, N-icosylmethyl sulfamoyl group, N, N-phenylmethyl sulfamoyl group, N, N-diphenyl sulfamoyl Two hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group and a group represented by the above formula or a derivatizing group thereof (for example, a carboxy group, a sulfo group, a nitro group, etc. Sulfamoyl groups substituted with hydroxy groups, halogens (preferably chlorine atoms), alkylsulfamoyl groups having 1 to 10 carbon atoms (preferably octylsulfamoyl groups), etc.) and Sulfamoyl groups and Tables 1Z5-5. In the compound shown in 15Z5, _{the groups corresponding to -SO 2} N (R ^102Z5X ) ₂ (however, R ^{102Z5X is the same as R 102Z5} except that it does not become a hydrogen atom) and Table 1 of Japanese Patent Application No. 2017-016290. Among the compounds shown in ~ 966, groups corresponding to −SO ₂ N (R ^102Z5X ) ₂ (however, R ^{102Z5X is the same as R 102Z5} except that it does not become a hydrogen atom) can be mentioned.
Preferably, it corresponds to _{−SO 2} N (R 102Z5) ₂ in the sulfamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or an inducible group thereof and the compounds shown in Tables 1Z5 to ^15Z5. The group etc. can be mentioned.

^-CON (R 102Z5) ₂ is a carbamoyl group;
N-methylcarbamoyl group, N-ethylcarbamoyl group, N-propylcarbamoyl group, N-isopropylcarbamoyl group, N-butylcarbamoyl group, N-isobutylcarbamoyl group, N-sec-butylcarbamoyl group, N-tert-butylcarbamoyl group. Group, N-pentylcarbamoyl group, N- (1-ethylpropyl) carbamoyl group, N-hexylcarbamoyl group, N- (2-ethyl) hexylcarbamoyl group, N-heptylcarbamoyl group, N-octylcarbamoyl group and N- One of nonylcarbamoyl group, N-decylcarbamoyl group, N-undecylcarbamoyl group, N-dodecylcarbamoyl group, N-icosylcarbamoyl group, N-phenylcarbamoyl group and the like, and a group represented by the above formula. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), and 1 to 10 carbon atoms. -CONH (R ^102Z5X ) (where R except ^{that 102Z5X} is not a hydrogen atom, -CONH (R ^102Z5X) (provided that the compounds shown in Table 1 to 966 groups and and Japanese Patent Application No. 2017-016290 corresponding to same in a) and R ^102Z5, R ^102Z5X Is the same as ^{R 102 Z5} except that it does not become a hydrogen atom).

N, N-dimethylcarbamoyl group, N, N-ethylmethylcarbamoyl group, N, N-diethylcarbamoyl group, N, N-propylmethylcarbamoyl group, N, N-dipropylcarbamoyl group, N, N-isopropylmethylcarbamoyl Group, N, N-diisopropylcarbamoyl group, N, N-tert-butylmethylcarbamoyl group, N, N-diisobutylcarbamoyl group, N, N-disec-butylcarbamoyl group, N, N-ditert-butylcarbamoyl group , N, N-butylmethylcarbamoyl group, N, N-dibutylcarbamoyl group, N, N-butyloctylcarbamoyl group, N, N-dipentylcarbamoyl group, N, N-di (1-ethylpropyl) carbamoyl group, N , N-dihexylcarbamoyl group, N, N-di (2-ethyl) hexylcarbamoyl group, N, N-diheptylcarbamoyl group, N, N-octylmethylcarbamoyl group, N, N-dioctylcarbamoyl group, N, N -Dinonylcarbamoyl group, N, N-decylmethylcarbamoyl group, N, N-undecylmethylcarbamoyl group, N, N-dodecylmethylcarbamoyl group, N, N-icosylmethylcarbamoyl group, N, N-phenylmethyl Two hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a carbamoyl group, an N, N-diphenylcarbamoyl group, etc., and a group represented by the above formula, or an inducing group thereof (for example, 1 to 20 carbon atoms). Substituted with a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably a group derived with an octyl sulfamoyl group), or the like). In the carbamoyl groups and the compounds shown in Tables 1Z5 to 15Z5, the groups corresponding to ^-CON (R 102Z5X) ₂ (however, R ^{102Z5X is the same as R 102Z5} except that it does not become a hydrogen atom), and the special feature. In the compounds shown in Tables 1 to 966 of Application No. 2017-016290, the groups corresponding to ^-CON (R 102Z5X) ₂ (however, R ^{102Z5X is the same as R 102Z5} except that it does not become a hydrogen atom) are listed. Be,
Preferably, a carbamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or an inducible group thereof, and a group corresponding to ^-CON (R 102Z5) _{2 in the compounds shown in Tables 1Z5 to 15Z5 and the like.} Can be mentioned.

−N (R ^102Z5 ) ₂ is an amino group;
N-methylamino group, N-ethylamino group, N-propylamino group, N-isopropylamino group, N-butylamino group, N-isobutylamino group, N-sec-butylamino group, N-tert-butylamino Group, N-pentylamino group, N-hexylamino group, N- (2-ethyl) hexylamino group, N-heptylamino group, N-octylamino group, N-nonylamino group, N-decylamino group, N-un A decylamino group, an N-dodecylamino group, an N-icosylamino group, an N-phenylamino group, etc., and a group represented by the above formula, etc., which have 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms). A hydrocarbon group or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group)). ^{-NH (R 102Z5X} ) (however, R ^102Z5X is the same as ^{R 102Z5} except that it does not become a hydrogen atom in the amino groups substituted with (groups induced by etc.) and the compounds shown in Tables 1Z5 to 15Z5. ^{-NH (R 102Z5X} ) (however, R ^102Z5X is the same as ^{R 102Z5} except that it does not become a hydrogen atom) in the groups corresponding to (there is) and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290. ), Etc.;

N, N-dimethylamino group, N, N-ethylmethylamino group, N, N-diethylamino group, N, N-propylmethylamino group, N, N-dipropylamino group, N, N-isopropylmethylamino group , N, N-diisopropylamino group, N, N-tert-butylmethylamino group, N, N-diisobutylamino group, N, N-disec-butylamino group, N, N-ditert-butylamino group, N, N-butylmethylamino group, N, N-dibutylamino group, N, N-dipentylamino group, N, N-di (1-ethylpropyl) amino group, N, N-dihexylamino group, N, N -Di (2-ethyl) hexylamino group, N, N-diheptylamino group, N, N-dioctylamino group, N, N-dinonylamino group, N, N-decylmethylamino group, N, N-undecyl Methylamino group, N, N-dodecylmethylamino group, N, N-icosylmethylamino group, N, N-phenylmethylamino group, N, N-diphenylamino group, etc., and groups represented by the above formulas. 2 hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or derivatizing groups thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon ^{-N (R 102Z5X} ) in amino groups substituted with an alkyl sulfamoyl group (preferably a group derivatized with an octyl sulfamoyl group) of numbers 1 to 10 and the compounds shown in Tables 1Z5 to 15Z5. ^{-N (R 102Z5X} ) _{2 in the groups corresponding to 2} (however, R ^{102Z5X is the same as R 102Z5} except that it does not become a hydrogen atom) and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290. (However, R ^102Z5X is the same as ^{R 102Z5} except that it does not become a hydrogen atom.)
Preferably, an amino group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or an inducible group thereof, and a group corresponding to ^{-N (R 102Z5} ) _{2 in the compounds shown in Tables 1Z5 to 15Z5 and the like.} Can be mentioned.

-NHCO-R ^102Z5 includes formylamino groups; acetylamino groups, propanoylamino groups, butanoylamino groups, 2,2-dimethylpropanoylamino groups, pentanoylamino groups, hexanoylamino groups, (2-ethyl). ) Hexanoylamino group, Heptanoylamino group, Octanoylamino group, Nonanoylamino group, Decanoylamino group, Undecanoylamino group, Dodecanoylamino group, Henikosanoylamino group, Bencoylamino group, etc. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group represented by the above formula or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, or a halogen (preferably). Is a chlorine atom), a carbonylamino group (a group derivatized with an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc.) is bonded (when the carbonylamino group is an acylamino group). , The number of carbon atoms is 1 to 40), and in the compounds shown in Tables 1Z5 to ^15Z5 , the group corresponding to -NHCO-R 102Z5 and in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290-NHCO- The groups corresponding to ^{R 102Z5 are listed.}
Preferably, a carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or an inducible group thereof is bonded (when the carbonylamino group is an alkanoylamino group, the carbon number is more preferably 1 to 10) and Table 1Z5. In the compounds shown in Table 15Z5, ^{groups corresponding to -NHCO-R 102Z5} and the like can be mentioned.

-NHCON (R ^102Z5 ) ₂ includes the groups listed above, the groups ^{corresponding to -NHCON (R 102Z5} ) ₂ in the compounds shown in Tables 1Z5 to 15Z5, and Table 1 to Japanese Patent Application No. 2017-016290. Examples of the compound shown in 966 include a group corresponding to ^{-NHCON (R 102Z5} ) _2.

-NHCOOR ^102Z5 includes the groups listed above, the groups ^{corresponding to -NHCOOR 102Z5} in the compounds shown in Tables 1Z5 to 15Z5, and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290. ^Examples include groups corresponding to 102Z5.

-OCON (R ^102Z5 ) ₂ includes the groups listed above, the groups ^{corresponding to -OCON (R 102Z5} ) ₂ in the compounds shown in Tables 1Z5 to 15Z5, and Tables 1 to 1 of Japanese Patent Application No. 2017-016290. ^{Examples of the} compound shown in 966 include a group corresponding to -OCON (R 102Z5) _2.

As the halogen atom, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom and the like are preferable.
Examples of _{M of −SO 3} M and −CO ₂ M include hydrogen atom; alkali metal atom such as lithium atom, sodium atom and potassium atom, and preferably hydrogen atom, sodium atom and potassium atom.

-CO-R ^102Z5 , -COO-R ^102Z5 , -OCO-R ^102Z5 , -COCO-R ^102Z5 , -O-R ^102Z5 , -SO _2- R ^102Z5 , -SO ₂ N (R ^102Z5 ) ₂ , -CON Substituents (first substituents) contained in (R ^102Z5 ) ₂ , -N (R ^102Z5 ) ₂ , -NHCO-R ^102Z5 , -NHCON (R ^102Z5 ) ₂ , -NHCOOR ^102Z5 , -OCON (R ^102Z5 ) _2. May be one or more, and the two or more substituents may be the same or different independently of each other.
Further, the first substituent may have another substituent (second substituent) bonded to the hydrocarbon group contained in a part thereof. The second substituent can be selected from the same groups as the first substituent.

The ^{rings formed by R 2Z5} and R ^3Z5 , R ^3Z5 and R ^4Z5 , and R ^4Z5 and R ^5Z5 are condensed with the benzene ring of the isoindoline skeleton of the compound represented by the formula (IZ5). The fused ring structures of the ring formed by R ^2Z5 and R ^3Z5 , R ^3Z5 and R ^4Z5 , and R ^4Z5 and R ^5Z5 and the benzene ring include inden, naphthalene, biphenylene, indacene, ashenanthrene, fluorene, phenanthrene, and phenanthrene. Hydrocyclic condensed ring structures such as anthracene, fluorantene, acephenanthrene, aceanthrene, triphenylene, pyrene, chrysene, N-methylphthalimide, N- (1-phenylethyl) phthalimide and tetracene, and their partial reductions ( For example, 9,10-dihydroanthracene, 1,2,3,4-tetrahydronaphthalene); indol, isoindole, indazole, quinoline, isoquinoline, phthalazine, quinoxaline, quinazoline, cinnoline, carbazole, carboline, phenanthrene, aclysine. , Perimidine, phenanthrene, phenazine and the like nitrogen-containing condensed heterocycles and their partial reductions; oxygen-containing condensation heterocycles such as 3-hydrobenzofuran 2-one and their partial reductions.

When R ^2Z5 and R ^3Z5 , R ^3Z5 and R ^4Z5 , and R ^4Z5 and R ^5Z5 form a ring, the ring may have a substituent. Examples of the ^{substituent, R N1Z5, R 1Z5, R} 2Z5, R 3Z5, R 4Z5, R 5Z5, R 6Z5, R 7Z5, which may have a hydrocarbon group represented by R ^101Z5 and R ^102Z5 substituted The same thing as the group can be mentioned. Preferred examples of the substituent, and ^{R N1Z5, R 1Z5, R 2Z5} , R 3Z5, R 4Z5, R 5Z5, R 6Z5, R 7Z5, have a hydrocarbon group represented by R ^101Z5 and R ^102Z5 The same preferred substituents may be mentioned.

When R ^{3Z 5} and R 4 ^{Z 5} form a ring, it is preferable that R ^{2Z 5} and R 5 ^{Z 5} are hydrogen atoms, amino groups and hydroxy groups independently of each other.
If R ^2Z5 and R ^3Z5 form a ring, R ^4Z5 and R ^5Z5 is preferably not form a ring, more preferably R ^4Z5 and R ^5Z5 is a hydrogen atom.
In the case where R ^4Z5 and R ^5Z5 form a ring, R ^2Z5 and R ^3Z5 is preferably not form a ring, more preferably R ^2Z5 and R ^3Z5 is a hydrogen atom.

R ^1Z5, R ^6Z5 and R ^7Z5 is preferably a hydrogen atom.

^RN1Z5 may have -CO-R ^102Z5 , -COO-R ^101Z5 , -CON (R ^102Z5 ) ₂ , -N (R ^102Z5 ) ₂ , -CO ₂ M or a substituent 1 to 1 It is preferably a hydrocarbon group of 40, more preferably a hydrocarbon group having 1 to 30 carbon atoms which may have a substituent, and may have a substituent of 1 to 20 carbon atoms. It is more preferably a hydrocarbon group of 1 to 15 carbon atoms which may have a substituent, and particularly preferably a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent. More preferably, it is a hydrocarbon group having 1 to 6 carbon atoms which may have a substituent or a hydrocarbon group having 1 to 5 carbon atoms which may have a substituent. It is particularly preferable to have a methyl group, an ethyl group, or a phenyl group, and more preferably a methyl group or an ethyl group.

^{At least one of R 2Z5} , R ^3Z5 , R ^4Z5 , and R ^5Z5 is -CO-R ^102Z5 , -COO-R ^101Z5 , from the viewpoint of reducing the phase difference value of the color filter formed from the coloring composition. -OCO-R ^102Z5 , -COCO-R ^102Z5 , -O-R ^102Z5 , -SO ₂ -R ^101Z5 , -SO ₂ N (R ^102Z5 ) ₂ ^{, -CON} (R 102Z5) ₂ , -N (R ^102Z5 ) ₂ , -NHCO-R ^102Z5 , -NHCO-N (R ^102Z5 ) ₂ , -NHCOOR ^102Z5 , -OCON (R ^102Z5 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, substituent It is preferable that it is a hydrocarbon group having 1 to 40 carbon atoms or a heterocyclic group which may have a substituent.
A hydrocarbon group having 1 to 40 carbon atoms, which may have a substituent, a halogen atom, -N (R ^102Z5 ) ₂ , a nitro group, and a hydrogen atom in which all or a part of the hydrocarbon atom is substituted with a fluorine atom has 1 to 1 carbon atoms. More preferably, there are 20 hydrocarbon groups, -NHCO-R ^102Z5 , ^{-OR 102Z5} , -SO ₃ M or -CO _{2 M.}
It is more preferably a hydrocarbon group having 1 to 40 carbon atoms which may have a nitro group or a substituent, and even more preferably a nitro group or a tert-butyl group. Alternatively, it is preferred that at least one set of ^{R 2Z 5} and R ^{3Z 5} , R ^{3Z 5} and R ^{4Z 5} , or R ^{4Z 5} and R 5 ^{Z 5 form a ring.}

From the viewpoint of reducing the phase difference value of the color filter formed from the coloring composition, at least one of ^{R 2Z5} , R ^3Z5 , R ^4Z5 , and R ^{5Z5 is used.}
A hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a halogen atom, -N (R ^102Z5 ) ₂ , a nitro group, and a fluorine atom in which all or a part of the hydrogen atom is substituted with a fluorine atom 1 to 1 20 hydrocarbon groups, preferably -NHCO-R ^102Z5 , ^{-OR 102Z5} , -SO ₃ M or -CO ₂ M, preferably.
It is more preferably a hydrocarbon group having 1 to 40 carbon atoms which may have a nitro group or a substituent, and even more preferably a nitro group or a tert-butyl group. Among them, R ^3Z5 is a nitro group or a tert-butyl group and R ^2Z5 , R ^4Z5 and R ^5Z5 are hydrogen atoms, or R ^2Z5 , R ^3Z5 and R ^5Z5 are hydrogen atoms and R ^4Z5 is nitro. It is even more preferably a group or a tert-butyl group.

Specific examples of the compound (IZ5) include compounds (IZ5-1) to compounds (IZ5-542) having substituents shown in Tables 1Z5 to 15Z5 or alkali metal salts thereof in the formula (IZ5-aa). Can be mentioned.
B ^a1Z5 B ^a2Z5 is a formula (BB2) to a formula (BB60), a formula (BBK2), a formula (BBK3), a formula (BBK4), a formula (BBK14), a formula (BBI1), a formula (BBO8), a formula (BBO10). , Represents any of the partial structures represented by the formula (BBD1) and the formula (BBJ2). Formulas (BB2) to formulas (BB60), formulas (BBK2), formulas (BBK3), formulas (BBK4), formulas (BBK14), formulas (BBI1), formulas (BBO8), formulas (BBO10), formulas (BBD1) and ^{The formula (BBJ2) represents B a1Z1} B ^a2Z1 of the formula (IZ1-aa) (BB2) to (BB60), the formula (BBK2), the formula (BBK3), the formula (BBK4), the formula (BBK14), the formula (BBI1). ), Equation (BBO8), Equation (BBO10), Equation (BBD1) and Equation (BBJ2). B ^a1Z5 and B ^a2Z5 represent a bond, respectively, and B ^a1Z5 is a formula (BB2) to a formula (BB60), a formula (BBK2), a formula (BBK3), a formula (BBK4), a formula (BBK14), a formula (BBI1). , formula (BBO8), formula (BBO10), formula (BBD1) and becomes a bond B ^A2Z5 is B ² when a bond of B ¹ of formula ^(BBJ2), B a1Z5 the expression (BB2) ~ formula (BB60 ), Formula (BBK2), Formula (BBK3), Formula (BBK4), Formula (BBK14), Formula (BBI1), Formula (BBO8), Formula (BBO10), Formula (BBD1) and Formula (BBJ2) B ²
When it is a bond of B ^{a2 Z5,} it is a bond of B ^1.
B ^a1Z5 B ^a2Z5 includes the formula (BB6), the formula (BB8), the formula (BB11), the formula (BB14), the formula (BB19), the formula (BB37), the formula (BB58), the formula (BBJ2), and the formula (BBO8). ) And the formula (BBO10) are preferable, and the formula (BB6) and the formula (BB19) are more preferable.

Each symbol in Tables 1Z5 to 15Z5 represents the following partial structure. In addition, in the partial structure
"Me" represents a methyl group
"Et" represents an ethyl group
"Bu" represents a butyl group
"TBu" represents a tert-butyl group and represents
"Hex" represents a hexyl group
"Oct" represents an octyl group
"2EH" represents a 2-ethylhexyl group and represents
"CHM" represents a cyclohexylmethyl group
"CH" represents a cyclohexyl group
"PH" represents a phenyl group
"BZ" represents a benzyl group
"NPR" represents a propyl group
"IPR" represents an isopropyl group
"IBu" represents an isobutyl group and represents
"EOE" stands for −CH ₂ CH ₂ OCH ₂ CH ₃
"ALL" represents an allyl group
"HYE" represents a 2-hydroxyethyl group
"COM" stands for -CO-CH ₃
"COE" stands for -COO-CH ₂ CH ₃
"OCM" stands for -OCO-CH ₃
"OME" stands for -O-CH ₃ and represents
"SOT" represents a tosyl group
“SNH” stands for −SO ₂ NH-CH ₂ CH (CH ₂ CH ₃ ) ((CH ₂ ) ₃ CH ₃ ).
“SN2” stands for −SO ₂ N (CH ₃ ) ((CH ₂ ) ₇ CH ₃ ).
"CNM" stands for -CONHCH ₃
"CN2" stands for -CON (CH ₃ ) C ₆ H ₅ and represents
"NPH" stands for -NHC ₆ H ₅ and represents
"NOT" stands for -N ((CH ₂ ) ₇ CH ₃ ) ₂
"NCO" stands for -NHCO ((CH ₂ ) ₄ CH ₃ )
"F" represents a fluorine atom
"Cl" represents a chlorine atom
"Br" represents a bromine atom
"CN" represents a cyano group
"NO2" represents a nitro group
"SUA" stands for -SO ₃ H
"CBA" stands for -CO ₂ H and represents
"CHO" stands for -CHO
"OCH" stands for -OCOH
"OH" stands for -OH
"SFM" stands for -SO ₂ NH ₂
"CBM" stands for -CONH _{2
"NH 2} " stands for -NH 2
"NCH" represents -NHCOH.
In the partial structure shown by the following formula, * represents a bond.

For example, the compound (IZ5-1) is a compound represented by the following formula (IZ5-1).

Compound (IZ5-1) to compound (IZ5-160) and compound (IZ5-247) to compound (IZ5-542) are preferable.
Compounds (IZ5-1) to compounds (IZ5-160) and compounds (IZ5-247) to compounds (IZ5-484) are more preferred.
Compounds (IZ5-1) to compounds (IZ5-160) are more preferred.
Compounds (IZ5-1) to compounds (IZ5-101) are even more preferred.
Compounds (IZ5-1) to compounds (IZ5-44) are particularly preferred.

Specific examples of the compound (IZ5) include compounds in which 1 to 3 hydrogen atoms contained in the compounds represented by Tables 1Z5 to 15Z5 are substituted with _{-SO 3} M or -CO _{2 M.} For example, a compound in which 1 to 3 sulfo groups are bonded to the compound (IZ5-1) in Table 1Z5 is represented by the following structure. However, in the formula, − (SO ₃ H) means that any hydrogen atom of the compound (IZ5-1) in Table 1Z5 is substituted.

Compounds (IZ5-1) to compound (IZ5-160) and compounds (IZ5-247) to compound (IZ5-542) to which 1 to 3 -SO ₃ M or -CO ₂ M are bound are preferable. ,
Compound (IZ5-1) to compound (IZ5-160) and compound (IZ5-247) to compound (IZ5-484) to which 1 to 3 -SO ₃ M or -CO ₂ M are bound are added. Preferably
_{Compounds in which 1 to 3 -SO 3} M or -CO ₂ M are bound to compound (IZ5-1) to compound (IZ5-160) are more preferable.
Compounds (IZ5-1) to compounds (IZ5-101) to which 1 to 3 -SO ₃ M or -CO ₂ M are bound are even more preferable.
_{Compounds in which 1 to 3 -SO 3} M or -CO ₂ M are bound to compound (IZ5-1) to compound (IZ5-44) are particularly preferable.

As the compound (IZ5), in the formula (IZ5),
R ^N1Z5 may have a substituent selected from the group consisting of -CO-R ^102Z5 , -COO-R ^101Z5 , -CON (R ^102Z5 ) ₂ , or -SO ₃ M and -CO _{2 M.} It is a hydrocarbon group having 1 to 20 carbon atoms.
R ^1Z5 is a hydrocarbon group having 1 to 20 carbon atoms, which may have a substituent selected from the group consisting of a hydrogen atom, -SO ₃ M and -CO _{2 M, -SO 3} M or -CO ₂ M and
In R ^{2Z5 to} R ^5Z5 , hydrogen atom, hydrocarbon group having 1 to 20 carbon atoms, halogen atom, -N (R 102Z5) ₂ , nitro group, and all or part of hydrogen atom are independently ^{composed of hydrogen atom.} Substituted hydrocarbon groups with 1 to 20 carbon atoms, -NHCO-R ^102Z5 , ^{-OR 102Z5} , -SO ₃ M or -CO ₂ M.
At ^{least one of R 2Z5 to} R ^5Z5 has a hydrocarbon group having 1 to 20 carbon atoms, a halogen atom, -N (R ^102Z5 ) ₂ , a nitro group, and a number of carbon atoms in which all or part of a hydrogen atom is replaced by a fluorine atom. 1 to 20 hydrocarbon groups, -NHCO-R ^102Z5 , ^{-OR 102Z5} , -SO ₃ M or -CO ₂ M.
R ^6Z5 and R ^7Z5 are independent of each other and may have a substituent selected from the group consisting of a hydrogen atom, −SO ₃ M and −CO ₂ M, a hydrocarbon group having 1 to 20 carbon atoms, −. SO ₃ M or -CO ₂ M,
R ^102Z5 is a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent selected from the group consisting of _{-SO 3} M and -CO _{2 M.}
R ^101Z5 is a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent selected from the group consisting of _{-SO 3} M and -CO _{2 M.}
M is preferably a compound which is a hydrogen atom or an alkali metal atom.
^RN1Z5 may have a substituent selected from the group consisting of -CO-R ^102Z5 , -CON (R ^102Z5 ) ₂ , or -SO ₃ M and -CO _{2 M and having 1 to 10 carbon atoms.} It is a hydrocarbon group and
R ^1Z5 is a hydrogen atom
In R ^{2Z5 to} R ^5Z5 , hydrogen atom, hydrocarbon group having 1 to 10 carbon atoms, halogen atom, -N (R 102Z5) ₂ , nitro group, and all or part of hydrogen atom are independently ^{composed of hydrogen atom.} Substituted hydrocarbon groups with 1 to 10 carbon atoms, -NHCO-R ^102Z5 , ^{-OR 102Z5} , -SO ₃ M or -CO ₂ M.
At ^{least one of R 2Z5 to} R ^5Z5 has a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, -N (R ^102Z5 ) ₂ , a nitro group, and a number of carbon atoms in which all or part of a hydrogen atom is replaced by a fluorine atom. 1-10 hydrocarbon groups, -NHCO-R ^102Z5 , ^{-OR 102Z5} , -SO ₃ M or -CO ₂ M.
R ^6Z5 and R ^7Z5 are hydrocarbons having 1 to 10 carbon atoms which are the same group and may have a hydrogen atom or a substituent selected from the group consisting of _{-SO 3} M and -CO _{2 M.} Is the basis and
R ^102Z5 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of _{-SO 3} M and -CO _{2 M.}
R ^101Z5 is a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of _{-SO 3} M and -CO _{2 M.}
M is more preferably a compound which is a hydrogen atom or an alkali metal atom.
^RN1Z5 may have a substituent selected from the group consisting of -CO-R ^102Z5 , -CON (R ^102Z5 ) ₂ , or -SO ₃ M and -CO _{2 M and having 1 to 10 carbon atoms.} It is a hydrocarbon group and
R ^1Z5 is a hydrogen atom
R ^{2Z5 to} R ^5Z5 are independently hydrogen atom, hydrocarbon group having 1 to 10 carbon atoms, halogen atom, -N (R ^102Z5 ) ₂ , nitro group, trifluoromethyl group, ^{-OR 102Z5} , respectively. -SO ₃ M or -CO ₂ M,
At ^{least one of R 2Z5 to} R ^5Z5 is a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, -N (R ^102Z5 ) ₂ , a nitro group, a trifluoromethyl group, ^{-OR 102Z5} , -SO ₃ M. Or -CO ₂ M,
R ^6Z5 and R ^7Z5 are the same group, a hydrogen atom, or a hydrocarbon group having 1 to 10 carbon atoms.
R ^102Z5 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of _{-SO 3} M and -CO _{2 M.}
R ^101Z5 is a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of _{-SO 3} M and -CO _{2 M.}
M is more preferably a compound which is a hydrogen atom or an alkali metal atom.

Compound (IZ5) when R ^1Z5 is a hydrogen atom, the compound represented by the formula (pt1Z5) (hereinafter sometimes referred to phthalonitrile compound) a compound represented by the formula (pt2Z5) (hereinafter, referred alkoxide compound It can be produced by further reacting the compound represented by the formula (pt3Z5) with the compound represented by the formula (pt4Z5) in the presence of an acid. Also when R ^1Z5 is other than hydrogen atom, can be prepared a compound (IZ5) by further reacting a compound of formula (pt5Z5).

Expression (pt1Z5), formula (pt2Z5), formula (pt3Z5), formula (pt4Z5), wherein (pt5Z5) and formula ^{(IZ5), R N1Z5, R} 1Z5, R 2Z5, R 3Z5, R 4Z5, R 5Z5, R ^6Z5 and R ^7Z5 have the same meanings as described above.
R ^14Z5 represents an alkyl group having 1 to 20 carbon atoms.
M ^1Z5 represents an alkali metal atom.
LG represents a halogen atom, a methanesulfonyloxy group, a toluenesulfonyloxy group or a trifluoromethanesulfonyloxy group. ]

^Examples of the alkyl group having 1 to 20 carbon atoms represented by R 14Z5 include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, a sec-butyl group and a tert-butyl group, which are preferable. Examples include alkyl groups having 1 to 6 carbon atoms.
Examples of the alkali metal atom represented by M ^{1Z 5} include a lithium atom, a sodium atom and a potassium atom.

The amount of the alkoxide compound used is usually 0.1 to 10 mol, preferably 0.2 to 5 mol, and more preferably 0.3 to 3 mol, based on 1 mol of the phthalonitrile compound. More preferably, it is 0.4 to 2 mol.

The amount of the compound (pt3Z5) used is usually 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, still more preferably 1 mol, relative to 1 mol of the phthalonitrile compound. ~ 2 mol.
The amount of the compound (pt4Z5) used is usually 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, still more preferably 1 mol, relative to 1 mol of the phthalonitrile compound. ~ 2 mol.

Examples of the acid include inorganic acids such as hydrochloric acid, hydrobromic acid, hydroiodic acid, sulfuric acid, nitric acid, fluorosulfonic acid and phosphoric acid; sulfonic acids such as methanesulfonic acid, trifluoromethanesulfonic acid and p-toluenesulfonic acid; Examples thereof include carboxylic acids such as acetic acid, citric acid, formic acid, gluconic acid, lactic acid, oxalic acid and tartrate acid, preferably hydrochloric acid, hydrobromic acid, sulfuric acid, methanesulfonic acid, trifluoromethanesulfonic acid, p-toluenesulfonic acid and Examples include carboxylic acids, more preferably acetic acids.
The amount of the acid used is usually 1 to 20 mol, preferably 1 to 10 mol, more preferably 1 to 8 mol, still more preferably 1 to 6 mol, based on 1 mol of the phthalonitrile compound. be.

The reaction of the phthalonitrile compound, the alkoxide compound, the compound (pt3Z5) and the compound (pt4Z5) is usually carried out in the presence of a solvent.
As the solvent, water; a nitrile solvent such as acetonitrile; an alcohol solvent such as methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol and 1-octanol; an ether solvent such as tetrahydrofuran; a ketone solvent such as acetone; acetic acid. Ester solvents such as ethyl; aliphatic hydrocarbon solvents such as hexane; aromatic hydrocarbon solvents such as toluene; halogenated hydrocarbon solvents such as methylene chloride and chloroform; amides such as N, N-dimethylformaldehyde and N-methylpyrrolidone. Solvents: Sulfoxide solvents such as dimethylsulfoxide, preferably water, nitrile solvents, alcohol solvents, ether solvents, ketone solvents, ester solvents, aromatic hydrocarbon solvents, halogenated hydrocarbon solvents, amide solvents and sulfoxide solvents. More preferably, water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, tetrahydrofuran, acetone, ethyl acetate, toluene, methylene chloride, chloroform, N, N-dimethylformaldehyde. , N-Methylpyrrolidone and dimethylsulfoxide, more preferably water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, acetone, methylene chloride, chloroform, N, N. -Dimethylformaldehyde, N-methylpyrrolidone and dimethylsulfoxide are mentioned, and water, acetonitrile, methanol, ethanol and 2-propanol are particularly preferable.
The amount of the solvent used is usually 1 to 1000 parts by mass with respect to 1 part by mass of the phthalonitrile compound.

The reaction temperature is usually 0 to 200 ° C, preferably 0 to 100 ° C, more preferably 0 to 70 ° C, still more preferably 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

The amount of compound (pt5Z5) the compound R ^1Z5 is a hydrogen atom (IZ5) relative to 1 mol, usually 1 to 10 moles, preferably 1 to 5 mol, more preferably 1 to 3 moles It is more preferably 1 to 2 mol.

When the compound (pt5Z5) is reacted, it is preferable that a base coexists. Bases include organic bases such as triethylamine, 4- (N, N-dimethylamino) pyridine, pyridine and piperidine; metal alkoxides such as sodium methoxide, sodium ethoxide, sodium tert-butoxide and potassium tert-butoxide; butyl lithium. , Tert-Organic metal compounds such as butyllithium and phenyllithium; and inorganic bases such as lithium hydroxide, sodium hydroxide and potassium hydroxide.

The amount of the base to be used, the compound R ^1Z5 is a hydrogen atom (IZ5) relative to 1 mol, usually 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 moles, more It is preferably 1 to 2 mol.

The reaction of compound (pt5Z5) is usually carried out in the presence of a solvent. The solvent can be selected from the same range as described above.
The amount of solvent used relative to the compound R ^1Z5 is a hydrogen atom (IZ5) 1 part by weight, it is usually 1 to 1000 parts by weight. The reaction temperature of the compound (pt5Z5) is usually −90 to 200 ° C., preferably −80 to 100 ° C., and more preferably 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

If compound (IZ5) _{does not have a sulfo group or -SO 3} M ²² , the compound (IZ 5) is reacted with a sulphonizing agent such as fuming sulfuric acid or chlorosulfuric acid to cause a sulfo group or -SO ₃ M ^22. Can be introduced.
M ²² represents an alkali metal atom.
Examples ^{of the alkali metal atom represented by M 22} include a lithium atom, a sodium atom and a potassium atom.

_{The amount of SO 3} used in fuming sulfuric acid is usually 1 to 50 mol, preferably 5 to 40 mol, more preferably 5 to 30 mol, still more preferably 5 to 30 mol, per 1 mol of compound (IZ5). It is 5 to 25 mol.
The amount of sulfuric acid used in fuming sulfuric acid is usually 1 to 200 mol, preferably 10 to 100 mol, more preferably 10 to 75 mol, and further preferably 10 to 1 mol of compound (IZ5). ~ 50 mol.

The amount of chlorosulfonic acid used is usually 1 to 500 mol, preferably 10 to 300 mol, more preferably 10 to 200 mol, still more preferably 10 to 150 mol, relative to 1 mol of compound (IZ5). It is a mole.

The reaction temperature for sulfonation is usually -20 to 200 ° C, preferably -10 to 100 ° C, and more preferably 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

The method for extracting the compound (IZ5) from the reaction mixture is not particularly limited, and the compound (IZ5) can be extracted by various known methods. For example, after completion of the reaction, the compound (IZ5) can be taken out by filtering the reaction mixture. Further, after filtration, the obtained residue may be subjected to column chromatography, recrystallization or the like. Further, after completion of the reaction, the solvent of the reaction mixture may be distilled off and then purified by column chromatography.

<Compound (IZ6)>
Compound (IZ6) is represented by the formula (IZ6).

[In formula (IZ6), D represents a structure having an isoindoline skeleton. Z is, -SO ₃ ^- represents a ^- or -CO _2. A ^{c +} represents a c-valent metal cation. a represents an integer of 1 to 10. b represents an integer of 1 or more. c represents an integer of 2 to 10. d represents an integer of 1 or more.
When a plurality of D, Z, a or ^{Ac +} exist, they may be the same or different from each other.
The formula (I'Z6) and the formula (I''Z6) represent the partial structure of the formula (IZ6), respectively, and D, Z, Ac ⁺ , a, b, c and d are those in the formula (IZ6). Represents the same thing as.
However, the absolute value of the negative valence of the substructure represented by the formula (I'Z6) and the positive valence of the substructure represented by the formula (I ″ Z6) are the same. ]

The integer represented by a is 1 to 10, preferably 1 to 8, more preferably 1 to 6, and even more preferably 1 to 4.

The integer represented by b is 1 or more, preferably 1 to 10, and more preferably 1 to 8.

The integer represented by c is 2 to 10, preferably 2 to 8, more preferably 2 to 6, and even more preferably 2 to 4.

The integer represented by d is 1 or more, preferably 1 to 10, and more preferably 1 to 8.

Z is preferably -CO ₂ ^- a.

^{Ac +} represents a divalent or higher valent metal cation.
As a divalent or higher metal cation,
Examples include metal cations of groups 2 to 15 of the periodic table of elements, preferably Mg ²⁺ , Ca ²⁺ , Sr ²⁺ , Ba ²⁺ , Cd ²⁺ , Ni ²⁺ , Zn ²⁺ , Divalent metal cations such as Cu ²⁺ , Hg ²⁺ , Fe ²⁺ , Co ²⁺ , Sn ²⁺ , Pb ²⁺ and Mn ^2+;
Trivalent metal cations such as Al ³⁺ , Fe ³⁺ and Cr ^3+;
Examples include tetravalent metal cations such as ^{Sn 4+} and Mn ^{4+ , more preferably Mg 2+} , Ca ²⁺ , Sr ²⁺ , Ba ²⁺ , Ni ²⁺ , Zn ²⁺ , Cu ²⁺ , Fe ²⁺ , Co ²⁺ , Sn ²⁺ , Mn ²⁺ , Al ³⁺ , Fe ³⁺ , Cr ³⁺ , Sn ⁴⁺ and Mn ⁴⁺ , more preferably Mg ²⁺ , Ca ²⁺ , ^Examples thereof include Sr ²⁺ , Ba ²⁺ , Zn ²⁺ , Cu ²⁺ , Fe ²⁺ , Mn ²⁺ , Al ³⁺ , Fe ³⁺ , Cr ³⁺ and Mn 4+.

The compound represented by the formula (IZ6) is preferably a compound represented by the formula (IZ6-A) (hereinafter, may be referred to as a compound (IZ6-A)).

[In the formula (IZ6-A),
A ^{c +} , b, c and d have the same meanings as described above.
R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 and R ^13AZ6 are independent of each other, hydrogen atom, -CO-R ^102AZ6 , -COO-R ^101AZ6 , -OCO- R ^102AZ6 , -COCO-R ^102AZ6 , ^{-OR 102AZ6} , -SO _2- R ^101AZ6 , -SO ₂ N (R ^102AZ6 ) ₂ ^{, -CON} (R 102AZ6) ₂ , -N (R ^102AZ6 ) ₂ , -NHCO ^{-R 102AZ6, -NHCO-N (R} 102AZ6) 2, -NHCOOR 102AZ6, -OCON (R 102AZ6) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , -SO 3 -, -CO ₂ ^-, a hydrocarbon group or optionally substituted heterocyclic group having carbon atoms of 1 to 40 which may have a substituent.
R ^2AZ6 and R ^3AZ6 , R ^3AZ6 and R ^4AZ6 , R ^4AZ6 and R ^5AZ6 , ^RAA1Z6 and ^RAA2Z6 and R ^12AZ6 and R ^13AZ6 may be bonded to each other to form a ring, respectively.
R ^101AZ6 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent independently of each other.
R ^102AZ6 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent, independently of each other.
M represents a hydrogen atom or an alkali metal atom.
Formulas (IZ6-A') and formulas (IZ6-A'') represent substructures of formula (IZ6-A), respectively, Ac ⁺ , b, c, d, R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 ,
R ^AA2Z6 , R ^12AZ6 and R ^13AZ6 represent the same as in formula (IZ6-A).
If there are multiple R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 , R ^102AZ6 , M, c or ^{Ac +} , they are the same. It may be present or different.
R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6 are at least one of (ra-i) to (ra-iii). and fulfill ^{the, R 1AZ6, R 2AZ6, R} 3AZ6, R 4AZ6, R 5AZ6, R AA1Z6, R AA2Z6, R 12AZ6, R 13AZ6, R 101AZ6 and -SO ₃ R ^102AZ6 has ^- or -CO ₂ ^- of The total number is a.
At least one ^{(ra-i) R 1AZ6,} R 2AZ6, R 3AZ6, R 4AZ6, R 5AZ6, R AA1Z6, R AA2Z6, R 12AZ6 and R ^13AZ6 is, -SO ₃ ^- or -CO ₂ ^- a.
^(Ra -ii) At least one of R 1AZ6, R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 and R ^13AZ6 is -CO-R ^102AZ6 , -COO-R ^101AZ6 , -OCO. -R ^102AZ6 , -COCO-R ^102AZ6 , -O-R ^102AZ6 , -SO ₂ -R ^101AZ6 , -SO ₂ N (R ^102AZ6 ) ₂ ^{, -CON} (R 102AZ6) ₂ , -N (R ^102AZ6 ) _2, - _{^{NHCO-R 102AZ6, -NHCO-N}} (R 102AZ6) 2, -NHCOOR 102AZ6, or -OCON (R ^102AZ6) a _2, wherein R ^101AZ6 and R ^102AZ6 is, -SO ₃ ^- having ^- or -CO ₂ hydrocarbon group or a -SO ₃ having 1 to 40 carbon atoms ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
^{(Ra-iii) R 1AZ6,} R 2AZ6, R 3AZ6, R 4AZ6, R 5AZ6, at least one of R ^AA1Z6, R ^AA2Z6, R ^12AZ6 and R ^13AZ6 is, -SO ₃ ^- or -CO ₂ ^- carbons having 1 40 hydrocarbon group or -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group and heterocyclic group, -SO ₃ ^- or -CO ₂ ^- may have other substituents.
a represents the same meaning as in the equation (IZ6). When a plurality of a exist, they may be the same or different.
The absolute value of the negative valence of the substructure represented by the formula (IZ6-A') and the positive valence of the substructure represented by the formula (IZ6-A'') are the same.
The wavy line represents an E-form or a Z-form. ]

The number of carbon atoms of the hydrocarbon groups represented by ^{R 1AZ6} , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^{102AZ6 is 1 to 40.} It is preferably 1 to 30, more preferably 1 to 20, still more preferably 1 to 15, and particularly preferably 1 to 10.

The hydrocarbon groups having 1 to 40 carbon atoms represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^{102AZ6 are aliphatic hydrocarbons.} It may be a hydrogen group and an aromatic hydrocarbon group, and the aliphatic hydrocarbon group may be saturated or unsaturated, or may be a chain or an alicyclic.

The saturated or unsaturated chain hydrocarbon group represented by ^{R 1AZ6} , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^{102AZ6 is a methyl group.} , Ethyl group, propyl group, butyl group, pentyl group, hexyl group, heptyl group, octyl group, nonyl group, decyl group, undecyl group, dodecyl group, heptadecyl group, octadecyl group, icosyl group and other linear alkyl groups, etc. Isopropyl group, isobutyl group, sec-butyl group, tert-butyl group, (2-ethyl) butyl group, isopentyl group, neopentyl group, tert-pentyl group, (1-methyl) pentyl group, (2-methyl) pentyl Branched chain such as group, (1-ethyl) pentyl group, (3-ethyl) pentyl group, isohexyl group, (5-methyl) hexyl group, (2-ethyl) hexyl group and (3-ethyl) heptyl group. Alkyl group, etc .; vinyl group, 1-propenyl group, 2-propenyl group (allyl group), (1-methyl) ethenyl group, 2-butenyl group, 3-butenyl group, 1,3-butadienyl group, (1-( 2-Propenyl)) Ethenyl groups, alkenyl groups such as (1,2-dimethyl) propenyl groups and 2-pentenyl groups; and the like. The saturated or unsaturated chain hydrocarbon group preferably has 1 to 30 carbon atoms, more preferably 1 to 20 carbon atoms, and further preferably 1 to 15 carbon atoms. Among them, a linear or branched alkyl group having 1 to 10 carbon atoms, more preferably 1 to 8 carbon atoms, and even more preferably 1 to 5 carbon atoms is particularly preferable.

The ^{R 1AZ6, R 2AZ6, R 3AZ6} , R 4AZ6, R 5AZ6, R AA1Z6, R AA2Z6, R 12AZ6, R 13AZ6, saturated or unsaturated alicyclic hydrocarbon group represented by R ^101AZ6 and R ^102AZ6, cyclo Propyl group, 1-methylcyclopropyl group, cyclobutyl group, cyclopentyl group, cyclohexyl group, cycloheptyl group, 1-methylcyclohexyl group, 2-methylcyclohexyl group, 3-methylcyclohexyl group, 4-methylcyclohexyl group, 1,2 -Dimethylcyclohexyl group, 1,3-dimethylcyclohexyl group, 1,4-dimethylcyclohexyl group, 2,3-dimethylcyclohexyl group, 2,4-dimethylcyclohexyl group, 2,5-dimethylcyclohexyl group, 2,6-dimethyl Cyclohexyl group, 3,4-dimethylcyclohexyl group, 3,5-dimethylcyclohexyl group, 2,2-dimethylcyclohexyl group, 3,3-dimethylcyclohexyl group, 4,4-dimethylcyclohexyl group, cyclooctyl group, 2,4 , 6-trimethylcyclohexyl group, 2,2,6,6-tetramethylcyclohexyl group and 3,3,5,5-tetramethylcyclohexyl group, 4-pentylcyclohexyl group, 4-octylcyclohexyl group, 4-cyclohexylcyclohexyl group Cycloalkyl groups such as: cyclohexenyl groups (eg, cyclohex-2-ene, cyclohexa-3-ene), cycloalkenyl groups such as cycloheptenyl and cyclooctenyl groups; norbornan, adamantyl, bicyclo [2.2.2] octane. And so on. The saturated or unsaturated alicyclic hydrocarbon group preferably has 3 to 30, more preferably 3 to 20, even more preferably 4 to 20, and even more preferably 4 to 15. Yes, more particularly preferably 5 to 15, and most preferably 5 to 10. Of these, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, and a cyclooctyl group are particularly preferable.

The ^{aromatic hydrocarbon groups represented by R 1AZ6} , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6 include phenyl group and o-trill. Group, m-tolyl group, p-tolyl group, 2-ethylphenyl group, 3-ethylphenyl group, 4-ethylphenyl group, 2,3-dimethylphenyl group, 2,4-dimethylphenyl group, 2,5- Dimethylphenyl group, 2,6-dimethylphenyl group, 3,4-dimethylphenyl group, 3,5-dimethylphenyl group, 4-vinylphenyl group, o-isopropylphenyl group, m-isopropylphenyl group, p-isopropylphenyl Group, o-tert-butylphenyl group, m-tert-butylphenyl group, p-tert-butylphenyl group, mesityl group, 4-ethylphenyl group, 4-butylphenyl group, 4-pentylphenyl group, 2,6 -Bis (2-propyl) phenyl group, 4-cyclohexylphenyl group, 2,4,6-trimethylphenyl group, 4-octylphenyl group, 1-naphthyl group, 2-naphthyl group, 5,6,7,8- Examples thereof include tetrahydro-1-naphthyl group, 5,6,7,8-tetrahydro-2-naphthyl group, fluorenyl group, phenyl group and aromatic hydrocarbon group such as anthryl group and pyrenyl group; and the like. The number of carbon atoms of the aromatic hydrocarbon group is preferably 6 to 30, more preferably 6 to 20, and even more preferably 6 to 15.

The ^{hydrocarbon groups represented by R 1AZ6} , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6 are the above-mentioned hydrocarbon groups (for example, It may be a group in which an aromatic hydrocarbon group is combined with at least one of a chain hydrocarbon group and an alicyclic hydrocarbon group), such as a benzyl group, a phenethyl group and a 1-methyl-1-phenylethyl group. Aralkyl group; arylalkenyl group such as phenylethenyl group (phenylvinyl group); arylalkynyl group such as phenylethynyl group; phenyl group to which one or more phenyl groups such as biphenylyl group and terphenylyl group are bonded; cyclohexylmethylphenyl Examples include a group, a benzyl phenyl group, a (dimethyl (phenyl) methyl) phenyl group and the like.
The ^{groups represented} by R 1AZ6, R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6 are the hydrocarbon groups listed above (for example, chain). As a group combining a hydrocarbon group and an alicyclic hydrocarbon group, for example, a cyclopropylmethyl group, a cyclopropylethyl group, a cyclobutylmethyl group, a cyclobutylethyl group, a cyclopentylmethyl group, a cyclopentylethyl group, a cyclohexylmethyl group. , 2-Methylcyclohexylmethyl group, cyclohexylethyl group, adamantylmethyl group and the like may be an alkyl group to which one or more alicyclic hydrocarbon groups are bonded.
These carbon numbers are preferably 4 to 30, more preferably 6 to 30, even more preferably 6 to 20, still preferably 4 to 20, and even more preferably 4 to 15. , Particularly preferably 6 to 15.

The hydrocarbon groups represented by ^{R 1AZ6} , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , ^RAA1Z6 , ^RAA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^{102AZ6 may have substituents.} .. The substituent may be monovalent or divalent. The divalent substituent preferably has two bonds bonded to the same carbon atom to form a double bond.
As the monovalent substituent,
Methoxy group, ethoxy group, propoxy group, isopropoxy group, butoxy group, isobutoxy group, sec-butoxy group, tert-butoxy group, pentyloxy group, hexyloxy group, (2-ethyl) hexyloxy group, heptyloxy group, Octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, dodecyloxy group, (2-ethyl) hexyloxy group, icosyloxy group, 1-phenylethoxy group, 1-methyl-1-phenylethoxy group, phenyloxy group , O-Trilloxy group, 2,3-dimethylphenyloxy group, 2,4-dimethylphenyloxy group, 2,5-dimethylphenyloxy group, 2,6-dimethylphenyloxy group, 3,4-dimethylphenyloxy group , 3,5-dimethylphenyloxy group, 2,2-dicyanophenyloxy group, 2,3-dicyanophenyloxy group, 2,4-dicyanophenyloxy group, 2,5-dicyanophenyloxy group, 2,6- Dicyanophenyloxy group, 3,4-dicyanophenyloxy group, 3,5-dicyanophenyloxy group, 4-methoxyphenyloxy group, 2-methoxyphenyloxy group, 3-methoxyphenyloxy group, 4-ethoxyphenyloxy group , 2-ethoxyphenyloxy group, 3-ethoxyphenyloxy group, etc., and groups represented by the following formulas, etc., which have 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or a derivatizing group thereof. (For example, a group derivatized with a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), or the like). Is an oxy group bonded to one side;

Methylthio group, ethylthio group, propylthio group, butylthio group, tert-butylthio group, pentylthio group, hexylthio group, (2-ethyl) hexylthio group, heptylthio group, octylthio group, nonylthio group, decylthio group, undecylthio group, dodecylthio group, icosylthio group. A sulfanyl group to which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group, a phenylthio group and an o-tolylthio group is bonded;

Epoxy group, oxetanyl group, tetrahydrofuryl group, tetrahydropyranyl group;
Holmil group;
Acetyl group, propanoyl group, butanoyl group, 2,2-dimethylpropanoyl group, pentanoyl group, hexanoyl group, (2-ethyl) hexanoyl group, heptanoil group, octanoyl group, nonanoyl group, decanoyl group, undecanoyl group, dodecanoyl group, A hydrocarbon group having a carbon number of 1 to 20 (preferably having a carbon number of 1 to 11) or an inducible group thereof (for example, a carboxy group or a sulfo group) such as a henicosanoyl group, a benzoyl group, and a group represented by the following formula. , A carbonyl group to which a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. are bonded. When the carbonyl group is an alkanoyl group, the number of carbon atoms is preferably 2 to 12);

Methoxycarbonyl group, ethoxycarbonyl group, propoxycarbonyl group, butoxycarbonyl group, tert-butoxycarbonyl group, pentyloxycarbonyl group, hexyloxycarbonyl group, (2-ethyl) hexyloxycarbonyl group, heptyloxycarbonyl group, octyloxycarbonyl group Group, nonyloxycarbonyl group, decyloxycarbonyl group, undecyloxycarbonyl group, dodecyloxycarbonyl group, icosyloxycarbonyl group, phenyloxycarbonyl group, o-tolyloxycarbonyl group, etc., and represented by the following formula A hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), a carbon number of carbon atoms). An oxycarbonyl group to which 1 to 10 alkylsulfamoyl groups (preferably groups derivatized with an octylsulfamoyl group) or the like are attached;

Amino group;
N-methylamino group, N, N-dimethylamino group, N-ethylamino group, N, N-diethylamino group, N-propylamino group, N, N-dipropylamino group, N-isopropylamino group, N, N-diisopropylamino group, N-butylamino group, N, N-dibutylamino group, N-isobutylamino group, N, N-diisobutylamino group, N-sec-butylamino group, N, N-disec-butyl Amino group, N-tert-butylamino group, N, N-ditert-butylamino group, N-pentylamino group, N, N-dipentylamino group, N- (1-ethylpropyl) amino group, N, N -Di (1-ethylpropyl) amino group, N-hexylamino group, N, N-dihexylamino group, N- (2-ethyl) hexylamino group, N, N-di (2-ethyl) hexylamino group, N-Heptylamino Group, N, N-Diheptylamino Group, N-octylamino Group, N, N-Dioctylamino Group, N-Nonylamino Group, N, N-Dinonylamino Group, N-Phenylamino Group, N, N -Diphenylamino group, N, N-ethylmethylamino group, N, N-propylmethylamino group, N, N-isopropylmethylamino group, N, N-butylmethylamino group, N-decylamino group, N, N- Decylmethylamino Group, N-Undecylamino Group, N, N-Undecylmethylamino Group, N-Dodecylamino Group, N, N-Dodecylmethylamino Group, N-Icosylamino Group, N, N-Icosylmethylamino One or two carbon atoms 1 to 20 (preferably 1 carbon atom) such as a group, an N, N-tert-butylmethylamino group, an N, N-phenylmethylamino group, etc., and a group represented by the following formula. A hydrocarbon group of 10) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), and an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsul). Amino group substituted with a famoyl group) or a derivatized group);

Sulfamoyl group;
N-methylsulfamoyl group, N, N-dimethylsulfamoyl group, N-ethylsulfamoyl group, N, N-diethylsulfamoyl group, N-propylsulfamoyl group, N, N-dipropyls Rufamoyl group, N-isopropylsulfamoyl group, N, N-diisopropylsulfamoyl group, N-butylsulfamoyl group, N, N-dibutylsulfamoyl group, N-isobutylsulfamoyl group, N, N-diisobutylsulfamoyl group, N-sec-butylsulfamoyl group, N, N-disec-butylsulfamoyl group, N-tert-butylsulfamoyl group, N, N-ditert-butylsul Famoyl group, N-pentyl sulfamoyl group, N, N-dipentyl sulfamoyl group, N- (1-ethylpropyl) sulfamoyl group, N, N-di (1-ethylpropyl) sulfamoyl group, N-hexyl Sulfamoyl group, N, N-dihexyl sulfamoyl group, N- (2-ethyl) hexyl sulfamoyl group, N, N-di (2-ethyl) hexyl sulfamoyl group, N-heptyl sulfamoyl Group, N, N-diheptyl sulfamoyl group, N-octyl sulfamoyl group, N, N-dioctyl sulfamoyl group, N, N-octylmethyl sulfamoyl group, N-nonyl sulfamoyl group, N, N-Dinonyl sulfamoyl group, N-phenyl sulfamoyl group, N, N-diphenyl sulfamoyl group, N, N-ethylmethyl sulfamoyl group, N, N-propylmethyl sulfamoyl group, N, N-isopropylmethylsulfamoyl group, N, N-butylmethylsulfamoyl group, N-decylsulfamoyl group, N, N-decylmethylsulfamoyl group, N-undecylsulfamoyl group, N , N-Undecylmethyl Sulfamoyl Group, N-Dodecyl Sulfamoyl Group, N, N-Dodecyl Methyl Sulfamoyl Group, N-Icosyl Sulfamoyl Group, N, N-Icosyl Methyl Sulfamoyl Group, N, N-tert-butylmethylsulfamoyl group, N, N-phenylmethylsulfamoyl group, etc., and one or two groups represented by the following formula, etc., having 1 or 2 carbon atoms (preferably carbons) A hydrocarbon group having a number of 1 to 10 or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), and an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably). Induced by octylsulfamoyl group) etc. Sulfamoyl group substituted with (ta group);

Formylamino group; acetylamino group, propanoylamino group, butanoylamino group, 2,2-dimethylpropanoylamino group, pentanoylamino group, hexanoylamino group, (2-ethyl) hexanoylamino group, heptanoil Amino group, octanoylamino group, nonanoylamino group, decanoyylamino group, undecanoylamino group, dodecanoylamino group, henicosanoylamino group, benzoylamino group, etc., and groups represented by the following formulas. Etc., a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 12 carbon atoms) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), 1 carbon atom). A carbonylamino group to which 10 to 10 alkylsulfamoyl groups (preferably groups derivatized with an octylsulfamoyl group) or the like are bonded (when the carbonylamino group is an alkanoylamino group, the number of carbon atoms is preferably 1. ~ 12);

Hydroxy group;
Halogen atoms such as fluorine atom, chlorine atom, bromine atom and iodine atom;
Carboxy group, -CO ₂ M ² (M ² is alkali metal, preferably lithium, sodium, potassium); sulfo group, -SO ₃ M ² (M ² is alkali metal, preferably lithium, sodium, potassium); nitro group Cyan group;

Formyloxy group; acetoxy group, propanoyloxy group, butanoyloxy group, 2,2-dimethylpropanoyloxy group, pentanoyloxy group, hexanoyloxy group, (2-ethyl) hexanoyloxy group, heptanoyloxy group Carbons such as groups, octanoyloxy groups, nonanoyloxy groups, decanoyloxy groups, undecanoyloxy groups, dodecanoyloxy groups, henicosanoyloxy groups, benzoyloxy groups, etc., and groups represented by the following formulas. A hydrocarbon group having a number of 1 to 20 (preferably 1 to 10 carbon atoms) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), and a group having 1 to 10 carbon atoms. A carbonyloxy group to which an alkylsulfamoyl group (preferably a group derivatized with an octylsulfamoyl group) or the like is bonded (when the carbonyloxy group is an alkanoyloxy group, the number of carbon atoms is preferably 1 to 10). be);

Methylsulfonyl group, ethylsulfonyl group, propylsulfonyl group, butylsulfonyl group, pentylsulfonyl group, hexylsulfonyl group, (2-ethyl) hexylsulfonyl group, heptylsulfonyl group, octylsulfonyl group, nonylsulfonyl group, decylsulfonyl group, un Decylsulfonyl group, dodecylsulfonyl group, icosylsulfonyl group, phenylsulfonyl group, p-tolylsulfonyl group and the like, and groups represented by the following formulas having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms). A hydrocarbon group or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group)). Sulfonyl group to which (groups derivatized by etc.) are bound;

Carbamic group;
N-Methylcarbamoyl group, N, N-dimethylcarbamoyl group, N-ethylcarbamoyl group, N, N-diethylcarbamoyl group, N-propylcarbamoyl group, N, N-dipropylcarbamoyl group, N-isopropylcarbamoyl group, N , N-diisopropylcarbamoyl group, N-butylcarbamoyl group, N, N-dibutylcarbamoyl group, N-isobutylcarbamoyl group, N, N-diisobutylcarbamoyl group, N-sec-butylcarbamoyl group, N, N-disec- Butylcarbamoyl group, N-tert-butylcarbamoyl group, N, N-ditert-butylcarbamoyl group, N-pentylcarbamoyl group, N, N-dipentylcarbamoyl group, N- (1-ethylpropyl) carbamoyl group, N, N-di (1-ethylpropyl) carbamoyl group, N-hexyl carbamoyl group, N, N-dihexyl carbamoyl group, N- (2-ethyl) hexyl carbamoyl group, N, N-di (2-ethyl) hexyl carbamoyl group , N-Heptylcarbamoyl group, N, N-diheptylcarbamoyl group, N-octylcarbamoyl group, N, N-dioctylcarbamoyl group, N-nonylcarbamoyl group, N, N-octylmethylcarbamoyl group, N, N-octyl Butylcarbamoyl group, N, N-dinonylcarbamoyl group, N-phenylcarbamoyl group, N, N-diphenylcarbamoyl group, N, N-ethylmethylcarbamoyl group, N, N-propylmethylcarbamoyl group, N, N-isopropyl Methylcarbamoyl group, N, N-butylmethylcarbamoyl group, N-decylcarbamoyl group, N, N-decylmethylcarbamoyl group, N-undecylcarbamoyl group, N, N-undecylmethylcarbamoyl group, N-dodecylcarbamoyl group , N, N-dodecylmethylcarbamoyl group, N-icosylcarbamoyl group, N, N-icosylmethylcarbamoyl group, N, N-tert-butylmethylcarbamoyl group, N, N-phenylmethylcarbamoyl group, etc. A hydrocarbon group having 1 or 2 carbon atoms (preferably 1 to 10 carbon atoms) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group) such as a group represented by the above formula. , A carbamoyl group substituted with halogen (preferably a chlorine atom), a group derivatized with an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc.;

Trifluoromethyl group, perfluoroethyl group, perfluoropropyl group, perfluoroisopropyl group, perfluorobutyl group, perfluoropentyl group, perfluorohexyl group, perfluoroheptyl group, perfluorooctyl group, perfluorononyl group, Carbonation of 1 to 20 carbon atoms in which all hydrogen atoms such as perfluorodecyl group, perfluoroundecyl group, perfluorododecyl group, perfluoroicosyl group, perfluorocyclohexyl group and perfluorophenyl group are substituted with fluorine atom. Hydrogen group;
Perfluoroethylmethyl group, perfluoropropylmethyl group, perfluoroisopropylmethyl group, perfluorobutylmethyl group, perfluoropentylmethyl group, perfluorohexylmethyl group, perfluoroheptylmethyl group, perfluorooctylmethyl group, perfluoro A linear chain having 1 to 20 carbon atoms in which all hydrogen atoms such as nonylmethyl group, perfluorodecylmethyl group, perfluoroundecylmethyl group, perfluorododecylmethyl group and perfluoroicosylmethyl group are substituted with fluorine atoms. Alternatively, a hydrocarbon group having 1 to 20 carbon atoms substituted with an alkyl group in the branched chain;

1 to 20 carbon atoms (preferably carbon number) in which a part of hydrogen atoms such as 2-fluorophenyl group, 3-fluorophenyl group, 4-fluorophenyl group and 2,4,6-trifluorophenyl group are replaced with fluorine. 1-10) hydrocarbon groups;

-CO-SH, -CO-S-CH ₃ , -CO-S-CH ₂ CH ₃ , -CO-S-CH ₂ -CH ₂ -CH ₃ and -CO-S-CH ₂ -CH ₂ -CH ₂ arylthiocarbonyl group having 6 to 20 carbon atoms an alkyl thio _{group, -CO-S-C 6 H} 5 , etc. of carbon number 1 to 20 (preferably 1 to 10 carbon atoms) of -CH ₃ and the like;

* -COCO-R as represented by the following formula (in the formula, R is a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms (for example, among the hydrocarbon groups listed above, it satisfies 1 to 20 carbon atoms). , Or its inducing group (eg, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group). Group) (group derived by etc.);

_{* -NRCONR 2} as represented by the following formula (in the formula, R is a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms (for example, among the hydrocarbon groups listed above, those satisfying 1 to 20 carbon atoms). ), Or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), etc. Groups derived from), the Rs of which may be the same or different from each other, or bonded to each other to form a ring);

_{* -OCONR 2} as represented by the following formula (in the formula, R is a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms (for example, among the hydrocarbon groups listed above, those satisfying 1 to 20 carbon atoms). ), Or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), etc. Groups derived from), the Rs of which may be the same or different from each other, or bonded to each other to form a ring);

* -NRCOOR as represented by the following formula (in the formula, R is a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms (for example, among the hydrocarbon groups listed above, those satisfying 1 to 20 carbon atoms)). , Or its inducing group (eg, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group), etc. Derivatized groups), the Rs of which may be the same or different from each other, or bonded to each other to form a ring) groups;

* -OP (O) (OCH ₃ ) ₂ such as * -OP (O) (OR) ₂ (In the formula, R is a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms (for example, the hydrocarbon group listed above). Of these, those satisfying 1 to 20 carbon atoms), or their inducible groups (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms). (Preferably a group derivatized with an octylsulfamoyl group) or the like), and the Rs may be the same or different from each other, or may be bonded to each other to form a ring).
* -Si (CH ₃ ) ₃ , _{* -Si (CH 2} CH ₃ ) ₃ , _{* -Si (C 6} H ₅ ) ₃ and * -Si (CH (CH ₃ ) ₂ ) _3, etc. * -SiR ₃ ( In the formula, R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, one of the above-mentioned hydrocarbon groups satisfying 1 to 20 carbon atoms), or an inducing group thereof (for example, a carboxy group or a sulfo group). A group derived from a group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), etc.), and the R is Groups of (may be the same or different from each other and may be bonded to each other to form a ring);

-SO ₃ ^-; -CO ₂ ^-; and the like.

As the divalent substituent, an oxo group, a thioxo group, an imino group, an imino group substituted with an alkyl group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) and an aryl group having 6 to 20 carbon atoms are substituted. Examples include the imino group. Examples of the imino group substituted with the alkyl group include CH _3- N =, CH _3- CH _2- N =, CH _3- (CH ₂ ) _2- N = and CH _3- (CH ₂ ) _3- N =. Can be mentioned. Examples of the imino group substituted with the aryl group include C ₆ H _5- N = and the like.

Preferred examples of the substituent of the hydrocarbon group having 1 to 40 carbon atoms include the substituent of the group s1. The inducible groups shown below are carboxy groups, sulfo groups, nitro groups, hydroxy groups, halogens (preferably chlorine atoms), alkylsulfamoyl groups having 1 to 10 carbon atoms (preferably octylsulfamoyl groups) and the like. It is preferably an derivatized group.
[Group s1]
An oxy group in which a hydrocarbon group having 1 to 20 carbon atoms or an inducible group thereof is bonded to one side;
A carbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
An oxycarbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
Amino group;
An amino group substituted with one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
Sulfamoyl group;
A sulfamoyl group substituted with one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
A carbonylamino group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
Hydroxy group;
Halogen atom;
-CO ₂ M (preferably a carboxy group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom);
-SO ₃ M (preferably a sulfo group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom);
Nitro group;
Cyano group;
A carbonyloxy group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
A sulfonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or an inducible group thereof is bonded;
Carbamic group;
A carbamoyl group substituted with one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
A hydrocarbon group having 1 to 20 carbon atoms in which all hydrogen atoms are replaced by fluorine atoms;
A hydrocarbon group having 1 to 20 carbon atoms in which all of the hydrogen atoms are substituted with fluorine atoms;
A hydrocarbon group having 1 to 20 carbon atoms in which a part of a hydrogen atom is replaced by fluorine;
Oxo group;
-SO ₃ ^-;
-CO ₂ ^-

As the substituent of the hydrocarbon group having 1 to 40 carbon atoms, a substituent of group s2 is more preferable.
[Group s2]
An oxy group in which a hydrocarbon group having 1 to 10 carbon atoms or an inducible group thereof is bonded to one side;
A carbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
An oxycarbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
Amino group;
An amino group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or an inducible group thereof;
Sulfamoyl group;
A sulfamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof;
A carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
Hydroxy group;
Fluorine atom, chlorine atom, bromine atom;
-CO ₂ M (preferably a carboxy group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom);
-SO ₃ M (preferably a sulfo group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom);
Nitro group;
Cyano group;
A carbonyloxy group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
A sulfonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or an inducible group thereof is bonded;
Carbamic group;
A carbamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof;
A hydrocarbon group having 1 to 10 carbon atoms in which all hydrogen atoms are replaced by fluorine atoms;
A hydrocarbon group having 1 to 10 carbon atoms in which all of the hydrogen atoms are substituted with fluorine atoms;
A hydrocarbon group having 1 to 10 carbon atoms in which a part of a hydrogen atom is replaced by fluorine;
Oxo group;
-SO ₃ ^-;
-CO ₂ ^-

As a hydrocarbon group having 1 to 40 carbon atoms having a substituent represented by ^{R 1AZ6} , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. Can be a hydrocarbon group having 1 to 40 carbon atoms having a monovalent or divalent substituent; preferably a saturated or unsaturated chain having 1 to 30 carbon atoms having a monovalent or divalent substituent. Saturated or unsaturated alicyclic hydrocarbon groups with 3 to 30 carbon atoms having monovalent or divalent substituents, aromatic hydrocarbons with 6 to 30 carbon atoms having monovalent or divalent substituents Groups having a combination of hydrogen groups or hydrocarbon groups and having a monovalent or divalent substituent and having 4 to 30 carbon atoms can be mentioned;
More preferably, a saturated or unsaturated chain hydrocarbon group having 1 to 20 carbon atoms having a substituent in group s1 and a saturated or unsaturated alicyclic hydrocarbon group having 3 to 20 carbon atoms having a substituent in group s1. , A group of 6 to 20 carbon atoms having a substituent of group s1 or a combination of hydrocarbon groups and a group of 4 to 20 carbon atoms having a substituent of group s1;
Particularly preferably, a saturated or unsaturated chain hydrocarbon group having 1 to 15 carbon atoms having a substituent in group s2 and a saturated or unsaturated alicyclic hydrocarbon group having 3 to 15 carbon atoms having a substituent in group s2. , A group having a substituent of group s2 and having 6 to 15 carbon atoms or a combination of hydrocarbon groups and a group having 4 to 15 carbon atoms having a substituent of group s2.

The ^{heterocyclic group represented by R 1AZ6} , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6 may be a single ring. It may be a polycycle, preferably a heterocycle containing a heteroatom as a component of the ring. Examples of the hetero atom include a nitrogen atom, an oxygen atom and a sulfur atom.
The number of carbon atoms of the heterocyclic group is preferably 3 to 30, more preferably 3 to 22, still more preferably 3 to 20, even more preferably 3 to 18, and even more preferably 3 to 3. It is 15, particularly preferably 3 to 14.

As a heterocycle containing a nitrogen atom,
Monocyclic saturated heterocycles such as aziridine, azetidine, pyrrolidine, piperidine and piperazine;
Pyrrole such as 2,5-dimethylpyrrole, pyrazole such as 2-methylpyrazole and 3-methylpyrazole, imidazole, 1,2,3-triazole and 5-membered ring-based unsaturated heterocycle such as 1,2,4-triazole ;
Pyrimidines such as pyridine, pyridazine, 6-methylpyrimidine, pyrazines and 6-membered ring unsaturated heterocycles such as 1,3,5-triazine;
Quinoxaline such as indazole, indolin, isoindolin, indole, indoline, benzimidazole, quinoline, isoquinoline, 5,6,7,8-tetrahydro (3-methyl) quinoxaline, 3-methylquinoxaline, quinazoline, cinnoline, phthalazine, diazanaphthalene. , Purine, pteridine, benzopyrazole, benzopiperidine and other fused bicyclic heterocycles;
Condensed tricyclic heterocycles such as carbazole, acridine and phenazine; and the like.

As a heterocycle containing an oxygen atom,
Monocyclic saturated heterocycles such as oxylan, oxetane, tetrahydrofuran, tetrahydropyran, 1,3-dioxane and 1,4-dioxane, 1-cyclopentyl dioxolane;
Bicyclic saturated heterocycles such as 1,4-dioxaspiro [4.5] decane and 1,4-dioxaspiro [4.5] nonane;
Lactone-based heterocycles such as α-acetolactone, β-propiolactone, γ-butyrolactone, γ-valerolactone and δ-valerolactone;
A 5-membered ring-based unsaturated heterocycle such as furan such as 2,3-dimethylfuran and 2,5-dimethylfuran;
6-membered ring-based unsaturated heterocycles such as 2H-pyran and 4H-pyran;
Benzopyrans such as 1-benzofuran and 4-methylbenzopyran, condensed bicyclic heterocycles such as benzodioxol, chroman and isochroman;
Condensed tricyclic heterocycles such as xanthene and dibenzofuran; and the like.

As a heterocycle containing a sulfur atom,
5-membered ring-based saturated heterocycle such as dithiolane;
6-membered ring-based saturated heterocycles such as thiane, 1,3-dithiane, 2-methyl 1,3-dithiane;
5-membered ring-based unsaturated heterocycles such as thiophenes such as 3-methylthiophene and 2-carboxythiophene, 4H-thiopyran, benzothiopyran such as benzotetrahydrothiopyran;
Condensation bicyclic heterocycles such as benzothiophene;
Condensed tricyclic heterocycles such as thianthrene and dibenzothiophene; and the like.

As a heterocycle containing a nitrogen atom and an oxygen atom,
Monocyclic saturated heterocycles such as morpholine, 2-pyrrolidone, 2-methyl-2-pyrrolidone, 2-piperidone and 2-methyl-2-piperidone;
Monocyclic unsaturated heterocycles such as oxazoles such as 4-methyloxazole, 2-methylisoxazoles, and isooxazoles such as 3-methylisoxazole;
Condensed bicyclic heterocycles such as benzoxazole, benzoisoxazole, benzoxazine, benzodioxan, benzoimidazoline;
Condensed tricyclic heterocycles such as phenoxazine; and the like.

As a heterocycle containing a nitrogen atom and a sulfur atom,
Monocyclic heterocycles such as thiazoles such as 3-methylthiazole and 2,4-dimethylthiazole;
Condensation bicyclic heterocycles such as benzothiazole;
Condensation tricyclic heterocycles such as phenothiazine; and the like.

The heterocycle may be a group in which the above-mentioned hydrocarbon groups are combined, and examples thereof include a tetrahydrofurylmethyl group.

Further, the heterocycle may be represented by the following formula.

Further, the heterocyclic group may be a heterocyclic group formed by bonding two or more of ^{R 1AZ6 to} R ^5AZ6. Such a heterocyclic group has a ring structure of two or more rings together with a benzene ring to which ^{R 1AZ6 to} R ^{5AZ6 are bonded.} Examples of the ring structure having two or more rings include the structure of the following formula.

The bond position of the above heterocycle is a portion where an arbitrary hydrogen atom contained in each ring is eliminated.

The ^{heterocyclic group represented by R 1AZ6} , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^{101AZ 6} and R ^{102AZ 6} may have a substituent. .. The substituents include the hydrocarbon groups represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. The same as a good substituent can be mentioned. When the heterocycle contains a nitrogen atom as a constituent element thereof, the hydrocarbon group mentioned above may be bonded to the nitrogen atom as a substituent.
Preferred substituents include hydrocarbon groups represented by ^{R 1AZ6} , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , ^RAA1Z6 , ^RAA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. Examples include the same preferred substituents that may be used.
Heterocyclic groups having substituents represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^{102AZ6 are monovalent or 2} A heterocyclic group having a valence substituent can be mentioned, preferably a heterocyclic group having a substituent of group s1, and more preferably a heterocyclic group having a substituent of group s2.
The above-mentioned hydrocarbon group or heterocyclic group may have one or more substituents (first substituents), and the two or more substituents are independent of each other. It may be the same or different. Further, the first substituent may have another substituent (second substituent) bonded to the hydrocarbon group contained in a part thereof. The second substituent can be selected from the same groups as the first substituent.

Below, R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 and R ^13AZ6 -CO-R ^102AZ6 , -COO-R ^101AZ6 , -OCO-R ^102AZ6 , -COCO- R ^102AZ6 , ^{-OR 102AZ6} , -SO ₂ -R ^101AZ6 , -SO ₂ N (R ^102AZ6 ) ₂ ^{, -CON} (R 102AZ6) ₂ , -N (R ^102AZ6 ) ₂ , -NHCO-R ^102AZ6 , -NHCO -N (R ^102AZ6 ) ₂ , -NHCOOR ^102AZ6 , -OCON (R ^102AZ6 ) ₂ , halogen atom, -SO ₃ M, -CO ₂ M will be described. Illustrated below-CO-R ^102AZ6 , -COO-R ^101AZ6 , -OCO-R ^102AZ6 , -COCO-R ^102AZ6 , ^{-OR 102AZ6} , -SO _2- R ^101AZ6 , -SO ₂ N (R ^102AZ6 ) ₂ ^{, -CON} (R 102AZ6) ₂ , -N (R ^102AZ6 ) ₂ , -NHCO-R ^102AZ6 , -NHCO-N (R ^102AZ6 ) ₂ , -NHCOOR ^102AZ6 , -OCON (R ^102AZ6 ) ₂ , R ^101AZ6 , R ^102AZ6 substituent groups s2 to the appropriate portions, in particular -SO ₃ ^-, -CO ₂ ^- that is, such as are bound preferred.

-CO-R ^102AZ6 includes formyl group; acetyl group, propanoyl group, butanoyl group, 2,2-dimethylpropanoyl group, pentanoyl group, hexanoyl group, (2-ethyl) hexanoyl group, heptanoil group, octanoyl group, nonanoyl. Derivation of a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group, a decanoyl group, an undecanoyl group, a dodecanoyl group, a henicosanoyl group, a benzoyl group, etc., and a group represented by the above formula. It was derivatized with a chemical group (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), or the like. A carbonyl group to which a group) is bonded (when the carbonyl group is an acyl group, the number of carbon atoms is 2 to 41), and the groups corresponding to ^{-CO-R 102AZ6 in the compounds shown in Tables 1Z6 to 4Z6 and special features.} In the compounds shown in Tables 1 to 966 of Application No. ^2017-016290 , a group corresponding to −CO-R 102AZ6 and the like can be mentioned, preferably a hydrocarbon group having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms). Alternatively, in the carbonyl group to which the derivatizing group is bonded (when the carbonyl group is an alkanoyl group, the number of carbon atoms is more preferably 2 to 12) and the compounds shown in Tables 1Z6 to 4Z6, -CO-R ^102AZ6 Applicable groups and the like can be mentioned.

-COO-R ^101AZ6 includes methoxycarbonyl group, ethoxycarbonyl group, propoxycarbonyl group, tert-butoxycarbonyl group, butoxycarbonyl group, pentyloxycarbonyl group, hexyloxycarbonyl group, (2-ethyl) hexyloxycarbonyl group, Heptyloxycarbonyl group, octyloxycarbonyl group, nonyloxycarbonyl group, decyloxycarbonyl group, undecyloxycarbonyl group, dodecyloxycarbonyl group, phenyloxycarbonyl group, icosyloxycarbonyl group, etc., and represented by the above formula. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or an inducing group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon In the oxycarbonyl group to which an alkylsulfamoyl group (preferably a group derivatized with an octylsulfamoyl group) of numbers 1 to 10 (preferably a group derivatized by an octylsulfamoyl group) or the like is bonded, and in the compounds shown in Tables 1Z6 to 4Z6, -COO-R ^102AZ6 Examples of the relevant group and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. ^2017-016290 include the group corresponding to -COO-R 102AZ6, and preferably a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof. Examples thereof include an oxycarbonyl group to which is bonded and a group corresponding to ^{-COO-R 102AZ6 in the compounds shown in Tables 1Z6 to 4Z6.}

-OCO-R ^102AZ6 includes formyloxy group; acetoxy group, propanoyloxy group, butanoyloxy group, 2,2-dimethylpropanoyloxy group, pentanoyloxy group, hexanoyloxy group, (2-ethyl). Hexanoyloxy group, heptanoiloxy group, octanoyloxy group, nonanoyloxy group, decanoyloxy group, undecanoyloxy group, dodecanoyloxy group, henikosanoyloxy group, benzoyloxy group, etc., and the above formula. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or an inducible group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, or a halogen (preferably a chlorine atom). ), A carbonyloxy group to which an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably a group derived from an octylsulfamoyl group) or the like is bonded (when the carbonyloxy group is an acyloxy group, the number of carbon atoms is 2 to 41), ^{and the groups corresponding to -OCO-R 102AZ6} in the compounds shown in Tables 1Z6 to 4Z6 and -OCO-R 102AZ6 in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. ^2017-016290. Examples of the group corresponding to the above, preferably a hydrocarbon group having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms) or a carbonyloxy group to which an inducible group thereof is bonded (the carbonyloxy group is referred to as an acyloxy group). In this case, the number of carbon atoms is more preferably 2 to 12), and in the compounds shown in Tables 1Z6 to ^4Z6 , groups corresponding to -OCO-R 102AZ6 and the like can be mentioned.

-COCO-R ^102AZ6 includes methyloxalyl group, ethyloxalyl group, propyloxalyl group, butyloxalyl group, pentyloxalyl group, hexyloxalyl group, (2-ethyl) hexyloxalyl group, heptyloxalyl group, octyloxalyl group and nonyl. Oxalyl group, decyl oxalyl group, undecyl oxalyl group, dodecyl oxalyl group, icosyl oxalyl group, cyclopentyl oxalyl group, cyclohexyl oxalyl group, phenyl oxalyl group, p-tolyl oxalyl group and the like, and groups represented by the above formulas and the like. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), 1 to 1 carbon atoms. Oxalyl groups to which 10 alkylsulfamoyl groups (preferably groups derivatized with octylsulfamoyl groups) and the like are bonded, and groups corresponding to ^{-COCO-R 102AZ6 in the compounds shown in Tables 1Z6 to 4Z6 and} Examples of the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290 include groups corresponding to ^{-COCO-R 102AZ6.}

^{-OR 102AZ6} includes hydroxy groups; methoxy group, ethoxy group, propoxy group, isopropoxy group, butoxy group, isobutoxy group, sec-butoxy group, tert-butoxy group, pentyloxy group, hexyloxy group, heptyloxy. Group, octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, dodecyloxy group, (2-ethyl) hexyloxy group, icosyloxy group, 1-phenylethoxy group, 1-methyl-1-phenylethoxy group, phenyl Oxy group, 2,3-dimethylphenyloxy group, 2,4-dimethylphenyloxy group, 2,5-dimethylphenyloxy group, 2,6-dimethylphenyloxy group, 3,4-dimethylphenyloxy group, 3, 5-Dimethylphenyloxy group, 2,2-dicyanophenyloxy group, 2,3-dicyanophenyloxy group, 2,4-dicyanophenyloxy group, 2,5-dicyanophenyloxy group, 2,6-dicyanophenyloxy Group, 3,4-dicyanophenyloxy group, 3,5-dicyanophenyloxy group, 4-methoxyphenyloxy group, 2-methoxyphenyloxy group, 3-methoxyphenyloxy group, 4-ethoxyphenyloxy group, 2- A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as an ethoxyphenyloxy group, a 3-ethoxyphenyloxy group, etc., and a group represented by the above formula, or an inducing group thereof (for example, carboxy). A group derived from a group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group), or the like is bonded. group corresponding to the -O-R ^102AZ6 in group and compounds shown in Table 1Z6~ Table 4Z6 -O-R ^102AZ6 Table 1-966 of the relevant group and Japanese Patent Application No. 2017-016290 to the compounds shown in the Examples thereof include an oxy group to which a hydrocarbon group having 1 to 10 carbon atoms or an inducible group thereof is bonded, and a group corresponding to ^{-OR 102AZ6 in the compounds shown in Tables 1Z6 to 4Z6.}

-SO _2- R ^101AZ6 includes methyl sulfonyl group, ethyl sulfonyl group, propyl sulfonyl group, butyl sulfonyl group, pentyl sulfonyl group, hexyl sulfonyl group, (2-ethyl) hexyl sulfonyl group, heptyl sulfonyl group, octyl sulfonyl group, Nonylsulfonyl group, decylsulfonyl group, undecylsulfonyl group, dodecylsulfonyl group, icosylsulfonyl group, phenylsulfonyl group, p-tolylsulfonyl group, etc., and groups represented by the above formula, etc. have 1 to 40 carbon atoms (1 to 40 carbon atoms). A hydrocarbon group having 1 to 20 carbon atoms or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms). Sulfonyl groups to which (preferably octylsulfamoyl groups) and the like (preferably octylsulfamoyl groups) and the compounds shown in Tables 1Z6 to ^4Z6 _{correspond to -SO 2-} R 102AZ6 and Japanese Patent Application No. 2017-016290. -SO ₂ in the compounds shown in Table 1~966 -R ^102AZ6 relevant group and the like in, preferably a sulfonyl group and tables 1Z6~ bonded hydrocarbon radical or a derivatized group having 1 to 10 carbon atoms group corresponding to -SO ₂ -R ^102AZ6 in the compounds shown in Table 4Z6 like.

-SO ₂ N (R ^102AZ6 ) ₂ is a sulfamoyl group;
N-methylsulfamoyl group, N-ethylsulfamoyl group, N-propylsulfamoyl group, N-isopropylsulfamoyl group, N-butylsulfamoyl group, N-isobutylsulfamoyl group, N- sec-butyl sulfamoyl group, N-tert-butyl sulfamoyl group, N-pentyl sulfamoyl group, N- (1-ethylpropyl) sulfamoyl group, N-hexyl sulfamoyl group, N- (2-) Ethyl) Hexyl sulfamoyl group, N-heptyl sulfamoyl group, N-octyl sulfamoyl group, N-nonyl sulfamoyl group, N-decyl sulfamoyl group, N-undecyl sulfamoyl group, N- One carbon number 1 to 40 (preferably 1 to 20) of one group such as dodecylsulfamoyl group, N-icosylsulfamoyl group, N-phenylsulfamoyl group, and a group represented by the above formula. (For example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably octyl sulfamoyl group). ^{_{) -SO 2 NH (R 102AZ6X)}} ( provided that the sulfamoyl group and tables 1Z6~ Table 4Z6 compounds shown in substituted with derivatized groups) in such, except that R ^102AZ6X is not a hydrogen atom, R ^102AZ6 -SO ₂ NH (R ^102AZ6X) (provided that the compounds shown in Table 1 to 966 of the corresponding group and Japanese Patent Application No. 2017-016290 the same as is) and, except that R ^102AZ6X is not a hydrogen atom, R ^102AZ6 (Same as))

N, N-dimethylsulfamoyl group, N, N-ethylmethylsulfamoyl group, N, N-diethylsulfamoyl group, N, N-propylmethylsulfamoyl group, N, N-dipropylsulfamoyl Group, N, N-isopropylmethylsulfamoyl group, N, N-diisopropylsulfamoyl group, N, N-tert-butylmethylsulfamoyl group, N, N-diisobutylsulfamoyl group, N, N- Disec-butyl sulfamoyl group, N, N-ditert-butyl sulfamoyl group, N, N-butylmethyl sulfamoyl group, N, N-dibutyl sulfamoyl group, N, N-dipentyl sulfa Moyl group, N, N-di (1-ethylpropyl) sulfamoyl group, N, N-dihexyl sulfamoyl group, N, N-di (2-ethyl) hexyl sulfamoyl group, N, N-diheptylsul Famoyl group, N, N-octylmethylsulfamoyl group, N, N-dioctylsulfamoyl group, N, N-dinonyl sulfamoyl group, N, N-decylmethylsulfamoyl group, N, N- Undecylmethyl sulfamoyl group, N, N-dodecylmethyl sulfamoyl group, N, N-icosylmethyl sulfamoyl group, N, N-phenylmethyl sulfamoyl group, N, N-diphenyl sulfamoyl Two hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group and a group represented by the above formula or a derivatizing group thereof (for example, a carboxy group, a sulfo group, a nitro group, etc. Sulfamoyl groups substituted with hydroxy groups, halogens (preferably chlorine atoms), alkylsulfamoyl groups having 1 to 10 carbon atoms (preferably octylsulfamoyl groups) and the like, and sulfamoyl groups and Tables 1Z6 to Tables 1Z6. In the compounds shown in 4Z6, _{the groups corresponding to -SO 2} N (R ^102AZ6X ) ₂ (however, R ^{102AZ6X is the same as R 102AZ6} except that it does not become a hydrogen atom) and Table 1 of Japanese Patent Application No. 2017-016290. Among the compounds shown in ~ 966, groups corresponding to −SO ₂ N (R ^102AZ6X ) ₂ (however, R ^{102AZ6X is the same as R 102AZ6} except that it does not become a hydrogen atom) can be mentioned.
Preferably, it corresponds to _{-SO 2} N (R 102AZ6) ₂ in the sulfamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or an inducible group thereof and the compounds shown in Tables 1Z6 to ^4Z6. The group etc. can be mentioned.

^-CON (R 102AZ6) ₂ is a carbamoyl group;
N-methylcarbamoyl group, N-ethylcarbamoyl group, N-propylcarbamoyl group, N-isopropylcarbamoyl group, N-butylcarbamoyl group, N-isobutylcarbamoyl group, N-sec-butylcarbamoyl group, N-tert-butylcarbamoyl group. Group, N-pentylcarbamoyl group, N- (1-ethylpropyl) carbamoyl group, N-hexylcarbamoyl group, N- (2-ethyl) hexylcarbamoyl group, N-heptylcarbamoyl group, N-octylcarbamoyl group and N- One of nonylcarbamoyl group, N-decylcarbamoyl group, N-undecylcarbamoyl group, N-dodecylcarbamoyl group, N-icosylcarbamoyl group, N-phenylcarbamoyl group and the like, and a group represented by the above formula. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), and 1 to 10 carbon atoms. -CONH (R ^102AZ6X ) (where R ^{102AZ6X is the same as R 102AZ6} except that it does not become a hydrogen atom), and in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290, -CONH (R ^102AZ6X ) (however, R ^102AZ6X is It is the same as ^{R 102 AZ6} except that it does not become a hydrogen atom).

N, N-dimethylcarbamoyl group, N, N-ethylmethylcarbamoyl group, N, N-diethylcarbamoyl group, N, N-propylmethylcarbamoyl group, N, N-dipropylcarbamoyl group, N, N-isopropylmethylcarbamoyl Group, N, N-diisopropylcarbamoyl group, N, N-tert-butylmethylcarbamoyl group, N, N-diisobutylcarbamoyl group, N, N-disec-butylcarbamoyl group, N, N-ditert-butylcarbamoyl group , N, N-butylmethylcarbamoyl group, N, N-dibutylcarbamoyl group, N, N-butyloctylcarbamoyl group, N, N-dipentylcarbamoyl group, N, N-di (1-ethylpropyl) carbamoyl group, N , N-dihexylcarbamoyl group, N, N-di (2-ethyl) hexylcarbamoyl group, N, N-diheptylcarbamoyl group, N, N-octylmethylcarbamoyl group, N, N-dioctylcarbamoyl group, N, N -Dinonylcarbamoyl group, N, N-decylmethylcarbamoyl group, N, N-undecylmethylcarbamoyl group, N, N-dodecylmethylcarbamoyl group, N, N-icosylmethylcarbamoyl group, N, N-phenylmethyl Two hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a carbamoyl group, an N, N-diphenylcarbamoyl group, etc., and a group represented by the above formula, or an inducing group thereof (for example, 1 to 20 carbon atoms). Substituted with a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably a group derived with an octyl sulfamoyl group), or the like). ^{Carbamoyl groups and the groups corresponding to -CON} (R 102AZ6X) ₂ in the compounds shown in Tables 1Z6 to 4Z6 (however, R ^102AZ6X is the same as R 102AZ6 except that it does not become a hydrogen atom) and the ^{special application.} In the compounds shown in Tables 1 to 966 of No. 2017-016290, ^{groups corresponding to −CON} (R 102AZ6X) ₂ (however, R ^{102AZ6X is the same as R 102AZ6} except that it does not become a hydrogen atom) can be mentioned. ,
Preferably, a carbamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or an inducible group thereof, and a group corresponding to ^-CON (R 102AZ6) _{2 in the compounds shown in Tables 1Z6 to 4Z6 and the like.} Can be mentioned.

-N (R ^102AZ6 ) ₂ is an amino group;
N-methylamino group, N-ethylamino group, N-propylamino group, N-isopropylamino group, N-butylamino group, N-isobutylamino group, N-sec-butylamino group, N-tert-butylamino Group, N-pentylamino group, N-hexylamino group, N- (2-ethyl) hexylamino group, N-heptylamino group, N-octylamino group, N-nonylamino group, N-decylamino group, N-un A decylamino group, an N-dodecylamino group, an N-icosylamino group, an N-phenylamino group, etc., and a group represented by the above formula, etc., which have 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms). A hydrocarbon group or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably an octyl sulfamoyl group)). ^{-NH (R 102AZ6X} ) (however, R ^102AZ6X is the same as ^{R 102AZ6} except that it does not become a hydrogen atom in the amino groups substituted with (groups induced by etc.) and the compounds shown in Tables 1Z6 to 4Z6. ^{-NH (R 102AZ6X} ) in the groups corresponding to (there is) and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290 (however, R ^102AZ6X is the same as ^{R 102AZ6} except that it does not become a hydrogen atom). Group corresponding to;

N, N-dimethylamino group, N, N-ethylmethylamino group, N, N-diethylamino group, N, N-propylmethylamino group, N, N-dipropylamino group, N, N-isopropylmethylamino group , N, N-diisopropylamino group, N, N-tert-butylmethylamino group, N, N-diisobutylamino group, N, N-disec-butylamino group, N, N-ditert-butylamino group, N, N-butylmethylamino group, N, N-dibutylamino group, N, N-dipentylamino group, N, N-di (1-ethylpropyl) amino group, N, N-dihexylamino group, N, N -Di (2-ethyl) hexylamino group, N, N-diheptylamino group, N, N-dioctylamino group, N, N-dinonylamino group, N, N-decylmethylamino group, N, N-undecyl Methylamino group, N, N-dodecylmethylamino group, N, N-icosylmethylamino group, N, N-phenylmethylamino group, N, N-diphenylamino group, etc., and groups represented by the above formulas. 2 hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or derivatizing groups thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon ^{-N (R 102AZ6X} ) in amino groups substituted with an alkyl sulfamoyl group (preferably a group derivatized with an octyl sulfamoyl group) of numbers 1 to 10 and the compounds shown in Tables 1Z6 to 4Z6. ^{-N (R 102AZ6X} ) _{2 in the groups corresponding to 2} (however, R ^{102AZ6X is the same as R 102AZ6} except that it does not become a hydrogen atom) and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290. (However, R ^102AZ6X is the same as ^{R 102AZ6} except that it does not become a hydrogen atom.)
Preferably, an amino group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or an inducible group thereof, and a group corresponding to ^{-N (R 102AZ6} ) _{2 in the compounds shown in Tables 1Z6 to 4Z6 and the like.} Can be mentioned.

-NHCO-R ^102AZ6 includes formylamino groups; acetylamino groups, propanoylamino groups, butanoylamino groups, 2,2-dimethylpropanoylamino groups, pentanoylamino groups, hexanoylamino groups, (2-ethyl). ) Hexanoylamino group, Heptanoylamino group, Octanoylamino group, Nonanoylamino group, Decanoylamino group, Undecanoylamino group, Dodecanoylamino group, Henikosanoylamino group, Bencoylamino group, etc. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group represented by the above formula or an inducing group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, or a halogen (preferably). Is a chlorine atom), a carbonylamino group (a group derivatized with an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc.) is bonded (when the carbonylamino group is an acylamino group). , The number of carbon atoms is 1 to 40), and in the compounds shown in Tables 1Z6 to ^4Z6 , the group corresponding to -NHCO-R 102AZ6 and in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290-NHCO- The groups corresponding to ^{R 102 AZ6 are listed,}
Preferably, a carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or an inducible group thereof is bonded (when the carbonylamino group is an alkanoylamino group, the carbon number is more preferably 1 to 10) and Table 1Z6. In the compounds shown in Table 4Z6, ^{groups corresponding to -NHCO-R 102AZ6} and the like can be mentioned.

-NHCON (R ^102AZ6 ) ₂ ^{includes the groups listed above and the groups corresponding to -NHCON (R 102AZ6} ) ₂ in the compounds shown in Tables 1Z6 to 4Z6, Tables 1 to 966 of Japanese Patent Application No. 2017-016290. Examples of the compounds shown in (1) include groups corresponding to ^{−NHCON (R 102AZ6} _{) 2.}

-NHCOOR ^{102AZ6 includes the groups listed above, the groups corresponding to -NHCOOR 102AZ6} in the compounds shown in Tables 1Z6 to 4Z6, and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. ^2017-016290. Examples of the group corresponding to.

-OCON (R ^102AZ6 ) ₂ ^{includes the groups listed above and the groups corresponding to -OCON (R 102AZ6} ) ₂ in the compounds shown in Tables 1Z6 to 4Z6, Tables 1 to 966 of Japanese Patent Application No. 2017-016290. ^{Examples of the} compounds shown in (1) include groups corresponding to _{−OCON (R 102AZ6) 2.}

As the halogen atom, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom and the like are preferable.
Examples of _{M of −SO 3} M and −CO ₂ M include hydrogen atom; alkali metal atom such as lithium atom, sodium atom and potassium atom, and preferably hydrogen atom, sodium atom and potassium atom.

-CO-R ^102AZ6 , -COO-R ^102AZ6 , -OCO-R ^102AZ6 , -COCO-R ^102AZ6 , -O-R ^102AZ6 , -SO _2- R ^102AZ6 , -SO ₂ N (R ^102AZ6 ) ₂ , -CON Substituents (first substituents) contained in (R ^102AZ6 ) ₂ , -N (R ^102AZ6 ) ₂ , -NHCO-R ^102AZ6 , -NHCON (R ^102AZ6 ) ₂ , -NHCOOR ^102AZ6 , -OCON (R ^102AZ6 ) _2. May be one or more, and the two or more substituents may be the same or different independently of each other.
Further, the first substituent may have another substituent (second substituent) bonded to the hydrocarbon group contained in a part thereof. The second substituent can be selected from the same groups as the first substituent.

R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 and R ^13AZ6 include hydrogen atom, -CO-R ^102AZ6 , -COO-R ^101AZ6 , -COCO-R ^102AZ6 , -O-R ^102AZ6 , -SO ₂ -R ^101AZ6 , -SO ₂ N (R ^102AZ6 ) ₂ ^{, -CON} (R 102AZ6) ₂ , -N (R ^102AZ6 ) ₂ , -NHCO-N (R ^102AZ6 ) ₂ ,- ^{NHCOOR 102AZ6, -OCON (R 102AZ6)} 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , -SO 3 -, -CO 2 -, carbon atoms, which may have a substituent A heterocyclic group which may have a hydrocarbon group of several 1 to 40 or a substituent is preferable.
As R ^101AZ6 , a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent is preferable.
As R ^102AZ6 , a hydrocarbon group having 1 to 40 carbon atoms which may have a hydrogen atom or a substituent is preferable.

The ^{rings formed by R 2AZ 6} and R ^{3AZ 6} , R ^{3AZ 6} and R ^{4AZ 6} , and R ^{4AZ 6} and R ^{5AZ 6} are condensed with the benzene ring of the isoindoline skeleton of the compound represented by the formula (IZ6). The fused ring structures of the ring formed by R ^2AZ6 and R ^3AZ6 , R ^3AZ6 and R ^4AZ6 , and R ^4AZ6 and R ^5AZ6 and the benzene ring include inden, naphthalene, biphenylene, indacene, acenaftylene, fluorene, phenanthrene, and phenanthrene. Hydrocyclic condensed ring structures such as anthracene, fluorantene, acephenanthrene, aceanthrene, triphenylene, pyrene, chrysene, N-methylphthalimide, N- (1-phenylethyl) phthalimide and tetracene, and their partial reductions ( For example, 9,10-dihydroanthracene, 1,2,3,4-tetrahydronaphthalene); indol, isoindole, indazole, quinoline, isoquinoline, phthalazine, quinoxaline, quinazoline, cinnoline, carbazole, carboline, phenanthrene, aclysine. , Perimidine, phenanthrene, phenazine and the like nitrogen-containing condensed heterocycles and their partial reductions; examples thereof include oxygen-containing condensation heterocycles such as 3-hydrobenzofuran 2-one and its partial reductions.

When R ^{2AZ 6} and R ^{3AZ 6} , R ^{3AZ 6} and R ^{4AZ 6} , and R ^{4AZ 6} and R ^{5AZ 6} form a ring, the ring may have a substituent. The substituents include the hydrocarbon groups represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. The same as a good substituent can be mentioned. Preferred substituents include hydrocarbon groups represented by ^{R 1AZ6} , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , ^RAA1Z6 , ^RAA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. Examples include the same preferred substituents that may be used.

When R ^{3AZ 6} and R ^{4AZ 6} form a ring, R ^{2AZ 6} and R ^{5AZ 6} are independent of each other, preferably a hydrogen atom, an amino group or a hydroxy group.
If R ^2AZ6 and R ^3AZ6 form a ring, R ^4AZ6 and R ^5AZ6 is preferably not form a ring, and more preferably R ^4AZ6 and R ^5AZ6 is a hydrogen atom.
In the case where R ^4AZ6 and R ^5AZ6 form a ring, R ^2AZ6 and R ^3AZ6 is preferably not form a ring, and more preferably R ^2AZ6 and R ^3AZ6 is a hydrogen atom.

Ring R ^AA1Z6 and R ^AA2Z6, and the R ^12AZ6 and R ^13AZ6 form is coupled with isoindoline skeleton of exomethylene (C = CH ₂₎ of formula (IZ6), R ^AA1Z6 and R ^AA2Z6, and R ^12AZ6 If the ring formed by R 13AZ6 and R _{13AZ6 is cited as a structure containing this exomethylene (C = CH 2} ), for example, carbonyl groups such as the following groups A and B, ^{exomethylene, and carbonyl groups are arranged in this order.} The structure can be exemplified. ** represents a bond with the isoindoline skeleton.
[Group A]

[Group B]

R ^104AZ6 , R ^105AZ6 , R ^106AZ6 , and R ^107AZ6 are independent of each other, hydrogen atom, -CO-R ^102AZ6 , -COO-R ^101AZ6 , -OCO-R ^102AZ6 , -COCO-R ^102AZ6 , -O-R ^102AZ6. , -SO ₂ -R ^101AZ6 , -SO ₂ N (R ^102AZ6 ) ₂ ^{, -CON} (R 102AZ6) ₂ , -N (R ^102AZ6 ) ₂ , -NHCO-R ^102AZ6 , -NHCO-N (R ^102AZ6 ) ₂ , ^{-NHCOOR 102AZ6, -OCON (R 102AZ6)} 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , -SO 3 -, -CO 2 -, which may have a substituent Represents a heterocyclic group which may have a hydrocarbon group or a substituent having 1 to 40 carbon atoms.

^Represented by R 104AZ6, R ^105AZ6 , R ^106AZ6 , and R ^107AZ6 , -CO-R ^102AZ6 , -COO-R ^101AZ6 , -OCO-R ^102AZ6 , -COCO-R ^102AZ6 , -O-R ^102AZ6 , -SO ₂ -R ^101AZ6 , -SO ₂ N (R ^102AZ6 ) ₂ ^{, -CON} (R 102AZ6) ₂ , -N (R ^102AZ6 ) ₂ , -NHCO-R ^102AZ6 , -NHCO-N (R ^102AZ6 ) ₂ , -NHCOOR ^102AZ6 , -OCON (R ^102AZ6 ) ₂ , halogen atom, -SO ₃ M and -CO ₂ M are represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , ^RAA1Z6 , ^RAA2Z6 , R ^12AZ6 and R ^13AZ6 . -CO-R ^102AZ6 , -COO-R ^101AZ6 , -OCO-R ^102AZ6 , -COCO-R ^102AZ6 , -O-R ^102AZ6 , -SO _2- R ^101AZ6 , -SO ₂ N (R ^102AZ6 ) ₂ ,- CON (R ^102AZ6 ) ₂ , -N (R ^102AZ6 ) ₂ , -NHCO-R ^102AZ6 , -NHCO-N (R ^102AZ6 ) ₂ , -NHCOOR ^102AZ6 , -OCON (R ^102AZ6 ) ₂ , halogen atom, -SO ₃ M And the same as -CO _{2 M.}

As ^{the heterocyclic group represented by R 104AZ6} , R ^105AZ6 , R ^106AZ6 , and R ^107AZ6 , which may have a hydrocarbon group having 1 to 40 carbon atoms and which may have a substituent. , R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^{101 AZ6} and R ^{102 AZ6} may have substituents represented by 1 to 1 carbon atoms. Examples include the same heterocyclic groups that may have 40 hydrocarbon groups or substituents.

The hydrocarbon group and the heterocyclic group having 1 to 40 carbon atoms represented by R ^104AZ6 , R ^105AZ6 , R ^106AZ6 , and R ^{107AZ6 may have a substituent.} The substituents include the hydrocarbon groups represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. The same as a good substituent can be mentioned. Preferred substituents include hydrocarbon groups represented by ^{R 1AZ6} , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , ^RAA1Z6 , ^RAA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. Examples include the same preferred substituents that may be used.

^{R 104AZ6, R 105AZ6, R 106AZ6} , and as the R ^107AZ6, preferably those same as preferred in the ^{R 1AZ6, R 2AZ6, R 3AZ6} , R 4AZ6, R 5AZ6, R AA1Z6, R AA2Z6, R 12AZ6 and R ^13AZ6 Can be mentioned.
R ^104AZ6 , R ^105AZ6 , R ^106AZ6 , and R ^107AZ6 are more preferably methyl group, ethyl group, propyl group, isopropyl group, butyl group, tert-butyl group, pentyl group, hexyl group, (2-ethyl) hexyl. Examples thereof include a hydrocarbon group having 1 to 10 carbon atoms such as a group, a heptyl group, an octyl group, a nonyl group, a cyclohexyl group and a phenyl group, and a hydrogen atom.

The groups exemplified in groups A and B may be those in which the hydrogen atom bonded to the ring structure is substituted with a substituent.
The substituents include the hydrocarbon groups represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. The same as a good substituent can be mentioned.
Among the substituents, the hydrocarbon groups represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6 are preferable. Examples include the same preferred substituents that may have.

R ^1AZ6 is a hydrogen atom, and R ^2AZ6 , R ^3AZ6 , R ^4AZ6 and R ^5AZ6 are independent of each other.
Hydrogen atom, hydrocarbon group with 1 to 20 carbon atoms, halogen atom, -N (R ^102AZ6 ) ₂ , nitro group, hydrocarbon group with 1 to 20 carbon atoms in which all or part of the hydrogen atom is replaced by a fluorine atom, It is preferably -NHCO-R ^102AZ6 , ^{-OR 102AZ6} , -SO ₃ M or -CO _{2 M.}
More preferably, it is a hydrogen atom, a tert-butyl group or a nitro group.

R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6 are at least one of (raa-i) to (raa-iii). it is preferable to ^{satisfy, R 1AZ6, R 2AZ6, R} 3AZ6, R 4AZ6, R 5AZ6, R AA1Z6, R AA2Z6, R 12AZ6, R 13AZ6, R 101AZ6 and -SO ₃ R ^102AZ6 has ^- or -CO ₂ ^- The total number of is a.
At least one ^{(raa-i) R 1AZ6,} R 2AZ6, R 3AZ6, R 4AZ6, R 5AZ6, R AA1Z6, R AA2Z6, R 12AZ6 and R ^13AZ6 is, -SO ₃ ^- or -CO ₂ ^- a.
(Raa-ii) At ^{least one of R 1AZ6} , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 and R ^13AZ6 is -CO-R ^102AZ6 , -COO-R ^101AZ6 , -O. -R ^102AZ6 , -SO ₂ -R ^101AZ6 , -SO ₂ N (R ^102AZ6 ) ₂ ^{, -CON} (R 102AZ6) ₂ or -N (R ^102AZ6 ) ₂ , and the R ^101AZ6 and R ^102AZ6 are -SO. ₃ ^- or -CO ₂ ^- 1 to 40 carbon atoms having a hydrocarbon group or a -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
(Raa-iii) At least one of ^{R 1AZ6} , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 and R ^13AZ6 _{has -SO 3} ^- or -CO ₂ ^-- carbon number 1 40 hydrocarbon group or -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.

Examples of the group A and the group B include rings represented by the formulas (QQ1) to (QQ25) and the formulas (QQA1) to (QQA36).

The compound represented by the formula (IZ6-A) is preferably a compound represented by the formula (IZ6-B) (hereinafter, may be referred to as a compound (IZ6-B)).

[In the formula (IZ6-B),
A ^{c +} , b, c, d and wavy lines have the same meanings as described above.
L ¹ is, -CO- or -SO ₂ - represents a.
R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 and R ^13BZ6 are independent of each other, hydrogen atom, -CO-R ^102BZ6 , -COO-R ^101BZ6 , -OCO-R ^102BZ6 , -COCO-R ^102BZ6 , -O-R ^102BZ6 , -SO _2- R ^101BZ6 , -SO ₂ N (R ^102BZ6 ) ₂ ^{, -CON} (R 102BZ6) ₂ , -N (R ^102BZ6 ) ₂ , -NHCO-R ^{102BZ6 , -NHCO-N (R 102BZ6)} 2, -NHCOOR 102BZ6, -OCON (R 102BZ6) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , -SO 3 -, -CO 2 ^—— Represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^2BZ6 and R ^3BZ6 , R ^3BZ6 and R ^4BZ6 , R ^4BZ6 and R ^5BZ6 , and R ^12BZ6 and R ^13BZ6 may be coupled to each other to form a ring, respectively.
R ^101BZ6 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent independently of each other.
R ^102BZ6 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent, independently of each other.
Formulas (IZ6-B') and formulas (IZ6-B'') represent the substructures of formula (IZ6-B), respectively, Ac ⁺ , b, c, d, R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 , R ^13BZ6 and L ¹ represent the same as those in the equation (IZ6-B).
M represents the same meaning as described above.
If there are multiple R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 , R ^13BZ6 , R ^101BZ6 , R ^102BZ6 , L ¹ , M, c or ^{Ac +} , they are the same. It may be present or different.
R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 , R ^13BZ6 , R ^101BZ6 and R ^102BZ6 satisfy at least one of (rb-i) to (rb-iii). ^{and, R 1BZ6, R 2BZ6, R} 3BZ6, R 4BZ6, R 5BZ6, R 11BZ6, R 12BZ6, R 13BZ6, R 101BZ6 and -SO ₃ R ^102BZ6 has ^- or -CO ₂ ^- total number of is a ..
At least one ^{(rb-i) R 1BZ6,} R 2BZ6, R 3BZ6, R 4BZ6, R 5BZ6, R 11BZ6, R 12BZ6 and R ^13BZ6 is, -SO ₃ ^- or -CO ₂ ^- a.
^(Rb -ii) At least one of R 1BZ6, R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 and R ^13BZ6 is -CO-R ^102BZ6 , -COO-R ^101BZ6 , -OCO-R ^102BZ6. , -COCO-R ^102BZ6 , -O-R ^102BZ6 , -SO _2- R ^101BZ6 , -SO ₂ N (R ^102BZ6 ) ₂ , or ^-CON (R 102BZ6) ₂ , -N (R ^102BZ6 ) ₂ , -NHCO- ^{R 102BZ6, -NHCO-N (R} 102BZ6) 2, -NHCOOR 102BZ6, or -OCON (R ^102BZ6) a _2, wherein R ^101BZ6 and R ^102BZ6 is, -SO ₃ ^- carbon atoms with ^- or -CO ₂ 1-40 hydrocarbon group or -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
At least one ^{(rb-iii) R 1BZ6,} R 2BZ6, R 3BZ6, R 4BZ6, R 5BZ6, R 11BZ6, R 12BZ6 and R ^13BZ6 is, -SO ₃ ^- 1 to 40 carbon atoms having a ^- or -CO ₂ hydrocarbon group or a -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
a represents the same meaning as in the formula (IZ6-A). When a plurality of a exist, they may be the same or different.
The absolute value of the negative valence of the substructure represented by the formula (IZ6-B') and the positive valence of the substructure represented by the formula (IZ6-B ″) are the same. ]

The ^{R 1BZ6, R 2BZ6, R 3BZ6} , R 4BZ6, R 5BZ6, R 11BZ6, R 12BZ6 and ^{R 13BZ6, R 1AZ6, R 2AZ6} , R 3AZ6, R 4AZ6, R 5AZ6, R AA1Z6, R AA2Z6, R 12AZ6 and The ^{same as R 13 AZ6} can be mentioned.
^{R 1BZ6, R 2BZ6, R 3BZ6} , R 4BZ6, R 5BZ6, R 11BZ6, preferable examples of R ^12BZ6 and R ^{13BZ6 is, R 1AZ6, R 2AZ6, R} 3AZ6, R 4AZ6, R 5AZ6, R AA1Z6, R AA2Z6, The same preferable ones of ^{R 12 AZ6} and R ^{13 AZ6 can be mentioned.}

The R ^101BZ6 is the same as the R ^{101A Z6.}
Preferable examples of R ^101BZ6 may be the same as those preferred for R ^101AZ6.

^Examples of the R 102BZ6 include the same as the R ^{102A Z6.}
Preferable examples of R ^102BZ6 may be the same as those preferred for R ^102AZ6.

The hydrocarbon groups and heterocyclic groups having 1 to 40 carbon atoms represented by R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 , R ^13BZ6 , R ^101BZ6 and R ^{102BZ6 are substituents.} May have. The substituents include the hydrocarbon groups represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. The same as a good substituent can be mentioned. Preferred substituents include hydrocarbon groups represented by ^{R 1AZ6} , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , ^RAA1Z6 , ^RAA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. Examples include the same preferred substituents that may be used.

L ¹ is preferably −CO−.

R ^11BZ6 is an aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a phenyl group which may have a substituent, a naphthyl group which may have a substituent, and a substituent. Being a tetrahydronaphthyl group which may have a group, a thienyl group which may have a substituent, a frill group which may have a substituent, or a pyridinyl group which may have a substituent. Is preferable.

The ^{aliphatic hydrocarbon group represented by R 11BZ6} has 1 to 40 carbon atoms, preferably 1 to 30 carbon atoms, more preferably 1 to 20 carbon atoms, and further preferably 1 to 15 carbon atoms.

The aliphatic hydrocarbon group may be saturated or unsaturated, or may be a chain or an alicyclic.

^Examples of the saturated or unsaturated chain aliphatic hydrocarbon group represented by R 11BZ6 include a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group, a heptyl group, an octyl group, a nonyl group and a decyl group. Linear alkyl groups such as undecyl group, dodecyl group, heptadecyl group, octadecyl group and icosyl group; isopropyl group, isobutyl group, sec-butyl group, tert-butyl group, (2-ethyl) butyl group, isopentyl group, etc. Neopentyl group, tert-pentyl group, (1-methyl) pentyl group, (2-methyl) pentyl group, (1-ethyl) pentyl group, (3-ethyl) pentyl group, isohexyl group, (5-methyl) hexyl group , Branched chain alkyl groups such as (2-ethyl) hexyl group and (3-ethyl) heptyl group; vinyl group, 1-propenyl group, 2-propenyl group (allyl group), (1-methyl) ethenyl group , 2-butenyl group, 3-butenyl group, 1,3-butadienyl group, (1- (2-propenyl)) ethenyl group, (1,2-dimethyl) propenyl group, 2-pentenyl group and other alkenyl groups; etc. Can be mentioned. The saturated or unsaturated chain hydrocarbon group preferably has 1 to 30 carbon atoms, more preferably 1 to 20 carbon atoms, still more preferably 1 to 15 carbon atoms, and particularly preferably 1 to 10 carbon atoms.

^Examples of the saturated or unsaturated alicyclic hydrocarbon group represented by R 11BZ6 include a cyclopropyl group, a 1-methylcyclopropyl group, a cyclobutyl group, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, a 1-methylcyclohexyl group, and 2 -Methylcyclohexyl group, 3-methylcyclohexyl group, 4-methylcyclohexyl group, 1,2-dimethylcyclohexyl group, 1,3-dimethylcyclohexyl group, 1,4-dimethylcyclohexyl group, 2,3-dimethylcyclohexyl group, 2 , 4-Dimethylcyclohexyl group, 2,5-dimethylcyclohexyl group, 2,6-dimethylcyclohexyl group, 3,4-dimethylcyclohexyl group, 3,5-dimethylcyclohexyl group, 2,2-dimethylcyclohexyl group, 3,3 -Dimethylcyclohexyl group, 4,4-dimethylcyclohexyl group, cyclooctyl group, 2,4,6-trimethylcyclohexyl group, 2,2,6,6-tetramethylcyclohexyl group and 3,3,5,5-tetramethyl Cycloalkyl groups such as cyclohexyl group, 4-pentylcyclohexyl group, 4-octylcyclohexyl group, 4-cyclohexylcyclohexyl group; cyclohexenyl group (eg, cyclohex-2-ene, cyclohexa-3-ene), cycloheptenyl group, cyclooctenyl group, etc. Cycloalkenyl group; norbornan group, adamantyl group, bicyclo [2.2.2] octane and the like. The saturated or unsaturated alicyclic hydrocarbon group preferably has 3 to 30, more preferably 3 to 20, even more preferably 4 to 20, and even more preferably 4 to 15. Yes, more particularly preferably 5 to 15, and most preferably 5 to 10. Of these, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, and a cyclooctyl group are particularly preferable.

The ^{aliphatic hydrocarbon group represented by R 11BZ6} is a group in which a hydrogen atom contained in the above-mentioned aliphatic hydrocarbon group is replaced with an aromatic hydrocarbon group having 1 to 40 carbon atoms or the above-mentioned fat. It may be a group in which a group hydrocarbon group is combined.
Examples of such aromatic hydrocarbon groups include phenyl group, o-tolyl group, m-tolyl group, p-tolyl group, 2-ethylphenyl group, 3-ethylphenyl group, 4-ethylphenyl group and 2,3-dimethyl group. Phenyl group, 2,4-dimethylphenyl group, 2,5-dimethylphenyl group, 2,6-dimethylphenyl group, 3,4-dimethylphenyl group, 3,5-dimethylphenyl group, o-isopropylphenyl group, m -Isopropylphenyl group, p-isopropylphenyl group, o-tert-butylphenyl group, m-tert-butylphenyl group, p-tert-butylphenyl group, mesityl group, 2,6-bis (2-propyl) phenyl group , 2,4,6-trimethylphenyl group, 1-naphthyl group, 2-naphthyl group, 5,6,7,8-tetrahydro-1-naphthyl group, 5,6,7,8-tetrahydro-2-naphthyl group , Aromatic hydrocarbon groups such as fluorenyl group, phenyl tril group and anthryl group; and the like. The aromatic hydrocarbon group preferably has 6 to 30, more preferably 6 to 20, and even more preferably 6 to 15.
Examples of the group in which the hydrogen atom contained in the above-mentioned aliphatic hydrocarbon group is replaced with an aromatic hydrocarbon group having 1 to 40 carbon atoms include a benzyl group, a phenethyl group and a 1-methyl-1-phenylethyl group. An aralkyl group can be mentioned. Examples of the group in which the aliphatic hydrocarbon groups mentioned above are combined include a (cycloalkyl) alkyl group such as a cyclohexylmethyl group. The number of carbon atoms of a group in which a hydrogen atom contained in an aliphatic hydrocarbon group is substituted with an aromatic hydrocarbon group having 1 to 40 carbon atoms or a group in which an aliphatic hydrocarbon group is combined is preferably 4 to 30 and more. It is preferably 4 to 20, and more preferably 4 to 15.

The aliphatic hydrocarbon group having 1 to 40 carbon atoms, the phenyl group, the naphthyl group, the tetrahydronaphthyl group, the thienyl group, the furyl group and the pyridinyl group represented by R ^{11BZ6 may have a substituent.}
The substituents include the hydrocarbon groups represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. The same as a good substituent can be mentioned.
Preferred substituents include hydrocarbon groups represented by ^{R 1AZ6} , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , ^RAA1Z6 , ^RAA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. Examples include the same preferred substituents that may be used.

In compound (IZ6-B), R ^1BZ6 is preferably a hydrogen atom.
R ^2BZ6 , R ^3BZ6 , R ^4BZ6 or R ^5BZ6 are independent of each other,
Hydrogen atom, hydrocarbon group with 1 to 20 carbon atoms, halogen atom, -N (R ^102BZ6 ) ₂ , nitro group, hydrocarbon group with 1 to 20 carbon atoms in which all or part of the hydrogen atom is replaced by a fluorine atom, It is preferably -NHCO-R ^102BZ6 , -O-R ^102BZ6 , -SO ₃ M or -CO _{2 M.}
More preferably, it is a hydrogen atom or a nitro group. The number of nitro groups is preferably 0 to 2, more preferably 0 or 1.

R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 , R ^13BZ6 , R ^101BZ6 and R ^102BZ6 satisfy at least one of (rbb-i) to (rbb-iii). total number of a ^- or -CO ₂ ^- is ^{preferably, R 1BZ6, R 2BZ6, R} 3BZ6, R 4BZ6, R 5BZ6, R 11BZ6, R 12BZ6, R 13BZ6, R 101BZ6 and -SO ₃ R ^102BZ6 has be.
At least one ^{(rbb-i) R 1BZ6,} R 2BZ6, R 3BZ6, R 4BZ6, R 5BZ6, R 11BZ6, R 12BZ6 and R ^13BZ6 is, -SO ₃ ^- or -CO ₂ ^- a.
^(Rbb -ii) At least one of R 1BZ6, R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 and R ^13BZ6 is -CO-R ^102BZ6 , -COO-R ^101BZ6 , ^{-OR 102BZ6.} , -SO ₂ -R ^101BZ6 , -SO ₂ N (R ^102BZ6 ) ₂ ^{, -CON} (R 102BZ6) ₂ or -N (R ^102BZ6 ) ₂ , and the R ^101BZ6 and R ^102BZ6 are -SO ₃ ^- or -CO ₂ ^- 1 to 40 carbon atoms having a hydrocarbon group or a -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
At least one ^{(rbb-iii) R 1BZ6,} R 2BZ6, R 3BZ6, R 4BZ6, R 5BZ6, R 11BZ6, R 12BZ6 and R ^13BZ6 is, -SO ₃ ^- 1 to 40 carbon atoms having a ^- or -CO ₂ hydrocarbon group or a -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.

In the formula (IZ6-B), when R ^12BZ6 and R ^13BZ6 do not form a ring, the compound (IZ6-B) is referred to as a compound represented by the formula (IZ6-C) (hereinafter referred to as a compound (IZ6-C)). In some cases).

[In the formula (IZ6-C),
A ^{c +} , b, c, d, L ¹ and wavy lines have the same meanings as described above.
L ² is, -CO- or -SO ₂ - represents a.
R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 and R ^14CZ6 are independent of each other, hydrogen atom, -CO-R ^102CZ6 , -COO-R ^101CZ6 , -OCO-R ^102CZ6 , -COCO- R ^102CZ6 , ^{-OR 102CZ6} , -SO ₂ -R ^101CZ6 , -SO ₂ N (R ^102CZ6 ) ₂ ^{, -CON} (R 102CZ6) ₂ , -N (R ^102CZ6 ) ₂ , -NHCO-R ^102CZ6 , -NHCO _{^{-N (R 102CZ6) 2, -NHCOOR}} 102CZ6, -OCON (R 102CZ6) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , -SO 3 -, -CO 2 -, substituted It represents a hydrocarbon group having 1 to 40 carbon atoms which may have a group or a heterocyclic group which may have a substituent.
R ^2CZ6 and R ^3CZ6 , R ^3CZ6 and R ^4CZ6 , and R ^4CZ6 and R ^5CZ6 may be bonded to each other to form a ring, respectively.
R ^101CZ6 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent independently of each other.
R ^102CZ6 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent, independently of each other.
M represents the same meaning as described above.
Formulas (IZ6-C') and formulas (IZ6-C'') represent the substructures of formula (IZ6-C), respectively, Ac ⁺ , b, c, d, R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 , R ^14CZ6 , L ¹ and L ² represent the same as those in the equation (IZ6-C).
If there are multiple R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 , R ^14CZ6 , R ^101CZ6 , R ^102CZ6 , L ¹ , L ² , M, c or ^{Ac +} , they are the same. It may be present or different.
R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 , R ^14CZ6 , R ^101CZ6 and R ^102CZ6 satisfy at least one of (rc-i) to (rc-iii). ^{R 1CZ6, R 2CZ6, R 3CZ6} , R 4CZ6, R 5CZ6, R 11CZ6, R 14CZ6, R 101CZ6 and -SO ₃ R ^102CZ6 has ^- or -CO ₂ ^- total number of is a.
At least one ^{(rc-i) R 1CZ6,} R 2CZ6, R 3CZ6, R 4CZ6, R 5CZ6, R 11CZ6 and R ^14CZ6 is, -SO ₃ ^- or -CO ₂ ^- a.
(Rc-ii) At ^{least one of R 1CZ6} , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 and R ^14CZ6 is -CO-R ^102CZ6 , -COO-R ^101CZ6 , -OCO-R ^102CZ6 , -COCO -R ^102CZ6 , -O-R ^102CZ6 , -SO ₂ -R ^101CZ6 , -SO ₂ N (R ^102CZ6 ) ₂ ^{, -CON} (R 102CZ6) ₂ , -N (R ^102CZ6 ) ₂ , -NHCO-R ^102CZ6 ,- _{^{NHCO-N (R 102CZ6) 2}} , -NHCOOR 102CZ6, or -OCON (R ^102CZ6) a _2, wherein R ^101CZ6 and R ^102CZ6 is, -SO ₃ ^- 1 to 40 carbon atoms having a ^- or -CO ₂ hydrocarbon group or a -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
^{(Rc-iii) R 1CZ6,} R 2CZ6, R 3CZ6, R 4CZ6, at least one of R ^5CZ6, R ^11CZ6 and R ^14CZ6 is, -SO ₃ ^- or -CO ₂ ^- Number 1-40 hydrocarbon group having a carbon having or -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
a represents the same meaning as in the formula (IZ6-B). When a plurality of a exist, they may be the same or different.
The absolute value of the negative valence of the substructure represented by the formula (IZ6-C') and the positive valence of the substructure represented by the formula (IZ6-C ″) are the same. ]

The ^{R 1CZ6, R 2CZ6, R 3CZ6} , R 4CZ6, R 5CZ6, R 11CZ6 and R ^14CZ6, and ^{R 1AZ6, R 2AZ6, R 3AZ6} , R 4AZ6, R 5AZ6, R AA1Z6, R AA2Z6, R 12AZ6 and R ^13AZ6 The same can be mentioned.
^{R 1CZ6, R 2CZ6, R 3CZ6} , as R ^4CZ6, R ^5CZ6, preferred R ^11CZ6 and R ^{14CZ6 is, R 1AZ6, R 2AZ6, R} 3AZ6, R 4AZ6, R 5AZ6, R AA1Z6, R AA2Z6, R 12AZ6 and The same as the preferred one of ^{R 13 AZ6 can be mentioned.}

The R ^101CZ6 is the same as the R ^{101A Z6.}
Preferable examples of R ^101CZ6 may be the same as those preferred for R ^101AZ6.

^Examples of the R 102CZ6 include the same as the R ^{102A Z6.}
Preferred R ^{102 CZ6 includes} the same preferred ones of R ^{102 AZ6} .

The hydrocarbon groups and heterocyclic groups having 1 to 40 carbon atoms represented by R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 , R ^14CZ6 , R ^101CZ6 and R ^{102CZ6 have substituents.} May be. The substituents include the hydrocarbon groups represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. The same as a good substituent can be mentioned. Preferred substituents include hydrocarbon groups represented by ^{R 1AZ6} , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , ^RAA1Z6 , ^RAA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. Examples include the same preferred substituents that may be used.

L ¹ or L ² is preferably −CO−.

It is preferable that R ^11CZ6 and R ^14CZ6 are the same group, and L ¹ and L ² are the same group.

L ¹ and L ² are preferably −CO−.

R ^11CZ6 and R ^14CZ6 have an aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a phenyl group which may have a substituent, and a substituent which are independent of each other. It has a naphthyl group which may have a substituent, a tetrahydronaphthyl group which may have a substituent, a thienyl group which may have a substituent, and a frill group or a substituent which may have a substituent. It is preferably a pyridinyl group.

It has an aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have such a substituent, a phenyl group which may have a substituent, a naphthyl group which may have a substituent, and a substituent. Examples of the tetrahydronaphthyl group which may have a tetrahydronaphthyl group, a thienyl group which may have a substituent, a frill group which may have a substituent or a pyridinyl group which may have a substituent include a compound (IZ6). The above-mentioned aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent and the phenyl group which may have a substituent, which are mentioned as preferable in R ^{11BZ6 in −B),} A naphthyl group which may have a substituent, a tetrahydronaphthyl group which may have a substituent, a thienyl group which may have a substituent, a frill group which may have a substituent or a substituent. The same as the pyridinyl group which may have a group can be mentioned.

In compound (IZ6-C), R ^1CZ6 is preferably a hydrogen atom.
R ^2CZ6 , R ^3CZ6 , R ^4CZ6 and R ^5CZ6 are independent of each other.
Hydrogen atom, hydrocarbon group with 1 to 20 carbon atoms, halogen atom, -N (R ^102CZ6 ) ₂ , nitro group, hydrocarbon group with 1 to 20 carbon atoms in which all or part of the hydrogen atom is replaced by a fluorine atom, It is preferably -NHCO-R ^102CZ6 , -O-R ^102CZ6 , -SO ₃ M or -CO _{2 M.}
More preferably, it is a hydrogen atom or a nitro group. The number of nitro groups is preferably 0 to 2, more preferably 0 or 1.

R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 , R ^14CZ6 , R ^101CZ6 and R ^102CZ6 preferably satisfy at least one of (rcc-i) to (rcc-iii). ^{, R 1CZ6, R 2CZ6, R} 3CZ6, R 4CZ6, R 5CZ6, R 11CZ6, R 14CZ6, R 101CZ6 and -SO ₃ R ^102CZ6 has ^- or -CO ₂ ^- total number of is a.
^{(Rcc-i) R 1CZ6,} R 2CZ6, R 3CZ6, R 4CZ6, R 5CZ6, R 11CZ6, and at least one of R ^14CZ6 is, -SO ₃ ^- or -CO ₂ ^- a.
(Rcc-ii) At ^{least one of R 1CZ6} , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 and R ^14CZ6 is -CO-R ^102CZ6 , -COO-R ^101CZ6 , -COCO-R ^102CZ6 , -O -R ^102CZ6 , -SO ₂ -R ^101CZ6 , -SO ₂ N (R ^102CZ6 ) ₂ ^{, -CON} (R 102CZ6) ₂ , -N (R ^102CZ6 ) ₂ , -NHCO-N (R ^102CZ6 ) ₂ , -NHCOOR ^102CZ6 , or -OCON a (R ^102CZ6) _2, wherein R ^101CZ6 and R ^102CZ6 is, -SO ₃ ^- or -CO ₂ ^- 1 to 40 carbon atoms having a hydrocarbon group or a -SO ₃ ^- or -CO ₂ ^- a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
^{(Rcc-iii) R 1CZ6,} R 2CZ6, R 3CZ6, R 4CZ6, at least one of R ^5CZ6, R ^11CZ6 and R ^14C are, -SO ₃ ^- or -CO ₂ ^- Number 1-40 hydrocarbon group having a carbon having or -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.

R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 , R ^14CZ6 , R ^101CZ6 and R ^102CZ6 preferably satisfy at least one of (rc-I) and (rc-II). ..
At least one ^{(rc-I) R 2CZ6,} R 3CZ6, R 4CZ6, R 5CZ6 is, -SO ₃ ^- or -CO ₂ ^- a.
^{(Rc-II) R 1CZ6,} R 11CZ6 and at least one of R ^14CZ6 is, -SO ₃ ^- or -CO ₂ ^- hydrocarbon radical or -SO ₃ of carbon atoms 1 to 40 which may have a substituent having ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 , R ^14CZ6 , R ^101CZ6 and R ^102CZ6 preferably satisfy at least one of (rcc-I) and (rcc-II). ..
At least one ^{(rcc-I) R 2CZ6,} R 3CZ6, R 4CZ6, R 5CZ6 is, -SO ₃ ^- or -CO ₂ ^- a.
At least one ^{(rcc-II) R 1CZ6,} R 11CZ6 and R ^14CZ6 is, -SO ₃ ^- or -CO ₂ ^- is a hydrocarbon group having carbon atoms of 1 to 40 optionally having a substituent having a. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
However ^{R 1CZ6, R 2CZ6, R 3CZ6} , R 4CZ6, R 5CZ6, R 11CZ6, R 14CZ6, R 101CZ6 and -SO ₃ R ^102CZ6 has ^- or -CO ₂ ^- Total number of is a.

In the compound (IZ6-B), when R ^12BZ6 and R ^13BZ6 form a ring, the compound (IZ6-B) is referred to as a compound represented by the formula (IZ6-D) (hereinafter referred to as a compound (IZ6-D)). In some cases).

[In the formula (IZ6-D),
A ^{c +} , b, c, d, L ¹ and wavy lines have the same meanings as described above.
R ^20DZ6 and R ^30DZ6 combine to form ring Q.
Ring Q may have a substituent and has 5 to 7 ring members, and the ring Q may be a hydrocarbon ring or a heterocycle. Ring Q is condensed with a monocycle selected from a hydrocarbon ring and a heterocycle, which may have a substituent having 5 to 7 ring members, or a condensed ring obtained by condensing two or more of the monocycles. You may.
R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 and R ^11DZ6 are independent of each other, hydrogen atom, -CO-R ^102DZ6 , -COO-R ^101DZ6 , -OCO-R ^102DZ6 , -COCO-R ^102DZ6 , -O-R ^102DZ6 , -SO ₂ -R ^101DZ6 , -SO ₂ N (R ^102DZ6 ) ₂ ^{, -CON} (R 102DZ6) ₂ , -N (R ^102DZ6 ) ₂ , -NHCO-R ^102DZ6 , -NHCO-N ( _{^{R 102DZ6) 2, -NHCOOR 102DZ6,}} -OCON (R 102DZ6) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , -SO 3 -, -CO 2 -, have a substituent It represents a hydrocarbon group having 1 to 40 carbon atoms or a heterocyclic group which may have a substituent.
R ^2DZ6 and R ^3DZ6 , R ^3DZ6 and R ^4DZ6 , and R ^4DZ6 and R ^5DZ6 may be coupled to each other to form a ring, respectively.
R ^101DZ6 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent independently of each other.
R ^102DZ6 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent, independently of each other.
M represents the same meaning as described above.
Formulas (IZ6-D') and formulas (IZ6-D'') represent the substructures of formula (IZ6-D), respectively, Ac ⁺ , b, c, d, R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 , R ^11DZ6 , R ^20DZ6 , R ^30DZ6 and L ¹ represent the same as those in the equation (IZ6-D).
If there are multiple R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 , R ^11DZ6 , R ^101DZ6 , R ^102DZ6 , L ¹ , M, R ^20DZ6 , R ^30DZ6 , ring Q, c or ^{Ac +, they are} They may be the same or different.
R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 , R ^11DZ6 , R ^101DZ6 , R ^102DZ6 and ring Q satisfy at least one of (rd-i) to (rd-iv). ^{R 1DZ6, R 2DZ6, R 3DZ6} , R 4DZ6, R 5DZ6, R 11DZ6, R 101DZ6, R 102DZ6 and -SO ₃ having the ring Q ^- or -CO ₂ ^- total number of is a.
At least one ^{(rd-i) R 1DZ6,} R 2DZ6, R 3DZ6, R 4DZ6, R 5DZ6 and R ^11DZ6 is, -SO ₃ ^- or -CO ₂ ^- a.
^(Rd -ii) At least one of R 1DZ6, R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 and R ^11DZ6 is -CO-R ^102DZ6 , -COO-R ^101DZ6 , -OCO-R ^102DZ6 , -COCO-R ^102DZ6. , ^{-OR 102DZ6} , -SO ₂ -R ^101DZ6 , -SO ₂ N (R ^102DZ6 ) ₂ ^{, -CON} (R 102DZ6) ₂ , -N (R ^102DZ6 ) ₂ , -NHCO-R ^102DZ6 , -NHCO-N _{^{(R 102DZ6) 2, -NHCOOR 102DZ6}} , or -OCON (R ^102DZ6) a _2, wherein R ^101DZ6 and R ^102DZ6 is, -SO ₃ ^- or -CO ₂ ^- number 1-40 hydrocarbon group having a carbon having or -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
^{(Rd-iii) R 1DZ6,} R 2DZ6, R 3DZ6, R 4DZ6, at least one of R ^5DZ6 and R ^11DZ6 is, -SO ₃ ^- or -CO ₂ ^- hydrocarbon radical or -SO having 1 to 40 carbon atoms having a ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
(Rd-iv) ring Q is, -SO ₃ ^- or -CO ₂ ^- a with represents the same meaning as in formula (IZ6-B). When a plurality of a exist, they may be the same or different.
The absolute value of the negative valence of the substructure represented by the formula (IZ6-D') and the positive valence of the substructure represented by the formula (IZ6-D ″) are the same. ]

The number of ring members is preferably 5-6.
It is preferable that these monocyclic or condensed rings are combined with the ring Q at two points to form a condensed ring.
Examples of the ring Q and the ring obtained by condensing a monocyclic ring or a condensed ring therein include the same ring Q as in the group A.
Of these, the formula (Q1), the formula (Q4), the formula (Q7), the formula (Q8) and the formula (Q18) are preferably mentioned, and the formula (Q8) and the formula (Q18) are more preferable.

Ring Q, and a single ring selected from a hydrocarbon ring and a heterocycle which may be condensed with ring Q, which may have a substituent having 5 to 7 members of the ring, or two or more of the monocycles. The fused ring may have a substituent. The substituents include the hydrocarbon groups represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. The same as a good substituent can be mentioned.
Preferred substituents include hydrocarbon groups represented by ^{R 1AZ6} , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , ^RAA1Z6 , ^RAA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. Examples include the same preferred substituents that may be used.

R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 and R ^11DZ6 are R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^{12AZ 6} and R ^13AZ Can be mentioned.
As R ^1DZ6, R ^2DZ6, preferred R ^3DZ6, R ^4DZ6, R ^5DZ6 and R ^11DZ6 is the ^{R 1AZ6, R 2AZ6, R 3AZ6} , R 4AZ6, R 5AZ6, R AA1Z6, R AA2Z6, R 12AZ6 and R ^13AZ6 The same ones as preferred are mentioned.

The R ^101DZ6 is the same as the R ^{101A Z6.}
Preferable examples of R ^101DZ6 may be the same as those preferred for R ^101AZ6.

^Examples of the R 102DZ6 include the same as the R ^{102A Z6.}
Preferable examples of R ^102DZ6 may be the same as those preferred for R ^102AZ6.

^Even if the hydrocarbon groups and heterocyclic groups having 1 to 40 carbon atoms represented by R 1DZ6, R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 , R ^11DZ6 , R ^101DZ6 and R ^{102DZ6 have substituents.} good. The substituents include the hydrocarbon groups represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. The same as a good substituent can be mentioned. Preferred substituents include hydrocarbon groups represented by ^{R 1AZ6} , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , ^RAA1Z6 , ^RAA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. Examples include the same preferred substituents that may be used.

L ¹ is preferably −CO−.

R ^11DZ6 may have an aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a phenyl group which may have a substituent, and a substituent which are independent of each other. A naphthyl group, a tetrahydronaphthyl group which may have a substituent, a thienyl group which may have a substituent, a frill group which may have a substituent or a pyridinyl which may have a substituent. It is preferably a group.

It has an aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have such a substituent, a phenyl group which may have a substituent, a naphthyl group which may have a substituent, and a substituent. Examples of the tetrahydronaphthyl group which may have a tetrahydronaphthyl group, a thienyl group which may have a substituent, a frill group which may have a substituent or a pyridinyl group which may have a substituent include a compound (IZ6). The above-mentioned aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent and the phenyl group which may have a substituent, which are mentioned as preferable in R ^{11BZ6 in −B),} A naphthyl group which may have a substituent, a tetrahydronaphthyl group which may have a substituent, a thienyl group which may have a substituent, a frill group which may have a substituent or a substituent. The same as the pyridinyl group which may have a group can be mentioned.

In compound (IZ6-D), R ^1DZ6 is preferably a hydrogen atom.
R ^2DZ6 , R ^3DZ6 , R ^4DZ6 and R ^5DZ6 are independent of each other,
Hydrogen atom, hydrocarbon group with 1 to 20 carbon atoms, halogen atom, -N (R ^102DZ6 ) ₂ , nitro group, hydrocarbon group with 1 to 20 carbon atoms in which all or part of the hydrogen atom is replaced by a fluorine atom, It is preferably -NHCO-R ^102DZ6 , ^{-OR 102DZ6} , -SO ₃ M or -CO _{2 M.}
More preferably, it is a hydrogen atom or a nitro group. The number of nitro groups is preferably 0 to 2, more preferably 0 or 1.

R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 , R ^11DZ6 , R ^101DZ6 , R ^102DZ6 and ring Q preferably satisfy at least one of (rdd-i) to (rdd-iv). ^{, R 1DZ6, R 2DZ6, R} 3DZ6, R 4DZ6, R 5DZ6, R 11DZ6, R 101DZ6, R 102DZ6 and -SO ₃ having the ring Q ^- or -CO ₂ ^- total number of is a.
At least one ^{(rdd-i) R 1DZ6,} R 2DZ6, R 3DZ6, R 4DZ6, R 5DZ6 and R ^11DZ6 is, -SO ₃ ^- or -CO ₂ ^- a.
^(Rdd -ii) At least one of R 1DZ6, R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 and R ^11DZ6 is -CO-R ^102DZ6 , -COO-R ^101DZ6 , ^{-OR 102DZ6} , -SO _2- R _{^{101DZ6, -SO 2 N (R 102DZ6}} ) 2, -CON (R 102DZ6) 2 or -N (R ^102DZ6) a _2, wherein R ^101DZ6 and R ^102DZ6 is, -SO ₃ ^- having ^- or -CO ₂ hydrocarbon group or a -SO ₃ having 1 to 40 carbon atoms ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
^{(Rdd-iii) R 1DZ6,} R 2DZ6, R 3DZ6, R 4DZ6, at least one of R ^5DZ6 and R ^11DZ6 is, -SO ₃ ^- or -CO ₂ ^- hydrocarbon radical or -SO having 1 to 40 carbon atoms having a ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
(Rdd-iv) ring Q is, -SO ₃ ^- having ^- or -CO _2.

The compound (IZ6-D) is more preferably a compound represented by the formula (IZ6-E) (hereinafter, may be referred to as a compound (IZ6-E)).

[In the formula (IZ6-E),
A ^{c +} , b, c, d, L ¹ and wavy lines have the same meanings as described above.
R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 and R ^11EZ6 are independent of each other, hydrogen atom, -CO-R ^102EZ6 , -COO-R ^101EZ6 , -OCO-R ^102EZ6 , -COCO-R ^102EZ6 , -O-R ^102EZ6 , -SO _2- R ^101EZ6 , -SO ₂ N (R ^102EZ6 ) ₂ ^{, -CON} (R 102EZ6) ₂ , -N (R ^102EZ6 ) ₂ , -NHCO-R ^{102EZ6 , -NHCO-N (R 102EZ6)} 2, -NHCOOR 102EZ6, -OCON (R 102EZ6) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , -SO 3 -, -CO 2 ^—— Represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^2EZ6 and R ^3EZ6 , R ^3EZ6 and R ^4EZ6 , and R ^4EZ6 and R ^5EZ6 may be bonded to each other to form a ring, respectively.
R ^101EZ6 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent independently of each other.
R ^102EZ6 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent, independently of each other.
M represents the same meaning as described above.
Formulas (IZ6-E') and formulas (IZ6-E'') represent the substructures of formula (IZ6-E), respectively, Ac ⁺ , b, c, d, R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 , R ^11EZ6 and L ¹ represent the same as those in the equation (IZ6-E).
If there are multiple R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 , R ^11EZ6 , R ^101EZ6 , R ^102EZ6 , L ¹ , M, c or ^{Ac +} , they are the same. It may be present or different.
R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 , R ^11EZ6 , R ^101EZ6 and R ^102EZ6 satisfy at least one of (re-i) to (re-iii). ^{and, R 1EZ6, R 2EZ6, R} 3EZ6, R 4EZ6, R 5EZ6, R 6EZ6, R 7EZ6, R 11EZ6, R 101EZ6 and -SO ₃ R ^102EZ6 has ^- or -CO ₂ ^- total number of is a in ..
At least one of ^{(re-i) R 1EZ6,} R 2EZ6, R 3EZ6, R 4EZ6, R 5EZ6, R 6EZ6, R 7EZ6 and R ^11EZ6 is, -SO ₃ ^- or -CO ₂ ^- a.
(Re-ii) At ^{least one of R 1EZ6} , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 and R ^11EZ6 is -CO-R ^102EZ6 , -COO-R ^101EZ6 , -OCO-R ^102EZ6. , -COCO-R ^102EZ6 , -O-R ^102EZ6 , -SO ₂ -R ^101EZ6 , -SO ₂ N (R ^102EZ6 ) ₂ ^{, -CON} (R 102EZ6) ₂ , -N (R ^102EZ6 ) ₂ , -NHCO-R ^{102EZ6, -NHCO-N (R 102EZ6} ) 2, -NHCOOR 102EZ6, or -OCON a (R ^102EZ6) _2, wherein R ^101EZ6 and R ^102EZ6 is, -SO ₃ ^- or -CO ₂ ^- carbons having 1 40 hydrocarbon group or -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
At least one of ^{(re-iii) R 1EZ6,} R 2EZ6, R 3EZ6, R 4EZ6, R 5EZ6, R 6EZ6, R 7EZ6 and R ^11EZ6 is, -SO ₃ ^- 1 to 40 carbon atoms having a ^- or -CO ₂ hydrocarbon group or a -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
a represents the same meaning as in the formula (IZ6-D). When a plurality of a exist, they may be the same or different.
The absolute value of the negative valence of the substructure represented by the formula (IZ6-E') and the positive valence of the substructure represented by the formula (IZ6-E ″) are the same. ]

The ^{R 1EZ6, R 2EZ6, R 3EZ6} , R 4EZ6, R 5EZ6, R 6EZ6, R 7EZ6 and ^{R 11EZ6, R 1AZ6, R 2AZ6} , R 3AZ6, R 4AZ6, R 5AZ6, R AA1Z6, R AA2Z6, R 12AZ6 and The ^{same as R 13 AZ6} can be mentioned.
^{R 1EZ6, R 2EZ6, R 3EZ6} , R 4EZ6, R 5EZ6, R 6EZ6, preferable examples of R ^7EZ6 and R ^{11EZ6 is, R 1AZ6, R 2AZ6, R} 3AZ6, R 4AZ6, R 5AZ6, R AA1Z6, R AA2Z6, The same preferable ones of ^{R 12 AZ6} and R ^{13 AZ6 can be mentioned.}

R ^6EZ6 and R ^7EZ6 are independent of each other, methyl group, ethyl group, propyl group, isopropyl group, butyl group, tert-butyl group, pentyl group, hexyl group, (2-ethyl) hexyl group, heptyl group, octyl group. , A hydrocarbon group having 1 to 10 carbon atoms such as a nonyl group, a cyclohexyl group and a phenyl group, or a hydrogen atom is preferable.

The R ^101EZ6 is the same as the R ^{101A Z6.}
Preferable examples of R ^101EZ6 may be the same as those preferred for R ^101AZ6.

^Examples of the R 102EZ6 include the same as the R ^{102A Z6.}
Preferable examples of R ^102EZ6 may be the same as those preferred for R ^102AZ6.

The hydrocarbon groups and heterocyclic groups having 1 to 40 carbon atoms represented by R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 , R ^11EZ6 , R ^101EZ6 and R ^{102EZ6 are substituents.} May have. The substituents include the hydrocarbon groups represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. The same as a good substituent can be mentioned. Preferred substituents include hydrocarbon groups represented by ^{R 1AZ6} , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , ^RAA1Z6 , ^RAA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. Examples include the same preferred substituents that may be used.

L ¹ is preferably −CO−.

R ^11EZ6 may have an aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a phenyl group which may have a substituent, and a substituent which are independent of each other. A naphthyl group, a tetrahydronaphthyl group which may have a substituent, a thienyl group which may have a substituent, a frill group which may have a substituent or a pyridinyl which may have a substituent. It is preferably a group.

It has an aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have such a substituent, a phenyl group which may have a substituent, a naphthyl group which may have a substituent, and a substituent. Examples of the tetrahydronaphthyl group which may have a tetrahydronaphthyl group, a thienyl group which may have a substituent, a frill group which may have a substituent or a pyridinyl group which may have a substituent include a compound (IZ6). The above-mentioned aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent and the phenyl group which may have a substituent, which are mentioned as preferable in R ^{11BZ6 in −B),} A naphthyl group which may have a substituent, a tetrahydronaphthyl group which may have a substituent, a thienyl group which may have a substituent, a frill group which may have a substituent or a substituent. The same as the pyridinyl group which may have a group can be mentioned.

In compound (IZ6-E), R ^1EZ6 is preferably a hydrogen atom.
R ^2EZ6 , R ^3EZ6 , R ^4EZ6 and R ^5EZ6 are independent of each other,
Hydrogen atom, hydrocarbon group with 1 to 20 carbon atoms, halogen atom, -N (R ^102EZ6 ) ₂ , nitro group, hydrocarbon group with 1 to 20 carbon atoms in which all or part of the hydrogen atom is replaced by a fluorine atom, It is preferably -NHCO-R ^102EZ6 , -O-R ^102EZ6 , -SO ₃ M or -CO _{2 M.}
More preferably, it is a hydrogen atom or a nitro group. The number of nitro groups is preferably 0 to 2, more preferably 0 or 1.

R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 , R ^11EZ6 , R ^101EZ6 and R ^102EZ6 satisfy at least one of (ree-i) to (ree-iii). total number of a ^- or -CO ₂ ^- is ^{preferably, R 1EZ6, R 2EZ6, R} 3EZ6, R 4EZ6, R 5EZ6, R 6EZ6, R 7EZ6, R 11EZ6, R 101EZ6 and -SO ₃ R ^102EZ6 has be.
At least one ^{(ree-i) R 1EZ6,} R 2EZ6, R 3EZ6, R 4EZ6, R 5EZ6, R 6EZ6, R 7EZ6 and R ^11EZ6 is, -SO ₃ ^- or -CO ₂ ^- a.
^(Ree -ii) At least one of R 1EZ6, R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 and R ^11EZ6 is -CO-R ^102EZ6 , -COO-R ^101EZ6 , -O-R ^102EZ6. , -SO ₂ -R ^101EZ6 , -SO ₂ N (R ^102EZ6 ) ₂ ^{, -CON} (R 102EZ6) ₂ or -N (R ^102EZ6 ) ₂ , and the R ^101EZ6 and R ^102EZ6 are -SO ₃ ^- or -CO ₂ ^- 1 to 40 carbon atoms having a hydrocarbon group or a -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
At least one ^{(ree-iii) R 1EZ6,} R 2EZ6, R 3EZ6, R 4EZ6, R 5EZ6, R 6EZ6, R 7EZ6 and R ^11EZ6 is, -SO ₃ ^- 1 to 40 carbon atoms having a ^- or -CO ₂ hydrocarbon group or a -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.

Specific examples of the compound (IZ6) include the compounds (IFZ6-1) to the compounds (IFZ6) shown in Tables 1Z6 to 4Z6 in the formulas (IFZ6), formula (IGZ6), formula (IHZ6) and formula (IJZ6). −32), compound (IGZ6-1) to compound (IGZ6-32), compound (IHZ6-1) to compound (IHZ6-32) and compound (IJZ6-1) to compound (IJZ6-32).
Equation (IFZ6), formula (IGZ6), in formula (IHZ6) and formula (IJZ6), "- SO ₃ ^-" is that by replacing one of the respective hydrogen atoms included in the partial structure within the brackets It shall mean.

For example, the compound (IFZ6-1) is a compound represented by the formula (IFZ6-1).

As a compound (IZ6),
Compound (IFZ6-1) to compound (IFZ6-4), compound (IFZ6-6) to compound (IFZ6-7), compound (IFZ6-10) to compound (IFZ6-13), compound (IFZ6-15) to compound (IFZ6-19), compound (IFZ6-21) to compound (IFZ6-22), compound (IFZ6-25) to compound (IFZ6-28) and compound (IFZ6-30) to compound (IFZ6-32);
Compound (IGZ6-1) to compound (IGZ6-4), compound (IGZ6-6) to compound (IGZ6-7), compound (IGZ6-10) to compound (IGZ6-13), compound (IGZ6-15) to compound (IGZ6-19), compound (IGZ6-21) to compound (IGZ6-22), compound (IGZ6-25) to compound (IGZ6-28) and compound (IGZ6-30) to compound (IGZ6-32);
Compound (IHZ6-1) to compound (IHZ6-4), compound (IHZ6-6) to compound (IHZ6-7), compound (IHZ6-10) to compound (IHZ6-13), compound (IHZ6-15) to compound (IHZ6-19), Compound (IHZ6-21) to Compound (IHZ6-22), Compound (IHZ6-25) to Compound (IHZ6-28) and Compound (IHZ6-30) to Compound (IHZ6-32); (IJZ6-1) -Compound (IJZ6-4), Compound (IJZ6-6) -Compound (IJZ6-7), Compound (IJZ6-10) -Compound (IJZ6-13), Compound (IJZ6-15) -Compound ( IJZ6-19), compound (IJZ6-21) to compound (IJZ6-22), compound (IJZ6-25) to compound (IJZ6-28) and compound (IJZ6-30) to compound (IJZ6-32) are preferable.
Compound (IFZ6-1) to compound (IFZ6-4), compound (IFZ6-6) to compound (IFZ6-7), compound (IFZ6-10) to compound (IFZ6-13), compound (IFZ6-15) to compound (IFZ6-19), compound (IFZ6-21) to compound (IFZ6-22), compound (IFZ6-25) to compound (IFZ6-28) and compound (IFZ6-30);
Compound (IGZ6-1) to compound (IGZ6-4), compound (IGZ6-6) to compound (IGZ6-7), compound (IGZ6-10) to compound (IGZ6-13), compound (IGZ6-15) to compound (IGZ6-19), compound (IGZ6-21) to compound (IGZ6-22), compound (IGZ6-25) to compound (IGZ6-28) and compound (IGZ6-30);
Compound (IHZ6-1) to compound (IHZ6-4), compound (IHZ6-6) to compound (IHZ6-7), compound (IHZ6-10) to compound (IHZ6-13), compound (IHZ6-15) to compound (IHZ6-19), compound (IHZ6-21) to compound (IHZ6-22), compound (IHZ6-25) to compound (IHZ6-28) and compound (IHZ6-30); and compound (IJZ6-1) to compound. (IJZ6-4), Compound (IJZ6-6) to Compound (IJZ6-7), Compound (IJZ6-10) to Compound (IJZ6-13), Compound (IJZ6-15) to Compound (IJZ6-19), Compound (IJZ6-19) More preferably, IJZ6-21) to compound (IJZ6-22), compound (IJZ6-25) to compound (IJZ6-28) and compound (IJZ6-30).
Compound (IFZ6-1) to compound (IFZ6-4), compound (IFZ6-6) to compound (IFZ6-7), compound (IFZ6-10) to compound (IFZ6-13), compound (IFZ6-15) to compound (IFZ6-19), compound (IFZ6-21) to compound (IFZ6-22), compound (IFZ6-25) to compound (IFZ6-28) and compound (IFZ6-30); and compound (IJZ6-1) to compound. (IJZ6-4), Compound (IJZ6-6) to Compound (IJZ6-7), Compound (IJZ6-10) to Compound (IJZ6-13), Compound (IJZ6-15) to Compound (IJZ6-19), Compound (IJZ6-19) IJZ6-21) to compound (IJZ6-22), compound (IJZ6-25) to compound (IJZ6-28) and compound (IJZ6-30) are more preferred.

As the compound (IZ6), in the formula (IZ6-C),
L ¹ and L ² are the same group, −CO _{− or −SO 2−} , preferably −CO−.
R ^11CZ6 and R ^14CZ6 has the same group, hydroxy group, -O ^-, or -SO ₃ ^-, -CO ₂ ^-, a substituent selected from the group consisting of -SO ₃ M and -CO ₂ M It is a hydrocarbon group having 1 to 20 carbon atoms which may be possessed.
R ^1CZ6 is a hydrogen atom or -SO ₃ ^-, -CO ₂ ^-, carbonization of -SO ₃ M and -CO ₂ carbon atoms which may have a substituent selected from the group consisting of M 1 to 20 hydrogen _{^{group, -SO 3 -, -CO 2 -}} , a -SO ₃ M or -CO ₂ M,
R ^{2CZ6 to} R ^5CZ6 are each independently composed of hydrogen atoms, hydrocarbon groups having 1 to 20 carbon atoms, halogen atoms, -N (R ^102CZ6 ) ₂ , nitro groups, and all or part of hydrogen atoms. substituted hydrocarbon group having a carbon number of ^{1~20, -NHCO-R 102CZ6, -O} -R 102CZ6, -SO 3 -, -CO 2 -, a -SO ₃ M or -CO ₂ M,
R ^102CZ6 is a hydrogen atom or -SO ₃ ^-, -CO ₂ ^-, carbonization of -SO ₃ M and -CO ₂ carbon atoms which may have a substituent selected from the group consisting of M 1 to 20 It is a hydrogen group
^{Ac +} is Mg ²⁺ , Ca ²⁺ , Sr ²⁺ , Ba ²⁺ , Cd ²⁺ , Ni ²⁺ , Zn ²⁺ , Cu ²⁺ , Hg ²⁺ , Fe ²⁺ , Co ²⁺ , Sn ^{2 Divalent metal cations such as +} , Pb ²⁺ and Mn ²⁺ , trivalent metal cations such as Al ³⁺ , Fe ³⁺ and Cr ³⁺ , tetravalent such as Sn ⁴⁺ and Mn ⁴⁺ It is a metal cation and
M is preferably a compound which is a hydrogen atom or an alkali metal atom.
L ¹ and L ² are the same group, −CO _{− or −SO 2−} , preferably −CO−.
R ^11CZ6 and R ^14CZ6 has the same group, hydroxy group, -O ^-, or -SO ₃ ^-, -CO ₂ ^-, a substituent selected from the group consisting of -SO ₃ M and -CO ₂ M It is a hydrocarbon group having 1 to 10 carbon atoms which may be possessed.
R ^1CZ6 is a hydrogen atom
R ^{2CZ6 to} R ^5CZ6 are each independently composed of hydrogen atoms, hydrocarbon groups having 1 to 10 carbon atoms, halogen atoms, -N (R ^102CZ6 ) ₂ , nitro groups, and all or part of hydrogen atoms. substituted hydrocarbon group having 1 to 10 carbon ^{atoms, -NHCO-R 102CZ6, -O-} R 102CZ6, -SO 3 -, -CO 2 -, a -SO ₃ M or -CO ₂ M,
R ^102CZ6 is a hydrogen atom or -SO ₃ ^-, -CO ₂ ^-, carbonization of -SO ₃ M and -CO ₂ M carbon atoms which may have a substituent selected from the group consisting of 1 to 10 It is a hydrogen group
^{Ac +} is Mg ²⁺ , Ca ²⁺ , Sr ²⁺ , Ba ²⁺ , Ni ²⁺ , Zn ²⁺ , Cu ²⁺ , Fe ²⁺ , Co ²⁺ , Sn ²⁺ , Mn ²⁺ , Al ^{3 +} , Fe ³⁺ , Cr ³⁺ , Sn ⁴⁺ or Mn ⁴⁺ ,
M is more preferably a compound which is a hydrogen atom or an alkali metal atom.
L ¹ and L ² are the same group, −CO _{− or −SO 2−} , preferably −CO−.
R ^11CZ6 and R ^14CZ6 has the same group, hydroxy group, -O ^-, or -SO ₃ ^-, -CO ₂ ^-, a substituent selected from the group consisting of -SO ₃ M and -CO ₂ M It is a hydrocarbon group having 1 to 10 carbon atoms which may be possessed.
R ^1CZ6 is a hydrogen atom
R ^{2CZ6 to} R ^5CZ6 are independently hydrogen atom, hydrocarbon group having 1 to 10 carbon atoms, halogen atom, -N (R ^102CZ6 ) ₂ , nitro group, trifluoromethyl group, ^{-OR 102CZ6} , respectively. -SO ₃ ^-, -CO ₂ ^-, a -SO ₃ M or -CO ₂ M,
R ^102CZ6 is a hydrogen atom or -SO ₃ ^-, -CO ₂ ^-, carbonization of -SO ₃ M and -CO ₂ M carbon atoms which may have a substituent selected from the group consisting of 1 to 10 It is a hydrogen group
^{Ac +} is Mg ²⁺ , Ca ²⁺ , Sr ²⁺ , Ba ²⁺ , Zn ²⁺ , Cu ²⁺ , Fe ²⁺ , Mn ²⁺ , Al ³⁺ , Fe ³⁺ , Cr ³⁺ or Mn ^{4 + And}
M is more preferably a compound which is a hydrogen atom or an alkali metal atom.

As the compound (IZ6), in the formula (IZ6-E),
L ¹ is, -CO- or -SO ₂ -, preferably -CO-,
R ^11EZ6 is hydroxy group, -O ^-, or _{^{-SO 3 -, -CO 2 -,}} -SO 3 M and -CO ₂ M carbon atoms which may have a substituent selected from the group consisting of 1 ~ 20 hydrocarbon groups
R ^1EZ6 is a hydrogen atom or -SO ₃ ^-, -CO ₂ ^-, carbonization of -SO ₃ M and -CO ₂ carbon atoms which may have a substituent selected from the group consisting of M 1 to 20 hydrogen _{^{group, -SO 3 -, -CO 2 -}} , a -SO ₃ M or -CO ₂ M,
In R ^{2EZ6 to} R ^5EZ6 , hydrogen atom, hydrocarbon group having 1 to 20 carbon atoms, halogen atom, -N (R ^102EZ6 ) ₂ , nitro group, and hydrogen atom are all or part of each, respectively. substituted hydrocarbon group having a carbon number of ^{1~20, -NHCO-R 102EZ6, -O} -R 102EZ6, -SO 3 -, -CO 2 -, a -SO ₃ M or -CO ₂ M,
R ^102EZ6 is a hydrogen atom or -SO ₃ ^-, -CO ₂ ^-, carbonization of -SO ₃ M and -CO ₂ carbon atoms which may have a substituent selected from the group consisting of M 1 to 20 It is a hydrogen group
R ^6EZ6 and R ^7EZ6, independently of each other, hydrogen atom, or -SO ₃ ^-, -CO ₂ ^-, which may have a substituent selected from the group consisting of -SO ₃ M and -CO ₂ M hydrocarbon group having 1 to 20 carbon _{^{atoms, -SO 3 -, -CO 2 -}} , a -SO ₃ M or -CO ₂ M,
A ^{c +} is Mg ²⁺ , Ca ²⁺ , Sr ²⁺ , Ba ²⁺ , Cd ²⁺ , Ni ²⁺ , Zn ²⁺ , Cu ²⁺ , Hg ²⁺ , Fe ²⁺ , Co ²⁺ , Sn ^{2 Divalent metal cations such as +} , Pb ²⁺ and Mn ²⁺ , trivalent metal cations such as Al ³⁺ , Fe ³⁺ and Cr ³⁺ , tetravalent such as Sn ⁴⁺ and Mn ⁴⁺ It is a metal cation, and M is preferably a compound which is a hydrogen atom or an alkali metal atom.
L ¹ is, -CO- or -SO ₂ -, preferably -CO-,
R ^11EZ6 is hydroxy group, -O ^-, or _{^{-SO 3 -, -CO 2 -,}} -SO 3 M and -CO ₂ M carbon atoms which may have a substituent selected from the group consisting of 1 It is a hydrocarbon group of 10 and
R ^1EZ6 is a hydrogen atom
In R ^{2EZ6 to} R ^5EZ6 , hydrogen atom, hydrocarbon group having 1 to 10 carbon atoms, halogen atom, -N (R ^102EZ6 ) ₂ , nitro group, and hydrogen atom are all or part of each, respectively. substituted hydrocarbon group having 1 to 10 carbon ^{atoms, -NHCO-R 102EZ6, -O-} R 102EZ6, -SO 3 -, -CO 2 -, a -SO ₃ M or -CO ₂ M,
R ^102EZ6 is a hydrogen atom or -SO ₃ ^-, -CO ₂ ^-, carbonization of -SO ₃ M and -CO ₂ M carbon atoms which may have a substituent selected from the group consisting of 1 to 10 It is a hydrogen group
R ^6EZ6 and R ^7EZ6, independently of each other, hydrogen atom, or -SO ₃ ^-, -CO ₂ ^-, which may have a substituent selected from the group consisting of -SO ₃ M and -CO ₂ M It is a hydrocarbon group having 1 to 10 carbon atoms.
^{Ac +} is Mg ²⁺ , Ca ²⁺ , Sr ²⁺ , Ba ²⁺ , Ni ²⁺ , Zn ²⁺ , Cu ²⁺ , Fe ²⁺ , Co ²⁺ , Sn ²⁺ , Mn ²⁺ , Al ^{3 +} , Fe ³⁺ , Cr ³⁺ , Sn ⁴⁺ or Mn ⁴⁺ ,
M is more preferably a compound which is a hydrogen atom or an alkali metal atom.
L ¹ is, -CO- or -SO ₂ -, preferably -CO-,
R ^11EZ6 is hydroxy group, -O ^-, or _{^{-SO 3 -, -CO 2 -,}} -SO 3 M and -CO ₂ M carbon atoms which may have a substituent selected from the group consisting of 1 It is a hydrocarbon group of 10 and
R ^1EZ6 is a hydrogen atom
R ^{2EZ6 to} R ^5EZ6 are independently hydrogen atom, hydrocarbon group having 1 to 10 carbon atoms, halogen atom, -N (R ^102EZ6 ) ₂ , nitro group, trifluoromethyl group, ^{-OR 102EZ6} , respectively. -SO ₃ ^-, -CO ₂ ^-, a -SO ₃ M or -CO ₂ M,
R ^102EZ6 is a hydrogen atom or -SO ₃ ^-, -CO ₂ ^-, carbonization of -SO ₃ M and -CO ₂ M carbon atoms which may have a substituent selected from the group consisting of 1 to 10 It is a hydrogen group
R ^6EZ6 and ^R7EZ6 are independent hydrogen atoms or hydrocarbon groups having 1 to 10 carbon atoms.
^{Ac +} is Mg ²⁺ , Ca ²⁺ , Sr ²⁺ , Ba ²⁺ , Zn ²⁺ , Cu ²⁺ , Fe ²⁺ , Mn ²⁺ , Al ³⁺ , Fe ³⁺ , Cr ³⁺ or Mn ^{4 + And}
M is more preferably a compound which is a hydrogen atom or an alkali metal atom.

The compound represented by the formula (IZ6) can be produced by reacting the compound represented by the formula (JZ6) with the compound represented by the formula (KZ6). However, as the compound represented by the formula (JZ6) and the compound represented by the formula (KZ6), one kind or two or more kinds can be used respectively.

[In the formula (JZ6), the formula (KZ6) and the formula (IZ6),
a, b, c, d, D, Z and ^{Ac +} have the same meanings as described above.
ZZ represents -SO ₃ M or -CO ₂ M.
M has the same meaning as described above.
MM represents a compound containing a metal in which 0 or more and c or less electrons are donated to ^{Ac +.}
When a plurality of compounds D, ZZ, a, MM, and M represented by the formula (JZ6) are present, they may be the same or different. ]

As a compound represented by the formula (KZ6),
Inorganic compounds such as chlorides, bromides, iodides, sulfates, nitrates, fluorosulfonates, phosphates, etc. containing metals that donated 0 to c electrons to A ^{c +;}
Sulfates such as methane sulfonates, trifluoromethane sulfonates, p-toluene sulfonates, etc. containing metals that donated 0 or more and c or less electrons to A ^{c +;}
Carborates such as acetates, citrates, formates, gluconates, lactates, oxalates, tartrates, etc. containing metals that donated 0 or more and c or less electrons to A ^{c +;}
A metal in which an alkoxy group such as a methoxy group, an ethoxy group, or a tert-butoxy group is substituted, and A ^{c +} is donated with 0 or more and c or less electrons;
A metal in which 0 or more and c or less electrons are donated to ^{Ac +} , which is substituted with a butyl group, tert-butyl group, phenyl group, etc.;
Examples thereof include a metal in which 0 or more and c or less electrons ^{are donated to Ac + in} which a hydroxy group is substituted.

The amount of the compound represented by the formula (KZ6) to be used is usually 0.05 to 20 mol, preferably 0.06 to 15 mol, preferably 0.1 mol, based on 1 mol of the compound represented by the formula (JZ6). 10 mol is more preferable.

When the compound represented by the formula (JZ6) and the compound represented by the formula (KZ6) are reacted, it is preferable that the bases coexist. Examples of the base include organic bases such as triethylamine, 4- (N, N-dimethylamino) pyridine, pyridine and piperidine, metal alkoxides such as sodium methoxide, sodium ethoxide, sodium tert-butoshikide and potassium tert-butoxide, and butyllithium. , Tert-Butyllithium, phenyllithium and other organic metal compounds, and inorganic bases such as lithium hydroxide, sodium hydroxide and potassium hydroxide.

The amount of the base used is usually 0.0001 to 10 mol, preferably 0.0001 to 8 mol, more preferably 0.0001 to 5 mol, and 0, based on 1 mol of the compound represented by the formula (JZ6). .0001-4 mol is more preferred.

The reaction between the compound represented by the formula (JZ6) and the compound represented by the formula (KZ6) is usually carried out in the presence of a solvent.
As the solvent, water; a nitrile solvent such as acetonitrile; an alcohol solvent such as methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol and 1-octanol; an ether solvent such as tetrahydrofuran; a ketone solvent such as acetone; acetic acid. Ester solvents such as ethyl; aliphatic hydrocarbon solvents such as hexane; aromatic hydrocarbon solvents such as toluene; halogenated hydrocarbon solvents such as methylene chloride and chloroform; amides such as N, N-dimethylformaldehyde and N-methylpyrrolidone. Solvents; and sulfoxide solvents such as dimethyl sulfoxide, preferably water, nitrile solvents, alcohol solvents, ether solvents, ketone solvents, ester solvents, aromatic hydrocarbon solvents, halogenated hydrocarbon solvents, amide solvents, and sulfoxides. Solvents include, more preferably water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, tetrahydrofuran, acetone, ethyl acetate, toluene, methylene chloride, chloroform, N, N. -Dimethylformaldehyde, N-methylpyrrolidone and dimethylsulfoxide, more preferably water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, acetone, methylene chloride, chloroform, Examples include N, N-dimethylformaldehyde, N-methylpyrrolidone and dimethylsulfoxide, with particular preference being water, acetonitrile, methanol, ethanol and 2-propanol.
The amount of the solvent used is usually 1 to 1000 parts by mass with respect to 1 part by mass of the compound represented by the formula (JZ6).

The reaction temperature of the compound represented by the formula (JZ6) and the compound represented by the formula (KZ6) is usually -20 to 200 ° C, preferably -10 to 100 ° C, and more preferably 0 to 50 ° C. Is. The reaction time is usually 0.5 to 300 hours.

When the compound represented by the formula (IZ6) is a compound represented by the formula (IZ6-A), it can be produced in the same manner as described above. Specifically, it can be produced by reacting a compound represented by the formula (JJZ6) with a compound represented by the formula (KZ6). However, as the compound represented by the formula (JJZ6) and the compound represented by the formula (KZ6), one kind or two or more kinds can be used respectively.

［式（ＪＪＺ６）、式（ＫＺ６）及び式（ＩＺ６−Ａ）中、
Ａ^c+、ｂ、ｃ、ｄ、Ｒ^1AZ6、Ｒ^2AZ6、Ｒ^3AZ6、Ｒ^4AZ6、Ｒ^5AZ6、Ｒ^AA1Z6、Ｒ^AA2Z6、Ｒ^12AZ6、Ｒ^13AZ6及び波線は、前記と同じ意味を表す。
Ｒ^1AAZ6、Ｒ^2AAZ6、Ｒ^3AAZ6、Ｒ^4AAZ6、Ｒ^5AAZ6、Ｒ^AAA1Z6、Ｒ^AAA2Z6、Ｒ^12AAZ6及びＲ^13AAZ6は、互いに独立に、水素原子、−ＣＯ−Ｒ^102AAZ6、−ＣＯＯ−Ｒ^101AAZ6、−ＯＣＯ−Ｒ^102AAZ6、−Ｏ−Ｒ^102AAZ6、−ＳＯ₂−Ｒ^101AAZ6、−ＳＯ₂Ｎ（Ｒ^102AAZ6）₂、−ＣＯＮ（Ｒ^102AAZ6）₂、−Ｎ（Ｒ^102AAZ6）₂、−ＮＨＣＯ−Ｒ^102AAZ6、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^2AAZ6とＲ^3AAZ6、Ｒ^3AAZ6とＲ^4AAZ6、Ｒ^4AAZ6とＲ^5AZ6、Ｒ^AAA1Z6とＲ^AAA2Z6及びＲ^12AAZ6とＲ^13AAZ6は、それぞれ互いに結合して環を形成してもよい。
Ｒ^101AAZ6は、互いに独立に、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102AAZ6は、互いに独立に、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、前記と同じ意味を表す。
Ｒ^1AAZ6、Ｒ^2AAZ6、Ｒ^3AAZ6、Ｒ^4AAZ6、Ｒ^5AAZ6、Ｒ^AAA1Z6、Ｒ^AAA2Z6、Ｒ^12AAZ6、Ｒ^13AAZ6、Ｒ^101AAZ6、Ｒ^102AAZ6又はＭが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
Ｒ^1AAZ6、Ｒ^2AAZ6、Ｒ^3AAZ6、Ｒ^4AAZ6、Ｒ^5AAZ6、Ｒ^AAA1Z6、Ｒ^AAA2Z6、Ｒ^12AAZ6、Ｒ^13AAZ6、Ｒ^101AAZ6及びＲ^102AAZ6は、（ｊ−ｉ）〜（ｊ−ｉｉｉ）のうち少なくとも１つを充足しており、Ｒ^1AAZ6、Ｒ^2AAZ6、Ｒ^3AAZ6、Ｒ^4AAZ6、Ｒ^5AAZ6、Ｒ^AAA1Z6、Ｒ^AAA2Z6、Ｒ^12AAZ6、Ｒ^13AAZ6、Ｒ^101AAZ6及びＲ^102AAZ6が有する−ＳＯ₃Ｍ又は−ＣＯ₂Ｍの合計個数はａ以上である。
（ｊ−ｉ）Ｒ^1AAZ6、Ｒ^2AAZ6、Ｒ^3AAZ6、Ｒ^4AAZ6、Ｒ^5AAZ6、Ｒ^AAA1Z6、Ｒ^AAA2Z6、Ｒ^12AAZ6及びＲ^13AAZ6の少なくとも一つが、−ＳＯ₃Ｍ又は−ＣＯ₂Ｍである。
（ｊ−ｉｉ）Ｒ^1AAZ6、Ｒ^2AAZ6、Ｒ^3AAZ6、Ｒ^4AAZ6、Ｒ^5AAZ6、Ｒ^AAA1Z6、Ｒ^AAA2Z6、Ｒ^12AAZ6及びＲ^13AAZ6の少なくとも一つが、−ＣＯ−Ｒ^102AAZ6、−ＣＯＯ−Ｒ^101AAZ6、−ＯＣＯ−Ｒ^102AAZ6、−Ｏ−Ｒ^102AAZ6、−ＳＯ₂−Ｒ^101AAZ6、−ＳＯ₂Ｎ（Ｒ^102AAZ6）₂、−ＣＯＮ（Ｒ^102AAZ6）₂、−Ｎ（Ｒ^102AAZ6）₂又は−ＮＨＣＯ−Ｒ^102AAZ6であって、該Ｒ^101AAZ6及びＲ^102AAZ6が、−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する炭素数１〜４０の炭化水素基又は−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する複素環基である。ただし該炭化水素基又は該複素環基は、−ＳＯ₃ ^-及び−ＣＯ₂ ^-以外の置換基を有していてもよい。
（ｊ−ｉｉｉ）Ｒ^1AAZ6、Ｒ^2AAZ6、Ｒ^3AAZ6、Ｒ^4AAZ6、Ｒ^5AAZ6、Ｒ^AAA1Z6、Ｒ^AAA2Z6、Ｒ^12AAZ6及びＲ^13AAZ6の少なくとも一つが、−ＳＯ₃Ｍ若しくは−ＣＯ₂Ｍを有する炭素数１〜４０の炭化水素基又は−ＳＯ₃Ｍ若しくは−ＣＯ₂Ｍを有する複素環基である。ただし該炭化水素基又は該複素環基は、−ＳＯ₃ ^-及び−ＣＯ₂ ^-以外の置換基を有していてもよい。
ａは、式（ＩＺ６）におけるものと同じ意味を表す。ａが複数存在する場合、それらは同一であってもよく、異なっていてもよい。］

[In the formula (JJZ6), the formula (KZ6) and the formula (IZ6-A),
A ^{c +} , b, c, d, R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 and wavy lines have the same meanings as described above.
R ^1AAZ6 , R ^2AAZ6 , R ^3AAZ6 , R ^4AAZ6 , R ^5AAZ6 , R ^AAA1Z6 , R ^AAA2Z6 , R ^12AAZ6 and R ^13AAZ6 are independent of each other, hydrogen atom, -CO-R ^102AAZ6 , -COO-R ^101AAZ6 , -OCO- R ^102AAZ6 , ^{-OR 102AAZ6} , -SO ₂ -R ^101AAZ6 , -SO ₂ N (R ^102AAZ6 ) ₂ ^{, -CON} (R 102AAZ6) ₂ , -N (R ^102AAZ6 ) ₂ , -NHCO-R ^102AAZ6 , Halogen atom , Cyano group, nitro group, -SO ₃ M, -CO ₂ M, hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent. ..
R ^2AAZ6 and R ^3AAZ6 , R ^3AAZ6 and R ^4AAZ6 , R ^4AAZ6 and R ^5AZ6 , R ^AAA1Z6 and R ^AAA2Z6 and R ^12AAZ6 and R ^13AAZ6 may be coupled to each other to form a ring, respectively.
R ^101AAZ6 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent independently of each other.
R ^102AAZ6 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent, independently of each other.
M represents the same meaning as described above.
If there are multiple R ^1AAZ6 , R ^2AAZ6 , R ^3AAZ6 , R ^4AAZ6 , R ^5AAZ6 , R ^AAA1Z6 , R ^AAA2Z6 , R ^12AAZ6 , R ^13AAZ6 , R ^101AAZ6 , R ^102AAZ6 or M, they may be the same or different. You may be.
R ^1AAZ6 , R ^2AAZ6 , R ^3AAZ6 , R ^4AAZ6 , R ^5AAZ6 , R ^AAA1Z6 , R ^AAA2Z6 , R ^12AAZ6 , R ^13AAZ6 , R ^101AAZ6 and R ^102AAZ6 are at least one of (j-i) to (j-iii). R ^1AAZ6 , R ^2AAZ6 , R ^3AAZ6 , R ^4AAZ6 , R ^5AAZ6 , R ^AAA1Z6 , R ^AAA2Z6 , R ^12AAZ6 , R ^13AAZ6 , R ^101AAZ6 and R ^102AAZ6 have -SO ₃ M or -CO ₂ M The total number is a or more.
(J-i) At least one of ^{R 1AAZ6} , R ^2AAZ6 , R ^3AAZ6 , R ^4AAZ6 , R ^5AAZ6 , R ^AAA1Z6 , R ^AAA2Z6 , R ^12AAZ6 and R ^13AAZ6 _{is -SO 3} M or -CO ₂ M.
(J-ii) At ^{least one of R 1AAZ6} , R ^2AAZ6 , R ^3AAZ6 , R ^4AAZ6 , R ^5AAZ6 , R ^AAA1Z6 , R ^AAA2Z6 , R ^12AAZ6 and R ^13AAZ6 is -CO-R ^102AAZ6 , -COO-R ^101AAZ6 , -OCO -R ^102AAZ6 , -O-R ^102AAZ6 , -SO ₂ -R ^101AAZ6 , -SO ₂ N (R ^102AAZ6 ) ₂ ^{, -CON} (R 102AAZ6) ₂ , -N (R ^102AAZ6 ) ₂ or -NHCO-R ^102AAZ6 Te, wherein R ^101AAZ6 and R ^102AAZ6 is, -SO ₃ ^- or -CO ₂ ^- 1 to 40 carbon atoms having a hydrocarbon group or a -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
(J-iii) At least one of ^{R 1AAZ6} , R ^2AAZ6 , R ^3AAZ6 , R ^4AAZ6 , R ^5AAZ6 , R ^AAA1Z6 , R ^AAA2Z6 , R ^12AAZ6 and R ^13AAZ6 _{has -SO 3} M or -CO ₂ M and has 1 carbon dioxide. A heterocyclic group having ~ 40 hydrocarbon groups or -SO ₃ M or -CO _{2 M.} However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
a represents the same meaning as in the equation (IZ6). When a plurality of a exist, they may be the same or different. ]

A compound represented by the formula (JJZ6) (hereinafter, may be referred to as a compound (JJZ6)) may be a compound represented by the formula (pt1Z6) (hereinafter, may be referred to as a phthalonitrile compound) when ^{R 1AAZ6 is a hydrogen atom.} After reacting with a compound represented by the formula (pt2Z6) (hereinafter, may be referred to as an alkoxide compound), a compound represented by the formula (pt3Z6) (hereinafter, may be referred to as a compound (pt3Z6)). It can be produced by further reacting with a compound represented by the formula (pt4Z6) (hereinafter, may be referred to as a compound (pt4Z6)) in the presence of an acid. When R ^{1AAZ 6} is other than a hydrogen atom, it is further reacted with a compound represented by the formula (pt5Z6) (hereinafter, may be referred to as a compound (pt5Z6)) to produce a compound represented by the formula (JJZ6). can.
Here, the compounds represented by the formula (pt1Z6), the formula (pt1Z6), the formula (pt3Z6), the formula (pt4Z6) and the formula (pt5Z6) may be independent compounds, or may be different compounds. It may be a mixture.

[In the formula (pt1Z6), formula (pt1Z6), formula (pt3Z6), formula (pt4Z6), formula (pt5Z6) and formula (JJZ6), R ^1AAZ6 , R ^2AAZ6 , R ^3AAZ6 , R ^4AAZ6 , R ^5AAZ6 , R ^AAA1Z6 R ^AAA2Z6 , R ^12AAZ6 and R ^13AAZ6 have the same meanings as described above.
R ^50Z6 represents an alkyl group having 1 to 20 carbon atoms.
M ^1Z6 represents an alkali metal atom.
LG represents a halogen atom, a methanesulfonyloxy group, a toluenesulfonyloxy group or a trifluoromethanesulfonyloxy group. ]

^Examples of the alkyl group having 1 to 20 carbon atoms represented by R 50Z6 include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, a sec-butyl group and a tert-butyl group, which are preferable. Examples include alkyl groups having 1 to 6 carbon atoms.
Examples of the alkali metal atom represented by M ^{1Z 6} include a lithium atom, a sodium atom and a potassium atom.

The amount of the alkoxide compound used is usually 0.1 to 10 mol, preferably 0.2 to 5 mol, and more preferably 0.3 to 3 mol, based on 1 mol of the phthalonitrile compound. More preferably, it is 0.4 to 2 mol.

The amount of the compound (pt3Z6) used is usually 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, still more preferably 1 mol, relative to 1 mol of the phthalonitrile compound. ~ 2 mol.
The amount of the compound (pt4Z6) used is usually 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, still more preferably 1 mol, relative to 1 mol of the phthalonitrile compound. ~ 2 mol.

Examples of the acid include inorganic acids such as hydrochloric acid, hydrobromic acid, hydroiodic acid, sulfuric acid, nitric acid, fluorosulfonic acid and phosphoric acid; sulfonic acids such as methanesulfonic acid, trifluoromethanesulfonic acid and p-toluenesulfonic acid; Examples thereof include carboxylic acids such as acetic acid, citric acid, formic acid, gluconic acid, lactic acid, oxalic acid and tartrate acid, preferably hydrochloric acid, hydrobromic acid, sulfuric acid, methanesulfonic acid, trifluoromethanesulfonic acid, p-toluenesulfonic acid and Examples include carboxylic acids, more preferably acetic acids.
The amount of the acid used is usually 1 to 20 mol, preferably 1 to 10 mol, more preferably 1 to 8 mol, still more preferably 1 to 6 mol, based on 1 mol of the phthalonitrile compound. be.

The reaction of the phthalonitrile compound, the alkoxide compound, the compound (pt3Z6) and the compound (pt4Z6) is usually carried out in the presence of a solvent.
As the solvent, water; a nitrile solvent such as acetonitrile; an alcohol solvent such as methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol and 1-octanol; an ether solvent such as tetrahydrofuran; a ketone solvent such as acetone; acetic acid. Ester solvents such as ethyl; aliphatic hydrocarbon solvents such as hexane; aromatic hydrocarbon solvents such as toluene; halogenated hydrocarbon solvents such as methylene chloride and chloroform; amides such as N, N-dimethylformaldehyde and N-methylpyrrolidone. Solvents: Sulfoxide solvents such as dimethylsulfoxide, preferably water, nitrile solvents, alcohol solvents, ether solvents, ketone solvents, ester solvents, aromatic hydrocarbon solvents, halogenated hydrocarbon solvents, amide solvents and sulfoxide solvents. More preferably, water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, tetrahydrofuran, acetone, ethyl acetate, toluene, methylene chloride, chloroform, N, N-dimethylformaldehyde. , N-Methylpyrrolidone and dimethylsulfoxide, more preferably water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, acetone, methylene chloride, chloroform, N, N. -Dimethylformaldehyde, N-methylpyrrolidone and dimethylsulfoxide are mentioned, and water, acetonitrile, methanol, ethanol and 2-propanol are particularly preferable.
The amount of the solvent used is usually 1 to 1000 parts by mass with respect to 1 part by mass of the phthalonitrile compound.

The reaction temperature is usually 0 to 200 ° C, preferably 0 to 100 ° C, more preferably 0 to 70 ° C, still more preferably 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

The amount of the compound (pt5Z6) used is usually 1 to 10 mol, preferably 1 to 5 mol, and more preferably 1 to 3 mol, relative to 1 mol of the compound (JJZ6) in which ^{R 1AAZ6 is a hydrogen atom.} It is more preferably 1 to 2 mol.

When the compound (pt5Z6) is reacted, it is preferable that a base coexists. Examples of the base include organic bases such as triethylamine, 4- (N, N-dimethylamino) pyridine, pyridine and piperidine, metal alkoxides such as sodium methoxide, sodium ethoxide, sodium tert-butoxide and potassium tert-butoxide, and butyl lithium. , Tert-Organic metal compounds such as lithium butyl and phenyl lithium; inorganic bases such as lithium hydroxide, sodium hydroxide and potassium hydroxide.

The amount of the base used is usually 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, and further, with respect to 1 mol of the compound (JJZ6) in which ^{R 1AAZ6 is a hydrogen atom.} It is preferably 1 to 2 mol.

The reaction of compound (pt5Z6) is usually carried out in the presence of a solvent. The solvent can be selected from the same range as described above.
The amount of the solvent used is usually 1 to 1000 parts by mass with respect to 1 part by mass of the compound (JJZ6) in which ^{R 1AAZ6 is a hydrogen atom.} The reaction temperature of the compound (pt5Z6) is usually −90 to 200 ° C., preferably −80 to 100 ° C., and more preferably 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

When the compound (JJZ6) is a _{compound that does not have -SO 3} M (hereinafter, may be referred to as a compound (JJJZ6)), the compound (JJZ6) is reacted with a sulfating agent such as fuming sulfuric acid or chlorosulfonic acid. By letting it be _{introduced, -SO 3} M can be introduced.

_{The amount of SO 3} used in fuming sulfuric acid is usually 1 to 50 mol, preferably 5 to 40 mol, more preferably 5 to 30 mol, still more preferably 5 to 30 mol, per 1 mol of compound (JJJJ6). It is 5 to 25 mol.
The amount of sulfuric acid used in fuming sulfuric acid is usually 1 to 200 mol, preferably 10 to 100 mol, more preferably 10 to 75 mol, and further preferably 10 to 1 mol of compound (JJJJ6). ~ 50 mol.

The amount of chlorosulfonic acid used is usually 1 to 500 mol, preferably 10 to 300 mol, more preferably 10 to 200 mol, still more preferably 10 to 150 mol, relative to 1 mol of compound (JJJJ6). It is a mole.

The reaction temperature for sulfonation is usually -20 to 200 ° C, preferably -10 to 100 ° C, and more preferably 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

The method for extracting the compound (JJZ6) from the reaction mixture is not particularly limited, and the compound (JJZ6) can be extracted by various known methods. For example, after completion of the reaction, the compound (JJZ6) can be taken out by filtering the reaction mixture. Further, after filtration, the obtained residue may be subjected to column chromatography, recrystallization or the like. Further, after completion of the reaction, the solvent of the reaction mixture may be distilled off and then purified by column chromatography.

The coloring composition of the present invention contains the compound (Z) and at least one of the resin (B) and the solvent (E), and contains both the compound (Z), the resin (B) and the solvent (E). It is preferable to include it.

The coloring composition of the present invention preferably contains a resin (hereinafter, may be referred to as a resin (B)). When the coloring composition contains the resin (B), the dispersion stability may be further improved.

<Resin (B)>
The resin (B) is preferably an alkali-soluble resin, and is at least one monomer (a) selected from the group consisting of unsaturated carboxylic acids and unsaturated carboxylic acid anhydrides (hereinafter referred to as "(a)"). It is more preferable that the polymer has a structural unit derived from (in some cases).
The resin (B) is a structural unit derived from a monomer (b) having a cyclic ether structure having 2 to 4 carbon atoms and an ethylenically unsaturated bond (hereinafter, may be referred to as “(b)”), and others. It is preferably a copolymer having the structural unit of.
As other structural units, the monomer (c) copolymerizable with the monomer (a) (however, it is different from the monomer (a) and the monomer (b). Hereinafter, “(c)”. A structural unit derived from (may be referred to as), a structural unit having an ethylenically unsaturated bond, and the like can be mentioned.

Examples of (a) include acrylic acid, methacrylic acid, crotonic acid, and unsaturated monocarboxylic acids such as o-, m-, and p-vinylbenzoic acid;
Maleic acid, fumaric acid, citraconic acid, mesaconic acid, itaconic acid, 3-vinylphthalic acid, 4-vinylphthalic acid, 3,4,5,6-tetrahydrophthalic acid, 1,2,3,6-tetrahydrophthalic acid, dimethyl Unsaturated dicarboxylic acids such as tetrahydrophthalic acid and 1,4-cyclohexendicarboxylic acid;
Methyl-5-norbornene-2,3-dicarboxylic acid, 5-carboxybicyclo [2.2.1] hept-2-ene, 5,6-dicarboxybicyclo [2.2.1] hept-2-ene, Bicyclounsaturated compounds containing carboxy groups such as 5-carboxymethylbicyclo [2.2.1] hept-2-ene and 5-carboxyethylbicyclo [2.2.1] hept-2-ene;
Carboxylic anhydrides such as the above unsaturated dicarboxylic acid anhydrides excluding fumaric acid and mesaconic acid;
Unsaturated mono-[(meth) acryloyloxyalkyl] esters of divalent or higher polyvalent carboxylic acids such as monosuccinate [2- (meth) acryloyloxyethyl] and mono [2- (meth) acryloyloxyethyl] phthalates. Kind;
Examples thereof include unsaturated acrylates containing a hydroxy group and a carboxy group in the same molecule, such as α- (hydroxymethyl) acrylic acid.
Of these, acrylic acid, methacrylic acid, maleic anhydride and the like are preferable from the viewpoint of copolymerization reactivity and the solubility of the obtained resin in an alkaline aqueous solution.

(B) refers to a polymerizable compound having a cyclic ether structure having 2 to 4 carbon atoms (for example, at least one selected from the group consisting of an oxylan ring, an oxetane ring and a tetrahydrofuran ring) and an ethylenically unsaturated bond. (B) is preferably a monomer having a cyclic ether having 2 to 4 carbon atoms and a (meth) acryloyloxy group.
Examples of (b) include a monomer (b1) having an oxylanyl group and an ethylenically unsaturated bond (hereinafter sometimes referred to as “(b1)”), and a simple monomer having an oxetanyl group and an ethylenically unsaturated bond. A metric (b2) (hereinafter sometimes referred to as "(b2)") and a monomer (b3) having a tetrahydrofuryl group and an ethylenically unsaturated bond (hereinafter sometimes referred to as "(b3)") and the like. Can be mentioned.

As (b1), for example, a monomer (b1-1) having a structure in which a linear or branched aliphatic unsaturated hydrocarbon is epoxidized (hereinafter referred to as “(b1-1)” may be used. There is) and a monomer (b1-2) having an epoxidized structure of an alicyclic unsaturated hydrocarbon (hereinafter, may be referred to as “(b1-2)”).

As (b1-1), a monomer having a glycidyl group and an ethylenically unsaturated bond is preferable. Specific examples of (b1-1) include glycidyl (meth) acrylate, β-methylglycidyl (meth) acrylate, β-ethylglycidyl (meth) acrylate, glycidyl vinyl ether, vinylbenzyl glycidyl ether, and α-methylvinylbenzyl. Glycidyl ether, 2,3-bis (glycidyloxymethyl) styrene, 2,4-bis (glycidyloxymethyl) styrene, 2,5-bis (glycidyloxymethyl) styrene, 2,6-bis (glycidyloxymethyl) styrene , 2,3,4-tris (glycidyloxymethyl) styrene, 2,3,5-tris (glycidyloxymethyl) styrene, 2,3,6-tris (glycidyloxymethyl) styrene, 3,4,5-tris Examples thereof include (glycidyloxymethyl) styrene and 2,4,6-tris (glycidyloxymethyl) styrene.
Examples of (b1-2) include vinylcyclohexene monooxide, 1,2-epoxy-4-vinylcyclohexane (for example, celloxide (registered trademark) 2000; manufactured by Daicel Corporation), and 3,4-epoxycyclohexylmethyl (meth). Acrylate (for example, Cyclomer (registered trademark) A400; manufactured by Daicel Corporation), 3,4-epoxycyclohexylmethyl (meth) acrylate (for example, Cyclomer (registered trademark) M100; manufactured by Daicel Corporation), formula ( Examples thereof include a compound represented by BI) and a compound represented by the formula (BII).

[In the formula (BI) and the formula (BII), ^Ra and R ^b independently represent a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and the hydrogen atom contained in the alkyl group is a hydroxy group. It may be replaced.
X ^a and X ^b are each independently a single ^{bond, * - R c -, *} - R c -O -, * - represents the R ^c -S- or * -R ^c -NH-.
R ^c represents an alkanediyl group having 1 to 6 carbon atoms.
* Represents a bond with O. ]

Examples of the compound represented by the formula (BI) include compounds represented by any of the formulas (BI-1) to (BI-15), preferably the formulas (BI-1) and the formula (BI-15). -3), formula (BI-5), formula (BI-7), formula (BI-9) and compounds represented by formulas (BI-11) to formulas (BI-15) are mentioned, more preferably. Examples thereof include compounds represented by the formula (BI-1), the formula (BI-7), the formula (BI-9) and the formula (BI-15).

Examples of the compound represented by the formula (BII) include compounds represented by any of the formulas (BII-1) to (BII-15), preferably the formulas (BII-1) and the formula (BII-15). -3), formulas (BII-5), formulas (BII-7), formulas (BII-9) and compounds represented by formulas (BII-11) to formulas (BII-15) are more preferable. Examples thereof include compounds represented by the formula (BII-1), the formula (BII-7), the formula (BII-9) and the formula (BII-15).

The compound represented by the formula (BI) and the compound represented by the formula (BII) may be used alone or in combination with the compound represented by the formula (BI) and the compound represented by the formula (BII). You may. When these are used in combination, the content ratio of the compound represented by the formula (BI) and the compound represented by the formula (BII) is, preferably 5:95 to 95: 5, more preferably 10: It is 90 to 90:10, more preferably 20:80 to 80:20.

Examples of (c) include methyl (meth) acrylate, ethyl (meth) acrylate, n-butyl (meth) acrylate, sec-butyl (meth) acrylate, tert-butyl (meth) acrylate, and 2-ethylhexyl (meth). Acrylate, dodecyl (meth) acrylate, lauryl (meth) acrylate, stearyl (meth) acrylate, cyclopentyl (meth) acrylate, tricyclo [5.2.1.0 ^2,6 ] decan-8-yl (meth) acrylate, tricyclo [5.2.1.0 ^2,6 ] Decane-9-yl (meth) acrylate, tricyclo [5.2.1.0 ^2,6 ] Decene-8-yl (meth) acrylate, tricyclo [5.2] .1.0 ^2,6 ] Decene-9-yl (meth) acrylate, dicyclopentanyloxyethyl (meth) acrylate, isobornyl (meth) acrylate, adamantyl (meth) acrylate, allyl (meth) acrylate, propargyl (meth) ) (Meta) acrylic acid esters such as acrylates, phenyl (meth) acrylates, naphthyl (meth) acrylates and benzyl (meth) acrylates;
Hydroxy group-containing (meth) acrylic acid esters such as 2-hydroxyethyl (meth) acrylate and 2-hydroxypropyl (meth) acrylate;
Dicarboxylic acid diesters such as diethyl maleate, diethyl fumarate and diethyl itaconic acid;
Bicyclo [2.2.1] hept-2-ene, 5-methylbicyclo [2.2.1] hept-2-ene, 5-ethylbicyclo [2.2.1] hept-2-ene, 5- Hydroxybicyclo [2.2.1] hept-2-ene, 5-hydroxymethylbicyclo [2.2.1] hept-2-ene, 5- (2'-hydroxyethyl) bicyclo [2.2.1] Hept-2-ene, 5-methoxybicyclo [2.2.1] hept-2-ene, 5-ethoxybicyclo [2.2.1] hept-2-ene, 5,6-dihydroxybicyclo [2.2] .1] Hept-2-ene, 5,6-di (hydroxymethyl) bicyclo [2.2.1] Hept-2-ene, 5,6-di (2'-hydroxyethyl) bicyclo [2.2. 1] Hept-2-ene, 5,6-dimethoxybicyclo [2.2.1] hept-2-ene, 5,6-diethoxybicyclo [2.2.1] hept-2-ene, 5-hydroxy -5-Methylbicyclo [2.2.1] hept-2-ene, 5-hydroxy-5-ethylbicyclo [2.2.1] hept-2-ene, 5-hydroxymethyl-5-methylbicyclo [2] .2.1] Hept-2-ene, 5-tert-butoxycarbonylbicyclo [2.2.1] hept-2-ene, 5-cyclohexyloxycarbonylbicyclo [2.2.1] hept-2-ene, 5-Phenoxycarbonylbicyclo [2.2.1] hept-2-ene, 5,6-bis (tert-butoxycarbonyl) bicyclo [2.2.1] hept-2-ene and 5,6-bis (cyclohexyl) Bicyclounsaturated compounds such as oxycarbonyl) bicyclo [2.2.1] hept-2-ene;
N-Phenylmaleimide, N-Cyclohexylmaleimide, N-benzylmaleimide, N-succinimidyl-3-maleimidebenzoate, N-succinimidyl-4-maleimidebutyrate, N-succinimidyl-6-maleimide caproate, N-succinimidyl-3 -Maleimide propionate and dicarbonylimide derivatives such as N- (9-acridinyl) maleimide;
Vinyl group-containing aromatic compounds such as styrene, α-methylstyrene, vinyltoluene and p-methoxystyrene; vinyl group-containing nitriles such as (meth) acrylonitrile; halogenated hydrocarbons such as vinyl chloride and vinylidene chloride; (meth) acrylamide. Such as vinyl group-containing amides; esters such as vinyl acetate; dienes such as 1,3-butadiene, isoprene and 2,3-dimethyl-1,3-butadiene; and the like.
Of these, from the viewpoint of copolymerization reactivity and heat resistance, styrene, vinyltoluene, tricyclo [5.2.1.0 ^2,6 ] decane-8-yl (meth) acrylate, tricyclo [5.2.1] .0 ^2,6 ] Decane-9-yl (meth) acrylate, tricyclo [5.2.1.0 ^2,6 ] Decene-8-yl (meth) acrylate, tricyclo [5.2.1.0 ^{2, 6} ] Decene-9-yl (meth) acrylate, N-phenylmaleimide, N-cyclohexylmaleimide, N-benzylmaleimide, bicyclo [2.2.1] hept-2-ene, benzyl (meth) acrylate and the like are preferable.

The structural unit having an ethylenically unsaturated bond is preferably a structural unit having a (meth) acryloyl group. A resin having such a structural unit has an ethylenically unsaturated bond in a polymer having a structural unit derived from (a) or (b) and a group capable of reacting with the group having (a) or (b). It can be obtained by adding a monomer having.
Such structural units include a structural unit in which glycidyl (meth) acrylate is added to a (meth) acrylic acid unit, a structural unit in which 2-hydroxyethyl (meth) acrylate is added to a maleic anhydride unit, and glycidyl (meth). ) A structural unit in which (meth) acrylic acid is added to the acrylate unit can be mentioned. When these structural units have a hydroxy group, a structural unit to which a carboxylic acid anhydride is further added can also be mentioned as a structural unit having an ethylenically unsaturated bond.

The polymer having the structural unit derived from (a) can be produced, for example, by polymerizing the monomers constituting the structural unit of the polymer in a solvent in the presence of a polymerization initiator. The polymerization initiator, solvent and the like are not particularly limited, and those usually used in the art can be used. For example, as the polymerization initiator, an azo compound (2,2'-azobisisobutyronitrile, 2,2'-azobis (2,4-dimethylvaleronitrile), etc.) or an organic peroxide (benzoyl peroxide, etc.) The solvent may be any one that dissolves each monomer.

As the obtained polymer, the solution after the reaction may be used as it is, a concentrated or diluted solution may be used, or the polymer is taken out as a solid (powder) by a method such as reprecipitation. May be used.
If necessary, a reaction catalyst of a carboxylic acid or carboxylic acid anhydride and a cyclic ether (for example, tris (dimethylaminomethyl) phenol, etc.), a polymerization inhibitor (for example, hydroquinone, etc.) and the like may be used.
Examples of the carboxylic acid anhydride include maleic anhydride, citraconic acid anhydride, itaconic acid anhydride, 3-vinylphthalic anhydride, 4-vinylphthalic anhydride, 3,4,5,6-tetrahydrophthalic anhydride, 1 , 2,3,6-tetrahydrophthalic anhydride, dimethyltetrahydrophthalic anhydride and 5,6-dicarboxybicyclo [2.2.1] hept-2-ene anhydride and the like.

Specific examples of the resin (B) include 3,4-epoxycyclohexylmethyl (meth) acrylate / (meth) acrylic acid copolymer and 3,4-epoxytricyclo [5.2.1.0 ^2,6. ] Decyl (meth) acrylate / (meth) acrylic acid copolymer, glycidyl (meth) acrylate / benzyl (meth) acrylate / (meth) acrylic acid copolymer, glycidyl (meth) acrylate / styrene / (meth) acrylic acid Copolymer, 3,4-epoxytricyclo [5.2.1.0 ^2,6 ] decyl (meth) acrylate / (meth) acrylic acid / N-cyclohexyl maleimide copolymer, 3,4-epoxytricyclo [5.2.1.0 ^2,6 ] Decyl (meth) acrylate / (meth) acrylic acid / N-cyclohexylmaleimide / 2-hydroxyethyl (meth) acrylate copolymer, 3,4-epoxytricyclo [5] 2.1.0 ^2,6 ] decyl (meth) acrylate / (meth) acrylic acid / vinyl toluene copolymer, 3,4- ^{epoxytricyclo [5.2.1.0 2,6} ] decyl (meth) ) Acrylate / (meth) acrylic acid / 2-ethylhexyl (meth) acrylate copolymer, 3,4-epoxytricyclo [5.2.1.0 ^2,6 ] decyl (meth) acrylate / tricyclo [5.2] .1.0 ^2,6 ] Decenyl (meth) acrylate / (meth) acrylic acid / N-cyclohexylmaleimide copolymer, 3-methyl-3- (meth) acrylic loyloxymethyloxetane / (meth) acrylic acid / styrene Copolymers, benzyl (meth) acrylate / (meth) acrylic acid copolymers, styrene / (meth) acrylic acid copolymers, and JP-A-9-106071, JP-A-2004-29518 and JP-A-2004- Examples thereof include the resins described in each of the publications of No. 361455.
Among them, as the resin (B), a copolymer containing a structural unit derived from (a) and a structural unit derived from (b) is preferable.
The resin (B) may be a combination of two or more, in which case the resin (B) is at least 3,4-epoxytricyclo [5.2.1.0 ^2,6 ] decyl (meth) acrylate. / (Meta) acrylic acid copolymer, 3,4-epoxytricyclo [5.2.1.0 ^2,6 ] decyl (meth) acrylate / (meth) acrylic acid / N-cyclohexylmaleimide / 2-hydroxyethyl (Meta) Acrylate Copolymer, 3,4-Epoxytricyclo [5.2.1.0 ^2,6 ] Decyl (meth) Acrylate / (Meta) Acrylate / Vinyl Toluene Copolymer, 3,4-Epoxy It preferably contains one or more selected from the tricyclo [5.2.1.0 ^2,6 ] decyl (meth) acrylate / (meth) acrylate / 2-ethylhexyl (meth) acrylate copolymer.

The polystyrene-equivalent weight average molecular weight (Mw) of the resin (B) is preferably 3,000 to 100,000, more preferably 5,000 to 50,000, and even more preferably 5,000 to 30, It is 000. The dispersity [weight average molecular weight (Mw) / number average molecular weight (Mn)] of the resin (B) is preferably 1.1 to 6, and more preferably 1.2 to 4.

The acid value (solid content conversion value) of the resin (B) is preferably 10 to 300 mg-KOH / g, more preferably 20 to 250 mg-KOH / g, and even more preferably 30 to 200 mg-KOH / g. Is. Here, the acid value is a value measured as the amount (mg) of potassium hydroxide required to neutralize 1 g of the resin (B), and can be obtained by titration using, for example, an aqueous potassium hydroxide solution. ..

The content of the resin (B) in the coloring composition is preferably 3 to 99% by mass, more preferably 5 to 99% by mass, and further preferably 7 to 95% by mass with respect to the total amount of solids. %.

The coloring composition of the present invention preferably contains a solvent (hereinafter, may be referred to as a solvent (E)). When the coloring composition contains the solvent (E), the dispersion stability may be further improved.

<Solvent (E)>
The solvent (E) includes, for example, an ester solvent (a solvent containing -COO- in the molecule and not containing -O-), an ether solvent (a solvent containing -O- in the molecule and not containing -COO-), and the like. Ether ester solvent (solvent containing -COO- and -O- in the molecule), ketone solvent (solvent containing -CO- in the molecule and not containing -COO-), alcohol solvent (solvent containing OH in the molecule) , -O-, -CO- and -COO-free solvents), aromatic hydrocarbon solvents, amide solvents, dimethylsulfoxide and the like.

Ester solvents include methyl lactate, ethyl lactate, butyl lactate, methyl 2-hydroxyisobutate, ethyl acetate, n-butyl acetate, isobutyl acetate, pentyl formate, isopentyl acetate, butyl propionate, isopropyl butyrate, ethyl butyrate, butyl butyrate. , Methyl pyruvate, ethyl pyruvate, propyl pyruvate, methyl acetoacetate, ethyl acetoacetate, cyclohexanol acetate, γ-butyrolactone and the like.

Examples of the ether solvent include ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monopropyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, propylene glycol monomethyl ether, and propylene glycol monoethyl ether. , Propropylene glycol monopropyl ether, propylene glycol monobutyl ether, 3-methoxy-1-butanol, 3-methoxy-3-methylbutanol, tetrahydrofuran, tetrahydropyran, 1,4-dioxane, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol methyl ethyl Examples thereof include ether, diethylene glycol dipropyl ether, diethylene glycol dibutyl ether, anisole, phenyletol, methyl anisole and the like.

Examples of the ether ester solvent include methyl methoxyacetate, ethyl methoxyacetate, butyl methoxyacetate, methyl ethoxyacetate, ethyl ethoxyacetate, methyl 3-methoxypropionate, ethyl 3-methoxypropionate, methyl 3-ethoxypropionate, 3-ethoxy. Ethyl propionate, methyl 2-methoxypropionate, ethyl 2-methoxypropionate, propyl 2-methoxypropionate, methyl 2-ethoxypropionate, ethyl 2-ethoxypropionate, methyl 2-methoxy-2-methylpropionate, Ethyl 2-ethoxy-2-methylpropionate, 3-methoxybutyl acetate, 3-methyl-3-methoxybutyl acetate, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, propylene glycol monopropyl ether acetate, ethylene glycol monomethyl Examples thereof include ether acetate, ethylene glycol monoethyl ether acetate, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether acetate and dipropylene glycol methyl ether acetate.

Ketone solvents include 4-hydroxy-4-methyl-2-pentanone, acetone, 2-butanone, 2-heptanone, 3-heptanone, 4-heptanone, 4-methyl-2-pentanone, cyclopentanone, cyclohexanone and isophorone. And so on.

Examples of the alcohol solvent include methanol, ethanol, propanol, butanol, hexanol, cyclohexanol, ethylene glycol, propylene glycol, glycerin and the like.
Examples of the aromatic hydrocarbon solvent include benzene, toluene, xylene, mesitylene and the like.
Examples of the amide solvent include N, N-dimethylformamide, N, N-dimethylacetamide, N-methylpyrrolidone and the like.
Two or more of these solvents may be used in combination.
The content of the solvent (E) is preferably 40 to 99% by mass, more preferably 50 to 95% by mass, based on the total amount of the coloring composition.

In the coloring composition of the present invention, the compound (Z) is preferably dispersed in the solvent (E).

The compound (Z) is treated with rosin, a surface treatment using a derivative having an acidic group or a basic group introduced therein, a graft treatment on the surface of the compound (Z) with a polymer compound or the like, and sulfuric acid atomization, if necessary. A micronization treatment by a method or the like, a cleaning treatment with an organic solvent or water for removing impurities, a removal treatment of ionic impurities by an ion exchange method or the like may be performed. The particle size of compound (Z) is preferably substantially uniform. The compound (Z) can be made into a state in which the compound (Z) is uniformly dispersed in the dispersion liquid by carrying out the dispersion treatment by incorporating a dispersant.

Examples of the dispersant include surfactants and the like, and any of cationic, anionic, nonionic and amphoteric surfactants may be used. Specific examples thereof include polyester-based, polyamine-based and acrylic-based surfactants. These dispersants may be used alone or in combination of two or more. Dispersants include KP (manufactured by Shin-Etsu Chemical Industry Co., Ltd.), Floren (manufactured by Kyoeisha Chemical Co., Ltd.), Solsperse (registered trademark) (manufactured by Zeneca Co., Ltd.), and EFKA (registered trademark). (BASF Co., Ltd.), Ajispar (registered trademark) (Ajinomoto Fine Techno Co., Ltd.), Disperbyk (registered trademark) (Big Chemie Co., Ltd.), BYK (registered trademark) (Big Chemie Co., Ltd.), etc. Can be mentioned.

When a dispersant is used, the amount of the dispersant (solid content) used is preferably 300 parts by mass or less, more preferably 5 parts by mass or more and 100 parts by mass or less, based on 100 parts by mass of compound (Z). .. When the amount of the dispersant used is in the above range, a coloring composition in a more uniform dispersed state tends to be obtained.

The content of compound (Z) in the coloring composition is usually 0.1 to 60% by mass, preferably 0.5 to 50% by mass, and more preferably 1 to 40% of the total amount of the coloring composition. It is mass%.

The content of compound (Z) in the coloring composition is usually 1% by mass or more and 90% by mass or less, preferably 1% by mass or more and 80% by mass or less, more preferably, with respect to the total amount of solid content. It is 2% by mass or more and 75% by mass or less.

When the coloring composition of the present invention contains a compound (Z), the coloring composition contains a coloring agent other than the compound (Z) (that is, the above-mentioned coloring agent (A1Z1), coloring agent (A1Z2), coloring agent (A1Z3)). , Colorant (A1Z4), colorant (A1Z5), colorant (A1Z6), etc.) may be further contained. When the colorant (A1Z1), the colorant (A1Z2), the colorant (A1Z3), the colorant (A1Z4), the colorant (A1Z5), and the colorant (A1Z6) are collectively referred to as "colorant (ZZ)" below. The colorant (ZZ) may contain one or more colorants. The colorant (ZZ) preferably contains a yellow colorant or a green colorant.

<Colorant (ZZ)>
The colorant (ZZ) may be a dye or a pigment. As the dye, a known dye can be used, and examples thereof include dyes listed in the Color Index (published by The Society of Dyers and Colorists) and Dyeing Note (Dyeing Co., Ltd.). Further, according to the chemical structure, azo dyes, anthraquinone dyes, triphenylmethane dyes, xanthene dyes, phthalocyanine dyes and the like can be mentioned. These dyes may be used alone or in combination of two or more.

Specific examples thereof include dyes having the following color index (CI) numbers. C. I. Solvent Yellow 14, 15, 23, 24, 25, 38, 62, 63, 68, 79, 81, 82, 83, 89, 94, 98, 99, 162;
C. I. Acid Yellow 1, 3, 7, 9, 11, 17, 23, 25, 29, 34, 36, 38, 40, 42, 54, 65, 72, 73, 76, 79, 98, 99, 111, 112, 113, 114, 116, 119, 123, 128, 134, 135, 138, 139, 140, 144, 150, 155, 157, 160, 161, 163, 168, 169, 172, 177, 178, 179, 184, 190, 193, 196, 197, 199, 202, 203, 204, 205, 207, 212, 214, 220, 221 228, 230, 232, 235, 238, 240, 242, 243, 251;
C. I. Reactive Yellow 2,76,116;
C. I. Direct Yellow 2, 4, 28, 33, 34, 35, 38, 39, 43, 44, 47, 50, 54, 58, 68, 69, 70, 71, 86, 93, 94, 95, 98, 102, 108, 109, 129, 132, 136, 138, 141;
C. I. Disperse Yellow 51, 54, 76;
C. I. Solvent Orange 2, 7, 11, 15, 26, 41, 54, 56, 99;
C. I. Acid Orange 6, 7, 8, 10, 12, 26, 50, 51, 52, 56, 62, 63, 64, 74, 75, 94, 95, 107, 108, 149, 162, 169, 173;
C. I. Reactive orange 16;
C. I. Direct Orange 26, 34, 39, 41, 46, 50, 52, 56, 57, 61, 64, 65, 68, 70, 96, 97, 106, 107;
C. I. Solvent Red 24, 49, 90, 91, 111, 118, 119, 122, 124, 125, 127, 130, 132, 143, 145, 146, 150, 151, 155, 160, 168, 169, 172, 175, 181, 207, 218, 222, 227, 230, 245, 247;
C. I. Acid Red 52, 73, 80, 91, 92, 97, 138, 151, 211, 274, 289;
C. I. Acid Violet 34, 102;
C. I. Disperse Violet 26, 27;
C. I. Solvent Violet 11, 13, 14, 26, 31, 36, 37, 38, 45, 47, 48, 51, 59, 60;
C. I. Solvent Blue 14, 18, 35, 36, 45, 58, 59, 59: 1, 63, 68, 69, 78, 79, 83, 94, 97, 98, 100, 101, 102, 104, 105, 111, 112, 122, 128, 132, 136, 139;
C. I. Acid Blue 25, 27, 40, 45, 78, 80, 112;
C. I. Direct Blue 40;
C. I. Disperse Blue 1, 14, 56, 60;
C. I. Solvent Green 1, 3, 5, 28, 29, 32, 33;
C. I. Acid Green 3, 5, 9, 25, 27, 28, 41;
C. I. Basic Green 1;
C. I. Bat green 1st prize.

As the pigment, known pigments can be used, and examples thereof include pigments classified as pigments in the Color Index (published by The Society of Dyers and Colorists). These can be used alone or in combination of two or more.
Specifically, C.I. I. Pigment Yellow 1, 3, 12, 13, 14, 15, 16, 17, 20, 24, 31, 53, 83, 86, 93, 94, 109, 110, 117, 125, 128, 129, 137, 138, Yellow pigments such as 139, 147, 148, 150, 153, 154, 166, 173, 185, 194, 214;
C. I. Pigment Orange 13, 31, 36, 38, 40, 42, 43, 51, 55, 59, 61, 64, 65, 71, 73 and other orange pigments;
C. I. Pigment Red 9, 97, 105, 122, 123, 144, 149, 166, 168, 176, 177, 179, 180, 192, 209, 215, 216, 224, 242, 254, 255, 264, 265, 266, Red pigments such as 268, 269, 273;
C. I. Pigment Blue 15, 15: 3, 15: 4, 15: 6, 60 and other blue pigments;
C. I. Pigment Violet 1, 19, 23, 29, 32, 36, 38 and other violet color pigments;
C. I. Pigment Green 7, 36, 58, 59 and other green pigments can be mentioned.

Examples of the colorant (ZZ) include yellow dyes and yellow pigments (hereinafter, these may be collectively referred to as "yellow colorants"), green dyes and green pigments (hereinafter, these are collectively referred to as "green colorants"). ) Is preferable, yellow pigments and green pigments are more preferable, and green pigments are even more preferable.
Examples of the yellow dye include dyes whose hue is classified as yellow among the above dyes, and examples of yellow pigments include pigments whose hue is classified as yellow among the above pigments.
Among the yellow pigments, quinophthalone yellow pigments, metal-containing yellow pigments, and isoindoline yellow pigments are preferable, and C.I. I. Pigment Yellow 129, 138, 139, 150, 185 are more preferred, and C.I. I. Pigment Yellow 138, 139, 150 and 185 are even more preferred.
Examples of the green dye include dyes whose hue is classified as green among the above dyes, and examples of the green pigment include pigments whose hue is classified as green among the above pigments.
Among the green pigments, phthalocyanine pigments are preferable, and at least one selected from the group consisting of halogenated copper phthalocyanine pigments and halogenated zinc phthalocyanine pigments is more preferable. I. At least one selected from the group consisting of Pigment Greens 7, 36, 58 and 59 is even more preferred.

When the coloring composition of the present invention contains a colorant (ZZ) and a solvent (E), a colorant (ZZ) -containing liquid containing the colorant (ZZ) and the solvent (E) is prepared in advance, and then the coloring is performed. The coloring composition may be prepared using the agent (ZZ) -containing liquid. When the colorant (ZZ) is not soluble in the solvent (E), the colorant (ZZ) -containing liquid can be prepared by dispersing the colorant (ZZ) in the solvent (E) and mixing. The colorant (ZZ) -containing liquid may contain a part or all of the solvent (E) contained in the coloring composition.

The coloring composition of the present invention
It is produced by mixing the compound (Z), the resin (B), and the colorant (ZZ) -containing liquid containing the colorant (ZZ) and the solvent (E).
It is produced by mixing the compound (Z), the solvent (E), and the colorant (ZZ) -containing liquid containing the colorant (ZZ) and the solvent (E).
It is preferably produced by mixing the compound (Z), the resin (B) and the solvent (E), and the colorant (ZZ) -containing liquid containing the colorant (ZZ) and the solvent (E). As the manufacturing method,
The compound (Z) and the resin (B) are mixed with a bead mill or the like to prepare a coloring composition, and the obtained coloring composition and a coloring agent (ZZ) containing a coloring agent (ZZ) and a solvent (E) are used. How to mix with the containing liquid
The compound (Z) and the solvent (E) are mixed with a bead mill or the like to prepare a coloring composition, and the obtained coloring composition and the coloring agent (ZZ) containing the coloring agent (ZZ) and the solvent (E) are used. How to mix with the containing liquid
The compound (Z), the resin (B) and the solvent (E) are mixed with a bead mill or the like to prepare a coloring composition, and the obtained coloring composition, the coloring agent (ZZ) and the solvent (E) are contained. A method of mixing with a colorant (ZZ) -containing liquid is preferable.

The colorant (ZZ) is preferably a colorant containing at least one selected from a green colorant and a yellow colorant.

The colorant (ZZ) is treated with a rosin, a surface treatment using a colorant derivative having an acidic group or a basic group introduced therein, or a graft treatment on the surface of the colorant (ZZ) with a polymer compound or the like, if necessary. , Aluminization treatment by a sulfuric acid atomization method or the like, cleaning treatment with an organic solvent or water for removing impurities, removal treatment by an ion exchange method of ionic impurities or the like may be performed. The particle size of the colorant (ZZ) is preferably substantially uniform. The colorant (ZZ) can be made into a state in which the colorant (ZZ) is uniformly dispersed in the colorant (ZZ) -containing liquid by carrying out the dispersion treatment by containing the dispersant. The colorant (ZZ) may be dispersed individually or a plurality of types may be mixed and dispersed.

Examples of the dispersant include surfactants and the like, and any of cationic, anionic, nonionic and amphoteric surfactants may be used. Specific examples thereof include polyester-based, polyamine-based and acrylic-based surfactants. These dispersants may be used alone or in combination of two or more. Dispersants include KP (manufactured by Shin-Etsu Chemical Industry Co., Ltd.), Floren (manufactured by Kyoeisha Chemical Co., Ltd.), Solsperse (registered trademark) (manufactured by Zeneca Co., Ltd.), and EFKA (registered trademark). (BASF Co., Ltd.), Ajispar (registered trademark) (Ajinomoto Fine Techno Co., Ltd.), Disperbyk (registered trademark) (Big Chemie Co., Ltd.), BYK (registered trademark) (Big Chemie Co., Ltd.), etc. Can be mentioned.

When a dispersant is used to prepare the colorant (ZZ) -containing liquid, the amount of the dispersant (solid content) used is preferably 300 parts by mass or less with respect to 100 parts by mass of the colorant (ZZ). Yes, more preferably 5 parts by mass or more and 100 parts by mass or less. When the amount of the dispersant used is in the above range, a colorant (ZZ) -containing liquid in a more uniform dispersed state tends to be obtained.

The content of the colorant (ZZ) in the colorant (ZZ) -containing liquid is usually 0.1 to 60% by mass, preferably 0.5 to 50% by mass, based on the total amount of the colorant (ZZ) -containing liquid. It is more preferably 1 to 40% by mass.

The content of the colorant (ZZ) in the colorant (ZZ) -containing liquid is usually 1% by mass or more and 90% by mass or less, preferably 1% by mass or more and 80% by mass or less, based on the total amount of solids. Yes, more preferably 2% by mass or more and 75% by mass or less.

The coloring composition of the present invention contains a resin (B), and after preparing a colorant (ZZ) -containing liquid containing a colorant (ZZ) and a solvent in advance, the colorant (ZZ) -containing liquid is used. When preparing the coloring composition of the present invention, the colorant (ZZ) -containing liquid is used.
A part or all, preferably a part of the resin (B) contained in the coloring composition may be contained in advance.
A part or all, preferably a part of the solvent (E) contained in the coloring composition may be contained in advance.
A part or all, preferably a part of the resin (B) and the solvent (E) contained in the coloring composition may be contained in advance.
By including the resin (B) in advance, the dispersion stability of the colorant (ZZ) -containing liquid can be further improved.
The content of the resin (B) in the colorant (ZZ) -containing liquid is, for example, 1 to 500 parts by mass, preferably 5 to 200 parts by mass with respect to 100 parts by mass of the colorant (ZZ). More preferably, it is 10 to 100 parts by mass.

The content of the colorant (ZZZ), which is a combination of the compound (Z) and the colorant (ZZ), in the coloring composition is usually 1% by mass or more and 90% by mass or less, preferably 1% by mass or more, based on the total amount of solids. It is 1% by mass or more and 80% by mass or less, and more preferably 2% by mass or more and 75% by mass or less.
The content of the compound (Z) is usually 0.001% by mass or more, preferably 0.003% by mass or more, more preferably 0.005% by mass or more, based on the total amount of the colorant (ZZZ). Is 100% by mass or less, preferably 99.999% by mass or less, and more preferably 99.997% by mass or less.
The content of compound (Z) is usually 0.001% by mass or more, preferably 40% by mass or more, more preferably 50% by mass or more, and even more preferably 60, based on the total amount of the yellow colorant. It is 0% by mass or more, particularly preferably 70% by mass or more, and the upper limit is 100% by mass or less, preferably 99.999% by mass or less, and more preferably 99.997% by mass or less.
When the colorant (ZZ) is contained, the content of the colorant (ZZ) is preferably 0.1 part by mass or more, and more preferably 0.5 part by mass or more with respect to 100 parts by mass of the compound (Z). It is more preferably 1 part by mass or more, preferably 10000 parts by mass or less, and more preferably 5000 parts by mass or less.

The color-curable composition of the present invention contains the compound (Z), at least one of the resin (B) and the solvent (E), and the polymerizable compound (C).

<Polymerizable compound (C)>
The polymerizable compound (C) is a compound that can be polymerized by an active radical and / or an acid generated from the polymerization initiator (D), and is, for example, a compound having a polymerizable ethylenically unsaturated bond, and is preferable. It is a (meth) acrylic acid ester compound.

Examples of the polymerizable compound having one ethylenically unsaturated bond include nonylphenylcarbitol acrylate, 2-hydroxy-3-phenoxypropyl acrylate, 2-ethylhexylcarbitol acrylate, 2-hydroxyethyl acrylate, and N-vinylpyrrolidone. Etc., as well as the above-mentioned monomers (a), monomer (b) and monomer (c).

Examples of the polymerizable compound having two ethylenically unsaturated bonds include 1,6-hexanediol di (meth) acrylate, ethylene glycol di (meth) acrylate, neopentyl glycol di (meth) acrylate, and triethylene glycol di. Examples thereof include (meth) acrylate, bis (acryloyloxyethyl) ether of bisphenol A, and 3-methylpentanediol di (meth) acrylate.

Among them, the polymerizable compound (C) is preferably a polymerizable compound having three or more ethylenically unsaturated bonds. Examples of such polymerizable compounds include trimethylolpropantri (meth) acrylate, pentaerythritol tri (meth) acrylate, pentaerythritol tetra (meth) acrylate, dipentaerythritol penta (meth) acrylate, and dipentaerythritol hexa (dipentaerythritol hexa (). Meta) acrylate, tripentaerythritol octa (meth) acrylate, tripentaerythritol hepta (meth) acrylate, tetrapentaerythritol deca (meth) acrylate, tetrapentaerythritol nona (meth) acrylate, tris (2- (meth) acryloyloxyethyl ) Isocyanurate, ethylene glycol-modified pentaerythritol tetra (meth) acrylate, ethylene glycol-modified dipentaerythritol hexa (meth) acrylate, propylene glycol-modified pentaerythritol tetra (meth) acrylate, propylene glycol-modified dipentaerythritol hexa (meth) acrylate, Examples thereof include caprolactone-modified pentaerythritol tetra (meth) acrylate and caprolactone-modified dipentaerythritol hexa (meth) acrylate, and preferably dipentaerythritol penta (meth) acrylate and dipentaerythritol hexa (meth) acrylate.

The weight average molecular weight of the polymerizable compound (C) is preferably 150 or more and 2,900 or less, and more preferably 250 or more and 1,500 or less.

The content of the polymerizable compound (C) is preferably 1 to 65% by mass, more preferably 3 to 60% by mass, based on the total amount of solids in the color-curable composition. It is more preferably ~ 55% by mass.

The color curable composition of the present invention may contain a polymerization initiator (D).

<Polymerization initiator (D)>
The polymerization initiator (D) is not particularly limited as long as it is a compound capable of generating active radicals, acids and the like by the action of light or heat and initiating polymerization, and a known polymerization initiator can be used.
Examples of the polymerization initiator (D) include an O-acyloxime compound, an alkylphenone compound, a biimidazole compound, a triazine compound, an acylphosphine oxide compound and the like.

Examples of the O-acyloxym compound include N-benzoyloxy-1- (4-phenylsulfanylphenyl) butane-1-one-2-imine and N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-. 1-one-2-imine, N-benzoyloxy-1- (4-phenylsulfanylphenyl) -3-cyclopentylpropane-1-one-2-imine, N-acetoxy-1- (4-phenylsulfanylphenyl)- 3-Cyclopentylpropan-1-one-2-imine, N-acetoxy-1- (4-phenylsulfanylphenyl) -3-cyclohexylpropane-1-one-2-imine, N-acetoxy-1- [9-ethyl -6- (2-methylbenzoyl) -9H-carbazole-3-yl] ethane-1-imine, N-acetoxy-1- [9-ethyl-6- {2-methyl-4- (3,3-dimethyl) -2,4-dioxacyclopentanylmethyloxy) benzoyl} -9H-carbazole-3-yl] ethane-1-imine, N-acetoxy-1- [9-ethyl-6- (2-methylbenzoyl)- 9H-carbazole-3-yl] -3-cyclopentylpropan-1-imine and N-benzoyloxy-1- [9-ethyl-6- (2-methylbenzoyl) -9H-carbazole-3-yl] -3- Cyclopentylpropan-1-one-2-imine and the like can be mentioned. Further, as the O-acyloxime compound, commercially available products such as Irgacure OXE01, OXE02 (all manufactured by BASF Corporation) and N-1919 (manufactured by ADEKA Corporation) may be used. Among them, as the O-acyloxym compound, N-benzoyloxy-1- (4-phenylsulfanylphenyl) butane-1-one-2-imine and N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane- At least one selected from the group consisting of 1-one-2-imine and N-benzoyloxy-1- (4-phenylsulfanylphenyl) -3-cyclopentylpropane-1-one-2-imine is preferable, and N-benzoyl is preferable. Oxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine is more preferred.

Examples of the alkylphenone compound include 2-methyl-2-morpholino-1- (4-methylsulfanylphenyl) propan-1-one and 2-dimethylamino-1- (4-morpholinophenyl) -2-benzylbutane-1-. Examples thereof include on and 2- (dimethylamino) -2-[(4-methylphenyl) methyl] -1- [4- (4-morpholinyl) phenyl] butane-1-one. As the alkylphenone compound, a commercially available product such as Irgacure 369, 907, 379 (all manufactured by BASF Limited) may be used.
Examples of the alkylphenone compound include 2-hydroxy-2-methyl-1-phenylpropan-1-one, 2-hydroxy-2-methyl-1- [4- (2-hydroxyethoxy) phenyl] propan-1-one, Also included are 1-hydroxycyclohexylphenyl ketone, an oligomer of 2-hydroxy-2-methyl-1- (4-isopropenylphenyl) propan-1-one, α, α-diethoxyacetophenone and benzyl dimethyl ketal.

Examples of the biimidazole compound include 2,2'-bis (2-chlorophenyl) -4,4', 5,5'-tetraphenylbiimidazole and 2,2'-bis (2,3-dichlorophenyl) -4. , 4', 5,5'-tetraphenylbiimidazole (see, for example, JP-A-6-75372, JP-A-6-75373, etc.), 2,2'-bis (2-chlorophenyl) -4, 4', 5,5'-tetra (alkoxyphenyl) biimidazole, 2,2'-bis (2-chlorophenyl) -4,4', 5,5'-tetra (dialkoxyphenyl) biimidazole, 2,2 '-Bis (2-chlorophenyl) -4,4', 5,5'-tetra (trialkoxyphenyl) biimidazole (see, for example, Japanese Patent Application Laid-Open No. 48-38403, Japanese Patent Application Laid-Open No. 62-174204, etc.) And an imidazole compound in which the phenyl group at the 4,4', 5,5'-position is substituted with a carboalkoxy group (see, for example, Japanese Patent Application Laid-Open No. 7-10913) and the like.

Examples of the triazine compound include 2,4-bis (trichloromethyl) -6- (4-methoxyphenyl) -1,3,5-triazine and 2,4-bis (trichloromethyl) -6- (4-methoxynaphthyl). -1,3,5-triazine, 2,4-bis (trichloromethyl) -6-piperonyl-1,3,5-triazine, 2,4-bis (trichloromethyl) -6- (4-methoxystyryl)- 1,3,5-triazine, 2,4-bis (trichloromethyl) -6- [2- (5-methylfuran-2-yl) ethenyl] -1,3,5-triazine, 2,4-bis ( Trichloromethyl) -6- [2- (fran-2-yl) ethenyl] -1,3,5-triazine, 2,4-bis (trichloromethyl) -6- [2- (4-diethylamino-2-methyl) Phenyl) ethenyl] -1,3,5-triazine and 2,4-bis (trichloromethyl) -6- [2- (3,4-dimethoxyphenyl) ethenyl] -1,3,5-triazine and the like can be mentioned. ..

Examples of the acylphosphine oxide compound include 2,4,6-trimethylbenzoyldiphenylphosphine oxide.

Further, as the polymerization initiator (D), benzoin compounds such as benzoin, benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether and benzoin isobutyl ether; benzophenone, o-benzoyl methyl benzoate, 4-phenylbenzophenone, 4-benzoyl- Benzophenone compounds such as 4'-methyldiphenylsulfide, 3,3', 4,4'-tetra (tert-butylperoxycarbonyl) benzophenone and 2,4,6-trimethylbenzophenone; 9,10-phenanthrene quinone, Kinone compounds such as 2-ethylanthraquinone and benzophenone; 10-butyl-2-chloroacrydone, benzyl, methyl phenylglycoxylate, titanosen compounds and the like can be mentioned.
These are preferably used in combination with the polymerization initiation aid (D1) (particularly amines) described later.

The polymerization initiator (D) is preferably a polymerization initiator containing at least one selected from the group consisting of an alkylphenone compound, a triazine compound, an acylphosphine oxide compound, an O-acyloxime compound and a biimidazole compound, and more preferably. A polymerization initiator containing an O-acyloxime compound.

The content of the polymerization initiator (D) is preferably 0.001 to 40% by mass, more preferably 0.01 to 30% by mass, based on the total amount of solids in the color-curable composition.

The color curable composition of the present invention may contain a polymerization initiation aid (D1).

<Polymerization initiation aid (D1)>
The polymerization initiator (D1) is a compound or a sensitizer used to promote the polymerization of a polymerizable compound whose polymerization has been initiated by the polymerization initiator. When the polymerization initiator (D1) is contained, it is usually used in combination with the polymerization initiator (D).
Examples of the polymerization initiation aid (D1) include amine compounds, alkoxyanthracene compounds, thioxanthone compounds and carboxylic acid compounds.

Examples of the amine compound include triethanolamine, methyldiethanolamine, triisopropanolamine, methyl 4-dimethylaminobenzoate, ethyl 4-dimethylaminobenzoate, isoamyl 4-dimethylaminobenzoate, 2-dimethylaminoethyl benzoate, 4-. 2-Ethylhexyl dimethylaminobenzoate, N, N-dimethylparatoluidine, 4,4'-bis (dimethylamino) benzophenone (commonly known as Michler's ketone), 4,4'-bis (diethylamino) benzophenone and 4,4'-bis ( Ethylmethylamino) benzophenone and the like can be mentioned, preferably 4,4'-bis (diethylamino) benzophenone and the like. Further, as the amine compound, a commercially available product such as EAB-F (manufactured by Hodogaya Chemical Co., Ltd.) may be used.

Examples of the alkoxyanthracene compound include 9,10-dimethoxyanthracene, 2-ethyl-9,10-dimethoxyanthracene, 9,10-diethoxyanthracene, 2-ethyl-9,10-diethoxyanthracene, and 9,10-dibutoxy. Examples thereof include anthracene and 2-ethyl-9,10-dibutoxyanthracene.

Examples of the thioxanthone compound include 2-isopropylthioxanthone, 4-isopropylthioxanthone, 2,4-diethylthioxanthone, 2,4-dichlorothioxanthone, 1-chloro-4-propoxythioxanthone and the like.

Examples of the carboxylic acid compound include phenylsulfanyl acetic acid, methylphenylsulfanyl acetic acid, ethylphenylsulfanyl acetic acid, methylethylphenylsulfanyl acetic acid, dimethylphenylsulfanyl acetic acid, methoxyphenylsulfanyl acetic acid, dimethoxyphenylsulfanyl acetic acid, chlorophenylsulfanyl acetic acid, dichlorophenylsulfanyl acetic acid, and N. -Phenylglycine, phenoxyacetic acid, naphthylthioacetic acid, N-naphthylglycine, naphthoxyacetic acid and the like can be mentioned.

When these polymerization initiators (D1) are used, the content thereof is preferably 0.001 to 30% by mass, more preferably 0.01 to 30% by mass, based on the total amount of solids in the color curable composition. It is 20% by mass.

The coloring composition of the present invention may further contain a leveling agent (F) and an antioxidant.

<Leveling agent (F)>
Examples of the leveling agent (F) include a silicone-based surfactant, a fluorine-based surfactant, and a silicone-based surfactant having a fluorine atom. These may have a polymerizable group in the side chain.
Examples of the silicone-based surfactant include surfactants having a siloxane bond in the molecule. Specifically, Torre Silicone DC3PA, SH7PA, DC11PA, SH21PA, SH28PA, SH29PA, SH30PA, SH8400 (trade name: manufactured by Toray Dow Corning Co., Ltd.), KP321, KP322, KP323, KP324 , KP326, KP340, KP341 (manufactured by Shin-Etsu Chemical Co., Ltd.), TSF400, TSF401, TSF410, TSF4300, TSF4440, TSF4445, TSF4446, TSF4452, TSF4460 (manufactured by Momentive Performance Materials Japan GK) and the like. ..

Examples of the fluorine-based surfactant include surfactants having a fluorocarbon chain in the molecule. Specifically, Florard (registered trademark) FC430, FC431 (manufactured by Sumitomo 3M Co., Ltd.), Megafuck (registered trademark) F142D, F171, F172, F173, F177, F183, F554, and F554. R30, RS-718-K (manufactured by DIC Co., Ltd.), Ftop (registered trademark) EF301, EF303, EF351, EF352 (manufactured by Mitsubishi Materials Electronics Co., Ltd.), Surflon (registered trademark) S381, Examples thereof include S382, SC101, SC105 (manufactured by Asahi Glass Co., Ltd.) and E5844 (manufactured by Daikin Fine Chemical Laboratory Co., Ltd.).

Examples of the silicone-based surfactant having a fluorine atom include a surfactant having a siloxane bond and a fluorocarbon chain in the molecule. Specific examples thereof include MegaFvck (registered trademark) R08, BL20, F475, F477 and F443 (manufactured by DIC Corporation).

When the leveling agent (F) is contained, the content thereof is usually 0.0005% by mass or more and 1% by mass or less, preferably 0.001% by mass or more and 0.5% by mass, based on the total amount of the coloring composition. % Or less, more preferably 0.001% by mass or more and 0.2% by mass or less, further preferably 0.002% by mass or more and 0.1% by mass or less, and particularly preferably 0.005% by mass or more. It is 0.1% by mass or less. When the content of the leveling agent (F) is within the above range, the flatness of the color filter can be improved.

<Antioxidant>
From the viewpoint of improving the heat resistance and light resistance of the colorant, it is preferable to use the antioxidant alone or in combination of two or more. The antioxidant is not particularly limited as long as it is an industrially generally used antioxidant, and a phenol-based antioxidant, a phosphorus-based antioxidant, a sulfur-based antioxidant and the like can be used.

Examples of the phenolic antioxidant include Irganox 1010 (Irganox 1010: pentaerythritol tetrakis [3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate], manufactured by BASF Co., Ltd.). Irganox 1076 (Irganox 1076: octadecyl-3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate, manufactured by BASF Co., Ltd.), Irganox 1330 (Irganox 1330: 3,3', 3' ', 5,5', 5''-Hexa-tert-butyl-a, a', a''- (methicylene-2,4,6-triyl) tri-p-cresol, manufactured by BASF Co., Ltd., Irganox 3114 (Irganox 3114: 1,3,5-tris (3,5-di-tert-butyl-4-hydroxybenzyl) -1,3,5-triazine-2,4,6 (1H, 3H, 5H) ) -Trion, manufactured by BASF Co., Ltd., Irganox 3790 (Irganox 3790: 1,3,5-tris ((4-tert-butyl-3-hydroxy-2,6-kisilyl) methyl) -1,3. 5-Triazine-2,4,6 (1H, 3H, 5H) -Trione, manufactured by BASF Co., Ltd., Irganox 1035: Thiodiethylenebis [3- (3,5-di-tert-butyl-) 4-Hydroxyphenyl) propionate], BASF Co., Ltd.), Irganox 1135 (Irganox 1135: benzenepropanoic acid, 3,5-bis (1,1-dimethylethyl) -4-hydroxy, C7-C9 side chain alkyl Ester, manufactured by BASF Co., Ltd., Irganox 1520L (Irganox 1520L: 4,6-bis (octylthiomethyl) -o-cresol, manufactured by BASF Co., Ltd.), Irganox 3125 (Irganox 3125, manufactured by BASF Co., Ltd.) ), Irganox 565: 2,4-bis (n-octylthio) -6- (4-hydroxy 3', 5'-di-tert-butylanilino) -1,3,5-triazine, BASF Co., Ltd. ), Adecastab AO-80 (Adecastab AO-80: 3,9-bis (2- (3- (3-tert-butyl-4-hydroxy-5-methylphenyl) propionyloxy) -1,1-dimethyl) Ethyl) -2,4,8,10-tetraoxaspiro (5,5) 5) Undecan, ADEKA Corporation), Sumilizer BHT (Sumilizer BHT, Sumitomo Chemical Co., Ltd.), Sumitomo GA-80 (Sumilizer GA-80, Sumitomo Chemical Co., Ltd.), Sumitomo GS (Sumilizer GS, Sumitomo Chemical Co., Ltd.) Examples thereof include Cyanox 1790 (manufactured by Cyanox 1790, manufactured by Cytec Co., Ltd.) and Vitamin E (manufactured by Eisai Corporation).

Examples of the phosphorus-based antioxidant include Irgafos 168 (Irgafos 168: Tris (2,4-di-tert-butylphenyl) phosfite, manufactured by BASF Co., Ltd.), Irgafos 12 (Irgafos 12: Tris [2-]. [[2,4,8,10-tetra-tert-butyldibenzo [d, f] [1,3,2] dioxaphosphin-6-yl] oxy] ethyl] amine, manufactured by BASF Co., Ltd.), Irgafos 38: Bis (2,4-bis (1,1-dimethylethyl) -6-methylphenyl) ethyl ester phosphite, manufactured by BASF Co., Ltd., Adecastab 329K (manufactured by ADEKA Co., Ltd.), Adecastab PEP36 (manufactured by ADEKA Co., Ltd.), Adecaster PEP-8 (manufactured by ADEKA Co., Ltd.), Sandstab P-EPQ (manufactured by Clariant), Weston 618 (manufactured by Weston 618, GE), Weston 619G (manufactured by Weston 619G, GE) Ultraknox 626 (Ultranox 626, manufactured by GE) and Sumilizer GP: 6- [3- (3-tert-butyl-4-hydroxy-5-methylphenyl) propoxy] -2,4 8,10-Tetra-tert-butyldibenz [d, f] [1.3.2] dioxaphosphepine) (manufactured by Sumitomo Chemical Co., Ltd.) and the like can be mentioned.

Examples of the sulfur-based antioxidant include β-alkyl mercaptopropion of a dialkylthiodipropionate compound such as dilauryl thiodipropionate, dimyristyl or distearyl, and a polyol such as tetrakis [methylene (3-dodecylthio) propionate] methane. Examples thereof include acid ester compounds.

<Other ingredients>
If necessary, the coloring composition of the present invention may contain additives known in the art such as fillers, other polymer compounds, adhesion promoters, light stabilizers, and chain transfer agents.
Examples of the adhesion accelerator include vinyltrimethoxysilane, vinyltriethoxysilane, vinyltris (2-methoxyethoxy) silane, 3-glycidyloxypropyltrimethoxysilane, 3-glycidoxypropylmethyldimethoxysilane, and 3-glycid. Xipropylmethyldimethoxysilane, 3-glycidoxypropylmethyldiethoxysilane, 2- (3,4-epoxycyclohexyl) ethyltrimethoxysilane, 3-chloropropylmethyldimethoxysilane, 3-chloropropyltrimethoxysilane, 3- Methacryloyloxypropyltrimethoxysilane, 3-mercaptopropyltrimethoxysilane, 3-sulfanylpropyltrimethoxysilane, 3-isocyanuppropyltriethoxysilane, N-2- (aminoethyl) -3-aminopropylmethyldimethoxysilane, N- 2- (Aminoethyl) -3-aminopropylmethyldiethoxysilane, N-2- (Aminoethyl) -3-aminopropyltrimethoxysilane, N-2- (Aminoethyl) -3-aminopropylmethyldiethoxysilane , 3-Aminopropyltrimethoxysilane, 3-aminopropyltriethoxysilane, N-phenyl-3-aminopropyltrimethoxysilane, N-phenyl-3-aminopropyltriethoxysilane and the like.

<Color filter>
A color filter can be formed from the coloring composition or the coloring curable composition of the present invention. Examples of the method for forming the colored pattern include a photolithography method, an inkjet method, a printing method, and the like, and a photolithography method is preferable. The photolithography method is a method in which the color-curable composition is applied to a substrate and dried to form a color-curable composition layer, and the color-curable composition layer is exposed and developed through a photomask. Is. In the photolithography method, it is preferable that the color curable composition contains the polymerization initiator (D). In the photolithography method, a colored coating film which is a cured product of the colored curable composition layer can be formed by not using a photomask at the time of exposure and / or not developing the photomask. The colored pattern or colored coating film thus formed can be used as the color filter of the present invention.
The film thickness of the color filter to be produced is not particularly limited and can be appropriately adjusted according to the purpose, application and the like. For example, it is 0.1 to 30 μm, preferably 0.1 to 20 μm, and more preferably 0.1 to 20 μm. Is 0.5 to 6 μm.

As the substrate, a glass plate, a resin plate, silicon, or a substrate on which an aluminum, silver, silver / copper / palladium alloy thin film, or the like is formed is used. Another color filter layer, resin layer, transistor, circuit, or the like may be formed on these substrates.

The formation of each color pixel by the photolithography method can be performed by a known or conventional device or condition. For example, it can be produced as follows.
First, the color-curable composition is applied onto a substrate and dried by heat drying (pre-baking) and / or vacuum drying to remove volatile components such as a solvent to obtain a smooth color-curable composition layer.
Examples of the coating method include a spin coating method, a slit coating method, a slit and spin coating method, and the like.

The color curable composition layer is then exposed via a photomask to form the desired color pattern. Since it is possible to uniformly irradiate the entire exposed surface with parallel light rays and accurately align the photomask with the substrate on which the colored curable composition layer is formed, an exposure device such as a mask aligner and a stepper can be used. It is preferable to use it.

A colored pattern is formed on the substrate by developing the colored curable composition layer after exposure by bringing it into contact with a developing solution. By development, the unexposed portion of the color-curable composition layer is dissolved in a developing solution and removed.
As the developing solution, for example, an aqueous solution of an alkaline compound such as potassium hydroxide, sodium hydrogen carbonate, sodium carbonate and tetramethylammonium hydroxide is preferable.
The developing method may be any of a paddle method, a dipping method, a spray method and the like. Further, the substrate may be tilted at an arbitrary angle during development.
The developed substrate is preferably washed with water.
Further, it is preferable to post-bake the obtained coloring pattern.

The color filter is useful as a color filter used in a display device (for example, a liquid crystal display device, an organic EL device, an electronic paper, etc.) and a solid-state image sensor, and more particularly as a color filter used in a liquid crystal display device.

Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited by the following examples as well as the present invention, and appropriate modifications are made to the extent that it can be adapted to the gist of the above and the following. Of course, it is possible to carry out, and all of them are included in the technical scope of the present invention. In the following, unless otherwise specified, "part" means "part by mass" and "%" means "% by mass".

In the following synthetic examples, the structure of the compound was confirmed by NMR (JMM-ECA-500; manufactured by JEOL Ltd.) or mass spectrometry (LC; Agilent 1200 type, MASS; Agilent LC / MSD6130 type).

The polystyrene-equivalent weight average molecular weight (Mw) and number average molecular weight (Mn) of the resin were measured by the GPC method under the following conditions.
Equipment: HLC-8120GPC (manufactured by Tosoh Corporation)
Column: TSK-GELG2000HXL
Column temperature: 40 ° C
Solvent: Tetrahydrofuran Flow rate: 1.0 mL / min Solid content concentration of analytical sample: 0.001 to 0.01% by mass
Injection volume: 50 μL
Detector: RI
Calibration standard material: TSK STANDARD POLYSTYRENE F-40, F-4, F-288, A-2500, A-500 (manufactured by Tosoh Corporation)
The ratio (Mw / Mn) of the polystyrene-equivalent weight average molecular weight (Mw) and the number average molecular weight (Mn) obtained above was defined as the degree of dispersion.

[Example Z1]
Example 1Z1
36.2 parts of 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 526 parts of methanol were mixed.
While keeping the temperature at 5 ° C., a mixture of 20.9 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 10 parts of methanol was added dropwise to the obtained mixture over 1 hour.
The resulting mixture was stirred at 5 ° C. for 4 hours.
13.1 parts of acetic acid and 23.7 parts of ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) were added to the obtained mixture while keeping the temperature below 5 ° C.
The obtained mixture was stirred at 5 ° C. for 1 hour and then at room temperature for 3 days.
2.37 parts of ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) and 231 parts of methanol were added to the obtained mixture, and the mixture was stirred at room temperature for 1 day.
To the obtained mixture, 0.496 parts of ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) and 26 parts of methanol were added, and the mixture was stirred at 40 ° C. for 2 hours and 30 minutes.
17.1 parts of acetic acid, 26.9 parts of barbituric acid and 793 parts of water were added to the obtained mixture, and the mixture was stirred at 40 ° C. for 2 hours.
To the obtained mixture, 17.0 parts of acetic acid, 26.9 parts of barbituric acid, 12 parts of methanol and 12 parts of water were added, and the mixture was stirred at 40 ° C. for 30 minutes and then at room temperature for 2 days.
The resulting mixture was filtered and the residue was washed once with 915 parts of 50% aqueous methanol solution, once with 950 parts of 50% aqueous methanol solution, once with 1600 parts of 50% aqueous methanol solution and once with 1800 parts of water.
The obtained residue was recrystallized from N, N-dimethylformamide to obtain 30.7 parts of a mixture of the compound represented by the formula (IZ1-38) and the compound represented by the formula (IZ1-39). ..

<Identification of the compound represented by the formula (IZ1-38)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 384
Exact Mass: 383

<Identification of the compound represented by the formula (IZ1-39)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 398
Exact Mass: 397

Example 2 Z1
The formula (IZ1) was carried out in the same manner as in Example 1Z1 except that 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) was replaced with 4-tert-butylphthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.). A mixture of the compound represented by -20) and the compound represented by the formula (IZ1-21) was obtained.

<Identification of the compound represented by the formula (IZ1-20)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 395
Exact Mass: 394

<Identification of the compound represented by the formula (IZ1-21)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 409
Exact Mass: 408

Example 3Z1
4-Nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) is replaced with phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) in the same manner as in Example 1Z1 and represented by the formula (IZ1-2). A mixture of the compound to be used and the compound represented by the formula (IZ1-3) was obtained.

<Identification of the compound represented by the formula (IZ1-2)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 339
Exact Mass: 338

<Identification of the compound represented by the formula (IZ1-3)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 353
Exact Mass: 352

Example 4Z1
It was carried out in the same manner as in Example 1Z1 except that ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) was replaced with methyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.), and was represented by the formula (IZ1-38). Compound was obtained.

<Identification of the compound represented by the formula (IZ1-38)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 384
Exact Mass: 383

Example 5Z1
4-Nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) is replaced with 4-tert-butylphthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) is used. , Methyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) was carried out in the same manner as in Example 1Z1 to obtain a compound represented by the formula (IZ1-20).

<Identification of the compound represented by the formula (IZ1-20)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 395
Exact Mass: 394

Example 6Z1
4-Nitrophthalonitrile (manufactured by Tokyo Kasei Kogyo Co., Ltd.) is replaced with phthalonitrile (manufactured by Tokyo Kasei Kogyo Co., Ltd.), and ethyl cyanoacetate (manufactured by Tokyo Kasei Kogyo Co., Ltd.) is replaced with methyl cyanoacetate (manufactured by Tokyo Kasei Kogyo Co., Ltd.). A compound represented by the formula (IZ1-2) was obtained in the same manner as in Example 1Z1 except that the compound was replaced with that of Industrial Co., Ltd.

<Identification of the compound represented by the formula (IZ1-2)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 339
Exact Mass: 338

Example 7Z1
10.0 parts of 4-tert-butyl phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 84 parts of methanol were mixed. A mixture of 8.15 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 73 parts of methanol was added dropwise to the obtained mixture at 5 ° C. or lower over 1 hour. The resulting mixture was stirred at 5-20 ° C. for 2 days.
At 10 to 20 ° C., 5.42 parts of acetic acid and 6.14 parts of ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) were added to the obtained mixture. The resulting mixture was stirred at 65 ° C. for 3 days. To the obtained mixture, 2.69 parts of acetic acid and 3.07 of ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) were added, and the mixture was stirred at 65 ° C. for 3 days. In addition to the methanol described above, a total of 206 parts of methanol was added up to this point.
To the obtained mixture, 5.36 parts of acetic acid, 7.25 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.) and 363 parts of water were added, and the mixture was stirred at 65 ° C. for 9 days.
After distilling off the solvent of the obtained mixture with a rotary evaporator, the obtained residue is purified by column chromatography to obtain a compound represented by the formula (IZ1-20) and a compound represented by the formula (IZ1-21). A mixture was obtained.

<Identification of the compound represented by the formula (IZ1-20)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 395
Exact Mass: 394

<Identification of the compound represented by the formula (IZ1-21)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 409
Exact Mass: 408

Example 8Z1
2.57 parts of phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 24.5 parts of methanol were mixed.
At room temperature, 2.00 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) was added to the obtained mixture.
The resulting mixture was stirred at 43 ° C. for 1 hour and 30 minutes.
To the obtained mixture, 2.53 parts of ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.), 1.26 parts of acetic acid, and 54.5 parts of methanol were added, and the mixture was stirred at 40 ° C. for 1 hour and 30 minutes.
To the obtained mixture, 2.84 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.), 1.63 parts of acetic acid and 9 parts of methanol were added, and the mixture was stirred at 40 ° C. for 1 hour.
After distilling off the solvent of the obtained mixture with a rotary evaporator, the obtained residue is purified by column chromatography to obtain a compound represented by the formula (IZ1-2) and a compound represented by the formula (IZ1-3). A mixture was obtained.

<Identification of the compound represented by the formula (IZ1-2)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 339
Exact Mass: 338

<Identification of the compound represented by the formula (IZ1-3)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 353
Exact Mass: 352

Example 9Z1
10.0 parts of 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 149 parts of methanol were mixed. While keeping the temperature at 2 to 6 ° C., 5.86 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) was added dropwise to the obtained mixture over 20 minutes. The resulting mixture was stirred for 5 hours while keeping below 5 ° C.
While keeping the obtained mixture at 5 ° C. or lower, 5.79 parts of acetic acid, 5.72 parts of methyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.), and 74 parts of methanol were added. The resulting mixture was stirred at 65 ° C. for 3 days.
To the obtained mixture, 2.88 parts of acetic acid and 2.86 parts of methyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) were added.
The resulting mixture was stirred at 65 ° C. for 3 days.
In addition to the methanol described above, a total of 140 parts of methanol was added up to this point.
To the obtained mixture, 24.0 parts of acetic acid, 15.3 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.) and 363 parts of water were added, and the mixture was stirred at 65 ° C. for 9 days.
The obtained mixture was solvent-distilled off by a rotary evaporator, and the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ1-38).

<Identification of the compound represented by the formula (IZ1-38)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 384
Exact Mass: 383

Example 10Z1
10.0 parts of 4-tert-butyl phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 84 parts of methanol were mixed. A mixture of 8.15 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 73 parts of methanol was added dropwise to the obtained mixture at 5 ° C. or lower over 1 hour. The resulting mixture was stirred at 5-20 ° C. for 2 days.
At 10 to 20 ° C., 5.42 parts of acetic acid and 5.38 parts of methyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) were added to the obtained mixture. The resulting mixture was stirred at 65 ° C. for 3 days.
To the obtained mixture, 2.69 parts of acetic acid and 2.69 methyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) were added, and the mixture was stirred at 65 ° C. for 3 days.
In addition to the methanol described above, a total of 206 parts of methanol was added up to this point.
To the obtained mixture, 5.36 parts of acetic acid, 7.25 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.) and 363 parts of water were added, and the mixture was stirred at 65 ° C. for 9 days.
The obtained mixture was solvent-distilled off by a rotary evaporator, and the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ1-20).

<Identification of the compound represented by the formula (IZ1-20)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 395
Exact Mass: 394

Example 11Z1
60.0 parts of phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 501 parts of methanol were mixed.
While keeping the temperature at 2 ° C., 46.7 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) was added dropwise to the obtained mixture over 15 minutes.
The resulting mixture was stirred for 5 hours while keeping at 2 ° C to 6 ° C.
556 parts of methanol was added to this mixture while keeping the temperature below 5 ° C.
To this mixture was added 29.3 parts of acetic acid, 46.5 parts of methyl cyanoacetate and 22 parts of methanol.
The mixture was stirred at room temperature for 12 hours and then at 40 ° C. for 3 hours and 20 minutes.
This mixture was mixed with 3.00 parts of acetic acid and 4.71 parts of methyl cyanoacetate, and stirred at 40 ° C. for 1 hour and 25 minutes.
This mixture was mixed with 2.98 parts of acetic acid and 4.71 parts of methyl cyanoacetate, and stirred at 40 ° C. for 2 hours.
This mixture was mixed with 2.96 parts of acetic acid and 4.70 parts of methyl cyanoacetate, and stirred at 40 ° C. for 2 hours.
This mixture was mixed with 1.50 parts of acetic acid and 2.40 parts of methyl cyanoacetate.
In addition to the methanol described above, a total of 111 parts of methanol was added up to this point.
The resulting mixture was stirred at 40 ° C. for 1 hour and 40 minutes.
To the obtained mixture, 38.1 parts of acetic acid and 60.6 parts of barbituric acid were added, and the mixture was stirred at 40 ° C. for 42 hours.
In addition to the methanol described above, a total of 66 parts of methanol was added up to this point.
The mixture was filtered and the residue was washed 6 times with 400 parts of methanol.
This residue was purified by column chromatography to obtain a compound represented by the formula (IZ1-2).

<Identification of the compound represented by the formula (IZ1-2)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 339
Exact Mass: 338

Example 12Z1
5.0 parts of 4,5-dichlorophthalonitrile and 62 parts of methanol were mixed.
While keeping the mixture at 5 ° C. or lower, a 25% sodium methoxide methanol solution containing 5.0 times the number of moles of 5.0 parts of 4,5-dichlorophthalonitrile of sodium methoxide was added.
The mixture was stirred at 5 ° C. and below for 5 hours.
While maintaining 5 ° C. or lower, methyl cyanoacetate and 6.1 parts of acetic acid were added to the mixture in a number of moles 1.5 times the number of moles of 5.0 parts of 4,5-dichlorophthalonitrile.
The mixture was stirred at 65 ° C. for 3 days.
This mixture was mixed with 4.2 parts of acetic acid, 5.2 parts of barbituric acid, 500 parts of methanol and 562 parts of water, and stirred at 65 ° C. for 9 days.
After distilling off the solvent of this mixture with a rotary evaporator, the obtained residue was purified by column chromatography to obtain 0.297 parts of the compound represented by the formula (IZ1-258).

<Identification of the compound represented by the formula (IZ1-258)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 407
Exact Mass: 406

Example 13Z1
25.9 parts of phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 513 parts of methanol were mixed.
A mixture of 30.3 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 12 parts of methanol was added dropwise to the obtained mixture at 3 ° C to 5 ° C over 10 minutes. ..
The resulting mixture was stirred for 6 hours while keeping at 3 ° C-5 ° C.
19.8 parts of acetic acid, 28.5 parts of tert-butyl cyanoacetic acid and 26 parts of methanol were added to the obtained mixture while maintaining the temperature at 3 ° C. to 5 ° C.
The resulting mixture was stirred at room temperature for 2 days and then at 40 ° C. for 3 hours.
To the obtained mixture, 5.09 parts of acetic acid and 7.17 parts of tert-butyl cyanoacetic acid were added, and the mixture was stirred at 40 ° C. for 4 hours.
To the obtained mixture, 4.95 parts of acetic acid, 7.15 parts of tert-butyl cyanoacetic acid and 38 parts of methanol were added, and the mixture was stirred at 40 ° C. for 16 hours.
To the obtained mixture, 19.9 parts of acetic acid, 25.8 parts of barbituric acid, 209 parts of methanol and 800 parts of water were added, and the mixture was stirred at 40 ° C. for 3 hours.
The resulting mixture was filtered to give a residue.
This residue was purified by column chromatography to obtain a compound represented by the formula (IZ1-5).

<Identification of the compound represented by the formula (IZ1-5)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 381
Exact Mass: 380

Example 14Z1
15.1 part of 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 284 parts of methanol were mixed.
A mixture of 8.81 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 18 parts of methanol was added dropwise to the obtained mixture at 5 ° C. or lower over 10 minutes.
The resulting mixture was stirred for 4 hours while keeping below 5 ° C.
5.55 parts of acetic acid was added to the obtained mixture while keeping the temperature below 5 ° C., and the mixture was stirred for 30 minutes.
This mixture was mixed with 12.3 parts of tert-butyl cyanoacetic acid and stirred at 40 ° C. for 14 hours.
This mixture was mixed with 0.654 parts of acetic acid and 1.24 parts of tert-butyl cyanoacetic acid, and the mixture was stirred at 40 ° C. for 4 hours.
This mixture was mixed with 0.613 parts of acetic acid and 1.23 parts of tert-butyl cyanoacetic acid, and the mixture was stirred at 40 ° C. for 3 hours.
This mixture was mixed with 0.647 parts of acetic acid and 1.24 parts of tert-butyl cyanoacetic acid. In addition to the methanol described above, a total of 89 parts of methanol was added up to this point.
The mixture was stirred at 40 ° C. for 17 hours.
This mixture was mixed with 7.14 parts of acetic acid, 11.3 parts of barbituric acid and 508 parts of water. In addition to the methanol described above, a total of 117 parts of methanol was added up to this point.
The mixture was stirred at 40 ° C. for 24 hours.
This mixture was mixed with 3.65 parts of acetic acid and 5.61 parts of barbituric acid, and stirred at 40 ° C. for 9 hours and at room temperature for 2 days.
The mixture was filtered and the residue was washed 3 times with 1330 parts of 50% aqueous methanol solution.
The obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ1-41).

<Identification of the compound represented by the formula (IZ1-41)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 426
Exact Mass: 425

Synthesis example 1
An appropriate amount of nitrogen was poured into a flask equipped with a reflux condenser, a dropping funnel and a stirrer to replace the nitrogen atmosphere, 280 parts of propylene glycol monomethyl ether acetate was placed therein, and the mixture was heated to 80 ° C. with stirring. Then 38 parts of acrylic acid, 3,4-epoxytricyclo [5.2.1.0 ^2,6 ] decane-8-ylacrylate and 3,4-epoxytricyclo [5.2.1.0 ^{2, 6} ] A mixed solution of 289 parts of a mixture of decane-9-ylacrylate and 125 parts of propylene glycol monomethyl ether acetate was added dropwise over 5 hours. On the other hand, a mixed solution prepared by dissolving 33 parts of 2,2-azobis (2,4-dimethylvaleronitrile) in 235 parts of propylene glycol monomethyl ether acetate was added dropwise over 6 hours. After completion of the dropping, the mixture was kept at the same temperature for 4 hours and then cooled to room temperature to obtain a solution of a copolymer (resin B1) having a solid content of 35.0%. The weight average molecular weight (Mw) of the obtained resin B1 was 8800, the dispersity was 2.1, and the solution acid value was 28 mg-KOH / g.

Synthesis example 2
An appropriate amount of nitrogen was poured into a flask equipped with a reflux condenser, a dropping funnel and a stirrer to replace the nitrogen atmosphere, 371 parts of propylene glycol monomethyl ether acetate was placed therein, and the mixture was heated to 85 ° C. with stirring. Then 54 parts of acrylic acid, 3,4-epoxytricyclo [5.2.1.0 ^2,6 ] decane-8-ylacrylate and 3,4-epoxytricyclo [5.2.1.0 ^{2, 6} ] A mixed solution of 225 parts of a mixture of decane-9-ylacrylate, 81 parts of vinyl toluene (isomer mixture) and 80 parts of propylene glycol monomethyl ether acetate was added dropwise over 4 hours. On the other hand, a solution prepared by dissolving 30 parts of the polymerization initiator 2,2-azobis (2,4-dimethylvaleronitrile) in 160 parts of propylene glycol monomethyl ether acetate was added dropwise over 5 hours. After completion of dropping the initiator solution, the mixture was kept at the same temperature for 4 hours and then cooled to room temperature to obtain a solution of a copolymer (resin B3) having a solid content of 37.5%. The weight average molecular weight (Mw) of the obtained resin B3 was 10600, the dispersity was 2.01, and the solution acid value was 43 mg-KOH / g.

Synthesis example 3
An appropriate amount of nitrogen was poured into a flask equipped with a reflux condenser, a dropping funnel and a stirrer to replace the nitrogen atmosphere, 350 parts of propylene glycol monomethyl ether acetate was placed therein, and the mixture was heated to 85 ° C. with stirring. Then 70 parts of acrylic acid, 3,4-epoxytricyclo [5.2.1.0 ^2,6 ] decane-8-ylacrylate and 3,4-epoxytricyclo [5.2.1.0 ^{2, 6} ] A mixed solution of 202 parts of a mixture of decane-9-ylacrylate, 78 parts of vinyl toluene (isomer mixture) and 100 parts of propylene glycol monomethyl ether acetate was added dropwise over 4 hours. On the other hand, a solution prepared by dissolving 33 parts of the polymerization initiator 2,2-azobis (2,4-dimethylvaleronitrile) in 167 parts of propylene glycol monomethyl ether acetate was added dropwise over 5 hours. After completion of dropping the initiator solution, the mixture was kept at the same temperature for 4 hours and then cooled to room temperature to obtain a solution of a copolymer (resin B5) having a solid content of 38.1%. The weight average molecular weight (Mw) of the obtained resin B5 was 10400, the dispersity was 2.03, and the solution acid value was 53 mg-KOH / g.

Example 101Z1
Pigment: C.I. I. Pigment Green 58 60 copies,
Acrylic pigment dispersant 8.1 parts,
A pigment dispersion (colorant (A1Z1) -containing liquid) in which 73 parts of a resin (B): resin B5 solution and 290 parts of a solvent (E): propylene glycol monomethyl ether acetate are mixed and the pigment is dispersed using a bead mill is used. Prepared.
Separately
Colorant (AZ1): 50 parts of a mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39).
Dispersant (BYK-LPN6919; manufactured by Big Chemie Japan Co., Ltd.) 58 copies,
A compound represented by the formula (IZ1-38) obtained in Example 1Z1 by mixing 93 parts of a resin (B): a resin B3 solution and 800 parts of a solvent (E): propylene glycol monomethyl ether acetate and using a bead mill. And a mixture with the compound represented by the formula (IZ1-39) were dispersed to obtain a colored composition.
Then
The total amount of the obtained pigment dispersion liquid (colorant (A1Z1) -containing liquid);
400 parts of the obtained coloring composition;
Resin (B): 45 parts of resin B1 solution;
Polymerizable compound (C): Dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kayaku Co., Ltd.) 25 parts;
Polymerization Initiator (D): N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure® OXE-01; manufactured by BASF Ltd.) 15 parts;
Solvent (E): 86 parts of propylene glycol monomethyl ether acetate; Leveling agent: Polyether-modified silicone oil (Tore Silicone SH8400; manufactured by Toray Dow Corning Co., Ltd.) 0.12 parts;
Was mixed to obtain a colored curable composition 1Z1.

[Making a colored pattern]
A color-curable composition 1Z1 was applied onto a 2-inch square glass substrate (Eagle XG; manufactured by Corning Inc.) by a spin coating method, and then prebaked at 100 ° C. for 3 minutes to form a color-curable composition layer. After cooling, the distance between the substrate on which the colored curable composition layer was formed and the quartz glass photomask was set to 200 μm, and using an exposure machine (TME-150RSK; manufactured by Topcon Co., Ltd.), 80 mJ / in an air atmosphere. Exposure was performed with an exposure amount of cm ^{2 (based on 365 nm).} still,
As the photomask, a photomask having a line-and-space pattern of 100 μm formed was used. The colored curable composition layer after exposure was developed by immersing it in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ° C. for 70 seconds, and washed with water. This color-curable composition layer was post-baked at 230 ° C. for 30 minutes to obtain a color pattern.

[Phase difference value measurement]
A color-curable composition 1Z1 was applied onto a 2-inch square glass substrate (Eagle XG; manufactured by Corning Inc.) by a spin coating method, and then prebaked at 100 ° C. for 3 minutes to form a color-curable composition layer. ^{After cooling, the colored curable composition layer was exposed to an exposure amount of 80 mJ / cm 2} (based on 365 nm) in an air atmosphere using an exposure machine (TME-150RSK; manufactured by Topcon Corporation). The colored curable composition layer after exposure was developed by immersing it in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ° C. for 70 seconds, and washed with water. This colored coating film was post-baked at 230 ° C. for 30 minutes to obtain a colored coating film.
The film thickness of the obtained colored coating film was measured using DEKTAK3 (manufactured by Nippon Vacuum Technology Co., Ltd.).
Using an ellipsometer (M-220 type spectroscopic ellipsometer; manufactured by JASCO Corporation), the phase difference value at a tilt angle of 45 ° of this colored coating film was measured. Light having a wavelength of 550 nm was used for the phase difference value measurement. The results are shown in Table 15Z1.

Example 102Z1
A mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) is combined with the compound represented by the formula (IZ1-20) obtained in Example 2Z1. A coloring curable composition 2Z1 was obtained in the same manner as in Example 101Z1 except that the mixture was replaced with a mixture of compounds represented by the formula (IZ1-21), and a coloring pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 15Z1.

Example 103Z1
A mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) is combined with the compound represented by the formula (IZ1-2) obtained in Example 3Z1. A coloring curable composition 3Z1 was obtained in the same manner as in Example 101Z1 except that the mixture was replaced with a mixture of compounds represented by the formula (IZ1-3), and a coloring pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 15Z1.

Example 104Z1
A mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was added to the compound represented by the formula (IZ1-38) obtained in Example 4Z1. A coloring curable composition 4Z1 was obtained in the same manner as in Example 101Z1 except for the replacement, and a coloring pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 15Z1.

Example 105Z1
A mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was added to the compound represented by the formula (IZ1-20) obtained in Example 5Z1. A coloring curable composition 5Z1 was obtained in the same manner as in Example 101Z1 except for the replacement, and a coloring pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 15Z1.

Example 106Z1
A mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was added to the compound represented by the formula (IZ1-2) obtained in Example 6Z1. A coloring curable composition 6Z1 was obtained in the same manner as in Example 101Z1 except for the replacement, and a coloring pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 15Z1.

Example 107Z1
C. I. Pigment Green 58 to C.I. I. A color-curable composition 7Z1 was obtained in the same manner as in Example 101Z1 except that it was replaced with Pigment Green 7, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 15Z1.

Example 108Z1
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 7, a mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was obtained by the formula (IZ1-20) obtained in Example 2Z1. A coloring curable composition 8Z1 was obtained in the same manner as in Example 101Z1 except that the mixture of the compound represented by (IZ1-21) and the compound represented by the formula (IZ1-21) was replaced, and a coloring pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 15Z1.

Example 109Z1
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 7, a mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was obtained by the formula (IZ1-2) obtained in Example 3Z1. A coloring curable composition 9Z1 was obtained in the same manner as in Example 101Z1 except that the mixture of the compound represented by (IZ1-3) and the compound represented by the formula (IZ1-3) was replaced, and a coloring pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 15Z1.

Example 110Z1
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 7, a mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was obtained by the formula (IZ1-38) obtained in Example 4Z1. A coloring curable composition 10Z1 was obtained in the same manner as in Example 101Z1 except that the compound represented by (1) was used, and a coloring pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 15Z1.

Example 111Z1
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 7, a mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was obtained by the formula (IZ1-20) obtained in Example 5Z1. A coloring curable composition 11Z1 was obtained in the same manner as in Example 101Z1 except that the compound represented by (1) was used, and a coloring pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 15Z1.

Example 112Z1
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 7, a mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was obtained by the formula (IZ1-2) obtained in Example 6Z1. A coloring curable composition 12Z1 was obtained in the same manner as in Example 101Z1 except that the compound represented by (1) was used, and a coloring pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 15Z1.

Example 113Z1
C. I. Pigment Green 58 to C.I. I. A color-curable composition 13Z1 was obtained in the same manner as in Example 101Z1 except that it was replaced with Pigment Green 59, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 15Z1.

Example 114Z1
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 59, a mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was obtained by the formula (IZ1-20) obtained in Example 2Z1. A coloring curable composition 14Z1 was obtained in the same manner as in Example 101Z1 except that the mixture of the compound represented by (IZ1-21) and the compound represented by the formula (IZ1-21) was replaced, and a coloring pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 15Z1.

Example 115Z1
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 59, a mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was obtained by the formula (IZ1-2) obtained in Example 3Z1. A coloring curable composition 15Z1 was obtained in the same manner as in Example 101Z1 except that the mixture of the compound represented by (IZ1-3) and the compound represented by the formula (IZ1-3) was replaced, and a coloring pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 15Z1.

Example 116Z1
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 59, a mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was obtained by the formula (IZ1-38) obtained in Example 4Z1. A coloring curable composition 16Z1 was obtained in the same manner as in Example 101Z1 except that the compound represented by (1) was used, and a coloring pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 15Z1.

Example 117Z1
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 59, a mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was obtained by the formula (IZ1-20) obtained in Example 5Z1. A coloring curable composition 17Z1 was obtained in the same manner as in Example 101Z1 except that the compound represented by (1) was used, and a coloring pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 15Z1.

Example 118Z1
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 59, a mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was obtained by the formula (IZ1-2) obtained in Example 6Z1. A coloring curable composition 18Z1 was obtained in the same manner as in Example 101Z1 except that the compound represented by (1) was used, and a coloring pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 15Z1.

Comparative Example 1Z1
A mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was obtained from C.I. I. A color-curable composition C1Z1 was obtained in the same manner as in Example 101Z1 except that it was replaced with Pigment Yellow 185, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 15Z1.

Comparative Example 2Z1
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 7, a mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was used as C.I. I. A color-curable composition C2Z1 was obtained in the same manner as in Example 101Z1 except that it was replaced with Pigment Yellow 185, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 15Z1.

Comparative Example 3Z1
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 59, a mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was used as C.I. I. A color-curable composition C3Z1 was obtained in the same manner as in Example 101Z1 except that it was replaced with Pigment Yellow 185, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 15Z1.

Example 119Z1
Pigment: C.I. I. Pigment Green 58 60 copies,
Acrylic pigment dispersant 8.1 parts,
A pigment dispersion (colorant (A1Z1) -containing liquid) in which 73 parts of a resin (B): resin B5 solution and 290 parts of a solvent (E): propylene glycol monomethyl ether acetate are mixed and the pigment is dispersed using a bead mill is used. Prepared.
Separately
Colorant (AZ1): 50 parts of a mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39).
Dispersant solution (solid content 60%) 58 parts,
A compound represented by the formula (IZ1-38) obtained in Example 1Z1 by mixing 93 parts of a resin (B): a resin B3 solution and 800 parts of a solvent (E): propylene glycol monomethyl ether acetate and using a bead mill. And a mixture with the compound represented by the formula (IZ1-39) were dispersed to obtain a colored composition.
Then
The total amount of the obtained pigment dispersion liquid (colorant (A1Z1) -containing liquid);
400 parts of the obtained coloring composition;
Resin (B): 45 parts of resin B1 solution;
Polymerizable compound (C): Dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kayaku Co., Ltd.) 25 parts;
Polymerization Initiator (D): N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure® OXE-01; manufactured by BASF Ltd.) 15 parts;
Solvent (E): 86 parts of propylene glycol monomethyl ether acetate; Leveling agent: Polyether-modified silicone oil (Tore Silicone SH8400; manufactured by Toray Dow Corning Co., Ltd.) 0.12 parts;
Was mixed to obtain a colored curable composition 19Z1.

A coloring pattern was produced in the same manner as in Example 101Z1 except that the coloring curable composition 19Z1 was used instead of the coloring curable composition 1Z1. Further, a colored coating film was obtained in the same manner as in Example 101Z1 except that the coloring curable composition 19Z1 was used instead of the coloring curable composition 1Z1, and the film thickness measurement and the retardation value measurement were performed. The results are shown in Table 16Z1.

Example 120Z1-Example 127Z1
Except that the mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) is replaced with the colorant shown in the "colorant" column of Table 16Z1. A coloring pattern was obtained in the same manner as in Example 119Z1. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 16Z1.

Example 128Z1 to Example 136Z1
The mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was replaced with the compound shown in the "colorant" column of Table 16Z1. I. Pigment Green 58 to C.I. I. A coloring pattern was obtained in the same manner as in Example 119Z1 except that the pigment green 7 was replaced. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 16Z1.

Example 137Z1 to Example 145Z1
The mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was replaced with the compound shown in the "colorant" column of Table 16Z1. I. Pigment Green 58 to C.I. I. A coloring pattern was obtained in the same manner as in Example 119Z1 except that the pigment green 59 was replaced. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 16Z1.

In the examination of Example Z1, from the above results, in the colored coating film formed from the colored curable composition containing the compound of the present invention, C.I. I. It was found that the retardation value was smaller than that of the colored coating film formed from the colored curable composition containing Pigment Yellow 185.

[Example Z2]
Example 1Z2
5.02 parts of 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 22 parts of methanol were mixed.
To the obtained mixture, 2.90 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) was added, and the mixture was stirred at 25 ° C. for 3 hours.
To the obtained mixture, 3.67 parts of ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.), 1.83 parts of acetic acid and 30 parts of methanol were added, and the mixture was stirred at 25 ° C. for 1 hour and 30 minutes.
To the obtained mixture, 3.62 parts of ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.), 2.37 parts of acetic acid and 30 parts of methanol were added, and the mixture was stirred at 63 ° C. for 3 hours.
To the obtained mixture, 3.63 parts of ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.), 2.36 parts of acetic acid and 30 parts of methanol were added, and the mixture was stirred at 63 ° C. for 2 hours.
To the obtained mixture, 3.62 parts of ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) and 2.40 parts of acetic acid were added, and the mixture was added at 63 ° C. for 1 hour, at room temperature for 11 hours, and at 63 ° C. for 6 hours. Stirred.
The temperature of the obtained mixture was lowered to room temperature and then filtered.
The obtained residue was dried to obtain 10.0 parts of a mixture of a compound represented by the formula (IaZ2-39), a compound represented by the formula (IaZ2-38) and a compound represented by the formula (IaZ2-149). Obtained.

<Identification of the compound represented by the formula (IaZ2-39)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 383
Exact Mass: 382

<Identification of the compound represented by the formula (IaZ2-38)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 355
Exact Mass: 354

<Identification of the compound represented by the formula (IaZ2-1149)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 369
Exact Mass: 368

Example 2 Z2
It was carried out in the same manner as in Example 1Z2 except that ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) was replaced with 2-cyanoacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.), and was represented by the formula (IbZ2-125). Compound was obtained.

<Identification of the compound represented by the formula (IbZ2-125)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 325
Exact Mass: 324

Example 3Z2
The same procedure as in Example 1Z2 was carried out except that ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) was replaced with 2-cyano-N-methylacetamide to obtain a compound represented by the formula (IbZ2-126). ..

<Identification of the compound represented by the formula (IbZ2-126)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 353
Exact Mass: 352

Example 4Z2
The formula (IbZ2) was carried out in the same manner as in Example 1Z2 except that ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) was replaced with 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.). A compound represented by -148) was obtained.

<Identification of the compound represented by the formula (IbZ2-148)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 381
Exact Mass: 380

Example 5Z2
The formula (IbZ2) was carried out in the same manner as in Example 1Z2 except that ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) was replaced with 2-cyano-N, N-diethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.). A compound represented by -149) was obtained.

<Identification of the compound represented by the formula (IbZ2-1149)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 437
Exact Mass: 436

Example 6Z2
It was carried out in the same manner as in Example 1Z2 except that ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) was replaced with 2-cyanoacetanilide (manufactured by Tokyo Chemical Industry Co., Ltd.), and was represented by the formula (IbZ2-128). Compound was obtained.

<Identification of the compound represented by the formula (IbZ2-128)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 477
Exact Mass: 476

Example 7Z2
2.55 parts of 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 84 parts of methanol were mixed.
While keeping this mixture at 5 ° C. or lower, a mixture of 1.47 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 30 parts of methanol was added. The mixture was stirred at 5 ° C. and below for 5 hours.
To this mixture was added 2.16 parts of acetic acid, 2.92 parts of 2-cyano-N-methylacetamide and 21 parts of methanol, and the mixture was stirred at 40 ° C. for 3 hours.
To this mixture, 13.5 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) was added, and the mixture was stirred at 40 ° C. for 12 hours and at 62 ° C. for 9 hours.
To this mixture, 1.50 parts of 2-cyano-N-methylacetamide and 3.05 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) were added, and the mixture was added at 62 ° C. for 5 hours at 40 ° C. It was stirred underneath for 17 hours.
In addition to the methanol described above, a total of 6 parts of methanol was added up to this point.
After distilling off the solvent of this mixture with a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IbZ2-126).

<Identification of the compound represented by the formula (IbZ2-126)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 353
Exact Mass: 352

Example 8Z2
10 parts of 4-nitrophthalonitrile and 80 parts of methanol were mixed.
While keeping this mixture at 0 ° C., a 25% sodium methoxide methanol solution containing 0.5 times the number of moles of 4-nitrophthalonitrile was added.
The mixture was stirred at 0 ° C. for 5 hours.
To this mixture was added 2-cyanoacetamide and 16 parts of acetic acid having a molar number of 3.3 times the number of moles of 10 parts of 4-nitrophthalonitrile, and the mixture was stirred at 60 ° C. for 21 days.
After distilling off the solvent of this mixture with a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IbZ2-125).

<Identification of the compound represented by the formula (IbZ2-125)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 325
Exact Mass: 324

Example 9Z2
10 parts of 4-nitrophthalonitrile and 80 parts of methanol were mixed.
While keeping this mixture at 0 ° C., a 25% sodium methoxide methanol solution containing 0.5 times the number of moles of 4-nitrophthalonitrile was added.
The mixture was stirred at 0 ° C. for 5 hours.
To this mixture was added 2-cyano-N, N-dimethylacetamide and 16 parts of acetic acid having a number of moles 3.3 times the number of moles of 10 parts of 4-nitrophthalonitrile, and the mixture was stirred at 60 ° C. for 21 days.
After distilling off the solvent of this mixture with a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IbZ2-148).

<Identification of the compound represented by the formula (IbZ2-148)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 381
Exact Mass: 380

Example 10Z2
10 parts of 4-nitrophthalonitrile and 80 parts of methanol were mixed.
While keeping this mixture at 0 ° C., a 25% sodium methoxide methanol solution containing 0.5 times the number of moles of 4-nitrophthalonitrile was added.
The mixture was stirred at 0 ° C. for 5 hours.
To this mixture was added 2-cyano-N, N-diethylacetamide and 16 parts of acetic acid having a number of moles 3.3 times the number of moles of 10 parts of 4-nitrophthalonitrile, and the mixture was stirred at 60 ° C. for 21 days.
After distilling off the solvent of this mixture with a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IbZ2-1149).

<Identification of the compound represented by the formula (IbZ2-1149)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 437
Exact Mass: 436

Example 11Z2
1.25 parts of 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 41 parts of methanol were mixed. A mixture of 0.722 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 19 parts of methanol was added dropwise to the obtained mixture at 5 ° C. or lower over 5 minutes. The resulting mixture was stirred for 4 hours while keeping below 5 ° C.
While keeping the obtained mixture at 5 ° C. or lower, 1.21 parts of acetic acid, 2.33 parts of 2-cyanoacetanilide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 18 parts of methanol were added. The resulting mixture was stirred at 40 ° C. for 21 hours.
To the obtained mixture, 0.596 parts of acetic acid, 1.17 parts of 2-cyanoacetanilide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 17 parts of methanol were added. The resulting mixture was stirred at 40 ° C. for 3 hours.
To the obtained mixture, 2.09 parts of acetic acid was added, and the mixture was stirred at 50 ° C. for 2 hours, 60 ° C. for 2 hours, room temperature for 15 hours and 62 ° C. for 3 hours.
To the obtained mixture, 0.981 parts of trifluoroacetic acid was added, and the mixture was stirred at 62 ° C. for 2 hours.
To the obtained mixture, 11.5 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) was added, and the mixture was stirred at 62 ° C. for 2 hours, at room temperature for 14 hours, and at 62 ° C. for 5 hours. bottom.
In addition to the methanol described above, a total of 10 parts of methanol was added up to this point.
The resulting mixture was cooled to 23 ° C. and added to 1100 parts of a 50% aqueous acetic acid solution.
To the obtained mixture, 40 parts of methanol and 400 parts of a 50% aqueous acetic acid solution were added.
The obtained mixture was filtered, and the obtained residue was washed 6 times with 250 parts of a 50% aqueous acetic acid solution and 3 times with 250 parts of water.
The obtained residue was dried under reduced pressure at 60 ° C. to obtain 3.32 parts of the compound represented by the formula (IbZ2-128).

<Identification of the compound represented by the formula (IbZ2-128)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 477
Exact Mass: 476

Example 12Z2
25.2 parts of 4-tert-butylphthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 212 parts of methanol were mixed. A mixture of 20.5 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 184 parts of methanol was added dropwise to the obtained mixture at 5 ° C. or lower over 1 hour. The resulting mixture was stirred at 5-20 ° C. for 2 days.
At 10-20 ° C., 13.7 parts of acetic acid and 13.5 parts of 2-cyano-N-methylacetamide were added to the resulting mixture. The resulting mixture was stirred at 10-20 ° C. for 5 hours and then at 40 ° C. for 16 hours.
To the obtained mixture, 6.79 parts of acetic acid and 6.75 parts of 2-cyano-N-methylacetamide were added, and the mixture was stirred at 40 ° C. for 6 hours and at 50 ° C. for 65 hours.
In addition to the methanol described above, a total of 201 parts of methanol was added up to this point.
To the obtained mixture, 13.5 parts of acetic acid, 18.3 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.) and 604 parts of water were added, and the mixture was stirred at 40 ° C. for 53 hours.
The resulting mixture was filtered and the residue was washed with 50% aqueous methanol solution. The obtained residue was purified by column chromatography to obtain a compound represented by the formula (IbZ2-64).

<Identification of the compound represented by the formula (IbZ2-64)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 364
Exact Mass: 363

Example 13Z2
25.9 parts of phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 513 parts of methanol were mixed.
A mixture of 30.3 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 12 parts of methanol was added dropwise to the obtained mixture at 3 ° C to 5 ° C over 10 minutes. ..
The resulting mixture was stirred for 6 hours while keeping at 3 ° C-5 ° C.
19.8 parts of acetic acid, 28.5 parts of tert-butyl cyanoacetic acid and 26 parts of methanol were added to the obtained mixture while maintaining the temperature at 3 ° C. to 5 ° C.
The resulting mixture was stirred at room temperature for 2 days and then at 40 ° C. for 3 hours.
To the obtained mixture, 5.09 parts of acetic acid and 7.17 parts of tert-butyl cyanoacetic acid were added, and the mixture was stirred at 40 ° C. for 4 hours.
To the obtained mixture, 4.95 parts of acetic acid, 7.15 parts of tert-butyl cyanoacetic acid and 38 parts of methanol were added, and the mixture was stirred at 40 ° C. for 16 hours.
To the obtained mixture, 19.9 parts of acetic acid, 25.8 parts of barbituric acid, 209 parts of methanol and 800 parts of water were added, and the mixture was stirred at 40 ° C. for 3 hours.
The resulting mixture was filtered to give a residue.
This residue was purified by column chromatography to obtain a compound represented by the formula (IaZ2-5).

<Identification of the compound represented by the formula (IaZ2-5)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 394
Exact Mass: 393

Example 14Z2
15.1 part of 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 284 parts of methanol were mixed.
A mixture of 8.81 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 18 parts of methanol was added dropwise to the obtained mixture at 5 ° C. or lower over 10 minutes.
The resulting mixture was stirred for 4 hours while keeping below 5 ° C.
5.55 parts of acetic acid was added to the obtained mixture while keeping the temperature below 5 ° C., and the mixture was stirred for 30 minutes.
This mixture was mixed with 12.3 parts of tert-butyl cyanoacetic acid and stirred at 40 ° C. for 14 hours.
This mixture was mixed with 0.654 parts of acetic acid and 1.24 parts of tert-butyl cyanoacetic acid, and the mixture was stirred at 40 ° C. for 4 hours.
This mixture was mixed with 0.613 parts of acetic acid and 1.23 parts of tert-butyl cyanoacetic acid, and the mixture was stirred at 40 ° C. for 3 hours.
This mixture was mixed with 0.647 parts of acetic acid and 1.24 parts of tert-butyl cyanoacetic acid. In addition to the methanol described above, a total of 89 parts of methanol was added up to this point.
The mixture was stirred at 40 ° C. for 17 hours.
This mixture was mixed with 7.14 parts of acetic acid, 11.3 parts of barbituric acid and 508 parts of water. In addition to the methanol described above, a total of 117 parts of methanol was added up to this point.
The mixture was stirred at 40 ° C. for 24 hours.
This mixture was mixed with 3.65 parts of acetic acid and 5.61 parts of barbituric acid, and stirred at 40 ° C. for 9 hours and at room temperature for 2 days.
The mixture was filtered and the residue was washed 3 times with 1330 parts of 50% aqueous methanol solution.
The obtained residue was purified by column chromatography to obtain a compound represented by the formula (IaZ2-41).

<Identification of the compound represented by the formula (IaZ2-41)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 439
Exact Mass: 438

Example 15Z2
5.41 parts of 3,4,5,6-tetrafluorophthalonitrile and 23.6 parts of methanol were mixed.
At 20 ° C. to 25 ° C., a mixture of 2.70 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 10 parts of methanol was added to this mixture.
The mixture was stirred at 20 ° C. to 25 ° C. for 4 hours and 20 minutes.
To this mixture was added 3.36 parts of acetic acid, 5.99 parts of methyl cyanoacetate and 7.5 parts of methanol.
The mixture was stirred at 63 ° C. for 2 hours.
The obtained mixture was solvent-distilled with a rotary evaporator, and the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IaZ2-223).

<Identification of the compound represented by the formula (IaZ2-223)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 382
Exact Mass: 381

Example 16Z2
2.52 parts of phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 22.8 parts of methanol were mixed.
At room temperature, 1.98 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) was added to this mixture.
The mixture was stirred at 38 ° C. for 3 hours.
To this mixture was added 2.79 parts of cyanoacetylurea (manufactured by Tokyo Chemical Industry Co., Ltd.) and 1.26 parts of acetic acid.
The mixture was stirred at 40 ° C. for 1 hour and 30 minutes.
To this mixture was added 2.77 parts of cyanoacetylurea (manufactured by Tokyo Chemical Industry Co., Ltd.) and 1.61 parts of acetic acid.
In addition to the methanol described above, a total of 39.2 parts of methanol was added up to this point.
The mixture was stirred at 40 ° C. for 1 hour.
To this mixture, 65.2 parts of water was added, and the mixture was stirred at 40 ° C. for 2 hours and 30 minutes.
To this mixture, 2.80 parts of cyanoacetylurea (manufactured by Tokyo Chemical Industry Co., Ltd.) and 1.60 parts of acetic acid were added, and the mixture was stirred at 40 ° C. for 20 hours.
In addition to the methanol described above, a total of 31 parts of methanol was added up to this point.
After distilling off the solvent of this mixture with a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IbZ2-19).

<Identification of the compound represented by the formula (IbZ2-19)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 366
Exact Mass: 365

Example 17Z2
8 parts of phthalonitrile and 63 parts of ethanol were mixed.
To this mixture was added a 21% sodium ethoxide ethanol solution containing 1 times the number of moles of sodium ethoxide in 8 parts of phthalonitrile.
The mixture was stirred at room temperature for 2 hours.
To this mixture was added a compound represented by the formula (ppp1) having a number of moles 2.3 times the number of moles of 25 parts of acetic acid and 8 parts of phthalonitrile, and the mixture was stirred at 90 ° C. for 64 hours.
The mixture was cooled to room temperature and filtered.
The obtained residue was washed with 160 parts of methanol and dried.
24 parts of the obtained residue and 230 parts of N, N-dimethylformamide were mixed.
210 parts of acetic acid was added to this mixture.
The mixture was filtered.
The obtained residue was washed with 79 parts of methanol and dried to obtain 17 parts of the compound represented by the formula (IbZ2-311).

<Identification of the compound represented by the formula (IbZ2-311)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 508
Exact Mass: 507

To 15 parts of the compound represented by the formula (IbZ2-311), 200 parts of dichloromethane and 150 parts of trifluoroacetic acid were added, and the mixture was stirred at room temperature for 50 hours.
160 parts of methanol was added to the obtained mixture, and the mixture was filtered.
The obtained residue was dried to obtain 13 parts of the residue.
12 parts of this residue and 230 parts of N, N-dimethylformamide were mixed, stirred for 1 hour, and then filtered.
The obtained residue and 160 parts of methanol were mixed and stirred at 70 ° C.
The resulting mixture was filtered.
The residue was dried to obtain 9 parts of the compound represented by the formula (IbZ2-317).

<Identification of the compound represented by the formula (IbZ2-317)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ M-H] - 394
Exact Mass: 395

Example 18Z2
5 parts of 4-nitrophthalonitrile and 39 parts of ethanol were mixed.
While keeping the mixture at 0 ° C., a 21% sodium ethoxide ethanol solution containing 0.5 times the number of moles of 5 parts of 4-nitrophthalonitrile was added.
The mixture was stirred at 0 ° C. for 3 hours.
To this mixture was added a compound represented by the formula (ppp1) having a number of moles 3.3 times the number of moles of 16 parts of acetic acid and 5 parts of 4-nitrophthalonitrile.
The mixture was sealed and stirred at 90 ° C. for 56 hours.
The mixture was cooled to room temperature and filtered.
The residue was washed with ethanol to obtain 8 parts of residue A.
10 parts of 4-nitrophthalonitrile and 79 parts of ethanol were mixed.
While keeping the mixture at 0 ° C., a 21% sodium ethoxide ethanol solution containing 0.5 times the number of moles of 10 parts of 4-nitrophthalonitrile was added.
The mixture was stirred at 0 ° C. for 3 hours.
To this mixture was added a compound represented by the formula (ppp1) having a number of moles 3.3 times the number of moles of 31 parts of acetic acid and 10 parts of 4-nitrophthalonitrile.
The mixture was sealed and stirred at 90 ° C. for 56 hours.
The mixture was cooled to room temperature and filtered.
The obtained residue was washed with ethanol to obtain 15 parts of residue B.
4 parts of residue A, 14 parts of residue B, and 170 parts of N, N-dimethylformamide were mixed.
This mixture was mixed with 710 parts of methanol and stirred at room temperature for 16 hours.
The mixture was filtered to give 13 parts of residue containing the compound represented by the formula (IbZ2-312).

<Identification of the compound represented by the formula (IbZ2-312)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 553
Exact Mass: 552

13 parts of the residue containing the compound represented by the formula (IbZ2-312), 170 parts of dichloromethane and 130 parts of trifluoroacetic acid were mixed and stirred at room temperature for 16 hours.
After distilling off the solvent from this mixture, 190 parts of N, N-dimethylformamide was added to 12 parts of the obtained residue, and the mixture was stirred at 90 ° C. for 10 minutes and then filtered.
The obtained filtrate was allowed to stand at room temperature for 16 hours.
The filtrate was filtered to give 8.0 parts of residue.
8.0 parts of this residue and 22 parts of tetrahydrofuran were mixed, stirred at 70 ° C. for 3 hours, and then filtered.
7.2 parts of the obtained residue and 21 parts of acetic acid were mixed, stirred at 80 ° C. for 2 hours, and then filtered.
6.2 parts of the obtained residue and 170 parts of toluene were mixed, stirred at 95 ° C. for 3 hours, and then filtered.
5.6 parts of the obtained residue and 50 parts of water were mixed, stirred at 90 ° C. for 16 hours, and then filtered.
The obtained residue was dried to obtain 5.4 parts of the compound represented by the formula (IbZ2-515).

<Identification of the compound represented by the formula (IbZ2-515)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ M-H] - 439
Exact Mass: 440

Example 19Z2
2 parts of phthalonitrile and 16 parts of methanol were mixed.
While keeping this mixture at 0 ° C., a 25% sodium methoxide methanol solution containing 0.5 times the number of moles of sodium methoxide in 2 parts of phthalonitrile was added.
The mixture was stirred at 0 ° C. for 5 hours.
To this mixture was added 4.2 parts of acetic acid and a compound represented by the formula (ppp2) having a number of moles 3.3 times the number of moles of 2 parts of phthalonitrile, and the mixture was stirred at 60 ° C. for 6 days.
The mixture was cooled to room temperature and filtered.
The obtained residue was washed with methanol to obtain 4 parts of residue Aa containing the compound represented by the formula (IbZ2-313).
8 parts of phthalonitrile and 63 parts of methanol were mixed.
While keeping the mixture at 0 ° C., a 25% sodium methoxide methanol solution containing 0.5 times the number of moles of 8 parts of phthalonitrile was added.
The mixture was stirred at 0 ° C. for 5 hours.
To this mixture was added 17 parts of acetic acid and a compound represented by the formula (ppp2) having a number of moles 3.3 times the number of moles of 8 parts of phthalonitrile, and the mixture was stirred at 60 ° C. for 10 days.
The mixture was cooled to room temperature and filtered.
The obtained residue was washed with methanol to obtain 16 parts of residue Bb containing the compound represented by the formula (IbZ2-313).

<Identification of the compound represented by the formula (IbZ2-313)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 536
Exact Mass: 535

2 parts of the residue Aa containing the compound represented by the formula (IbZ2-313), 27 parts of dichloromethane and 22 parts of trifluoroacetic acid were mixed and stirred at room temperature for 16 hours.
The solvent was distilled off from this mixture to obtain 2 parts of residue Aaa.
2 parts of the residue Aa containing the compound represented by the formula (IbZ2-313), 16 parts of the residue Bb containing the compound represented by the formula (IbZ2-313), 240 parts of dichloromethane, and 190 parts of trifluoroacetic acid are mixed and mixed at room temperature. The mixture was stirred for 16 hours.
The solvent was distilled off from this mixture to obtain 16 parts of residue Ccc.
1.7 parts of residue Aaa, 16 parts of residue Ccc and 210 parts of acetic acid were mixed and stirred at 80 ° C. for 16 hours.
The mixture was filtered to give 13 parts of residue.
The residue and 71 parts of diethyl ether were mixed and stirred at room temperature for 16 hours.
The mixture was filtered and the obtained residue was dried to give 12 parts of the compound represented by the formula (IbZ2-318).

<Identification of the compound represented by the formula (IbZ2-318)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ M-H] - 422
Exact Mass: 423

Example 20Z2
2 parts of 4-nitrophthalonitrile and 16 parts of methanol were mixed.
While keeping the mixture at 0 ° C., a 25% sodium methoxide methanol solution containing 0.5 times the number of moles of 2-part 4-nitrophthalonitrile of sodium methoxide was added.
The mixture was stirred at 0 ° C. for 3 hours.
To this mixture was added a compound represented by the formula (ppp2) having a molar number of 3.3 times the number of moles of 2 parts of 4-nitrophthalonitrile and 2.1 parts of acetic acid, and the mixture was stirred at 60 ° C. for 15 days.
The mixture was cooled to room temperature and filtered.
The obtained residue was washed with 48 parts of methanol to obtain 8.4 parts of a residue containing the compound represented by the formula (IbZ2-314).

<Identification of the compound represented by the formula (IbZ2-314)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 581
Exact Mass: 580

8.4 parts of the residue containing the compound represented by the formula (IbZ2-314), 110 parts of dichloromethane and 89 parts of trifluoroacetic acid were mixed and stirred at room temperature for 16 hours.
The solvent was distilled off from this mixture to obtain 6.9 parts of a residue.
6.1 parts of this residue and 34 parts of dimethyl sulfoxide were mixed and stirred at room temperature for 5 minutes.
This mixture and 190 parts of acetic acid were mixed and stirred at room temperature for 30 minutes.
This mixture was mixed with 290 parts of methanol and stirred at room temperature for 1 hour.
The mixture was filtered to give 5.7 parts of residue.
5.6 parts of this residue and 150 parts of water were mixed, stirred at 80 ° C. for 2 hours, and filtered.
The obtained residue was dried to obtain 5.4 parts of the compound represented by the formula (IbZ2-516).

<Identification of the compound represented by the formula (IbZ2-516)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ M-H] - 467
Exact Mass: 468

Example 21Z2
A compound represented by the formula (ppp3) having a number of moles 1.1 times the number of moles of 6 parts of phthalonitrile, and tert-butoxypotassium having 66 parts of dimethylsulfooxide and 1 time the number of moles of 6 parts of phthalonitrile. Was mixed and stirred at room temperature for 10 minutes.
To this mixture, 6 parts of phthalonitrile was added, and the mixture was stirred at 80 ° C. for 2 hours.
A compound represented by the formula (ppp3) having a number of moles 1.1 times the number of moles of 6 parts of phthalonitrile was added to this mixture, and the mixture was stirred at 180 ° C. for 2 hours.
The mixture was cooled to room temperature and filtered to give 5.3 parts of residue.
5.0 parts of this residue, 55 parts of dimethyl sulfoxide and 47 parts of N, N-dimethylformamide were mixed and stirred at 80 ° C. for 30 minutes.
This mixture was mixed with 240 parts of methanol and stirred at 80 ° C. for 30 minutes.
The mixture was cooled to room temperature and filtered.
The obtained residue was mixed with 55 parts of dimethyl sulfoxide and 47 parts of N, N-dimethylformamide, and stirred at 80 ° C. for 30 minutes.
This mixture was mixed with 240 parts of methanol and stirred at 80 ° C. for 30 minutes.
The mixture was cooled to room temperature and filtered to give 4.6 parts of residue.
The residue and methanol were mixed and stirred at 80 ° C. for 2 hours.
The mixture was filtered and the obtained residue was dried to give 4.5 parts of the compound represented by the formula (IbZ2-319).

<Identification of the compound represented by the formula (IbZ2-319)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ M-H] - 518
Exact Mass: 519

Example 22Z2
50 parts of 4-aminomethyl benzoic acid and 50 parts of 4-aminomethyl benzoic acid have 1.2 times the number of moles of cyanoacetic acid, and 50 parts of 4-aminomethyl benzoic acid have 0.9 times the number of moles. A number of N, N'-dicyclohexylcarbodiimide and 890 parts of tetrahydrofuran were mixed and stirred at room temperature for 16 hours.
The mixture was filtered and the filtrate was evaporated to give a residue.
The obtained residue and 270 parts of ethyl acetate were mixed and filtered.
The obtained residue was dried to obtain 30 parts of the compound represented by the formula (ppp4).

<Identification of the compound represented by the formula (ppp4)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ M-H] - 217
Exact Mass: 218

3 parts of phthalonitrile and 110 parts of ethylene glycol were mixed.
To this mixture was added a 25% sodium methoxide methanol solution containing sodium methoxide in a molar number 1.5 times the molar number of 3 parts of phthalonitrile at room temperature.
The mixture was stirred at room temperature for 4 hours.
To this mixture was added 110 parts of ethylene glycol and a compound represented by the formula (ppp4) having 3.1 times the number of moles of 3 parts of phthalonitrile, and the mixture was stirred at 110 ° C. for 16 hours.
After cooling the mixture to room temperature, 630 parts of methanol was added.
This mixture was mixed with 26 parts of acetic acid.
The mixture was filtered to give 11 parts of residue.
This residue was mixed with 220 parts of dimethyl sulfoxide.
This mixture was mixed with 630 parts of methanol.
The mixture was filtered to give 9.5 parts of residue.
This residue was mixed with 220 parts of dimethyl sulfoxide.
This mixture was mixed with 630 parts of methanol.
The mixture was filtered to give 9 parts of residue.
The residue and 200 parts of water were mixed and stirred at 80 ° C. for 2 hours.
This mixture was mixed with 2.1 parts of acetic acid.
The mixture was filtered to give 8.5 parts of residue.
8.1 parts of this residue and 260 parts of dimethyl sulfoxide were mixed and stirred at 60 ° C. for 20 minutes.
The mixture was cooled to room temperature, allowed to stand at room temperature for 2 hours and filtered.
The obtained residue was washed with a 2% aqueous acetic acid solution to obtain 6.2 parts of the residue.
The residue and 150 parts of water were mixed and stirred at 80 ° C. for 30 minutes.
The mixture was cooled to room temperature and filtered.
The obtained residue was washed with 200 parts of water.
The residue was dried to obtain 6 parts of the compound represented by the formula (IbZ2-320).

<Identification of the compound represented by the formula (IbZ2-320)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ M-H] - 546
Exact Mass: 547

Example 23Z2
5 parts of 4,5-dibromophthalonitrile and 93 parts of 2-ethoxyethanol were mixed.
To this mixture was added a 25% sodium methoxide methanol solution containing 5 parts of 4,5-dibromophthalonitrile in moles of sodium methoxide.
The mixture was stirred at room temperature for 6 hours.
To this mixture, a compound represented by the formula (ppp1) having a molar number 6 times the number of moles of 5 parts of 4,5-dibromophthalonitrile was added, and the mixture was stirred at 90 ° C. for 65 hours and then 10 at 100 ° C. Stirred for hours.
This mixture was mixed with 300 parts of water and 21 parts of acetic acid.
The mixture was filtered to give 10 parts of residue.
This residue was mixed with 120 parts of methanol and 10 parts of acetic acid.
The mixture was filtered to give 5.5 parts of a residue containing the compound represented by the formula (IbZ2-315).

<Identification of the compound represented by the formula (IbZ2-315)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 664
Exact Mass: 663

5.5 parts of the residue containing the compound represented by the formula (IbZ2-315), 45 parts of trifluoroacetic acid and 80 parts of dichloromethane were mixed and stirred at room temperature for 16 hours.
The solvent was distilled off from this mixture to obtain 6 parts of a residue.
This residue and 79 parts of methanol were mixed.
The mixture was filtered to give 4 parts of residue.
This residue was mixed with 0.24 part of lithium hydroxide, 36 parts of tetrahydrofuran and 12 parts of water, and stirred at room temperature for 6 hours.
Tetrahydrofuran was distilled off from this mixture using an evaporator. Water and 1.5N hydrochloric acid were added to the resulting mixture.
The mixture was filtered to give 3.5 parts of residue.
This residue and 40 parts of methanol were mixed.
The mixture was filtered and the residue was washed with 13 parts of hexane to give 3 parts of residue.
2.8 parts of this residue and 33 parts of dimethyl sulfoxide were mixed and stirred at 70 ° C. for 20 minutes.
The mixture was cooled to room temperature and filtered.
The obtained residue was washed with 40 parts of methanol and then with 50 parts of water.
The residue was dried to obtain 1.8 parts of the compound represented by the formula (IbZ2-706).

<Identification of the compound represented by the formula (IbZ2-706)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ M-H] - 550
Exact Mass: 551

Example 24Z2
13 parts of 4,5-dichlorophthalonitrile and 160 parts of methanol were mixed.
While keeping the mixture at 0 ° C., a 25% sodium methoxide methanol solution containing sodium methoxide in a molar number 0.5 times the molar number of 13 parts of 4,5-dichlorophthalonitrile was added.
The mixture was stirred at 0 ° C. for 5 hours.
To this mixture was added 16 parts of acetic acid and a compound represented by the formula (ppp1) having a molar number of 4.4 times the number of moles of 13 parts of 4,5-dichlorophthalonitrile, and the mixture was stirred at 75 ° C. for 7 days.
To this mixture was added a compound represented by the formula (ppp1) having three times the number of moles of 14 parts of acetic acid and 13 parts of 4,5-dichlorophthalonitrile, and the mixture was stirred at 75 ° C. for 11 days.
The mixture was filtered.
The obtained residue was washed with 320 parts of methanol to obtain 26 parts of the residue.
13 parts of this residue, 100 parts of methanol, 16 parts of acetic acid, and 26.3 parts of the compound represented by the formula (ppp1) were mixed and stirred at 75 ° C. for 48 hours.
The mixture was filtered.
The obtained residue was washed with 40 parts of methanol to obtain 12 parts of a residue containing the compound represented by the formula (IbZ2-316).

<Identification of the compound represented by the formula (IbZ2-316)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 576
Exact Mass: 575

12 parts of the residue containing the compound represented by the formula (IbZ2-316), 160 parts of dichloromethane and 130 parts of trifluoroacetic acid were mixed and stirred at room temperature for 16 hours.
The mixture was filtered to give 6.2 parts of residue.
The residue and 73 parts of acetic acid were mixed and stirred at 80 ° C. for 2 hours.
The mixture was filtered to give 5.3 parts of residue.
The residue and 60 parts of water were mixed and stirred at 80 ° C. for 2 hours.
The mixture was filtered and the obtained residue was dried to give 5 parts of the compound represented by the formula (IbZ2-389).

<Identification of the compound represented by the formula (IbZ2-389)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ M-H] - 462
Exact Mass: 463

Example 101Z2
Pigment: C.I. I. Pigment Green 58 60 copies,
Acrylic pigment dispersant 8.1 parts,
A pigment dispersion (colorant (A1Z2) -containing liquid) in which 73 parts of a resin (B): resin B5 solution and 290 parts of a solvent (E): propylene glycol monomethyl ether acetate are mixed and the pigment is dispersed using a bead mill is used. Prepared.
Separately
Colorant (AZ2): Mixture of the compound represented by the formula (IaZ2-39) obtained in Example 1Z2, the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) 50 Department,
Dispersant (BYK-LPN6919; manufactured by Big Chemie Japan Co., Ltd.) 58 copies,
A compound represented by the formula (IaZ2-39) obtained in Example 1Z2 by mixing 93 parts of a resin (B): a resin B3 solution and 800 parts of a solvent (E): propylene glycol monomethyl ether acetate and using a bead mill. , A mixture of a compound represented by the formula (IaZ2-38) and a compound represented by the formula (IaZ2-149) was dispersed to obtain a colored composition.
Then
Total amount of the obtained pigment dispersion liquid (colorant (A1Z2) -containing liquid);
400 parts of the obtained coloring composition;
Resin (B): 45 parts of resin B1 solution;
Polymerizable compound (C): Dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kayaku Co., Ltd.) 25 parts;
Polymerization Initiator (D): N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure® OXE-01; manufactured by BASF Ltd.) 15 parts;
Solvent (E): 86 parts of propylene glycol monomethyl ether acetate; Leveling agent: Polyether-modified silicone oil (Tore Silicone SH8400; manufactured by Toray Dow Corning Co., Ltd.) 0.12 parts;
Was mixed to obtain a colored curable composition 1Z2.

[Making a colored pattern]
A color-curable composition 1Z2 was applied onto a 2-inch square glass substrate (Eagle XG; manufactured by Corning Inc.) by a spin coating method, and then prebaked at 100 ° C. for 3 minutes to form a color-curable composition layer. After cooling, the distance between the substrate on which the colored curable composition layer was formed and the quartz glass photomask was set to 200 μm, and using an exposure machine (TME-150RSK; manufactured by Topcon Co., Ltd.), 80 mJ / in an air atmosphere. Exposure was performed with an exposure amount of cm ^{2 (based on 365 nm).} still,
As the photomask, a photomask having a line-and-space pattern of 100 μm formed was used. The colored curable composition layer after exposure was developed by immersing it in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ° C. for 70 seconds, and washed with water. This color-curable composition layer was post-baked at 230 ° C. for 30 minutes to obtain a color pattern.

[Phase difference value measurement]
A color-curable composition 1Z2 was applied onto a 2-inch square glass substrate (Eagle XG; manufactured by Corning Inc.) by a spin coating method, and then prebaked at 100 ° C. for 3 minutes to form a color-curable composition layer. ^{After cooling, the colored curable composition layer was exposed to an exposure amount of 80 mJ / cm 2} (based on 365 nm) in an air atmosphere using an exposure machine (TME-150RSK; manufactured by Topcon Corporation). The colored curable composition layer after exposure was developed by immersing it in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ° C. for 70 seconds, and washed with water. The colored curable composition layer was post-baked at 230 ° C. for 30 minutes to obtain a colored coating film.
The film thickness of the obtained colored coating film was measured using DEKTAK3 (manufactured by Nippon Vacuum Technology Co., Ltd.).
Using an ellipsometer (M-220 type spectroscopic ellipsometer; manufactured by JASCO Corporation), the phase difference value at a tilt angle of 45 ° of this colored coating film was measured. Light having a wavelength of 550 nm was used for the phase difference value measurement. The results are shown in Table 44Z2.

Example 102 Z2
A mixture of the compound represented by the formula (IaZ2-39) obtained in Example 1Z2, the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) was obtained in Example 2Z2. A color-curable composition 2Z2 was obtained in the same manner as in Example 101Z2 except that the compound represented by the formula (IbZ2-125) was replaced, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 44Z2.

Example 103Z2
A mixture of the compound represented by the formula (IaZ2-39) obtained in Example 1Z2, the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) was obtained in Example 3Z2. A color curable composition 3Z2 was obtained in the same manner as in Example 101Z2 except that the compound represented by the formula (IbZ2-126) was replaced, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 44Z2.

Example 104Z2
A mixture of the compound represented by the formula (IaZ2-39) obtained in Example 1Z2, the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) was obtained in Example 4Z2. A color curable composition 4Z2 was obtained in the same manner as in Example 101Z2 except that the compound represented by the formula (IbZ2-148) was replaced, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 44Z2.

Example 105Z2
A mixture of the compound represented by the formula (IaZ2-39) obtained in Example 1Z2, the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) was obtained in Example 5Z2. A coloring curable composition 5Z2 was obtained in the same manner as in Example 101Z2 except that the compound represented by the formula (IbZ2-1149) was used, and a coloring pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 44Z2.

Example 106Z2
A mixture of the compound represented by the formula (IaZ2-39) obtained in Example 1Z2, the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) was obtained in Example 6Z2. A color curable composition 6Z2 was obtained in the same manner as in Example 101Z2 except that the compound represented by the formula (IbZ2-128) was replaced, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 44Z2.

Example 107Z2
C. I. Pigment Green 58 to C.I. I. A color-curable composition 7Z2 was obtained in the same manner as in Example 101Z2 except that it was replaced with Pigment Green 7, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 44Z2.

Example 108Z2
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 7, a mixture of the compound represented by the formula (IaZ2-39) obtained in Example 1Z2, the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) is used. A coloring curable composition 8Z2 was obtained in the same manner as in Example 101Z2 except that the compound represented by the formula (IbZ2-125) obtained in Example 2Z2 was replaced, and a coloring pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 44Z2.

Example 109Z2
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 7, a mixture of the compound represented by the formula (IaZ2-39) obtained in Example 1Z2, the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) is used. A coloring curable composition 9Z2 was obtained in the same manner as in Example 101Z2 except that the compound represented by the formula (IbZ2-126) obtained in Example 3Z2 was replaced, and a coloring pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 44Z2.

Example 110Z2
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 7, a mixture of the compound represented by the formula (IaZ2-39) obtained in Example 1Z2, the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) is used. A coloring curable composition 10Z2 was obtained in the same manner as in Example 101Z2 except that the compound represented by the formula (IbZ2-148) obtained in Example 4Z2 was replaced, and a coloring pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 44Z2.

Example 111Z2
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 7, a mixture of the compound represented by the formula (IaZ2-39) obtained in Example 1Z2, the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) is used. A coloring curable composition 11Z2 was obtained in the same manner as in Example 101Z2 except that the compound represented by the formula (IbZ2-1149) obtained in Example 5Z2 was replaced, and a coloring pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 44Z2.

Example 112Z2
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 7, a mixture of the compound represented by the formula (IaZ2-39) obtained in Example 1Z2, the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) is used. A coloring curable composition 12Z2 was obtained in the same manner as in Example 101Z2 except that the compound represented by the formula (IbZ2-128) obtained in Example 6Z2 was replaced, and a coloring pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 44Z2.

Example 113Z2
C. I. Pigment Green 58 to C.I. I. A coloring curable composition 13Z2 was obtained in the same manner as in Example 101Z2 except that the pigment green 59 was replaced, and a coloring pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 44Z2.

Example 114Z2
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 59, a mixture of the compound represented by the formula (IaZ2-39) obtained in Example 1Z2, the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) is used. A coloring curable composition 14Z2 was obtained in the same manner as in Example 101Z2 except that the compound represented by the formula (IbZ2-125) obtained in Example 2Z2 was replaced, and a coloring pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 44Z2.

Example 115Z2
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 59, a mixture of the compound represented by the formula (IaZ2-39) obtained in Example 1Z2, the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) is used. A coloring curable composition 15Z2 was obtained in the same manner as in Example 101Z2 except that the compound represented by the formula (IbZ2-126) obtained in Example 3Z2 was replaced, and a coloring pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 44Z2.

Example 116Z2
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 59, a mixture of the compound represented by the formula (IaZ2-39) obtained in Example 1Z2, the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) is used. A coloring curable composition 16Z2 was obtained in the same manner as in Example 101Z2 except that the compound represented by the formula (IbZ2-148) obtained in Example 4Z2 was replaced, and a coloring pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 44Z2.

Example 117Z2
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 59, a mixture of the compound represented by the formula (IaZ2-39) obtained in Example 1Z2, the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) is used. A coloring curable composition 17Z2 was obtained in the same manner as in Example 101Z2, except that the compound represented by the formula (IbZ2-1149) obtained in Example 5Z2 was replaced, and a coloring pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 44Z2.

Example 118Z2
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 59, a mixture of the compound represented by the formula (IaZ2-39) obtained in Example 1Z2, the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) is used. A coloring curable composition 18Z2 was obtained in the same manner as in Example 101Z2 except that the compound represented by the formula (IbZ2-128) obtained in Example 6Z2 was replaced, and a coloring pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 44Z2.

Comparative Example 1Z2
C.I., C.I. I. A color-curable composition C1Z2 was obtained in the same manner as in Example 101Z2 except that it was replaced with Pigment Yellow 185, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 44Z2.

Comparative Example 2Z2
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 7, a mixture of the compound represented by the formula (IaZ2-39) obtained in Example 1Z2, the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) is used. C. I. A color-curable composition C2Z2 was obtained in the same manner as in Example 101Z2 except that it was replaced with Pigment Yellow 185, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 44Z2.

Comparative Example 3Z2
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 59, a mixture of the compound represented by the formula (IaZ2-39) obtained in Example 1Z2, the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) is used. C. I. A color-curable composition C3Z2 was obtained in the same manner as in Example 101Z2 except that it was replaced with Pigment Yellow 185, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 44Z2.

Example 119Z2
Pigment: C.I. I. Pigment Green 58 60 copies,
Acrylic pigment dispersant 8.1 parts,
A pigment dispersion (colorant (A1Z2) -containing liquid) in which 73 parts of a resin (B): resin B5 solution and 290 parts of a solvent (E): propylene glycol monomethyl ether acetate are mixed and the pigment is dispersed using a bead mill is used. Prepared.
Separately
Colorant (AZ2): Mixture of the compound represented by the formula (IaZ2-39) obtained in Example 1Z2, the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) 50 Department,
Dispersant solution (solid content 60%) 58 parts,
A compound represented by the formula (IaZ2-39) obtained in Example 1Z2 by mixing 93 parts of a resin (B): a resin B3 solution and 800 parts of a solvent (E): propylene glycol monomethyl ether acetate and using a bead mill. , A mixture of a compound represented by the formula (IaZ2-38) and a compound represented by the formula (IaZ2-149) was dispersed to obtain a colored composition.
Then
Total amount of the obtained pigment dispersion liquid (colorant (A1Z2) -containing liquid);
400 parts of the obtained coloring composition;
Resin (B): 45 parts of resin B1 solution;
Polymerizable compound (C): Dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kayaku Co., Ltd.) 25 parts;
Polymerization Initiator (D): N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure® OXE-01; manufactured by BASF Ltd.) 15 parts;
Solvent (E): 86 parts of propylene glycol monomethyl ether acetate; Leveling agent: Polyether-modified silicone oil (Tore Silicone SH8400; manufactured by Toray Dow Corning Co., Ltd.) 0.12 parts;
Was mixed to obtain a colored curable composition 19Z2.

A coloring pattern was produced in the same manner as in Example 101Z2 except that the coloring curable composition 19Z2 was used instead of the coloring curable composition 1Z2. Further, a colored coating film was obtained in the same manner as in Example 101Z2 except that the coloring curable composition 19Z2 was used instead of the coloring curable composition 1Z2, and the film thickness measurement and the retardation value measurement were performed. The results are shown in Table 45Z2.

Example 120Z2 to Example 138Z2
A mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in Example 1Z2 is referred to as "colorant" in Table 45Z2. A coloring pattern was obtained in the same manner as in Example 119Z2, except that the colorant was replaced with the colorant shown in the column. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 45Z2.

Example 139Z2 to Example 158Z2
A mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in Example 1Z2 is referred to as "colorant" in Table 46Z2. Instead of the compounds shown in the column, C.I. I. Pigment Green 58 to C.I. I. A coloring pattern was obtained in the same manner as in Example 119Z2 except that the pigment green 7 was replaced. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 46Z2.

Example 159Z2 to Example 178Z2
A mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in Example 1Z2 is referred to as "colorant" in Table 47Z2. Instead of the compounds shown in the column, C.I. I. Pigment Green 58 to C.I. I. A coloring pattern was obtained in the same manner as in Example 119Z2 except that the pigment green 59 was replaced. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 47Z2.

In Table 45Z2, Table 46Z2, and Table 47Z2, the chemical formulas of the compounds represented by the formula (IaZ2-1) are shown.

In the examination of Example Z2, from the above results, in the colored coating film formed from the colored curable composition containing the compound of the present invention, C.I. I. It was found that the retardation value was smaller than that of the colored coating film formed from the colored curable composition containing Pigment Yellow 185.

[Example Z3]
Example 1Z3
10.3 parts of phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 44.8 parts of methanol were mixed.
While keeping the temperature at 20 to 25 ° C., 8.01 part of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) was added dropwise to the obtained mixture.
The resulting mixture was stirred at 20 ° C-25 ° C for 2 hours.
10 parts of methanol was added to the resulting mixture while keeping it at 20-25 ° C.
The resulting mixture was stirred at 20-25 ° C. for 2 hours.
To the obtained mixture, 7.49 parts of 2-cyanoacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 4.98 parts of acetic acid were added, and the obtained mixture was added to the mixture at 40 ° C. for 2 hours and 65 ° C. for 2 hours. Stirred.
To the obtained mixture, 11.3 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.), 6.53 parts of acetic acid and 160 parts of water were added, and the obtained mixture was added at 65 ° C. for 3 hours at room temperature. The mixture was stirred at 75 ° C. for 5 hours for 2 days.
At room temperature, 230 parts of methanol was added to the resulting mixture.
The obtained compound was filtered, and the obtained residue was washed once with 170 parts of methanol, twice with 400 parts of methanol, once with 1000 parts of water, and 11 times with 200 parts of methanol.
To the obtained residue, 641 parts of a 5% aqueous sodium hydroxide solution was added, and the mixture was stirred at room temperature.
The resulting mixture was filtered and the resulting residue was washed with 1000 parts of water.
To the obtained residue, 478 parts of water was added, and the mixture was stirred at room temperature.
The resulting mixture was filtered and the resulting residue was washed with 500 parts of water.
The obtained residue was dried to obtain 19.1 parts of the compound represented by the formula (IZ3-1).

<Identification of the compound represented by the formula (IZ3-1)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 324
Exact Mass: 323

Example 2Z3
It is carried out in the same manner as in Example 1Z3 except that phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) is replaced with 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.), and is represented by the formula (IZ3-19). Compound was obtained.

<Identification of the compound represented by the formula (IZ3-19)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 369
Exact Mass: 368

Example 3Z3
Except for replacing phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) with 4-tert-butylphthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.), the same procedure as in Example 1Z3 was carried out, and the formula (IZ3-6) was used. The compound represented was obtained.

<Identification of the compound represented by the formula (IZ3-6)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 380
Exact Mass: 379

Example 4Z3
10.3 parts of phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 44.8 parts of methanol were mixed.
While keeping the temperature at 20 to 25 ° C., 8.01 part of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) was added dropwise to the obtained mixture.
The resulting mixture was stirred at 20 ° C-25 ° C for 2 hours.
10 parts of methanol was added to the resulting mixture while keeping it at 20-25 ° C.
The resulting mixture was stirred at 20-25 ° C. for 2 hours.
To the obtained mixture, 7.49 parts of 2-cyanoacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 4.98 parts of acetic acid were added, and the obtained mixture was added to the mixture at 40 ° C. for 2 hours and 65 ° C. for 2 hours. Stirred.
To the obtained mixture, 11.3 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.), 6.53 parts of acetic acid and 160 parts of water were added, and the obtained mixture was added at 65 ° C. for 3 hours at room temperature. The mixture was stirred at 75 ° C. for 5 hours for 2 days.
At room temperature, 230 parts of methanol was added to the resulting mixture.
The obtained compound was filtered, and the obtained residue was washed once with 170 parts of methanol, twice with 400 parts of methanol, once with 1000 parts of water, and 11 times with 200 parts of methanol.
To the obtained residue, 641 parts of a 5% aqueous sodium hydroxide solution was added, and the mixture was stirred at room temperature.
The resulting mixture was filtered and the resulting residue was washed with 1000 parts of water.
To the obtained residue, 478 parts of water was added, and the mixture was stirred at room temperature.
The resulting mixture was filtered and the resulting residue was washed with 500 parts of water.
The obtained residue was purified by column chromatography to obtain a compound portion represented by the formula (IZ3-1).

<Identification of the compound represented by the formula (IZ3-1)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 324
Exact Mass: 323

Example 5Z3
10.0 parts of 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 149 parts of methanol were mixed. While keeping the temperature at 2 to 6 ° C., 5.86 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) was added dropwise to the obtained mixture over 20 minutes. The resulting mixture was stirred for 5 hours while keeping below 5 ° C.
While keeping the obtained mixture at 5 ° C. or lower, 5.79 parts of acetic acid, 4.86 parts of 2-cyanoacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.), and 74 parts of methanol were added. The resulting mixture was stirred at 65 ° C. for 3 days.
To the obtained mixture, 2.88 parts of acetic acid and 2.43 parts of 2-cyanoacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) were added.
The resulting mixture was stirred at 65 ° C. for 3 days.
In addition to the methanol described above, a total of 140 parts of methanol was added up to this point.
To the obtained mixture, 24.0 parts of acetic acid, 15.3 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.) and 363 parts of water were added, and the mixture was stirred at 65 ° C. for 9 days.
The obtained mixture was solvent-distilled off by a rotary evaporator, and the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ3-19).

<Identification of the compound represented by the formula (IZ3-19)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 369
Exact Mass: 368

Example 6Z3
10.0 parts of 4-tert-butyl phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 84 parts of methanol were mixed. A mixture of 8.15 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 73 parts of methanol was added dropwise to the obtained mixture at 5 ° C. or lower over 1 hour. The resulting mixture was stirred at 5-20 ° C. for 2 days.
At 10 to 20 ° C., 5.42 parts of acetic acid and 4.56 parts of 2-cyanoacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) were added to the obtained mixture. The resulting mixture was stirred at 65 ° C. for 3 days.
To the obtained mixture, 2.69 parts of acetic acid and 2.28 of 2-cyanoacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) were added, and the mixture was stirred at 65 ° C. for 3 days.
In addition to the methanol described above, a total of 206 parts of methanol was added up to this point.
To the obtained mixture, 5.36 parts of acetic acid, 7.25 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.) and 363 parts of water were added, and the mixture was stirred at 65 ° C. for 9 days.
The obtained mixture was solvent-distilled off by a rotary evaporator, and the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ3-6).

<Identification of the compound represented by the formula (IZ3-6)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 380
Exact Mass: 379

Example 7Z3
5.0 parts of 4,5-dichlorophthalonitrile and 62 parts of methanol were mixed.
While keeping the mixture at 5 ° C. or lower, a 25% sodium methoxide methanol solution containing 5.0 times the number of moles of 5.0 parts of 4,5-dichlorophthalonitrile of sodium methoxide was added.
The mixture was stirred at 5 ° C. and below for 5 hours.
2-Cyanoacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) and acetic acid 6 have 1.5 times the number of moles of 5.0 parts of 4,5-dichlorophthalonitrile in this mixture while maintaining 5 ° C. or lower. . One copy was added.
The mixture was stirred at 65 ° C. for 3 days.
This mixture was mixed with 4.2 parts of acetic acid, 5.2 parts of barbituric acid, 500 parts of methanol and 562 parts of water, and stirred at 65 ° C. for 9 days.
After distilling off the solvent of this mixture with a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ3-8).

<Identification of the compound represented by the formula (IZ3-8)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 392
Exact Mass: 391

Example 101Z3
Pigment: C.I. I. Pigment Green 58 60 copies,
Acrylic pigment dispersant 8.1 parts,
Resin (B): 73 parts of resin B5 solution,
And solvent (E): 290 parts of propylene glycol monomethyl ether acetate was mixed, and a pigment dispersion liquid (colorant (A1Z3) -containing liquid) in which pigments were dispersed was prepared using a bead mill.
Separately
Colorant (AZ3): 50 parts of the compound represented by the formula (IZ3-1) obtained in Example 1Z3,
Dispersant (BYK-LPN6919; manufactured by Big Chemie Japan Co., Ltd.) 58 copies,
Resin (B): 93 parts of resin B3 solution,
And solvent (E): 800 parts of propylene glycol monomethyl ether acetate was mixed, and the compound represented by the formula (IZ3-1) obtained in Example 1Z3 was dispersed using a bead mill to obtain a colored composition.
Then
Total amount of the obtained pigment dispersion liquid (colorant (A1Z3) -containing liquid);
400 parts of the obtained coloring composition;
Resin (B): 45 parts of resin B1 solution;
Polymerizable compound (C): Dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kayaku Co., Ltd.) 25 parts;
Polymerization Initiator (D): N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure® OXE-01; manufactured by BASF Ltd.) 15 parts;
Solvent (E): 86 parts of propylene glycol monomethyl ether acetate;
And leveling agent: Polyether-modified silicone oil (Toray Silicone SH8400; manufactured by Toray Dow Corning Co., Ltd.) 0.12 parts;
Was mixed to obtain a colored curable composition 1Z3.

[Making a colored pattern]
A color-curable composition 1Z3 was applied onto a 2-inch square glass substrate (Eagle XG; manufactured by Corning Inc.) by a spin coating method, and then prebaked at 100 ° C. for 3 minutes to form a color-curable composition layer. After cooling, the distance between the substrate on which the colored curable composition layer was formed and the quartz glass photomask was set to 200 μm, and using an exposure machine (TME-150RSK; manufactured by Topcon Co., Ltd.), 80 mJ / in an air atmosphere. Exposure was performed with an exposure amount of cm ^{2 (based on 365 nm).} As the photomask, a photomask having a line-and-space pattern of 100 μm formed was used. The colored curable composition layer after exposure was developed by immersing it in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ° C. for 70 seconds, and washed with water. This color-curable composition layer was post-baked at 230 ° C. for 30 minutes to obtain a color pattern.

[Phase difference value measurement]
A color-curable composition 1Z3 was applied onto a 2-inch square glass substrate (Eagle XG; manufactured by Corning Inc.) by a spin coating method, and then prebaked at 100 ° C. for 3 minutes to form a color-curable composition layer. ^{After cooling, the colored curable composition layer was exposed to an exposure amount of 80 mJ / cm 2} (based on 365 nm) in an air atmosphere using an exposure machine (TME-150RSK; manufactured by Topcon Corporation). The colored curable composition layer after exposure was developed by immersing it in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ° C. for 70 seconds, and washed with water. The colored curable composition layer was post-baked at 230 ° C. for 30 minutes to obtain a colored coating film.
The film thickness of the obtained colored coating film was measured using DEKTAK3 (manufactured by Nippon Vacuum Technology Co., Ltd.).
Using an ellipsometer (M-220 type spectroscopic ellipsometer; manufactured by JASCO Corporation), the phase difference value at a tilt angle of 45 ° of this colored coating film was measured. Light having a wavelength of 550 nm was used for the phase difference value measurement. The results are shown in Table 7Z3.

Example 102Z3
Color curing in the same manner as in Example 101Z3, except that the compound represented by the formula (IZ3-1) obtained in Example 1Z3 is replaced with the compound represented by the formula (IZ3-19) obtained in Example 2Z3. The sex composition 2Z3 was obtained to obtain a coloring pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z3.

Example 103Z3
Color curing in the same manner as in Example 101Z3, except that the compound represented by the formula (IZ3-1) obtained in Example 1Z3 is replaced with the compound represented by the formula (IZ3-6) obtained in Example 3Z3. The sex composition 3Z3 was obtained to obtain a coloring pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z3.

Example 104Z3
C. I. Pigment Green 58 to C.I. I. A color-curable composition 4Z3 was obtained in the same manner as in Example 101Z3 except that it was replaced with Pigment Green 7, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z3.

Example 105Z3
C. I. Pigment Green 58 to C.I. I. Example 101Z3, except that the compound represented by the formula (IZ3-1) obtained in Example 1Z3 is replaced with the compound represented by the formula (IZ3-19) obtained in Example 2Z3 instead of Pigment Green 7. Similarly, a coloring curable composition 5Z3 was obtained to obtain a coloring pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z3.

Example 106Z3
C. I. Pigment Green 58 to C.I. I. Example 101Z3, except that the compound represented by the formula (IZ3-1) obtained in Example 1Z3 is replaced with the compound represented by the formula (IZ3-6) obtained in Example 3Z3 instead of Pigment Green 7. Similarly, a coloring curable composition 6Z3 was obtained to obtain a coloring pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z3.

Example 107Z3
C. I. Pigment Green 58 to C.I. I. A color-curable composition 7Z3 was obtained in the same manner as in Example 101Z3 except that the pigment green 59 was replaced, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z3.

Example 108Z3
C. I. Pigment Green 58 to C.I. I. Example 101Z3, except that the compound represented by the formula (IZ3-1) obtained in Example 1Z3 is replaced with the compound represented by the formula (IZ3-19) obtained in Example 2Z3 instead of Pigment Green 59. Similarly, a coloring curable composition 8Z3 was obtained to obtain a coloring pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z3.

Example 109Z3
C. I. Pigment Green 58 to C.I. I. Example 101Z3, except that the compound represented by the formula (IZ3-1) obtained in Example 1Z3 is replaced with the compound represented by the formula (IZ3-6) obtained in Example 3Z3 instead of Pigment Green 59. Similarly, a coloring curable composition 9Z3 was obtained to obtain a coloring pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z3.

Comparative Example 1Z3
The compound represented by the formula (IZ3-1) obtained in Example 1Z3 was designated as C.I. I. A color-curable composition C1Z3 was obtained in the same manner as in Example 101Z3 except that it was replaced with Pigment Yellow 185, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z3.

Comparative Example 2Z3
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 7, a compound represented by the formula (IZ3-1) obtained in Example 1Z3 was used as C.I. I. A color-curable composition C2Z3 was obtained in the same manner as in Example 101Z3 except that it was replaced with Pigment Yellow 185, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z3.

Comparative Example 3Z3
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 59, a compound represented by the formula (IZ3-1) obtained in Example 1Z3 was used as C.I. I. A color-curable composition C3Z3 was obtained in the same manner as in Example 101Z3 except that it was replaced with Pigment Yellow 185, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z3.

Example 110Z3
Pigment: C.I. I. Pigment Green 58 60 copies,
Acrylic pigment dispersant 8.1 parts,
Resin (B): 73 parts of resin B5 solution,
And solvent (E): 290 parts of propylene glycol monomethyl ether acetate was mixed, and a pigment dispersion liquid (colorant (A1Z3) -containing liquid) in which pigments were dispersed was prepared using a bead mill.
Separately
Colorant (AZ3): 50 parts of the compound represented by the formula (IZ3-1),
Dispersant solution (solid content 60%) 58 parts,
Resin (B): 93 parts of resin B3 solution,
And solvent (E): 800 parts of propylene glycol monomethyl ether acetate was mixed, and the compound represented by the formula (IZ3-1) was dispersed using a bead mill to obtain a colored composition.
Then
Total amount of the obtained pigment dispersion liquid (colorant (A1Z3) -containing liquid);
400 parts of the obtained coloring composition;
Resin (B): 45 parts of resin B1 solution;
Polymerizable compound (C): Dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kayaku Co., Ltd.) 25 parts;
Polymerization Initiator (D): N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure® OXE-01; manufactured by BASF Ltd.) 15 parts;
Solvent (E): 86 parts of propylene glycol monomethyl ether acetate;
And leveling agent: Polyether-modified silicone oil (Toray Silicone SH8400; manufactured by Toray Dow Corning Co., Ltd.) 0.12 parts;
Was mixed to obtain a color curable composition 10Z3.

A coloring pattern was produced in the same manner as in Example 101Z3 except that the coloring curable composition 10Z3 was used instead of the coloring curable composition 1Z3. Further, a colored coating film was obtained in the same manner as in Example 101Z3 except that the coloring curable composition 10Z3 was used instead of the coloring curable composition 1Z3, and the film thickness measurement and the retardation value measurement were performed. The results are shown in Table 8Z3.

Example 111Z3 to Example 113Z3
A coloring pattern was obtained in the same manner as in Example 110Z3, except that the compound represented by the formula (IZ3-1) was replaced with the coloring agent shown in the “Coloring agent” column of Table 8Z3. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z3.

Examples 114Z3 to 117Z3
The compound represented by the formula (IZ3-1) was replaced with the compound shown in the “Colorant” column of Table 8Z3, and C.I. I. Pigment Green 58 to C.I. I. A coloring pattern was obtained in the same manner as in Example 110Z3 except that the pigment green 7 was replaced. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z3.

Examples 118Z3 to 121Z3
The compound represented by the formula (IZ3-1) was replaced with the compound shown in the “Colorant” column of Table 8Z3, and C.I. I. Pigment Green 58 to C.I. I. A coloring pattern was obtained in the same manner as in Example 110Z3 except that the pigment green 59 was replaced. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z3.

In Example Z3, from the above results, in the colored coating film formed from the colored curable composition containing the compound of the present invention, C.I. I. It was found that the retardation value was smaller than that of the colored coating film formed from the colored curable composition containing Pigment Yellow 185.

[Example Z4]
Example 1Z4
20.5 parts of phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 171 parts of methanol were mixed.
While keeping the temperature at 5 ° C., a mixture of 23.9 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 215 parts of methanol was added dropwise to the obtained mixture over 1 hour and 20 minutes. bottom.
The resulting mixture was stirred at 2-6 ° C. for 7 hours.
To the obtained mixture, 15.6 parts of acetic acid, 17.9 parts of 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 118 parts of methanol were added, and the mixture was added at 40 ° C. for 15 hours for 65 hours. The mixture was stirred at ° C. for 7 hours.
To the obtained mixture, 7.82 parts of acetic acid, 8.97 parts of 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 80 parts of methanol were added, and the mixture was added at 40 ° C. for 17 hours for 65 hours. The mixture was stirred at ° C. for 4 hours.
To the obtained mixture, 12.6 parts of acetic acid, 14.3 parts of 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 104 parts of methanol were added, and the mixture was added at 40 ° C. for 16 hours for 60 hours. The mixture was stirred at ° C. for 9 hours.
To the obtained mixture, 6.32 parts of acetic acid, 7.19 parts of 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 40 parts of methanol were added, and the mixture was added at 60 ° C. for 3 hours at room temperature. Was stirred for 59 hours.
To the obtained mixture, 15.7 parts of acetic acid, 20.5 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.), 16 parts of methanol and 744 parts of water were added, and the mixture was stirred at 60 ° C. for 24 hours.
The resulting mixture was filtered and the residue was washed with 50% aqueous methanol solution.
The obtained residue was dried under reduced pressure at 60 ° C. to obtain 43.1 parts of the compound represented by the formula (IZ4-1).

<Identification of the compound represented by the formula (IZ4-1)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 352
Exact Mass: 351

Example 2 Z4
Similar to Example 1Z4 except that 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) is replaced with 2-cyano-N, N-diethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.). This was carried out to obtain a compound represented by the formula (IZ4-2).

<Identification of the compound represented by the formula (IZ4-2)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 380
Exact Mass: 379

Example 3Z4
It is carried out in the same manner as in Example 1Z4 except that phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) is replaced with 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.), and is represented by the formula (IZ4-79). Compound was obtained.

<Identification of the compound represented by the formula (IZ4-79)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 397
Exact Mass: 396

Example 4Z4
Phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) is replaced with 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.), and 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) is replaced by 2. A compound represented by the formula (IZ4-80) was obtained in the same manner as in Example 1Z4 except that it was replaced with -cyano-N, N-diethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.).

<Identification of the compound represented by the formula (IZ4-80)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 425
Exact Mass: 424

Example 5Z4
Except for replacing phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) with 4-tert-butylphthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.), the same procedure as in Example 1Z4 was carried out, and the formula (IZ4-40) was used. The compound represented was obtained.

<Identification of the compound represented by the formula (IZ4-40)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 408
Exact Mass: 407

Example 6Z4
2-Cyano-N, N-dimethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) instead of 4-tert-butylphthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) instead of phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) Was replaced with 2-cyano-N, N-diethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) in the same manner as in Example 1Z4 to obtain a compound represented by the formula (IZ4-41).

<Identification of the compound represented by the formula (IZ4-41)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 436
Exact Mass: 435

Example 7Z4
20.5 parts of phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 171 parts of methanol were mixed.
While keeping the temperature at 2 to 5 ° C., a mixture of 23.9 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 215 parts of methanol was added to the obtained mixture over 1 hour and 20 minutes. And dropped.
The resulting mixture was stirred at 2-6 ° C. for 7 hours.
To the obtained mixture, 15.6 parts of acetic acid, 17.9 parts of 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 46.9 parts of methanol were added.
In addition to the methanol described above, a total of 71 parts of methanol was added up to this point.
The resulting mixture was stirred at 40 ° C. for 15 hours and at 65 ° C. for 7 hours.
To the obtained mixture, 7.82 parts of acetic acid, 8.97 parts of 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 80 parts of methanol were added, and the mixture was added at 40 ° C. for 17 hours for 65 hours. The mixture was stirred at ° C. for 4 hours.
To the obtained mixture, 12.6 parts of acetic acid, 14.3 parts of 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 104 parts of methanol were added, and the mixture was added at 40 ° C. for 16 hours for 60 hours. The mixture was stirred at ° C. for 9 hours.
To the obtained mixture, 6.32 parts of acetic acid, 7.19 parts of 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 40 parts of methanol were added, and the mixture was added at 60 ° C. for 3 hours at room temperature. Was stirred for 59 hours.
To the obtained mixture, 15.7 parts of acetic acid, 20.5 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.), 16 parts of methanol and 744 parts of water were added, and the mixture was stirred at 60 ° C. for 9 days.
The resulting mixture was filtered and the residue was washed with 50% aqueous methanol solution.
The obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ4-1).

<Identification of the compound represented by the formula (IZ4-1)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 352
Exact Mass: 351

Example 8Z4
10.0 parts of phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 83 parts of methanol were mixed.
While keeping the temperature at 2 to 5 ° C., 11.7 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 105 parts of methanol were added to the obtained mixture over 1 hour and 30 minutes. And dropped.
The resulting mixture was stirred at 2-6 ° C. for 7 hours.
To the obtained mixture, 7.62 parts of acetic acid, 10.9 parts of 2-cyano-N, N-diethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 140 parts of methanol were added.
In addition to the methanol described above, a total of 35 parts of methanol was added up to this point.
The resulting mixture was stirred at 65 ° C. for 3 days.
To the obtained mixture, 3.82 parts of acetic acid and 5.48 parts of 2-cyano-N, N-diethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) were added, and the mixture was stirred at 65 ° C. for 3 days.
To the obtained mixture, 7.65 parts of acetic acid, 10.0 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.) and 363 parts of water were added, and the mixture was stirred at 65 ° C. for 9 days.
After distilling off the solvent of the obtained mixture with a rotary evaporator, the obtained residue was purified by column chromatography and carried out in the same manner as in Example 1Z4 to obtain a compound represented by the formula (IZ4-2). ..

<Identification of the compound represented by the formula (IZ4-2)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 380
Exact Mass: 379

Example 9Z4
2.56 parts of 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 22 parts of methanol were mixed. 2.96 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) was added to the obtained mixture while keeping the temperature below 5 ° C. The resulting mixture was stirred for 3 hours while keeping below 5 ° C.
While keeping the obtained mixture at 5 ° C. or lower, 1.84 parts of 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 1.90 parts of acetic acid were added. The resulting mixture was stirred at 40 ° C. for 1 hour and at 65 ° C. for 1 hour.
To the obtained mixture, 2.09 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.), 2.48 parts of acetic acid, and 41 parts of water were added.
In addition to the methanol described above, a total of 24 parts of methanol was added up to this point.
The resulting mixture was stirred at 65 ° C. for 15 hours.
The obtained mixture was solvent-distilled off by a rotary evaporator, and the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ4-79).

<Identification of the compound represented by the formula (IZ4-79)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 397
Exact Mass: 396

Example 10Z4
10.0 parts of 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 149 parts of methanol were mixed. While keeping the temperature at 2 to 6 ° C., 5.86 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) was added dropwise to the obtained mixture over 20 minutes. The resulting mixture was stirred for 5 hours while keeping below 5 ° C.
While keeping the obtained mixture at 5 ° C. or lower, 5.79 parts of acetic acid, 8.10 parts of 2-cyano-N, N-diethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 74 parts of methanol were added. The resulting mixture was stirred at 65 ° C. for 3 days.
To the obtained mixture, 2.88 parts of acetic acid and 4.05 parts of 2-cyano-N, N-diethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) were added.
The resulting mixture was stirred at 65 ° C. for 3 days.
In addition to the methanol described above, a total of 140 parts of methanol was added up to this point.
To the obtained mixture, 24.0 parts of acetic acid, 15.3 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.) and 363 parts of water were added, and the mixture was stirred at 65 ° C. for 9 days.
The obtained mixture was solvent-distilled off by a rotary evaporator, and the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ4-80).

<Identification of the compound represented by the formula (IZ4-80)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 425
Exact Mass: 424

Example 11Z4
10.0 parts of 4-tert-butyl phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 84 parts of methanol were mixed. A mixture of 8.15 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 73 parts of methanol was added dropwise to the obtained mixture at 5 ° C. or lower over 1 hour. The resulting mixture was stirred at 5-20 ° C. for 2 days.
At 10 to 20 ° C., 5.42 parts of acetic acid and 6.09 parts of 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) were added to the obtained mixture. The resulting mixture was stirred at 65 ° C. for 3 days.
To the obtained mixture, 2.69 parts of acetic acid and 3.04 of 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) were added, and the mixture was stirred at 65 ° C. for 3 days.
In addition to the methanol described above, a total of 206 parts of methanol was added up to this point.
To the obtained mixture, 5.36 parts of acetic acid, 7.25 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.) and 363 parts of water were added, and the mixture was stirred at 65 ° C. for 9 days.
The obtained mixture was solvent-distilled off by a rotary evaporator, and the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ4-40).

<Identification of the compound represented by the formula (IZ4-40)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 408
Exact Mass: 407

Example 12Z4
10.0 parts of 4-tert-butyl phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 84 parts of methanol were mixed. A mixture of 8.15 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 73 parts of methanol was added dropwise to the obtained mixture at 5 ° C. or lower over 1 hour. The resulting mixture was stirred at 5-20 ° C. for 2 days.
At 10 to 20 ° C., 5.42 parts of acetic acid and 7.61 parts of 2-cyano-N, N-diethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) were added to the obtained mixture. The resulting mixture was stirred at 65 ° C. for 3 days.
To the obtained mixture, 2.69 parts of acetic acid and 3.80 of 2-cyano-N, N-diethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) were added, and the mixture was stirred at 65 ° C. for 3 days.
In addition to the methanol described above, a total of 206 parts of methanol was added up to this point.
To the obtained mixture, 5.36 parts of acetic acid, 7.25 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.) and 363 parts of water were added, and the mixture was stirred at 65 ° C. for 9 days.
The obtained mixture was solvent-distilled off by a rotary evaporator, and the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ4-41).

<Identification of the compound represented by the formula (IZ4-41)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 436
Exact Mass: 435

Example 13Z4
5.0 parts of 4,5-dichlorophthalonitrile and 62 parts of methanol were mixed.
While keeping the mixture at 5 ° C. or lower, a 25% sodium methoxide methanol solution containing 5.0 times the number of moles of 5.0 parts of 4,5-dichlorophthalonitrile of sodium methoxide was added.
The mixture was stirred at 5 ° C. and below for 5 hours.
2-Cyano-N, N-dimethylacetamide (Tokyo Chemical Industry Co., Ltd.) was added to this mixture at a temperature of 5 ° C. or lower, which was 1.5 times the number of moles of 5.0 parts of 4,5-dichlorophthalonitrile. ) And 6.1 parts of acetic acid were added.
The mixture was stirred at 65 ° C. for 3 days.
This mixture was mixed with 4.2 parts of acetic acid, 5.2 parts of barbituric acid, 500 parts of methanol and 562 parts of water, and stirred at 65 ° C. for 9 days.
After distilling off the solvent of this mixture with a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ4-321).

<Identification of the compound represented by the formula (IZ4-321)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 420
Exact Mass: 419

Example 101Z4
Pigment: C.I. I. Pigment Green 58 60 copies,
Acrylic pigment dispersant 8.1 parts,
A pigment dispersion (colorant (A1Z4) -containing liquid) in which 73 parts of a resin (B): resin B5 solution and 290 parts of a solvent (E): propylene glycol monomethyl ether acetate are mixed and the pigment is dispersed using a bead mill is used. Prepared.
Separately
Colorant (AZ4): 50 parts of the compound represented by the formula (IZ4-1) obtained in Example 1Z4,
Dispersant (BYK-LPN6919; manufactured by Big Chemie Japan Co., Ltd.) 58 copies,
Resin (B): 93 parts of resin B3 solution and solvent (E): 800 parts of propylene glycol monomethyl ether acetate are mixed, and a compound represented by the formula (IZ4-1) obtained in Example 1Z4 is used using a bead mill. Was dispersed to obtain a colored composition.
Then
Total amount of the obtained pigment dispersion liquid (colorant (A1Z4) -containing liquid);
400 parts of the obtained coloring composition;
Resin (B): 45 parts of resin B1 solution;
Polymerizable compound (C): Dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kayaku Co., Ltd.) 25 parts;
Polymerization Initiator (D): N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure® OXE-01; manufactured by BASF Ltd.) 15 parts;
Solvent (E): 86 parts of propylene glycol monomethyl ether acetate; and leveling agent: 0.12 parts of polyether-modified silicone oil (Torre Silicone SH8400; manufactured by Toray Dow Corning Co., Ltd.); Color curable composition 1Z4 Got

[Making a colored pattern]
A color-curable composition 1Z4 was applied onto a 2-inch square glass substrate (Eagle XG; manufactured by Corning Inc.) by a spin coating method, and then prebaked at 100 ° C. for 3 minutes to form a color-curable composition layer. After cooling, the distance between the substrate on which the colored curable composition layer was formed and the quartz glass photomask was set to 200 μm, and using an exposure machine (TME-150RSK; manufactured by Topcon Co., Ltd.), 80 mJ / in an air atmosphere. Exposure was performed with an exposure amount of cm ^{2 (based on 365 nm).} still,
As the photomask, a photomask having a line-and-space pattern of 100 μm formed was used. The colored curable composition layer after exposure was developed by immersing it in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ° C. for 70 seconds, and washed with water. This color-curable composition layer was post-baked at 230 ° C. for 30 minutes to obtain a color pattern.

[Phase difference value measurement]
A color-curable composition 1Z4 was applied onto a 2-inch square glass substrate (Eagle XG; manufactured by Corning Inc.) by a spin coating method, and then prebaked at 100 ° C. for 3 minutes to form a color-curable composition layer. ^{After cooling, the colored curable composition layer was exposed to an exposure amount of 80 mJ / cm 2} (based on 365 nm) in an air atmosphere using an exposure machine (TME-150RSK; manufactured by Topcon Corporation). The colored curable composition layer after exposure was developed by immersing it in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ° C. for 70 seconds, and washed with water. The colored curable composition layer was post-baked at 230 ° C. for 30 minutes to obtain a colored coating film.
The film thickness of the obtained colored coating film was measured using DEKTAK3 (manufactured by Nippon Vacuum Technology Co., Ltd.).
Using an ellipsometer (M-220 type spectroscopic ellipsometer; manufactured by JASCO Corporation), the phase difference value at a tilt angle of 45 ° of this colored coating film was measured. Light having a wavelength of 550 nm was used for the phase difference value measurement. The results are shown in Table 21Z4.

Example 102Z4
Color curing in the same manner as in Example 101Z4, except that the compound represented by the formula (IZ4-1) obtained in Example 1Z4 is replaced with the compound represented by the formula (IZ4-2) obtained in Example 2Z4. The sex composition 2Z4 was obtained to obtain a coloring pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 21Z4.

Example 103Z4
Color curing in the same manner as in Example 101Z4, except that the compound represented by the formula (IZ4-1) obtained in Example 1Z4 is replaced with the compound represented by the formula (IZ4-79) obtained in Example 3Z4. The sex composition 3Z4 was obtained to obtain a coloring pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 21Z4.

Example 104Z4
Color curing in the same manner as in Example 101Z4, except that the compound represented by the formula (IZ4-1) obtained in Example 1Z4 is replaced with the compound represented by the formula (IZ4-80) obtained in Example 4Z4. The sex composition 4Z4 was obtained to obtain a coloring pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 21Z4.

Example 105Z4
Color curing in the same manner as in Example 101Z4, except that the compound represented by the formula (IZ4-1) obtained in Example 1Z4 is replaced with the compound represented by the formula (IZ4-40) obtained in Example 5Z4. The sex composition 5Z4 was obtained to obtain a coloring pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 21Z4.

Example 106Z4
Color curing in the same manner as in Example 101Z4, except that the compound represented by the formula (IZ4-1) obtained in Example 1Z4 is replaced with the compound represented by the formula (IZ4-41) obtained in Example 6Z4. The sex composition 6Z4 was obtained to obtain a coloring pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 21Z4.

Example 107Z4
C. I. Pigment Green 58 to C.I. I. A color-curable composition 7Z4 was obtained in the same manner as in Example 101Z4 except that it was replaced with Pigment Green 7, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 21Z4.

Example 108Z4
C. I. Pigment Green 58 to C.I. I. Example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in Example 1Z4 is replaced with the compound represented by the formula (IZ4-2) obtained in Example 2Z4 instead of Pigment Green 7. Similarly, a coloring curable composition 8Z4 was obtained to obtain a coloring pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 21Z4.

Example 109Z4
C. I. Pigment Green 58 to C.I. I. Example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in Example 1Z4 is replaced with the compound represented by the formula (IZ4-79) obtained in Example 3Z4 instead of Pigment Green 7. Similarly, a coloring curable composition 9Z4 was obtained to obtain a coloring pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 21Z4.

Example 110Z4
C. I. Pigment Green 58 to C.I. I. Example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in Example 1Z4 is replaced with the compound represented by the formula (IZ4-80) obtained in Example 4Z4 instead of Pigment Green 7. Similarly, a coloring curable composition 10Z4 was obtained to obtain a coloring pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 21Z4.

Example 111Z4
C. I. Pigment Green 58 to C.I. I. Example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in Example 1Z4 is replaced with the compound represented by the formula (IZ4-40) obtained in Example 5Z4 instead of Pigment Green 7. Similarly, a coloring curable composition 11Z4 was obtained to obtain a coloring pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 21Z4.

Example 112Z4
C. I. Pigment Green 58 to C.I. I. Example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in Example 1Z4 is replaced with the compound represented by the formula (IZ4-41) obtained in Example 6Z4 instead of Pigment Green 7. Similarly, a coloring curable composition 12Z4 was obtained to obtain a coloring pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 21Z4.

Example 113Z4
C. I. Pigment Green 58 to C.I. I. A color-curable composition 13Z4 was obtained in the same manner as in Example 101Z4 except that it was replaced with Pigment Green 59, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 21Z4.

Example 114Z4
C. I. Pigment Green 58 to C.I. I. Example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in Example 1Z4 is replaced with the compound represented by the formula (IZ4-2) obtained in Example 2Z4 instead of Pigment Green 59. Similarly, a coloring curable composition 14Z4 was obtained to obtain a coloring pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 21Z4.

Example 115Z4
C. I. Pigment Green 58 to C.I. I. Example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in Example 1Z4 is replaced with the compound represented by the formula (IZ4-79) obtained in Example 3Z4 instead of the pigment green 59. Similarly, a coloring curable composition 15Z4 was obtained to obtain a coloring pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 21Z4.

Example 116Z4
C. I. Pigment Green 58 to C.I. I. Example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in Example 1Z4 is replaced with the compound represented by the formula (IZ4-80) obtained in Example 4Z4 instead of the pigment green 59. Similarly, a coloring curable composition 16Z4 was obtained to obtain a coloring pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 21Z4.

Example 117Z4
C. I. Pigment Green 58 to C.I. I. Example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in Example 1Z4 is replaced with the compound represented by the formula (IZ4-40) obtained in Example 5Z4 instead of the pigment green 59. Similarly, a coloring curable composition 17Z4 was obtained to obtain a coloring pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 21Z4.

Example 118Z4
C. I. Pigment Green 58 to C.I. I. Example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in Example 1Z4 is replaced with the compound represented by the formula (IZ4-41) obtained in Example 6Z4 instead of the pigment green 59. Similarly, a coloring curable composition 18Z4 was obtained to obtain a coloring pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 21Z4.

Comparative Example 1Z4
The compound represented by the formula (IZ4-1) obtained in Example 1Z4 was designated as C.I. I. A color-curable composition C1Z4 was obtained in the same manner as in Example 101Z4 except that it was replaced with Pigment Yellow 185, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 21Z4.

Comparative Example 2Z4
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 7, a compound represented by the formula (IZ4-1) obtained in Example 1Z4 was used as C.I. I. A color-curable composition C2Z4 was obtained in the same manner as in Example 101Z4 except that it was replaced with Pigment Yellow 185, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 21Z4.

Comparative Example 3Z4
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 59, a compound represented by the formula (IZ4-1) obtained in Example 1Z4 was used as C.I. I. A color-curable composition C3Z4 was obtained in the same manner as in Example 101Z4 except that it was replaced with Pigment Yellow 185, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 21Z4.

Example 119Z4
Pigment: C.I. I. Pigment Green 58 60 copies,
Acrylic pigment dispersant 8.1 parts,
A pigment dispersion (colorant (A1Z4) -containing liquid) in which 73 parts of a resin (B): resin B5 solution and 290 parts of a solvent (E): propylene glycol monomethyl ether acetate are mixed and the pigment is dispersed using a bead mill is used. Prepared.
Separately
Colorant (AZ4): 50 parts of the compound represented by the formula (IZ4-1),
Dispersant solution (solid content 60%) 58 parts,
Resin (B): 93 parts of resin B3 solution and solvent (E): 800 parts of propylene glycol monomethyl ether acetate are mixed, and the compound represented by the formula (IZ4-1) is dispersed using a bead mill to form a coloring composition. I got something.
Then
Total amount of the obtained pigment dispersion liquid (colorant (A1Z4) -containing liquid);
400 parts of the obtained coloring composition;
Resin (B): 45 parts of resin B1 solution;
Polymerizable compound (C): Dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kayaku Co., Ltd.) 25 parts;
Polymerization Initiator (D): N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure® OXE-01; manufactured by BASF Ltd.) 15 parts;
Solvent (E): 86 parts of propylene glycol monomethyl ether acetate; and leveling agent: 0.12 parts of polyether-modified silicone oil (Torre Silicone SH8400; manufactured by Toray Dow Corning Co., Ltd.); Color curable composition 19Z4 Got

A coloring pattern was produced in the same manner as in Example 101Z4 except that the coloring curable composition 19Z4 was used instead of the coloring curable composition 1Z4. Further, a colored coating film was obtained in the same manner as in Example 101Z4 except that the coloring curable composition 19Z4 was used instead of the coloring curable composition 1Z4, and the film thickness measurement and the retardation value measurement were performed. The results are shown in Table 22Z4.

Examples 120Z4 to 125Z4
A coloring pattern was obtained in the same manner as in Example 119Z4, except that the compound represented by the formula (IZ4-1) was replaced with the coloring agent shown in the “Colorant” column of Table 22Z4. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 22Z4.

Examples 126Z4 to 132Z4
The compound represented by the formula (IZ4-1) was replaced with the compound shown in the “Colorant” column of Table 22Z4, and C.I. I. Pigment Green 58 to C.I. I. A coloring pattern was obtained in the same manner as in Example 119Z4 except that the pigment green 7 was replaced. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 22Z4.

Example 133Z4 to Example 139Z4
The compound represented by the formula (IZ4-1) was replaced with the compound shown in the “Colorant” column of Table 22Z4, and C.I. I. Pigment Green 58 to C.I. I. A coloring pattern was obtained in the same manner as in Example 119Z4 except that the pigment green 59 was replaced. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 22Z4.

In Example Z4, from the above results, in the colored coating film formed from the colored curable composition containing the compound of the present invention, C.I. I. It was found that the retardation value was smaller than that of the colored coating film formed from the colored curable composition containing Pigment Yellow 185.

[Example Z5]
Example 1Z5
25.2 parts of 4-tert-butylphthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 212 parts of methanol were mixed. A mixture of 20.5 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 184 parts of methanol was added dropwise to the obtained mixture at 5 ° C. over 1 hour. The resulting mixture was stirred at 5-20 ° C. for 2 days.
At 10-20 ° C., 13.7 parts of acetic acid and 13.5 parts of 2-cyano-N-methylacetamide were added to the resulting mixture. The resulting mixture was stirred at 10-20 ° C. for 5 hours and then at 40 ° C. for 16 hours. To the obtained mixture, 6.79 parts of acetic acid, 6.75 parts of 2-cyano-N-methylacetamide and 201 parts of methanol were added, and the mixture was stirred at 40 ° C. for 6 hours and at 50 ° C. for 65 hours. To the obtained mixture, 13.5 parts of acetic acid, 18.3 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.) and 604 parts of water were added, and the mixture was stirred at 40 ° C. for 52 hours. The resulting mixture was filtered and the residue was washed with 50% aqueous methanol solution. The obtained residue was dried under reduced pressure at 60 ° C. to obtain 49.9 parts of the compound represented by the formula (IZ5-1).

<Identification of the compound represented by the formula (IZ5-1)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 394
Exact Mass: 393

Example 2Z5
The same procedure as in Example 1Z5 was carried out except that 2-cyano-N-methylacetamide was replaced with 2-cyanoacetanilide (manufactured by Tokyo Chemical Industry Co., Ltd.) to obtain a compound represented by the formula (IZ5-3). rice field.

<Identification of the compound represented by the formula (IZ5-3)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 456
Exact Mass: 455

Example 3Z5
Except for replacing 4-tert-butylphthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) with 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) The compound represented by 23) was obtained.

<Identification of the compound represented by the formula (IZ5-23)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 383
Exact Mass: 382

Example 4Z5
4-tert-Butylphthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) is replaced with 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.), and 2-cyano-N-methylacetamide is replaced with 2-cyanoacetanilide (manufactured by Tokyo Chemical Industry Co., Ltd.). A compound represented by the formula (IZ5-25) was obtained in the same manner as in Example 1Z5 except that the compound was replaced with that of Industrial Co., Ltd.

<Identification of the compound represented by the formula (IZ5-25)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 445
Exact Mass: 444

Example 5Z5
25.2 parts of 4-tert-butylphthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 212 parts of methanol were mixed. A mixture of 20.5 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 184 parts of methanol was added dropwise to the obtained mixture at 5 ° C. or lower over 1 hour. The resulting mixture was stirred at 5-20 ° C. for 2 days.
At 10-20 ° C., 13.7 parts of acetic acid and 13.5 parts of 2-cyano-N-methylacetamide were added to the resulting mixture. The resulting mixture was stirred at 10-20 ° C. for 5 hours and then at 40 ° C. for 16 hours.
To the obtained mixture, 6.79 parts of acetic acid and 6.75 parts of 2-cyano-N-methylacetamide were added, and the mixture was stirred at 40 ° C. for 6 hours and at 50 ° C. for 65 hours. In addition to the methanol described above, a total of 201 parts of methanol was added up to this point.
To the obtained mixture, 13.5 parts of acetic acid, 18.3 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.) and 604 parts of water were added, and the mixture was stirred at 40 ° C. for 53 hours.
The resulting mixture was filtered and the residue was washed with 50% aqueous methanol solution. The obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ5-1).

<Identification of the compound represented by the formula (IZ5-1)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 394
Exact Mass: 393

Example 6Z5
10.0 parts of 4-tert-butyl phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 84 parts of methanol were mixed. A mixture of 8.15 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 73 parts of methanol was added dropwise to the obtained mixture at 5 ° C. or lower over 1 hour. The resulting mixture was stirred at 5-20 ° C. for 2 days.
At 10 to 20 ° C., 5.42 parts of acetic acid and 8.69 parts of 2-cyanoacetanilide (manufactured by Tokyo Chemical Industry Co., Ltd.) were added to the obtained mixture. The resulting mixture was stirred at 65 ° C. for 3 days.
To the obtained mixture, 2.69 parts of acetic acid and 4.35 of 2-cyanoacetanilide (manufactured by Tokyo Chemical Industry Co., Ltd.) were added, and the mixture was stirred at 65 ° C. for 3 days.
In addition to the methanol described above, a total of 206 parts of methanol was added up to this point.
To the obtained mixture, 5.36 parts of acetic acid, 7.25 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.) and 363 parts of water were added, and the mixture was stirred at 65 ° C. for 9 days.
The obtained mixture was solvent-distilled off by a rotary evaporator, and the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ5-3).

<Identification of the compound represented by the formula (IZ5-3)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 456
Exact Mass: 455

Example 7Z5
25.2 parts of 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 376 parts of methanol were mixed. While keeping the temperature at 2 to 6 ° C., 14.8 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) was added dropwise to the obtained mixture over 20 minutes. The resulting mixture was stirred for 5 hours while keeping below 5 ° C.
While keeping the resulting mixture below 5 ° C., 9.31 parts of acetic acid and 14.4 parts of 2-cyano-N-methylacetamide were added. The resulting mixture was stirred at room temperature for 14 hours and at 40 ° C. for 29 hours.
To the resulting mixture, 1.50 parts of acetic acid and 2.24 parts of 2-cyano-N-methylacetamide were added. The resulting mixture was stirred at 40 ° C. for 19 hours.
To the resulting mixture was added 4.83 parts of acetic acid and 7.36 parts of 2-cyano-N-methylacetamide. The resulting mixture was stirred at 40 ° C. for 79 hours.
To the resulting mixture was added 4.60 parts of acetic acid and 7.30 parts of 2-cyano-N-methylacetamide. The resulting mixture was stirred at 40 ° C. for 24 hours.
In addition to the methanol described above, a total of 259 parts of methanol was added up to this point.
To the obtained mixture, 12.1 parts of acetic acid, 19.1 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.), 635 parts of water, 14.2 parts of methanol and 20 parts of 50% aqueous methanol solution were added, and the temperature was 40 ° C. The mixture was stirred under 21 hours and at 63 ° C. for 5 hours.
23.4 parts of acetic acid was added to the obtained mixture, and the mixture was stirred at 63 ° C. for 18 hours.
To the obtained mixture, 24.9 parts of acetic acid, 19.4 parts of barbituric acid and 32.8 parts of methanol were added, and the mixture was stirred at 63 ° C. for 7 hours.
259 parts of a 50% aqueous methanol solution was added to the obtained mixture, and the mixture was stirred at 63 ° C. for 7 days.
The resulting mixture was filtered.
902 parts of tetrahydrofuran was added to the obtained residue, and the mixture was stirred at room temperature.
The mixture was filtered and the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ5-23).

<Identification of the compound represented by the formula (IZ5-23)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 383
Exact Mass: 382

Example 8Z5
10.0 parts of 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 149 parts of methanol were mixed. While keeping the temperature at 2 to 6 ° C., 5.86 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) was added dropwise to the obtained mixture over 20 minutes. The resulting mixture was stirred for 5 hours while keeping below 5 ° C.
While keeping the obtained mixture at 5 ° C. or lower, 5.79 parts of acetic acid, 9.25 parts of 2-cyanoacetanilide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 74 parts of methanol were added. The resulting mixture was stirred at 65 ° C. for 3 days.
To the obtained mixture, 2.88 parts of acetic acid and 4.63 parts of 2-cyanoacetanilide (manufactured by Tokyo Chemical Industry Co., Ltd.) were added.
The resulting mixture was stirred at 65 ° C. for 3 days.
In addition to the methanol described above, a total of 140 parts of methanol was added up to this point.
To the obtained mixture, 24.0 parts of acetic acid, 15.3 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.) and 363 parts of water were added, and the mixture was stirred at 65 ° C. for 9 days.
The obtained mixture was solvent-distilled off by a rotary evaporator, and the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ5-25).

<Identification of the compound represented by the formula (IZ5-25)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 445
Exact Mass: 444

Example 9Z5
5.0 parts of 4,5-dichlorophthalonitrile and 62 parts of methanol were mixed.
While keeping the mixture at 5 ° C. or lower, a 25% sodium methoxide methanol solution containing 5.0 times the number of moles of 5.0 parts of 4,5-dichlorophthalonitrile of sodium methoxide was added.
The mixture was stirred at 5 ° C. and below for 5 hours.
To this mixture, keep the temperature below 5 ° C., add 2-cyano-N-methylacetamide and 6.1 parts of acetic acid, which are 1.5 times the number of moles of 5.0 parts of 4,5-dichlorophthalonitrile. rice field.
The mixture was stirred at 65 ° C. for 3 days.
This mixture was mixed with 4.2 parts of acetic acid, 5.2 parts of barbituric acid, 500 parts of methanol and 562 parts of water, and stirred at 65 ° C. for 9 days.
After distilling off the solvent of this mixture with a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ5-247).

<Identification of the compound represented by the formula (IZ5-247)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 406
Exact Mass: 405

Example 101Z5
Pigment: C.I. I. Pigment Green 58 60 copies,
Acrylic pigment dispersant 8.1 parts,
A pigment dispersion (colorant (A1Z5) -containing liquid) in which 73 parts of a resin (B): resin B5 solution and 290 parts of a solvent (E): propylene glycol monomethyl ether acetate are mixed and the pigment is dispersed using a bead mill is used. Prepared.
Separately
Colorant (AZ5): 50 parts of the compound represented by the formula (IZ5-1) obtained in Example 1Z5,
Dispersant (BYK-LPN6919; manufactured by Big Chemie Japan Co., Ltd.) 58 copies,
Resin (B): 93 parts of resin B3 solution and solvent (E): 800 parts of propylene glycol monomethyl ether acetate are mixed, and a compound represented by the formula (IZ5-1) obtained in Example 1Z5 is used using a bead mill. Was dispersed to obtain a colored composition.
Then
The total amount of the obtained pigment dispersion liquid (colorant (A1Z5) -containing liquid);
400 parts of the obtained coloring composition;
Resin (B): 45 parts of resin B1 solution;
Polymerizable compound (C): Dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kayaku Co., Ltd.) 25 parts;
Polymerization Initiator (D): N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure® OXE-01; manufactured by BASF Ltd.) 15 parts;
Solvent (E): 86 parts of propylene glycol monomethyl ether acetate; Leveling agent: Polyether-modified silicone oil (Tore Silicone SH8400; manufactured by Toray Dow Corning Co., Ltd.) 0.12 parts;
Was mixed to obtain a color curable composition 1Z5.

[Making a colored pattern]
A color-curable composition 1Z5 was applied onto a 2-inch square glass substrate (Eagle XG; manufactured by Corning Inc.) by a spin coating method, and then prebaked at 100 ° C. for 3 minutes to form a color-curable composition layer. After cooling, the distance between the substrate on which the colored curable composition layer was formed and the quartz glass photomask was set to 200 μm, and using an exposure machine (TME-150RSK; manufactured by Topcon Co., Ltd.), 80 mJ / in an air atmosphere. Exposure was performed with an exposure amount of cm ^{2 (based on 365 nm).} As the photomask, a photomask having a line-and-space pattern of 100 μm formed was used. The colored curable composition layer after exposure was developed by immersing it in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ° C. for 70 seconds, and washed with water. This color-curable composition layer was post-baked at 230 ° C. for 30 minutes to obtain a color pattern.

[Phase difference value measurement]
A color-curable composition 1Z5 was applied onto a 2-inch square glass substrate (Eagle XG; manufactured by Corning Inc.) by a spin coating method, and then prebaked at 100 ° C. for 3 minutes to form a color-curable composition layer. ^{After cooling, the colored curable composition layer was exposed to an exposure amount of 80 mJ / cm 2} (based on 365 nm) in an air atmosphere using an exposure machine (TME-150RSK; manufactured by Topcon Corporation). The colored curable composition layer after exposure was developed by immersing it in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ° C. for 70 seconds, and washed with water. The colored curable composition layer was post-baked at 230 ° C. for 30 minutes to obtain a colored coating film.
The film thickness of the obtained colored coating film was measured using DEKTAK3 (manufactured by Nippon Vacuum Technology Co., Ltd.).
Using an ellipsometer (M-220 type spectroscopic ellipsometer; manufactured by JASCO Corporation), the phase difference value at a tilt angle of 45 ° of this colored coating film was measured. Light having a wavelength of 550 nm was used for the phase difference value measurement. The results are shown in Table 16Z5.

Example 102Z5
Color curing in the same manner as in Example 101Z5, except that the compound represented by the formula (IZ5-1) obtained in Example 1Z5 is replaced with the compound represented by the formula (IZ5-3) obtained in Example 2Z5. The sex composition 2Z5 was obtained to obtain a coloring pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 16Z5.

Example 103Z5
Color curing in the same manner as in Example 101Z5, except that the compound represented by the formula (IZ5-1) obtained in Example 1Z5 is replaced with the compound represented by the formula (IZ5-23) obtained in Example 3Z5. The sex composition 3Z5 was obtained to obtain a coloring pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 16Z5.

Example 104Z5
Color curing in the same manner as in Example 101Z5, except that the compound represented by the formula (IZ5-1) obtained in Example 1Z5 is replaced with the compound represented by the formula (IZ5-25) obtained in Example 4Z5. The sex composition 4Z5 was obtained to obtain a coloring pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 16Z5.

Example 105Z5
C. I. Pigment Green 58 to C.I. I. A color-curable composition 5Z5 was obtained in the same manner as in Example 101Z5 except that it was replaced with Pigment Green 7, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 16Z5.

Example 106Z5
C. I. Pigment Green 58 to C.I. I. Example 101Z5 except that the compound represented by the formula (IZ5-1) obtained in Example 1Z5 is replaced with the compound represented by the formula (IZ5-3) obtained in Example 2Z5 instead of Pigment Green 7. Similarly, a coloring curable composition 6Z5 was obtained to obtain a coloring pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 16Z5.

Example 107Z5
C. I. Pigment Green 58 to C.I. I. Example 101Z5 except that the compound represented by the formula (IZ5-1) obtained in Example 1Z5 is replaced with the compound represented by the formula (IZ5-23) obtained in Example 3Z5 instead of Pigment Green 7. Similarly, a coloring curable composition 7Z5 was obtained to obtain a coloring pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 16Z5.

Example 108Z5
C. I. Pigment Green 58 to C.I. I. Example 101Z5 except that the compound represented by the formula (IZ5-1) obtained in Example 1Z5 is replaced with the compound represented by the formula (IZ5-25) obtained in Example 4Z5 instead of Pigment Green 7. Similarly, a coloring curable composition 8Z5 was obtained to obtain a coloring pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 16Z5.

Example 109Z5
C. I. Pigment Green 58 to C.I. I. A color-curable composition 9Z5 was obtained in the same manner as in Example 101Z5 except that the pigment green 59 was replaced, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 16Z5.

Example 110Z5
C. I. Pigment Green 58 to C.I. I. Example 101Z5 except that the compound represented by the formula (IZ5-1) obtained in Example 1Z5 is replaced with the compound represented by the formula (IZ5-3) obtained in Example 2Z5 instead of Pigment Green 59. Similarly, a coloring curable composition 10Z5 was obtained to obtain a coloring pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 16Z5.

Example 111Z5
C. I. Pigment Green 58 to C.I. I. Example 101Z5 except that the compound represented by the formula (IZ5-1) obtained in Example 1Z5 is replaced with the compound represented by the formula (IZ5-23) obtained in Example 3Z5 instead of Pigment Green 59. Similarly, a coloring curable composition 11Z5 was obtained to obtain a coloring pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 16Z5.

Example 112Z5
C. I. Pigment Green 58 to C.I. I. Example 101Z5 except that the compound represented by the formula (IZ5-1) obtained in Example 1Z5 is replaced with the compound represented by the formula (IZ5-25) obtained in Example 4Z5 instead of the pigment green 59. Similarly, a coloring curable composition 12Z5 was obtained to obtain a coloring pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 16Z5.

Comparative Example 1Z5
The compound represented by the formula (IZ5-1) obtained in Example 1Z5 was designated as C.I. I. A color-curable composition C1Z5 was obtained in the same manner as in Example 101Z5 except that it was replaced with Pigment Yellow 185, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 16Z5.

Comparative Example 2Z5
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 7, a compound represented by the formula (IZ5-1) obtained in Example 1Z5 was used as C.I. I. A color-curable composition C2Z5 was obtained in the same manner as in Example 101Z5 except that it was replaced with Pigment Yellow 185, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 16Z5.

Comparative Example 3Z5
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 59, a compound represented by the formula (IZ5-1) obtained in Example 1Z5 was used as C.I. I. A color-curable composition C3Z5 was obtained in the same manner as in Example 101Z5 except that it was replaced with Pigment Yellow 185, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 16Z5.

Example 113Z5
Pigment: C.I. I. Pigment Green 58 60 copies,
Acrylic pigment dispersant 8.1 parts,
A pigment dispersion (colorant (A1Z5) -containing liquid) in which 73 parts of a resin (B): resin B5 solution and 290 parts of a solvent (E): propylene glycol monomethyl ether acetate are mixed and the pigment is dispersed using a bead mill is used. Prepared.
Separately
Colorant (AZ5): 50 parts of the compound represented by the formula (IZ5-1),
Dispersant solution (solid content 60%) 58 parts,
Resin (B): 93 parts of resin B3 solution and solvent (E): 800 parts of propylene glycol monomethyl ether acetate are mixed, and the compound represented by the formula (IZ5-1) is dispersed using a bead mill to form a coloring composition. I got something.
Then
The total amount of the obtained pigment dispersion liquid (colorant (A1Z5) -containing liquid);
400 parts of the obtained coloring composition;
Resin (B): 45 parts of resin B1 solution;
Polymerizable compound (C): Dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kayaku Co., Ltd.) 25 parts;
Polymerization Initiator (D): N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure® OXE-01; manufactured by BASF Ltd.) 15 parts;
Solvent (E): 86 parts of propylene glycol monomethyl ether acetate;
And leveling agent: Polyether-modified silicone oil (Toray Silicone SH8400; manufactured by Toray Dow Corning Co., Ltd.) 0.12 parts;
Was mixed to obtain a color curable composition 13Z5.

A coloring pattern was produced in the same manner as in Example 101Z5 except that the coloring curable composition 13Z5 was used instead of the coloring curable composition 1Z5. Further, a colored coating film was obtained in the same manner as in Example 101Z5 except that the coloring curable composition 13Z5 was used instead of the coloring curable composition 1Z5, and the film thickness measurement and the retardation value measurement were performed. The results are shown in Table 17Z5.

Example 114Z5 to Example 117Z5
A coloring pattern was obtained in the same manner as in Example 113Z5, except that the compound represented by the formula (IZ5-1) was replaced with the coloring agent shown in the “Coloring agent” column of Table 17Z5. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 17Z5.

Example 118Z5 to Example 122Z5
The compound represented by the formula (IZ5-1) was replaced with the compound shown in the “Colorant” column of Table 17Z5, and C.I. I. Pigment Green 58 to C.I. I. A coloring pattern was obtained in the same manner as in Example 113Z5 except that the pigment green 7 was replaced. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 17Z5.

Example 123Z5 to Example 127Z5
The compound represented by the formula (IZ5-1) was replaced with the compound shown in the “Colorant” column of Table 17Z5, and C.I. I. Pigment Green 58 to C.I. I. A coloring pattern was obtained in the same manner as in Example 113Z5 except that the pigment green 59 was replaced. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 17Z5.

In Example Z5, from the above results, in the colored coating film formed from the colored curable composition containing the compound of the present invention, C.I. I. It was found that the retardation value was smaller than that of the colored coating film formed from the colored curable composition containing Pigment Yellow 185.

[Example Z6]
Example 1Z6
7.02 parts of phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 61.6 parts of methanol were mixed. While keeping the temperature of the obtained mixture at 2 ° C., a mixture of 8.20 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 74.6 parts of methanol was added for 1 hour and 30 minutes. Dropped over. The resulting mixture was stirred at 2 ° C. for 6 hours and 15 minutes. 10.7 parts of acetic acid was added while keeping the temperature of the obtained mixture below 4 ° C. To the obtained mixture, 17.6 parts of benzoyl acetonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) was added, and the mixture was stirred at room temperature for 44 hours. The resulting mixture was filtered and the residue was washed with 800 parts of methanol. The obtained residue was dried under reduced pressure at 60 ° C. to obtain 18.0 parts of the compound represented by the formula (IFFZ6-1).

<Identification of the compound represented by the formula (IFFZ6-1)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 402
Exact Mass: 401

Compound 0.513 represented by the formula (IFFZ6-1) obtained in Example 2Z6 while stirring 7.6 parts of fuming sulfuric acid (25%) (manufactured by Wako Pure Chemical Industries, Ltd.) at 3 ° C. Added a part. 3.8 parts of fuming sulfuric acid (25%) (manufactured by Wako Pure Chemical Industries, Ltd.) was added to the obtained mixture. The resulting mixture was raised to 15 ° C. over 3 hours and 30 minutes with stirring. 139 parts of ice water was added to the obtained mixture, and 38.2 parts of sodium chloride was further added. The resulting mixture was filtered and the resulting residue was washed with 64 parts of a 21.5% aqueous sodium chloride solution. The obtained residue was dried under reduced pressure at 60 ° C. to obtain 1.02 part of the compound represented by the formula (IFFZ6-2).

<Identification of the compound represented by the formula (IFFZ6-2)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ M-H] - 560
Exact Mass: 561

At room temperature, 5.11 parts of the compound represented by the formula (IFFZ6-2) and 511 parts of water were mixed. A mixture of 6.72 parts of barium chloride dihydrate (manufactured by Wako Pure Chemical Industries, Ltd.) and 60 parts of water was added to the obtained mixture. The resulting mixture was filtered and the resulting residue was washed with water. The obtained residue was dried under reduced pressure at 60 ° C. to obtain 2.98 parts of the compound represented by the formula (IFZ6-4).

<Identification of the compound represented by the formula (IFZ6-4)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ M-Ba 2+ + H] - 560
Exact Mass: 697

Example 2 Z6
At room temperature, 10.0 parts of the compound represented by the formula (IFFZ6-2) and 1000 parts of water were mixed. A 5% aqueous sodium hydroxide solution was added dropwise to the obtained mixture to obtain a uniform solution. To this uniform solution, 87.0 parts of a 10% aqueous solution of barium chloride dihydrate was added. The resulting mixture was filtered and the resulting residue was washed with water. The obtained residue was dried under reduced pressure at 60 ° C. to obtain 9.43 parts of the compound represented by the formula (IFZ6-4).

<Identification of the compound represented by the formula (IFZ6-4)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ M-Ba + H] - 560
Exact Mass: 697

Example 3Z6
At room temperature, 5.02 parts of the compound represented by the formula (IFFZ6-2) and 500 parts of a 50% aqueous methanol solution were mixed. A 5% aqueous sodium hydroxide solution was added dropwise to the obtained mixture to obtain a uniform solution. To this uniform solution, 95.0 parts of a 10% aqueous solution of strontium chloride hexahydrate was added. The resulting mixture was filtered and the resulting residue was washed with 50% aqueous methanol solution. The obtained residue was dried under reduced pressure at 60 ° C. to obtain 4.00 parts of the compound represented by the formula (IFZ6-3).

<Identification of the compound represented by the formula (IFZ6-3)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ M-Sr + H] - 560
Exact Mass: 647

Example 4Z6
At room temperature, 0.501 parts of the compound represented by the formula (IFFZ6-2) and 50.0 parts of water were mixed. A 5% aqueous sodium hydroxide solution was added dropwise to the obtained mixture to obtain a uniform solution. To this uniform solution, 12.6 parts of a 10% aqueous calcium chloride solution was added. The resulting mixture was filtered and the resulting residue was washed with water. The obtained residue was dried under reduced pressure at 60 ° C. to obtain 0.024 part of the compound represented by the formula (IFZ6-2).

<Identification of the compound represented by the formula (IFZ6-2)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ M-Ca + H] - 560
Exact Mass: 599

Example 5Z6
At room temperature, 0.500 parts of the compound represented by the formula (IFFZ6-2) and 50.0 parts of water were mixed. A 5% aqueous sodium hydroxide solution was added dropwise to the obtained mixture to obtain a uniform solution. 3.52 parts of a 10% manganese chloride tetrahydrate aqueous solution was added to this uniform solution. The resulting mixture was filtered and the resulting residue was washed with water. The obtained residue was dried under reduced pressure at 60 ° C. to obtain 0.015 parts of the compound represented by the formula (IFZ6-10).

<Identification of the compound represented by the formula (IFZ6-10)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ M-Mn + H] - 560
Exact Mass: 614

Example 6Z6
A compound represented by the formula (IFZ6-6) was obtained in the same manner as in Example 2Z6 except that the barium chloride dihydrate was replaced with zinc nitrate hexahydrate.

<Identification of the compound represented by the formula (IFZ6-6)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ M-Zn + H] - 560
Exact Mass: 623

Example 7Z6
At room temperature, 5.00 parts of the compound represented by the formula (IFFZ6-2) and 500 parts of water were mixed. A 5% aqueous sodium hydroxide solution was added dropwise to the obtained mixture to obtain a uniform solution. To this uniform solution was added 23.7 parts of a 10% aqueous aluminum chloride solution. The resulting mixture was filtered and the resulting residue was washed with water. The obtained residue was dried under reduced pressure at 60 ° C. to obtain 0.474 parts of the compound represented by the formula (IFZ6-11).

<Identification of the compound represented by the formula (IFZ6-11)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ (M-2Al) / 3 + H] - 560
Exact Mass: 1731

Example 8Z6
At room temperature, 5.01 parts of the compound represented by the formula (IFFZ6-2) and 500 parts of water were mixed. A 5% aqueous sodium hydroxide solution was added dropwise to the obtained mixture to obtain a uniform solution. To this uniform solution, 36.0 parts of a 10% aqueous iron nitrate hydrate solution was added. The resulting mixture was filtered and the resulting residue was washed with water. The obtained residue was dried under reduced pressure at 60 ° C. to obtain 3.80 parts of the compound represented by the formula (IFZ6-12).

<Identification of the compound represented by the formula (IFZ6-12)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ (M-2Fe) / 3 + H] - 560
Exact Mass: 1789

Example 9Z6
At room temperature, 0.498 parts of the compound represented by the formula (IFFZ6-2) and 49.9 parts of water were mixed. A 5% aqueous sodium hydroxide solution was added dropwise to the obtained mixture to obtain a uniform solution. To this uniform solution, 4.45 parts of a 10% aqueous solution of copper sulfate pentahydrate was added. The resulting mixture was filtered and the resulting residue was washed with water. The obtained residue was dried under reduced pressure at 60 ° C. to obtain 0.018 parts of the compound represented by the formula (IFZ6-31).

<Identification of the compound represented by the formula (IFZ6-31)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ M-Cu + H] - 560
Exact Mass: 622

Example 10Z6
It is represented by the formula (IJJZ6-1) in the same manner as in the method for obtaining the compound represented by the formula (IFFZ6-1) in Example 1Z6 except that the benzoyl acetonitrile is replaced with 4-cyanoacetylbenzoic acid. The compound was obtained.

<Identification of the compound represented by the formula (IJJZ6-1)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ M-H] - 488
Exact Mass: 489

At room temperature, 16.3 parts of the compound represented by the formula (IJJZ6-1) and 1630 parts of water were mixed. A 5% aqueous sodium hydroxide solution was added dropwise to the obtained mixture to obtain a uniform solution. To the obtained uniform solution, 163 parts of a 10% aqueous solution of barium chloride dihydrate was added. The resulting mixture was filtered and the resulting residue was washed with water. The obtained residue was dried under reduced pressure at 60 ° C. to obtain 7.49 parts of the compound represented by the formula (IJZ6-4).

<Identification of the compound represented by the formula (IJZ6-4)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ M-Ba + H] - 488
Exact Mass: 625

Example 11Z6
The same procedure as in Example 10Z6 was carried out except that barium chloride dihydrate was replaced with strontium chloride hexahydrate to obtain a compound represented by the formula (IJZ6-3).

<Identification of the compound represented by the formula (IJZ6-3)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ M-Sr + H] - 488
Exact Mass: 575

Example 12Z6
A compound represented by the formula (IJZ6-2) was obtained in the same manner as in Example 10Z6 except that barium chloride dihydrate was replaced with calcium chloride.

<Identification of the compound represented by the formula (IJZ6-2)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ M-Ca + H] - 488
Exact Mass: 527

Example 13Z6
A compound represented by the formula (IJZ6-10) was obtained in the same manner as in Example 10Z6 except that barium chloride dihydrate was replaced with manganese chloride tetrahydrate.

<Identification of the compound represented by the formula (IJZ6-10)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ M-Mn + H] - 488
Exact Mass: 542

Example 14Z6
A compound represented by the formula (IJZ6-31) was obtained in the same manner as in Example 10Z6 except that the barium chloride dihydrate was replaced with copper sulfate pentahydrate.

<Identification of the compound represented by the formula (IJZ6-31)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ M-Cu + H] - 488
Exact Mass: 550

Example 15Z6
A compound represented by the formula (IJZ6-6) was obtained in the same manner as in Example 10Z6 except that the barium chloride dihydrate was replaced with zinc nitrate hexahydrate.

<Identification of the compound represented by the formula (IJZ6-6)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ M-Zn + H] - 488
Exact Mass: 551

Example 16Z6
A compound represented by the formula (IJZ6-11) was obtained in the same manner as in Example 10Z6 except that barium chloride dihydrate was replaced with aluminum chloride.

<Identification of the compound represented by the formula (IJZ6-11)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ (M-2Al) / 3 + H] - 488
Exact Mass: 1515

Example 17Z6
A compound represented by the formula (IJZ6-12) was obtained in the same manner as in Example 10Z6 except that the barium chloride dihydrate was replaced with iron nitrate nineahydrate.

<Identification of the compound represented by the formula (IJZ6-12)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ (M-2Fe) / 3 + H] - 488
Exact Mass: 1573

Example 18Z6
A compound represented by the formula (IJZ6-1) was obtained in the same manner as in Example 10Z6 except that barium chloride dihydrate was replaced with magnesium chloride.

<Identification of the compound represented by the formula (IJZ6-1)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ M-Mg + H] - 488
Exact Mass: 511

Synthesis example 19Z6
5.00 parts of phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 44 parts of methanol were mixed. A mixture of 5.84 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 54 parts of methanol was added dropwise to the obtained mixture over 1 hour and 30 minutes while keeping the temperature below 5 ° C. .. The resulting mixture was stirred at 5 ° C. and below for 12 hours. While keeping the temperature below 5 ° C., 11.5 parts of acetic acid was added to the obtained mixture, and 24.5 parts of 4-cyanoacetylbenzoic acid and 712 parts of methanol were further added. The obtained mixture was stirred at room temperature for 4 hours and then at 40 ° C. for 96 hours. The obtained mixture was solvent-distilled with a rotary evaporator, and the obtained residue was purified by column chromatography to obtain 0.471 parts of the compound represented by the formula (IJJZ6-1).

<Identification of the compound represented by the formula (IJJZ6-1)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ M-H] - 488
Exact Mass: 489

Example 101Z6
Pigment: C.I. I. Pigment Green 58 60 copies,
Acrylic pigment dispersant 8.1 parts,
A pigment dispersion (colorant (A1Z6) -containing liquid) in which 73 parts of a resin (B): resin B5 solution and 290 parts of a solvent (E): propylene glycol monomethyl ether acetate are mixed and the pigment is dispersed using a bead mill is used. Prepared.
Separately
Colorant (AZ6): 50 parts of the compound represented by the formula (IFZ6-4),
Dispersant (BYK-LPN6919; manufactured by Big Chemie Japan Co., Ltd.) 58 copies,
Resin (B): 93 parts of resin B3 solution and solvent (E): 800 parts of propylene glycol monomethyl ether acetate are mixed, and the compound represented by the formula (IFZ6-4) is dispersed using a bead mill to form a coloring composition. I got something.
Then
Total amount of the obtained pigment dispersion liquid (colorant (A1Z6) -containing liquid);
400 parts of the obtained coloring composition;
Resin (B): 45 parts of resin B1 solution;
Polymerizable compound (C): Dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kayaku Co., Ltd.) 25 parts;
Polymerization Initiator (D): N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure® OXE-01; manufactured by BASF Ltd.) 15 parts;
Solvent (E): 86 parts of propylene glycol monomethyl ether acetate; Leveling agent: Polyether-modified silicone oil (Tore Silicone SH8400; manufactured by Toray Dow Corning Co., Ltd.) 0.12 parts;
Was mixed to obtain a colored curable composition 1Z6.

[Making a colored pattern]
A color-curable composition 1Z6 was applied onto a 2-inch square glass substrate (Eagle XG; manufactured by Corning Inc.) by a spin coating method, and then prebaked at 100 ° C. for 3 minutes to form a color-curable composition layer. After cooling, the distance between the substrate on which the colored curable composition layer was formed and the quartz glass photomask was set to 200 μm, and using an exposure machine (TME-150RSK; manufactured by Topcon Co., Ltd.), 80 mJ / in an air atmosphere. Exposure was performed with an exposure amount of cm ^{2 (based on 365 nm).} still,
As the photomask, a photomask having a line-and-space pattern of 100 μm formed was used. The colored curable composition layer after exposure was developed by immersing it in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ° C. for 70 seconds, and washed with water. This color-curable composition layer was post-baked at 230 ° C. for 30 minutes to obtain a color pattern.

[Phase difference value measurement]
A color-curable composition 1Z6 was applied onto a 2-inch square glass substrate (Eagle XG; manufactured by Corning Inc.) by a spin coating method, and then prebaked at 100 ° C. for 3 minutes to form a color-curable composition layer. ^{After cooling, the colored curable composition layer was exposed to an exposure amount of 80 mJ / cm 2} (based on 365 nm) in an air atmosphere using an exposure machine (TME-150RSK; manufactured by Topcon Corporation). The color-curable composition layer after exposure was developed by immersing it in an aqueous solution containing 0.12% of nonionic surfactant and 0.04% of potassium hydroxide at 25 ° C. for 70 seconds, washed with water, and dried. .. The colored curable composition layer after drying was post-baked at 230 ° C. for 30 minutes to obtain a colored coating film.
The film thickness of the obtained colored coating film was measured using DEKTAK3 (manufactured by Nippon Vacuum Technology Co., Ltd.).
Using an ellipsometer (M-220 type spectroscopic ellipsometer; manufactured by JASCO Corporation), the phase difference value at a tilt angle of 45 ° of this colored coating film was measured. Light having a wavelength of 550 nm was used for the phase difference value measurement. The results are shown in Table 5Z6.

Example 102Z6
A color curable composition 2Z6 is obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) is replaced with the compound represented by the formula (IFZ6-2) to obtain a color pattern. rice field. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z6.

Example 103Z6
A color curable composition 3Z6 is obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) is replaced with the compound represented by the formula (IFZ6-3) to obtain a color pattern. rice field. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z6.

Example 104Z6
A color curable composition 4Z6 is obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) is replaced with the compound represented by the formula (IFZ6-6) to obtain a color pattern. rice field. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z6.

Example 105Z6
A color curable composition 5Z6 is obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) is replaced with the compound represented by the formula (IFZ6-10) to obtain a color pattern. rice field. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z6.

Example 106Z6
A color curable composition 6Z6 is obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) is replaced with the compound represented by the formula (IFZ6-11) to obtain a color pattern. rice field. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z6.

Example 107Z6
A coloring curable composition 7Z6 was obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-12) to obtain a coloring pattern. rice field. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z6.

Example 108Z6
A color curable composition 8Z6 is obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) is replaced with the compound represented by the formula (IFZ6-31) to obtain a color pattern. rice field. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z6.

Example 109Z6
A coloring curable composition 9Z6 was obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-1) to obtain a coloring pattern. rice field. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z6.

Example 110Z6
A coloring curable composition 10Z6 was obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-2) to obtain a coloring pattern. rice field. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z6.

Example 111Z6
A coloring curable composition 11Z6 was obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-3) to obtain a coloring pattern. rice field. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z6.

Example 112Z6
A coloring curable composition 12Z6 was obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-4) to obtain a coloring pattern. rice field. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z6.

Example 113Z6
A coloring curable composition 13Z6 was obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-6) to obtain a coloring pattern. rice field. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z6.

Example 114Z6
A coloring curable composition 14Z6 was obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-10) to obtain a coloring pattern. rice field. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z6.

Example 115Z6
A coloring curable composition 15Z6 was obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-11) to obtain a coloring pattern. rice field. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z6.

Example 116Z6
A coloring curable composition 16Z6 was obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-12) to obtain a coloring pattern. rice field. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z6.

Example 117Z6
A coloring curable composition 17Z6 was obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-31) to obtain a coloring pattern. rice field. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z6.

Example 118Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-2), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 18Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 7, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z6.

Example 119Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-3), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 19Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 7, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z6.

Example 120Z6
C. I. Pigment Green 58 to C.I. I. A color-curable composition 20Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 7, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z6.

Example 121Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-6), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 21Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 7, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z6.

Example 122Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-10), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 22Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 7, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z6.

Example 123Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-11), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 23Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 7, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z6.

Example 124Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-12), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 24Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 7, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z6.

Example 125Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-31), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 25Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 7, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z6.

Example 126Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-1), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 26Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 7, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z6.

Example 127Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-2), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 27Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 7, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z6.

Example 128Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-3), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 28Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 7, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z6.

Example 129Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-4), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 29Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 7, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z6.

Example 130Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-6), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 30Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 7, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z6.

Example 131Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-10), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 31Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 7, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z6.

Example 132Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-11), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 32Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 7, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z6.

Example 133Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-12), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 33Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 7, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z6.

Example 134Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-31), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 34Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 7, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z6.

Example 135Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-2), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 35Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 59, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z6.

Example 136Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-3), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 36Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 59, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z6.

Example 137Z6
C. I. Pigment Green 58 to C.I. I. A color-curable composition 37Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 59, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z6.

Example 138Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-6), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 38Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 59, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z6.

Example 139Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-10), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 39Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 59, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z6.

Example 140Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-11), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 40Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 59, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z6.

Example 141Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-12), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 41Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 59, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z6.

Example 142 Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-31), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 42Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 59, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z6.

Example 143Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-1), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 43Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 59, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z6.

Example 144Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-2), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 44Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 59, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z6.

Example 145Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-3), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 45Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 59, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z6.

Example 146Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-4), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 46Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 59, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z6.

Example 147Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-6), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 47Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 59, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z6.

Example 148Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-10), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 48Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 59, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z6.

Example 149Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-11), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 49Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 59, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z6.

Example 150Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-12), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 50Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 59, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z6.

Example 151Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-31), and C.I. I. Pigment Green 58 to C.I. I. A color-curable composition 51Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Green 59, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z6.

Comparative Example 1Z6
The compound represented by the formula (IFZ6-4) is referred to as C.I. I. A color-curable composition C1Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Yellow 185, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z6.

Comparative Example 2Z6
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 7, a compound represented by the formula (IFZ6-4) was used as C.I. I. A color-curable composition C2Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Yellow 185, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z6.

Comparative Example 3Z6
C. I. Pigment Green 58 to C.I. I. Instead of Pigment Green 59, a compound represented by the formula (IFZ6-4) was used in C.I. I. A color-curable composition C3Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with Pigment Yellow 185, and a color pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z6.

Example 152Z6
Pigment: C.I. I. Pigment Green 58 60 copies,
Acrylic pigment dispersant 8.1 parts,
A pigment dispersion (colorant (A1Z6) -containing liquid) in which 73 parts of a resin (B): resin B5 solution and 290 parts of a solvent (E): propylene glycol monomethyl ether acetate are mixed and the pigment is dispersed using a bead mill is used. Prepared.
Separately
Colorant (AZ6): 50 parts of the compound represented by the formula (IFZ6-4),
Dispersant solution (solid content 60%) 58 parts,
Resin (B): 93 parts of resin B3 solution and solvent (E): 800 parts of propylene glycol monomethyl ether acetate are mixed, and the compound represented by the formula (IFZ6-4) is dispersed using a bead mill to form a coloring composition. I got something.
Then
Total amount of the obtained pigment dispersion liquid (colorant (A1Z6) -containing liquid);
400 parts of the obtained coloring composition;
Resin (B): 45 parts of resin B1 solution;
Polymerizable compound (C): Dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kayaku Co., Ltd.) 25 parts;
Polymerization Initiator (D): N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure® OXE-01; manufactured by BASF Ltd.) 15 parts;
Solvent (E): 86 parts of propylene glycol monomethyl ether acetate; Leveling agent: Polyether-modified silicone oil (Tore Silicone SH8400; manufactured by Toray Dow Corning Co., Ltd.) 0.12 parts;
Was mixed to obtain a colored curable composition 52Z6.

A coloring pattern was produced in the same manner as in Example 101Z6 except that the coloring curable composition 52Z6 was used instead of the coloring curable composition 1Z6. Further, a colored coating film was obtained in the same manner as in Example 101Z6 except that the coloring curable composition 52Z6 was used instead of the coloring curable composition 1Z6, and the film thickness measurement and the retardation value measurement were performed. The results are shown in Table 9Z6.

Example 153Z6 to Example 168Z6
A coloring pattern was obtained in the same manner as in Example 152Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the coloring agent shown in the “Colorant” column of Table 9Z6. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 9Z6.

Example 169Z6 to Example 185Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound shown in the “Colorant” column of Table 10Z6, and C.I. I. Pigment Green 58 to C.I. I. A coloring pattern was obtained in the same manner as in Example 152Z6 except that the pigment green 7 was replaced. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 10Z6.

Example 186Z6 to Example 202Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound shown in the “Colorant” column of Table 11Z6, and C.I. I. Pigment Green 58 to C.I. I. A coloring pattern was obtained in the same manner as in Example 152Z6 except that the pigment green 59 was replaced. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 11Z6.

In Example Z6, from the above results, in the colored coating film formed from the colored curable composition containing the compound of the present invention, C.I. I. It was found that the retardation value was smaller than that of the colored coating film formed from the colored curable composition containing Pigment Yellow 185.

Since the coloring composition and compound of the present invention can be used for forming a color filter having a small retardation value, they are suitably used for display devices such as color filters and liquid crystal display devices.

Claims (17)

A coloring composition containing a compound represented by the formula (IZ6-B) and an alkali-soluble resin.

[In the formula (IZ6-B),
A ^{c +} represents a c-valent metal cation.
b represents an integer of 1 or more.
c represents an integer of 2 to 10.
d represents an integer of 1 or more.
L ¹ represents −CO−.
R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 and R ^13BZ6 are independent of each other, hydrogen atom, -CO-R ^102BZ6 , -COO-R ^101BZ6 , -OCO-R ^102BZ6 , -COCO-R ^102BZ6 , -O-R ^102BZ6 , -SO _2- R ^101BZ6 , -SO ₂ N (R ^102BZ6 ) ₂ ^{, -CON} (R 102BZ6) ₂ , -N (R ^102BZ6 ) ₂ , -NHCO-R ^{102BZ6 , -NHCO-N (R 102BZ6)} 2, -NHCOOR 102BZ6, -OCON (R 102BZ6) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , -SO 3 -, -CO 2 ^—— Represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^2BZ6 and R ^3BZ6 , R ^3BZ6 and R ^4BZ6 , R ^4BZ6 and R ^5BZ6 , and R ^12BZ6 and R ^13BZ6 may be coupled to each other to form a ring, respectively.
R ^101BZ6 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent independently of each other.
R ^102BZ6 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent, independently of each other.
Formulas (IZ6-B') and formulas (IZ6-B'') represent the substructures of formula (IZ6-B), respectively, Ac ⁺ , b, c, d, R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 , R ^13BZ6 and L ¹ represent the same as those in the equation (IZ6-B).
M represents a hydrogen atom or an alkali metal atom.
If there are multiple R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 , R ^13BZ6 , R ^101BZ6 , R ^102BZ6 , L ¹ , M, c or ^{Ac +} , they are the same. It may be present or different.
R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 , R ^13BZ6 , R ^101BZ6 and R ^102BZ6 satisfy at least one of (rb-i) to (rb-iii). ^{and, R 1BZ6, R 2BZ6, R} 3BZ6, R 4BZ6, R 5BZ6, R 11BZ6, R 12BZ6, R 13BZ6, R 101BZ6 and -SO ₃ R ^102BZ6 has ^- or -CO ₂ ^- total number of is a ..
At least one ^{(rb-i) R 1BZ6,} R 2BZ6, R 3BZ6, R 4BZ6, R 5BZ6, R 11BZ6, R 12BZ6 and R ^13BZ6 is, -SO ₃ ^- or -CO ₂ ^- a.
^(Rb -ii) At least one of R 1BZ6, R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 and R ^13BZ6 is -CO-R ^102BZ6 , -COO-R ^101BZ6 , -OCO-R ^102BZ6. , -COCO-R ^102BZ6 , -O-R ^102BZ6 , -SO ₂ -R ^101BZ6 , -SO ₂ N (R ^102BZ6 ) ₂ ^{, -CON} (R 102BZ6) ₂ , -N (R ^102BZ6 ) ₂ , -NHCO-R ^102BZ6 , -NHCO-N (R ^102BZ6 ) ₂ , -NHCOOR ^102BZ6 , or -OCON (R ^102BZ6 ) ₂ .
The R ^101BZ6 and R ^102BZ6 is, -SO ₃ ^- or -CO ₂ ^- 1 to 40 carbon atoms having a hydrocarbon group or a -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
At least one ^{(rb-iii) R 1BZ6,} R 2BZ6, R 3BZ6, R 4BZ6, R 5BZ6, R 11BZ6, R 12BZ6 and R ^13BZ6 is, -SO ₃ ^- 1 to 40 carbon atoms having a ^- or -CO ₂ hydrocarbon group or a -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
a represents an integer of 1 to 10. When a plurality of a exist, they may be the same or different.
The absolute value of the negative valence of the substructure represented by the formula (IZ6-B') and the positive valence of the substructure represented by the formula (IZ6-B ″) are the same.
The wavy line represents an E-form or a Z-form. ] The coloring composition according to claim 1, further comprising a solvent. The coloring composition according to claim 1 or 2, further comprising a yellow colorant or a green colorant. The coloring composition according to any one of claims 1 to 3, and a coloring curable composition containing a polymerizable compound. The color-curable composition according to claim 4, further comprising a polymerization initiator. A color filter formed from the coloring composition according to any one of claims 1 to 3 or the coloring curable composition according to claim 4 or 5. A liquid crystal display device including the color filter according to claim 6. A compound represented by the formula (IZ6-B).

[In the formula (IZ6-B),
A ^{c +} represents a c-valent metal cation.
b represents an integer of 1 or more.
c represents an integer of 2 to 10.
d represents an integer of 1 or more.
L ¹ represents −CO−.
R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 and R ^13BZ6 are independent of each other, hydrogen atom, -CO-R ^102BZ6 , -COO-R ^101BZ6 , -OCO-R ^102BZ6 , -COCO-R ^102BZ6 , -O-R ^102BZ6 , -SO _2- R ^101BZ6 , -SO ₂ N (R ^102BZ6 ) ₂ ^{, -CON} (R 102BZ6) ₂ , -N (R ^102BZ6 ) ₂ , -NHCO-R ^{102BZ6 , -NHCO-N (R 102BZ6)} 2, -NHCOOR 102BZ6, -OCON (R 102BZ6) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , -SO 3 -, -CO 2 ^—— Represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^2BZ6 and R ^3BZ6 , R ^3BZ6 and R ^4BZ6 , R ^4BZ6 and R ^5BZ6 , and R ^12BZ6 and R ^13BZ6 may be coupled to each other to form a ring, respectively.
R ^101BZ6 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent independently of each other.
R ^102BZ6 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent, independently of each other.
Formulas (IZ6-B') and formulas (IZ6-B'') represent the substructures of formula (IZ6-B), respectively, Ac ⁺ , b, c, d, R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 , R ^13BZ6 and L ¹ represent the same as those in the equation (IZ6-B).
M represents a hydrogen atom or an alkali metal atom.
If there are multiple R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 , R ^13BZ6 , R ^101BZ6 , R ^102BZ6 , L ¹ , M, c or ^{Ac +} , they are the same. It may be present or different.
R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 , R ^13BZ6 , R ^101BZ6 and R ^102BZ6 satisfy at least one of (rb-i) to (rb-iii). ^{and, R 1BZ6, R 2BZ6, R} 3BZ6, R 4BZ6, R 5BZ6, R 11BZ6, R 12BZ6, R 13BZ6, R 101BZ6 and -SO ₃ R ^102BZ6 has ^- or -CO ₂ ^- total number of is a ..
At least one ^{(rb-i) R 1BZ6,} R 2BZ6, R 3BZ6, R 4BZ6, R 5BZ6, R 11BZ6, R 12BZ6 and R ^13BZ6 is, -SO ₃ ^- or -CO ₂ ^- a.
^(Rb -ii) At least one of R 1BZ6, R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 and R ^13BZ6 is -CO-R ^102BZ6 , -COO-R ^101BZ6 , -OCO-R ^102BZ6. , -COCO-R ^102BZ6 , -O-R ^102BZ6 , -SO ₂ -R ^101BZ6 , -SO ₂ N (R ^102BZ6 ) ₂ ^{, -CON} (R 102BZ6) ₂ , -N (R ^102BZ6 ) ₂ , -NHCO-R ^102BZ6 , -NHCO-N (R ^102BZ6 ) ₂ , -NHCOOR ^102BZ6 , or -OCON (R ^102BZ6 ) ₂ .
The R ^101BZ6 and R ^102BZ6 is, -SO ₃ ^- or -CO ₂ ^- 1 to 40 carbon atoms having a hydrocarbon group or a -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
At least one ^{(rb-iii) R 1BZ6,} R 2BZ6, R 3BZ6, R 4BZ6, R 5BZ6, R 11BZ6, R 12BZ6 and R ^13BZ6 is, -SO ₃ ^- 1 to 40 carbon atoms having a ^- or -CO ₂ hydrocarbon group or a -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
a represents an integer of 1 to 10. When a plurality of a exist, they may be the same or different.
The absolute value of the negative valence of the substructure represented by the formula (IZ6-B') and the positive valence of the substructure represented by the formula (IZ6-B ″) are the same.
The wavy line represents an E-form or a Z-form. ] R ^11BZ6 is an aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a phenyl group which may have a substituent, a naphthyl group which may have a substituent, and a substituent. Claimed to be a tetrahydronaphthyl group which may have a group, a thienyl group which may have a substituent, a frill group which may have a substituent or a pyridinyl group which may have a substituent. Item 8. The compound according to Item 8. The compound according to claim 8, wherein the compound represented by the formula (IZ6-B) is a compound represented by the formula (IZ6-C).

[In the formula (IZ6-C),
A ^{c +} , b, c, d, L ¹ and wavy lines have the same meanings as described above.
L ² is, -CO- or -SO ₂ - represents a.
R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 and R ^14CZ6 are independent of each other, hydrogen atom, -CO-R ^102CZ6 , -COO-R ^101CZ6 , -OCO-R ^102CZ6 , -COCO- R ^102CZ6 , ^{-OR 102CZ6} , -SO ₂ -R ^101CZ6 , -SO ₂ N (R ^102CZ6 ) ₂ ^{, -CON} (R 102CZ6) ₂ , -N (R ^102CZ6 ) ₂ , -NHCO-R ^102CZ6 , -NHCO _{^{-N (R 102CZ6) 2, -NHCOOR}} 102CZ6, -OCON (R 102CZ6) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , -SO 3 -, -CO 2 -, substituted It represents a hydrocarbon group having 1 to 40 carbon atoms which may have a group or a heterocyclic group which may have a substituent.
R ^2CZ6 and R ^3CZ6 , R ^3CZ6 and R ^4CZ6 , and R ^4CZ6 and R ^5CZ6 may be bonded to each other to form a ring, respectively.
R ^101CZ6 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent independently of each other.
R ^102CZ6 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent, independently of each other.
M represents the same meaning as described above.
Formulas (IZ6-C') and formulas (IZ6-C'') represent the substructures of formula (IZ6-C), respectively, Ac ⁺ , b, c, d, R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 , R ^14CZ6 , L ¹ and L ² represent the same as those in the equation (IZ6-C).
If there are multiple R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 , R ^14CZ6 , R ^101CZ6 , R ^102CZ6 , L ¹ , L ² , M, c or ^{Ac +} , they are the same. It may be present or different.
R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 , R ^14CZ6 , R ^101CZ6 and R ^102CZ6 satisfy at least one of (rc-i) to (rc-iii). ^{R 1CZ6, R 2CZ6, R 3CZ6} , R 4CZ6, R 5CZ6, R 11CZ6, R 14CZ6, R 101CZ6 and -SO ₃ R ^102CZ6 has ^- or -CO ₂ ^- total number of is a.
At least one ^{(rc-i) R 1CZ6,} R 2CZ6, R 3CZ6, R 4CZ6, R 5CZ6, R 11CZ6 and R ^14CZ6 is, -SO ₃ ^- or -CO ₂ ^- a.
(Rc-ii) At ^{least one of R 1CZ6} , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 and R ^14CZ6 is -CO-R ^102CZ6 , -COO-R ^101CZ6 , -OCO-R ^102CZ6 , -COCO -R ^102CZ6 , -O-R ^102CZ6 , -SO ₂ -R ^101CZ6 , -SO ₂ N (R ^102CZ6 ) ₂ ^{, -CON} (R 102CZ6) ₂ , -N (R ^102CZ6 ) ₂ , -NHCO-R ^102CZ6 ,- _{^{NHCO-N (R 102CZ6) 2}} , -NHCOOR 102CZ6, or -OCON (R ^102CZ6) a _2, wherein R ^101CZ6 and R ^102CZ6 is, -SO ₃ ^- 1 to 40 carbon atoms having a ^- or -CO ₂ hydrocarbon group or a -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
^{(Rc-iii) R 1CZ6,} R 2CZ6, R 3CZ6, R 4CZ6, at least one of R ^5CZ6, R ^11CZ6 and R ^14CZ6 is, -SO ₃ ^- or -CO ₂ ^- Number 1-40 hydrocarbon group having a carbon having or -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
a represents the same meaning as in the formula (IZ6-B). When a plurality of a exist, they may be the same or different.
The absolute value of the negative valence of the substructure represented by the formula (IZ6-C') and the positive valence of the substructure represented by the formula (IZ6-C ″) are the same. ] The compound according to claim 10, wherein R ^11CZ6 and R ^14CZ6 are the same group, and L ¹ and L ^{2 are the same group.} The compound according to claim 10, wherein L ¹ and L ^{2 are −CO−.} R ^11CZ6 and R ^14CZ6 have an aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a phenyl group which may have a substituent, and a naphthyl which may have a substituent. A group, a tetrahydronaphthyl group which may have a substituent, a thienyl group which may have a substituent, a frill group which may have a substituent or a pyridinyl group which may have a substituent. The compound according to any one of claims 10 to 12. The compound according to claim 8, wherein the compound represented by the formula (IZ6-B) is a compound represented by the formula (IZ6-D).

[In the formula (IZ6-D),
A ^{c +} , b, c, d, L ¹ and wavy lines have the same meanings as described above.
R ^20DZ6 and R ^30DZ6 combine to form ring Q.
Ring Q may have a substituent and has 5 to 7 ring members, and the ring Q may be a hydrocarbon ring or a heterocycle. Ring Q is condensed with a monocycle selected from a hydrocarbon ring and a heterocycle, which may have a substituent having 5 to 7 ring members, or a condensed ring obtained by condensing two or more of the monocycles. You may.
R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 and R ^11DZ6 are independent of each other, hydrogen atom, -CO-R ^102DZ6 , -COO-R ^101DZ6 , -OCO-R ^102DZ6 , -COCO-R ^102DZ6 , -O-R ^102DZ6 , -SO ₂ -R ^101DZ6 , -SO ₂ N (R ^102DZ6 ) ₂ ^{, -CON} (R 102DZ6) ₂ , -N (R ^102DZ6 ) ₂ , -NHCO-R ^102DZ6 , -NHCO-N ( _{^{R 102DZ6) 2, -NHCOOR 102DZ6,}} -OCON (R 102DZ6) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , -SO 3 -, -CO 2 -, have a substituent It represents a hydrocarbon group having 1 to 40 carbon atoms or a heterocyclic group which may have a substituent.
R ^2DZ6 and R ^3DZ6 , R ^3DZ6 and R ^4DZ6 , and R ^4DZ6 and R ^5DZ6 may be coupled to each other to form a ring, respectively.
R ^101DZ6 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent independently of each other.
R ^102DZ6 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent, independently of each other.
M represents the same meaning as described above.
Formulas (IZ6-D') and formulas (IZ6-D'') represent the substructures of formula (IZ6-D), respectively, Ac ⁺ , b, c, d, R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 , R ^11DZ6 , R ^20DZ6 , R ^30DZ6 and L ¹ represent the same as those in the equation (IZ6-D).
If there are multiple R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 , R ^11DZ6 , R ^101DZ6 , R ^102DZ6 , L ¹ , M, R ^20DZ6 , R ^30DZ6 , ring Q, c or ^{Ac +, they are} They may be the same or different.
R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 , R ^11DZ6 , R ^101DZ6 , R ^102DZ6 and ring Q satisfy at least one of (rd-i) to (rd-iv). ^{R 1DZ6, R 2DZ6, R 3DZ6} , R 4DZ6, R 5DZ6, R 11DZ6, R 101DZ6, R 102DZ6 and -SO ₃ having the ring Q ^- or -CO ₂ ^- total number of is a.
At least one ^{(rd-i) R 1DZ6,} R 2DZ6, R 3DZ6, R 4DZ6, R 5DZ6 and R ^11DZ6 is, -SO ₃ ^- or -CO ₂ ^- a.
^(Rd -ii) At least one of R 1DZ6, R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 and R ^11DZ6 is -CO-R ^102DZ6 , -COO-R ^101DZ6 , -OCO-R ^102DZ6 , -COCO-R ^102DZ6. , ^{-OR 102DZ6} , -SO ₂ -R ^101DZ6 , -SO ₂ N (R ^102DZ6 ) ₂ ^{, -CON} (R 102DZ6) ₂ , -N (R ^102DZ6 ) ₂ , -NHCO-R ^102DZ6 , -NHCO-N _{^{(R 102DZ6) 2, -NHCOOR 102DZ6}} , or -OCON (R ^102DZ6) a _2, wherein R ^101DZ6 and R ^102DZ6 is, -SO ₃ ^- or -CO ₂ ^- number 1-40 hydrocarbon group having a carbon having or -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
^{(Rd-iii) R 1DZ6,} R 2DZ6, R 3DZ6, R 4DZ6, at least one of R ^5DZ6 and R ^11DZ6 is, -SO ₃ ^- or -CO ₂ ^- hydrocarbon radical or -SO having 1 to 40 carbon atoms having a ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
(Rd-iv) ring Q is, -SO ₃ ^- having ^- or -CO _2.
a represents the same meaning as in the formula (IZ6-B). When a plurality of a exist, they may be the same or different.
The absolute value of the negative valence of the substructure represented by the formula (IZ6-D') and the positive valence of the substructure represented by the formula (IZ6-D ″) are the same. ] R ^11DZ6 is an aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a phenyl group which may have a substituent, a naphthyl group which may have a substituent, and a substituent. Claimed to be a tetrahydronaphthyl group which may have a group, a thienyl group which may have a substituent, a frill group which may have a substituent or a pyridinyl group which may have a substituent. Item 4. The compound according to Item 14. The compound according to claim 14, wherein the compound represented by the formula (IZ6-D) is a compound represented by the formula (IZ6-E).

[In the formula (IZ6-E),
A ^{c +} , b, c, d, L ¹ and wavy lines have the same meanings as described above.
R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 and R ^11EZ6 are independent of each other, hydrogen atom, -CO-R ^102EZ6 , -COO-R ^101EZ6 , -OCO-R ^102EZ6 , -COCO-R ^102EZ6 , -O-R ^102EZ6 , -SO _2- R ^101EZ6 , -SO ₂ N (R ^102EZ6 ) ₂ ^{, -CON} (R 102EZ6) ₂ , -N (R ^102EZ6 ) ₂ , -NHCO-R ^{102EZ6 , -NHCO-N (R 102EZ6)} 2, -NHCOOR 102EZ6, -OCON (R 102EZ6) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , -SO 3 -, -CO 2 ^—— Represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^2EZ6 and R ^3EZ6 , R ^3EZ6 and R ^4EZ6 , and R ^4EZ6 and R ^5EZ6 may be bonded to each other to form a ring, respectively.
R ^101EZ6 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent independently of each other.
R ^102EZ6 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent, independently of each other.
M represents the same meaning as described above.
Formulas (IZ6-E') and formulas (IZ6-E'') represent the substructures of formula (IZ6-E), respectively, Ac ⁺ , b, c, d, R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 , R ^11EZ6 and L ¹ represent the same as those in the equation (IZ6-E).
If there are multiple R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 , R ^11EZ6 , R ^101EZ6 , R ^102EZ6 , L ¹ , M, c or ^{Ac +} , they are the same. It may be present or different.
R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 , R ^11EZ6 , R ^101EZ6 and R ^102EZ6 satisfy at least one of (re-i) to (re-iii). ^{and, R 1EZ6, R 2EZ6, R} 3EZ6, R 4EZ6, R 5EZ6, R 6EZ6, R 7EZ6, R 11EZ6, R 101EZ6 and -SO ₃ R ^102EZ6 has ^- or -CO ₂ ^- total number of is a in ..
At least one of ^{(re-i) R 1EZ6,} R 2EZ6, R 3EZ6, R 4EZ6, R 5EZ6, R 6EZ6, R 7EZ6 and R ^11EZ6 is, -SO ₃ ^- or -CO ₂ ^- a.
(Re-ii) At ^{least one of R 1EZ6} , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 and R ^11EZ6 is -CO-R ^102EZ6 , -COO-R ^101EZ6 , -OCO-R ^102EZ6. , -COCO-R ^102EZ6 , -O-R ^102EZ6 , -SO ₂ -R ^101EZ6 , -SO ₂ N (R ^102EZ6 ) ₂ ^{, -CON} (R 102EZ6) ₂ , -N (R ^102EZ6 ) ₂ , -NHCO-R ^{102EZ6, -NHCO-N (R 102EZ6} ) 2, -NHCOOR 102EZ6, or -OCON a (R ^102EZ6) _2, wherein R ^101EZ6 and R ^102EZ6 is, -SO ₃ ^- or -CO ₂ ^- carbons having 1 40 hydrocarbon group or -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
At least one of ^{(re-iii) R 1EZ6,} R 2EZ6, R 3EZ6, R 4EZ6, R 5EZ6, R 6EZ6, R 7EZ6 and R ^11EZ6 is, -SO ₃ ^- 1 to 40 carbon atoms having a ^- or -CO ₂ hydrocarbon group or a -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However the hydrocarbon group or heterocyclic group, -SO ₃ ^- and -CO ₂ ^- may have other substituents.
a represents the same meaning as in the formula (IZ6-D). When a plurality of a exist, they may be the same or different.
The absolute value of the negative valence of the substructure represented by the formula (IZ6-E') and the positive valence of the substructure represented by the formula (IZ6-E ″) are the same. ] R ^11EZ6 is an aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a phenyl group which may have a substituent, a naphthyl group which may have a substituent, and a substituent. Claimed to be a tetrahydronaphthyl group which may have a group, a thienyl group which may have a substituent, a frill group which may have a substituent or a pyridinyl group which may have a substituent. Item 16. The compound according to Item 16.