CN113376963A - Coloring composition and compound - Google Patents

Abstract

The present invention relates to a coloring composition and a compound. The present invention provides a coloring composition comprising: a compound represented by formula (IZ3), and an alkali-soluble resin.

Description

Coloring composition and compound

The present application is a divisional application of an invention application having an application date of 2017, 8/31/2017, an application number of 201710776175.5, and an invention name of "coloring composition and compound".

Technical Field

The present invention relates to a coloring composition and a compound.

Background

The colored curable composition has been used for producing a color filter (color filter) that can be used in a display device such as a liquid crystal display device or an electroluminescence display device. As a colorant contained in this colored curable composition, c.i. pigment yellow 185 is known (japanese patent laid-open No. 2016-66020).

Disclosure of Invention

The present invention includes the following inventions.

[1] A coloring composition comprising:

at least one selected from the group consisting of a compound represented by the formula (IZ1), a compound represented by the formula (IZ2), a compound represented by the formula (IZ3), a compound represented by the formula (IZ4), a compound represented by the formula (IZ5) and a compound represented by the formula (IZ6), and

at least one of a resin and a solvent.

[ formula (IZ1), R ^O1Z1Represents a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group.

R^1Z1、R^2Z1、R^3Z1、R^4Z1、R^5Z1、R^6Z1And R^7Z1Independently of one another, represents a hydrogen atom, -CO-R^102Z1、-COO-R^101Z1、-OCO-R^102Z1、-COCO-R^102Z1、-O-R^102Z1、-SO₂-R^101Z1、-SO₂N(R^102Z1)₂、-CON(R^102Z1)₂、-N(R^102Z1)₂、-NHCO-R^102Z1、-NHCO-N(R^102Z1)₂、-NHCOOR^102Z1、-OCON(R^102Z1)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.

R^2Z1And R^3Z1、R^3Z1And R^4Z1And R^4Z1And R^5Z1Each of which may be bonded to each other to form a ring.

R^101Z1The alkyl group may have a substituent and has 1 to 40 carbon atoms, or a heterocyclic group may have a substituent.

R^102Z1Represents a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group.

M represents a hydrogen atom or an alkali metal atom.

R^101Z1、R^102Z1And when there are a plurality of M, they may be the same or different. The wavy line indicates the E-body or the Z-body.]

[ formula (IZ2), R^CO1Z2And R^CO2Z2Independently of one another represent-O-R^O1Z2or-NR^N1Z2R^N2Z2。R^N1Z2、R^N2Z2、R^1Z2、R^2Z2、R^3Z2、R^4Z2And R^5Z2Independently of one another, represents a hydrogen atom, -CO-R^102Z2、-COO-R^101Z2、-OCO-R^102Z2、-COCO-R^102Z2、-O-R^102Z2、-SO₂-R^101Z2、-SO₂N(R^102Z2)₂、-CON(R^102Z2)₂、-N(R^102Z2)₂、-NHCO-R^102Z2、-NHCO-N(R^102Z2)₂、-NHCOOR^102Z2、-OCON(R^102Z2)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent. R^2Z2And R^3Z2、R^3Z2And R^4Z2And R^4Z2And R^5Z2Each of which may be bonded to each other to form a ring.

R^101Z2The alkyl group may have a substituent and has 1 to 40 carbon atoms, or a heterocyclic group may have a substituent. R ^O1Z2And R^102Z2Independently represent a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group. M represents a hydrogen atom or an alkali metal atom. R^O1Z2、R^N1Z2、R^N2Z2、R^101Z2、R^102Z2And when there are a plurality of M, they may be the same or different. The wavy line indicates the E-body or the Z-body.]

[ formula (IZ3), R^1Z3、R^2Z3、R^3Z3、R^4Z3、R^5Z3、R^6Z3And R^7Z3Independently of one another, represents a hydrogen atom, -CO-R^102Z3、-COO-R^101Z3、-OCO-R^102Z3、-COCO-R^102Z3、-O-R^102Z3、-SO₂-R^101Z3、-SO₂N(R^102Z3)₂、-CON(R^102Z3)₂、-N(R^102Z3)₂、-NHCO-R^102Z3、-NHCO-N(R^102Z3)₂、-NHCOOR^102Z3、-OCON(R^102Z3)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent. R^2Z3And R^3Z3、R^3Z3And R^4Z3And R^4Z3And R^5Z3Each of which may be bonded to each other to form a ring. R^101Z3The alkyl group may have a substituent and has 1 to 40 carbon atoms, or a heterocyclic group may have a substituent. R^102Z3Represents a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group. M represents a hydrogen atom or an alkali metal atom. R^101Z3、R^102Z3And when there are a plurality of M, they may be the same or different. The wavy line indicates the E-body or the Z-body.]

[ formula (IZ4), R^N1Z4And R^N2Z4Independently of one another represent-CO-R^102Z4、-COO-R^101Z4、-OCO-R^102Z4、-COCO-R^102Z4、-O-R^102Z4、-SO₂-R^101Z4、-SO₂N(R^102Z4)₂、-CON(R^102Z4)₂、-N(R^102Z4)₂、-NHCO-R^102Z4、-NHCO-N(R^102Z4)₂、-NHCOOR^102Z4、-OCON(R^102Z4)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.

R^1Z4、R^2Z4、R^3Z4、R^4Z4、R^5Z4、R^6Z4And R^7Z4Independently of one another, represents a hydrogen atom, -CO-R^102Z4、-COO-R^101Z4、-OCO-R^102Z4、-COCO-R^102Z4、-O-R^102Z4、-SO₂-R^101Z4、-SO₂N(R^102Z4)₂、-CON(R^102Z4)₂、-N(R^102Z4)₂、-NHCO-R^102Z4、-NHCO-N(R^102Z4)₂、-NHCOOR^102Z4、-OCON(R^102Z4)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent. R^2Z4And R^3Z4、R^3Z4And R^4Z4And R^4Z4And R^5Z4Each of which may be bonded to each other to form a ring. R^101Z4The alkyl group may have a substituent and has 1 to 40 carbon atoms, or a heterocyclic group may have a substituent. R^102Z4Represents a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group. M represents a hydrogen atom or an alkali metal atom. R^101Z4、R^102Z4And when there are a plurality of M, they may be the same or different. The wavy line indicates the E-body or the Z-body.]

[ formula (IZ5), R^N1Z5represents-CO-R^102Z5、-COO-R^101Z5、-OCO-R^102Z5、-COCO-R^102Z5、-O-R^102Z5、-SO₂-R^101Z5、-SO₂N(R^102Z5)₂、-CON(R^102Z5)₂、-N(R^102Z5)₂、-NHCO-R^102Z5、-NHCO-N(R^102Z5)₂、-NHCOOR^102Z5、-OCON(R^102Z5)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M, optionally substituted carbon atomA hydrocarbon group or a heterocyclic group which may have a substituent, wherein the number of the hydrocarbon groups is 1 to 40.

R^1Z5、R^2Z5、R^3Z5、R^4Z5、R^5Z5、R^6Z5And R^7Z5Independently of one another, represents a hydrogen atom, -CO-R^102Z5、-COO-R^101Z5、-OCO-R^102Z5、-COCO-R^102Z5、-O-R^102Z5、-SO₂-R^101Z5、-SO₂N(R^102Z5)₂、-CON(R^102Z5)₂、-N(R^102Z5)₂、-NHCO-R^102Z5、-NHCO-N(R^102Z5)₂、-NHCOOR^102Z5、-OCON(R^102Z5)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group, R is^2Z5And R^3Z5、R^3Z5And R^4Z5And R^4Z5And R^5Z5Each of which may be bonded to each other to form a ring, R^2Z5、R^3Z5、R^4Z5And R^5Z5At least one of which is-CO-R ^102Z5、-COO-R^101Z5、-OCO-R^102Z5、-COCO-R^102Z5、-O-R^102Z5、-SO₂-R^101Z5、-SO₂N(R^102Z5)₂、-CON(R^102Z5)₂、-N(R^102Z5)₂、-NHCO-R^102Z5、-NHCO-N(R^102Z5)₂、-NHCOOR^102Z5、-OCON(R^102Z5)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent, or R is^2Z5And R^3Z5、R^3Z5And R^4Z5And R^4Z5And R^5Z5At least one group of them is bonded to form a ring.

R^101Z5The alkyl group may have a substituent and has 1 to 40 carbon atoms, or a heterocyclic group may have a substituent.

R^102Z5Represents a hydrogen atom, may haveThe substituent is a hydrocarbon group having 1 to 40 carbon atoms or a heterocyclic group which may have a substituent.

M represents a hydrogen atom or an alkali metal atom.

R^101Z5、R^102Z5And when there are a plurality of M, they may be the same or different. The wavy line indicates the E-body or the Z-body.]

[ in the formula (IZ6), D represents a structure having an isoindoline skeleton. Z represents-SO₃ ^-or-CO₂ ^-。A^c+Represents a metal cation having a valence of c. a represents an integer of 1 to 10.

b represents an integer of 1 or more. c represents an integer of 2 to 10. d represents an integer of 1 or more. D. Z, a or A^c+When there are a plurality of them, they may be the same or different. The formula (I 'Z6) and the formula (I' Z6) respectively represent partial structures of the formula (IZ6), D, Z, A^c+A, b, c and d represent the same meanings as the corresponding symbols in formula (IZ 6).

The partial structure represented by the formula (I' Z6) has the same negative valence as the partial structure represented by the formula (I "Z6) has the same positive valence in absolute value. ]

[2] A colored curable composition comprising a polymerizable compound and the colored composition according to [1 ].

[3] A color filter comprising the colored composition according to [1] or the colored curable composition according to [2] or [11 ].

[4] A liquid crystal display device comprising the color filter according to [3 ].

[5] A compound represented by the formula (Z1-B).

[ formula (IZ1-B) wherein R^O11Z1Represents a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group.

R^1Z1、R^21Z1、R^31Z1、R^41Z1、R^51Z1、R^61Z1And R^71Z1Independently of one another, represents a hydrogen atom, -CO-R^102Z1、-COO-R^101Z1、-OCO-R^102Z1、-COCO-R^102Z1、-O-R^102Z1、-SO₂-R^101Z1、-SO₂N(R^102Z1)₂、-CON(R^102Z1)₂、-N(R^102Z1)₂、-NHCO-R^102Z1、-NHCO-N(R^102Z1)₂、-NHCOOR^102Z1、-OCON(R^102Z1)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent. R^21Z1And R^31Z1、R^31Z1And R^41Z1And R^41Z1And R^51Z1Each of which may be bonded to each other to form a ring. Wherein R is^21Z1、R^31Z1、R^41Z1And R^51Z1At least one of which is-CO-R^102Z1、-COO-R^101Z1、-OCO-R^102Z1、-COCO-R^102Z1、-O-R^102Z1、-SO₂-R^101Z1、-SO₂N(R^102Z1)₂、-CON(R^102Z1)₂、-N(R^102Z1)₂、-NHCO-R^102Z1、-NHCO-N(R^102Z1)₂、-NHCOOR^102Z1、-OCON(R^102Z1)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a C1-40 hydrocarbon group which may have a substituent or may have a substituentA heterocyclic radical of a substituent, or, R^21Z1And R^31Z1、R^31Z1And R^41Z1And R^41Z1And R^51Z1At least one group of them is bonded to form a ring. R^101Z1The alkyl group may have a substituent and has 1 to 40 carbon atoms, or a heterocyclic group may have a substituent.

R^102Z1Represents a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group. M represents a hydrogen atom or an alkali metal atom.

R^101Z1、R^102Z1And when there are a plurality of M, they may be the same or different. The wavy line indicates the E-body or the Z-body.]

[6] A compound represented by the formula (IZ 2-B).

[ formula (IZ2-B) wherein R^CO11Z2And R^CO21Z2Independently of one another represent-O-R^O1Z2or-NR^N1Z2R^N2Z2，R^CO11Z2And R^CO21Z2At least one of which is-NR^N1Z2R^N2Z2。

R^N1Z2、R^N2Z2、R^1Z2、R^21Z2、R^31Z2、R^41Z2And R^51Z2Independently of one another, represents a hydrogen atom, -CO-R^102Z2、-COO-R^101Z2、-OCO-R^102Z2、-COCO-R^102Z2、-O-R^102Z2、-SO₂-R^101Z2、-SO₂N(R^102Z2)₂、-CON(R^102Z2)₂、-N(R^102Z2)₂、-NHCO-R^102Z2、-NHCO-N(R^102Z2)₂、-NHCOOR^102Z2、-OCON(R^102Z2)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group, R is^21Z2And R^31Z2、R^31Z2And R^41Z2And R^41Z2And R^51Z2Each of which may be bonded to each other to form a ring, R^21Z2、R^31Z2、R^41Z2And R^51Z2At least one of which is-CO-R^102Z2、-COO-R^101Z2、-OCO-R^102Z2、-COCO-R^102Z2、-O-R^102Z2、-SO₂-R^101Z2、-SO₂N(R^102Z2)₂、-CON(R^102Z2)₂、-N(R^102Z2)₂、-NHCO-R^102Z2、-NHCO-N(R^102Z2)₂、-NHCOOR^102Z2、-OCON(R^102Z2)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent, or R is^21Z2And R^31Z2、R^31Z2And R^41Z2And R^41Z2And R^51Z2At least one group of them is bonded to form a ring.

R^101Z2The alkyl group may have a substituent and has 1 to 40 carbon atoms, or a heterocyclic group may have a substituent.

R^O1Z2And R^102Z2Independently represent a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group.

M represents a hydrogen atom or an alkali metal atom.

R^O1Z2、R^N1Z2、R^N2Z2、R^101Z2、R^102Z2And when there are a plurality of M, they may be the same or different. The wavy line indicates the E-body or the Z-body.]

[7] A compound represented by the formula (IZ 3-B).

[ formula (IZ3-B) wherein R^1Z3、R^21Z3、R^31Z3、R^41Z3、R^51Z3、R^61Z3And R^71Z3Independently of one another represent hydrogen atomSon, -CO-R^102Z3、-COO-R^101Z3、-OCO-R^102Z3、-COCO-R^102Z3、-O-R^102Z3、-SO₂-R^101Z3、-SO₂N(R^102Z3)₂、-CON(R^102Z3)₂、-N(R^102Z3)₂、-NHCO-R^102Z3、-NHCO-N(R^102Z3)₂、-NHCOOR^102Z3、-OCON(R^102Z3)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.

R^21Z3And R^31Z3、R^31Z3And R^41Z3And R^41Z3And R^51Z3Each of which may be bonded to each other to form a ring.

Wherein R is^21Z3、R^31Z3、R^41Z3And R^51Z3At least one of which is-CO-R^102Z3、-COO-R^101Z3、-OCO-R^102Z3、-COCO-R^102Z3、-O-R^102Z3、-SO₂-R^101Z3、-SO₂N(R^102Z3)₂、-CON(R^102Z3)₂、-N(R^102Z3)₂、-NHCO-R^102Z3、-NHCO-N(R^102Z3)₂、-NHCOOR^102Z3、-OCON(R^102Z3)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent, or R is^21Z3And R^31Z3、R^31Z3And R^41Z3And R^41Z3And R^51Z3At least one group of them is bonded to form a ring. R^101Z3The alkyl group may have a substituent and has 1 to 40 carbon atoms, or a heterocyclic group may have a substituent. R^102Z3Represents a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group. M represents a hydrogen atom or an alkali metal atom.

R^101Z3、R^102Z3And in the case where there are a plurality of M,they may be the same or different. The wavy line indicates the E-body or the Z-body. ]

[8] A compound represented by the formula (IZ 4).

[ formula (IZ4), R^N1Z4And R^N2Z4Independently of one another represent-CO-R^102Z4、-COO-R^101Z4、-OCO-R^102Z4、-COCO-R^102Z4、-O-R^102Z4、-SO₂-R^101Z4、-SO₂N(R^102Z4)₂、-CON(R^102Z4)₂、-N(R^102Z4)₂、-NHCO-R^102Z4、-NHCO-N(R^102Z4)₂、-NHCOOR^102Z4、-OCON(R^102Z4)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.

R^1Z4、R^2Z4、R^3Z4、R^4Z4、R^5Z4、R^6Z4And R^7Z4Independently of one another, represents a hydrogen atom, -CO-R^102Z4、-COO-R^101Z4、-OCO-R^102Z4、-COCO-R^102Z4、-O-R^102Z4、-SO₂-R^101Z4、-SO₂N(R^102Z4)₂、-CON(R^102Z4)₂、-N(R^102Z4)₂、-NHCO-R^102Z4、-NHCO-N(R^102Z4)₂、-NHCOOR^102Z4、-OCON(R^102Z4)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent. R^2Z4And R^3Z4、R^3Z4And R^4Z4And R^4Z4And R^5Z4Each of which may be bonded to each other to form a ring. R^101Z4The alkyl group may have a substituent and has 1 to 40 carbon atoms, or a heterocyclic group may have a substituent. R^102Z4Represents a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group. M represents a hydrogen atom or an alkali metal atom. R^101Z4、R^102Z4And when there are a plurality of M, they may be the same or different. The wavy line indicates the E-body or the Z-body.]

[9] A compound represented by the formula (IZ 5).

[ formula (IZ5), R^N1Z5represents-CO-R^102Z5、-COO-R^101Z5、-OCO-R^102Z5、-COCO-R^102Z5、-O-R^102Z5、-SO₂-R^101Z5、-SO₂N(R^102Z5)₂、-CON(R^102Z5)₂、-N(R^102Z5)₂、-NHCO-R^102Z5、-NHCO-N(R^102Z5)₂、-NHCOOR^102Z5、-OCON(R^102Z5)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.

R^1Z5、R^2Z5、R^3Z5、R^4Z5、R^5Z5、R^6Z5And R ^7Z5Independently of one another, represents a hydrogen atom, -CO-R^102Z5、-COO-R^101Z5、-OCO-R^102Z5、-COCO-R^102Z5、-O-R^102Z5、-SO₂-R^101Z5、-SO₂N(R^102Z5)₂、-CON(R^102Z5)₂、-N(R^102Z5)₂、-NHCO-R^102Z5、-NHCO-N(R^102Z5)₂、-NHCOOR^102Z5、-OCON(R^102Z5)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group, R is^2Z5And R^3Z5、R^3Z5And R^4Z5And R^4Z5And R^5Z5Each of which may be bonded to each other to form a ring, R^2Z5、R^3Z5、R^4Z5And R^5Z5At least one of which is-CO-R^102Z5、-COO-R^101Z5、-OCO-R^102Z5、-COCO-R^102Z5、-O-R^102Z5、-SO₂-R^101Z5、-SO₂N(R^102Z5)₂、-CON(R^102Z5)₂、-N(R^102Z5)₂、-NHCO-R^102Z5、-NHCO-N(R^102Z5)₂、-NHCOOR^102Z5、-OCON(R^102Z5)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent, or R is^2Z5And R^3Z5、R^3Z5And R^4Z5And R^4Z5And R^5Z5At least one group of them is bonded to form a ring.

R^101Z5The alkyl group may have a substituent and has 1 to 40 carbon atoms, or a heterocyclic group may have a substituent. R^102Z5Represents a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group. M represents a hydrogen atom or an alkali metal atom. R^101Z5、R^102Z5And when there are a plurality of M, they may be the same or different. The wavy line indicates the E-body or the Z-body.]

[10] A compound represented by the formula (IZ 6).

[ formula (IZ6)Wherein D represents a structure having an isoindoline skeleton. Z represents-SO₃ ^-or-CO₂ ^-。A^c+Represents a metal cation having a valence of c. a represents an integer of 1 to 10.

b represents an integer of 1 or more. c represents an integer of 2 to 10.

d represents an integer of 1 or more. D. Z, a or A^c+When there are a plurality of them, they may be the same or different. The formula (I 'Z6) and the formula (I' Z6) respectively represent partial structures of the formula (IZ6), D, Z, A^c+A, b, c and d represent the same meanings as the corresponding symbols in formula (IZ 6).

The partial structure represented by the formula (I' Z6) has the same negative valence as the partial structure represented by the formula (I "Z6) has the same positive valence in absolute value. ]

[11] The colored curable composition according to [2], further comprising a polymerization initiator.

The invention also includes:

1. a coloring composition comprising:

at least one of a resin and a solvent, and

1 or more selected from the group consisting of a compound represented by formula (IZ1), a compound represented by formula (IZ2), a compound represented by formula (IZ3), a compound represented by formula (IZ4), a compound represented by formula (IZ5), and a compound represented by formula (IZ 6);

in the formula (IZ1), R^O1Z1Represents a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group;

R^1Z1、R^2Z1、R^3Z1、R^4Z1、R^5Z1、R^6Z1and R^7Z1Independently of one another, represents a hydrogen atom, -CO-R^102Z1、-COO-R^101Z1、-OCO-R^102Z1、-COCO-R^102Z1、-O-R^102Z1、-SO₂-R^101Z1、-SO₂N(R^102Z1)₂、-CON(R^102Z1)₂、-N(R^102Z1)₂、-NHCO-R^102Z1、-NHCO-N(R^102Z1)₂、-NHCOOR^102Z1、-OCON(R^102Z1)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent;

R^2Z1And R^3Z1、R^3Z1And R^4Z1And R^4Z1And R^5Z1May be bonded to each other to form a ring;

R^101Z1represents an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group;

R^102Z1represents a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group;

m represents a hydrogen atom or an alkali metal atom;

R^101Z1、R^102Z1and when there are a plurality of M, they may be the same or different; the wavy line represents the E or Z body;

in the formula (IZ2), R^CO1Z2And R^CO2Z2Independently of one another represent-O-R^O1Z2or-NR^N1Z2R^N2Z2；R^N1Z2、R^N2Z2、R^1Z2、R^2Z2、R^3Z2、R^4Z2And R^5Z2Independently of one another, represents a hydrogen atom, -CO-R^102Z2、-COO-R^101Z2、-OCO-R^102Z2、-COCO-R^102Z2、-O-R^102Z2、-SO₂-R^101Z2、-SO₂N(R^102Z2)₂、-CON(R^102Z2)₂、-N(R^102Z2)₂、-NHCO-R^102Z2、-NHCO-N(R^102Z2)₂、-NHCOOR^102Z2、-OCON(R^102Z2)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent;

R^2Z2and R^3Z2、R^3Z2And R^4Z2And R^4Z2And R^5Z2May be bonded to each other to form a ring;

R^101Z2represents an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group;

R^O1Z2and R^102Z2Independently represent a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group;

m represents a hydrogen atom or an alkali metal atom;

R^O1Z2、R^N1Z2、R^N2Z2、R^101Z2、R^102Z2and when there are a plurality of M, they may be the same or different; the wavy line represents the E or Z body;

In the formula (IZ3), R^1Z3、R^2Z3、R^3Z3、R^4Z3、R^5Z3、R^6Z3And R^7Z3Independently of one another, represents a hydrogen atom, -CO-R^102Z3、-COO-R^101Z3、-OCO-R^102Z3、-COCO-R^102Z3、-O-R^102Z3、-SO₂-R^101Z3、-SO₂N(R^102Z3)₂、-CON(R^102Z3)₂、-N(R^102Z3)₂、-NHCO-R^102Z3、-NHCO-N(R^102Z3)₂、-NHCOOR^102Z3、-OCON(R^102Z3)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent;

R^2Z3and R^3Z3、R^3Z3And R^4Z3And R^4Z3And R^5Z3May be bonded to each other to form a ring;

R^101Z3represents an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group;

R^102Z3represents a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group;

m represents a hydrogen atom or an alkali metal atom;

R^101Z3、R^102Z3and when there are a plurality of M, they may be the same or different; the wavy line represents the E or Z body;

in the formula (IZ4), R^N1Z4And R^N2Z4Independently of one another represent-CO-R^102Z4、-COO-R^101Z4、-OCO-R^102Z4、-COCO-R^102Z4、-O-R^102Z4、-SO₂-R^101Z4、-SO₂N(R^102Z4)₂、-CON(R^102Z4)₂、-N(R^102Z4)₂、-NHCO-R^102Z4、-NHCO-N(R^102Z4)₂、-NHCOOR^102Z4、-OCON(R^102Z4)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent;

R^1Z4、R^2Z4、R^3Z4、R^4Z4、R^5Z4、R^6Z4and R^7Z4Independently of one another, represents a hydrogen atom, -CO-R^102Z4、-COO-R^101Z4、-OCO-R^102Z4、-COCO-R^102Z4、-O-R^102Z4、-SO₂-R^101Z4、-SO₂N(R^102Z4)₂、-CON(R^102Z4)₂、-N(R^102Z4)₂、-NHCO-R^102Z4、-NHCO-N(R^102Z4)₂、-NHCOOR^102Z4、-OCON(R^102Z4)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent;

R^2Z4and R^3Z4、R^3Z4And R^4Z4And R^4Z4And R^5Z4May be bonded to each other to form a ring;

R^101Z4Represents an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group;

R^102Z4represents a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group;

m represents a hydrogen atom or an alkali metal atom;

R^101Z4、R^102Z4and when there are a plurality of M, they may be the same or different; the wavy line represents the E or Z body;

in the formula (IZ5), R^N1Z5represents-CO-R^102Z5、-COO-R^101Z5、-OCO-R^102Z5、-COCO-R^102Z5、-O-R^102Z5、-SO₂-R^101Z5、-SO₂N(R^102Z5)₂、-CON(R^102Z5)₂、-N(R^102Z5)₂、-NHCO-R^102Z5、-NHCO-N(R^102Z5)₂、-NHCOOR^102Z5、-OCON(R^102Z5)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent;

R^1Z5、R^2Z5、R^3Z5、R^4Z5、R^5Z5、R^6Z5and R^7Z5Independently of one another, represents a hydrogen atom, -CO-R^102Z5、-COO-R^101Z5、-OCO-R^102Z5、-COCO-R^102Z5、-O-R^102Z5、-SO₂-R^101Z5、-SO₂N(R^102Z5)₂、-CON(R^102Z5)₂、-N(R^102Z5)₂、-NHCO-R^102Z5、-NHCO-N(R^102Z5)₂、-NHCOOR^102Z5、-OCON(R^102Z5)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group, R is^2Z5And R^3Z5、R^3Z5And R^4Z5And R^4Z5And R^5Z5Each of which may be bonded to each other to form a ring, R^2Z5、R^3Z5、R^4Z5And R^5Z5At least one of which is-CO-R^102Z5、-COO-R^101Z5、-OCO-R^102Z5、-COCO-R^102Z5、-O-R^102Z5、-SO₂-R^101Z5、-SO₂N(R^102Z5)₂、-CON(R^102Z5)₂、-N(R^102Z5)₂、-NHCO-R^102Z5、-NHCO-N(R^102Z5)₂、-NHCOOR^102Z5、-OCON(R^102Z5)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent, or R is^2Z5And R^3Z5、R^3Z5And R^4Z5And R^4Z5And R^5Z5At least one group of them is bonded to form a ring;

R^101Z5represents an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group;

R^102Z5Represents a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group;

m represents a hydrogen atom or an alkali metal atom;

R^101Z5、R^102Z5and when there are a plurality of M, they may be the same or different; the wavy line represents the E or Z body;

in the formula (IZ6), D represents a structure having an isoindoline skeleton; z represents-SO₃ ^-or-CO₂ ^-；A^c+A metal cation representing a valence of c; a represents an integer of 1 to 10;

b represents an integer of 1 or more; c represents an integer of 2 to 10; d represents an integer of 1 or more; D. z, a or A^c+When there are plural, they may be the same or different; the formula (I 'Z6) and the formula (I' Z6) respectively represent partial structures of the formula (IZ6), D, Z, A^c+A, b, c and d represent the same meanings as the corresponding symbols in formula (IZ 6);

the partial structure represented by the formula (I' Z6) has the same negative valence as the partial structure represented by the formula (I "Z6) has the same positive valence in absolute value.

2. The coloring composition as described in the above 1, which comprises: a compound represented by the formula (IZ1), a compound represented by the formula (IZ2), or a compound represented by the formula (IZ3), and a resin.

3. The coloring composition as described in the above 1, which comprises: a compound represented by formula (IZ4), a compound represented by formula (IZ5), or a compound represented by formula (IZ6), and a solvent.

4. The coloring composition according to the above 1 or 2, comprising a compound represented by the formula (IZ1) wherein R is^1Z1、R^6Z1And R^7Z1Is a hydrogen atom.

5. The coloring composition according to 1 to 2 or 4, wherein the coloring composition comprises a compound represented by the formula (IZ1) wherein R^O1Z1Is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent.

6. The coloring composition according to 1 to 2, 4 or 5, wherein the coloring composition comprises a compound represented by the formula (IZ1) wherein R is^2Z1、R^3Z1、R^4Z1And R^5Z1At least one of which is-CO-R^102Z1、-COO-R^101Z1、-OCO-R^102Z1、-COCO-R^102Z1、-O-R^102Z1、-SO₂-R^101Z1、-SO₂N(R^102Z1)₂、-CON(R^102Z1)₂、-N(R^102Z1)₂、-NHCO-R^102Z1、-NHCO-N(R^102Z1)₂、-NHCOOR^102Z1、-OCON(R^102Z1)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent, or R is^2Z1And R^3Z1、R^3Z1And R^4Z1And R^4Z1And R^5Z1At least one group of them is bonded to form a ring.

7. The coloring composition according to any one of the above 1 to 2 or 4 to 6, which comprises a compound represented by the formula (IZ1) wherein R^2Z1、R^3Z1、R^4Z1And R^5Z1At least one of which is nitro or tert-butyl.

8. The coloring composition according to the above 1 or 2, comprising a compound represented by the formula (IZ2) wherein R is^O1Z2、R^N1Z2And R^N2Z2Independently of each other, a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent.

9. The coloring composition according to 1 to 2 or 8, wherein the coloring composition comprises a compound represented by the formula (IZ2) wherein R^1Z2Is a hydrogen atom.

10. 1 to 2, 8 orThe coloring composition according to 9, which comprises a compound represented by the formula (IZ2) wherein R is^2Z2、R^3Z2、R^4Z2And R^5Z2At least one of which is-CO-R^102Z2、-COO-R^101Z2、-OCO-R^102Z2、-COCO-R^102Z2、-O-R^102Z2、-SO₂-R^101Z2、-SO₂N(R^102Z2)₂、-CON(R^102Z2)₂、-N(R^102Z2)₂、-NHCO-R^102Z2、-NHCO-N(R^102Z2)₂、-NHCOOR^102Z2、-OCON(R^102Z2)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent, or R is^2Z2And R^3Z2、R^3Z2And R^4Z2And R^4Z2And R^5Z2At least one group of them is bonded to form a ring.

11. The coloring composition according to any one of the above 1 to 2 or 8 to 10, which comprises a compound represented by the formula (IZ2) wherein R is^2Z2、R^3Z2、R^4Z2And R^5Z2At least one of which is nitro or tert-butyl.

12. The coloring composition according to the above 1 or 2, comprising a compound represented by the formula (IZ3) wherein R is^1Z3、R^6Z3And R^7Z3Is a hydrogen atom.

13. The coloring composition according to 1 to 2 or 12, wherein the coloring composition comprises a compound represented by the formula (IZ3) wherein R^2Z3、R^3Z3、R^4Z3And R^5Z3At least one of which is-CO-R^102Z3、-COO-R^101Z3、-OCO-R^102Z3、-COCO-R^102Z3、-O-R^102Z3、-SO₂-R^101Z3、-SO₂N(R^102Z3)₂、-CON(R^102Z3)₂、-N(R^102Z3)₂、-NHCO-R^102Z3、-NHCO-N(R^102Z3)₂、-NHCOOR^102Z3、-OCON(R^102Z3)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent, or R is ^2Z3And R^3Z3、R^3Z3And R^4Z3And R^4Z3And R^5Z3At least one group of them is bonded to form a ring.

14. The coloring composition according to 1 to 2, 12 or 13, wherein the coloring composition comprises a compound represented by the formula (IZ3) wherein R is^2Z3、R^3Z3、R^4Z3And R^5Z3At least one of which is nitro or tert-butyl.

15. The coloring composition according to any one of the above 1 to 14, which comprises both a resin and a solvent.

16. The coloring composition according to any one of the above 1 to 15, further comprising a yellow coloring agent or a green coloring agent.

17. A colored curable composition comprising a polymerizable compound and the colored composition according to any one of 1 to 16.

18. The colored curable composition according to claim 17, further comprising a polymerization initiator.

19. A color filter comprising the colored composition according to any one of 1 to 16 or the colored curable composition according to 17 or 18.

20. A liquid crystal display device comprising the color filter according to 19.

21. A compound represented by the formula (IZ 1-B);

in the formula (IZ1-B),

R^O11Z1represents a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group;

R^1Z1、R^21Z1、R^31Z1、R^41Z1、R^51Z1、R^61Z1And R^71Z1Independently of one another, represents a hydrogen atom, -CO-R^102Z1、-COO-R^101Z1、-OCO-R^102Z1、-COCO-R^102Z1、-O-R^102Z1、-SO₂-R^101Z1、-SO₂N(R^102Z1)₂、-CON(R^102Z1)₂、-N(R^102Z1)₂、-NHCO-R^102Z1、-NHCO-N(R^102Z1)₂、-NHCOOR^102Z1、-OCON(R^102Z1)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent;

R^21Z1and R^31Z1、R^31Z1And R^41Z1And R^41Z1And R^51Z1May be bonded to each other to form a ring;

wherein R is^21Z1、R^31Z1、R^41Z1And R^51Z1At least one of which is-CO-R^102Z1、-COO-R^101Z1、-OCO-R^102Z1、-COCO-R^102Z1、-O-R^102Z1、-SO₂-R^101Z1、-SO₂N(R^102Z1)₂、-CON(R^102Z1)₂、-N(R^102Z1)₂、-NHCO-R^102Z1、-NHCO-N(R^102Z1)₂、-NHCOOR^102Z1、-OCON(R^102Z1)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent, or R is^21Z1And R^31Z1、R^31Z1And R^41Z1And R^41Z1And R^51Z1At least one group of them is bonded to form a ring;

R^101Z1represents an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group;

R^102Z1representing a hydrogen atom which may have a substituentA hydrocarbon group having 1 to 40 carbon atoms or a heterocyclic group which may have a substituent;

m represents a hydrogen atom or an alkali metal atom;

R^101Z1、R^102Z1and when there are a plurality of M, they may be the same or different;

the wavy line indicates the E-body or the Z-body.

22. The compound according to claim 21, wherein R^1Z1、R^61Z1And R^71Z1Is a hydrogen atom.

23. The compound according to 21 or 22, wherein R^O11Z1Is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent.

24. The compound according to any one of the above 21 to 23, wherein R^21Z1、R^31Z1、R^41Z1And R^51Z1At least one of which is nitro or tert-butyl.

25. A compound represented by the formula (IZ 2-B);

in the formula (IZ2-B), R^CO11Z2And R^CO21Z2Independently of one another represent-O-R^O1Z2or-NR^N1Z2R^N2Z2，R^CO11Z2And R^CO21Z2At least one of which is-NR^N1Z2R^N2Z2；

R^N1Z2、R^N2Z2、R^1Z2、R^21Z2、R^31Z2、R^41Z2And R^51Z2Independently of one another, represents a hydrogen atom, -CO-R^102Z2、-COO-R^101Z2、-OCO-R^102Z2、-COCO-R^102Z2、-O-R^102Z2、-SO₂-R^101Z2、-SO₂N(R^102Z2)₂、-CON(R^102Z2)₂、-N(R^102Z2)₂、-NHCO-R^102Z2、-NHCO-N(R^102Z2)₂、-NHCOOR^102Z2、-OCON(R^102Z2)₂A halogen atom,Cyano, nitro, -SO₃M、-CO₂M is an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group, R is^21Z2And R^31Z2、R^31Z2And R^41Z2And R^41Z2And R^51Z2Each of which may be bonded to each other to form a ring,

R^21Z2、R^31Z2、R^41Z2and R^51Z2At least one of which is-CO-R^102Z2、-COO-R^101Z2、-OCO-R^102Z2、-COCO-R^102Z2、-O-R^102Z2、-SO₂-R^101Z2、-SO₂N(R^102Z2)₂、-CON(R^102Z2)₂、-N(R^102Z2)₂、-NHCO-R^102Z2、-NHCO-N(R^102Z2)₂、-NHCOOR^102Z2、-OCON(R^102Z2)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent, or R is^21Z2And R^31Z2、R^31Z2And R^41Z2And R^41Z2And R^51Z2At least one group of them is bonded to form a ring;

R^101Z2represents an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group;

R^O1Z2and R^102Z2Independently represent a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group;

m represents a hydrogen atom or an alkali metal atom;

R^O1Z2、R^N1Z2、R^N2Z2、R^101Z2、R^102Z2and when there are a plurality of M, they may be the same or different; the wavy line indicates the E-body or the Z-body.

26. The compound of claim 25, wherein R^O1Z2、R^N1Z2And R^N2Z2Is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent.

27. The compound according to claim 25 or 26, wherein R^1Z2Is a hydrogen atom.

28. The compound according to any one of the above 25 to 27, wherein R^21Z2、R^31Z2、R^41Z2And R^51Z2At least one of which is nitro or tert-butyl.

29. A compound represented by the formula (IZ 3-B);

in the formula (IZ3-B), R^1Z3、R^21Z3、R^31Z3、R^41Z3、R^51Z3、R^61Z3And R^71Z3Independently of one another, represents a hydrogen atom, -CO-R^102Z3、-COO-R^101Z3、-OCO-R^102Z3、-COCO-R^102Z3、-O-R^102Z3、-SO₂-R^101Z3、-SO₂N(R^102Z3)₂、-CON(R^102Z3)₂、-N(R^102Z3)₂、-NHCO-R^102Z3、-NHCO-N(R^102Z3)₂、-NHCOOR^102Z3、-OCON(R^102Z3)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent;

R^21Z3and R^31Z3、R^31Z3And R^41Z3And R^41Z3And R^51Z3May be bonded to each other to form a ring;

wherein R is^21Z3、R^31Z3、R^41Z3And R^51Z3At least one of which is-CO-R^102Z3、-COO-R^101Z3、-OCO-R^102Z3、-COCO-R^102Z3、-O-R^102Z3、-SO₂-R^101Z3、-SO₂N(R^102Z3)₂、-CON(R^102Z3)₂、-N(R^102Z3)₂、-NHCO-R^102Z3、-NHCO-N(R^102Z3)₂、-NHCOOR^102Z3、-OCON(R^102Z3)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent, or R is^21Z3And R^31Z3、R^31Z3And R^41Z3And R^41Z3And R^51Z3At least one group of them is bonded to form a ring;

R^101Z3represents an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group;

R^102Z3represents a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group;

M represents a hydrogen atom or an alkali metal atom;

R^101Z3、R^102Z3and when there are a plurality of M, they may be the same or different; the wavy line indicates the E-body or the Z-body.

30. The compound of claim 29, wherein R^1Z3、R^61Z3And R^71Z3Is a hydrogen atom.

31. The compound according to claim 29 or 30, wherein R^21Z3、R^31Z3、R^41Z3And R^51Z3At least one of which is nitro or tert-butyl.

32. A compound represented by formula (IZ 4);

in the formula (IZ4), R^N1Z4And R^N2Z4Independently of one another represent-CO-R^102Z4、-COO-R^101Z4、-OCO-R^102Z4、-COCO-R^102Z4、-O-R^102Z4、-SO₂-R^101Z4、-SO₂N(R^102Z4)₂、-CON(R^102Z4)₂、-N(R^102Z4)₂、-NHCO-R^102Z4、-NHCO-N(R^102Z4)₂、-NHCOOR^102Z4、-OCON(R^102Z4)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent;

R^1Z4、R^2Z4、R^3Z4、R^4Z4、R^5Z4、R^6Z4and R^7Z4Independently of one another, represents a hydrogen atom, -CO-R^102Z4、-COO-R^101Z4、-OCO-R^102Z4、-COCO-R^102Z4、-O-R^102Z4、-SO₂-R^101Z4、-SO₂N(R^102Z4)₂、-CON(R^102Z4)₂、-N(R^102Z4)₂、-NHCO-R^102Z4、-NHCO-N(R^102Z4)₂、-NHCOOR^102Z4、-OCON(R^102Z4)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent;

R^2Z4and R^3Z4、R^3Z4And R^4Z4And R^4Z4And R^5Z4May be bonded to each other to form a ring; r^101Z4Represents an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group;

R^102Z4represents a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group;

m represents a hydrogen atom or an alkali metal atom;

R^101Z4、R^102Z4And when there are a plurality of M, they may be the same or different; the wavy line indicates the E-body or the Z-body.

33. The compound of 32, wherein R^1Z4、R^6Z4And R^7Z4Is a hydrogen atom.

34. The compound according to the above 32 or 33, wherein R^N1Z4And R^N2Z4Independently of each other, a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent.

35. The compound according to any one of the above 32 to 34, wherein R^2Z4、R^3Z4、R^4Z4And R^5Z4At least one of which is-CO-R^102Z4、-COO-R^101Z4、-OCO-R^102Z4、COCO-R^102Z4、-O-R^102Z4、-SO₂-R^101Z4、-SO₂N(R^102Z4)₂、-CON(R^102Z4)₂、-N(R^102Z4)₂、-NHCO-R^102Z4、-NHCO-N(R^102Z4)₂、-NHCOOR^102Z4、-OCON(R^102Z4)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent, or R is^2Z4And R^3Z4、R^3Z4And R^4Z4And R^4Z4And R^5Z4At least one group of them is bonded to form a ring.

36. The compound according to any one of the above 32 to 35, wherein R^2Z4、R^3Z4、R^4Z4And R^5Z4At least one of which is nitro or tert-butyl.

37. A compound represented by formula (IZ 5);

in the formula (IZ5), R^N1Z5represents-CO-R^102Z5、-COO-R^101Z5、-OCO-R^102Z5、-COCO-R^102Z5、-O-R^102Z5、-SO₂-R^101Z5、-SO₂N(R^102Z5)₂、-CON(R^102Z5)₂、-N(R^102Z5)₂、-NHCO-R^102Z5、-NHCO-N(R^102Z5)₂、-NHCOOR^102Z5、-OCON(R^102Z5)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent;

R^1Z5、R^2Z5、R^3Z5、R^4Z5、R^5Z5、R^6Z5and R^7Z5Independently of one another, represents a hydrogen atom, -CO-R^102Z5、-COO-R^101Z5、-OCO-R^102Z5、-COCO-R^102Z5、-O-R^102Z5、-SO₂-R^101Z5、-SO₂N(R^102Z5)₂、-CON(R^102Z5)₂、-N(R^102Z5)₂、-NHCO-R^102Z5、-NHCO-N(R^102Z5)₂、-NHCOOR^102Z5、-OCON(R^102Z5)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group, R is ^2Z5And R^3Z5、R^3Z5And R^4Z5And R^4Z5And R^5Z5Each of which may be bonded to each other to form a ring, R^2Z5、R^3Z5、R^4Z5And R^5Z5At least one of which is-CO-R^102Z5、-COO-R^101Z5、-OCO-R^102Z5、-COCO-R^102Z5、-O-R^102Z5、-SO₂-R^101Z5、-SO₂N(R^102Z5)₂、-CON(R^102Z5)₂、-N(R^102Z5)₂、-NHCO-R^102Z5、-NHCO-N(R^102Z5)₂、-NHCOOR^102Z5、-OCON(R^102Z5)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent, or R is^2Z5And R^3Z5、R^3Z5And R^4Z5And R^4Z5And R^5Z5At least one group of them is bonded to form a ring;

R^101Z5represents an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group; r^102Z5Represents a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group;

m represents a hydrogen atom or an alkali metal atom;

R^101Z5、R^102Z5and when there are a plurality of M, they may be the same or different; the wavy line indicates the E-body or the Z-body.

38. The compound of claim 37, wherein R^N1Z5The hydrocarbon group may have a substituent and has 1 to 10 carbon atoms.

39. The compound according to 37 or 38, wherein R^1Z5、R^6Z5And R^7Z5Is a hydrogen atom.

40. The compound according to any one of claims 37 to 39, wherein R^2Z5、R^3Z5、R^4Z5And R^5Z5At least one of which is nitro or tert-butyl.

41. A compound represented by formula (IZ 6);

in the formula (IZ6), D represents a structure having an isoindoline skeleton; z represents-SO ₃ ^-or-CO₂ ^-；A^c+A metal cation representing a valence of c; a represents an integer of 1 to 10;

b represents an integer of 1 or more; c represents an integer of 2 to 10;

d represents an integer of 1 or more; D. z, a or A^c+When there are plural, they may be the same or different; the formula (I 'Z6) and the formula (I' Z6) respectively represent partial structures of the formula (IZ6), D, Z, A^c+A, b, c and d represent the same meanings as the corresponding symbols in formula (IZ 6);

the partial structure represented by the formula (I' Z6) has the same negative valence as the partial structure represented by the formula (I "Z6) has the same positive valence in absolute value.

42. The compound according to 41, wherein the compound represented by formula (IZ6) is a compound represented by formula (IZ 6-A);

in the formula (IZ6-A), A^c+B, c and d are as defined above;

R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6and R^13AZ6Independently of one another, represents a hydrogen atom, -CO-R^102AZ6、-COO-R^101AZ6、-OCO-R^102AZ6、-COCO-R^102AZ6、-O-R^102AZ6、-SO₂-R^101AZ6、-SO₂N(R^102AZ6)₂、-CON(R^102AZ6)₂、-N(R^102AZ6)₂、-NHCO-R^102AZ6、-NHCO-N(R^102AZ6)₂、-NHCOOR^102AZ6、-OCON(R^102AZ6)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M、-SO₃ ^-、-CO₂ ^-A C1-40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent;

R^2AZ6and R^3AZ6、R^3AZ6And R^4AZ6、R^4AZ6And R^5AZ6、R^AA1Z6And R^AA2Z6And R^12AZ6And R^13AZ6May be bonded to each other to form a ring;

R^101AZ6independently represent a C1-40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent;

R^102AZ6Independently represent a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group;

m represents a hydrogen atom or an alkali metal atom;

the formula (IZ6-A ') and the formula (IZ 6-A') each represent a partial structure of the formula (IZ6-A), A^c+、b、c、d、R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6And R^13AZ6Represents the same meaning as the corresponding symbol in formula (IZ 6-A);

R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6、R^102AZ6m, c or A^c+When there are plural, they may be the same or different;

R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6and R^102AZ6Satisfies at least 1 of (ra-i) to (ra-iii), R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6having-SO of₃ ^-or-CO₂ ^-The total number of (a);

(ra-i)R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6and R^13AZ6At least one of which is-SO₃ ^-or-CO₂ ^-；

(ra-ii)R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6And R^13AZ6At least one of which is-CO-R^102AZ6、-COO-R^101AZ6、-OCO-R^102AZ6、-COCO-R^102AZ6、-O-R^102AZ6、-SO₂-R^101AZ6、-SO₂N(R^102AZ6)₂、-CON(R^102AZ6)₂、-N(R^102AZ6)₂、-NHCO-R^102AZ6、-NHCO-N(R^102AZ6)₂、-NHCOOR^102AZ6or-OCON (R)^102AZ6)₂R is a hydrogen atom^101AZ6And R^102AZ6To have-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO₃ ^-or-CO₂ ^-A heterocyclic group of (a); wherein the hydrocarbon group or the heterocyclic group may have-SO₃ ^-and-CO₂ ^-A substituent other than;

(ra-iii)R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6and R^13AZ6At least one of which is a compound having-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO₃ ^-or-CO₂ ^-A heterocyclic group of (a); wherein the hydrocarbon group and the heterocyclic group may have-SO₃ ^-or-CO₂ ^-A substituent other than;

a represents the same meaning as the symbol in formula (IZ 6); when a plurality of a exist, they may be the same or different;

The negative valence number of the partial structure represented by the formula (IZ 6-A') is the same as the absolute value of the positive valence number of the partial structure represented by the formula (IZ6-A ");

the wavy line indicates the E-body or the Z-body.

43. The compound according to item 42, wherein the compound represented by formula (IZ6-A) is a compound represented by formula (IZ 6-B);

in the formula (IZ6-B), A^c+B, c, d and the wavy line have the same meanings as described above; l is¹represents-CO-or-SO₂-；

R^1BZ6、R^2BZ6、R^3BZ6、R^4BZ6、R^5BZ6、R^11BZ6、R^12BZ6And R^13BZ6Independently of one another, represents a hydrogen atom, -CO-R^102BZ6、-COO-R^101BZ6、-OCO-R^102BZ6、-COCO-R^102BZ6、-O-R^102BZ6、-SO₂-R^101BZ6、-SO₂N(R^102AZ6)₂、-CON(R^102AZ6)₂、-N(R^102AZ6)₂、-NHCO-R^102BZ6、-NHCO-N(R^102AZ6)₂、-NHCOOR^102BZ6、-OCON(R^102AZ6)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M、-SO₃ ^-、-CO₂ ^-A C1-40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent;

R^2BZ6and R^3BZ6、R^3BZ6And R^4BZ6、R^4BZ6And R^5BZ6And R^12BZ6And R^13BZ6May be bonded to each other to form a ring;

R^101BZ6independently of each other, the number of carbon atoms which may have a substituent1 to 40 hydrocarbon groups or heterocyclic groups which may have substituents;

R^102BZ6independently represent a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group;

the formula (IZ6-B ') and the formula (IZ 6-B') each represent a partial structure of the formula (IZ6-B), A^c+、b、c、d、R^1BZ6、R^2BZ6、R^3BZ6、R^4BZ6、R^5BZ6、R^11BZ6、R^12BZ6、R^13BZ6And L¹Represents the same meaning as the corresponding symbol in formula (IZ 6-B);

m represents the same meaning as described above;

R^1BZ6、R^2BZ6、R^3BZ6、R^4BZ6、R^5BZ6、R^11BZ6、R^12BZ6、R^13BZ6、R^101BZ6、R^102BZ6、L¹M, c or A^c+When there are plural, they may be the same or different;

R^1BZ6、R^2BZ6、R^3BZ6、R^4BZ6、R^5BZ6、R^11BZ6、R^12BZ6、R^13BZ6、R^101BZ6and R^102BZ6Satisfies at least 1 of (rb-i) to (rb-iii), R^1BZ6、R^2BZ6、R^3BZ6、R^4BZ6、R^5BZ6、R^11BZ6、R^12BZ6、R^13BZ6、R^101BZ6And R^102BZ6having-SO of₃ ^-or-CO₂ ^-The total number of (a);

(rb-i)R^1BZ6、R^2BZ6、R^3BZ6、R^4BZ6、R^5BZ6、R^11BZ6、R^12BZ6and R^13BZ6At least one of which is-SO₃ ^-or-CO₂ ^-；

(rb-ii)R^1BZ6、R^2BZ6、R^3BZ6、R^4BZ6、R^5BZ6、R^11BZ6、R^12BZ6And R^13BZ6At least one of which is-CO-R^102BZ6、-COO-R^101BZ6、-OCO-R^102BZ6、-COCO-R^102BZ6、-O-R^102BZ6、-SO₂-R^101BZ6、-SO₂N(R^102AZ6)₂、-CON(R^102AZ6)₂、-N(R^102AZ6)₂、-NHCO-R^102BZ6、-NHCO-N(R^102AZ6)₂、-NHCOOR^102BZ6or-OCON (R)^102AZ6)₂，

The R is^101BZ6And R^102BZ6To have-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO₃ ^-or-CO₂ ^-A heterocyclic group of (a); wherein the hydrocarbon group or the heterocyclic group may have-SO₃ ^-and-CO₂ ^-A substituent other than;

(rb-iii)R^1BZ6、R^2BZ6、R^3BZ6、R^4BZ6、R^5BZ6、R^11BZ6、R^12BZ6and R^13BZ6At least one of which is a compound having-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO₃ ^-or-CO₂ ^-A heterocyclic group of (a); wherein the hydrocarbon group or the heterocyclic group may have-SO₃ ^-and-CO₂ ^-A substituent other than;

a represents the same meaning as the symbol in the formula (IZ 6-A); when a plurality of a exist, they may be the same or different;

the partial structure represented by the formula (IZ6-B ') has the same negative valence as the partial structure represented by the formula (IZ 6-B') has the same positive valence in absolute value.

44. The compound of 43, wherein L¹is-CO-.

45. The compound according to 43 or 44, wherein R^11BZ6An optionally substituted aliphatic hydrocarbon group having 1 to 40 carbon atoms, an optionally substituted phenyl group, an optionally substituted naphthyl group, an optionally substituted tetrahydronaphthyl group A thienyl group which may have a substituent, a furyl group which may have a substituent, or a pyridyl group which may have a substituent.

46. The compound according to 43, wherein the compound represented by the formula (IZ6-B) is a compound represented by the formula (IZ 6-C);

in the formula (IZ6-C), A^c+、b、c、d、L¹And the wavy line means the same as above;

L²represents-CO-or-SO₂-；

R^1CZ6、R^2CZ6、R^3CZ6、R^4CZ6、R^5CZ6、R^11CZ6And R^14CZ6Independently of one another, represents a hydrogen atom, -CO-R^102CZ6、-COO-R^101CZ6、-OCO-R^102CZ6、-COCO-R^102CZ6、-O-R^102CZ6、-SO₂-R^101CZ6、-SO₂N(R^102CZ6)₂、-CON(R^102CZ6)₂、-N(R^102CZ6)₂、-NHCO-R^102CZ6、-NHCO-N(R^102CZ6)₂、-NHCOOR^102CZ6、-OCON(R^102CZ6)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M、-SO₃ ^-、-CO₂ ^-A C1-40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent;

R^2CZ6and R^3CZ6、R^3CZ6And R^4CZ6And R^4CZ6And R^5CZ6Respectively can beBonded to each other to form a ring;

R^101CZ6independently represent a C1-40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent;

R^102CZ6independently represent a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group;

m represents the same meaning as described above;

the formula (IZ6-C ') and the formula (IZ 6-C') each represent a partial structure of the formula (IZ6-C), A^c+、b、c、d、R^1CZ6、R^2CZ6、R^3CZ6、R^4CZ6、R^5CZ6、R^11CZ6、R^14CZ6、L¹And L²Represents the same meaning as the corresponding symbol in formula (IZ 6-C);

R^1CZ6、R^2CZ6、R^3CZ6、R^4CZ6、R^5CZ6、R^11CZ6、R^14CZ6、R^101CZ6、R^102CZ6、L¹、L²m, c or A^c+When there are plural, they may be the same or different;

R^1CZ6、R^2CZ6、R^3CZ6、R^4CZ6、R^5CZ6、R^11CZ6、R^14CZ6、R^101CZ6And R^102CZ6Satisfies at least 1 of (rc-i) to (rc-iii), R^1CZ6、R^2CZ6、R^3CZ6、R^4CZ6、R^5CZ6、R^11CZ6、R^14CZ6、R^101CZ6And R^102CZ6having-SO of₃ ^-or-CO₂ ^-The total number of (a);

(rc-i)R^1CZ6、R^2CZ6、R^3CZ6、R^4CZ6、R^5CZ6、R^11CZ6and R^14CZ6At least one of which is-SO₃ ^-or-CO₂ ^-；

(rc-ii)R^1CZ6、R^2CZ6、R^3CZ6、R^4CZ6、R^5CZ6、R^11CZ6And R^14CZ6At least one of which is-CO-R^102CZ6、-COO-R^101CZ6、-OCO-R^102CZ6、-COCO-R^102CZ6、-O-R^102CZ6、-SO₂-R^101CZ6、-SO₂N(R^102CZ6)₂、-CON(R^102CZ6)₂、-N(R^102CZ6)₂、-NHCO-R^102CZ6、-NHCO-N(R^102CZ6)₂、-NHCOOR^102CZ6or-OCON (R)^102CZ6)₂R is a hydrogen atom^101CZ6And R^102CZ6To have-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO₃ ^-or-CO₂ ^-A heterocyclic group of (a); wherein the hydrocarbon group or the heterocyclic group may have-SO₃ ^-and-CO₂ ^-A substituent other than;

(rc-iii)R^1CZ6、R^2CZ6、R^3CZ6、R^4CZ6、R^5CZ6、R^11CZ6and R^14CZ6At least one of which is a compound having-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO₃ ^-or-CO₂ ^-A heterocyclic group of (a); wherein the hydrocarbon group or the heterocyclic group may have-SO₃ ^-and-CO₂ ^-A substituent other than;

a represents the same meaning as the symbol in the formula (IZ 6-B); when a plurality of a exist, they may be the same or different;

the partial structure represented by the formula (IZ 6-C') has the same negative valence as the partial structure represented by the formula (IZ6-C ") has the same positive valence in absolute value.

47. The compound of 46, wherein R^11CZ6And R^14CZ6Are identical radicals, L¹And L²Are the same group.

48. The compound of claim 46 or 47, wherein L¹And L²is-CO-.

49. Any one of the above 46 to 48A compound of formula (I) wherein R ^11CZ6And R^14CZ6The alkyl group is an aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a phenyl group which may have a substituent, a naphthyl group which may have a substituent, a tetrahydronaphthyl group which may have a substituent, a thienyl group which may have a substituent, a furyl group which may have a substituent, or a pyridyl group which may have a substituent.

50. The compound according to 43, wherein the compound represented by the formula (IZ6-B) is a compound represented by the formula (IZ 6-D);

in the formula (IZ6-D), A^c+、b、c、d、L¹And the wavy line means the same as above; r^20DZ6And R^30DZ6Bonded to form a ring Q; the ring Q may have a substituent, and is a ring having 5 to 7 constitutional elements of the ring, and the ring Q may be a hydrocarbon ring or a heterocyclic ring; the following rings may be fused/condensed on ring Q: a monocyclic ring which is selected from hydrocarbon rings and hetero rings and which may have a substituent, wherein the number of constituent elements of the ring is 5 to 7; or a condensed ring in which at least 2 of the monocyclic rings are condensed;

R^1DZ6、R^2DZ6、R^3DZ6、R^4DZ6、R^5DZ6and R^11DZ6Independently of one another, represents a hydrogen atom, -CO-R^102DZ6、-COO-R^101DZ6、-OCO-R^102DZ6、-COCO-R^102DZ6、-O-R^102DZ6、-SO₂-R^101DZ6、-SO₂N(R^102DZ6)₂、-CON(R^102DZ6)₂、-N(R^102DZ6)₂、-NHCO-R^102DZ6、-NHCO-N(R^102DZ6)₂、-NHCOOR^102DZ6、-OCON(R^102DZ6)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M、-SO₃ ^-、-CO₂ ^-A C1-40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent;

R^2DZ6and R^3DZ6、R^3DZ6And R^4DZ6And R^4DZ6And R^5DZ6May be bonded to each other to form a ring;

R^101DZ6Independently represent a C1-40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent;

R^102DZ6independently represent a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group;

m represents the same meaning as described above;

the formulae (IZ 6-D') and (IZ6-D ") each represent a partial structure of the formula (IZ6-D), A^c+、b、c、d、R^1DZ6、R^2DZ6、R^3DZ6、R^4DZ6、R^5DZ6、R^11DZ6、R^20DZ6、R^30DZ6And L¹Represents the same meaning as the corresponding symbol in the formula (IZ 6-D);

R^1DZ6、R^2DZ6、R^3DZ6、R^4DZ6、R^5DZ6、R^11DZ6、R^101DZ6、R^102DZ6、L¹、M、R^20DZ6、R^30DZ6ring Q, c or A^c+When there are plural, they may be the same or different;

R^1DZ6、R^2DZ6、R^3DZ6、R^4DZ6、R^5DZ6、R^11DZ6、R^101DZ6、R^102DZ6and ring Q satisfies at least 1 of (rd-i) to (rd-iv), R^1DZ6、R^2DZ6、R^3DZ6、R^4DZ6、R^5DZ6、R^11DZ6、R^101DZ6、R^102DZ6And ring Q hasis-SO of₃ ^-or-CO₂ ^-The total number of (a);

(rd-i)R^1DZ6、R^2DZ6、R^3DZ6、R^4DZ6、R^5DZ6and R^11DZ6At least one of which is-SO₃ ^-or-CO₂ ^-；

(rd-ii)R^1DZ6、R^2DZ6、R^3DZ6、R^4DZ6、R^5DZ6And R^11DZ6At least one of which is-CO-R^102DZ6、-COO-R^101DZ6、-OCO-R^102DZ6、-COCO-R^102DZ6、-O-R^102DZ6、-SO₂-R^101DZ6、-SO₂N(R^102DZ6)₂、-CON(R^102DZ6)₂、-N(R^102DZ6)₂、-NHCO-R^102DZ6、-NHCO-N(R^102DZ6)、-NHCOOR^102DZ6or-OCON (R)^102DZ6)₂R is a hydrogen atom^101DZ6And R^102DZ6To have-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO₃ ^-or-CO₂ ^-A heterocyclic group of (a); wherein the hydrocarbon group or the heterocyclic group may have-SO₃ ^-and-CO₂ ^-A substituent other than;

(rd-iii)R^1DZ6、R^2DZ6、R^3DZ6、R^4DZ6、R^5DZ6and R^11DZ6At least one of which is a compound having-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO₃ ^-or-CO₂ ^-A heterocyclic group of (a); wherein the hydrocarbon group or the heterocyclic group may have-SO₃ ^-and-CO ₂ ^-A substituent other than;

(rd-iv) Ring Q has-SO₃ ^-or-CO₂ ^-；

a represents the same meaning as the symbol in the formula (IZ 6-B); when a plurality of a exist, they may be the same or different;

the partial structure represented by the formula (IZ 6-D') has the same negative valence as the partial structure represented by the formula (IZ6-D ") has the same positive valence in absolute value.

51. A compound as claimed in 50 above, wherein L¹is-CO-.

52. The compound according to 50 or 51, wherein R^11DZ6The alkyl group is an aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a phenyl group which may have a substituent, a naphthyl group which may have a substituent, a tetrahydronaphthyl group which may have a substituent, a thienyl group which may have a substituent, a furyl group which may have a substituent, or a pyridyl group which may have a substituent.

53. The compound according to 50, wherein the compound represented by the formula (IZ6-D) is a compound represented by the formula (IZ 6-E);

in the formula (IZ6-E), A^c+、b、c、d、L¹And the wavy line means the same as above;

R^1EZ6、R^2EZ6、R^3EZ6、R^4EZ6、R^5EZ6、R^6EZ6、R^7EZ6and R^11EZ6Independently of one another, represents a hydrogen atom, -CO-R^102EZ6、-COO-R^101EZ6、-OCO-R^102EZ6、-COCO-R^102EZ6、-O-R^102EZ6、-SO₂-R^101EZ6、-SO₂N(R^102EZ6)₂、-CON(R^102EZ6)₂、-N(R^102EZ6)₂、-NHCO-R^102EZ6、-NHCO-N(R^102EZ6)₂、-NHCOOR^102EZ6、-OCON(R^102EZ6)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M、-SO₃ ^-、-CO₂ ^-A C1-40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent; r ^2EZ6And R^3EZ6、R^3EZ6And R^4EZ6And R^4EZ6And R^5EZ6May be bonded to each other to form a ring;

R^101EZ6independently represent a C1-40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent;

R^102EZ6independently represent a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group; m represents the same meaning as described above;

the formulae (IZ6-E ') and (IZ 6-E') each represent a partial structure of the formula (IZ6-E), A^c+、b、c、d、R^1EZ6、R^2EZ6、R^3EZ6、R^4EZ6、R^5EZ6、R^6EZ6、R^7EZ6、R^11EZ6And L¹Represents the same meaning as the corresponding symbol in formula (IZ 6-E);

R^1EZ6、R^2EZ6、R^3EZ6、R^4EZ6、R^5EZ6、R^6EZ6、R^7EZ6、R^11EZ6、R^101EZ6、R^102EZ6、L¹m, c or A^c+When there are plural, they may be the same or different;

R^1EZ6、R^2EZ6、R^3EZ6、R^4EZ6、R^5EZ6、R^6EZ6、R^7EZ6、R^11EZ6、R^101EZ6and R^102EZ6Satisfies at least 1 of (re-i) to (re-iii), R^1EZ6、R^2EZ6、R^3EZ6、R^4EZ6、R^5EZ6、R^6EZ6、R^7EZ6、R^11EZ6、R^101EZ6And R^102EZ6having-SO of₃ ^-or-CO₂ ^-The total number of (a);

(re-i)R^1EZ6、R^2EZ6、R^3EZ6、R^4EZ6、R^5EZ6、R^6EZ6、R^7EZ6and R^11EZ6At least one of which is-SO₃ ^-or-CO₂ ^-；

(re-ii)R^1EZ6、R^2EZ6、R^3EZ6、R^4EZ6、R^5EZ6、R^6EZ6、R^7EZ6And R^11EZ6At least one of which is-CO-R^102EZ6、-COO-R^101EZ6、-OCO-R^102EZ6、-COCO-R^102EZ6、-O-R^102EZ6、-SO₂-R^101EZ6、-SO₂N(R^102EZ6)₂、-CON(R^102EZ6)₂、-N(R^102EZ6)₂、-NHCO-R^102EZ6、-NHCO-N(R^102EZ6)₂、-NHCOOR^102EZ6or-OCON (R)^102EZ6)₂R is a hydrogen atom^101EZ6And R^102EZ6To have-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO₃ ^-or-CO₂ ^-A heterocyclic group of (a); wherein the hydrocarbon group or the heterocyclic group may have-SO₃ ^-and-CO₂ ^-A substituent other than;

(re-iii)R^1EZ6、R^2EZ6、R^3EZ6、R^4EZ6、R^5EZ6、R^6EZ6、R^7EZ6and R^11EZ6At least one of which is a compound having-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO₃ ^-or-CO₂ ^-A heterocyclic group of (a); wherein the hydrocarbon group or the heterocyclic group may have-SO ₃ ^-and-CO₂ ^-A substituent other than;

a represents the same meaning as the symbol in the formula (IZ 6-D); when a plurality of a exist, they may be the same or different;

the partial structure represented by the formula (IZ6-E ') has the same negative valence as the partial structure represented by the formula (IZ 6-E') has the same positive valence in absolute value.

54. A compound as described in 53 above, wherein L¹is-CO-.

55. The compound according to 53 or 54 above, wherein R^11EZ6The alkyl group is an aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a phenyl group which may have a substituent, a naphthyl group which may have a substituent, a tetrahydronaphthyl group which may have a substituent, a thienyl group which may have a substituent, a furyl group which may have a substituent, or a pyridyl group which may have a substituent.

Detailed Description

The coloring composition of the present invention comprises: at least one of a resin (hereinafter, sometimes referred to as a resin (B)) and a solvent (hereinafter, sometimes referred to as a solvent (E)), and at least one selected from the group consisting of a compound represented by formula (IZ1) (hereinafter, sometimes referred to as a compound IZ 1)), a compound represented by formula (IZ2) (hereinafter, sometimes referred to as a compound IZ 2)), a compound represented by formula (IZ3) (hereinafter, sometimes referred to as a compound IZ3), a compound represented by formula (IZ4) (hereinafter, sometimes referred to as a compound IZ4), a compound represented by formula (IZ5) (hereinafter, sometimes referred to as a compound IZ5), and a compound represented by formula (IZ6) (hereinafter, sometimes referred to as a compound IZ6) (hereinafter, sometimes referred to as a compound Z).

The compound IZ1, the compound IZ2, the compound IZ3, the compound IZ4, the compound IZ5 and the compound IZ6 include tautomers thereof and salts thereof, respectively.

The above compounds can be used as colorants, respectively.

The coloring composition of the present invention may contain 1 or 2 or more compounds IZ1, may contain 1 or 2 or more compounds IZ2, may contain 1 or 2 or more compounds IZ3, may contain 1 or 2 or more compounds IZ4, may contain 1 or 2 or more compounds IZ5, and may contain 1 or 2 or more compounds IZ 6.

When the coloring composition of the present invention contains 1 or more selected from the group consisting of the compound IZ1, the compound IZ2, and the compound IZ3, it is preferable that the coloring composition contains the resin (B) as an essential component.

When the coloring composition of the present invention contains 1 or more selected from the group consisting of the compound IZ4, the compound IZ5, and the compound IZ6, it is preferable that the coloring composition contains the solvent (E) as an essential component.

When the coloring composition of the present invention contains a solvent, the compound IZ1, the compound IZ2, the compound IZ3, the compound IZ4, the compound IZ5, and the compound IZ6 are preferably dispersed in the solvent (E).

When the coloring composition of the present invention contains the compound IZ1, the coloring composition may further contain a colorant other than the compound IZ1 (hereinafter, sometimes referred to as the colorant a1z1. also, hereinafter, sometimes the compound IZ1 and the colorant A1Z1 are collectively referred to as the "colorant AZ 1"). The colorant A1Z1 may contain 1 or 2 or more colorants.

When the coloring composition of the present invention contains the compound IZ2, the coloring composition may further contain a colorant other than the compound IZ2 (hereinafter, sometimes referred to as a colorant a1z2. also, hereinafter, sometimes the compound IZ2 and the colorant A1Z2 are collectively referred to as a "colorant AZ 2"). The colorant A1Z2 may contain 1 or 2 or more colorants.

When the coloring composition of the present invention contains the compound IZ3, the coloring composition may further contain a colorant other than the compound IZ3 (hereinafter, sometimes referred to as a colorant a1z3. also, hereinafter, sometimes the compound IZ3 and the colorant A1Z3 are collectively referred to as a "colorant AZ 3"). The colorant A1Z3 may contain 1 or 2 or more colorants.

When the coloring composition of the present invention contains the compound IZ4, the coloring composition may further contain a colorant other than the compound IZ4 (hereinafter, sometimes referred to as a colorant a1z4. also, hereinafter, sometimes the compound IZ4 and the colorant A1Z4 are collectively referred to as a "colorant AZ 4"). The colorant A1Z4 may contain 1 or 2 or more colorants.

When the coloring composition of the present invention contains the compound IZ5, the coloring composition may further contain a colorant other than the compound IZ5 (hereinafter, sometimes referred to as a colorant a1z5. furthermore, hereinafter, sometimes the compound IZ5 and the colorant A1Z5 are collectively referred to as a "colorant AZ 5"). The colorant A1Z5 may contain 1 or 2 or more colorants.

When the coloring composition of the present invention contains the compound IZ6, the coloring composition may further contain a colorant other than the compound IZ6 (hereinafter, sometimes referred to as a colorant a1z6. furthermore, the compound IZ6 and the colorant A1Z6 are sometimes collectively referred to as a "colorant AZ 6"). The colorant A1Z6 may contain 1 or 2 or more colorants.

Hereinafter, 1 or more selected from the group consisting of the colorant A1Z1, the colorant A1Z2, the colorant A1Z3, the colorant A1Z4, the colorant A1Z5, and the colorant A1Z6 are collectively referred to as the colorant ZZ. The colorant ZZ preferably comprises a yellow colorant or a green colorant.

Hereinafter, 1 or more selected from the colorant AZ1, the colorant AZ2, the colorant AZ3, the colorant AZ4, the colorant AZ5, and the colorant AZ6 will be collectively referred to as a colorant ZZZ.

The coloring composition of the present invention preferably contains both the resin (B) and the solvent (E).

Further, the colored curable composition of the present invention comprises:

at least one selected from the group consisting of a compound represented by the formula (IZ1), a compound represented by the formula (IZ2), a compound represented by the formula (IZ3), a compound represented by the formula (IZ4), a compound represented by the formula (IZ5) and a compound represented by the formula (IZ6), and

at least one of resin (B) and solvent (E), and

A polymerizable compound (C).

In other words, the colored curable composition of the present invention comprises a colored composition and a polymerizable compound (C).

The colored curable composition of the invention may contain a polymerization initiator (D).

The colored curable composition of the invention may contain a polymerization initiation aid (D1).

The coloring composition of the present invention may further comprise a leveling agent (F) and an antioxidant.

< Compound IZ1 >)

Compound IZ1 is a compound represented by formula (IZ 1).

[ formula (IZ1), R^O1Z1Represents a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group.

R^1Z1、R^2Z1、R^3Z1、R^4Z1、R^5Z1、R^6Z1And R^7Z1Independently of one another, represents a hydrogen atom, -CO-R^102Z1、-COO-R^101Z1、-OCO-R^102Z1、-COCO-R^102Z1、-O-R^102Z1、-SO₂-R^101Z1、-SO₂N(R^102Z1)₂、-CON(R^102Z1)₂、-N(R^102Z1)₂、-NHCO-R^102Z1、-NHCO-N(R^102Z1)₂、-NHCOOR^102Z1、-OCON(R^102Z1)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.

R^2Z1And R^3Z1、R^3Z1And R^4Z1And R^4Z1And R^5Z1Each of which may be bonded to each other to form a ring. R^101Z1The alkyl group may have a substituent and has 1 to 40 carbon atoms, or a heterocyclic group may have a substituent. R^102Z1Represents a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group. M represents a hydrogen atom or an alkali metal atom. R ^101Z1、R^102Z1And when there are a plurality of M, they may be the same or different. The wavy line indicates the E-body or the Z-body.]

R^O1Z1、R^1Z1、R^2Z1、R^3Z1、R^4Z1、R^5Z1、R^6Z1、R^7Z1、R^101Z1And R^102Z1The number of carbon atoms of the hydrocarbon group is 1 to 40, preferably 1 to 30, more preferably 1 to 20, still more preferably 1 to 15, particularly preferably 1 to 10。

R^O1Z1、R^1Z1、R^2Z1、R^3Z1、R^4Z1、R^5Z1、R^6Z1、R^7Z1、R^101Z1And R^102Z1The hydrocarbon group having 1 to 40 carbon atoms may be an aliphatic hydrocarbon group or an aromatic hydrocarbon group, and the aliphatic hydrocarbon group may be saturated or unsaturated, and may be a chain or alicyclic group.

As R^O1Z1、R^1Z1、R^2Z1、R^3Z1、R^4Z1、R^5Z1、R^6Z1、R^7Z1、R^101Z1And R^102Z1Examples of the saturated or unsaturated chain hydrocarbon group include straight chain alkyl groups such as methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, heptadecyl, octadecyl, and eicosyl; branched alkyl groups such as isopropyl, isobutyl, sec-butyl, tert-butyl, (2-ethyl) butyl, isopentyl, neopentyl, tert-pentyl, (1-methyl) pentyl, (2-methyl) pentyl, (1-ethyl) pentyl, (3-ethyl) pentyl, isohexyl, (5-methyl) hexyl, (2-ethyl) hexyl and (3-ethyl) heptyl; alkenyl groups such as vinyl, 1-propenyl, 2-propenyl (allyl), (1-methyl) vinyl, 2-butenyl, 3-butenyl, 1, 3-butadienyl, (1- (2-propenyl)) vinyl, (1, 2-dimethyl) propenyl, and 2-pentenyl; and so on. The number of carbon atoms of the saturated or unsaturated chain hydrocarbon group is preferably 1 to 30, more preferably 1 to 20, further preferably 1 to 15, particularly preferably 1 to 10, further more preferably 1 to 8, and particularly preferably 1 to 5. Among them, a linear or branched alkyl group having 1 to 10 carbon atoms, more preferably 1 to 8 carbon atoms is particularly preferable, and a methyl group, an ethyl group, and a tert-butyl group are particularly preferable.

As R^O1Z1、R^1Z1、R^2Z1、R^3Z1、R^4Z1、R^5Z1、R^6Z1、R^7Z1、R^101Z1And R^102Z1Examples of the saturated or unsaturated alicyclic hydrocarbon group include cyclopropyl, 1-methylcyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl and 1-methylcyclohexyl2-methylcyclohexyl group, 3-methylcyclohexyl group, 4-methylcyclohexyl group, 1, 2-dimethylcyclohexyl group, 1, 3-dimethylcyclohexyl group, 1, 4-dimethylcyclohexyl group, 2, 3-dimethylcyclohexyl group, 2, 4-dimethylcyclohexyl group, 2, 5-dimethylcyclohexyl group, 2, 6-dimethylcyclohexyl group, 3, 4-dimethylcyclohexyl group, 3, 5-dimethylcyclohexyl group, 2-dimethylcyclohexyl group, 3-dimethylcyclohexyl group, 4-dimethylcyclohexyl group, cyclooctyl group, 2,4, 6-trimethylcyclohexyl group, 2,6, 6-tetramethylcyclohexyl group, 3,5, 5-tetramethylcyclohexyl group, 4-pentylcyclohexyl group, 4-octylcyclohexyl group, 3, 4-octylcyclohexyl group, 1, 3-dimethylcyclohexyl group, 2, 4-dimethylcyclohexyl group, 3, 5-dimethylcyclohexyl group, 3-dimethylcyclohexyl group, 4-dimethylcyclohexyl group, 3, 4-dimethylcyclohexyl group, 2, 6-dimethylcyclohexyl group, 2,3, 5-dimethylcyclohexyl group, 4-dimethylcyclohexyl group, 3, 4-dimethylcyclohexyl group, 2,3, 2, 4-dimethylcyclohexyl group, 2,3, 4-dimethylcyclohexyl group, 2, 4-dimethylcyclohexyl group, 3, 2,3, 2,3, 4-dimethylcyclohexyl group, 2,6, 2,3, 2,6, 2,3, 6, 3, 2,6, and the like, Cycloalkyl groups such as 4-cyclohexylcyclohexyl; cycloalkenyl groups such as cyclohexenyl (e.g., cyclohex-2-ene, cyclohex-3-ene), cycloheptenyl, cyclooctenyl, and the like; norbornyl, adamantyl, bicyclo [2.2.2]An octyl group and the like. The number of carbon atoms of the saturated or unsaturated alicyclic hydrocarbon group is preferably 3 to 30, more preferably 3 to 20, still more preferably 4 to 20, yet more preferably 4 to 15, even more preferably 5 to 15, and most preferably 5 to 10. Among them, cyclopentyl, cyclohexyl, cycloheptyl, and cyclooctyl are particularly preferable.

As R^O1Z1、R^1Z1、R^2Z1、R^3Z1、R^4Z1、R^5Z1、R^6Z1And R^7Z1、R^101Z1And R^102Z1The aromatic hydrocarbon group may include a phenyl group, an o-tolyl group, a m-tolyl group, a p-tolyl group, a 2, 3-dimethylphenyl group, a 2, 4-dimethylphenyl group, a 2, 5-dimethylphenyl group, a 2, 6-dimethylphenyl group, a 3, 4-dimethylphenyl group, a 3, 5-dimethylphenyl group, a 4-vinylphenyl group, an o-isopropylphenyl group, a m-isopropylphenyl group, a p-isopropylphenyl group, an o-tert-butylphenyl group, a m-tert-butylphenyl group, a p-tert-butylphenyl group, a mesityl (mesityl group), a 4-ethylphenyl group, a 4-butylphenyl group, a 4-pentylphenyl group, a 2, 6-bis (2-propyl) phenyl group, a 4-cyclohexylphenyl group, a 2,4, 6-trimethylphenyl group, a 4-octylphenyl group, a 4-vinylphenyl group, a 1-naphthyl group, a 4-pentylphenyl group, a, Aromatic hydrocarbon groups such as 2-naphthyl, 5,6,7, 8-tetrahydro-1-naphthyl, 5,6,7, 8-tetrahydro-2-naphthyl, fluorenyl, phenanthryl, anthracyl, pyrenyl and the like; and so on. The number of carbon atoms of the aromatic hydrocarbon group is preferably 6 to 30, more preferably 6 to 20, and further preferably 6 to 15.

R^O1Z1、R^1Z1、R^2Z1、R^3Z1、R^4Z1、R^5Z1、R^6Z1、R^7Z1、R^101Z1And R^102Z1The hydrocarbon group may be a combination of the hydrocarbon groups listed above (for example, an aromatic hydrocarbon group, and at least 1 of a chain hydrocarbon group and an alicyclic hydrocarbon group), and examples thereof include aralkyl groups such as benzyl, phenethyl, and 1-methyl-1-phenylethyl; arylalkenyl groups such as phenylvinyl (styryl); arylalkynyl groups such as phenylethynyl; a phenyl group having 1 or more phenyl groups bonded thereto, such as a biphenyl group and a terphenyl group; cyclohexylmethylphenyl, benzylphenyl, (dimethyl (phenyl) methyl) phenyl, and the like.

For R^O1Z1、R^1Z1、R^2Z1、R^3Z1、R^4Z1、R^5Z1、R^6Z1、R^7Z1、R^101Z1And R^102Z1Examples of the group represented by the above-mentioned groups, which are a combination of the above-mentioned hydrocarbon groups (e.g., chain hydrocarbon groups and alicyclic hydrocarbon groups), include alkyl groups to which 1 or more alicyclic hydrocarbon groups are bonded, such as cyclopropylmethyl groups, cyclopropylethyl groups, cyclobutylmethyl groups, cyclobutylethyl groups, cyclopentylmethyl groups, cyclopentylethyl groups, cyclohexylmethyl groups, 2-methylcyclohexylmethyl groups, cyclohexylethyl groups, and adamantylmethyl groups.

The number of carbon atoms is preferably 4 to 30, more preferably 6 to 30, further preferably 6 to 20, further preferably 4 to 15, and particularly preferably 6 to 15.

R^O1Z1、R^1Z1、R^2Z1、R^3Z1、R^4Z1、R^5Z1、R^6Z1、R^7Z1、R^101Z1And R^102Z1The hydrocarbon group represented may have a substituent. The substituent may have a valence of 1 or 2. For substituents having a valence of 2, preferably 2 chemical bonds are bonded to the same carbon atom to form a double bond.

Examples of the substituent having a valence of 1 include:

methoxy group, ethoxy group, propoxy group, isopropoxy group, butoxy group, isobutoxy group, sec-butoxy group, tert-butoxy group, pentyloxy group, hexyloxy group, (2-ethyl) hexyloxy group, heptyloxy group, octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, dodecyloxy group, (2-ethyl) hexyloxy group, eicosyloxy group, 1-phenylethoxy group, 1-methyl-1-phenylethoxy group, phenyloxy group, o-tolyloxy group, 2, 3-dimethylphenyloxy group, 2, 4-dimethylphenyloxy group, 2, 5-dimethylphenyloxy group, 2, 6-dimethylphenyloxy group, 3, 4-dimethylphenyloxy group, 3, 5-dimethylphenyloxy group, 2-dicyanophenyloxy group, 2, 3-dicyanophenyloxy group, 2-dicyanophenyloxy group, 2, 4-dicyanophenyloxy group, 2, 5-dicyanophenyloxy group, 2, 6-dicyanophenyloxy group, 3, 4-dicyanophenyloxy group, 3, 5-dicyanophenyloxy group, 4-methoxyphenyloxy group, an oxy group having a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like) bonded to one side, such as a 2-methoxyphenyloxy group, a 3-methoxyphenyloxy group, a 4-ethoxyphenyloxy group, a 2-ethoxyphenyloxy group, a 3-ethoxyphenyloxy group, or a group represented by the following chemical formula;

A thio group (sulfo group) to which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) is bonded, such as a methylthio group, an ethylthio group, a propylthio group, a butylthio group, a tert-butylthio group, a pentylthio group, a hexylthio group, (2-ethyl) hexylthio group, a heptylthio group, an octylthio group, a nonylthio group, a decylthio group, an undecylthio group, a dodecylthio group, an eicosylthio group, a phenylthio group, and an o-tolylthio group;

epoxy, oxetanyl, tetrahydrofuranyl, tetrahydropyranyl;

a formyl group;

a carbonyl group (preferably 2 to 12 carbon atoms when the carbonyl group is an alkanoyl group) having a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 11 carbon atoms) or a derivative thereof (for example, a derivative thereof such as a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), or an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)) bonded thereto, such as an acetyl group, a propionyl group, a butyryl group, a 2, 2-dimethylpropionyl group, a pentanoyl group, a hexanoyl group, (2-ethyl) hexanoyl group, a heptanoyl group, an octanoyl group, a nonanoyl group, a decanoyl group, an undecanoyl group, a dodecanoyl group, an heneicosanoyl group, and a benzoyl group;

An oxycarbonyl group in which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) is bonded, such as a methoxycarbonyl group, an ethoxycarbonyl group, a propoxycarbonyl group, a butoxycarbonyl group, a tert-butoxycarbonyl group, a pentyloxycarbonyl group, a hexyloxycarbonyl group, (2-ethyl) a hexyloxycarbonyl group, a heptyloxycarbonyl group, an octyloxycarbonyl group, a nonyloxycarbonyl group, a decyloxycarbonyl group, a undecyloxycarbonyl group, a dodecyloxycarbonyl group, an eicosyloxycarbonyl group, a phenyloxycarbonyl group, or an o-tolyloxycarbonyl group represented by the following chemical formula);

an amino group; n-methylamino, N-dimethylamino, N-ethylamino, N-diethylamino, N-propylamino, N-dipropylamino, N-isopropylamino, N-diisopropylamino, N-butylamino, N-dibutylamino, N-isobutylamino, N-diisobutylamino, N-sec-butylamino, N-di-sec-butylamino, N-tert-butylamino, N-di-tert-butylamino, N-pentylamino, N-dipentylamino, N- (1-ethylpropyl) amino, N-di (1-ethylpropyl) amino, N-hexylamino, N-dihexylamino, N- (2-ethyl) hexylamino, N-diethylamino, N-propylamino, N-dipropylamino, N-isopropylamino, N-di-sec-butylamino, N-pentylamino, N-dipentylamino, N-1-ethylpropyl) amino, N-di (1-ethylpropyl) amino, N-hexylamino, N-butylamino, N-butylamino, N-di-butylamino, N-butylamino, N, n, N-di (2-ethyl) hexylamino group, N-heptylamino group, N-diheptylamino group, N-octylamino group, N-dioctylamino group, N-nonylamino group, N-dinonylamino group, N-phenylamino group, N-diphenylamino group, N-ethylmethylamino group, N-propylmethylamino group, N-isopropylmethylamino group, N-butylmethylamino group, N-decylamino group, N-decylmethylamino group, N-undecylamino group, N-undecylmethylamino group, N-dodecylamino group, N-dodecylmethylamino group, N-eicosylamino group, N-eicosylmethyl amino group, An amino group substituted with 1 or 2 hydrocarbon groups having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or derivative groups thereof (for example, groups derived from carboxyl, sulfo, nitro, hydroxyl, halogen (preferably chlorine atom), alkylsulfamoyl having 1 to 10 carbon atoms (preferably octylsulfamoyl), and the like, such as an N, N-tert-butylmethylamino group, an N, N-phenylmethylamino group, and the like, and groups represented by the following chemical formula);

A sulfamoyl group; n-methylsulfamoyl, N-dimethylsulfamoyl, N-ethylsulfamoyl, N-diethylsulfamoyl, N-propylsulfamoyl, N-dipropylsulfamoyl, N-isopropylsulfamoyl, N-diisopropylsulfamoyl, N-butylsulfamoyl, N-dibutylsulfamoyl, N-isobutylsulfamoyl, N-diisobutylsulfamoyl, N-sec-butylsulfamoyl, N-tert-butylsulfamoyl, N-di-tert-butylsulfamoyl, N-pentylsulfamoyl, N-dipentylsulfamoyl, N- (1-ethylpropyl) sulfamoyl, N-di (1-ethylpropyl) sulfamoyl, N-diethylsulfamoyl, N-di (1-ethylpropyl) sulfamoyl, N-diethylsulfamoyl, N-butylsulfamoyl, N-di (1-ethylpropyl) sulfamoyl, N-butylsulfamoyl, N-di (1-isobutylsulfamoyl), N-dibutylsulfamoyl, N, di (1-di (ethyl, N, N, N-hexylsulfamoyl, N-dihexylsulfamoyl, N- (2-ethyl) hexylsulfamoyl, N-di (2-ethyl) hexylsulfamoyl, N-heptylsulfamoyl, N-diheptylsulfamoyl, N-octylsulfamoyl, N-dioctylsulfamoyl, N-octylmethylsulfamoyl, N-nonylsulfamoyl, N-dinonylsulfamoyl, N-phenylsulfamoyl, N-diphenylsulfamoyl, N-ethylmethylsulfamoyl, N-propylmethylsulfamoyl, N-isopropylmethylsulfamoyl, N-butylmethylsulfamoyl, N-decylsulfamoyl, N-decylmethylsulfamoyl, Sulfamoyl groups substituted with 1 or 2 hydrocarbon groups having 1 to 20 (preferably 1 to 10) carbon atoms or derivative groups thereof (for example, groups derived from carboxyl, sulfo, nitro, hydroxyl, halogen (preferably chlorine atom), alkylsulfamoyl having 1 to 10 carbon atoms (preferably octylsulfamoyl), and the like, such as N-undecylsulfamoyl, N-undecylmethylsulfamoyl, N-dodecylsulfamoyl, N-dodecylmethylsulfamoyl, N-eicosylsulfamoyl, N-eicosylmethylsulfamoyl, N-tert-butylmethylsulfamoyl, N-phenylmethylsulfamoyl, and the like, and groups represented by the following chemical formulae);

A formylamino group; acetylamino, propionylamino, butyrylamino, 2-dimethylpropionylamino, valerylamino, hexanoylamino, (2-ethyl) hexanoylamino, heptanoylamino, a carbonylamino group (preferably 1 to 12 carbon atoms in the case where the carbonylamino group is an alkanoylamino group), to which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 12 carbon atoms) or a derivative thereof (for example, a derivative thereof such as a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)) is bonded, such as an octanoylamino group, a nonanoylamino group, a decanoylamino group, a undecanoylamino group, a dodecanoylamino group, a heneicosanoylamino group, or a benzoylamino group represented by the following chemical formula;

a hydroxyl group; halogen atoms such as fluorine atom, chlorine atom, bromine atom and iodine atom;

carboxy, -CO₂M²(M²Is an alkali metal, preferably lithium, sodium, potassium); sulfo, -SO₃M²(M²Is an alkali metal, preferably lithium, sodium, potassium); a nitro group; a cyano group; a formyloxy group; acetoxy, propionyloxy, butyryloxy, 2-dimethylpropionyloxy, pentanoyloxy, hexanoyloxy, (2-ethyl) hexanoyloxy, heptanoyloxy, a carbonyloxy group (preferably 1 to 10 carbon atoms in the case where the carbonyloxy group is an alkanoyloxy group) to which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or a derivative thereof (for example, a derivative thereof such as a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)) is bonded, such as an octanoyloxy group, a nonanoyloxy group, a decanoyloxy group, a undecanoyloxy group, a dodecanoyloxy group, a heneicosanoyloxy group, a benzoyloxy group, and the like, and a group represented by the following chemical formula;

A sulfonyl group having a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like) bonded thereto, such as a methylsulfonyl group, an ethylsulfonyl group, a propylsulfonyl group, a butylsulfonyl group, a pentylsulfonyl group, a hexylsulfonyl group, a (2-ethyl) hexylsulfonyl group, a heptylsulfonyl group, an octylsulfonyl group, a nonylsulfonyl group, a decylsulfonyl group, an undecylsulfonyl group, a dodecylsulfonyl group, an eicosylsulfonyl group, a phenylsulfonyl group, a p-tolylsulfonyl group, or the like represented by the following chemical formula;

a carbamoyl group; n-methylcarbamoyl, N-dimethylcarbamoyl, N-ethylcarbamoyl, N-diethylcarbamoyl, N-propylcarbamoyl, N-dipropylcarbamoyl, N-isopropylcarbamoyl, N-diisopropylcarbamoyl, N-butylcarbamoyl, N-dibutylcarbamoyl, N-isobutylcarbamoyl, N-diisobutylcarbamoyl, N-sec-butylcarbamoyl, N-di-sec-butylcarbamoyl, N-tert-butylcarbamoyl, N-di-tert-butylcarbamoyl, N-pentylcarbamoyl, N-dipentylcarbamoyl, N- (1-ethylpropyl) carbamoyl, N-ethylcarbamoyl, N-diethylcarbamoyl, N-isopropylcarbamoyl, N-diisopropylcarbamoyl, N-isopropylcarbamoyl, N-butylcarbamoyl, N-t-butylcarbamoyl, N-t-butylcarbamoyl, N-N-butylcarbamoyl, N-t-butylcarbamoyl, N-N-butylcarbamoyl, N-t-N-t-butylcarbamoyl, N-t-butylcarbamoyl, N-t, N, N-di (1-ethylpropyl) carbamoyl, N-hexylcarbamoyl, N-dihexylcarbamoyl, N- (2-ethyl) hexylcarbamoyl, N-di (2-ethyl) hexylcarbamoyl, N-heptylcarbamoyl, N-diheptylcarbamoyl, N-octylcarbamoyl, N-dioctylcarbamoyl, N-nonylcarbamoyl, N-octylmethylcarbamoyl, N-octylbutylcarbamoyl, N-dinonylcarbamoyl, N-phenylcarbamoyl, N-diphenylcarbamoyl, N-ethylmethylcarbamoyl, N-propylmethylcarbamoyl, N-ethylmethylcarbamoyl, N-propylmethylcarbamoyl, N-ethylhexylcarbamoyl, N-dihexylcarbamoyl, N- (2-ethyl) hexylcarbamoyl, N-octylcarbamoyl, N-diheptylcarbamoyl, N-octylcarbamoyl, N-nonylcarbamoyl, N-octylcarbamoyl, N-octylmethylcarbamoyl, N-octylcarbamoyl, N-octylmethylcarbamoyl, N-nonylcarbamoyl, N-dimethylcarbamoyl, N, a hydrocarbon group having 1 to 2 carbon atoms of 1 to 20 (preferably 1 to 10 carbon atoms) or a derivative thereof (for example, a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an N, N-isopropylmethylcarbamoyl group, an N, N-butylmethylcarbamoyl group, an N-decylmethylcarbamoyl group, an N, N-decylmethylcarbamoyl group, an N-undecylcarbamoyl group, an N, N-undecylmethylcarbamoyl group, an N-dodecylcarbamoyl group, an N, N-dodecylmethylcarbamoyl group, an N-eicosylcarbamoyl group, an N, N-eicosylmethylcarbamoyl group, an N, N-tert-butylmethylcarbamoyl group, an N, N-phenylmethylcarbamoyl group, etc., and a group represented by the following chemical formula, etc. (preferably a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), a derivative thereof, A carbamoyl group substituted with an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably, an octylsulfamoyl group) or the like;

A hydrocarbon group having 1 to 20 carbon atoms, which is obtained by substituting all hydrogen atoms with fluorine atoms such as a trifluoromethyl group, a perfluoroethyl group, a perfluoropropyl group, a perfluoroisopropyl group, a perfluorobutyl group, a perfluoropentyl group, a perfluorohexyl group, a perfluoroheptyl group, a perfluorooctyl group, a perfluorononyl group, a perfluorodecyl group, a perfluoroundecyl group, a perfluorododecyl group, a perfluoroeicosyl group, a perfluorocyclohexyl group, and a perfluorophenyl group;

a hydrocarbon group having 1 to 20 carbon atoms which has, as a substituent, a linear or branched alkyl group having 1 to 20 carbon atoms in which all hydrogen atoms are substituted with fluorine atoms, such as a perfluoroethylmethyl group, a perfluoropropylmethyl group, a perfluoroisopropylmethyl group, a perfluorobutylmethyl group, a perfluoropentylmethyl group, a perfluorohexylmethyl group, a perfluoroheptylmethyl group, a perfluorooctylmethyl group, a perfluorononylmethyl group, a perfluorodecylmethyl group, a perfluoroundecylmethyl group, a perfluorododecylmethyl group, or a perfluoroeicosylmethyl group;

a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) in which some hydrogen atoms are substituted with fluorine, such as a 2-fluorophenyl group, a 3-fluorophenyl group, a 4-fluorophenyl group, and a 2,4, 6-trifluorophenyl group;

-CO-SH、-CO-S-CH₃、-CO-S-CH₂CH₃、-CO-S-CH₂-CH₂-CH₃、-CO-S-CH₂-CH₂-CH₂-CH₃a thio group bonded to an alkyl group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms)Carbonyl (thiocarbonyl), -CO-S-C ₆H₅A thiocarbonyl group bonded to an aryl group having 6 to 20 carbon atoms;

a group represented by the following chemical formula, — COCO-R (wherein R represents a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)), or the like);

-NRCONR represented by the following chemical formula₂(wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group having 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like), and R's may be the same or different from each other and may be bonded to each other to form a ring);

OCONR represented by the following chemical formula₂(wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group having 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like), and R's may be the same or different from each other and may be bonded to each other to form a ring);

A group represented by the following chemical formula-NRCOOR (wherein R represents a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like), wherein R may be the same or different from each other, and may be bonded to each other to form a ring);

*-OP(O)(OCH₃)₂etc.. OP (O) (OR)₂(wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group having 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like), and R's may be the same or different from each other and may be bonded to each other to form a ring);

*-Si(CH₃)₃、*-Si(CH₂CH₃)₃、*-Si(C₆H₅)₃and-Si (CH)₃)₂)₃Etc. -SiR₃(wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group having 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like), and R's may be the same or different from each other and may be bonded to each other to form a ring); and so on.

Examples of the substituent having a valence of 2 include an oxo (oxo) group, a thioxo (thioxo) group, an imino group, and a group substituted with an alkyl group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms)And imino groups substituted with an aryl group having 6 to 20 carbon atoms. Examples of the imino group substituted with an alkyl group include CH₃-N＝、CH₃-CH₂-N＝、CH₃-(CH₂)₂-N ═ and CH₃-(CH₂)₃-N ═ and the like. Examples of the imino group substituted with an aryl group include C₆H₅-N ═ and the like.

As the substituent of the hydrocarbon group having 1 to 40 carbon atoms, preferred is a substituent of group s 1. The derivative group shown below is preferably a derivative group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like.

[ group s1]

An oxy group having a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof bonded to one side thereof; a carbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof is bonded; an oxycarbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof is bonded; an amino group; amino substituted by 1 or 2 alkyl with 1-20 carbon atoms or derivative groups thereof; a sulfamoyl group; a sulfamoyl group substituted with 1 or 2 hydrocarbon groups having 1 to 20 carbon atoms or derivative groups thereof; a carbonylamino group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof is bonded; a hydroxyl group; a halogen atom; -CO ₂M (preferably carboxyl group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom); -SO₃M (preferably sulfo) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom); a nitro group; a cyano group; a carbonyloxy group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof is bonded; a sulfonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof is bonded; a carbamoyl group; carbamoyl substituted by 1 or 2 hydrocarbon groups having 1 to 20 carbon atoms or derivative groups thereof; a hydrocarbon group having 1 to 20 carbon atoms, wherein all hydrogen atoms are substituted with fluorine atoms; a hydrocarbon group having 1 to 20 carbon atoms, which has a linear or branched alkyl group having 1 to 20 carbon atoms, wherein all hydrogen atoms are substituted with fluorine atoms, as a substituent; a hydrocarbon group having 1 to 20 carbon atoms, wherein a part of hydrogen atoms is substituted with fluorine; oxo radical。

The substituent of the hydrocarbon group having 1 to 40 carbon atoms is more preferably a substituent of group s 2.

[ group s2]

An oxy group having a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof bonded to one side thereof;

a carbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded;

an oxycarbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded;

An amino group; an amino group substituted with 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms;

a sulfamoyl group; a sulfamoyl group substituted with 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms or derivative groups thereof; a carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded; a hydroxyl group; fluorine atom, chlorine atom, bromine atom;

-CO₂m (preferably carboxyl group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom); -SO₃M (preferably sulfo) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom); a nitro group; a cyano group; a carbonyloxy group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded; a sulfonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded; a carbamoyl group; carbamoyl substituted by 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms or derivative groups thereof; a hydrocarbon group having 1 to 10 carbon atoms, wherein all hydrogen atoms are substituted with fluorine atoms; a hydrocarbon group having 1 to 10 carbon atoms, which has a linear or branched alkyl group having 1 to 10 carbon atoms, wherein all hydrogen atoms are substituted with fluorine atoms, as a substituent;

a hydrocarbon group having 1 to 10 carbon atoms, wherein a part of hydrogen atoms is substituted with fluorine; an oxo group.

As R^O1Z1、R^1Z1、R^2Z1、R^3Z1、R^4Z1、R^5Z1、R^6Z1、R^7Z1、R^101Z1And R^102Z1The hydrocarbyl group having 1 to 40 carbon atoms which is a substituent represented by the formula (I) includes those having 1 to 40 carbon atoms which are substituents having a valence of 1 or 2The hydrocarbon group is preferably a saturated or unsaturated chain hydrocarbon group having 1 to 30 carbon atoms and having a substituent having a valence of 1 or 2, a saturated or unsaturated alicyclic hydrocarbon group having 3 to 30 carbon atoms and having a substituent having a valence of 1 or 2, an aromatic hydrocarbon group having 6 to 30 carbon atoms and having a substituent having a valence of 1 or 2, or a group having 1 to 30 carbon atoms and having a substituent having a valence of 1 or 2, which is a combination of hydrocarbon groups,

more preferably, the hydrocarbon group includes a saturated or unsaturated chain hydrocarbon group having 1 to 20 carbon atoms having a substituent of group s1, a saturated or unsaturated alicyclic hydrocarbon group having 3 to 20 carbon atoms having a substituent of group s1, an aromatic hydrocarbon group having 6 to 20 carbon atoms having a substituent of group s1, or a combination of hydrocarbon groups having 1 to 20 carbon atoms having a substituent of group s1,

particularly preferred examples thereof include a saturated or unsaturated chain hydrocarbon group having 1 to 15 carbon atoms having a substituent of group s2, a saturated or unsaturated alicyclic hydrocarbon group having 3 to 15 carbon atoms having a substituent of group s2, an aromatic hydrocarbon group having 6 to 15 carbon atoms having a substituent of group s2, or a group having 1 to 15 carbon atoms having a substituent of group s2, which is a combination of hydrocarbon groups.

As R^O1Z1、R^1Z1、R^2Z1、R^3Z1、R^4Z1、R^5Z1、R^6Z1、R^7Z1、R^101Z1And R^102Z1The heterocyclic group represented by (a) may be monocyclic or polycyclic, and is preferably a heterocyclic ring containing a heteroatom as a constituent of the ring. Examples of the hetero atom include a nitrogen atom, an oxygen atom, a sulfur atom and the like.

The number of carbon atoms of the heterocyclic group is preferably 3 to 30, more preferably 3 to 22, further preferably 3 to 20, further preferably 3 to 18, further more preferably 3 to 15, and particularly preferably 3 to 14.

Examples of the heterocyclic ring containing a nitrogen atom include:

monocyclic saturated heterocycles such as aziridine, azetidine, pyrrolidine, piperidine and piperazine;

five-membered ring system unsaturated heterocycles such as pyrrole (e.g., 2, 5-dimethylpyrrole), pyrazole (e.g., 2-methylpyrazole and 3-methylpyrazole), imidazole, 1,2, 3-triazole and 1,2, 4-triazole;

a six-membered ring system unsaturated heterocycle such as pyrimidine, pyrazine and 1,3, 5-triazine, for example pyridine, pyridazine and 6-methylpyrimidine;

a fused bicyclic heterocycle such as quinoxaline (e.g., indazole, indoline, isoindoline, indole, indolizine, benzimidazole, quinoline, isoquinoline, 5,6,7, 8-tetrahydro (3-methyl) quinoxaline or 3-methylquinoxaline, quinazoline, cinnoline, phthalazine, naphthyridine, purine, pteridine, benzopyrazole or phenylpiperidine;

Condensed tricyclic heterocycles such as carbazole, acridine and phenazine; and so on.

Examples of the heterocyclic ring containing an oxygen atom include:

monocyclic saturated heterocycles such as oxetane, tetrahydrofuran, tetrahydropyran, 1, 3-dioxane, 1, 4-dioxane and 1-cyclopentyldioxolane; bicyclic saturated heterocycles such as 1, 4-dioxaspiro [4.5] decane and 1, 4-dioxaspiro [4.5] nonane; lactone-based heterocycles such as α -acetolactone, β -propiolactone, γ -butyrolactone, γ -valerolactone and δ -valerolactone;

five-membered ring system unsaturated heterocycles such as furan (e.g., 2, 3-dimethylfuran, 2, 5-dimethylfuran); a six-membered ring system unsaturated heterocycle such as 2H-pyran, 4H-pyran; fused bicyclic heterocycles such as benzopyrans (e.g., 1-benzofuran and 4-methylbenzopyran), benzodioxole (benzodioxole), chroman and isochroman; fused tricyclic heterocycles such as xanthene and dibenzofuran; and so on.

Examples of the heterocyclic ring containing a sulfur atom include a five-membered ring system saturated heterocyclic ring such as dithiolane; saturated heterocycles with six-membered ring systems, such as thiacyclohexane (thiane), 1, 3-dithiane, 2-methyl-1, 3-dithiane; a five-membered ring system unsaturated heterocycle such as thiophene (e.g., 3-methylthiophene, 2-carboxythiophene), benzothiopyran (e.g., 4H-thiopyran, tetrahydrothiopyran); fused bicyclic heterocycles such as benzothiophene;

Fused tricyclic heterocycles such as thianthrene and dibenzothiophene; and so on.

Examples of the heterocyclic ring containing a nitrogen atom and an oxygen atom include:

monocyclic saturated heterocycles such as morpholine, 2-pyrrolidone, 2-methyl-2-pyrrolidone, 2-piperidone and 2-methyl-2-piperidone;

a monocyclic unsaturated heterocycle such as oxazole (e.g., 4-methyloxazole), isoxazole (e.g., 2-methylisoxazole, and 3-methylisoxazole); fused bicyclic heterocycles such as benzoxazole, benzisoxazole, benzoxazine, benzodioxane, and benzimidazoline; condensed tricyclic heterocycles such as phenoxazine; and so on.

Examples of the heterocyclic ring containing a nitrogen atom and a sulfur atom include monocyclic heterocyclic rings such as thiazoles, e.g., 3-methylthiazole and 2, 4-dimethylthiazole; fused bicyclic heterocycles such as benzothiazole; fused tricyclic heterocycles such as phenothiazine; and so on.

The heterocyclic ring may be a combination of the above-mentioned hydrocarbon groups, and examples thereof include tetrahydrofurylmethyl and the like.

The heterocyclic ring may be a heterocyclic ring represented by the following chemical formula.

The above heterocyclic group may be R^1Z1～R^5Z12 or more of them are bonded to form a heterocyclic group. Such heterocyclic radicals contain R^1Z1～R^5Z1The bonded benzene ring has a ring structure of 2 or more rings inside. The 2 or more ring structures include, for example, the structures of the following chemical formulae.

The bonding position of the heterocycle is a portion where any hydrogen atom contained in each ring is removed.

R^O1Z1、R^1Z1、R^2Z1、R^3Z1、R^4Z1、R^5Z1、R^6Z1、R^7Z1、R^101Z1And R^102Z1The heterocyclic group represented may have a substituent. As the substituent, there may be mentionedAre mentioned with R^O1Z1、R^1Z1、R^2Z1、R^3Z1、R^4Z1、R^5Z1、R^6Z1、R^7Z1、R^101Z1And R^102Z1The hydrocarbon group may have the same substituent as the substituent. In addition, in the case where the above-mentioned heterocyclic ring contains a nitrogen atom as its constituent element, the above-mentioned hydrocarbon group as a substituent may be bonded to the nitrogen atom.

Preferred examples of the substituent include^O1Z1、R^1Z1、R^2Z1、R^3Z1、R^4Z1、R^5Z1、R^6Z1、R^7Z1、R^101Z1And R^102Z1The preferable examples of the substituents which the hydrocarbon group may have are the same. As R^O1Z1、R^1Z1、R^2Z1、R^3Z1、R^4Z1、R^5Z1、R^6Z1、R^7Z1、R^101Z1And R^102Z1The heterocyclic group having a substituent represented by the formula (i) includes a heterocyclic group having a substituent having a valence of 1 or 2, preferably a heterocyclic group having a substituent of group s1, and more preferably a heterocyclic group having a substituent of group s 2.

The substituent (first substituent) that the hydrocarbon group or heterocyclic group may have may be 1 or 2 or more, and 2 or more substituents may be the same or different and independent of each other. Further, the first substituent may have another substituent (second substituent) bonded to the hydrocarbon group included in a part thereof. The second substituent may be selected from the same groups as the first substituent.

Below, for R^1Z1、R^2Z1、R^3Z1、R^4Z1、R^5Z1、R^6Z1、R^7Z1Of (a) is-CO-R^102Z1、-COO-R^101Z1、-OCO-R^102Z1、-COCO-R^102Z1、-O-R^102Z1、-SO₂-R^101Z1、-SO₂N(R^102Z1)₂、-CON(R^102Z1)₂、-N(R^102Z1)₂、-NHCO-R^102Z1、-NHCO-N(R^102Z1)₂、-NHCOOR^102Z1、-OCON(R^102Z1)₂Halogen atom, -SO₃M、-CO₂M is explained.

as-CO-R^102Z1Examples thereof include a formyl group; acetyl, propionyl, butyryl, 2-dimethylpropionyl, pentanoyl, hexanoyl, (2-ethyl) hexanoyl, heptanoyl, examples of the carbonyl group include a carbonyl group (in the case where the carbonyl group is an acyl group, the number of carbon atoms is 2 to 41) in which a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)) is bonded, such as an octanoyl group, a nonanoyl group, a decanoyl group, a undecanoyl group, a dodecanoyl group, an heneicosanoyl group, and a benzoyl group, and the compounds shown in tables 1Z1 to 7Z1 and 10Z1 to 13Z1 correspond to — CO — R.^102Z1Preferable examples of the group(s) include a carbonyl group (more preferably 2 to 12 carbon atoms when the carbonyl group is an alkanoyl group) to which a hydrocarbon group having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms) or a derivative thereof is bonded, and compounds shown in tables 1Z1 to 7Z1 and tables 10Z1 to 13Z1 correspond to-CO-R ^102Z1And the like.

as-COO-R^101Z1Examples thereof include methoxycarbonyl, ethoxycarbonyl, propoxycarbonyl, tert-butoxycarbonyl, pentyloxycarbonyl, hexyloxycarbonyl, (2-ethyl) hexyloxycarbonyl and heptyloxycarbonyl, an oxycarbonyl group in which a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) is bonded such as an octyloxycarbonyl group, a nonyloxycarbonyl group, a decyloxycarbonyl group, an undecyloxycarbonyl group, a dodecyloxycarbonyl group, a phenyloxycarbonyl group, an eicosyloxycarbonyl group and the like, and the groups represented by the above chemical formulae, and the compounds shown in tables 1Z1 to 7Z1 and tables 10Z1 to 13Z1 correspond to-COO-R.^101Z1Preferred examples of the group (b) include oxycarbonyl groups to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded, and compounds shown in tables 1Z1 to 7Z1 and tables 10Z1 to 13Z1 which correspond to-COO-R^101Z1And the like.

as-OCO-R^102Z1Examples thereof include a formyloxy group; acetoxy, propionyloxy, butyryloxy, 2-dimethylpropionyloxy, pentanoyloxy, hexanoyloxy, (2-ethyl) hexanoyloxy, heptanoyloxy, octanoyloxy, nonanoyloxy, decanoyloxy, undecanoyloxy, dodecanoyloxy, heneicosanoyloxy, benzoyloxy and the like, carbonyloxy (carbon number 2 to 41 in the case where the carbonyloxy group is an acyloxy group), carbonyloxy group in which a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) is bonded such as the group represented by the above chemical formula, and the compounds shown in tables 1Z1 to 7Z1 and tables 10Z1 to 13Z1 correspond to-OCO- R ^102Z1Preferable examples of the group(s) include a carbonyloxy group (more preferably 2 to 12 carbon atoms in the case where the carbonyloxy group is an acyloxy group) to which a hydrocarbon group having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms) or a derivative thereof is bonded, and a compound represented by any one of tables 1Z1 to 7Z1 and tables 10Z1 to 13Z1 corresponds to-OCO-R^102Z1And the like.

as-COCO-R^102Z1Examples thereof include a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof bonded (for example, via a carboxyl group, a sulfo group, a nitro group, a carboxyl group, a sulfo group, a carboxyl group, a nitro group, a carboxyl group, a sulfo group, a pentyl group, a hexyl group, a (2-ethyl) hexyl group, a heptyl group, an octyl group, a nonyl group, a decyl group, an undecyl group, a dodecyl group, an eicosyl group, a cyclopentyl group, a cyclohexyl group, a phenyl group, a tolyl group, a p-tolyl group and the likeOxalyl groups derived from a hydroxyl group, a halogen (preferably chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl), and the like), and compounds represented by tables 1Z1 to 7Z1 and tables 10Z1 to 13Z1, wherein the oxalyl groups correspond to-COCO-R ^102Z1And the like.

as-O-R^102Z1There may be mentioned a hydroxyl group; methoxy, ethoxy, propoxy, isopropoxy, butoxy, isobutoxy, sec-butoxy, tert-butoxy, pentyloxy, hexyloxy, heptyloxy, octyloxy, nonyloxy, decyloxy, undecyloxy, dodecyloxy, (2-ethyl) hexyloxy, eicosyloxy, 1-phenylethoxy, 1-methyl-1-phenylethoxy, phenyloxy, 2, 3-dimethylphenyloxy, 2, 4-dimethylphenyloxy, 2, 5-dimethylphenyloxy, 2, 6-dimethylphenyloxy, 3, 4-dimethylphenyloxy, 3, 5-dimethylphenyloxy, 2-dicyanophenyloxy, 2, 3-dicyanophenyloxy, 2, 4-dicyanophenyloxy, sec-butyloxy, tert-butyloxy, pentyloxy, hexyloxy, heptyloxy, octyloxy, decyloxy, 2, 3-dimethylphenyloxy, 2, 4-dimethylphenyloxy, 2, 4-dimethylphenyloxy, 3-dimethylphenyloxy, 2-dicyanophenyloxy, 2, 4-di-yloxy, 2-di-methyl-1-phenylethoxy, 2, 4-di-methyl, and mixtures thereof, 2, 5-dicyanophenyloxy group, 2, 6-dicyanophenyloxy group, 3, 4-dicyanophenyloxy group, 3, 5-dicyanophenyloxy group, 4-methoxyphenyloxy group, 2-methoxyphenyloxy group, examples of the oxygen group include an oxygen group having a hydrocarbyl group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like bonded thereto, such as a 3-methoxyphenyloxy group, a 4-ethoxyphenyloxy group, a 2-ethoxyphenyloxy group, a 3-ethoxyphenyloxy group, or the like, and a group represented by the above chemical formulae), and compounds shown in tables 1Z1 to 7Z1 and tables 10Z1 to 13Z1 correspond to — O — R. ^102Z1Preferred examples of the group (b) include an oxy group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded, and compounds shown in tables 1Z1 to 7Z1 and tables 10Z1 to 13Z1, which correspond to-O-R^102Z1And the like.

as-SO₂-R^101Z1Examples thereof include methylsulfonyl, ethylsulfonyl, propylsulfonyl, butylsulfonyl, pentylsulfonyl, hexylsulfonyl, (2-ethyl) hexylsulfonyl, and heptylsulfonylSulfonyl groups in which a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) is bonded, such as a alkylsulfonyl group, an octylsulfonyl group, a nonylsulfonyl group, a decylsulfonyl group, an undecylsulfonyl group, a dodecylsulfonyl group, an eicosylsulfonyl group, a phenylsulfonyl group, a p-tolylsulfonyl group, and the like, and a group represented by the above chemical formulae (i) and (ii) are bonded, and (ii) compounds corresponding to-SO in tables 1Z1 to 7Z1 and tables 10Z1 to 13Z1 are listed₂-R^101Z1Preferable examples of the group (b) include sulfonyl groups to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded, and compounds represented by tables 1Z1 to 7Z1 and tables 10Z1 to 13Z1, which correspond to-SO ₂-R^101Z1And the like.

as-SO₂N(R^102Z1)₂Examples thereof include:

a sulfamoyl group; n-methylsulfamoyl, N-ethylsulfamoyl, N-propylsulfamoyl, N-isopropylsulfamoyl, N-butylsulfamoyl, N-isobutylsulfamoyl, N-sec-butylsulfamoyl, N-tert-butylsulfamoyl, N-pentylsulfamoyl, N- (1-ethylpropyl) sulfamoyl, N-hexylsulfamoyl, N- (2-ethyl) hexylsulfamoyl, N-heptylsulfamoyl, N-octylsulfamoyl, N-nonylsulfamoyl, N-decylsulfamoyl, N-undecylsulfamoyl, N-dodecylsulfamoyl, N-eicosylsulfamoyl, N-phenylsulfamoyl, etc., and a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group represented by the above formula, or a derivative thereof Sulfamoyl substituted with a raw group (e.g., a group derived from carboxyl, sulfo, nitro, hydroxyl, halogen (preferably chlorine atom), alkylsulfamoyl having 1 to 10 carbon atoms (preferably octylsulfamoyl), etc.), and compounds shown in tables 1Z1 to 7Z1 and tables 10Z1 to 13Z1, which correspond to-SO₂NH(R^102Z1X)(R^102Z1XIs not a hydrogen atom, other than, and R^102Z1The same as defined above), etc.;

N, N-dimethylsulfamoyl, N-ethylmethylsulfamoyl, N-diethylsulfamoyl, N-propylmethylsulfamoyl, N-dipropylsulfamoyl, N-isopropylmethylsulfamoyl, N-diisopropylsulfamoyl, N-tert-butylmethylsulfamoyl, N-diisobutylsulfamoyl, N-di-sec-butylsulfamoyl, N-di-tert-butylsulfamoyl, N-butylmethylsulfamoyl, N-dibutylsulfamoyl, N-dipentylsulfamoyl, N-bis (1-ethylpropyl) sulfamoyl, N-dihexylsulfamoyl, N-bis (2-ethyl) hexylsulfamoyl, N-diethylsulfamoyl, N, N-diheptylsulfamoyl, N-octylmethylsulfamoyl, N-dioctylsulfamoyl, N-dinonylsulfamoyl, N-decylmethylsulfamoyl, N-undecylmethylsulfamoyl, N-dodecylmethylsulfamoyl, N-eicosylmethylsulfamoyl, N-phenylmethylsulfamoyl, N-diphenylsulfamoyl and the like, and sulfamoyl groups represented by the above chemical formulae and the like substituted with a hydrocarbon group having 1 to 40 (preferably 1 to 20) carbon atoms or a derivative thereof (for example, a derivative derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl) and the like), and sulfamoyl groups shown in tables 1Z1 to 7Z1 and tables 10Z1 to 13Z1 Corresponding to-SO in the compound ₂N(R^102Z1X)₂(wherein, R^102Z1XIs not a hydrogen atom, other than, and R^102Z1The same as defined above) and the like,

preferred examples thereof include sulfamoyl groups substituted with 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms or derivatives thereof, and compounds represented by tables 1Z1 to 7Z1 and tables 10Z1 to 13Z1, which correspond to-SO₂N(R^102Z1)₂And the like.

as-CON (R)^102Z1)₂Examples thereof include:

a carbamoyl group; n-methylcarbamoyl, N-ethylcarbamoyl, N-propylcarbamoyl, N-isopropylcarbamoyl, N-butylcarbamoyl, N-isobutylcarbamoyl, N-sec-butylcarbamoyl, N-tert-butylcarbamoyl, N-pentylcarbamoylCarbamoyl groups such as carbamoyl, N- (1-ethylpropyl) carbamoyl, N-hexylcarbamoyl, N- (2-ethyl) hexylcarbamoyl, N-heptylcarbamoyl, N-octylcarbamoyl, N-nonylcarbamoyl, N-decylcarbamoyl, N-undecylcarbamoyl, N-dodecylcarbamoyl, N-eicosylcarbamoyl, N-phenylcarbamoyl and the like, and carbamoyl groups represented by the above chemical formulae which are substituted with a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a derivative thereof with a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) and the like), and also, in tables 1Z1 to 7Z1 and 10Z1 to the compounds shown in Table 13Z1 correspond to-CONH (R) ^102Z1X) (wherein, R^102Z1XIs not a hydrogen atom, other than, and R^102Z1The same as defined above), etc.;

n, N-dimethylcarbamoyl group, N-ethylmethylcarbamoyl group, N-diethylcarbamoyl group, N-propylmethylcarbamoyl group, N-dipropylcarbamoyl group, N-isopropylmethylcarbamoyl group, N-diisopropylcarbamoyl group, N-tert-butylmethylcarbamoyl group, N-diisobutylcarbamoyl group, N-di-sec-butylcarbamoyl group, N-di-tert-butylcarbamoyl group, N-butylmethylcarbamoyl group, N-dibutylcarbamoyl group, N-butyloctylcarbamoyl group, N-dipentylcarbamoyl group, N-di (1-ethylpropyl) carbamoyl group, N-diethylcarbamoyl group, N-diisopropylcarbamoyl group, N-di (1-ethylpropyl) carbamoyl group, N-t-butylmethylcarbamoyl group, N-di-butylmethylcarbamoyl group, N-t-butylmethylcarbamoyl group, N-di (1-ethylpropyl) carbamoyl group, N-t-butylmethylcarbamoyl group, N-di-isobutylcarbamoyl group, N-di (s-butylmethylcarbamoyl group, N-di-butylmethylcarbamoyl group, N-di-N-butylcarbamoyl group, N, a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a carboxyl group, a sulfo group, an N, N-di (2-ethyl) hexylcarbamoyl group, an N, N-diheptylcarbamoyl group, an N, N-octylmethylcarbamoyl group, an N, N-dinonylcarbamoyl group, an N, N-decylmethylcarbamoyl group, an N, N-undecylmethylcarbamoyl group, an N, N-dodecylmethylcarbamoyl group, an N, N-eicosylmethylcarbamoyl group, an N, N-phenylmethylcarbamoyl group, an N, N-diphenylcarbamoyl group, etc., and a group represented by the above chemical formula, Nitro, hydroxy, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group), and the like) and the compounds shown in tables 1Z1 to 7Z1 and tables 10Z1 to 13Z1 correspond to-CON (R)^102Z1X)₂(wherein, R^102Z1XIs not a hydrogen atom, other than, and R^102Z1The same as defined above) and the like,

preferred examples thereof include a carbamoyl group substituted with 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms or a derivative thereof and a compound represented by any one of tables 1Z1 to 7Z1 and 10Z1 to 13Z1 which corresponds to-CON (R)^102Z1)₂And the like.

as-N (R)^102Z1)₂Examples thereof include:

an amino group; a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom)), such as an N-methylamino group, an N-ethylamino group, an N-propylamino group, an N-isopropylamino group, an N-butylamino group, an N-isobutylamino group, an N-sec-butylamino group, an N-tert-butylamino group, an N-pentylamino group, an N-hexylamino group, an N- (2-ethyl) hexylamino group, an N-heptylamino group, an N-octylamino group, an N-nonylamino group, an N-decylamino group, an N-undecylamino group, an N-dodecylamino group, an N-eicosylamino group, an N-phenylamino group, and the like, and a group represented by the above chemical formula, A group derived from an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably, an octylsulfamoyl group) or the like) and a compound shown in tables 1Z1 to 7Z1 and 10Z1 to 13Z1, wherein the compound corresponds to-NH (R ^102Z1X) (wherein, R^102Z1XIs not a hydrogen atom, other than, and R^102Z1The same as defined above), etc.;

n, N-dimethylamino group, N-ethylmethylamino group, N-diethylamino group, N-propylmethylamino group, N-dipropylamino group, N-isopropylmethylamino group, N-diisopropylamino group, N-tert-butylmethylamino group, N-diisobutylamino group, N-di-sec-butylamino group, N-di-tert-butylamino group, N-butylmethylamino group, N-dibutylamino group, N-dipentylamino group, N-bis (1-ethylpropyl) amino group, N-dipropylamino group, N-isopropylmethylamino group, N-diisopropylamino group, N-tert-butylmethylamino group, N-diisobutylamino group, N-di-sec-butylamino group, N-di (1-ethylpropyl) amino group, N-di (tert-butylamino group, N-dibutylamino group, N-dipentylamino group, N-di (1-ethylpropyl) amino group, N-di (i-butylamino group, N-butylamino group, N-butylamino group, N-butylamino group, N-butylamino, N, or the like, N, or the like, N,an amino group substituted with a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), and the like, and a compound shown in tables 1Z1 to 7Z1 and tables 10Z 35 1 to 13Z1, such as a compound shown in tables 1Z 8932 and tables 10Z 353925 Is equivalent to-N (R) ^102Z1X)₂And the like,

preferred examples thereof include amino groups substituted with 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms or derivatives thereof and compounds shown in tables 1Z1 to 7Z1 and tables 10Z1 to 13Z1 which correspond to-N (R)^102Z1)₂And the like.

as-NHCO-R^102Z1Examples thereof include formylamino; acetylamino, propionylamino, butyrylamino, 2-dimethylpropionylamino, valerylamino, hexanoylamino, (2-ethyl) hexanoylamino, heptanoylamino, octanoylamino, nonanoylamino, decanoylamino, undecanoylamino, dodecanoylamino, heneicosanoylamino, benzoylamino and the like, carbonylamino (carbon number 1 to 40 in the case of carbonylamino being an acylamino group, carbon number 1 to 40 in the case of carbonylamino), carbonylamino to which a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 in the case of carbonylamino being a carbonylamino group) or a derivative thereof (for example, a derivative thereof such as a hydrocarbon group having 1 to 10 carbon atoms (preferably a C1 to 10 alkylsulfamoyl group) is bonded such as a group represented by the above formula, and compounds represented by tables 1Z1 to 7Z1 and tables 10Z1 to 13Z1 correspond to-NHCO- R ^102Z1And the like,

preferably, the carbonyl amino group (in which the carbonyl amino group is an alkanoylamino group) to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bondedIn the case where the number of carbon atoms is more preferably 1 to 10), and the compounds shown in Table 1Z1 to Table 7Z1 and Table 10Z1 to Table 13Z1 correspond to-NHCO-R^102Z1And the like.

as-NHCON (R)^102Z1)₂Examples thereof include the groups listed above and the compounds shown in tables 1Z1 to 7Z1 and tables 10Z1 to 13Z1 which correspond to-NHCON (R)^102Z1)₂And the like.

as-NHCOOR^102Z1Examples thereof include those corresponding to-NHCOOR among the above-mentioned groups and the compounds shown in tables 1Z1 to 7Z1 and tables 10Z1 to 13Z1^102Z1And the like.

as-OCON (R)^102Z1)₂Examples thereof include those corresponding to-OCON (R) among the above-mentioned groups and the compounds shown in tables 1Z1 to 7Z1 and tables 10Z1 to 13Z1^102Z1)₂And the like.

The halogen atom is preferably a fluorine atom, a chlorine atom, a bromine atom, an iodine atom or the like.

as-SO₃M and-CO₂M in M is a hydrogen atom; the alkali metal atom such as lithium atom, sodium atom and potassium atom, preferably hydrogen atom, sodium atom and potassium atom.

The above-mentioned-CO-R^102Z1、-COO-R^102Z1、-OCO-R^102Z1、-COCO-R^102Z1、-O-R^102Z1、-SO₂-R^102Z1、-SO₂N(R^102Z1)₂、-CON(R^102Z1)₂、-N(R^102Z1)₂、-NHCO-R^102Z1、-NHCON(R^102Z)₂、-NHCOOR^102Z1、-OCON(R^102Z1)₂The number of the substituents (first substituents) contained in (2) may be 1 or 2 or more, and 2 or more substituents may be the same or different and independent of each other.

Further, the first substituent may have another substituent (second substituent) bonded to the hydrocarbon group included in a part thereof. The second substituent may be selected from the same groups as the first substituent.

R^2Z1And R^3Z1、R^3Z1And R^4Z1And R^4Z1And R^5Z1The ring formed is fused with the benzene ring of the isoindoline skeleton of the compound represented by the formula (IZ 1). As R^2Z1And R^3Z1、R^3Z1And R^4Z1And R^4Z1And R^5Z1Examples of the condensed ring structure of the ring formed and the benzene ring include indene, naphthalene, biphenylene (biphenylene), indacene (indacene), acenaphthylene, fluorene, phenalene (phenalene), phenanthrene, anthracene, fluoranthene, acephenanthrylene (aceanthrylene), aceanthrylene (aceanthrylene), and benzo [9,10 ] benzo]Phenanthrene (triphenylene), pyrene,

Hydrocarbon-based condensed ring structures such as N-methylphthalimide, N- (1-phenylethyl) phthalimide, and tetracene, and partially reduced products thereof (for example, 9, 10-dihydroanthracene, 1,2,3, 4-tetrahydronaphthalene, and the like); indole, isoindole, indazole, quinoline, isoquinoline, phthalazine, quinoxaline, quinazoline, cinnoline, carbazole, carboline, phenanthridine, acridine, quinoline, quinoxaline, quinoline, and/or quinoline derivative,

Nitrogen-containing fused heterocycles such as pyridine, phenanthroline, and phenazine, and partial reductants thereof; oxygen-containing fused heterocycles such as 3-hydrobenzofuran-2-one and partial reductants thereof.

R^2Z1And R^3Z1、R^3Z1And R^4Z1And R^4Z1And R^5Z1In the case of forming a ring, the ring may have a substituent. Examples of the substituent include^O1Z1、R^1Z1、R^2Z1、R^3Z1、R^4Z1、R^5Z1、R^6Z1、R^7Z1、R^101Z1And R^102Z1The hydrocarbon group may have the same substituent as the substituent. Preferred examples of the substituent include^O1Z1、R^1Z1、R^2Z1、R^3Z1、R^4Z1、R^5Z1、R^6Z1、R^7Z1、R^101Z1And R^102Z1The preferable examples of the substituents which the hydrocarbon group may have are the same.

R^3Z1And R^4Z1When forming a ring, as R^2Z1And R^5Z1Independently of one another, hydrogen atoms, amino groups and hydroxyl groups are preferred.

R^2Z1And R^3Z1When a ring is formed, R is preferably^4Z1And R^5Z1Does not form a ring, more preferably R^4Z1And R^5Z1Is a hydrogen atom.

In addition, R^4Z1And R^5Z1When a ring is formed, R is preferably^2Z1And R^3Z1Does not form a ring, more preferably R^2Z1And R^3Z1Is a hydrogen atom.

In the present invention, R^1Z1、R^6Z1And R^7Z1Preferably a hydrogen atom.

In the present invention, R^O1Z1The hydrocarbon group is preferably a hydrogen atom or a hydrocarbon group having 1 to 30 carbon atoms which may have a substituent, more preferably a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent, still more preferably a hydrogen atom or a hydrocarbon group having 1 to 15 carbon atoms which may have a substituent, particularly preferably a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent, particularly preferably a hydrogen atom or a hydrocarbon group having 1 to 6 carbon atoms which may have a substituent or a hydrocarbon group having 1 to 5 carbon atoms which may have a substituent, particularly preferably a hydrogen atom, a methyl group, an ethyl group or a phenyl group, and most preferably a hydrogen atom, a methyl group or an ethyl group.

From the viewpoint of reducing the retardation value of a color filter made of the colored composition, R is preferably^2Z1、R^3Z1、R^4Z1And R^5Z1At least one of which is-CO-R^102Z1、-COO-R^101Z1、-OCO-R^102Z1、-COCO-R^102Z1、-O-R^102Z1、-SO₂-R^101Z1、-SO₂N(R^102Z1)₂、-CON(R^102Z1)₂、-N(R^102Z1)₂、-NHCO-R^102Z1、-NHCO-N(R^102Z1)₂、-NHCOOR^102Z1、-OCON(R^102Z1)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M、A hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent,

more preferably a C1-40 hydrocarbon group which may have a substituent, a halogen atom, or-N (R)^102Z1)₂A C1-20 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R^102Z1、-O-R^102Z1、-SO₃M or-CO₂M is more preferably a nitro group or a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, and still more preferably a nitro group or a tert-butyl group. Alternatively, R is preferred^2Z1And R^3Z1、R^3Z1And R^4Z1Or R^4Z1And R^5Z1Form a ring.

Compound IZ1 is preferably the following compound: r^2Z1、R^3Z1、R^4Z1And R^5Z1At least one of which is-CO-R^102Z1、-COO-R^101Z1、-OCO-R^102Z1、-COCO-R^102Z1、-O-R^102Z1、-SO₂-R^101Z1、-SO₂N(R^102Z1)₂、-CON(R^102Z1)₂、-N(R^102Z1)₂、-NHCO-R^102Z1、-NHCO-N(R^102Z1)₂、-NHCOOR^102Z1、-OCON(R^102Z1)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent, or R^2Z1And R^3Z1、R^3Z1And R^4Z1And R^4Z1And R^5Z1At least one group of the compounds (hereinafter, this compound may be referred to as "compound IZ 1-B") is bonded to form a ring. When the compound IZ1 is the compound IZ1-B, the retardation value of the color filter produced from the colored composition becomes small.

From the viewpoint of reducing the retardation value of a color filter made of the colored composition, R is preferably^2Z1、R^3Z1、R^4Z1And R^5Z1At least one of the above (B) is a C1-4 carbon atom which may have a substituent0 hydrocarbyl group, halogen atom, -N (R)^102Z1)₂A C1-20 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R^102Z1、-O-R^102Z1、-SO₃M or-CO₂M，

More preferably a nitro group or a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, and still more preferably a nitro group or a tert-butyl group. It is especially preferred that R^3Z1Is nitro or tert-butyl, R^2Z1、R^4Z1And R^5Z1Is a hydrogen atom; or, R^2Z1、R^3Z1And R^5Z1Is a hydrogen atom, R^4Z1Is nitro or tert-butyl.

When the above compound IZ1-B is defined by a chemical formula, it is as follows.

[ formula (IZ1-B) wherein R^O11Z1Represents a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group. R^1Z1、R^21Z1、R^31Z1、R^41Z1、R^51Z1、R^61Z1And R^71Z1Independently of one another, represents a hydrogen atom, -CO-R^102Z1、-COO-R^101Z1、-OCO-R^102Z1、-COCO-R^102Z1、-O-R^102Z1、-SO₂-R^101Z1、-SO₂N(R^102Z1)₂、-CON(R^102Z1)₂、-N(R^102Z1)₂、-NHCO-R^102Z1、-NHCO-N(R^102Z1)₂、-NHCOOR^102Z1、-OCON(R^102Z1)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.

R^21Z1And R^31Z1、R^31Z1And R^41Z1And R^41Z1And R^51Z1Can be bonded to each other to form a ring。

Wherein R is^21Z1、R^31Z1、R^41Z1And R ^51Z1At least one of which is-CO-R^102Z1、-COO-R^101Z1、-OCO-R^102Z1、-COCO-R^102Z1、-O-R^102Z1、-SO₂-R^101Z1、-SO₂N(R^102Z1)₂、-CON(R^102Z1)₂、-N(R^102Z1)₂、-NHCO-R^102Z1、-NHCO-N(R^102Z1)₂、-NHCOOR^102Z1、-OCON(R^102Z1)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent, or R is^21Z1And R^31Z1、R^31Z1And R^41Z1And R^41Z1And R^51Z1At least one group of them is bonded to form a ring. R^101Z1The alkyl group may have a substituent and has 1 to 40 carbon atoms, or a heterocyclic group may have a substituent. R^102Z1Represents a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group. M represents a hydrogen atom or an alkali metal atom. R^101Z1、R^102Z1And when there are a plurality of M, they may be the same or different. The wavy line indicates the E-body or the Z-body.]

With respect to R in the formula (IZ1-B)^O11Z1、R^21Z1、R^31Z1、R^41Z1、R^51Z1、R^61Z1And R^71Z1Respectively, R in the formula (IZ1)^O1Z1、R^2Z1、R^3Z1、R^4Z1、R^5Z1、R^6Z1And R^7Z1The same example.

With respect to the preferred R in the formula (IZ1-B)^O11Z1、R^21Z1、R^31Z1、R^41Z1、R^51Z1、R^61Z1And R^71Z1Respectively, R in the formula (IZ1)^O1Z1、R^2Z1、R^3Z1、R^4Z1、R^5Z1、R^6Z1And R^7Z1Is superior toThe same example was chosen.

In the formula (IZI-B), (mode 1) R^1Z1、R^61Z1And R^71Z1Is preferably a hydrogen atom. In addition, (mode 2) R^O11Z1It is also preferable that the hydrocarbon group is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent. Further, (mode 3) R^21Z1、R^31Z1、R^41Z1And R^51Z1It is also preferred that at least one of them is nitro or tert-butyl. The above-mentioned modes 1 to 3 can be adopted individually, or they can be combined appropriately.

Specific examples of the compound IZ1 include compounds IZ1-1 to IZ1-529 and alkali metal salts thereof having a substituent shown in table 1Z1, table 2Z1, table 3Z1, table 4Z1, table 5Z1, table 6Z1, table 7Z1, table 10Z1, table 11Z1, table 12Z1 and table 13Z1 in formula (IZ 1-aa).

B^a1Z1B^a2Z1The partial structure represented by any one of formulae (BB1) to (BB60), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1), formula (BBO8), formula (BBO10), formula (BBD1) and formula (BBJ2) is shown. As B^a1Z1B^a2Z1Formula (BB1), formula (BB6), formula (BB8), formula (BB11), formula (BB14), formula (BB19), formula (BB37), formula (BB58), formula (BBJ2), formula (BBO8), and formula (BBO10) are preferable, and formula (BB1), formula (BB6), and formula (BB19) are more preferable.

Each symbol in table 1Z1, table 2Z1, table 3Z1, table 4Z1, table 5Z1, table 6Z1, table 7Z1, table 10Z1, table 11Z1, table 12Z1, and table 13Z1 represents the following partial structure. In the partial structure, "Me" represents a methyl group, "Et" represents an ethyl group, "Bu" represents a butyl group,

"TBu" means t-butyl, "Hex" means hexyl, "Oct" means octyl,

"2 EH" represents 2-ethylhexyl, "CHM" represents cyclohexylmethyl, "CH" represents cyclohexyl, "PH" represents phenyl, "BZ" represents benzyl, "NPR" represents propyl,

"IPR" represents isopropyl, "IBu" represents isobutyl, and "EOE" represents-CH₂CH₂OCH₂CH₃"ALL" represents allyl, "HYE" represents 2-hydroxyethyl, and "COM" represents-CO-CH₃And "COE" represents-COO-CH₂CH₃And "OCM" represents-OCO-CH₃And "OME" represents-O-CH₃"SOT" represents a tosyl group, and "SNH" represents-SO₂NH-CH₂CH(CH₂CH₃)((CH₂)₃CH₃) "SN 2" represents-SO₂N(CH₃)((CH₂)₇CH₃) "CNM" represents-CONHCH₃And "CN 2" represents-CON (CH)₃)C₆H₅And "NPH" represents-NHC₆H₅，

"NOT" means-N ((CH)₂)₇CH₃)₂And "NCO" represents-NHCO ((CH)₂)₄CH₃) "F" represents a fluorine atom, "Cl" represents a chlorine atom, "Br" represents a bromine atom, "CN" represents a cyano group, "NO 2" represents a nitro group, and "SUA" represents-SO₃H, "CBA" means-CO₂H, "CHO" means-CHO, "OCH" means-OCOH, "OH" means-OH, "SFM" means-SO₂NH₂"CBM" represents-CONH₂"NH 2" means-NH₂"NCH" represents-nhcooh, and represents a chemical bond.

B^a1Z1And B^a2Z1Each represents a chemical bond, B^a1Z1Is as follows B¹When a chemical bond of (A) is present, B^a2Z1B is as follows²The chemical bond of (a); b is^a1Z1Is as follows B²When a chemical bond of (A) is present, B^a2Z1B is as follows¹The chemical bond of (1).

[ Table 1Z1]

TABLE 1Z1

	RO1Z1	Ba1Z1Ba2Z1	R1Z1	R6Z1	R7Z1
						IZ1-1	H	BB1	H	H	H
IZ1-2	Me	BB1	H	H	H
						IZ1-3	Et	BB1	H	H	H
IZ1-4	Bu	BB1	H	H	H
						IZ1-5	TBu	BB1	H	H	H
IZ1-6	Hex	BB1	H	H	H
						IZ1-7	Oct	BB1	H	H	H
IZ1-8	2EH	BB1	H	H	H
						IZ1-9	CHM	BB1	H	H	H
IZ1-10	CH	BB1	H	H	H
						IZ1-11	PH	BB1	H	H	H
IZ1-12	BZ	BB1	H	H	H
						IZ1-13	NPR	BB1	H	H	H
IZ1-14	IPR	BB1	H	H	H
						IZ1-15	IBu	BB1	H	H	H
IZ1-16	EOE	BB1	H	H	H
						IZ1-17	ALL	BB1	H	H	H
IZ1-18	HYE	BB1	H	H	H
						IZ1-19	H	BB6	H	H	H
IZ1-20	Me	BB6	H	H	H
						IZ1-21	Et	BB6	H	H	H
IZ1-22	Bu	BB6	H	H	H
						IZ1-23	TBu	BB6	H	H	H
IZ1-24	Hex	BB6	H	H	H
						IZ1-25	Oct	BB6	H	H	H
IZ1-26	2EH	BB6	H	H	H
						IZ1-27	CHM	BB6	H	H	H
IZ1-28	CH	BB6	H	H	H
						IZ1-29	PH	BB6	H	H	H
IZ1-30	BZ	BB6	H	H	H
						IZ1-31	NPR	BB6	H	H	H
IZ1-32	IPR	BB6	H	H	H
						IZ1-33	IBu	BB6	H	H	H
IZ1-34	EOE	BB6	H	H	H
						IZ1-35	ALL	BB6	H	H	H
IZ1-36	HYE	BB6	H	H	H
						IZ1-37	H	BB19	H	H	H
IZ1-38	Me	BB19	H	H	H
						IZ1-39	Et	BB19	H	H	H
IZ1-40	Bu	BB19	H	H	H

[ Table 2Z1]

TABLE 2Z1

	RO1Z1	Ba1Z1Ba2Z1	R1Z1	R6Z1	R7Z1
						IZ1-41	TBu	BB19	H	H	H
IZ1-42	Hex	BB19	H	H	H
						IZ1-43	Oct	BB19	H	H	H
IZ1-44	2EH	BB19	H	H	H
						IZ1-45	CHM	BB19	H	H	H
IZ1-46	CH	BB19	H	H	H
						IZ1-47	PH	BB19	H	H	H
IZ1-48	BZ	BB19	H	H	H
						IZ1-49	NPR	BB19	H	H	H
IZ1-50	IPR	BB19	H	H	H
						IZ1-51	IBu	BB19	H	H	H
IZ1-52	EOE	BB19	H	H	H
						IZ1-53	ALL	BB19	H	H	H
IZ1-54	HYE	BB19	H	H	H
						IZ1-55	H	BB2	H	H	H
IZ1-56	Me	BB3	H	H	H
						IZ1-57	Et	BB4	H	H	H
IZ1-58	Bu	BB5	H	H	H
						IZ1-59	TBu	BB7	H	H	H
IZ1-60	Hex	BB8	H	H	H
						IZ1-61	Oct	BB9	H	H	H
IZ1-62	2EH	BB10	H	H	H
						IZ1-63	CHM	BB11	H	H	H
IZ1-64	CH	BB12	H	H	H
						IZ1-65	PH	BB13	H	H	H
IZ1-66	BZ	BB14	H	H	H
						IZ1-67	NPR	BB15	H	H	H
IZ1-68	IPR	BB16	H	H	H
						IZ1-69	IBu	BB17	H	H	H
IZ1-70	EOE	BB18	H	H	H
						IZ1-71	ALL	BB20	H	H	H
IZ1-72	HYE	BB21	H	H	H
						IZ1-73	H	BB22	H	H	H
IZ1-74	Me	BB23	H	H	H
						IZ1-75	Et	BB24	H	H	H
IZ1-76	Bu	BB25	H	H	H
						IZ1-77	TBu	BB26	H	H	H
IZ1-78	Hex	BB27	H	H	H
						IZ1-79	Oct	BB28	H	H	H
IZ1-80	2EH	BB29	H	H	H

[ Table 3Z1]

TABLE 3Z1

	RO1Z1	Ba1Z1Ba2Z1	R1Z1	R6Z1	R7Z1
						IZ1-81	CHM	BB30	H	H	H
IZ1-82	CH	BB31	H	H	H
						IZ1-83	PH	BB32	H	H	H
IZ1-84	BZ	BB33	H	H	H
						IZ1-85	NPR	BB34	H	H	H
IZ1-86	IPR	BB35	H	H	H
						IZ1-87	IBu	BB36	H	H	H
IZ1-88	EOE	BB37	H	H	H
						IZ1-89	ALL	BB38	H	H	H
IZ1-90	HYE	BB39	H	H	H
						IZ1-91	H	BB40	H	H	H
IZ1-92	Me	BB41	H	H	H
						IZ1-93	Et	BB42	H	H	H
IZ1-94	Bu	BB43	H	H	H
						IZ1-95	TBu	BB44	H	H	H
IZ1-96	Hex	BB45	H	H	H
						IZ1-97	Oct	BB46	H	H	H
IZ1-98	2EH	BB47	H	H	H
						IZ1-99	CHM	BB48	H	H	H
IZ1-100	CH	BB49	H	H	H
						IZ1-101	PH	BB50	H	H	H
IZ1-102	BZ	BB51	H	H	H
						IZ1-103	NPR	BB52	H	H	H
IZ1-104	IPR	BB53	H	H	H
						IZ1-105	IBu	BB54	H	H	H
IZ1-106	EOE	BB55	H	H	H
						IZ1-107	ALL	BB56	H	H	H
IZ1-108	HYE	BB57	H	H	H
						IZ1-109	H	BB58	H	H	H
IZ1-110	Me	BB59	H	H	H
						IZ1-111	Et	BB60	H	H	H
IZ1-112	Et	BB1	H	Me	Me
						IZ1-113	Bu	BB2	H	CH	CH
IZ1-114	TBu	BB3	H	BZ	H
						IZ1-115	Hex	BB4	Me	Me	Me
IZ1-116	H	BB5	Et	CH	CH
						IZ1-117	Me	BB6	H	Et	Et
IZ1-118	Et	BB7	H	Bu	Bu
						IZ1-119	Bu	BB8	H	TBu	TBu
IZ1-120	TBu	BB9	H	Hex	Hex

[ Table 4Z1]

TABLE 4Z1

	RO1Z1	Ba1Z1Ba2Z1	R1Z1	R6Z1	R7Z1
						IZ1-121	Hex	BB10	H	Oct	Oct
IZ1-122	Oct	BB11	H	2EH	2EH
						IZ1-123	2EH	BB12	H	CHM	CHM
IZ1-124	CHM	BB13	H	PH	PH
						IZ1-125	CH	BB14	H	BZ	BZ
IZ1-126	PH	BB15	H	NPR	NPR
						IZ1-127	BZ	BB16	H	IPR	IPR
IZ1-128	NPR	BB17	H	IBu	IBu
						IZ1-129	IPR	BB18	H	EOE	EOE
IZ1-130	IBu	BB19	H	ALL	ALL
						IZ1-131	EOE	BB20	H	NH2	NH2
IZ1-132	ALL	BB21	H	CBM	CBM
						IZ1-133	HYE	BB22	H	COM	COM
IZ1-134	H	BB23	H	COE	COE
						IZ1-135	Me	BB24	H	CBA	CBA
IZ1-136	Et	BB25	H	HYE	HYE
						IZ1-137	Bu	BB26	H	Me	Me
IZ1-138	TBu	BB27	H	CH	CH
						IZ1-139	Hex	BB28	H	BZ	H
IZ1-140	Oct	BB29	Me	Me	Me
						IZ1-141	2EH	BB30	Et	CH	CH
IZ1-142	CHM	BB31	H	Et	Et
						IZ1-143	CH	BB32	H	Bu	Bu
IZ1-144	PH	BB33	H	TBu	TBu
						IZ1-145	BZ	BB34	H	Hex	Hex
IZ1-146	NPR	BB35	H	Oct	Oct
						IZ1-147	IPR	BB36	H	2EH	2EH
IZ1-148	IBu	BB37	H	CHM	CHM
						IZ1-149	EOE	BB38	H	PH	PH
IZ1-150	ALL	BB39	H	BZ	BZ
						IZ1-151	HYE	BB40	H	NPR	NPR
IZ1-152	H	BB41	H	IPR	IPR
						IZ1-153	Me	BB42	H	IBu	IBu
IZ1-154	Et	BB43	H	EOE	EOE
						IZ1-155	Bu	BB44	H	ALL	ALL
IZ1-156	TBu	BB45	H	NH2	NH2
						IZ1-157	Hex	BB46	H	CBM	CBM
IZ1-158	Oct	BB47	H	COM	COM
						IZ1-159	2EH	BB48	H	COE	COE
IZ1-160	CHM	BB49	H	CBA	CBA

[ Table 5Z1]

TABLE 5Z1

	RO1Z1	Ba1Z1Ba2Z1	R1Z1	R6Z1	R7Z1
						IZ1-161	CH	BB50	H	HYE	HYE
IZ1-162	PH	BB51	H	Me	Me
						IZ1-163	BZ	BB52	H	CH	CH
IZ1-164	NPR	BB53	H	BZ	H
						IZ1-165	IPR	BB54	Me	Me	Me
IZ1-166	IBu	BB55	Et	CH	CH
						IZ1-167	EOE	BB56	H	Et	Et
IZ1-168	ALL	BB57	H	Bu	Bu
						IZ1-169	HYE	BB58	H	TBu	TBu
IZ1-170	H	BB59	H	Hex	Hex
						IZ1-171	Me	BB60	H	Oct	Oct
IZ1-172	CHM	BB1	Me	H	H
						IZ1-173	CH	BB2	COM	H	H
IZ1-174	PH	BB3	COE	H	H
						IZ1-175	BZ	BB4	Et	H	H
IZ1-176	NPR	BB5	OCM	H	H
						IZ1-177	IPR	BB6	OME	H	H
IZ1-178	IBu	BB7	Bu	H	H
						IZ1-179	EOE	BB8	SOT	H	H
IZ1-180	ALL	BB9	SNH	H	H
						IZ1-181	HYE	BB10	TBu	H	H
IZ1-182	H	BB11	SN2	H	H
						IZ1-183	Me	BB12	CNM	H	H
IZ1-184	Et	BB13	Hex	H	H
						IZ1-185	Bu	BB14	CN2	H	H
IZ1-186	TBu	BB15	NPH	H	H
						IZ1-187	Hex	BB16	Oct	H	H
IZ1-188	Oct	BB17	NOT	H	H
						IZ1-189	2EH	BB18	NCO	H	H
IZ1-190	CHM	BB19	2EH	H	H
						IZ1-191	CH	BB20	F	H	H
IZ1-192	PH	BB21	Cl	H	H
						IZ1-193	BZ	BB22	CHM	H	H
IZ1-194	NPR	BB23	Br	H	H
						IZ1-195	IPR	BB24	CN	H	H
IZ1-196	IBu	BB25	CH	H	H
						IZ1-197	EOE	BB26	NO2	H	H
IZ1-198	ALL	BB27	SUA	H	H
						IZ1-199	HYE	BB28	PH	H	H
IZ1-200	H	BB29	CBA	H	H

[ Table 6Z1]

TABLE 6Z1

	RO1Z1	Ba1Z1Ba2Z1	R1Z1	R6Z1	R7Z1
						IZ1-201	Me	BB30	CHO	H	H
IZ1-202	Et	BB31	BZ	H	H
						IZ1-203	Bu	BB32	OCH	H	H
IZ1-204	TBu	BB33	NPR	H	H
						IZ1-205	Hex	BB34	OH	H	H
IZ1-206	Oct	BB35	IPR	H	H
						IZ1-207	2EH	BB36	SFM	H	H
IZ1-208	CHM	BB37	IBu	H	H
						IZ1-209	CH	BB38	CBM	H	H
IZ1-210	PH	BB39	EOE	H	H
						IZ1-211	BZ	BB40	NH2	H	H
IZ1-212	NPR	BB41	ALL	H	H
						IZ1-213	IPR	BB42	NCH	H	H
IZ1-214	IBu	BB43	HYE	H	H
						IZ1-215	EOE	BB44	H	Me	H
IZ1-216	ALL	BB45	H	H	COM
						IZ1-217	HYE	BB46	H	COE	H
IZ1-218	H	BB47	H	H	Et
						IZ1-219	Me	BB48	H	OCM	H
IZ1-220	Et	BB49	H	H	OME
						IZ1-221	Bu	BB50	H	Bu	H
IZ1-222	TBu	BB51	H	H	SOT
						IZ1-223	Hex	BB52	H	SNH	H
IZ1-224	Oct	BB53	H	H	TBu
						IZ1-225	2EH	BB54	H	SN2	H
IZ1-226	CHM	BB55	H	H	CNM
						IZ1-227	CH	BB56	H	Hex	H
IZ1-228	PH	BB57	H	H	CN2
						IZ1-229	BZ	BB58	H	NPH	H
IZ1-230	NPR	BB59	H	H	Oct
						IZ1-231	IPR	BB60	H	NOT	H
IZ1-232	IBu	BB1	H	H	NCO
						IZ1-233	EOE	BB2	H	2EH	H
IZ1-234	ALL	BB3	H	H	F
						IZ1-235	HYE	BB4	H	Cl	H
IZ1-236	H	BB5	H	H	CHM
						IZ1-237	Me	BB6	H	Br	H
IZ1-238	Et	BB7	H	H	CN
						IZ1-239	Bu	BB8	H	CH	H
IZ1-240	TBu	BB9	H	H	NO2

[ Table 7Z1]

TABLE 7Z1

	RO1Z1	Ba1Z1Ba2Z1	R1Z1	R6Z1	R7Z1
						IZ1-241	Hex	BB10	H	SUA	H
IZ1-242	Oct	BB11	H	H	PH
						IZ1-243	2EH	BB12	H	CBA	H
IZ1-244	CHM	BB13	H	H	CHO
						IZ1-245	CH	BB14	H	BZ	BZ
IZ1-246	PH	BB15	H	H	OCH
						IZ1-247	BZ	BB16	H	NPR	H
IZ1-248	NPR	BB17	H	H	OH
						IZ1-249	IPR	BB18	H	IPR	H
IZ1-250	IBu	BB19	H	H	SFM
						IZ1-251	EOE	BB20	H	IBu	H
IZ1-252	ALL	BB21	H	H	CBM
						IZ1-253	HYE	BB22	H	EOE	H
IZ1-254	H	BB23	H	H	NH2
						IZ1-255	Me	BB24	H	ALL	H
IZ1-256	Et	BB25	H	H	NCH
						IZ1-257	Bu	BB26	H	HYE	H
IZ1-258	Me	BB8	H	H	H

[ Table 10Z1]

TABLE 10Z1

RO1Z1

Ba1Z1Ba2Z1

R1Z1

R6Z1

R7Z1

RO1Z1

Ba1Z1Ba2Z1

R1Z1

R6Z1

R7Z1

IZ1-259

NA1

BB1

H

H

H

IZ1-299

H

BB11

H

H

H

IZ1-260

HHk8

BB1

H

H

H

IZ1-300

Me

BB11

H

H

H

IZ1-261

NA2

BB1

H

H

H

IZ1-301

Et

BB11

H

H

H

IZ1-262

HHk7

BB1

H

H

H

IZ1-302

Bu

BB11

H

H

H

IZ1-263

HH37

BB1

H

H

H

IZ1-303

TBu

BB11

H

H

H

IZ1-264

HHk6

BB1

H

H

H

IZ1-304

Hex

BB11

H

H

H

IZ1-265

NA3

BB1

H

H

H

IZ1-305

Oct

BB11

H

H

H

IZ1-266

HHJ2

BB1

H

H

H

IZ1-306

2EH

BB11

H

H

H

IZ1-267

HHk11

BB1

H

H

H

IZ1-307

CH

BB11

H

H

H

IZ1-268

NA1

BB6

H

H

H

IZ1-308

PH

BB11

H

H

H

IZ1-269

HHk8

BB6

H

H

H

IZ1-309

BZ

BB11

H

H

H

IZ1-270

NA2

BB6

H

H

H

IZ1-310

EOE

BB11

H

H

H

IZ1-271

HHk7

BB6

H

H

H

IZ1-311

ALL

BB11

H

H

H

IZ1-272

HH37

BB6

H

H

H

IZ1-312

HYE

BB11

H

H

H

IZ1-273

HHk6

BB6

H

H

H

IZ1-313

NA1

BB11

H

H

H

IZ1-274

NA3

BB6

H

H

H

IZ1-314

HHk8

BB11

H

H

H

IZ1-275

HHJ2

BB6

H

H

H

IZ1-315

NA2

BB11

H

H

H

IZ1-276

HHk11

BB6

H

H

H

IZ1-316

HHk7

BB11

H

H

H

IZ1-277

H

BB8

H

H

H

IZ1-317

HH37

BB11

H

H

H

IZ1-278

Et

BB8

H

H

H

IZ1-318

HHk6

BB11

H

H

H

IZ1-279

Bu

BB8

H

H

H

IZ1-319

NA3

BB11

H

H

H

IZ1-280

TBu

BB8

H

H

H

IZ1-320

HHJ2

BB11

H

H

H

IZ1-281

Oct

BB8

H

H

H

IZ1-321

HHk11

BB11

H

H

H

IZ1-282

2EH

BB8

H

H

H

IZ1-322

H

BB14

H

H

H

IZ1-283

CHM

BB8

H

H

H

IZ1-323

Me

BB14

H

H

H

IZ1-284

CH

BB8

H

H

H

IZ1-324

Et

BB14

H

H

H

IZ1-285

PH

BB8

H

H

H

IZ1-325

Bu

BB14

H

H

H

IZ1-286

BZ

BB8

H

H

H

IZ1-326

TBu

BB14

H

H

H

IZ1-287

EOE

BB8

H

H

H

IZ1-327

Hex

BB14

H

H

H

IZ1-288

ALL

BB8

H

H

H

IZ1-328

Oct

BB14

H

H

H

IZ1-289

HYE

BB8

H

H

H

IZ1-329

2EH

BB14

H

H

H

IZ1-290

NA1

BB8

H

H

H

IZ1-330

CHM

BB14

H

H

H

IZ1-291

HHk8

BB8

H

H

H

IZ1-331

CH

BB14

H

H

H

IZ1-292

NA2

BB8

H

H

H

IZ1-332

PH

BB14

H

H

H

IZ1-293

HHk7

BB8

H

H

H

IZ1-333

EOE

BB14

H

H

H

IZ1-294

HH37

BB8

H

H

H

IZ1-334

ALL

BB14

H

H

H

IZ1-295

HHk6

BB8

H

H

H

IZ1-335

HYE

BB14

H

H

H

IZ1-296

NA3

BB8

H

H

H

IZ1-336

NA1

BB14

H

H

H

IZ1-297

HHJ2

BB8

H

H

H

IZ1-337

HHk8

BB14

H

H

H

IZ1-298

HHk11

BB8

H

H

H

IZ1-338

NA2

BB14

H

H

H

[ Table 11Z1]

TABLE 11Z1

RO1Z1

Ba1Z1Ba2Z1

R1Z1

R6Z1

R7Z1

RO1Z1

Ba1Z1Ba2Z1

R1Z1

R6Z1

R7Z1

IZ1-339

HHk7

BB14

H

H

H

IZ1-379

Bu

BB58

H

H

H

IZ1-340

HH37

BB14

H

H

H

IZ1-380

TBu

BB58

H

H

H

IZ1-341

HHk6

BB14

H

H

H

IZ1-381

Hex

BB58

H

H

H

IZ1-342

NA3

BB14

H

H

H

IZ1-382

Oct

BB58

H

H

H

IZ1-343

HHJ2

BB14

H

H

H

IZ1-383

2EH

BB58

H

H

H

IZ1-344

HHk11

BB14

H

H

H

IZ1-384

CHM

BB58

H

H

H

IZ1-345

NA1

BB19

H

H

H

IZ1-385

CH

BB58

H

H

H

IZ1-346

HHk8

BB19

H

H

H

IZ1-386

PH

BB58

H

H

H

IZ1-347

NA2

BB19

H

H

H

IZ1-387

BZ

BB58

H

H

H

IZ1-348

HHk7

BB19

H

H

H

IZ1-388

EOE

BB58

H

H

H

IZ1-349

HH37

BB19

H

H

H

IZ1-389

ALL

BB58

H

H

H

IZ1-350

HHk6

BB19

H

H

H

IZ1-390

HYE

BB58

H

H

H

IZ1-351

NA3

BB19

H

H

H

IZ1-391

NA1

BB58

H

H

H

IZ1-352

HHJ2

BB19

H

H

H

IZ1-392

HHk8

BB58

H

H

H

IZ1-353

HHk11

BB19

H

H

H

IZ1-393

NA2

BB58

H

H

H

IZ1-354

H

BB37

H

H

H

IZ1-394

HHk7

BB58

H

H

H

IZ1-355

Me

BB37

H

H

H

IZ1-395

HH37

BB58

H

H

H

IZ1-356

Et

BB37

H

H

H

IZ1-396

HHk6

BB58

H

H

H

IZ1-357

Bu

BB37

H

H

H

IZ1-397

NA3

BB58

H

H

H

IZ1-358

TBu

BB37

H

H

H

IZ1-398

HHJ2

BB58

H

H

H

IZ1-359

Hex

BB37

H

H

H

IZ1-399

HHk11

BB58

H

H

H

IZ1-360

Oct

BB37

H

H

H

IZ1-400

H

BBJ2

H

H

H

IZ1-361

2EH

BB37

H

H

H

IZ1-401

Me

BBJ2

H

H

H

IZ1-362

CHM

BB37

H

H

H

IZ1-402

Et

BBJ2

H

H

H

IZ1-363

CH

BB37

H

H

H

IZ1-403

Bu

BBJ2

H

H

H

IZ1-364

PH

BB37

H

H

H

IZ1-404

TBu

BBJ2

H

H

H

IZ1-365

BZ

BB37

H

H

H

IZ1-405

Hex

BBJ2

H

H

H

IZ1-366

ALL

BB37

H

H

H

IZ1-406

Oct

BBJ2

H

H

H

IZ1-367

HYE

BB37

H

H

H

IZ1-407

2EH

BBJ2

H

H

H

IZ1-368

NA1

BB37

H

H

H

IZ1-408

CHM

BBJ2

H

H

H

IZ1-369

HHk8

BB37

H

H

H

IZ1-409

CH

BBJ2

H

H

H

IZ1-370

NA2

BB37

H

H

H

IZ1-410

PH

BBJ2

H

H

H

IZ1-371

HHk7

BB37

H

H

H

IZ1-411

BZ

BBJ2

H

H

H

IZ1-372

HH37

BB37

H

H

H

IZ1-412

EOE

BBJ2

H

H

H

IZ1-373

HHk6

BB37

H

H

H

IZ1-413

ALL

BBJ2

H

H

H

IZ1-374

NA3

BB37

H

H

H

IZ1-414

HYE

BBJ2

H

H

H

IZ1-375

HHJ2

BB37

H

H

H

IZ1-415

NA1

BBJ2

H

H

H

IZ1-376

HHk11

BB37

H

H

H

IZ1-416

HHk8

BBJ2

H

H

H

IZ1-377

Me

BB58

H

H

H

IZ1-417

NA2

BBJ2

H

H

H

IZ1-378

Et

BB58

H

H

H

IZ1-418

HHk7

BBJ2

H

H

H

[ Table 12Z1]

TABLE 12Z1

RO1Z1

Ba1Z1Ba2Z1

R1Z1

R6Z1

R7Z1

RO1Z1

Ba1Z1Ba2Z1

R1Z1

R6Z1

R7Z1

IZ1-419

HH37

BBJ2

H

H

H

IZ1-459

BZ

BBO10

H

H

H

IZ1-420

HHk6

BBJ2

H

H

H

IZ1-460

EOE

BBO10

H

H

H

IZ1-421

NA3

BBJ2

H

H

H

IZ1-461

ALL

BBO10

H

H

H

IZ1-422

HHJ2

BBJ2

H

H

H

IZ1-462

HYE

BBO10

H

H

H

IZ1-423

HHk11

BBJ2

H

H

H

IZ1-463

NA1

BBO10

H

H

H

IZ1-424

H

BBO8

H

H

H

IZ1-464

HHk8

BBO10

H

H

H

IZ1-425

Me

BBO8

H

H

H

IZ1-465

NA2

BBO10

H

H

H

IZ1-426

Et

BBO8

H

H

H

IZ1-466

HHk7

BBO10

H

H

H

IZ1-427

Bu

BBO8

H

H

H

IZ1-467

HH37

BBO10

H

H

H

IZ1-428

TBu

BBO8

H

H

H

IZ1-468

HHk6

BBO10

H

H

H

IZ1-429

Hex

BBO8

H

H

H

IZ1-469

NA3

BBO10

H

H

H

IZ1-430

Oct

BBO8

H

H

H

IZ1-470

HHJ2

BBO10

H

H

H

IZ1-431

2EH

BBO8

H

H

H

IZ1-471

HHk11

BBO10

H

H

H

IZ1-432

CHM

BBO8

H

H

H

IZ1-472

HH9

BB2

H

H

H

IZ1-433

CH

BBO8

H

H

H

IZ1-473

HHk7

BB3

H

H

H

IZ1-434

PH

BBO8

H

H

H

IZ1-474

HHk8

BB4

H

H

H

IZ1-435

BZ

BBO8

H

H

H

IZ1-475

HHe4

BB5

H

H

H

IZ1-436

EOE

BBO8

H

H

H

IZ1-476

HHa2

BB7

H

H

H

IZ1-437

ALL

BBO8

H

H

H

IZ1-477

HHj10

BB9

H

H

H

IZ1-438

HYE

BBO8

H

H

H

IZ1-478

HH46

BB10

H

H

H

IZ1-439

NA1

BBO8

H

H

H

IZ1-479

HHh8

BB12

H

H

H

IZ1-440

HHk8

BBO8

H

H

H

IZ1-480

HHf5

BB13

H

H

H

IZ1-441

NA2

BBO8

H

H

H

IZ1-481

HH81

BB15

H

H

H

IZ1-442

HHk7

BBO8

H

H

H

IZ1-482

HHJ2

BB16

H

H

H

IZ1-443

HH37

BBO8

H

H

H

IZ1-483

HHk5

BB17

H

H

H

IZ1-444

HHk6

BBO8

H

H

H

IZ1-484

HH76

BB18

H

H

H

IZ1-445

NA3

BBO8

H

H

H

IZ1-485

HHJ10

BB20

H

H

H

IZ1-446

HHJ2

BBO8

H

H

H

IZ1-486

HH13

BB21

H

H

H

IZ1-447

HHk11

BBO8

H

H

H

IZ1-487

HHJ3

BB22

H

H

H

IZ1-448

H

BBO10

H

H

H

IZ1-488

HHj19

BB23

H

H

H

IZ1-449

Me

BBO10

H

H

H

IZ1-489

NA1

BB24

H

H

H

IZ1-450

Et

BBO10

H

H

H

IZ1-490

HH36

BB25

H

H

H

IZ1-451

Bu

BBO10

H

H

H

IZ1-491

HH49

BB26

H

H

H

IZ1-452

TBu

BBO10

H

H

H

IZ1-492

HH40

BB27

H

H

H

IZ1-453

Hex

BBO10

H

H

H

IZ1-493

NA5

BB28

H

H

H

IZ1-454

Oct

BBO10

H

H

H

IZ1-494

HH37

BB29

H

H

H

IZ1-455

2EH

BBO10

H

H

H

IZ1-495

HH65

BB30

H

H

H

IZ1-456

CHM

BBO10

H

H

H

IZ1-496

HHj17

BB31

H

H

H

IZ1-457

CH

BBO10

H

H

H

IZ1-497

HH35

BB32

H

H

H

IZ1-458

PH

BBO10

H

H

H

IZ1-498

HH43

BB33

H

H

H

[ Table 13Z1]

TABLE 13Z1

	RO1Z1	Ba1Z1Ba2Z1	R1Z1	R6Z1	R7Z1
						IZ1-499	HHg2	BB34	H	H	H
IZ1-500	HHJ4	BB35	H	H	H
						IZ1-501	NA4	BB36	H	H	H
IZ1-502	HHc1	BB38	H	H	H
						IZ1-503	HHk4	BB39	H	H	H
IZ1-504	HHk1	BB40	H	H	H
						IZ1-505	HHk3	BB41	H	H	H
IZ1-506	HHf14	BB42	H	H	H
						IZ1-507	HH34	BB43	H	H	H
IZ1-508	HHi11	BB44	H	H	H
						IZ1-509	HHh1	BB45	H	H	H
IZ1-510	HH83	BB46	H	H	H
						IZ1-511	HH78	BB47	H	H	H
IZ1-512	NA2	BB48	H	H	H
						IZ1-513	HHd6	BB49	H	H	H
IZ1-514	HH61	BB50	H	H	H
						IZ1-515	HH80	BB51	H	H	H
IZ1-516	HH28	BB52	H	H	H
						IZ1-517	NA3	BB53	H	H	H
IZ1-518	HHf11	BB54	H	H	H
						IZ1-519	HH55	BB55	H	H	H
IZ1-520	HH69	BB56	H	H	H
						IZ1-521	HHk11	BB57	H	H	H
IZ1-522	HHh4	BB59	H	H	H
						IZ1-523	HHk6	BB60	H	H	H
IZ1-524	HHb3	BBI1	H	H	H
						IZ1-525	HH58	BBD1	H	H	H
IZ1-526	HHf1	BBK2	H	H	H
						IZ1-527	HH22	BBK3	H	H	H
IZ1-528	HHg1	BBK4	H	H	H
						IZ1-529	HHg5	BBK14	H	H	H

For example, the compound IZ1-1 is a compound represented by the formula (IZ 1-1).

As a compound of formula (I) Z1,

preferably a compound IZ1-1 to a compound IZ1-171, a compound IZ1-258 to a compound IZ1-529, more preferably a compound IZ1-1 to a compound IZ1-171, a compound IZ1-258 to a compound IZ1-471,

the compound IZ1-1 to the compound IZ1-171 are more preferable, the compound IZ1-1 to the compound IZ1-111 are still more preferable, the compound IZ1-1 to the compound IZ1-54 are particularly preferable, and the compound IZ1-2 to the compound IZ1-3, the compound IZ1-20 to the compound IZ1-21 and the compound IZ1-38 to the compound IZ1-39 are particularly preferable.

Specific examples of the compound IZ1 include compounds represented by table 1Z1, table 2Z1, table 3Z1, table 4Z1, table 5Z1, table 6Z1, table 7Z1, table 10Z1, table 11Z1, table 12Z1, and table 13Z1 in which 1 to 3 hydrogen atoms contained in the compound are replaced by — SO₃M or-CO₂M is substituted. For example, compounds having 1 to 3 sulfo groups bonded to the compound IZ1-1 of Table 1Z1 are represented by the following structures. Wherein, in the formula, - (SO)₃H) Represents a compound in which any hydrogen atom in compound IZ1-1 of Table 1Z1 is substituted.

In the present invention, it is preferable that 1 to 3-SO groups are bonded to the compound IZ1-1 to the compound IZ1-171, the compound IZ1-258 to the compound IZ1-529₃M or-CO₂More preferably, the compound of M is a compound in which 1 to 3-SO groups are bonded to the compound IZ1-1 to the compound IZ1-171, the compound IZ1-258 to the compound IZ1-431₃M or-CO₂A compound formed by the reaction of M,

more preferably, 1 to 3-SO groups are bonded to the compound IZ1-1 to the compound IZ1-171₃M or-CO₂A compound formed by the reaction of M,

more preferably, 1 to 3-SO groups are bonded to the compound IZ1-1 to the compound IZ1-111₃M or-CO₂A compound formed by the reaction of M,

particularly preferably, 1 to 3-SO groups are bonded to the compound IZ1-1 to the compound IZ1-54₃M or-CO₂A compound formed by the reaction of M,

particularly preferably, 1 to 3-SO groups are bonded to the compound IZ1-2 to the compound IZ1-3, the compound IZ1-20 to the compound IZ1-21, and the compound IZ1-38 to the compound IZ1-39₃M or-CO₂M, or a salt thereof.

As the compound (IZ1), the following compounds are preferable: in the formula (IZ1), R^O1Z1Is a hydrogen atom, or may have a radical selected from the group consisting of-SO₃M and-CO₂A C1-20 hydrocarbon group as a substituent in the group consisting of M, R^1Z1Is a hydrogen atom and may have a radical selected from the group consisting of-SO₃M and-CO₂A C1-20 hydrocarbon group, -SO ₃M or-CO₂M，R^2Z1～R^5Z1Each independently represents a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogen atom, or-N (R)^102Z1)₂A C1-20 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R^102Z1、-O-R^102Z1、-SO₃M or-CO₂M，

R^6Z1And R^7Z1Independently of one another, a hydrogen atom, may have a structure selected from the group consisting of-SO₃M and-CO₂A C1-20 hydrocarbon group, -SO₃M or-CO₂M，

R^102Z1Is a hydrogen atom, or may have a radical selected from the group consisting of-SO₃M and-CO₂A hydrocarbyl group having 1 to 20 carbon atoms as a substituent in the group consisting of M,

a compound in which M is a hydrogen atom or an alkali metal atom;

more preferred are the following compounds:

R^O1Z1is a hydrogen atom, or may have a radical selected from the group consisting of-SO₃M and-CO₂A hydrocarbyl group having 1 to 10 carbon atoms as a substituent in the group consisting of M,

R^1Z1is a hydrogen atom, and is a hydrogen atom,

R^2Z1～R^5Z1each independently represents a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, or-N (R)^102Z1)₂A C1-10 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R^102Z1、-O-R^102Z1、-SO₃M or-CO₂M，

R^6Z1And R^7Z1Are the same radicals, are hydrogenAtoms, or may have radicals selected from-SO₃M and-CO₂A hydrocarbyl group having 1 to 10 carbon atoms as a substituent in the group consisting of M,

R^102Z1is a hydrogen atom, or may have a radical selected from the group consisting of-SO ₃M and-CO₂A hydrocarbyl group having 1 to 10 carbon atoms as a substituent in the group consisting of M,

a compound in which M is a hydrogen atom or an alkali metal atom;

further preferred are the following compounds:

R^O1Z1is a hydrogen atom, or may have a radical selected from the group consisting of-SO₃M and-CO₂A hydrocarbyl group having 1 to 10 carbon atoms as a substituent in the group consisting of M,

R^1Z1is a hydrogen atom, and is a hydrogen atom,

R^2Z1～R^5Z1each independently represents a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, or-N (R)^102Z1)₂Nitro, trifluoromethyl, -O-R^102Z1、-SO₃M or-CO₂M，

R^6Z1And R^7Z1The same group is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms,

R^102Z1is a hydrogen atom, or may have a radical selected from the group consisting of-SO₃M and-CO₂A hydrocarbyl group having 1 to 10 carbon atoms as a substituent in the group consisting of M,

m is a hydrogen atom or an alkali metal atom.

For compound IZ1, R^1Z1In the case of a hydrogen atom, the compound represented by the formula (pt1Z1) (hereinafter, may be referred to as phthalonitrile (phthalonitrile) compound) may be reacted with the compound represented by the formula (pt2Z1) (hereinafter, may be referred to as alkoxide (alkoxide) compound), and then, the compound represented by the formula (pt3Z1) and the compound represented by the formula (pt4Z1) may be further reacted in the presence of an acid. In addition, R^1Z1When not a hydrogen atom, the compound is further reacted with a compound represented by the formula (pt5Z1) to produce a compound IZ 1.

In [ formula (pt1Z1), formula (pt2Z1), formula (pt3Z1), formula (pt4Z1), formula (pt5Z1) and formula (IZ1), R^O1Z1、R^1Z1、R^2Z1、R^3Z1、R^4Z1、R^5Z1、R^6Z1And R^7Z1The same meanings as described above are indicated. R^14Z1Represents an alkyl group having 1 to 20 carbon atoms. M^1Z1Represents an alkali metal atom. LG represents a halogen atom, a mesyloxy group, a tosyloxy group or a trifluormesyloxy group.]

As R^14Z1Examples of the alkyl group having 1 to 20 carbon atoms include methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec-butyl, tert-butyl, and the like, and preferred examples thereof include alkyl groups having 1 to 6 carbon atoms.

As M^1Z1Examples of the alkali metal atom include a lithium atom, a sodium atom and a potassium atom.

The amount of the alkoxide compound used is usually 0.1 to 10 moles, preferably 0.2 to 5 moles, more preferably 0.3 to 3 moles, and still more preferably 0.4 to 2 moles, based on 1 mole of the phthalonitrile compound.

The amount of the compound pt3Z1 used is usually 1 to 10 moles, preferably 1 to 5 moles, more preferably 1 to 3 moles, and still more preferably 1 to 2 moles, based on 1 mole of the phthalonitrile compound.

The amount of the compound pt4Z1 used is usually 1 to 10 moles, preferably 1 to 5 moles, more preferably 1 to 3 moles, and still more preferably 1 to 2 moles, based on 1 mole of the phthalonitrile compound.

Examples of the acid include inorganic acids such as hydrochloric acid, hydrobromic acid, hydroiodic acid, sulfuric acid, nitric acid, fluorosulfonic acid, and phosphoric acid; sulfonic acids such as methanesulfonic acid, trifluoromethanesulfonic acid, and p-toluenesulfonic acid; examples of the carboxylic acid include acetic acid, citric acid, formic acid, gluconic acid, lactic acid, oxalic acid, tartaric acid, and the like, and preferably include hydrochloric acid, hydrobromic acid, sulfuric acid, methanesulfonic acid, trifluoromethanesulfonic acid, p-toluenesulfonic acid, and carboxylic acid, and more preferably include acetic acid.

The amount of the acid used is usually 1 to 20 moles, preferably 1 to 10 moles, more preferably 1 to 8 moles, and still more preferably 1 to 6 moles, based on 1 mole of the phthalonitrile compound.

The reaction of the phthalonitrile compound, the alkoxide compound, the compound pt3Z1, and the compound pt4Z1 can be usually carried out in the presence of a solvent.

As the solvent, water may be mentioned; nitrile solvents such as acetonitrile; alcohol solvents such as methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, and 1-octanol; ether solvents such as tetrahydrofuran; ketone solvents such as acetone; ester solvents such as ethyl acetate; aliphatic hydrocarbon solvents such as hexane; aromatic hydrocarbon solvents such as toluene; halogenated hydrocarbon solvents such as dichloromethane and chloroform; amide solvents such as N, N-dimethylformamide and N-methylpyrrolidone; sulfoxide solvents such as dimethyl sulfoxide, preferably include water, nitrile solvents, alcohol solvents, ether solvents, ketone solvents, ester solvents, aromatic hydrocarbon solvents, halogenated hydrocarbon solvents, amide solvents and sulfoxide solvents, more preferably include water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, tetrahydrofuran, acetone, ethyl acetate, toluene, dichloromethane, chloroform, N-dimethylformamide, N-methylpyrrolidone and dimethyl sulfoxide, still more preferably include water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, acetone, dichloromethane, chloroform, N-dimethylformamide, N-methylpyrrolidone and dimethyl sulfoxide, and particularly preferably include water, methanol, ethanol, methanol, ethanol, butanol, methanol, ethanol, 1-butanol, 1-pentanol, 1-octanol, acetone, dichloromethane, chloroform, N-methylpyrrolidone and dimethyl sulfoxide, Acetonitrile, methanol, ethanol and 2-propanol.

The amount of the solvent used is usually 1 to 1000 parts by mass per 1 part by mass of the phthalonitrile compound.

The reaction temperature is usually 0 to 200 ℃, preferably 0 to 100 ℃, more preferably 0 to 70 ℃, and further preferably 0 to 50 ℃. The reaction time is usually 0.5 to 300 hours.

With respect to the amount of compound pt5Z1 used, relative to R^1Z1The amount of the compound IZ11 which is a hydrogen atom is usually 1 to 10 moles, preferably 1 to 5 moles, more preferably 1 to 3 moles, and still more preferably 1 to 2 moles.

In addition, when the compound pt5Z1 is reacted, a base is preferably coexisted. Examples of the base include organic bases such as triethylamine, 4- (N, N-dimethylamino) pyridine, and piperidine; metal alkoxides such as sodium methoxide, sodium ethoxide, sodium tert-butoxide, and potassium tert-butoxide; organic metal compounds such as butyl lithium, tert-butyl lithium and phenyl lithium; inorganic bases such as lithium hydroxide, sodium hydroxide and potassium hydroxide.

As for the amount of the base used, with respect to R^1Z1The amount of the compound IZ11 which is a hydrogen atom is usually 1 to 10 moles, preferably 1 to 5 moles, more preferably 1 to 3 moles, and still more preferably 1 to 2 moles.

In addition, the reaction of the compound pt5Z1 can be generally carried out in the presence of a solvent. The solvent may be selected from the same ranges as described above.

As to the amount of the solvent used, with respect to R^1Z1The amount of the compound IZ 11 is usually 1 to 1000 parts by mass. The reaction temperature of the compound pt5Z1 is usually-90 to 200 ℃, preferably-80 to 100 ℃, and more preferably 0 to 50 ℃. The reaction time is usually 0.5 to 300 hours.

Compound IZ1 having no sulfo group or-SO₃M²²In the case of (3), the compound IZ1 can be reacted with a sulfonating agent such as fuming sulfuric acid or chlorosulfonic acid to introduce a sulfo group or-SO₃M²。

M²²Represents an alkali metal atom.

As M²²Examples of the alkali metal atom include a lithium atom, a sodium atom and a potassium atom.

With respect to SO in oleum₃The amount of (b) is usually 1 to 50 mol, preferably 5 to 40 mol, more preferably 5 to 30 mol, and still more preferably 5 to 25 mol based on 11 mol of the compound IZ.

The amount of sulfuric acid used in the oleum is usually 1 to 200 moles, preferably 10 to 100 moles, more preferably 10 to 75 moles, and still more preferably 10 to 50 moles, based on 11 moles of the compound IZ.

The amount of chlorosulfonic acid used is usually 1 to 500 moles, preferably 10 to 300 moles, more preferably 10 to 200 moles, and still more preferably 10 to 150 moles, based on 11 moles of the compound IZ.

The reaction temperature of sulfonation is usually-20 to 200 ℃, preferably-10 to 100 ℃, and more preferably 0 to 50 ℃. The reaction time is usually 0.5 to 300 hours.

The method for extracting the compound IZ1 from the reaction mixture is not particularly limited, and it can be extracted by various known methods. For example, after the reaction is completed, the reaction mixture is filtered to extract the compound IZ 1. Further, the residue obtained after filtration may be subjected to column chromatography, recrystallization, or the like. After the completion of the reaction, the solvent of the reaction mixture may be distilled off and then purified by column chromatography.

< Compound IZ2 >)

Compound IZ2 is a compound represented by formula (IZ 2).

[ in the formula (IZ2),

R^CO1Z2and R^CO2Z2Independently of one another represent-O-R^O1Z2or-NR^N1Z2R^N2Z2。

R^N1Z2、R^N2Z2、R^1Z2、R^2Z2、R^3Z2、R^4Z2And R^5Z2Independently of one another, represents a hydrogen atom, -CO-R^102Z2、-COO-R^101Z2、-OCO-R^102Z2、-COCO-R^102Z2、-O-R^102Z2、-SO₂-R^101Z2、-SO₂N(R^102Z2)₂、-CON(R^102Z2)₂、-N(R^102Z2)₂、-NHCO-R^102Z2、-NHCO-N(R^102Z2)₂、-NHCOOR^102Z2、-OCON(R^102Z2)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.

R^2Z2And R^3Z2、R^3Z2And R^4Z2And R^4Z2And R^5Z2Each of which may be bonded to each other to form a ring. R^101Z2The alkyl group may have a substituent and has 1 to 40 carbon atoms, or a heterocyclic group may have a substituent. R^O1Z2And R^102Z2Independently represent a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group. M represents a hydrogen atom or an alkali metal atom.

R^O1Z2、R^N1Z2、R^N2Z2、R^101Z2、R^102Z2And when there are a plurality of M, they may be the same or different. The wavy line indicates the E-body or the Z-body.]

R^O1Z2、R^N1Z2、R^N2Z2、R^1Z2、R^2Z2、R^3Z2、R^4Z2、R^5Z2、R^101Z2And R^102Z2The number of carbon atoms of the optionally substituted hydrocarbon group is 1 to 40, preferably 1 to 30, more preferably 1 to 20, still more preferably 1 to 15, particularly preferably 1 to 10, and particularly preferably 1 to 5.

R^O1Z2、R^N1Z2、R^N2Z2、R^1Z2、R^2Z2、R^3Z2、R^4Z2、R^5Z2、R^101Z2And R^102Z2The hydrocarbon group having 1 to 40 carbon atoms may be an aliphatic hydrocarbon group or an aromatic hydrocarbon group, and the aliphatic hydrocarbon group may be saturated or unsaturated, and may be a chain or alicyclic group.

As R^O1Z2、R^N1Z2、R^N2Z2、R^1Z2、R^2Z2、R^3Z2、R^4Z2、R^5Z2、R^101Z2And R^102Z2Examples of the saturated or unsaturated chain hydrocarbon group include straight chain alkyl groups such as methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, heptadecyl, octadecyl, and eicosyl; isopropyl, isobutyl, sec-butyl, tert-butyl, (2-ethyl) butyl, isopentyl, neopentylBranched alkyl groups such as a tert-pentyl group, a (1-methyl) pentyl group, a (2-methyl) pentyl group, a (1-ethyl) pentyl group, a (3-ethyl) pentyl group, an isohexyl group, a (5-methyl) hexyl group, a (2-ethyl) hexyl group, and a (3-ethyl) heptyl group; alkenyl groups such as vinyl, 1-propenyl, 2-propenyl (allyl), (1-methyl) vinyl, 2-butenyl, 3-butenyl, 1, 3-butadienyl, (1- (2-propenyl)) vinyl, (1, 2-dimethyl) propenyl, and 2-pentenyl; and so on. The number of carbon atoms of the saturated or unsaturated chain hydrocarbon group is preferably 1 to 30, more preferably 1 to 20, further preferably 1 to 15, particularly preferably 1 to 10, further more preferably 1 to 8, and particularly preferably 1 to 5. Among them, a linear or branched alkyl group having 1 to 10 carbon atoms, more preferably 1 to 8 carbon atoms is particularly preferable, and a methyl group, an ethyl group, and a tert-butyl group are particularly preferable.

As R^O1Z2、R^N1Z2、R^N2Z2、R^1Z2、R^2Z2、R^3Z2、R^4Z2、R^5Z2、R^101Z2And R^102Z2Examples of the saturated or unsaturated alicyclic hydrocarbon group include cyclopropyl, 1-methylcyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, 1-methylcyclohexyl, 2-methylcyclohexyl, 3-methylcyclohexyl, 4-methylcyclohexyl, 1, 2-dimethylcyclohexyl, 1, 3-dimethylcyclohexyl, 1, 4-dimethylcyclohexyl, 2, 3-dimethylcyclohexyl, 2, 4-dimethylcyclohexyl, 2, 5-dimethylcyclohexyl, 2, 6-dimethylcyclohexyl, 3, 4-dimethylcyclohexyl, 3, 5-dimethylcyclohexyl, 2-dimethylcyclohexyl, 3-dimethylcyclohexyl, 4-dimethylcyclohexyl, cyclooctyl, 2,4, 6-trimethylcyclohexyl, and, Cycloalkyl groups such as 2,2,6, 6-tetramethylcyclohexyl, 3,5, 5-tetramethylcyclohexyl, 4-pentylcyclohexyl, 4-octylcyclohexyl and 4-cyclohexylcyclohexyl; cycloalkenyl groups such as cyclohexenyl (e.g., cyclohex-2-ene, cyclohex-3-ene), cycloheptenyl, cyclooctenyl, and the like; norbornyl, adamantyl, bicyclo [2.2.2]An octyl group and the like. The number of carbon atoms of the saturated or unsaturated alicyclic hydrocarbon group is preferably 3 to 30, more preferably 3 to 20, still more preferably 4 to 20, yet more preferably 4 to 15, even more preferably 5 to 15, and most preferably 5 to 10. Among them, cyclopentyl group, and the like are particularly preferable, Cyclohexyl, cycloheptyl, cyclooctyl.

As R^O1Z2、R^N1Z2、R^N2Z2、R^1Z2、R^2Z2、R^3Z2、R^4Z2、R^5Z2、R^101Z2And R^102Z2The aromatic hydrocarbon group may include a phenyl group, an o-tolyl group, a m-tolyl group, a p-tolyl group, a 2, 3-dimethylphenyl group, a 2, 4-dimethylphenyl group, a 2, 5-dimethylphenyl group, a 2, 6-dimethylphenyl group, a 3, 4-dimethylphenyl group, a 3, 5-dimethylphenyl group, a 4-vinylphenyl group, an o-isopropylphenyl group, a m-isopropylphenyl group, a p-isopropylphenyl group, an o-tert-butylphenyl group, a m-tert-butylphenyl group, a p-tert-butylphenyl group, a mesityl group, a 4-ethylphenyl group, a 4-butylphenyl group, a 4-pentylphenyl group, a 2, 6-bis (2-propyl) phenyl group, a 4-cyclohexylphenyl group, a 2,4, 6-trimethylphenyl group, a 4-octylphenyl group, a 4-vinylphenyl group, a 1-naphthyl group, a 2-naphthyl group, a, Aromatic hydrocarbon groups such as 5,6,7, 8-tetrahydro-1-naphthyl, 5,6,7, 8-tetrahydro-2-naphthyl, fluorenyl, phenanthryl, anthracyl, pyrenyl and the like; and so on. The number of carbon atoms of the aromatic hydrocarbon group is preferably 6 to 30, more preferably 6 to 20, and further preferably 6 to 15.

R^O1Z2、R^N1Z2、R^N2Z2、R^1Z2、R^2Z2、R^3Z2、R^4Z2、R^5Z2、R^101Z2And R^102Z2The hydrocarbon group may be a combination of the hydrocarbon groups listed above (for example, an aromatic hydrocarbon group, and at least 1 of a chain hydrocarbon group and an alicyclic hydrocarbon group), and examples thereof include aralkyl groups such as benzyl, phenethyl, and 1-methyl-1-phenylethyl; arylalkenyl groups such as phenylvinyl (styryl); arylalkynyl groups such as phenylethynyl; a phenyl group having 1 or more phenyl groups bonded thereto, such as a biphenyl group and a terphenyl group; cyclohexylmethylphenyl, benzylphenyl, (dimethyl (phenyl) methyl) phenyl, and the like.

For R^O1Z2、R^N1Z2、R^N2Z2、R^1Z2、R^2Z2、R^3Z2、R^4Z2、R^5Z2、R^101Z2And R^102Z2As the group represented, a group obtained by combining the above-mentioned hydrocarbon groups (for example, a chain hydrocarbon group and an alicyclic hydrocarbon group) may be mentionedExamples of the alkyl group include an alkyl group to which 1 or more alicyclic hydrocarbon groups are bonded, such as a cyclopropylmethyl group, a cyclopropylethyl group, a cyclobutylmethyl group, a cyclobutylethyl group, a cyclopentylmethyl group, a cyclopentylethyl group, a cyclohexylmethyl group, a 2-methylcyclohexylmethyl group, a cyclohexylethyl group, and an adamantylmethyl group.

The number of carbon atoms is preferably 4 to 30, more preferably 6 to 30, further preferably 6 to 20, further preferably 4 to 15, and particularly preferably 6 to 15.

R^O1Z2、R^N1Z2、R^N2Z2、R^1Z2、R^2Z2、R^3Z2、R^4Z2、R^5Z2、R^101Z2And R^102Z2The hydrocarbon group represented may have a substituent. The substituent may have a valence of 1 or 2. For substituents having a valence of 2, preferably 2 chemical bonds are bonded to the same carbon atom to form a double bond.

Examples of the substituent having a valence of 1 include:

methoxy group, ethoxy group, propoxy group, isopropoxy group, butoxy group, isobutoxy group, sec-butoxy group, tert-butoxy group, pentyloxy group, hexyloxy group, (2-ethyl) hexyloxy group, heptyloxy group, octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, dodecyloxy group, (2-ethyl) hexyloxy group, eicosyloxy group, 1-phenylethoxy group, 1-methyl-1-phenylethoxy group, phenyloxy group, o-tolyloxy group, 2, 3-dimethylphenyloxy group, 2, 4-dimethylphenyloxy group, 2, 5-dimethylphenyloxy group, 2, 6-dimethylphenyloxy group, 3, 4-dimethylphenyloxy group, 3, 5-dimethylphenyloxy group, 2-dicyanophenyloxy group, 2, 3-dicyanophenyloxy group, 2-dicyanophenyloxy group, 2, 4-dicyanophenyloxy group, 2, 5-dicyanophenyloxy group, 2, 6-dicyanophenyloxy group, 3, 4-dicyanophenyloxy group, 3, 5-dicyanophenyloxy group, 4-methoxyphenyloxy group, an oxy group having a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like) bonded to one side, such as a 2-methoxyphenyloxy group, a 3-methoxyphenyloxy group, a 4-ethoxyphenyloxy group, a 2-ethoxyphenyloxy group, and a 3-ethoxyphenyloxy group, or a group represented by the following chemical formula;

A thio group (sulfo group) to which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) is bonded, such as a methylthio group, an ethylthio group, a propylthio group, a butylthio group, a tert-butylthio group, a pentylthio group, a hexylthio group, (2-ethyl) hexylthio group, a heptylthio group, an octylthio group, a nonylthio group, a decylthio group, an undecylthio group, a dodecylthio group, an eicosylthio group, a phenylthio group, and an o-tolylthio group;

epoxy, oxetanyl, tetrahydrofuranyl, tetrahydropyranyl;

a formyl group;

a carbonyl group (preferably 2 to 12 carbon atoms when the carbonyl group is an alkanoyl group) having a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 11 carbon atoms) or a derivative thereof (for example, a derivative thereof such as a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), or an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)) bonded thereto, such as an acetyl group, a propionyl group, a butyryl group, a 2, 2-dimethylpropionyl group, a pentanoyl group, a hexanoyl group, (2-ethyl) hexanoyl group, a heptanoyl group, an octanoyl group, a nonanoyl group, a decanoyl group, an undecanoyl group, a dodecanoyl group, an heneicosanoyl group, and a benzoyl group;

An oxycarbonyl group in which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) is bonded, such as a methoxycarbonyl group, an ethoxycarbonyl group, a propoxycarbonyl group, a butoxycarbonyl group, a tert-butoxycarbonyl group, a pentyloxycarbonyl group, a hexyloxycarbonyl group, (2-ethyl) a hexyloxycarbonyl group, a heptyloxycarbonyl group, an octyloxycarbonyl group, a nonyloxycarbonyl group, a decyloxycarbonyl group, a undecyloxycarbonyl group, a dodecyloxycarbonyl group, an eicosyloxycarbonyl group, a phenyloxycarbonyl group, or an o-tolyloxycarbonyl group represented by the following chemical formula);

an amino group; n-methylamino, N-dimethylamino, N-ethylamino, N-diethylamino, N-propylamino, N-dipropylamino, N-isopropylamino, N-diisopropylamino, N-butylamino, N-dibutylamino, N-isobutylamino, N-diisobutylamino, N-sec-butylamino, N-di-sec-butylamino, N-tert-butylamino, N-di-tert-butylamino, N-pentylamino, N-dipentylamino, N- (1-ethylpropyl) amino, N-di (1-ethylpropyl) amino, N-hexylamino, N-dihexylamino, N- (2-ethyl) hexylamino, N-diethylamino, N-propylamino, N-dipropylamino, N-isopropylamino, N-di-sec-butylamino, N-pentylamino, N-dipentylamino, N-1-ethylpropyl) amino, N-di (1-ethylpropyl) amino, N-hexylamino, N-butylamino, N-butylamino, N-di-butylamino, N-butylamino, N, n, N-di (2-ethyl) hexylamino group, N-heptylamino group, N-diheptylamino group, N-octylamino group, N-dioctylamino group, N-nonylamino group, N-dinonylamino group, N-phenylamino group, N-diphenylamino group, N-ethylmethylamino group, N-propylmethylamino group, N-isopropylmethylamino group, N-butylmethylamino group, N-decylamino group, N-decylmethylamino group, N-undecylamino group, N-undecylmethylamino group, N-dodecylamino group, N-dodecylmethylamino group, N-eicosylamino group, N-eicosylmethyl amino group, An amino group substituted with 1 or 2 hydrocarbon groups having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or derivative groups thereof (for example, groups derived from carboxyl, sulfo, nitro, hydroxyl, halogen (preferably chlorine atom), alkylsulfamoyl having 1 to 10 carbon atoms (preferably octylsulfamoyl), and the like, such as an N, N-tert-butylmethylamino group, an N, N-phenylmethylamino group, and the like, and groups represented by the following chemical formulae;

A sulfamoyl group; n-methylsulfamoyl, N-dimethylsulfamoyl, N-ethylsulfamoyl, N-diethylsulfamoyl, N-propylsulfamoyl, N-dipropylsulfamoyl, N-isopropylsulfamoyl, N-diisopropylsulfamoyl, N-butylsulfamoyl, N-dibutylsulfamoyl, N-isobutylsulfamoyl, N-diisobutylsulfamoyl, N-sec-butylsulfamoyl, N-tert-butylsulfamoyl, N-di-tert-butylsulfamoyl, N-pentylsulfamoyl, N-dipentylsulfamoyl, N- (1-ethylpropyl) sulfamoyl, N-di (1-ethylpropyl) sulfamoyl, N-diethylsulfamoyl, N-di (1-ethylpropyl) sulfamoyl, N-diethylsulfamoyl, N-butylsulfamoyl, N-di (1-ethylpropyl) sulfamoyl, N-butylsulfamoyl, N-di (1-isobutylsulfamoyl), N-dibutylsulfamoyl, N, di (1-di (ethyl, N, N, N-hexylsulfamoyl, N-dihexylsulfamoyl, N- (2-ethyl) hexylsulfamoyl, N-di (2-ethyl) hexylsulfamoyl, N-heptylsulfamoyl, N-diheptylsulfamoyl, N-octylsulfamoyl, N-dioctylsulfamoyl, N-octylmethylsulfamoyl, N-nonylsulfamoyl, N-dinonylsulfamoyl, N-phenylsulfamoyl, N-diphenylsulfamoyl, N-ethylmethylsulfamoyl, N-propylmethylsulfamoyl, N-isopropylmethylsulfamoyl, N-butylmethylsulfamoyl, N-decylsulfamoyl, N-decylmethylsulfamoyl, Sulfamoyl groups substituted with 1 or 2 hydrocarbon groups having 1 to 20 (preferably 1 to 10) carbon atoms or derivative groups thereof (for example, groups derived from carboxyl, sulfo, nitro, hydroxyl, halogen (preferably chlorine atom), alkylsulfamoyl having 1 to 10 carbon atoms (preferably octylsulfamoyl), and the like, such as N-undecylsulfamoyl, N-undecylmethylsulfamoyl, N-dodecylsulfamoyl, N-dodecylmethylsulfamoyl, N-eicosylsulfamoyl, N-eicosylmethylsulfamoyl, N-tert-butylmethylsulfamoyl, and N, N-phenylmethylsulfamoyl);

A formylamino group; acetylamino, propionylamino, butyrylamino, 2-dimethylpropionylamino, valerylamino, hexanoylamino, (2-ethyl) hexanoylamino, heptanoylamino, a carbonylamino group (preferably 1 to 12 carbon atoms in the case where the carbonylamino group is an alkanoylamino group), to which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 12 carbon atoms) or a derivative thereof (for example, a derivative thereof such as a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)) is bonded, such as an octanoylamino group, a nonanoylamino group, a decanoylamino group, a undecanoylamino group, a dodecanoylamino group, a heneicosanoylamino group, or a benzoylamino group represented by the following chemical formula;

a hydroxyl group; halogen atoms such as fluorine atom, chlorine atom, bromine atom and iodine atom;

carboxy, -CO₂M²(M²Is an alkali metal, preferably lithium, sodium, potassium); sulfo, -SO₃M²(M²Is an alkali metal, preferably lithium, sodium, potassium); a nitro group; a cyano group;

a formyloxy group; acetoxy, propionyloxy, butyryloxy, 2-dimethylpropionyloxy, pentanoyloxy, hexanoyloxy, (2-ethyl) hexanoyloxy, heptanoyloxy, a carbonyloxy group (preferably 1 to 10 carbon atoms in the case where the carbonyloxy group is an alkanoyloxy group) to which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or a derivative thereof (for example, a derivative thereof such as a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)) is bonded, such as an octanoyloxy group, a nonanoyloxy group, a decanoyloxy group, a undecanoyloxy group, a dodecanoyloxy group, a heneicosanoyloxy group, a benzoyloxy group, and the like, and a group represented by the following chemical formula;

A sulfonyl group having a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like) bonded thereto, such as a methylsulfonyl group, an ethylsulfonyl group, a propylsulfonyl group, a butylsulfonyl group, a pentylsulfonyl group, a hexylsulfonyl group, a (2-ethyl) hexylsulfonyl group, a heptylsulfonyl group, an octylsulfonyl group, a nonylsulfonyl group, a decylsulfonyl group, an undecylsulfonyl group, a dodecylsulfonyl group, an eicosylsulfonyl group, a phenylsulfonyl group, a p-tolylsulfonyl group, or the like represented by the following chemical formula;

a carbamoyl group; n-methylcarbamoyl, N-dimethylcarbamoyl, N-ethylcarbamoyl, N-diethylcarbamoyl, N-propylcarbamoyl, N-dipropylcarbamoyl, N-isopropylcarbamoyl, N-diisopropylcarbamoyl, N-butylcarbamoyl, N-dibutylcarbamoyl, N-isobutylcarbamoyl, N-diisobutylcarbamoyl, N-sec-butylcarbamoyl, N-di-sec-butylcarbamoyl, N-tert-butylcarbamoyl, N-di-tert-butylcarbamoyl, N-pentylcarbamoyl, N-dipentylcarbamoyl, N- (1-ethylpropyl) carbamoyl, N-ethylcarbamoyl, N-diethylcarbamoyl, N-isopropylcarbamoyl, N-diisopropylcarbamoyl, N-isopropylcarbamoyl, N-butylcarbamoyl, N-t-butylcarbamoyl, N-t-butylcarbamoyl, N-N-butylcarbamoyl, N-t-butylcarbamoyl, N-N-butylcarbamoyl, N-t-N-t-butylcarbamoyl, N-t-butylcarbamoyl, N-t, N, N-di (1-ethylpropyl) carbamoyl, N-hexylcarbamoyl, N-dihexylcarbamoyl, N- (2-ethyl) hexylcarbamoyl, N-di (2-ethyl) hexylcarbamoyl, N-heptylcarbamoyl, N-diheptylcarbamoyl, N-octylcarbamoyl, N-dioctylcarbamoyl, N-nonylcarbamoyl, N-octylmethylcarbamoyl, N-octylbutylcarbamoyl, N-dinonylcarbamoyl, N-phenylcarbamoyl, N-diphenylcarbamoyl, N-ethylmethylcarbamoyl, N-propylmethylcarbamoyl, N-ethylmethylcarbamoyl, N-propylmethylcarbamoyl, N-ethylhexylcarbamoyl, N-dihexylcarbamoyl, N- (2-ethyl) hexylcarbamoyl, N-octylcarbamoyl, N-diheptylcarbamoyl, N-octylcarbamoyl, N-nonylcarbamoyl, N-octylcarbamoyl, N-octylmethylcarbamoyl, N-octylcarbamoyl, N-octylmethylcarbamoyl, N-nonylcarbamoyl, N-dimethylcarbamoyl, N, a hydrocarbon group having 1 to 2 carbon atoms of 1 to 20 (preferably 1 to 10 carbon atoms) or a derivative thereof (for example, a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an N, N-isopropylmethylcarbamoyl group, an N, N-butylmethylcarbamoyl group, an N-decylmethylcarbamoyl group, an N, N-decylmethylcarbamoyl group, an N-undecylcarbamoyl group, an N, N-undecylmethylcarbamoyl group, an N-dodecylcarbamoyl group, an N, N-dodecylmethylcarbamoyl group, an N-eicosylcarbamoyl group, an N, N-eicosylmethylcarbamoyl group, an N, N-tert-butylmethylcarbamoyl group, an N, N-phenylmethylcarbamoyl group, etc., and a group represented by the following chemical formula, etc. (preferably a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), a derivative thereof, A carbamoyl group substituted with an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably, an octylsulfamoyl group) or the like;

A hydrocarbon group having 1 to 20 carbon atoms, which is obtained by substituting all hydrogen atoms with fluorine atoms such as a trifluoromethyl group, a perfluoroethyl group, a perfluoropropyl group, a perfluoroisopropyl group, a perfluorobutyl group, a perfluoropentyl group, a perfluorohexyl group, a perfluoroheptyl group, a perfluorooctyl group, a perfluorononyl group, a perfluorodecyl group, a perfluoroundecyl group, a perfluorododecyl group, a perfluoroeicosyl group, a perfluorocyclohexyl group, and a perfluorophenyl group;

a hydrocarbon group having 1 to 20 carbon atoms which has, as a substituent, a linear or branched alkyl group having 1 to 20 carbon atoms in which all hydrogen atoms are substituted with fluorine atoms, such as a perfluoroethylmethyl group, a perfluoropropylmethyl group, a perfluoroisopropylmethyl group, a perfluorobutylmethyl group, a perfluoropentylmethyl group, a perfluorohexylmethyl group, a perfluoroheptylmethyl group, a perfluorooctylmethyl group, a perfluorononylmethyl group, a perfluorodecylmethyl group, a perfluoroundecylmethyl group, a perfluorododecylmethyl group, and a perfluoroeicosylmethyl group;

a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) in which some hydrogen atoms are substituted with fluorine, such as a 2-fluorophenyl group, a 3-fluorophenyl group, a 4-fluorophenyl group, and a 2,4, 6-trifluorophenyl group;

-CO-SH、-CO-S-CH₃、-CO-S-CH₂CH₃、-CO-S-CH₂-CH₂-CH₃and-CO-S-CH₂-CH₂-CH₂-CH₃Or a thiocarbonyl group, -CO-S-C, bonded to an alkyl group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) ₆H₅A thiocarbonyl group bonded to an aryl group having 6 to 20 carbon atoms;

a group represented by the following chemical formula, — COCO-R (wherein R represents a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)), or the like);

-NRCONR represented by the following chemical formula₂(wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereofA group derived from a percarboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), and the like), wherein R's may be the same or different from each other, and may be bonded to each other to form a ring);

OCONR represented by the following chemical formula₂(wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group having 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like), and R's may be the same or different from each other and may be bonded to each other to form a ring);

A group represented by the following chemical formula-NRCOOR (wherein R represents a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like), wherein R may be the same or different from each other, and may be bonded to each other to form a ring);

*-OP(O)(OCH₃)₂etc.. OP (O) (OR)₂(wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereofA group derived from a percarboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), and the like), wherein R's may be the same or different from each other, and may be bonded to each other to form a ring);

*-Si(CH₃)₃、*-Si(CH₂CH₃)₃、*-Si(C₆H₅)₃and-Si (CH)₃)₂)₃Etc. -SiR₃(wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group having 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like), and R's may be the same or different from each other and may be bonded to each other to form a ring); and so on.

Examples of the substituent having a valence of 2 include an oxo group, a thioxo group, an imino group substituted with an alkyl group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms), and an imino group substituted with an aryl group having 6 to 20 carbon atoms. Examples of the imino group substituted with an alkyl group include CH₃-N＝、CH₃-CH₂-N＝、CH₃-(CH₂)₂-N ═ and CH₃-(CH₂)₃-N ═ and the like. Examples of the imino group substituted with an aryl group include C₆H₅-N ═ and the like.

As the substituent of the hydrocarbon group having 1 to 40 carbon atoms, preferred is a substituent of group s 1. The derivative group shown below is preferably a derivative group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like.

[ group s1]

An oxy group having a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof bonded to one side thereof;

a carbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof is bonded;

an oxycarbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof is bonded;

an amino group; amino substituted by 1 or 2 alkyl with 1-20 carbon atoms or derivative groups thereof; a sulfamoyl group; a sulfamoyl group substituted with 1 or 2 hydrocarbon groups having 1 to 20 carbon atoms or derivative groups thereof; a carbonylamino group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof is bonded; a hydroxyl group; a halogen atom;

-CO₂M (preferably carboxyl group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom); -SO₃M (preferably sulfo) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom); a nitro group; a cyano group; a carbonyloxy group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof is bonded;

a sulfonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof is bonded; a carbamoyl group; carbamoyl substituted by 1 or 2 hydrocarbon groups having 1 to 20 carbon atoms or derivative groups thereof; a hydrocarbon group having 1 to 20 carbon atoms, wherein all hydrogen atoms are substituted with fluorine atoms;

a hydrocarbon group having 1 to 20 carbon atoms, which has a linear or branched alkyl group having 1 to 20 carbon atoms, wherein all hydrogen atoms are substituted with fluorine atoms, as a substituent; a hydrocarbon group having 1 to 20 carbon atoms, wherein a part of hydrogen atoms is substituted with fluorine; an oxo group.

The substituent of the hydrocarbon group having 1 to 40 carbon atoms is more preferably a substituent of group s 2.

[ group s2]

An oxy group having a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof bonded to one side thereof;

a carbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded;

an oxycarbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded;

An amino group; an amino group substituted with 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms;

a sulfamoyl group; a sulfamoyl group substituted with 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms or derivative groups thereof;

a carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded;

a hydroxyl group; fluorine atom, chlorine atom, bromine atom;

-CO₂m (preferably carboxyl group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom);

-SO₃m (preferably sulfo) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom); a nitro group; a cyano group;

a carbonyloxy group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded;

a sulfonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded;

a carbamoyl group; carbamoyl substituted by 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms or derivative groups thereof; a hydrocarbon group having 1 to 10 carbon atoms, wherein all hydrogen atoms are substituted with fluorine atoms; a hydrocarbon group having 1 to 10 carbon atoms, which has a linear or branched alkyl group having 1 to 10 carbon atoms, wherein all hydrogen atoms are substituted with fluorine atoms, as a substituent; a hydrocarbon group having 1 to 10 carbon atoms, wherein a part of hydrogen atoms is substituted with fluorine; an oxo group.

As R^O1Z2、R^N1Z2、R^N2Z2、R^1Z2、R^2Z2、R^3Z2、R^4Z2、R^5Z2、R^101Z2And R^102Z2The hydrocarbon group having 1 to 40 carbon atoms and having a substituent represented by the formula (I) includes a hydrocarbon group having 1 to 40 carbon atoms and having a substituent having a valence of 1 or 2, preferably a saturated or unsaturated chain hydrocarbon group having 1 to 30 carbon atoms and having a substituent having a valence of 1 or 2, a saturated or unsaturated alicyclic hydrocarbon group having 3 to 30 carbon atoms and having a substituent having a valence of 1 or 2, an aromatic hydrocarbon group having 6 to 30 carbon atoms and having a substituent having a valence of 1 or 2, and a group having 1 to 30 carbon atoms and having a substituent having a valence of 1 or 2, which are a combination of hydrocarbon groups,

more preferably, the hydrocarbon group includes a saturated or unsaturated chain hydrocarbon group having 1 to 20 carbon atoms having a substituent of group s1, a saturated or unsaturated alicyclic hydrocarbon group having 3 to 20 carbon atoms having a substituent of group s1, an aromatic hydrocarbon group having 6 to 20 carbon atoms having a substituent of group s1, or a combination of hydrocarbon groups having 1 to 20 carbon atoms having a substituent of group s1,

particularly preferred examples thereof include a saturated or unsaturated chain hydrocarbon group having 1 to 15 carbon atoms having a substituent of group s2, a saturated or unsaturated alicyclic hydrocarbon group having 3 to 15 carbon atoms having a substituent of group s2, an aromatic hydrocarbon group having 6 to 15 carbon atoms having a substituent of group s2, or a group having 1 to 15 carbon atoms having a substituent of group s2, which is a combination of hydrocarbon groups.

As R^O1Z2、R^N1Z2、R^N2Z2、R^1Z2、R^2Z2、R^3Z2、R^4Z2、R^5Z2、R^101Z2And R^102Z2The heterocyclic group represented by (a) may be monocyclic or polycyclic, and is preferably a heterocyclic ring containing a heteroatom as a constituent of the ring. Examples of the hetero atom include a nitrogen atom, an oxygen atom, a sulfur atom and the like. The number of carbon atoms of the heterocyclic group is preferably 3 to 30, more preferably 3 to 22, further preferably 3 to 20, further preferably 3 to 18, further more preferably 3 to 15, and particularly preferably 3 to 14.

Examples of the heterocyclic ring containing a nitrogen atom include:

monocyclic saturated heterocycles such as aziridine, azetidine, pyrrolidine, piperidine and piperazine; five-membered ring system unsaturated heterocycles such as pyrrole (e.g., 2, 5-dimethylpyrrole), pyrazole (e.g., 2-methylpyrazole and 3-methylpyrazole), imidazole, 1,2, 3-triazole and 1,2, 4-triazole;

a six-membered ring system unsaturated heterocycle such as pyrimidine, pyrazine and 1,3, 5-triazine, for example pyridine, pyridazine and 6-methylpyrimidine;

a fused bicyclic heterocycle such as quinoxaline (e.g., indazole, indoline, isoindoline, indole, indolizine, benzimidazole, quinoline, isoquinoline, 5,6,7, 8-tetrahydro (3-methyl) quinoxaline or 3-methylquinoxaline, quinazoline, cinnoline, phthalazine, naphthyridine, purine, pteridine, benzopyrazole or phenylpiperidine; condensed tricyclic heterocycles such as carbazole, acridine and phenazine; and so on.

Examples of the heterocyclic ring containing an oxygen atom include:

monocyclic saturated heterocycles such as oxetane, tetrahydrofuran, tetrahydropyran, 1, 3-dioxane, 1, 4-dioxane and 1-cyclopentyldioxolane; bicyclic saturated heterocycles such as 1, 4-dioxaspiro [4.5] decane and 1, 4-dioxaspiro [4.5] nonane; lactone heterocycles such as α -caprolactone, β -propiolactone, γ -butyrolactone, γ -valerolactone and δ -valerolactone; five-membered ring system unsaturated heterocycles such as furan (e.g., 2, 3-dimethylfuran, 2, 5-dimethylfuran); a six-membered ring system unsaturated heterocycle such as 2H-pyran, 4H-pyran; fused bicyclic heterocycles such as benzopyrans (e.g., 1-benzofuran and 4-methylbenzopyran), benzodioxole, chroman and isochroman; fused tricyclic heterocycles such as xanthene and dibenzofuran; and so on.

Examples of the heterocyclic ring containing a sulfur atom include:

five-membered ring system saturated heterocycles such as dithiolane;

saturated heterocyclic rings of six-membered ring systems such as thiacyclohexane, 1, 3-dithiane, 2-methyl-1, 3-dithiane and the like;

a five-membered ring system unsaturated heterocycle such as thiophene (e.g., 3-methylthiophene, 2-carboxythiophene), benzothiopyran (e.g., 4H-thiopyran, tetrahydrothiopyran);

fused bicyclic heterocycles such as benzothiophene; fused tricyclic heterocycles such as thianthrene and dibenzothiophene; and so on.

Examples of the heterocyclic ring containing a nitrogen atom and an oxygen atom include:

monocyclic saturated heterocycles such as morpholine, 2-pyrrolidone, 2-methyl-2-pyrrolidone, 2-piperidone and 2-methyl-2-piperidone; a monocyclic unsaturated heterocycle such as oxazole (e.g., 4-methyloxazole), isoxazole (e.g., 2-methylisoxazole, and 3-methylisoxazole);

fused bicyclic heterocycles such as benzoxazole, benzisoxazole, benzoxazine, benzodioxane, and benzimidazoline; condensed tricyclic heterocycles such as phenoxazine; and so on.

Examples of the heterocyclic ring containing a nitrogen atom and a sulfur atom include monocyclic heterocyclic rings such as thiazoles, e.g., 3-methylthiazole and 2, 4-dimethylthiazole; fused bicyclic heterocycles such as benzothiazole; fused tricyclic heterocycles such as phenothiazine; and so on.

The heterocyclic ring may be a group obtained by combining the hydrocarbon groups listed above, and examples thereof include tetrahydrofurylmethyl and the like.

The heterocyclic ring may be a heterocyclic ring represented by the following chemical formula.

The above heterocyclic group may be R^1Z2～R^5Z22 or more of them are bonded to form a heterocyclic group. Such heterocyclic radicals contain R^1Z2～R^5Z2The bonded benzene ring has a ring structure of 2 or more rings inside. The 2 or more ring structures include, for example, the structures of the following chemical formulae.

The bonding position of the heterocycle is a portion where any hydrogen atom contained in each ring is removed.

R^O1Z2、R^N1Z2、R^N2Z2、R^1Z2、R^2Z2、R^3Z2、R^4Z2、R^5Z2、R^101Z2And R^102Z2The heterocyclic group represented may have a substituent. Examples of the substituent include^O1Z2、R^N1Z2、R^N2Z2、R^1Z2、R^2Z2、R^3Z2、R^4Z2、R^5Z2、R^101Z2And R^102Z2The hydrocarbon group may have the same substituent as the substituent. In addition, in the case where the above-mentioned heterocyclic ring contains a nitrogen atom as its constituent element, the above-mentioned hydrocarbon group as a substituent may be bonded to the nitrogen atom.

Preferred examples of the substituent include^O1Z2、R^N1Z2、R^N2Z2、R^1Z2、R^2Z2、R^3Z2、R^4Z2、R^5Z2、R^101Z2And R^102Z2The preferable examples of the substituents which the hydrocarbon group may have are the same. As R^O1Z2、R^N1Z2、R^N2Z2、R^1Z2、R^2Z2、R^3Z2、R^4Z2、R^5Z2、R^101Z2And R^102Z2The heterocyclic group having a substituent represented by the formula (i) includes a heterocyclic group having a substituent having a valence of 1 or 2, preferably a heterocyclic group having a substituent of group s1, and more preferably a heterocyclic group having a substituent of group s 2.

The substituent (first substituent) that the hydrocarbon group or heterocyclic group may have may be 1 or 2 or more, and 2 or more substituents may be the same or different and independent of each other. Further, the first substituent may have another substituent (second substituent) bonded to the hydrocarbon group included in a part thereof. The second substituent may be selected from the same groups as the first substituent.

Below, for R^N1Z2、R^N2Z2、R^1Z2、R^2Z2、R^3Z2、R^4Z2、R^5Z2Of (a) is-CO-R^102Z2、-COO-R^101Z2、-OCO-R^102Z2、-COCO-R^102Z2、-O-R^102Z2、-SO₂-R^101Z2、-SO₂N(R^102Z2)₂、-CON(R^102Z2)₂、-N(R^102Z2)₂、-NHCO-R^102Z2、-NHCO-N(R^102Z2)₂、-NHCOOR^102Z2、-OCON(R^102Z2)₂Halogen atom, -SO₃M、-CO₂M is explained.

as-CO-R^102Z2Examples thereof include a formyl group; a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, or a halogen group (preferably 1 to 20 carbon atoms) is bonded to a group represented by the above formula or the like (for example, a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, or a halogen group is bonded to a group represented by the above formula)Chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), and the like) and a carbonyl group (having 2 to 41 carbon atoms when the carbonyl group is an acyl group) corresponding to-CO-R in the compounds shown in tables 1Z2 to 22Z2 and tables 27Z2 to 37Z2^102Z2Preferable examples of the group(s) include a carbonyl group (more preferably 2 to 12 carbon atoms when the carbonyl group is an alkanoyl group) to which a hydrocarbon group having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms) or a derivative thereof is bonded, and compounds shown in tables 1Z2 to 22Z2 and 27Z2 to 37Z2 correspond to-CO-R ^102Z2And the like.

as-COO-R^101Z2Examples thereof include methoxycarbonyl, ethoxycarbonyl, propoxycarbonyl, tert-butoxycarbonyl, pentyloxycarbonyl, hexyloxycarbonyl, (2-ethyl) hexyloxycarbonyl and heptyloxycarbonyl, an oxycarbonyl group in which a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) is bonded such as an octyloxycarbonyl group, a nonyloxycarbonyl group, a decyloxycarbonyl group, an undecyloxycarbonyl group, a dodecyloxycarbonyl group, a phenyloxycarbonyl group, an eicosyloxycarbonyl group and the like, and the groups represented by the above chemical formulae, and the compounds shown in tables 1Z2 to 22Z2 and tables 27Z2 to 37Z2 correspond to-COO-R.^101Z2Preferred examples of the group (b) include oxycarbonyl groups to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded, and compounds shown in tables 1Z2 to 22Z2 and tables 27Z2 to 37Z2 which correspond to-COO-R^101Z2And the like.

as-OCO-R^102Z2Examples thereof include a formyloxy group; acetoxy, propionyloxy, butyryloxy, 2-dimethylpropionyloxy, pentanoyloxy, hexanoyloxy, (2-ethyl) hexanoyloxy, heptanoyloxy, octanoyloxy, nonanoyloxy, decanoyloxy, undecanoyloxy, dodecanoyloxy, heneicosanoyloxy, benzoyloxy A carbonyloxy group (having 2 to 41 carbon atoms when the carbonyloxy group is an acyloxy group) in which a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)) is bonded to a group represented by the above chemical formula, or the like, and a compound represented by table 1Z2 to table 22Z2 and table 27Z2 to table 37Z2 corresponds to-OCO-R^102Z2Preferable examples of the group(s) include a carbonyloxy group (more preferably 2 to 12 carbon atoms when the carbonyloxy group is an acyloxy group) to which a hydrocarbon group having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms) or a derivative thereof is bonded, and a compound represented by any one of tables 1Z2 to 22Z2 and tables 27Z2 to 37Z2 corresponds to-OCO-R^102Z2And the like.

as-COCO-R^102Z2Examples thereof include methyloxalyl, ethyloxalyl, propyloxalyl, butyloxalyl, pentyloxalyl, hexyloxalyl, (2-ethyl) hexyloxalyl, heptyloxalyl, octyloxalyl, nonyloxalyl, an oxalyl group in which a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group) is bonded, such as decyl oxalyl group, undecyloxalyl group, dodecyl oxalyl group, eicosyl oxalyl group, cyclopentyl oxalyl group, cyclohexyl oxalyl group, phenyl oxalyl group, p-tolyloxalyl group, and the group represented by the above chemical formula), and compounds shown in tables 1Z2 to 22Z2 and tables 27Z2 to 37Z2 correspond to — COCO — R. ^102Z2And the like.

as-O-R^102Z2Examples of the group include a hydroxyl group; methoxy, ethoxy, propoxy, isopropoxy, butoxy, isobutoxy, sec-butoxy, tert-butoxy, pentyloxy, hexyloxy, heptyloxy, octyloxy, nonyloxy, decyloxy, undecyloxy, dodecyloxy, (2-ethyl) hexyloxyA group, an eicosyloxy group, a 1-phenylethoxy group, a 1-methyl-1-phenylethoxy group, a phenyloxy group, a 2, 3-dimethylphenyloxy group, a 2, 4-dimethylphenyloxy group, a 2, 5-dimethylphenyloxy group, a 2, 6-dimethylphenyloxy group, a 3, 4-dimethylphenyloxy group, a 3, 5-dimethylphenyloxy group, a 2, 2-dicyanophenyloxy group, a 2, 3-dicyanophenyloxy group, a 2, 4-dicyanophenyloxy group, a 2, 5-dicyanophenyloxy group, a 2, 6-dicyanophenyloxy group, a 3, 4-dicyanophenyloxy group, a 3, 5-dicyanophenyloxy group, a 4-methoxyphenyloxy group, a 2-methoxyphenyloxy group, a 3-methoxyphenyloxy group, a, An oxy group having a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like) bonded thereto, such as a 4-ethoxyphenyloxy group, a 2-ethoxyphenyloxy group, a 3-ethoxyphenyloxy group, or a group represented by the above chemical formula, and compounds shown in tables 1Z2 to 22Z2 and tables 27Z2 to 37Z2, which correspond to-O-R ^102Z2Preferred examples of the group (b) include an oxy group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded, and compounds shown in tables 1Z2 to 22Z2 and 27Z2 to 37Z2, which correspond to-O-R^102Z2And the like.

as-SO₂-R^101Z2Examples thereof include methylsulfonyl, ethylsulfonyl, propylsulfonyl, butylsulfonyl, pentylsulfonyl, hexylsulfonyl, (2-ethyl) hexylsulfonyl, heptylsulfonyl, octylsulfonyl, nonyl sulfonyl group, decyl sulfonyl group, undecyl sulfonyl group, dodecyl sulfonyl group, eicosyl sulfonyl group, phenyl sulfonyl group, p-tolyl sulfonyl group, and the like, and sulfonyl groups in which a hydrocarbon group having 1 to 40 (preferably 1 to 20) carbon atoms or a derivative thereof (a derivative thereof such as carboxyl group, sulfo group, nitro group, hydroxyl group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octyl sulfamoyl group) is bonded, such as the group represented by the above chemical formula), and-SO corresponds to the compounds shown in tables 1Z2 to 22Z2 and tables 27Z2 to 37Z 2.₂-R^101Z2Preferable examples of the group (b) include sulfonyl groups to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded, and compounds represented by tables 1Z2 to 22Z2 and tables 27Z2 to 37Z2, which correspond to-SO ₂-R^101Z2And the like.

as-SO₂N(R^102Z2)₂Examples thereof include: a sulfamoyl group; n-methylsulfamoyl, N-ethylsulfamoyl, N-propylsulfamoyl, N-isopropylsulfamoyl, N-butylsulfamoyl, N-isobutylsulfamoyl, N-sec-butylsulfamoyl, N-tert-butylsulfamoyl, N-pentylsulfamoyl, N- (1-ethylpropyl) sulfamoyl, N-hexylsulfamoyl, N- (2-ethyl) hexylsulfamoyl, N-heptylsulfamoyl, N-octylsulfamoyl, N-nonylsulfamoyl, N-decylsulfamoyl, N-undecylsulfamoyl, N-dodecylsulfamoyl, N-eicosylsulfamoyl, N-phenylsulfamoyl, etc., and a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group represented by the above formula, or a derivative thereof Sulfamoyl substituted with a raw group (e.g., a group derived from carboxyl, sulfo, nitro, hydroxyl, halogen (preferably chlorine atom), alkylsulfamoyl having 1 to 10 carbon atoms (preferably octylsulfamoyl), etc.), and compounds represented by tables 1Z2 to 22Z2 and tables 27Z2 to 37Z2, which correspond to-SO₂NH(R^102Z2X)(R^102Z2XIs not a hydrogen atom, other than, and R^102Z2The same as defined above), etc.; n, N-dimethylsulfamoyl, N-ethylmethylsulfamoyl, N-diethylsulfamoyl, N-propylmethylsulfamoyl, N-dipropylsulfamoyl, N-isopropylmethylsulfamoyl, N-diisopropylsulfamoyl, N-tert-butylmethylsulfamoyl, N-diisobutylsulfamoyl, N-di-sec-butylsulfamoyl, N-di-tert-butylsulfamoyl, N-butylmethylsulfamoyl, N-dibutylsulfamoyl, N-dipentylsulfamoyl, N-bis (1-ethylpropyl) sulfamoyl, N-dihexylsulfamoyl, N-bis (2-ethyl) hexylsulfamoyl, N-diethylsulfamoyl, N, N-diheptylsulfamoyl, N-octylmethylsulfamoyl, N-dioctylsulfamoyl, N-dinonylsulfamoyl, N-decylmethylsulfamoyl Sulfamoyl groups substituted with 2 hydrocarbon groups having 1 to 40 (preferably 1 to 20) carbon atoms or derivative groups thereof (for example, groups derived from carboxyl groups, sulfo groups, nitro groups, hydroxyl groups, halogens (preferably chlorine atoms), alkylsulfamoyl groups having 1 to 10 carbon atoms (preferably octylsulfamoyl groups), and the like, such as a group represented by the above chemical formula, N-undecylmethylsulfamoyl group, N-dodecylmethylsulfamoyl group, N-eicosylmethylsulfamoyl group, N-phenylmethylsulfamoyl group, N-diphenylsulfamoyl group, and the like, and the sulfamoyl groups corresponding to-SO-in the compounds represented by tables 1Z2 to 22Z2 and 27Z2 to 37Z2, and the like₂N(R^102Z2X)₂(wherein, R^102Z2XIs not a hydrogen atom, other than, and R^102Z2The same as defined above) and the like,

preferred examples thereof include sulfamoyl groups substituted with 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms or derivatives thereof, and compounds represented by tables 1Z2 to 22Z2 and tables 27Z2 to 37Z2, which correspond to-SO₂N(R^102Z2)₂And the like.

as-CON (R)^102Z2)₂Examples thereof include:

a carbamoyl group; n-methylcarbamoyl, N-ethylcarbamoyl, N-propylcarbamoyl, N-isopropylcarbamoyl, N-butylcarbamoyl, N-isobutylcarbamoyl, N-sec-butylcarbamoyl, N-tert-butylcarbamoyl, N-pentylcarbamoyl, N- (1-ethylpropyl) carbamoyl, N-hexylcarbamoyl, N- (2-ethyl) hexylcarbamoyl, N-heptylcarbamoyl, N-octylcarbamoyl, N-nonylcarbamoyl, N-decylcarbamoyl, N-undecylcarbamoyl, N-dodecylcarbamoyl, N-eicosylcarbamoyl, N-phenylcarbamoyl and the like, Carbamoyl groups substituted with a 1-40 (preferably 1-20) carbon hydrocarbon group or a derivative thereof (e.g., a derivative derived from a carboxyl group, sulfo group, nitro group, hydroxyl group, halogen (preferably chlorine atom), 1-10 carbon alkylsulfamoyl group (preferably octylsulfamoyl group)), such as the group represented by the above formula, and The compounds shown in tables 1Z2 to 22Z2 and tables 27Z2 to 37Z2 correspond to-CONH (R)^102Z2X) (wherein, R^102Z2XIs not a hydrogen atom, other than, and R^102Z2The same as defined above), etc.;

n, N-dimethylcarbamoyl group, N-ethylmethylcarbamoyl group, N-diethylcarbamoyl group, N-propylmethylcarbamoyl group, N-dipropylcarbamoyl group, N-isopropylmethylcarbamoyl group, N-diisopropylcarbamoyl group, N-tert-butylmethylcarbamoyl group, N-diisobutylcarbamoyl group, N-di-sec-butylcarbamoyl group, N-di-tert-butylcarbamoyl group, N-butylmethylcarbamoyl group, N-dibutylcarbamoyl group, N-butyloctylcarbamoyl group, N-dipentylcarbamoyl group, N-di (1-ethylpropyl) carbamoyl group, N-diethylcarbamoyl group, N-diisopropylcarbamoyl group, N-di (1-ethylpropyl) carbamoyl group, N-t-butylmethylcarbamoyl group, N-di-butylmethylcarbamoyl group, N-t-butylmethylcarbamoyl group, N-di (1-ethylpropyl) carbamoyl group, N-t-butylmethylcarbamoyl group, N-di-isobutylcarbamoyl group, N-di (s-butylmethylcarbamoyl group, N-di-butylmethylcarbamoyl group, N-di-N-butylcarbamoyl group, N, a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a carboxyl group, a sulfo group, an N, N-di (2-ethyl) hexylcarbamoyl group, an N, N-diheptylcarbamoyl group, an N, N-octylmethylcarbamoyl group, an N, N-dinonylcarbamoyl group, an N, N-decylmethylcarbamoyl group, an N, N-undecylmethylcarbamoyl group, an N, N-dodecylmethylcarbamoyl group, an N, N-eicosylmethylcarbamoyl group, an N, N-phenylmethylcarbamoyl group, an N, N-diphenylcarbamoyl group, etc., and a group represented by the above chemical formula, A carbamoyl group substituted with a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), and a compound represented by any one of tables 1Z2 to 22Z2, 27Z2 to 37Z2, wherein-CON (R) is the equivalent of ^102Z2X)₂(wherein, R^102Z2XIs not a hydrogen atom, other than, and R^102Z2The same as defined above) and the like,

preferred examples thereof include a carbamoyl group substituted with 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms or a derivative thereof and a compound represented by any one of tables 1Z2 to 22Z2 and 27Z2 to 37Z2 which corresponds to-CON (R)^102Z2)₂And the like.

as-N (R)^102Z2)₂Examples thereof include:

an amino group;

a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom)), such as an N-methylamino group, an N-ethylamino group, an N-propylamino group, an N-isopropylamino group, an N-butylamino group, an N-isobutylamino group, an N-sec-butylamino group, an N-tert-butylamino group, an N-pentylamino group, an N-hexylamino group, an N- (2-ethyl) hexylamino group, an N-heptylamino group, an N-octylamino group, an N-nonylamino group, an N-decylamino group, an N-undecylamino group, an N-dodecylamino group, an N-eicosylamino group, an N-phenylamino group, and the like, and a group represented by the above chemical formula, A group derived from an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably, an octylsulfamoyl group) or the like) and a compound shown in tables 1Z2 to 22Z2 and 27Z2 to 37Z2, wherein the compound corresponds to-NH (R ^102Z2X) (wherein, R^102Z2XIs not a hydrogen atom, other than, and R^102Z2The same as defined above), etc.;

n, N-dimethylamino group, N-ethylmethylamino group, N-diethylamino group, N-propylmethylamino group, N-dipropylamino group, N-isopropylmethylamino group, N-diisopropylamino group, N-tert-butylmethylamino group, N-diisobutylamino group, N-di-sec-butylamino group, N-di-tert-butylamino group, N-butylmethylamino group, N-dibutylamino group, N-dipentylamino group, N-bis (1-ethylpropyl) amino group, N-dihexylamino group, N-bis (2-ethyl) hexylamino group, N-diheptylamino group, N-dioctylamino group, N, amino groups substituted with 2 hydrocarbon groups having 1 to 40 (preferably 1 to 20) carbon atoms or derivative groups thereof (for example, groups derived from carboxyl, sulfo, nitro, hydroxyl, halogen (preferably chlorine atom), alkylsulfamoyl having 1 to 10 carbon atoms (preferably octylsulfamoyl) and the like), such as N-dinonylamino, N-decylmethylamino, N-undecylmethylamino, N-dodecylmethylamino, N-eicosylmethylamino, N-phenylmethylamino, N-diphenylamino and the like, and groups represented by the above chemical formulae, and amino groups represented by the above formulae, and tables 1Z2 to 22Z2 and 27Z 2 2 to the compounds shown in Table 37Z2 corresponding to-N (R)^102Z2X)₂(wherein, R^102Z2XIs not a hydrogen atom, other than, and R^102Z2The same as defined above) and the like,

preferred examples thereof include amino groups substituted with 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms or derivatives thereof and compounds shown in tables 1Z2 to 22Z2 and 27Z2 to 37Z2, which correspond to-N (R)^102Z2)₂And the like.

as-NHCO-R^102Z2Examples thereof include formylamino; acetylamino, propionylamino, butyrylamino, 2-dimethylpropionylamino, valerylamino, hexanoylamino, (2-ethyl) hexanoylamino, heptanoylamino, octanoylamino, nonanoylamino, decanoylamino, undecanoylamino, dodecanoylamino, heneicosanoylamino, benzoylamino and the like, carbonylamino (for example, in the case where the carbonylamino is an acylamino group, the carbon number is 1 to 40), carbonylamino to which a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20) or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) is bonded such as a group represented by the above formula) and carbonylamino groups having 1 to 40 carbon atoms among the compounds represented by tables 1Z2 to 22Z2 and tables 27Z2 to 37Z2 correspond to-NHCO- R ^102Z2And the like,

preferred examples thereof include carbonylamino groups to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded (in the case where the carbonylamino group is an alkanoylamino group, the carbon number is more preferably 1 to 10), and compounds represented by tables 1Z2 to 22Z2 and tables 27Z2 to 37Z2, which correspond to-NHCO-R^102Z2And the like.

as-NHCON (R)^102Z2)₂Examples thereof include the groups listed above and the compounds shown in tables 1Z2 to 22Z2 and 27Z2 to 37Z2 which correspond to-NHCON (R)^102Z2)₂And the like.

as-NHCOOR^102Z2Examples thereof include the groups listed above and those shown in tables 1Z2 to 22Z2 and tables 27Z2 to 37Z2Corresponding to-NHCOOR in the compound^102Z2And the like.

as-OCON (R)^102Z2)₂Examples thereof include those corresponding to-OCON (R) among the above-mentioned groups and the compounds shown in tables 1Z2 to 22Z2 and 27Z2 to 37Z2^102Z2)₂And the like.

The halogen atom is preferably a fluorine atom, a chlorine atom, a bromine atom, an iodine atom or the like.

as-SO₃M and-CO₂M in M is a hydrogen atom; the alkali metal atom such as lithium atom, sodium atom and potassium atom, preferably hydrogen atom, sodium atom and potassium atom.

The above-mentioned-CO-R^102Z2、-COO-R^102Z2、-OCO-R^102Z2、-COCO-R^102Z2、-O-R^102Z2、-SO₂-R^102Z2、-SO₂N(R^102Z2)₂、-CON(R^102Z2)₂、-N(R^102Z2)₂、-NHCO-R^102Z2、-NHCON(R^102Z2)₂、-NHCOOR^102Z2、-OCON(R^102Z2)₂The number of the substituents (first substituents) contained in (2) may be 1 or 2 or more, and 2 or more substituents may be the same or different and independent of each other.

Further, the first substituent may have another substituent (second substituent) bonded to the hydrocarbon group included in a part thereof. The second substituent may be selected from the same groups as the first substituent.

R^2Z2And R^3Z2、R^3Z2And R^4Z2And R^4Z2And R^5Z2The ring formed is fused with the benzene ring of the isoindoline skeleton of the compound represented by the formula (IZ 2). As R^2Z2And R^3Z2、R^3Z2And R^4Z2And R^4Z2And R^5Z2Examples of the condensed ring structure of the ring formed and the benzene ring include indene, naphthalene, biphenylene, indacene, acenaphthylene, fluorene, phenalene, phenanthrene, anthracene, fluoranthene, acephenanthrene, aceanthrylene, and benzo [9,10 ] ene]Phenanthrene, pyrene,

Hydrocarbon-based condensed ring structures such as N-methylphthalimide, N- (1-phenylethyl) phthalimide and butachlor, and partially reduced products thereof (for example, 9, 10-dihydroanthracene, 1,2,3, 4-tetrahydronaphthalene, etc.); indole, isoindole, indazole, quinoline, isoquinoline, phthalazine, quinoxaline, quinazoline, cinnoline, carbazole, carboline, phenanthridine, acridine, quinoline, quinoxaline, quinoline, and/or quinoline derivative,

Nitrogen-containing fused heterocycles such as pyridine, phenanthroline, and phenazine, and partial reductants thereof; oxygen-containing fused heterocycles such as 3-hydrobenzofuran-2-one and partial reductants thereof.

R^2Z2And R^3Z2、R^3Z2And R^4Z2And R^4Z2And R^5Z2In the case of forming a ring, the ring may have a substituent. Examples of the substituent include ^O1Z2、R^N1Z2、R^N2Z2、R^1Z2、R^2Z2、R^3Z2、R^4Z2、R^5Z2、R^101Z2And R^102Z2The hydrocarbon group may have the same substituent as the substituent. Preferred examples of the substituent include^O1Z2、R^N1Z2、R^N2Z2、R^1Z2、R^2Z2、R^3Z2、R^4Z2、R^5Z2、R^101Z2And R^102Z2The preferable examples of the substituents which the hydrocarbon group may have are the same.

R^3Z2And R^4Z2When forming a ring, as R^2Z2And R^5Z2Independently of one another, hydrogen atoms, amino groups and hydroxyl groups are preferred.

R^2Z2And R^3Z2When a ring is formed, R is preferably^4Z2And R^5Z2Does not form a ring, more preferably R^4Z2And R^5Z2Is a hydrogen atom.

R^4Z2And R^5Z2When a ring is formed, R is preferably^2Z2And R^3Z2Does not form a ring, more preferably R^2Z2And R^3Z2Is a hydrogen atom. R^1Z2Preferably a hydrogen atom. R^O1Z2The hydrocarbon group is preferably a hydrogen atom or a hydrocarbon group having 1 to 30 carbon atoms which may have a substituent, more preferably a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent, still more preferably a hydrogen atom or a hydrocarbon group having 1 to 15 carbon atoms which may have a substituent, particularly preferably a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent, particularly preferably a hydrogen atom or a hydrocarbon group having 1 to 5 carbon atoms which may have a substituent, and particularly preferably a hydrogen atom, a methyl group or an ethyl group.

R^N1Z2And R^N2Z2Preferably a hydrogen atom, -CO-R^102Z2、-COO-R^101Z2、-CON(R^102Z2)₂、-N(R^102Z2)₂、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, more preferably a hydrogen atom or a hydrocarbon group having 1 to 30 carbon atoms which may have a substituent, still more preferably a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent, particularly preferably a hydrogen atom or a hydrocarbon group having 1 to 15 carbon atoms which may have a substituent, particularly preferably a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent, particularly preferably a hydrogen atom or a hydrocarbon group having 1 to 6 carbon atoms which may have a substituent or a hydrocarbon group having 1 to 5 carbon atoms which may have a substituent, still more particularly preferably a hydrogen atom, a methyl group, an ethyl group or a phenyl group, and most preferably a hydrogen atom, a methyl group or an ethyl group. In addition, R ^N1Z2And R^N2Z2The groups may be the same or different, but preferably the same.

From the viewpoint of reducing the retardation value of the color filter formed from the colored composition, R is preferable^2Z2、R^3Z2、R^4Z2、R^5Z2At least one of which is-CO-R^102Z2、-COO-R^101Z2、-OCO-R^102Z2、-COCO-R^102Z2、-O-R^102Z2、-SO₂-R^101Z2、-SO₂N(R^102Z2)₂、-CON(R^102Z2)₂、-N(R^102Z2)₂、-NHCO-R^102Z2、-NHCO-N(R^102Z2)₂、-NHCOOR^102Z2、-OCON(R^102Z2)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent, more preferably a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a halogen atom, -N (R)^102Z2)₂A C1-20 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R^102Z2、-O-R^102Z2、-SO₃M or-CO₂M is more preferably a nitro group or a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, and still more preferably a nitro group or a tert-butyl group. Alternatively, R is preferred^2Z2And R^3Z2、R^3Z2And R^4Z2Or R^4Z2And R^5Z2Form a ring.

From the viewpoint of reducing the retardation value of the color filter formed from the colored composition, R is preferable^2Z2、R^3Z2、R^4Z2、R^5Z2At least one of which is an optionally substituted hydrocarbon group having 1 to 40 carbon atoms, a halogen atom, or-N (R)^102Z2)₂A C1-20 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R ^102Z2、-O-R^102Z2、-SO₃M or-CO₂M is more preferably a nitro group or a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, and further preferably a nitro group or a tert-butyl group. Among them, R is more preferable^3Z2Is nitro or tert-butyl, R^2Z2、R^4Z2And R^5Z2Is a hydrogen atom; or, R^2Z2、R^3Z2And R^5Z2Is a hydrogen atom, R^4Z2Is nitro or tert-butyl.

The compound IZ2 is preferably a compound represented by the formula (IZ2-B) (hereinafter, may be referred to as a compound IZ 2-B.). When the compound IZ2 is the compound IZ2-B, the phase difference value of the color filter formed from the colored composition containing the compound IZ2-B becomes smaller.

[ formula (IZ2-B) wherein R^CO11Z2And R^CO21Z2Independently of one another represent-O-R^O1Z2or-NR^N1Z2R^N2Z2，R^CO11Z2And R^CO21Z2At least one of which is-NR^N1Z2R^N2Z2。

R^N1Z2、R^N2Z2、R^1Z2、R^21Z2、R^31Z2、R^41Z2、R^51Z2Independently of one another, represents a hydrogen atom, -CO-R^102Z2、-COO-R^101Z2、-OCO-R^102Z2、-COCO-R^102Z2、-O-R^102Z2、-SO₂-R^101Z2、-SO₂N(R^102Z2)₂、-CON(R^102Z2)₂、-N(R^102Z2)₂、-NHCO-R^102Z2、-NHCO-N(R^102Z2)₂、-NHCOOR^102Z2、-OCON(R^102Z2)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group, R is^21Z2And R^31Z2、R^31Z2And R^41Z2And R^41Z2And R^51Z2Each of which may be bonded to each other to form a ring, R^21Z2、R^31Z2、R^41Z2And R^51Z2At least one of which is-CO-R^102Z2、-COO-R^101Z2、-OCO-R^102Z2、-COCO-R^102Z2、-O-R^102Z2、-SO₂-R^101Z2、-SO₂N(R^102Z2)₂、-CON(R^102Z2)₂、-N(R^102Z2)₂、-NHCO-R^102Z2、-NHCO-N(R^102Z2)₂、-NHCOOR^102Z2、-OCON(R^102Z2)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent, or R is^21Z2And R^31Z2、R^31Z2And R^41Z2And R^41Z2And R^51Z2At least one group of them is bonded to form a ring.

R^101Z2The alkyl group may have a substituent and has 1 to 40 carbon atoms, or a heterocyclic group may have a substituent. R^O1Z2And R^102Z2Independently represent a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group. M represents a hydrogen atom or an alkali metal atom.

R^O1Z2、R^N1Z2、R^N2Z2、R^101Z2、R^102Z2And when there are a plurality of M, they may be the same or different. The wavy line indicates the E-body or the Z-body.]

As R in the formula (IZ2-B)^CO11Z2、R^CO21Z2、R^21Z2、R^31Z2、R^41Z2And R^51Z2Examples thereof include the compounds represented by the formula (IZ2) and R^CO1Z2、R^CO2Z2、R^2Z2、R^3Z2、R^4Z2And R^5Z2The same example.

As preferred R in the formula (IZ2-B)^CO11Z2、R^CO21Z2、R^21Z2、R^31Z2、R^41Z2And R^51Z2Examples thereof include the compounds represented by the formula (IZ2) and R^CO1Z2、R^CO2Z2、R^2Z2、R^3Z2、R^4Z2And R^5Z2The same preferred examples as those of (1).

In the formula (IZ2-B), R is^1Z2Preferably a hydrogen atom.

In the formula (IZ2-B), R^O1Z2The hydrocarbon group is preferably a hydrogen atom or a hydrocarbon group having 1 to 30 carbon atoms which may have a substituent, more preferably a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent, still more preferably a hydrogen atom or a hydrocarbon group having 1 to 15 carbon atoms which may have a substituent, particularly preferably a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent, particularly preferably a hydrogen atom or a hydrocarbon group having 1 to 5 carbon atoms which may have a substituent, and particularly preferably a hydrogen atom, a methyl group or an ethyl group.

R^N1Z2And R^N2Z2Preferably a hydrogen atom, -CO-R^102Z2、-COO-R^101Z2、-CON(R^102Z2)₂、-N(R^102Z2)₂、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, more preferably a hydrogen atom or a hydrocarbon group having 1 to 30 carbon atoms which may have a substituent, still more preferably a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent, particularly preferably a hydrogen atom or a hydrocarbon group having 1 to 15 carbon atoms which may have a substituent, particularly preferably a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent, particularly preferably a hydrogen atom or a hydrocarbon group having 1 to 6 carbon atoms which may have a substituent or a hydrocarbon group having 1 to 5 carbon atoms which may have a substituent, still more particularly preferably a hydrogen atom, a methyl group, an ethyl group or a phenyl group, and most preferably a hydrogen atom, a methyl group or an ethyl group. In addition, R^N1Z2And R^N2Z2The groups may be the same or different, but preferably the same.

In the formula (IZ2-B), R is preferably R from the viewpoint of reducing the retardation value of the color filter formed of the colored composition^21Z2、R^31Z2、R^41Z2And R^51Z2At least one of which is an optionally substituted hydrocarbon group having 1 to 40 carbon atoms, a halogen atom, or-N (R)^102Z2)₂A C1-20 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R ^102Z2、-O-R^102Z2、-SO₃M or-CO₂M，

More preferably a nitro group or a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, and still more preferably a nitro group or a tert-butyl group. Among them, R is more preferable^31Z2Is nitro or tert-butyl, R^21Z2、R^41Z2And R^51Z2Is a hydrogen atom; or, R^21Z2、R^31Z2And R^51Z2Is a hydrogen atom, R^41Z2Is nitro or tert-butyl.

Specific examples of the compound IZ2 include, for example,

examples of the compound of formula (IaZ2) include compounds IaZ2-1 to IaZ2-494 and alkali metal salts thereof each having a substituent shown in table 1Z2, table 2Z2, table 3Z2, table 4Z2, table 5Z2, table 6Z2, table 27Z2, table 28Z2, table 29Z2 and table 30Z 2;

in formula (IbZ2), examples of compounds IbZ2-1 to IbZ2-840 or alkali metal salts thereof having a substituent shown in table 7Z2, table 8Z2, table 9Z2, table 10Z2, table 11Z2, table 12Z2, table 13Z2, table 14Z2, table 31Z2, table 32Z2, table 33Z2, table 34Z2, table 35Z2, table 36Z2, and table 37Z 2;

in formula (IcZ2), compounds IcZ2-1 to IcZ2-296 having a substituent shown in table 15Z2, table 16Z2, table 17Z2, table 18Z2, table 19Z2, table 20Z2, table 21Z2, and table 22Z2, or an alkali metal salt thereof are mentioned.

B^a1Z2B^a2Z2The partial structure represented by any one of formulae (BB1) to (BB60), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1), formula (BBO8), formula (BBO10), formula (BBD1) and formula (BBJ2) is shown. The formulae (BB1) to (BB60), (BBK2), (BBK3), (BBK4), (BBK14), (BBI1), (BBO8), (BBO10), (BBD1) and (BBJ2) are the same as B representing formula (IZ1-aa) ^a1Z1B^a2Z1The same structures as (BB1) to (BB60), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1), formula (BBO8), formula (BBO10), formula (BBD1) and formula (BBJ2) described above. B is^a1Z2And B^a2Z2Each represents a chemical bond, B^a1Z2B of formulae (BB1) to (BB60), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1), formula (BBO8), formula (BBO10), formula (BBD1) and formula (BBJ2)¹When a chemical bond of (A) is present, B^a2Z2To be B²The chemical bond of (a); b is^a1Z2B of formulae (BB1) to (BB60), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1), formula (BBO8), formula (BBO10), formula (BBD1) and formula (BBJ2)²When a chemical bond of (A) is present, B^a2Z2To be B¹The chemical bond of (1).

As B^a1Z2B^a2Z2Formula (BB1), formula (BB6), formula (BB8), formula (BB11), formula (BB14), formula (BB19), formula (BB37), formula (BB58), formula (BBJ2), formula (BBO8), and formula (BBO10) are preferable, and formula (BB1), formula (BB6), and formula (BB19) are more preferable.

Each symbol in table 1Z2, table 2Z2, table 3Z2, table 4Z2, table 5Z2, table 6Z2, table 7Z2, table 8Z2, table 9Z2, table 10Z2, table 11Z2, table 12Z2, table 13Z2, table 14Z2, table 15Z2, table 16Z2, table 17Z2, table 18Z2, table 19Z2, table 20Z2, table 21Z2, table 22Z2, table 27Z2, table 28Z2, table 29Z2, table 30Z2, table 31Z2, table 32Z2, table 33Z2, table 34Z2, table 35Z2, table 36Z2, and table 37Z2 represents a partial structure below. In the partial structure, "Me" represents a methyl group, "Et" represents an ethyl group, "Bu" represents a butyl group, "TBu" represents a tert-butyl group, "Hex" represents a hexyl group, "Oct" represents an octyl group, "2 EH" represents a 2-ethylhexyl group, "CHM" represents a cyclohexylmethyl group, "CH" represents a cyclohexyl group, "PH" represents a phenyl group, "BZ" represents a benzyl group, "NPR" represents a propyl group, "IPR" represents an isopropyl group, "IBu" represents an isobutyl group, and "EOE" represents a-CH group ₂CH₂OCH₂CH₃"ALL" represents allyl, "HYE" represents 2-hydroxyethyl, and "COM" represents-CO-CH₃And "COE" represents-COO-CH₂CH₃"CBA" means-CO₂H, "CBM" denotes-CONH₂"NH 2" means-NH₂Denotes a bond.

In the table, a partial structure represented by the following formula is represented by a symbol.

[ Table 1Z2]

TABLE 1Z2

	RO11Z2	RO12Z2	Ba1Z2Ba2Z2	R1Z2
					IaZ2-1	H	H	BB1	H
IaZ2-2	Me	Me	BB1	H
					IaZ2-3	Et	Et	BB1	H
IaZ2-4	Bu	Bu	BB1	H
					IaZ2-5	TBu	TBu	BB1	H
IaZ2-6	Hex	Hex	BB1	H
					IaZ2-7	Oct	Oct	BB1	H
IaZ2-8	2EH	2EH	BB1	H
					IaZ2-9	CHM	CHM	BB1	H
IaZ2-10	CH	CH	BB1	H
					IaZ2-11	PH	PH	BB1	H
IaZ2-12	BZ	BZ	BB1	H
					IaZ2-13	NPR	NPR	BB1	H
IaZ2-14	IPR	IPR	BB1	H
					IaZ2-15	IBu	IBu	BB1	H
IaZ2-16	EOE	EOE	BB1	H
					IaZ2-17	ALL	ALL	BB1	H
IaZ2-18	HYE	HYE	BB1	H
					IaZ2-19	H	H	BB6	H
IaZ2-20	Me	Me	BB6	H
					IaZ2-21	Et	Et	BB6	H
IaZ2-22	Bu	Bu	BB6	H
					IaZ2-23	TBu	TBu	BB6	H
IaZ2-24	Hex	Hex	BB6	H
					IaZ2-25	Oct	Oct	BB6	H
IaZ2-26	2EH	2EH	BB6	H
					IaZ2-27	CHM	CHM	BB6	H
IaZ2-28	CH	CH	BB6	H
					IaZ2-29	PH	PH	BB6	H
IaZ2-30	BZ	BZ	BB6	H
					IaZ2-31	NPR	NPR	BB6	H
IaZ2-32	IPR	IPR	BB6	H
					IaZ2-33	IBu	IBu	BB6	H
IaZ2-34	EOE	EOE	BB6	H
					IaZ2-35	ALL	ALL	BB6	H
IaZ2-36	HYE	HYE	BB6	H
					IaZ2-37	H	H	BB19	H
IaZ2-38	Me	Me	BB19	H
					IaZ2-39	Et	Et	BB19	H
IaZ2-40	Bu	Bu	BB19	H

[ Table 2Z2]

TABLE 2Z2

	RO11Z2	RO12Z2	Ba1Z2Ba2Z2	R1Z2
					IaZ2-41	TBu	TBu	BB19	H
IaZ2-42	Hex	Hex	BB19	H
					IaZ2-43	Oct	Oct	BB19	H
IaZ2-44	2EH	2EH	BB19	H
					IaZ2-45	CHM	CHM	BB19	H
IaZ2-46	CH	CH	BB19	H
					IaZ2-47	PH	PH	BB19	H
IaZ2-48	BZ	BZ	BB19	H
					IaZ2-49	NPR	NPR	BB19	H
IaZ2-50	IPR	IPR	BB19	H
					IaZ2-51	IBu	IBu	BB19	H
IaZ2-52	EOE	EOE	BB19	H
					IaZ2-53	ALL	ALL	BB19	H
IaZ2-54	HYE	HYE	BB19	H
					IaZ2-55	H	H	BB2	H
IaZ2-56	Me	Me	BB3	H
					IaZ2-57	Et	Et	BB4	H
IaZ2-58	Bu	Bu	BB5	H
					IaZ2-59	TBu	TBu	BB7	H
IaZ2-60	Hex	Hex	BB8	H
					IaZ2-61	Oct	Oct	BB9	H
IaZ2-62	2EH	2EH	BB10	H
					IaZ2-63	CHM	CHM	BB11	H
IaZ2-64	CH	CH	BB12	H
					IaZ2-65	PH	PH	BB13	H
IaZ2-66	BZ	BZ	BB14	H
					IaZ2-67	NPR	NPR	BB15	H
IaZ2-68	IPR	IPR	BB16	H
					IaZ2-69	IBu	IBu	BB17	H
IaZ2-70	EOE	EOE	BB18	H
					IaZ2-71	ALL	ALL	BB20	H
IaZ2-72	HYE	HYE	BB21	H
					IaZ2-73	H	H	BB22	H
IaZ2-74	Me	Me	BB23	H
					IaZ2-75	Et	Et	BB24	H
IaZ2-76	Bu	Bu	BB25	H
					IaZ2-77	TBu	TBu	BB26	H
IaZ2-78	Hex	Hex	BB27	H
					IaZ2-79	Oct	Oct	BB28	H
IaZ2-80	2EH	2EH	BB29	H

[ Table 3Z2]

TABLE 3Z2

	RO11Z2	RO12Z2	Ba1Z2Ba2Z2	R1Z2
					IaZ2-81	CHM	CHM	BB30	H
IaZ2-82	CH	CH	BB31	H
					IaZ2-83	PH	PH	BB32	H
IaZ2-84	BZ	BZ	BB33	H
					IaZ2-85	NPR	NPR	BB34	H
IaZ2-86	IPR	IPR	BB35	H
					IaZ2-87	IBu	IBu	BB36	H
IaZ2-88	EOE	EOE	BB37	H
					IaZ2-89	ALL	ALL	BB38	H
IaZ2-90	HYE	HYE	BB39	H
					IaZ2-91	H	H	BB40	H
IaZ2-92	Me	Me	BB41	H
					IaZ2-93	Et	Et	BB42	H
IaZ2-94	Bu	Bu	BB43	H
					IaZ2-95	TBu	TBu	BB44	H
IaZ2-96	Hex	Hex	BB45	H
					IaZ2-97	Oct	Oct	BB46	H
IaZ2-98	2EH	2EH	BB47	H
					IaZ2-99	CHM	CHM	BB48	H
IaZ2-100	CH	CH	BB49	H
					IaZ2-101	PH	PH	BB50	H
IaZ2-102	BZ	BZ	BB51	H
					IaZ2-103	NPR	NPR	BB52	H
IaZ2-104	IPR	IPR	BB53	H
					IaZ2-105	IBu	IBu	BB54	H
IaZ2-106	EOE	EOE	BB55	H
					IaZ2-107	ALL	ALL	BB56	H
IaZ2-108	HYE	HYE	BB57	H
					IaZ2-109	H	H	BB58	H
IaZ2-110	Me	Me	BB59	H
					IaZ2-111	Et	Et	BB60	H
IaZ2-112	H	HYE	BB1	H
					IaZ2-113	Me	H	BB1	H
IaZ2-114	Et	Me	BB1	H
					IaZ2-115	Bu	Et	BB1	H
IaZ2-116	TBu	Bu	BB1	H
					IaZ2-117	Hex	TBu	BB1	H
IaZ2-118	Oct	Hex	BB1	H
					IaZ2-119	2EH	Oct	BB1	H
IaZ2-120	CHM	2EH	BB1	H

[ Table 4Z2]

TABLE 4Z2

	RO11Z2	RO12Z2	Ba1Z2Ba2Z2	R1Z2
					IaZ2-121	CH	CHM	BB1	H
IaZ2-122	PH	CH	BB1	H
					IaZ2-123	BZ	PH	BB1	H
IaZ2-124	NPR	BZ	BB1	H
					IaZ2-125	IPR	NPR	BB1	H
IaZ2-126	IBu	IPR	BB1	H
					IaZ2-127	EOE	IBu	BB1	H
IaZ2-128	ALL	EOE	BB1	H
					IaZ2-129	HYE	ALL	BB1	H
IaZ2-130	H	BZ	BB6	H
					IaZ2-131	Me	NPR	BB6	H
IaZ2-132	Et	Me	BB6	H
					IaZ2-133	Bu	IBu	BB6	H
IaZ2-134	TBu	EOE	BB6	H
					IaZ2-135	Hex	ALL	BB6	H
IaZ2-136	Oct	HYE	BB6	H
					IaZ2-137	2EH	H	BB6	H
IaZ2-138	CHM	IPR	BB6	H
					IaZ2-139	CH	Et	BB6	H
IaZ2-140	PH	Bu	BB6	H
					IaZ2-141	BZ	TBu	BB6	H
IaZ2-142	NPR	Hex	BB6	H
					IaZ2-143	IPR	Oct	BB6	H
IaZ2-144	IBu	2EH	BB6	H
					IaZ2-145	EOE	CHM	BB6	H
IaZ2-146	ALL	CH	BB6	H
					IaZ2-147	HYE	PH	BB6	H
IaZ2-148	H	Oct	BB19	H
					IaZ2-149	Me	Et	BB19	H
IaZ2-150	Et	CHM	BB19	H
					IaZ2-151	Bu	CH	BB19	H
IaZ2-152	TBu	PH	BB19	H
					IaZ2-153	Hex	BZ	BB19	H
IaZ2-154	Oct	2EH	BB19	H
					IaZ2-155	2EH	IPR	BB19	H
IaZ2-156	CHM	IBu	BB19	H
					IaZ2-157	CH	EOE	BB19	H
IaZ2-158	PH	ALL	BB19	H
					IaZ2-159	BZ	HYE	BB19	H
IaZ2-160	NPR	H	BB19	H

[ Table 5Z2]

TABLE 5Z2

	RO11Z2	RO12Z2	Ba1Z2Ba2Z2	R1Z2
					IaZ2-161	IPR	Me	BB19	H
IaZ2-162	IBu	NPR	BB19	H
					IaZ2-163	EOE	Bu	BB19	H
IaZ2-164	ALL	TBu	BB19	H
					IaZ2-165	HYE	Hex	BB19	H
IaZ2-166	H	EOE	BB2	H
					IaZ2-167	Me	ALL	BB3	H
IaZ2-168	Et	HYE	BB4	H
					IaZ2-169	Bu	H	BB5	H
IaZ2-170	TBu	Me	BB7	H
					IaZ2-171	Hex	Et	BB8	H
IaZ2-172	Oct	Bu	BB9	H
					IaZ2-173	2EH	TBu	BB10	H
IaZ2-174	CHM	Hex	BB11	H
					IaZ2-175	CH	Oct	BB12	H
IaZ2-176	PH	2EH	BB13	H
					IaZ2-177	BZ	CHM	BB14	H
IaZ2-178	NPR	CH	BB15	H
					IaZ2-179	IPR	PH	BB16	H
IaZ2-180	IBu	BZ	BB17	H
					IaZ2-181	EOE	NPR	BB18	H
IaZ2-182	ALL	IPR	BB20	H
					IaZ2-183	HYE	IBu	BB21	H
IaZ2-184	H	TBu	BB22	H
					IaZ2-185	Me	Hex	BB23	H
IaZ2-186	Et	Oct	BB24	H
					IaZ2-187	Bu	2EH	BB25	H
IaZ2-188	TBu	CHM	BB26	H
					IaZ2-189	Hex	CH	BB27	H
IaZ2-190	Oct	PH	BB28	H
					IaZ2-191	2EH	BZ	BB29	H
IaZ2-192	CHM	NPR	BB30	H
					IaZ2-193	CH	IPR	BB31	H
IaZ2-194	PH	IBu	BB32	H
					IaZ2-195	BZ	EOE	BB33	H
IaZ2-196	NPR	ALL	BB34	H
					IaZ2-197	IPR	HYE	BB35	H
IaZ2-198	IBu	H	BB36	H
					IaZ2-199	EOE	Me	BB37	H
IaZ2-200	ALL	Et	BB38	H

[ Table 6Z2]

TABLE 6Z2

	RO11Z2	RO12Z2	Ba1Z2Ba2Z2	R1Z2
					IaZ2-201	HYE	Bu	BB39	H
IaZ2-202	H	CHM	BB40	H
					IaZ2-203	Me	CH	BB41	H
IaZ2-204	Et	PH	BB42	H
					IaZ2-205	Bu	BZ	BB43	H
IaZ2-206	TBu	NPR	BB44	H
					IaZ2-207	Hex	IPR	BB45	H
IaZ2-208	Oct	IBu	BB46	H
					IaZ2-209	2EH	EOE	BB47	H
IaZ2-210	CHM	ALL	BB48	H
					IaZ2-211	CH	HYE	BB49	H
IaZ2-212	PH	H	BB50	H
					IaZ2-213	BZ	Me	BB51	H
IaZ2-214	NPR	Et	BB52	H
					IaZ2-215	IPR	Bu	BB53	H
IaZ2-216	IBu	TBu	BB54	H
					IaZ2-217	EOE	Hex	BB55	H
IaZ2-218	ALL	Oct	BB56	H
					IaZ2-219	HYE	2EH	BB57	H
IaZ2-220	H	Me	BB58	H
					IaZ2-221	Me	Et	BB59	H
IaZ2-222	Et	Bu	BB60	H
					IaZ2-223	Me	Me	BB14	H

[ Table 7Z2]

TABLE 7Z2

RN11Z2

RN21Z2

RN12Z2

RN22Z2

Ba1Z2Ba2Z2

R1Z2

IbZ2-1

H

H

H

H

BB1

H

IbZ2-2

Me

H

Me

H

BB1

H

IbZ2-3

Et

H

Et

H

BB1

H

IbZ2-4

PH

H

PH

H

BB1

H

IbZ2-5

Bu

H

Bu

H

BB1

H

IbZ2-6

TBu

H

TBu

H

BB1

H

IbZ2-7

Hex

H

Hex

H

BB1

H

IbZ2-8

Oct

H

Oct

H

BB1

H

IbZ2-9

2EH

H

2EH

H

BB1

H

IbZ2-10

CHM

H

CHM

H

BB1

H

IbZ2-11

CH

H

CH

H

BB1

H

IbZ2-12

BZ

H

BZ

H

BB1

H

IbZ2-13

NPR

H

NPR

H

BB1

H

IbZ2-14

IPR

H

IPR

H

BB1

H

IbZ2-15

IBu

H

IBu

H

BB1

H

IbZ2-16

EOE

H

EOE

H

BB1

H

IbZ2-17

ALL

H

ALL

H

BB1

H

IbZ2-18

NH2

H

NH2

H

BB1

H

IbZ2-19

CBM

H

CBM

H

BB1

H

IbZ2-20

COM

H

COM

H

BB1

H

IbZ2-21

COE

H

COE

H

BB1

H

IbZ2-22

CBA

H

CBA

H

BB1

H

IbZ2-23

HYE

H

HYE

H

BB1

H

IbZ2-24

Me

Me

Me

Me

BB1

H

IbZ2-25

Et

Et

Et

Et

BB1

H

IbZ2-26

PH

PH

PH

PH

BB1

H

IbZ2-27

Bu

Me

Bu

Me

BB1

H

IbZ2-28

TBu

Et

TBu

Et

BB1

H

IbZ2-29

Hex

NPR

Hex

NPR

BB1

H

IbZ2-30

Oct

IPR

Oct

IPR

BB1

H

IbZ2-31

2EH

HYE

2EH

HYE

BB1

H

IbZ2-32

CHM

ALL

CHM

ALL

BB1

H

IbZ2-33

CH

COM

CH

COM

BB1

H

IbZ2-34

BZ

Me

BZ

Me

BB1

H

IbZ2-35

NPR

Et

NPR

Et

BB1

H

IbZ2-36

IPR

NPR

IPR

NPR

BB1

H

IbZ2-37

IBu

IPR

IBu

IPR

BB1

H

IbZ2-38

EOE

HYE

EOE

HYE

BB1

H

IbZ2-39

ALL

ALL

ALL

ALL

BB1

H

IbZ2-40

NH2

COM

NH2

COM

BB1

H

[ Table 8Z2]

TABLE 8Z2

RN11Z2

RN21Z2

RN12Z2

RN22Z2

Ba1Z2Ba2Z2

R1Z2

IbZ2-41

CBM

Me

CBM

Me

BB1

H

IbZ2-42

COM

Et

COM

Et

BB1

H

IbZ2-43

COE

NPR

COE

NPR

BB1

H

IbZ2-44

CBA

IPR

CBA

IPR

BB1

H

IbZ2-45

HYE

HYE

HYE

HYE

BB1

H

IbZ2-46

Bu

Bu

Bu

Bu

BB1

H

IbZ2-47

TBu

TBu

TBu

TBu

BB1

H

IbZ2-48

Hex

Hex

Hex

Hex

BB1

H

IbZ2-49

Oct

Oct

Oct

Oct

BB1

H

IbZ2-50

2EH

2EH

2EH

2EH

BB1

H

IbZ2-51

CHM

CHM

CHM

CHM

BB1

H

IbZ2-52

CH

CH

CH

CH

BB1

H

IbZ2-53

BZ

BZ

BZ

BZ

BB1

H

IbZ2-54

NPR

NPR

NPR

NPR

BB1

H

IbZ2-55

IPR

IPR

IPR

IPR

BB1

H

IbZ2-56

IBu

IBu

IBu

IBu

BB1

H

IbZ2-57

EOE

EOE

EOE

EOE

BB1

H

IbZ2-58

NH2

NH2

NH2

NH2

BB1

H

IbZ2-59

CBM

CBM

CBM

CBM

BB1

H

IbZ2-60

COM

COM

COM

COM

BB1

H

IbZ2-61

COE

COE

COE

COE

BB1

H

IbZ2-62

CBA

CBA

CBA

CBA

BB1

H

IbZ2-63

H

H

H

H

BB6

H

IbZ2-64

Me

H

Me

H

BB6

H

IbZ2-65

Et

H

Et

H

BB6

H

IbZ2-66

PH

H

PH

H

BB6

H

IbZ2-67

Bu

H

Bu

H

BB6

H

IbZ2-68

TBu

H

TBu

H

BB6

H

IbZ2-69

Hex

H

Hex

H

BB6

H

IbZ2-70

Oct

H

Oct

H

BB6

H

IbZ2-71

2EH

H

2EH

H

BB6

H

IbZ2-72

CHM

H

CHM

H

BB6

H

IbZ2-73

CH

H

CH

H

BB6

H

IbZ2-74

BZ

H

BZ

H

BB6

H

IbZ2-75

NPR

H

NPR

H

BB6

H

IbZ2-76

IPR

H

IPR

H

BB6

H

IbZ2-77

IBu

H

IBu

H

BB6

H

IbZ2-78

EOE

H

EOE

H

BB6

H

IbZ2-79

ALL

H

ALL

H

BB6

H

IbZ2-80

NH2

H

NH2

H

BB6

H

[ Table 9Z2]

TABLE 9Z2

RN11Z2

RN21Z2

RN12Z2

RN22Z2

Ba1Z2Ba2Z2

R1Z2

IbZ2-81

CBM

H

CBM

H

BB6

H

IbZ2-82

COM

H

COM

H

BB6

H

IbZ2-83

COE

H

COE

H

BB6

H

IbZ2-84

CBA

H

CBA

H

BB6

H

IbZ2-85

HYE

H

HYE

H

BB6

H

IbZ2-86

Me

Me

Me

Me

BB6

H

IbZ2-87

Et

Et

Et

Et

BB6

H

IbZ2-88

PH

PH

PH

PH

BB6

H

IbZ2-89

Bu

Me

Bu

Me

BB6

H

IbZ2-90

TBu

Et

TBu

Et

BB6

H

IbZ2-91

Hex

NPR

Hex

NPR

BB6

H

IbZ2-92

Oct

IPR

Oct

IPR

BB6

H

IbZ2-93

2EH

HYE

2EH

HYE

BB6

H

IbZ2-94

CHM

ALL

CHM

ALL

BB6

H

IbZ2-95

CH

COM

CH

COM

BB6

H

IbZ2-96

BZ

Me

BZ

Me

BB6

H

IbZ2-97

NPR

Et

NPR

Et

BB6

H

IbZ2-98

IPR

NPR

IPR

NPR

BB6

H

IbZ2-99

IBu

IPR

IBu

IPR

BB6

H

IbZ2-100

EOE

HYE

EOE

HYE

BB6

H

IbZ2-101

ALL

ALL

ALL

ALL

BB6

H

IbZ2-102

NH2

COM

NH2

COM

BB6

H

IbZ2-103

CBM

Me

CBM

Me

BB6

H

IbZ2-104

COM

Et

COM

Et

BB6

H

IbZ2-105

COE

NPR

COE

NPR

BB6

H

IbZ2-106

CBA

IPR

CBA

IPR

BB6

H

IbZ2-107

HYE

HYE

HYE

HYE

BB6

H

IbZ2-108

Bu

Bu

Bu

Bu

BB6

H

IbZ2-109

TBu

TBu

TBu

TBu

BB6

H

IbZ2-110

Hex

Hex

Hex

Hex

BB6

H

IbZ2-111

Oct

Oct

Oct

Oct

BB6

H

IbZ2-112

2EH

2EH

2EH

2EH

BB6

H

IbZ2-113

CHM

CHM

CHM

CHM

BB6

H

IbZ2-114

CH

CH

CH

CH

BB6

H

IbZ2-115

BZ

BZ

BZ

BZ

BB6

H

IbZ2-116

NPR

NPR

NPR

NPR

BB6

H

IbZ2-117

IPR

IPR

IPR

IPR

BB6

H

IbZ2-118

IBu

IBu

IBu

IBu

BB6

H

IbZ2-119

EOE

EOE

EOE

EOE

BB6

H

IbZ2-120

NH2

NH2

NH2

NH2

BB6

H

[ Table 10Z2]

TABLE 10Z2

RN11Z2

RN21Z2

RN12Z2

RN22Z2

Ba1Z2Ba2Z2

R1Z2

IbZ2-121

CBM

CBM

CBM

CBM

BB6

H

IbZ2-122

COM

COM

COM

COM

BB6

H

IbZ2-123

COE

COE

COE

COE

BB6

H

IbZ2-124

CBA

CBA

CBA

CBA

BB6

H

IbZ2-125

H

H

H

H

BB19

H

IbZ2-126

Me

H

Me

H

BB19

H

IbZ2-127

Et

H

Et

H

BB19

H

IbZ2-128

PH

H

PH

H

BB19

H

IbZ2-129

Bu

H

Bu

H

BB19

H

IbZ2-130

TBu

H

TBu

H

BB19

H

IbZ2-131

Hex

H

Hex

H

BB19

H

IbZ2-132

Oct

H

Oct

H

BB19

H

IbZ2-133

2EH

H

2EH

H

BB19

H

IbZ2-134

CHM

H

CHM

H

BB19

H

IbZ2-135

CH

H

CH

H

BB19

H

IbZ2-136

BZ

H

BZ

H

BB19

H

IbZ2-137

NPR

H

NPR

H

BB19

H

IbZ2-138

IPR

H

IPR

H

BB19

H

IbZ2-139

IBu

H

IBu

H

BB19

H

IbZ2-140

EOE

H

EOE

H

BB19

H

IbZ2-141

ALL

H

ALL

H

BB19

H

IbZ2-142

NH2

H

NH2

H

BB19

H

IbZ2-143

CBM

H

CBM

H

BB19

H

IbZ2-144

COM

H

COM

H

BB19

H

IbZ2-145

COE

H

COE

H

BB19

H

IbZ2-146

CBA

H

CBA

H

BB19

H

IbZ2-147

HYE

H

HYE

H

BB19

H

IbZ2-148

Me

Me

Me

Me

BB19

H

IbZ2-149

Et

Et

Et

Et

BB19

H

IbZ2-150

PH

PH

PH

PH

BB19

H

IbZ2-151

Bu

Me

Bu

Me

BB19

H

IbZ2-152

TBu

Et

TBu

Et

BB19

H

IbZ2-153

Hex

NPR

Hex

NPR

BB19

H

IbZ2-154

Oct

IPR

Oct

IPR

BB19

H

IbZ2-155

2EH

HYE

2EH

HYE

BB19

H

IbZ2-156

CHM

ALL

CHM

ALL

BB19

H

IbZ2-157

CH

COM

CH

COM

BB19

H

IbZ2-158

BZ

Me

BZ

Me

BB19

H

IbZ2-159

NPR

Et

NPR

Et

BB19

H

IbZ2-160

IPR

NPR

IPR

NPR

BB19

H

[ Table 11Z2]

TABLE 11Z2

RN11Z2

RN21Z2

RN12Z2

RN22Z2

Ba1Z2Ba2Z2

R1Z2

IbZ2-161

IBu

IPR

IBu

IPR

BB19

H

IbZ2-162

EOE

HYE

EOE

HYE

BB19

H

IbZ2-163

ALL

ALL

ALL

ALL

BB19

H

IbZ2-164

NH2

COM

NH2

COM

BB19

H

IbZ2-165

CBM

Me

CBM

Me

BB19

H

IbZ2-166

COM

Et

COM

Et

BB19

H

IbZ2-167

COE

NPR

COE

NPR

BB19

H

IbZ2-168

CBA

IPR

CBA

IPR

BB19

H

IbZ2-169

HYE

HYE

HYE

HYE

BB19

H

IbZ2-170

Bu

Bu

Bu

Bu

BB19

H

IbZ2-171

TBu

TBu

TBu

TBu

BB19

H

IbZ2-172

Hex

Hex

Hex

Hex

BB19

H

IbZ2-173

Oct

Oct

Oct

Oct

BB19

H

IbZ2-174

2EH

2EH

2EH

2EH

BB19

H

IbZ2-175

CHM

CHM

CHM

CHM

BB19

H

IbZ2-176

CH

CH

CH

CH

BB19

H

IbZ2-177

BZ

BZ

BZ

BZ

BB19

H

IbZ2-178

NPR

NPR

NPR

NPR

BB19

H

IbZ2-179

IPR

IPR

IPR

IPR

BB19

H

IbZ2-180

IBu

IBu

IBu

IBu

BB19

H

IbZ2-181

EOE

EOE

EOE

EOE

BB19

H

IbZ2-182

NH2

NH2

NH2

NH2

BB19

H

IbZ2-183

CBM

CBM

CBM

CBM

BB19

H

IbZ2-184

COM

COM

COM

COM

BB19

H

IbZ2-185

COE

COE

COE

COE

BB19

H

IbZ2-186

CBA

CBA

CBA

CBA

BB19

H

IbZ2-187

H

H

H

H

BB2

H

IbZ2-188

HYE

HYE

HYE

HYE

BB3

H

IbZ2-189

BZ

BZ

BZ

BZ

BB4

H

IbZ2-190

Me

H

Me

H

BB5

H

IbZ2-191

CBA

IPR

CBA

IPR

BB7

H

IbZ2-192

NPR

NPR

NPR

NPR

BB8

H

IbZ2-193

Et

H

Et

H

BB9

H

IbZ2-194

COE

NPR

COE

NPR

BB10

H

IbZ2-195

CH

CH

CH

CH

BB11

H

IbZ2-196

PH

H

PH

H

BB12

H

IbZ2-197

COM

Et

COM

Et

BB13

H

IbZ2-198

IPR

IPR

IPR

IPR

BB14

H

IbZ2-199

Bu

H

Bu

H

BB15

H

IbZ2-200

CBM

Me

CBM

Me

BB16

H

[ Table 12Z2]

TABLE 12Z2

RN11Z2

RN21Z2

RN12Z2

RN22Z2

Ba1Z2Ba2Z2

R1Z2

IbZ2-201

IBu

IBu

IBu

IBu

BB17

H

IbZ2-202

TBu

H

TBu

H

BB18

H

IbZ2-203

NH2

COM

NH2

COM

BB20

H

IbZ2-204

CHM

CHM

CHM

CHM

BB21

H

IbZ2-205

Hex

H

Hex

H

BB22

H

IbZ2-206

ALL

ALL

ALL

ALL

BB23

H

IbZ2-207

EOE

EOE

EOE

EOE

BB24

H

IbZ2-208

Oct

H

Oct

H

BB25

H

IbZ2-209

EOE

HYE

EOE

HYE

BB26

H

IbZ2-210

2EH

2EH

2EH

2EH

BB27

H

IbZ2-211

2EH

H

2EH

H

BB28

H

IbZ2-212

IBu

IPR

IBu

IPR

BB29

H

IbZ2-213

NH2

NH2

NH2

NH2

BB30

H

IbZ2-214

CHM

H

CHM

H

BB31

H

IbZ2-215

IPR

NPR

IPR

NPR

BB32

H

IbZ2-216

Oct

Oct

Oct

Oct

BB33

H

IbZ2-217

CH

H

CH

H

BB34

H

IbZ2-218

NPR

Et

NPR

Et

BB35

H

IbZ2-219

CBM

CBM

CBM

CBM

BB36

H

IbZ2-220

BZ

H

BZ

H

BB37

H

IbZ2-221

BZ

Me

BZ

Me

BB38

H

IbZ2-222

Hex

Hex

Hex

Hex

BB39

H

IbZ2-223

HYE

H

HYE

H

BB40

H

IbZ2-224

CH

COM

CH

COM

BB41

H

IbZ2-225

COM

COM

COM

COM

BB42

H

IbZ2-226

NPR

H

NPR

H

BB43

H

IbZ2-227

2EH

HYE

2EH

HYE

BB44

H

IbZ2-228

IPR

H

IPR

H

BB45

H

IbZ2-229

CHM

ALL

CHM

ALL

BB46

H

IbZ2-230

COE

COE

COE

COE

BB47

H

IbZ2-231

IBu

H

IBu

H

BB48

H

IbZ2-232

Hex

NPR

Hex

NPR

BB49

H

IbZ2-233

EOE

H

EOE

H

BB50

H

IbZ2-234

Oct

IPR

Oct

IPR

BB51

H

IbZ2-235

TBu

TBu

TBu

TBu

BB52

H

IbZ2-236

ALL

H

ALL

H

BB53

H

IbZ2-237

TBu

Et

TBu

Et

BB54

H

IbZ2-238

NH2

H

NH2

H

BB55

H

IbZ2-239

Bu

Bu

Bu

Bu

BB56

H

IbZ2-240

CBM

H

CBM

H

BB57

H

[ Table 13Z2]

TABLE 13Z2

RN11Z2

RN21Z2

RN12Z2

RN22Z2

Ba1Z2Ba2Z2

R1Z2

IbZ2-241

PH

PH

PH

PH

BB58

H

IbZ2-242

COM

H

COM

H

BB59

H

IbZ2-243

Bu

Me

Bu

Me

BB60

H

IbZ2-244

CBA

CBA

CBA

CBA

BB2

H

IbZ2-245

COE

H

COE

H

BB3

H

IbZ2-246

Me

Me

Me

Me

BB4

H

IbZ2-247

CBA

H

CBA

H

BB5

H

IbZ2-248

Et

Et

Et

Et

BB7

H

IbZ2-249

H

H

NPR

Et

BB1

H

IbZ2-250

HYE

HYE

CBM

CBM

BB2

H

IbZ2-251

BZ

BZ

BZ

H

BB3

H

IbZ2-252

Me

H

BZ

Me

BB4

H

IbZ2-253

CBA

IPR

Hex

Hex

BB5

H

IbZ2-254

NPR

NPR

HYE

H

BB6

H

IbZ2-255

Et

H

CH

COM

BB7

H

IbZ2-256

COE

NPR

COM

COM

BB8

H

IbZ2-257

CH

CH

NPR

H

BB9

H

IbZ2-258

PH

H

2EH

HYE

BB10

H

IbZ2-259

COM

Et

IPR

H

BB11

H

IbZ2-260

IPR

IPR

CHM

ALL

BB12

H

IbZ2-261

Bu

H

COE

COE

BB13

H

IbZ2-262

CBM

Me

IBu

H

BB14

H

IbZ2-263

IBu

IBu

Hex

NPR

BB15

H

IbZ2-264

TBu

H

EOE

H

BB16

H

IbZ2-265

NH2

COM

Oct

IPR

BB17

H

IbZ2-266

CHM

CHM

TBu

TBu

BB18

H

IbZ2-267

Hex

H

ALL

H

BB19

H

IbZ2-268

ALL

ALL

TBu

Et

BB20

H

IbZ2-269

EOE

EOE

NH2

H

BB21

H

IbZ2-270

Oct

H

Bu

Bu

BB22

H

IbZ2-271

EOE

HYE

CBM

H

BB23

H

IbZ2-272

2EH

2EH

PH

PH

BB24

H

IbZ2-273

2EH

H

COM

H

BB25

H

IbZ2-274

IBu

IPR

Bu

Me

BB26

H

IbZ2-275

NH2

NH2

CBA

CBA

BB27

H

IbZ2-276

CHM

H

COE

H

BB28

H

IbZ2-277

IPR

NPR

Me

Me

BB29

H

IbZ2-278

Oct

Oct

CBA

H

BB30

H

IbZ2-279

CH

H

Et

Et

BB31

H

IbZ2-280

NPR

Et

H

H

BB32

H

[ Table 14Z2]

TABLE 14Z2

RN11Z2

RN21Z2

RN12Z2

RN22Z2

Ba1Z2Ba2Z2

R1Z2

IbZ2-281

CBM

CBM

HYE

HYE

BB33

H

IbZ2-282

BZ

H

BZ

BZ

BB34

H

IbZ2-283

BZ

Me

Me

H

BB35

H

IbZ2-284

Hex

Hex

CBA

IPR

BB36

H

IbZ2-285

HYE

H

NPR

NPR

BB37

H

IbZ2-286

CH

COM

Et

H

BB38

H

IbZ2-287

COM

COM

COE

NPR

BB39

H

IbZ2-288

NPR

H

CH

CH

BB40

H

IbZ2-289

2EH

HYE

PH

H

BB41

H

IbZ2-290

IPR

H

COM

Et

BB42

H

IbZ2-291

CHM

ALL

IPR

IPR

BB43

H

IbZ2-292

COE

COE

Bu

H

BB44

H

IbZ2-293

IBu

H

CBM

Me

BB45

H

IbZ2-294

Hex

NPR

IBu

IBu

BB46

H

IbZ2-295

EOE

H

TBu

H

BB47

H

IbZ2-296

Oct

IPR

NH2

COM

BB48

H

IbZ2-297

TBu

TBu

CHM

CHM

BB49

H

IbZ2-298

ALL

H

Hex

H

BB50

H

IbZ2-299

TBu

Et

ALL

ALL

BB51

H

IbZ2-300

NH2

H

EOE

EOE

BB52

H

IbZ2-301

Bu

Bu

Oct

H

BB53

H

IbZ2-302

CBM

H

EOE

HYE

BB54

H

IbZ2-303

PH

PH

2EH

2EH

BB55

H

IbZ2-304

COM

H

2EH

H

BB56

H

IbZ2-305

Bu

Me

IBu

IPR

BB57

H

IbZ2-306

CBA

CBA

NH2

NH2

BB58

H

IbZ2-307

COE

H

CHM

H

BB59

H

IbZ2-308

Me

Me

IPR

NPR

BB60

H

IbZ2-309

CBA

H

Oct

Oct

BB1

H

IbZ2-310

Et

Et

CH

H

BB19

H

IbZ2-311

NA1

H

NA1

H

BB1

H

IbZ2-312

NA1

H

NA1

H

BB19

H

IbZ2-313

NA2

H

NA2

H

BB1

H

IbZ2-314

NA2

H

NA2

H

BB19

H

IbZ2-315

NA1

H

NA1

H

BBO8

H

IbZ2-316

NA1

H

NA1

H

BB8

H

[ Table 15Z2]

TABLE 15Z2

	RO13Z2	RN13Z2	RN23Z2	Ba1Z2Ba2Z2	R1Z2
						IcZ2-1	H	H	H	BB1	H
IcZ2-2	H	Me	H	BB1	H
						IcZ2-3	H	Et	H	BB1	H
IcZ2-4	H	PH	H	BB1	H
						IcZ2-5	H	NPR	H	BB1	H
IcZ2-6	H	NH2	H	BB1	H
						IcZ2-7	H	CBM	H	BB1	H
IcZ2-8	H	COM	H	BB1	H
						IcZ2-9	H	HYE	H	BB1	H
IcZ2-10	H	Me	Me	BB1	H
						IcZ2-11	H	Et	Et	BB1	H
IcZ2-12	H	PH	PH	BB1	H
						IcZ2-13	H	HYE	HYE	BB1	H
IcZ2-14	Me	H	H	BB1	H
						IcZ2-15	Me	Me	H	BB1	H
IcZ2-16	Me	Et	H	BB1	H
						IcZ2-17	Me	PH	H	BB1	H
IcZ2-18	Me	NPR	H	BB1	H
						IcZ2-19	Me	NH2	H	BB1	H
IcZ2-20	Me	CBM	H	BB1	H
						IcZ2-21	Me	COM	H	BB1	H
IcZ2-22	Me	HYE	H	BB1	H
						IcZ2-23	Me	Me	Me	BB1	H
IcZ2-24	Me	Et	Et	BB1	H
						IcZ2-25	Me	PH	PH	BB1	H
IcZ2-26	Me	HYE	HYE	BB1	H
						IcZ2-27	Et	H	H	BB1	H
IcZ2-28	Et	Me	H	BB1	H
						IcZ2-29	Et	Et	H	BB1	H
IcZ2-30	Et	PH	H	BB1	H
						IcZ2-31	Et	NPR	H	BB1	H
IcZ2-32	Et	NH2	H	BB1	H
						IcZ2-33	Et	CBM	H	BB1	H
IcZ2-34	Et	COM	H	BB1	H
						IcZ2-35	Et	HYE	H	BB1	H
IcZ2-36	Et	Me	Me	BB1	H
						IcZ2-37	Et	Et	Et	BB1	H
IcZ2-38	Et	PH	PH	BB1	H
						IcZ2-39	Et	HYE	HYE	BB1	H
IcZ2-40	PH	H	H	BB1	H

[ Table 16Z2]

TABLE 16Z2

	RO13Z2	RN13Z2	RN23Z2	Ba1Z2Ba2Z2	R1Z2
						IcZ2-41	PH	Me	H	BB1	H
IcZ2-42	PH	Et	H	BB1	H
						IcZ2-43	PH	PH	H	BB1	H
IcZ2-44	PH	NPR	H	BB1	H
						IcZ2-45	PH	NH2	H	BB1	H
IcZ2-46	PH	CBM	H	BB1	H
						IcZ2-47	PH	COM	H	BB1	H
IcZ2-48	PH	HYE	H	BB1	H
						IcZ2-49	PH	Me	Me	BB1	H
IcZ2-50	PH	Et	Et	BB1	H
						IcZ2-51	PH	PH	PH	BB1	H
IcZ2-52	PH	HYE	HYE	BB1	H
						IcZ2-53	NPR	H	H	BB1	H
IcZ2-54	NPR	Me	H	BB1	H
						IcZ2-55	NPR	Et	H	BB1	H
IcZ2-56	NPR	PH	H	BB1	H
						IcZ2-57	NPR	NPR	H	BB1	H
IcZ2-58	NPR	NH2	H	BB1	H
						IcZ2-59	NPR	CBM	H	BB1	H
IcZ2-60	NPR	COM	H	BB1	H
						IcZ2-61	NPR	HYE	H	BB1	H
IcZ2-62	NPR	Me	Me	BB1	H
						IcZ2-63	NPR	Et	Et	BB1	H
IcZ2-64	NPR	PH	PH	BB1	H
						IcZ2-65	NPR	HYE	HYE	BB1	H
IcZ2-66	HYE	H	H	BB1	H
						IcZ2-67	HYE	Me	H	BB1	H
IcZ2-68	HYE	Et	H	BB1	H
						IcZ2-69	HYE	PH	H	BB1	H
IcZ2-70	HYE	NPR	H	BB1	H
						IcZ2-71	HYE	NH2	H	BB1	H
IcZ2-72	HYE	CBM	H	BB1	H
						IcZ2-73	HYE	COM	H	BB1	H
IcZ2-74	HYE	HYE	H	BB1	H
						IcZ2-75	HYE	Me	Me	BB1	H
IcZ2-76	HYE	Et	Et	BB1	H
						IcZ2-77	HYE	PH	PH	BB1	H
IcZ2-78	HYE	HYE	HYE	BB1	H
						IcZ2-79	H	H	H	BB6	H
IcZ2-80	H	Me	H	BB6	H

[ Table 17Z2]

TABLE 17Z2

	RO13Z2	RN13Z2	RN23Z2	Ba1Z2Ba2Z2	R1Z2
						IcZ2-81	H	Et	H	BB6	H
IcZ2-82	H	PH	H	BB6	H
						IcZ2-83	H	NPR	H	BB6	H
IcZ2-84	H	NH2	H	BB6	H
						IcZ2-85	H	CBM	H	BB6	H
IcZ2-86	H	COM	H	BB6	H
						IcZ2-87	H	HYE	H	BB6	H
IcZ2-88	H	Me	Me	BB6	H
						IcZ2-89	H	Et	Et	BB6	H
IcZ2-90	H	PH	PH	BB6	H
						IcZ2-91	H	HYE	HYE	BB6	H
IcZ2-92	Me	H	H	BB6	H
						IcZ2-93	Me	Me	H	BB6	H
IcZ2-94	Me	Et	H	BB6	H
						IcZ2-95	Me	PH	H	BB6	H
IcZ2-96	Me	NPR	H	BB6	H
						IcZ2-97	Me	NH2	H	BB6	H
IcZ2-98	Me	CBM	H	BB6	H
						IcZ2-99	Me	COM	H	BB6	H
IcZ2-100	Me	HYE	H	BB6	H
						IcZ2-101	Me	Me	Me	BB6	H
IcZ2-102	Me	Et	Et	BB6	H
						IcZ2-103	Me	PH	PH	BB6	H
IcZ2-104	Me	HYE	HYE	BB6	H
						IcZ2-105	Et	H	H	BB6	H
IcZ2-106	Et	Me	H	BB6	H
						IcZ2-107	Et	Et	H	BB6	H
IcZ2-108	Et	PH	H	BB6	H
						IcZ2-109	Et	NPR	H	BB6	H
IcZ2-110	Et	NH2	H	BB6	H
						IcZ2-111	Et	CBM	H	BB6	H
IcZ2-112	Et	COM	H	BB6	H
						IcZ2-113	Et	HYE	H	BB6	H
IcZ2-114	Et	Me	Me	BB6	H
						IcZ2-115	Et	Et	Et	BB6	H
IcZ2-116	Et	PH	PH	BB6	H
						IcZ2-117	Et	HYE	HYE	BB6	H
IcZ2-118	PH	H	H	BB6	H
						IcZ2-119	PH	Me	H	BB6	H
IcZ2-120	PH	Et	H	BB6	H

[ Table 18Z2]

TABLE 18Z2

	RO13Z2	RN13Z2	RN23Z2	Ba1Z2Ba2Z2	R1Z2
						IcZ2-121	PH	PH	H	BB6	H
IcZ2-122	PH	NPR	H	BB6	H
						IcZ2-123	PH	NH2	H	BB6	H
IcZ2-124	PH	CBM	H	BB6	H
						IcZ2-125	PH	COM	H	BB6	H
IcZ2-126	PH	HYE	H	BB6	H
						IcZ2-127	PH	Me	Me	BB6	H
IcZ2-128	PH	Et	Et	BB6	H
						IcZ2-129	PH	PH	PH	BB6	H
IcZ2-130	PH	HYE	HYE	BB6	H
						IcZ2-131	NPR	H	H	BB6	H
IcZ2-132	NPR	Me	H	BB6	H
						IcZ2-133	NPR	Et	H	BB6	H
IcZ2-134	NPR	PH	H	BB6	H
						IcZ2-135	NPR	NPR	H	BB6	H
IcZ2-136	NPR	NH2	H	BB6	H
						IcZ2-137	NPR	CBM	H	BB6	H
IcZ2-138	NPR	COM	H	BB6	H
						IcZ2-139	NPR	HYE	H	BB6	H
IcZ2-140	NPR	Me	Me	BB6	H
						IcZ2-141	NPR	Et	Et	BB6	H
IcZ2-142	NPR	PH	PH	BB6	H
						IcZ2-143	NPR	HYE	HYE	BB6	H
IcZ2-144	HYE	H	H	BB6	H
						IcZ2-145	HYE	Me	H	BB6	H
IcZ2-146	HYE	Et	H	BB6	H
						IcZ2-147	HYE	PH	H	BB6	H
IcZ2-148	HYE	NPR	H	BB6	H
						IcZ2-149	HYE	NH2	H	BB6	H
IcZ2-150	HYE	CBM	H	BB6	H
						IcZ2-151	HYE	COM	H	BB6	H
IcZ2-152	HYE	HYE	H	BB6	H
						IcZ2-153	HYE	Me	Me	BB6	H
IcZ2-154	HYE	Et	Et	BB6	H
						IcZ2-155	HYE	PH	PH	BB6	H
IcZ2-156	HYE	HYE	HYE	BB6	H
						IcZ2-157	H	H	H	BB19	H
IcZ2-158	H	Me	H	BB19	H
						IcZ2-159	H	Et	H	BB19	H
IcZ2-160	H	PH	H	BB19	H

[ Table 19Z2]

TABLE 19Z2

	RO13Z2	RN13Z2	RN23Z2	Ba1Z2Ba2Z2	R1Z2
						IcZ2-161	H	NPR	H	BB19	H
IcZ2-162	H	NH2	H	BB19	H
						IcZ2-163	H	CBM	H	BB19	H
IcZ2-164	H	COM	H	BB19	H
						IcZ2-165	H	HYE	H	BB19	H
IcZ2-166	H	Me	Me	BB19	H
						IcZ2-167	H	Et	Et	BB19	H
IcZ2-168	H	PH	PH	BB19	H
						IcZ2-169	H	HYE	HYE	BB19	H
IcZ2-170	Me	H	H	BB19	H
						IcZ2-171	Me	Me	H	BB19	H
IcZ2-172	Me	Et	H	BB19	H
						IcZ2-173	Me	PH	H	BB19	H
IcZ2-174	Me	NPR	H	BB19	H
						IcZ2-175	Me	NH2	H	BB19	H
IcZ2-176	Me	CBM	H	BB19	H
						IcZ2-177	Me	COM	H	BB19	H
IcZ2-178	Me	HYE	H	BB19	H
						IcZ2-179	Me	Me	Me	BB19	H
IcZ2-180	Me	Et	Et	BB19	H
						IcZ2-181	Me	PH	PH	BB19	H
IcZ2-182	Me	HYE	HYE	BB19	H
						IcZ2-183	Et	H	H	BB19	H
IcZ2-184	Et	Me	H	BB19	H
						IcZ2-185	Et	Et	H	BB19	H
IcZ2-186	Et	PH	H	BB19	H
						IcZ2-187	Et	NPR	H	BB19	H
IcZ2-188	Et	NH2	H	BB19	H
						IcZ2-189	Et	CBM	H	BB19	H
IcZ2-190	Et	COM	H	BB19	H
						IcZ2-191	Et	HYE	H	BB19	H
IcZ2-192	Et	Me	Me	BB19	H
						IcZ2-193	Et	Et	Et	BB19	H
IcZ2-194	Et	PH	PH	BB19	H
						IcZ2-195	Et	HYE	HYE	BB19	H
IcZ2-196	PH	H	H	BB19	H
						IcZ2-197	PH	Me	H	BB19	H
IcZ2-198	PH	Et	H	BB19	H
						IcZ2-199	PH	PH	H	BB19	H
IcZ2-200	PH	NPR	H	BB19	H

[ Table 20Z2]

TABLE 20Z2

	RO13Z2	RN13Z2	RN23Z2	Ba1Z2Ba2Z2	R1Z2
						IcZ2-201	PH	NH2	H	BB19	H
IcZ2-202	PH	CBM	H	BB19	H
						IcZ2-203	PH	COM	H	BB19	H
IcZ2-204	PH	HYE	H	BB19	H
						IcZ2-205	PH	Me	Me	BB19	H
IcZ2-206	PH	Et	Et	BB19	H
						IcZ2-207	PH	PH	PH	BB19	H
IcZ2-208	PH	HYE	HYE	BB19	H
						IcZ2-209	NPR	H	H	BB19	H
IcZ2-210	NPR	Me	H	BB19	H
						IcZ2-211	NPR	Et	H	BB19	H
IcZ2-212	NPR	PH	H	BB19	H
						IcZ2-213	NPR	NPR	H	BB19	H
IcZ2-214	NPR	NH2	H	BB19	H
						IcZ2-215	NPR	CBM	H	BB19	H
IcZ2-216	NPR	COM	H	BB19	H
						IcZ2-217	NPR	HYE	H	BB19	H
IcZ2-218	NPR	Me	Me	BB19	H
						IcZ2-219	NPR	Et	Et	BB19	H
IcZ2-220	NPR	PH	PH	BB19	H
						IcZ2-221	NPR	HYE	HYE	BB19	H
IcZ2-222	HYE	H	H	BB19	H
						IcZ2-223	HYE	Me	H	BB19	H
IcZ2-224	HYE	Et	H	BB19	H
						IcZ2-225	HYE	PH	H	BB19	H
IcZ2-226	HYE	NPR	H	BB19	H
						IcZ2-227	HYE	NH2	H	BB19	H
IcZ2-228	HYE	CBM	H	BB19	H
						IcZ2-229	HYE	COM	H	BB19	H
IcZ2-230	HYE	HYE	H	BB19	H
						IcZ2-231	HYE	Me	Me	BB19	H
IcZ2-232	HYE	Et	Et	BB19	H
						IcZ2-233	HYE	PH	PH	BB19	H
IcZ2-234	HYE	HYE	HYE	BB19	H
						IcZ2-235	H	Hex	H	BB1	H
IcZ2-236	Me	ALL	ALL	BB2	H
						IcZ2-237	Et	EOE	EOE	BB3	H
IcZ2-238	PH	Oct	H	BB4	H
						IcZ2-239	NPR	EOE	HYE	BB5	H
IcZ2-240	HYE	2EH	2EH	BB6	H

[ Table 21Z2]

TABLE 21Z2

	RO13Z2	RN13Z2	RN23Z2	Ba1Z2Ba2Z2	R1Z2
						IcZ2-241	Me	2EH	H	BB7	H
IcZ2-242	Et	IBu	IPR	BB8	H
						IcZ2-243	H	NH2	NH2	BB9	H
IcZ2-244	Me	CHM	H	BB10	H
						IcZ2-245	Et	IPR	NPR	BB11	H
IcZ2-246	Bu	Oct	Oct	BB12	H
						IcZ2-247	TBu	CH	H	BB13	H
IcZ2-248	Hex	NPR	Et	BB14	H
						IcZ2-249	Oct	CBM	CBM	BB15	H
IcZ2-250	2EH	BZ	H	BB16	H
						IcZ2-251	CHM	BZ	Me	BB17	H
IcZ2-252	CH	Hex	Hex	BB18	H
						IcZ2-253	PH	HYE	H	BB19	H
IcZ2-254	BZ	CH	COM	BB20	H
						IcZ2-255	NPR	COM	COM	BB21	H
IcZ2-256	IPR	NPR	H	BB22	H
						IcZ2-257	IBu	2EH	HYE	BB23	H
IcZ2-258	EOE	IPR	H	BB24	H
						IcZ2-259	ALL	CHM	ALL	BB25	H
IcZ2-260	HYE	COE	COE	BB26	H
						IcZ2-261	H	IBu	H	BB27	H
IcZ2-262	Me	Hex	NPR	BB28	H
						IcZ2-263	Et	EOE	H	BB29	H
IcZ2-264	Bu	Oct	IPR	BB30	H
						IcZ2-265	TBu	TBu	TBu	BB31	H
IcZ2-266	Hex	ALL	H	BB32	H
						IcZ2-267	Oct	TBu	Et	BB33	H
IcZ2-268	2EH	NH2	H	BB34	H
						IcZ2-269	CHM	Bu	Bu	BB35	H
IcZ2-270	CH	CBM	H	BB36	H
						IcZ2-271	PH	PH	PH	BB37	H
IcZ2-272	BZ	COM	H	BB38	H
						IcZ2-273	NPR	Bu	Me	BB39	H
IcZ2-274	IPR	CBA	CBA	BB40	H
						IcZ2-275	IBu	COE	H	BB41	H
IcZ2-276	EOE	Me	Me	BB42	H
						IcZ2-277	ALL	CBA	H	BB43	H
IcZ2-278	HYE	Et	Et	BB44	H
						IcZ2-279	H	H	H	BB45	H
IcZ2-280	Me	HYE	HYE	BB46	H

[ Table 22Z2]

TABLE 22Z2

	RO13Z2	RN13Z2	RN23Z2	Ba1Z2Ba2Z2	R1Z2
						IcZ2-281	Et	BZ	BZ	BB47	H
IcZ2-282	Bu	Me	H	BB48	H
						IcZ2-283	TBu	CBA	IPR	BB49	H
IcZ2-284	Hex	NPR	NPR	BB50	H
						IcZ2-285	Oct	Et	H	BB51	H
IcZ2-286	2EH	COE	NPR	BB52	H
						IcZ2-287	CHM	CH	CH	BB53	H
IcZ2-288	CH	PH	H	BB54	H
						IcZ2-289	PH	COM	Et	BB55	H
IcZ2-290	BZ	IPR	IPR	BB56	H
						IcZ2-291	NPR	Bu	H	BB57	H
IcZ2-292	IPR	CBM	Me	BB58	H
						IcZ2-293	IBu	IBu	IBu	BB59	H
IcZ2-294	EOE	TBu	H	BB60	H
						IcZ2-295	ALL	NH2	COM	BB1	H
IcZ2-296	HYE	CHM	CHM	BB19	H

[ Table 27Z2]

TABLE 27Z2

RO11Z2

RO12Z2

Ba1Z2Ba2Z2

R1Z2

RO11Z2

RO12Z2

Ba1Z2Ba2Z2

R1Z2

IaZ2-224

NA1

NA1

BB1

H

IaZ2-264

HHk11

HHk11

BB8

H

IaZ2-225

HHk8

HHk8

BB1

H

IaZ2-265

H

H

BB11

H

IaZ2-226

NA2

NA2

BB1

H

IaZ2-266

Me

Me

BB11

H

IaZ2-227

HHk7

HHk7

BB1

H

IaZ2-267

Et

Et

BB11

H

IaZ2-228

HH37

HH37

BB1

H

IaZ2-268

Bu

Bu

BB11

H

IaZ2-229

HHk6

HHk6

BB1

H

IaZ2-269

TBu

TBu

BB11

H

IaZ2-230

NA3

NA3

BB1

H

IaZ2-270

Hex

Hex

BB11

H

IaZ2-231

HHJ2

HHJ2

BB1

H

IaZ2-271

Oct

Oct

BB11

H

IaZ2-232

HHk11

HHk11

BB1

H

IaZ2-272

2EH

2EH

BB11

H

IaZ2-233

NA1

NA1

BB6

H

IaZ2-273

CH

CH

BB11

H

IaZ2-234

HHk8

HHk8

BB6

H

IaZ2-274

PH

PH

BB11

H

IaZ2-235

NA2

NA2

BB6

H

IaZ2-275

BZ

BZ

BB11

H

IaZ2-236

HHk7

HHk7

BB6

H

IaZ2-276

EOE

EOE

BB11

H

IaZ2-237

HH37

HH37

BB6

H

IaZ2-277

ALL

ALL

BB11

H

IaZ2-238

HHk6

HHk6

BB6

H

IaZ2-278

HYE

HYE

BB11

H

IaZ2-239

NA3

NA3

BB6

H

IaZ2-279

NA1

NA1

BB11

H

IaZ2-240

HHJ2

HHJ2

BB6

H

IaZ2-280

HHk8

HHk8

BB11

H

IaZ2-241

HHk11

HHk11

BB6

H

IaZ2-281

NA2

NA2

BB11

H

IaZ2-242

H

H

BB8

H

IaZ2-282

HHk7

HHk7

BB11

H

IaZ2-243

Me

Me

BB8

H

IaZ2-283

HH37

HH37

BB11

H

IaZ2-244

Et

Et

BB8

H

IaZ2-284

HHk6

HHk6

BB11

H

IaZ2-245

Bu

Bu

BB8

H

IaZ2-285

NA3

NA3

BB11

H

IaZ2-246

TBu

TBu

BB8

H

IaZ2-286

HHJ2

HHJ2

BB11

H

IaZ2-247

Oct

Oct

BB8

H

IaZ2-287

HHk11

HHk11

BB11

H

IaZ2-248

2EH

2EH

BB8

H

IaZ2-288

H

H

BB14

H

IaZ2-249

CHM

CHM

BB8

H

IaZ2-289

Et

Et

BB14

H

IaZ2-250

CH

CH

BB8

H

IaZ2-290

Bu

Bu

BB14

H

IaZ2-251

PH

PH

BB8

H

IaZ2-291

TBu

TBu

BB14

H

IaZ2-252

BZ

BZ

BB8

H

IaZ2-292

Hex

Hex

BB14

H

IaZ2-253

EOE

EOE

BB8

H

IaZ2-293

Oct

Oct

BB14

H

IaZ2-254

ALL

ALL

BB8

H

IaZ2-294

2EH

2EH

BB14

H

IaZ2-255

HYE

HYE

BB8

H

IaZ2-295

CHM

CHM

BB14

H

IaZ2-256

NA1

NA1

BB8

H

IaZ2-296

CH

CH

BB14

H

IaZ2-257

HHk8

HHk8

BB8

H

IaZ2-297

PH

PH

BB14

H

IaZ2-258

NA2

NA2

BB8

H

IaZ2-298

EOE

EOE

BB14

H

IaZ2-259

HHk7

HHk7

BB8

H

IaZ2-299

ALL

ALL

BB14

H

IaZ2-260

HH37

HH37

BB8

H

IaZ2-300

HYE

HYE

BB14

H

IaZ2-261

HHk6

HHk6

BB8

H

IaZ2-301

NA1

NA1

BB14

H

IaZ2-262

NA3

NA3

BB8

H

IaZ2-302

HHk8

HHk8

BB14

H

IaZ2-263

HHJ2

HHJ2

BB8

H

IaZ2-303

NA2

NA2

BB14

H

[ Table 28Z2]

TABLE 28Z2

RO11Z2

RO12Z2

Ba1Z2Ba2Z2

R1Z2

RO11Z2

RO12Z2

Ba1Z2Ba2Z2

R1Z2

IaZ2-304

HHk7

HHk7

BB14

H

IaZ2-344

Bu

Bu

BB58

H

IaZ2-305

HH37

HH37

BB14

H

IaZ2-345

TBu

TBu

BB58

H

IaZ2-306

HHk6

HHk6

BB14

H

IaZ2-346

Hex

Hex

BB58

H

IaZ2-307

NA3

NA3

BB14

H

IaZ2-347

Oct

Oct

BB58

H

IaZ2-308

HHJ2

HHJ2

BB14

H

IaZ2-348

2EH

2EH

BB58

H

IaZ2-309

HHk11

HHk11

BB14

H

IaZ2-349

CHM

CHM

BB58

H

IaZ2-310

NA1

NA1

BB19

H

IaZ2-350

CH

CH

BB58

H

IaZ2-311

HHk8

HHk8

BB19

H

IaZ2-351

PH

PH

BB58

H

IaZ2-312

NA2

NA2

BB19

H

IaZ2-352

BZ

BZ

BB58

H

IaZ2-313

HHk7

HHk7

BB19

H

IaZ2-353

EOE

EOE

BB58

H

IaZ2-314

HH37

HH37

BB19

H

IaZ2-354

ALL

ALL

BB58

H

IaZ2-315

HHk6

HHk6

BB19

H

IaZ2-355

HYE

HYE

BB58

H

IaZ2-316

NA3

NA3

BB19

H

IaZ2-356

NA1

NA1

BB58

H

IaZ2-317

HHJ2

HHJ2

BB19

H

IaZ2-357

HHk8

HHk8

BB58

H

IaZ2-318

HHk11

HHk11

BB19

H

IaZ2-358

NA2

NA2

BB58

H

IaZ2-319

H

H

BB37

H

IaZ2-359

HHk7

HHk7

BB58

H

IaZ2-320

Me

Me

BB37

H

IaZ2-360

HH37

HH37

BB58

H

IaZ2-321

Et

Et

BB37

H

IaZ2-361

HHk6

HHk6

BB58

H

IaZ2-322

Bu

Bu

BB37

H

IaZ2-362

NA3

NA3

BB58

H

IaZ2-323

TBu

TBu

BB37

H

IaZ2-363

HHJ2

HHJ2

BB58

H

IaZ2-324

Hex

Hex

BB37

H

IaZ2-364

HHk11

HHk11

BB58

H

IaZ2-325

Oct

Oct

BB37

H

IaZ2-365

H

H

BBJ2

H

IaZ2-326

2EH

2EH

BB37

H

IaZ2-366

Me

Me

BBJ2

H

IaZ2-327

CHM

CHM

BB37

H

IaZ2-367

Et

Et

BBJ2

H

IaZ2-328

CH

CH

BB37

H

IaZ2-368

Bu

Bu

BBJ2

H

IaZ2-329

PH

PH

BB37

H

IaZ2-369

TBu

TBu

BBJ2

H

IaZ2-330

BZ

BZ

BB37

H

IaZ2-370

Hex

Hex

BBJ2

H

IaZ2-331

ALL

ALL

BB37

H

IaZ2-371

Oct

Oct

BBJ2

H

IaZ2-332

HYE

HYE

BB37

H

IaZ2-372

2EH

2EH

BBJ2

H

IaZ2-333

NA1

NA1

BB37

H

IaZ2-373

CHM

CHM

BBJ2

H

IaZ2-334

HHk8

HHk8

BB37

H

IaZ2-374

CH

CH

BBJ2

H

IaZ2-335

NA2

NA2

BB37

H

IaZ2-375

PH

PH

BBJ2

H

IaZ2-336

HHk7

HHk7

BB37

H

IaZ2-376

BZ

BZ

BBJ2

H

IaZ2-337

HH37

HH37

BB37

H

IaZ2-377

EOE

EOE

BBJ2

H

IaZ2-338

HHk6

HHk6

BB37

H

IaZ2-378

ALL

ALL

BBJ2

H

IaZ2-339

NA3

NA3

BB37

H

IaZ2-379

HYE

HYE

BBJ2

H

IaZ2-340

HHJ2

HHJ2

BB37

H

IaZ2-380

NA1

NA1

BBJ2

H

IaZ2-341

HHk11

HHk11

BB37

H

IaZ2-381

HHk8

HHk8

BBJ2

H

IaZ2-342

Me

Me

BB58

H

IaZ2-382

NA2

NA2

BBJ2

H

IaZ2-343

Et

Et

BB58

H

IaZ2-383

HHk7

HHk7

BBJ2

H

[ Table 29Z2]

TABLE 29Z2

RO11Z2

RO12Z2

Ba1Z2Ba2Z2

R1Z2

RO11Z2

RO12Z2

Ba1Z2Ba2Z2

R1Z2

IaZ2-384

HH37

HH37

BBJ2

H

IaZ2-424

BZ

BZ

BBO10

H

IaZ2-385

HHk6

HHk6

BBJ2

H

IaZ2-425

EOE

EOE

BBO10

H

IaZ2-386

NA3

NA3

BBJ2

H

IaZ2-426

ALL

ALL

BBO10

H

IaZ2-387

HHJ2

HHJ2

BBJ2

H

IaZ2-427

HYE

HYE

BBO10

H

IaZ2-388

HHk11

HHk11

BBJ2

H

IaZ2-428

NA1

NA1

BBO10

H

IaZ2-389

H

H

BBO8

H

IaZ2-429

HHk8

HHk8

BBO10

H

IaZ2-390

Me

Me

BBO8

H

IaZ2-430

NA2

NA2

BBO10

H

IaZ2-391

Et

Et

BBO8

H

IaZ2-431

HHk7

HHk7

BBO10

H

IaZ2-392

Bu

Bu

BBO8

H

IaZ2-432

HH37

HH37

BBO10

H

IaZ2-393

TBu

TBu

BBO8

H

IaZ2-433

HHk6

HHk6

BBO10

H

IaZ2-394

Hex

Hex

BBO8

H

IaZ2-434

NA3

NA3

BBO10

H

IaZ2-395

Oct

Oct

BBO8

H

IaZ2-435

HHJ2

HHJ2

BBO10

H

IaZ2-396

2EH

2EH

BBO8

H

IaZ2-436

HHk11

HHk11

BBO10

H

IaZ2-397

CHM

CHM

BBO8

H

IaZ2-437

HHf1

HHf1

BB2

H

IaZ2-398

CH

CH

BBO8

H

IaZ2-438

HH55

HH55

BB3

H

IaZ2-399

PH

PH

BBO8

H

IaZ2-439

HHh8

HHh8

BB4

H

IaZ2-400

BZ

BZ

BBO8

H

IaZ2-440

HHf5

HHf5

BB5

H

IaZ2-401

EOE

EOE

BBO8

H

IaZ2-441

HH83

HH83

BB7

H

IaZ2-402

ALL

ALL

BBO8

H

IaZ2-442

HH58

HH58

BB9

H

IaZ2-403

HYE

HYE

BBO8

H

IaZ2-443

HHf11

HHf11

BB10

H

IaZ2-404

NA1

NA1

BBO8

H

IaZ2-444

HH34

HH34

BB12

H

IaZ2-405

HHk8

HHk8

BBO8

H

IaZ2-445

HH80

HH80

BB13

H

IaZ2-406

NA2

NA2

BBO8

H

IaZ2-446

HHb3

HHb3

BB15

H

IaZ2-407

HHk7

HHk7

BBO8

H

IaZ2-447

HH13

HH13

BB16

H

IaZ2-408

HH37

HH37

BBO8

H

IaZ2-448

HH81

HH81

BB17

H

IaZ2-409

HHk6

HHk6

BBO8

H

IaZ2-449

HH49

HH49

BB18

H

IaZ2-410

NA3

NA3

BBO8

H

IaZ2-450

HHk6

HHk6

BB20

H

IaZ2-411

HHJ2

HHJ2

BBO8

H

IaZ2-451

HHk7

HHk7

BB21

H

IaZ2-412

HHk11

HHk11

BBO8

H

IaZ2-452

HHJ2

HHJ2

BB22

H

IaZ2-413

H

H

BBO10

H

IaZ2-453

HH28

HH28

BB23

H

IaZ2-414

Me

Me

BBO10

H

IaZ2-454

HHd6

HHd6

BB24

H

IaZ2-415

Et

Et

BBO10

H

IaZ2-455

HH37

HH37

BB25

H

IaZ2-416

Bu

Bu

BBO10

H

IaZ2-456

HH43

HH43

BB26

H

IaZ2-417

TBu

TBu

BBO10

H

IaZ2-457

NA4

NA4

BB27

H

IaZ2-418

Hex

Hex

BBO10

H

IaZ2-458

HH40

HH40

BB28

H

IaZ2-419

Oct

Oct

BBO10

H

IaZ2-459

HHg5

HHg5

BB29

H

IaZ2-420

2EH

2EH

BBO10

H

IaZ2-460

HHk3

HHk3

BB30

H

IaZ2-421

CHM

CHM

BBO10

H

IaZ2-461

HHk5

HHk5

BB31

H

IaZ2-422

CH

CH

BBO10

H

IaZ2-462

HH76

HH76

BB32

H

IaZ2-423

PH

PH

BBO10

H

IaZ2-463

HH78

HH78

BB33

H

[ Table 30Z2]

TABLE 30Z2

	RO11Z2	RO12Z2	Ba1Z2Ba2Z2	R1Z2
					IaZ2-464	HHJ10	HHJ10	BB34	H
IaZ2-465	HHJ3	HHJ3	BB35	H
					IaZ2-466	HHk4	HHk4	BB36	H
IaZ2-467	HHc1	HHc1	BB38	H
					IaZ2-468	HH61	HH61	BB39	H
IaZ2-469	HH65	HH65	BB40	H
					IaZ2-470	HHg2	HHg2	BB41	H
IaZ2-471	HH69	HH69	BB42	H
					IaZ2-472	HHJ4	HHJ4	BB43	H
IaZ2-473	HHi11	HHi11	BB44	H
					IaZ2-474	NA2	NA2	BB45	H
IaZ2-475	HHk8	HHk8	BB46	H
					IaZ2-476	NA3	NA3	BB47	H
IaZ2-477	HHe4	HHe4	BB48	H
					IaZ2-478	HHk1	HHk1	BB49	H
IaZ2-479	HHh1	HHh1	BB50	H
					IaZ2-480	HHj19	HHj19	BB51	H
IaZ2-481	HHk11	HHk11	BB52	H
					IaZ2-482	HHh4	HHh4	BB53	H
IaZ2-483	HH22	HH22	BB54	H
					IaZ2-484	HHj10	HHj10	BB55	H
IaZ2-485	HH36	HH36	BB56	H
					IaZ2-486	NA5	NA5	BB57	H
IaZ2-487	NA1	NA1	BB59	H
					IaZ2-488	HHf14	HHf14	BB60	H
IaZ2-489	HH35	HH35	BBI1	H
					IaZ2-490	HHg1	HHg1	BBD1	H
IaZ2-491	HH9	HH9	BBK2	H
					IaZ2-492	HHa2	HHa2	BBK3	H
IaZ2-493	HHj17	HHj17	BBK4	H
					IaZ2-494	HH46	HH46	BBK14	H

[ Table 31Z2]

TABLE 31Z2

RN11Z2

RN21Z2

RN12Z2

RN22Z2

Ba1Z2Ba2Z2

R1Z2

RN11Z2

RN21Z2

RN12Z2

RN22Z2

Ba1Z2Ba2Z2

R1Z2

IbZ2-317

HHk8

H

HHk8

H

BB1

H

IbZ2-357

NA3

NA3

NA3

NA3

BB6

H

IbZ2-318

HHk7

H

HHk7

H

BB1

H

IbZ2-358

HHJ2

HHJ2

HHJ2

HHJ2

BB6

H

IbZ2-319

HH37

H

HH37

H

BB1

H

IbZ2-359

HHk11

HHk11

HHk11

HHk11

BB6

H

IbZ2-320

HHk6

H

HHk6

H

BB1

H

IbZ2-360

NA1

Me

NA1

Me

BB6

H

IbZ2-321

NA3

H

NA3

H

BB1

H

IbZ2-361

HHk8

Me

HHk8

Me

BB6

H

IbZ2-322

HHJ2

H

HHJ2

H

BB1

H

IbZ2-362

NA2

Me

NA2

Me

BB6

H

IbZ2-323

HHk11

H

HHk11

H

BB1

H

IbZ2-363

HHk7

Me

HHk7

Me

BB6

H

IbZ2-324

NA1

NA1

NA1

NA1

BB1

H

IbZ2-364

HH37

Me

HH37

Me

BB6

H

IbZ2-325

HHk8

HHk8

HHk8

HHk8

BB1

H

IbZ2-365

HHk6

Me

HHk6

Me

BB6

H

IbZ2-326

NA2

NA2

NA2

NA2

BB1

H

IbZ2-366

NA3

Me

NA3

Me

BB6

H

IbZ2-327

HHk7

HHk7

HHk7

HHk7

BB1

H

IbZ2-367

HHJ2

Me

HHJ2

Me

BB6

H

IbZ2-328

HH37

HH37

HH37

HH37

BB1

H

IbZ2-368

HHk11

Me

HHk11

Me

BB6

H

IbZ2-329

HHk6

HHk6

HHk6

HHk6

BB1

H

IbZ2-369

H

H

H

H

BB8

H

IbZ2-330

NA3

NA3

NA3

NA3

BB1

H

IbZ2-370

Me

H

Me

H

BB8

H

IbZ2-331

HHJ2

HHJ2

HHJ2

HHJ2

BB1

H

IbZ2-371

Et

H

Et

H

BB8

H

IbZ2-332

HHk11

HHk11

HHk11

HHk11

BB1

H

IbZ2-372

PH

H

PH

H

BB8

H

IbZ2-333

NA1

Me

NA1

Me

BB1

H

IbZ2-373

Bu

H

Bu

H

BB8

H

IbZ2-334

HHk8

Me

HHk8

Me

BB1

H

IbZ2-374

TBu

H

TBu

H

BB8

H

IbZ2-335

NA2

Me

NA2

Me

BB1

H

IbZ2-375

Hex

H

Hex

H

BB8

H

IbZ2-336

HHk7

Me

HHk7

Me

BB1

H

IbZ2-376

Oct

H

Oct

H

BB8

H

IbZ2-337

HH37

Me

HH37

Me

BB1

H

IbZ2-377

2EH

H

2EH

H

BB8

H

IbZ2-338

HHk6

Me

HHk6

Me

BB1

H

IbZ2-378

CHM

H

CHM

H

BB8

H

IbZ2-339

NA3

Me

NA3

Me

BB1

H

IbZ2-379

CH

H

CH

H

BB8

H

IbZ2-340

HHJ2

Me

HHJ2

Me

BB1

H

IbZ2-380

BZ

H

BZ

H

BB8

H

IbZ2-341

HHk11

Me

HHk11

Me

BB1

H

IbZ2-381

EOE

H

EOE

H

BB8

H

IbZ2-342

NA1

H

NA1

H

BB6

H

IbZ2-382

ALL

H

ALL

H

BB8

H

IbZ2-343

HHk8

H

HHk8

H

BB6

H

IbZ2-383

NH2

H

NH2

H

BB8

H

IbZ2-344

NA2

H

NA2

H

BB6

H

IbZ2-384

CBM

H

CBM

H

BB8

H

IbZ2-345

HHk7

H

HHk7

H

BB6

H

IbZ2-385

COM

H

COM

H

BB8

H

IbZ2-346

HH37

H

HH37

H

BB6

H

IbZ2-386

COE

H

COE

H

BB8

H

IbZ2-347

HHk6

H

HHk6

H

BB6

H

IbZ2-387

CBA

H

CBA

H

BB8

H

IbZ2-348

NA3

H

NA3

H

BB6

H

IbZ2-388

HYE

H

HYE

H

BB8

H

IbZ2-349

HHJ2

H

HHJ2

H

BB6

H

IbZ2-389

HHk8

H

HHk8

H

BB8

H

IbZ2-350

HHk11

H

HHk11

H

BB6

H

IbZ2-390

NA2

H

NA2

H

BB8

H

IbZ2-351

NA1

NA1

NA1

NA1

BB6

H

IbZ2-391

HHk7

H

HHk7

H

BB8

H

IbZ2-352

HHk8

HHk8

HHk8

HHk8

BB6

H

IbZ2-392

HH37

H

HH37

H

BB8

H

IbZ2-353

NA2

NA2

NA2

NA2

BB6

H

IbZ2-393

HHk6

H

HHk6

H

BB8

H

IbZ2-354

HHk7

HHk7

HHk7

HHk7

BB6

H

IbZ2-394

NA3

H

NA3

H

BB8

H

IbZ2-355

HH37

HH37

HH37

HH37

BB6

H

IbZ2-395

HHJ2

H

HHJ2

H

BB8

H

IbZ2-356

HHk6

HHk6

HHk6

HHk6

BB6

H

IbZ2-396

HHk11

H

HHk11

H

BB8

H

[ Table 32Z2]

TABLE 32Z2

RN11Z2

RN21Z2

RN12Z2

RN22Z2

Ba1Z2Ba2Z2

R1Z2

RN11Z2

RN21Z2

RN12Z2

RN22Z2

Ba1Z2Ba2Z2

R1Z2

IbZ2-397

Me

Me

Me

Me

BB8

H

IbZ2-437

NA1

H

NA1

H

BB11

H

IbZ2-398

PH

PH

PH

PH

BB8

H

IbZ2-438

HHk8

H

HHk8

H

BB11

H

IbZ2-399

NA1

NA1

NA1

NA1

BB8

H

IbZ2-439

NA2

H

NA2

H

BB11

H

IbZ2-400

HHk8

HHk8

HHk8

HHk8

BB8

H

IbZ2-440

HHk7

H

HHk7

H

BB11

H

IbZ2-401

NA2

NA2

NA2

NA2

BB8

H

IbZ2-441

HH37

H

HH37

H

BB11

H

IbZ2-402

HHk7

HHk7

HHk7

HHk7

BB8

H

IbZ2-442

HHk6

H

HHk6

H

BB11

H

IbZ2-403

HH37

HH37

HH37

HH37

BB8

H

IbZ2-443

NA3

H

NA3

H

BB11

H

IbZ2-404

HHk6

HHk6

HHk6

HHk6

BB8

H

IbZ2-444

HHJ2

H

HHJ2

H

BB11

H

IbZ2-405

NA3

NA3

NA3

NA3

BB8

H

IbZ2-445

HHk11

H

HHk11

H

BB11

H

IbZ2-406

HHJ2

HHJ2

HHJ2

HHJ2

BB8

H

IbZ2-446

Me

Me

Me

Me

BB11

H

IbZ2-407

HHk11

HHk11

HHk11

HHk11

BB8

H

IbZ2-447

PH

PH

PH

PH

BB11

H

IbZ2-408

NA1

Me

NA1

Me

BB8

H

IbZ2-448

NA1

NA1

NA1

NA1

BB11

H

IbZ2-409

HHk8

Me

HHk8

Me

BB8

H

IbZ2-449

HHk8

HHk8

HHk8

HHk8

BB11

H

IbZ2-410

NA2

Me

NA2

Me

BB8

H

IbZ2-450

NA2

NA2

NA2

NA2

BB11

H

IbZ2-411

HHk7

Me

HHk7

Me

BB8

H

IbZ2-451

HHk7

HHk7

HHk7

HHk7

BB11

H

IbZ2-412

HH37

Me

HH37

Me

BB8

H

IbZ2-452

HH37

HH37

HH37

HH37

BB11

H

IbZ2-413

HHk6

Me

HHk6

Me

BB8

H

IbZ2-453

HHk6

HHk6

HHk6

HHk6

BB11

H

IbZ2-414

NA3

Me

NA3

Me

BB8

H

IbZ2-454

NA3

NA3

NA3

NA3

BB11

H

IbZ2-415

HHJ2

Me

HHJ2

Me

BB8

H

IbZ2-455

HHJ2

HHJ2

HHJ2

HHJ2

BB11

H

IbZ2-416

HHk11

Me

HHk11

Me

BB8

H

IbZ2-456

HHk11

HHk11

HHk11

HHk11

BB11

H

IbZ2-417

H

H

H

H

BB11

H

IbZ2-457

NA1

Me

NA1

Me

BB11

H

IbZ2-418

Me

H

Me

H

BB11

H

IbZ2-458

HHk8

Me

HHk8

Me

BB11

H

IbZ2-419

Et

H

Et

H

BB11

H

IbZ2-459

NA2

Me

NA2

Me

BB11

H

IbZ2-420

PH

H

PH

H

BB11

H

IbZ2-460

HHk7

Me

HHk7

Me

BB11

H

IbZ2-421

Bu

H

Bu

H

BB11

H

IbZ2-461

HH37

Me

HH37

Me

BB11

H

IbZ2-422

TBu

H

TBu

H

BB11

H

IbZ2-462

HHk6

Me

HHk6

Me

BB11

H

IbZ2-423

Hex

H

Hex

H

BB11

H

IbZ2-463

NA3

Me

NA3

Me

BB11

H

IbZ2-424

Oct

H

Oct

H

BB11

H

IbZ2-464

HHJ2

Me

HHJ2

Me

BB11

H

IbZ2-425

2EH

H

2EH

H

BB11

H

IbZ2-465

HHk11

Me

HHk11

Me

BB11

H

IbZ2-426

CHM

H

CHM

H

BB11

H

IbZ2-466

H

H

H

H

BB14

H

IbZ2-427

CH

H

CH

H

BB11

H

IbZ2-467

Me

H

Me

H

BB14

H

IbZ2-428

BZ

H

BZ

H

BB11

H

IbZ2-468

Et

H

Et

H

BB14

H

IbZ2-429

EOE

H

EOE

H

BB11

H

IbZ2-469

PH

H

PH

H

BB14

H

IbZ2-430

ALL

H

ALL

H

BB11

H

IbZ2-470

Bu

H

Bu

H

BB14

H

IbZ2-431

NH2

H

NH2

H

BB11

H

IbZ2-471

TBu

H

TBu

H

BB14

H

IbZ2-432

CBM

H

CBM

H

BB11

H

IbZ2-472

Hex

H

Hex

H

BB14

H

IbZ2-433

COM

H

COM

H

BB11

H

IbZ2-473

Oct

H

Oct

H

BB14

H

IbZ2-434

COE

H

COE

H

BB11

H

IbZ2-474

2EH

H

2EH

H

BB14

H

IbZ2-435

CBA

H

CBA

H

BB11

H

IbZ2-475

CHM

H

CHM

H

BB14

H

IbZ2-436

HYE

H

HYE

H

BB11

H

IbZ2-476

CH

H

CH

H

BB14

H

[ Table 33Z2]

TABLE 33Z2

RN11Z2

RN21Z2

RN12Z2

RN22Z2

Ba1Z2Ba2Z2

R1Z2

RN11Z2

RN21Z2

RN12Z2

RN22Z2

Ba1Z2Ba2Z2

R1Z2

IbZ2-477

BZ

H

BZ

H

BB14

H

IbZ2-517

HH37

H

HH37

H

BB19

H

IbZ2-478

EOE

H

EOE

H

BB14

H

IbZ2-518

HHk6

H

HHk6

H

BB19

H

IbZ2-479

ALL

H

ALL

H

BB14

H

IbZ2-519

NA3

H

NA3

H

BB19

H

IbZ2-480

NH2

H

NH2

H

BB14

H

IbZ2-520

HHJ2

H

HHJ2

H

BB19

H

IbZ2-481

CBM

H

CBM

H

BB14

H

IbZ2-521

HHk11

H

HHk11

H

BB19

H

IbZ2-482

COM

H

COM

H

BB14

H

IbZ2-522

NA1

NA1

NA1

NA1

BB19

H

IbZ2-483

COE

H

COE

H

BB14

H

IbZ2-523

HHk8

HHk8

HHk8

HHk8

BB19

H

IbZ2-484

CBA

H

CBA

H

BB14

H

IbZ2-524

NA2

NA2

NA2

NA2

BB19

H

IbZ2-485

HYE

H

HYE

H

BB14

H

IbZ2-525

HHk7

HHk7

HHk7

HHk7

BB19

H

IbZ2-486

NA1

H

NA1

H

BB14

H

IbZ2-526

HH37

HH37

HH37

HH37

BB19

H

IbZ2-487

HHk8

H

HHk8

H

BB14

H

IbZ2-527

HHk6

HHk6

HHk6

HHk6

BB19

H

IbZ2-488

NA2

H

NA2

H

BB14

H

IbZ2-528

NA3

NA3

NA3

NA3

BB19

H

IbZ2-489

HHk7

H

HHk7

H

BB14

H

IbZ2-529

HHJ2

HHJ2

HHJ2

HHJ2

BB19

H

IbZ2-490

HH37

H

HH37

H

BB14

H

IbZ2-530

HHk11

HHk11

HHk11

HHk11

BB19

H

IbZ2-491

HHk6

H

HHk6

H

BB14

H

IbZ2-531

NA1

Me

NA1

Me

BB19

H

IbZ2-492

NA3

H

NA3

H

BB14

H

IbZ2-532

HHk8

Me

HHk8

Me

BB19

H

IbZ2-493

HHJ2

H

HHJ2

H

BB14

H

IbZ2-533

NA2

Me

NA2

Me

BB19

H

IbZ2-494

HHk11

H

HHk11

H

BB14

H

IbZ2-534

HHk7

Me

HHk7

Me

BB19

H

IbZ2-495

Me

Me

Me

Me

BB14

H

IbZ2-535

HH37

Me

HH37

Me

BB19

H

IbZ2-496

PH

PH

PH

PH

BB14

H

IbZ2-536

HHk6

Me

HHk6

Me

BB19

H

IbZ2-497

NA1

NA1

NA1

NA1

BB14

H

IbZ2-537

NA3

Me

NA3

Me

BB19

H

IbZ2-498

HHk8

HHk8

HHk8

HHk8

BB14

H

IbZ2-538

HHJ2

Me

HHJ2

Me

BB19

H

IbZ2-499

NA2

NA2

NA2

NA2

BB14

H

IbZ2-539

HHk11

Me

HHk11

Me

BB19

H

IbZ2-500

HHk7

HHk7

HHk7

HHk7

BB14

H

IbZ2-540

H

H

H

H

BB37

H

IbZ2-501

HH37

HH37

HH37

HH37

BB14

H

IbZ2-541

Me

H

Me

H

BB37

H

IbZ2-502

HHk6

HHk6

HHk6

HHk6

BB14

H

IbZ2-542

Et

H

Et

H

BB37

H

IbZ2-503

NA3

NA3

NA3

NA3

BB14

H

IbZ2-543

PH

H

PH

H

BB37

H

IbZ2-504

HHJ2

HHJ2

HHJ2

HHJ2

BB14

H

IbZ2-544

Bu

H

Bu

H

BB37

H

IbZ2-505

HHk11

HHk11

HHk11

HHk11

BB14

H

IbZ2-545

TBu

H

TBu

H

BB37

H

IbZ2-506

NA1

Me

NA1

Me

BB14

H

IbZ2-546

Hex

H

Hex

H

BB37

H

IbZ2-507

HHk8

Me

HHk8

Me

BB14

H

IbZ2-547

Oct

H

Oct

H

BB37

H

IbZ2-508

NA2

Me

NA2

Me

BB14

H

IbZ2-548

2EH

H

2EH

H

BB37

H

IbZ2-509

HHk7

Me

HHk7

Me

BB14

H

IbZ2-549

CHM

H

CHM

H

BB37

H

IbZ2-510

HH37

Me

HH37

Me

BB14

H

IbZ2-550

CH

H

CH

H

BB37

H

IbZ2-511

HHk6

Me

HHk6

Me

BB14

H

IbZ2-551

EOE

H

EOE

H

BB37

H

IbZ2-512

NA3

Me

NA3

Me

BB14

H

IbZ2-552

ALL

H

ALL

H

BB37

H

IbZ2-513

HHJ2

Me

HHJ2

Me

BB14

H

IbZ2-553

NH2

H

NH2

H

BB37

H

IbZ2-514

HHk11

Me

HHk11

Me

BB14

H

IbZ2-554

CBM

H

CBM

H

BB37

H

IbZ2-515

HHk8

H

HHk8

H

BB19

H

IbZ2-555

COM

H

COM

H

BB37

H

IbZ2-516

HHk7

H

HHk7

H

BB19

H

IbZ2-556

COE

H

COE

H

BB37

H

[ Table 34Z2]

TABLE 34Z2

RN11Z2

RN21Z2

RN12Z2

RN22Z2

Ba1Z2Ba2Z2

R1Z2

RN11Z2

RN21Z2

RN12Z2

RN22Z2

Ba1Z2Ba2Z2

R1Z2

IbZ2-557

CBA

H

CBA

H

BB37

H

IbZ2-597

CHM

H

CHM

H

BB58

H

IbZ2-558

HYE

H

HYE

H

BB37

H

IbZ2-598

CH

H

CH

H

BB58

H

IbZ2-559

NA1

H

NA1

H

BB37

H

IbZ2-599

BZ

H

BZ

H

BB58

H

IbZ2-560

HHk8

H

HHk8

H

BB37

H

IbZ2-600

EOE

H

EOE

H

BB58

H

IbZ2-561

NA2

H

NA2

H

BB37

H

IbZ2-601

ALL

H

ALL

H

BB58

H

IbZ2-562

HHk7

H

HHk7

H

BB37

H

IbZ2-602

NH2

H

NH2

H

BB58

H

IbZ2-563

HH37

H

HH37

H

BB37

H

IbZ2-603

CBM

H

CBM

H

BB58

H

IbZ2-564

HHk6

H

HHk6

H

BB37

H

IbZ2-604

COM

H

COM

H

BB58

H

IbZ2-565

NA3

H

NA3

H

BB37

H

IbZ2-605

COE

H

COE

H

BB58

H

IbZ2-566

HHJ2

H

HHJ2

H

BB37

H

IbZ2-606

CBA

H

CBA

H

BB58

H

IbZ2-567

HHk11

H

HHk11

H

BB37

H

IbZ2-607

HYE

H

HYE

H

BB58

H

IbZ2-568

Me

Me

Me

Me

BB37

H

IbZ2-608

NA1

H

NA1

H

BB58

H

IbZ2-569

PH

PH

PH

PH

BB37

H

IbZ2-609

HHk8

H

HHk8

H

BB58

H

IbZ2-570

NA1

NA1

NA1

NA1

BB37

H

IbZ2-610

NA2

H

NA2

H

BB58

H

IbZ2-571

HHk8

HHk8

HHk8

HHk8

BB37

H

IbZ2-611

HHk7

H

HHk7

H

BB58

H

IbZ2-572

NA2

NA2

NA2

NA2

BB37

H

IbZ2-612

HH37

H

HH37

H

BB58

H

IbZ2-573

HHk7

HHk7

HHk7

HHk7

BB37

H

IbZ2-613

HHk6

H

HHk6

H

BB58

H

IbZ2-574

HH37

HH37

HH37

HH37

BB37

H

IbZ2-614

NA3

H

NA3

H

BB58

H

IbZ2-575

HHk6

HHk6

HHk6

HHk6

BB37

H

IbZ2-615

HHJ2

H

HHJ2

H

BB58

H

IbZ2-576

NA3

NA3

NA3

NA3

BB37

H

IbZ2-616

HHk11

H

HHk11

H

BB58

H

IbZ2-577

HHJ2

HHJ2

HHJ2

HHJ2

BB37

H

IbZ2-617

Me

Me

Me

Me

BB58

H

IbZ2-578

HHk11

HHk11

HHk11

HHk11

BB37

H

IbZ2-618

PH

PH

PH

PH

BB58

H

IbZ2-579

NA1

Me

NA1

Me

BB37

H

IbZ2-619

NA1

NA1

NA1

NA1

BB58

H

IbZ2-580

HHk8

Me

HHk8

Me

BB37

H

IbZ2-620

HHk8

HHk8

HHk8

HHk8

BB58

H

IbZ2-581

NA2

Me

NA2

Me

BB37

H

IbZ2-621

NA2

NA2

NA2

NA2

BB58

H

IbZ2-582

HHk7

Me

HHk7

Me

BB37

H

IbZ2-622

HHk7

HHk7

HHk7

HHk7

BB58

H

IbZ2-583

HH37

Me

HH37

Me

BB37

H

IbZ2-623

HH37

HH37

HH37

HH37

BB58

H

IbZ2-584

HHk6

Me

HHk6

Me

BB37

H

IbZ2-624

HHk6

HHk6

HHk6

HHk6

BB58

H

IbZ2-585

NA3

Me

NA3

Me

BB37

H

IbZ2-625

NA3

NA3

NA3

NA3

BB58

H

IbZ2-586

HHJ2

Me

HHJ2

Me

BB37

H

IbZ2-626

HHJ2

HHJ2

HHJ2

HHJ2

BB58

H

IbZ2-587

HHk11

Me

HHk11

Me

BB37

H

IbZ2-627

HHk11

HHk11

HHk11

HHk11

BB58

H

IbZ2-588

H

H

H

H

BB58

H

IbZ2-628

NA1

Me

NA1

Me

BB58

H

IbZ2-589

Me

H

Me

H

BB58

H

IbZ2-629

HHk8

Me

HHk8

Me

BB58

H

IbZ2-590

Et

H

Et

H

BB58

H

IbZ2-630

NA2

Me

NA2

Me

BB58

H

IbZ2-591

PH

H

PH

H

BB58

H

IbZ2-631

HHk7

Me

HHk7

Me

BB58

H

IbZ2-592

Bu

H

Bu

H

BB58

H

IbZ2-632

HH37

Me

HH37

Me

BB58

H

IbZ2-593

TBu

H

TBu

H

BB58

H

IbZ2-633

HHk6

Me

HHk6

Me

BB58

H

IbZ2-594

Hex

H

Hex

H

BB58

H

IbZ2-634

NA3

Me

NA3

Me

BB58

H

IbZ2-595

Oct

H

Oct

H

BB58

H

IbZ2-635

HHJ2

Me

HHJ2

Me

BB58

H

IbZ2-596

2EH

H

2EH

H

BB58

H

IbZ2-636

HHk11

Me

HHk11

Me

BB58

H

[ Table 35Z2]

TABLE 35Z2

RN11Z2

RN21Z2

RN12Z2

RN22Z2

Ba1Z2Ba2Z2

R1Z2

RN11Z2

RN21Z2

RN12Z2

RN22Z2

Ba1Z2Ba2Z2

R1Z2

IbZ2-637

H

H

H

H

BBJ2

H

IbZ2-677

NA1

Me

NA1

Me

BBJ2

H

IbZ2-638

Me

H

Me

H

BBJ2

H

IbZ2-678

HHk8

Me

HHk8

Me

BBJ2

H

IbZ2-639

Et

H

Et

H

BBJ2

H

IbZ2-679

NA2

Me

NA2

Me

BBJ2

H

IbZ2-640

PH

H

PH

H

BBJ2

H

IbZ2-680

HHk7

Me

HHk7

Me

BBJ2

H

IbZ2-641

Bu

H

Bu

H

BBJ2

H

IbZ2-681

HH37

Me

HH37

Me

BBJ2

H

IbZ2-642

TBu

H

TBu

H

BBJ2

H

IbZ2-682

HHk6

Me

HHk6

Me

BBJ2

H

IbZ2-643

Hex

H

Hex

H

BBJ2

H

IbZ2-683

NA3

Me

NA3

Me

BBJ2

H

IbZ2-644

Oct

H

Oct

H

BBJ2

H

IbZ2-684

HHJ2

Me

HHJ2

Me

BBJ2

H

IbZ2-645

2EH

H

2EH

H

BBJ2

H

IbZ2-685

HHk11

Me

HHk11

Me

BBJ2

H

IbZ2-646

CHM

H

CHM

H

BBJ2

H

IbZ2-686

H

H

H

H

BBO8

H

IbZ2-647

CH

H

CH

H

BBJ2

H

IbZ2-687

Me

H

Me

H

BBO8

H

IbZ2-648

BZ

H

BZ

H

BBJ2

H

IbZ2-688

Et

H

Et

H

BBO8

H

IbZ2-649

EOE

H

EOE

H

BBJ2

H

IbZ2-689

PH

H

PH

H

BBO8

H

IbZ2-650

ALL

H

ALL

H

BBJ2

H

IbZ2-690

Bu

H

Bu

H

BBO8

H

IbZ2-651

NH2

H

NH2

H

BBJ2

H

IbZ2-691

TBu

H

TBu

H

BBO8

H

IbZ2-652

CBM

H

CBM

H

BBJ2

H

IbZ2-692

Hex

H

Hex

H

BBO8

H

IbZ2-653

COM

H

COM

H

BBJ2

H

IbZ2-693

Oct

H

Oct

H

BBO8

H

IbZ2-654

COE

H

COE

H

BBJ2

H

IbZ2-694

2EH

H

2EH

H

BBO8

H

IbZ2-655

CBA

H

CBA

H

BBJ2

H

IbZ2-695

CHM

H

CHM

H

BBO8

H

IbZ2-656

HYE

H

HYE

H

BBJ2

H

IbZ2-696

CH

H

CH

H

BBO8

H

IbZ2-657

NA1

H

NA1

H

BBJ2

H

IbZ2-697

BZ

H

BZ

H

BBO8

H

IbZ2-658

HHk8

H

HHk8

H

BBJ2

H

IbZ2-698

EOE

H

EOE

H

BBO8

H

IbZ2-659

NA2

H

NA2

H

BBJ2

H

IbZ2-699

ALL

H

ALL

H

BBO8

H

IbZ2-660

HHk7

H

HHk7

H

BBJ2

H

IbZ2-700

NH2

H

NH2

H

BBO8

H

IbZ2-661

HH37

H

HH37

H

BBJ2

H

IbZ2-701

CBM

H

CBM

H

BBO8

H

IbZ2-662

HHk6

H

HHk6

H

BBJ2

H

IbZ2-702

COM

H

COM

H

BBO8

H

IbZ2-663

NA3

H

NA3

H

BBJ2

H

IbZ2-703

COE

H

COE

H

BBO8

H

IbZ2-664

HHJ2

H

HHJ2

H

BBJ2

H

IbZ2-704

CBA

H

CBA

H

BBO8

H

IbZ2-665

HHk11

H

HHk11

H

BBJ2

H

IbZ2-705

HYE

H

HYE

H

BBO8

H

IbZ2-666

Me

Me

Me

Me

BBJ2

H

IbZ2-706

HHk8

H

HHk8

H

BBO8

H

IbZ2-667

PH

PH

PH

PH

BBJ2

H

IbZ2-707

NA2

H

NA2

H

BBO8

H

IbZ2-668

NA1

NA1

NA1

NA1

BBJ2

H

IbZ2-708

HHk7

H

HHk7

H

BBO8

H

IbZ2-669

HHk8

HHk8

HHk8

HHk8

BBJ2

H

IbZ2-709

HH37

H

HH37

H

BBO8

H

IbZ2-670

NA2

NA2

NA2

NA2

BBJ2

H

IbZ2-710

HHk6

H

HHk6

H

BBO8

H

IbZ2-671

HHk7

HHk7

HHk7

HHk7

BBJ2

H

IbZ2-711

NA3

H

NA3

H

BBO8

H

IbZ2-672

HH37

HH37

HH37

HH37

BBJ2

H

IbZ2-712

HHJ2

H

HHJ2

H

BBO8

H

IbZ2-673

HHk6

HHk6

HHk6

HHk6

BBJ2

H

IbZ2-713

HHk11

H

HHk11

H

BBO8

H

IbZ2-674

NA3

NA3

NA3

NA3

BBJ2

H

IbZ2-714

Me

Me

Me

Me

BBO8

H

IbZ2-675

HHJ2

HHJ2

HHJ2

HHJ2

BBJ2

H

IbZ2-715

PH

PH

PH

PH

BBO8

H

IbZ2-676

HHk11

HHk11

HHk11

HHk11

BBJ2

H

IbZ2-716

NA1

NA1

NA1

NA1

BBO8

H

[ Table 36Z2]

TABLE 36Z2

RN11Z2

RN21Z2

RN12Z2

RN22Z2

Ba1Z2Ba2Z2

R1Z2

RN11Z2

RN21Z2

RN12Z2

RN22Z2

Ba1Z2Ba2Z2

R1Z2

IbZ2-717

HHk8

HHk8

HHk8

HHk8

BBO8

H

IbZ2-757

HHk7

H

HHk7

H

BBO10

H

IbZ2-718

NA2

NA2

NA2

NA2

BBO8

H

IbZ2-758

HH37

H

HH37

H

BBO10

H

IbZ2-719

HHk7

HHk7

HHk7

HHk7

BBO8

H

IbZ2-759

HHk6

H

HHk6

H

BBO10

H

IbZ2-720

HH37

HH37

HH37

HH37

BBO8

H

IbZ2-760

NA3

H

NA3

H

BBO10

H

IbZ2-721

HHk6

HHk6

HHk6

HHk6

BBO8

H

IbZ2-761

HHJ2

H

HHJ2

H

BBO10

H

IbZ2-722

NA3

NA3

NA3

NA3

BBO8

H

IbZ2-762

HHk11

H

HHk11

H

BBO10

H

IbZ2-723

HHJ2

HHJ2

HHJ2

HHJ2

BBO8

H

IbZ2-763

Me

Me

Me

Me

BBO10

H

IbZ2-724

HHk11

HHk11

HHk11

HHk11

BBO8

H

IbZ2-764

PH

PH

PH

PH

BBO10

H

IbZ2-725

NA1

Me

NA1

Me

BBO8

H

IbZ2-765

NA1

NA1

NA1

NA1

BBO10

H

IbZ2-726

HHk8

Me

HHk8

Me

BBO8

H

IbZ2-766

HHk8

HHk8

HHk8

HHk8

BBO10

H

IbZ2-727

NA2

Me

NA2

Me

BBO8

H

IbZ2-767

NA2

NA2

NA2

NA2

BBO10

H

IbZ2-728

HHk7

Me

HHk7

Me

BBO8

H

IbZ2-768

HHk7

HHk7

HHk7

HHk7

BBO10

H

IbZ2-729

HH37

Me

HH37

Me

BBO8

H

IbZ2-769

HH37

HH37

HH37

HH37

BBO10

H

IbZ2-730

HHk6

Me

HHk6

Me

BBO8

H

IbZ2-770

HHk6

HHk6

HHk6

HHk6

BBO10

H

IbZ2-731

NA3

Me

NA3

Me

BBO8

H

IbZ2-771

NA3

NA3

NA3

NA3

BBO10

H

IbZ2-732

HHJ2

Me

HHJ2

Me

BBO8

H

IbZ2-772

HHJ2

HHJ2

HHJ2

HHJ2

BBO10

H

IbZ2-733

HHk11

Me

HHk11

Me

BBO8

H

IbZ2-773

HHk11

HHk11

HHk11

HHk11

BBO10

H

IbZ2-734

H

H

H

H

BBO10

H

IbZ2-774

NA1

Me

NA1

Me

BBO10

H

IbZ2-735

Me

H

Me

H

BBO10

H

IbZ2-775

HHk8

Me

HHk8

Me

BBO10

H

IbZ2-736

Et

H

Et

H

BBO10

H

IbZ2-776

NA2

Me

NA2

Me

BBO10

H

IbZ2-737

PH

H

PH

H

BBO10

H

IbZ2-777

HHk7

Me

HHk7

Me

BBO10

H

IbZ2-738

Bu

H

Bu

H

BBO10

H

IbZ2-778

HH37

Me

HH37

Me

BBO10

H

IbZ2-739

TBu

H

TBu

H

BBO10

H

IbZ2-779

HHk6

Me

HHk6

Me

BBO10

H

IbZ2-740

Hex

H

Hex

H

BBO10

H

IbZ2-780

NA3

Me

NA3

Me

BBO10

H

IbZ2-741

Oct

H

Oct

H

BBO10

H

IbZ2-781

HHJ2

Me

HHJ2

Me

BBO10

H

IbZ2-742

2EH

H

2EH

H

BBO10

H

IbZ2-782

HHk11

Me

HHk11

Me

BBO10

H

IbZ2-743

CHM

H

CHM

H

BBO10

H

IbZ2-783

HHj10

H

HHj10

H

BB2

H

IbZ2-744

CH

H

CH

H

BBO10

H

IbZ2-784

HHk1

H

HHk1

H

BB3

H

IbZ2-745

BZ

H

BZ

H

BBO10

H

IbZ2-785

HH61

H

HH61

H

BB4

H

IbZ2-746

EOE

H

EOE

H

BBO10

H

IbZ2-786

HH65

H

HH65

H

BB5

H

IbZ2-747

ALL

H

ALL

H

BBO10

H

IbZ2-787

HHk5

H

HHk5

H

BB7

H

IbZ2-748

NH2

H

NH2

H

BBO10

H

IbZ2-788

HHf14

H

HHf14

H

BB9

H

IbZ2-749

CBM

H

CBM

H

BBO10

H

IbZ2-789

HHk6

H

HHk6

H

BB10

H

IbZ2-750

COM

H

COM

H

BBO10

H

IbZ2-790

HH37

H

HH37

H

BB12

H

IbZ2-751

COE

H

COE

H

BBO10

H

IbZ2-791

HH46

H

HH46

H

BB13

H

IbZ2-752

CBA

H

CBA

H

BBO10

H

IbZ2-792

HHk3

H

HHk3

H

BB15

H

IbZ2-753

HYE

H

HYE

H

BBO10

H

IbZ2-793

HH22

H

HH22

H

BB16

H

IbZ2-754

NA1

H

NA1

H

BBO10

H

IbZ2-794

HHc1

H

HHc1

H

BB17

H

IbZ2-755

HHk8

H

HHk8

H

BBO10

H

IbZ2-795

NA4

H

NA4

H

BB18

H

IbZ2-756

NA2

H

NA2

H

BBO10

H

IbZ2-796

HH40

H

HH40

H

BB20

H

[ Table 37Z2]

TABLE 37Z2

For example, compound IaZ2-1 is a compound represented by formula (IaZ 2-1).

Preferably IaZ2-1 to IaZ2-165, IaZ2-223 to IaZ2-494, compound IbZ2-1 to IbZ2-248, compound IbZ2-311 to IbZ2-840, compound IcZ2-1 to IcZ2-234, more preferably IaZ2-1 to IaZ2-165, IaZ2-223 to IaZ2-436, compound IbZ2-1 to IbZ2-248, compound IbZ2-311 to IbZ2-782, compound IcZ2-1 to IcZ2-234,

More preferred are compound IaZ2-1 to compound IaZ2-165, compound IbZ2-1 to compound IbZ2-248, and compound IcZ2-1 to compound IcZ2-234, still more preferred are compound IaZ2-1 to compound IaZ2-111, compound IbZ2-1 to compound IbZ2-248, and compound IcZ2-1 to compound IcZ2-234, and particularly preferred are compound IaZ2-1 to compound IaZ2-54, and compound IbZ2-1 to compound IbZ 2-186.

Specific examples of the compound IZ2 include: tables 1Z2, 2Z2, 3Z2, 4Z2, 5Z2, 6Z2, 7Z2, 8Z2, 9Z2, 10Z2, 11Z2, 12Z2, 13Z2, 14Z2, 15Z2, 16Z2, 17Z2, 18Z2, 19Z2, 20Z2, 21Z2, 22Z2, 27Z2, 28Z2, 29Z2, 30Z2, 31Z2, 32Z2, 33Z2, 34Z2, 35Z2, 36Z2, and 37Z2 show that 1 to 3 hydrogen atoms contained in the compound are replaced with — SO₃M or-CO₂M is substituted. For example, a compound having 1 to 3 sulfo groups bonded to compound IaZ2-1 of table 1Z2 is represented by the following structure. Wherein, in the formula, - (SO)₃H) Represents a compound IaZ2-1 in which any hydrogen atom in table 1Z2 is substituted.

Preferably, 1 to 3-SO groups are bonded to the compound IaZ2-1 to the compound IaZ2-165, the compound IaZ2-223 to the compound IaZ2-494, the compound IbZ2-1 to the compound IbZ2-248, the compound IbZ2-311 to the compound IbZ2-840, and the compound IcZ2-1 to the compound IcZ2-234 ₃M or-CO₂A compound formed by the reaction of M,

more preferably, the compound is one selected from the group consisting of compounds IaZ2-1 to IaZ2-165, IaZ2-223 to IaZ2-436, and IbZ2-1 to IbZ2-248Compounds IbZ 2-311-IbZ 2-782, compounds IcZ 2-1-IcZ 2-234, to which 1-3-SO groups are bonded₃M or-CO₂A compound formed by the reaction of M,

more preferably, 1 to 3-SO groups are bonded to the compound IaZ2-1 to the compound IaZ2-165, the compound IbZ2-1 to the compound IbZ2-248, and the compound IcZ2-1 to the compound IcZ2-234₃M or-CO₂A compound formed by the reaction of M,

more preferably, 1 to 3-SO groups are bonded to the compound IaZ2-1 to the compound IaZ2-111, the compound IbZ2-1 to the compound IbZ2-248, and the compound IcZ2-1 to the compound IcZ2-234₃M or-CO₂A compound formed by the reaction of M,

particularly preferably, 1 to 3-SO groups are bonded to the compound IaZ2-1 to the compound IaZ2-54 and the compound IbZ2-1 to the compound IbZ2-186₃M or-CO₂M, or a salt thereof.

As a bond with-CO₂Examples of the compound of M include compounds wherein 2-CO-CO groups are bonded to compound IbZ2-2, compound IbZ2-3, compound IbZ2-4, compound IbZ2-12, compound IbZ2-126, compound IbZ2-127, compound IbZ2-687, compound IbZ2-370, and the like₂Among the compounds of H, particularly, compounds IbZ2 to 317, compounds IbZ2 to 318, compounds IbZ2 to 319, compounds IbZ2 to 320, compounds IbZ2 to 515, compounds IbZ2 to 516, compounds IbZ2 to 706, compounds IbZ2 to 389 and the like are particularly preferable.

As the compound (IZ2), the following compounds are preferable: in the formula (IZ2), R^CO1Z2And R^CO1Z2Are identical radicals, R^O1Z2Is a hydrogen atom, or may have a radical selected from the group consisting of-SO₃M and-CO₂A C1-20 hydrocarbon group as a substituent in the group consisting of M, R^N1Z2And R^N2Z2Independently of one another, a hydrogen atom, -CO-R^102Z2、-COO-R^101Z2、-CON(R^102Z2)₂Or may have a structure selected from the group consisting of-SO₃M and-CO₂M in the groupA substituent group of a hydrocarbon group having 1 to 20 carbon atoms, R^1Z2Is a hydrogen atom and may have a radical selected from the group consisting of-SO₃M and-CO₂A C1-20 hydrocarbon group, -SO₃M or-CO₂M，R^2Z2～R^5Z2Each independently represents a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogen atom, or-N (R)^102Z2)₂A C1-20 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R^102Z2、-O-R^102Z2、-SO₃M or-CO₂M，R^102Z2Is a hydrogen atom, or may have a radical selected from the group consisting of-SO₃M and-CO₂A hydrocarbyl group having 1 to 20 carbon atoms as a substituent in the group consisting of M,

R^101Z2may have a structure selected from the group consisting of-SO₃M and-CO₂A compound in which the substituent in the group consisting of M is a hydrocarbon group having 1 to 20 carbon atoms, and M is a hydrogen atom or an alkali metal atom;

more preferred are the following compounds:

R^CO1Z2and R^CO1Z2Are identical radicals, R^O1Z2Is a hydrogen atom, or may have a radical selected from the group consisting of-SO ₃M and-CO₂A C1-10 hydrocarbon group as a substituent in the group consisting of M, R^N1Z2And R^N2Z2Independently of one another, a hydrogen atom, -CO-R^102Z2、-CON(R^102Z2)₂Or may have a structure selected from the group consisting of-SO₃M and-CO₂A C1-10 hydrocarbon group as a substituent in the group consisting of M, R^1Z2Is a hydrogen atom, R^2Z2～R^5Z2Each independently represents a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, or-N (R)^102Z2)₂A C1-10 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R^102Z2、-O-R^102Z2、-SO₃M or-CO₂M，R^102Z2Is a hydrogen atom, or may have a radical selected from the group consisting of-SO₃M and-CO₂A C1-10 hydrocarbon group as a substituent in the group consisting of M, R^101Z2To be provided withIs selected from-SO₃M and-CO₂A compound in which the substituent in the group consisting of M is a hydrocarbon group having 1 to 10 carbon atoms, and M is a hydrogen atom or an alkali metal atom;

further preferred are the following compounds:

R^CO1Z2and R^CO1Z2Are identical radicals, R^O1Z2Is a hydrogen atom, or may have a radical selected from the group consisting of-SO₃M and-CO₂A C1-10 hydrocarbon group as a substituent in the group consisting of M, R^N1Z2And R^N2Z2Independently of one another, a hydrogen atom, -CO-R^102Z2、-CON(R^102Z2)₂Or may have a structure selected from the group consisting of-SO₃M and-CO₂A C1-10 hydrocarbon group as a substituent in the group consisting of M, R ^1Z2Is a hydrogen atom, R^2Z2～R^5Z2Each independently represents a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, or-N (R)^102Z2)₂Nitro, trifluoromethyl, -O-R^102Z2、-SO₃M or-CO₂M，R^102Z2Is a hydrogen atom, or may have a radical selected from the group consisting of-SO₃M and-CO₂A C1-10 hydrocarbon group as a substituent in the group consisting of M, R^101Z2May have a structure selected from the group consisting of-SO₃M and-CO₂And M is a compound in which the substituent in the group consisting of M is a hydrocarbon group having 1 to 10 carbon atoms and M is a hydrogen atom or an alkali metal atom.

For compound IZ2, R^1Z2In the case of a hydrogen atom, the compound represented by the formula (pt1Z2) (hereinafter, may be referred to as a phthalonitrile compound) may be produced by reacting a compound represented by the formula (pt2Z2) (hereinafter, may be referred to as an alkoxide compound), and then further reacting the compound represented by the formula (pt3Z2) and the compound represented by the formula (pt4Z2) in the presence of an acid. In addition, R^1Z2When not a hydrogen atom, the compound is further reacted with a compound represented by the formula (pt5Z2) to produce a compound IZ 2.

In [ formula (pt1Z2), formula (pt2Z2), formula (pt3Z2), formula (pt4Z2), formula (pt5Z2) and formula (IZ2), R^CO1Z2、R^CO2Z2、R^1Z2、R^2Z2、R^3Z2、R^4Z2And R^5Z2The same meanings as described above are indicated. R^14Z2Represents an alkyl group having 1 to 20 carbon atoms. M^1Z2Represents an alkali metal atom.

LG represents a halogen atom, a mesyloxy group, a tosyloxy group or a trifluormesyloxy group. ]

As R^14Z2Examples of the alkyl group having 1 to 20 carbon atoms include methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec-butyl, tert-butyl, and the like, and preferred examples thereof include alkyl groups having 1 to 6 carbon atoms.

As M^1Z2Examples of the alkali metal atom include a lithium atom, a sodium atom and a potassium atom.

The amount of the alkoxide compound used is usually 0.1 to 10 moles, preferably 0.2 to 5 moles, more preferably 0.3 to 3 moles, and still more preferably 0.4 to 2 moles, based on 1 mole of the phthalonitrile compound.

The amount of the compound pt3Z2 used is usually 1 to 10 moles, preferably 1 to 5 moles, more preferably 1 to 3 moles, and still more preferably 1 to 2 moles, based on 1 mole of the phthalonitrile compound.

The amount of the compound pt4Z2 used is usually 1 to 10 moles, preferably 1 to 5 moles, more preferably 1 to 3 moles, and still more preferably 1 to 2 moles, based on 1 mole of the phthalonitrile compound.

Examples of the acid include inorganic acids such as hydrochloric acid, hydrobromic acid, hydroiodic acid, sulfuric acid, nitric acid, fluorosulfonic acid, and phosphoric acid; sulfonic acids such as methanesulfonic acid, trifluoromethanesulfonic acid, and p-toluenesulfonic acid; examples of the carboxylic acid include acetic acid, citric acid, formic acid, gluconic acid, lactic acid, oxalic acid, tartaric acid, and the like, and preferably include hydrochloric acid, hydrobromic acid, sulfuric acid, methanesulfonic acid, trifluoromethanesulfonic acid, p-toluenesulfonic acid, and carboxylic acid, and more preferably include acetic acid.

The amount of the acid used is usually 1 to 20 moles, preferably 1 to 10 moles, more preferably 1 to 8 moles, and still more preferably 1 to 6 moles, based on 1 mole of the phthalonitrile compound.

The reaction of the phthalonitrile compound, the alkoxide compound, the compound pt3Z2, and the compound pt4Z2 can be usually carried out in the presence of a solvent.

As the solvent, water may be mentioned; nitrile solvents such as acetonitrile; alcohol solvents such as methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, and 1-octanol; ether solvents such as tetrahydrofuran; ketone solvents such as acetone; ester solvents such as ethyl acetate; aliphatic hydrocarbon solvents such as hexane; aromatic hydrocarbon solvents such as toluene; halogenated hydrocarbon solvents such as dichloromethane and chloroform; amide solvents such as N, N-dimethylformamide and N-methylpyrrolidone; sulfoxide solvents such as dimethyl sulfoxide, preferably include water, nitrile solvents, alcohol solvents, ether solvents, ketone solvents, ester solvents, aromatic hydrocarbon solvents, halogenated hydrocarbon solvents, amide solvents and sulfoxide solvents, more preferably include water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, tetrahydrofuran, acetone, ethyl acetate, toluene, dichloromethane, chloroform, N-dimethylformamide, N-methylpyrrolidone and dimethyl sulfoxide, still more preferably include water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, acetone, dichloromethane, chloroform, N-dimethylformamide, N-methylpyrrolidone and dimethyl sulfoxide, and particularly preferably include water, methanol, ethanol, methanol, ethanol, butanol, methanol, ethanol, 1-butanol, 1-pentanol, 1-octanol, acetone, dichloromethane, chloroform, N-methylpyrrolidone and dimethyl sulfoxide, Acetonitrile, methanol, ethanol and 2-propanol.

The amount of the solvent used is usually 1 to 1000 parts by mass per 1 part by mass of the phthalonitrile compound.

The reaction temperature is usually 0 to 200 ℃, preferably 0 to 100 ℃, more preferably 0 to 70 ℃, and further preferably 0 to 50 ℃. The reaction time is usually 0.5 to 300 hours.

With respect to the amount of compound pt5Z2 used, relative to R^1Z2The amount of the compound IZ21 which is a hydrogen atom is usually 1 to 10 moles, preferably 1 to 5 moles, more preferably 1 to 3 moles, and still more preferably 1 to 2 moles.

When the compound pt5Z2 is reacted, a base is preferably coexisted. Examples of the base include organic bases such as triethylamine, 4- (N, N-dimethylamino) pyridine, and piperidine; metal alkoxides such as sodium methoxide, sodium ethoxide, sodium tert-butoxide, and potassium tert-butoxide; organic metal compounds such as butyl lithium, tert-butyl lithium and phenyl lithium; inorganic bases such as lithium hydroxide, sodium hydroxide and potassium hydroxide.

As for the amount of the base used, with respect to R^1Z2The amount of the compound IZ21 which is a hydrogen atom is usually 1 to 10 moles, preferably 1 to 5 moles, more preferably 1 to 3 moles, and still more preferably 1 to 2 moles.

The reaction of compound pt5Z2 can generally be carried out in the presence of a solvent. The solvent may be selected from the same ranges as described above.

As to the amount of the solvent used, with respect to R^1Z2The amount of the compound IZ 21 is usually 1 to 1000 parts by mass. The reaction temperature of the compound pt5Z2 is usually-90 to 200 ℃, preferably-80 to 100 ℃, and more preferably 0 to 50 ℃. The reaction time is usually 0.5 to 300 hours.

Compound IZ2 having no sulfo group or-SO₃M²²In the case of (3), the compound IZ2 can be reacted with a sulfonating agent such as fuming sulfuric acid or chlorosulfonic acid to introduce a sulfo group or-SO₃M²。

M²²Represents an alkali metal atom.

As M²²Examples of the alkali metal atom include a lithium atom, a sodium atom and a potassium atom.

With respect to SO in oleum₃The amount of (b) is usually 1 to 50 mol, preferably 5 to 40 mol, more preferably 5 to 30 mol, and still more preferably 5 to 25 mol based on 21 mol of the compound IZ.

The amount of sulfuric acid used in the oleum is usually 1 to 200 moles, preferably 10 to 100 moles, more preferably 10 to 75 moles, and still more preferably 10 to 50 moles, based on 21 moles of the compound IZ.

The amount of chlorosulfonic acid used is usually 1 to 500 moles, preferably 10 to 300 moles, more preferably 10 to 200 moles, and still more preferably 10 to 150 moles, based on 21 moles of the compound IZ.

The reaction temperature of sulfonation is usually-20 to 200 ℃, preferably-10 to 100 ℃, and more preferably 0 to 50 ℃. The reaction time is usually 0.5 to 300 hours.

The method for extracting the compound IZ2 from the reaction mixture is not particularly limited, and it can be extracted by various known methods. For example, after the reaction is completed, the reaction mixture is filtered to extract the compound IZ 2. Further, the residue obtained after filtration may be subjected to column chromatography, recrystallization, or the like. After the completion of the reaction, the solvent of the reaction mixture may be distilled off and then purified by column chromatography.

< Compound IZ3 >)

Compound IZ3 is a compound represented by formula (IZ 3).

[ formula (IZ3), R^1Z3、R^2Z3、R^3Z3、R^4Z3、R^5Z3、R^6Z3And R^7Z3Independently of one another, represents a hydrogen atom, -CO-R^102Z3、-COO-R^101Z3、-OCO-R^102Z3、-COCO-R^102Z3、-O-R^102Z3、-SO₂-R^101Z3、-SO₂N(R^102Z3)₂、-CON(R^102Z3)₂、-N(R^102Z3)₂、-NHCO-R^102Z3、-NHCO-N(R^102Z3)₂、-NHCOOR^102Z3、-OCON(R^102Z3)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent. R^2Z3And R^3Z3、R^3Z3And R^4Z3And R^4Z3And R^5Z3Each of which may be bonded to each other to form a ring. R^101Z3The alkyl group may have a substituent and has 1 to 40 carbon atoms, or a heterocyclic group may have a substituent. R^102Z3Represents a hydrogen atom or an optionally substituted carbonA hydrocarbon group having 1 to 40 atoms or a heterocyclic group which may have a substituent. M represents a hydrogen atom or an alkali metal atom. R ^101Z3、R^102Z3And when there are a plurality of M, they may be the same or different. The wavy line indicates the E-body or the Z-body.]

R^1Z3、R^2Z3、R^3Z3、R^4Z3、R^5Z3、R^6Z3、R^7Z3、R^101Z3And R^102Z3The number of carbon atoms of the hydrocarbon group is 1 to 40, preferably 1 to 30, more preferably 1 to 20, still more preferably 1 to 15, and particularly preferably 1 to 10.

R^1Z3、R^2Z3、R^3Z3、R^4Z3、R^5Z3、R^6Z3、R^7Z3、R^101Z3And R^102Z3The hydrocarbon group having 1 to 40 carbon atoms may be an aliphatic hydrocarbon group or an aromatic hydrocarbon group, and the aliphatic hydrocarbon group may be saturated or unsaturated, and may be a chain or alicyclic group.

As R^1Z3、R^2Z3、R^3Z3、R^4Z3、R^5Z3、R^6Z3、R^7Z3、R^101Z3And R^102Z3Examples of the saturated or unsaturated chain hydrocarbon group include straight chain alkyl groups such as methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, heptadecyl, octadecyl, and eicosyl; branched alkyl groups such as isopropyl, isobutyl, sec-butyl, tert-butyl, (2-ethyl) butyl, isopentyl, neopentyl, tert-pentyl, (1-methyl) pentyl, (2-methyl) pentyl, (1-ethyl) pentyl, (3-ethyl) pentyl, isohexyl, (5-methyl) hexyl, (2-ethyl) hexyl and (3-ethyl) heptyl; alkenyl groups such as vinyl, 1-propenyl, 2-propenyl (allyl), (1-methyl) vinyl, 2-butenyl, 3-butenyl, 1, 3-butadienyl, (1- (2-propenyl)) vinyl, (1, 2-dimethyl) propenyl, and 2-pentenyl; and so on. The number of carbon atoms of the saturated or unsaturated chain hydrocarbon group is preferably 1 to 30, more preferably 1 to 20, further preferably 1 to 15, particularly preferably 1 to 10, further more preferably 1 to 8, and particularly preferably 1 to 5. Wherein A linear or branched alkyl group having 1 to 10 carbon atoms, more preferably 1 to 8 carbon atoms is particularly preferable, and a methyl group, an ethyl group, or a tert-butyl group is particularly preferable.

As R^1Z3、R^2Z3、R^3Z3、R^4Z3、R^5Z3、R^6Z3、R^7Z3、R^101Z3And R^102Z3Examples of the saturated or unsaturated alicyclic hydrocarbon group include cyclopropyl, 1-methylcyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, 1-methylcyclohexyl, 2-methylcyclohexyl, 3-methylcyclohexyl, 4-methylcyclohexyl, 1, 2-dimethylcyclohexyl, 1, 3-dimethylcyclohexyl, 1, 4-dimethylcyclohexyl, 2, 3-dimethylcyclohexyl, 2, 4-dimethylcyclohexyl, 2, 5-dimethylcyclohexyl, 2, 6-dimethylcyclohexyl, 3, 4-dimethylcyclohexyl, 3, 5-dimethylcyclohexyl, 2-dimethylcyclohexyl, 3-dimethylcyclohexyl, 4-dimethylcyclohexyl, cyclooctyl, 2,4, 6-trimethylcyclohexyl, and, Cycloalkyl groups such as 2,2,6, 6-tetramethylcyclohexyl, 3,5, 5-tetramethylcyclohexyl, 4-pentylcyclohexyl, 4-octylcyclohexyl and 4-cyclohexylcyclohexyl; cycloalkenyl groups such as cyclohexenyl (e.g., cyclohex-2-ene, cyclohex-3-ene), cycloheptenyl, cyclooctenyl, and the like; norbornyl, adamantyl, bicyclo [2.2.2]An octyl group and the like. The number of carbon atoms of the saturated or unsaturated alicyclic hydrocarbon group is preferably 3 to 30, more preferably 3 to 20, still more preferably 4 to 20, yet more preferably 4 to 15, even more preferably 5 to 15, and most preferably 5 to 10. Among them, cyclopentyl, cyclohexyl, cycloheptyl, and cyclooctyl are particularly preferable.

As R^1Z3、R^2Z3、R^3Z3、R^4Z3、R^5Z3、R^6Z3、R^7Z3、R^101Z3And R^102Z3Examples of the aromatic hydrocarbon group include a phenyl group, an o-tolyl group, a m-tolyl group, a p-tolyl group, a 2, 3-dimethylphenyl group, a 2, 4-dimethylphenyl group, a 2, 5-dimethylphenyl group, a 2, 6-dimethylphenyl group, a 3, 4-dimethylphenyl group, a 3, 5-dimethylphenyl group, a 4-vinylphenyl group, an o-isopropylphenyl group, a m-isopropylphenyl group, a p-isopropylphenyl group, an o-tert-butylphenyl group, a m-tert-butylphenyl group, a p-tert-butylphenyl group, and a homo-tert-butylphenyl groupAromatic hydrocarbon groups such as a trimethylphenyl group, a 4-ethylphenyl group, a 4-butylphenyl group, a 4-pentylphenyl group, a 2, 6-bis (2-propyl) phenyl group, a 4-cyclohexylphenyl group, a 2,4, 6-trimethylphenyl group, a 4-octylphenyl group, a 4-vinylphenyl group, a 1-naphthyl group, a 2-naphthyl group, a 5,6,7, 8-tetrahydro-1-naphthyl group, a 5,6,7, 8-tetrahydro-2-naphthyl group, a fluorenyl group, a phenanthryl group, an anthracenyl group, and a pyrenyl group; and so on. The number of carbon atoms of the aromatic hydrocarbon group is preferably 6 to 30, more preferably 6 to 20, and further preferably 6 to 15.

R^1Z3、R^2Z3、R^3Z3、R^4Z3、R^5Z3、R^6Z3、R^7Z3、R^101Z3And R^102Z3The hydrocarbon group may be a combination of the hydrocarbon groups listed above (for example, an aromatic hydrocarbon group, and at least 1 of a chain hydrocarbon group and an alicyclic hydrocarbon group), and examples thereof include aralkyl groups such as benzyl, phenethyl, and 1-methyl-1-phenylethyl; arylalkenyl groups such as phenylvinyl (styryl); arylalkynyl groups such as phenylethynyl; a phenyl group having 1 or more phenyl groups bonded thereto, such as a biphenyl group and a terphenyl group; cyclohexylmethylphenyl, benzylphenyl, (dimethyl (phenyl) methyl) phenyl, and the like.

For R^1Z3、R^2Z3、R^3Z3、R^4Z3、R^5Z3、R^6Z3、R^7Z3、R^101Z3And R^102Z3Examples of the group represented by the above-mentioned groups, which are a combination of the above-mentioned hydrocarbon groups (e.g., chain hydrocarbon groups and alicyclic hydrocarbon groups), include alkyl groups to which 1 or more alicyclic hydrocarbon groups are bonded, such as cyclopropylmethyl groups, cyclopropylethyl groups, cyclobutylmethyl groups, cyclobutylethyl groups, cyclopentylmethyl groups, cyclopentylethyl groups, cyclohexylmethyl groups, 2-methylcyclohexylmethyl groups, cyclohexylethyl groups, and adamantylmethyl groups.

The number of carbon atoms is preferably 4 to 30, more preferably 6 to 30, further preferably 6 to 20, further preferably 4 to 15, and particularly preferably 6 to 15.

R^1Z3、R^2Z3、R^3Z3、R^4Z3、R^5Z3、R^6Z3、R^7Z3、R^101Z3And R^102Z3The hydrocarbyl group represented may haveAnd (4) a substituent. The substituent may have a valence of 1 or 2. For substituents having a valence of 2, preferably 2 chemical bonds are bonded to the same carbon atom to form a double bond.

Examples of the substituent having a valence of 1 include:

methoxy group, ethoxy group, propoxy group, isopropoxy group, butoxy group, isobutoxy group, sec-butoxy group, tert-butoxy group, pentyloxy group, hexyloxy group, (2-ethyl) hexyloxy group, heptyloxy group, octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, dodecyloxy group, (2-ethyl) hexyloxy group, eicosyloxy group, 1-phenylethoxy group, 1-methyl-1-phenylethoxy group, phenyloxy group, o-tolyloxy group, 2, 3-dimethylphenyloxy group, 2, 4-dimethylphenyloxy group, 2, 5-dimethylphenyloxy group, 2, 6-dimethylphenyloxy group, 3, 4-dimethylphenyloxy group, 3, 5-dimethylphenyloxy group, 2-dicyanophenyloxy group, 2, 3-dicyanophenyloxy group, 2-dicyanophenyloxy group, 2, 4-dicyanophenyloxy group, 2, 5-dicyanophenyloxy group, 2, 6-dicyanophenyloxy group, 3, 4-dicyanophenyloxy group, 3, 5-dicyanophenyloxy group, 4-methoxyphenyloxy group, an oxy group having a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like) bonded to one side, such as a 2-methoxyphenyloxy group, a 3-methoxyphenyloxy group, a 4-ethoxyphenyloxy group, a 2-ethoxyphenyloxy group, a 3-ethoxyphenyloxy group, or a group represented by the following chemical formula;

A thio group (sulfo group) to which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) is bonded, such as a methylthio group, an ethylthio group, a propylthio group, a butylthio group, a tert-butylthio group, a pentylthio group, a hexylthio group, (2-ethyl) hexylthio group, a heptylthio group, an octylthio group, a nonylthio group, a decylthio group, an undecylthio group, a dodecylthio group, an eicosylthio group, a phenylthio group, and an o-tolylthio group;

epoxy, oxetanyl, tetrahydrofuranyl, tetrahydropyranyl;

a formyl group;

a carbonyl group (preferably 2 to 12 carbon atoms when the carbonyl group is an alkanoyl group) having a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 11 carbon atoms) or a derivative thereof (for example, a derivative thereof such as a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), or an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)) bonded thereto, such as an acetyl group, a propionyl group, a butyryl group, a 2, 2-dimethylpropionyl group, a pentanoyl group, a hexanoyl group, (2-ethyl) hexanoyl group, a heptanoyl group, an octanoyl group, a nonanoyl group, a decanoyl group, an undecanoyl group, a dodecanoyl group, an heneicosanoyl group, and a benzoyl group;

An oxycarbonyl group in which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) is bonded, such as a methoxycarbonyl group, an ethoxycarbonyl group, a propoxycarbonyl group, a butoxycarbonyl group, a tert-butoxycarbonyl group, a pentyloxycarbonyl group, a hexyloxycarbonyl group, (2-ethyl) a hexyloxycarbonyl group, a heptyloxycarbonyl group, an octyloxycarbonyl group, a nonyloxycarbonyl group, a decyloxycarbonyl group, a undecyloxycarbonyl group, a dodecyloxycarbonyl group, an eicosyloxycarbonyl group, a phenyloxycarbonyl group, or an o-tolyloxycarbonyl group represented by the following chemical formula);

an amino group; n-methylamino, N-dimethylamino, N-ethylamino, N-diethylamino, N-propylamino, N-dipropylamino, N-isopropylamino, N-diisopropylamino, N-butylamino, N-dibutylamino, N-isobutylamino, N-diisobutylamino, N-sec-butylamino, N-di-sec-butylamino, N-tert-butylamino, N-di-tert-butylamino, N-pentylamino, N-dipentylamino, N- (1-ethylpropyl) amino, N-di (1-ethylpropyl) amino, N-hexylamino, N-dihexylamino, N- (2-ethyl) hexylamino, N-diethylamino, N-propylamino, N-dipropylamino, N-isopropylamino, N-di-sec-butylamino, N-pentylamino, N-dipentylamino, N-1-ethylpropyl) amino, N-di (1-ethylpropyl) amino, N-hexylamino, N-butylamino, N-butylamino, N-di-butylamino, N-butylamino, N, n, N-di (2-ethyl) hexylamino group, N-heptylamino group, N-diheptylamino group, N-octylamino group, N-dioctylamino group, N-nonylamino group, N-dinonylamino group, N-phenylamino group, N-diphenylamino group, N-ethylmethylamino group, N-propylmethylamino group, N-isopropylmethylamino group, N-butylmethylamino group, N-decylamino group, N-decylmethylamino group, N-undecylamino group, N-undecylmethylamino group, N-dodecylamino group, N-dodecylmethylamino group, N-eicosylamino group, N-eicosylmethyl amino group, An amino group substituted with 1 or 2 hydrocarbon groups having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or derivative groups thereof (for example, groups derived from carboxyl, sulfo, nitro, hydroxyl, halogen (preferably chlorine atom), alkylsulfamoyl having 1 to 10 carbon atoms (preferably octylsulfamoyl), and the like, such as an N, N-tert-butylmethylamino group, an N, N-phenylmethylamino group, and the like, and groups represented by the following chemical formula);

A sulfamoyl group; n-methylsulfamoyl, N-dimethylsulfamoyl, N-ethylsulfamoyl, N-diethylsulfamoyl, N-propylsulfamoyl, N-dipropylsulfamoyl, N-isopropylsulfamoyl, N-diisopropylsulfamoyl, N-butylsulfamoyl, N-dibutylsulfamoyl, N-isobutylsulfamoyl, N-diisobutylsulfamoyl, N-sec-butylsulfamoyl, N-tert-butylsulfamoyl, N-di-tert-butylsulfamoyl, N-pentylsulfamoyl, N-dipentylsulfamoyl, N- (1-ethylpropyl) sulfamoyl, N-di (1-ethylpropyl) sulfamoyl, N-diethylsulfamoyl, N-di (1-ethylpropyl) sulfamoyl, N-diethylsulfamoyl, N-butylsulfamoyl, N-di (1-ethylpropyl) sulfamoyl, N-butylsulfamoyl, N-di (1-isobutylsulfamoyl), N-dibutylsulfamoyl, N, di (1-di (ethyl, N, N, N-hexylsulfamoyl, N-dihexylsulfamoyl, N- (2-ethyl) hexylsulfamoyl, N-di (2-ethyl) hexylsulfamoyl, N-heptylsulfamoyl, N-diheptylsulfamoyl, N-octylsulfamoyl, N-dioctylsulfamoyl, N-octylmethylsulfamoyl, N-nonylsulfamoyl, N-dinonylsulfamoyl, N-phenylsulfamoyl, N-diphenylsulfamoyl, N-ethylmethylsulfamoyl, N-propylmethylsulfamoyl, N-isopropylmethylsulfamoyl, N-butylmethylsulfamoyl, N-decylsulfamoyl, N-decylmethylsulfamoyl, Sulfamoyl groups substituted with 1 or 2 hydrocarbon groups having 1 to 20 (preferably 1 to 10) carbon atoms or derivative groups thereof (for example, groups derived from carboxyl, sulfo, nitro, hydroxyl, halogen (preferably chlorine atom), alkylsulfamoyl having 1 to 10 carbon atoms (preferably octylsulfamoyl), and the like, such as N-undecylsulfamoyl, N-undecylmethylsulfamoyl, N-dodecylsulfamoyl, N-dodecylmethylsulfamoyl, N-eicosylsulfamoyl, N-eicosylmethylsulfamoyl, N-tert-butylmethylsulfamoyl, N-phenylmethylsulfamoyl, and the like, and groups represented by the following chemical formulae);

A formylamino group; acetylamino, propionylamino, butyrylamino, 2-dimethylpropionylamino, valerylamino, hexanoylamino, (2-ethyl) hexanoylamino, heptanoylamino, a carbonylamino group (preferably 1 to 12 carbon atoms in the case where the carbonylamino group is an alkanoylamino group), to which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 12 carbon atoms) or a derivative thereof (for example, a derivative thereof such as a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)) is bonded, such as an octanoylamino group, a nonanoylamino group, a decanoylamino group, a undecanoylamino group, a dodecanoylamino group, a heneicosanoylamino group, or a benzoylamino group represented by the following chemical formula;

a hydroxyl group; halogen atoms such as fluorine atom, chlorine atom, bromine atom and iodine atom; carboxy, -CO₂M²(M²Is an alkali metal, preferably lithium, sodium, potassium); sulfo, -SO₃M²(M²Is an alkali metal, preferably lithium, sodium, potassium); a nitro group; a cyano group; a formyloxy group; acetoxy, propionyloxy, butyryloxy, 2-dimethylpropionyloxy, pentanoyloxy, hexanoyloxy, (2-ethyl) hexanoyloxy, heptanoyloxy, a carbonyloxy group (preferably 1 to 10 carbon atoms in the case where the carbonyloxy group is an alkanoyloxy group) to which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or a derivative thereof (for example, a derivative thereof such as a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)) is bonded, such as an octanoyloxy group, a nonanoyloxy group, a decanoyloxy group, a undecanoyloxy group, a dodecanoyloxy group, a heneicosanoyloxy group, a benzoyloxy group, and the like, and a group represented by the following chemical formula;

A sulfonyl group having a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like) bonded thereto, such as a methylsulfonyl group, an ethylsulfonyl group, a propylsulfonyl group, a butylsulfonyl group, a pentylsulfonyl group, a hexylsulfonyl group, a (2-ethyl) hexylsulfonyl group, a heptylsulfonyl group, an octylsulfonyl group, a nonylsulfonyl group, a decylsulfonyl group, an undecylsulfonyl group, a dodecylsulfonyl group, an eicosylsulfonyl group, a phenylsulfonyl group, a p-tolylsulfonyl group, or the like represented by the following chemical formula;

a carbamoyl group; n-methylcarbamoyl, N-dimethylcarbamoyl, N-ethylcarbamoyl, N-diethylcarbamoyl, N-propylcarbamoyl, N-dipropylcarbamoyl, N-isopropylcarbamoyl, N-diisopropylcarbamoyl, N-butylcarbamoyl, N-dibutylcarbamoyl, N-isobutylcarbamoyl, N-diisobutylcarbamoyl, N-sec-butylcarbamoyl, N-di-sec-butylcarbamoyl, N-tert-butylcarbamoyl, N-di-tert-butylcarbamoyl, N-pentylcarbamoyl, N-dipentylcarbamoyl, N- (1-ethylpropyl) carbamoyl, N-ethylcarbamoyl, N-diethylcarbamoyl, N-isopropylcarbamoyl, N-diisopropylcarbamoyl, N-isopropylcarbamoyl, N-butylcarbamoyl, N-t-butylcarbamoyl, N-t-butylcarbamoyl, N-N-butylcarbamoyl, N-t-butylcarbamoyl, N-N-butylcarbamoyl, N-t-N-t-butylcarbamoyl, N-t-butylcarbamoyl, N-t, N, N-di (1-ethylpropyl) carbamoyl, N-hexylcarbamoyl, N-dihexylcarbamoyl, N- (2-ethyl) hexylcarbamoyl, N-di (2-ethyl) hexylcarbamoyl, N-heptylcarbamoyl, N-diheptylcarbamoyl, N-octylcarbamoyl, N-dioctylcarbamoyl, N-nonylcarbamoyl, N-octylmethylcarbamoyl, N-octylbutylcarbamoyl, N-dinonylcarbamoyl, N-phenylcarbamoyl, N-diphenylcarbamoyl, N-ethylmethylcarbamoyl, N-propylmethylcarbamoyl, N-ethylmethylcarbamoyl, N-propylmethylcarbamoyl, N-ethylhexylcarbamoyl, N-dihexylcarbamoyl, N- (2-ethyl) hexylcarbamoyl, N-octylcarbamoyl, N-diheptylcarbamoyl, N-octylcarbamoyl, N-nonylcarbamoyl, N-octylcarbamoyl, N-octylmethylcarbamoyl, N-octylcarbamoyl, N-octylmethylcarbamoyl, N-nonylcarbamoyl, N-dimethylcarbamoyl, N, a hydrocarbon group having 1 to 2 carbon atoms of 1 to 20 (preferably 1 to 10 carbon atoms) or a derivative thereof (for example, a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an N, N-isopropylmethylcarbamoyl group, an N, N-butylmethylcarbamoyl group, an N-decylmethylcarbamoyl group, an N, N-decylmethylcarbamoyl group, an N-undecylcarbamoyl group, an N, N-undecylmethylcarbamoyl group, an N-dodecylcarbamoyl group, an N, N-dodecylmethylcarbamoyl group, an N-eicosylcarbamoyl group, an N, N-eicosylmethylcarbamoyl group, an N, N-tert-butylmethylcarbamoyl group, an N, N-phenylmethylcarbamoyl group, etc., and a group represented by the following chemical formula, etc. (preferably a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), a derivative thereof, A carbamoyl group substituted with an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably, an octylsulfamoyl group) or the like;

A hydrocarbon group having 1 to 20 carbon atoms, which is obtained by substituting all hydrogen atoms with fluorine atoms such as a trifluoromethyl group, a perfluoroethyl group, a perfluoropropyl group, a perfluoroisopropyl group, a perfluorobutyl group, a perfluoropentyl group, a perfluorohexyl group, a perfluoroheptyl group, a perfluorooctyl group, a perfluorononyl group, a perfluorodecyl group, a perfluoroundecyl group, a perfluorododecyl group, a perfluoroeicosyl group, a perfluorocyclohexyl group, and a perfluorophenyl group;

a hydrocarbon group having 1 to 20 carbon atoms which has, as a substituent, a linear or branched alkyl group having 1 to 20 carbon atoms in which all hydrogen atoms are substituted with fluorine atoms, such as a perfluoroethylmethyl group, a perfluoropropylmethyl group, a perfluoroisopropylmethyl group, a perfluorobutylmethyl group, a perfluoropentylmethyl group, a perfluorohexylmethyl group, a perfluoroheptylmethyl group, a perfluorooctylmethyl group, a perfluorononylmethyl group, a perfluorodecylmethyl group, a perfluoroundecylmethyl group, a perfluorododecylmethyl group, or a perfluoroeicosylmethyl group;

a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) in which some hydrogen atoms are substituted with fluorine, such as a 2-fluorophenyl group, a 3-fluorophenyl group, a 4-fluorophenyl group, and a 2,4, 6-trifluorophenyl group;

-CO-SH、-CO-S-CH₃、-CO-S-CH₂CH₃、-CO-S-CH₂-CH₂-CH₃、-CO-S-CH₂-CH₂-CH₂-CH₃or a thiocarbonyl group, -CO-S-C, bonded to an alkyl group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) ₆H₅A thiocarbonyl group bonded to an aryl group having 6 to 20 carbon atoms; a group represented by the following chemical formula, — COCO-R (wherein R represents a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)), or the like);

-NRCONR represented by the following chemical formula₂(wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group having 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like), and R's may be the same or different from each other and may be bonded to each other to form a ring);

OCONR represented by the following chemical formula₂(wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group having 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octyl group) Sulfamoyl) and the like, and the R groups may be the same or different from each other and may be bonded to each other to form a ring);

a group represented by the following chemical formula-NRCOOR (wherein R represents a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like), wherein R may be the same or different from each other, and may be bonded to each other to form a ring);

*-OP(O)(OCH₃)₂etc.. OP (O) (OR)₂(wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group having 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like), and R's may be the same or different from each other and may be bonded to each other to form a ring);

*-Si(CH₃)₃、*-Si(CH₂CH₃)₃、*-Si(C₆H₅)₃and-Si (CH)₃)₂)₃Etc. -SiR ₃(wherein R is a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above)) Or a derivative thereof (e.g., a derivative thereof with a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like), wherein R's may be the same or different from each other, and may be bonded to each other to form a ring); and so on.

Examples of the substituent having a valence of 2 include an oxo group, a thioxo group, an imino group substituted with an alkyl group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms), and an imino group substituted with an aryl group having 6 to 20 carbon atoms. Examples of the imino group substituted with an alkyl group include CH₃-N＝、CH₃-CH₂-N＝、CH₃-(CH₂)₂-N ═ and CH₃-(CH₂)₃-N ═ and the like. Examples of the imino group substituted with an aryl group include C₆H₅-N ═ and the like.

As the substituent of the hydrocarbon group having 1 to 40 carbon atoms, preferred is a substituent of group s 1. The derivative group shown below is preferably a derivative group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like.

[ group s1]

An oxy group having a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof bonded to one side thereof;

a carbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof is bonded;

an oxycarbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof is bonded;

an amino group; amino substituted by 1 or 2 alkyl with 1-20 carbon atoms or derivative groups thereof; a sulfamoyl group; a sulfamoyl group substituted with 1 or 2 hydrocarbon groups having 1 to 20 carbon atoms or derivative groups thereof; a carbonylamino group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof is bonded; a hydroxyl group; a halogen atom; -CO₂M (preferably carboxyl group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom); -SO₃M (preferably sulfo) (M represents a hydrogen atom or an alkali metal atom, preferably hydrogenAn atom. ) (ii) a A nitro group; a cyano group; a carbonyloxy group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof is bonded; a sulfonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof is bonded; a carbamoyl group; carbamoyl substituted by 1 or 2 hydrocarbon groups having 1 to 20 carbon atoms or derivative groups thereof;

a hydrocarbon group having 1 to 20 carbon atoms, wherein all hydrogen atoms are substituted with fluorine atoms;

A hydrocarbon group having 1 to 20 carbon atoms, which has a linear or branched alkyl group having 1 to 20 carbon atoms, wherein all hydrogen atoms are substituted with fluorine atoms, as a substituent;

a hydrocarbon group having 1 to 20 carbon atoms, wherein a part of hydrogen atoms is substituted with fluorine;

an oxo group.

The substituent of the hydrocarbon group having 1 to 40 carbon atoms is more preferably a substituent of group s 2.

[ group s2]

An oxy group having a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof bonded to one side thereof;

a carbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded;

an oxycarbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded;

an amino group; an amino group substituted with 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms;

a sulfamoyl group; a sulfamoyl group substituted with 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms or derivative groups thereof; a carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded; a hydroxyl group; fluorine atom, chlorine atom, bromine atom; -CO₂M (preferably carboxyl group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom); -SO₃M (preferably sulfo) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom); a nitro group; a cyano group; a carbonyloxy group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded; a sulfonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded;

A carbamoyl group; carbamoyl substituted by 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms or derivative groups thereof; a hydrocarbon group having 1 to 10 carbon atoms, wherein all hydrogen atoms are substituted with fluorine atoms; a hydrocarbon group having 1 to 10 carbon atoms, which has a linear or branched alkyl group having 1 to 10 carbon atoms, wherein all hydrogen atoms are substituted with fluorine atoms, as a substituent; a hydrocarbon group having 1 to 10 carbon atoms, wherein a part of hydrogen atoms is substituted with fluorine; an oxo group.

As R^1Z3、R^2Z3、R^3Z3、R^4Z3、R^5Z3、R^6Z3、R^7Z3、R^101Z3And R^102Z3The hydrocarbon group having 1 to 40 carbon atoms and having a substituent represented by the formula (I) includes a hydrocarbon group having 1 to 40 carbon atoms and having a substituent having a valence of 1 or 2, preferably a saturated or unsaturated chain hydrocarbon group having 1 to 30 carbon atoms and having a substituent having a valence of 1 or 2, a saturated or unsaturated alicyclic hydrocarbon group having 3 to 30 carbon atoms and having a substituent having a valence of 1 or 2, an aromatic hydrocarbon group having 6 to 30 carbon atoms and having a substituent having a valence of 1 or 2, and a group having 1 to 30 carbon atoms and having a substituent having a valence of 1 or 2, which are a combination of hydrocarbon groups,

more preferably, the hydrocarbon group includes a saturated or unsaturated chain hydrocarbon group having 1 to 20 carbon atoms having a substituent of group s1, a saturated or unsaturated alicyclic hydrocarbon group having 3 to 20 carbon atoms having a substituent of group s1, an aromatic hydrocarbon group having 6 to 20 carbon atoms having a substituent of group s1, or a combination of hydrocarbon groups having 1 to 20 carbon atoms having a substituent of group s1,

Particularly preferred examples thereof include a saturated or unsaturated chain hydrocarbon group having 1 to 15 carbon atoms having a substituent of group s2, a saturated or unsaturated alicyclic hydrocarbon group having 3 to 15 carbon atoms having a substituent of group s2, an aromatic hydrocarbon group having 6 to 15 carbon atoms having a substituent of group s2, or a group having 1 to 15 carbon atoms having a substituent of group s2, which is a combination of hydrocarbon groups.

As R^1Z3、R^2Z3、R^3Z3、R^4Z3、R^5Z3、R^6Z3、R^7Z3、R^101Z3And R^102Z3The heterocyclic group may be a monocyclic or monocyclic ringAnd polycyclic, preferably heterocyclic, containing a heteroatom as a ring member. Examples of the hetero atom include a nitrogen atom, an oxygen atom, a sulfur atom and the like.

The number of carbon atoms of the heterocyclic group is preferably 3 to 30, more preferably 3 to 22, further preferably 3 to 20, further preferably 3 to 18, further more preferably 3 to 15, and particularly preferably 3 to 14.

Examples of the heterocyclic ring containing a nitrogen atom include:

monocyclic saturated heterocycles such as aziridine, azetidine, pyrrolidine, piperidine and piperazine; five-membered ring system unsaturated heterocycles such as pyrrole (e.g., 2, 5-dimethylpyrrole), pyrazole (e.g., 2-methylpyrazole and 3-methylpyrazole), imidazole, 1,2, 3-triazole and 1,2, 4-triazole;

a six-membered ring system unsaturated heterocycle such as pyrimidine, pyrazine and 1,3, 5-triazine, for example pyridine, pyridazine and 6-methylpyrimidine;

A fused bicyclic heterocycle such as quinoxaline (e.g., indazole, indoline, isoindoline, indole, indolizine, benzimidazole, quinoline, isoquinoline, 5,6,7, 8-tetrahydro (3-methyl) quinoxaline or 3-methylquinoxaline, quinazoline, cinnoline, phthalazine, naphthyridine, purine, pteridine, benzopyrazole or phenylpiperidine; condensed tricyclic heterocycles such as carbazole, acridine and phenazine; and so on.

Examples of the heterocyclic ring containing an oxygen atom include:

monocyclic saturated heterocycles such as oxetane, tetrahydrofuran, tetrahydropyran, 1, 3-dioxane, 1, 4-dioxane and 1-cyclopentyldioxolane; bicyclic saturated heterocycles such as 1, 4-dioxaspiro [4.5] decane and 1, 4-dioxaspiro [4.5] nonane; lactone heterocycles such as α -caprolactone, β -propiolactone, γ -butyrolactone, γ -valerolactone and δ -valerolactone; five-membered ring system unsaturated heterocycles such as furan (e.g., 2, 3-dimethylfuran, 2, 5-dimethylfuran); a six-membered ring system unsaturated heterocycle such as 2H-pyran, 4H-pyran;

fused bicyclic heterocycles such as benzopyrans (e.g., 1-benzofuran and 4-methylbenzopyran), benzodioxole, chroman and isochroman; fused tricyclic heterocycles such as xanthene and dibenzofuran; and so on.

Examples of the heterocyclic ring containing a sulfur atom include:

five-membered ring system saturated heterocycles such as dithiolane; saturated heterocyclic rings of six-membered ring systems such as thiacyclohexane, 1, 3-dithiane, 2-methyl-1, 3-dithiane and the like; a five-membered ring system unsaturated heterocycle such as thiophene (e.g., 3-methylthiophene, 2-carboxythiophene), benzothiopyran (e.g., 4H-thiopyran, tetrahydrothiopyran); fused bicyclic heterocycles such as benzothiophene; fused tricyclic heterocycles such as thianthrene and dibenzothiophene; and so on.

Examples of the heterocyclic ring containing a nitrogen atom and an oxygen atom include:

monocyclic saturated heterocycles such as morpholine, 2-pyrrolidone, 2-methyl-2-pyrrolidone, 2-piperidone and 2-methyl-2-piperidone; a monocyclic unsaturated heterocycle such as oxazole (e.g., 4-methyloxazole), isoxazole (e.g., 2-methylisoxazole, and 3-methylisoxazole);

fused bicyclic heterocycles such as benzoxazole, benzisoxazole, benzoxazine, benzodioxane, and benzimidazoline; condensed tricyclic heterocycles such as phenoxazine; and so on.

Examples of the heterocyclic ring containing a nitrogen atom and a sulfur atom include monocyclic heterocyclic rings such as thiazoles, e.g., 3-methylthiazole and 2, 4-dimethylthiazole; fused bicyclic heterocycles such as benzothiazole; fused tricyclic heterocycles such as phenothiazine; and so on.

The heterocyclic ring may be a combination of the above-mentioned hydrocarbon groups, and examples thereof include tetrahydrofurylmethyl and the like.

The heterocyclic ring may be a heterocyclic ring represented by the following chemical formula.

The above heterocyclic group may be R^1Z3～R^5Z32 or more of them are bonded to form a heterocyclic group. Such heterocyclic radicals contain R^1Z3～R^5Z3The bonded benzene ring has a ring structure of 2 or more rings inside. The 2 or more ring structures include, for example, the structures of the following chemical formulae.

The bonding position of the heterocycle is a portion where any hydrogen atom contained in each ring is removed.

R^1Z3、R^2Z3、R^3Z3、R^4Z3、R^5Z3、R^6Z3、R^7Z3、R^101Z3And R^102Z3The heterocyclic group represented may have a substituent. Examples of the substituent include^1Z3、R^2Z3、R^3Z3、R^4Z3、R^5Z3、R^6Z3、R^7Z3、R^101Z3And R^102Z3The hydrocarbon group may have the same substituent as the substituent. In addition, in the case where the above-mentioned heterocyclic ring contains a nitrogen atom as its constituent element, the above-mentioned hydrocarbon group as a substituent may be bonded to the nitrogen atom.

Preferred examples of the substituent include^1Z3、R^2Z3、R^3Z3、R^4Z3、R^5Z3、R^6Z3、R^7Z3、R^101Z3And R^102Z3The preferable examples of the substituents which the hydrocarbon group may have are the same. As R^1Z3、R^2Z3、R^3Z3、R^4Z3、R^5Z3、R^6Z3、R^7Z3、R^101Z3And R^102Z3The heterocyclic group having a substituent represented by the formula (i) includes a heterocyclic group having a substituent having a valence of 1 or 2, preferably a heterocyclic group having a substituent of group s1, and more preferably a heterocyclic group having a substituent of group s 2.

The substituent (first substituent) that the hydrocarbon group or heterocyclic group may have may be 1 or 2 or more, and 2 or more substituents may be the same or different and independent of each other. As for the above-mentioned first substituent, another substituent (second substituent) may be bonded to the hydrocarbon group contained in a part thereof. The second substituent may be selected from the same groups as the first substituent.

Below, for R^1Z3、R^2Z3、R^3Z3、R^4Z3、R^5Z3、R^6Z3And R^7Z3Of (a) is-CO-R^102Z3、-COO-R^101Z3、-OCO-R^102Z3、-COCO-R^102Z3、-O-R^102Z3、-SO₂-R^101Z3、-SO₂N(R^102Z3)₂、-CON(R^102Z3)₂、-N(R^102Z3)₂、-NHCO-R^102Z3、-NHCO-N(R^102Z3)₂、-NHCOOR^102Z3、-OCON(R^102Z3)₂Halogen atom, -SO₃M、-CO₂M is explained.

as-CO-R^102Z3Examples thereof include a formyl group; a carbonyl group (e.g., a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)) to which a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (e.g., a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) is bonded such as an acetyl group, a propionyl group, a butyryl group, a 2, 2-dimethylpropionyl group, a pentanoyl group, a hexanoyl group, (2-ethyl) hexanoyl group, a heptanoyl group, an octanoyl group, a nonanoyl group, a decanoyl group, a undecanoyl group, a dodecanoyl group, a benzoyl group, and a group represented by the above chemical formula, and the like, and the carbonyl group corresponding to-CO-R-in the compounds represented by tables 1Z3 to 6Z3 ^102Z3Preferable examples of the group(s) include a carbonyl group (more preferably 2 to 12 carbon atoms when the carbonyl group is an alkanoyl group) to which a hydrocarbon group having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms) or a derivative thereof is bonded, and a group corresponding to-CO-R in the compounds shown in tables 1Z3 to 6Z3^102Z3And the like.

as-COO-R^101Z3Examples thereof include methoxycarbonyl, ethoxycarbonyl, propoxycarbonyl, tert-butoxycarbonyl, pentyloxycarbonyl, hexyloxycarbonyl, (2-ethyl) hexyloxycarbonyl, heptyloxycarbonyl, octyloxycarbonyl, nonyloxycarbonyl, decyloxycarbonyl, undecyloxycarbonyl, dodecyloxycarbonyl, phenyloxycarbonyl, icosyl-L-butyloxycarbonylAn alkoxycarbonyl group having a C1-40 (preferably C1-20) hydrocarbon group or a derivative thereof (e.g., a derivative thereof with a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group (preferably an octylsulfamoyl group) having C1-10) bonded thereto such as an alkyloxycarbonyl group or the like, and a group represented by the above chemical formula, and a compound corresponding to-COO-R in tables 1Z3 to 6Z3 ^102Z3Preferred examples of the group (b) include oxycarbonyl groups to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded and compounds represented by tables 1Z3 to 6Z3 corresponding to-COO-R^102Z3And the like.

as-OCO-R^102Z3Examples thereof include a formyloxy group; acetoxy, propionyloxy, butyryloxy, 2-dimethylpropionyloxy, pentanoyloxy, hexanoyloxy, (2-ethyl) hexanoyloxy, heptanoyloxy, octanoyloxy, nonanoyloxy, decanoyloxy, undecanoyloxy, dodecanoyloxy, heneicosanoyloxy, benzoyloxy and the like, carbonyloxy (having 2 to 41 carbon atoms in the case where the carbonyloxy group is an acyloxy group), carbonyloxy having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) bonded to a group represented by the above formula) and the like, And the compounds shown in tables 1Z3 to 6Z3 correspond to-OCO-R^102Z3Preferable examples of the group(s) include a carbonyloxy group (more preferably 2 to 12 carbon atoms when the carbonyloxy group is an acyloxy group) to which a hydrocarbon group having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms) or a derivative thereof is bonded, and a compound represented by any one of tables 1Z3 to 6Z3 corresponding to-OCO-R ^102Z3And the like.

as-COCO-R^102Z3Examples thereof include methyloxalyl, ethyloxalyl, propyloxalyl, butyloxalyl, pentyloxalyl, hexyloxalyl, (2-ethyl) hexyloxalyl, heptyloxalyl, octyloxalyl, nonyloxalylOxalyl groups in which a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) is bonded, such as oxalyl group, decyloxyl group, undecyloxalyl group, dodecyloxalyl group, eicosanyl group, cyclopentyloxalyl group, cyclohexyloxalyl group, phenyloxalyl group, p-tolyloxalyl group, and the group represented by the above chemical formula), and compounds represented by tables 1Z3 to 6Z3 corresponding to-COCO-R^102Z3And the like.

as-O-R^102Z3There may be mentioned a hydroxyl group; methoxy, ethoxy, propoxy, isopropoxy, butoxy, isobutoxy, sec-butoxy, tert-butoxy, pentyloxy, hexyloxy, heptyloxy, octyloxy, nonyloxy, decyloxy, undecyloxy, dodecyloxy, (2-ethyl) hexyloxy, eicosyloxy, 1-phenylethoxy, 1-methyl-1-phenylethoxy, phenyloxy, 2, 3-dimethylphenyloxy, 2, 4-dimethylphenyloxy, 2, 5-dimethylphenyloxy, 2, 6-dimethylphenyloxy, 3, 4-dimethylphenyloxy, 3, 5-dimethylphenyloxy, 2-dicyanophenyloxy, 2, 3-dicyanophenyloxy, 2, 4-dicyanophenyloxy, sec-butyloxy, tert-butyloxy, pentyloxy, hexyloxy, heptyloxy, octyloxy, decyloxy, 2, 3-dimethylphenyloxy, 2, 4-dimethylphenyloxy, 2, 4-dimethylphenyloxy, 3-dimethylphenyloxy, 2-dicyanophenyloxy, 2, 4-di-yloxy, 2-di-methyl-1-phenylethoxy, 2, 4-di-methyl, and mixtures thereof, 2, 5-dicyanophenyloxy group, 2, 6-dicyanophenyloxy group, 3, 4-dicyanophenyloxy group, 3, 5-dicyanophenyloxy group, 4-methoxyphenyloxy group, 2-methoxyphenyloxy group, examples of the oxygen group include an oxygen group having a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like bonded thereto, such as a 3-methoxyphenyloxy group, a 4-ethoxyphenyloxy group, a 2-ethoxyphenyloxy group, a 3-ethoxyphenyloxy group, or a group represented by the above chemical formula), and compounds shown in tables 1Z3 to 6Z3, which correspond to — O — R. ^102Z3Preferable examples of the group (b) include an oxy group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded and groups shown in tables 1Z3 to 6Z3In the compounds shown, the corresponding-O-R^102Z3And the like.

as-SO₂-R^101Z3Examples thereof include sulfonyl groups in which a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a derivative thereof by a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc.) is bonded, such as methylsulfonyl group, ethylsulfonyl group, propylsulfonyl group, butylsulfonyl group, pentylsulfonyl group, hexylsulfonyl group, (2-ethyl) hexylsulfonyl group, heptylsulfonyl group, octylsulfonyl group, nonylsulfonyl group, decylsulfonyl group, undecylsulfonyl group, dodecylsulfonyl group, eicosylsulfonyl group, phenylsulfonyl group, p-tolylsulfonyl group, etc., and groups represented by the above chemical formulae, and sulfonyl groups corresponding to-SO-in the compounds represented by tables 1Z3 to 6Z3₂-R^102Z3Preferable examples of the group (b) include a sulfonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded and a group corresponding to-SO in the compounds represented by tables 1Z3 to 6Z3 ₂-R^102Z3And the like.

as-SO₂N(R^102Z3)₂Examples thereof include: a sulfamoyl group; n-methylsulfamoyl, N-ethylsulfamoyl, N-propylsulfamoyl, N-isopropylsulfamoyl, N-butylsulfamoyl, N-isobutylsulfamoyl, N-sec-butylsulfamoyl, N-tert-butylsulfamoyl, N-pentylsulfamoyl, N- (1-ethylpropyl) sulfamoyl, N-hexylsulfamoyl, N- (2-ethyl) hexylsulfamoyl, N-heptylsulfamoyl, N-octylsulfamoyl, N-nonylsulfamoyl, N-decylsulfamoyl, N-undecylsulfamoyl, N-dodecylsulfamoyl, N-eicosylsulfamoyl, N-phenylsulfamoyl, etc., and a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group represented by the above formula, or a derivative thereof Sulfamoyl groups substituted with a raw group (e.g., a group derived from carboxyl group, sulfo group, nitro group, hydroxyl group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group)), and the like, and the amino groups shown in tables 1Z3 to 6Z3Corresponding to-SO in the compound (A) of₂NH(R^102Z3X) (wherein, R^102Z3XIs not a hydrogen atom, other than, and R^102Z3The same as defined above), etc.;

N, N-dimethylsulfamoyl, N-ethylmethylsulfamoyl, N-diethylsulfamoyl, N-propylmethylsulfamoyl, N-dipropylsulfamoyl, N-isopropylmethylsulfamoyl, N-diisopropylsulfamoyl, N-tert-butylmethylsulfamoyl, N-diisobutylsulfamoyl, N-di-sec-butylsulfamoyl, N-di-tert-butylsulfamoyl, N-butylmethylsulfamoyl, N-dibutylsulfamoyl, N-dipentylsulfamoyl, N-bis (1-ethylpropyl) sulfamoyl, N-dihexylsulfamoyl, N-bis (2-ethyl) hexylsulfamoyl, N-diethylsulfamoyl, N, N-diheptylsulfamoyl, N-octylmethylsulfamoyl, N-dioctylsulfamoyl, N-dinonylsulfamoyl, N-decylmethylsulfamoyl, N-undecylmethylsulfamoyl, N-dodecylmethylsulfamoyl, N-eicosylmethylsulfamoyl, N-phenylmethylsulfamoyl, N-diphenylsulfamoyl and the like, and sulfamoyl groups represented by the above chemical formulae and the like substituted with a hydrocarbon group having 1 to 40 (preferably 1 to 20) carbon atoms or a derivative thereof (for example, a derivative derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl) and the like, and the compounds represented by tables 1Z3 to 6Z3 correspond to those of the compounds represented by tables 1Z3 to 6Z3 -SO ₂N(R^102Z3X)₂(wherein, R^102Z3XIs not a hydrogen atom, other than, and R^102Z3The same as defined above) and the like,

preferred examples thereof include sulfamoyl groups substituted with 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms or derivatives thereof and compounds represented by tables 1Z3 to 6Z3, which correspond to-SO₂N(R^102Z3)₂And the like.

as-CON (R)^102Z3)₂Examples thereof include:

a carbamoyl group; n-methylcarbamoyl, N-ethylcarbamoyl, N-propylcarbamoylA hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a carboxyl group, an N-isopropylcarbamoyl group, an N-butylcarbamoyl group, an N-isobutylcarbamoyl group, an N-sec-butylcarbamoyl group, an N-tert-butylcarbamoyl group, an N-pentylcarbamoyl group, an N- (1-ethylpropyl) carbamoyl group, an N-hexylcarbamoyl group, an N- (2-ethyl) hexylcarbamoyl group, an N-heptylcarbamoyl group, an N-octylcarbamoyl group, an N-nonylcarbamoyl group, an N-decylcarbamoyl group, an N-undecylcarbamoyl group, an N-dodecylcarbamoyl group, an N-eicosylcarbamoyl group, an N-phenylcarbamoyl group and the like, and a group represented by the above chemical formula, A carbamoyl group substituted with a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like), and a compound represented by any of tables 1Z3 to 6Z3, wherein the carbamoyl group corresponds to-CONH (R is R ^102Z3X)(R^102Z3XIs not a hydrogen atom, other than, and R^102Z3The same as defined above), etc.;

n, N-dimethylcarbamoyl group, N-ethylmethylcarbamoyl group, N-diethylcarbamoyl group, N-propylmethylcarbamoyl group, N-dipropylcarbamoyl group, N-isopropylmethylcarbamoyl group, N-diisopropylcarbamoyl group, N-tert-butylmethylcarbamoyl group, N-diisobutylcarbamoyl group, N-di-sec-butylcarbamoyl group, N-di-tert-butylcarbamoyl group, N-butylmethylcarbamoyl group, N-dibutylcarbamoyl group, N-butyloctylcarbamoyl group, N-dipentylcarbamoyl group, N-di (1-ethylpropyl) carbamoyl group, N-diethylcarbamoyl group, N-diisopropylcarbamoyl group, N-di (1-ethylpropyl) carbamoyl group, N-t-butylmethylcarbamoyl group, N-di-butylmethylcarbamoyl group, N-t-butylmethylcarbamoyl group, N-di (1-ethylpropyl) carbamoyl group, N-t-butylmethylcarbamoyl group, N-di-isobutylcarbamoyl group, N-di (s-butylmethylcarbamoyl group, N-di-butylmethylcarbamoyl group, N-di-N-butylcarbamoyl group, N, n, N-dihexylcarbamoyl group, N-di (2-ethyl) hexylcarbamoyl group, N-diheptylcarbamoyl group, N-octylmethylcarbamoyl group, N-dioctylcarbamoyl group, N-dinonylcarbamoyl group, N-decylmethylcarbamoyl group, N-undecylmethylcarbamoyl group, N-dodecylmethylcarbamoyl group, N-eicosylmethylcarbamoyl group, N-phenylmethylcarbamoyl group, N-diphenylcarbamoyl group, etc., and a group represented by the above chemical formula, etc., each having 2 carbon atoms Carbamoyl groups substituted with a hydrocarbyl group having 1 to 40 (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a derivative thereof such as carboxyl, sulfo, nitro, hydroxyl, halogen (preferably chlorine atom), alkylsulfamoyl (preferably octylsulfamoyl) having 1 to 10 carbon atoms) and compounds shown in tables 1Z3 to 6Z3 corresponding to-CON (R^102Z3X)₂(R^102Z3XIs not a hydrogen atom, other than, and R^102Z3The same as defined above) and the like,

preferred examples thereof include a carbamoyl group substituted with 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms or a derivative thereof and a compound represented by any one of tables 1Z3 to 6Z3 corresponding to-CON (R)^102Z3)₂And the like.

as-N (R)^102Z3)₂Examples thereof include:

an amino group; a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom)), such as an N-methylamino group, an N-ethylamino group, an N-propylamino group, an N-isopropylamino group, an N-butylamino group, an N-isobutylamino group, an N-sec-butylamino group, an N-tert-butylamino group, an N-pentylamino group, an N-hexylamino group, an N- (2-ethyl) hexylamino group, an N-heptylamino group, an N-octylamino group, an N-nonylamino group, an N-decylamino group, an N-undecylamino group, an N-dodecylamino group, an N-eicosylamino group, an N-phenylamino group, and the like, and a group represented by the above chemical formula, A group derived from an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) and the like) and a compound shown in tables 1Z3 to 6Z3 corresponding to-NH (R ^102Z3X)(R^102Z3XIs not a hydrogen atom, other than, and R^102Z3The same as defined above), etc.;

n, N-dimethylamino group, N-ethylmethylamino group, N-diethylamino group, N-propylmethylamino group, N-dipropylamino group, N-isopropylmethylamino group, N-diisopropylamino group, N-tert-butylmethylamino group, N-diisobutylamino group, N-di-sec-butylamino group, N-di-tert-butylamino group, N-butylmethylamino group, N-dibutylamino group, N-A group derived from a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like, such as a dipentylamino group, an N, N-di (1-ethylpropyl) amino group, an N, N-dihexylamino group, an N, N-di (2-ethyl) hexylamino group, an N, N-diheptylamino group, an N, N-dioctylamino group, an N, N-dinonylamino group, an N, N-decylmethylamino group, an N, N-undecylmethylamino group, an N, N-dodecylmethylamino group, an N, N-eicosylmethylamino group, an N, N-phenylmethylamino group, an N, N-diphenylamino group, or the like, and a group represented by the above chemical formula ) The substituted amino group and the compounds shown in tables 1Z3 to 6Z3 correspond to-N (R) ^102Z3X)₂(R^102Z3XIs not a hydrogen atom, other than, and R^102Z3The same as defined above), and the like, and preferably include amino groups substituted with 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms or derivatives thereof and groups corresponding to-N (R) in the compounds shown in tables 1Z3 to 6Z3^102Z3)₂And the like.

as-NHCO-R^102Z3Examples thereof include formylamino; a carbonylamino group (in the case where the carbonylamino group is an acylamino group, the number of carbon atoms is 1 to 40) in which a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a derivative thereof such as a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) is bonded, such as an acetylamino group, a propionylamino group, a butyrylamino group, a 2, 2-dimethylpropionylamino group, a valerylamino group, a hexanoylamino group, (2-ethyl) hexanoylamino group, a heptanoylamino group, an octanoylamino group, a nonanoylamino group, a decanoylamino group, a nonanoylamino group, a decanoylamino group, a undecanoylamino group, a dodecanoylamino group, a heneicosanoylamino group, a benzoylamino group, and the like, and a group represented by the above-mentioned chemical formula, and-NHCO-R is equivalent to in the compounds shown in tables 1Z3 to 6Z3 ^102Z3And the like,

preferably, the carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded(in the case where the carbonylamino group is an alkanoylamino group, the number of carbon atoms is more preferably 1 to 10) and the compounds represented by tables 1Z3 to 6Z3 correspond to-NHCO-R^102Z3And the like.

as-NHCON (R)^102Z3)₂Examples thereof include the groups listed above and the compounds shown in tables 1Z3 to 6Z3 which correspond to-NHCON (R)^102Z3)₂And the like.

as-NHCOOR^102Z3Examples thereof include the groups listed above and the groups corresponding to-NHCOOR among the compounds shown in tables 1Z3 to 6Z3^102Z3And the like.

as-OCON (R)^102Z3)₂Examples thereof include those corresponding to-OCON (R) in the above-mentioned groups and the compounds shown in tables 1Z3 to 6Z3^102Z3)₂And the like.

The halogen atom is preferably a fluorine atom, a chlorine atom, a bromine atom, an iodine atom or the like.

as-SO₃M and-CO₂M in M is a hydrogen atom; the alkali metal atom such as lithium atom, sodium atom and potassium atom, preferably hydrogen atom, sodium atom and potassium atom.

The above-mentioned-CO-R^102Z3、-COO-R^102Z3、-OCO-R^102Z3、-COCO-R^102Z3、-O-R^102Z3、-SO₂-R^102Z3、-SO₂N(R^102Z3)₂、-CON(R^102Z3)₂、-N(R^102Z3)₂、-NHCO-R^102Z3、-NHCON(R^102Z3)₂、-NHCOOR^102Z3、-OCON(R^102Z3)₂The number of the substituents (first substituents) contained in (2) may be 1 or 2 or more, and 2 or more substituents may be the same or different and independent of each other.

Further, the first substituent may have another substituent (second substituent) bonded to the hydrocarbon group included in a part thereof. The second substituent may be selected from the same groups as the first substituent.

R^2Z3And R^3Z3、R^3Z3And R^4Z3And R^4Z3And R^5Z3The ring formed is fused with the benzene ring of the isoindoline skeleton of the compound represented by the formula (IZ 3). As R^2Z3And R^3Z3、R^3Z3And R^4Z3And R^4Z3And R^5Z3Examples of the condensed ring structure of the ring formed and the benzene ring include indene, naphthalene, biphenylene, indacene, acenaphthylene, fluorene, phenalene, phenanthrene, anthracene, fluoranthene, acephenanthrene, aceanthrylene, and benzo [9,10 ] ene]Phenanthrene, pyrene,

Hydrocarbon-based condensed ring structures such as N-methylphthalimide, N- (1-phenylethyl) phthalimide and butachlor, and partially reduced products thereof (for example, 9, 10-dihydroanthracene, 1,2,3, 4-tetrahydronaphthalene, etc.); indole, isoindole, indazole, quinoline, isoquinoline, phthalazine, quinoxaline, quinazoline, cinnoline, carbazole, carboline, phenanthridine, acridine, quinoline, quinoxaline, quinoline, and/or quinoline derivative,

Nitrogen-containing fused heterocycles such as pyridine, phenanthroline, and phenazine, and partial reductants thereof; oxygen-containing fused heterocycles such as 3-hydrobenzofuran-2-one and partial reductants thereof.

R^2Z3And R^3Z3、R^3Z3And R^4Z3And R^4Z3And R^5Z3In the case of forming a ring, the ring may have a substituent. Examples of the substituent include^1Z3、R^2Z3、R^3Z3、R^4Z3、R^5Z3、R^6Z3、R^7Z3、R^101Z3And R^102Z3The hydrocarbon group may have the same substituent as the substituent. Preferred examples of the substituent include^1Z3、R^2Z3、R^3Z3、R^4Z3、R^5Z3、R^6Z3、R^7Z3、R^101Z3And R^102Z3The preferable examples of the substituents which the hydrocarbon group may have are the same.

R^3Z3And R^4Z3When forming a ring, as R^2Z3And R^5Z3Independently of one another, hydrogen atoms, amino groups and hydroxyl groups are preferred.

R^2Z3And R^3Z3When a ring is formed, R is preferably^4Z3And R^5Z3Does not form a ring, more preferably R^4Z3And R^5Z3Is a hydrogen atom.

R^4Z3And R^5Z3When a ring is formed, R is preferably^2Z3And R^3Z3Does not form a ring, more preferably R^2Z3And R^3Z3Is a hydrogen atom.

In the present invention, R^1Z3、R^6Z3And R^7Z3Preferably a hydrogen atom.

From the viewpoint of reducing the retardation value of a color filter made of the colored composition, R is preferably^2Z3、R^3Z3、R^4Z3And R^5Z3At least one of which is-CO-R^102Z3、-COO-R^101Z3、-OCO-R^102Z3、-COCO-R^102Z3、-O-R^102Z3、-SO₂-R^101Z3、-SO₂N(R^102Z3)₂、-CON(R^102Z3)₂、-N(R^102Z3)₂、-NHCO-R^102Z3、-NHCO-N(R^102Z3)₂、-NHCOOR^102Z3、-OCON(R^102Z3)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent, more preferably a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a halogen atom, -N (R)^102Z3)₂A C1-20 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R^102Z3、-O-R^102Z3、-SO₃M or-CO₂M is more preferably a nitro group or a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, and still more preferably a nitro group or a tert-butyl group. Alternatively, R is preferred^2Z3And R^3Z3、R^3Z3And R^4Z3Or R^4Z3And R^5Z3Form a ring.

Compound IZ3 is preferably the following compound: r ^2Z3、R^3Z3、R^4Z3And R^5Z3At least one of which is-CO-R^102Z3、-COO-R^101Z3、-OCO-R^102Z3、-COCO-R^102Z3、-O-R^102Z3、-SO₂-R^101Z3、-SO₂N(R^102Z3)₂、-CON(R^102Z3)₂、-N(R^102Z3)₂、-NHCO-R^102Z3、-NHCO-N(R^102Z3)₂、-NHCOOR^102Z3、-OCON(R^102Z3)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent, or R is^2Z3And R^3Z3、R^3Z3And R^4Z3And R^4Z3And R^5Z3At least one group of the compounds (hereinafter, this compound may be referred to as "compound IZ 3-B") is bonded to form a ring. When the compound IZ3 is the compound IZ3-B, the retardation value of the color filter produced from the colored composition becomes small.

When the above compound IZ3-B is defined by a chemical formula, it is as follows.

[ formula (IZ3-B) wherein R^1Z3、R^21Z3、R^31Z3、R^41Z3、R^51Z3、R^61Z3And R^71Z3Independently of one another, represents a hydrogen atom, -CO-R^102Z3、-COO-R^101Z3、-OCO-R^102Z3、-COCO-R^102Z3、-O-R^102Z3、-SO₂-R^101Z3、-SO₂N(R^102Z3)₂、-CON(R^102Z3)₂、-N(R^102Z3)₂、-NHCO-R^102Z3、-NHCO-N(R^102Z3)₂、-NHCOOR^102Z3、-OCON(R^102Z3)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.

R^21Z3And R^31Z3、R^31Z3And R^41Z3And R^41Z3And R^51Z3Each of which may be bonded to each other to form a ring.

Wherein R is^21Z3、R^31Z3、R^41Z3And R^5Z3At least one of which is-CO-R^102Z3、-COO-R^101Z3、-OCO-R^102Z3、-COCO-R^102Z3、-O-R^102Z3、-SO₂-R^101Z3、-SO₂N(R^102Z3)₂、-CON(R^102Z3)₂、-N(R^102Z3)₂、-NHCO-R^102Z3、-NHCO-N(R^102Z3)₂、-NHCOOR^102Z3、-OCON(R^102Z3)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent, or R is^21Z3And R^31Z3、R^31Z3And R^41Z3And R^41Z3And R^51Z3At least one group of them is bonded to form a ring.

R^101Z3The alkyl group may have a substituent and has 1 to 40 carbon atoms, or a heterocyclic group may have a substituent.

R^102Z3Represents a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group.

M represents a hydrogen atom or an alkali metal atom.

R^101Z3、R^102Z3And when there are a plurality of M, they may be the same or different. The wavy line indicates the E-body or the Z-body.]

In the formula (IZ3-B), with respect to R^21Z3、R^31Z3、R^41Z3、R^51Z3、R^61Z3And R^71Z3Respectively, R in the formula (IZ3)^2Z3、R^3Z3、R^4Z3、R^5Z3、R^6Z3And R^7Z3The same example.

In the formula (IZ3-B), with respect to preferred R^21Z3、R^31Z3、R^41Z3、R^51Z3、R^61Z3And R^71Z3Respectively, R in the formula (IZ3)^2Z3、R^3Z3、R^4Z3、R^5Z3、R^6Z3And R^7Z3The same preferred examples as those of (1).

In the formula (IZ3-B), (mode 1) R^1Z3、R^61Z3And R^71Z3Is preferably a hydrogen atom. In addition, (mode 2) R^21Z3、R^31Z3、R^41Z3And R^51Z3It is also preferred that at least one of them is nitro or tert-butyl. Either or both of the modes 1 and 2 may be employed.

From the viewpoint of reducing the retardation value of a color filter made of the colored composition, R is preferably^2Z3、R^3Z3、R^4Z3And R^5Z3At least one of which is an optionally substituted hydrocarbon group having 1 to 40 carbon atoms, a halogen atom, or-N (R)^102Z3)₂A C1-20 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R^102Z3、-O-R^102Z3、-SO₃M or-CO₂M is more preferably a nitro group or a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, and still more preferably a nitro group or a tert-butyl group. It is especially preferred that R ^3Z3Is nitro or tert-butyl, R^2Z3、R^4Z3And R^5Z3Is a hydrogen atom; or, R^2Z3、R^3Z3And R^5Z3Is a hydrogen atom, R^4Z3Is nitro or tert-butyl.

Specific examples of the compound IZ3 include compounds IZ3-1 to IZ3-212 having a substituent shown in table 1Z3, table 2Z3, table 3Z3, table 4Z3, table 5Z3, and table 6Z3 in formula (IZ3-aa), and alkali metal salts thereof.

B^a1Z3B^a2Z3The partial structure represented by any one of formulae (BB1) to (BB60), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1), formula (BBO8), formula (BBO10), formula (BBD1) and formula (BBJ2) is shown. Formulae (BB1) to (BB60), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1), formula (BBO8),Formula (BBO10), formula (BBD1) and formula (BBJ2) are the same as B representing formula (IZ1-aa)^a1Z1B^a2Z1The same structures as (BB1) to (BB60), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1), formula (BBO8), formula (BBO10), formula (BBD1) and formula (BBJ2) described above. B is^a1Z3And B^a2Z3Each represents a chemical bond, B^a1Z3B of formulae (BB1) to (BB60), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1), formula (BBO8), formula (BBO10), formula (BBD1) and formula (BBJ2)¹When a chemical bond of (A) is present, B^a2Z3To be B²The chemical bond of (a); b is^a1Z3B of formulae (BB1) to (BB60), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1), formula (BBO8), formula (BBO10), formula (BBD1) and formula (BBJ2) ²When a chemical bond of (A) is present, B^a2Z3To be B¹The chemical bond of (1). As B^a1Z3B^a2Z3Formula (BB1), formula (BB6), formula (BB8), formula (BB11), formula (BB14), formula (BB19), formula (BB37), formula (BB58), formula (BBJ2), formula (BBO8), and formula (BBO10) are preferable, and formula (BB1), formula (BB6), and formula (BB19) are more preferable.

Each symbol in table 1Z3, table 2Z3, table 3Z3, table 4Z3, table 5Z3, and table 6Z3 represents the following partial structure. In the partial structure, "Me" represents a methyl group, "Et" represents an ethyl group, "Bu" represents a butyl group, "TBu" represents a tert-butyl group, "Hex" represents a hexyl group, "Oct" represents an octyl group, "2 EH" represents a 2-ethylhexyl group, "CHM" represents a cyclohexylmethyl group, "CH" represents a cyclohexyl group,

"PH" represents phenyl, "BZ" represents benzyl, "NPR" represents propyl, "IPR" represents isopropyl, "IBu" represents isobutyl, and "EOE" represents-CH₂CH₂OCH₂CH₃"ALL" represents allyl, "HYE" represents 2-hydroxyethyl, and "COM" represents-CO-CH₃And "COE" represents-COO-CH₂CH₃And "OCM" represents-OCO-CH₃And "OME" represents-O-CH₃，“SOT"represents a tosyl group," SNH "represents-SO₂NH-CH₂CH(CH₂CH₃)((CH₂)₃CH₃) "SN 2" represents-SO₂N(CH₃)((CH₂)₇CH₃) "CNM" represents-CONHCH₃And "CN 2" represents-CON (CH) ₃)C₆H₅And "NPH" represents-NHC₆H₅And "NOT" represents-N ((CH)₂)₇CH₃)₂And "NCO" represents-NHCO ((CH)₂)₄CH₃) "F" represents a fluorine atom, "Cl" represents a chlorine atom, "Br" represents a bromine atom, "CN" represents a cyano group, "NO 2" represents a nitro group, and "SUA" represents-SO₃H, "CBA" means-CO₂H, "CHO" means-CHO, "OCH" means-OCOH, "OH" means-OH, "SFM" means-SO₂NH₂"CBM" represents-CONH₂"NH 2" means-NH₂"NCH" represents-NHCOH.

[ Table 1Z3]

TABLE 1Z3

	Ba1Z3Ba2Z3	R1Z3	R6Z3	R7Z3
					IZ3-1	BB1	H	H	H
IZ3-2	BB2	H	H	H
					IZ3-3	BB3	H	H	H
IZ3-4	BB4	H	H	H
					IZ3-5	BB5	H	H	H
IZ3-6	BB6	H	H	H
					IZ3-7	BB7	H	H	H
IZ3-8	BB8	H	H	H
					IZ3-9	BB9	H	H	H
IZ3-10	BB10	H	H	H
					IZ3-11	BB11	H	H	H
IZ3-12	BB12	H	H	H
					IZ3-13	BB13	H	H	H
IZ3-14	BB14	H	H	H
					IZ3-15	BB15	H	H	H
IZ3-16	BB16	H	H	H
					IZ3-17	BB17	H	H	H
IZ3-18	BB18	H	H	H
					IZ3-19	BB19	H	H	H
IZ3-20	BB20	H	H	H
					IZ3-21	BB21	H	H	H
IZ3-22	BB22	H	H	H
					IZ3-23	BB23	H	H	H
IZ3-24	BB24	H	H	H
					IZ3-25	BB25	H	H	H
IZ3-26	BB26	H	H	H
					IZ3-27	BB27	H	H	H
IZ3-28	BB28	H	H	H
					IZ3-29	BB29	H	H	H
IZ3-30	BB30	H	H	H
					IZ3-31	BB31	H	H	H
IZ3-32	BB32	H	H	H
					IZ3-33	BB33	H	H	H
IZ3-34	BB34	H	H	H
					IZ3-35	BB35	H	H	H
IZ3-36	BB36	H	H	H
					IZ3-37	BB37	H	H	H
IZ3-38	BB38	H	H	H
					IZ3-39	BB39	H	H	H
IZ3-40	BB40	H	H	H

[ Table 2Z3]

TABLE 2Z3

	Ba1Z3Ba2Z3	R1Z3	R6Z3	R7Z3
					IZ3-41	BB41	H	H	H
IZ3-42	BB42	H	H	H
					IZ3-43	BB43	H	H	H
IZ3-44	BB44	H	H	H
					IZ3-45	BB45	H	H	H
IZ3-46	BB46	H	H	H
					IZ3-47	BB47	H	H	H
IZ3-48	BB48	H	H	H
					IZ3-49	BB49	H	H	H
IZ3-50	BB50	H	H	H
					IZ3-51	BB51	H	H	H
IZ3-52	BB52	H	H	H
					IZ3-53	BB53	H	H	H
IZ3-54	BB54	H	H	H
					IZ3-55	BB55	H	H	H
IZ3-56	BB56	H	H	H
					IZ3-57	BB57	H	H	H
IZ3-58	BB58	H	H	H
					IZ3-59	BB59	H	H	H
IZ3-60	BB60	H	H	H
					IZ3-61	BB1	H	EOE	EOE
IZ3-62	BB2	H	ALL	ALL
					IZ3-63	BB3	H	NH2	NH2
IZ3-64	BB4	H	CBM	CBM
					IZ3-65	BB5	H	COM	COM
IZ3-66	BB6	H	COE	COE
					IZ3-67	BB7	H	CBA	CBA
IZ3-68	BB8	H	HYE	HYE
					IZ3-69	BB9	H	Me	Me
IZ3-70	BB10	H	CH	CH
					IZ3-71	BB11	H	BZ	H
IZ3-72	BB12	Me	Me	Me
					IZ3-73	BB13	Et	CH	CH
IZ3-74	BB14	H	Et	Et
					IZ3-75	BB15	H	Bu	Bu
IZ3-76	BB16	H	TBu	TBu
					IZ3-77	BB17	H	Hex	Hex
IZ3-78	BB18	H	Oct	Oct
					IZ3-79	BB19	H	Me	Me
IZ3-80	BB20	H	CH	CH

[ Table 3Z3]

TABLE 3Z3

	Ba1Z3Ba2Z3	R1Z3	R6Z3	R7Z3
					IZ3-81	BB21	H	BZ	H
IZ3-82	BB22	Me	Me	Me
					IZ3-83	BB23	Et	CH	CH
IZ3-84	BB24	H	Et	Et
					IZ3-85	BB25	H	Bu	Bu
IZ3-86	BB26	H	TBu	TBu
					IZ3-87	BB27	H	Hex	Hex
IZ3-88	BB28	H	Oct	Oct
					IZ3-89	BB29	H	2EH	2EH
IZ3-90	BB30	H	CHM	CHM
					IZ3-91	BB31	H	PH	PH
IZ3-92	BB32	H	BZ	BZ
					IZ3-93	BB33	H	NPR	NPR
IZ3-94	BB34	H	IPR	IPR
					IZ3-95	BB35	H	IBu	IBu
IZ3-96	BB36	H	EOE	EOE
					IZ3-97	BB37	H	ALL	ALL
IZ3-98	BB38	H	NH2	NH2
					IZ3-99	BB39	H	CBM	CBM
IZ3-100	BB40	H	COM	COM
					IZ3-101	BB41	H	COE	COE
IZ3-102	BB42	H	CBA	CBA
					IZ3-103	BB43	H	HYE	HYE
IZ3-104	BB44	H	Me	Me
					IZ3-105	BB45	H	CH	CH
IZ3-106	BB46	H	BZ	H
					IZ3-107	BB47	Me	Me	Me
IZ3-108	BB48	Et	CH	CH
					IZ3-109	BB49	H	Et	Et
IZ3-110	BB50	H	Bu	Bu
					IZ3-111	BB51	H	TBu	TBu
IZ3-112	BB52	H	Hex	Hex
					IZ3-113	BB53	H	Oct	Oct
IZ3-114	BB54	H	2EH	2EH
					IZ3-115	BB55	H	CHM	CHM
IZ3-116	BB56	H	PH	PH
					IZ3-117	BB57	H	BZ	BZ
IZ3-118	BB58	H	NPR	NPR
					IZ3-119	BB59	H	IPR	IPR
IZ3-120	BB60	H	IBu	IBu

[ Table 4Z3]

TABLE 4Z3

	Ba1Z3Ba2Z3	R1Z3	R6Z3	R7Z3
					IZ3-121	BB1	H	Me	H
IZ3-122	BB2	H	H	COM
					IZ3-123	BB3	H	COE	H
IZ3-124	BB4	H	H	Et
					IZ3-125	BB5	H	OCM	H
IZ3-126	BB6	H	H	OME
					IZ3-127	BB7	H	Bu	H
IZ3-128	BB8	H	H	SOT
					IZ3-129	BB9	H	SNH	H
IZ3-130	BB10	H	H	TBu
					IZ3-131	BB11	H	SN2	H
IZ3-132	BB12	H	H	CNM
					IZ3-133	BB13	H	Hex	H
IZ3-134	BB14	H	H	CN2
					IZ3-135	BB15	H	NPH	H
IZ3-136	BB16	H	H	Oct
					IZ3-137	BB17	H	NOT	H
IZ3-138	BB18	H	H	NCO
					IZ3-139	BB19	H	2EH	H
IZ3-140	BB20	H	H	F
					IZ3-141	BB21	H	Cl	H
IZ3-142	BB22	H	H	CHM
					IZ3-143	BB23	H	Br	H
IZ3-144	BB24	H	H	CN
					IZ3-145	BB25	H	CH	H
IZ3-146	BB26	H	H	NO2
					IZ3-147	BB27	H	SUA	H
IZ3-148	BB28	H	H	PH
					IZ3-149	BB29	H	CBA	H
IZ3-150	BB30	H	H	CHO
					IZ3-151	BB31	H	BZ	BZ
IZ3-152	BB32	H	H	OCH
					IZ3-153	BB33	H	NPR	H
IZ3-154	BB34	H	H	OH
					IZ3-155	BB35	H	IPR	H
IZ3-156	BB36	H	H	SFM
					IZ3-157	BB37	H	IBu	H
IZ3-158	BB38	H	H	CBM
					IZ3-159	BB39	H	EOE	H
IZ3-160	BB40	H	H	NH2

[ Table 5Z3]

TABLE 5Z3

	Ba1Z3Ba2Z3	R1Z3	R6Z3	R7Z3
					IZ3-161	BB41	H	ALL	H
IZ3-162	BB42	H	H	NCH
					IZ3-163	BB43	H	HYE	H
IZ3-164	BB44	Me	H	H
					IZ3-165	BB45	COM	H	H
IZ3-166	BB46	COE	H	H
					IZ3-167	BB47	Et	H	H
IZ3-168	BB48	OCM	H	H
					IZ3-169	BB49	OME	H	H
IZ3-170	BB50	Bu	H	H
					IZ3-171	BB51	SOT	H	H
IZ3-172	BB52	SNH	H	H
					IZ3-173	BB53	TBu	H	H
IZ3-174	BB54	SN2	H	H
					IZ3-175	BB55	CNM	H	H
IZ3-176	BB56	Hex	H	H
					IZ3-177	BB57	CN2	H	H
IZ3-178	BB58	NPH	H	H
					IZ3-179	BB59	Oct	H	H
IZ3-180	BB60	NOT	H	H
					IZ3-181	BB1	NCO	H	H
IZ3-182	BB2	2EH	H	H
					IZ3-183	BB3	F	H	H
IZ3-184	BB4	Cl	H	H
					IZ3-185	BB5	CHM	H	H
IZ3-186	BB6	Br	H	H
					IZ3-187	BB7	CN	H	H
IZ3-188	BB8	CH	H	H
					IZ3-189	BB9	NO2	H	H
IZ3-190	BB10	SUA	H	H
					IZ3-191	BB11	PH	H	H
IZ3-192	BB12	CBA	H	H
					IZ3-193	BB13	CHO	H	H
IZ3-194	BB14	BZ	H	H
					IZ3-195	BB15	OCH	H	H
IZ3-196	BB16	NPR	H	H
					IZ3-197	BB17	OH	H	H
IZ3-198	BB18	IPR	H	H
					IZ3-199	BB19	SFM	H	H
IZ3-200	BB20	IBu	H	H

[ Table 6Z3]

TABLE 6Z3

	Ba1Z3Ba2Z3	R1Z3	R6Z3	R7Z3
					IZ3-201	BB21	CBM	H	H
IZ3-202	BB22	EOE	H	H
					IZ3-203	BB23	NH2	H	H
IZ3-204	BB24	ALL	H	H
					IZ3-205	BB25	NCH	H	H
IZ3-206	BB26	HYE	H	H
					IZ3-207	BBI1	H	H	H
IZ3-208	BBD1	H	H	H
					IZ3-209	BBK2	H	H	H
IZ3-210	BBK3	H	H	H
					IZ3-211	BBK4	H	H	H
IZ3-212	BBK14	H	H	H

For example, the compound IZ3-1 is a compound represented by the formula (IZ 3-1).

The compound IZ3 is preferably a compound IZ3-1 to a compound IZ3-120 and a compound IZ3-207 to a compound IZ3-212, more preferably a compound IZ3-1 to a compound IZ3-120, further preferably a compound IZ3-1 to a compound IZ3-60, further more preferably a compound IZ3-1 to a compound IZ3-36, a compound IZ3-37 and a compound IZ3-58,

particularly preferred are the compounds IZ3-1 to IZ3-36, particularly more preferred are the compounds IZ3-1, IZ3-6, IZ3-8, IZ3-11, IZ3-14 and IZ3-19, and particularly preferred are the compounds IZ3-1, IZ3-6 and IZ 3-19.

Specific examples of the compound IZ3 include those shown in tables 1Z3 to 6Z31 to 3 hydrogen atoms contained in the compound are replaced by-SO₃M or-CO₂M is substituted. For example, compounds having 1 to 3 sulfo groups bonded to the compound IZ3-1 of Table 1Z3 are represented by the following structures. Wherein, in the formula, - (SO)₃H) Represents a compound in which any hydrogen atom in compound IZ3-1 of Table 1Z3 is substituted.

In the present invention, it is preferable that 1 to 3-SO groups are bonded to the compound IZ3-1 to the compound IZ3-120 and the compound IZ3-207 to the compound IZ3-212₃M or-CO₂A compound formed by the reaction of M,

more preferably, 1 to 3-SO groups are bonded to the compound IZ3-1 to the compound IZ3-120₃M or-CO₂M, more preferably 1 to 3-SO groups are bonded to the compound IZ3-1 to the compound IZ3-60₃M or-CO₂More preferably, the compound of M is one in which 1 to 3-SO groups are bonded to the compound IZ3-1 to the compound IZ3-36, the compound IZ3-37 or the compound IZ3-58₃M or-CO₂M, particularly preferably 1 to 3-SO groups are bonded to the compound IZ3-1 to the compound IZ3-36₃M or-CO₂M, particularly preferably 1 to 3-SO groups are bonded to the compound IZ3-1, the compound IZ3-6, the compound IZ3-8, the compound IZ3-11, the compound IZ3-14 and the compound IZ3-19 ₃M or-CO₂M, particularly preferably 1 to 3-SO groups are bonded to the compound IZ3-1, the compound IZ3-6 or the compound IZ3-19₃M or-CO₂M, or a salt thereof.

As the compound (IZ3), the following compounds are preferable:

in the formula (IZ3), R^1Z3Is a hydrogen atom and may have a radical selected from the group consisting of-SO₃M and-CO₂The number of carbon atoms of the substituent in the group consisting of M is1 to 20 hydrocarbyl groups, -SO₃M or-CO₂M，

R^2Z3～R^5Z3Each independently represents a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogen atom, or-N (R)^102Z3)₂A C1-20 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R^102Z3、-O-R^102Z3、-SO₃M or-CO₂M，

R^6Z3And R^7Z3Independently of one another, a hydrogen atom, may have a structure selected from the group consisting of-SO₃M and-CO₂A C1-20 hydrocarbon group, -SO₃M or-CO₂M，R^102Z3Is a hydrogen atom, or may have a radical selected from the group consisting of-SO₃M and-CO₂A compound in which the substituent in the group consisting of M is a hydrocarbon group having 1 to 20 carbon atoms, and M is a hydrogen atom or an alkali metal atom;

more preferred are the following compounds:

R^1Z3is a hydrogen atom, and is a hydrogen atom,

R^2Z3～R^5Z3each independently represents a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, or-N (R)^102Z3)₂A C1-10 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R ^102Z3、-O-R^102Z3、-SO₃M or-CO₂M，R^6Z3And R^7Z3Are the same group, are hydrogen atoms, or may have a structure selected from the group consisting of₃M and-CO₂A C1-10 hydrocarbon group as a substituent in the group consisting of M, R^102Z3Is a hydrogen atom, or may have a radical selected from the group consisting of-SO₃M and-CO₂A hydrocarbyl group having 1 to 10 carbon atoms as a substituent in the group consisting of M,

a compound in which M is a hydrogen atom or an alkali metal atom;

further preferred are the following compounds:

R^1Z3is a hydrogen atom, R^2Z3～R^5Z3Each independently a hydrogen atom, a C1-10 hydrocarbon group, a halogenAtom, -N (R)^102Z3)₂Nitro, trifluoromethyl, -O-R^102Z3、-SO₃M or-CO₂M，R^6Z3And R^7Z3The same group is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms,

R^102Z3is a hydrogen atom, or may have a radical selected from the group consisting of-SO₃M and-CO₂A hydrocarbyl group having 1 to 10 carbon atoms as a substituent in the group consisting of M,

m is a hydrogen atom or an alkali metal atom.

For compound IZ3, R^1Z3In the case of a hydrogen atom, the compound represented by the formula (pt1Z3) (hereinafter, may be referred to as a phthalonitrile compound) may be produced by reacting a compound represented by the formula (pt2Z3) (hereinafter, may be referred to as an alkoxide compound), and then further reacting the compound represented by the formula (pt3Z3) and the compound represented by the formula (pt4Z3) in the presence of an acid. In addition, R ^1Z3When not a hydrogen atom, the compound is further reacted with a compound represented by the formula (pt5Z3) to produce a compound IZ 3.

In [ formula (pt1Z3), formula (pt2Z3), formula (pt3Z3), formula (pt4Z3), formula (pt5Z3) and formula (IZ3), R^1Z3～R^7Z3The same meanings as described above are indicated. R^14Z3Represents an alkyl group having 1 to 20 carbon atoms. M^1Z3Represents an alkali metal atom. LG represents a halogen atom, a mesyloxy group, a tosyloxy group or a trifluormesyloxy group.]

As R^14Z3Examples of the alkyl group having 1 to 20 carbon atoms include methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec-butyl, tert-butyl, and the like, and preferred examples thereof include alkyl groups having 1 to 6 carbon atoms.

As M^1Z3Examples of the alkali metal atom include a lithium atom, a sodium atom and a potassium atom.

The amount of the alkoxide compound used is usually 0.1 to 10 moles, preferably 0.2 to 5 moles, more preferably 0.3 to 3 moles, and still more preferably 0.4 to 2 moles, based on 1 mole of the phthalonitrile compound.

The amount of the compound pt3Z3 used is usually 1 to 10 moles, preferably 1 to 5 moles, more preferably 1 to 3 moles, and still more preferably 1 to 2 moles, based on 1 mole of the phthalonitrile compound.

The amount of the compound pt4Z3 used is usually 1 to 10 moles, preferably 1 to 5 moles, more preferably 1 to 3 moles, and still more preferably 1 to 2 moles, based on 1 mole of the phthalonitrile compound.

Examples of the acid include inorganic acids such as hydrochloric acid, hydrobromic acid, hydroiodic acid, sulfuric acid, nitric acid, fluorosulfonic acid, and phosphoric acid; sulfonic acids such as methanesulfonic acid, trifluoromethanesulfonic acid, and p-toluenesulfonic acid; examples of the carboxylic acid include acetic acid, citric acid, formic acid, gluconic acid, lactic acid, oxalic acid, tartaric acid, and the like, and preferably include hydrochloric acid, hydrobromic acid, sulfuric acid, methanesulfonic acid, trifluoromethanesulfonic acid, p-toluenesulfonic acid, and carboxylic acid, and more preferably include acetic acid.

The amount of the acid used is usually 1 to 20 moles, preferably 1 to 10 moles, more preferably 1 to 8 moles, and still more preferably 1 to 6 moles, based on 1 mole of the phthalonitrile compound.

The reaction of the phthalonitrile compound, the alkoxide compound, the compound pt3Z3, and the compound pt4Z3 can be usually carried out in the presence of a solvent.

As the solvent, water may be mentioned; nitrile solvents such as acetonitrile; alcohol solvents such as methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, and 1-octanol; ether solvents such as tetrahydrofuran; ketone solvents such as acetone; ester solvents such as ethyl acetate; aliphatic hydrocarbon solvents such as hexane; aromatic hydrocarbon solvents such as toluene; halogenated hydrocarbon solvents such as dichloromethane and chloroform; amide solvents such as N, N-dimethylformamide and N-methylpyrrolidone; sulfoxide solvents such as dimethyl sulfoxide, preferably include water, nitrile solvents, alcohol solvents, ether solvents, ketone solvents, ester solvents, aromatic hydrocarbon solvents, halogenated hydrocarbon solvents, amide solvents and sulfoxide solvents, more preferably include water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, tetrahydrofuran, acetone, ethyl acetate, toluene, dichloromethane, chloroform, N-dimethylformamide, N-methylpyrrolidone and dimethyl sulfoxide, still more preferably include water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, acetone, dichloromethane, chloroform, N-dimethylformamide, N-methylpyrrolidone and dimethyl sulfoxide, and particularly preferably include water, methanol, ethanol, methanol, ethanol, butanol, methanol, ethanol, 1-butanol, 1-pentanol, 1-octanol, acetone, dichloromethane, chloroform, N-methylpyrrolidone and dimethyl sulfoxide, Acetonitrile, methanol, ethanol and 2-propanol.

The amount of the solvent used is usually 1 to 1000 parts by mass per 1 part by mass of the phthalonitrile compound.

The reaction temperature is usually 0 to 200 ℃, preferably 0 to 100 ℃, more preferably 0 to 70 ℃, and further preferably 0 to 50 ℃. The reaction time is usually 0.5 to 300 hours.

With respect to the amount of compound pt5Z3 used, relative to R^1Z3The amount of the compound IZ31 which is a hydrogen atom is usually 1 to 10 moles, preferably 1 to 5 moles, more preferably 1 to 3 moles, and still more preferably 1 to 2 moles.

When the compound pt5Z3 is reacted, a base is preferably coexisted. Examples of the base include organic bases such as triethylamine, 4- (N, N-dimethylamino) pyridine, and piperidine; metal alkoxides such as sodium methoxide, sodium ethoxide, sodium tert-butoxide, and potassium tert-butoxide; organic metal compounds such as butyl lithium, tert-butyl lithium and phenyl lithium; inorganic bases such as lithium hydroxide, sodium hydroxide and potassium hydroxide.

As for the amount of the base used, with respect to R^1Z3The amount of the compound IZ31 which is a hydrogen atom is usually 1 to 10 moles, preferably 1 to 5 moles, more preferably 1 to 3 moles, and still more preferably 1 to 2 moles.

The reaction of compound pt5Z3 can generally be carried out in the presence of a solvent. The solvent may be selected from the same ranges as described above.

As to the amount of the solvent used, with respect to R^1Z3The amount of the compound IZ 31 is usually 1 to 1000 parts by mass. The reaction temperature of the compound pt5Z3 is usually-90 to 200 ℃, preferably-80 to 100 ℃, and more preferably 0 to 50 ℃. The reaction time is usually 0.5 to 300 hours.

Compound IZ3 having no sulfo group or-SO₃M²In the case of (3), the compound IZ3 can be reacted with a sulfonating agent such as fuming sulfuric acid or chlorosulfonic acid to introduce a sulfo group or-SO₃M²²。

M²²Represents an alkali metal atom. As M²²Examples of the alkali metal atom include a lithium atom, a sodium atom and a potassium atom.

With respect to SO in oleum₃The amount of (b) is usually 1 to 50 mol, preferably 5 to 40 mol, more preferably 5 to 30 mol, and still more preferably 5 to 25 mol based on 31 mol of the compound IZ.

The amount of sulfuric acid used in the oleum is usually 1 to 200 moles, preferably 10 to 100 moles, more preferably 10 to 75 moles, and still more preferably 10 to 50 moles, based on 31 moles of the compound IZ.

The amount of chlorosulfonic acid used is usually 1 to 500 moles, preferably 10 to 300 moles, more preferably 10 to 200 moles, and still more preferably 10 to 150 moles, based on 31 moles of the compound IZ.

The reaction temperature of sulfonation is usually-20 to 200 ℃, preferably-10 to 100 ℃, and more preferably 0 to 50 ℃. The reaction time is usually 0.5 to 300 hours.

The method for extracting the compound IZ3 from the reaction mixture is not particularly limited, and it can be extracted by various known methods. For example, after the reaction is completed, the reaction mixture is filtered to extract the compound IZ 3. Further, the residue obtained after filtration may be subjected to column chromatography, recrystallization, or the like. After the completion of the reaction, the solvent of the reaction mixture may be distilled off and then purified by column chromatography.

< Compound IZ4 >)

Compound IZ4 is a compound represented by formula (IZ 4).

[ in the formula (IZ4),R^N1Z4and R^N2Z4Independently of one another represent-CO-R^102Z4、-COO-R^101Z4、-OCO-R^102Z4、-COCO-R^102Z4、-O-R^102Z4、-SO₂-R^101Z4、-SO₂N(R^102Z4)₂、-CON(R^102Z4)₂、-N(R^102Z4)₂、-NHCO-R^102Z4、-NHCO-N(R^102Z4)₂、-NHCOOR^102Z4、-OCON(R^102Z4)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.

R^1Z4、R^2Z4、R^3Z4、R^4Z4、R^5Z4、R^6Z4And R^7Z4Independently of one another, represents a hydrogen atom, -CO-R^102Z4、-COO-R^101Z4、-OCO-R^102Z4、-COCO-R^102Z4、-O-R^102Z4、-SO₂-R^101Z4、-SO₂N(R^102Z4)₂、-CON(R^102Z4)₂、-N(R^102Z4)₂、-NHCO-R^102Z4、-NHCO-N(R^102Z4)₂、-NHCOOR^102Z4、-OCON(R^102Z4)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent. R^2Z4And R^3Z4、R^3Z4And R^4Z4And R^4Z4And R^5Z4Each of which may be bonded to each other to form a ring. R ^101Z4The alkyl group may have a substituent and has 1 to 40 carbon atoms, or a heterocyclic group may have a substituent. R^102Z4Represents a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group.

M represents a hydrogen atom or an alkali metal atom.

R^101Z4、R^102Z4And when there are a plurality of M, they may be the same or different. The wavy line indicates the E-body or the Z-body.]

R^N1Z4、R^N2Z4、R^1Z4、R^2Z4、R^3Z4、R^4Z4、R^5Z4、R^6Z4、R^7Z4、R^101Z4And R^102Z4The number of carbon atoms of the hydrocarbon group is 1 to 40, preferably 1 to 30, more preferably 1 to 20, still more preferably 1 to 15, and particularly preferably 1 to 10. R^N1Z4、R^N2Z4、R^1Z4、R^2Z4、R^3Z4、R^4Z4、R^5Z4、R^6Z4、R^7Z4、R^101Z4And R^102Z4The hydrocarbon group having 1 to 40 carbon atoms may be an aliphatic hydrocarbon group or an aromatic hydrocarbon group, and the aliphatic hydrocarbon group may be saturated or unsaturated, and may be a chain or alicyclic group.

As R^N1Z4、R^N2Z4、R^1Z4、R^2Z4、R^3Z4、R^4Z4、R^5Z4、R^6Z4、R^7Z4、R^101Z4And R^102Z4Examples of the saturated or unsaturated chain hydrocarbon group include straight chain alkyl groups such as methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, heptadecyl, octadecyl, and eicosyl; branched alkyl groups such as isopropyl, isobutyl, sec-butyl, tert-butyl, (2-ethyl) butyl, isopentyl, neopentyl, tert-pentyl, (1-methyl) pentyl, (2-methyl) pentyl, (1-ethyl) pentyl, (3-ethyl) pentyl, isohexyl, (5-methyl) hexyl, (2-ethyl) hexyl and (3-ethyl) heptyl; alkenyl groups such as vinyl, 1-propenyl, 2-propenyl (allyl), (1-methyl) vinyl, 2-butenyl, 3-butenyl, 1, 3-butadienyl, (1- (2-propenyl)) vinyl, (1, 2-dimethyl) propenyl, and 2-pentenyl; and so on. The number of carbon atoms of the saturated or unsaturated chain hydrocarbon group is preferably 1 to 30, more preferably 1 to 20, further preferably 1 to 15, particularly preferably 1 to 10, further more preferably 1 to 8, and particularly preferably 1 to 5. Among them, a linear or branched alkyl group having 1 to 10 carbon atoms, more preferably 1 to 8 carbon atoms is particularly preferable, and a methyl group, an ethyl group, and a tert-butyl group are particularly preferable.

As R^N1Z4、R^N2Z4、R^1Z4、R^2Z4、R^3Z4、R^4Z4、R^5Z4、R^6Z4、R^7Z4、R^101Z4And R^102Z4Examples of the saturated or unsaturated alicyclic hydrocarbon group include cyclopropyl, 1-methylcyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, 1-methylcyclohexyl, 2-methylcyclohexyl, 3-methylcyclohexyl, 4-methylcyclohexyl, 1, 2-dimethylcyclohexyl, 1, 3-dimethylcyclohexyl, 1, 4-dimethylcyclohexyl, 2, 3-dimethylcyclohexyl, 2, 4-dimethylcyclohexyl, 2, 5-dimethylcyclohexyl, 2, 6-dimethylcyclohexyl, 3, 4-dimethylcyclohexyl, 3, 5-dimethylcyclohexyl, 2-dimethylcyclohexyl, 3-dimethylcyclohexyl, 4-dimethylcyclohexyl, cyclooctyl, 2,4, 6-trimethylcyclohexyl, and, Cycloalkyl groups such as 2,2,6, 6-tetramethylcyclohexyl, 3,5, 5-tetramethylcyclohexyl, 4-pentylcyclohexyl, 4-octylcyclohexyl and 4-cyclohexylcyclohexyl; cycloalkenyl groups such as cyclohexenyl (e.g., cyclohex-2-ene, cyclohex-3-ene), cycloheptenyl, cyclooctenyl, and the like; norbornyl, adamantyl, bicyclo [2.2.2]An octyl group and the like. The number of carbon atoms of the saturated or unsaturated alicyclic hydrocarbon group is preferably 3 to 30, more preferably 3 to 20, still more preferably 4 to 20, yet more preferably 4 to 15, even more preferably 5 to 15, and most preferably 5 to 10. Among them, cyclopentyl, cyclohexyl, cycloheptyl, and cyclooctyl are particularly preferable.

As R^N1Z4、R^N2Z4、R^1Z4、R^2Z4、R^3Z4、R^4Z4、R^5Z4、R^6Z4、R^7Z4、R^101Z4And R^102Z4The aromatic hydrocarbon group may include a phenyl group, an o-tolyl group, a m-tolyl group, a p-tolyl group, a 2, 3-dimethylphenyl group, a 2, 4-dimethylphenyl group, a 2, 5-dimethylphenyl group, a 2, 6-dimethylphenyl group, a 3, 4-dimethylphenyl group, a 3, 5-dimethylphenyl group, a 4-vinylphenyl group, an o-isopropylphenyl group, a m-isopropylphenyl group, a p-isopropylphenyl group, an o-tert-butylphenyl group, a m-tert-butylphenyl group, a p-tert-butylphenyl group, a mesityl group, a 4-ethylphenyl group, a 4-butylphenyl group, a 4-pentylphenyl group, and a 2, 6-bis (2-propyl) benzeneAn aromatic hydrocarbon group such as a phenyl group, a 4-cyclohexylphenyl group, a 2,4, 6-trimethylphenyl group, a 4-octylphenyl group, a 4-vinylphenyl group, a 1-naphthyl group, a 2-naphthyl group, a 5,6,7, 8-tetrahydro-1-naphthyl group, a 5,6,7, 8-tetrahydro-2-naphthyl group, a fluorenyl group, a phenanthryl group, an anthracyl group, or a pyrenyl group; and so on. The number of carbon atoms of the aromatic hydrocarbon group is preferably 6 to 30, more preferably 6 to 20, and further preferably 6 to 15.

R^N1Z4、R^N2Z4、R^1Z4、R^2Z4、R^3Z4、R^4Z4、R^5Z4、R^6Z4、R^7Z4、R^101Z4And R^102Z4The hydrocarbon group may be a combination of the hydrocarbon groups listed above (for example, an aromatic hydrocarbon group, and at least 1 of a chain hydrocarbon group and an alicyclic hydrocarbon group), and examples thereof include aralkyl groups such as benzyl, phenethyl, and 1-methyl-1-phenylethyl; arylalkenyl groups such as phenylvinyl (styryl); arylalkynyl groups such as phenylethynyl; a phenyl group having 1 or more phenyl groups bonded thereto, such as a biphenyl group and a terphenyl group; cyclohexylmethylphenyl, benzylphenyl, (dimethyl (phenyl) methyl) phenyl, and the like.

For R^N1Z4、R^N2Z4、R^1Z4、R^2Z4、R^3Z4、R^4Z4、R^5Z4、R^6Z4、R^7Z4、R^101Z4And R^102Z4Examples of the group represented by the above-mentioned groups, which are a combination of the above-mentioned hydrocarbon groups (e.g., chain hydrocarbon groups and alicyclic hydrocarbon groups), include alkyl groups to which 1 or more alicyclic hydrocarbon groups are bonded, such as cyclopropylmethyl groups, cyclopropylethyl groups, cyclobutylmethyl groups, cyclobutylethyl groups, cyclopentylmethyl groups, cyclopentylethyl groups, cyclohexylmethyl groups, 2-methylcyclohexylmethyl groups, cyclohexylethyl groups, and adamantylmethyl groups.

The number of carbon atoms is preferably 4 to 30, more preferably 6 to 30, further preferably 6 to 20, further preferably 4 to 15, and particularly preferably 6 to 15.

R^N1Z4、R^N2Z4、R^1Z4、R^2Z4、R^3Z4、R^4Z4、R^5Z4、R^6Z4、R^7Z4、R^101Z4And R^102Z4The hydrocarbon group represented may have a substituent. The substituent may have a valence of 1 or 2. For substituents having a valence of 2, preferably 2 chemical bonds are bonded to the same carbon atom to form a double bond.

Examples of the substituent having a valence of 1 include:

methoxy group, ethoxy group, propoxy group, isopropoxy group, butoxy group, isobutoxy group, sec-butoxy group, tert-butoxy group, pentyloxy group, hexyloxy group, (2-ethyl) hexyloxy group, heptyloxy group, octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, dodecyloxy group, (2-ethyl) hexyloxy group, eicosyloxy group, 1-phenylethoxy group, 1-methyl-1-phenylethoxy group, phenyloxy group, o-tolyloxy group, 2, 3-dimethylphenyloxy group, 2, 4-dimethylphenyloxy group, 2, 5-dimethylphenyloxy group, 2, 6-dimethylphenyloxy group, 3, 4-dimethylphenyloxy group, 3, 5-dimethylphenyloxy group, 2-dicyanophenyloxy group, 2, 3-dicyanophenyloxy group, 2-dicyanophenyloxy group, 2, 4-dicyanophenyloxy group, 2, 5-dicyanophenyloxy group, 2, 6-dicyanophenyloxy group, 3, 4-dicyanophenyloxy group, 3, 5-dicyanophenyloxy group, 4-methoxyphenyloxy group, an oxy group having a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like) bonded to one side, such as a 2-methoxyphenyloxy group, a 3-methoxyphenyloxy group, a 4-ethoxyphenyloxy group, a 2-ethoxyphenyloxy group, a 3-ethoxyphenyloxy group, or a group represented by the following chemical formula;

A thio group (sulfo group) to which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) is bonded, such as a methylthio group, an ethylthio group, a propylthio group, a butylthio group, a tert-butylthio group, a pentylthio group, a hexylthio group, (2-ethyl) hexylthio group, a heptylthio group, an octylthio group, a nonylthio group, a decylthio group, an undecylthio group, a dodecylthio group, an eicosylthio group, a phenylthio group, and an o-tolylthio group;

epoxy, oxetanyl, tetrahydrofuranyl, tetrahydropyranyl; a formyl group; a carbonyl group (preferably 2 to 12 carbon atoms when the carbonyl group is an alkanoyl group) having a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 11 carbon atoms) or a derivative thereof (for example, a derivative thereof such as a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), or an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)) bonded thereto, such as an acetyl group, a propionyl group, a butyryl group, a 2, 2-dimethylpropionyl group, a pentanoyl group, a hexanoyl group, (2-ethyl) hexanoyl group, a heptanoyl group, an octanoyl group, a nonanoyl group, a decanoyl group, an undecanoyl group, a dodecanoyl group, an heneicosanoyl group, and a benzoyl group;

An oxycarbonyl group in which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) is bonded, such as a methoxycarbonyl group, an ethoxycarbonyl group, a propoxycarbonyl group, a butoxycarbonyl group, a tert-butoxycarbonyl group, a pentyloxycarbonyl group, a hexyloxycarbonyl group, (2-ethyl) a hexyloxycarbonyl group, a heptyloxycarbonyl group, an octyloxycarbonyl group, a nonyloxycarbonyl group, a decyloxycarbonyl group, a undecyloxycarbonyl group, a dodecyloxycarbonyl group, an eicosyloxycarbonyl group, a phenyloxycarbonyl group, or an o-tolyloxycarbonyl group represented by the following chemical formula);

an amino group; n-methylamino, N-dimethylamino, N-ethylamino, N-diethylamino, N-propylamino, N-dipropylamino, N-isopropylamino, N-diisopropylamino, N-butylamino, N-dibutylamino, N-isobutylamino, N-diisobutylamino, N-sec-butylamino, N-di-sec-butylamino, N-tert-butylamino, N-di-tert-butylamino, N-pentylamino, N-dipentylamino, N- (1-ethylpropyl) amino, N-di (1-ethylpropyl) amino, N-hexylamino, N-dihexylamino, N- (2-ethyl) hexylamino, N-diethylamino, N-propylamino, N-dipropylamino, N-isopropylamino, N-di-sec-butylamino, N-pentylamino, N-dipentylamino, N-1-ethylpropyl) amino, N-di (1-ethylpropyl) amino, N-hexylamino, N-butylamino, N-butylamino, N-di-butylamino, N-butylamino, N, n, N-di (2-ethyl) hexylamino group, N-heptylamino group, N-diheptylamino group, N-octylamino group, N-dioctylamino group, N-nonylamino group, N-dinonylamino group, N-phenylamino group, N-diphenylamino group, N-ethylmethylamino group, N-propylmethylamino group, N-isopropylmethylamino group, N-butylmethylamino group, N-decylamino group, N-decylmethylamino group, N-undecylamino group, N-undecylmethylamino group, N-dodecylamino group, N-dodecylmethylamino group, N-eicosylamino group, N-eicosylmethyl amino group, An amino group substituted with 1 or 2 hydrocarbon groups having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or derivative groups thereof (for example, groups derived from carboxyl, sulfo, nitro, hydroxyl, halogen (preferably chlorine atom), alkylsulfamoyl having 1 to 10 carbon atoms (preferably octylsulfamoyl), and the like, such as an N, N-tert-butylmethylamino group, an N, N-phenylmethylamino group, and the like, and groups represented by the following chemical formula);

A sulfamoyl group; n-methylsulfamoyl, N-dimethylsulfamoyl, N-ethylsulfamoyl, N-diethylsulfamoyl, N-propylsulfamoyl, N-dipropylsulfamoyl, N-isopropylsulfamoyl, N-diisopropylsulfamoyl, N-butylsulfamoyl, N-dibutylsulfamoyl, N-isobutylsulfamoyl, N-diisobutylsulfamoyl, N-sec-butylsulfamoyl, N-tert-butylsulfamoyl, N-di-tert-butylsulfamoyl, N-pentylsulfamoyl, N-dipentylsulfamoyl, N- (1-ethylpropyl) sulfamoyl, N-di (1-ethylpropyl) sulfamoyl, N-diethylsulfamoyl, N-di (1-ethylpropyl) sulfamoyl, N-diethylsulfamoyl, N-butylsulfamoyl, N-di (1-ethylpropyl) sulfamoyl, N-butylsulfamoyl, N-di (1-isobutylsulfamoyl), N-dibutylsulfamoyl, N, di (1-di (ethyl, N, N, N-hexylsulfamoyl, N-dihexylsulfamoyl, N- (2-ethyl) hexylsulfamoyl, N-di (2-ethyl) hexylsulfamoyl, N-heptylsulfamoyl, N-diheptylsulfamoyl, N-octylsulfamoyl, N-dioctylsulfamoyl, N-octylmethylsulfamoyl, N-nonylsulfamoyl, N-dinonylsulfamoyl, N-phenylsulfamoyl, N-diphenylsulfamoyl, N-ethylmethylsulfamoyl, N-propylmethylsulfamoyl, N-isopropylmethylsulfamoyl, N-butylmethylsulfamoyl, N-decylsulfamoyl, N-decylmethylsulfamoyl, Sulfamoyl groups substituted with 1 or 2 hydrocarbon groups having 1 to 20 (preferably 1 to 10) carbon atoms or derivative groups thereof (for example, groups derived from carboxyl, sulfo, nitro, hydroxyl, halogen (preferably chlorine atom), alkylsulfamoyl having 1 to 10 carbon atoms (preferably octylsulfamoyl), and the like, such as N-undecylsulfamoyl, N-undecylmethylsulfamoyl, N-dodecylsulfamoyl, N-dodecylmethylsulfamoyl, N-eicosylsulfamoyl, N-eicosylmethylsulfamoyl, N-tert-butylmethylsulfamoyl, N-phenylmethylsulfamoyl, and the like, and groups represented by the following chemical formulae);

A formylamino group; acetylamino, propionylamino, butyrylamino, 2-dimethylpropionylamino, valerylamino, hexanoylamino, (2-ethyl) hexanoylamino, heptanoylamino, a carbonylamino group (preferably 1 to 12 carbon atoms in the case where the carbonylamino group is an alkanoylamino group), to which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 12 carbon atoms) or a derivative thereof (for example, a derivative thereof such as a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)) is bonded, such as an octanoylamino group, a nonanoylamino group, a decanoylamino group, a undecanoylamino group, a dodecanoylamino group, a heneicosanoylamino group, or a benzoylamino group represented by the following chemical formula;

a hydroxyl group; halogen atoms such as fluorine atom, chlorine atom, bromine atom and iodine atom;

carboxy, -CO₂M²(M²Is an alkali metal, preferably lithium, sodium, potassium); sulfo, -SO₃M²(M²Is an alkali metal, preferably lithium, sodium, potassium); a nitro group; a cyano group;

a formyloxy group; acetoxy, propionyloxy, butyryloxy, 2-dimethylpropionyloxy, pentanoyloxy, hexanoyloxy, (2-ethyl) hexanoyloxy, heptanoyloxy, a carbonyloxy group (preferably 1 to 10 carbon atoms in the case where the carbonyloxy group is an alkanoyloxy group) to which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or a derivative thereof (for example, a derivative thereof such as a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)) is bonded, such as an octanoyloxy group, a nonanoyloxy group, a decanoyloxy group, a undecanoyloxy group, a dodecanoyloxy group, a heneicosanoyloxy group, a benzoyloxy group, and the like, and a group represented by the following chemical formula;

A sulfonyl group having a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like) bonded thereto, such as a methylsulfonyl group, an ethylsulfonyl group, a propylsulfonyl group, a butylsulfonyl group, a pentylsulfonyl group, a hexylsulfonyl group, a (2-ethyl) hexylsulfonyl group, a heptylsulfonyl group, an octylsulfonyl group, a nonylsulfonyl group, a decylsulfonyl group, an undecylsulfonyl group, a dodecylsulfonyl group, an eicosylsulfonyl group, a phenylsulfonyl group, a p-tolylsulfonyl group, or the like represented by the following chemical formula;

a carbamoyl group; n-methylcarbamoyl, N-dimethylcarbamoyl, N-ethylcarbamoyl, N-diethylcarbamoyl, N-propylcarbamoyl, N-dipropylcarbamoyl, N-isopropylcarbamoyl, N-diisopropylcarbamoyl, N-butylcarbamoyl, N-dibutylcarbamoyl, N-isobutylcarbamoyl, N-diisobutylcarbamoyl, N-sec-butylcarbamoyl, N-di-sec-butylcarbamoyl, N-tert-butylcarbamoyl, N-di-tert-butylcarbamoyl, N-pentylcarbamoyl, N-dipentylcarbamoyl, N- (1-ethylpropyl) carbamoyl, N-ethylcarbamoyl, N-diethylcarbamoyl, N-isopropylcarbamoyl, N-diisopropylcarbamoyl, N-isopropylcarbamoyl, N-butylcarbamoyl, N-t-butylcarbamoyl, N-t-butylcarbamoyl, N-N-butylcarbamoyl, N-t-butylcarbamoyl, N-N-butylcarbamoyl, N-t-N-t-butylcarbamoyl, N-t-butylcarbamoyl, N-t, N, N-di (1-ethylpropyl) carbamoyl, N-hexylcarbamoyl, N-dihexylcarbamoyl, N- (2-ethyl) hexylcarbamoyl, N-di (2-ethyl) hexylcarbamoyl, N-heptylcarbamoyl, N-diheptylcarbamoyl, N-octylcarbamoyl, N-dioctylcarbamoyl, N-nonylcarbamoyl, N-octylmethylcarbamoyl, N-octylbutylcarbamoyl, N-dinonylcarbamoyl, N-phenylcarbamoyl, N-diphenylcarbamoyl, N-ethylmethylcarbamoyl, N-propylmethylcarbamoyl, N-ethylmethylcarbamoyl, N-propylmethylcarbamoyl, N-ethylhexylcarbamoyl, N-dihexylcarbamoyl, N- (2-ethyl) hexylcarbamoyl, N-octylcarbamoyl, N-diheptylcarbamoyl, N-octylcarbamoyl, N-nonylcarbamoyl, N-octylcarbamoyl, N-octylmethylcarbamoyl, N-octylcarbamoyl, N-octylmethylcarbamoyl, N-nonylcarbamoyl, N-dimethylcarbamoyl, N, a hydrocarbon group having 1 to 2 carbon atoms of 1 to 20 (preferably 1 to 10 carbon atoms) or a derivative thereof (for example, a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an N, N-isopropylmethylcarbamoyl group, an N, N-butylmethylcarbamoyl group, an N-decylmethylcarbamoyl group, an N, N-decylmethylcarbamoyl group, an N-undecylcarbamoyl group, an N, N-undecylmethylcarbamoyl group, an N-dodecylcarbamoyl group, an N, N-dodecylmethylcarbamoyl group, an N-eicosylcarbamoyl group, an N, N-eicosylmethylcarbamoyl group, an N, N-tert-butylmethylcarbamoyl group, an N, N-phenylmethylcarbamoyl group, etc., and a group represented by the following chemical formula, etc. (preferably a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), a derivative thereof, A carbamoyl group substituted with an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably, an octylsulfamoyl group) or the like;

A hydrocarbon group having 1 to 20 carbon atoms, which is obtained by substituting all hydrogen atoms with fluorine atoms such as a trifluoromethyl group, a perfluoroethyl group, a perfluoropropyl group, a perfluoroisopropyl group, a perfluorobutyl group, a perfluoropentyl group, a perfluorohexyl group, a perfluoroheptyl group, a perfluorooctyl group, a perfluorononyl group, a perfluorodecyl group, a perfluoroundecyl group, a perfluorododecyl group, a perfluoroeicosyl group, a perfluorocyclohexyl group, and a perfluorophenyl group;

a hydrocarbon group having 1 to 20 carbon atoms which has, as a substituent, a linear or branched alkyl group having 1 to 20 carbon atoms in which all hydrogen atoms are substituted with fluorine atoms, such as a perfluoroethylmethyl group, a perfluoropropylmethyl group, a perfluoroisopropylmethyl group, a perfluorobutylmethyl group, a perfluoropentylmethyl group, a perfluorohexylmethyl group, a perfluoroheptylmethyl group, a perfluorooctylmethyl group, a perfluorononylmethyl group, a perfluorodecylmethyl group, a perfluoroundecylmethyl group, a perfluorododecylmethyl group, or a perfluoroeicosylmethyl group;

a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) in which some hydrogen atoms are substituted with fluorine, such as a 2-fluorophenyl group, a 3-fluorophenyl group, a 4-fluorophenyl group, and a 2,4, 6-trifluorophenyl group;

-CO-SH、-CO-S-CH₃、-CO-S-CH₂CH₃、-CO-S-CH₂-CH₂-CH₃、-CO-S-CH₂-CH₂-CH₂-CH₃or a thiocarbonyl group, -CO-S-C, bonded to an alkyl group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) ₆H₅A thiocarbonyl group bonded to an aryl group having 6 to 20 carbon atoms;

a group represented by the following chemical formula, — COCO-R (wherein R represents a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)), or the like);

-NRCONR represented by the following chemical formula₂(wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group having 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like), and R's may be the same or different from each other and may be bonded to each other to form a ring);

OCONR represented by the following chemical formula₂(wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorogen) A derivative of an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)), wherein R's may be the same or different and may be bonded to each other to form a ring);

a group represented by the following chemical formula-NRCOOR (wherein R represents a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like), wherein R may be the same or different from each other, and may be bonded to each other to form a ring);

*-OP(O)(OCH₃)₂etc.. OP (O) (OR)₂(wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group having 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like), and R's may be the same or different from each other and may be bonded to each other to form a ring);

*-Si(CH₃)₃、*-Si(CH₂CH₃)₃、*-Si(C₆H₅)₃and-Si (CH)₃)₂)₃Etc. -SiR₃(wherein R is a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms) (for exampleA hydrocarbon group having 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereof with a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like), wherein R may be the same or different from each other, and may be bonded to each other to form a ring); and so on.

Examples of the substituent having a valence of 2 include an oxo group, a thioxo group, an imino group substituted with an alkyl group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms), and an imino group substituted with an aryl group having 6 to 20 carbon atoms. Examples of the imino group substituted with an alkyl group include CH₃-N＝、CH₃-CH₂-N＝、CH₃-(CH₂)₂-N ═ and CH₃-(CH₂)₃-N ═ and the like. Examples of the imino group substituted with an aryl group include C₆H₅-N ═ and the like.

As the substituent of the hydrocarbon group having 1 to 40 carbon atoms, preferred is a substituent of group s 1. The derivative group shown below is preferably a derivative group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like.

[ group s1]

An oxy group having a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof bonded to one side thereof;

a carbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof is bonded;

an oxycarbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof is bonded;

an amino group; amino substituted by 1 or 2 alkyl with 1-20 carbon atoms or derivative groups thereof; a sulfamoyl group; a sulfamoyl group substituted with 1 or 2 hydrocarbon groups having 1 to 20 carbon atoms or derivative groups thereof; a carbonylamino group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof is bonded; a hydroxyl group; a halogen atom; -CO₂M (preferably carboxyl group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom); -SO₃M (you)Sulfo group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom. ) (ii) a A nitro group; a cyano group; a carbonyloxy group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof is bonded; a sulfonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof is bonded; a carbamoyl group; carbamoyl substituted by 1 or 2 hydrocarbon groups having 1 to 20 carbon atoms or derivative groups thereof; a hydrocarbon group having 1 to 20 carbon atoms, wherein all hydrogen atoms are substituted with fluorine atoms; a hydrocarbon group having 1 to 20 carbon atoms, which has a linear or branched alkyl group having 1 to 20 carbon atoms, wherein all hydrogen atoms are substituted with fluorine atoms, as a substituent;

A hydrocarbon group having 1 to 20 carbon atoms, wherein a part of hydrogen atoms is substituted with fluorine;

an oxo group.

The substituent of the hydrocarbon group having 1 to 40 carbon atoms is more preferably a substituent of group s 2.

[ group s2]

An oxy group having a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof bonded to one side thereof;

a carbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded;

an oxycarbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded;

an amino group; an amino group substituted with 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms;

a sulfamoyl group; a sulfamoyl group substituted with 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms or derivative groups thereof; a carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded; a hydroxyl group; fluorine atom, chlorine atom, bromine atom; -CO₂M (preferably carboxyl group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom); -SO₃M (preferably sulfo) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom); a nitro group; a cyano group; a carbonyloxy group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded; a sulfonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded; a carbamoyl group; carbamoyl substituted by 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms or derivative groups thereof; fluorine A hydrocarbon group having 1 to 10 carbon atoms in which all hydrogen atoms are substituted with atoms; a hydrocarbon group having 1 to 10 carbon atoms, which has a linear or branched alkyl group having 1 to 10 carbon atoms, wherein all hydrogen atoms are substituted with fluorine atoms, as a substituent; a hydrocarbon group having 1 to 10 carbon atoms, wherein a part of hydrogen atoms is substituted with fluorine; an oxo group.

As R^N1Z4、R^N2Z4、R^1Z4、R^2Z4、R^3Z4、R^4Z4、R^5Z4、R^6Z4、R^7Z4、R^101Z4And R^102Z4The hydrocarbon group having 1 to 40 carbon atoms and having a substituent represented by the formula (I) includes a hydrocarbon group having 1 to 40 carbon atoms and having a substituent having a valence of 1 or 2, preferably a saturated or unsaturated chain hydrocarbon group having 1 to 30 carbon atoms and having a substituent having a valence of 1 or 2, a saturated or unsaturated alicyclic hydrocarbon group having 3 to 30 carbon atoms and having a substituent having a valence of 1 or 2, an aromatic hydrocarbon group having 6 to 30 carbon atoms and having a substituent having a valence of 1 or 2, and a group having 1 to 30 carbon atoms and having a substituent having a valence of 1 or 2, which are a combination of hydrocarbon groups,

more preferably, the hydrocarbon group includes a saturated or unsaturated chain hydrocarbon group having 1 to 20 carbon atoms having a substituent of group s1, a saturated or unsaturated alicyclic hydrocarbon group having 3 to 20 carbon atoms having a substituent of group s1, an aromatic hydrocarbon group having 6 to 20 carbon atoms having a substituent of group s1, or a combination of hydrocarbon groups having 1 to 20 carbon atoms having a substituent of group s1,

Particularly preferred examples thereof include a saturated or unsaturated chain hydrocarbon group having 1 to 15 carbon atoms having a substituent of group s2, a saturated or unsaturated alicyclic hydrocarbon group having 3 to 15 carbon atoms having a substituent of group s2, an aromatic hydrocarbon group having 6 to 15 carbon atoms having a substituent of group s2, or a group having 1 to 15 carbon atoms having a substituent of group s2, which is a combination of hydrocarbon groups.

As R^N1Z4、R^N2Z4、R^1Z4、R^2Z4、R^3Z4、R^4Z4、R^5Z4、R^6Z4、R^7Z4、R^101Z4And R^102Z4Hetero ofThe cyclic group may be monocyclic or polycyclic, and is preferably a heterocyclic ring containing a heteroatom as a constituent of the ring. Examples of the hetero atom include a nitrogen atom, an oxygen atom, a sulfur atom and the like.

The number of carbon atoms of the heterocyclic group is preferably 3 to 30, more preferably 3 to 22, further preferably 3 to 20, further preferably 3 to 18, further more preferably 3 to 15, and particularly preferably 3 to 14.

Examples of the heterocyclic ring containing a nitrogen atom include:

monocyclic saturated heterocycles such as aziridine, azetidine, pyrrolidine, piperidine and piperazine; five-membered ring system unsaturated heterocycles such as pyrrole (e.g., 2, 5-dimethylpyrrole), pyrazole (e.g., 2-methylpyrazole and 3-methylpyrazole), imidazole, 1,2, 3-triazole and 1,2, 4-triazole;

a six-membered ring system unsaturated heterocycle such as pyrimidine, pyrazine and 1,3, 5-triazine, for example pyridine, pyridazine and 6-methylpyrimidine;

A fused bicyclic heterocycle such as quinoxaline (e.g., indazole, indoline, isoindoline, indole, indolizine, benzimidazole, quinoline, isoquinoline, 5,6,7, 8-tetrahydro (3-methyl) quinoxaline or 3-methylquinoxaline, quinazoline, cinnoline, phthalazine, naphthyridine, purine, pteridine, benzopyrazole or phenylpiperidine;

condensed tricyclic heterocycles such as carbazole, acridine and phenazine; and so on.

Examples of the heterocyclic ring containing an oxygen atom include:

monocyclic saturated heterocycles such as oxetane, tetrahydrofuran, tetrahydropyran, 1, 3-dioxane, 1, 4-dioxane and 1-cyclopentyldioxolane;

bicyclic saturated heterocycles such as 1, 4-dioxaspiro [4.5] decane and 1, 4-dioxaspiro [4.5] nonane;

lactone heterocycles such as α -caprolactone, β -propiolactone, γ -butyrolactone, γ -valerolactone and δ -valerolactone;

five-membered ring system unsaturated heterocycles such as furan (e.g., 2, 3-dimethylfuran, 2, 5-dimethylfuran); a six-membered ring system unsaturated heterocycle such as 2H-pyran, 4H-pyran;

fused bicyclic heterocycles such as benzopyrans (e.g., 1-benzofuran and 4-methylbenzopyran), benzodioxole, chroman and isochroman;

fused tricyclic heterocycles such as xanthene and dibenzofuran; and so on.

Examples of the heterocyclic ring containing a sulfur atom include:

five-membered ring system saturated heterocycles such as dithiolane;

saturated heterocyclic rings of six-membered ring systems such as thiacyclohexane, 1, 3-dithiane, 2-methyl-1, 3-dithiane and the like;

a five-membered ring system unsaturated heterocycle such as thiophene (e.g., 3-methylthiophene, 2-carboxythiophene), benzothiopyran (e.g., 4H-thiopyran, tetrahydrothiopyran);

fused bicyclic heterocycles such as benzothiophene; fused tricyclic heterocycles such as thianthrene and dibenzothiophene; and so on.

Examples of the heterocyclic ring containing a nitrogen atom and an oxygen atom include:

monocyclic saturated heterocycles such as morpholine, 2-pyrrolidone, 2-methyl-2-pyrrolidone, 2-piperidone and 2-methyl-2-piperidone; a monocyclic unsaturated heterocycle such as oxazole (e.g., 4-methyloxazole), isoxazole (e.g., 2-methylisoxazole, and 3-methylisoxazole);

fused bicyclic heterocycles such as benzoxazole, benzisoxazole, benzoxazine, benzodioxane, and benzimidazoline; condensed tricyclic heterocycles such as phenoxazine; and so on.

Examples of the heterocyclic ring containing a nitrogen atom and a sulfur atom include monocyclic heterocyclic rings such as thiazoles, e.g., 3-methylthiazole and 2, 4-dimethylthiazole; fused bicyclic heterocycles such as benzothiazole; fused tricyclic heterocycles such as phenothiazine; and so on.

The heterocyclic ring may be a combination of the above-mentioned hydrocarbon groups, and examples thereof include tetrahydrofurylmethyl and the like.

The heterocyclic ring may be a heterocyclic ring represented by the following chemical formula.

The above heterocyclic group may be R^1Z4～R^5Z42 or more of them are bonded to form a heterocyclic group. Such heterocyclic radicals contain R^1Z4～R^5Z4The bonded benzene ring has a ring structure of 2 or more rings inside. The 2 or more ring structures include, for example, the structures of the following chemical formulae.

The bonding position of the heterocyclic ring is a portion where any hydrogen atom contained in each ring is removed.

R^N1Z4、R^N2Z4、R^1Z4、R^2Z4、R^3Z4、R^4Z4、R^5Z4、R^6Z4、R^7Z4、R^101Z4And R^102Z4The heterocyclic group represented may have a substituent. Examples of the substituent include^N1Z4、R^N2Z4、R^1Z4、R^2Z4、R^3Z4、R^4Z4、R^5Z4、R^6Z4、R^7Z4、R^101Z4And R^102Z4The hydrocarbon group may have the same substituent as the substituent. In the case where the above-mentioned heterocyclic ring contains a nitrogen atom as its constituent element, the above-mentioned hydrocarbon group as a substituent may be bonded to the nitrogen atom.

Preferred examples of the substituent include^N1Z4、R^N2Z4、R^1Z4、R^2Z4、R^3Z4、R^4Z4、R^5Z4、R^6Z4、R^7Z4、R^101Z4And R^102Z4The preferable examples of the substituents which the hydrocarbon group may have are the same.

As R^N1Z4、R^N2Z4、R^1Z4、R^2Z4、R^3Z4、R^4Z4、R^5Z4、R^6Z4、R^7Z4、R^101Z4And R^102Z4The heterocyclic group having a substituent(s) represented by (a) may be a heterocyclic group having a substituent having a valence of 1 or 2, preferably a heterocyclic group having a substituent of group s1, and more preferably Preferred examples thereof include heterocyclic groups having a substituent of group s 2. The substituent (first substituent) that the hydrocarbon group or heterocyclic group may have may be 1 or 2 or more, and 2 or more substituents may be the same or different and independent of each other. Further, the first substituent may have another substituent (second substituent) bonded to the hydrocarbon group included in a part thereof. The second substituent may be selected from the same groups as the first substituent.

Below, for R^N1Z4、R^N2Z4、R^1Z4、R^2Z4、R^3Z4、R^4Z4、R^5Z4、R^6Z4、R^7Z4Of (a) is-CO-R^102Z4、-COO-R^101Z4、-OCO-R^102Z4、-COCO-R^102Z4、-O-R^102Z4、-SO₂-R^101Z4、-SO₂N(R^102Z4)₂、-CON(R^102Z4)₂、-N(R^102Z4)₂、-NHCO-R^102Z4、-NHCO-N(R^102Z4)₂、-NHCOOR^102Z4、-OCON(R^102Z4)₂Halogen atom, -SO₃M、-CO₂M is explained.

as-CO-R^102Z4Examples thereof include a formyl group; acetyl, propionyl, butyryl, 2-dimethylpropionyl, pentanoyl, hexanoyl, (2-ethyl) hexanoyl, heptanoyl, examples of the carbonyl group include a carbonyl group (in the case where the carbonyl group is an acyl group, the number of carbon atoms is 2 to 41) in which a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)) is bonded, such as an octanoyl group, a nonanoyl group, a decanoyl group, a undecanoyl group, a dodecanoyl group, an heneicosanoyl group, and a benzoyl group, and the compounds shown in tables 1Z4 to 8Z4 and 11Z4 to 16Z4 correspond to — CO — R. ^102Z4The group (b) preferably includes a carbonyl group (in which the carbonyl group is an alkanoyl group) to which a hydrocarbon group having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms) or a derivative thereof is bondedIn the case, the number of carbon atoms is more preferably 2 to 12) and the compounds shown in Table 1Z4 to Table 8Z4 and Table 11Z4 to Table 16Z4 correspond to-CO-R^102Z4And the like.

as-COO-R^101Z4Examples thereof include methoxycarbonyl, ethoxycarbonyl, propoxycarbonyl, tert-butoxycarbonyl, pentyloxycarbonyl, hexyloxycarbonyl, (2-ethyl) hexyloxycarbonyl and heptyloxycarbonyl, an oxycarbonyl group in which a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) is bonded such as an octyloxycarbonyl group, a nonyloxycarbonyl group, a decyloxycarbonyl group, an undecyloxycarbonyl group, a dodecyloxycarbonyl group, a phenyloxycarbonyl group, an eicosyloxycarbonyl group and the like, and the groups represented by the above chemical formulae, and the compounds shown in tables 1Z4 to 8Z4 and tables 11Z4 to 16Z4 correspond to-COO-R. ^102Z4Preferred examples of the group (b) include oxycarbonyl groups to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded, and compounds shown in tables 1Z4 to 8Z4 and tables 11Z4 to 16Z4 which correspond to-COO-R^102Z4And the like.

as-OCO-R^102Z4Examples thereof include a formyloxy group; acetoxy, propionyloxy, butyryloxy, 2-dimethylpropionyloxy, pentanoyloxy, hexanoyloxy, (2-ethyl) hexanoyloxy, heptanoyloxy, examples of the carbonyl group include a carbonyl group (in the case where the carbonyl group is an acyloxy group, the carbon number is 2 to 41) in which a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a derivative thereof such as a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)) is bonded, such as an octanoyloxy group, a nonanoyloxy group, a decanoyloxy group, a undecanoyloxy group, a dodecanoyloxy group, a heneicosanoyloxy group, and a benzoyloxy group, and tables 1Z4 to 8Z4 and 11Z4 to 16Z 4.Corresponding to-OCO-R in the compound^102Z4Preferable examples of the group(s) include a carbonyloxy group (more preferably 2 to 12 carbon atoms when the carbonyloxy group is an acyloxy group) to which a hydrocarbon group having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms) or a derivative thereof is bonded, and a compound represented by any one of tables 1Z4 to 8Z4 and tables 11Z4 to 16Z4 corresponds to-OCO-R ^102Z4And the like.

as-COCO-R^102Z4Examples thereof include methyloxalyl, ethyloxalyl, propyloxalyl, butyloxalyl, pentyloxalyl, hexyloxalyl, (2-ethyl) hexyloxalyl, heptyloxalyl, octyloxalyl, nonyloxalyl, an oxalyl group in which a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group) is bonded, such as decyl oxalyl group, undecyloxalyl group, dodecyl oxalyl group, eicosyl oxalyl group, cyclopentyl oxalyl group, cyclohexyl oxalyl group, phenyl oxalyl group, p-tolyloxalyl group, and the group represented by the above chemical formula), and compounds shown in tables 1Z4 to 8Z4 and tables 11Z4 to 16Z4 correspond to — COCO — R.^102Z4And the like.

as-O-R^102Z4There may be mentioned a hydroxyl group; methoxy, ethoxy, propoxy, isopropoxy, butoxy, isobutoxy, sec-butoxy, tert-butoxy, pentyloxy, hexyloxy, heptyloxy, octyloxy, nonyloxy, decyloxy, undecyloxy, dodecyloxy, (2-ethyl) hexyloxy, eicosyloxy, 1-phenylethoxy, 1-methyl-1-phenylethoxy, phenyloxy, 2, 3-dimethylphenyloxy, 2, 4-dimethylphenyloxy, 2, 5-dimethylphenyloxy, 2, 6-dimethylphenyloxy, 3, 4-dimethylphenyloxy, 3, 5-dimethylphenyloxy, 2-dicyanophenyloxy, 2, 3-dicyanophenyloxy, 2, 4-dicyanophenyloxy, sec-butyloxy, tert-butyloxy, pentyloxy, hexyloxy, heptyloxy, octyloxy, decyloxy, 2, 3-dimethylphenyloxy, 2, 4-dimethylphenyloxy, 2, 4-dimethylphenyloxy, 3-dimethylphenyloxy, 2-dicyanophenyloxy, 2, 4-di-yloxy, 2-di-methyl-1-phenylethoxy, 2, 4-di-methyl, and mixtures thereof, 2, 5-dicyanophenyloxy, 2, 6-dicyanophenyloxy, 3, 4-dicyanophenyloxy, 3, 5-dicyanophenyloxy, 4-methoxyphenyloxy An oxy group having a hydrocarbyl group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)) bonded thereto, such as a phenylphenoxy group, a 2-methoxyphenyloxy group, a 3-methoxyphenyloxy group, a 4-ethoxyphenyloxy group, a 2-ethoxyphenyloxy group, a 3-ethoxyphenyloxy group, or a group represented by the above chemical formula, and a group corresponding to-O-R-4 and the compounds represented by tables 1Z4 to 8Z4 and 11Z4 to 16Z4^102Z4Preferred examples of the group (b) include an oxy group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded, and compounds shown in tables 1Z4 to 8Z4 and tables 11Z4 to 16Z4, which correspond to-O-R^102Z4And the like.

as-SO₂-R^101Z4Examples thereof include methylsulfonyl, ethylsulfonyl, propylsulfonyl, butylsulfonyl, pentylsulfonyl, hexylsulfonyl, (2-ethyl) hexylsulfonyl, heptylsulfonyl, octylsulfonyl, nonyl sulfonyl, decyl sulfonyl, undecyl sulfonyl, dodecyl sulfonyl, eicosyl sulfonyl, phenyl sulfonyl, p-tolyl sulfonyl, and the like, and sulfonyl groups in which a hydrocarbon group having 1 to 40 (preferably 1 to 20) carbon atoms or a derivative thereof (for example, a derivative derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like is bonded, such as the group represented by the above chemical formula, and-SO corresponds to the compounds shown in tables 1Z4 to 8Z4 and tables 11Z4 to 16Z 4. ₂-R^102Z4Preferable examples of the group (b) include sulfonyl groups to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded, and compounds represented by tables 1Z4 to 8Z4 and tables 11Z4 to 16Z4, which correspond to-SO₂-R^102Z4And the like.

as-SO₂N(R^102Z4)₂Examples thereof include:

a sulfamoyl group; n-methylsulfamoyl, N-ethylsulfamoyl, N-propylsulfamoyl, N-isopropylsulfamoylA hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a carboxyl group, a sulfo group, an N-butylsulfamoyl group, an N-sec-butylsulfamoyl group, an N-tert-butylsulfamoyl group, an N-pentylsulfamoyl group, an N- (1-ethylpropyl) sulfamoyl group, an N-hexylsulfamoyl group, an N- (2-ethyl) hexylsulfamoyl group, an N-heptylsulfamoyl group, an N-octylsulfamoyl group, an N-nonylsulfamoyl group, an N-decylsulfamoyl group, an N-undecylsulfamoyl group, an N-dodecylsulfamoyl group, an N-eicosylsulfamoyl group, an N-phenylsulfamoyl group and the like, and a group represented by the above formula, A derivative of nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group), or the like), and compounds represented by tables 1Z4 to 8Z4 and tables 11Z4 to 16Z4, which correspond to-SO ₂NH(R^102Z4X) (wherein, R^102Z4XIs not a hydrogen atom, other than, and R^102Z4The same as defined above), etc.;

n, N-dimethylsulfamoyl, N-ethylmethylsulfamoyl, N-diethylsulfamoyl, N-propylmethylsulfamoyl, N-dipropylsulfamoyl, N-isopropylmethylsulfamoyl, N-diisopropylsulfamoyl, N-tert-butylmethylsulfamoyl, N-diisobutylsulfamoyl, N-di-sec-butylsulfamoyl, N-di-tert-butylsulfamoyl, N-butylmethylsulfamoyl, N-dibutylsulfamoyl, N-dipentylsulfamoyl, N-bis (1-ethylpropyl) sulfamoyl, N-dihexylsulfamoyl, N-bis (2-ethyl) hexylsulfamoyl, N-diethylsulfamoyl, A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), a carbon atom, or a derivative thereof (for example, a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), a carbon atom), and the like, such as an N, N-diheptylsulfamoyl group, an N, N-dioctylsulfamoyl group, an N, N-dinonylsulfamoyl group, an N, N-decylmethylsulfamoyl group, an N, N-undecylmethylsulfamoyl group, an N, N-dodecylmethylsulfamoyl group, an N, N-eicosylmethylsulfamoyl group, an N, N-phenylmethanesulfonyl group, an N, and an N, N-diphenylsulfamoyl group, and the like, and a group represented by the above chemical formula Groups derived from 1 to 10 alkylsulfamoyl groups (preferably octylsulfamoyl groups) and compounds shown in tables 1Z4 to 8Z4 and tables 11Z4 to 16Z4 correspond to-SO₂N(R^102Z4X)₂(wherein, R^102Z4XIs not a hydrogen atom, other than, and R^102Z4The same as defined above) and the like,

preferred examples thereof include sulfamoyl groups substituted with 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms or derivatives thereof and compounds represented by tables 1Z4 to 8Z4 and tables 11Z4 to 16Z4, which correspond to-SO₂N(R^102Z4)₂And the like.

as-CON (R)^102Z4)₂Examples thereof include:

a carbamoyl group; n-methylcarbamoyl, N-ethylcarbamoyl, N-propylcarbamoyl, N-isopropylcarbamoyl, N-butylcarbamoyl, N-isobutylcarbamoyl, N-sec-butylcarbamoyl, N-tert-butylcarbamoyl, N-pentylcarbamoyl, N- (1-ethylpropyl) carbamoyl, N-hexylcarbamoyl, N- (2-ethyl) hexylcarbamoyl, N-heptylcarbamoyl, N-octylcarbamoyl and N-nonylcarbamoyl, N-decylcarbamoyl, N-undecylcarbamoyl, N-dodecylcarbamoyl, N-eicosylcarbamoyl, N-phenylcarbamoyl and the like, Carbamoyl groups substituted with a 1-40 (preferably 1-20) carbon hydrocarbon group or derivative thereof (e.g., a derivative derived from carboxyl group, sulfo group, nitro group, hydroxyl group, halogen (preferably chlorine atom), 1-10 carbon alkylsulfamoyl group (preferably octylsulfamoyl group)) such as the group represented by the above formula, and compounds shown in tables 1Z 4-8Z 4 and tables 11Z 4-16Z 4 corresponding to-CONH (R) ^102Z4X) (wherein, R^102Z4XIs not a hydrogen atom, other than, and R^102Z4The same as defined above), etc.;

n, N-dimethylcarbamoyl, N-ethylmethylcarbamoyl, N-diethylcarbamoyl, N-propylmethylcarbamoyl, N-dipropylcarbamoylN, N-isopropylmethylcarbamoyl, N-diisopropylcarbamoyl, N-tert-butylmethylcarbamoyl, N-diisobutylcarbamoyl, N-di-sec-butylcarbamoyl, N-di-tert-butylcarbamoyl, N-butylmethylcarbamoyl, N-dibutylcarbamoyl, N-butyloctylcarbamoyl, N-dipentylcarbamoyl, N-bis (1-ethylpropyl) carbamoyl, N-dihexylcarbamoyl, N-bis (2-ethyl) hexylcarbamoyl, N-diheptylcarbamoyl, N-octylmethylcarbamoyl, N-dioctylcarbamoyl, N-butylmethylcarbamoyl, N-dibutylcarbamoyl, N-butylmethylcarbamoyl, N-dibutylcarbamoyl, N-butylmethylcarbamoyl, N-dibutylcarbamoyl, N-butylmethylcarbamoyl, N-dibutylcarbamoyl, N-butylmethylcarbamoyl, N-butylt-butylmethylcarbamoyl, N-butylt-butylmethylcarbamoyl, N-butylt-butylmethylcarbamoyl, N-butylt-butylmethylcarbamoyl, N-butylt-butylmethylcarbamoyl, N-butylt-butyl, N, N-dinonylcarbamoyl, N-decylmethylcarbamoyl, N-undecylmethylcarbamoyl, N-dodecylmethylcarbamoyl, N-eicosylmethyl-carbamoyl, N-phenylmethylcarbamoyl, N, n-diphenylcarbamoyl and carbamoyl groups such as those represented by the above chemical formula which are substituted with 2 hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or derivative groups thereof (for example, groups derived from carboxyl group, sulfo group, nitro group, hydroxyl group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group), and the like), and the compounds shown in tables 1Z4 to 8Z4 and tables 11Z4 to 16Z4 correspond to-CON (R). ^102Z4X)₂(wherein, R^102Z4XIs not a hydrogen atom, other than, and R^102Z4The same as defined above) and the like,

preferred examples thereof include a carbamoyl group substituted with 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms or a derivative thereof and a compound represented by any one of tables 1Z4 to 8Z4 and 11Z4 to 16Z4 which corresponds to-CON (R)^102Z4)₂And the like.

as-N (R)^102Z4)₂There may be mentioned amino groups; n-methylamino, N-ethylamino, N-propylamino, N-isopropylamino, N-butylamino, N-isobutylamino, N-sec-butylamino, N-tert-butylamino, N-pentylamino, N-hexylamino, N- (2-ethyl) hexylamino, N-heptylamino, N-octylamino, N-nonylamino, N-decylamino, N-undecylamino, N-dodecylamino, N-eicosylamino, N-isobutylamino, N-sec-butylamino, N-pentylamino, N-hexylamino, N- (2-ethyl) hexylamino, N-heptylamino, N-octylamino, N-nonylamino, N-decylamino, N-undecylamino, N-dodecylamino, N-eicosylamino, N-dodecylamino, N-2-d-y-d-y-d-y-d,An amino group such as an N-phenylamino group, which is substituted with a 1-C1-40 (preferably C1-20) hydrocarbon group or a derivative thereof (e.g., a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), a C1-10 alkylsulfamoyl group (preferably octylsulfamoyl group), etc.), or a group represented by the above formula, or an equivalent of-NH (R) in the compounds shown in tables 1Z4 to 8Z4 and tables 11Z4 to 16Z4 ^102Z4X) (wherein, R^102Z4XIs not a hydrogen atom, other than, and R^102Z4The same as defined above), etc.; n, N-dimethylamino group, N-ethylmethylamino group, N-diethylamino group, N-propylmethylamino group, N-dipropylamino group, N-isopropylmethylamino group, N-diisopropylamino group, N-tert-butylmethylamino group, N-diisobutylamino group, N-di-sec-butylamino group, N-di-tert-butylamino group, N-butylmethylamino group, N-dibutylamino group, N-dipentylamino group, N-bis (1-ethylpropyl) amino group, N-dihexylamino group, N-bis (2-ethyl) hexylamino group, N-diheptylamino group, N-dioctylamino group, N, an amino group substituted with a hydrocarbon group having 1 to 40 (preferably 1 to 20) carbon atoms or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc., such as an N-dinonylamino group, an N, N-decylmethylamino group, an N, N-undecylmethylamino group, an N, N-dodecylmethylamino group, an N, N-eicosylmethylamino group, an N, N-phenylmethylamino group, an N, N-diphenylamino group, etc., and a group represented by the above chemical formula, and an amino group corresponding to-N (R) in the compounds shown in tables 1Z4 to 8Z4 and tables 11Z4 to 16Z4, respectively ^102Z4X)₂(wherein, R^102Z4XIs not a hydrogen atom, other than, and R^102Z4The same as defined above) and the like,

preferred examples thereof include amino groups substituted with 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms or derivatives thereof and compounds shown in tables 1Z4 to 8Z4 and 11Z4 to 16Z4 which correspond to-N (R)^102Z4)₂And the like.

as-NHCO-R^102Z4Can do toTo produce formylamino; acetylamino, propionylamino, butyrylamino, 2-dimethylpropionylamino, valerylamino, hexanoylamino, (2-ethyl) hexanoylamino, heptanoylamino, octanoylamino, nonanoylamino, decanoylamino, undecanoylamino, dodecanoylamino, heneicosanoylamino, benzoylamino and the like, carbonylamino (for example, in the case where the carbonylamino is an acylamino group, the carbon number is 1 to 40), carbonylamino to which a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20) or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) is bonded such as a group represented by the above-mentioned chemical formula) and carbonylamino (in the case where the carbonylamino group is an acylamino group, the carbon number is 1 to 40) corresponding to-NHCO- R ^102Z4And the like,

preferred examples thereof include carbonylamino groups to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded (in the case where the carbonylamino group is an alkanoylamino group, the carbon number is more preferably 1 to 10), and compounds represented by tables 1Z4 to 8Z4 and tables 11Z4 to 16Z4, which correspond to-NHCO-R^102Z4And the like.

as-NHCON (R)^102Z4)₂Examples thereof include the groups listed above and the compounds shown in tables 1Z4 to 8Z4 and 11Z4 to 16Z4 which correspond to-NHCON (R)^102Z4)₂A group of (a); and so on.

as-NHCOOR^102Z4Examples thereof include those corresponding to-NHCOOR among the above-mentioned groups and the compounds shown in tables 1Z4 to 8Z4 and tables 11Z4 to 16Z4^102Z4And the like.

as-OCON (R)^102Z4)₂Examples thereof include those corresponding to-OCON (R) among the above-mentioned groups and the compounds shown in tables 1Z4 to 8Z4 and 11Z4 to 16Z4^102Z4)₂And the like.

The halogen atom is preferably a fluorine atom, a chlorine atom, a bromine atom, an iodine atom or the like.

as-SO₃M and-CO₂M of M is hydrogen atomA seed; the alkali metal atom such as lithium atom, sodium atom and potassium atom, preferably hydrogen atom, sodium atom and potassium atom.

The above-mentioned-CO-R^102Z4、-COO-R^102Z4、-OCO-R^102Z4、-COCO-R^102Z4、-O-R^102Z4、-SO₂-R^102Z4、-SO₂N(R^102Z4)₂、-CON(R^102Z4)₂、-N(R^102Z4)₂、-NHCO-R^102Z4、-NHCON(R^102Z4)₂、-NHCOOR^102Z4、-OCON(R^102Z4)₂The number of the substituents (first substituents) contained in (2) may be 1 or 2 or more, and 2 or more substituents may be the same or different and independent of each other.

Further, the first substituent may have another substituent (second substituent) bonded to the hydrocarbon group included in a part thereof. The second substituent may be selected from the same groups as the first substituent.

R^2Z4And R^3Z4、R^3Z4And R^4Z4And R^4Z4And R^5Z4The ring formed is fused with the benzene ring of the isoindoline skeleton of the compound represented by the formula (IZ 4). As R^2Z4And R^3Z4、R^3Z4And R^4Z4And R^4Z4And R^5Z4Examples of the condensed ring structure of the ring formed and the benzene ring include indene, naphthalene, biphenylene, indacene, acenaphthylene, fluorene, phenalene, phenanthrene, anthracene, fluoranthene, acephenanthrene, aceanthrylene, and benzo [9,10 ] ene]Phenanthrene, pyrene,

Hydrocarbon-based condensed ring structures such as N-methylphthalimide, N- (1-phenylethyl) phthalimide and butachlor, and partially reduced products thereof (for example, 9, 10-dihydroanthracene, 1,2,3, 4-tetrahydronaphthalene, etc.); indole, isoindole, indazole, quinoline, isoquinoline, phthalazine, quinoxaline, quinazoline, cinnoline, carbazole, carboline, phenanthridine, acridine, quinoline, quinoxaline, quinoline, and/or quinoline derivative,

Pyridine, phenanthroline and thiopheneNitrogen-containing fused heterocycles such as oxazines and partial reductants thereof; oxygen-containing fused heterocycles such as 3-hydrobenzofuran-2-one and partial reductants thereof.

R^2Z4And R^3Z4、R^3Z4And R^4Z4And R^4Z4And R^5Z4In the case of forming a ring, the ring may have a substituent. Examples of the substituent include ^N1Z4、R^N2Z4、R^1Z4、R^2Z4、R^3Z4、R^4Z4、R^5Z4、R^6Z4、R^7Z4、R^101Z4And R^102Z4The hydrocarbon group may have the same substituent as the substituent. Preferred examples of the substituent include^N1Z4、R^N2Z4、R^1Z4、R^2Z4、R^3Z4、R^4Z4、R^5Z4、R^6Z4、R^7Z4、R^101Z4And R^102Z4The preferable examples of the substituents which the hydrocarbon group may have are the same.

R^3Z4And R^4Z4When forming a ring, as R^2Z4And R^5Z4Independently of one another, hydrogen atoms, amino groups and hydroxyl groups are preferred.

R^2Z4And R^3Z4When a ring is formed, R is preferably^4Z4And R^5Z4Does not form a ring, more preferably R^4Z4And R^5Z4Is a hydrogen atom.

In addition, R^4Z4And R^5Z4When a ring is formed, R is preferably^2Z4And R^3Z4Does not form a ring, more preferably R^2Z4And R^3Z4Is a hydrogen atom.

In the present invention, R^1Z4、R^6Z4And R^7Z4Preferably a hydrogen atom.

In the present invention, R^N1Z4And R^N2Z4Independently of one another, are preferably-CO-R^102Z4、-COO-R^101Z4、-CON(R^102Z4)₂、-N(R^102Z4)₂、-CO₂M or a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, more preferably a hydrocarbon group having 1 to 30 carbon atoms which may have a substituent, still more preferablyThe hydrocarbon group having 1 to 20 carbon atoms which may have a substituent is selected, the hydrocarbon group having 1 to 15 carbon atoms which may have a substituent is particularly preferable, the hydrocarbon group having 1 to 10 carbon atoms which may have a substituent is particularly preferable, the hydrocarbon group having 1 to 6 carbon atoms which may have a substituent or the hydrocarbon group having 1 to 5 carbon atoms which may have a substituent is particularly preferable, the methyl group, the ethyl group or the phenyl group is further particularly preferable, and the methyl group or the ethyl group is most preferable. In addition, R ^N1Z4And R^N2Z4The groups may be the same or different, but preferably the same.

From the viewpoint of reducing the retardation value of a color filter made of the colored composition, R is preferably^2Z4、R^3Z4、R^4Z4And R^5Z4At least one of which is-CO-R^102Z4、-COO-R^101Z4、-OCO-R^102Z4、-COCO-R^102Z4、-O-R^102Z4、-SO₂-R^101Z4、-SO₂N(R^102Z4)₂、-CON(R^102Z4)₂、-N(R^102Z4)₂、-NHCO-R^102Z4、-NHCO-N(R^102Z4)₂、-NHCOOR^102Z4、-OCON(R^102Z4)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent,

more preferably a C1-40 hydrocarbon group which may have a substituent, a halogen atom, or-N (R)^102Z4)₂A C1-20 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R^102Z4、-O-R^102Z4、-SO₃M or-CO₂M，

More preferably a nitro group or a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, and still more preferably a nitro group or a tert-butyl group. Alternatively, R is preferred^2Z4And R^3Z4、R^3Z4And R^4Z4Or R^4Z4And R^5Z4Form a ring.

From coloringFrom the viewpoint of reducing the retardation value of the color filter produced from the composition, R is preferably^2Z4、R^3Z4、R^4Z4And R^5Z4At least one of which is an optionally substituted hydrocarbon group having 1 to 40 carbon atoms, a halogen atom, or-N (R)^102Z4)₂A C1-20 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R ^102Z4、-O-R^102Z4、-SO₃M or-CO₂M is more preferably a nitro group or a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, and still more preferably a nitro group or a tert-butyl group. It is especially preferred that R^3Z4Is nitro or tert-butyl, R^2Z4、R^4Z4And R^5Z4Is a hydrogen atom; or, R^2Z4、R^3Z4And R^5Z4Is a hydrogen atom, R^4Z4Is nitro or tert-butyl.

Specific examples of the compound IZ4 include compounds IZ4-1 to IZ4-769 having a substituent shown in table 1Z4, table 2Z4, table 3Z4, table 4Z4, table 5Z4, table 6Z4, table 7Z4, table 8Z4, and table 11Z4 to table 16Z4 in formula (IZ4-aa), and alkali metal salts thereof.

B^a1Z4B^a2Z4The partial structure represented by any one of formulae (BB1) to (BB60), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1), formula (BBO8), formula (BBO10), formula (BBD1) and formula (BBJ2) is shown. The formulae (BB1) to (BB60), (BBK2), (BBK3), (BBK4), (BBK14), (BBI1), (BBO8), (BBO10), (BBD1) and (BBJ2) are the same as B representing formula (IZ1-aa)^a1Z1B^a2Z1The same structures as (BB1) to (BB60), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1), formula (BBO8), formula (BBO10), formula (BBD1) and formula (BBJ2) described above. B is^a1Z4And B^a2Z4Each represents a chemical bond, B^a1Z4B of formulae (BB1) to (BB60), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1), formula (BBO8), formula (BBO10), formula (BBD1) and formula (BBJ2) ¹When a chemical bond of (A) is present, B^a2Z4To be B²The chemical bond of (a); b is^a1Z4Are represented by the formulae (BB1) to (BB60), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK 14)) B of the formulae (BBI1), (BBO8), (BBO10), (BBD1) and (BBJ2)²When a chemical bond of (A) is present, B^a2Z4To be B¹The chemical bond of (1).

As B^a1Z4B^a2Z4Formula (BB1), formula (BB6), formula (BB8), formula (BB11), formula (BB14), formula (BB19), formula (BB37), formula (BB58), formula (BBJ2), formula (BBO8), and formula (BBO10) are preferable, and formula (BB1), formula (BB6), and formula (BB19) are more preferable.

Each symbol in table 1Z4, table 2Z4, table 3Z4, table 4Z4, table 5Z4, table 6Z4, table 7Z4, table 8Z4, and tables 11Z4 to 16Z4 represents the following partial structure. In the partial structure, "Me" represents a methyl group, "Et" represents an ethyl group, "Bu" represents a butyl group, "TBu" represents a tert-butyl group,

"Hex" represents a hexyl group, "Oct" represents an octyl group, "2 EH" represents a 2-ethylhexyl group, "CHM" represents a cyclohexylmethyl group,

"CH" represents cyclohexyl, "PH" represents phenyl, "BZ" represents benzyl, "NPR" represents propyl,

"IPR" represents isopropyl, "IBu" represents isobutyl, and "EOE" represents-CH₂CH₂OCH₂CH₃"ALL" represents allyl, "HYE" represents 2-hydroxyethyl, and "COM" represents-CO-CH ₃And "COE" represents-COO-CH₂CH₃And "OCM" represents-OCO-CH₃And "OME" represents-O-CH₃"SOT" represents a tosyl group, and "SNH" represents-SO₂NH-CH₂CH(CH₂CH₃)((CH₂)₃CH₃) "SN 2" represents-SO₂N(CH₃)((CH₂)₇CH₃) "CNM" represents-CONHCH₃And "CN 2" represents-CON (CH)₃)C₆H₅And "NPH" represents-NHC₆H₅And "NOT" represents-N ((CH)₂)₇CH₃)₂，“NCO "represents-NHCO ((CH)₂)₄CH₃) "F" represents a fluorine atom, "Cl" represents a chlorine atom, "Br" represents a bromine atom, "CN" represents a cyano group, "NO 2" represents a nitro group, and "SUA" represents-SO₃H, "CBA" means-CO₂H, "CHO" means-CHO, "OCH" means-OCOH, "OH" means-OH, "SFM" means-SO₂NH₂"CBM" represents-CONH₂"NH 2" means-NH₂"NCH" represents-nhcooh, and represents a chemical bond.

In the table, a part of the structure shown in the following formula is represented by a symbol denoted by the structure.

[ Table 1Z4]

TABLE 1Z4

RN1Z4

RN2Z4

Ba1Z4Ba2Z4

R1Z4

R6Z4

R7Z4

IZ4-1

Me

Me

BB1

H

H

H

IZ4-2

Et

Et

BB1

H

H

H

IZ4-3

PH

PH

BB1

H

H

H

IZ4-4

Bu

Me

BB1

H

H

H

IZ4-5

TBu

Et

BB1

H

H

H

IZ4-6

Hex

NPR

BB1

H

H

H

IZ4-7

Oct

IPR

BB1

H

H

H

IZ4-8

2EH

HYE

BB1

H

H

H

IZ4-9

CHM

ALL

BB1

H

H

H

IZ4-10

CH

COM

BB1

H

H

H

IZ4-11

BZ

Me

BB1

H

H

H

IZ4-12

NPR

Et

BB1

H

H

H

IZ4-13

IPR

NPR

BB1

H

H

H

IZ4-14

IBu

IPR

BB1

H

H

H

IZ4-15

EOE

HYE

BB1

H

H

H

IZ4-16

ALL

ALL

BB1

H

H

H

IZ4-17

NH2

COM

BB1

H

H

H

IZ4-18

CBM

Me

BB1

H

H

H

IZ4-19

COM

Et

BB1

H

H

H

IZ4-20

COE

NPR

BB1

H

H

H

IZ4-21

CBA

IPR

BB1

H

H

H

IZ4-22

HYE

HYE

BB1

H

H

H

IZ4-23

Bu

Bu

BB1

H

H

H

IZ4-24

TBu

TBu

BB1

H

H

H

IZ4-25

Hex

Hex

BB1

H

H

H

IZ4-26

Oct

Oct

BB1

H

H

H

IZ4-27

2EH

2EH

BB1

H

H

H

IZ4-28

CHM

CHM

BB1

H

H

H

IZ4-29

CH

CH

BB1

H

H

H

IZ4-30

BZ

BZ

BB1

H

H

H

IZ4-31

NPR

NPR

BB1

H

H

H

IZ4-32

IPR

IPR

BB1

H

H

H

IZ4-33

IBu

IBu

BB1

H

H

H

IZ4-34

EOE

EOE

BB1

H

H

H

IZ4-35

NH2

NH2

BB1

H

H

H

IZ4-36

CBM

CBM

BB1

H

H

H

IZ4-37

COM

COM

BB1

H

H

H

IZ4-38

COE

COE

BB1

H

H

H

IZ4-39

CBA

CBA

BB1

H

H

H

IZ4-40

Me

Me

BB6

H

H

H

[ Table 2Z4]

TABLE 2Z4

RN1Z4

RN2Z4

Ba1Z4Ba2Z4

R1Z4

R6Z4

R7Z4

IZ4-41

Et

Et

BB6

H

H

H

IZ4-42

PH

PH

BB6

H

H

H

IZ4-43

Bu

Me

BB6

H

H

H

IZ4-44

TBu

Et

BB6

H

H

H

IZ4-45

Hex

NPR

BB6

H

H

H

IZ4-46

Oct

IPR

BB6

H

H

H

IZ4-47

2EH

HYE

BB6

H

H

H

IZ4-48

CHM

ALL

BB6

H

H

H

IZ4-49

CH

COM

BB6

H

H

H

IZ4-50

BZ

Me

BB6

H

H

H

IZ4-51

NPR

Et

BB6

H

H

H

IZ4-52

IPR

NPR

BB6

H

H

H

IZ4-53

IBu

IPR

BB6

H

H

H

IZ4-54

EOE

HYE

BB6

H

H

H

IZ4-55

ALL

ALL

BB6

H

H

H

IZ4-56

NH2

COM

BB6

H

H

H

IZ4-57

CBM

Me

BB6

H

H

H

IZ4-58

COM

Et

BB6

H

H

H

IZ4-59

COE

NPR

BB6

H

H

H

IZ4-60

CBA

IPR

BB6

H

H

H

IZ4-61

HYE

HYE

BB6

H

H

H

IZ4-62

Bu

Bu

BB6

H

H

H

IZ4-63

TBu

TBu

BB6

H

H

H

IZ4-64

Hex

Hex

BB6

H

H

H

IZ4-65

Oct

Oct

BB6

H

H

H

IZ4-66

2EH

2EH

BB6

H

H

H

IZ4-67

CHM

CHM

BB6

H

H

H

IZ4-68

CH

CH

BB6

H

H

H

IZ4-69

BZ

BZ

BB6

H

H

H

IZ4-70

NPR

NPR

BB6

H

H

H

IZ4-71

IPR

IPR

BB6

H

H

H

IZ4-72

IBu

IBu

BB6

H

H

H

IZ4-73

EOE

EOE

BB6

H

H

H

IZ4-74

NH2

NH2

BB6

H

H

H

IZ4-75

CBM

CBM

BB6

H

H

H

IZ4-76

COM

COM

BB6

H

H

H

IZ4-77

COE

COE

BB6

H

H

H

IZ4-78

CBA

CBA

BB6

H

H

H

IZ4-79

Me

Me

BB19

H

H

H

IZ4-80

Et

Et

BB19

H

H

H

[ Table 3Z4]

TABLE 3Z4

RN1Z4

RN2Z4

Ba1Z4Ba2Z4

R1Z4

R6Z4

R7Z4

IZ4-81

PH

PH

BB19

H

H

H

IZ4-82

Bu

Me

BB19

H

H

H

IZ4-83

TBu

Et

BB19

H

H

H

IZ4-84

Hex

NPR

BB19

H

H

H

IZ4-85

Oct

IPR

BB19

H

H

H

IZ4-86

2EH

HYE

BB19

H

H

H

IZ4-87

CHM

ALL

BB19

H

H

H

IZ4-88

CH

COM

BB19

H

H

H

IZ4-89

BZ

Me

BB19

H

H

H

IZ4-90

NPR

Et

BB19

H

H

H

IZ4-91

IPR

NPR

BB19

H

H

H

IZ4-92

IBu

IPR

BB19

H

H

H

IZ4-93

EOE

HYE

BB19

H

H

H

IZ4-94

ALL

ALL

BB19

H

H

H

IZ4-95

NH2

COM

BB19

H

H

H

IZ4-96

CBM

Me

BB19

H

H

H

IZ4-97

COM

Et

BB19

H

H

H

IZ4-98

COE

NPR

BB19

H

H

H

IZ4-99

CBA

IPR

BB19

H

H

H

IZ4-100

HYE

HYE

BB19

H

H

H

IZ4-101

Bu

Bu

BB19

H

H

H

IZ4-102

TBu

TBu

BB19

H

H

H

IZ4-103

Hex

Hex

BB19

H

H

H

IZ4-104

Oct

Oct

BB19

H

H

H

IZ4-105

2EH

2EH

BB19

H

H

H

IZ4-106

CHM

CHM

BB19

H

H

H

IZ4-107

CH

CH

BB19

H

H

H

IZ4-108

BZ

BZ

BB19

H

H

H

IZ4-109

NPR

NPR

BB19

H

H

H

IZ4-110

IPR

IPR

BB19

H

H

H

IZ4-111

IBu

IBu

BB19

H

H

H

IZ4-112

EOE

EOE

BB19

H

H

H

IZ4-113

NH2

NH2

BB19

H

H

H

IZ4-114

CBM

CBM

BB19

H

H

H

IZ4-115

COM

COM

BB19

H

H

H

IZ4-116

COE

COE

BB19

H

H

H

IZ4-117

CBA

CBA

BB19

H

H

H

IZ4-118

Me

Me

BB2

H

H

H

IZ4-119

Et

Et

BB3

H

H

H

IZ4-120

PH

PH

BB4

H

H

H

[ Table 4Z4]

TABLE 4Z4

RN1Z4

RN2Z4

Ba1Z4Ba2Z4

R1Z4

R6Z4

R7Z4

IZ4-121

Bu

Me

BB5

H

H

H

IZ4-122

TBu

Et

BB7

H

H

H

IZ4-123

Hex

NPR

BB8

H

H

H

IZ4-124

Oct

IPR

BB9

H

H

H

IZ4-125

2EH

HYE

BB10

H

H

H

IZ4-126

CHM

ALL

BB11

H

H

H

IZ4-127

CH

COM

BB12

H

H

H

IZ4-128

BZ

Me

BB13

H

H

H

IZ4-129

NPR

Et

BB14

H

H

H

IZ4-130

IPR

NPR

BB15

H

H

H

IZ4-131

IBu

IPR

BB16

H

H

H

IZ4-132

EOE

HYE

BB17

H

H

H

IZ4-133

ALL

ALL

BB18

H

H

H

IZ4-134

NH2

COM

BB20

H

H

H

IZ4-135

CBM

Me

BB21

H

H

H

IZ4-136

COM

Et

BB22

H

H

H

IZ4-137

COE

NPR

BB23

H

H

H

IZ4-138

CBA

IPR

BB24

H

H

H

IZ4-139

HYE

HYE

BB25

H

H

H

IZ4-140

Bu

Bu

BB26

H

H

H

IZ4-141

TBu

TBu

BB27

H

H

H

IZ4-142

Hex

Hex

BB28

H

H

H

IZ4-143

Oct

Oct

BB29

H

H

H

IZ4-144

2EH

2EH

BB30

H

H

H

IZ4-145

CHM

CHM

BB31

H

H

H

IZ4-146

CH

CH

BB32

H

H

H

IZ4-147

BZ

BZ

BB33

H

H

H

IZ4-148

NPR

NPR

BB34

H

H

H

IZ4-149

IPR

IPR

BB35

H

H

H

IZ4-150

IBu

IBu

BB36

H

H

H

IZ4-151

EOE

EOE

BB37

H

H

H

IZ4-152

NH2

NH2

BB38

H

H

H

IZ4-153

CBM

CBM

BB39

H

H

H

IZ4-154

COM

COM

BB40

H

H

H

IZ4-155

COE

COE

BB41

H

H

H

IZ4-156

CBA

CBA

BB42

H

H

H

IZ4-157

Me

Me

BB43

H

H

H

IZ4-158

Et

Et

BB44

H

H

H

IZ4-159

PH

PH

BB45

H

H

H

IZ4-160

Bu

Me

BB46

H

H

H

[ Table 5Z4]

TABLE 5Z4

RN1Z4

RN2Z4

Ba1Z4Ba2Z4

R1Z4

R6Z4

R7Z4

IZ4-161

TBu

Et

BB47

H

H

H

IZ4-162

Hex

NPR

BB48

H

H

H

IZ4-163

Oct

IPR

BB49

H

H

H

IZ4-164

2EH

HYE

BB50

H

H

H

IZ4-165

CHM

ALL

BB51

H

H

H

IZ4-166

CH

COM

BB52

H

H

H

IZ4-167

BZ

Me

BB53

H

H

H

IZ4-168

NPR

Et

BB54

H

H

H

IZ4-169

IPR

NPR

BB55

H

H

H

IZ4-170

IBu

IPR

BB56

H

H

H

IZ4-171

EOE

HYE

BB57

H

H

H

IZ4-172

ALL

ALL

BB58

H

H

H

IZ4-173

NH2

COM

BB59

H

H

H

IZ4-174

CBM

Me

BB60

H

H

H

IZ4-175

Bu

Me

BB1

H

Et

Et

IZ4-176

TBu

Et

BB2

H

PH

PH

IZ4-177

Hex

NPR

BB3

H

NPR

NPR

IZ4-178

Oct

IPR

BB4

H

IPR

IPR

IZ4-179

2EH

HYE

BB5

H

ALL

ALL

IZ4-180

CHM

ALL

BB6

H

Me

Me

IZ4-181

CH

COM

BB7

H

CH

CH

IZ4-182

BZ

Me

BB8

H

BZ

H

IZ4-183

NPR

Et

BB9

Me

Me

Me

IZ4-184

IPR

NPR

BB10

Et

CH

CH

IZ4-185

IBu

IPR

BB11

H

Et

Et

IZ4-186

EOE

HYE

BB12

H

Bu

Bu

IZ4-187

ALL

ALL

BB13

H

TBu

TBu

IZ4-188

NH2

COM

BB14

H

Hex

Hex

IZ4-189

CBM

Me

BB15

H

Oct

Oct

IZ4-190

COM

Et

BB16

H

2EH

2EH

IZ4-191

COE

NPR

BB17

H

CHM

CHM

IZ4-192

CBA

IPR

BB18

H

PH

PH

IZ4-193

Me

Me

BB19

H

BZ

BZ

IZ4-194

Et

Et

BB20

H

NPR

NPR

IZ4-195

PH

PH

BB21

H

IPR

IPR

IZ4-196

Bu

Me

BB22

H

IBu

IBu

IZ4-197

TBu

Et

BB23

H

EOE

EOE

IZ4-198

Hex

NPR

BB24

H

ALL

ALL

IZ4-199

Oct

IPR

BB25

H

NH2

NH2

IZ4-200

2EH

HYE

BB26

H

CBM

CBM

[ Table 6Z4]

TABLE 6Z4

RN1Z4

RN2Z4

Ba1Z4Ba2Z4

R1Z4

R6Z4

R7Z4

IZ4-201

CHM

ALL

BB27

H

COM

COM

IZ4-202

CH

COM

BB28

H

COE

COE

IZ4-203

BZ

Me

BB29

H

CBA

CBA

IZ4-204

NPR

Et

BB30

H

HYE

HYE

IZ4-205

IPR

NPR

BB31

H

Me

Me

IZ4-206

IBu

IPR

BB32

H

CH

CH

IZ4-207

EOE

HYE

BB33

H

BZ

H

IZ4-208

ALL

ALL

BB34

Me

Me

Me

IZ4-209

NH2

COM

BB35

Et

CH

CH

IZ4-210

CBM

Me

BB36

H

Et

Et

IZ4-211

COM

Et

BB37

H

Bu

Bu

IZ4-212

COE

NPR

BB38

H

TBu

TBu

IZ4-213

CBA

IPR

BB39

H

Hex

Hex

IZ4-214

HYE

HYE

BB40

H

Oct

Oct

IZ4-215

Bu

Bu

BB41

H

2EH

2EH

IZ4-216

TBu

TBu

BB42

H

CHM

CHM

IZ4-217

Hex

Hex

BB43

H

PH

PH

IZ4-218

Oct

Oct

BB44

H

BZ

BZ

IZ4-219

2EH

2EH

BB45

H

NPR

NPR

IZ4-220

CHM

CHM

BB46

H

IPR

IPR

IZ4-221

CH

CH

BB47

H

IBu

IBu

IZ4-222

BZ

BZ

BB48

H

EOE

EOE

IZ4-223

NPR

NPR

BB49

H

ALL

ALL

IZ4-224

IPR

IPR

BB50

H

NH2

NH2

IZ4-225

IBu

IBu

BB51

H

CBM

CBM

IZ4-226

EOE

EOE

BB52

H

COM

COM

IZ4-227

NH2

NH2

BB53

H

COE

COE

IZ4-228

CBM

CBM

BB54

H

CBA

CBA

IZ4-229

COM

COM

BB55

H

HYE

HYE

IZ4-230

COE

COE

BB56

H

Me

Me

IZ4-231

CBA

CBA

BB57

H

CH

CH

IZ4-232

Me

Me

BB58

H

BZ

H

IZ4-233

Et

Et

BB59

Me

Me

Me

IZ4-234

PH

PH

BB60

Et

CH

CH

IZ4-235

Bu

Me

BB1

H

H

NO2

IZ4-236

TBu

Et

BB2

H

SUA

H

IZ4-237

Hex

NPR

BB3

H

H

PH

IZ4-238

Oct

IPR

BB4

H

CBA

H

IZ4-239

2EH

HYE

BB5

H

H

CHO

IZ4-240

Me

Me

BB6

H

BZ

BZ

[ Table 7Z4]

TABLE 7Z4

RN1Z4

RN2Z4

Ba1Z4Ba2Z4

R1Z4

R6Z4

R7Z4

IZ4-241

Et

Et

BB7

H

H

OCH

IZ4-242

PH

PH

BB8

H

NPR

H

IZ4-243

Bu

Me

BB9

H

H

OH

IZ4-244

TBu

Et

BB10

H

IPR

H

IZ4-245

Hex

NPR

BB11

H

H

SFM

IZ4-246

Oct

IPR

BB12

H

IBu

H

IZ4-247

2EH

HYE

BB13

H

H

CBM

IZ4-248

CHM

ALL

BB14

H

EOE

H

IZ4-249

CH

COM

BB15

H

H

NH2

IZ4-250

BZ

Me

BB16

H

ALL

H

IZ4-251

NPR

Et

BB17

H

H

NCH

IZ4-252

IPR

NPR

BB18

H

HYE

H

IZ4-253

IBu

IPR

BB19

Me

H

H

IZ4-254

EOE

HYE

BB20

COM

H

H

IZ4-255

ALL

ALL

BB21

COE

H

H

IZ4-256

NH2

COM

BB22

Et

H

H

IZ4-257

CBM

Me

BB23

OCM

H

H

IZ4-258

COM

Et

BB24

OME

H

H

IZ4-259

COE

NPR

BB25

Bu

H

H

IZ4-260

CBA

IPR

BB26

SOT

H

H

IZ4-261

HYE

HYE

BB27

SNH

H

H

IZ4-262

Bu

Bu

BB28

TBu

H

H

IZ4-263

TBu

TBu

BB29

SN2

H

H

IZ4-264

Hex

Hex

BB30

CNM

H

H

IZ4-265

Oct

Oct

BB31

Hex

H

H

IZ4-266

2EH

2EH

BB32

CN2

H

H

IZ4-267

CHM

CHM

BB33

NPH

H

H

IZ4-268

CH

CH

BB34

Oct

H

H

IZ4-269

BZ

BZ

BB35

NOT

H

H

IZ4-270

NPR

NPR

BB36

NCO

H

H

IZ4-271

IPR

IPR

BB37

H

Me

H

IZ4-272

IBu

IBu

BB38

H

H

COM

IZ4-273

EOE

EOE

BB39

H

COE

H

IZ4-274

NH2

NH2

BB40

H

H

Et

IZ4-275

CBM

CBM

BB41

H

OCM

H

IZ4-276

COM

COM

BB42

H

H

OME

IZ4-277

COE

COE

BB43

H

Bu

H

IZ4-278

CBA

CBA

BB44

H

H

SOT

IZ4-279

Me

Me

BB45

H

SNH

H

IZ4-280

Et

Et

BB46

H

H

TBu

[ Table 8Z4]

TABLE 8Z4

RN1Z4

RN2Z4

Ba1Z4Ba2Z4

R1Z4

R6Z4

R7Z4

IZ4-281

PH

PH

BB47

H

SN2

H

IZ4-282

Bu

Me

BB48

H

H

CNM

IZ4-283

TBu

Et

BB49

H

Hex

H

IZ4-284

Hex

NPR

BB50

H

H

CN2

IZ4-285

Oct

IPR

BB51

H

NPH

H

IZ4-286

2EH

HYE

BB52

H

H

Oct

IZ4-287

CHM

ALL

BB53

H

NOT

H

IZ4-288

CH

COM

BB54

H

H

NCO

IZ4-289

BZ

Me

BB55

H

2EH

H

IZ4-290

NPR

Et

BB56

H

H

F

IZ4-291

IPR

NPR

BB57

H

Cl

H

IZ4-292

IBu

IPR

BB58

H

H

CHM

IZ4-293

EOE

HYE

BB59

H

Br

H

IZ4-294

ALL

ALL

BB60

H

H

CN

IZ4-295

NH2

COM

BB1

H

CH

H

IZ4-296

CBM

Me

BB2

2EH

H

H

IZ4-297

COM

Et

BB3

F

H

H

IZ4-298

COE

NPR

BB4

Cl

H

H

IZ4-299

CBA

IPR

BB5

CHM

H

H

IZ4-300

HYE

HYE

BB6

Br

H

H

IZ4-301

Bu

Bu

BB7

CN

H

H

IZ4-302

TBu

TBu

BB8

CH

H

H

IZ4-303

Hex

Hex

BB9

NO2

H

H

IZ4-304

Oct

Oct

BB10

SUA

H

H

IZ4-305

2EH

2EH

BB11

PH

H

H

IZ4-306

CHM

CHM

BB12

CBA

H

H

IZ4-307

CH

CH

BB13

CHO

H

H

IZ4-308

BZ

BZ

BB14

BZ

H

H

IZ4-309

NPR

NPR

BB15

OCH

H

H

IZ4-310

IPR

IPR

BB16

NPR

H

H

IZ4-311

IBu

IBu

BB17

OH

H

H

IZ4-312

EOE

EOE

BB18

IPR

H

H

IZ4-313

NH2

NH2

BB19

SFM

H

H

IZ4-314

CBM

CBM

BB20

IBu

H

H

IZ4-315

COM

COM

BB21

CBM

H

H

IZ4-316

COE

COE

BB22

EOE

H

H

IZ4-317

CBA

CBA

BB23

NH2

H

H

IZ4-318

Me

Me

BB24

ALL

H

H

IZ4-319

Et

Et

BB25

NCH

H

H

IZ4-320

PH

PH

BB26

HYE

H

H

IZ4-321

Me

Me

BB8

H

H

H

[ Table 11Z4]

TABLE 11Z4

RN1Z4

RN2Z4

Ba1Z4Ba2Z4

R1Z4

R6Z4

R7Z4

RN1Z4

RN2Z4

Ba1Z4Ba2Z4

R1Z4

R6Z4

R7Z4

IZ4-322

NA1

NA1

BB1

H

H

H

IZ4-362

CH

Me

BB6

H

H

H

IZ4-323

HHk8

HHk8

BB1

H

H

H

IZ4-363

EOE

Me

BB6

H

H

H

IZ4-324

NA2

NA2

BB1

H

H

H

IZ4-364

ALL

Me

BB6

H

H

H

IZ4-325

HHk7

HHk7

BB1

H

H

H

IZ4-365

CBA

Me

BB6

H

H

H

IZ4-326

HH37

HH37

BB1

H

H

H

IZ4-366

HYE

Me

BB6

H

H

H

IZ4-327

HHk6

HHk6

BB1

H

H

H

IZ4-367

NA1

Me

BB6

H

H

H

IZ4-328

NA3

NA3

BB1

H

H

H

IZ4-368

HHk8

Me

BB6

H

H

H

IZ4-329

HHJ2

HHJ2

BB1

H

H

H

IZ4-369

NA2

Me

BB6

H

H

H

IZ4-330

HHk11

HHk11

BB1

H

H

H

IZ4-370

HHk7

Me

BB6

H

H

H

IZ4-331

Et

Me

BB1

H

H

H

IZ4-371

HH37

Me

BB6

H

H

H

IZ4-332

PH

Me

BB1

H

H

H

IZ4-372

HHk6

Me

BB6

H

H

H

IZ4-333

Oct

Me

BB1

H

H

H

IZ4-373

NA3

Me

BB6

H

H

H

IZ4-334

CHM

Me

BB1

H

H

H

IZ4-374

HHJ2

Me

BB6

H

H

H

IZ4-335

CH

Me

BB1

H

H

H

IZ4-375

HHk11

Me

BB6

H

H

H

IZ4-336

EOE

Me

BB1

H

H

H

IZ4-376

Et

Et

BB8

H

H

H

IZ4-337

ALL

Me

BB1

H

H

H

IZ4-377

PH

PH

BB8

H

H

H

IZ4-338

CBA

Me

BB1

H

H

H

IZ4-378

Oct

Oct

BB8

H

H

H

IZ4-339

HYE

Me

BB1

H

H

H

IZ4-379

CHM

CHM

BB8

H

H

H

IZ4-340

NA1

Me

BB1

H

H

H

IZ4-380

CH

CH

BB8

H

H

H

IZ4-341

HHk8

Me

BB1

H

H

H

IZ4-381

BZ

BZ

BB8

H

H

H

IZ4-342

NA2

Me

BB1

H

H

H

IZ4-382

EOE

EOE

BB8

H

H

H

IZ4-343

HHk7

Me

BB1

H

H

H

IZ4-383

ALL

ALL

BB8

H

H

H

IZ4-344

HH37

Me

BB1

H

H

H

IZ4-384

CBA

CBA

BB8

H

H

H

IZ4-345

HHk6

Me

BB1

H

H

H

IZ4-385

HYE

HYE

BB8

H

H

H

IZ4-346

NA3

Me

BB1

H

H

H

IZ4-386

NA1

NA1

BB8

H

H

H

IZ4-347

HHJ2

Me

BB1

H

H

H

IZ4-387

HHk8

HHk8

BB8

H

H

H

IZ4-348

HHk11

Me

BB1

H

H

H

IZ4-388

NA2

NA2

BB8

H

H

H

IZ4-349

NA1

NA1

BB6

H

H

H

IZ4-389

HHk7

HHk7

BB8

H

H

H

IZ4-350

HHk8

HHk8

BB6

H

H

H

IZ4-390

HH37

HH37

BB8

H

H

H

IZ4-351

NA2

NA2

BB6

H

H

H

IZ4-391

HHk6

HHk6

BB8

H

H

H

IZ4-352

HHk7

HHk7

BB6

H

H

H

IZ4-392

NA3

NA3

BB8

H

H

H

IZ4-353

HH37

HH37

BB6

H

H

H

IZ4-393

HHJ2

HHJ2

BB8

H

H

H

IZ4-354

HHk6

HHk6

BB6

H

H

H

IZ4-394

HHk11

HHk11

BB8

H

H

H

IZ4-355

NA3

NA3

BB6

H

H

H

IZ4-395

Et

Me

BB8

H

H

H

IZ4-356

HHJ2

HHJ2

BB6

H

H

H

IZ4-396

PH

Me

BB8

H

H

H

IZ4-357

HHk11

HHk11

BB6

H

H

H

IZ4-397

Oct

Me

BB8

H

H

H

IZ4-358

Et

Me

BB6

H

H

H

IZ4-398

CHM

Me

BB8

H

H

H

IZ4-359

PH

Me

BB6

H

H

H

IZ4-399

CH

Me

BB8

H

H

H

IZ4-360

Oct

Me

BB6

H

H

H

IZ4-400

BZ

Me

BB8

H

H

H

IZ4-361

CHM

Me

BB6

H

H

H

IZ4-401

EOE

Me

BB8

H

H

H

[ Table 12Z4]

TABLE 12Z4

RN1Z4

RN2Z4

Ba1Z4Ba2Z4

R1Z4

R6Z4

R7Z4

RN1Z4

RN2Z4

Ba1Z4Ba2Z4

R1Z4

R6Z4

R7Z4

IZ4-402

ALL

Me

BB8

H

H

H

IZ4-442

CBA

Me

BB11

H

H

H

IZ4-403

CBA

Me

BB8

H

H

H

IZ4-443

HYE

Me

BB11

H

H

H

IZ4-404

HYE

Me

BB8

H

H

H

IZ4-444

NA1

Me

BB11

H

H

H

IZ4-405

NA1

Me

BB8

H

H

H

IZ4-445

HHk8

Me

BB11

H

H

H

IZ4-406

HHk8

Me

BB8

H

H

H

IZ4-446

NA2

Me

BB11

H

H

H

IZ4-407

NA2

Me

BB8

H

H

H

IZ4-447

HHk7

Me

BB11

H

H

H

IZ4-408

HHk7

Me

BB8

H

H

H

IZ4-448

HH37

Me

BB11

H

H

H

IZ4-409

HH37

Me

BB8

H

H

H

IZ4-449

HHk6

Me

BB11

H

H

H

IZ4-410

HHk6

Me

BB8

H

H

H

IZ4-450

NA3

Me

BB11

H

H

H

IZ4-411

NA3

Me

BB8

H

H

H

IZ4-451

HHJ2

Me

BB11

H

H

H

IZ4-412

HHJ2

Me

BB8

H

H

H

IZ4-452

HHk11

Me

BB11

H

H

H

IZ4-413

HHk11

Me

BB8

H

H

H

IZ4-453

Me

Me

BB14

H

H

H

IZ4-414

Me

Me

BB11

H

H

H

IZ4-454

Et

Et

BB14

H

H

H

IZ4-415

Et

Et

BB11

H

H

H

IZ4-455

PH

PH

BB14

H

H

H

IZ4-416

PH

PH

BB11

H

H

H

IZ4-456

Oct

Oct

BB14

H

H

H

IZ4-417

Oct

Oct

BB11

H

H

H

IZ4-457

CHM

CHM

BB14

H

H

H

IZ4-418

CHM

CHM

BB11

H

H

H

IZ4-458

CH

CH

BB14

H

H

H

IZ4-419

CH

CH

BB11

H

H

H

IZ4-459

BZ

BZ

BB14

H

H

H

IZ4-420

BZ

BZ

BB11

H

H

H

IZ4-460

EOE

EOE

BB14

H

H

H

IZ4-421

EOE

EOE

BB11

H

H

H

IZ4-461

ALL

ALL

BB14

H

H

H

IZ4-422

ALL

ALL

BB11

H

H

H

IZ4-462

CBA

CBA

BB14

H

H

H

IZ4-423

CBA

CBA

BB11

H

H

H

IZ4-463

HYE

HYE

BB14

H

H

H

IZ4-424

HYE

HYE

BB11

H

H

H

IZ4-464

NA1

NA1

BB14

H

H

H

IZ4-425

NA1

NA1

BB11

H

H

H

IZ4-465

HHk8

HHk8

BB14

H

H

H

IZ4-426

HHk8

HHk8

BB11

H

H

H

IZ4-466

NA2

NA2

BB14

H

H

H

IZ4-427

NA2

NA2

BB11

H

H

H

IZ4-467

HHk7

HHk7

BB14

H

H

H

IZ4-428

HHk7

HHk7

BB11

H

H

H

IZ4-468

HH37

HH37

BB14

H

H

H

IZ4-429

HH37

HH37

BB11

H

H

H

IZ4-469

HHk6

HHk6

BB14

H

H

H

IZ4-430

HHk6

HHk6

BB11

H

H

H

IZ4-470

NA3

NA3

BB14

H

H

H

IZ4-431

NA3

NA3

BB11

H

H

H

IZ4-471

HHJ2

HHJ2

BB14

H

H

H

IZ4-432

HHJ2

HHJ2

BB11

H

H

H

IZ4-472

HHk11

HHk11

BB14

H

H

H

IZ4-433

HHk11

HHk11

BB11

H

H

H

IZ4-473

Et

Me

BB14

H

H

H

IZ4-434

Et

Me

BB11

H

H

H

IZ4-474

PH

Me

BB14

H

H

H

IZ4-435

PH

Me

BB11

H

H

H

IZ4-475

Oct

Me

BB14

H

H

H

IZ4-436

Oct

Me

BB11

H

H

H

IZ4-476

CHM

Me

BB14

H

H

H

IZ4-437

CHM

Me

BB11

H

H

H

IZ4-477

CH

Me

BB14

H

H

H

IZ4-438

CH

Me

BB11

H

H

H

IZ4-478

BZ

Me

BB14

H

H

H

IZ4-439

BZ

Me

BB11

H

H

H

IZ4-479

EOE

Me

BB14

H

H

H

IZ4-440

EOE

Me

BB11

H

H

H

IZ4-480

ALL

Me

BB14

H

H

H

IZ4-441

ALL

Me

BB11

H

H

H

IZ4-481

CBA

Me

BB14

H

H

H

[ Table 13Z4]

TABLE 13Z4

RN1Z4

RN2Z4

Ba1Z4Ba2Z4

R1Z4

R6Z4

R7Z4

RN1Z4

RN2Z4

Ba1Z4Ba2Z4

R1Z4

R6Z4

R7Z4

IZ4-482

HYE

Me

BB14

H

H

H

IZ4-522

Oct

Oct

BB37

H

H

H

IZ4-483

NA1

Me

BB14

H

H

H

IZ4-523

CHM

CHM

BB37

H

H

H

IZ4-484

HHk8

Me

BB14

H

H

H

IZ4-524

CH

CH

BB37

H

H

H

IZ4-485

NA2

Me

BB14

H

H

H

IZ4-525

BZ

BZ

BB37

H

H

H

IZ4-486

HHk7

Me

BB14

H

H

H

IZ4-526

ALL

ALL

BB37

H

H

H

IZ4-487

HH37

Me

BB14

H

H

H

IZ4-527

CBA

CBA

BB37

H

H

H

IZ4-488

HHk6

Me

BB14

H

H

H

IZ4-528

HYE

HYE

BB37

H

H

H

IZ4-489

NA3

Me

BB14

H

H

H

IZ4-529

NA1

NA1

BB37

H

H

H

IZ4-490

HHJ2

Me

BB14

H

H

H

IZ4-530

HHk8

HHk8

BB37

H

H

H

IZ4-491

HHk11

Me

BB14

H

H

H

IZ4-531

NA2

NA2

BB37

H

H

H

IZ4-492

NA1

NA1

BB19

H

H

H

IZ4-532

HHk7

HHk7

BB37

H

H

H

IZ4-493

HHk8

HHk8

BB19

H

H

H

IZ4-533

HH37

HH37

BB37

H

H

H

IZ4-494

NA2

NA2

BB19

H

H

H

IZ4-534

HHk6

HHk6

BB37

H

H

H

IZ4-495

HHk7

HHk7

BB19

H

H

H

IZ4-535

NA3

NA3

BB37

H

H

H

IZ4-496

HH37

HH37

BB19

H

H

H

IZ4-536

HHJ2

HHJ2

BB37

H

H

H

IZ4-497

HHk6

HHk6

BB19

H

H

H

IZ4-537

HHk11

HHk11

BB37

H

H

H

IZ4-498

NA3

NA3

BB19

H

H

H

IZ4-538

Et

Me

BB37

H

H

H

IZ4-499

HHJ2

HHJ2

BB19

H

H

H

IZ4-539

PH

Me

BB37

H

H

H

IZ4-500

HHk11

HHk11

BB19

H

H

H

IZ4-540

Oct

Me

BB37

H

H

H

IZ4-501

Et

Me

BB19

H

H

H

IZ4-541

CHM

Me

BB37

H

H

H

IZ4-502

PH

Me

BB19

H

H

H

IZ4-542

CH

Me

BB37

H

H

H

IZ4-503

Oct

Me

BB19

H

H

H

IZ4-543

BZ

Me

BB37

H

H

H

IZ4-504

CHM

Me

BB19

H

H

H

IZ4-544

EOE

Me

BB37

H

H

H

IZ4-505

CH

Me

BB19

H

H

H

IZ4-545

ALL

Me

BB37

H

H

H

IZ4-506

EOE

Me

BB19

H

H

H

IZ4-546

CBA

Me

BB37

H

H

H

IZ4-507

ALL

Me

BB19

H

H

H

IZ4-547

HYE

Me

BB37

H

H

H

IZ4-508

CBA

Me

BB19

H

H

H

IZ4-548

NA1

Me

BB37

H

H

H

IZ4-509

HYE

Me

BB19

H

H

H

IZ4-549

HHk8

Me

BB37

H

H

H

IZ4-510

NA1

Me

BB19

H

H

H

IZ4-550

NA2

Me

BB37

H

H

H

IZ4-511

HHk8

Me

BB19

H

H

H

IZ4-551

HHk7

Me

BB37

H

H

H

IZ4-512

NA2

Me

BB19

H

H

H

IZ4-552

HH37

Me

BB37

H

H

H

IZ4-513

HHk7

Me

BB19

H

H

H

IZ4-553

HHk6

Me

BB37

H

H

H

IZ4-514

HH37

Me

BB19

H

H

H

IZ4-554

NA3

Me

BB37

H

H

H

IZ4-515

HHk6

Me

BB19

H

H

H

IZ4-555

HHJ2

Me

BB37

H

H

H

IZ4-516

NA3

Me

BB19

H

H

H

IZ4-556

HHk11

Me

BB37

H

H

H

IZ4-517

HHJ2

Me

BB19

H

H

H

IZ4-557

Me

Me

BB58

H

H

H

IZ4-518

HHk11

Me

BB19

H

H

H

IZ4-558

Et

Et

BB58

H

H

H

IZ4-519

Me

Me

BB37

H

H

H

IZ4-559

PH

PH

BB58

H

H

H

IZ4-520

Et

Et

BB37

H

H

H

IZ4-560

Oct

Oct

BB58

H

H

H

IZ4-521

PH

PH

BB37

H

H

H

IZ4-561

CHM

CHM

BB58

H

H

H

[ Table 14Z4]

TABLE 14Z4

RN1Z4

RN2Z4

Ba1Z4Ba2Z4

R1Z4

R6Z4

R7Z4

RN1Z4

RN2Z4

Ba1Z4Ba2Z4

R1Z4

R6Z4

R7Z4

IZ4-562

CH

CH

BB58

H

H

H

IZ4-602

EOE

EOE

BBJ2

H

H

H

IZ4-563

BZ

BZ

BB58

H

H

H

IZ4-603

ALL

ALL

BBJ2

H

H

H

IZ4-564

EOE

EOE

BB58

H

H

H

IZ4-604

CBA

CBA

BBJ2

H

H

H

IZ4-565

CBA

CBA

BB58

H

H

H

IZ4-605

HYE

HYE

BBJ2

H

H

H

IZ4-566

HYE

HYE

BB58

H

H

H

IZ4-606

NA1

NA1

BBJ2

H

H

H

IZ4-567

NA1

NA1

BB58

H

H

H

IZ4-607

HHk8

HHk8

BBJ2

H

H

H

IZ4-568

HHk8

HHk8

BB58

H

H

H

IZ4-608

NA2

NA2

BBJ2

H

H

H

IZ4-569

NA2

NA2

BB58

H

H

H

IZ4-609

HHk7

HHk7

BBJ2

H

H

H

IZ4-570

HHk7

HHk7

BB58

H

H

H

IZ4-610

HH37

HH37

BBJ2

H

H

H

IZ4-571

HH37

HH37

BB58

H

H

H

IZ4-611

HHk6

HHk6

BBJ2

H

H

H

IZ4-572

HHk6

HHk6

BB58

H

H

H

IZ4-612

NA3

NA3

BBJ2

H

H

H

IZ4-573

NA3

NA3

BB58

H

H

H

IZ4-613

HHJ2

HHJ2

BBJ2

H

H

H

IZ4-574

HHJ2

HHJ2

BB58

H

H

H

IZ4-614

HHk11

HHk11

BBJ2

H

H

H

IZ4-575

HHk11

HHk11

BB58

H

H

H

IZ4-615

Et

Me

BBJ2

H

H

H

IZ4-576

Et

Me

BB58

H

H

H

IZ4-616

PH

Me

BBJ2

H

H

H

IZ4-577

PH

Me

BB58

H

H

H

IZ4-617

Oct

Me

BBJ2

H

H

H

IZ4-578

Oct

Me

BB58

H

H

H

IZ4-618

CHM

Me

BBJ2

H

H

H

IZ4-579

CHM

Me

BB58

H

H

H

IZ4-619

CH

Me

BBJ2

H

H

H

IZ4-580

CH

Me

BB58

H

H

H

IZ4-620

BZ

Me

BBJ2

H

H

H

IZ4-581

BZ

Me

BB58

H

H

H

IZ4-621

EOE

Me

BBJ2

H

H

H

IZ4-582

EOE

Me

BB58

H

H

H

IZ4-622

ALL

Me

BBJ2

H

H

H

IZ4-583

ALL

Me

BB58

H

H

H

IZ4-623

CBA

Me

BBJ2

H

H

H

IZ4-584

CBA

Me

BB58

H

H

H

IZ4-624

HYE

Me

BBJ2

H

H

H

IZ4-585

HYE

Me

BB58

H

H

H

IZ4-625

NA1

Me

BBJ2

H

H

H

IZ4-586

NA1

Me

BB58

H

H

H

IZ4-626

HHk8

Me

BBJ2

H

H

H

IZ4-587

HHk8

Me

BB58

H

H

H

IZ4-627

NA2

Me

BBJ2

H

H

H

IZ4-588

NA2

Me

BB58

H

H

H

IZ4-628

HHk7

Me

BBJ2

H

H

H

IZ4-589

HHk7

Me

BB58

H

H

H

IZ4-629

HH37

Me

BBJ2

H

H

H

IZ4-590

HH37

Me

BB58

H

H

H

IZ4-630

HHk6

Me

BBJ2

H

H

H

IZ4-591

HHk6

Me

BB58

H

H

H

IZ4-631

NA3

Me

BBJ2

H

H

H

IZ4-592

NA3

Me

BB58

H

H

H

IZ4-632

HHJ2

Me

BBJ2

H

H

H

IZ4-593

HHJ2

Me

BB58

H

H

H

IZ4-633

HHk11

Me

BBJ2

H

H

H

IZ4-594

HHk11

Me

BB58

H

H

H

IZ4-634

Me

Me

BBO8

H

H

H

IZ4-595

Me

Me

BBJ2

H

H

H

IZ4-635

Et

Et

BBO8

H

H

H

IZ4-596

Et

Et

BBJ2

H

H

H

IZ4-636

PH

PH

BBO8

H

H

H

IZ4-597

PH

PH

BBJ2

H

H

H

IZ4-637

Oct

Oct

BBO8

H

H

H

IZ4-598

Oct

Oct

BBJ2

H

H

H

IZ4-638

CHM

CHM

BBO8

H

H

H

IZ4-599

CHM

CHM

BBJ2

H

H

H

IZ4-639

CH

CH

BBO8

H

H

H

IZ4-600

CH

CH

BBJ2

H

H

H

IZ4-640

BZ

BZ

BBO8

H

H

H

IZ4-601

BZ

BZ

BBJ2

H

H

H

IZ4-641

EOE

EOE

BBO8

H

H

H

[ Table 15Z4]

TABLE 15Z4

RN1Z4

RN2Z4

Ba1Z4Ba2Z4

R1Z4

R6Z4

R7Z4

RN1Z4

RN2Z4

Ba1Z4Ba2Z4

R1Z4

R6Z4

R7Z4

IZ4-642

ALL

ALL

BBO8

H

H

H

IZ4-682

CBA

CBA

BBO10

H

H

H

IZ4-643

CBA

CBA

BBO8

H

H

H

IZ4-683

HYE

HYE

BBO10

H

H

H

IZ4-644

HYE

HYE

BBO8

H

H

H

IZ4-684

NA1

NA1

BBO10

H

H

H

IZ4-645

NA1

NA1

BBO8

H

H

H

IZ4-685

HHk8

HHk8

BBO10

H

H

H

IZ4-646

HHk8

HHk8

BBO8

H

H

H

IZ4-686

NA2

NA2

BBO10

H

H

H

IZ4-647

NA2

NA2

BBO8

H

H

H

IZ4-687

HHk7

HHk7

BBO10

H

H

H

IZ4-648

HHk7

HHk7

BBO8

H

H

H

IZ4-688

HH37

HH37

BBO10

H

H

H

IZ4-649

HH37

HH37

BBO8

H

H

H

IZ4-689

HHk6

HHk6

BBO10

H

H

H

IZ4-650

HHk6

HHk6

BBO8

H

H

H

IZ4-690

NA3

NA3

BBO10

H

H

H

IZ4-651

NA3

NA3

BBO8

H

H

H

IZ4-691

HHJ2

HHJ2

BBO10

H

H

H

IZ4-652

HHJ2

HHJ2

BBO8

H

H

H

IZ4-692

HHk11

HHk11

BBO10

H

H

H

IZ4-653

HHk11

HHk11

BBO8

H

H

H

IZ4-693

Et

Me

BBO10

H

H

H

IZ4-654

Et

Me

BBO8

H

H

H

IZ4-694

PH

Me

BBO10

H

H

H

IZ4-655

PH

Me

BBO8

H

H

H

IZ4-695

Oct

Me

BBO10

H

H

H

IZ4-656

Oct

Me

BBO8

H

H

H

IZ4-696

CHM

Me

BBO10

H

H

H

IZ4-657

CHM

Me

BBO8

H

H

H

IZ4-697

CH

Me

BBO10

H

H

H

IZ4-658

CH

Me

BBO8

H

H

H

IZ4-698

BZ

Me

BBO10

H

H

H

IZ4-659

BZ

Me

BBO8

H

H

H

IZ4-699

EOE

Me

BBO10

H

H

H

IZ4-660

EOE

Me

BBO8

H

H

H

IZ4-700

ALL

Me

BBO10

H

H

H

IZ4-661

ALL

Me

BBO8

H

H

H

IZ4-701

CBA

Me

BBO10

H

H

H

IZ4-662

CBA

Me

BBO8

H

H

H

IZ4-702

HYE

Me

BBO10

H

H

H

IZ4-663

HYE

Me

BBO8

H

H

H

IZ4-703

NA1

Me

BBO10

H

H

H

IZ4-664

NA1

Me

BBO8

H

H

H

IZ4-704

HHk8

Me

BBO10

H

H

H

IZ4-665

HHk8

Me

BBO8

H

H

H

IZ4-705

NA2

Me

BBO10

H

H

H

IZ4-666

NA2

Me

BBO8

H

H

H

IZ4-706

HHk7

Me

BBO10

H

H

H

IZ4-667

HHk7

Me

BBO8

H

H

H

IZ4-707

HH37

Me

BBO10

H

H

H

IZ4-668

HH37

Me

BBO8

H

H

H

IZ4-708

HHk6

Me

BBO10

H

H

H

IZ4-669

HHk6

Me

BBO8

H

H

H

IZ4-709

NA3

Me

BBO10

H

H

H

IZ4-670

NA3

Me

BBO8

H

H

H

IZ4-710

HHJ2

Me

BBO10

H

H

H

IZ4-671

HHJ2

Me

BBO8

H

H

H

IZ4-711

HHk11

Me

BBO10

H

H

H

IZ4-672

HHk11

Me

BBO8

H

H

H

IZ4-712

HH9

HHf5

BB2

H

H

H

IZ4-673

Me

Me

BBO10

H

H

H

IZ4-713

HHh1

HHj19

BB3

H

H

H

IZ4-674

Et

Et

BBO10

H

H

H

IZ4-714

HH55

HH81

BB4

H

H

H

IZ4-675

PH

PH

BBO10

H

H

H

IZ4-715

HHf1

HHi11

BB5

H

H

H

IZ4-676

Oct

Oct

BBO10

H

H

H

IZ4-716

NA5

HHJ10

BB7

H

H

H

IZ4-677

CHM

CHM

BBO10

H

H

H

IZ4-717

HHk7

HHc1

BB9

H

H

H

IZ4-678

CH

CH

BBO10

H

H

H

IZ4-718

HHf11

HH28

BB10

H

H

H

IZ4-679

BZ

BZ

BBO10

H

H

H

IZ4-719

HH13

HH46

BB12

H

H

H

IZ4-680

EOE

EOE

BBO10

H

H

H

IZ4-720

HHJ4

HH78

BB13

H

H

H

IZ4-681

ALL

ALL

BBO10

H

H

H

IZ4-721

HHb3

HH22

BB15

H

H

H

[ Table 16Z4]

TABLE 16Z4

For example, the compound IZ4-1 is a compound represented by the formula (IZ 4-1).

The compound IZ4 is preferably a compound IZ4-1 to a compound IZ4-234 and a compound IZ4-321 to a compound IZ4-769, more preferably a compound IZ4-1 to a compound IZ4-234 and a compound IZ4-321 to a compound IZ4-711, still more preferably a compound IZ4-1 to a compound IZ4-234, yet more preferably a compound IZ4-1 to a compound IZ4-174, particularly preferably a compound IZ4-1 to a compound IZ4-117,

particularly preferred are the compound IZ4-1 to the compound IZ4-2, the compound IZ4-40 to the compound IZ4-41, and the compound IZ4-79 to the compound IZ 4-80.

Specific examples of the compound IZ4 include compounds represented by table 1Z4, table 2Z4, table 3Z4, table 4Z4, table 5Z4, table 6Z4, table 7Z4, table 8Z4, and tables 11Z4 to 16Z4, in which 1 to 3 hydrogen atoms contained in the compounds are replaced by — SO₃M or-CO₂M is substituted. For example, compounds having 1 to 3 sulfo groups bonded to the compound IZ4-1 of Table 1Z4 are represented by the following structures. Wherein, in the formula, - (SO)₃H) Represents a compound in which any hydrogen atom in compound IZ4-1 of Table 1Z4 is substituted.

In the present invention, it is preferable that 1 to 3-SO groups are bonded to the compound IZ4-1 to the compound IZ4-234 and the compound IZ4-321 to the compound IZ4-769₃M or-CO₂More preferably, the compound of M is a compound in which 1 to 3-SO groups are bonded to the compound IZ4-1 to the compound IZ4-234 and the compound IZ4-321 to the compound IZ4-711 ₃M or-CO₂A compound formed by the reaction of M,

more preferably, 1 to 3-SO groups are bonded to the compound IZ4-1 to the compound IZ4-234₃M or-CO₂A compound formed by the reaction of M,

more preferably, 1 to 3-SO groups are bonded to the compound IZ4-1 to the compound IZ4-174₃M or-CO₂A compound formed by the reaction of M,

particularly preferably, 1 to 3-SO groups are bonded to the compound IZ4-1 to the compound IZ4-117₃M or-CO₂A compound formed by the reaction of M,

particularly preferably, 1 to 3-SO groups are bonded to the compound IZ4-1 to the compound IZ4-2, the compound IZ4-40 to the compound IZ4-41, and the compound IZ4-79 to the compound IZ4-80₃M or-CO₂M, or a salt thereof.

As the compound (IZ4), the following compounds are preferable:

in the formula (IZ4), R^N1Z4And R^N2Z4Independently of one another are-CO-R^102Z4、-COO-R^101Z4、-CON(R^102Z4)₂Or may have a structure selected from the group consisting of-SO₃M and-CO₂A C1-20 hydrocarbon group as a substituent in the group consisting of M, R^1Z4Is a hydrogen atom and may have a radical selected from the group consisting of-SO₃M and-CO₂Taking of group consisting of MA substituted hydrocarbon group having 1 to 20 carbon atoms, -SO₃M or-CO₂M，

R^2Z4～R^5Z4Each independently represents a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogen atom, or-N (R)^102Z4)₂A C1-20 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R ^102Z4、-O-R^102Z4、-SO₃M or-CO₂M，R^6Z4And R^7Z4Independently of one another, a hydrogen atom, may have a structure selected from the group consisting of-SO₃M and-CO₂A C1-20 hydrocarbon group, -SO₃M or-CO₂M，R^102Z4Is a hydrogen atom, or may have a radical selected from the group consisting of-SO₃M and-CO₂A C1-20 hydrocarbon group as a substituent in the group consisting of M, R^101Z4May have a structure selected from the group consisting of-SO₃M and-CO₂A compound in which the substituent in the group consisting of M is a hydrocarbon group having 1 to 20 carbon atoms, and M is a hydrogen atom or an alkali metal atom;

more preferred are the following compounds:

R^N1Z4and R^N2Z4Independently of one another are-CO-R^102Z4、-CON(R^102Z4)₂Or may have a structure selected from the group consisting of-SO₃M and-CO₂A C1-10 hydrocarbon group as a substituent in the group consisting of M, R^1Z4Is a hydrogen atom, R^2Z4～R^5Z4Each independently represents a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, or-N (R)^102Z4)₂A C1-10 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R^102Z4、-O-R^102Z4、-SO₃M or-CO₂M，

R^6Z4And R^7Z4Are the same group, are hydrogen atoms, or may have a structure selected from the group consisting of₃M and-CO₂A hydrocarbyl group having 1 to 10 carbon atoms as a substituent in the group consisting of M,

R^102Z4is a hydrogen atom, or may have a radical selected from the group consisting of-SO₃M and-CO₂a C1-10 hydrocarbon group as a substituent in the group consisting of M, R ^101Z4May have a structure selected from the group consisting of-SO₃M and-CO₂A compound in which the substituent in the group consisting of M is a hydrocarbon group having 1 to 10 carbon atoms, and M is a hydrogen atom or an alkali metal atom;

further preferred are the following compounds:

R^N1Z4and R^N2Z4Independently of one another are-CO-R^102Z4、-CON(R^102Z4)₂Or may have a structure selected from the group consisting of-SO₃M and-CO₂A hydrocarbyl group having 1 to 10 carbon atoms as a substituent in the group consisting of M,

R^1Z4is a hydrogen atom, R^2Z4～R^5Z4Each independently represents a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, or-N (R)^102Z4)₂Nitro, trifluoromethyl, -O-R^102Z4、-SO₃M or-CO₂M，

R^6Z4And R^7Z4The same group is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms, R^102Z4Is a hydrogen atom, or may have a radical selected from the group consisting of-SO₃M and-CO₂A hydrocarbyl group having 1 to 10 carbon atoms as a substituent in the group consisting of M,

R^101Z4may have a structure selected from the group consisting of-SO₃M and-CO₂And M is a compound in which the substituent in the group consisting of M is a hydrocarbon group having 1 to 10 carbon atoms and M is a hydrogen atom or an alkali metal atom.

For compound IZ4, R^1Z4In the case of a hydrogen atom, the compound represented by the formula (pt1Z4) (hereinafter, may be referred to as a phthalonitrile compound) may be produced by reacting a compound represented by the formula (pt2Z4) (hereinafter, may be referred to as an alkoxide compound), and then further reacting the compound represented by the formula (pt3Z4) and the compound represented by the formula (pt4Z4) in the presence of an acid. In addition, R ^1Z4When not a hydrogen atom, the compound is further reacted with a compound represented by the formula (pt5Z4) to produce a compound IZ 4.

In [ formula (pt1Z4), formula (pt2Z4), formula (pt3Z4), formula (pt4Z4), formula (pt5Z4) and formula (IZ4), R^N1Z4、R^N2Z4、R^1Z4、R^2Z4、R^3Z4、R^4Z4、R^5Z4、R^6Z4And R^7Z4The same meanings as described above are indicated. R^14Z4Represents an alkyl group having 1 to 20 carbon atoms. M^1Z4Represents an alkali metal atom. LG represents a halogen atom, a mesyloxy group, a tosyloxy group or a trifluormesyloxy group.]

As R^14Z4Examples of the alkyl group having 1 to 20 carbon atoms include methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec-butyl, tert-butyl, and the like, and preferred examples thereof include alkyl groups having 1 to 6 carbon atoms.

As M^1Z4Examples of the alkali metal atom include a lithium atom, a sodium atom and a potassium atom. The amount of the alkoxide compound used is usually 0.1 to 10 moles, preferably 0.2 to 5 moles, more preferably 0.3 to 3 moles, and still more preferably 0.4 to 2 moles, based on 1 mole of the phthalonitrile compound.

The amount of the compound pt3Z4 used is usually 1 to 10 moles, preferably 1 to 5 moles, more preferably 1 to 3 moles, and still more preferably 1 to 2 moles, based on 1 mole of the phthalonitrile compound.

The amount of the compound pt4Z4 used is usually 1 to 10 moles, preferably 1 to 5 moles, more preferably 1 to 3 moles, and still more preferably 1 to 2 moles, based on 1 mole of the phthalonitrile compound.

Examples of the acid include inorganic acids such as hydrochloric acid, hydrobromic acid, hydroiodic acid, sulfuric acid, nitric acid, fluorosulfonic acid, and phosphoric acid; sulfonic acids such as methanesulfonic acid, trifluoromethanesulfonic acid, and p-toluenesulfonic acid; examples of the carboxylic acid include acetic acid, citric acid, formic acid, gluconic acid, lactic acid, oxalic acid, tartaric acid, and the like, and preferably include hydrochloric acid, hydrobromic acid, sulfuric acid, methanesulfonic acid, trifluoromethanesulfonic acid, p-toluenesulfonic acid, and carboxylic acid, and more preferably include acetic acid.

The amount of the acid used is usually 1 to 20 moles, preferably 1 to 10 moles, more preferably 1 to 8 moles, and still more preferably 1 to 6 moles, based on 1 mole of the phthalonitrile compound.

The reaction of the phthalonitrile compound, the alkoxide compound, the compound pt3Z4, and the compound pt4Z4 can be usually carried out in the presence of a solvent.

As the solvent, water may be mentioned; nitrile solvents such as acetonitrile; alcohol solvents such as methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, and 1-octanol; ether solvents such as tetrahydrofuran; ketone solvents such as acetone; ester solvents such as ethyl acetate; aliphatic hydrocarbon solvents such as hexane; aromatic hydrocarbon solvents such as toluene; halogenated hydrocarbon solvents such as dichloromethane and chloroform; amide solvents such as N, N-dimethylformamide and N-methylpyrrolidone; sulfoxide solvents such as dimethyl sulfoxide, preferably include water, nitrile solvents, alcohol solvents, ether solvents, ketone solvents, ester solvents, aromatic hydrocarbon solvents, halogenated hydrocarbon solvents, amide solvents and sulfoxide solvents, more preferably include water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, tetrahydrofuran, acetone, ethyl acetate, toluene, dichloromethane, chloroform, N-dimethylformamide, N-methylpyrrolidone and dimethyl sulfoxide, still more preferably include water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, acetone, dichloromethane, chloroform, N-dimethylformamide, N-methylpyrrolidone and dimethyl sulfoxide, and particularly preferably include water, methanol, ethanol, methanol, ethanol, butanol, methanol, ethanol, 1-butanol, 1-pentanol, 1-octanol, acetone, dichloromethane, chloroform, N-methylpyrrolidone and dimethyl sulfoxide, Acetonitrile, methanol, ethanol and 2-propanol.

The amount of the solvent used is usually 1 to 1000 parts by mass per 1 part by mass of the phthalonitrile compound. The reaction temperature is usually 0 to 200 ℃, preferably 0 to 100 ℃, more preferably 0 to 70 ℃, and further preferably 0 to 50 ℃. The reaction time is usually 0.5 to 300 hours.

With respect to the amount of compound pt5Z4 used, relative to R^1Z4The amount of the compound IZ41 which is a hydrogen atom is usually 1 to 10 moles, preferably 1 to 5 moles, more preferably 1 to 3 moles, and still more preferably 1 to 2 moles.

When the compound pt5Z4 is reacted, a base is preferably coexisted. Examples of the base include organic bases such as triethylamine, 4- (N, N-dimethylamino) pyridine, and piperidine; metal alkoxides such as sodium methoxide, sodium ethoxide, sodium tert-butoxide, and potassium tert-butoxide; organic metal compounds such as butyl lithium, tert-butyl lithium and phenyl lithium; inorganic bases such as lithium hydroxide, sodium hydroxide and potassium hydroxide.

As for the amount of the base used, with respect to R^1Z4The amount of the compound IZ41 which is a hydrogen atom is usually 1 to 10 moles, preferably 1 to 5 moles, more preferably 1 to 3 moles, and still more preferably 1 to 2 moles.

The reaction of compound pt5Z4 can generally be carried out in the presence of a solvent. The solvent may be selected from the same ranges as described above.

As to the amount of the solvent used, with respect to R^1Z4The amount of the compound IZ 41 is usually 1 to 1000 parts by mass. The reaction temperature of the compound pt5Z4 is usually-90 to 200 ℃, preferably-80 to 100 ℃, and more preferably 0 to 50 ℃. The reaction time is usually 0.5 to 300 hours.

Compound IZ4 having no sulfo group or-SO₃M²In the case of (3), the compound IZ4 can be reacted with a sulfonating agent such as fuming sulfuric acid or chlorosulfonic acid to introduce a sulfo group or-SO₃M²²。

M²²Represents an alkali metal atom. As M²²Examples of the alkali metal atom include a lithium atom, a sodium atom and a potassium atom.

With respect to SO in oleum₃The amount of (b) is usually 1 to 50 mol, preferably 5 to 40 mol, more preferably 5 to 30 mol, and still more preferably 5 to 25 mol based on 41 mol of the compound IZ.

The amount of sulfuric acid used in the oleum is usually 1 to 200 moles, preferably 10 to 100 moles, more preferably 10 to 75 moles, and still more preferably 10 to 50 moles, based on 41 moles of the compound IZ.

The amount of chlorosulfonic acid used is usually 1 to 500 moles, preferably 10 to 300 moles, more preferably 10 to 200 moles, and still more preferably 10 to 150 moles, based on 41 moles of the compound IZ.

The reaction temperature of sulfonation is usually-20 to 200 ℃, preferably-10 to 100 ℃, and more preferably 0 to 50 ℃. The reaction time is usually 0.5 to 300 hours.

The method for extracting the compound IZ4 from the reaction mixture is not particularly limited, and it can be extracted by various known methods. For example, after the reaction is completed, the reaction mixture is filtered to extract the compound IZ 4. Further, the residue obtained after filtration may be subjected to column chromatography, recrystallization, or the like. After the completion of the reaction, the solvent of the reaction mixture may be distilled off and then purified by column chromatography.

< Compound IZ5 >)

Compound IZ5 is represented by formula (IZ 5).

[ formula (IZ5), R^N1Z5represents-CO-R^102Z5、-COO-R^101Z5、-OCO-R^102Z5、-COCO-R^102Z5、-O-R^102Z5、-SO₂-R^101Z5、-SO₂N(R^102Z5)₂、-CON(R^102Z5)₂、-N(R^102Z5)₂、-NHCO-R^102Z5、-NHCO-N(R^102Z5)₂、-NHCOOR^102Z5、-OCON(R^102Z5)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.

R^1Z5、R^2Z5、R^3Z5、R^4Z5、R^5Z5、R^6Z5And R^7Z5Independently of one another, represents a hydrogen atom, -CO-R^102Z5、-COO-R^101Z5、-OCO-R^102Z5、-COCO-R^102Z5、-O-R^102Z5、-SO₂-R^101Z5、-SO₂N(R^102Z5)₂、-CON(R^102Z5)₂、-N(R^102Z5)₂、-NHCO-R^102Z5、-NHCO-N(R^102Z5)₂、-NHCOOR^102Z5、-OCON(R^102Z5)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group, R is^2Z5And R^3Z5、R^3Z5And R^4Z5And R^4Z5And R^5Z5Each of which may be bonded to each other to form a ring, R^2Z5、R^3Z5、R^4Z5And R^5Z5At least one of which is-CO-R ^102Z5、-COO-R^101Z5、-OCO-R^102Z5、-COCO-R^102Z5、-O-R^102Z5、-SO₂-R^101Z5、-SO₂N(R^102Z5)₂、-CON(R^102Z5)₂、-N(R^102Z5)₂、-NHCO-R^102Z5、-NHCO-N(R^102Z5)₂、-NHCOOR^102Z5、-OCON(R^102Z5)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent, or R is^2Z5And R^3Z5、R^3Z5And R^4Z5And R^4Z5And R^5Z5At least one group of them is bonded to form a ring.

R^101Z5The alkyl group may have a substituent and has 1 to 40 carbon atoms, or a heterocyclic group may have a substituent.

R^102Z5Represents a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group. M represents a hydrogen atom or an alkali metal atom. R^101Z5、R^102Z5And when there are a plurality of M, they may be the same or different. The wavy line indicates the E-body or the Z-body.]

R^N1Z5、R^1Z5、R^2Z5、R^3Z5、R^4Z5、R^5Z5、R^6Z5、R^7Z5、R^101Z5And R^102Z5The number of carbon atoms of the optionally substituted hydrocarbon group is 1 to 40, preferably 1 to 401 to 30, more preferably 1 to 20, further preferably 1 to 15, particularly preferably 1 to 10, and particularly preferably 1 to 5.

R^N1Z5、R^1Z5、R^2Z5、R^3Z5、R^4Z5、R^5Z5、R^6Z5、R^7Z5、R^101Z5And R^102Z5The hydrocarbon group having 1 to 40 carbon atoms may be an aliphatic hydrocarbon group or an aromatic hydrocarbon group, and the aliphatic hydrocarbon group may be saturated or unsaturated, and may be a chain or alicyclic group.

As R^N1Z5、R^1Z5、R^2Z5、R^3Z5、R^4Z5、R^5Z5、R^6Z5、R^7Z5、R^101Z5And R^102Z5Examples of the saturated or unsaturated chain hydrocarbon group include straight chain alkyl groups such as methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, heptadecyl, octadecyl, and eicosyl; branched alkyl groups such as isopropyl, isobutyl, sec-butyl, tert-butyl, (2-ethyl) butyl, isopentyl, neopentyl, tert-pentyl, (1-methyl) pentyl, (2-methyl) pentyl, (1-ethyl) pentyl, (3-ethyl) pentyl, isohexyl, (5-methyl) hexyl, (2-ethyl) hexyl and (3-ethyl) heptyl; alkenyl groups such as vinyl, 1-propenyl, 2-propenyl (allyl), (1-methyl) vinyl, 2-butenyl, 3-butenyl, 1, 3-butadienyl, (1- (2-propenyl)) vinyl, (1, 2-dimethyl) propenyl, and 2-pentenyl; and so on. The number of carbon atoms of the saturated or unsaturated chain hydrocarbon group is preferably 1 to 30, more preferably 1 to 20, further preferably 1 to 15, particularly preferably 1 to 10, further more preferably 1 to 8, and particularly preferably 1 to 5. Among them, a linear or branched alkyl group having 1 to 10 carbon atoms, more preferably 1 to 8 carbon atoms is particularly preferable, and a methyl group, an ethyl group, and a tert-butyl group are particularly preferable.

As R^N1Z5、R^1Z5、R^2Z5、R^3Z5、R^4Z5、R^5Z5、R^6Z5、R^7Z5、R^101Z5And R^102Z5A saturated or unsaturated alicyclic hydrocarbon group represented byExamples thereof include cyclopropyl group, 1-methylcyclopropyl group, cyclobutyl group, cyclopentyl group, cyclohexyl group, cycloheptyl group, 1-methylcyclohexyl group, 2-methylcyclohexyl group, 3-methylcyclohexyl group, 4-methylcyclohexyl group, 1, 2-dimethylcyclohexyl group, 1, 3-dimethylcyclohexyl group, 1, 4-dimethylcyclohexyl group, 2, 3-dimethylcyclohexyl group, 2, 4-dimethylcyclohexyl group, 2, 5-dimethylcyclohexyl group, 2, 6-dimethylcyclohexyl group, 3, 4-dimethylcyclohexyl group, 3, 5-dimethylcyclohexyl group, 2-dimethylcyclohexyl group, 3-dimethylcyclohexyl group, 4-dimethylcyclohexyl group, cyclooctyl group, 2,4, 6-trimethylcyclohexyl group, 2,6, 6-tetramethylcyclohexyl group and 3, cycloalkyl groups such as 3,5, 5-tetramethylcyclohexyl, 4-pentylcyclohexyl, 4-octylcyclohexyl and 4-cyclohexylcyclohexyl; cycloalkenyl groups such as cyclohexenyl (e.g., cyclohex-2-ene, cyclohex-3-ene), cycloheptenyl, and cyclooctenyl; norbornyl, adamantyl, bicyclo [2.2.2]An octyl group and the like. The number of carbon atoms of the saturated or unsaturated alicyclic hydrocarbon group is preferably 3 to 30, more preferably 3 to 20, still more preferably 4 to 20, yet more preferably 4 to 15, even more preferably 5 to 15, and most preferably 5 to 10. Among them, cyclopentyl, cyclohexyl, cycloheptyl, and cyclooctyl are particularly preferable.

As R^N1Z5、R^1Z5、R^2Z5、R^3Z5、R^4Z5、R^5Z5、R^6Z5、R^7Z5、R^101Z5And R^102Z5The aromatic hydrocarbon group may include a phenyl group, an o-tolyl group, a m-tolyl group, a p-tolyl group, a 2, 3-dimethylphenyl group, a 2, 4-dimethylphenyl group, a 2, 5-dimethylphenyl group, a 2, 6-dimethylphenyl group, a 3, 4-dimethylphenyl group, a 3, 5-dimethylphenyl group, a 4-vinylphenyl group, an o-isopropylphenyl group, a m-isopropylphenyl group, a p-isopropylphenyl group, an o-tert-butylphenyl group, a m-tert-butylphenyl group, a p-tert-butylphenyl group, a mesityl group, a 4-ethylphenyl group, a 4-butylphenyl group, a 4-pentylphenyl group, a 2, 6-bis (2-propyl) phenyl group, a 4-cyclohexylphenyl group, a 2,4, 6-trimethylphenyl group, a 4-octylphenyl group, a 4-vinylphenyl group, a 1-naphthyl group, a 2-naphthyl group, a, Aromatic hydrocarbon groups such as 5,6,7, 8-tetrahydro-1-naphthyl, 5,6,7, 8-tetrahydro-2-naphthyl, fluorenyl, phenanthryl, anthracyl, pyrenyl and the like; and so on. The number of carbon atoms of the aromatic hydrocarbon group is preferably 6 to 30, more preferably 6 to 20, and further more preferably 6 to 20Preferably 6 to 15.

R^N1Z5、R^1Z5、R^2Z5、R^3Z5、R^4Z5、R^5Z5、R^6Z5、R^7Z5、R^101Z5And R^102Z5The hydrocarbon group may be a combination of the hydrocarbon groups listed above (for example, an aromatic hydrocarbon group, and at least 1 of a chain hydrocarbon group and an alicyclic hydrocarbon group), and examples thereof include aralkyl groups such as benzyl, phenethyl, and 1-methyl-1-phenylethyl; arylalkenyl groups such as phenylvinyl (styryl); arylalkynyl groups such as phenylethynyl; a phenyl group having 1 or more phenyl groups bonded thereto, such as a biphenyl group and a terphenyl group; cyclohexylmethylphenyl, benzylphenyl, (dimethyl (phenyl) methyl) phenyl, and the like.

For R^N1Z5、R^1Z5、R^2Z5、R^3Z5、R^4Z5、R^5Z5、R^6Z5、R^7Z5、R^101Z5And R^102Z5Examples of the group represented by the above-mentioned groups, which are a combination of the above-mentioned hydrocarbon groups (e.g., chain hydrocarbon groups and alicyclic hydrocarbon groups), include alkyl groups to which 1 or more alicyclic hydrocarbon groups are bonded, such as cyclopropylmethyl groups, cyclopropylethyl groups, cyclobutylmethyl groups, cyclobutylethyl groups, cyclopentylmethyl groups, cyclopentylethyl groups, cyclohexylmethyl groups, 2-methylcyclohexylmethyl groups, cyclohexylethyl groups, and adamantylmethyl groups. The number of carbon atoms is preferably 4 to 30, more preferably 6 to 30, further preferably 6 to 20, further preferably 4 to 15, and particularly preferably 6 to 15.

R^N1Z5、R^1Z5、R^2Z5、R^3Z5、R^4Z5、R^5Z5、R^6Z5、R^7Z5、R^101Z5And R^102Z5The hydrocarbon group represented may have a substituent. The substituent may have a valence of 1 or 2. For substituents having a valence of 2, preferably 2 chemical bonds are bonded to the same carbon atom to form a double bond.

Examples of the substituent having a valence of 1 include:

methoxy group, ethoxy group, propoxy group, isopropoxy group, butoxy group, isobutoxy group, sec-butoxy group, tert-butoxy group, pentyloxy group, hexyloxy group, (2-ethyl) hexyloxy group, heptyloxy group, octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, dodecyloxy group, (2-ethyl) hexyloxy group, eicosyloxy group, 1-phenylethoxy group, 1-methyl-1-phenylethoxy group, phenyloxy group, o-tolyloxy group, 2, 3-dimethylphenyloxy group, 2, 4-dimethylphenyloxy group, 2, 5-dimethylphenyloxy group, 2, 6-dimethylphenyloxy group, 3, 4-dimethylphenyloxy group, 3, 5-dimethylphenyloxy group, 2-dicyanophenyloxy group, 2, 3-dicyanophenyloxy group, 2-dicyanophenyloxy group, 2, 4-dicyanophenyloxy group, 2, 5-dicyanophenyloxy group, 2, 6-dicyanophenyloxy group, 3, 4-dicyanophenyloxy group, 3, 5-dicyanophenyloxy group, 4-methoxyphenyloxy group, an oxy group having a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like) bonded to one side, such as a 2-methoxyphenyloxy group, a 3-methoxyphenyloxy group, a 4-ethoxyphenyloxy group, a 2-ethoxyphenyloxy group, a 3-ethoxyphenyloxy group, or a group represented by the following chemical formula;

A thio group (sulfo group) to which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) is bonded, such as a methylthio group, an ethylthio group, a propylthio group, a butylthio group, a tert-butylthio group, a pentylthio group, a hexylthio group, (2-ethyl) hexylthio group, a heptylthio group, an octylthio group, a nonylthio group, a decylthio group, an undecylthio group, a dodecylthio group, an eicosylthio group, a phenylthio group, and an o-tolylthio group;

epoxy, oxetanyl, tetrahydrofuranyl, tetrahydropyranyl;

a formyl group; a carbonyl group (preferably 2 to 12 carbon atoms when the carbonyl group is an alkanoyl group) having a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 11 carbon atoms) or a derivative thereof (for example, a derivative thereof such as a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), or an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)) bonded thereto, such as an acetyl group, a propionyl group, a butyryl group, a 2, 2-dimethylpropionyl group, a pentanoyl group, a hexanoyl group, (2-ethyl) hexanoyl group, a heptanoyl group, an octanoyl group, a nonanoyl group, a decanoyl group, an undecanoyl group, a dodecanoyl group, an heneicosanoyl group, and a benzoyl group;

An oxycarbonyl group in which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) is bonded, such as a methoxycarbonyl group, an ethoxycarbonyl group, a propoxycarbonyl group, a butoxycarbonyl group, a tert-butoxycarbonyl group, a pentyloxycarbonyl group, a hexyloxycarbonyl group, (2-ethyl) a hexyloxycarbonyl group, a heptyloxycarbonyl group, an octyloxycarbonyl group, a nonyloxycarbonyl group, a decyloxycarbonyl group, a undecyloxycarbonyl group, a dodecyloxycarbonyl group, an eicosyloxycarbonyl group, a phenyloxycarbonyl group, or an o-tolyloxycarbonyl group represented by the following chemical formula);

an amino group; n-methylamino, N-dimethylamino, N-ethylamino, N-diethylamino, N-propylamino, N-dipropylamino, N-isopropylamino, N-diisopropylamino, N-butylamino, N-dibutylamino, N-isobutylamino, N-diisobutylamino, N-sec-butylamino, N-di-sec-butylamino, N-tert-butylamino, N-di-tert-butylamino, N-pentylamino, N-dipentylamino, N- (1-ethylpropyl) amino, N-di (1-ethylpropyl) amino, N-hexylamino, N-dihexylamino, N- (2-ethyl) hexylamino, N-diethylamino, N-propylamino, N-dipropylamino, N-isopropylamino, N-di-sec-butylamino, N-pentylamino, N-dipentylamino, N-1-ethylpropyl) amino, N-di (1-ethylpropyl) amino, N-hexylamino, N-butylamino, N-butylamino, N-di-butylamino, N-butylamino, N, n, N-di (2-ethyl) hexylamino group, N-heptylamino group, N-diheptylamino group, N-octylamino group, N-dioctylamino group, N-nonylamino group, N-dinonylamino group, N-phenylamino group, N-diphenylamino group, N-ethylmethylamino group, N-propylmethylamino group, N-isopropylmethylamino group, N-butylmethylamino group, N-decylamino group, N-decylmethylamino group, N-undecylamino group, N-undecylmethylamino group, N-dodecylamino group, N-dodecylmethylamino group, N-eicosylamino group, N-eicosylmethyl amino group, An amino group substituted with 1 or 2 hydrocarbon groups having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or derivative groups thereof (for example, groups derived from carboxyl, sulfo, nitro, hydroxyl, halogen (preferably chlorine atom), alkylsulfamoyl having 1 to 10 carbon atoms (preferably octylsulfamoyl), and the like, such as an N, N-tert-butylmethylamino group, an N, N-phenylmethylamino group, and the like, and groups represented by the following chemical formula);

A sulfamoyl group; n-methylsulfamoyl, N-dimethylsulfamoyl, N-ethylsulfamoyl, N-diethylsulfamoyl, N-propylsulfamoyl, N-dipropylsulfamoyl, N-isopropylsulfamoyl, N-diisopropylsulfamoyl, N-butylsulfamoyl, N-dibutylsulfamoyl, N-isobutylsulfamoyl, N-diisobutylsulfamoyl, N-sec-butylsulfamoyl, N-tert-butylsulfamoyl, N-di-tert-butylsulfamoyl, N-pentylsulfamoyl, N-dipentylsulfamoyl, N- (1-ethylpropyl) sulfamoyl, N-di (1-ethylpropyl) sulfamoyl, N-diethylsulfamoyl, N-di (1-ethylpropyl) sulfamoyl, N-diethylsulfamoyl, N-butylsulfamoyl, N-di (1-ethylpropyl) sulfamoyl, N-butylsulfamoyl, N-di (1-isobutylsulfamoyl), N-dibutylsulfamoyl, N, di (1-di (ethyl, N, N, N-hexylsulfamoyl, N-dihexylsulfamoyl, N- (2-ethyl) hexylsulfamoyl, N-di (2-ethyl) hexylsulfamoyl, N-heptylsulfamoyl, N-diheptylsulfamoyl, N-octylsulfamoyl, N-dioctylsulfamoyl, N-octylmethylsulfamoyl, N-nonylsulfamoyl, N-dinonylsulfamoyl, N-phenylsulfamoyl, N-diphenylsulfamoyl, N-ethylmethylsulfamoyl, N-propylmethylsulfamoyl, N-isopropylmethylsulfamoyl, N-butylmethylsulfamoyl, N-decylsulfamoyl, N-decylmethylsulfamoyl, Sulfamoyl groups substituted with 1 or 2 hydrocarbon groups having 1 to 20 (preferably 1 to 10) carbon atoms or derivative groups thereof (for example, groups derived from carboxyl, sulfo, nitro, hydroxyl, halogen (preferably chlorine atom), alkylsulfamoyl having 1 to 10 carbon atoms (preferably octylsulfamoyl), and the like, such as N-undecylsulfamoyl, N-undecylmethylsulfamoyl, N-dodecylsulfamoyl, N-dodecylmethylsulfamoyl, N-eicosylsulfamoyl, N-eicosylmethylsulfamoyl, N-tert-butylmethylsulfamoyl, N-phenylmethylsulfamoyl, and the like, and groups represented by the following chemical formulae);

A formylamino group; acetylamino, propionylamino, butyrylamino, 2-dimethylpropionylamino, valerylamino, hexanoylamino, (2-ethyl) hexanoylamino, heptanoylamino, a carbonylamino group (preferably 1 to 12 carbon atoms in the case where the carbonylamino group is an alkanoylamino group), to which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 12 carbon atoms) or a derivative thereof (for example, a derivative thereof such as a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)) is bonded, such as an octanoylamino group, a nonanoylamino group, a decanoylamino group, a undecanoylamino group, a dodecanoylamino group, a heneicosanoylamino group, or a benzoylamino group represented by the following chemical formula;

a hydroxyl group; halogen atoms such as fluorine atom, chlorine atom, bromine atom and iodine atom;

carboxy, -CO₂M²(M²Is an alkali metal, preferably lithium, sodium, potassium); sulfo, -SO₃M²(M²Is an alkali metal, preferably lithium, sodium, potassium); a nitro group; a cyano group;

a formyloxy group; acetoxy, propionyloxy, butyryloxy, 2-dimethylpropionyloxy, pentanoyloxy, hexanoyloxy, (2-ethyl) hexanoyloxy, heptanoyloxy, a carbonyloxy group (preferably 1 to 10 carbon atoms in the case where the carbonyloxy group is an alkanoyloxy group) to which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or a derivative thereof (for example, a derivative thereof such as a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)) is bonded, such as an octanoyloxy group, a nonanoyloxy group, a decanoyloxy group, a undecanoyloxy group, a dodecanoyloxy group, a heneicosanoyloxy group, a benzoyloxy group, and the like, and a group represented by the following chemical formula;

A sulfonyl group having a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like) bonded thereto, such as a methylsulfonyl group, an ethylsulfonyl group, a propylsulfonyl group, a butylsulfonyl group, a pentylsulfonyl group, a hexylsulfonyl group, a (2-ethyl) hexylsulfonyl group, a heptylsulfonyl group, an octylsulfonyl group, a nonylsulfonyl group, a decylsulfonyl group, an undecylsulfonyl group, a dodecylsulfonyl group, an eicosylsulfonyl group, a phenylsulfonyl group, a p-tolylsulfonyl group, or the like represented by the following chemical formula;

a carbamoyl group; n-methylcarbamoyl, N-dimethylcarbamoyl, N-ethylcarbamoyl, N-diethylcarbamoyl, N-propylcarbamoyl, N-dipropylcarbamoyl, N-isopropylcarbamoyl, N-diisopropylcarbamoyl, N-butylcarbamoyl, N-dibutylcarbamoyl, N-isobutylcarbamoyl, N-diisobutylcarbamoyl, N-sec-butylcarbamoyl, N-di-sec-butylcarbamoyl, N-tert-butylcarbamoyl, N-di-tert-butylcarbamoyl, N-pentylcarbamoyl, N-dipentylcarbamoyl, N- (1-ethylpropyl) carbamoyl, N-ethylcarbamoyl, N-diethylcarbamoyl, N-isopropylcarbamoyl, N-diisopropylcarbamoyl, N-isopropylcarbamoyl, N-butylcarbamoyl, N-t-butylcarbamoyl, N-t-butylcarbamoyl, N-N-butylcarbamoyl, N-t-butylcarbamoyl, N-N-butylcarbamoyl, N-t-N-t-butylcarbamoyl, N-t-butylcarbamoyl, N-t, N, N-di (1-ethylpropyl) carbamoyl, N-hexylcarbamoyl, N-dihexylcarbamoyl, N- (2-ethyl) hexylcarbamoyl, N-di (2-ethyl) hexylcarbamoyl, N-heptylcarbamoyl, N-diheptylcarbamoyl, N-octylcarbamoyl, N-dioctylcarbamoyl, N-nonylcarbamoyl, N-octylmethylcarbamoyl, N-octylbutylcarbamoyl, N-dinonylcarbamoyl, N-phenylcarbamoyl, N-diphenylcarbamoyl, N-ethylmethylcarbamoyl, N-propylmethylcarbamoyl, N-ethylmethylcarbamoyl, N-propylmethylcarbamoyl, N-ethylhexylcarbamoyl, N-dihexylcarbamoyl, N- (2-ethyl) hexylcarbamoyl, N-octylcarbamoyl, N-diheptylcarbamoyl, N-octylcarbamoyl, N-nonylcarbamoyl, N-octylcarbamoyl, N-octylmethylcarbamoyl, N-octylcarbamoyl, N-octylmethylcarbamoyl, N-nonylcarbamoyl, N-dimethylcarbamoyl, N, a hydrocarbon group having 1 to 2 carbon atoms of 1 to 20 (preferably 1 to 10 carbon atoms) or a derivative thereof (for example, a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an N, N-isopropylmethylcarbamoyl group, an N, N-butylmethylcarbamoyl group, an N-decylmethylcarbamoyl group, an N, N-decylmethylcarbamoyl group, an N-undecylcarbamoyl group, an N, N-undecylmethylcarbamoyl group, an N-dodecylcarbamoyl group, an N, N-dodecylmethylcarbamoyl group, an N-eicosylcarbamoyl group, an N, N-eicosylmethylcarbamoyl group, an N, N-tert-butylmethylcarbamoyl group, an N, N-phenylmethylcarbamoyl group, etc., and a group represented by the following chemical formula, etc. (preferably a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), a derivative thereof, A carbamoyl group substituted with an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably, an octylsulfamoyl group) or the like;

A hydrocarbon group having 1 to 20 carbon atoms, which is obtained by substituting all hydrogen atoms with fluorine atoms such as a trifluoromethyl group, a perfluoroethyl group, a perfluoropropyl group, a perfluoroisopropyl group, a perfluorobutyl group, a perfluoropentyl group, a perfluorohexyl group, a perfluoroheptyl group, a perfluorooctyl group, a perfluorononyl group, a perfluorodecyl group, a perfluoroundecyl group, a perfluorododecyl group, a perfluoroeicosyl group, a perfluorocyclohexyl group, and a perfluorophenyl group;

a hydrocarbon group having 1 to 20 carbon atoms which has, as a substituent, a linear or branched alkyl group having 1 to 20 carbon atoms in which all hydrogen atoms are substituted with fluorine atoms, such as a perfluoroethylmethyl group, a perfluoropropylmethyl group, a perfluoroisopropylmethyl group, a perfluorobutylmethyl group, a perfluoropentylmethyl group, a perfluorohexylmethyl group, a perfluoroheptylmethyl group, a perfluorooctylmethyl group, a perfluorononylmethyl group, a perfluorodecylmethyl group, a perfluoroundecylmethyl group, a perfluorododecylmethyl group, and a perfluoroeicosylmethyl group;

a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) in which some hydrogen atoms are substituted with fluorine, such as a 2-fluorophenyl group, a 3-fluorophenyl group, a 4-fluorophenyl group, and a 2,4, 6-trifluorophenyl group;

-CO-SH、-CO-S-CH₃、-CO-S-CH₂CH₃、-CO-S-CH₂-CH₂-CH₃and-CO-S-CH₂-CH₂-CH₂-CH₃Or a thiocarbonyl group, -CO-S-C, bonded to an alkyl group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) ₆H₅A thiocarbonyl group bonded to an aryl group having 6 to 20 carbon atoms;

a group represented by the following chemical formula, — COCO-R (wherein R represents a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)), or the like);

-NRCONR represented by the following chemical formula₂(wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group having 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like), and R's may be the same or different from each other and may be bonded to each other to form a ring);

OCONR represented by the following chemical formula₂(wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group having 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereof with a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc.), and R's may be the same or different from each other, and may be mutually different Bonded to form a ring);

a group represented by the following chemical formula-NRCOOR (wherein R represents a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like), wherein R may be the same or different from each other, and may be bonded to each other to form a ring);

*-OP(O)(OCH₃)₂etc.. OP (O) (OR)₂(wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group having 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like), and R's may be the same or different from each other and may be bonded to each other to form a ring);

*-Si(CH₃)₃、*-Si(CH₂CH₃)₃、*-Si(C₆H₅)₃and-Si (CH)₃)₂)₃Etc. -SiR₃(wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group having 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like), and R's may be the same or different from each other and may be bonded to each other to form a ring); and so on.

Examples of the substituent having a valence of 2 include an oxo group, a thioxo group, an imino group substituted with an alkyl group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms), and an imino group substituted with an aryl group having 6 to 20 carbon atoms. Examples of the imino group substituted with an alkyl group include CH₃-N＝、CH₃-CH₂-N＝、CH₃-(CH₂)₂-N ═ and CH₃-(CH₂)₃-N ═ and the like. Examples of the imino group substituted with an aryl group include C₆H₅-N ═ and the like.

As the substituent of the hydrocarbon group having 1 to 40 carbon atoms, preferred is a substituent of group s 1. The derivative group shown below is preferably a derivative group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like.

[ group s1]

An oxy group having a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof bonded to one side thereof;

a carbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof is bonded;

an oxycarbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof is bonded;

an amino group; amino substituted by 1 or 2 alkyl with 1-20 carbon atoms or derivative groups thereof; a sulfamoyl group; a sulfamoyl group substituted with 1 or 2 hydrocarbon groups having 1 to 20 carbon atoms or derivative groups thereof; a carbonylamino group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof is bonded; a hydroxyl group; a halogen atom; -CO ₂M (preferably carboxyl group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom); -SO₃M (preferably sulfo) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom); a nitro group; a cyano group; a carbonyloxy group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof is bonded; a sulfonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof is bonded; a carbamoyl group; carbamoyl substituted by 1 or 2 hydrocarbon groups having 1 to 20 carbon atoms or derivative groups thereof; fluorine atomA hydrocarbon group having 1 to 20 carbon atoms, wherein all hydrogen atoms are substituted; a hydrocarbon group having 1 to 20 carbon atoms, which has a linear or branched alkyl group having 1 to 20 carbon atoms, wherein all hydrogen atoms are substituted with fluorine atoms, as a substituent; a hydrocarbon group having 1 to 20 carbon atoms, wherein a part of hydrogen atoms is substituted with fluorine; an oxo group.

The substituent of the hydrocarbon group having 1 to 40 carbon atoms is more preferably a substituent of group s 2.

[ group s2]

An oxy group having a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof bonded to one side thereof;

a carbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded;

an oxycarbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded;

An amino group; an amino group substituted with 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms;

a sulfamoyl group; a sulfamoyl group substituted with 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms or derivative groups thereof; a carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded; a hydroxyl group; fluorine atom, chlorine atom, bromine atom; -CO₂M (preferably carboxyl group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom); -SO₃M (preferably sulfo) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom); a nitro group; a cyano group; a carbonyloxy group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded; a sulfonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded; a carbamoyl group; carbamoyl substituted by 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms or derivative groups thereof; a hydrocarbon group having 1 to 10 carbon atoms, wherein all hydrogen atoms are substituted with fluorine atoms; a hydrocarbon group having 1 to 10 carbon atoms, which has a linear or branched alkyl group having 1 to 10 carbon atoms, wherein all hydrogen atoms are substituted with fluorine atoms, as a substituent;

a hydrocarbon group having 1 to 10 carbon atoms, wherein a part of hydrogen atoms is substituted with fluorine; an oxo group.

As R^N1Z5、R^1Z5、R^2Z5、R^3Z5、R^4Z5、R^5Z5、R^6Z5、R^7Z5、R^101Z5And R^102Z5The hydrocarbon group having 1 to 40 carbon atoms and having a substituent represented by the formula (I) includes a hydrocarbon group having 1 to 40 carbon atoms and having a substituent having a valence of 1 or 2, preferably a saturated or unsaturated chain hydrocarbon group having 1 to 30 carbon atoms and having a substituent having a valence of 1 or 2, a saturated or unsaturated alicyclic hydrocarbon group having 3 to 30 carbon atoms and having a substituent having a valence of 1 or 2, an aromatic hydrocarbon group having 6 to 30 carbon atoms and having a substituent having a valence of 1 or 2, and a group having 1 to 30 carbon atoms and having a substituent having a valence of 1 or 2, which are a combination of hydrocarbon groups,

more preferably, the hydrocarbon group includes a saturated or unsaturated chain hydrocarbon group having 1 to 20 carbon atoms having a substituent of group s1, a saturated or unsaturated alicyclic hydrocarbon group having 3 to 20 carbon atoms having a substituent of group s1, an aromatic hydrocarbon group having 6 to 20 carbon atoms having a substituent of group s1, or a combination of hydrocarbon groups having 1 to 20 carbon atoms having a substituent of group s1,

particularly preferred examples thereof include a saturated or unsaturated chain hydrocarbon group having 1 to 15 carbon atoms having a substituent of group s2, a saturated or unsaturated alicyclic hydrocarbon group having 3 to 15 carbon atoms having a substituent of group s2, an aromatic hydrocarbon group having 6 to 15 carbon atoms having a substituent of group s2, or a group having 1 to 15 carbon atoms having a substituent of group s2, which is a combination of hydrocarbon groups.

As R^N1Z5、R^1Z5、R^2Z5、R^3Z5、R^4Z5、R^5Z5、R^6Z5、R^7Z5、R^101Z5And R^102Z5The heterocyclic group represented by (a) may be monocyclic or polycyclic, and is preferably a heterocyclic ring containing a heteroatom as a constituent of the ring. Examples of the hetero atom include a nitrogen atom, an oxygen atom, a sulfur atom and the like.

The number of carbon atoms of the heterocyclic group is preferably 3 to 30, more preferably 3 to 22, further preferably 3 to 20, further preferably 3 to 18, further more preferably 3 to 15, and particularly preferably 3 to 14.

Examples of the heterocyclic ring containing a nitrogen atom include:

monocyclic saturated heterocycles such as aziridine, azetidine, pyrrolidine, piperidine and piperazine; five-membered ring system unsaturated heterocycles such as pyrrole (e.g., 2, 5-dimethylpyrrole), pyrazole (e.g., 2-methylpyrazole and 3-methylpyrazole), imidazole, 1,2, 3-triazole and 1,2, 4-triazole;

a six-membered ring system unsaturated heterocycle such as pyrimidine, pyrazine and 1,3, 5-triazine, for example pyridine, pyridazine and 6-methylpyrimidine;

a fused bicyclic heterocycle such as quinoxaline (e.g., indazole, indoline, isoindoline, indole, indolizine, benzimidazole, quinoline, isoquinoline, 5,6,7, 8-tetrahydro (3-methyl) quinoxaline or 3-methylquinoxaline, quinazoline, cinnoline, phthalazine, naphthyridine, purine, pteridine, benzopyrazole or phenylpiperidine; condensed tricyclic heterocycles such as carbazole, acridine and phenazine; and so on.

Examples of the heterocyclic ring containing an oxygen atom include:

monocyclic saturated heterocycles such as oxetane, tetrahydrofuran, tetrahydropyran, 1, 3-dioxane, 1, 4-dioxane and 1-cyclopentyldioxolane; bicyclic saturated heterocycles such as 1, 4-dioxaspiro [4.5] decane and 1, 4-dioxaspiro [4.5] nonane; lactone heterocycles such as α -caprolactone, β -propiolactone, γ -butyrolactone, γ -valerolactone and δ -valerolactone; five-membered ring system unsaturated heterocycles such as furan (e.g., 2, 3-dimethylfuran, 2, 5-dimethylfuran); a six-membered ring system unsaturated heterocycle such as 2H-pyran, 4H-pyran; fused bicyclic heterocycles such as benzopyrans (e.g., 1-benzofuran and 4-methylbenzopyran), benzodioxole, chroman and isochroman; fused tricyclic heterocycles such as xanthene and dibenzofuran; and so on.

Examples of the heterocyclic ring containing a sulfur atom include:

five-membered ring system saturated heterocycles such as dithiolane;

saturated heterocyclic rings of six-membered ring systems such as thiacyclohexane, 1, 3-dithiane, 2-methyl-1, 3-dithiane and the like;

a five-membered ring system unsaturated heterocycle such as thiophene (e.g., 3-methylthiophene, 2-carboxythiophene), benzothiopyran (e.g., 4H-thiopyran, tetrahydrothiopyran);

fused bicyclic heterocycles such as benzothiophene; fused tricyclic heterocycles such as thianthrene and dibenzothiophene; and so on.

Examples of the heterocyclic ring containing a nitrogen atom and an oxygen atom include monocyclic saturated heterocyclic rings such as morpholine, 2-pyrrolidone, 2-methyl-2-pyrrolidone, 2-piperidone and 2-methyl-2-piperidone; a monocyclic unsaturated heterocycle such as oxazole (e.g., 4-methyloxazole), isoxazole (e.g., 2-methylisoxazole, and 3-methylisoxazole); fused bicyclic heterocycles such as benzoxazole, benzisoxazole, benzoxazine, benzodioxane, and benzimidazoline; condensed tricyclic heterocycles such as phenoxazine; and so on.

Examples of the heterocyclic ring containing a nitrogen atom and a sulfur atom include monocyclic heterocyclic rings such as thiazoles, e.g., 3-methylthiazole and 2, 4-dimethylthiazole; fused bicyclic heterocycles such as benzothiazole; fused tricyclic heterocycles such as phenothiazine; and so on.

The heterocyclic ring may be a combination of the above-mentioned hydrocarbon groups, and examples thereof include tetrahydrofurylmethyl and the like.

The heterocyclic ring may be a heterocyclic ring represented by the following chemical formula.

The above heterocyclic group may be R^1Z5～R^5Z52 or more of them are bonded to form a heterocyclic group. Such heterocyclic radicals contain R^1Z5～R^5Z5The bonded benzene ring has a ring structure of 2 or more rings inside. The 2 or more ring structures include, for example, the structures of the following chemical formulae.

The bonding position of the heterocycle is a portion where any hydrogen atom contained in each ring is removed.

R^N1Z5、R^1Z5、R^2Z5、R^3Z5、R^4Z5、R^5Z5、R^6Z5、R^7Z5、R^101Z5And R^102Z5The heterocyclic group represented may have a substituent. Examples of the substituent include^N1Z5、R^1Z5、R^2Z5、R^3Z5、R^4Z5、R^5Z5、R^6Z5、R^7Z5、R^101Z5And R^102Z5The hydrocarbon group may have the same substituent as the substituent. In addition, in the case where the above-mentioned heterocyclic ring contains a nitrogen atom as its constituent element, the above-mentioned hydrocarbon group as a substituent may be bonded to the nitrogen atom. Preferred examples of the substituent include^N1Z5、R^1Z5、R^2Z5、R^3Z5、R^4Z5、R^5Z5、R^6Z5、R^7Z5、R^101Z5And R^102Z5The preferable examples of the substituents which the hydrocarbon group may have are the same.

As R^N1Z5、R^1Z5、R^2Z5、R^3Z5、R^4Z5、R^5Z5、R^6Z5、R^7Z5、R^101Z5And R^102Z5The heterocyclic group having a substituent represented by the formula (i) includes a heterocyclic group having a substituent having a valence of 1 or 2, preferably a heterocyclic group having a substituent of group s1, and more preferably a heterocyclic group having a substituent of group s 2.

The substituent (first substituent) that the hydrocarbon group or heterocyclic group may have may be 1 or 2 or more, and 2 or more substituents may be the same or different and independent of each other. As for the above-mentioned first substituent, another substituent (second substituent) may be bonded to the hydrocarbon group contained in a part thereof. The second substituent may be selected from the same groups as the first substituent.

Below, for R^N1Z5、R^1Z5、R^2Z5、R^3Z5、R^4Z5、R^5Z5、R^6Z5And R^7Z5Of (a) is-CO-R^102Z5、-COO-R^101Z5、-OCO-R^102Z5、-COCO-R^102Z5、-O-R^102Z5、-SO₂-R^101Z5、-SO₂N(R^102Z5)₂、-CON(R^102Z5)₂、-N(R^102Z5)₂、-NHCO-R^102Z5、-NHCO-N(R^102Z5)₂、-NHCOOR^102Z5、-OCON(R^102Z5)₂Halogen atom, -SO₃M、-CO₂M is explained.

as-CO-R^102Z5Examples thereof include a formyl group; acetyl, propionyl, butyryl, 2-dimethylpropionyl, pentanoyl, hexanoyl, (2-ethyl) hexanoyl, heptanoyl, examples of the carbonyl group include a carbonyl group (in the case where the carbonyl group is an acyl group, the number of carbon atoms is 2 to 41) in which a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)) is bonded, such as an octanoyl group, a nonanoyl group, a decanoyl group, a undecanoyl group, a dodecanoyl group, an heneicosanoyl group, and a benzoyl group, and the compounds shown in tables 1Z5 to 7Z5 and 10Z5 to 13Z5 correspond to — CO — R.^102Z5Preferable examples of the group(s) include a carbonyl group (more preferably 2 to 12 carbon atoms when the carbonyl group is an alkanoyl group) to which a hydrocarbon group having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms) or a derivative thereof is bonded, and compounds shown in tables 1Z5 to 7Z5 and tables 10Z5 to 13Z5 correspond to-CO-R ^102Z5And the like.

as-COO-R^101Z5Examples thereof include methoxycarbonyl, ethoxycarbonyl, propoxycarbonyl, tert-butoxycarbonyl, pentyloxycarbonyl, hexyloxycarbonyl, (2-ethyl) hexyloxycarbonyl, heptyloxycarbonyl, octyloxycarbonyl, nonyloxycarbonyl, decyloxycarbonyl, undecyloxycarbonyl, dodecyloxycarbonyl, phenyloxycarbonyl, eicosyloxycarbonyl and the like, and hydrocarbyl groups having 1 to 40 (preferably 1 to 20) carbon atoms or derived groups thereof (for example, through carboxyl, sulfo, nitro, hydroxyl, halogen (preferably chlorine atom), alkylaminosulfonyl groups having 1 to 10 carbon atoms (preferably through carboxyl, sulfo, nitro, hydroxyl, halogen (preferably chlorine atom)) are bonded to groups represented by the above formulaeOctyl sulfamoyl) and the like) and the corresponding-COO-R in the compounds shown in tables 1Z5 to 7Z5 and tables 10Z5 to 13Z5^102Z5Preferred examples of the group (b) include oxycarbonyl groups to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded, and compounds shown in tables 1Z5 to 7Z5 and tables 10Z5 to 13Z5 which correspond to-COO-R^102Z5And the like.

as-OCO-R^102Z5Examples thereof include a formyloxy group; acetoxy, propionyloxy, butyryloxy, 2-dimethylpropionyloxy, pentanoyloxy, hexanoyloxy, (2-ethyl) hexanoyloxy, heptanoyloxy, octanoyloxy, nonanoyloxy, decanoyloxy, undecanoyloxy, dodecanoyloxy, heneicosanoyloxy, benzoyloxy and the like, carbonyloxy (having 2 to 41 carbon atoms in the case where the carbonyloxy group is an acyloxy group), carbonyloxy having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) bonded to a group represented by the above formula) and the like, And those shown in tables 1Z5 to 7Z5 and tables 10Z5 to 13Z5 correspond to-OCO-R ^102Z5Preferable examples of the group(s) include a carbonyloxy group (more preferably 2 to 12 carbon atoms when the carbonyloxy group is an acyloxy group) to which a hydrocarbon group having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms) or a derivative thereof is bonded, and a compound represented by any one of tables 1Z5 to 7Z5 and tables 10Z5 to 13Z5 corresponds to-OCO-R^102Z5And the like.

as-COCO-R^102Z5Examples thereof include methyloxalyl, ethyloxalyl, propyloxalyl, butyloxalyl, pentyloxalyl, hexyloxalyl, (2-ethyl) hexyloxalyl, heptyloxalyl, octyloxalyl, nonyloxalyl, decyloxyl, undecyloxalyl, dodecyloxalyl, eicosanoyl, cyclopentyloxalyl, cyclohexyloxalyl, phenyloxalyl, p-tolyloxalyl and the like,And oxalyl groups in which a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a derivative thereof with a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) is bonded to a group represented by the above formula, and compounds represented by tables 1Z5 to 7Z5 and tables 10Z5 to 13Z5 corresponding to-COCO-R ^102Z5And the like.

as-O-R^102Z5Examples of the group include a hydroxyl group; methoxy, ethoxy, propoxy, isopropoxy, butoxy, isobutoxy, sec-butoxy, tert-butoxy, pentyloxy, hexyloxy, heptyloxy, octyloxy, nonyloxy, decyloxy, undecyloxy, dodecyloxy, (2-ethyl) hexyloxy, eicosyloxy, 1-phenylethoxy, 1-methyl-1-phenylethoxy, phenyloxy, 2, 3-dimethylphenyloxy, 2, 4-dimethylphenyloxy, 2, 5-dimethylphenyloxy, 2, 6-dimethylphenyloxy, 3, 4-dimethylphenyloxy, 3, 5-dimethylphenyloxy, 2-dicyanophenyloxy, 2, 3-dicyanophenyloxy, 2, 4-dicyanophenyloxy, sec-butyloxy, tert-butyloxy, pentyloxy, hexyloxy, heptyloxy, octyloxy, decyloxy, 2, 3-dimethylphenyloxy, 2, 4-dimethylphenyloxy, 2, 4-dimethylphenyloxy, 3-dimethylphenyloxy, 2-dicyanophenyloxy, 2, 4-di-yloxy, 2-di-methyl-1-phenylethoxy, 2, 4-di-methyl, and mixtures thereof, 2, 5-dicyanophenyloxy group, 2, 6-dicyanophenyloxy group, 3, 4-dicyanophenyloxy group, 3, 5-dicyanophenyloxy group, 4-methoxyphenyloxy group, 2-methoxyphenyloxy group, examples of the oxygen group include an oxygen group having a hydrocarbyl group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like bonded thereto, such as a 3-methoxyphenyloxy group, a 4-ethoxyphenyloxy group, a 2-ethoxyphenyloxy group, a 3-ethoxyphenyloxy group, or the like, and a group represented by the above chemical formulae), and compounds shown in tables 1Z5 to 7Z5 and tables 10Z5 to 13Z5 correspond to — O — R. ^102Z5Preferred examples of the group (b) include an oxy group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded, and compounds shown in tables 1Z5 to 7Z5 and tables 10Z5 to 13Z5, which correspond to-O-R^102Z5And the like.

as-SO₂-R^101Z5Examples thereof include methylsulfonyl, ethylsulfonyl, propylsulfonyl, butylsulfonyl, pentylsulfonyl, hexylsulfonyl, (2-ethyl) hexylsulfonyl, heptylsulfonyl, octylsulfonyl, nonyl sulfonyl, decyl sulfonyl, undecyl sulfonyl, dodecyl sulfonyl, eicosyl sulfonyl, phenyl sulfonyl, p-tolyl sulfonyl, and the like, and sulfonyl groups in which a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like is bonded, such as the group represented by the above chemical formula, and-SO corresponds to the compounds shown in tables 1Z5 to 7Z5 and tables 10Z5 to 13Z 5.₂-R^102Z5Preferable examples of the group (b) include sulfonyl groups to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded, and compounds represented by tables 1Z5 to 7Z5 and tables 10Z5 to 13Z5, which correspond to-SO ₂-R^102Z5And the like.

as-SO₂N(R^102Z5)₂Examples thereof include:

a sulfamoyl group; n-methylsulfamoyl, N-ethylsulfamoyl, N-propylsulfamoyl, N-isopropylsulfamoyl, N-butylsulfamoyl, N-isobutylsulfamoyl, N-sec-butylsulfamoyl, N-tert-butylsulfamoyl, N-pentylsulfamoyl, N- (1-ethylpropyl) sulfamoyl, N-hexylsulfamoyl, N- (2-ethyl) hexylsulfamoyl, N-heptylsulfamoyl, N-octylsulfamoyl, N-nonylsulfamoyl, N-decylsulfamoyl, N-undecylsulfamoyl, N-dodecylsulfamoyl, N-eicosylsulfamoyl, N-phenylsulfamoyl, etc., and a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group represented by the above formula, or a derivative thereof Sulfamoyl groups substituted with a raw group (e.g., a group derived from carboxyl group, sulfo group, nitro group, hydroxyl group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group)), and compounds shown in tables 1Z5 to 7Z5 and tables 10Z5 to 13Z5 correspond to the above groups-SO₂NH(R^102Z5X) (wherein, R^102Z5XIs not a hydrogen atom, other than, and R^102Z5The same as defined above), etc.;

N, N-dimethylsulfamoyl, N-ethylmethylsulfamoyl, N-diethylsulfamoyl, N-propylmethylsulfamoyl, N-dipropylsulfamoyl, N-isopropylmethylsulfamoyl, N-diisopropylsulfamoyl, N-tert-butylmethylsulfamoyl, N-diisobutylsulfamoyl, N-di-sec-butylsulfamoyl, N-di-tert-butylsulfamoyl, N-butylmethylsulfamoyl, N-dibutylsulfamoyl, N-dipentylsulfamoyl, N-bis (1-ethylpropyl) sulfamoyl, N-dihexylsulfamoyl, N-bis (2-ethyl) hexylsulfamoyl, N-diethylsulfamoyl, N, N-diheptylsulfamoyl, N-octylmethylsulfamoyl, N-dioctylsulfamoyl, N-dinonylsulfamoyl, N-decylmethylsulfamoyl, N-undecylmethylsulfamoyl, N-dodecylmethylsulfamoyl, N-eicosylmethylsulfamoyl, N-phenylmethylsulfamoyl, N-diphenylsulfamoyl and the like, and sulfamoyl groups represented by the above chemical formulae and the like substituted with a hydrocarbon group having 1 to 40 (preferably 1 to 20) carbon atoms or a derivative thereof (for example, a derivative derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl) and the like), and sulfamoyl groups shown in tables 1Z5 to 7Z5 and tables 10Z5 to 13Z5 Corresponding to-SO in the compound ₂N(R^102Z5X)₂(wherein, R^102Z5XIs not a hydrogen atom, other than, and R^102Z5The same as defined above) and the like,

preferred examples thereof include sulfamoyl groups substituted with 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms or derivatives thereof, and compounds represented by tables 1Z5 to 7Z5 and tables 10Z5 to 13Z5, which correspond to-SO₂N(R^102Z5)₂And the like.

as-CON (R)^102Z5)₂Examples thereof include:

a carbamoyl group; n-methylcarbamoyl, N-ethylcarbamoyl, N-propylA hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a carboxyl group, an N-isopropylcarbamoyl group, an N-butylcarbamoyl group, an N-isobutylcarbamoyl group, an N-sec-butylcarbamoyl group, an N-tert-butylcarbamoyl group, an N-pentylcarbamoyl group, an N- (1-ethylpropyl) carbamoyl group, an N-hexylcarbamoyl group, an N- (2-ethyl) hexylcarbamoyl group, an N-heptylcarbamoyl group, an N-octylcarbamoyl group, an N-nonylcarbamoyl group, an N-decylcarbamoyl group, an N-undecylcarbamoyl group, an N-dodecylcarbamoyl group, an N-eicosylcarbamoyl group, an N-phenylcarbamoyl group and the like, and a group represented by the above chemical formula A carbamoyl group substituted with a group derived from sulfo, nitro, hydroxy, halogen (preferably chlorine atom), alkylsulfamoyl having 1 to 10 carbon atoms (preferably octylsulfamoyl), or the like), and a compound shown in tables 1Z5 to 7Z5 and tables 10Z5 to 13Z5 corresponds to-CONH (R is ^102Z5X) (wherein, R^102Z5XIs not a hydrogen atom, other than, and R^102Z5The same as defined above), etc.;

n, N-dimethylcarbamoyl group, N-ethylmethylcarbamoyl group, N-diethylcarbamoyl group, N-propylmethylcarbamoyl group, N-dipropylcarbamoyl group, N-isopropylmethylcarbamoyl group, N-diisopropylcarbamoyl group, N-tert-butylmethylcarbamoyl group, N-diisobutylcarbamoyl group, N-di-sec-butylcarbamoyl group, N-di-tert-butylcarbamoyl group, N-butylmethylcarbamoyl group, N-dibutylcarbamoyl group, N-butyloctylcarbamoyl group, N-dipentylcarbamoyl group, N-di (1-ethylpropyl) carbamoyl group, N-diethylcarbamoyl group, N-diisopropylcarbamoyl group, N-di (1-ethylpropyl) carbamoyl group, N-t-butylmethylcarbamoyl group, N-di-butylmethylcarbamoyl group, N-t-butylmethylcarbamoyl group, N-di (1-ethylpropyl) carbamoyl group, N-t-butylmethylcarbamoyl group, N-di-isobutylcarbamoyl group, N-di (s-butylmethylcarbamoyl group, N-di-butylmethylcarbamoyl group, N-di-N-butylcarbamoyl group, N, n, N-dihexylcarbamoyl group, N-di (2-ethyl) hexylcarbamoyl group, N-diheptylcarbamoyl group, N-octylmethylcarbamoyl group, N-dioctylcarbamoyl group, N-dinonylcarbamoyl group, N-decylmethylcarbamoyl group, N-undecylmethylcarbamoyl group, N-dodecylmethylcarbamoyl group, N-eicosylmethylcarbamoyl group, N-phenylmethylcarbamoyl group, N-diphenylcarbamoyl group, etc., and the above Carbamoyl groups such as the group represented by the above chemical formula, which are substituted with 2C 1-40 (preferably C1-20) hydrocarbon groups or derivative groups thereof (e.g., groups derived from carboxyl, sulfo, nitro, hydroxyl, halogen (preferably chlorine atom), C1-10 alkylsulfamoyl (preferably octylsulfamoyl), etc.), and compounds shown in tables 1Z 5-7Z 5 and tables 10Z 5-13Z 5 which correspond to-CON (R)^102Z5X)₂(R^102Z5XIs not a hydrogen atom, other than, and R^102Z5The same as defined above) and the like,

preferred examples thereof include a carbamoyl group substituted with 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms or a derivative thereof and a compound represented by any one of tables 1Z5 to 7Z5 and 10Z5 to 13Z5 which corresponds to-CON (R)^102Z5)₂And the like.

as-N (R)^102Z5)₂Examples thereof include:

an amino group; a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom)), such as an N-methylamino group, an N-ethylamino group, an N-propylamino group, an N-isopropylamino group, an N-butylamino group, an N-isobutylamino group, an N-sec-butylamino group, an N-tert-butylamino group, an N-pentylamino group, an N-hexylamino group, an N- (2-ethyl) hexylamino group, an N-heptylamino group, an N-octylamino group, an N-nonylamino group, an N-decylamino group, an N-undecylamino group, an N-dodecylamino group, an N-eicosylamino group, an N-phenylamino group, and the like, and a group represented by the above chemical formula, A group derived from an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably, an octylsulfamoyl group) or the like) and a compound shown in tables 1Z5 to 7Z5 and 10Z5 to 13Z5, wherein the compound corresponds to-NH (R ^102Z5X)(R^102Z5XIs not a hydrogen atom, other than, and R^102Z5The same as defined above), etc.;

n, N-dimethylamino group, N-ethylmethylamino group, N-diethylamino group, N-propylmethylamino group, N-dipropylamino group, N-isopropylmethylamino group, N-diisopropylamino group, N-t-butylmethylamino group, N-diisobutylamino groupA hydrocarbon group having 2 carbon atoms of 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a carboxyl group, a di-sec-butylamino group, an N, N-di-tert-butylamino group, an N, N-butylmethylamino group, an N, N-dibutylamino group, an N, N-dipentylamino group, an N, N-di (1-ethylpropyl) amino group, an N, N-dihexylamino group, an N, N-di (2-ethyl) hexylamino group, an N, N-diheptylamino group, an N, N-dioctylamino group, an N, N-dinonylamino group, an N, N-decylmethylamino group, an N, N-undecylmethylamino group, an N, N-dodecylmethylamino group, an N, N-eicosylmethylamino group, an N, N-phenylmethylamino group, an N, N-diphenylamino group, etc., and a group represented by the above chemical formula, A derivative of sulfo, nitro, hydroxy, halogen (preferably chlorine atom), alkylsulfamoyl having 1 to 10 carbon atoms (preferably octylsulfamoyl), or the like) and a compound shown in tables 1Z5 to 7Z5 and 10Z5 to 13Z5, wherein the compound corresponds to-N (R ^102Z5X)₂(wherein, R^102Z5XIs not a hydrogen atom, other than, and R^102Z5The same as defined above) and the like,

preferred examples thereof include amino groups substituted with 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms or derivatives thereof and compounds shown in tables 1Z5 to 7Z5 and tables 10Z5 to 13Z5 which correspond to-N (R)^102Z5)₂And the like.

as-NHCO-R^102Z5Examples thereof include formylamino; acetylamino, propionylamino, butyrylamino, 2-dimethylpropionylamino, valerylamino, hexanoylamino, (2-ethyl) hexanoylamino, heptanoylamino, a carbonylamino group (in the case where the carbonylamino group is an acylamino group, the carbon number is 1 to 40), wherein a hydrocarbon group having 1 to 40 (preferably 1 to 20) carbon atoms or a derivative thereof (for example, a derivative thereof such as a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) is bonded to an octanoylamino group, a nonanoylamino group, a decanoylamino group, a undecanoylamino group, a dodecanoylamino group, a heneicosanoylamino group, a benzoylamino group, or the like, or a group represented by the above chemical formula), and tables 1Z5 to 7Z5 and tables. 10Z5 to Table 13Z5 correspond to-NHCO-R^102Z5And the like,

preferred examples thereof include carbonylamino groups to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded (in the case where the carbonylamino group is an alkanoylamino group, the carbon number is more preferably 1 to 10), and compounds represented by tables 1Z5 to 7Z5 and tables 10Z5 to 13Z5, which correspond to-NHCO-R^102Z5And the like.

as-NHCON (R)^102Z5)₂Examples thereof include the groups listed above and the compounds shown in tables 1Z5 to 7Z5 and tables 10Z5 to 13Z5 which correspond to-NHCON (R)^102Z5)₂And the like.

as-NHCOOR^102Z5Examples thereof include those corresponding to-NHCOOR among the above-mentioned groups and the compounds shown in tables 1Z5 to 7Z5 and tables 10Z5 to 13Z5^102Z5And the like.

as-OCON (R)^102Z5)₂Examples thereof include those corresponding to-OCON (R) among the above-mentioned groups and the compounds shown in tables 1Z5 to 7Z5 and tables 10Z5 to 13Z5^102Z5)₂And the like.

The halogen atom is preferably a fluorine atom, a chlorine atom, a bromine atom, an iodine atom or the like.

as-SO₃M and-CO₂M in M is a hydrogen atom; the alkali metal atom such as lithium atom, sodium atom and potassium atom, preferably hydrogen atom, sodium atom and potassium atom.

The above-mentioned-CO-R^102Z5、-COO-R^102Z5、-OCO-R^102Z5、-COCO-R^102Z5、-O-R^102Z5、-SO₂-R^102Z5、-SO₂N(R^102Z5)₂、-CON(R^102Z5)₂、-N(R^102Z5)₂、-NHCO-R^102Z5、-NHCON(R^102Z5)₂、-NHCOOR^102Z5、-OCON(R^102Z5)₂The number of the substituents (first substituents) contained in (2) may be 1 or 2 or more, and 2 or more substituents may be the same or different and independent of each other.

Further, the first substituent may have another substituent (second substituent) bonded to the hydrocarbon group included in a part thereof. The second substituent may be selected from the same groups as the first substituent.

R^2Z5And R^3Z5、R^3Z5And R^4Z5And R^4Z5And R^5Z5The ring formed is fused with the benzene ring of the isoindoline skeleton of the compound represented by the formula (IZ 5). As R^2Z5And R^3Z5、R^3Z5And R^4Z5And R^4Z5And R^5Z5Examples of the condensed ring structure of the ring formed and the benzene ring include indene, naphthalene, biphenylene, indacene, acenaphthylene, fluorene, phenalene, phenanthrene, anthracene, fluoranthene, acephenanthrene, aceanthrylene, and benzo [9,10 ] ene]Phenanthrene, pyrene,

Hydrocarbon-based condensed ring structures such as N-methylphthalimide, N- (1-phenylethyl) phthalimide and butachlor, and partially reduced products thereof (for example, 9, 10-dihydroanthracene, 1,2,3, 4-tetrahydronaphthalene, etc.); indole, isoindole, indazole, quinoline, isoquinoline, phthalazine, quinoxaline, quinazoline, cinnoline, carbazole, carboline, phenanthridine, acridine, quinoline, quinoxaline, quinoline, and/or quinoline derivative,

Nitrogen-containing fused heterocycles such as pyridine, phenanthroline, and phenazine, and partial reductants thereof; oxygen-containing fused heterocycles such as 3-hydrobenzofuran-2-one and partial reductants thereof.

R^2Z5And R^3Z5、R^3Z5And R^4Z5And R^4Z5And R^5Z5In the case of forming a ring, the ring may have a substituent. Examples of the substituent include ^N1Z5、R^1Z5、R^2Z5、R^3Z5、R^4Z5、R^5Z5、R^6Z5、R^7Z5、R^101Z5And R^102Z5The hydrocarbon group may have the same substituent as the substituent. Preferred examples of the substituent include^N1Z5、R^1Z5、R^2Z5、R^3Z5、R^4Z5、R^5Z5、R^6Z5、R^7Z5、R^101Z5And R^102Z5The preferable examples of the substituents which the hydrocarbon group may have are the same.

R^3Z5And R^4Z5When forming a ring, as R^2Z5And R^5Z5Independently of one another, hydrogen atoms, amino groups and hydroxyl groups are preferred.

R^2Z5And R^3Z5When a ring is formed, R is preferably^4Z5And R^5Z5Does not form a ring, more preferably R^4Z5And R^5Z5Is a hydrogen atom.

R^4Z5And R^5Z5When a ring is formed, R is preferably^2Z5And R^3Z5Does not form a ring, more preferably R^2Z5And R^3Z5Is a hydrogen atom. R^1Z5、R^6Z5And R^7Z5Preferably a hydrogen atom.

R^N1Z5preferably-CO-R^102Z5、-COO-R^101Z5、-CON(R^102Z5)₂、-N(R^102Z5)₂、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, more preferably a hydrocarbon group having 1 to 30 carbon atoms which may have a substituent, still more preferably a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent, particularly preferably a hydrocarbon group having 1 to 15 carbon atoms which may have a substituent, particularly preferably a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent, particularly preferably a hydrocarbon group having 1 to 6 carbon atoms which may have a substituent or a hydrocarbon group having 1 to 5 carbon atoms which may have a substituent, still more preferably a methyl group, an ethyl group or a phenyl group, and most preferably a methyl group or an ethyl group.

From the viewpoint of reducing the retardation value of the color filter formed from the colored composition, R is preferable^2Z5、R^3Z5、R^4Z5And R^5Z5At least one of which is-CO-R^102Z5、-COO-R^101Z5、-OCO-R^102Z5、-COCO-R^102Z5、-O-R^102Z5、-SO₂-R^101Z5、-SO₂N(R^102Z5)₂、-CON(R^102Z5)₂、-N(R^102Z5)₂、-NHCO-R^102Z5、-NHCO-N(R^102Z5)₂、-NHCOOR^102Z5、-OCON(R^102Z5)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent, more preferably a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a halogen atom, -N (R)^102Z5)₂A C1-20 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R^102Z5、-O-R^102Z5、-SO₃M or-CO₂M is more preferably a nitro group or a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, and still more preferably a nitro group or a tert-butyl group. Alternatively, R is preferred^2Z5And R^3Z5、R^3Z5And R^4Z5Or R^4Z5And R^5Z5Form a ring.

From the viewpoint of reducing the retardation value of the color filter formed from the colored composition, R is preferable^2Z5、R^3Z5、R^4Z5And R^5Z5At least one of which is an optionally substituted hydrocarbon group having 1 to 40 carbon atoms, a halogen atom, or-N (R)^102Z5)₂A C1-20 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R^102Z5、-O-R^102Z5、-SO₃M or-CO₂M，

More preferably a nitro group or a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, and still more preferably a nitro group or a tert-butyl group. Among them, it is still more preferable that R ^3Z5Is nitro or tert-butyl, R^2Z5、R^4Z5And R^5Z5Is a hydrogen atom; or, R^2Z5、R^3Z5And R^5Z5Is a hydrogen atom, R^4Z5Is nitro or tert-butyl.

Specific examples of compound IZ5 include compounds IZ5-1 to IZ5-1 having substituents shown in table 1Z5, table 2Z5, table 3Z5, table 4Z5, table 5Z5, table 6Z5, table 7Z5, and table 10Z5 to table 13Z5 in formula (IZ5-aa)IZ5-542 or an alkali metal salt thereof. B is^a1Z5B^a2Z5The partial structure represented by any one of formulae (BB2) to (BB60), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1), formula (BBO8), formula (BBO10), formula (BBD1) and formula (BBJ2) is shown. The formulae (BB2) to (BB60), (BBK2), (BBK3), (BBK4), (BBK14), (BBI1), (BBO8), (BBO10), (BBD1) and (BBJ2) are the same as B representing formula (IZ1-aa)^a1Z1B^a2Z1The same structures as (BB2) to (BB60), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1), formula (BBO8), formula (BBO10), formula (BBD1) and formula (BBJ2) described above. B is^a1Z5And B^a2Z5Each represents a chemical bond, B^a1Z5B of formulae (BB2) to (BB60), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1), formula (BBO8), formula (BBO10), formula (BBD1) and formula (BBJ2)¹When a chemical bond of (A) is present, B^a2Z5To be B²The chemical bond of (a); b is^a1Z5B of formulae (BB2) to (BB60), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1), formula (BBO8), formula (BBO10), formula (BBD1) and formula (BBJ2) ²When a chemical bond of (A) is present, B^a2Z5To be B¹The chemical bond of (1). As B^a1Z5B^a2Z5Formula (BB6), formula (BB8), formula (BB11), formula (BB14), formula (BB19), formula (BB37), formula (BB58), formula (BBJ2), formula (BBO8), and formula (BBO10) are preferable, and formula (BB6) and formula (BB19) are more preferable.

Each symbol in table 1Z5, table 2Z5, table 3Z5, table 4Z5, table 5Z5, table 6Z5, table 7Z5, and tables 10Z5 to table 13Z5 represents the following partial structure. In the partial structure, "Me" represents a methyl group, "Et" represents an ethyl group, "Bu" represents a butyl group, "TBu" represents a tert-butyl group, "Hex" represents a hexyl group, "Oct" represents an octyl group, "2 EH" represents a 2-ethylhexyl group, "CHM" represents a cyclohexylmethyl group, "CH" represents a cyclohexyl group, "PH" represents a phenyl group, "BZ" represents a benzyl group, "NPR" represents a propyl group, "IPR" represents an isopropyl group, "IBu" represents an isobutyl group, and "EOE"represents-CH₂CH₂OCH₂CH₃"ALL" represents allyl, "HYE" represents 2-hydroxyethyl, and "COM" represents-CO-CH₃And "COE" represents-COO-CH₂CH₃And "OCM" represents-OCO-CH₃And "OME" represents-O-CH₃"SOT" represents a tosyl group, and "SNH" represents-SO₂NH-CH₂CH(CH₂CH₃)((CH₂)₃CH₃) "SN 2" represents-SO₂N(CH₃)((CH₂)₇CH₃) "CNM" represents-CONHCH ₃And "CN 2" represents-CON (CH)₃)C₆H₅And "NPH" represents-NHC₆H₅And "NOT" represents-N ((CH)₂)₇CH₃)₂And "NCO" represents-NHCO ((CH)₂)₄CH₃) "F" represents a fluorine atom, "Cl" represents a chlorine atom, "Br" represents a bromine atom, "CN" represents a cyano group, "NO 2" represents a nitro group, and "SUA" represents-SO₃H, "CBA" means-CO₂H, "CHO" means-CHO, "OCH" means-OCOH, "OH" means-OH, "SFM" means-SO₂NH₂"CBM" represents-CONH₂"NH 2" means-NH₂"NCH" represents-nhcooh, and represents a chemical bond. In the table, the following partial structures are denoted by symbols.

[ Table 1Z5]

TABLE 1Z5

	RN1Z5	Ba1Z5Ba2Z5	R1Z5	R6Z5	R7Z5
						IZ5-1	Me	BB6	H	H	H
IZ5-2	Et	BB6	H	H	H
						IZ5-3	PH	BB6	H	H	H
IZ5-4	Bu	BB6	H	H	H
						IZ5-5	TBu	BB6	H	H	H
IZ5-6	Hex	BB6	H	H	H
						IZ5-7	Oct	BB6	H	H	H
IZ5-8	2EH	BB6	H	H	H
						IZ5-9	CHM	BB6	H	H	H
IZ5-10	CH	BB6	H	H	H
						IZ5-11	BZ	BB6	H	H	H
IZ5-12	NPR	BB6	H	H	H
						IZ5-13	IPR	BB6	H	H	H
IZ5-14	IBu	BB6	H	H	H
						IZ5-15	EOE	BB6	H	H	H
IZ5-16	ALL	BB6	H	H	H
						IZ5-17	NH2	BB6	H	H	H
IZ5-18	CBM	BB6	H	H	H
						IZ5-19	COM	BB6	H	H	H
IZ5-20	COE	BB6	H	H	H
						IZ5-21	CBA	BB6	H	H	H
IZ5-22	HYE	BB6	H	H	H
						IZ5-23	Me	BB19	H	H	H
IZ5-24	Et	BB19	H	H	H
						IZ5-25	PH	BB19	H	H	H
IZ5-26	Bu	BB19	H	H	H
						IZ5-27	TBu	BB19	H	H	H
IZ5-28	Hex	BB19	H	H	H
						IZ5-29	Oct	BB19	H	H	H
IZ5-30	2EH	BB19	H	H	H
						IZ5-31	CHM	BB19	H	H	H
IZ5-32	CH	BB19	H	H	H
						IZ5-33	BZ	BB19	H	H	H
IZ5-34	NPR	BB19	H	H	H
						IZ5-35	IPR	BB19	H	H	H
IZ5-36	IBu	BB19	H	H	H
						IZ5-37	EOE	BB19	H	H	H
IZ5-38	ALL	BB19	H	H	H
						IZ5-39	NH2	BB19	H	H	H
IZ5-40	CBM	BB19	H	H	H

[ Table 2Z5]

TABLE 2Z5

	RN1Z5	Ba1Z5Ba2Z5	R1Z5	R6Z5	R7Z5
						IZ5-41	COM	BB19	H	H	H
IZ5-42	COE	BB19	H	H	H
						IZ5-43	CBA	BB19	H	H	H
IZ5-44	HYE	BB19	H	H	H
						IZ5-45	BZ	BB2	H	H	H
IZ5-46	CHM	BB3	H	H	H
						IZ5-47	ALL	BB4	H	H	H
IZ5-48	CBM	BB5	H	H	H
						IZ5-49	Me	BB7	H	H	H
IZ5-50	NH2	BB8	H	H	H
						IZ5-51	2EH	BB9	H	H	H
IZ5-52	Et	BB10	H	H	H
						IZ5-53	IPR	BB11	H	H	H
IZ5-54	COM	BB12	H	H	H
						IZ5-55	CBA	BB13	H	H	H
IZ5-56	HYE	BB14	H	H	H
						IZ5-57	Bu	BB15	H	H	H
IZ5-58	Hex	BB16	H	H	H
						IZ5-59	EOE	BB17	H	H	H
IZ5-60	CH	BB18	H	H	H
						IZ5-61	PH	BB20	H	H	H
IZ5-62	COE	BB21	H	H	H
						IZ5-63	TBu	BB22	H	H	H
IZ5-64	Oct	BB23	H	H	H
						IZ5-65	IBu	BB24	H	H	H
IZ5-66	NPR	BB25	H	H	H
						IZ5-67	BZ	BB26	H	H	H
IZ5-68	CHM	BB27	H	H	H
						IZ5-69	ALL	BB28	H	H	H
IZ5-70	CBM	BB29	H	H	H
						IZ5-71	Me	BB30	H	H	H
IZ5-72	NH2	BB31	H	H	H
						IZ5-73	2EH	BB32	H	H	H
IZ5-74	Et	BB33	H	H	H
						IZ5-75	IPR	BB34	H	H	H
IZ5-76	COM	BB35	H	H	H
						IZ5-77	CBA	BB36	H	H	H
IZ5-78	HYE	BB37	H	H	H
						IZ5-79	Bu	BB38	H	H	H
IZ5-80	Hex	BB39	H	H	H

[ Table 3Z5]

TABLE 3Z5

	RN1Z5	Ba1Z5Ba2Z5	R1Z5	R6Z5	R7Z5
						IZ5-81	EOE	BB40	H	H	H
IZ5-82	CH	BB41	H	H	H
						IZ5-83	PH	BB42	H	H	H
IZ5-84	COE	BB43	H	H	H
						IZ5-85	TBu	BB44	H	H	H
IZ5-86	Oct	BB45	H	H	H
						IZ5-87	IBu	BB46	H	H	H
IZ5-88	NPR	BB47	H	H	H
						IZ5-89	BZ	BB48	H	H	H
IZ5-90	CHM	BB49	H	H	H
						IZ5-91	ALL	BB50	H	H	H
IZ5-92	CBM	BB51	H	H	H
						IZ5-93	Me	BB52	H	H	H
IZ5-94	NH2	BB53	H	H	H
						IZ5-95	2EH	BB54	H	H	H
IZ5-96	Et	BB55	H	H	H
						IZ5-97	IPR	BB56	H	H	H
IZ5-98	COM	BB57	H	H	H
						IZ5-99	CBA	BB58	H	H	H
IZ5-100	HYE	BB59	H	H	H
						IZ5-101	PH	BB60	H	H	H
IZ5-102	Et	BB2	H	Et	Et
						IZ5-103	IPR	BB3	H	NPR	NPR
IZ5-104	COM	BB4	H	HYE	HYE
						IZ5-105	CBA	BB5	H	PH	PH
IZ5-106	HYE	BB6	H	Me	Me
						IZ5-107	Bu	BB7	H	ALL	ALL
IZ5-108	PH	BB8	H	2EH	2EH
						IZ5-109	EOE	BB9	H	CH	CH
IZ5-110	BZ	BB10	H	BZ	H
						IZ5-111	CHM	BB11	Me	Me	Me
IZ5-112	ALL	BB12	H	COM	COM
						IZ5-113	CBM	BB13	H	NPR	NPR
IZ5-114	Me	BB14	H	IBu	IBu
						IZ5-115	NH2	BB15	H	Oct	Oct
IZ5-116	2EH	BB16	H	COE	COE
						IZ5-117	Et	BB17	H	HYE	HYE
IZ5-118	IPR	BB18	H	EOE	EOE
						IZ5-119	COM	BB19	Me	Me	Me
IZ5-120	CBA	BB20	H	Hex	Hex

[ Table 4Z5]

TABLE 4Z5

	RN1Z5	Ba1Z5Ba2Z5	R1Z5	R6Z5	R7Z5
						IZ5-121	HYE	BB21	H	IPR	IPR
IZ5-122	Bu	BB22	H	NH2	NH2
						IZ5-123	Hex	BB23	H	Et	Et
IZ5-124	EOE	BB24	H	BZ	BZ
						IZ5-125	CH	BB25	H	Me	Me
IZ5-126	PH	BB26	H	CBA	CBA
						IZ5-127	COE	BB27	H	BZ	H
IZ5-128	TBu	BB28	H	CHM	CHM
						IZ5-129	Oct	BB29	H	TBu	TBu
IZ5-130	IBu	BB30	H	PH	PH
						IZ5-131	NPR	BB31	H	Bu	Bu
IZ5-132	BZ	BB32	Et	CH	CH
						IZ5-133	CHM	BB33	H	ALL	ALL
IZ5-134	ALL	BB34	H	CBM	CBM
						IZ5-135	CBM	BB35	H	CH	CH
IZ5-136	Me	BB36	H	2EH	2EH
						IZ5-137	NH2	BB37	H	COM	COM
IZ5-138	2EH	BB38	H	NPR	NPR
						IZ5-139	Et	BB39	H	IBu	IBu
IZ5-140	IPR	BB40	H	Oct	Oct
						IZ5-141	COM	BB41	H	COE	COE
IZ5-142	CBA	BB42	H	HYE	HYE
						IZ5-143	HYE	BB43	H	EOE	EOE
IZ5-144	Bu	BB44	Me	Me	Me
						IZ5-145	Hex	BB45	H	Hex	Hex
IZ5-146	EOE	BB46	H	IPR	IPR
						IZ5-147	CH	BB47	H	NH2	NH2
IZ5-148	PH	BB48	H	Et	Et
						IZ5-149	COE	BB49	H	BZ	BZ
IZ5-150	TBu	BB50	H	Me	Me
						IZ5-151	Oct	BB51	H	CBA	CBA
IZ5-152	IBu	BB52	H	BZ	H
						IZ5-153	NPR	BB53	H	CHM	CHM
IZ5-154	BZ	BB54	H	TBu	TBu
						IZ5-155	CHM	BB55	H	PH	PH
IZ5-156	ALL	BB56	H	Bu	Bu
						IZ5-157	CBM	BB57	Et	CH	CH
IZ5-158	Me	BB58	H	ALL	ALL
						IZ5-159	NH2	BB59	H	CBM	CBM
IZ5-160	2EH	BB60	H	CH	CH

[ Table 5Z5]

TABLE 5Z5

	RN1Z5	Ba1Z5Ba2Z5	R1Z5	R6Z5	R7Z5
						IZ5-161	ALL	BB2	SOT	H	H
IZ5-162	CBM	BB3	SNH	H	H
						IZ5-163	Me	BB4	TBu	H	H
IZ5-164	NH2	BB5	SN2	H	H
						IZ5-165	2EH	BB6	CNM	H	H
IZ5-166	Et	BB7	Hex	H	H
						IZ5-167	IPR	BB8	CN2	H	H
IZ5-168	COM	BB9	NPH	H	H
						IZ5-169	CBA	BB10	Oct	H	H
IZ5-170	HYE	BB11	NOT	H	H
						IZ5-171	Bu	BB12	NCO	H	H
IZ5-172	Hex	BB13	H	2EH	H
						IZ5-173	EOE	BB14	H	H	F
IZ5-174	CH	BB15	H	Cl	H
						IZ5-175	PH	BB16	H	H	CHM
IZ5-176	COE	BB17	H	Br	H
						IZ5-177	IBu	BB18	H	H	CN
IZ5-178	NPR	BB19	H	CH	H
						IZ5-179	BZ	BB20	H	H	NO2
IZ5-180	CHM	BB21	H	SUA	H
						IZ5-181	ALL	BB22	H	H	PH
IZ5-182	CBM	BB23	H	CBA	H
						IZ5-183	Me	BB24	H	H	CHO
IZ5-184	NH2	BB25	H	BZ	BZ
						IZ5-185	2EH	BB26	H	H	OCH
IZ5-186	Et	BB27	H	NPR	H
						IZ5-187	IPR	BB28	H	H	OH
IZ5-188	COM	BB29	H	IPR	H
						IZ5-189	CBA	BB30	H	H	SFM
IZ5-190	HYE	BB31	H	IBu	H
						IZ5-191	Bu	BB32	H	H	CBM
IZ5-192	Hex	BB33	H	EOE	H
						IZ5-193	EOE	BB34	H	H	NH2
IZ5-194	CH	BB35	H	ALL	H
						IZ5-195	PH	BB36	H	H	NCH
IZ5-196	COE	BB37	H	HYE	H
						IZ5-197	TBu	BB38	2EH	H	H
IZ5-198	Oct	BB39	F	H	H
						IZ5-199	IBu	BB40	Cl	H	H
IZ5-200	NPR	BB41	CHM	H	H

[ Table 6Z5]

TABLE 6Z5

	RN1Z5	Ba1Z5Ba2Z5	R1Z5	R6Z5	R7Z5
						IZ5-201	BZ	BB42	Br	H	H
IZ5-202	CHM	BB43	CN	H	H
						IZ5-203	ALL	BB44	CH	H	H
IZ5-204	CBM	BB45	NO2	H	H
						IZ5-205	Me	BB46	SUA	H	H
IZ5-206	NH2	BB47	PH	H	H
						IZ5-207	2EH	BB48	CBA	H	H
IZ5-208	Et	BB49	CHO	H	H
						IZ5-209	IPR	BB50	BZ	H	H
IZ5-210	COM	BB51	OCH	H	H
						IZ5-211	CBA	BB52	NPR	H	H
IZ5-212	HYE	BB53	OH	H	H
						IZ5-213	Bu	BB54	IPR	H	H
IZ5-214	Hex	BB55	SFM	H	H
						IZ5-215	EOE	BB56	IBu	H	H
IZ5-216	CH	BB57	CBM	H	H
						IZ5-217	PH	BB58	EOE	H	H
IZ5-218	COE	BB59	NH2	H	H
						IZ5-219	TBu	BB60	ALL	H	H
IZ5-220	Oct	BB2	NCH	H	H
						IZ5-221	IBu	BB3	HYE	H	H
IZ5-222	NPR	BB4	H	Me	H
						IZ5-223	BZ	BB5	H	H	COM
IZ5-224	CHM	BB6	H	COE	H
						IZ5-225	ALL	BB7	H	H	Et
IZ5-226	CBM	BB8	H	OCM	H
						IZ5-227	Me	BB9	H	H	OME
IZ5-228	NH2	BB10	H	Bu	H
						IZ5-229	2EH	BB11	H	H	SOT
IZ5-230	Et	BB12	H	SNH	H
						IZ5-231	IPR	BB13	H	H	TBu
IZ5-232	COM	BB14	H	SN2	H
						IZ5-233	CBA	BB15	H	H	CNM
IZ5-234	HYE	BB16	H	Hex	H
						IZ5-235	Bu	BB17	H	H	CN2
IZ5-236	Hex	BB18	H	NPH	H
						IZ5-237	EOE	BB19	H	H	Oct
IZ5-238	CH	BB20	H	NOT	H
						IZ5-239	PH	BB21	H	H	NCO
IZ5-240	COE	BB22	Me	H	H

[ Table 7Z5]

TABLE 7Z5

	RN1Z5	Ba1Z5Ba2Z5	R1Z5	R6Z5	R7Z5
						IZ5-241	TBu	BB23	COM	H	H
IZ5-242	Oct	BB24	COE	H	H
						IZ5-243	IBu	BB25	Et	H	H
IZ5-244	NPR	BB26	OCM	H	H
						IZ5-245	BZ	BB27	OME	H	H
IZ5-246	CHM	BB28	Bu	H	H
						IZ5-247	Me	BB8	H	H	H

[ Table 10Z5]

TABLE 10Z5

RN1Z5

Ba1Z5Ba2Z5

R1Z5

R6Z5

R7Z5

RN1Z5

Ba1Z5Ba2Z5

R1Z5

R6Z5

R7Z5

IZ5-248

NA1

BB6

H

H

H

IZ5-288

Hex

BB11

H

H

H

IZ5-249

HHk8

BB6

H

H

H

IZ5-289

Oct

BB11

H

H

H

IZ5-250

NA2

BB6

H

H

H

IZ5-290

2EH

BB11

H

H

H

IZ5-251

HHk7

BB6

H

H

H

IZ5-291

CHM

BB11

H

H

H

IZ5-252

HH37

BB6

H

H

H

IZ5-292

CH

BB11

H

H

H

IZ5-253

HHk6

BB6

H

H

H

IZ5-293

BZ

BB11

H

H

H

IZ5-254

NA3

BB6

H

H

H

IZ5-294

EOE

BB11

H

H

H

IZ5-255

HHJ2

BB6

H

H

H

IZ5-295

ALL

BB11

H

H

H

IZ5-256

HHk11

BB6

H

H

H

IZ5-296

NH2

BB11

H

H

H

IZ5-257

Et

BB8

H

H

H

IZ5-297

CBM

BB11

H

H

H

IZ5-258

PH

BB8

H

H

H

IZ5-298

COM

BB11

H

H

H

IZ5-259

Bu

BB8

H

H

H

IZ5-299

COE

BB11

H

H

H

IZ5-260

TBu

BB8

H

H

H

IZ5-300

CBA

BB11

H

H

H

IZ5-261

Hex

BB8

H

H

H

IZ5-301

HYE

BB11

H

H

H

IZ5-262

Oct

BB8

H

H

H

IZ5-302

NA1

BB11

H

H

H

IZ5-263

2EH

BB8

H

H

H

IZ5-303

HHk8

BB11

H

H

H

IZ5-264

CHM

BB8

H

H

H

IZ5-304

NA2

BB11

H

H

H

IZ5-265

CH

BB8

H

H

H

IZ5-305

HHk7

BB11

H

H

H

IZ5-266

BZ

BB8

H

H

H

IZ5-306

HH37

BB11

H

H

H

IZ5-267

EOE

BB8

H

H

H

IZ5-307

HHk6

BB11

H

H

H

IZ5-268

ALL

BB8

H

H

H

IZ5-308

NA3

BB11

H

H

H

IZ5-269

CBM

BB8

H

H

H

IZ5-309

HHJ2

BB11

H

H

H

IZ5-270

COM

BB8

H

H

H

IZ5-310

HHk11

BB11

H

H

H

IZ5-271

COE

BB8

H

H

H

IZ5-311

Me

BB14

H

H

H

IZ5-272

CBA

BB8

H

H

H

IZ5-312

Et

BB14

H

H

H

IZ5-273

HYE

BB8

H

H

H

IZ5-313

PH

BB14

H

H

H

IZ5-274

NA1

BB8

H

H

H

IZ5-314

Bu

BB14

H

H

H

IZ5-275

HHk8

BB8

H

H

H

IZ5-315

TBu

BB14

H

H

H

IZ5-276

NA2

BB8

H

H

H

IZ5-316

Hex

BB14

H

H

H

IZ5-277

HHk7

BB8

H

H

H

IZ5-317

Oct

BB14

H

H

H

IZ5-278

HH37

BB8

H

H

H

IZ5-318

2EH

BB14

H

H

H

IZ5-279

HHk6

BB8

H

H

H

IZ5-319

CHM

BB14

H

H

H

IZ5-280

NA3

BB8

H

H

H

IZ5-320

CH

BB14

H

H

H

IZ5-281

HHJ2

BB8

H

H

H

IZ5-321

BZ

BB14

H

H

H

IZ5-282

HHk11

BB8

H

H

H

IZ5-322

EOE

BB14

H

H

H

IZ5-283

Me

BB11

H

H

H

IZ5-323

ALL

BB14

H

H

H

IZ5-284

Et

BB11

H

H

H

IZ5-324

NH2

BB14

H

H

H

IZ5-285

PH

BB11

H

H

H

IZ5-325

CBM

BB14

H

H

H

IZ5-286

Bu

BB11

H

H

H

IZ5-326

COM

BB14

H

H

H

IZ5-287

TBu

BB11

H

H

H

IZ5-327

COE

BB14

H

H

H

[ Table 11Z5]

TABLE 11Z5

RN1Z5

Ba1Z5Ba2Z5

R1Z5

R6Z5

R7Z5

RN1Z5

Ba1Z5Ba2Z5

R1Z5

R6Z5

R7Z5

IZ5-328

CBA

BB14

H

H

H

IZ5-368

HHk7

BB37

H

H

H

IZ5-329

NA1

BB14

H

H

H

IZ5-369

HH37

BB37

H

H

H

IZ5-330

HHk8

BB14

H

H

H

IZ5-370

HHk6

BB37

H

H

H

IZ5-331

NA2

BB14

H

H

H

IZ5-371

NA3

BB37

H

H

H

IZ5-332

HHk7

BB14

H

H

H

IZ5-372

HHJ2

BB37

H

H

H

IZ5-333

HH37

BB14

H

H

H

IZ5-373

HHk11

BB37

H

H

H

IZ5-334

HHk6

BB14

H

H

H

IZ5-374

Me

BB58

H

H

H

IZ5-335

NA3

BB14

H

H

H

IZ5-375

Et

BB58

H

H

H

IZ5-336

HHJ2

BB14

H

H

H

IZ5-376

PH

BB58

H

H

H

IZ5-337

HHk11

BB14

H

H

H

IZ5-377

Bu

BB58

H

H

H

IZ5-338

NA1

BB19

H

H

H

IZ5-378

TBu

BB58

H

H

H

IZ5-339

HHk8

BB19

H

H

H

IZ5-379

Hex

BB58

H

H

H

IZ5-340

NA2

BB19

H

H

H

IZ5-380

Oct

BB58

H

H

H

IZ5-341

HHk7

BB19

H

H

H

IZ5-381

2EH

BB58

H

H

H

IZ5-342

HH37

BB19

H

H

H

IZ5-382

CHM

BB58

H

H

H

IZ5-343

HHk6

BB19

H

H

H

IZ5-383

CH

BB58

H

H

H

IZ5-344

NA3

BB19

H

H

H

IZ5-384

BZ

BB58

H

H

H

IZ5-345

HHJ2

BB19

H

H

H

IZ5-385

EOE

BB58

H

H

H

IZ5-346

HHk11

BB19

H

H

H

IZ5-386

ALL

BB58

H

H

H

IZ5-347

Me

BB37

H

H

H

IZ5-387

NH2

BB58

H

H

H

IZ5-348

Et

BB37

H

H

H

IZ5-388

CBM

BB58

H

H

H

IZ5-349

PH

BB37

H

H

H

IZ5-389

COM

BB58

H

H

H

IZ5-350

Bu

BB37

H

H

H

IZ5-390

COE

BB58

H

H

H

IZ5-351

TBu

BB37

H

H

H

IZ5-391

HYE

BB58

H

H

H

IZ5-352

Hex

BB37

H

H

H

IZ5-392

NA1

BB58

H

H

H

IZ5-353

Oct

BB37

H

H

H

IZ5-393

HHk8

BB58

H

H

H

IZ5-354

2EH

BB37

H

H

H

IZ5-394

NA2

BB58

H

H

H

IZ5-355

CHM

BB37

H

H

H

IZ5-395

HHk7

BB58

H

H

H

IZ5-356

CH

BB37

H

H

H

IZ5-396

HH37

BB58

H

H

H

IZ5-357

BZ

BB37

H

H

H

IZ5-397

HHk6

BB58

H

H

H

IZ5-358

EOE

BB37

H

H

H

IZ5-398

NA3

BB58

H

H

H

IZ5-359

ALL

BB37

H

H

H

IZ5-399

HHJ2

BB58

H

H

H

IZ5-360

NH2

BB37

H

H

H

IZ5-400

HHk11

BB58

H

H

H

IZ5-361

CBM

BB37

H

H

H

IZ5-401

Me

BBJ2

H

H

H

IZ5-362

COM

BB37

H

H

H

IZ5-402

Et

BBJ2

H

H

H

IZ5-363

COE

BB37

H

H

H

IZ5-403

PH

BBJ2

H

H

H

IZ5-364

CBA

BB37

H

H

H

IZ5-404

Bu

BBJ2

H

H

H

IZ5-365

NA1

BB37

H

H

H

IZ5-405

TBu

BBJ2

H

H

H

IZ5-366

HHk8

BB37

H

H

H

IZ5-406

Hex

BBJ2

H

H

H

IZ5-367

NA2

BB37

H

H

H

IZ5-407

Oct

BBJ2

H

H

H

[ Table 12Z5] Table 12Z5

RN1Z5

Ba1Z5Ba2Z5

R1Z5

R6Z5

R7Z5

RN1Z5

Ba1Z5Ba2Z5

R1Z5

R6Z5

R7Z5

IZ5-408

2EH

BBJ2

H

H

H

IZ5-448

NA1

BBO8

H

H

H

IZ5-409

CHM

BBJ2

H

H

H

IZ5-449

HHk8

BBO8

H

H

H

IZ5-410

CH

BBJ2

H

H

H

IZ5-450

NA2

BBO8

H

H

H

IZ5-411

BZ

BBJ2

H

H

H

IZ5-451

HHk7

BBO8

H

H

H

IZ5-412

EOE

BBJ2

H

H

H

IZ5-452

HH37

BBO8

H

H

H

IZ5-413

ALL

BBJ2

H

H

H

IZ5-453

HHk6

BBO8

H

H

H

IZ5-414

NH2

BBJ2

H

H

H

IZ5-454

NA3

BBO8

H

H

H

IZ5-415

CBM

BBJ2

H

H

H

IZ5-455

HHJ2

BBO8

H

H

H

IZ5-416

COM

BBJ2

H

H

H

IZ5-456

HHk11

BBO8

H

H

H

IZ5-417

COE

BBJ2

H

H

H

IZ5-457

Me

BBO10

H

H

H

IZ5-418

CBA

BBJ2

H

H

H

IZ5-458

Et

BBO10

H

H

H

IZ5-419

HYE

BBJ2

H

H

H

IZ5-459

PH

BBO10

H

H

H

IZ5-420

NA1

BBJ2

H

H

H

IZ5-460

Bu

BBO10

H

H

H

IZ5-421

HHk8

BBJ2

H

H

H

IZ5-461

TBu

BBO10

H

H

H

IZ5-422

NA2

BBJ2

H

H

H

IZ5-462

Hex

BBO10

H

H

H

IZ5-423

HHk7

BBJ2

H

H

H

IZ5-463

Oct

BBO10

H

H

H

IZ5-424

HH37

BBJ2

H

H

H

IZ5-464

2EH

BBO10

H

H

H

IZ5-425

HHk6

BBJ2

H

H

H

IZ5-465

CHM

BBO10

H

H

H

IZ5-426

NA3

BBJ2

H

H

H

IZ5-466

CH

BBO10

H

H

H

IZ5-427

HHJ2

BBJ2

H

H

H

IZ5-467

BZ

BBO10

H

H

H

IZ5-428

HHk11

BBJ2

H

H

H

IZ5-468

EOE

BBO10

H

H

H

IZ5-429

Me

BBO8

H

H

H

IZ5-469

ALL

BBO10

H

H

H

IZ5-430

Et

BBO8

H

H

H

IZ5-470

NH2

BBO10

H

H

H

IZ5-431

PH

BBO8

H

H

H

IZ5-471

CBM

BBO10

H

H

H

IZ5-432

Bu

BBO8

H

H

H

IZ5-472

COM

BBO10

H

H

H

IZ5-433

TBu

BBO8

H

H

H

IZ5-473

COE

BBO10

H

H

H

IZ5-434

Hex

BBO8

H

H

H

IZ5-474

CBA

BBO10

H

H

H

IZ5-435

Oct

BBO8

H

H

H

IZ5-475

HYE

BBO10

H

H

H

IZ5-436

2EH

BBO8

H

H

H

IZ5-476

NA1

BBO10

H

H

H

IZ5-437

CHM

BBO8

H

H

H

IZ5-477

HHk8

BBO10

H

H

H

IZ5-438

CH

BBO8

H

H

H

IZ5-478

NA2

BBO10

H

H

H

IZ5-439

BZ

BBO8

H

H

H

IZ5-479

HHk7

BBO10

H

H

H

IZ5-440

EOE

BBO8

H

H

H

IZ5-480

HH37

BBO10

H

H

H

IZ5-441

ALL

BBO8

H

H

H

IZ5-481

HHk6

BBO10

H

H

H

IZ5-442

NH2

BBO8

H

H

H

IZ5-482

NA3

BBO10

H

H

H

IZ5-443

CBM

BBO8

H

H

H

IZ5-483

HHJ2

BBO10

H

H

H

IZ5-444

COM

BBO8

H

H

H

IZ5-484

HHk11

BBO10

H

H

H

IZ5-445

COE

BBO8

H

H

H

IZ5-485

HH22

BB2

H

H

H

IZ5-446

CBA

BBO8

H

H

H

IZ5-486

HH40

BB3

H

H

H

IZ5-447

HYE

BBO8

H

H

H

IZ5-487

HHk7

BB4

H

H

H

[ Table 13Z5]

TABLE 13Z5

For example, the compound IZ5-1 is a compound represented by the following formula (IZ 5-1).

The compound IZ5-1 to the compound IZ5-160 and the compound IZ5-247 to the compound IZ5-542 are preferable, the compound IZ5-1 to the compound IZ5-160 and the compound IZ5-247 to the compound IZ5-484 are more preferable, the compound IZ5-1 to the compound IZ5-160 are still more preferable, the compound IZ5-1 to the compound IZ5-101 are still more preferable, and the compound IZ5-1 to the compound IZ5-44 are particularly preferable.

Specific examples of the compound IZ5 include compounds represented by table 1Z5, table 2Z5, table 3Z5, table 4Z5, table 5Z5, table 6Z5, table 7Z5, and tables 10Z5 to 13Z5, in which 1 to 3 hydrogen atoms are replaced by-SO₃M or-CO₂M is substituted. For example, compounds having 1 to 3 sulfo groups bonded to the compound IZ5-1 of Table 1Z5 are represented by the following structures. Wherein in (SO)₃H) Represents a compound in which any hydrogen atom in compound IZ5-1 of Table 1Z5 is substituted.

Preferably, 1 to 3-SO groups are bonded to the compound IZ5-1 to the compound IZ5-160 and the compound IZ5-247 to the compound IZ5-542₃M or-CO₂A compound formed by the reaction of M,

more preferably, 1 to 3-SO groups are bonded to the compound IZ5-1 to the compound IZ5-160 and the compound IZ5-247 to the compound IZ5-484₃M or-CO₂A compound formed by the reaction of M,

more preferably, 1 to 3-SO groups are bonded to the compound IZ5-1 to the compound IZ5-160₃M or-CO₂M, more preferably 1 to 3-SO groups are bonded to the compound IZ5-1 to the compound IZ5-101₃M or-CO₂M, particularly preferably 1 to 3-SO groups are bonded to the compound IZ5-1 to the compound IZ5-44₃M or-CO₂M, or a salt thereof.

As the compound (IZ5), the following compounds are preferable:

In the formula (IZ5), R^N1Z5is-CO-R^102Z5、-COO-R^101Z5、-CON(R^102Z5)₂Or may have a structure selected from the group consisting of-SO₃M and-CO₂A C1-20 hydrocarbon group as a substituent in the group consisting of M, R^1Z5Is a hydrogen atom and may have a radical selected from the group consisting of-SO₃M and-CO₂A C1-20 hydrocarbon group, -SO₃M or-CO₂M，R^2Z5～R^5Z5Each independently represents a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogen atom, or-N (R)^102Z5)₂A C1-20 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R^102Z5、-O-R^102Z5、-SO₃M or-CO₂M，R^2Z5～R^5Z5At least one of which is a hydrocarbon group having 1 to 20 carbon atoms, a halogen atom, or-N (R)^102Z5)₂A C1-20 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R^102Z5、-O-R^102Z5、-SO₃M or-CO₂M，

R^6Z5And R^7Z5Independently of one another, a hydrogen atom, may have a structure selected from the group consisting of-SO₃M and-CO₂A C1-20 hydrocarbon group, -SO₃M or-CO₂M，

R^102Z5Is a hydrogen atom, or may have a radical selected from the group consisting of-SO₃M and-CO₂A C1-20 hydrocarbon group as a substituent in the group consisting of M, R^101Z5May have a structure selected from the group consisting of-SO₃M and-CO₂A compound in which the substituent in the group consisting of M is a hydrocarbon group having 1 to 20 carbon atoms, and M is a hydrogen atom or an alkali metal atom;

More preferred are the following compounds:

R^N1Z5is-CO-R^102Z5、-CON(R^102Z5)₂Or may have a structure selected from the group consisting of-SO₃M and-CO₂A C1-10 hydrocarbon group as a substituent in the group consisting of M, R^1Z5Is a hydrogen atom, R^2Z5～R^5Z5Each independently represents a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, or-N (R)^102Z5)₂A C1-10 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R^102Z5、-O-R^102Z5、-SO₃M or-CO₂M，R^2Z5～R^5Z5At least one of which is a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, or-N (R)^102Z5)₂A C1-10 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R^102Z5、-O-R^102Z5、-SO₃M or-CO₂M，R^6Z5And R^7Z5Are the same group, are hydrogen atoms, or may have a structure selected from the group consisting of₃M and-CO₂A C1-10 hydrocarbon group as a substituent in the group consisting of M, R^102Z5Is a hydrogen atom, or may have a radical selected from the group consisting of-SO₃M and-CO₂A C1-10 hydrocarbon group as a substituent in the group consisting of M, R^101Z5May have a structure selected from the group consisting of-SO₃M and-CO₂A compound in which the substituent in the group consisting of M is a hydrocarbon group having 1 to 10 carbon atoms, and M is a hydrogen atom or an alkali metal atom;

further preferred are the following compounds:

R^N1Z5is-CO-R^102Z5、-CON(R^102Z5)₂Or may have a structure selected from the group consisting of-SO ₃M and-CO₂A hydrocarbyl group having 1 to 10 carbon atoms as a substituent in the group consisting of M,

R^1Z5is a hydrogen atom, R^2Z5～R^5Z5Each independently represents a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, or-N (R)^102Z5)₂Nitro, trifluoromethyl, -O-R^102Z5、-SO₃M or-CO₂M，R^2Z5～R^5Z5At least one of which is a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, or-N (R)^102Z5)₂Nitro, trifluoromethyl, -O-R^102Z5、-SO₃M or-CO₂M，

R^6Z5And R^7Z5The same group is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms,

R^102Z5is a hydrogen atom, or may have a radical selected from the group consisting of-SO₃M and-CO₂A C1-10 hydrocarbon group as a substituent in the group consisting of M, R^101Z5May have a structure selected from the group consisting of-SO₃M and-CO₂And M is a compound in which the substituent in the group consisting of M is a hydrocarbon group having 1 to 10 carbon atoms and M is a hydrogen atom or an alkali metal atom.

For compound IZ5, R^1Z5In the case of a hydrogen atom, the compound represented by the formula (pt1Z5) (hereinafter, may be referred to as a phthalonitrile compound) may be produced by reacting a compound represented by the formula (pt2Z5) (hereinafter, may be referred to as an alkoxide compound), and then further reacting the compound represented by the formula (pt3Z5) and the compound represented by the formula (pt4Z5) in the presence of an acid. In addition, R^1Z5When not a hydrogen atom, the compound is further reacted with a compound represented by the formula (pt5Z5) to produce a compound IZ 5.

In [ formula (pt1Z5), formula (pt2Z5), formula (pt3Z5), formula (pt4Z5), formula (pt5Z5) and formula (IZ5), R^N1Z5、R^1Z5、R^2Z5、R^3Z5、R^4Z5、R^5Z5、R^6Z5And R^7Z5The same meanings as described above are indicated. R^14Z5Represents an alkyl group having 1 to 20 carbon atoms. M^1Z5Represents an alkali metal atom. LG represents halogenAn elemental atom, a mesyloxy group, a tosyloxy group or a trifluormesyloxy group.]

As R^14Z5Examples of the alkyl group having 1 to 20 carbon atoms include methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec-butyl, tert-butyl, and the like, and preferred examples thereof include alkyl groups having 1 to 6 carbon atoms.

As M^1Z5Examples of the alkali metal atom include a lithium atom, a sodium atom and a potassium atom.

The amount of the alkoxide compound used is usually 0.1 to 10 moles, preferably 0.2 to 5 moles, more preferably 0.3 to 3 moles, and still more preferably 0.4 to 2 moles, based on 1 mole of the phthalonitrile compound.

The amount of the compound pt3Z5 used is usually 1 to 10 moles, preferably 1 to 5 moles, more preferably 1 to 3 moles, and still more preferably 1 to 2 moles, based on 1 mole of the phthalonitrile compound.

The amount of the compound pt4Z5 used is usually 1 to 10 moles, preferably 1 to 5 moles, more preferably 1 to 3 moles, and still more preferably 1 to 2 moles, based on 1 mole of the phthalonitrile compound.

Examples of the acid include inorganic acids such as hydrochloric acid, hydrobromic acid, hydroiodic acid, sulfuric acid, nitric acid, fluorosulfonic acid, and phosphoric acid; sulfonic acids such as methanesulfonic acid, trifluoromethanesulfonic acid, and p-toluenesulfonic acid; examples of the carboxylic acid include acetic acid, citric acid, formic acid, gluconic acid, lactic acid, oxalic acid, tartaric acid, and the like, and preferably include hydrochloric acid, hydrobromic acid, sulfuric acid, methanesulfonic acid, trifluoromethanesulfonic acid, p-toluenesulfonic acid, and carboxylic acid, and more preferably include acetic acid.

The amount of the acid used is usually 1 to 20 moles, preferably 1 to 10 moles, more preferably 1 to 8 moles, and still more preferably 1 to 6 moles, based on 1 mole of the phthalonitrile compound.

The reaction of the phthalonitrile compound, the alkoxide compound, the compound pt3Z5, and the compound pt4Z5 can be usually carried out in the presence of a solvent.

As the solvent, water may be mentioned; nitrile solvents such as acetonitrile; alcohol solvents such as methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, and 1-octanol; ether solvents such as tetrahydrofuran; ketone solvents such as acetone; ester solvents such as ethyl acetate; aliphatic hydrocarbon solvents such as hexane; aromatic hydrocarbon solvents such as toluene; halogenated hydrocarbon solvents such as dichloromethane and chloroform; amide solvents such as N, N-dimethylformamide and N-methylpyrrolidone; sulfoxide solvents such as dimethyl sulfoxide, preferably include water, nitrile solvents, alcohol solvents, ether solvents, ketone solvents, ester solvents, aromatic hydrocarbon solvents, halogenated hydrocarbon solvents, amide solvents and sulfoxide solvents, more preferably include water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, tetrahydrofuran, acetone, ethyl acetate, toluene, dichloromethane, chloroform, N-dimethylformamide, N-methylpyrrolidone and dimethyl sulfoxide, still more preferably include water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, acetone, dichloromethane, chloroform, N-dimethylformamide, N-methylpyrrolidone and dimethyl sulfoxide, and particularly preferably include water, methanol, ethanol, methanol, ethanol, butanol, methanol, ethanol, 1-butanol, 1-pentanol, 1-octanol, acetone, dichloromethane, chloroform, N-methylpyrrolidone and dimethyl sulfoxide, Acetonitrile, methanol, ethanol and 2-propanol.

The amount of the solvent used is usually 1 to 1000 parts by mass per 1 part by mass of the phthalonitrile compound.

The reaction temperature is usually 0 to 200 ℃, preferably 0 to 100 ℃, more preferably 0 to 70 ℃, and further preferably 0 to 50 ℃. The reaction time is usually 0.5 to 300 hours.

With respect to the amount of compound pt5Z5 used, relative to R^1Z5The amount of the compound IZ51 which is a hydrogen atom is usually 1 to 10 moles, preferably 1 to 5 moles, more preferably 1 to 3 moles, and still more preferably 1 to 2 moles.

When the compound pt5Z5 is reacted, a base is preferably coexisted. Examples of the base include organic bases such as triethylamine, 4- (N, N-dimethylamino) pyridine, and piperidine; metal alkoxides such as sodium methoxide, sodium ethoxide, sodium tert-butoxide, and potassium tert-butoxide; organic metal compounds such as butyl lithium, tert-butyl lithium and phenyl lithium; inorganic bases such as lithium hydroxide, sodium hydroxide and potassium hydroxide.

As for the amount of the base used, with respect to R^1Z5The amount of the compound IZ51 is usually 1 to 10 mol based on the hydrogen atomThe amount of the organic solvent is preferably 1 to 5 moles, more preferably 1 to 3 moles, and still more preferably 1 to 2 moles.

The reaction of compound pt5Z5 can generally be carried out in the presence of a solvent. The solvent may be selected from the same ranges as described above.

As to the amount of the solvent used, with respect to R^1Z5The amount of the compound IZ 51 is usually 1 to 1000 parts by mass. The reaction temperature of the compound pt5Z5 is usually-90 to 200 ℃, preferably-80 to 100 ℃, and more preferably 0 to 50 ℃. The reaction time is usually 0.5 to 300 hours.

Compound IZ5 having no sulfo group or-SO₃M²In the case of (3), the compound IZ5 can be reacted with a sulfonating agent such as fuming sulfuric acid or chlorosulfonic acid to introduce a sulfo group or-SO₃M²²。M²²Represents an alkali metal atom. As M²²Examples of the alkali metal atom include a lithium atom, a sodium atom and a potassium atom.

With respect to SO in oleum₃The amount of (b) is usually 1 to 50 mol, preferably 5 to 40 mol, more preferably 5 to 30 mol, and still more preferably 5 to 25 mol based on 51 mol of the compound IZ. The amount of sulfuric acid used in the oleum is usually 1 to 200 moles, preferably 10 to 100 moles, more preferably 10 to 75 moles, and still more preferably 10 to 50 moles, based on 51 moles of the compound IZ. The amount of chlorosulfonic acid used is usually 1 to 500 moles, preferably 10 to 300 moles, more preferably 10 to 200 moles, and still more preferably 10 to 150 moles, based on 51 moles of the compound IZ.

The reaction temperature of sulfonation is usually-20 to 200 ℃, preferably-10 to 100 ℃, and more preferably 0 to 50 ℃. The reaction time is usually 0.5 to 300 hours.

The method for extracting the compound IZ5 from the reaction mixture is not particularly limited, and it can be extracted by various known methods. For example, after the reaction is completed, the reaction mixture is filtered to extract the compound IZ 5. The residue obtained after filtration may be subjected to column chromatography, recrystallization, or the like. After completion of the reaction, the solvent of the reaction mixture may be distilled off and then purified by column chromatography.

< Compound IZ6 >)

Compound IZ6 is represented by formula (IZ 6).

[ in the formula (IZ6), D represents a structure having an isoindoline skeleton. Z represents-SO₃ ^-or-CO₂ ^-。A^c+Represents a metal cation having a valence of c. a represents an integer of 1 to 10. b represents an integer of 1 or more. c represents an integer of 2 to 10. d represents an integer of 1 or more.

D. Z, a or A^c+When there are a plurality of them, they may be the same or different. The formula (I 'Z6) and the formula (I' Z6) respectively represent partial structures of the formula (IZ6), D, Z, A^c+A, b, c and d represent the same meanings as the corresponding symbols in formula (IZ 6). The partial structure represented by the formula (I' Z6) has the same negative valence as the partial structure represented by the formula (I "Z6) has the same positive valence in absolute value. ]

The integer represented by a is 1 to 10, preferably 1 to 8, more preferably 1 to 6, and further preferably 1 to 4. The integer represented by b is 1 or more, preferably 1 to 10, and more preferably 1 to 8. The integer represented by c is 2 to 10, preferably 2 to 8, more preferably 2 to 6, and further preferably 2 to 4. d represents an integer of 1 or more, preferably 1 to 10, more preferably 1 to 8. Z is preferably-CO₂ ^-。

A^c+Represents a metal cation having a valence of 2 or more. As the metal cation having a valence of 2 or more,

examples thereof include:the cation of a metal of groups 2 to 15 of the periodic Table of the elements is preferably Mg²⁺、Ca²⁺、Sr^{2 +}、Ba²⁺、Cd²⁺、Ni²⁺、Zn²⁺、Cu²⁺、Hg²⁺、Fe²⁺、Co²⁺、Sn²⁺、Pb²⁺And Mn²⁺An isovalent 2 metal cation; al (Al)³⁺、Fe³⁺And Cr³⁺An equivalent 3 valent metal cation; sn (tin)⁴⁺And Mn⁴⁺The metal cation having a valence of 4, more preferably Mg²⁺、Ca²⁺、Sr²⁺、Ba²⁺、Ni²⁺、Zn²⁺、Cu²⁺、Fe²⁺、Co²⁺、Sn²⁺、Mn²⁺、Al³⁺、Fe³⁺、Cr³⁺、Sn⁴⁺And Mn⁴⁺More preferably, Mg is mentioned²⁺、Ca^{2 +}、Sr²⁺、Ba²⁺、Zn²⁺、Cu²⁺、Fe²⁺、Mn²⁺、Al³⁺、Fe³⁺、Cr³⁺And Mn⁴⁺。

The compound represented by the formula (IZ6) is preferably a compound represented by the formula (IZ6-A) (hereinafter, may be referred to as a compound IZ 6-A.).

[ in the formula (IZ6-A), A^c+B, c and d are as defined above.

R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6And R^13AZ6Independently of one another, represents a hydrogen atom, -CO-R^102AZ6、-COO-R^101AZ6、-OCO-R^102AZ6、-COCO-R^102AZ6、-O-R^102AZ6、-SO₂-R^101AZ6、-SO₂N(R^102AZ6)₂、-CON(R^102AZ6)₂、-N(R^102AZ6)₂、-NHCO-R^102AZ6、-NHCO-N(R^102AZ6)₂、-NHCOOR^102AZ6、-OCON(R^102AZ6)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M、-SO₃ ^-、-CO₂ ^-The hydrocarbon group may have a substituent and has 1 to 40 carbon atoms, or the heterocyclic group may have a substituent.

R^2AZ6And R ^3AZ6、R^3AZ6And R^4AZ6、R^4AZ6And R^5AZ6、R^AA1Z6And R^AA2Z6And R^12AZ6And R^13AZ6Each of which may be bonded to each other to form a ring. R^101AZ6Independently represent a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.

R^102AZ6Independently represent a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group. M represents a hydrogen atom or an alkali metal atom.

The formula (IZ6-A ') and the formula (IZ 6-A') each represent a partial structure of the formula (IZ6-A), A^c+、b、c、d、R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6And R^13AZ6Represents the same meaning as the corresponding symbol in the formula (IZ 6-A).

R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6、R^102AZ6M, c or A^c+When there are plural, they may or may not be the sameThe same is true.

R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6Satisfies at least 1 of (ra-i) to (ra-iii), R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6having-SO of₃ ^-or-CO₂ ^-The total number of (a) is a.

(ra-i)R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6And R^13AZ6At least one of which is-SO₃ ^-or-CO₂ ^-。

(ra-ii)R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6And R^13AZ6At least one of which is-CO-R^102AZ6、-COO-R^101AZ6、-OCO-R^102AZ6、-COCO-R^102AZ6、-O-R^102AZ6、-SO₂-R^101AZ6、-SO₂N(R^102AZ6)₂、-CON(R^102AZ6)₂、-N(R^102AZ6)₂、-NHCO-R^102AZ6、-NHCO-N(R^102AZ6)₂、-NHCOOR^102AZ6or-OCON (R)^102AZ6)₂R is a hydrogen atom^101AZ6And R^102AZ6To have-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO₃ ^-or-CO₂ ^-The heterocyclic group of (1). Wherein the hydrocarbon group or the heterocyclic group may have-SO₃ ^-and-CO₂ ^-And (ii) an additional substituent.

(ra-iii)R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6And R^13AZ6At least one of which is a compound having-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO₃ ^-or-CO ₂ ^-The heterocyclic group of (1). Wherein the hydrocarbon group and the heterocyclic group may have-SO₃ ^-or-CO₂ ^-And (ii) an additional substituent.

a represents the same meaning as the symbol in the formula (IZ 6). When a plurality of a exist, they may be the same or different.

The partial structure represented by the formula (IZ 6-A') has the same negative valence as the partial structure represented by the formula (IZ6-A ") has the same positive valence in absolute value. The wavy line indicates the E-body or the Z-body. ]

R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6The number of carbon atoms of the hydrocarbon group is 1 to 40, preferably 1 to 30, more preferably 1 to 20, still more preferably 1 to 15, and particularly preferably 1 to 10.

R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6The hydrocarbon group having 1 to 40 carbon atoms may be an aliphatic hydrocarbon group or an aromatic hydrocarbon group, and the aliphatic hydrocarbon group may be saturated or unsaturated, and may be a chain or alicyclic group.

As R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6Examples of the saturated or unsaturated chain hydrocarbon group include straight chain alkyl groups such as methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, heptadecyl, octadecyl, and eicosyl; an isopropyl group,Branched alkyl groups such as isobutyl, sec-butyl, tert-butyl, (2-ethyl) butyl, isopentyl, neopentyl, tert-pentyl, (1-methyl) pentyl, (2-methyl) pentyl, (1-ethyl) pentyl, (3-ethyl) pentyl, isohexyl, (5-methyl) hexyl, (2-ethyl) hexyl and (3-ethyl) heptyl; alkenyl groups such as vinyl, 1-propenyl, 2-propenyl (allyl), (1-methyl) vinyl, 2-butenyl, 3-butenyl, 1, 3-butadienyl, (1- (2-propenyl)) vinyl, (1, 2-dimethyl) propenyl, and 2-pentenyl; and so on. The number of carbon atoms of the saturated or unsaturated chain hydrocarbon group is preferably 1 to 30, more preferably 1 to 20, and further preferably 1 to 15. Among them, a linear or branched alkyl group having 1 to 10 carbon atoms, more preferably 1 to 8 carbon atoms, and still more preferably 1 to 5 carbon atoms is particularly preferable.

As R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6Examples of the saturated or unsaturated alicyclic hydrocarbon group include cyclopropyl, 1-methylcyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, 1-methylcyclohexyl, 2-methylcyclohexyl, 3-methylcyclohexyl, 4-methylcyclohexyl, 1, 2-dimethylcyclohexyl, 1, 3-dimethylcyclohexyl, 1, 4-dimethylcyclohexyl, 2, 3-dimethylcyclohexyl, 2, 4-dimethylcyclohexyl, 2, 5-dimethylcyclohexyl, 2, 6-dimethylcyclohexyl, 3, 4-dimethylcyclohexyl, 3, 5-dimethylcyclohexyl, 2-dimethylcyclohexyl, 3-dimethylcyclohexyl, 4-dimethylcyclohexyl, cyclooctyl, 2,4, 6-trimethylcyclohexyl, and, Cycloalkyl groups such as 2,2,6, 6-tetramethylcyclohexyl, 3,5, 5-tetramethylcyclohexyl, 4-pentylcyclohexyl, 4-octylcyclohexyl and 4-cyclohexylcyclohexyl; cycloalkenyl groups such as cyclohexenyl (e.g., cyclohex-2-ene, cyclohex-3-ene), cycloheptenyl, and cyclooctenyl; norbornyl, adamantyl, bicyclo [2.2.2]An octyl group and the like. The number of carbon atoms of the saturated or unsaturated alicyclic hydrocarbon group is preferably 3 to 30, more preferably 3 to 20, still more preferably 4 to 20, yet more preferably 4 to 15, even more preferably 5 to 15, and most preferably 5 to 10. Among them, particularly preferred is Is cyclopentyl, cyclohexyl, cycloheptyl and cyclooctyl.

As R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6The aromatic hydrocarbon group may include a phenyl group, an o-tolyl group, a m-tolyl group, a p-tolyl group, a 2, 3-dimethylphenyl group, a 2, 4-dimethylphenyl group, a 2, 5-dimethylphenyl group, a 2, 6-dimethylphenyl group, a 3, 4-dimethylphenyl group, a 3, 5-dimethylphenyl group, a 4-vinylphenyl group, an o-isopropylphenyl group, a m-isopropylphenyl group, a p-isopropylphenyl group, an o-tert-butylphenyl group, a m-tert-butylphenyl group, a p-tert-butylphenyl group, a mesityl group, a 4-ethylphenyl group, a 4-butylphenyl group, a 4-pentylphenyl group, a 2, 6-bis (2-propyl) phenyl group, a 4-cyclohexylphenyl group, a 2,4, 6-trimethylphenyl group, a 4-octylphenyl group, a 4-vinylphenyl group, a 1-naphthyl group, a 2-naphthyl group, a, Aromatic hydrocarbon groups such as 5,6,7, 8-tetrahydro-1-naphthyl, 5,6,7, 8-tetrahydro-2-naphthyl, fluorenyl, phenanthryl, anthracyl, pyrenyl and the like; and so on. The number of carbon atoms of the aromatic hydrocarbon group is preferably 6 to 30, more preferably 6 to 20, and further preferably 6 to 15.

R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6The hydrocarbon group may be a combination of the hydrocarbon groups listed above (for example, an aromatic hydrocarbon group, and at least 1 of a chain hydrocarbon group and an alicyclic hydrocarbon group), and examples thereof include aralkyl groups such as benzyl, phenethyl, and 1-methyl-1-phenylethyl; arylalkenyl groups such as phenylvinyl (styryl); arylalkynyl groups such as phenylethynyl; a phenyl group having 1 or more phenyl groups bonded thereto, such as a biphenyl group and a terphenyl group; cyclohexylmethylphenyl, benzylphenyl, (dimethyl (phenyl) methyl) phenyl, and the like.

For R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6A group represented byExamples of the group formed by combining the hydrocarbon groups (e.g., the chain hydrocarbon group and the alicyclic hydrocarbon group) include an alkyl group in which 1 or more alicyclic hydrocarbon groups are bonded, such as a cyclopropylmethyl group, a cyclopropylethyl group, a cyclobutylmethyl group, a cyclobutylethyl group, a cyclopentylmethyl group, a cyclopentylethyl group, a cyclohexylmethyl group, a 2-methylcyclohexylmethyl group, a cyclohexylethyl group, and an adamantylmethyl group.

The number of carbon atoms is preferably 4 to 30, more preferably 6 to 30, further preferably 6 to 20, further preferably 4 to 15, and particularly preferably 6 to 15.

R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6The hydrocarbon group represented may have a substituent. The substituent may have a valence of 1 or 2. For substituents having a valence of 2, preferably 2 chemical bonds are bonded to the same carbon atom to form a double bond.

Examples of the substituent having a valence of 1 include:

methoxy group, ethoxy group, propoxy group, isopropoxy group, butoxy group, isobutoxy group, sec-butoxy group, tert-butoxy group, pentyloxy group, hexyloxy group, (2-ethyl) hexyloxy group, heptyloxy group, octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, dodecyloxy group, (2-ethyl) hexyloxy group, eicosyloxy group, 1-phenylethoxy group, 1-methyl-1-phenylethoxy group, phenyloxy group, o-tolyloxy group, 2, 3-dimethylphenyloxy group, 2, 4-dimethylphenyloxy group, 2, 5-dimethylphenyloxy group, 2, 6-dimethylphenyloxy group, 3, 4-dimethylphenyloxy group, 3, 5-dimethylphenyloxy group, 2-dicyanophenyloxy group, 2, 3-dicyanophenyloxy group, 2-dicyanophenyloxy group, 2, 4-dicyanophenyloxy group, 2, 5-dicyanophenyloxy group, 2, 6-dicyanophenyloxy group, 3, 4-dicyanophenyloxy group, 3, 5-dicyanophenyloxy group, 4-methoxyphenyloxy group, an oxy group having a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like) bonded to one side, such as a 2-methoxyphenyloxy group, a 3-methoxyphenyloxy group, a 4-ethoxyphenyloxy group, a 2-ethoxyphenyloxy group, a 3-ethoxyphenyloxy group, or a group represented by the following chemical formula;

A thio group (sulfo group) to which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) is bonded, such as a methylthio group, an ethylthio group, a propylthio group, a butylthio group, a tert-butylthio group, a pentylthio group, a hexylthio group, (2-ethyl) hexylthio group, a heptylthio group, an octylthio group, a nonylthio group, a decylthio group, an undecylthio group, a dodecylthio group, an eicosylthio group, a phenylthio group, and an o-tolylthio group;

epoxy, oxetanyl, tetrahydrofuranyl, tetrahydropyranyl;

a formyl group;

a carbonyl group (preferably 2 to 12 carbon atoms when the carbonyl group is an alkanoyl group) having a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 11 carbon atoms) or a derivative thereof (for example, a derivative thereof such as a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), or an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)) bonded thereto, such as an acetyl group, a propionyl group, a butyryl group, a 2, 2-dimethylpropionyl group, a pentanoyl group, a hexanoyl group, (2-ethyl) hexanoyl group, a heptanoyl group, an octanoyl group, a nonanoyl group, a decanoyl group, an undecanoyl group, a dodecanoyl group, an heneicosanoyl group, and a benzoyl group;

An oxycarbonyl group in which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) is bonded, such as a methoxycarbonyl group, an ethoxycarbonyl group, a propoxycarbonyl group, a butoxycarbonyl group, a tert-butoxycarbonyl group, a pentyloxycarbonyl group, a hexyloxycarbonyl group, (2-ethyl) a hexyloxycarbonyl group, a heptyloxycarbonyl group, an octyloxycarbonyl group, a nonyloxycarbonyl group, a decyloxycarbonyl group, a undecyloxycarbonyl group, a dodecyloxycarbonyl group, an eicosyloxycarbonyl group, a phenyloxycarbonyl group, or an o-tolyloxycarbonyl group represented by the following chemical formula);

an amino group; n-methylamino, N-dimethylamino, N-ethylamino, N-diethylamino, N-propylamino, N-dipropylamino, N-isopropylamino, N-diisopropylamino, N-butylamino, N-dibutylamino, N-isobutylamino, N-diisobutylamino, N-sec-butylamino, N-di-sec-butylamino, N-tert-butylamino, N-di-tert-butylamino, N-pentylamino, N-dipentylamino, N- (1-ethylpropyl) amino, N-di (1-ethylpropyl) amino, N-hexylamino, N-dihexylamino, N- (2-ethyl) hexylamino, N-diethylamino, N-propylamino, N-dipropylamino, N-isopropylamino, N-di-sec-butylamino, N-pentylamino, N-dipentylamino, N-1-ethylpropyl) amino, N-di (1-ethylpropyl) amino, N-hexylamino, N-butylamino, N-butylamino, N-di-butylamino, N-butylamino, N, n, N-di (2-ethyl) hexylamino group, N-heptylamino group, N-diheptylamino group, N-octylamino group, N-dioctylamino group, N-nonylamino group, N-dinonylamino group, N-phenylamino group, N-diphenylamino group, N-ethylmethylamino group, N-propylmethylamino group, N-isopropylmethylamino group, N-butylmethylamino group, N-decylamino group, N-decylmethylamino group, N-undecylamino group, N-undecylmethylamino group, N-dodecylamino group, N-dodecylmethylamino group, N-eicosylamino group, N-eicosylmethyl amino group, An amino group substituted with 1 or 2 hydrocarbon groups having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or derivative groups thereof (for example, groups derived from carboxyl, sulfo, nitro, hydroxyl, halogen (preferably chlorine atom), alkylsulfamoyl having 1 to 10 carbon atoms (preferably octylsulfamoyl), and the like, such as an N, N-tert-butylmethylamino group, an N, N-phenylmethylamino group, and the like, and groups represented by the following chemical formula);

A sulfamoyl group; n-methylsulfamoyl, N-dimethylsulfamoyl, N-ethylsulfamoyl, N-diethylsulfamoyl, N-propylsulfamoyl, N-dipropylsulfamoyl, N-isopropylsulfamoyl, N-diisopropylsulfamoyl, N-butylsulfamoyl, N-dibutylsulfamoyl, N-isobutylsulfamoyl, N-diisobutylsulfamoyl, N-sec-butylsulfamoyl, N-tert-butylsulfamoyl, N-di-tert-butylsulfamoyl, N-pentylsulfamoyl, N-dipentylsulfamoyl, N- (1-ethylpropyl) sulfamoyl, N-di (1-ethylpropyl) sulfamoyl, N-diethylsulfamoyl, N-di (1-ethylpropyl) sulfamoyl, N-diethylsulfamoyl, N-butylsulfamoyl, N-di (1-ethylpropyl) sulfamoyl, N-butylsulfamoyl, N-di (1-isobutylsulfamoyl), N-dibutylsulfamoyl, N, di (1-di (ethyl, N, N, N-hexylsulfamoyl, N-dihexylsulfamoyl, N- (2-ethyl) hexylsulfamoyl, N-di (2-ethyl) hexylsulfamoyl, N-heptylsulfamoyl, N-diheptylsulfamoyl, N-octylsulfamoyl, N-dioctylsulfamoyl, N-octylmethylsulfamoyl, N-nonylsulfamoyl, N-dinonylsulfamoyl, N-phenylsulfamoyl, N-diphenylsulfamoyl, N-ethylmethylsulfamoyl, N-propylmethylsulfamoyl, N-isopropylmethylsulfamoyl, N-butylmethylsulfamoyl, N-decylsulfamoyl, N-decylmethylsulfamoyl, Sulfamoyl groups substituted with 1 or 2 hydrocarbon groups having 1 to 20 (preferably 1 to 10) carbon atoms or derivative groups thereof (for example, groups derived from carboxyl, sulfo, nitro, hydroxyl, halogen (preferably chlorine atom), alkylsulfamoyl having 1 to 10 carbon atoms (preferably octylsulfamoyl), and the like, such as N-undecylsulfamoyl, N-undecylmethylsulfamoyl, N-dodecylsulfamoyl, N-dodecylmethylsulfamoyl, N-eicosylsulfamoyl, N-eicosylmethylsulfamoyl, N-tert-butylmethylsulfamoyl, N-phenylmethylsulfamoyl, and the like, and groups represented by the following chemical formulae);

A formylamino group; acetylamino, propionylamino, butyrylamino, 2-dimethylpropionylamino, valerylamino, hexanoylamino, (2-ethyl) hexanoylamino, heptanoylamino, a carbonylamino group (preferably 1 to 12 carbon atoms in the case where the carbonylamino group is an alkanoylamino group), to which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 12 carbon atoms) or a derivative thereof (for example, a derivative thereof such as a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)) is bonded, such as an octanoylamino group, a nonanoylamino group, a decanoylamino group, a undecanoylamino group, a dodecanoylamino group, a heneicosanoylamino group, or a benzoylamino group represented by the following chemical formula;

a hydroxyl group; halogen atoms such as fluorine atom, chlorine atom, bromine atom and iodine atom;

carboxy, -CO₂M²(M²Is an alkali metal, preferably lithium, sodium, potassium); sulfo, -SO₃M²(M²Is alkali goldGenus, preferably lithium, sodium, potassium); a nitro group; a cyano group;

a formyloxy group; acetoxy, propionyloxy, butyryloxy, 2-dimethylpropionyloxy, pentanoyloxy, hexanoyloxy, (2-ethyl) hexanoyloxy, heptanoyloxy, a carbonyloxy group (preferably 1 to 10 carbon atoms in the case where the carbonyloxy group is an alkanoyloxy group) to which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or a derivative thereof (for example, a derivative thereof such as a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)) is bonded, such as an octanoyloxy group, a nonanoyloxy group, a decanoyloxy group, a undecanoyloxy group, a dodecanoyloxy group, a heneicosanoyloxy group, a benzoyloxy group, and the like, and a group represented by the following chemical formula;

A sulfonyl group having a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like) bonded thereto, such as a methylsulfonyl group, an ethylsulfonyl group, a propylsulfonyl group, a butylsulfonyl group, a pentylsulfonyl group, a hexylsulfonyl group, a (2-ethyl) hexylsulfonyl group, a heptylsulfonyl group, an octylsulfonyl group, a nonylsulfonyl group, a decylsulfonyl group, an undecylsulfonyl group, a dodecylsulfonyl group, an eicosylsulfonyl group, a phenylsulfonyl group, a p-tolylsulfonyl group, or the like represented by the following chemical formula;

a carbamoyl group; n-methylcarbamoyl, N-dimethylcarbamoyl, N-ethylcarbamoyl, N-diethylcarbamoyl, N-propylcarbamoyl, N-dipropylcarbamoyl, N-isopropylcarbamoyl, N-diisopropylcarbamoyl, N-butylcarbamoyl, N-dibutylcarbamoyl, N-isobutylcarbamoyl, N-diisobutylcarbamoyl, N-sec-butylcarbamoyl, N-di-sec-butylcarbamoyl, N-tert-butylcarbamoyl, N-di-tert-butylcarbamoyl, N-pentylcarbamoyl, N-dipentylcarbamoyl, N- (1-ethylpropyl) carbamoyl, N-ethylcarbamoyl, N-diethylcarbamoyl, N-isopropylcarbamoyl, N-diisopropylcarbamoyl, N-isopropylcarbamoyl, N-butylcarbamoyl, N-t-butylcarbamoyl, N-t-butylcarbamoyl, N-N-butylcarbamoyl, N-t-butylcarbamoyl, N-N-butylcarbamoyl, N-t-N-t-butylcarbamoyl, N-t-butylcarbamoyl, N-t, N, N-di (1-ethylpropyl) carbamoyl, N-hexylcarbamoyl, N-dihexylcarbamoyl, N- (2-ethyl) hexylcarbamoyl, N-di (2-ethyl) hexylcarbamoyl, N-heptylcarbamoyl, N-diheptylcarbamoyl, N-octylcarbamoyl, N-dioctylcarbamoyl, N-nonylcarbamoyl, N-octylmethylcarbamoyl, N-octylbutylcarbamoyl, N-dinonylcarbamoyl, N-phenylcarbamoyl, N-diphenylcarbamoyl, N-ethylmethylcarbamoyl, N-propylmethylcarbamoyl, N-ethylmethylcarbamoyl, N-propylmethylcarbamoyl, N-ethylhexylcarbamoyl, N-dihexylcarbamoyl, N- (2-ethyl) hexylcarbamoyl, N-octylcarbamoyl, N-diheptylcarbamoyl, N-octylcarbamoyl, N-nonylcarbamoyl, N-octylcarbamoyl, N-octylmethylcarbamoyl, N-octylcarbamoyl, N-octylmethylcarbamoyl, N-nonylcarbamoyl, N-dimethylcarbamoyl, N, a hydrocarbon group having 1 to 2 carbon atoms of 1 to 20 (preferably 1 to 10 carbon atoms) or a derivative thereof (for example, a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an N, N-isopropylmethylcarbamoyl group, an N, N-butylmethylcarbamoyl group, an N-decylmethylcarbamoyl group, an N, N-decylmethylcarbamoyl group, an N-undecylcarbamoyl group, an N, N-undecylmethylcarbamoyl group, an N-dodecylcarbamoyl group, an N, N-dodecylmethylcarbamoyl group, an N-eicosylcarbamoyl group, an N, N-eicosylmethylcarbamoyl group, an N, N-tert-butylmethylcarbamoyl group, an N, N-phenylmethylcarbamoyl group, etc., and a group represented by the following chemical formula, etc. (preferably a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), a derivative thereof, A carbamoyl group substituted with an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably, an octylsulfamoyl group) or the like;

A hydrocarbon group having 1 to 20 carbon atoms, which is obtained by substituting all hydrogen atoms with fluorine atoms such as a trifluoromethyl group, a perfluoroethyl group, a perfluoropropyl group, a perfluoroisopropyl group, a perfluorobutyl group, a perfluoropentyl group, a perfluorohexyl group, a perfluoroheptyl group, a perfluorooctyl group, a perfluorononyl group, a perfluorodecyl group, a perfluoroundecyl group, a perfluorododecyl group, a perfluoroeicosyl group, a perfluorocyclohexyl group, and a perfluorophenyl group;

a hydrocarbon group having 1 to 20 carbon atoms which has, as a substituent, a linear or branched alkyl group having 1 to 20 carbon atoms in which all hydrogen atoms are substituted with fluorine atoms, such as a perfluoroethylmethyl group, a perfluoropropylmethyl group, a perfluoroisopropylmethyl group, a perfluorobutylmethyl group, a perfluoropentylmethyl group, a perfluorohexylmethyl group, a perfluoroheptylmethyl group, a perfluorooctylmethyl group, a perfluorononylmethyl group, a perfluorodecylmethyl group, a perfluoroundecylmethyl group, a perfluorododecylmethyl group, and a perfluoroeicosylmethyl group;

a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) in which some hydrogen atoms are substituted with fluorine, such as a 2-fluorophenyl group, a 3-fluorophenyl group, a 4-fluorophenyl group, and a 2,4, 6-trifluorophenyl group;

-CO-SH、-CO-S-CH₃、-CO-S-CH₂CH₃、-CO-S-CH₂-CH₂-CH₃and-CO-S-CH₂-CH₂-CH₂-CH₃An alkylthio carbonyl group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms), -CO-S-C ₆H₅An arylthiocarbonyl group having 6 to 20 carbon atoms;

a group represented by the following chemical formula, — COCO-R (wherein R represents a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group)), or the like);

-NRCONR represented by the following chemical formula₂(wherein R represents a hydrogen atom and the number of carbon atoms is 1A hydrocarbyl group of up to 20 (for example, a hydrocarbyl group having 1 to 20 carbon atoms among the above-mentioned hydrocarbyl groups), or a derivative thereof (for example, a derivative thereof such as a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), and the like), wherein R's may be the same or different from each other, and may be bonded to each other to form a ring);

OCONR represented by the following chemical formula₂(wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group having 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like), and R's may be the same or different from each other and may be bonded to each other to form a ring);

A group represented by the following chemical formula-NRCOOR (wherein R represents a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like), wherein R may be the same or different from each other, and may be bonded to each other to form a ring);

*-OP(O)(OCH₃)₂etc.. OP (O) (OR)₂(wherein R represents a hydrogen atom and the number of carbon atoms is 1A hydrocarbyl group of up to 20 (for example, a hydrocarbyl group having 1 to 20 carbon atoms among the above-mentioned hydrocarbyl groups), or a derivative thereof (for example, a derivative thereof such as a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), and the like), wherein R's may be the same or different from each other, and may be bonded to each other to form a ring);

*-Si(CH₃)₃、*-Si(CH₂CH₃)₃、*-Si(C₆H₅)₃and-Si (CH)₃)₂)₃Etc. -SiR₃(wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, a hydrocarbon group having 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like), and R's may be the same or different from each other and may be bonded to each other to form a ring); -SO ₃ ^-；-CO₂ ^-(ii) a And so on.

Examples of the substituent having a valence of 2 include an oxo group, a thioxo group, an imino group substituted with an alkyl group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms), and an imino group substituted with an aryl group having 6 to 20 carbon atoms. Examples of the imino group substituted with an alkyl group include CH₃-N＝、CH₃-CH₂-N＝、CH₃-(CH₂)₂-N ═ and CH₃-(CH₂)₃-N ═ and the like. Examples of the imino group substituted with an aryl group include C₆H₅-N ═ and the like.

As the substituent of the hydrocarbon group having 1 to 40 carbon atoms, preferred is a substituent of group s 1. The derivative group shown below is preferably a derivative group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like.

[ group s1]

An oxy group having a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof bonded to one side thereof;

a carbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof is bonded;

an oxycarbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof is bonded;

an amino group; amino substituted by 1 or 2 alkyl with 1-20 carbon atoms or derivative groups thereof; a sulfamoyl group; a sulfamoyl group substituted with 1 or 2 hydrocarbon groups having 1 to 20 carbon atoms or derivative groups thereof; a carbonylamino group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof is bonded; a hydroxyl group; a halogen atom; -CO ₂M (preferably carboxyl group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom);

-SO₃m (preferably sulfo) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom); a nitro group; a cyano group; a carbonyloxy group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof is bonded; a sulfonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivative thereof is bonded; a carbamoyl group; carbamoyl substituted by 1 or 2 hydrocarbon groups having 1 to 20 carbon atoms or derivative groups thereof; a hydrocarbon group having 1 to 20 carbon atoms, wherein all hydrogen atoms are substituted with fluorine atoms; a hydrocarbon group having 1 to 20 carbon atoms, which has a linear or branched alkyl group having 1 to 20 carbon atoms, wherein all hydrogen atoms are substituted with fluorine atoms, as a substituent; a hydrocarbon group having 1 to 20 carbon atoms, wherein a part of hydrogen atoms is substituted with fluorine; an oxo group; -SO₃ ^-；-CO₂ ^-。

The substituent of the hydrocarbon group having 1 to 40 carbon atoms is more preferably a substituent of group s 2.

[ group s2]

An oxy group having a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof bonded to one side thereof;

a carbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded;

an oxycarbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded;

An amino group; an amino group substituted with 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms;

a sulfamoyl group; a sulfamoyl group substituted with 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms or derivative groups thereof; a carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded; a hydroxyl group; fluorine atom, chlorine atom, bromine atom; -CO₂M (preferably carboxyl group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom);

-SO₃m (preferably sulfo) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom); a nitro group; a cyano group;

a carbonyloxy group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded;

a sulfonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded;

a carbamoyl group; carbamoyl substituted by 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms or derivative groups thereof; a hydrocarbon group having 1 to 10 carbon atoms, wherein all hydrogen atoms are substituted with fluorine atoms;

a hydrocarbon group having 1 to 10 carbon atoms, which has a linear or branched alkyl group having 1 to 10 carbon atoms, wherein all hydrogen atoms are substituted with fluorine atoms, as a substituent; a hydrocarbon group having 1 to 10 carbon atoms, wherein a part of hydrogen atoms is substituted with fluorine; an oxo group; -SO ₃ ^-；-CO₂ ^-。

As R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6The substituted hydrocarbon group having 1 to 40 carbon atoms includes a substituted hydrocarbon group having 1 to 40 carbon atoms having a valence of 1 or 2; preferably, the hydrocarbon-based compound includes a saturated or unsaturated chain hydrocarbon group having 1 to 30 carbon atoms and having a substituent having a valence of 1 or 2, a saturated or unsaturated alicyclic hydrocarbon group having 3 to 30 carbon atoms and having a substituent having a valence of 1 or 2, an aromatic hydrocarbon group having 6 to 30 carbon atoms and having a substituent having a valence of 1 or 2, or a group having 4 to 30 carbon atoms and having a substituent having a valence of 1 or 2, which are a combination of the hydrocarbon groups;

more preferably, the hydrocarbon group includes a saturated or unsaturated chain hydrocarbon group having 1 to 20 carbon atoms having a substituent of group s1, a saturated or unsaturated alicyclic hydrocarbon group having 3 to 20 carbon atoms having a substituent of group s1, an aromatic hydrocarbon group having 6 to 20 carbon atoms having a substituent of group s1, or a combination of hydrocarbon groups, and the group has 4 to 20 carbon atoms having a substituent of group s 1;

particularly preferred examples thereof include a saturated or unsaturated chain hydrocarbon group having 1 to 15 carbon atoms having a substituent of group s2, a saturated or unsaturated alicyclic hydrocarbon group having 3 to 15 carbon atoms having a substituent of group s2, an aromatic hydrocarbon group having 6 to 15 carbon atoms having a substituent of group s2, or a group having 4 to 15 carbon atoms having a substituent of group s2, which is a combination of hydrocarbon groups.

As R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6The heterocyclic group represented by (a) may be monocyclic or polycyclic, and is preferably a heterocyclic ring containing a heteroatom as a constituent of the ring. Examples of the hetero atom include a nitrogen atom, an oxygen atom, a sulfur atom and the like.

The number of carbon atoms of the heterocyclic group is preferably 3 to 30, more preferably 3 to 22, further preferably 3 to 20, further preferably 3 to 18, further more preferably 3 to 15, and particularly preferably 3 to 14.

Examples of the heterocyclic ring containing a nitrogen atom include monocyclic saturated heterocyclic rings such as aziridine, azetidine, pyrrolidine, piperidine, and piperazine; five-membered ring system unsaturated heterocycles such as pyrrole (e.g., 2, 5-dimethylpyrrole), pyrazole (e.g., 2-methylpyrazole and 3-methylpyrazole), imidazole, 1,2, 3-triazole and 1,2, 4-triazole; a six-membered ring system unsaturated heterocycle such as pyrimidine, pyrazine and 1,3, 5-triazine, for example pyridine, pyridazine and 6-methylpyrimidine; a fused bicyclic heterocycle such as quinoxaline (e.g., indazole, indoline, isoindoline, indole, indolizine, benzimidazole, quinoline, isoquinoline, 5,6,7, 8-tetrahydro (3-methyl) quinoxaline or 3-methylquinoxaline, quinazoline, cinnoline, phthalazine, naphthyridine, purine, pteridine, benzopyrazole or phenylpiperidine; condensed tricyclic heterocycles such as carbazole, acridine and phenazine; and so on.

Examples of the heterocyclic ring containing an oxygen atom include:

monocyclic saturated heterocycles such as oxetane, tetrahydrofuran, tetrahydropyran, 1, 3-dioxane, 1, 4-dioxane and 1-cyclopentyldioxolane; bicyclic saturated heterocycles such as 1, 4-dioxaspiro [4.5] decane and 1, 4-dioxaspiro [4.5] nonane; lactone heterocycles such as α -caprolactone, β -propiolactone, γ -butyrolactone, γ -valerolactone and δ -valerolactone; five-membered ring system unsaturated heterocycles such as furan (e.g., 2, 3-dimethylfuran, 2, 5-dimethylfuran); a six-membered ring system unsaturated heterocycle such as 2H-pyran, 4H-pyran;

fused bicyclic heterocycles such as benzopyrans (e.g., 1-benzofuran and 4-methylbenzopyran), benzodioxole, chroman and isochroman; fused tricyclic heterocycles such as xanthene and dibenzofuran; and so on.

Examples of the heterocyclic ring containing a sulfur atom include a five-membered ring system saturated heterocyclic ring such as dithiolane; saturated heterocyclic rings of six-membered ring systems such as thiacyclohexane, 1, 3-dithiane, 2-methyl-1, 3-dithiane and the like; a five-membered ring system unsaturated heterocycle such as thiophene (e.g., 3-methylthiophene, 2-carboxythiophene), benzothiopyran (e.g., 4H-thiopyran, tetrahydrothiopyran); fused bicyclic heterocycles such as benzothiophene; fused tricyclic heterocycles such as thianthrene and dibenzothiophene; and so on.

Examples of the heterocyclic ring containing a nitrogen atom and an oxygen atom include:

monocyclic saturated heterocycles such as morpholine, 2-pyrrolidone, 2-methyl-2-pyrrolidone, 2-piperidone and 2-methyl-2-piperidone; a monocyclic unsaturated heterocycle such as oxazole (e.g., 4-methyloxazole), isoxazole (e.g., 2-methylisoxazole, and 3-methylisoxazole);

fused bicyclic heterocycles such as benzoxazole, benzisoxazole, benzoxazine, benzodioxane, and benzimidazoline; condensed tricyclic heterocycles such as phenoxazine; and so on.

Examples of the heterocyclic ring containing a nitrogen atom and a sulfur atom include monocyclic heterocyclic rings such as thiazoles, e.g., 3-methylthiazole and 2, 4-dimethylthiazole; fused bicyclic heterocycles such as benzothiazole; fused tricyclic heterocycles such as phenothiazine; and so on.

The heterocyclic ring may be a combination of the above-mentioned hydrocarbon groups, and examples thereof include tetrahydrofurylmethyl and the like.

The heterocyclic ring may be a heterocyclic ring represented by the following chemical formula.

The above heterocyclic group may be R^1AZ6～R^5AZ62 or more of them are bonded to form a heterocyclic group. Such heterocyclic radicals contain R^1AZ6～R^5AZ6The bonded benzene ring has a ring structure of 2 or more rings inside. The 2 or more ring structures include, for example, the structures of the following chemical formulae.

The bonding position of the heterocycle is a portion where any hydrogen atom contained in each ring is removed.

R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6The heterocyclic group represented may have a substituent. Examples of the substituent include^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6The hydrocarbon group may have the same substituent as the substituent. In addition, in the case where the above-mentioned heterocyclic ring contains a nitrogen atom as its constituent element, the above-mentioned hydrocarbon group as a substituent may be bonded to the nitrogen atom.

Preferred examples of the substituent include^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6The preferable examples of the substituents which the hydrocarbon group may have are the same.

As R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6The heterocyclic group having a substituent represented by the formula (i) includes a heterocyclic group having a substituent having a valence of 1 or 2, preferably a heterocyclic group having a substituent of group s1, and more preferably a heterocyclic group having a substituent of group s 2.

The substituent (first substituent) that the hydrocarbon group or heterocyclic group may have may be 1 or 2 or more, and 2 or more substituents may be the same or different and independent of each other. Further, the first substituent may have another substituent (second substituent) bonded to the hydrocarbon group included in a part thereof. The second substituent may be selected from the same groups as the first substituent.

Below, for R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6And R^13AZ6Of (a) is-CO-R^102AZ6、-COO-R^101AZ6、-OCO-R^102AZ6、-COCO-R^102AZ6、-O-R^102AZ6、-SO₂-R^101AZ6、-SO₂N(R^102AZ6)₂、-CON(R^102AZ6)₂、-N(R^102AZ6)₂、-NHCO-R^102AZ6、-NHCO-N(R^102AZ6)₂、-NHCOOR^102AZ6、-OCON(R^102AZ6)₂Halogen atom, -SO₃M、-CO₂M is explained. Examples of-CO-R hereinafter^102AZ6、-COO-R^101AZ6、-OCO-R^102AZ6、-COCO-R^102AZ6、-O-R^102AZ6、-SO₂-R^101AZ6、-SO₂N(R^102AZ6)₂、-CON(R^102AZ6)₂、-N(R^102AZ6)₂、-NHCO-R^102AZ6、-NHCO-N(R^102AZ6)₂、-NHCOOR^102AZ6、-OCON(R^102AZ6)₂Preferably in the range corresponding to R^101AZ6、R^102AZ6In which a substituent of group s2, in particular-SO₃ ^-、-CO₂ ^-And the like.

as-CO-R^102AZ6Examples thereof include a formyl group; a carbonyl group (having 2 to 41 carbon atoms when the carbonyl group is an acyl group), wherein the carbonyl group is a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a derivative thereof such as a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like) bonded to a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as an acetyl group, a propionyl group, a butyryl group, a 2, 2-dimethylpropionyl group, a pentanoyl group, a hexanoyl group, a (2-ethyl) hexanoyl group, a heptanoyl group, an octanoyl group, a nonanoyl group, a decanoyl group, a undecanoyl group, a dodecanoyl group, a heneicosanoyl group, a benzoyl group, or the group represented by the above chemical formula (i) and the like), and the carbonyl group corresponding to-CO-R-in the compounds represented by Table 1Z6 to Table 4Z6^102AZ6Preferable examples of the group(s) include a carbonyl group (more preferably 2 to 12 carbon atoms when the carbonyl group is an alkanoyl group) to which a hydrocarbon group having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms) or a derivative thereof is bonded, and compounds represented by tables 1Z6 to 4Z6 corresponding to-CO-R ^102AZ6And the like.

as-COO-R^101AZ6Examples thereof include methoxycarbonyl, ethoxycarbonyl, propoxycarbonyl, tert-butoxycarbonyl, pentyloxycarbonyl, hexyloxycarbonyl, (2-ethyl) hexyloxycarbonyl, heptyloxycarbonyl, octyloxycarbonyl, nonyloxycarbonyl, decyloxycarbonyl, undecyloxycarbonyl, dodecyloxycarbonyl, phenyloxycarbonyl, eicosyloxycarbonyl and the like, and a hydrocarbon group having 1 to 40 (preferably 1 to 20) carbon atoms or a derivative thereof (for example, a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an orthocarbon group bonded to a group represented by the above formula or the likeGroups derived from alkylsulfamoyl (preferably octylsulfamoyl) having 1 to 10 moles) and compounds shown in tables 1Z6 to 4Z6, which correspond to-COO-R^102AZ6Preferred examples of the group (b) include oxycarbonyl groups to which a C1-10 hydrocarbon group or a derivative thereof is bonded and compounds represented by tables 1Z6 to 4Z6 corresponding to-COO-R^102AZ6And the like.

as-OCO-R^102AZ6Examples thereof include a formyloxy group; acetoxy, propionyloxy, butyryloxy, 2-dimethylpropionyloxy, pentanoyloxy, hexanoyloxy, (2-ethyl) hexanoyloxy, heptanoyloxy, octanoyloxy, nonanoyloxy, decanoyloxy, undecanoyloxy, dodecanoyloxy, heneicosanoyloxy, benzoyloxy and the like, carbonyloxy (having 2 to 41 carbon atoms in the case where the carbonyloxy group is an acyloxy group), carbonyloxy having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a derivative thereof derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) bonded to a group represented by the above formula) and the like, And the compounds shown in tables 1Z6 to 4Z6 correspond to-OCO-R ^102AZ6The group (B) preferably includes a carbonyloxy group (more preferably 2 to 12 carbon atoms in the case where the carbonyloxy group is an acyloxy group) to which a hydrocarbon group having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms) or a derivative thereof is bonded, and a compound represented by any one of tables 1Z6 to 4Z6 corresponding to-OCO-R^102AZ6And the like.

as-COCO-R^102Z6Examples thereof include methyloxalyl, ethyloxalyl, propyloxalyl, butyloxalyl, pentyloxalyl, hexyloxalyl, (2-ethyl) hexyloxalyl, heptyloxalyl, octyloxalyl, nonyloxalyl, decyloxyl, undecyloxalyl, dodecyloxalyl, eicosanoyl, cyclopentyloxalyl, cyclohexyloxalyl, phenyloxalyl, p-tolyloxalyl and the like, and a group represented by the above-mentioned chemical formulaAnd an oxalyl group to which a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a derivative thereof such as a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) is bonded).

as-O-R^102AZ6There may be mentioned a hydroxyl group; methoxy, ethoxy, propoxy, isopropoxy, butoxy, isobutoxy, sec-butoxy, tert-butoxy, pentyloxy, hexyloxy, heptyloxy, octyloxy, nonyloxy, decyloxy, undecyloxy, dodecyloxy, (2-ethyl) hexyloxy, eicosyloxy, 1-phenylethoxy, 1-methyl-1-phenylethoxy, phenyloxy, 2, 3-dimethylphenyloxy, 2, 4-dimethylphenyloxy, 2, 5-dimethylphenyloxy, 2, 6-dimethylphenyloxy, 3, 4-dimethylphenyloxy, 3, 5-dimethylphenyloxy, 2-dicyanophenyloxy, 2, 3-dicyanophenyloxy, 2, 4-dicyanophenyloxy, sec-butyloxy, tert-butyloxy, pentyloxy, hexyloxy, heptyloxy, octyloxy, decyloxy, 2, 3-dimethylphenyloxy, 2, 4-dimethylphenyloxy, 2, 4-dimethylphenyloxy, 3-dimethylphenyloxy, 2-dicyanophenyloxy, 2, 4-di-yloxy, 2-di-methyl-1-phenylethoxy, 2, 4-di-methyl, and mixtures thereof, 2, 5-dicyanophenyloxy group, 2, 6-dicyanophenyloxy group, 3, 4-dicyanophenyloxy group, 3, 5-dicyanophenyloxy group, 4-methoxyphenyloxy group, 2-methoxyphenyloxy group, examples of the oxygen group include an oxygen group having a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a group derived from a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like bonded thereto, such as a 3-methoxyphenyloxy group, a 4-ethoxyphenyloxy group, a 2-ethoxyphenyloxy group, a 3-ethoxyphenyloxy group, or a group represented by the above chemical formula), and compounds shown in tables 1Z6 to 4Z6, which correspond to — O — R. ^102AZ6Preferable examples of the group (b) include an oxy group to which a C1-10 hydrocarbon group or a derivative thereof is bonded, and compounds represented by tables 1Z6 to 4Z6 corresponding to-O-R^102AZ6And the like.

as-SO₂-R^101AZ6Examples thereof include methylsulfonyl, ethylsulfonyl, propylsulfonyl, butylsulfonyl, pentylsulfonyl, hexylsulfonyl, (2-ethyl) hexylsulfonyl, heptylsulfonyl, ethylsulfonyl, pentylsulfonyl, ethylsulfonyl, 2-hexylsulfonyl, ethylsulfonyl, ethyl,Octylsulfonyl group, nonylsulfonyl group, decylsulfonyl group, undecylsulfonyl group, dodecylsulfonyl group, eicosylsulfonyl group, phenylsulfonyl group, p-tolylsulfonyl group and the like, and sulfonyl groups in which a hydrocarbon group having 1 to 40 (preferably 1 to 20) carbon atoms or a derivative thereof (for example, a derivative thereof such as a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group) is bonded such as the group represented by the above chemical formula) and the compounds shown in tables 1Z6 to 4Z6 correspond to-SO₂-R^102AZ6Preferable examples of the group (b) include a sulfonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded and a group corresponding to-SO in the compounds represented by tables 1Z6 to 4Z6 ₂-R^102AZ6And the like.

as-SO₂N(R^102AZ6)₂Examples thereof include: a sulfamoyl group; n-methylsulfamoyl, N-ethylsulfamoyl, N-propylsulfamoyl, N-isopropylsulfamoyl, N-butylsulfamoyl, N-isobutylsulfamoyl, N-sec-butylsulfamoyl, N-tert-butylsulfamoyl, N-pentylsulfamoyl, N- (1-ethylpropyl) sulfamoyl, N-hexylsulfamoyl, N- (2-ethyl) hexylsulfamoyl, N-heptylsulfamoyl, N-octylsulfamoyl, N-nonylsulfamoyl, N-decylsulfamoyl, N-undecylsulfamoyl, N-dodecylsulfamoyl, N-eicosylsulfamoyl, N-phenylsulfamoyl, etc., and a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group represented by the above formula, or a derivative thereof Sulfamoyl groups substituted with a raw group (e.g., a group derived from carboxyl group, sulfo group, nitro group, hydroxyl group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group)), and compounds represented by tables 1Z6 to 4Z6, which correspond to — SO₂NH(R^102AZ6X)(R^102AZ6XIs not a hydrogen atom, other than, and R^102AZ6The same as defined above), etc.; n, N-dimethylsulfamoyl, N-ethylmethylsulfamoyl, N-diethylsulfamoyl, N-propylmethylsulfamoyl, N-dipropylamido Sulfonyl, N-isopropylmethylsulfamoyl, N-diisopropylsulfamoyl, N-tert-butylmethylsulfamoyl, N-diisobutylaminosulfonyl, N-di-sec-butylsulfamoyl, N-di-tert-butylsulfamoyl, N-butylmethylsulfamoyl, N-dibutylsulfamoyl, N-dipentylsulfamoyl, N-bis (1-ethylpropyl) sulfamoyl, N-dihexylsulfamoyl, N-bis (2-ethyl) hexylsulfamoyl, N-diheptylsulfamoyl, N-octylmethylsulfamoyl, N-dioctylsulfamoyl, N-dinonylsulfamoyl, N-decylmethylsulfamoyl, Sulfamoyl groups substituted with 2 hydrocarbon groups having 1 to 40 (preferably 1 to 20) carbon atoms or derivative groups thereof (e.g., groups derived from carboxyl, sulfo, nitro, hydroxyl, halogen (preferably chlorine atom), alkylsulfamoyl having 1 to 10 carbon atoms (preferably octylsulfamoyl), and the like, such as N, N-undecylmethylsulfamoyl, N-dodecylmethylsulfamoyl, N-eicosylmethylsulfamoyl, N-phenylmethylsulfamoyl, N-diphenylsulfamoyl, and the like, and groups represented by the above chemical formulae), and sulfamoyl groups derived from compounds represented by tables 1Z6 to 4Z6, which correspond to-SO ₂N(R^102AZ6X)₂(R^102AZ6XIs not a hydrogen atom, other than, and R^102AZ6The same as defined above), and the like, and preferably include sulfamoyl groups substituted with 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms or derivatives thereof and compounds represented by tables 1Z6 to 4Z6, which correspond to-SO₂N(R^102AZ6)₂And the like.

as-CON (R)^102AZ6)₂Examples thereof include:

a carbamoyl group; n-methylcarbamoyl, N-ethylcarbamoyl, N-propylcarbamoyl, N-isopropylcarbamoyl, N-butylcarbamoyl, N-isobutylcarbamoyl, N-sec-butylcarbamoyl, N-tert-butylcarbamoyl, N-pentylcarbamoyl, N- (1-ethylpropyl) carbamoyl, N-hexylcarbamoyl, N- (2-ethyl) hexylcarbamoyl, N-heptylcarbamoyl, N-octylcarbamoyl and N-nonylcarbamoyl, N-decylcarbamoyl, N-decadecadecylcarbamoylMonoalkylcarbamoyl, N-dodecylcarbamoyl, N-eicosylcarbamoyl, N-phenylcarbamoyl and the like, and carbamoyl groups represented by the above chemical formulae which are substituted with a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a derivative thereof with a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) or the like), and a compound represented by one of tables 1Z6 to 4Z6 corresponds to-CONH (R-CONH) ^102AZ6X)(R^102AZ6XIs not a hydrogen atom, other than, and R^102AZ6The same as defined above), etc.;

n, N-dimethylcarbamoyl group, N-ethylmethylcarbamoyl group, N-diethylcarbamoyl group, N-propylmethylcarbamoyl group, N-dipropylcarbamoyl group, N-isopropylmethylcarbamoyl group, N-diisopropylcarbamoyl group, N-tert-butylmethylcarbamoyl group, N-diisobutylcarbamoyl group, N-di-sec-butylcarbamoyl group, N-di-tert-butylcarbamoyl group, N-butylmethylcarbamoyl group, N-dibutylcarbamoyl group, N-butyloctylcarbamoyl group, N-dipentylcarbamoyl group, N-di (1-ethylpropyl) carbamoyl group, N-diethylcarbamoyl group, N-diisopropylcarbamoyl group, N-di (1-ethylpropyl) carbamoyl group, N-t-butylmethylcarbamoyl group, N-di-butylmethylcarbamoyl group, N-t-butylmethylcarbamoyl group, N-di (1-ethylpropyl) carbamoyl group, N-t-butylmethylcarbamoyl group, N-di-isobutylcarbamoyl group, N-di (s-butylmethylcarbamoyl group, N-di-butylmethylcarbamoyl group, N-di-N-butylcarbamoyl group, N, a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a carboxyl group, a sulfo group, an N, N-di (2-ethyl) hexylcarbamoyl group, an N, N-diheptylcarbamoyl group, an N, N-octylmethylcarbamoyl group, an N, N-dinonylcarbamoyl group, an N, N-decylmethylcarbamoyl group, an N, N-undecylmethylcarbamoyl group, an N, N-dodecylmethylcarbamoyl group, an N, N-eicosylmethylcarbamoyl group, an N, N-phenylmethylcarbamoyl group, an N, N-diphenylcarbamoyl group, etc., and a group represented by the above chemical formula, A carbamoyl group substituted with a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), or the like), and a compound represented by any one of tables 1Z6 to 4Z6 corresponding to-CON (R) ^102AZ6X)₂(R^102AZ6XIs not a hydrogen atom, other than, and R^102AZ6The same as defined above) and the like,

preferred examples thereof include a carbamoyl group substituted with 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms or a derivative thereof and a compound represented by any one of tables 1Z6 to 4Z6 corresponding to-CON (R)^102AZ6)₂And the like.

as-N (R)^102AZ6)₂Examples thereof include: an amino group; a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom)), such as an N-methylamino group, an N-ethylamino group, an N-propylamino group, an N-isopropylamino group, an N-butylamino group, an N-isobutylamino group, an N-sec-butylamino group, an N-tert-butylamino group, an N-pentylamino group, an N-hexylamino group, an N- (2-ethyl) hexylamino group, an N-heptylamino group, an N-octylamino group, an N-nonylamino group, an N-decylamino group, an N-undecylamino group, an N-dodecylamino group, an N-eicosylamino group, an N-phenylamino group, and the like, and a group represented by the above chemical formula, A group derived from an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) and the like) and a compound shown in tables 1Z6 to 4Z6 corresponding to-NH (R^102AZ6X) (wherein, R ^102AZ6XIs not a hydrogen atom, other than, and R^102AZ6The same as defined above), etc.;

n, N-dimethylamino group, N-ethylmethylamino group, N-diethylamino group, N-propylmethylamino group, N-dipropylamino group, N-isopropylmethylamino group, N-diisopropylamino group, N-tert-butylmethylamino group, N-diisobutylamino group, N-di-sec-butylamino group, N-di-tert-butylamino group, N-butylmethylamino group, N-dibutylamino group, N-dipentylamino group, N-bis (1-ethylpropyl) amino group, N-dihexylamino group, N-bis (2-ethyl) hexylamino group, N-diheptylamino group, N-dioctylamino group, N, n-dinonylamino group, N-decylmethylamino group, N-undecylmethylamino group, N-dodecylmethylamino group, N-eicosylmethyl amino group, N-phenylmethylamino group, N-diphenylamino group, etc., and a group represented by the above chemical formula, etc., having 2 carbon atomsAmino groups substituted with 1 to 40 (preferably 1 to 20 carbon atoms) hydrocarbon groups or derivative groups thereof (for example, groups derived from carboxyl groups, sulfo groups, nitro groups, hydroxyl groups, halogens (preferably chlorine atoms), alkylsulfamoyl groups (preferably octylsulfamoyl groups) having 1 to 10 carbon atoms), and the like, and compounds shown in tables 1Z6 to 4Z6 corresponding to-N (R is ^102AZ6X)₂(wherein, R^102AZ6XIs not a hydrogen atom, other than, and R^102AZ6The same as defined above), and the like, and preferably include an amino group substituted with 1 or 2 hydrocarbon groups having 1 to 10 carbon atoms or derivatives thereof and a group corresponding to-N (R) in the compounds shown in tables 1Z6 to 4Z6^102AZ6)₂And the like.

as-NHCO-R^102AZ6Examples thereof include formylamino; acetylamino, propionylamino, butyrylamino, 2-dimethylpropionylamino, valerylamino, hexanoylamino, (2-ethyl) hexanoylamino, heptanoylamino, examples of the carbonylamino group (the number of carbon atoms is 1 to 40 in the case where the carbonylamino group is an acylamino group), to which a hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof (for example, a derivative thereof such as a carboxyl group, a sulfo group, a nitro group, a hydroxyl group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) is bonded such as an octanoylamino group, a nonanoylamino group, a decanoylamino group, a undecanoylamino group, a dodecanoylamino group, a heneicosanoylamino group, a benzoylamino group and the like, and the compounds shown in tables 1Z6 to 4Z6 correspond to-NHCO-R. ^102AZ6Preferable examples of the group (b) include a carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivative thereof is bonded (in the case where the carbonylamino group is an alkanoylamino group, the carbon number is more preferably 1 to 10), and compounds represented by tables 1Z6 to 4Z6, wherein the compound corresponds to-NHCO-R^102AZ6And the like.

as-NHCON (R)^102AZ6)₂Examples thereof include the groups listed above and the compounds shown in tables 1Z6 to 4Z6 which correspond to-NHCON (R)^102AZ6)₂And the like.

as-NHCOOR^102AZ6Examples thereof include the groups listed above and the groups corresponding to-NHCOOR among the compounds shown in tables 1Z6 to 4Z6^102AZ6And the like.

as-OCON (R)^102AZ6)₂Examples thereof include those corresponding to-OCON (R) in the above-mentioned groups and the compounds shown in tables 1Z6 to 4Z6^102AZ6)₂And the like.

The halogen atom is preferably a fluorine atom, a chlorine atom, a bromine atom, an iodine atom or the like.

as-SO₃M and-CO₂M in M is a hydrogen atom; the alkali metal atom such as lithium atom, sodium atom and potassium atom, preferably hydrogen atom, sodium atom and potassium atom.

The above-mentioned-CO-R^102AZ6、-COO-R^102AZ6、-OCO-R^102AZ6、-COCO-R^102AZ6、-O-R^102AZ6、-SO₂-R^102AZ6、-SO₂N(R^102AZ6)₂、-CON(R^102AZ6)₂、-N(R^102AZ6)₂、-NHCO-R^102AZ6、-NHCON(R^102AZ6)₂、-NHCOOR^102AZ6、-OCON(R^102AZ6)₂The number of the substituents (first substituents) contained in (2) may be 1 or 2 or more, and 2 or more substituents may be the same or different and independent of each other.

Further, the first substituent may have another substituent (second substituent) bonded to the hydrocarbon group included in a part thereof. The second substituent may be selected from the same groups as the first substituent.

As R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6And R^13AZ6Preferably a hydrogen atom, -CO-R^102AZ6、-COO-R^101AZ6、-COCO-R^102AZ6、-O-R^102AZ6、-SO₂-R^101AZ6、-SO₂N(R^102AZ6)₂、-CON(R^102AZ6)₂、-N(R^102AZ6)₂、-NHCO-N(R^102AZ6)₂、-NHCOOR^102AZ6、-OCON(R^102AZ6)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M、-SO₃ ^-、-CO₂ ^-The hydrocarbon group may have a substituent and has 1 to 40 carbon atoms, or the heterocyclic group may have a substituent.

As R^101AZ6The hydrocarbon group having 1 to 40 carbon atoms which may have a substituent is preferable.

As R^102AZ6Preferably, the hydrocarbon group has 1 to 40 carbon atoms and may have a substituent.

R^2AZ6And R^3AZ6、R^3AZ6And R^4AZ6And R^4AZ6And R^5AZ6The ring formed is fused with the benzene ring of the isoindoline skeleton of the compound represented by the formula (IZ 6). As R^2AZ6And R^3AZ6、R^3AZ6And R^4AZ6And R^4AZ6And R^5AZ6Examples of the condensed ring structure of the ring formed and the benzene ring include indene, naphthalene, biphenylene, indacene, acenaphthylene, fluorene, phenalene, phenanthrene, anthracene, fluoranthene, acephenanthrene, aceanthrylene, and benzo [9,10 ] ene]Phenanthrene, pyrene,

Hydrocarbon-based condensed ring structures such as N-methylphthalimide, N- (1-phenylethyl) phthalimide and butachlor, and partially reduced products thereof (for example, 9, 10-dihydroanthracene, 1,2,3, 4-tetrahydronaphthalene, etc.); indole, isoindole, indazole, quinoline, isoquinoline, phthalazine, quinoxaline, quinazoline, cinnoline, carbazole, carboline, phenanthridine, acridine, quinoline, quinoxaline, quinoline, and/or quinoline derivative,

Nitrogen-containing fused heterocycles and partial reductants thereof such as pyridine, phenanthroline and phenazine; oxygen-containing fused heterocycles such as 3-hydrobenzofuran-2-one and partial reductants thereof.

R^2AZ6And R^3AZ6、R^3AZ6And R^4AZ6And R^4AZ6And R^5AZ6In the case of forming a ring, the ring may have a substituent. AsThe substituent includes^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6The hydrocarbon group may have the same substituent as the substituent. Preferred examples of the substituent include^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6The preferable examples of the substituents which the hydrocarbon group may have are the same.

R^3AZ6And R^4AZ6In the case of forming a ring, R^2AZ6And R^5AZ6Independently of one another, hydrogen atoms, amino groups or hydroxyl groups are preferred.

R^2AZ6And R^3AZ6When a ring is formed, R is preferably^4AZ6And R^5AZ6Does not form a ring, more preferably R^4AZ6And R^5AZ6Is a hydrogen atom.

In addition, R^4AZ6And R^5AZ6When a ring is formed, R is preferably^2AZ6And R^3AZ6Does not form a ring, more preferably R^2AZ6And R^3AZ6Is a hydrogen atom.

R^AA1Z6And R^AA2Z6And R^12AZ6And R^13AZ6The ring formed is bonded to the exocyclic methylene (C ═ CH) group of the isoindoline skeleton of formula (IZ6)₂) Is bonded to contain the exocyclic methylene (C ═ CH)₂) In the form of structures within, R is listed^AA1Z6And R^AA2Z6And R^12AZ6And R^13AZ6Examples of the ring to be formed include structures in which a carbonyl group, an exocyclic methylene group and a carbonyl group are arranged in this order as shown in the following groups A and B. Represents a bond to the isoindoline backbone.

[ group A ]

[ group B ]

R^104AZ6、R^105AZ6、R^106AZ6And R^107AZ6Independently of one another, represents a hydrogen atom, -CO-R^102AZ6、-COO-R^101AZ6、-OCO-R^102AZ6、-COCO-R^102AZ6、-O-R^102AZ6、-SO₂-R^101AZ6、-SO₂N(R^102AZ6)₂、-CON(R^102AZ6)₂、-N(R^102AZ6)₂、-NHCO-R^102AZ6、-NHCO-N(R^102AZ6)₂、-NHCOOR^102AZ6、-OCON(R^102AZ6)₂Halogen atom, cyano group, nitro group, -SO ₃M、-CO₂M、-SO₃ ^-、-CO₂ ^-The hydrocarbon group may have a substituent and has 1 to 40 carbon atoms, or the heterocyclic group may have a substituent.

With respect to R^104AZ6、R^105AZ6、R^106AZ6And R^107AZ6Represented by-CO-R^102AZ6、-COO-R^101AZ6、-OCO-R^102AZ6、-COCO-R^102AZ6、-O-R^102AZ6、-SO₂-R^101AZ6、-SO₂N(R^102AZ6)₂、-CON(R^102AZ6)₂、-N(R^102AZ6)₂、-NHCO-R^102AZ6、-NHCO-N(R^102AZ6)₂、-NHCOOR^102AZ6、-OCON(R^102AZ6)₂Halogen atom, -SO₃M and-CO₂M, may be exemplified by^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6And R^13AZ6Represented by-CO-R^102AZ6、-COO-R^101AZ6、-OCO-R^102AZ6、-COCO-R^102AZ6、-O-R^102AZ6、-SO₂-R^101AZ6、-SO₂N(R^102AZ6)₂、-CON(R^102AZ6)₂、-N(R^102AZ6)₂、-NHCO-R^102AZ6、-NHCO-N(R^102AZ6)₂、-NHCOOR^102AZ6、-OCON(R^102AZ6)₂Halogen atom, -SO₃M and-CO₂M is the same example.

As R^104AZ6、R^105AZ6、R^106AZ6And R^107AZ6The optionally substituted hydrocarbon group having 1 to 40 carbon atoms and the optionally substituted heterocyclic group are represented by^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6The hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or the heterocyclic group which may have a substituent are the same.

R^104AZ6、R^105AZ6、R^106AZ6And R^107AZ6The hydrocarbon group and the heterocyclic group having 1 to 40 carbon atoms may have a substituent. Examples of the substituent include^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6The hydrocarbon group may have the same substituent as the substituent. Preferred examples of the substituent include^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6The preferable examples of the substituents which the hydrocarbon group may have are the same.

As R^104AZ6、R^105AZ6、R^106AZ6And R^107AZ6Preferably, R is^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6And R^13AZ6The same preferable example as in (1).

As R^104AZ6、R^105AZ6、R^106AZ6And R^107AZ6More preferably, the alkyl group has 1 to 10 carbon atoms and a hydrogen atom, such as a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, a tert-butyl group, a pentyl group, a hexyl group, a (2-ethyl) hexyl group, a heptyl group, an octyl group, a nonyl group, a cyclohexyl group, and a phenyl group.

For the groups exemplified in group A and group B, the hydrogen atom bonded to the ring structure may be substituted with a substituent.

Examples of the substituent include^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6The hydrocarbon group may have the same substituent as the substituent.

Preferred examples of the substituent include^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6The preferable examples of the substituents which the hydrocarbon group may have are the same.

R^1AZ6Is a hydrogen atom, R^2AZ6、R^3AZ6、R^4AZ6And R^5AZ6Independently of each other, a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogen atom, -N (R)^102AZ6)₂A C1-20 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R^102AZ6、-O-R^102AZ6、-SO₃M or-CO₂M，

More preferably a hydrogen atom, a tert-butyl group or a nitro group.

R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6Preferably satisfies at least 1 of (raa-i) to (raa-iii), R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6having-SO of₃ ^-or-CO₂ ^-The total number of (a) is a.

(raa-i)R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6And R^13AZ6At least one of which is-SO₃ ^-or-CO₂ ^-。

(raa-ii)R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6And R^13AZ6At least one of which is-CO-R^102AZ6、-COO-R^101AZ6、-O-R^102AZ6、-SO₂-R^101AZ6、-SO₂N(R^102AZ6)₂、-CON(R^102AZ6)₂or-N (R)^102AZ6)₂R is a hydrogen atom^101AZ6And R^102AZ6To have-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO₃ ^-or-CO₂ ^-The heterocyclic group of (1). Wherein the hydrocarbon group or the heterocyclic group may have-SO₃ ^-and-CO₂ ^-And (ii) an additional substituent.

(raa-iii)R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6And R^13AZ6At least one of which is a compound having-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO ₃ ^-or-CO₂ ^-The heterocyclic group of (1). The hydrocarbon group or the heterocyclic group may have-SO₃ ^-and-CO₂ ^-And (ii) an additional substituent.

Examples of the groups a and B include rings represented by the formulae (QQ1) to (QQ25) and the formulae (QQA1) to (QQA 36).

The compound represented by the formula (IZ6-A) is preferably a compound represented by the formula (IZ6-B) (hereinafter, may be referred to as a compound IZ 6-B.).

[ formula (IZ6-B) wherein A^c+B, c, d and the wavy line have the same meanings as described above. L is¹represents-CO-or-SO₂-。R^1BZ6、R^2BZ6、R^3BZ6、R^4BZ6、R^5BZ6、R^11BZ6、R^12BZ6And R^13BZ6Independently of one another, represents a hydrogen atom, -CO-R^102BZ6、-COO-R^101BZ6、-OCO-R^102BZ6、-COCO-R^102BZ6、-O-R^102BZ6、-SO₂-R^101BZ6、-SO₂N(R^102BZ6)₂、-CON(R^102BZ6)₂、-N(R^102BZ6)₂、-NHCO-R^102BZ6、-NHCO-N(R^102BZ6)₂、-NHCOOR^102BZ6、-OCON(R^102BZ6)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M、-SO₃ ^-、-CO₂ ^-The hydrocarbon group may have a substituent and has 1 to 40 carbon atoms, or the heterocyclic group may have a substituent.

R^2BZ6And R^3BZ6、R^3BZ6And R^4BZ6、R^4BZ6And R^5BZ6And R^12BZ6And R^13BZ6Each of which may be bonded to each other to form a ring.

R^101BZ6Independently represent a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.

R^102BZ6Independently represent a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group.

The formula (IZ6-B ') and the formula (IZ 6-B') each represent a partial structure of the formula (IZ6-B), A^c+、b、c、d、R^1BZ6、R^2BZ6、R^3BZ6、R^4BZ6、R^5BZ6、R^11BZ6、R^12BZ6、R^13BZ6And L¹Represents the same meaning as the corresponding symbol in the formula (IZ 6-B).

M represents the same meaning as described above.

R^1BZ6、R^2BZ6、R^3BZ6、R^4BZ6、R^5BZ6、R^11BZ6、R^12BZ6、R^13BZ6、R^101BZ6、R^102BZ6、L¹M, c or A^c+When there are a plurality of them, they may be the same or different.

R^1BZ6、R^2BZ6、R^3BZ6、R^4BZ6、R^5BZ6、R^11BZ6、R^12BZ6、R^13BZ6、R^101BZ6And R^102BZ6Satisfies at least 1 of (rb-i) to (rb-iii), R^1BZ6、R^2BZ6、R^3BZ6、R^4BZ6、R^5BZ6、R^11BZ6、R^12BZ6、R^13BZ6、R^101BZ6And R^102BZ6Is provided withis-SO of₃ ^-or-CO₂ ^-The total number of (a) is a.

(rb-i)R^1BZ6、R^2BZ6、R^3BZ6、R^4BZ6、R^5BZ6、R^11BZ6、R^12BZ6And R^13BZ6At least one of which is-SO₃ ^-or-CO₂ ^-。

(rb-ii)R^1BZ6、R^2BZ6、R^3BZ6、R^4BZ6、R^5BZ6、R^11BZ6、R^12BZ6And R^13BZ6At least one of which is-CO-R^102BZ6、-COO-R^101BZ6、-OCO-R^102BZ6、-COCO-R^102BZ6、-O-R^102BZ6、-SO₂-R^101BZ6、-SO₂N(R^102BZ6)₂、-CON(R^102BZ6)₂、-N(R^102BZ6)₂、-NHCO-R^102BZ6、-NHCO-N(R^102BZ6)₂、-NHCOOR^102BZ6or-OCON (R)^102BZ6)₂R is a hydrogen atom^101BZ6And R^102BZ6To have-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO₃ ^-or-CO₂ ^-The heterocyclic group of (1). Wherein the hydrocarbon group or the heterocyclic group may have-SO₃ ^-and-CO₂ ^-And (ii) an additional substituent.

(rb-iii)R^1BZ6、R^2BZ6、R^3BZ6、R^4BZ6、R^5BZ6、R^11BZ6、R^12BZ6And R^13BZ6At least one of which is a compound having-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO₃ ^-or-CO₂ ^-The heterocyclic group of (1). Wherein the hydrocarbon group or the heterocyclic group may have-SO₃ ^-and-CO₂ ^-And (ii) an additional substituent.

a represents the same meaning as the symbol in the formula (IZ 6-A). When a plurality of a exist, they may be the same or different.

The partial structure represented by the formula (IZ6-B ') has the same negative valence as the partial structure represented by the formula (IZ 6-B') has the same positive valence in absolute value. ]

As R^1BZ6、R^2BZ6、R^3BZ6、R^4BZ6、R^5BZ6、R^11BZ6、R^12BZ6And R^13BZ6Examples thereof include the compounds with R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6And R^13AZ6The same example.

As R^1BZ6、R^2BZ6、R^3BZ6、R^4BZ6、R^5BZ6、R^11BZ6、R^12BZ6And R^13BZ6Preferred examples of (3) include^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6And R^13AZ6The same preferred examples as those of (1).

As R ^101BZ6Examples thereof include the compounds with R^101AZ6The same example. As R^101BZ6Preferred examples of (3) include^101AZ6The same preferred examples as those of (1). As R^102BZ6Examples thereof include the compounds with R^102AZ6The same example. As R^102BZ6Preferred examples of (3) include^102AZ6The same preferred examples as those of (1). R^1BZ6、R^2BZ6、R^3BZ6、R^4BZ6、R^5BZ6、R^11BZ6、R^12BZ6、R^13BZ6、R^101BZ6And R^102BZ6The hydrocarbon group and the heterocyclic group having 1 to 40 carbon atoms may have a substituent. Examples of the substituent include^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6The hydrocarbon group may have the same substituent as the substituent. Preferred examples of the substituent include^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6The preferable examples of the substituents which the hydrocarbon group may have are the same.

L¹preferably-CO-.

R^11BZ6The alkyl group is an aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a phenyl group which may have a substituent, a naphthyl group which may have a substituent, a tetrahydronaphthyl group which may have a substituent, a thienyl group which may have a substituent, a furyl group which may have a substituent, or a pyridyl group which may have a substituent.

R^11BZ6The aliphatic hydrocarbon group has 1 to 40 carbon atoms, preferably 1 to 30 carbon atoms, more preferably 1 to 20 carbon atoms, and further preferably 1 to 15 carbon atoms.

The aliphatic hydrocarbon group may be saturated or unsaturated, and may be a chain or alicyclic ring.

As R^11BZ6Examples of the saturated or unsaturated chain aliphatic hydrocarbon group include straight chain alkyl groups such as methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, heptadecyl, octadecyl, and eicosyl; branched alkyl groups such as isopropyl, isobutyl, sec-butyl, tert-butyl, (2-ethyl) butyl, isopentyl, neopentyl, tert-pentyl, (1-methyl) pentyl, (2-methyl) pentyl, (1-ethyl) pentyl, (3-ethyl) pentyl, isohexyl, (5-methyl) hexyl, (2-ethyl) hexyl and (3-ethyl) heptyl; alkenyl groups such as vinyl, 1-propenyl, 2-propenyl (allyl), (1-methyl) vinyl, 2-butenyl, 3-butenyl, 1, 3-butadienyl, (1- (2-propenyl)) vinyl, (1, 2-dimethyl) propenyl, and 2-pentenyl; and so on. The number of carbon atoms of the saturated or unsaturated chain hydrocarbon group is preferably 1 to 30, more preferably 1 to 20, further preferably 1 to 15, and particularly preferably 1 to 10.

As R^11BZ6Examples of the saturated or unsaturated alicyclic hydrocarbon group include cyclopropyl, 1-methylcyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, 1-methylcyclohexyl, 2-methylcyclohexyl, and 3-methylcyclohexylCyclohexyl, 4-methylcyclohexyl, 1, 2-dimethylcyclohexyl, 1, 3-dimethylcyclohexyl, 1, 4-dimethylcyclohexyl, 2, 3-dimethylcyclohexyl, 2, 4-dimethylcyclohexyl, 2, 5-dimethylcyclohexyl, 2, 6-dimethylcyclohexyl, 3, 4-dimethylcyclohexyl, cycloalkyl groups such as 3, 5-dimethylcyclohexyl, 2-dimethylcyclohexyl, 3-dimethylcyclohexyl, 4-dimethylcyclohexyl, cyclooctyl, 2,4, 6-trimethylcyclohexyl, 2,6, 6-tetramethylcyclohexyl, 3,5, 5-tetramethylcyclohexyl, 4-pentylcyclohexyl, 4-octylcyclohexyl and 4-cyclohexylcyclohexyl; cycloalkenyl groups such as cyclohexenyl (e.g., cyclohex-2-ene, cyclohex-3-ene), cycloheptenyl, cyclooctenyl, and the like; norbornyl, adamantyl, bicyclo [2.2.2]An octyl group and the like. The number of carbon atoms of the saturated or unsaturated alicyclic hydrocarbon group is preferably 3 to 30, more preferably 3 to 20, still more preferably 4 to 20, yet more preferably 4 to 15, even more preferably 5 to 15, and most preferably 5 to 10. Among them, cyclopentyl, cyclohexyl, cycloheptyl, and cyclooctyl are particularly preferable.

R^11BZ6The aliphatic hydrocarbon group represented by (a) may be a group in which a hydrogen atom contained in the above-mentioned aliphatic hydrocarbon group is substituted with an aromatic hydrocarbon group having 1 to 40 carbon atoms or a group in which the above-mentioned aliphatic hydrocarbon groups are combined.

Examples of the aromatic hydrocarbon group include a phenyl group, an o-tolyl group, an m-tolyl group, a p-tolyl group, a 2, 3-dimethylphenyl group, a 2, 4-dimethylphenyl group, a 2, 5-dimethylphenyl group, a 2, 6-dimethylphenyl group, a 3, 4-dimethylphenyl group, a 3, 5-dimethylphenyl group, an o-isopropylphenyl group, an m-isopropylphenyl group, a p-isopropylphenyl group, aromatic hydrocarbon groups such as o-tert-butylphenyl, m-tert-butylphenyl, p-tert-butylphenyl, mesityl, 2, 6-bis (2-propyl) phenyl, 2,4, 6-trimethylphenyl, 1-naphthyl, 2-naphthyl, 5,6,7, 8-tetrahydro-1-naphthyl, 5,6,7, 8-tetrahydro-2-naphthyl, fluorenyl, phenanthryl, and anthracenyl; and so on. The number of carbon atoms of the aromatic hydrocarbon group is preferably 6 to 30, more preferably 6 to 20, and further preferably 6 to 15.

Examples of the group in which a hydrogen atom contained in the above-mentioned aliphatic hydrocarbon group is substituted with an aromatic hydrocarbon group having 1 to 40 carbon atoms include aralkyl groups such as benzyl, phenethyl, and 1-methyl-1-phenylethyl. Examples of the group formed by combining the above-mentioned aliphatic hydrocarbon groups include (cycloalkyl) alkyl groups such as cyclohexylmethyl groups. The number of carbon atoms of a group in which a hydrogen atom contained in an aliphatic hydrocarbon group is substituted with an aromatic hydrocarbon group having 1 to 40 carbon atoms or a group in which aliphatic hydrocarbon groups are combined is preferably 4 to 30, more preferably 4 to 20, and further preferably 4 to 15.

R^11BZ6The aliphatic hydrocarbon group having 1 to 40 carbon atoms, phenyl group, naphthyl group, tetrahydronaphthyl group, thienyl group, furyl group and pyridyl group may have a substituent.

Examples of the substituent include^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6The hydrocarbon group may have the same substituent as the substituent. Preferred examples of the substituent include^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6The preferable examples of the substituents which the hydrocarbon group may have are the same.

In the compound IZ6-B, R^1BZ6Preferably a hydrogen atom.

R^2BZ6、R^3BZ6、R^4BZ6Or R^5BZ6Independently of each other, a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogen atom, -N (R)^102BZ6)₂A C1-20 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R^102BZ6、-O-R^102BZ6、-SO₃M or-CO₂M, more preferably a hydrogen atom or a nitro group. The number of nitro groups is preferably 0 to 2, more preferably 0 or 1.

R^1BZ6、R^2BZ6、R^3BZ6、R^4BZ6、R^5BZ6、R^11BZ6、R^12BZ6、R^13BZ6、R^101BZ6And R^102BZ6Preferably satisfies at least 1 of (rbb-i) to (rbb-iii), R^1BZ6、R^2BZ6、R^3BZ6、R^4BZ6、R^5BZ6、R^11BZ6、R^12BZ6、R^13BZ6、R^101BZ6And R^102BZ6having-SO of₃ ^-or-CO₂ ^-The total number of (a) is a.

(rbb-i)R^1BZ6、R^2BZ6、R^3BZ6、R^4BZ6、R^5BZ6、R^11BZ6、R^12BZ6And R^13BZ6At least one of which is-SO₃ ^-or-CO₂ ^-。

(rbb-ii)R^1BZ6、R^2BZ6、R^3BZ6、R^4BZ6、R^5BZ6、R^11BZ6、R^12BZ6And R^13BZ6At least one of which is-CO-R^102BZ6、-COO-R^101BZ6、-O-R^102BZ6、-SO₂-R^101BZ6、-SO₂N(R^102BZ6)₂、-CON(R^102BZ6)₂or-N (R)^102BZ6)₂R is a hydrogen atom^101BZ6And R^102BZ6To have-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO₃ ^-or-CO₂ ^-The heterocyclic group of (1). Wherein the hydrocarbon group or the heterocyclic group may have-SO ₃ ^-and-CO₂ ^-And (ii) an additional substituent.

(rbb-iii)R^1BZ6、R^2BZ6、R^3BZ6、R^4BZ6、R^5BZ6、R^11BZ6、R^12BZ6And R^13BZ6At least one of which is a compound having-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO₃ ^-or-CO₂ ^-The heterocyclic group of (1). Wherein the hydrocarbon group or the heterocyclic group may have-SO₃ ^-and-CO₂ ^-And (ii) an additional substituent.

In the formula (IZ6-B), R^12BZ6And R^13BZ6When no ring is formed, the compound IZ6-B is preferably a compound represented by the formula (IZ6-C) (hereinafter, may be referred to as a compound IZ 6-C.).

[ formula (IZ6-C) wherein A^c+、b、c、d、L¹And the wavy line means the same as described above.

L²represents-CO-or-SO₂-。R^1CZ6、R^2CZ6、R^3CZ6、R^4CZ6、R^5CZ6、R^11CZ6And R^14CZ6Independently of one another, represents a hydrogen atom, -CO-R^102CZ6、-COO-R^101CZ6、-OCO-R^102CZ6、-COCO-R^102CZ6、-O-R^102CZ6、-SO₂-R^101CZ6、-SO₂N(R^102CZ6)₂、-CON(R^102CZ6)₂、-N(R^102CZ6)₂、-NHCO-R^102CZ6、-NHCO-N(R^102CZ6)₂、-NHCOOR^102CZ6、-OCON(R^102CZ6)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M、-SO₃ ^-、-CO₂ ^-The hydrocarbon group may have a substituent and has 1 to 40 carbon atoms, or the heterocyclic group may have a substituent.

R^2CZ6And R^3CZ6、R^3CZ6And R^4CZ6And R^4CZ6And R^5CZ6Each of which may be bonded to each other to form a ring.

R^101CZ6Independently represent a carbon atom number of 1 to E which may have a substituent40 or a heterocyclic group which may have a substituent.

R^102CZ6Independently represent a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group.

M represents the same meaning as described above.

The formula (IZ6-C ') and the formula (IZ 6-C') each represent a partial structure of the formula (IZ6-C), A ^c+、b、c、d、R^1CZ6、R^2CZ6、R^3CZ6、R^4CZ6、R^5CZ6、R^11CZ6、R^14CZ6、L¹And L²Represents the same meaning as the corresponding symbol in the formula (IZ 6-C).

R^1CZ6、R^2CZ6、R^3CZ6、R^4CZ6、R^5CZ6、R^11CZ6、R^14CZ6、R^101CZ6、R^102CZ6、L¹、L²M, c or A^c+When there are a plurality of them, they may be the same or different.

R^1CZ6、R^2CZ6、R^3CZ6、R^4CZ6、R^5CZ6、R^11CZ6、R^14CZ6、R^101CZ6And R^102CZ6Satisfies at least 1 of (rc-i) to (rc-iii), R^1CZ6、R^2CZ6、R^3CZ6、R^4CZ6、R^5CZ6、R^11CZ6、R^14CZ6、R^101CZ6And R^102CZ6having-SO of₃ ^-or-CO₂ ^-The total number of (a) is a.

(rc-i)R^1CZ6、R^2CZ6、R^3CZ6、R^4CZ6、R^5CZ6、R^11CZ6And R^14CZ6At least one of which is-SO₃ ^-or-CO₂ ^-。

(rc-ii)R^1CZ6、R^2CZ6、R^3CZ6、R^4CZ6、R^5CZ6、R^11CZ6And R^14CZ6At least one of which is-CO-R^102CZ6、-COO-R^101CZ6、-OCO-R^102CZ6、-COCO-R^102CZ6、-O-R^102CZ6、-SO₂-R^101CZ6、-SO₂N(R^102CZ6)₂、-CON(R^102CZ6)₂、-N(R^102CZ6)₂、-NHCO-R^102CZ6、-NHCO-N(R^102CZ6)₂、-NHCOOR^102CZ6or-OCON (R)^102CZ6)₂R is a hydrogen atom^101CZ6And R^102CZ6To have-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO₃ ^-or-CO₂ ^-The heterocyclic group of (1). The hydrocarbon group or the heterocyclic group may have-SO₃ ^-and-CO₂ ^-And (ii) an additional substituent.

(rc-iii)R^1CZ6、R^2CZ6、R^3CZ6、R^4CZ6、R^5CZ6、R^11CZ6And R^14CZ6At least one of which is a compound having-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO₃ ^-or-CO₂ ^-The heterocyclic group of (1). Wherein the hydrocarbon group or the heterocyclic group may have-SO₃ ^-and-CO₂ ^-And (ii) an additional substituent.

a represents the same meaning as the symbol in the formula (IZ 6-B). When a plurality of a exist, they may be the same or different.

The partial structure represented by the formula (IZ 6-C') has the same negative valence as the partial structure represented by the formula (IZ6-C ") has the same positive valence in absolute value. ]

As R^1CZ6、R^2CZ6、R^3CZ6、R^4CZ6、R^5CZ6、R^11CZ6And R^14CZ6Examples thereof include the compounds with R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6And R^13AZ6The same example. As R^1CZ6、R^2CZ6、R^3CZ6、R^4CZ6、R^5CZ6、R^11CZ6And R^14CZ6Preferred examples of (3) include ^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6And R^13AZ6The same preferred examples as those of (1).

As R^101CZ6Examples thereof include the compounds with R^101AZ6The same example. As R^101CZ6Preferred examples of (3) include^101AZ6The same preferred examples as those of (1).

As R^102CZ6Examples thereof include the compounds with R^102AZ6The same example. As R^102CZ6Preferred examples of (3) include^102AZ6The same preferred examples as those of (1).

R^1CZ6、R^2CZ6、R^3CZ6、R^4CZ6、R^5CZ6、R^11CZ6、R^14CZ6、R^101CZ6And R^102CZ6The hydrocarbon group and the heterocyclic group having 1 to 40 carbon atoms may have a substituent. Examples of the substituent include^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6The hydrocarbon group may have the same substituent as the substituent. Preferred examples of the substituent include^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6The preferable examples of the substituents which the hydrocarbon group may have are the same.

L¹Or L²preferably-CO-. Preferably, R^11CZ6And R^14CZ6Are identical radicals, L¹And L²Are the same group.

R^11CZ6And R^14CZ6Independently of each other, it is preferably an aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a phenyl group which may have a substituent, a naphthyl group which may have a substituent, a tetrahydronaphthyl group which may have a substituent, a thienyl group which may have a substituent, or a naphthyl group which may have a substituentA furyl group which may have a substituent or a pyridyl group which may have a substituent.

Examples of the optionally substituted aliphatic hydrocarbon group having 1 to 40 carbon atoms, the optionally substituted phenyl group, the optionally substituted naphthyl group, the optionally substituted tetrahydronaphthyl group, the optionally substituted thienyl group, the optionally substituted furyl group or the optionally substituted pyridyl group include those related to R in the compound IZ6-B ^11BZ6Preferable examples of the above-mentioned (a) include the same examples as those of the above-mentioned aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent(s), the phenyl group which may have a substituent(s), the naphthyl group which may have a substituent(s), the tetrahydronaphthyl group which may have a substituent(s), the thienyl group which may have a substituent(s), the furyl group which may have a substituent(s), and the pyridyl group which may have a substituent(s).

In the compound IZ6-C, R^1CZ6Preferably a hydrogen atom.

R^2CZ6、R^3CZ6、R^4CZ6And R^5CZ6Independently of each other, a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogen atom, -N (R)^102CZ6)₂A C1-20 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R^102CZ6、-O-R^102CZ6、-SO₃M or-CO₂M, more preferably a hydrogen atom or a nitro group. The number of nitro groups is preferably 0 to 2, more preferably 0 or 1.

R^1CZ6、R^2CZ6、R^3CZ6、R^4CZ6、R^5CZ6、R^11CZ6、R^14CZ6、R^101CZ6And R^102CZ6Preferably satisfies at least 1 of (rcc-i) to (rcc-iii), R^1CZ6、R^2CZ6、R^3CZ6、R^4CZ6、R^5CZ6、R^11CZ6、R^14CZ6、R^101CZ6And R^102CZ6having-SO of₃ ^-or-CO₂ ^-The total number of (a) is a.

(rcc-i)R^1CZ6、R^2CZ6、R^3CZ6、R^4CZ6、R^5CZ6、R^11CZ6And R^14CZ6At least one of which is-SO₃ ^-or-CO₂ ^-。

(rcc-ii)R^1CZ6、R^2CZ6、R^3CZ6、R^4CZ6、R^5CZ6、R^11CZ6And R^14CZ6At least one of which is-CO-R^102CZ6、-COO-R^101CZ6、-COCO-R^102CZ6、-O-R^102CZ6、-SO₂-R^101CZ6、-SO₂N(R^102CZ6)₂、-CON(R^102CZ6)₂、-N(R^102CZ6)₂、-NHCO-N(R^102CZ6)₂、-NHCOOR^102CZ6or-OCON (R)^102CZ6)₂R is a hydrogen atom^101CZ6And R^102CZ6To have-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO₃ ^-or-CO₂ ^-The heterocyclic group of (1). Wherein the hydrocarbon group or the heterocyclic group may have-SO ₃ ^-and-CO₂ ^-And (ii) an additional substituent.

(rcc-iii)R^1CZ6、R^2CZ6、R^3CZ6、R^4CZ6、R^5CZ6、R^11CZ6And R^14CZ6At least one of which is a compound having-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO₃ ^-or-CO₂ ^-The heterocyclic group of (1). Wherein the hydrocarbon group or the heterocyclic group may have-SO₃ ^-and-CO₂ ^-And (ii) an additional substituent.

R^1CZ6、R^2CZ6、R^3CZ6、R^4CZ6、R^5CZ6、R^11CZ6、R^14CZ6、R^101CZ6And R^102CZ6Preferably, at least 1 of (rc-I) and (rc-II) is satisfied.

(rc-I)R^2CZ6、R^3CZ6、R^4CZ6、R^5CZ6At least one of which is-SO₃ ^-or-CO₂ ^-。(rc-II)R^1CZ6、R^11CZ6And R^14CZ6At least one of which is a compound having-SO₃ ^-or-CO₂ ^-The optionally substituted hydrocarbon group having 1 to 40 carbon atoms or having-SO₃ ^-or-CO₂ ^-The heterocyclic group of (1). Wherein the hydrocarbon group or the heterocyclic group may have-SO₃ ^-and-CO₂ ^-And (ii) an additional substituent.

R^1CZ6、R^2CZ6、R^3CZ6、R^4CZ6、R^5CZ6、R^11CZ6、R^14CZ6、R^101CZ6And R^102CZ6Preferably, at least 1 of (rcc-I) and (rcc-II) is satisfied.

(rcc-I)R^2CZ6、R^3CZ6、R^4CZ6、R^5CZ6At least one of which is-SO₃ ^-or-CO₂ ^-。

(rcc-II)R^1CZ6、R^11CZ6And R^14CZ6At least one of which is a compound having-SO₃ ^-or-CO₂ ^-The hydrocarbon group having 1 to 40 carbon atoms which may have a substituent(s). Wherein the hydrocarbon group or the heterocyclic group may have-SO₃ ^-and-CO₂ ^-And (ii) an additional substituent.

Wherein R is^1CZ6、R^2CZ6、R^3CZ6、R^4CZ6、R^5CZ6、R^11CZ6、R^14CZ6、R^101CZ6And R^102CZ6having-SO of₃ ^-or-CO₂ ^-The total number of (a) is a.

In the compound IZ6-B, R^12BZ6And R^13BZ6When a ring is formed, the compound IZ6-B is preferably a compound represented by the formula (IZ6-D) (hereinafter, may be referred to as a compound IZ 6-D.).

[ formula (IZ6-D) wherein A^c+、b、c、d、L¹And the wavy line means the same as described above. R ^20DZ6And R^30DZ6Bonded to form a ring Q. The ring Q may have a substituent, and is a ring having 5 to 7 ring-constituting elements, and the ring Q may be a hydrocarbon ring or a heterocyclic ring. The following rings may be fused/condensed on ring Q: a monocyclic ring which is selected from hydrocarbon rings and hetero rings and which may have a substituent, wherein the number of constituent elements of the ring is 5 to 7; or 2 or more condensed rings obtained by condensing the monocyclic rings.

R^1DZ6、R^2DZ6、R^3DZ6、R^4DZ6、R^5DZ6And R^11DZ6Independently of one another, represents a hydrogen atom, -CO-R^102DZ6、-COO-R^101DZ6、-OCO-R^102DZ6、-COCO-R^102DZ6、-O-R^102DZ6、-SO₂-R^101DZ6、-SO₂N(R^102DZ6)₂、-CON(R^102DZ6)₂、-N(R^102DZ6)₂、-NHCO-R^102DZ6、-NHCO-N(R^102DZ6)₂、-NHCOOR^102DZ6、-OCON(R^102DZ6)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M、-SO₃ ^-、-CO₂ ^-The hydrocarbon group may have a substituent and has 1 to 40 carbon atoms, or the heterocyclic group may have a substituent.

R^2DZ6And R^3DZ6、R^3DZ6And R^4DZ6And R^4DZ6And R^5DZ6Each of which may be bonded to each other to form a ring.

R^101DZ6Independently represent a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.

R^102DZ6Independently represent a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted hydrocarbon groupA heterocyclic group having a substituent.

M represents the same meaning as described above.

The formulae (IZ 6-D') and (IZ6-D ") each represent a partial structure of the formula (IZ6-D), A^c+、b、c、d、R^1DZ6、R^2DZ6、R^3DZ6、R^4DZ6、R^5DZ6、R^11DZ6、R^20DZ6、R^30DZ6And L¹Represents the same meaning as the corresponding symbol in the formula (IZ 6-D).

R^1DZ6、R^2DZ6、R^3DZ6、R^4DZ6、R^5DZ6、R^11DZ6、R^101DZ6、R^102DZ6、L¹、M、R^20DZ6、R^30DZ6Ring Q, c or A^c+When there are a plurality of them, they may be the same or different.

R^1DZ6、R^2DZ6、R^3DZ6、R^4DZ6、R^5DZ6、R^11DZ6、R^101DZ6、R^102DZ6And ring Q satisfies at least 1 of (rd-i) to (rd-iv), R^1DZ6、R^2DZ6、R^3DZ6、R^4DZ6、R^5DZ6、R^11DZ6、R^101DZ6、R^102DZ6and-SO of ring Q₃ ^-or-CO₂ ^-The total number of (a) is a.

(rd-i)R^1DZ6、R^2DZ6、R^3DZ6、R^4DZ6、R^5DZ6And R^11DZ6At least one of which is-SO₃ ^-or-CO₂ ^-。

(rd-ii)R^1DZ6、R^2DZ6、R^3DZ6、R^4DZ6、R^5DZ6And R^11DZ6At least one of which is-CO-R^102DZ6、-COO-R^101DZ6、-OCO-R^102DZ6、-COCO-R^102DZ6、-O-R^102DZ6、-SO₂-R^101DZ6、-SO₂N(R^102DZ6)₂、-CON(R^102DZ6)₂、-N(R^102DZ6)₂、-NHCO-R^102DZ6、-NHCO-N(R^102DZ6)₂、-NHCOOR^102DZ6or-OCON (R)^102DZ6)₂R is a hydrogen atom^101DZ6And R^102DZ6To have-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO₃ ^-or-CO₂ ^-The heterocyclic group of (1). Wherein the hydrocarbon group or the heterocyclic group may have-SO₃ ^-and-CO₂ ^-And (ii) an additional substituent.

(rd-iii)R^1DZ6、R^2DZ6、R^3DZ6、R^4DZ6、R^5DZ6And R^11DZ6At least one of which is a compound having-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO₃ ^-or-CO₂ ^-The heterocyclic group of (1). The hydrocarbon group or the heterocyclic group may have-SO₃ ^-and-CO₂ ^-And (ii) an additional substituent.

(rd-iv) Ring Q has-SO₃ ^-or-CO₂ ^-。

a represents the same meaning as the symbol in the formula (IZ 6-B). When a plurality of a exist, they may be the same or different.

The partial structure represented by the formula (IZ 6-D') has the same negative valence as the partial structure represented by the formula (IZ6-D ") has the same positive valence in absolute value. ]

The number of ring-constituting elements is preferably 5 to 6.

These monocyclic or condensed rings are preferably bonded to ring Q at 2 positions to form a condensed ring.

Examples of the ring Q and the ring having a monocyclic or condensed ring fused thereto include those similar to those of the above-mentioned group A.

Among them, preferred are formula (Q1), formula (Q4), formula (Q7), formula (Q8) and formula (Q18), and more preferred are formula (Q8) and formula (Q18).

The monocyclic ring (the monocyclic ring is selected from hydrocarbon rings and hetero rings) which may have a substituent, or the condensed ring in which 2 or more of the monocyclic rings are condensed, wherein the number of the constituent elements of the ring Q and the ring which may be condensed/condensed on the ring Q is 5 to 7, may haveHas a substituent. Examples of the substituent include^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6The hydrocarbon group may have the same substituent as the substituent.

Preferred examples of the substituent include^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6The preferable examples of the substituents which the hydrocarbon group may have are the same.

As R^1DZ6、R^2DZ6、R^3DZ6、R^4DZ6、R^5DZ6And R^11DZ6Examples thereof include the compounds with R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6And R^13AZ6The same example.

As R^1DZ6、R^2DZ6、R^3DZ6、R^4DZ6、R^5DZ6And R^11DZ6Preferred examples of (3) include^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6And R^13AZ6The same preferred examples as those of (1).

As R^101DZ6Examples thereof include the compounds with R^101AZ6The same example. As R^101DZ6Preferred examples of (3) include^101AZ6The same preferred examples as those of (1).

As R^102DZ6Examples thereof include the compounds with R^102AZ6The same example. As R^102DZ6Preferred examples of (3) include^102AZ6The same preferred examples as those of (1).

R^1DZ6、R^2DZ6、R^3DZ6、R^4DZ6、R^5DZ6、R^11DZ6、R^101DZ6And R^102DZ6Carbon ofThe hydrocarbyl group and the heterocyclic group having 1 to 40 atoms may have a substituent. Examples of the substituent include ^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6The hydrocarbon group may have the same substituent as the substituent. Preferred examples of the substituent include^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6The preferable examples of the substituents which the hydrocarbon group may have are the same.

L¹preferably-CO-.

R^11DZ6Independently of each other, an aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a phenyl group which may have a substituent, a naphthyl group which may have a substituent, a tetrahydronaphthyl group which may have a substituent, a thienyl group which may have a substituent, a furyl group which may have a substituent, or a pyridyl group which may have a substituent is preferable.

Examples of the optionally substituted aliphatic hydrocarbon group having 1 to 40 carbon atoms, the optionally substituted phenyl group, the optionally substituted naphthyl group, the optionally substituted tetrahydronaphthyl group, the optionally substituted thienyl group, the optionally substituted furyl group or the optionally substituted pyridyl group include those related to R in the compound IZ6-B^11BZ6Preferable examples of the above-mentioned (a) include the same examples as those of the above-mentioned aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent(s), the phenyl group which may have a substituent(s), the naphthyl group which may have a substituent(s), the tetrahydronaphthyl group which may have a substituent(s), the thienyl group which may have a substituent(s), the furyl group which may have a substituent(s), and the pyridyl group which may have a substituent(s).

In the compound IZ6-D, R^1DZ6Preferably a hydrogen atom.

R^2DZ6、R^3DZ6、R^4DZ6And R^5DZ6Independently of each otherPreferably a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogen atom, -N (R)^102DZ6)₂A C1-20 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R^102DZ6、-O-R^102DZ6、-SO₃M or-CO₂M, more preferably a hydrogen atom or a nitro group. The number of nitro groups is preferably 0 to 2, more preferably 0 or 1.

R^1DZ6、R^2DZ6、R^3DZ6、R^4DZ6、R^5DZ6、R^11DZ6、R^101DZ6、R^102DZ6And ring Q preferably satisfies at least 1 of (rdd-i) to (rdd-iv), R^1DZ6、R^2DZ6、R^3DZ6、R^4DZ6、R^5DZ6、R^11DZ6、R^101DZ6、R^102DZ6and-SO of ring Q₃ ^-or-CO₂ ^-The total number of (a) is a.

(rdd-i)R^1DZ6、R^2DZ6、R^3DZ6、R^4DZ6、R^5DZ6And R^11DZ6At least one of which is-SO₃ ^-or-CO₂ ^-。

(rdd-ii)R^1DZ6、R^2DZ6、R^3DZ6、R^4DZ6、R^5DZ6And R^11DZ6At least one of which is-CO-R^102DZ6、-COO-R^101DZ6、-O-R^102DZ6、-SO₂-R^101DZ6、-SO₂N(R^102DZ6)₂、-CON(R^102DZ6)₂or-N (R)^102DZ6)₂R is a hydrogen atom^101DZ6And R^102DZ6To have-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO₃ ^-or-CO₂ ^-The heterocyclic group of (1). Wherein the hydrocarbon group or the heterocyclic group may have-SO₃ ^-and-CO₂ ^-And (ii) an additional substituent.

(rdd-iii)R^1DZ6、R^2DZ6、R^3DZ6、R^4DZ6、R^5DZ6And R^11DZ6At leastOne is having a-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO₃ ^-or-CO₂ ^-The heterocyclic group of (1). The hydrocarbon group or the heterocyclic group may have-SO₃ ^-and-CO₂ ^-And (ii) an additional substituent.

(rdd-iv) Ring Q has-SO₃ ^-or-CO₂ ^-。

The compound IZ6-D is more preferably a compound represented by the formula (IZ6-E) (hereinafter, may be referred to as a compound IZ 6-E.).

[ formula (IZ6-E), wherein A is^c+、b、c、d、L¹And the wavy line means the same as described above.

R^1EZ6、R^2EZ6、R^3EZ6、R^4EZ6、R^5EZ6、R^6EZ6、R^7EZ6And R^11EZ6Independently of one another, represents a hydrogen atom, -CO-R^102EZ6、-COO-R^101EZ6、-OCO-R^102EZ6、-COCO-R^102EZ6、-O-R^102EZ6、-SO₂-R^101EZ6、-SO₂N(R^102EZ6)₂、-CON(R^102EZ6)₂、-N(R^102EZ6)₂、-NHCO-R^102EZ6、-NHCO-N(R^102EZ6)₂、-NHCOOR^102EZ6、-OCON(R^102EZ6)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M、-SO₃ ^-、-CO₂ ^-And can haveA substituted hydrocarbon group having 1 to 40 carbon atoms or a heterocyclic group which may have a substituent.

R^2EZ6And R^3EZ6、R^3EZ6And R^4EZ6And R^4EZ6And R^5EZ6Each of which may be bonded to each other to form a ring.

R^101EZ6Independently represent a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.

R^102EZ6Independently represent a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group.

M represents the same meaning as described above.

The formulae (IZ6-E ') and (IZ 6-E') each represent a partial structure of the formula (IZ6-E), A^c+、b、c、d、R^1EZ6、R^2EZ6、R^3EZ6、R^4EZ6、R^5EZ6、R^6EZ6、R^7EZ6、R^11EZ6And L¹Represents the same meaning as the corresponding symbol in the formula (IZ 6-E).

R^1EZ6、R^2EZ6、R^3EZ6、R^4EZ6、R^5EZ6、R^6EZ6、R^7EZ6、R^11EZ6、R^101EZ6、R^102EZ6、L¹M, c or A^c+When there are a plurality of them, they may be the same or different.

R^1EZ6、R^2EZ6、R^3EZ6、R^4EZ6、R^5EZ6、R^6EZ6、R^7EZ6、R^11EZ6、R^101EZ6And R^102EZ6Satisfies at least 1 of (re-i) to (re-iii), R^1EZ6、R^2EZ6、R^3EZ6、R^4EZ6、R^5EZ6、R^6EZ6、R^7EZ6、R^11EZ6、R^101EZ6And R^102EZ6having-SO of₃ ^-or-CO₂ ^-The total number of (a) is a.

(re-i)R^1EZ6、R^2EZ6、R^3EZ6、R^4EZ6、R^5EZ6、R^6EZ6、R^7EZ6And R^11EZ6At least one of which is-SO₃ ^-or-CO₂ ^-。

(re-ii)R^1EZ6、R^2EZ6、R^3EZ6、R^4EZ6、R^5EZ6、R^6EZ6、R^7EZ6And R^11EZ6At least one of which is-CO-R^102EZ6、-COO-R^101EZ6、-OCO-R^102EZ6、-COCO-R^102EZ6、-O-R^102EZ6、-SO₂-R^101EZ6、-SO₂N(R^102EZ6)₂、-CON(R^102EZ6)₂、-N(R^102EZ6)₂、-NHCO-R^102EZ6、-NHCO-N(R^102EZ6)₂、-NHCOOR^102EZ6or-OCON (R)^102EZ6)₂R is a hydrogen atom^101EZ6And R^102EZ6To have-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO ₃ ^-or-CO₂ ^-The heterocyclic group of (1). Wherein the hydrocarbon group or the heterocyclic group may have-SO₃ ^-and-CO₂ ^-And (ii) an additional substituent.

(re-iii)R^1EZ6、R^2EZ6、R^3EZ6、R^4EZ6、R^5EZ6、R^6EZ6、R^7EZ6And R^11EZ6At least one of which is a compound having-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO₃ ^-or-CO₂ ^-The heterocyclic group of (1). Wherein the hydrocarbon group or the heterocyclic group may have-SO₃ ^-and-CO₂ ^-And (ii) an additional substituent.

a represents the same meaning as the symbol in the formula (IZ 6-D). When a plurality of a exist, they may be the same or different.

The partial structure represented by the formula (IZ6-E ') has the same negative valence as the partial structure represented by the formula (IZ 6-E') has the same positive valence in absolute value. ]

As R^1EZ6、R^2EZ6、R^3EZ6、R^4EZ6、R^5EZ6、R^6EZ6、R^7EZ6And R^11EZ6Examples thereof include the compounds with R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6And R^13AZ6The same example.

As R^1EZ6、R^2EZ6、R^3EZ6、R^4EZ6、R^5EZ6、R^6EZ6、R^7EZ6And R^11EZ6Preferred examples of (3) include^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6And R^13AZ6The same preferred examples as those of (1).

R^6EZ6And R^7EZ6Independently of each other, a hydrocarbon group having 1 to 10 carbon atoms or a hydrogen atom such as a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, a tert-butyl group, a pentyl group, a hexyl group, a (2-ethyl) hexyl group, a heptyl group, an octyl group, a nonyl group, a cyclohexyl group, a phenyl group and the like is preferable.

As R^101EZ6Examples thereof include the compounds with R^101AZ6The same example. As R^101EZ6Preferred examples of (3) include^101AZ6The same preferred examples as those of (1).

As R^102EZ6Examples thereof include the compounds with R ^102AZ6The same example. As R^102EZ6Preferred examples of (3) include^102AZ6The same preferred examples as those of (1).

R^1EZ6、R^2EZ6、R^3EZ6、R^4EZ6、R^5EZ6、R^6EZ6、R^7EZ6、R^11EZ6、R^101EZ6And R^102EZ6The hydrocarbon group and the heterocyclic group having 1 to 40 carbon atoms may have a substituent. Examples of the substituent include^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6The hydrocarbon group represented may haveThe same substituents are used. Preferred examples of the substituent include^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6、R^101AZ6And R^102AZ6The preferable examples of the substituents which the hydrocarbon group may have are the same.

L¹preferably-CO-.

R^11EZ6Independently of each other, an aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a phenyl group which may have a substituent, a naphthyl group which may have a substituent, a tetrahydronaphthyl group which may have a substituent, a thienyl group which may have a substituent, a furyl group which may have a substituent, or a pyridyl group which may have a substituent is preferable.

Examples of the optionally substituted aliphatic hydrocarbon group having 1 to 40 carbon atoms, the optionally substituted phenyl group, the optionally substituted naphthyl group, the optionally substituted tetrahydronaphthyl group, the optionally substituted thienyl group, the optionally substituted furyl group or the optionally substituted pyridyl group include those related to R in the compound IZ6-B ^11BZ6Preferable examples of the above-mentioned (a) include the same examples as those of the above-mentioned aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent(s), the phenyl group which may have a substituent(s), the naphthyl group which may have a substituent(s), the tetrahydronaphthyl group which may have a substituent(s), the thienyl group which may have a substituent(s), the furyl group which may have a substituent(s), and the pyridyl group which may have a substituent(s).

In the compound IZ6-E, R^1EZ6Preferably a hydrogen atom.

R^2EZ6、R^3EZ6、R^4EZ6And R^5EZ6Independently of each other, a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogen atom, -N (R)^102EZ6)₂A C1-20 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R^102EZ6、-O-R^102EZ6、-SO₃M or-CO₂M，

More preferably a hydrogen atom or a nitro group. The number of nitro groups is preferably 0 to 2, more preferably 0 or 1.

R^1EZ6、R^2EZ6、R^3EZ6、R^4EZ6、R^5EZ6、R^6EZ6、R^7EZ6、R^11EZ6、R^101EZ6And R^102EZ6Preferably satisfies at least 1 of (ree-i) to (ree-iii), R^1EZ6、R^2EZ6、R^3EZ6、R^4EZ6、R^5EZ6、R^6EZ6、R^7EZ6、R^11EZ6、R^101EZ6And R^102EZ6having-SO of₃ ^-or-CO₂ ^-The total number of (a) is a.

(ree-i)R^1EZ6、R^2EZ6、R^3EZ6、R^4EZ6、R^5EZ6、R^6EZ6、R^7EZ6And R^11EZ6At least one of which is-SO₃ ^-or-CO₂ ^-。

(ree-ii)R^1EZ6、R^2EZ6、R^3EZ6、R^4EZ6、R^5EZ6、R^6EZ6、R^7EZ6And R^11EZ6At least one of which is-CO-R^102EZ6、-COO-R^101EZ6、-O-R^102EZ6、-SO₂-R^101EZ6、-SO₂N(R^102EZ6)₂、-CON(R^102EZ6)₂or-N (R)^102EZ6)₂R is a hydrogen atom^101EZ6And R^102EZ6To have-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO₃ ^-or-CO₂ ^-The heterocyclic group of (1). Wherein the hydrocarbon group or the heterocyclic group may have-SO₃ ^-and-CO₂ ^-And (ii) an additional substituent.

(ree-iii)R^1EZ6、R^2EZ6、R^3EZ6、R^4EZ6、R^5EZ6、R^6EZ6、R^7EZ6And R^11EZ6At least one of which is a compound having-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO₃ ^-or-CO₂ ^-The heterocyclic group of (1). Wherein the hydrocarbon group or the heterocyclic group may have-SO₃ ^-and-CO₂ ^-And (ii) an additional substituent.

Specific examples of compound IZ6 include compounds IFZ6-1 to IFZ6-32, compounds IGZ6-1 to IGZ6-32, compounds IHZ6-1 to IHZ6-32, and compounds IJZ6-1 to IJZ6-32, which are shown in tables 1Z6 to 4Z6, among formula (IFZ6), formula (IGZ6), formula (IHZ6), and formula (IJZ 6).

"-SO in the formulae (IFZ6), (IGZ6), (IHZ6) and (IJZ6)₃ ^-"represents a substitution of any hydrogen atom contained in the partial structure in parentheses, respectively.

[ Table 1Z6]

TABLE 1Z6

	R4Z6	Ac+	b	d
					IFZ6-1	H	Mg2+	1	1
IFZ6-2	H	Ca2+	1	1
					IFZ6-3	H	Sr2+	1	1
IFZ6-4	H	Ba2+	1	1
					IFZ6-5	H	Ni2+	1	1
IFZ6-6	H	Zn2+	1	1
					IFZ6-7	H	Fe2+	1	1
IFZ6-8	H	Co2+	1	1
					IFZ6-9	H	Sn2+	1	1
IFZ6-10	H	Mn2+	1	1
					IFZ6-11	H	Al3+	3	2
IFZ6-12	H	Fe3+	3	2
					IFZ6-13	H	Cr3+	3	2
IFZ6-14	H	Sn4+	2	1
					IFZ6-15	H	Mn4+	2	1
IFZ6-16	NO2	Mg2+	1	1
					IFZ6-17	NO2	Ca2+	1	1
IFZ6-18	NO2	Sr2+	1	1
					IFZ6-19	NO2	Ba2+	1	1
IFZ6-20	NO2	Ni2+	1	1
					IFZ6-21	NO2	Zn2+	1	1
IFZ6-22	NO2	Fe2+	1	1
					IFZ6-23	NO2	Co2+	1	1
IFZ6-24	NO2	Sn2+	1	1
					IFZ6-25	NO2	Mn2+	1	1
IFZ6-26	NO2	Al3+	3	2
					IFZ6-27	NO2	Fe3+	3	2
IFZ6-28	NO2	Cr3+	3	2
					IFZ6-29	NO2	Sn4+	2	1
IFZ6-30	NO2	Mn4+	2	1
					IFZ6-31	H	Cu2+	1	1
IFZ6-32	NO2	Cu2+	1	1

[ Table 2Z6]

TABLE 2Z6

	R4Z6	Ac+	b	d
					IGZ6-1	H	Mg2+	1	1
IGZ6-2	H	Ca2+	1	1
					IGZ6-3	H	Sr2+	1	1
IGZ6-4	H	Ba2+	1	1
					IGZ6-5	H	Ni2+	1	1
IGZ6-6	H	Zn2+	1	1
					IGZ6-7	H	Fe2+	1	1
IGZ6-8	H	Co2+	1	1
					IGZ6-9	H	Sn2+	1	1
IGZ6-10	H	Mn2+	1	1
					IGZ6-11	H	Al3+	3	2
IGZ6-12	H	Fe3+	3	2
					IGZ6-13	H	Cr3+	3	2
IGZ6-14	H	Sn4+	2	1
					IGZ6-15	H	Mn4+	2	1
IGZ6-16	NO2	Mg2+	1	1
					IGZ6-17	NO2	Ca2+	1	1
IGZ6-18	NO2	Sr2+	1	1
					IGZ6-19	NO2	Ba2+	1	1
IGZ6-20	NO2	Ni2+	1	1
					IGZ6-21	NO2	Zn2+	1	1
IGZ6-22	NO2	Fe2+	1	1
					IGZ6-23	NO2	Co2+	1	1
IGZ6-24	NO2	Sn2+	1	1
					IGZ6-25	NO2	Mn2+	1	1
IGZ6-26	NO2	Al3+	3	2
					IGZ6-27	NO2	Fe3+	3	2
IGZ6-28	NO2	Cr3+	3	2
					IGZ6-29	NO2	Sn4+	2	1
IGZ6-30	NO2	Mn4+	2	1
					IGZ6-31	H	Cu2+	1	1
IGZ6-32	NO2	Cu2+	1	1

[ Table 3Z6]

TABLE 3Z6

	R4Z6	Ac+	b	d
					IHZ6-1	H	Mg2+	1	1
IHZ6-2	H	Ca2+	1	1
					IHZ6-3	H	Sr2+	1	1
IHZ6-4	H	Ba2+	1	1
					IHZ6-5	H	Ni2+	1	1
IHZ6-6	H	Zn2+	1	1
					IHZ6-7	H	Fe2+	1	1
IHZ6-8	H	Co2+	1	1
					IHZ6-9	H	Sn2+	1	1
IHZ6-10	H	Mn2+	1	1
					IHZ6-11	H	Al3+	3	2
IHZ6-12	H	Fe3+	3	2
					IHZ6-13	H	Cr3+	3	2
IHZ6-14	H	Sn4+	2	1
					IHZ6-15	H	Mn4+	2	1
IHZ6-16	NO2	Mg2+	1	1
					IHZ6-17	NO2	Ca2+	1	1
IHZ6-18	NO2	Sr2+	1	1
					IHZ6-19	NO2	Ba2+	1	1
IHZ6-20	NO2	Ni2+	1	1
					IHZ6-21	NO2	Zn2+	1	1
IHZ6-22	NO2	Fe2+	1	1
					IHZ6-23	NO2	Co2+	1	1
IHZ6-24	NO2	Sn2+	1	1
					IHZ6-25	NO2	Mn2+	1	1
IHZ6-26	NO2	Al3+	3	2
					IHZ6-27	NO2	Fe3+	3	2
IHZ6-28	NO2	Cr3+	3	2
					IHZ6-29	NO2	Sn4+	2	1
IHZ6-30	NO2	Mn4+	2	1
					IHZ6-31	H	Cu2+	1	1
IHZ6-32	NO2	Cu2+	1	1

[ Table 4Z6]

TABLE 4Z6

	R4Z6	Ac+	b	d
					IJZ6-1	H	Mg2+	1	1
IJZ6-2	H	Ca2+	1	1
					IJZ6-3	H	Sr2+	1	1
IJZ6-4	H	Ba2+	1	1
					IJZ6-5	H	Ni2+	1	1
IJZ6-6	H	Zn2+	1	1
					IJZ6-7	H	Fe2+	1	1
IJZ6-8	H	Co2+	1	1
					IJZ6-9	H	Sn2+	1	1
IJZ6-10	H	Mn2+	1	1
					IJZ6-11	H	Al3+	3	2
IJZ6-12	H	Fe3+	3	2
					IJZ6-13	H	Cr3+	3	2
IJZ6-14	H	Sn4+	2	1
					IJZ6-15	H	Mn4+	2	1
IJZ6-16	NO2	Mg2+	1	1
					IJZ6-17	NO2	Ca2+	1	1
IJZ6-18	NO2	Sr2+	1	1
					IJZ6-19	NO2	Ba2+	1	1
IJZ6-20	NO2	Ni2+	1	1
					IJZ6-21	NO2	Zn2+	1	1
IJZ6-22	NO2	Fe2+	1	1
					IJZ6-23	NO2	Co2+	1	1
IJZ6-24	NO2	Sn2+	1	1
					IJZ6-25	NO2	Mn2+	1	1
IJZ6-26	NO2	Al3+	3	2
					IJZ6-27	NO2	Fe3+	3	2
IJZ6-28	NO2	Cr3+	3	2
					IJZ6-29	NO2	Sn4+	2	1
IJZ6-30	NO2	Mn4+	2	1
					IJZ6-31	H	Cu2+	1	1
IJZ6-32	NO2	Cu2+	1	1

For example, compound IFZ6-1 is a compound represented by formula (IFZ 6-1).

The compound IZ6 is preferably the compound IFZ6-1 to the compound IFZ6-4, the compound IFZ6-6 to the compound IFZ6-7, the compound IFZ6-10 to the compound IFZ6-13, the compound IFZ6-15 to the compound IFZ6-19, the compound IFZ6-21 to the compound IFZ6-22, the compound IFZ6-25 to the compound IFZ6-28, or the compound IFZ6-30 to the compound IFZ 6-31; compound IGZ6-1 to compound IGZ6-4, compound IGZ6-6 to compound IGZ6-7, compound IGZ6-10 to compound IGZ6-13, compound IGZ6-15 to compound IGZ6-19, compound IGZ6-21 to compound IGZ6-22, compound IGZ6-25 to compound IGZ6-28, and compound IGZ 6-30; compound IHZ6-1 to compound IHZ6-4, compound IHZ6-6 to compound IHZ6-7, compound IHZ6-10 to compound IHZ6-13, compound IHZ6-15 to compound IHZ6-19, compound IHZ6-21 to compound IHZ6-22, compound IHZ6-25 to compound IHZ6-28, and compound IHZ 6-30; and compounds IJZ6-1 to IJZ6-4, IJZ6-6 to IJZ6-7, IJZ6-10 to IJZ6-13, IJZ6-15 to IJZ6-19, IJZ6-21 to IJZ6-22, IJZ6-25 to IJZ6-28 and IJZ6-30,

More preferably, the compound is IFZ6-1 to IFZ6-4, IFZ6-6 to IFZ6-7, IFZ6-10 to IFZ6-13, IFZ6-15 to IFZ6-19, IFZ6-21 to IFZ6-22, IFZ6-25 to IFZ6-28 or IFZ 6-30; and compound IJZ6-1 to compound IJZ6-4, compound IJZ6-6 to compound IJZ6-7, compound IJZ6-10 to compound IJZ6-13, compound IJZ6-15 to compound IJZ6-19, compound IJZ6-21 to compound IJZ6-22, compound IJZ6-25 to compound IJZ6-28, and compound IJZ6-30 to compound IJZ 6-32.

As the compound (IZ6), the following compounds are preferable:

in the formula (IZ6-C), L¹And L²Are the same group and are-CO-or-SO₂-, preferably-CO-, R^11CZ6And R^14CZ6Are identical radicals, are hydroxy, -O^-Or may have a structure selected from the group consisting of-SO₃ ^-、-CO₂ ^-、-SO₃M and-CO₂A C1-20 hydrocarbon group as a substituent in the group consisting of M, R^1CZ6Is a hydrogen atom, or may have a radical selected from the group consisting of-SO₃ ^-、-CO₂ ^-、-SO₃M and-CO₂A C1-20 hydrocarbon group, -SO₃ ^-、-CO₂ ^-、-SO₃M or-CO₂M，

R^2CZ6～R^5CZ6Each independently represents a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogen atom, or-N (R)^102CZ6)₂A C1-20 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R ^102CZ6、-O-R^102CZ6、-SO₃ ^-、-CO₂ ^-、-SO₃M or-CO₂M，R^102CZ6Is a hydrogen atom, or may have a radical selected from the group consisting of-SO₃ ^-、-CO₂ ^-、-SO₃M and-CO₂A hydrocarbyl group having 1 to 20 carbon atoms as a substituent in the group consisting of M,

A^c+is Mg²⁺、Ca²⁺、Sr²⁺、Ba²⁺、Cd²⁺、Ni²⁺、Zn²⁺、Cu²⁺、Hg²⁺、Fe²⁺、Co²⁺、Sn²⁺、Pb²⁺And Mn²⁺Metal cation of equivalent 2 valence, Al³⁺、Fe³⁺And Cr³⁺Equi-3 valent metal cation, Sn⁴⁺And Mn⁴⁺A compound of an equivalent metal cation having a valence of 4, M being a hydrogen atom or an alkali metal atom;

more preferred are the following compounds:

L¹and L²Are the same group and are-CO-or-SO₂-, preferably-CO-, R^11CZ6And R^14CZ6Are identical radicals, are hydroxy, -O^-Or may have a structure selected from the group consisting of-SO₃ ^-、-CO₂ ^-、-SO₃M and-CO₂A C1-10 hydrocarbon group as a substituent in the group consisting of M, R^1CZ6Is a hydrogen atom, R^2CZ6～R^5CZ6Each independently represents a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, or-N (R)^102CZ6)₂A C1-10 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R^102CZ6、-O-R^102CZ6、-SO₃ ^-、-CO₂ ^-、-SO₃M or-CO₂M，

R^102CZ6Is a hydrogen atom, or may have a radical selected from the group consisting of-SO₃ ^-、-CO₂ ^-、-SO₃M and-CO₂A hydrocarbyl group having 1 to 10 carbon atoms as a substituent in the group consisting of M,

A^c+is Mg²⁺、Ca²⁺、Sr²⁺、Ba²⁺、Ni²⁺、Zn²⁺、Cu²⁺、Fe²⁺、Co²⁺、Sn²⁺、Mn²⁺、Al³⁺、Fe³⁺、Cr³⁺、Sn⁴⁺Or Mn⁴⁺M is a hydrogen atom or an alkali metal atom;

further preferred are the following compounds:

L¹and L²Are the same group and are-CO-or-SO₂-, preferably-CO-, R^11CZ6And R^14CZ6Are identical radicals, are hydroxy, -O ^-Or may have a structure selected from the group consisting of-SO₃ ^-、-CO₂ ^-、-SO₃M and-CO₂A C1-10 hydrocarbon group as a substituent in the group consisting of M, R^1CZ6Is a hydrogen atom, R^2CZ6～R^5CZ6Each independently represents a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, or-N (R)^102CZ6)₂Nitro, trifluoromethyl, -O-R^102CZ6、-SO₃ ^-、-CO₂ ^-、-SO₃M or-CO₂M，R^102CZ6Is a hydrogen atom, or may have a radical selected from the group consisting of-SO₃ ^-、-CO₂ ^-、-SO₃M and-CO₂A C1-10 hydrocarbon group as a substituent in the group consisting of M, A^c+Is Mg²⁺、Ca²⁺、Sr²⁺、Ba²⁺、Zn²⁺、Cu²⁺、Fe²⁺、Mn²⁺、Al³⁺、Fe³⁺、Cr³⁺Or Mn⁴⁺And M is a hydrogen atom or an alkali metal atom.

As the compound (IZ6), the following compounds are preferable:

in the formula (IZ6-E), L¹is-CO-or-SO₂-, preferably-CO-, R^11EZ6Is hydroxy, -O^-Or may have a structure selected from the group consisting of-SO₃ ^-、-CO₂ ^-、-SO₃M and-CO₂A C1-20 hydrocarbon group as a substituent in the group consisting of M, R^1EZ6Is a hydrogen atom, or may have a radical selected from the group consisting of-SO₃ ^-、-CO₂ ^-、-SO₃M and-CO₂A C1-20 hydrocarbon group, -SO₃ ^-、-CO₂ ^-、-SO₃M or-CO₂M，

R^2EZ6～R^5EZ6Each independently represents a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogen atom, or-N (R)^102EZ6)₂A C1-20 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R^102EZ6、-O-R^102EZ6、-SO₃ ^-、-CO₂ ^-、-SO₃M or-CO₂M，

R^102EZ6Is a hydrogen atom, or may have a radical selected from the group consisting of-SO₃ ^-、-CO₂ ^-、-SO₃M and-CO ₂A hydrocarbyl group having 1 to 20 carbon atoms as a substituent in the group consisting of M,

R^6EZ6and R^7EZ6Independently of one another, are hydrogen atoms or may have radicals selected from the group consisting of-SO₃ ^-、-CO₂ ^-、-SO₃M and-CO₂A C1-20 hydrocarbon group, -SO₃ ^-、-CO₂ ^-、-SO₃M or-CO₂M，

A^c+Is Mg²⁺、Ca²⁺、Sr²⁺、Ba²⁺、Cd²⁺、Ni²⁺、Zn²⁺、Cu²⁺、Hg²⁺、Fe²⁺、Co²⁺、Sn²⁺、Pb²⁺And Mn²⁺Metal cation of equivalent 2 valence, Al³⁺、Fe³⁺And Cr³⁺Equi-3 valent metal cation, Sn⁴⁺And Mn⁴⁺And the equivalent of a metal cation having a valence of 4,

a compound in which M is a hydrogen atom or an alkali metal atom;

more preferred are the following compounds:

L¹is-CO-or-SO₂-, preferably-CO-,

R^11EZ6is hydroxy, -O^-Or may have a structure selected from the group consisting of-SO₃ ^-、-CO₂ ^-、-SO₃M and-CO₂A hydrocarbyl group having 1 to 10 carbon atoms as a substituent in the group consisting of M,

R^1EZ6is a hydrogen atom, R^2EZ6～R^5EZ6Each independently represents a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, or-N (R)^102EZ6)₂A C1-10 hydrocarbon group in which all or a part of the hydrogen atoms are replaced by nitro groups or fluorine atoms, -NHCO-R^102EZ6、-O-R^102EZ6、-SO₃ ^-、-CO₂ ^-、-SO₃M or-CO₂M，

R^102EZ6Is a hydrogen atom, or may have a radical selected from the group consisting of-SO₃ ^-、-CO₂ ^-、-SO₃M and-CO₂A hydrocarbyl group having 1 to 10 carbon atoms as a substituent in the group consisting of M,

R^6EZ6and R^7EZ6Independently of one another, are hydrogen atoms or may have radicals selected from the group consisting of-SO₃ ^-、-CO₂ ^-、-SO₃M and-CO₂A C1-10 hydrocarbon group as a substituent in the group consisting of M, A ^c+Is Mg²⁺、Ca²⁺、Sr²⁺、Ba²⁺、Ni²⁺、Zn²⁺、Cu²⁺、Fe^{2 +}、Co²⁺、Sn²⁺、Mn²⁺、Al³⁺、Fe³⁺、Cr³⁺、Sn⁴⁺Or Mn⁴⁺M is a hydrogen atom or an alkali metal atom;

further preferred are the following compounds:

L¹is-CO-or-SO₂-, preferably-CO-, R^11EZ6Is hydroxy, -O^-Or may have a structure selected from the group consisting of-SO₃ ^-、-CO₂ ^-、-SO₃M and-CO₂A hydrocarbyl group having 1 to 10 carbon atoms as a substituent in the group consisting of M,

R^1EZ6is a hydrogen atom, R^2EZ6～R^5EZ6Each independently represents a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, or-N (R)^102EZ6)₂Nitro, trifluoromethyl, -O-R^102EZ6、-SO₃ ^-、-CO₂ ^-、-SO₃M or-CO₂M，R^102EZ6Is a hydrogen atom, or may have a radical selected from the group consisting of-SO₃ ^-、-CO₂ ^-、-SO₃M and-CO₂A C1-10 hydrocarbon group as a substituent in the group consisting of M, R^6EZ6And R^7EZ6Independently represents a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms, A^c+Is Mg²⁺、Ca²⁺、Sr²⁺、Ba²⁺、Zn²⁺、Cu²⁺、Fe²⁺、Mn²⁺、Al³⁺、Fe³⁺、Cr³⁺Or Mn⁴⁺And M is a hydrogen atom or an alkali metal atom.

The compound represented by formula (IZ6) can be produced by reacting the compound represented by formula (JZ6) with the compound represented by formula (KZ 6). In particular, 1 or 2 or more compounds of formula (JZ6) and formula (KZ6) may be used.

[ in the formula (JZ6), the formula (KZ6) and the formula (IZ6), a, b, c, D, D, Z and A^c+The same meanings as described above are indicated. ZZ represents-SO₃M or-CO₂And M. M represents the same meaning as described above. MM denotes the direction of inclusion A ^c+A metal compound which provides 0 or more and c or less electrons.

When a plurality of compounds represented by the formula (JZ6), D, ZZ, a, MM, and M are present, they may be the same or different. ]

Examples of the compound represented by formula (KZ6) include:

comprises the direction A^c+Inorganic compounds such as chlorides, bromides, iodides, sulfates, nitrates, fluorosulfonates, and phosphates of metals that provide 0 or more and c or less electrons; comprises the direction A^c+Sulfonates such as methanesulfonate, trifluoromethanesulfonate and p-toluenesulfonate of a metal which provide 0 or more and c or less electrons;

comprises the direction A^c+Carboxylates such as acetates, citrates, formates, gluconates, lactates, oxalates, and tartrates of metals that provide 0 or more and c or less electrons;

substituted by alkoxy groups such as methoxy, ethoxy, tert-butoxy, etc. to A^c+A metal providing 0 or more and c or less electrons; substituted by butyl, tert-butyl, phenyl, etc. to A^c+A metal providing 0 or more and c or less electrons;

by substitution of hydroxy groupsIn the direction of A^c+A metal which supplies 0 or more and c or less electrons, and the like.

The amount of the compound represented by the formula (KZ6) used is usually 0.05 to 20 mol, preferably 0.06 to 15 mol, and more preferably 0.1 to 10 mol, based on 1 mol of the compound represented by the formula (JZ 6).

When the compound represented by the formula (JZ6) is reacted with the compound represented by the formula (KZ6), a base is preferably present. Examples of the base include organic bases such as triethylamine, 4- (N, N-dimethylamino) pyridine, and piperidine, metal alkoxides such as sodium methoxide, sodium ethoxide, sodium tert-butoxide, and potassium tert-butoxide, organic metal compounds such as butyllithium, tert-butyllithium, and phenyllithium, and inorganic bases such as lithium hydroxide, sodium hydroxide, and potassium hydroxide.

The amount of the base used is usually 0.0001 to 10 moles, preferably 0.0001 to 8 moles, more preferably 0.0001 to 5 moles, and still more preferably 0.0001 to 4 moles, based on 1 mole of the compound represented by formula (JZ 6).

The reaction of the compound represented by the formula (JZ6) with the compound represented by the formula (KZ6) can be usually carried out in the presence of a solvent.

As the solvent, water may be mentioned; nitrile solvents such as acetonitrile; alcohol solvents such as methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, and 1-octanol; ether solvents such as tetrahydrofuran; ketone solvents such as acetone; ester solvents such as ethyl acetate; aliphatic hydrocarbon solvents such as hexane; aromatic hydrocarbon solvents such as toluene; halogenated hydrocarbon solvents such as dichloromethane and chloroform; amide solvents such as N, N-dimethylformamide and N-methylpyrrolidone; and sulfoxide solvents such as dimethyl sulfoxide, preferably water, nitrile solvents, alcohol solvents, ether solvents, ketone solvents, ester solvents, aromatic hydrocarbon solvents, halogenated hydrocarbon solvents, amide solvents and sulfoxide solvents, more preferably water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, tetrahydrofuran, acetone, ethyl acetate, toluene, dichloromethane, chloroform, N-dimethylformamide, N-methylpyrrolidone and dimethyl sulfoxide, still more preferably water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, acetone, dichloromethane, chloroform, N-dimethylformamide, N-methylpyrrolidone and dimethyl sulfoxide, and particularly preferably water, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, acetone, dichloromethane, chloroform, N-dimethylformamide, N-methylpyrrolidone and dimethyl sulfoxide, Acetonitrile, methanol, ethanol and 2-propanol.

The amount of the solvent used is usually 1 to 1000 parts by mass relative to 1 part by mass of the compound represented by formula (JZ 6).

The reaction temperature of the compound represented by the formula (JZ6) and the compound represented by the formula (KZ6) is usually-20 to 200 ℃, preferably-10 to 100 ℃, and more preferably 0 to 50 ℃. The reaction time is usually 0.5 to 300 hours.

When the compound represented by the formula (IZ6) is a compound represented by the formula (IZ6-A), it can be produced in the same manner as described above. Specifically, the compound represented by the formula (JJZ6) can be produced by reacting a compound represented by the formula (KZ 6). In particular, 1 or 2 or more compounds of formula (JJZ6) and (KZ6) may be used, respectively.

[ formula (JJZ6), formula (KZ6) and formula (IZ6-A) wherein A^c+、b、c、d、R^1AZ6、R^2AZ6、R^3AZ6、R^4AZ6、R^5AZ6、R^AA1Z6、R^AA2Z6、R^12AZ6、R^13AZ6And the wavy line means the same as described above.

R^1AAZ6、R^2AAZ6、R^3AAZ6、R^4AAZ6、R^5AAZ6、R^AAA1Z6、R^AAA2Z6、R^12AAZ6And R^13AAZ6Independently of one another, represents a hydrogen atom, -CO-R^102AAZ6、-COO-R^101AAZ6、-OCO-R^102AAZ6、-O-R^102AAZ6、-SO₂-R^101AAZ6、-SO₂N(R^102AAZ6)₂、-CON(R^102AAZ6)₂、-N(R^102AAZ6)₂、-NHCO-R^102AAZ6Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a C1-40 hydrocarbon group which may have a substituent orA heterocyclic group which may have a substituent.

R^2AAZ6And R^3AAZ6、R^3AAZ6And R^4AAZ6、R^4AAZ6And R^5AZ6、R^AAA1Z6And R^AAA2Z6And R^12AAZ6And R^13AAZ6Each of which may be bonded to each other to form a ring.

R^101AAZ6Independently represent a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.

R^102AAZ6Independently represent a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group.

M represents the same meaning as described above. R^1AAZ6、R^2AAZ6、R^3AAZ6、R^4AAZ6、R^5AAZ6、R^AAA1Z6、R^AAA2Z6、R^12AAZ6、R^13AAZ6、R^101AAZ6、R^102AAZ6Or when there are a plurality of M, they may be the same or different.

R^1AAZ6、R^2AAZ6、R^3AAZ6、R^4AAZ6、R^5AAZ6、R^AAA1Z6、R^AAA2Z6、R^12AAZ6、R^13AAZ6、R^101AAZ6And R^102AAZ6Satisfies at least 1 of (j-i) to (j-iii), R^1AAZ6、R^2AAZ6、R^3AAZ6、R^4AAZ6、R^5AAZ6、R^AAA1Z6、R^AAA2Z6、R^12AAZ6、R^13AAZ6、R^101AAZ6And R^102AAZ6having-SO of₃M or-CO₂The total number of M is more than a.

(j-i)R^1AAZ6、R^2AAZ6、R^3AAZ6、R^4AAZ6、R^5AAZ6、R^AAA1Z6、R^AAA2Z6、R^12AAZ6And R^13AAZ6At least one of which is-SO₃M or-CO₂M。

(j-ii)R^1AAZ6、R^2AAZ6、R^3AAZ6、R^4AAZ6、R^5AAZ6、R^AAA1Z6、R^AAA2Z6、R^12AAZ6And R^13AAZ6At least one of which is-CO-R^102AAZ6、-COO-R^101AAZ6、-OCO-R^102AAZ6、-O-R^102AAZ6、-SO₂-R^101AAZ6、-SO₂N(R^102AAZ6)₂、-CON(R^102AAZ6)₂、-N(R^102AAZ6)₂or-NHCO-R^102AAZ6R is a hydrogen atom^101AAZ6And R^102AAZ6To have-SO₃ ^-or-CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or having-SO₃ ^-or-CO₂ ^-The heterocyclic group of (1). Wherein the hydrocarbon group or the heterocyclic group may have-SO₃ ^-and-CO₂ ^-And (ii) an additional substituent.

(j-iii)R^1AAZ6、R^2AAZ6、R^3AAZ6、R^4AAZ6、R^5AAZ6、R^AAA1Z6、R^AAA2Z6、R^12AAZ6And R^13AAZ6At least one of which is a compound having-SO₃M or-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms or has-SO₃M or-CO₂A heterocyclic group of M. Wherein the hydrocarbon group or the heterocyclic group may have-SO₃ ^-and-CO₂ ^-And (ii) an additional substituent.

a represents the same meaning as the symbol in the formula (IZ 6). When a plurality of a exist, they may be the same or different. ]

With respect to the compound represented by the formula (JJZ6) (hereinafter, may be referred to as compound JJZ6), R^1AAZ6In the case of a hydrogen atom, the compound represented by the formula (pt1Z6) (hereinafter, may be referred to as a phthalonitrile compound) and the compound represented by the formula (pt2Z6) (hereinafter, may be referred to as an alkoxide compound) are reacted with each other, and then the compound represented by the formula (pt3Z6) (hereinafter, may be referred to as a compound pt3Z6) and the compound represented by the formula (pt4Z6) (hereinafter, may be referred to as a compound pt4Z6) are further reacted with each other in the presence of an acid. In addition, R ^1AAZ6When not a hydrogen atom, a compound represented by the formula (pt5Z6) (hereinafter, may be referred to as a compound pt5Z 6).) The reaction to produce a compound represented by formula (JJZ 6). Here, the compounds represented by the formula (pt1Z6), the formula (pt2Z6), the formula (pt3Z6), the formula (pt4Z6) and the formula (pt5Z6) may be independent of each other, individual compounds, or a mixture of different compounds.

In [ formula (pt1Z6), formula (pt2Z6), formula (pt3Z6), formula (pt4Z6), formula (pt5Z6) and formula (JJZ6), R^1AAZ6、R^2AAZ6、R^3AAZ6、R^4AAZ6、R^5AAZ6、R^AAA1Z6、R^AAA2Z6、R^12AAZ6And R^13AAZ6The same meanings as described above are indicated. R^50Z6Represents an alkyl group having 1 to 20 carbon atoms. M^1Z6Represents an alkali metal atom. LG represents a halogen atom, a mesyloxy group, a tosyloxy group or a trifluormesyloxy group.]

As R^50Z6Examples of the alkyl group having 1 to 20 carbon atoms include methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec-butyl, tert-butyl, and the like, and preferred examples thereof include alkyl groups having 1 to 6 carbon atoms.

As M^1Z6Examples of the alkali metal atom include a lithium atom, a sodium atom and a potassium atom.

The amount of the alkoxide compound used is usually 0.1 to 10 moles, preferably 0.2 to 5 moles, more preferably 0.3 to 3 moles, and still more preferably 0.4 to 2 moles, based on 1 mole of the phthalonitrile compound.

The amount of the compound pt3Z6 used is usually 1 to 10 moles, preferably 1 to 5 moles, more preferably 1 to 3 moles, and still more preferably 1 to 2 moles, based on 1 mole of the phthalonitrile compound.

The amount of the compound pt4Z6 used is usually 1 to 10 moles, preferably 1 to 5 moles, more preferably 1 to 3 moles, and still more preferably 1 to 2 moles, based on 1 mole of the phthalonitrile compound.

Examples of the acid include inorganic acids such as hydrochloric acid, hydrobromic acid, hydroiodic acid, sulfuric acid, nitric acid, fluorosulfonic acid, and phosphoric acid; sulfonic acids such as methanesulfonic acid, trifluoromethanesulfonic acid, and p-toluenesulfonic acid; examples of the carboxylic acid include acetic acid, citric acid, formic acid, gluconic acid, lactic acid, oxalic acid, tartaric acid, and the like, and preferably include hydrochloric acid, hydrobromic acid, sulfuric acid, methanesulfonic acid, trifluoromethanesulfonic acid, p-toluenesulfonic acid, and carboxylic acid, and more preferably include acetic acid.

The amount of the acid used is usually 1 to 20 moles, preferably 1 to 10 moles, more preferably 1 to 8 moles, and still more preferably 1 to 6 moles, based on 1 mole of the phthalonitrile compound.

The reaction of the phthalonitrile compound, the alkoxide compound, the compound pt3Z6, and the compound pt4Z6 can be usually carried out in the presence of a solvent.

As the solvent, water may be mentioned; nitrile solvents such as acetonitrile; alcohol solvents such as methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, and 1-octanol; ether solvents such as tetrahydrofuran; ketone solvents such as acetone; ester solvents such as ethyl acetate; aliphatic hydrocarbon solvents such as hexane; aromatic hydrocarbon solvents such as toluene; halogenated hydrocarbon solvents such as dichloromethane and chloroform; amide solvents such as N, N-dimethylformamide and N-methylpyrrolidone; sulfoxide solvents such as dimethyl sulfoxide, preferably include water, nitrile solvents, alcohol solvents, ether solvents, ketone solvents, ester solvents, aromatic hydrocarbon solvents, halogenated hydrocarbon solvents, amide solvents and sulfoxide solvents, more preferably include water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, tetrahydrofuran, acetone, ethyl acetate, toluene, dichloromethane, chloroform, N-dimethylformamide, N-methylpyrrolidone and dimethyl sulfoxide, still more preferably include water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, acetone, dichloromethane, chloroform, N-dimethylformamide, N-methylpyrrolidone and dimethyl sulfoxide, and particularly preferably include water, methanol, ethanol, methanol, ethanol, butanol, methanol, ethanol, 1-butanol, 1-pentanol, 1-octanol, acetone, dichloromethane, chloroform, N-methylpyrrolidone and dimethyl sulfoxide, Acetonitrile, methanol, ethanol and 2-propanol.

The amount of the solvent used is usually 1 to 1000 parts by mass per 1 part by mass of the phthalonitrile compound.

The reaction temperature is usually 0 to 200 ℃, preferably 0 to 100 ℃, more preferably 0 to 70 ℃, and further preferably 0 to 50 ℃. The reaction time is usually 0.5 to 300 hours.

With respect to the amount of compound pt5Z6 used, relative to R^1AAZ6The amount of the compound JJZ 61 which is a hydrogen atom is usually 1 to 10 moles, preferably 1 to 5 moles, more preferably 1 to 3 moles, and still more preferably 1 to 2 moles.

When the compound pt5Z6 is reacted, a base is preferably coexisted. Examples of the base include organic bases such as triethylamine, 4- (N, N-dimethylamino) pyridine, and piperidine, metal alkoxides such as sodium methoxide, sodium ethoxide, sodium tert-butoxide, and potassium tert-butoxide, and organic metal compounds such as butyllithium, tert-butyllithium, and phenyllithium; inorganic bases such as lithium hydroxide, sodium hydroxide and potassium hydroxide.

As for the amount of the base used, with respect to R^1AAZ6The amount of the compound JJZ 61 which is a hydrogen atom is usually 1 to 10 moles, preferably 1 to 5 moles, more preferably 1 to 3 moles, and still more preferably 1 to 2 moles.

The reaction of compound pt5Z6 can generally be carried out in the presence of a solvent. The solvent may be selected from the same ranges as described above.

As to the amount of the solvent used, with respect to R^1AAZ6The amount of the compound JJZ 61 which is a hydrogen atom is usually 1 to 1000 parts by mass. The reaction temperature of the compound pt5Z6 is usually-90 to 200 ℃, preferably-80 to 100 ℃, and more preferably 0 to 50 ℃. The reaction time is usually 0.5 to 300 hours.

Compound JJZ6 is a compound having no-SO₃In the case of the compound of M (hereinafter, sometimes referred to as compound JJJZ6), the compound JJJZ6 may be introduced into-SO by reacting it with a sulfonating agent such as fuming sulfuric acid or chlorosulfonic acid₃M。

With respect to SO in oleum₃The amount of (b) is usually 1 to 50 moles, preferably 5 to 40 moles, more preferably 5 to 30 moles, and still more preferably 5 to 25 moles, based on the moles of the compound jjjjz 61.

The amount of sulfuric acid used in oleum is usually 1 to 200 moles, preferably 10 to 100 moles, more preferably 10 to 75 moles, and still more preferably 10 to 50 moles, based on the moles of compound jjjjz 61 moles.

The amount of chlorosulfonic acid used is usually 1 to 500 moles, preferably 10 to 300 moles, more preferably 10 to 200 moles, and still more preferably 10 to 150 moles, based on the moles of the compound JJJZ 61.

The reaction temperature of sulfonation is usually-20 to 200 ℃, preferably-10 to 100 ℃, and more preferably 0 to 50 ℃. The reaction time is usually 0.5 to 300 hours.

The method for extracting the compound JJZ6 from the reaction mixture is not particularly limited, and it can be extracted by various known methods. For example, compound JJZ6 can be extracted by filtering the reaction mixture after the reaction is completed. Further, the residue obtained after filtration may be subjected to column chromatography, recrystallization, or the like. After the completion of the reaction, the solvent of the reaction mixture may be distilled off and then purified by column chromatography.

The coloring composition of the present invention contains the compound Z and at least one of the resin (B) and the solvent (E), and preferably contains both the resin (B) and the solvent (E) and the compound Z.

The coloring composition of the present invention preferably contains a resin (hereinafter, sometimes referred to as resin (B)). By including the resin (B) in the coloring composition, dispersion stability may be further improved.

< resin (B) >

The resin (B) is preferably an alkali-soluble resin, and more preferably a polymer having a structural unit derived from at least 1 monomer (a) (hereinafter, sometimes referred to as "(a)") selected from the group consisting of an unsaturated carboxylic acid and an unsaturated carboxylic acid anhydride.

The resin (B) is preferably a copolymer having a structural unit derived from a monomer (B) (hereinafter sometimes referred to as "(B)") having a cyclic ether structure having 2 to 4 carbon atoms and an ethylenically unsaturated bond, and other structural units.

Examples of other structural units include: a structural unit derived from a monomer (c) copolymerizable with the monomer (a) (however, it is different from the monomer (a) and the monomer (b) and may be referred to as "(c)" hereinafter), a structural unit having an ethylenically unsaturated bond, and the like.

Examples of (a) include:

unsaturated monocarboxylic acids such as acrylic acid, methacrylic acid, crotonic acid, o-vinylbenzoic acid, m-vinylbenzoic acid, and p-vinylbenzoic acid;

unsaturated dicarboxylic acids such as maleic acid, fumaric acid, citraconic acid, mesaconic acid, itaconic acid, 3-vinylphthalic acid, 4-vinylphthalic acid, 3,4,5, 6-tetrahydrophthalic acid, 1,2,3, 6-tetrahydrophthalic acid, dimethyltetrahydrophthalic acid, and 1, 4-cyclohexenedicarboxylic acid;

carboxyl group-containing bicyclic unsaturated compounds such as methyl-5-norbornene-2, 3-dicarboxylic acid, 5-carboxybicyclo [2.2.1] hept-2-ene, 5, 6-dicarboxybicyclo [2.2.1] hept-2-ene, 5-carboxymethylbicyclo [2.2.1] hept-2-ene and 5-carboxyethylbicyclo [2.2.1] hept-2-ene; carboxylic acid anhydrides such as anhydrides of the above unsaturated dicarboxylic acids other than fumaric acid and mesaconic acid; unsaturated mono [ (meth) acryloyloxyalkyl ] esters of 2-or more-membered polycarboxylic acids such as succinic acid mono [ 2- (meth) acryloyloxyethyl ] ester and phthalic acid mono [ 2- (meth) acryloyloxyethyl ] ester;

And unsaturated acrylates containing a hydroxyl group and a carboxyl group in the same molecule, such as α - (hydroxymethyl) acrylic acid.

Among these, acrylic acid, methacrylic acid, maleic anhydride and the like are preferable from the viewpoint of copolymerization reactivity and solubility of the obtained resin in an aqueous alkaline solution.

(b) The polymerizable compound has a cyclic ether structure having 2 to 4 carbon atoms (for example, at least 1 selected from the group consisting of an oxirane ring, an oxetane ring, and a tetrahydrofuran ring) and an ethylenically unsaturated bond. (b) Preferably, the monomer has a cyclic ether having 2 to 4 carbon atoms and a (meth) acryloyloxy group.

Examples of (b) include: a monomer (b1) (hereinafter sometimes referred to as "(b 1)") having an oxetanyl group and an ethylenically unsaturated bond, a monomer (b2) (hereinafter sometimes referred to as "(b 2)") having an oxetanyl group and an ethylenically unsaturated bond, and a monomer (b3) (hereinafter sometimes referred to as "(b 3)") having a tetrahydrofuranyl group and an ethylenically unsaturated bond.

Examples of (b1) include: a monomer (b1-1) (hereinafter sometimes referred to as "(b 1-1)") having a structure obtained by epoxidizing a linear or branched aliphatic unsaturated hydrocarbon, and a monomer (b1-2) (hereinafter sometimes referred to as "(b 1-2)") having a structure obtained by epoxidizing an alicyclic unsaturated hydrocarbon.

As (b1-1), a monomer having a glycidyl group and an ethylenically unsaturated bond is preferable. Specific examples of (b1-1) include glycidyl (meth) acrylate,. beta. -methylglycidyl (meth) acrylate,. beta. -ethylglycidyl (meth) acrylate, glycidyl vinyl ether, vinylbenzyl glycidyl ether,. alpha. -methylvinylbenzyl glycidyl ether, 2, 3-bis (glycidyloxymethyl) styrene, 2, 4-bis (glycidyloxymethyl) styrene, 2, 5-bis (glycidyloxymethyl) styrene, 2, 6-bis (glycidyloxymethyl) styrene, 2,3, 4-tris (glycidyloxymethyl) styrene, 2,3, 5-tris (glycidyloxymethyl) styrene, 2,3, 6-tris (glycidyloxymethyl) styrene, 3,4, 5-tris (glycidyloxymethyl) styrene, 2,4, 6-tris (glycidyloxymethyl) styrene and the like.

Examples of (b1-2) include vinylcyclohexene monooxide, 1, 2-epoxy-4-vinylcyclohexane (for example, CELLOXIDE (registered trademark) 2000 (manufactured by DAicel Co., Ltd.), (3, 4-epoxycyclohexylmethyl (meth) acrylate (for example, CYCLOMER (registered trademark) A400 (manufactured by Daicel Co., Ltd.), (3, 4-epoxycyclohexylmethyl (meth) acrylate (for example, CYCLOMER (registered trademark) M100 (manufactured by Daicel Co., Ltd.)), the compound represented by the formula (BI), and the compound represented by the formula (BII).

[ formula (BI) and formula (BII) wherein R^aAnd R^bIndependently represent a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, the alkyl groupThe hydrogen atoms contained in the radicals may be substituted by hydroxyl groups. X^aAnd X^bIndependently of one another, represents a single bond, -R^c-、*-R^c-O-、*-R^c-S-or R^c-NH-。R^cRepresents an alkanediyl (alkanediyl) group having 1 to 6 carbon atoms. Denotes a bond to O.]

The compound represented by formula (BI) includes compounds represented by any one of formulae (BI-1) to (BI-15), preferably compounds represented by formulae (BI-1), (BI-3), (BI-5), (BI-7), (BI-9), and (BI-11) to (BI-15), and more preferably compounds represented by formulae (BI-1), (BI-7), (BI-9), and (BI-15).

The compound represented by formula (BII) includes compounds represented by any one of formulae (BII-1) to (BII-15), preferably compounds represented by formulae (BII-1), (BII-3), (BII-5), (BII-7), (BII-9), and (BII-11) to (BII-15), and more preferably compounds represented by formulae (BII-1), (BII-7), (BII-9), and (BII-15).

The compound represented by the formula (BI) and the compound represented by the formula (BII) may be used alone or in combination. When they are used in combination, the content ratio of the compound represented by the formula (BI) to the compound represented by the formula (BII) is preferably 5:95 to 95:5, more preferably 10:90 to 90:10, and further preferably 20:80 to 80:20 on a molar basis.

Examples of (c) include: methyl (meth) acrylate, ethyl (meth) acrylate, n-butyl (meth) acrylate, sec-butyl (meth) acrylate, tert-butyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, dodecyl (meth) acrylate, and (meth) acrylic acidLauryl (meth) acrylate, stearyl (meth) acrylate, cyclopentyl (meth) acrylate, tricyclo [5.2.1.0 (meth) acrylate^2,6]Decan-8-yl ester, tricyclo [5.2.1.0 ] meth (acrylic acid)^2,6]Decan-9-yl ester, tricyclo [5.2.1.0 ] meth (acrylic acid)^2,6]Decen-8-yl ester, tricyclo [5.2.1.0 ] meth (acrylic acid)^2,6](meth) acrylates such as decen-9-yl ester, dicyclopentanyl oxyethyl (meth) acrylate, isobornyl (meth) acrylate, adamantyl (meth) acrylate, allyl (meth) acrylate, propargyl (meth) acrylate, phenyl (meth) acrylate, naphthyl (meth) acrylate, and benzyl (meth) acrylate;

hydroxyl group-containing (meth) acrylates such as 2-hydroxyethyl (meth) acrylate and 2-hydroxypropyl (meth) acrylate;

dicarboxylic acid diesters such as diethyl maleate, diethyl fumarate and diethyl itaconate; bicyclo [2.2.1] hept-2-ene, 5-methylbicyclo [2.2.1] hept-2-ene, 5-ethylbicyclo [2.2.1] hept-2-ene, 5-hydroxybicyclo [2.2.1] hept-2-ene, 5-hydroxymethylbicyclo [2.2.1] hept-2-ene, 5- (2 '-hydroxyethyl) bicyclo [2.2.1] hept-2-ene, 5-methoxybicyclo [2.2.1] hept-2-ene, 5-ethoxybicyclo [2.2.1] hept-2-ene, 5, 6-dihydroxybicyclo [2.2.1] hept-2-ene, 5, 6-bis (hydroxymethyl) bicyclo [2.2.1] hept-2-ene, 5, 6-bis (2' -hydroxyethyl) bicyclo [2.2.1] hept-2-ene, 5, 6-dimethoxybicyclo [2.2.1] hept-2-ene, 5, 6-diethoxybicyclo [2.2.1] hept-2-ene, 5-hydroxy-5-methylbicyclo [2.2.1] hept-2-ene, 5-hydroxy-5-ethylbicyclo [2.2.1] hept-2-ene, 5-hydroxymethyl-5-methylbicyclo [2.2.1] hept-2-ene, bicyclic unsaturated compounds such as 5-tert-butoxycarbonylbicyclo [2.2.1] hept-2-ene, 5-cyclohexyloxycarbonybicyclo [2.2.1] hept-2-ene, 5-phenoxycarbonylbicyclo [2.2.1] hept-2-ene, 5, 6-bis (tert-butoxycarbonyl) bicyclo [2.2.1] hept-2-ene and 5, 6-bis (cyclohexyloxycarbonyl) bicyclo [2.2.1] hept-2-ene; dicarbonylimide derivatives such as N-phenylmaleimide, N-cyclohexylmaleimide, N-benzylmaleimide, N-succinimidyl 3-maleimidobenzoate, N-succinimidyl 4-maleimidobutyrate, N-succinimidyl 6-maleimidohexanoate, N-succinimidyl 3-maleimidopropionate and N- (9-acridinyl) maleimide;

Vinyl group-containing aromatic compounds such as styrene, α -methylstyrene, vinyltoluene and p-methoxystyrene; vinyl group-containing nitriles such as (meth) acrylonitrile; halogenated hydrocarbons such as vinyl chloride and vinylidene chloride; vinyl group-containing amides such as (meth) acrylamide; esters such as vinyl acetate; dienes such as 1, 3-butadiene, isoprene and 2, 3-dimethyl-1, 3-butadiene; and so on.

Among these, styrene, vinyltoluene, and tricyclo [5.2.1.0 (meth) acrylate are preferable from the viewpoint of copolymerization reactivity and heat resistance^2,6]Decan-8-yl ester, tricyclo [5.2.1.0 ] meth (acrylic acid)^2,6]Decan-9-yl ester, tricyclo [5.2.1.0 ] meth (acrylic acid)^2,6]Decen-8-yl ester, tricyclo [5.2.1.0 ] meth (acrylic acid)^2,6]Decen-9-yl ester, N-phenylmaleimide, N-cyclohexylmaleimide, N-benzylmaleimide, bicyclo [2.2.1]Hept-2-ene, benzyl (meth) acrylate, and the like.

The structural unit having an ethylenically unsaturated bond is preferably a structural unit having a (meth) acryloyl group. The resin having such a structural unit can be obtained by adding a monomer having an ethylenically unsaturated bond in a group reactive with the group (a) and/or (b) to a polymer having a structural unit derived from (a) and/or (b).

Examples of such a structural unit include a structural unit in which glycidyl (meth) acrylate is added to a (meth) acrylic acid unit, a structural unit in which 2-hydroxyethyl (meth) acrylate is added to a maleic anhydride unit, and a structural unit in which glycidyl (meth) acrylate is added to a (meth) acrylic acid unit. When these structural units have a hydroxyl group, a structural unit obtained by further adding a carboxylic anhydride may be mentioned as a structural unit having an ethylenically unsaturated bond.

The polymer having a structural unit derived from (a) can be produced, for example, by polymerizing a monomer constituting the structural unit of the polymer in a solvent in the presence of a polymerization initiator. The polymerization initiator and the solvent are not particularly limited, and polymerization initiators and solvents generally used in the art can be used. Examples of the polymerization initiator include azo compounds (e.g., 2 '-azobisisobutyronitrile, 2' -azobis (2, 4-dimethylvaleronitrile), and organic peroxides (e.g., benzoyl peroxide), and any solvent may be used as long as it dissolves the monomers.

The polymer obtained may be used as it is in a solution after the reaction, may be used as a solution obtained by concentration or dilution, or may be used as a copolymer obtained in a solid (powder) form by a method such as reprecipitation.

If necessary, a catalyst for the reaction of a carboxylic acid or a carboxylic anhydride with a cyclic ether (e.g., tris (dimethylaminomethyl) phenol) and a polymerization inhibitor (e.g., hydroquinone) can be used.

Examples of the carboxylic acid anhydride include maleic anhydride, citraconic anhydride, itaconic anhydride, 3-vinylphthalic anhydride, 4-vinylphthalic anhydride, 3,4,5, 6-tetrahydrophthalic anhydride, 1,2,3, 6-tetrahydrophthalic anhydride, dimethyltetrahydrophthalic anhydride, and 5, 6-dicarboxybicyclo [2.2.1] hept-2-ene anhydride.

Specific examples of the resin (B) include a 3, 4-epoxycyclohexylmethyl (meth) acrylate/(meth) acrylic acid copolymer, and a 3, 4-epoxytricyclo [5.2.1.0 ] meth (acrylic acid)^2,6]Decyl ester/(meth) acrylic acid copolymer, glycidyl (meth) acrylate/(benzyl (meth) acrylate/(meth) acrylic acid copolymer, glycidyl (meth) acrylate/styrene/(meth) acrylic acid copolymer, and 3, 4-epoxytricyclo [5.2.1.0 ] meth) acrylic acid^2,6]Decyl ester/(meth) acrylic acid/N-cyclohexylmaleimide copolymer, 3, 4-epoxytricyclo [5.2.1.0 ] meth (acrylic acid)^2,6]Decyl ester/(meth) acrylic acid/N-cyclohexylmaleimide/(meth) acrylic acid 2-hydroxyethyl ester copolymer, 3, 4-epoxytricyclo [5.2.1.0 ] meth (acrylic acid) ^2,6]Decyl ester/(meth) acrylic acid/vinyltoluene copolymer, 3, 4-epoxytricyclo [5.2.1.0 ] meth (acrylic acid)^2,6]Decyl ester/(meth) acrylic acid 2-ethylhexyl esterEster copolymer, 3, 4-epoxy tricyclo [5.2.1.0 ] meth (acrylic acid)^2,6]Decyl ester/(meth) acrylic acid tricyclo [5.2.1.0^2,6]Decenyl ester/(meth) acrylic acid/N-cyclohexylmaleimide copolymer, 3-methyl-3- (meth) acryloyloxymethyloxetane/(meth) acrylic acid/styrene copolymer, benzyl (meth) acrylate/(meth) acrylic acid copolymer, styrene/(meth) acrylic acid copolymer, and resins described in each of Japanese patent application laid-open Nos. 9-106071, 2004-29518 and 2004-361455.

Among these, the resin (B) is preferably a copolymer containing a structural unit derived from (a) and a structural unit derived from (B).

In the case where 2 or more species are combined with the resin (B), it is preferable that the resin (B) contains at least 3, 4-epoxytricyclo [5.2.1.0 ] selected from (meth) acrylic acid^2,6]Decyl ester/(meth) acrylic acid copolymer, 3, 4-epoxytricyclo [5.2.1.0 ] meth (acrylic acid)^2,6]Decyl ester/(meth) acrylic acid/N-cyclohexylmaleimide/(meth) acrylic acid 2-hydroxyethyl ester copolymer, 3, 4-epoxytricyclo [5.2.1.0 ] meth (acrylic acid) ^2,6]Decyl ester/(meth) acrylic acid/vinyltoluene copolymer, 3, 4-epoxytricyclo [5.2.1.0 ] meth (acrylic acid)^2,6]1 or more of decyl ester/(meth) acrylic acid 2-ethylhexyl ester copolymer.

The weight average molecular weight (Mw) of the resin (B) in terms of polystyrene is preferably 3,000 to 100,000, more preferably 5,000 to 50,000, and still more preferably 5,000 to 30,000. The dispersity [ weight average molecular weight (Mw)/number average molecular weight (Mn) ] of the resin (B) is preferably 1.1 to 6, more preferably 1.2 to 4.

The acid value (in terms of solid content) of the resin (B) is preferably 10 to 300mg-KOH/g, more preferably 20 to 250mg-KOH/g, and still more preferably 30 to 200 mg-KOH/g. Here, the acid value is a value measured as the amount (mg) of potassium hydroxide required for neutralizing 1g of the resin (B), and can be determined, for example, by titration using an aqueous potassium hydroxide solution.

The content of the resin (B) in the coloring composition is preferably 3 to 99% by mass, more preferably 5 to 99% by mass, and still more preferably 7 to 95% by mass, based on the total amount of the solid components.

The coloring composition of the present invention preferably contains a solvent (hereinafter, sometimes referred to as "solvent (E)"). By including the solvent (E) in the coloring composition, the dispersion stability may be further improved.

< solvent (E) >

Examples of the solvent (E) include an ester solvent (a solvent containing-COO-and not containing-O-in the molecule), an ether solvent (a solvent containing-O-and not containing-COO-in the molecule), an ether ester solvent (a solvent containing-COO-and not containing-O-in the molecule), a ketone solvent (a solvent containing-CO-and not containing-COO-in the molecule), an alcohol solvent (a solvent containing OH and not containing-O-, -CO-, and-COO-in the molecule), an aromatic hydrocarbon solvent, an amide solvent, and dimethyl sulfoxide.

Examples of the ester solvent include methyl lactate, ethyl lactate, butyl lactate, methyl 2-hydroxyisobutyrate, ethyl acetate, n-butyl acetate, isobutyl acetate, amyl formate, isoamyl acetate, butyl propionate, isopropyl butyrate, ethyl butyrate, butyl butyrate, methyl pyruvate, ethyl pyruvate, propyl pyruvate, methyl acetoacetate, ethyl acetoacetate, cyclohexanol acetate, and γ -butyrolactone.

Examples of the ether solvent include ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monopropyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monopropyl ether, propylene glycol monobutyl ether, 3-methoxy-1-butanol, 3-methoxy-3-methylbutanol, tetrahydrofuran, tetrahydropyran, 1, 4-dioxane, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol methyl ethyl ether, diethylene glycol dipropyl ether, diethylene glycol dibutyl ether, anisole, phenetole, and methyl anisole.

Examples of the ether ester solvent include methyl methoxyacetate, ethyl methoxyacetate, butyl methoxyacetate, methyl ethoxyacetate, ethyl ethoxyacetate, methyl 3-methoxypropionate, ethyl 3-methoxypropionate, methyl 3-ethoxypropionate, ethyl 3-ethoxypropionate, methyl 2-methoxypropionate, ethyl 2-methoxypropionate, propyl 2-methoxypropionate, methyl 2-ethoxypropionate, ethyl 2-ethoxypropionate, methyl 2-methoxy-2-methylpropionate, ethyl 2-ethoxy-2-methylpropionate, 3-methoxybutyl acetate, 3-methyl-3-methoxybutyl acetate, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, propylene glycol monopropyl ether acetate, and mixtures thereof, Ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether acetate, dipropylene glycol methyl ether acetate, and the like.

Examples of the ketone solvent include 4-hydroxy-4-methyl-2-pentanone, acetone, 2-butanone, 2-heptanone, 3-heptanone, 4-methyl-2-pentanone, cyclopentanone, cyclohexanone, and isophorone.

Examples of the alcohol solvent include methanol, ethanol, propanol, butanol, hexanol, cyclohexanol, ethylene glycol, propylene glycol, glycerin, and the like.

Examples of the aromatic hydrocarbon solvent include benzene, toluene, xylene, mesitylene, and the like.

Examples of the amide solvent include N, N-dimethylformamide, N-dimethylacetamide, and N-methylpyrrolidone.

These solvents may be used in combination of 2 or more.

The content of the solvent (E) is preferably 40 to 99% by mass, and more preferably 50 to 95% by mass, based on the total amount of the coloring composition.

In the coloring composition of the present invention, the compound Z is preferably dispersed in the solvent (E).

For the compound Z, the following treatments may be carried out, as required: rosin treatment; surface treatment using a derivative or the like into which an acidic group or a basic group is introduced; grafting treatment of the surface of the compound Z with a polymer compound or the like; micronization treatment by sulfuric acid micronization method; washing treatment with an organic solvent, water or the like for removing impurities; and a treatment of removing ionic impurities by an ion exchange method or the like. Preferably, the particle size of the compound Z is substantially uniform. The compound Z can be dispersed uniformly in the dispersion liquid by adding a dispersant and performing a dispersion treatment.

The dispersant may be any of cationic, anionic, nonionic and amphoteric surfactants. Specifically, there may be mentioned polyester, polyamine, acrylic and other surfactants. These dispersants may be used alone or in combination of two or more. Examples of the dispersant include KP (manufactured by shin-Etsu chemical industries, Ltd.), FLOWLEN (manufactured by Kyoho chemical Co., Ltd.), SOLSPERSE (registered trademark) (manufactured by Zeneca), EFKA (registered trademark) (manufactured by BASF (manufactured by Kyoho Co., Ltd.), AJISPER (registered trademark) (manufactured by Ajinomoto Fine-Technio Co., Ltd.), Disperbyk (registered trademark) (manufactured by BYK-Chemie Co., Ltd.), BYK (registered trademark) (manufactured by BYK-Chemie (manufactured by Co., Ltd.), and the like.

When a dispersant is used, the amount of the dispersant (solid component) used is preferably 300 parts by mass or less, and more preferably 5 parts by mass or more and 100 parts by mass or less, relative to 100 parts by mass of the compound Z. When the amount of the dispersant used is within the above range, a colored composition having a more uniform dispersion state tends to be obtained.

The content of the compound Z in the coloring composition is usually 0.1 to 60% by mass, preferably 0.5 to 50% by mass, and more preferably 1 to 40% by mass, based on the total amount of the coloring composition.

The content of the compound Z in the coloring composition is usually 1 mass% to 90 mass%, preferably 1 mass% to 80 mass%, and more preferably 2 mass% to 75 mass% with respect to the total amount of the solid content.

When the coloring composition of the present invention contains the compound Z, the coloring composition may further contain a colorant other than the compound Z (that is, the above-mentioned colorant A1Z1, colorant A1Z2, colorant A1Z3, colorant A1Z4, colorant A1Z5, colorant A1Z6, and the like). Hereinafter, the colorant A1Z1, the colorant A1Z2, the colorant A1Z3, the colorant A1Z4, the colorant A1Z5, and the colorant A1Z6 may be collectively referred to as "colorant ZZ". The coloring agent ZZ may contain 1 or 2 or more coloring agents. The colorant ZZ preferably comprises a yellow colorant or a green colorant.

< colorant ZZ >

The coloring agent ZZ may be a dye or a pigment. As The dye, known dyes can be used, and there can be mentioned dyes described in The index of dyes (published by The Society of Dyers and Colourists) and Dyeing notes (color Dyeing company). Further, depending on the chemical structure, azo dyes, anthraquinone dyes, triphenylmethane dyes, xanthene dyes, phthalocyanine dyes, and the like can be given. These dyes may be used alone, or 2 or more of them may be used in combination.

Specifically, the following dyes are given by the color index (c.i.) number. C.i. solvent yellow 14, 15, 23, 24, 25, 38, 62, 63, 68, 79, 81, 82, 83, 89, 94, 98, 99, 162;

c.i. acid yellow 1, 3, 7, 9, 11, 17, 23, 25, 29, 34, 36, 38, 40, 42, 54, 65, 72, 73, 76, 79, 98, 99, 111, 112, 113, 114, 116, 119, 123, 128, 134, 135, 138, 139, 140, 144, 150, 155, 157, 160, 161, 163, 168, 169, 172, 177, 178, 179, 184, 190, 193, 196, 197, 199, 202, 203, 204, 205, 207, 212, 214, 220, 221, 228, 230, 232, 235, 238, 240, 242, 243, 251;

c.i. reactive yellow 2, 76, 116;

C.i. direct yellow 2, 4, 28, 33, 34, 35, 38, 39, 43, 44, 47, 50, 54, 58, 68, 69, 70, 71, 86, 93, 94, 95, 98, 102, 108, 109, 129, 132, 136, 138, 141;

c.i. disperse yellow 51, 54, 76;

c.i. solvent orange 2, 7, 11, 15, 26, 41, 54, 56, 99;

c.i. acid orange 6, 7, 8, 10, 12, 26, 50, 51, 52, 56, 62, 63, 64, 74, 75, 94, 95, 107, 108, 149, 162, 169, 173;

c.i. reactive orange 16;

c.i. direct orange 26, 34, 39, 41, 46, 50, 52, 56, 57, 61, 64, 65, 68, 70, 96, 97, 106, 107;

c.i. solvent red 24, 49, 90, 91, 111, 118, 119, 122, 124, 125, 127, 130, 132, 143, 145, 146, 150, 151, 155, 160, 168, 169, 172, 175, 181, 207, 218, 222, 227, 230, 245, 247;

c.i. acid red 52, 73, 80, 91, 92, 97, 138, 151, 211, 274, 289;

c.i. acid violet 34, 102;

c.i. disperse violet 26, 27;

c.i. solvent violet 11, 13, 14, 26, 31, 36, 37, 38, 45, 47, 48, 51, 59, 60;

c.i. solvent blue 14, 18, 35, 36, 45, 58, 59:1, 63, 68, 69, 78, 79, 83, 94, 97, 98, 100, 101, 102, 104, 105, 111, 112, 122, 128, 132, 136, 139;

C.i. acid blue 25, 27, 40, 45, 78, 80, 112;

c.i. direct blue 40;

c.i. disperse blue 1, 14, 56, 60;

c.i. solvent green 1, 3, 5, 28, 29, 32, 33;

c.i. acid green 3, 5, 9, 25, 27, 28, 41;

c.i. alkaline green 1;

c.i. vat green 1, etc.

As The Pigment, known pigments can be used, and for example, pigments classified as "pigments (pigments)" in The color index (published by The Society of Dyers and Colourists) can be cited. These may be used alone, or 2 or more of them may be used in combination.

Specifically, there may be mentioned:

c.i. pigment yellow 1, 3, 12, 13, 14, 15, 16, 17, 20, 24, 31, 53, 83, 86, 93, 94, 109, 110, 117, 125, 128, 129, 137, 138, 139, 147, 148, 150, 153, 154, 166, 173, 185, 194, 214 and the like;

orange pigments such as c.i. pigment orange 13, 31, 36, 38, 40, 42, 43, 51, 55, 59, 61, 64, 65, 71, 73;

red pigments such as c.i. pigment red 9, 97, 105, 122, 123, 144, 149, 166, 168, 176, 177, 179, 180, 192, 209, 215, 216, 224, 242, 254, 255, 264, 265, 266, 268, 269, 273 and the like;

c.i. pigment blue 15, 15:3, 15:4, 15:6, 60, etc.;

C.i. pigment violet 1, 19, 23, 29, 32, 36, 38 and the like violet pigment;

c.i. pigment green 7, 36, 58, 59 and the like.

The colorant ZZ is preferably a yellow dye and a yellow pigment (hereinafter, these may be collectively referred to as "yellow colorant"), a green dye and a green pigment (hereinafter, these may be collectively referred to as "green colorant"), more preferably a yellow pigment and a green pigment, and still more preferably a green pigment.

Examples of the yellow dye include dyes of which hue is classified as yellow among the dyes, and examples of the yellow pigment include pigments of which hue is classified as yellow among the pigments.

Among the yellow pigments, quinophthalone yellow pigment, metal-containing yellow pigment, and isoindoline yellow pigment are preferable, c.i. pigment yellow 129, 138, 139, 150, and 185 are more preferable, and c.i. pigment yellow 138, 139, 150, and 185 are further preferable.

Examples of the green dye include dyes of which hue is classified as green among the dyes, and examples of the green pigment include pigments of which hue is classified as green among the pigments.

Among the green pigments, phthalocyanine pigments are preferable, at least one selected from the group consisting of halogenated copper phthalocyanine pigments and halogenated zinc phthalocyanine pigments is more preferable, and at least one selected from the group consisting of c.i. pigment green 7, 36, 58 and 59 is further preferable.

In the case where the coloring composition of the present invention contains the colorant ZZ and the solvent (E), a liquid containing the colorant ZZ, which contains the colorant ZZ and the solvent (E), may be prepared in advance, and then the coloring composition may be prepared using the liquid containing the colorant ZZ. In the case where the colorant ZZ is insoluble in the solvent (E), a liquid containing the colorant ZZ may be prepared by dispersing the colorant ZZ in the solvent (E) and mixing them. The liquid containing the colorant ZZ may contain a part or all of the solvent (E) contained in the coloring composition.

Preferably, the coloring composition of the present invention can be produced by mixing the compound Z, the resin (B), and a liquid containing the colorant ZZ and the solvent (E), or by mixing the compound Z, the solvent (E), and a liquid containing the colorant ZZ and the solvent (E), or by mixing the compound Z, the resin (B), the solvent (E), and a liquid containing the colorant ZZ and the solvent (E).

As the above-mentioned production method, the following methods are preferred: a method in which a coloring composition is prepared by mixing the compound Z and the resin (B) using a bead mill or the like, and the obtained coloring composition is mixed with a liquid containing the coloring agent ZZ and containing the solvent (E); alternatively, a method in which the compound Z and the solvent (E) are mixed by a bead mill or the like to prepare a coloring composition, and the obtained coloring composition is mixed with a liquid containing the coloring agent ZZ and containing the solvent (E); alternatively, a method in which the compound Z, the resin (B) and the solvent (E) are mixed by a bead mill or the like to prepare a coloring composition, and the obtained coloring composition is mixed with a liquid containing the colorant ZZ and the solvent (E).

The colorant ZZ preferably contains 1 or more colorants selected from a green colorant and a yellow colorant.

For the coloring agent ZZ, the following treatments may be carried out, as necessary: rosin treatment; surface treatment using a colorant derivative or the like into which an acidic group or a basic group has been introduced; grafting treatment of the surface of the coloring agent ZZ with a high molecular compound or the like; micronization treatment by sulfuric acid micronization method; washing treatment with an organic solvent, water or the like for removing impurities; and a treatment of removing ionic impurities by an ion exchange method or the like. Preferably, the particle size of the colouring agent ZZ is substantially uniform. In the case of the colorant ZZ, the colorant ZZ is dispersed in a liquid containing the colorant ZZ uniformly by the dispersion treatment with the dispersant. The colorant ZZ may be dispersed separately or in a mixture of two or more.

The dispersant may be any of cationic, anionic, nonionic and amphoteric surfactants. Specifically, there may be mentioned polyester, polyamine, acrylic and other surfactants. These dispersants may be used alone or in combination of two or more. Examples of the dispersant include KP (manufactured by shin-Etsu chemical industries, Ltd.), FLOWLEN (manufactured by Kyoho chemical Co., Ltd.), SOLSPERSE (registered trademark) (manufactured by Zeneca), EFKA (registered trademark) (manufactured by BASF (manufactured by Kyoho Co., Ltd.), AJISPER (registered trademark) (manufactured by Ajinomoto Fine-Technio Co., Ltd.), Disperbyk (registered trademark) (manufactured by BYK-Chemie Co., Ltd.), BYK (registered trademark) (manufactured by BYK-Chemie (manufactured by Co., Ltd.), and the like.

When a dispersant is used for the preparation of the liquid containing the colorant ZZ, the amount of the dispersant (solid component) used is preferably 300 parts by mass or less, more preferably 5 parts by mass or more and 100 parts by mass or less, based on 100 parts by mass of the colorant ZZ. When the amount of the dispersant used is within the above range, a liquid containing the colorant ZZ in a more uniform dispersion state tends to be obtained.

The content of the coloring agent ZZ in the liquid containing the coloring agent ZZ is usually 0.1 to 60% by mass, preferably 0.5 to 50% by mass, and more preferably 1 to 40% by mass, of the total amount of the liquid containing the coloring agent ZZ.

The content of the colorant ZZ in the liquid containing the colorant ZZ is usually 1% by mass or more and 90% by mass or less, preferably 1% by mass or more and 80% by mass or less, and more preferably 2% by mass or more and 75% by mass or less, based on the total amount of the solid components.

The coloring composition of the invention comprises a resin (B), and in the case where a liquid containing a colorant ZZ, which comprises the colorant ZZ and a solvent, is prepared in advance, and then the coloring composition of the invention is prepared using the liquid containing the colorant ZZ, the liquid containing the colorant ZZ may comprise in advance a part or all, preferably a part, of the resin (B) contained in the coloring composition.

By containing the resin (B) in advance, the dispersion stability of the liquid containing the colorant ZZ can be further improved.

The content of the resin (B) in the liquid containing the colorant ZZ is, for example, 1 to 500 parts by mass, preferably 5 to 200 parts by mass, and more preferably 10 to 100 parts by mass with respect to 100 parts by mass of the colorant ZZ.

The content of the colorant ZZZ in the coloring composition, which is a mixture of the compound Z and the colorant ZZ, is usually 1 mass% or more and 90 mass% or less, preferably 1 mass% or more and 80 mass% or less, and more preferably 2 mass% or more and 75 mass% or less, based on the total amount of the solid components.

The content of the compound Z is usually 0.001 mass% or more, preferably 0.003 mass% or more, and more preferably 0.005 mass% or more, and the upper limit is 100 mass% or less, preferably 99.999 mass% or less, and more preferably 99.997 mass% or less, in the total amount of the colorant ZZZ.

The content of the compound Z is usually 0.001 mass% or more, preferably 40 mass% or more, more preferably 50 mass% or more, still more preferably 60 mass% or more, and particularly preferably 70 mass% or more, in the total amount of the yellow coloring agent, and the upper limit is 100 mass% or less, preferably 99.999 mass% or less, and more preferably 99.997 mass% or less.

In the case where the colorant ZZ is contained, the content of the colorant ZZ is preferably 0.1 part by mass or more, more preferably 0.5 part by mass or more, further preferably 1 part by mass or more, preferably 10000 parts by mass or less, and more preferably 5000 parts by mass or less with respect to 100 parts by mass of the compound Z.

The colored curable composition of the present invention comprises: a compound Z; at least one of a resin (B) and a solvent (E); and a polymerizable compound (C).

< polymerizable Compound (C) >)

The polymerizable compound (C) is a compound polymerizable by an active radical and/or an acid generated by the polymerization initiator (D), and is, for example, a compound having a polymerizable ethylenically unsaturated bond, and is preferably a (meth) acrylate compound.

Examples of the polymerizable compound having 1 ethylenically unsaturated bond include nonylphenyl carbitol acrylate, 2-hydroxy-3-phenoxypropyl acrylate, 2-ethylhexyl carbitol acrylate, 2-hydroxyethyl acrylate, and N-vinylpyrrolidone, and the above-mentioned monomer (a), monomer (b), and monomer (c).

Examples of the polymerizable compound having 2 ethylenically unsaturated bonds include 1, 6-hexanediol di (meth) acrylate, ethylene glycol di (meth) acrylate, neopentyl glycol di (meth) acrylate, triethylene glycol di (meth) acrylate, bis (acryloyloxyethyl) ether of bisphenol a, and 3-methylpentanediol di (meth) acrylate.

Among them, the polymerizable compound (C) is preferably a polymerizable compound having 3 or more ethylenically unsaturated bonds. Examples of such polymerizable compounds include trimethylolpropane tri (meth) acrylate, pentaerythritol tetra (meth) acrylate, dipentaerythritol penta (meth) acrylate, dipentaerythritol hexa (meth) acrylate, tripentaerythritol octa (meth) acrylate, tripentaerythritol hepta (meth) acrylate, tetrapentaerythritol deca (meth) acrylate, tetrapentaerythritol nona (meth) acrylate, tris (2- (meth) acryloyloxyethyl) isocyanurate, ethylene glycol-modified pentaerythritol tetra (meth) acrylate, ethylene glycol-modified dipentaerythritol hexa (meth) acrylate, propylene glycol-modified pentaerythritol tetra (meth) acrylate, propylene glycol-modified dipentaerythritol hexa (meth) acrylate, caprolactone-modified pentaerythritol tetra (meth) acrylate, and caprolactone-modified dipentaerythritol hexa (meth) The acrylic acid ester and the like are preferably dipentaerythritol penta (meth) acrylate and dipentaerythritol hexa (meth) acrylate.

The weight average molecular weight of the polymerizable compound (C) is preferably 150 to 2,900, more preferably 250 to 1,500.

The content of the polymerizable compound (C) in the colored curable composition is preferably 1 to 65% by mass, more preferably 3 to 60% by mass, and still more preferably 5 to 55% by mass, based on the total amount of the solid components.

The colored curable composition of the invention may contain a polymerization initiator (D).

< polymerization initiator (D) >)

The polymerization initiator (D) is not particularly limited as long as it is a compound that can initiate polymerization by generating an active radical, an acid, or the like by the action of light or heat, and a known polymerization initiator can be used.

Examples of the polymerization initiator (D) include an O-acyloxime compound, an alkylphenone compound, a biimidazole compound, a triazine compound, and an acylphosphine oxide compound.

Examples of the O-acyloxime compound include N-benzoyloxy-1- (4-phenylsulfanyl) phenyl) butan-1-one-2-imine, N-benzoyloxy-1- (4-phenylsulfanyl) phenyl) octan-1-one-2-imine, N-benzoyloxy-1- (4-phenylsulfanyl phenyl) -3-cyclopentylpropane-1-one-2-imine, N-acetyloxy-1- (4-phenylsulfanyl phenyl) -3-cyclohexylpropane-1-one-2-imine -imine, N-acetyloxy-1- [ 9-ethyl-6- (2-methylbenzoyl) -9H-carbazol-3-yl ] ethane-1-imine, N-acetyloxy-1- [ 9-ethyl-6- { 2-methyl-4- (3, 3-dimethyl-2, 4-dioxopentylmethyloxy) benzoyl } -9H-carbazol-3-yl ] ethane-1-imine, N-acetyloxy-1- [ 9-ethyl-6- (2-methylbenzoyl) -9H-carbazol-3-yl ] -3-cyclopentylpropane-1-imine and N-benzoyloxy-1- [ 9-Ethyl-6- (2-methylbenzoyl) -9H-carbazol-3-yl ] -3-cyclopentylpropane-1-one-2-imine, and the like. Further, as the O-acyloxime compound, commercially available products such as IRGACURE OXE01, OXE02 (manufactured by BASF corporation), N-1919 (manufactured by ADEKA corporation), and the like can be used. Among them, as the O-acyloxime compound, at least 1 selected from the group consisting of N-benzoyloxy-1- (4-phenylthiophenyl) butan-1-one-2-imine, N-benzoyloxy-1- (4-phenylthiophenyl) octan-1-one-2-imine, and N-benzoyloxy-1- (4-phenylthiophenyl) -3-cyclopentylpropane-1-one-2-imine is preferable, and N-benzoyloxy-1- (4-phenylthiophenyl) octan-1-one-2-imine is more preferable.

Examples of the alkylphenone compound include 2-methyl-2-morpholino (morpholino) -1- (4-methylthiophenyl) propan-1-one, 2-dimethylamino-1- (4-morpholinophenyl) -2-benzylbutan-1-one, and 2- (dimethylamino) -2- [ (4-methylphenyl) methyl ] -1- [4- (4-morpholino (morpholino)) phenyl ] butan-1-one. As the alkylphenone compound, commercially available products such as IRGACURE 369, 907 and 379 (manufactured by BASF corporation) can be used.

Examples of the alkylphenone compound include 2-hydroxy-2-methyl-1-phenylpropan-1-one, 2-hydroxy-2-methyl-1- [4- (2-hydroxyethoxy) phenyl ] propan-1-one, 1-hydroxycyclohexylphenyl ketone, oligomers of 2-hydroxy-2-methyl-1- (4-isopropenylphenyl) propan-1-one, α -diethoxyacetophenone and benzildimethylketal.

Examples of the biimidazole compound include 2,2 ' -bis (2-chlorophenyl) -4,4 ', 5,5 ' -tetraphenylbiimidazole, 2 ' -bis (2, 3-dichlorophenyl) -4,4 ', 5,5 ' -tetraphenylbiimidazole (see, for example, japanese patent application laid-open No. 6-75372, japanese patent application laid-open No. 6-75373, etc.), 2 ' -bis (2-chlorophenyl) -4,4 ', 5,5 ' -tetrakis (alkoxyphenyl) biimidazole, 2 ' -bis (2-chlorophenyl) -4,4 ', 5,5 ' -tetrakis (dialkoxyphenyl) biimidazole, 2 ' -bis (2-chlorophenyl) -4,4 ', 5,5 ' -tetrakis (trialkoxyphenyl) biimidazole (for example, see, for example, Japanese patent application laid-open No. 48-38403 and Japanese patent application laid-open No. 62-174204) and imidazole compounds in which the phenyl group at the 4,4 ', 5, 5' -position is substituted with an alkoxycarbonyl group (e.g., Japanese patent application laid-open No. 7-10913).

Examples of the triazine compound include 2, 4-bis (trichloromethyl) -6- (4-methoxyphenyl) -1,3, 5-triazine, 2, 4-bis (trichloromethyl) -6- (4-methoxynaphthyl) -1,3, 5-triazine, 2, 4-bis (trichloromethyl) -6-piperonyl-1, 3, 5-triazine, 2, 4-bis (trichloromethyl) -6- (4-methoxystyryl) -1,3, 5-triazine, 2, 4-bis (trichloromethyl) -6- [ 2- (5-methylfuran-2-yl) vinyl ] -1,3, 5-triazine, 2, 4-bis (trichloromethyl) -6- [ 2- (furan-2-yl) vinyl ] -one 1,3, 5-triazine, 2, 4-bis (trichloromethyl) -6- [ 2- (4-diethylamino-2-methylphenyl) vinyl ] -1,3, 5-triazine, and 2, 4-bis (trichloromethyl) -6- [ 2- (3, 4-dimethoxyphenyl) vinyl ] -1,3, 5-triazine.

Examples of the acylphosphine oxide compound include 2,4, 6-trimethylbenzoyldiphenylphosphine oxide and the like.

Examples of the polymerization initiator (D) include benzoin compounds such as benzoin, benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether, and benzoin isobutyl ether; benzophenone compounds such as benzophenone, methyl o-benzoylbenzoate, 4-phenylbenzophenone, 4-benzoyl-4 ' -methyldiphenyl sulfide, 3 ', 4,4 ' -tetrakis (t-butylperoxycarbonyl) benzophenone, and 2,4, 6-trimethylbenzophenone; quinone compounds such as 9, 10-phenanthrenequinone, 2-ethylanthraquinone and camphorquinone; 10-butyl-2-chloroacridone, benzil, methyl benzoylformate, titanocene compound, and the like.

These are preferably used in combination with the polymerization initiation assistant (D1) (particularly amines) described later.

The polymerization initiator (D) is preferably a polymerization initiator containing at least one selected from the group consisting of an alkylphenone compound, a triazine compound, an acylphosphine oxide compound, an O-acyloxime compound, and a bisimidazole compound, and more preferably a polymerization initiator containing an O-acyloxime compound.

The content of the polymerization initiator (D) is preferably 0.001 to 40% by mass, and more preferably 0.01 to 30% by mass, based on the total amount of solid components in the colored curable composition.

The colored curable composition of the invention may contain a polymerization initiator aid (D1).

< polymerization initiation assistant (D1) >)

The polymerization initiation aid (D1) is a compound or a sensitizer used for promoting the polymerization of a polymerizable compound whose polymerization is initiated by a polymerization initiator. In the case of containing the polymerization initiation aid (D1), generally, it may be used in combination with the polymerization initiator (D).

Examples of the polymerization initiation aid (D1) include amine compounds, alkoxyanthracene compounds, thioxanthone compounds, and carboxylic acid compounds.

Examples of the amine compound include triethanolamine, methyldiethanolamine, triisopropanolamine, methyl 4-dimethylaminobenzoate, ethyl 4-dimethylaminobenzoate, isoamyl 4-dimethylaminobenzoate, 2-dimethylaminoethyl benzoate, 2-ethylhexyl 4-dimethylaminobenzoate, N-dimethyl-p-toluidine, 4 ' -bis (dimethylamino) benzophenone (known as Michler's ketone), 4 ' -bis (diethylamino) benzophenone, and 4,4 ' -bis (ethylmethylamino) benzophenone, and 4,4 ' -bis (diethylamino) benzophenone is preferable. As the amine compound, a commercially available compound such as EAB-F (manufactured by UK chemical Co., Ltd.) can be used.

Examples of the alkoxyanthracene compound include 9, 10-dimethoxyanthracene, 2-ethyl-9, 10-dimethoxyanthracene, 9, 10-diethoxyanthracene, 2-ethyl-9, 10-diethoxyanthracene, 9, 10-dibutoxyanthracene, and 2-ethyl-9, 10-dibutoxyanthracene.

Examples of the thioxanthone compound include 2-isopropylthioxanthone, 4-isopropylthioxanthone, 2, 4-diethylthioxanthone, 2, 4-dichlorothioxanthone, and 1-chloro-4-propoxythioxanthone.

Examples of the carboxylic acid compound include phenylthioacetic acid, methylphenylthioacetic acid, ethylphenylthioacetic acid, methylethylphenylthioacetic acid, dimethylphenylthioacetic acid, methoxyphenylthioacetic acid, dimethoxyphenylthioacetic acid, chlorophenylthioacetic acid, dichlorophenylthioacetic acid, N-phenylglycine, phenoxyacetic acid, naphthylthioacetic acid, N-naphthylglycine, naphthyloxyacetic acid and the like.

When these polymerization initiation aids (D1) are used, the content thereof is preferably 0.001 to 30% by mass, more preferably 0.01 to 20% by mass, based on the total amount of solid components in the colored curable composition.

The coloring composition of the present invention may further contain a leveling agent (F) and an antioxidant.

< leveling agent (F) >

Examples of the leveling agent (F) include a silicone surfactant, a fluorine surfactant, and a silicone surfactant having a fluorine atom. They may have a polymerizable group in a side chain.

Examples of the silicone surfactant include surfactants having a siloxane bond in the molecule. Specifically, Toray Silicone DC3PA, Toray Silicone SH7PA, Toray Silicone DC11PA, Toray Silicone SH21PA, Toray Silicone SH28PA, Toray Silicone SH29PA, Toray Silicone SH30PA, Toray Silicone SH8400 (trade name; manufactured by Dow Corning Co., Ltd.), KP321, KP322, KP323, KP324, KP326, KP340, KP341 (manufactured by shin-Etsu chemical Co., Ltd.), TSF400, TSF401, TSF410, F4300, TSF4440, TSF4445, TSF4446, TSF4452, and TSF4460 (manufactured by Moive Performance Materials Japan Co., Ltd.) can be mentioned.

Examples of the fluorine-based surfactant include surfactants having a fluorocarbon chain in the molecule. Specifically, examples thereof include Fluorad (registered trademark) FC430, Fluorad FC431 (manufactured by Sumitomo 3M Ltd.), MEGAFAC (registered trademark) F142D, MEGAFAC F171, MEGAFAC F172, MEGAFAC F173, MEGAFAC F177, MEGAFAC F183, MEGAFAC F554, MEGAFAC R30, MEGAFAC RS-718K (manufactured by DIC corporation), EFTOP (registered trademark) EF301, EFTOP EF303, EFTOP EF351, EFTOP EF352(Mitsubishi Materials Electronic Chemicals Co., manufactured by Ltd.), Surflon (registered trademark) S381, Surflon S382, Surflon SC101, Surflon SC105 (manufactured by Asnitro corporation) and E5844 (Danin fire K., manufactured by Kenkyu K).

Examples of the silicone surfactant having a fluorine atom include surfactants having a siloxane bond and a fluorocarbon chain in the molecule. Specifically, there may be mentioned MEGAFAC (registered trademark) R08, MEGAFAC BL20, MEGAFAC F475, MEGAFAC F477, and MEGAFAC F443 (available from DIC Co., Ltd.).

When the leveling agent (F) is contained, the content thereof is usually 0.0005 mass% or more and 1 mass% or less, preferably 0.001 mass% or more and 0.5 mass% or less, more preferably 0.001 mass% or more and 0.2 mass% or less, further preferably 0.002 mass% or more and 0.1 mass% or less, and particularly preferably 0.005 mass% or more and 0.1 mass% or less, based on the total amount of the coloring composition. When the content of the leveling agent (F) is within the above range, the flatness of the color filter can be improved.

< antioxidant >

The antioxidant may be used alone or in combination of 2 or more from the viewpoint of improving the heat resistance and light resistance of the colorant. The antioxidant is not particularly limited as long as it is an industrially commonly used antioxidant, and a phenol-based antioxidant, a phosphorus-based antioxidant, a sulfur-based antioxidant, and the like can be used.

Examples of the phenolic antioxidant include Irganox 1010(イルガノックス 1010: pentaerythritol tetrakis [3- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ], manufactured by BASF corporation), Irganox 1076(イルガノックス 1076: octadecyl-3- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate, manufactured by BASF corporation), Irganox 1330(イルガノックス 1330: 3,3 ', 5,5 ' -hexa-tert-butyl-a, a ' - (mesitylene-2, 4, 6-triyl) tri-p-cresol, manufactured by BASF corporation), Irganox 3114(イルガノックス 3114: 1,3, 5-tris (3, 5-di-tert-butyl-4-hydroxybenzyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione, manufactured by BASF corporation), Irganox 3790(イルガノックス 3790: 1,3, 5-tris ((4-tert-butyl-3-hydroxy-2, 6-xylyl) methyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione, manufactured by BASF (ltd.), Irganox 1035(イルガノックス 1035: thiodiethylene bis [3- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ], manufactured by BASF corporation), Irganox 1135(イルガノックス 1135: C7-C9 side chain alkyl ester of 3, 5-bis (1, 1-dimethylethyl) -4-hydroxypropionic acid, manufactured by BASF (ltd.), Irganox 1520L (イルガノックス 1520L: 4, 6-bis (octylthiomethyl) o-cresol, manufactured by BASF corporation), Irganox 3125(イルガノックス 3125, manufactured by BASF corporation), Irganox 565(イルガノックス 565: 2, 4-bis (n-octylthio) -6- (4-hydroxy-3 ', 5' -di-tert-butylanilino) -1,3, 5-triazine manufactured by BASF (ltd)), Adekastab AO-80(アデカスタブ AO-80: 3, 9-bis (2- (3- (3-tert-butyl-4-hydroxy-5-methylphenyl) propionyloxy) -1, 1-dimethylethyl) -2,4,8, 10-tetraoxaspiro (5,5) undecane (manufactured by ADEKA), Sumilizer BHT (スミライザー BHT, manufactured by Sumilizer chemical corporation), Sumilizer GA-80(スミライザー GA-80, manufactured by Sumilizer chemical corporation), Sumilizer GS (スミライザー GS, manufactured by Sumilizer chemical corporation), Cyanox 1790(シアノックス 1790 (manufactured by Cytec), vitamin E (Eisai co., ltd.).

Examples of the phosphorus-based antioxidant include Irgafos 168(イルガフォス 168: tris (2, 4-di-t-butylphenyl) phosphite, manufactured by BASF corporation), Irgafos 12(イルガフォス 12: tris [2- [ [2,4,8, 10-tetra-t-butyldibenzo [ d, f ] [1,3,2] dioxaphosphorin-6-yl ] oxy ] ethyl ] amine, manufactured by BASF corporation), Irgafos 38(イルガフォス 38: bis (2, 4-bis (1, 1-dimethylethyl) -6-methylphenyl) ethyl phosphite, manufactured by BASF corporation), Adekastab 329K (manufactured by ADEKA), Adekastab PEP36 (manufactured by ADEKA), Adekastab PEP-8 ((manufactured by SanEKA), dstab P-EPQ (manufactured by Clariant), Weston 618 (618, manufactured by Weston GE corporation), manufactured by ウェストン 618, manufactured by SAEK, Weston 619G (ウェストン 619G, GE Co., Ltd.), Ultranox 626(ウルトラノックス 626, GE Co., Ltd.), Sumilizer GP (スミライザー GP: 6- [3- (3-tert-butyl-4-hydroxy-5-methylphenyl) propoxy ] -2,4,8, 10-tetra-tert-butyldibenzo [ d, f ] [1.3.2] dioxaphosphepin (dioxiphospin)) (manufactured by Sumitomo chemical Co., Ltd.), and the like.

Examples of the sulfur-based antioxidant include dialkyl thiodipropionate compounds such as dilauryl thiodipropionate, dimyristyl thiodipropionate and distearyl thiodipropionate, and β -alkylmercaptopropionate compounds of polyhydric alcohols such as tetrakis [ methylene (3-dodecylthio) propionate ] methane.

< other ingredients >

The coloring composition of the present invention may contain additives known in the art, such as a filler, another polymer compound, an adhesion promoter, a light stabilizer, and a chain transfer agent, as required.

Examples of the adhesion promoter include vinyltrimethoxysilane, vinyltriethoxysilane, vinyltris (2-methoxyethoxy) silane, 3-glycidyloxypropyltrimethoxysilane, 3-glycidoxypropylmethyldimethoxysilane, 3-glycidoxypropylmethyldiethoxysilane, 2- (3, 4-epoxycyclohexyl) ethyltrimethoxysilane, 3-chloropropylmethyldimethoxysilane, 3-chloropropyltrimethoxysilane, 3-methacryloxypropyltrimethoxysilane, 3-mercaptopropyltrimethoxysilane, 3-isocyanatopropyltriethoxysilane, and the like, N-2- (aminoethyl) -3-aminopropylmethyldimethoxysilane, N-2- (aminoethyl) -3-aminopropylmethyldiethoxysilane, N-2- (aminoethyl) -3-aminopropyltrimethoxysilane, N-2- (aminoethyl) -3-aminopropylmethyldiethoxysilane, 3-aminopropyltrimethoxysilane, 3-aminopropyltriethoxysilane, N-phenyl-3-aminopropyltrimethoxysilane, N-phenyl-3-aminopropyltriethoxysilane, etc.

< color filter >

The color filter can be formed from the colored composition or the colored curable composition of the invention. As a method for forming a colored pattern, a photolithography method, an ink jet method, a printing method, and the like can be mentioned, and a photolithography method can be preferably mentioned. The photolithography method is as follows: the colored curable composition is applied to a substrate and dried to form a colored curable composition layer, and the colored curable composition layer is exposed to light through a photomask and developed. In the photolithography method, the colored curable composition preferably contains a polymerization initiator (D). A colored coating film which is a cured product of the colored curable composition layer can be formed by a photolithography method without using a photomask and/or without performing development during exposure. The colored pattern and the colored coating film formed as described above can be used as the color filter of the present invention.

The film thickness of the color filter to be produced is not particularly limited, and may be suitably adjusted according to the purpose, use, and the like, and is, for example, 0.1 to 30 μm, preferably 0.1 to 20 μm, and more preferably 0.5 to 6 μm.

As the substrate, a glass plate, a resin plate, silicon, a substrate obtained by forming a thin film of aluminum, silver/copper/palladium alloy, or the like on the above substrate, or the like can be used. Other color filter layers, resin layers, transistors, circuits, and the like may be formed on these substrates.

The formation of each color pixel by photolithography can be performed by using a known or commonly used apparatus and conditions. For example, the following method can be used.

First, a colored curable composition is applied onto a substrate, and dried by removing volatile components such as a solvent by heat drying (prebaking) and/or drying under reduced pressure, thereby obtaining a smooth colored curable composition layer.

Examples of the coating method include spin coating, slit and spin coating (slit and spin coating).

Next, the colored curable composition layer is exposed to light through a photomask for forming a target colored pattern. In order to uniformly irradiate the entire exposure surface with parallel light or to accurately align the photomask with the substrate on which the colored curable composition layer is formed, an exposure apparatus such as a mask aligner or a stepper is preferably used.

The exposed colored curable composition layer is brought into contact with a developer to develop the layer, whereby a colored pattern can be formed on the substrate. By the development, the unexposed portion of the colored curable composition layer is dissolved in a developing solution and removed.

As the developer, for example, an aqueous solution of an alkaline compound such as potassium hydroxide, sodium bicarbonate, sodium carbonate, or tetramethylammonium hydroxide is preferable.

The developing method may be any of spin immersion (dip method), immersion method, spray method, and the like. In addition, the substrate may be inclined at an arbitrary angle at the time of development.

The developed substrate is preferably washed with water.

Further, the obtained colored pattern is preferably subjected to post-baking.

The color filter is useful as a color filter used in a display device (a liquid crystal display device, an organic EL device, electronic paper, or the like) or a solid-state imaging device, particularly as a color filter used in a liquid crystal display device.

[ examples ]

Hereinafter, "part" means "part by mass" and "%" means "% by mass" unless otherwise specified.

In the following synthesis examples, the structure of the compound was confirmed by NMR (JMM-ECA-500; manufactured by Japan Electron Ltd.) or MASS spectrometry (LC; model 1200 manufactured by Agilent, MASS; model LC/MSD6130 manufactured by Agilent).

The weight average molecular weight (Mw) and the number average molecular weight (Mn) of the resin in terms of polystyrene were measured by GPC under the following conditions.

The device comprises the following steps: HLC-8120GPC (manufactured by Tosoh corporation)

Column: TSK-GELG2000HXL

Column temperature: 40 deg.C

Solvent: tetrahydrofuran (THF)

Flow rate: 1.0 mL/min

Solid content concentration of analysis sample: 0.001 to 0.01% by mass

Sample introduction amount: 50 μ L

A detector: RI (Ri)

Calibration standard substance: TSK STANDARD POLYSTYRENE F-40, F-4, F-288, A-2500, A-500 (manufactured by Tosoh corporation)

The ratio (Mw/Mn) of the weight average molecular weight (Mw) and the number average molecular weight (Mn) in terms of polystyrene obtained in the above manner was defined as the degree of dispersion.

Example Z1

Example 1Z1

36.2 parts of 4-nitrophthalonitrile (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 526 parts of methanol were mixed.

While keeping the temperature at 5 ℃, a mixture of 20.9 parts of 28% sodium methoxide methanol solution (manufactured by Wako pure chemical industries, Ltd.) and 10 parts of methanol was added dropwise to the obtained mixture over 1 hour.

The resulting mixture was stirred at 5 ℃ for 4 hours.

To the obtained mixture were added 13.1 parts of acetic acid and 23.7 parts of ethyl cyanoacetate (manufactured by Tokyo chemical industry Co., Ltd.) while keeping the temperature at 5 ℃ or lower.

The resulting mixture was stirred at 5 ℃ for 1 hour and then at room temperature for 3 days.

To the obtained mixture were added 2.37 parts of ethyl cyanoacetate (manufactured by tokyo chemical industries, ltd.) and 231 parts of methanol, and the mixture was stirred at room temperature for 1 day. To the obtained mixture were added 0.496 parts of ethyl cyanoacetate (manufactured by tokyo chemical industry co.) and 26 parts of methanol, and the mixture was stirred at 40 ℃ for 2 hours and 30 minutes.

To the obtained mixture were added 17.1 parts of acetic acid, 26.9 parts of barbituric acid and 793 parts of water, and the mixture was stirred at 40 ℃ for 2 hours.

To the resulting mixture were added 17.0 parts of acetic acid, 26.9 parts of barbituric acid, 12 parts of methanol, and 12 parts of water, and the mixture was stirred at 40 ℃ for 30 minutes and then at room temperature for 2 days.

The resulting mixture was filtered, and the residue was washed 1 time with 915 parts of 50% aqueous methanol solution, 1 time with 950 parts of 50% aqueous methanol solution, 1 time with 1600 parts of 50% aqueous methanol solution, and 1 time with 1800 parts of water.

The obtained residue was recrystallized from N, N-dimethylformamide to obtain 30.7 parts of a mixture of the compound represented by the formula (IZ1-38) and the compound represented by the formula (IZ 1-39).

Identification of Compound represented by the formula (IZ1-38)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺384

Exact molecular weight (Exact masses): 383

Identification of Compound represented by the formula (IZ1-39)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺398

Exact molecular weight (Exact masses): 397

Example 2Z1

A mixture of the compound represented by the formula (IZ1-20) and the compound represented by the formula (IZ1-21) was obtained in the same manner as in example 1Z1, except that 4-nitrophthalonitrile (manufactured by Tokyo chemical industry Co., Ltd.) was replaced with 4-tert-butylphthalonitrile (manufactured by Tokyo chemical industry Co., Ltd.).

Identification of Compound represented by the formula (IZ1-20)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺395

Exact molecular weight (Exact masses): 394

Identification of Compound represented by the formula (IZ1-21)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺409

Exact molecular weight (Exact masses): 408

Example 3Z1

A mixture of the compound represented by the formula (IZ1-2) and the compound represented by the formula (IZ1-3) was obtained in the same manner as in example 1Z1, except that 4-nitrophthalonitrile (manufactured by Tokyo chemical industry Co., Ltd.) was replaced with phthalonitrile (manufactured by Tokyo chemical industry Co., Ltd.).

Identification of Compound represented by the formula (IZ1-2)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺339

Exact molecular weight (Exact masses): 338

Identification of Compound represented by the formula (IZ1-3)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺353

Exact molecular weight (Exact masses): 352

Example 4Z1

A compound represented by the formula (IZ1-38) was obtained in the same manner as in example 1Z1, except that ethyl cyanoacetate (manufactured by tokyo chemical industry co.) was replaced with methyl cyanoacetate (manufactured by tokyo chemical industry co.).

Identification of Compound represented by the formula (IZ1-38)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H ]⁺384

Exact molecular weight (Exact masses): 383

Example 5Z1

The procedure of example 1Z1 was repeated except for replacing 4-nitrophthalonitrile (manufactured by tokyo chemical industry co., ltd.) with 4-tert-butylphthalonitrile (manufactured by tokyo chemical industry co., ltd.) and replacing ethyl cyanoacetate (manufactured by tokyo chemical industry co., ltd.) with methyl cyanoacetate (manufactured by tokyo chemical industry co., ltd.), thereby obtaining a compound represented by formula (IZ 1-20).

Identification of Compound represented by the formula (IZ1-20)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺395

Exact molecular weight (Exact masses): 394

Example 6Z1

The procedure of example 1Z1 was repeated except for replacing 4-nitrophthalonitrile (manufactured by tokyo chemical industry co.) with phthalonitrile (manufactured by tokyo chemical industry co.) and replacing ethyl cyanoacetate (manufactured by tokyo chemical industry co.) with methyl cyanoacetate (manufactured by tokyo chemical industry co.) to obtain a compound represented by formula (IZ 1-2).

Identification of Compound represented by the formula (IZ1-2)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺339

Exact molecular weight (Exact masses): 338

Example 7Z1XXX (tBu)

10.0 parts of 4-tert-butyl phthalonitrile (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 84 parts of methanol were mixed. While keeping the temperature at 5 ℃ or lower, a mixture of 8.15 parts of 28% sodium methoxide methanol solution (manufactured by Wako pure chemical industries, Ltd.) and 73 parts of methanol was added dropwise to the obtained mixture over 1 hour. The resulting mixture was stirred at 5-20 ℃ for 2 days.

To the obtained mixture, 5.42 parts of acetic acid and 6.14 parts of ethyl cyanoacetate (manufactured by Tokyo chemical industry Co., Ltd.) were added at 10 to 20 ℃. The resulting mixture was stirred at 65 ℃ for 3 days.

To the obtained mixture were added 2.69 parts of acetic acid and 3.07 parts of ethyl cyanoacetate (manufactured by Tokyo Kasei Kogyo Co., Ltd.), and the mixture was stirred at 65 ℃ for 3 days. In addition, up to this point in time, a total of 206 parts of methanol were added in addition to the above-mentioned methanol. To the obtained mixture were added 5.36 parts of acetic acid, 7.25 parts of barbituric acid (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 363 parts of water, and the mixture was stirred at 65 ℃ for 9 days.

The solvent of the resulting mixture was distilled off by a rotary evaporator, and then the resulting residue was purified by column chromatography to obtain a mixture of the compound represented by the formula (IZ1-20) and the compound represented by the formula (IZ 1-21).

Identification of Compound represented by the formula (IZ1-20)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺395

Exact molecular weight (Exact masses): 394

Identification of Compound represented by the formula (IZ1-21)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺409

Exact molecular weight (Exact masses): 408

Example 8Z1XXX (542)

2.57 parts of phthalonitrile (manufactured by Tokyo chemical Co., Ltd.) and 24.5 parts of methanol were mixed. To the resulting mixture, 2.00 parts of 28% sodium methoxide methanol solution (Wako pure chemical industries, Ltd.) was added at room temperature. The resulting mixture was stirred at 43 ℃ for 1 hour and 30 minutes.

To the resulting mixture, 2.53 parts of ethyl cyanoacetate (manufactured by Tokyo chemical industry Co., Ltd.), 1.26 parts of acetic acid and 54.5 parts of methanol were added, and the mixture was stirred at 40 ℃ for 1 hour and 30 minutes. To the obtained mixture, 2.84 parts of barbituric acid (manufactured by Tokyo chemical industry Co., Ltd.), 1.63 parts of acetic acid and 9 parts of methanol were added, and the mixture was stirred at 40 ℃ for 1 hour. The solvent of the resulting mixture was distilled off by a rotary evaporator, and then the resulting residue was purified by column chromatography to obtain a mixture of the compound represented by the formula (IZ1-2) and the compound represented by the formula (IZ 1-3).

Identification of Compound represented by the formula (IZ1-2)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺339

Exact molecular weight (Exact masses): 338

Identification of Compound represented by the formula (IZ1-3)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺353

Exact molecular weight (Exact masses): 352

Example 9Z1XXX (NO2)

10.0 parts of 4-nitrophthalonitrile (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 149 parts of methanol were mixed. While keeping the temperature at 2 to 6 ℃, 5.86 parts of 28% sodium methoxide methanol solution (manufactured by Wako pure chemical industries, Ltd.) was added dropwise to the obtained mixture over 20 minutes. The resulting mixture was stirred for 5 hours while being kept at 5 ℃ or lower. While the resulting mixture was kept at 5 ℃ or lower, 5.79 parts of acetic acid, 5.72 parts of methyl cyanoacetate (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 74 parts of methanol were added. The resulting mixture was stirred at 65 ℃ for 3 days. To the obtained mixture were added 2.88 parts of acetic acid and 2.86 parts of methyl cyanoacetate (manufactured by tokyo chemical industries, ltd.). The resulting mixture was stirred at 65 ℃ for 3 days. In addition, up to this point in time, a total of 140 parts of methanol was added in addition to the above-mentioned methanol. To the obtained mixture were added 24.0 parts of acetic acid, 15.3 parts of barbituric acid (manufactured by Tokyo chemical industry Co., Ltd.) and 363 parts of water, and the mixture was stirred at 65 ℃ for 9 days. The solvent of the resulting mixture was distilled off by a rotary evaporator, and then the resulting residue was purified by column chromatography to give a compound represented by the formula (IZ 1-38).

Identification of Compound represented by the formula (IZ1-38)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺384

Exact molecular weight (Exact masses): 383

Example 10Z1XXX (tBu)

10.0 parts of 4-tert-butyl phthalonitrile (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 84 parts of methanol were mixed. While keeping the temperature at 5 ℃ or lower, a mixture of 8.15 parts of 28% sodium methoxide methanol solution (manufactured by Wako pure chemical industries, Ltd.) and 73 parts of methanol was added dropwise to the obtained mixture over 1 hour. The resulting mixture was stirred at 5-20 ℃ for 2 days.

To the obtained mixture, 5.42 parts of acetic acid and 5.38 parts of methyl cyanoacetate (manufactured by Tokyo Kasei Kogyo Co., Ltd.) were added at 10 to 20 ℃. The resulting mixture was stirred at 65 ℃ for 3 days.

To the obtained mixture were added 2.69 parts of acetic acid and 2.69 parts of methyl cyanoacetate (manufactured by Tokyo Kasei Kogyo Co., Ltd.), and the mixture was stirred at 65 ℃ for 3 days. In addition, up to this point in time, a total of 206 parts of methanol were added in addition to the above-mentioned methanol. To the obtained mixture were added 5.36 parts of acetic acid, 7.25 parts of barbituric acid (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 363 parts of water, and the mixture was stirred at 65 ℃ for 9 days.

The solvent of the resulting mixture was distilled off by a rotary evaporator, and then the resulting residue was purified by column chromatography to give a compound represented by the formula (IZ 1-20).

Identification of Compound represented by the formula (IZ1-20)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺395

Exact molecular weight (Exact masses): 394

Example 11Z1XXX (645)

60.0 parts of phthalonitrile (manufactured by Tokyo chemical Co., Ltd.) and 501 parts of methanol were mixed. To the resulting mixture, 46.7 parts of 28% sodium methoxide methanol solution (manufactured by Wako pure chemical industries, Ltd.) was added dropwise over 15 minutes while keeping the temperature at 2 ℃. The resulting mixture was stirred for 5 hours while being maintained at 2 to 6 ℃. 556 parts of methanol was added to the mixture while keeping the temperature at 5 ℃ or lower. To the mixture were added 29.3 parts of acetic acid, 46.5 parts of methyl cyanoacetate, and 22 parts of methanol. The mixture was stirred at room temperature for 12 hours and then at 40 ℃ for 3 hours and 20 minutes. This mixture was mixed with 3.00 parts of acetic acid and 4.71 parts of methyl cyanoacetate, and stirred at 40 ℃ for 1 hour and 25 minutes. This mixture was mixed with 2.98 parts of acetic acid and 4.71 parts of methyl cyanoacetate, and stirred at 40 ℃ for 2 hours. This mixture was mixed with 2.96 parts of acetic acid and 4.70 parts of methyl cyanoacetate, and stirred at 40 ℃ for 2 hours. This mixture was mixed with 1.50 parts of acetic acid and 2.40 parts of methyl cyanoacetate.

In addition, a total of 111 parts of methanol was added up to this time point, in addition to the above-mentioned methanol. The resulting mixture was stirred at 40 ℃ for 1 hour and 40 minutes. To the resulting mixture, 38.1 parts of acetic acid and 60.6 parts of barbituric acid were added, and the mixture was stirred at 40 ℃ for 42 hours. In addition, up to this point in time, a total of 66 parts of methanol was added in addition to the above-mentioned methanol. The mixture was filtered and the residue was washed 6 times with 400 parts of methanol. The residue was purified by column chromatography to give a compound represented by the formula (IZ 1-2).

Identification of Compound represented by the formula (IZ1-2)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺339

Exact molecular weight (Exact masses): 338

Example 12Z1

5.0 parts of 4, 5-dichlorophthalonitrile and 62 parts of methanol were mixed. While the mixture was kept at 5 ℃ or lower, a 25% sodium methoxide methanol solution containing sodium methoxide in an amount of 0.5 times the molar amount of 5.0 parts by mole of 4, 5-dichlorophthalonitrile was added. The mixture was stirred at 5 ℃ or below for 5 hours. Methyl cyanoacetate 1.5 times the molar amount of 5.0 parts of 4, 5-dichlorophthalonitrile and 6.1 parts of acetic acid were added to the mixture while keeping the temperature at 5 ℃ or lower.

The mixture was stirred at 65 ℃ for 3 days. This mixture was mixed with 4.2 parts of acetic acid, 5.2 parts of barbituric acid, 500 parts of methanol and 562 parts of water, and stirred at 65 ℃ for 9 days. The solvent was distilled off from the mixture by a rotary evaporator, and the obtained residue was purified by column chromatography to obtain 0.297 parts of a compound represented by the formula (IZ 1-258).

Identification of Compound represented by the formula (IZ1-258)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺407

Exact molecular weight (Exact masses): 406

Example 13Z1XXX (659)

25.9 parts of phthalonitrile (manufactured by Tokyo chemical Co., Ltd.) and 513 parts of methanol were mixed. 30.3 parts of a 28% sodium methoxide methanol solution (Wako pure chemical industries, Ltd.) and 12 parts of methanol were added dropwise to the obtained mixture over 10 minutes while maintaining the temperature at 3 to 5 ℃. The resulting mixture was stirred for 6 hours while being maintained at 3 to 5 ℃. To the obtained mixture were added 19.8 parts of acetic acid, 28.5 parts of t-butyl cyanoacetate and 26 parts of methanol while maintaining the temperature at 3 to 5 ℃. The resulting mixture was stirred at room temperature for 2 days, and then at 40 ℃ for 3 hours. To the resulting mixture were added 5.09 parts of acetic acid and 7.17 parts of tert-butyl cyanoacetate, and the mixture was stirred at 40 ℃ for 4 hours. To the resulting mixture were added 4.95 parts of acetic acid, 7.15 parts of tert-butyl cyanoacetate and 38 parts of methanol, and the mixture was stirred at 40 ℃ for 16 hours. To the resulting mixture were added 19.9 parts of acetic acid, 25.8 parts of barbituric acid, 209 parts of methanol, and 800 parts of water, and the mixture was stirred at 40 ℃ for 3 hours.

The resulting mixture was filtered to give a residue. The residue was purified by column chromatography to give a compound represented by the formula (IZ 1-5).

Identification of Compound represented by the formula (IZ1-5)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺381

Exact molecular weight (Exact masses): 380

Example 14Z1XXX (661)

15.1 parts of 4-nitrophthalonitrile (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 284 parts of methanol were mixed. While keeping the temperature at 5 ℃ or lower, a mixture of 8.81 parts of 28% sodium methoxide methanol solution (manufactured by Wako pure chemical industries, Ltd.) and 18 parts of methanol was added dropwise to the obtained mixture over 10 minutes. The resulting mixture was stirred for 4 hours while being kept at 5 ℃ or lower.

To the obtained mixture, 5.55 parts of acetic acid was added while keeping the temperature at 5 ℃ or lower, and the mixture was stirred for 30 minutes. This mixture was mixed with 12.3 parts of t-butyl cyanoacetate, and stirred at 40 ℃ for 14 hours. This mixture was mixed with 0.654 parts of acetic acid and 1.24 parts of t-butyl cyanoacetate, and stirred at 40 ℃ for 4 hours. This mixture was mixed with 0.613 part of acetic acid and 1.23 parts of t-butyl cyanoacetate, and stirred at 40 ℃ for 3 hours. This mixture was mixed with 0.647 parts of acetic acid and 1.24 parts of t-butyl cyanoacetate. Further, up to this point, a total of 89 parts of methanol was added in addition to the above-mentioned methanol. The mixture was stirred at 40 ℃ for 17 hours. This mixture was mixed with 7.14 parts of acetic acid, 11.3 parts of barbituric acid and 508 parts of water. Up to this point, a total of 117 parts of methanol was added in addition to the above-mentioned methanol. The mixture was stirred at 40 ℃ for 24 hours. This mixture was mixed with 3.65 parts of acetic acid and 5.61 parts of barbituric acid, and stirred at 40 ℃ for 9 hours and at room temperature for 2 days. The mixture was filtered and the residue was washed 3 times with 1330 parts of 50% aqueous methanol solution. The obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ 1-41).

Identification of Compound represented by the formula (IZ1-41)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺426

Exact molecular weight (Exact masses): 425

Synthesis example 1

An appropriate amount of nitrogen was introduced into a flask equipped with a reflux condenser, a dropping funnel and a stirrer, and the atmosphere was replaced with nitrogen, 280 parts of propylene glycol monomethyl ether acetate was charged, and the mixture was heated to 80 ℃ with stirring. Then, 38 parts of acrylic acid and 3, 4-epoxytricyclo [5.2.1.0 ] acrylic acid were added dropwise over 5 hours^2,6]Decan-8-yl ester and acrylic acid 3, 4-epoxytricyclo [5.2.1.0^2,6]A mixed solution of 289 parts of a mixture of decane-9-yl esters and 125 parts of propylene glycol monomethyl ether acetate. On the other hand, a mixed solution obtained by dissolving 33 parts of 2, 2-azobis (2, 4-dimethylvaleronitrile) in 235 parts of propylene glycol monomethyl ether acetate was added dropwise over 6 hours. After completion of the dropwise addition, the mixture was kept at this temperature for 4 hours and then cooled to room temperature to obtain a copolymer (resin B1) solution having a solid content of 35.0%. The resulting resin B1 had a weight average molecular weight (Mw) of 8800, a dispersity of 2.1, and an acid value of the solution of 28 mg-KOH/g.

Synthesis example 2

An appropriate amount of nitrogen was introduced into a flask equipped with a reflux condenser, a dropping funnel and a stirrer, and the atmosphere was replaced with nitrogen, and 371 parts of propylene glycol monomethyl ether acetate was charged and heated to 85 ℃ with stirring. Then, 54 parts of acrylic acid and 3, 4-epoxytricyclo [5.2.1.0 ] acrylic acid were added dropwise over 4 hours ^2,6]Decan-8-yl ester and acrylic acid 3, 4-epoxytricyclo [5.2.1.0^2,6]A mixed solution of 225 parts of a mixture of decane-9-yl ester, 81 parts of vinyltoluene (isomer mixture) and 80 parts of propylene glycol monomethyl ether acetate. On the other hand, a solution obtained by dissolving 30 parts of 2, 2-azobis (2, 4-dimethylvaleronitrile), a polymerization initiator, in 160 parts of propylene glycol monomethyl ether acetate was added dropwise over 5 hours. After the end of the dropwise addition of the initiator solution, the temperature was maintained for 4 hours and then cooledThe temperature was then cooled to room temperature, whereby a copolymer (resin B3) solution containing 37.5% of solid matter was obtained. The resulting resin B3 had a weight-average molecular weight (Mw) of 10600, a dispersity of 2.01, and an acid value of 43 mg-KOH/g.

Synthesis example 3

An appropriate amount of nitrogen was introduced into a flask equipped with a reflux condenser, a dropping funnel and a stirrer, and the atmosphere was replaced with nitrogen, 350 parts of propylene glycol monomethyl ether acetate was charged, and the mixture was heated to 85 ℃ with stirring. Subsequently, 70 parts of acrylic acid and 3, 4-epoxytricyclo [5.2.1.0 ] acrylic acid were added dropwise over 4 hours^2,6]Decane-8-yl ester or/and acrylic acid 3, 4-epoxytricyclo [5.2.1.0^2,6]A mixed solution of 202 parts of a mixture of decane-9-yl ester, 78 parts of vinyltoluene (isomer mixture) and 100 parts of propylene glycol monomethyl ether acetate. On the other hand, a solution obtained by dissolving 33 parts of 2, 2-azobis (2, 4-dimethylvaleronitrile), a polymerization initiator, in 167 parts of propylene glycol monomethyl ether acetate was added dropwise over 5 hours. After the completion of the dropwise addition of the initiator solution, the mixture was held at this temperature for 4 hours and then cooled to room temperature to obtain a copolymer (resin B5) solution having a solid content of 38.1%. The obtained resin B5 had a weight-average molecular weight (Mw) of 10400, a dispersity of 2.03 and an acid value of 53 mg-KOH/g.

Example 101Z1

The following substances are mixed together and then,

pigment: 5860 portions of C.I. pigment green,

8.1 parts of acrylic pigment dispersing agent,

resin (B): 73 parts of resin B5 solution, and

solvent (E): 290 parts of propylene glycol monomethyl ether acetate

The pigment dispersion liquid (liquid containing colorant A1Z 1) was prepared by dispersing the pigment using a bead mill. In addition, the following substances were mixed,

colorant AZ 1: 50 parts of a mixture of the compound represented by the formula (IZ1-38) obtained in example 1Z1 and the compound represented by the formula (IZ1-39),

58 parts of a dispersant (BYK-LPN 6919; manufactured by BYK-Chemie Japan, Ltd.),

resin (B): 93 parts of resin B3 solution, and

solvent (E): propylene glycol monomethyl ether acetate 800 parts

A mixture of the compound represented by the formula (IZ1-38) obtained in example 1Z1 and the compound represented by the formula (IZ1-39) was dispersed using a bead mill, to thereby obtain a colored composition. Next, the following were mixed to obtain colored curable composition 1Z1,

the total amount of the obtained pigment dispersion (the liquid containing the colorant A1Z 1);

400 parts of the obtained coloring composition;

Resin (B): 45 parts of resin B1 solution;

polymerizable compound (C): 25 parts of dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kagaku Co., Ltd.);

polymerization initiator (D): 15 parts of N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure (registered trademark) OXE-01; manufactured by BASF corporation);

solvent (E): 86 parts of propylene glycol monomethyl ether acetate; and

leveling agent: 0.12 part of polyether-modified Silicone oil (Toray Silicone SH 8400; manufactured by Dow Corning Toray Co., Ltd.).

[ preparation of colored Pattern ]

A colored curable composition 1Z1 was applied to a 2-inch square glass substrate (EAGLE XG; manufactured by Corning corporation) by a spin coating method, and then prebaked at 100 ℃ for 3 minutes to form a colored curable composition layer. After cooling, the substrate on which the colored curable composition layer was formed and a photomask made of quartz glass were spaced at a distance of 200 μm, and exposed to an exposure apparatus (TME-150 RSK; manufactured by Topcon Corporation) at a rate of 80mJ/cm in an atmospheric atmosphere²Exposure was carried out with the exposure amount (based on 365 nm). As the photomask, a line and space pattern (li) having a thickness of 100 μm was used ne-and-space pattern). The colored curable composition layer after exposure was immersed in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ℃ for 70 seconds, developed, and washed with water. The colored curable composition layer was post-baked at 230 ℃ for 30 minutes, whereby a colored pattern was obtained.

[ measurement of phase difference value ]

A colored curable composition 1Z1 was applied to a 2-inch square glass substrate (EAGLE XG; manufactured by Corning corporation) by a spin coating method, and then prebaked at 100 ℃ for 3 minutes to form a colored curable composition layer. After cooling, an exposure machine (TME-150 RSK; manufactured by Topcon Corporation) was used for the colored curable composition layer under an atmospheric atmosphere at 80mJ/cm²Exposure was carried out with the exposure amount (based on 365 nm). The colored curable composition layer after exposure was immersed in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ℃ for 70 seconds, developed, and washed with water. The colored coating film was post-baked at 230 ℃ for 30 minutes, thereby obtaining a colored coating film.

The film thickness of the obtained colored coating film was measured using DEKTAK3 (manufactured by japan vacuum technology corporation). The phase difference value at an inclination angle (angle あおり Japanese) of the colored coating film of 45 ℃ was measured using an ellipsometer (model M-220 spectroscopic ellipsometer; manufactured by Nippon corporation). For the measurement of the retardation value, light having a wavelength of 550nm was used. The results are shown in Table 8Z 1.

Example 102Z1

A colored curable composition 2Z1 was obtained and a colored pattern was obtained in the same manner as in example 101Z1 except that the mixture of the compound represented by the formula (IZ1-38) and the compound represented by the formula (IZ1-39) obtained in example 1Z1 was replaced with the mixture of the compound represented by the formula (IZ1-20) and the compound represented by the formula (IZ1-21) obtained in example 2Z 1. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 1.

Example 103Z1

A colored curable composition 3Z1 was obtained and a colored pattern was obtained in the same manner as in example 101Z1 except that the mixture of the compound represented by the formula (IZ1-38) and the compound represented by the formula (IZ1-39) obtained in example 1Z1 was replaced with the mixture of the compound represented by the formula (IZ1-2) and the compound represented by the formula (IZ1-3) obtained in example 3Z 1. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 1.

Example 104Z1

A colored curable composition 4Z1 was obtained and a colored pattern was obtained in the same manner as in example 101Z1 except that the mixture of the compound represented by the formula (IZ1-38) and the compound represented by the formula (IZ1-39) obtained in example 1Z1 was replaced with the compound represented by the formula (IZ1-38) obtained in example 4Z 1. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 1.

Example 105Z1

A colored curable composition 5Z1 was obtained and a colored pattern was obtained in the same manner as in example 101Z1 except that the mixture of the compound represented by the formula (IZ1-38) and the compound represented by the formula (IZ1-39) obtained in example 1Z1 was replaced with the compound represented by the formula (IZ1-20) obtained in example 5Z 1. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 1.

Example 106Z1

A colored curable composition 6Z1 was obtained and a colored pattern was obtained in the same manner as in example 101Z1 except that the mixture of the compound represented by the formula (IZ1-38) and the compound represented by the formula (IZ1-39) obtained in example 1Z1 was replaced with the compound represented by the formula (IZ1-2) obtained in example 6Z 1. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 1.

Example 107Z1

A colored curable composition 7Z1 was obtained and a colored pattern was obtained in the same manner as in example 101Z1, except that c.i. pigment green 58 was replaced with c.i. pigment green 7. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 1.

Example 108Z1

A colored curable composition 8Z1 was obtained in the same manner as in example 101Z1 and a colored pattern was obtained in the same manner as in example 101Z1, except that the c.i. pigment green 58 was replaced with the c.i. pigment green 7, and the mixture of the compound represented by the formula (IZ1-38) and the compound represented by the formula (IZ1-39) obtained in example 1Z1 was replaced with the mixture of the compound represented by the formula (IZ1-20) and the compound represented by the formula (IZ1-21) obtained in example 2Z 1. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 1.

Example 109Z1

A colored curable composition 9Z1 was obtained in the same manner as in example 101Z1 and a colored pattern was obtained in the same manner as in example 101Z1 except that the c.i. pigment green 58 was replaced with the c.i. pigment green 7 and the mixture of the compound represented by the formula (IZ1-38) and the compound represented by the formula (IZ1-39) obtained in example 1Z1 was replaced with the mixture of the compound represented by the formula (IZ1-2) and the compound represented by the formula (IZ1-3) obtained in example 3Z 1. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 1.

Example 110Z1

A colored curable composition 10Z1 was obtained in the same manner as in example 101Z1 except that the c.i. pigment green 58 was replaced with the c.i. pigment green 7 and the mixture of the compound represented by the formula (IZ1-38) and the compound represented by the formula (IZ1-39) obtained in example 1Z1 was replaced with the compound represented by the formula (IZ1-38) obtained in example 4Z1, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 1.

Example 111Z1

A colored curable composition 11Z1 was obtained in the same manner as in example 101Z1 except that the c.i. pigment green 58 was replaced with the c.i. pigment green 7 and the mixture of the compound represented by the formula (IZ1-38) and the compound represented by the formula (IZ1-39) obtained in example 1Z1 was replaced with the compound represented by the formula (IZ1-20) obtained in example 5Z1, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 1.

Example 112Z1

A colored curable composition 12Z1 was obtained in the same manner as in example 101Z1 except that the c.i. pigment green 58 was replaced with the c.i. pigment green 7 and the mixture of the compound represented by the formula (IZ1-38) and the compound represented by the formula (IZ1-39) obtained in example 1Z1 was replaced with the compound represented by the formula (IZ1-2) obtained in example 6Z1, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 1.

Example 113Z1

A colored curable composition 13Z1 was obtained in the same manner as in example 101Z1 except that c.i. pigment green 58 was replaced with c.i. pigment green 59, and a colored pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 1.

Example 114Z1

A colored curable composition 14Z1 was obtained in the same manner as in example 101Z1 and a colored pattern was obtained in the same manner as in example 101Z1 except that the c.i. pigment green 58 was replaced with the c.i. pigment green 59 and the mixture of the compound represented by the formula (IZ1-38) and the compound represented by the formula (IZ1-39) obtained in example 1Z1 was replaced with the mixture of the compound represented by the formula (IZ1-20) and the compound represented by the formula (IZ1-21) obtained in example 2Z 1. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 1.

Example 115Z1

A colored curable composition 15Z1 was obtained in the same manner as in example 101Z1 and a colored pattern was obtained in the same manner as in example 101Z1, except that the c.i. pigment green 58 was replaced with the c.i. pigment green 59, and the mixture of the compound represented by the formula (IZ1-38) and the compound represented by the formula (IZ1-39) obtained in example 1Z1 was replaced with the mixture of the compound represented by the formula (IZ1-2) and the compound represented by the formula (IZ1-3) obtained in example 3Z 1. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 1.

Example 116Z1

A colored curable composition 16Z1 was obtained in the same manner as in example 101Z1 except that the c.i. pigment green 58 was replaced with the c.i. pigment green 59 and the mixture of the compound represented by the formula (IZ1-38) and the compound represented by the formula (IZ1-39) obtained in example 1Z1 was replaced with the compound represented by the formula (IZ1-38) obtained in example 4Z1, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 1.

Example 117Z1

A colored curable composition 17Z1 was obtained in the same manner as in example 101Z1 except that the c.i. pigment green 58 was replaced with the c.i. pigment green 59 and the mixture of the compound represented by the formula (IZ1-38) and the compound represented by the formula (IZ1-39) obtained in example 1Z1 was replaced with the compound represented by the formula (IZ1-20) obtained in example 5Z1, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 1.

Example 118Z1

A colored curable composition 18Z1 was obtained in the same manner as in example 101Z1 except that the c.i. pigment green 58 was replaced with the c.i. pigment green 59 and the mixture of the compound represented by the formula (IZ1-38) and the compound represented by the formula (IZ1-39) obtained in example 1Z1 was replaced with the compound represented by the formula (IZ1-2) obtained in example 6Z1, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 1.

Comparative example 1Z1

A colored curable composition C1Z1 was obtained in the same manner as in example 101Z1 except that the mixture of the compound represented by the formula (IZ1-38) and the compound represented by the formula (IZ1-39) obtained in example 1Z1 was replaced with c.i. pigment yellow 185, and a colored pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 1.

Comparative example 2Z1

A colored curable composition C2Z1 was obtained in the same manner as in example 101Z1 except that the mixture of the compound represented by the formula (IZ1-38) and the compound represented by the formula (IZ1-39) obtained in example 1Z1 was replaced with c.i. pigment green 7 and the mixture was replaced with c.i. pigment yellow 185, thereby obtaining a colored pattern, instead of c.i. pigment green 58. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 1.

Comparative example 3Z1

A colored curable composition C3Z1 was obtained in the same manner as in example 101Z1 except that the mixture of the compound represented by the formula (IZ1-38) and the compound represented by the formula (IZ1-39) obtained in example 1Z1 was replaced with c.i. pigment green 58 and the mixture was replaced with c.i. pigment yellow 185, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 1.

[ Table 8Z1]

TABLE 8Z1

	Film thickness (mum)	Phase difference value (nm)
			Example 101Z1	2.3	3
Example 102Z1	2.3	3
			Example 103Z1	2.3	4
Practice ofExample 104Z1	2.3	3
			Example 105Z1	2.3	3
Example 106Z1	2.3	4
			Example 107Z1	2.3	3
Example 108Z1	2.3	3
			Example 109Z1	2.3	4
Example 110Z1	2.3	3
			Example 111Z1	2.3	3
Example 112Z1	2.3	4
			Example 113Z1	2.3	3
Example 114Z1	2.3	3
			Example 115Z1	2.3	4
Example 116Z1	2.3	3
			Example 117Z1	2.3	3
Example 118Z1	2.3	4
			Comparative example 1Z1	2.3	15
Comparative example 2Z1	2.3	15
			Comparative example 3Z1	2.3	15

Example 119Z1

The following substances are mixed together and then,

pigment: 5860 portions of C.I. pigment green,

8.1 parts of acrylic pigment dispersing agent,

resin (B): 73 parts of resin B5 solution, and

solvent (E): 290 parts of propylene glycol monomethyl ether acetate

The pigment dispersion liquid (liquid containing colorant A1Z 1) was prepared by dispersing the pigment using a bead mill.

In addition, the following substances were mixed,

colorant AZ 1: 50 parts of a mixture of the compound represented by the formula (IZ1-38) obtained in example 1Z1 and the compound represented by the formula (IZ1-39),

58 parts of a dispersant solution (solid content: 60%),

resin (B): 93 parts of resin B3 solution, and

solvent (E): propylene glycol monomethyl ether acetate 800 parts

A mixture of the compound represented by the formula (IZ1-38) obtained in example 1Z1 and the compound represented by the formula (IZ1-39) was dispersed using a bead mill, to thereby obtain a colored composition.

Next, the following were mixed to obtain a colored curable composition 19Z1,

The total amount of the obtained pigment dispersion (the liquid containing the colorant A1Z 1);

400 parts of the obtained coloring composition;

resin (B): 45 parts of resin B1 solution;

polymerizable compound (C): 25 parts of dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kagaku Co., Ltd.);

polymerization initiator (D): 15 parts of N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure (registered trademark) OXE-01; manufactured by BASF corporation);

solvent (E): 86 parts of propylene glycol monomethyl ether acetate; and

leveling agent: 0.12 part of polyether-modified Silicone oil (Toray Silicone SH 8400; manufactured by Dow Corning Toray Co., Ltd.).

A colored pattern was produced in the same manner as in example 101Z1 except that a colored curable composition 19Z1 was used instead of the colored curable composition 1Z 1. A colored coating film was obtained in the same manner as in example 101Z1 except that a colored curable composition 19Z1 was used in place of the colored curable composition 1Z1, and the film thickness and the retardation value were measured. The results are shown in Table 9Z 1.

Example 120Z1 to example 127Z1

A colored pattern was obtained in the same manner as in example 119Z1 except that the mixture of the compound represented by the formula (IZ1-38) and the compound represented by the formula (IZ1-39) obtained in example 1Z1 was replaced with the colorant shown in the column of "colorant" in table 9Z 1. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 9Z 1.

Example 128Z1 to example 136Z1

A colored pattern was obtained in the same manner as in example 119Z1 except that the mixture of the compound represented by the formula (IZ1-38) and the compound represented by the formula (IZ1-39) obtained in example 1Z1 was replaced with the compound shown in the column of "colorant" in table 9Z1, and c.i. pigment green 58 was replaced with c.i. pigment green 7. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 9Z 1.

Example 137Z1 to example 145Z1

A colored pattern was obtained in the same manner as in example 119Z1 except that the mixture of the compound represented by the formula (IZ1-38) and the compound represented by the formula (IZ1-39) obtained in example 1Z1 was replaced with the compound shown in the column of "colorant" in table 9Z1, and c.i. pigment green 58 was replaced with c.i. pigment green 59. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 9Z 1.

[ Table 9Z1]

TABLE 9Z1

In the examination of example Z1, it is understood from the above results that the retardation value of the colored coating film formed from the colored curable composition containing the compound of the present invention is smaller than that of the colored coating film formed from the colored curable composition containing c.i. pigment yellow 185.

Example Z2

Example 1Z2

5.02 parts of 4-nitrophthalonitrile (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 22 parts of methanol were mixed. To the resulting mixture, 2.90 parts of 28% sodium methoxide methanol solution (Wako pure chemical industries, Ltd.) was added, and the mixture was stirred at 25 ℃ for 3 hours.

To the obtained mixture were added 3.67 parts of ethyl cyanoacetate (manufactured by Tokyo chemical industry Co., Ltd.), 1.83 parts of acetic acid and 30 parts of methanol, and the mixture was stirred at 25 ℃ for 1 hour and 30 minutes.

To the obtained mixture were added 3.62 parts of ethyl cyanoacetate (manufactured by tokyo chemical industries, ltd.), 2.37 parts of acetic acid and 30 parts of methanol, and the mixture was stirred at 63 ℃ for 3 hours.

To the obtained mixture were added 3.63 parts of ethyl cyanoacetate (manufactured by tokyo chemical industry co., ltd.), 2.36 parts of acetic acid and 30 parts of methanol, and the mixture was stirred at 63 ℃ for 2 hours.

To the obtained mixture were added 3.62 parts of ethyl cyanoacetate (manufactured by Tokyo chemical industry Co., Ltd.) and 2.40 parts of acetic acid, and the mixture was stirred at 63 ℃ for 1 hour, at room temperature for 11 hours and at 63 ℃ for 6 hours.

The temperature of the resulting mixture was lowered to room temperature, followed by filtration.

The obtained residue was dried to obtain 10.0 parts of a mixture of the compound represented by formula (IaZ2-39), the compound represented by formula (IaZ2-38) and the compound represented by formula (IaZ 2-149).

Identification of Compound represented by the formula (IaZ2-39)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺383

Exact molecular weight (Exact masses): 382

Identification of Compound represented by the formula (IaZ2-38)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺355

Exact molecular weight (Exact masses): 354

Identification of Compound represented by the formula (IaZ2-149)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺369

Exact molecular weight (Exact masses): 368

Example 2Z2

A compound represented by formula (IbZ2-125) was obtained in the same manner as in example 1Z2, except that ethyl cyanoacetate (manufactured by tokyo chemical industry co.) was replaced with 2-cyanoacetamide (manufactured by tokyo chemical industry co.).

Identification of Compound represented by the formula (IbZ2-125)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺325

Exact molecular weight (Exact masses): 324

Example 3Z2

The procedure of example 1Z2 was repeated except for replacing ethyl cyanoacetate (manufactured by tokyo chemical industries, ltd.) with 2-cyano-N-methylacetamide to obtain compounds represented by the formula (IbZ 2-126).

Identification of Compound represented by the formula (IbZ2-126)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺353

Exact molecular weight (Exact masses): 352

Example 4Z2

A compound represented by formula (IbZ2-148) was obtained in the same manner as in example 1Z2, except that ethyl cyanoacetate (manufactured by tokyo chemical industry co.) was replaced with 2-cyano-N, N-dimethylacetamide (manufactured by tokyo chemical industry co.).

Identification of Compound represented by the formula (IbZ2-148)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺381

Exact molecular weight (Exact masses): 380

Example 5Z2

A compound represented by formula (IbZ2-149) was obtained in the same manner as in example 1Z2, except that ethyl cyanoacetate (manufactured by tokyo chemical industry co.) was replaced with 2-cyano-N, N-diethylacetamide (manufactured by tokyo chemical industry co.).

Identification of Compound represented by the formula (IbZ2-149)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺437

Exact molecular weight (Exact masses): 436

Example 6Z2

The procedure of example 1Z2 was repeated except for replacing ethyl cyanoacetate (manufactured by tokyo chemical industry co.) with 2-cyanoacetanilide (2-cyanoacetanilide) (manufactured by tokyo chemical industry co.) to obtain compounds represented by the formulae (IbZ2 to 128).

Identification of Compound represented by the formula (IbZ2-128)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺477

Exact molecular weight (Exact masses): 476

Example 7Z2XXX (662)

2.55 parts of 4-nitrophthalonitrile (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 84 parts of methanol were mixed. While the mixture was kept at 5 ℃ or lower, a mixture of 1.47 parts of 28% sodium methoxide methanol solution (Wako pure chemical industries, Ltd.) and 30 parts of methanol was added. The mixture was stirred at 5 ℃ or below for 5 hours. To the mixture were added 2.16 parts of acetic acid, 2.92 parts of 2-cyano-N-methylacetamide and 21 parts of methanol, and the mixture was stirred at 40 ℃ for 3 hours.

To the mixture was added 13.5 parts of 28% sodium methoxide methanol solution (manufactured by Wako pure chemical industries, Ltd.), and the mixture was stirred at 40 ℃ for 12 hours and at 62 ℃ for 9 hours.

To the mixture were added 1.50 parts of 2-cyano-N-methylacetamide and 3.05 parts of 28% sodium methoxide methanol solution (Wako pure chemical industries, Ltd.), and the mixture was stirred at 62 ℃ for 5 hours and at 40 ℃ for 17 hours. In addition, up to this point in time, 6 parts in total of methanol were added in addition to the above-mentioned methanol. After the solvent was distilled off from the mixture by a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IbZ 2-126).

Identification of Compound represented by the formula (IbZ2-126)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺353

Exact molecular weight (Exact masses): 352

Example 8Z2

10 parts of 4-nitrophthalonitrile and 80 parts of methanol are mixed.

While the mixture was kept at 0 ℃, a 25% sodium methoxide methanol solution containing sodium methoxide in an amount of 0.5 times the molar amount of 4-nitrophthalonitrile 10 parts was added. The mixture was stirred at 0 ℃ for 5 hours.

To the mixture were added 16 parts of acetic acid and 2-cyanoacetamide in an amount of 3.3 times the molar amount of 10 parts of 4-nitrophthalonitrile, and the mixture was stirred at 60 ℃ for 21 days.

After the solvent was distilled off from the mixture by a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IbZ 2-125).

Identification of Compound represented by the formula (IbZ2-125)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺325

Exact molecular weight (Exact masses): 324

Example 9Z2

10 parts of 4-nitrophthalonitrile and 80 parts of methanol are mixed.

While the mixture was kept at 0 ℃, a 25% sodium methoxide methanol solution containing sodium methoxide in an amount of 0.5 times the molar amount of 4-nitrophthalonitrile 10 parts was added. The mixture was stirred at 0 ℃ for 5 hours.

To the mixture were added 16 parts of acetic acid and 2-cyano-N, N-dimethylacetamide in an amount of 3.3 times the number of moles of 10 parts of 4-nitrophthalonitrile, and the mixture was stirred at 60 ℃ for 21 days. After the solvent was distilled off from the mixture by a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IbZ 2-148).

Identification of Compound represented by the formula (IbZ2-148)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺381

Exact molecular weight (Exact masses): 380

Example 10Z2

10 parts of 4-nitrophthalonitrile and 80 parts of methanol are mixed. While the mixture was kept at 0 ℃, a 25% sodium methoxide methanol solution containing sodium methoxide in an amount of 0.5 times the molar amount of 4-nitrophthalonitrile 10 parts was added. The mixture was stirred at 0 ℃ for 5 hours. To the mixture were added 16 parts of acetic acid and 2-cyano-N, N-diethylacetamide in an amount of 3.3 times the number of moles of 10 parts of 4-nitrophthalonitrile, and the mixture was stirred at 60 ℃ for 21 days.

After the solvent was distilled off from the mixture by a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IbZ 2-149).

Identification of Compound represented by the formula (IbZ2-149)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺437

Exact molecular weight (Exact masses): 436

Example 11Z2XXX (660)

1.25 parts of 4-nitrophthalonitrile (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 41 parts of methanol were mixed. While keeping the temperature at 5 ℃ or lower, a mixture of 0.722 parts of 28% sodium methoxide methanol solution (manufactured by Wako pure chemical industries, Ltd.) and 19 parts of methanol was added dropwise to the obtained mixture over 5 minutes. The resulting mixture was stirred for 4 hours while being kept at 5 ℃ or lower.

While the resulting mixture was kept at 5 ℃ or lower, 1.21 parts of acetic acid, 2.33 parts of 2-cyanoacetanilide (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 18 parts of methanol were added. The resulting mixture was stirred at 40 ℃ for 21 hours. To the obtained mixture were added 0.596 parts of acetic acid, 1.17 parts of 2-cyanoacetanilide (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 17 parts of methanol. The resulting mixture was stirred at 40 ℃ for 3 hours. To the resulting mixture, 2.09 parts of acetic acid was added, and stirring was performed at 50 ℃ for 2 hours, at 60 ℃ for 2 hours, at room temperature for 15 hours, and at 62 ℃ for 3 hours.

To the resulting mixture, 0.981 part of trifluoroacetic acid was added, and stirring was performed at 62 ℃ for 2 hours.

To the resulting mixture, 11.5 parts of 28% sodium methoxide methanol solution (manufactured by Wako pure chemical industries, Ltd.) was added, and the mixture was stirred at 62 ℃ for 2 hours, at room temperature for 14 hours, and at 62 ℃ for 5 hours. In addition, 10 parts in total of methanol other than the above-mentioned methanol was added up to this point. The resulting mixture was cooled to 23 ℃ and added to 1100 parts of 50% aqueous acetic acid.

To the resulting mixture, 40 parts of methanol and 400 parts of 50% aqueous acetic acid were added.

The resulting mixture was filtered, and the resulting residue was washed 6 times with 250 parts of 50% aqueous acetic acid solution and 3 times with 250 parts of water. The obtained residue was dried under reduced pressure at 60 ℃ to obtain 3.32 parts of a compound represented by the formula (IbZ 2-128).

Identification of Compound represented by the formula (IbZ2-128)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺477

Exact molecular weight (Exact masses): 476

Example 12Z2XXX (653)

25.2 parts of 4-tert-butylphthalonitrile (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 212 parts of methanol were mixed. While keeping the temperature at 5 ℃ or lower, a mixture of 20.5 parts of 28% sodium methoxide methanol solution (manufactured by Wako pure chemical industries, Ltd.) and 184 parts of methanol was added dropwise to the obtained mixture over 1 hour. The resulting mixture was stirred at 5-20 ℃ for 2 days.

To the resulting mixture, 13.7 parts of acetic acid and 13.5 parts of 2-cyano-N-methylacetamide were added at 10 to 20 ℃. The obtained mixture was stirred at 10 to 20 ℃ for 5 hours and then at 40 ℃ for 16 hours. To the resulting mixture, 6.79 parts of acetic acid and 6.75 parts of 2-cyano-N-methylacetamide were added, and stirring was performed at 40 ℃ for 6 hours and at 50 ℃ for 65 hours. In addition, a total of 201 parts of methanol was added up to this time point, in addition to the above-mentioned methanol. To the resulting mixture were added 13.5 parts of acetic acid, 18.3 parts of barbituric acid (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 604 parts of water, and the mixture was stirred at 40 ℃ for 53 hours.

The resulting mixture was filtered, and the residue was washed with 50% aqueous methanol. The obtained residue was purified by column chromatography to obtain a compound represented by the formula (IbZ 2-64).

Identification of Compound represented by the formula (IbZ2-64)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺364

Exact molecular weight (Exact masses): 363

Example 13Z2XXX (659)

25.9 parts of phthalonitrile (manufactured by Tokyo chemical Co., Ltd.) and 513 parts of methanol were mixed. 30.3 parts of a 28% sodium methoxide methanol solution (Wako pure chemical industries, Ltd.) and 12 parts of methanol were added dropwise to the obtained mixture over 10 minutes while maintaining the temperature at 3 to 5 ℃. The resulting mixture was stirred for 6 hours while being maintained at 3 to 5 ℃.

To the obtained mixture were added 19.8 parts of acetic acid, 28.5 parts of t-butyl cyanoacetate and 26 parts of methanol while maintaining the temperature at 3 to 5 ℃. The resulting mixture was stirred at room temperature for 2 days, and then at 40 ℃ for 3 hours. To the resulting mixture were added 5.09 parts of acetic acid and 7.17 parts of tert-butyl cyanoacetate, and the mixture was stirred at 40 ℃ for 4 hours.

To the resulting mixture were added 4.95 parts of acetic acid, 7.15 parts of tert-butyl cyanoacetate and 38 parts of methanol, and the mixture was stirred at 40 ℃ for 16 hours. To the resulting mixture were added 19.9 parts of acetic acid, 25.8 parts of barbituric acid, 209 parts of methanol, and 800 parts of water, and the mixture was stirred at 40 ℃ for 3 hours. The resulting mixture was filtered to give a residue. The residue was purified by column chromatography to give a compound represented by the formula (IaZ 2-5).

Identification of Compound represented by the formula (IaZ2-5)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺394

Exact molecular weight (Exact masses): 393

Example 14Z2XXX (661)

15.1 parts of 4-nitrophthalonitrile (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 284 parts of methanol were mixed. While keeping the temperature at 5 ℃ or lower, a mixture of 8.81 parts of 28% sodium methoxide methanol solution (manufactured by Wako pure chemical industries, Ltd.) and 18 parts of methanol was added dropwise to the obtained mixture over 10 minutes. The resulting mixture was stirred for 4 hours while being kept at 5 ℃ or lower. To the obtained mixture, 5.55 parts of acetic acid was added while keeping the temperature at 5 ℃ or lower, and the mixture was stirred for 30 minutes. This mixture was mixed with 12.3 parts of t-butyl cyanoacetate, and stirred at 40 ℃ for 14 hours.

This mixture was mixed with 0.654 parts of acetic acid and 1.24 parts of t-butyl cyanoacetate, and stirred at 40 ℃ for 4 hours. This mixture was mixed with 0.613 part of acetic acid and 1.23 parts of t-butyl cyanoacetate, and stirred at 40 ℃ for 3 hours. This mixture was mixed with 0.647 parts of acetic acid and 1.24 parts of t-butyl cyanoacetate. Further, up to this point, a total of 89 parts of methanol was added in addition to the above-mentioned methanol. The mixture was stirred at 40 ℃ for 17 hours. This mixture was mixed with 7.14 parts of acetic acid, 11.3 parts of barbituric acid and 508 parts of water. In addition, up to this point in time, 117 parts in total of methanol were added in addition to the above-mentioned methanol. The mixture was stirred at 40 ℃ for 24 hours. This mixture was mixed with 3.65 parts of acetic acid and 5.61 parts of barbituric acid, and stirred at 40 ℃ for 9 hours and at room temperature for 2 days. The mixture was filtered and the residue was washed 3 times with 1330 parts of 50% aqueous methanol solution. The obtained residue was purified by column chromatography to obtain a compound represented by the formula (IaZ 1-41).

Identification of Compound represented by the formula (IaZ1-41)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H ]⁺439

Exact molecular weight (Exact masses): 438

Example 15Z2XXX (520)

5.41 parts of 3,4,5, 6-tetrafluorophthalonitrile and 23.6 parts of methanol were mixed. To the mixture was added a mixture of 2.70 parts of 28% sodium methoxide methanol solution (Wako pure chemical industries, Ltd.) and 10 parts of methanol at 20 to 25 ℃.

The mixture was stirred at 20 to 25 ℃ for 4 hours and 20 minutes. To the mixture were added 3.36 parts of acetic acid, 5.99 parts of methyl cyanoacetate, and 7.5 parts of methanol. The mixture was stirred at 63 ℃ for 2 hours. The solvent was distilled off from the obtained mixture by a rotary evaporator, and the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IaZ 2-223).

Identification of Compound represented by the formula (IaZ2-223)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺382

Exact molecular weight (Exact masses): 381

Example 16Z2XXX (538)

2.52 parts of phthalonitrile (manufactured by Tokyo chemical Co., Ltd.) and 22.8 parts of methanol were mixed. To the mixture was added 1.98 parts of 28% sodium methoxide methanol solution (Wako pure chemical industries, Ltd.) at room temperature. The mixture was stirred at 38 ℃ for 3 hours.

To the mixture were added 2.79 parts of cyanoacetylurea (manufactured by tokyo chemical industries, ltd.) and 1.26 parts of acetic acid. The mixture was stirred at 40 ℃ for 1 hour and 30 minutes.

To the mixture were added 2.77 parts of cyanoacetylurea (manufactured by tokyo chemical industries, ltd.) and 1.61 parts of acetic acid. In addition, a total of 39.2 parts of methanol was added up to this time point, in addition to the above-mentioned methanol. The mixture was stirred at 40 ℃ for 1 hour. To the mixture was added 65.2 parts of water, and the mixture was stirred at 40 ℃ for 2 hours and 30 minutes. To the mixture were added 2.80 parts of cyanoacetylurea (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 1.60 parts of acetic acid, and the mixture was stirred at 40 ℃ for 20 hours. In addition, up to this point in time, a total of 31 parts of methanol was added in addition to the above-mentioned methanol. After the solvent was distilled off from the mixture by a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IbZ 2-19).

Identification of Compound represented by the formula (IbZ2-19)

(Mass Spectrometry) ionization mode ESI +: m-z＝[M+H]⁺366

Exact molecular weight (Exact masses): 365

Example 17Z2

8 parts of phthalonitrile and 63 parts of ethanol are mixed.

To the mixture was added a 21% sodium ethoxide ethanol solution containing sodium ethoxide in a molar amount 1 times that of 8 parts of phthalonitrile. The mixture was stirred at room temperature for 2 hours. To the mixture were added 25 parts of acetic acid and a compound represented by the formula (ppp1) in an amount of 2.3 times the mole number of 8 parts of phthalonitrile, and the mixture was stirred at 90 ℃ for 64 hours.

The mixture was cooled to room temperature and filtered. The obtained residue was washed with 160 parts of methanol and dried. The obtained residue 24 parts and N, N-dimethylformamide 230 parts were mixed.

To the mixture was added 210 parts of acetic acid. The mixture was filtered.

The obtained residue was washed with 79 parts of methanol and dried to obtain 17 parts of a compound represented by the formula (IbZ 2-311).

Identification of Compound represented by the formula (IbZ2-311)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺508

Exact molecular weight (Exact masses): 507

To 15 parts of the compound represented by the formula (IbZ2-311), 200 parts of methylene chloride and 150 parts of trifluoroacetic acid were added, and the mixture was stirred at room temperature for 50 hours.

To the resulting mixture was added 160 parts of methanol, followed by filtration.

The obtained residue was dried to obtain 13 parts of a residue.

The residue 12 parts and N, N-dimethylformamide 230 parts were mixed, stirred for 1 hour, and then filtered. The obtained residue was mixed with 160 parts of methanol and stirred at 70 ℃.

The resulting mixture was filtered. The residue was dried to obtain 9 parts of a compound represented by the formula (IbZ 2-317).

Identification of Compound represented by the formula (IbZ2-317)

(Mass Spectrometry) ionization mode-ESI-: m/z ═ M-H]^-394

Exact molecular weight (Exact masses): 395

Example 18Z2

5 parts of 4-nitrophthalonitrile and 39 parts of ethanol are mixed.

While the mixture was kept at 0 ℃, a 21% sodium ethoxide ethanol solution containing sodium ethoxide in an amount of 0.5 times the mole of 5 parts of 4-nitrophthalonitrile was added. The mixture was stirred at 0 ℃ for 3 hours. To the mixture were added 16 parts of acetic acid and a compound represented by the formula (ppp1) in a molar amount of 3.3 times that of 5 parts of 4-nitrophthalonitrile. The mixture was sealed in a tube and stirred at 90 ℃ for 56 hours. The mixture was cooled to room temperature and filtered. The residue was washed with ethanol to give residue A8 parts. 10 parts of 4-nitrophthalonitrile and 79 parts of ethanol are mixed. While the mixture was kept at 0 ℃, a 21% sodium ethoxide ethanol solution containing sodium ethoxide in an amount of 0.5 times the mole number of 10 parts of 4-nitrophthalonitrile was added. The mixture was stirred at 0 ℃ for 3 hours. To the mixture were added 31 parts of acetic acid and a compound represented by the formula (ppp1) in a molar amount of 3.3 times that of 10 parts of 4-nitrophthalonitrile. The mixture was sealed in a tube and stirred at 90 ℃ for 56 hours. The mixture was cooled to room temperature and filtered. The obtained residue was washed with ethanol to obtain 15 parts of a residue B. The residue A4 parts and the residue B14 parts were mixed together with 170 parts of N, N-dimethylformamide.

The mixture was mixed with 710 parts of methanol and stirred at room temperature for 16 hours.

The mixture was filtered to obtain 13 parts of a residue containing the compound represented by the formula (IbZ 2-312).

Identification of Compound represented by the formula (IbZ2-312)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺553

Exact molecular weight (Exact masses): 552

The residue containing the compound represented by the formula (IbZ2-312) (13 parts) was mixed with dichloromethane (170 parts) and trifluoroacetic acid (130 parts) and stirred at room temperature for 16 hours.

To the mixture, the solvent was distilled off, 190 parts of N, N-dimethylformamide was added to 12 parts of the obtained residue, and the mixture was stirred at 90 ℃ for 10 minutes and then filtered. The resulting filtrate was allowed to stand at room temperature for 16 hours. The filtrate was filtered to obtain 8.0 parts of a residue. This residue 8.0 parts and tetrahydrofuran 22 parts were mixed, stirred at 70 ℃ for 3 hours, and then filtered.

The obtained residue 7.2 parts and acetic acid 21 parts were mixed, stirred at 80 ℃ for 2 hours, and then filtered.

The obtained residue 6.2 parts and toluene 170 parts were mixed, stirred at 95 ℃ for 3 hours, and then filtered.

The obtained residue 5.6 parts and water 50 parts were mixed, stirred at 90 ℃ for 16 hours, and then filtered.

The obtained residue was dried to obtain 5.4 parts of a compound represented by the formula (IbZ 2-515).

Identification of Compound represented by the formula (IbZ2-515)

(Mass Spectrometry) ionization mode-ESI-: m/z ═ M-H]^-439

Exact molecular weight (Exact masses): 440

Example 19Z2

2 parts of phthalonitrile and 16 parts of methanol are mixed.

While the mixture was kept at 0 ℃, a 25% sodium methoxide methanol solution containing sodium methoxide in an amount of 0.5 times the molar amount of phthalonitrile 2 parts was added.

The mixture was stirred at 0 ℃ for 5 hours. To the mixture were added 4.2 parts by mole of a compound represented by the formula (ppp2) in an amount of 3.3 times the mole of 2 parts by mole of phthalonitrile, and the mixture was stirred at 60 ℃ for 6 days. The mixture was cooled to room temperature and filtered. The obtained residue was washed with methanol to obtain 4 parts of a residue Aa containing the compound represented by the formula (IbZ 2-313). 8 parts of phthalonitrile and 63 parts of methanol are mixed. While the mixture was kept at 0 ℃, a 25% sodium methoxide methanol solution containing sodium methoxide in an amount of 0.5 times the mole of 8 parts of phthalonitrile was added. The mixture was stirred at 0 ℃ for 5 hours. To the mixture were added 17 parts of acetic acid and a compound represented by the formula (ppp2) in an amount of 3.3 times the number of moles of 8 parts of phthalonitrile, and the mixture was stirred at 60 ℃ for 10 days.

The mixture was cooled to room temperature and filtered. The obtained residue was washed with methanol to obtain 16 parts of a residue Bb containing the compound represented by formula (IbZ 2-313).

Identification of Compound represented by the formula (IbZ2-313)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺536

Exact molecular weight (Exact masses): 535

The residue Aa 2 parts containing the compound represented by the formula (IbZ2-313) was mixed with 27 parts of methylene chloride and 22 parts of trifluoroacetic acid, and stirred at room temperature for 16 hours. The solvent of the mixture was distilled off to obtain a residue Aaa 2 parts. The residue Aa 2 parts containing the compound represented by the formula (IbZ2-313), the residue Bb 16 parts containing the compound represented by the formula (IbZ2-313), 240 parts of methylene chloride and 190 parts of trifluoroacetic acid were mixed and stirred at room temperature for 16 hours.

The solvent of the mixture was distilled off to obtain 16 parts of residue Ccc.

1.7 parts of residue Aaa, 16 parts of residue Ccc and 210 parts of acetic acid were mixed and stirred at 80 ℃ for 16 hours. The mixture was filtered to obtain 13 parts of a residue. The residue was mixed with 71 parts of diethyl ether and stirred at room temperature for 16 hours. The mixture was filtered, and the obtained residue was dried to obtain 12 parts of a compound represented by the formula (IbZ 2-318).

Identification of Compound represented by the formula (IbZ2-318)

(Mass Spectrometry) ionization mode-ESI-: m/z ═ M-H]^-422

Exact molecular weight (Exact masses): 423

Example 20Z2

2 parts of 4-nitrophthalonitrile and 16 parts of methanol are mixed.

While the mixture was kept at 0 ℃, a 25% sodium methoxide methanol solution containing sodium methoxide in an amount of 0.5 times the molar amount of 4-nitrophthalonitrile 2 parts was added. The mixture was stirred at 0 ℃ for 3 hours. To the mixture were added 2.1 parts by mole of a compound represented by the formula (ppp2) 3.3 times the mole of 2 parts by mole of 4-nitrophthalonitrile and 2.1 parts by mole of acetic acid, and the mixture was stirred at 60 ℃ for 15 days. The mixture was cooled to room temperature and filtered. The obtained residue was washed with 48 parts of methanol to obtain 8.4 parts of a residue containing the compound represented by the formula (IbZ 2-314).

Identification of Compound represented by the formula (IbZ2-314)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺581

Exact molecular weight (Exact masses): 580

The residue containing the compound represented by the formula (IbZ2-314) (8.4 parts) was mixed with dichloromethane (110 parts) and trifluoroacetic acid (89 parts) and stirred at room temperature for 16 hours. The solvent of the mixture was distilled off to obtain 6.9 parts of a residue. This residue 6.1 parts and 34 parts of dimethyl sulfoxide were mixed and stirred at room temperature for 5 minutes. The mixture was mixed with 190 parts of acetic acid, and stirred at room temperature for 30 minutes. The mixture was mixed with 290 parts of methanol and stirred at room temperature for 1 hour. The mixture was filtered to give a residue of 5.7 parts. The residue 5.6 parts and water 150 parts were mixed, stirred at 80 ℃ for 2 hours, and filtered.

The obtained residue was dried to obtain 5.4 parts of a compound represented by the formula (IbZ 2-516).

< identification of Compound represented by formula (IbZ2-516 >

(Mass Spectrometry) ionization mode-ESI-: m/z ═ M-H]^-467

Exact molecular weight (Exact masses): 468

Example 21Z2

A compound represented by the formula (ppp3) in an amount of 1.1 times the mole of 6 parts of phthalonitrile, 66 parts of dimethyl sulfoxide and 1 time the mole of potassium tert-butoxide in an amount of 6 parts of phthalonitrile were mixed and stirred at room temperature for 10 minutes. To the mixture was added 6 parts of phthalonitrile, and the mixture was stirred at 80 ℃ for 2 hours. To the mixture was added a compound represented by the formula (ppp3) in an amount of 1.1 times the mole of 6 parts of phthalonitrile, and the mixture was stirred at 180 ℃ for 2 hours. The mixture was cooled to room temperature and filtered to obtain 5.3 parts of a residue. This residue 5.0 parts was mixed with 55 parts of dimethyl sulfoxide and 47 parts of N, N-dimethylformamide, and stirred at 80 ℃ for 30 minutes.

This mixture was mixed with 240 parts of methanol and stirred at 80 ℃ for 30 minutes.

The mixture was cooled to room temperature and filtered. The obtained residue was mixed with 55 parts of dimethyl sulfoxide and 47 parts of N, N-dimethylformamide, and stirred at 80 ℃ for 30 minutes. This mixture was mixed with 240 parts of methanol and stirred at 80 ℃ for 30 minutes. The mixture was cooled to room temperature and filtered to obtain 4.6 parts of a residue. The residue was mixed with methanol and stirred at 80 ℃ for 2 hours. The mixture was filtered, and the obtained residue was dried to obtain 4.5 parts of a compound represented by the formula (IbZ 2-319).

Identification of Compound represented by the formula (IbZ2-319)

(Mass Spectrometry) ionization mode-ESI-: m/z ═ M-H]^-518

Exact molecular weight (Exact masses): 519

Example 22Z2

50 parts of 4-aminomethylbenzoic acid, cyanoacetic acid in an amount of 1.2 times the molar amount of 50 parts of 4-aminomethylbenzoic acid, N' -dicyclohexylcarbodiimide in an amount of 0.9 times the molar amount of 50 parts of 4-aminomethylbenzoic acid, and 890 parts of tetrahydrofuran were mixed and stirred at room temperature for 16 hours. The mixture was filtered, and the solvent of the filtrate was distilled off to obtain a residue.

The obtained residue was mixed with 270 parts of ethyl acetate and filtered.

The obtained residue was dried to obtain 30 parts of a compound represented by the formula (ppp 4).

Identification of Compound represented by the formula (ppp4)

(Mass Spectrometry) ionization mode-ESI-: m/z ═ M-H]^-217

Exact molecular weight (Exact masses): 218

In addition, 3 parts of phthalonitrile and 110 parts of ethylene glycol were mixed. To the mixture was added 25% sodium methoxide methanol solution containing sodium methoxide in an amount of 1.5 times the mole of 3 parts of phthalonitrile at room temperature.

The mixture was stirred at room temperature for 4 hours. To the mixture were added 110 parts of a compound represented by the formula (ppp4) in an amount of 3.1 times the mole of 3 parts of phthalonitrile and 110 parts of ethylene glycol, and the mixture was stirred at 110 ℃ for 16 hours. After the mixture was cooled to room temperature, 630 parts of methanol was added. The mixture was mixed with 26 parts of acetic acid. The mixture was filtered to obtain 11 parts of a residue. The residue was mixed with 220 parts of dimethyl sulfoxide. This mixture was mixed with 630 parts of methanol. The mixture was filtered to give a residue of 9.5 parts. The residue was mixed with 220 parts of dimethyl sulfoxide. This mixture was mixed with 630 parts of methanol. The mixture was filtered to obtain 9 parts of a residue. The residue was mixed with 200 parts of water and stirred at 80 ℃ for 2 hours. The mixture was mixed with 2.1 parts of acetic acid. The mixture was filtered to give 8.5 parts of a residue. The residue (8.1 parts) and dimethyl sulfoxide (260 parts) were mixed and stirred at 60 ℃ for 20 minutes. The mixture was cooled to room temperature, allowed to stand at room temperature for 2 hours, and filtered.

The obtained residue was washed with 2% aqueous acetic acid solution to obtain 6.2 parts of a residue. The residue was mixed with 150 parts of water and stirred at 80 ℃ for 30 minutes. The mixture was cooled to room temperature and filtered.

The obtained residue was washed with 200 parts of water. The residue was dried to obtain 6 parts of a compound represented by the formula (IbZ 2-320).

Identification of Compound represented by the formula (IbZ2-320)

(Mass Spectrometry) ionization mode-ESI-: m/z ═ M-H]^-546

Exact molecular weight (Exact masses): 547

Example 23Z2

5 parts of 4, 5-dibromophthalonitrile and 93 parts of 2-ethoxyethanol are mixed.

To the mixture was added a 25% sodium methoxide methanol solution containing 1 time by mole of sodium methoxide as much as 5 parts by mole of 4, 5-dibromophthalonitrile. The mixture was stirred at room temperature for 6 hours. To the mixture was added a compound represented by the formula (ppp1) in an amount of 6 times the mole number of 5 parts of 4, 5-dibromophthalonitrile, and the mixture was stirred at 90 ℃ for 65 hours and then at 100 ℃ for 10 hours. This mixture was mixed with 300 parts of water and 21 parts of acetic acid. The mixture was filtered to obtain 10 parts of a residue. The residue was mixed with 120 parts of methanol and 10 parts of acetic acid. The mixture was filtered to obtain 5.5 parts of a residue containing the compound represented by the formula (IbZ 2-315).

Identification of Compound represented by the formula (IbZ2-315)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺664

Exact molecular weight (Exact masses): 663

The residue containing the compound represented by the formula (IbZ2-315) (5.5 parts) was mixed with trifluoroacetic acid (45 parts) and dichloromethane (80 parts), and stirred at room temperature for 16 hours. The solvent of the mixture was distilled off to obtain 6 parts of a residue. The residue was mixed with 79 parts of methanol. The mixture was filtered to obtain 4 parts of a residue.

This residue was mixed with 0.24 part of lithium hydroxide, 36 parts of tetrahydrofuran and 12 parts of water, and stirred at room temperature for 6 hours. Tetrahydrofuran was distilled off from the mixture using an evaporator. To the resulting mixture, water and 1.5N hydrochloric acid were added. The mixture was filtered to give a residue of 3.5 parts. The residue was mixed with 40 parts of methanol. The mixture was filtered, and the residue was washed with 13 parts of hexane to give 3 parts of residue. This residue 2.8 parts and dimethyl sulfoxide 33 parts were mixed and stirred at 70 ℃ for 20 minutes. The mixture was cooled to room temperature and filtered.

The obtained residue was washed with 40 parts of methanol and then 50 parts of water.

The residue was dried to obtain 1.8 parts of a compound represented by the formula (IbZ 2-706).

Identification of Compound represented by the formula (IbZ2-706)

(Mass Spectrometry) ionization mode-ESI-: m/z ═ M-H]^-550

Exact molecular weight (Exact masses): 551

Example 24Z2

13 parts of 4, 5-dichlorophthalonitrile and 160 parts of methanol were mixed.

While the mixture was kept at 0 ℃ a 25% sodium methoxide methanol solution containing sodium methoxide in an amount of 0.5 times the mole number of 13 parts by mole of 4, 5-dichlorophthalonitrile was added. The mixture was stirred at 0 ℃ for 5 hours. To the mixture were added a compound represented by the formula (ppp1) in an amount of 4.4 times the mole number of 13 parts of 4, 5-dichlorophthalonitrile and 16 parts of acetic acid, and the mixture was stirred at 75 ℃ for 7 days. To the mixture were added 14 parts of acetic acid and a compound represented by the formula (ppp1) in an amount of 3 times the mole number of 13 parts of 4, 5-dichlorophthalonitrile, and the mixture was stirred at 75 ℃ for 11 days.

The mixture was filtered. The obtained residue was washed with 320 parts of methanol to obtain 26 parts of a residue.

13 parts of this residue was mixed with 100 parts of methanol, 16 parts of acetic acid and 26.3 parts of a compound represented by the formula (ppp1), and stirred at 75 ℃ for 48 hours. The mixture was filtered. The obtained residue was washed with 40 parts of methanol to obtain 12 parts of a residue containing the compound represented by the formula (IbZ 2-316).

Identification of Compound represented by the formula (IbZ2-316)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺576

Exact molecular weight (Exact masses): 575

The residue containing the compound represented by the formula (IbZ2-316) (12 parts) was mixed with dichloromethane (160 parts) and trifluoroacetic acid (130 parts), and the mixture was stirred at room temperature for 16 hours. The mixture was filtered to obtain 6.2 parts of a residue. The residue was mixed with 73 parts of acetic acid and stirred at 80 ℃ for 2 hours. The mixture was filtered to give 5.3 parts of a residue. The residue was mixed with 60 parts of water and stirred at 80 ℃ for 2 hours. The mixture was filtered, and the obtained residue was dried to obtain 5 parts of a compound represented by the formula (IbZ 2-389).

Identification of Compound represented by the formula (IbZ2-389)

(Mass Spectrometry) ionization mode-ESI-: m/z ═ M-H]^-462

Exact molecular weight (Exact masses): 463

Example 101Z2

The following substances are mixed together and then,

pigment: 5860 portions of C.I. pigment green,

8.1 parts of acrylic pigment dispersing agent,

resin (B): 73 parts of resin B5 solution, and

solvent (E): 290 parts of propylene glycol monomethyl ether acetate

The pigment dispersion liquid (liquid containing colorant A1Z 2) was prepared by dispersing the pigment using a bead mill. In addition, the following substances were mixed,

Colorant AZ 2: 50 parts of a mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in example 1Z2,

58 parts of a dispersant (BYK-LPN 6919; manufactured by BYK-Chemie Japan, Ltd.),

resin (B): 93 parts of resin B3 solution, and

solvent (E): propylene glycol monomethyl ether acetate 800 parts

A mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in example 1Z2 was dispersed using a bead mill to obtain a coloring composition.

Next, the following were mixed to obtain colored curable composition 1Z2,

the total amount of the obtained pigment dispersion (the liquid containing the colorant A1Z 2);

400 parts of the obtained coloring composition;

resin (B): 45 parts of resin B1 solution;

polymerizable compound (C): 25 parts of dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kagaku Co., Ltd.);

polymerization initiator (D): 15 parts of N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure (registered trademark) OXE-01; manufactured by BASF corporation);

Solvent (E): 86 parts of propylene glycol monomethyl ether acetate; and

leveling agent: 0.12 part of polyether-modified Silicone oil (Toray Silicone SH 8400; manufactured by Dow Corning Toray Co., Ltd.).

[ preparation of colored Pattern ]

A2-inch square glass substrate (EAGLE XG; manufactured by Corning Inc.) was coated with a colored curable composition 1Z2 by spin coating, and then prebaked at 100 ℃ for 3 minutes to form a colored curable composition layer. After cooling, the substrate on which the colored curable composition layer was formed and a photomask made of quartz glass were spaced at a distance of 200 μm, and exposed to an exposure apparatus (TME-150 RSK; manufactured by Topcon Corporation) at a rate of 80mJ/cm in an atmospheric atmosphere²Exposure was carried out with the exposure amount (based on 365 nm). As the photomask, a photomask in which a line-and-space pattern of 100 μm was formed was used. The colored curable composition layer after exposure was immersed in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ℃ for 70 seconds, developed, and washed with water. The colored curable composition layer was post-baked at 230 ℃ for 30 minutes, whereby a colored pattern was obtained.

[ measurement of phase difference value ]

A colored curable composition 1Z2 was applied to a 2-inch square glass substrate (EAGLE XG; manufactured by Corning corporation) by a spin coating method, and then prebaked at 100 ℃ for 3 minutes to form a colored curable composition layer. After cooling, an exposure machine (TME-150 RSK; manufactured by Topcon Corporation) was used for the colored curable composition layer under an atmospheric atmosphere at 80mJ/cm²Exposure was carried out with the exposure amount (based on 365 nm). The colored curable composition layer after exposure was immersed in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ℃ for 70 seconds, developed, and washed with water. The colored curable composition layer was post-baked at 230 ℃ for 30 minutes, thereby obtaining a colored coating film.

The film thickness of the obtained colored coating film was measured using DEKTAK3 (manufactured by japan vacuum technology corporation). The phase difference value at an inclination angle of 45 ° of the colored coating film was measured using an ellipsometer (M-220 type spectroscopic ellipsometer; manufactured by japan spectro (ltd.)). For the measurement of the retardation value, light having a wavelength of 550nm was used. The results are shown in Table 23Z 2.

Example 102Z2

A colored curable composition 2Z2 was obtained and a colored pattern was obtained in the same manner as in example 101Z2 except that the mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in example 1Z2 was replaced with the compound represented by the formula (IbZ2-125) obtained in example 2Z 2. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 23Z 2.

Example 103Z2

A colored curable composition 3Z2 was obtained and a colored pattern was obtained in the same manner as in example 101Z2 except that the mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in example 1Z2 was replaced with the compound represented by the formula (IbZ2-126) obtained in example 3Z 2. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 23Z 2.

Example 104Z2

A colored curable composition 4Z2 was obtained and a colored pattern was obtained in the same manner as in example 101Z2 except that the mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in example 1Z2 was replaced with the compound represented by the formula (IbZ2-148) obtained in example 4Z 2. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 23Z 2.

Example 105Z2

A colored curable composition 5Z2 was obtained and a colored pattern was obtained in the same manner as in example 101Z2 except that the mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in example 1Z2 was replaced with the compound represented by the formula (IbZ2-149) obtained in example 5Z 2. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 23Z 2.

Example 106Z2

A colored curable composition 6Z2 was obtained and a colored pattern was obtained in the same manner as in example 101Z2 except that the mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in example 1Z2 was replaced with the compound represented by the formula (IbZ2-128) obtained in example 6Z 2. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 23Z 2.

Example 107Z2

A colored curable composition 7Z2 was obtained and a colored pattern was obtained in the same manner as in example 101Z2, except that c.i. pigment green 58 was replaced with c.i. pigment green 7. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 23Z 2.

Example 108Z2

A colored curable composition 8Z2 was obtained in the same manner as in example 101Z2 and a colored pattern was obtained in the same manner as in example 101Z2 except that c.i. pigment green 58 was replaced with c.i. pigment green 7 and the mixture of the compound represented by formula (IaZ2-39), the compound represented by formula (IaZ2-38) and the compound represented by formula (IaZ2-149) obtained in example 1Z2 was replaced with the compound represented by formula (IbZ2-125) obtained in example 2Z 2. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 23Z 2.

Example 109Z2

A colored curable composition 9Z2 was obtained in the same manner as in example 101Z2 and a colored pattern was obtained in the same manner as in example 101Z2 except that c.i. pigment green 58 was replaced with c.i. pigment green 7 and the mixture of the compound represented by formula (IaZ2-39), the compound represented by formula (IaZ2-38) and the compound represented by formula (IaZ2-149) obtained in example 1Z2 was replaced with the compound represented by formula (IbZ2-126) obtained in example 3Z 2. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 23Z 2.

Example 110Z2

A colored curable composition 10Z2 was obtained in the same manner as in example 101Z2 and a colored pattern was obtained in the same manner as in example 101Z2 except that c.i. pigment green 58 was replaced with c.i. pigment green 7 and the mixture of the compound represented by formula (IaZ2-39), the compound represented by formula (IaZ2-38) and the compound represented by formula (IaZ2-149) obtained in example 1Z2 was replaced with the compound represented by formula (IbZ2-148) obtained in example 4Z 2. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 23Z 2.

Example 111Z2

A colored curable composition 11Z2 was obtained in the same manner as in example 101Z2 and a colored pattern was obtained in the same manner as in example 101Z2 except that c.i. pigment green 58 was replaced with c.i. pigment green 7 and the mixture of the compound represented by formula (IaZ2-39), the compound represented by formula (IaZ2-38) and the compound represented by formula (IaZ2-149) obtained in example 1Z2 was replaced with the compound represented by formula (IbZ2-149) obtained in example 5Z 2. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 23Z 2.

Example 112Z2

A colored curable composition 12Z2 was obtained in the same manner as in example 101Z2 and a colored pattern was obtained in the same manner as in example 101Z2 except that c.i. pigment green 58 was replaced with c.i. pigment green 7 and the mixture of the compound represented by formula (IaZ2-39), the compound represented by formula (IaZ2-38) and the compound represented by formula (IaZ2-149) obtained in example 1Z2 was replaced with the compound represented by formula (IbZ2-128) obtained in example 6Z 2. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 23Z 2.

Example 113Z2

A colored curable composition 13Z2 was obtained in the same manner as in example 101Z2 except that c.i. pigment green 58 was replaced with c.i. pigment green 59, and a colored pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 23Z 2.

Example 114Z2

A colored curable composition 14Z2 was obtained in the same manner as in example 101Z2 except that c.i. pigment green 58 was replaced with c.i. pigment green 59, and the mixture of the compound represented by formula (IaZ2-39), the compound represented by formula (IaZ2-38), and the compound represented by formula (IaZ2-149) obtained in example 1Z2 was replaced with the compound represented by formula (IbZ2-125) obtained in example 2Z2, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 23Z 2.

Example 115Z2

A colored curable composition 15Z2 was obtained in the same manner as in example 101Z2 and a colored pattern was obtained in the same manner as in example 101Z2 except that c.i. pigment green 58 was replaced with c.i. pigment green 59 and the mixture of the compound represented by formula (IaZ2-39), the compound represented by formula (IaZ2-38) and the compound represented by formula (IaZ2-149) obtained in example 1Z2 was replaced with the compound represented by formula (IbZ2-126) obtained in example 3Z 2. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 23Z 2.

Example 116Z2

A colored curable composition 16Z2 was obtained in the same manner as in example 101Z2 and a colored pattern was obtained in the same manner as in example 101Z2 except that c.i. pigment green 58 was replaced with c.i. pigment green 59 and the mixture of the compound represented by formula (IaZ2-39), the compound represented by formula (IaZ2-38) and the compound represented by formula (IaZ2-149) obtained in example 1Z2 was replaced with the compound represented by formula (IbZ2-148) obtained in example 4Z 2. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 23Z 2.

Example 117Z2

A colored curable composition 17Z2 was obtained in the same manner as in example 101Z2 and a colored pattern was obtained in the same manner as in example 101Z2 except that c.i. pigment green 58 was replaced with c.i. pigment green 59 and the mixture of the compound represented by formula (IaZ2-39), the compound represented by formula (IaZ2-38) and the compound represented by formula (IaZ2-149) obtained in example 1Z2 was replaced with the compound represented by formula (IbZ2-149) obtained in example 5Z 2. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 23Z 2.

Example 118Z2

A colored curable composition 18Z2 was obtained in the same manner as in example 101Z2 and a colored pattern was obtained in the same manner as in example 101Z2 except that c.i. pigment green 58 was replaced with c.i. pigment green 59 and the mixture of the compound represented by formula (IaZ2-39), the compound represented by formula (IaZ2-38) and the compound represented by formula (IaZ2-149) obtained in example 1Z2 was replaced with the compound represented by formula (IbZ2-128) obtained in example 6Z 2. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 23Z 2.

Comparative example 1Z2

A colored curable composition C1Z2 was obtained and a colored pattern was obtained in the same manner as in example 101Z2 except that the mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in example 1Z2 was replaced with c.i. pigment yellow 185. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 23Z 2.

Comparative example 2Z2

A colored curable composition C2Z2 was obtained in the same manner as in example 101Z2 except that c.i. pigment green 58 was replaced with c.i. pigment green 7, and the mixture of the compound represented by formula (IaZ2-39), the compound represented by formula (IaZ2-38), and the compound represented by formula (IaZ2-149) obtained in example 1Z2 was replaced with c.i. pigment yellow 185, to obtain a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 23Z 2.

Comparative example 3Z2

A colored curable composition C3Z2 was obtained in the same manner as in example 101Z2 except that c.i. pigment green 58 was replaced with c.i. pigment green 59, and the mixture of the compound represented by formula (IaZ2-39), the compound represented by formula (IaZ2-38), and the compound represented by formula (IaZ2-149) obtained in example 1Z2 was replaced with c.i. pigment yellow 185, to obtain a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 23Z 2.

[ Table 23Z2]

TABLE 23Z2

	Film thickness (mum)	Phase difference value (nm)
			Example 101Z2	2.3	3
Example 102Z2	2.3	4
			Example 103Z2	2.3	3
Example 104Z2	2.3	3
			Example 105Z2	2.3	3
Example 106Z2	2.3	3
			Example 107Z2	2.3	3
Example 108Z2	2.3	3
			Example 109Z2	2.3	3
Practice ofExample 110Z2	2.3	3
			Example 111Z2	2.3	4
Example 112Z2	2.3	3
			Example 113Z2	2.3	3
Example 114Z2	2.3	3
			Example 115Z2	2.3	3
Example 116Z2	2.3	3
			Example 117Z2	2.3	3
Example 118Z2	2.3	3
			Comparative example 1Z2	2.3	15
Comparative example 2Z2	2.3	15
			Comparative example 3Z2	2.3	15

Example 119Z2

The following substances are mixed together and then,

pigment: 5860 portions of C.I. pigment green,

8.1 parts of acrylic pigment dispersing agent,

resin (B): 73 parts of resin B5 solution, and

solvent (E): 290 parts of propylene glycol monomethyl ether acetate

The pigment dispersion liquid (liquid containing colorant A1Z 2) was prepared by dispersing the pigment using a bead mill.

In addition, the following substances were mixed,

colorant AZ 2: 50 parts of a mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in example 1Z2,

58 parts of a dispersant solution (solid content: 60%),

resin (B): 93 parts of resin B3 solution, and

solvent (E): propylene glycol monomethyl ether acetate 800 parts

A mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in example 1Z2 was dispersed using a bead mill to obtain a coloring composition.

Next, the following were mixed to obtain a colored curable composition 19Z2,

the total amount of the obtained pigment dispersion (the liquid containing the colorant A1Z 2);

400 parts of the obtained coloring composition;

resin (B): 45 parts of resin B1 solution;

polymerizable compound (C): 25 parts of dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kagaku Co., Ltd.);

Polymerization initiator (D): 15 parts of N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure (registered trademark) OXE-01; manufactured by BASF corporation);

solvent (E): 86 parts of propylene glycol monomethyl ether acetate; and

leveling agent: 0.12 part of polyether-modified Silicone oil (Toray Silicone SH 8400; manufactured by Dow Corning Toray Co., Ltd.).

A colored pattern was produced in the same manner as in example 101Z2 except that a colored curable composition 19Z2 was used instead of the colored curable composition 1Z 2. A colored coating film was obtained in the same manner as in example 101Z2 except that a colored curable composition 19Z2 was used in place of the colored curable composition 1Z2, and the film thickness and the retardation value were measured. The results are shown in Table 24Z 2.

Example 120Z2 to example 138Z2

A colored pattern was obtained in the same manner as in example 119Z2, except that the mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38), and the compound represented by the formula (IaZ2-149) obtained in example 1Z2 was replaced with the colorant shown in the column of "colorant" in table 24Z 2. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 24Z 2.

Example 139Z2 to example 158Z2

A colored pattern was obtained in the same manner as in example 119Z2, except that the mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38), and the compound represented by the formula (IaZ2-149) obtained in example 1Z2 was replaced with the compound shown in the column of "colorant" in table 24Z2, and c.i. pigment green 58 was replaced with c.i. pigment green 7. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 25Z 2.

Example 159Z2 to example 178Z2

A colored pattern was obtained in the same manner as in example 119Z2, except that the mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38), and the compound represented by the formula (IaZ2-149) obtained in example 1Z2 was replaced with the compound shown in the column of "colorant" in table 24Z2, and c.i. pigment green 58 was replaced with c.i. pigment green 59. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 26Z 2.

[ Table 24Z2]

TABLE 24Z2

[ Table 25Z2]

TABLE 25Z2

[ Table 26Z2]

TABLE 26Z2

Chemical formulas of compounds represented by formula (IaZ2-1) in tables 24Z2, 25Z2, and 26Z2 are shown.

In the examination of example Z2, it is understood from the above results that the retardation value of the colored coating film formed from the colored curable composition containing the compound of the present invention is smaller than that of the colored coating film formed from the colored curable composition containing c.i. pigment yellow 185.

Example Z3

Example 1Z3

10.3 parts of phthalonitrile (manufactured by Tokyo chemical Co., Ltd.) and 44.8 parts of methanol were mixed. While keeping the temperature at 20 to 25 ℃, 8.01 parts of 28% sodium methoxide methanol solution (manufactured by Wako pure chemical industries, Ltd.) was added dropwise to the obtained mixture.

The resulting mixture was stirred at 20 to 25 ℃ for 2 hours.

10 parts of methanol was added to the obtained mixture while keeping the temperature at 20 to 25 ℃.

The resulting mixture was stirred at 20-25 ℃ for 2 hours.

To the obtained mixture, 7.49 parts of 2-cyanoacetamide (manufactured by tokyo chemical industries, Ltd.) and 4.98 parts of acetic acid were added, and the obtained mixture was stirred at 40 ℃ for 2 hours and at 65 ℃ for 2 hours.

To the obtained mixture were added 11.3 parts of barbituric acid (manufactured by tokyo chemical industry corporation), 6.53 parts of acetic acid, and 160 parts of water, and the obtained mixture was stirred at 65 ℃ for 3 hours, at room temperature for 2 days, and at 75 ℃ for 5 hours.

To the resulting mixture was added 230 parts of methanol at room temperature.

The obtained compound was filtered, and the obtained residue was washed with 170 parts of methanol 1 time, 400 parts of methanol 2 times, 1000 parts of water 1 time, and 200 parts of methanol 11 times.

To the resulting residue was added 641 parts of a 5% aqueous sodium hydroxide solution, and the mixture was stirred at room temperature.

The resulting mixture was filtered, and the resulting residue was washed with 1000 parts of water.

To the resulting residue was added 478 parts of water, followed by stirring at room temperature.

The resulting mixture was filtered, and the resulting residue was washed with 500 parts of water.

The obtained residue was dried to obtain 19.1 parts of a compound represented by the formula (IZ 3-1).

Identification of Compound represented by the formula (IZ3-1)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺324

Exact molecular weight (Exact masses): 323

Example 2Z3

The procedure of example 1Z3 was repeated except for replacing phthalonitrile (manufactured by tokyo chemical industry co.) with 4-nitrophthalonitrile (manufactured by tokyo chemical industry co.) to obtain a compound represented by the formula (IZ 3-19).

Identification of Compound represented by the formula (IZ3-19)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺369

Exact molecular weight (Exact masses): 368

Example 3Z3

A compound represented by the formula (IZ3-6) was obtained in the same manner as in example 1Z3, except that phthalonitrile (manufactured by Tokyo chemical industry Co., Ltd.) was replaced with 4-tert-butylphthalonitrile (manufactured by Tokyo chemical industry Co., Ltd.).

Identification of Compound represented by the formula (IZ3-6)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺380

Exact molecular weight (Exact masses): 379

Example 4Z3XXX (516)

10.3 parts of phthalonitrile (manufactured by Tokyo chemical Co., Ltd.) and 44.8 parts of methanol were mixed.

While keeping the temperature at 20 to 25 ℃, 8.01 parts of 28% sodium methoxide methanol solution (manufactured by Wako pure chemical industries, Ltd.) was added dropwise to the obtained mixture.

The resulting mixture was stirred at 20 to 25 ℃ for 2 hours.

10 parts of methanol was added to the obtained mixture while keeping the temperature at 20 to 25 ℃.

The resulting mixture was stirred at 20-25 ℃ for 2 hours.

To the obtained mixture, 7.49 parts of 2-cyanoacetamide (manufactured by tokyo chemical industries, Ltd.) and 4.98 parts of acetic acid were added, and the obtained mixture was stirred at 40 ℃ for 2 hours and at 65 ℃ for 2 hours.

To the obtained mixture were added 11.3 parts of barbituric acid (manufactured by tokyo chemical industry corporation), 6.53 parts of acetic acid, and 160 parts of water, and the obtained mixture was stirred at 65 ℃ for 3 hours, at room temperature for 2 days, and at 75 ℃ for 5 hours.

To the resulting mixture was added 230 parts of methanol at room temperature.

The obtained compound was filtered, and the obtained residue was washed with 170 parts of methanol 1 time, 400 parts of methanol 2 times, 1000 parts of water 1 time, and 200 parts of methanol 11 times.

To the resulting residue was added 641 parts of a 5% aqueous sodium hydroxide solution, and the mixture was stirred at room temperature.

The resulting mixture was filtered, and the resulting residue was washed with 1000 parts of water.

To the resulting residue was added 478 parts of water, followed by stirring at room temperature.

The resulting mixture was filtered, and the resulting residue was washed with 500 parts of water.

The obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ 3-1).

Identification of Compound represented by the formula (IZ3-1)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺324

Exact molecular weight (Exact masses): 323

Example 5Z3XXX

10.0 parts of 4-nitrophthalonitrile (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 149 parts of methanol were mixed. While keeping the temperature at 2 to 6 ℃, 5.86 parts of 28% sodium methoxide methanol solution (manufactured by Wako pure chemical industries, Ltd.) was added dropwise to the obtained mixture over 20 minutes. The resulting mixture was stirred for 5 hours while being kept at 5 ℃ or lower. While the resulting mixture was kept at 5 ℃ or lower, 5.79 parts of acetic acid, 4.86 parts of 2-cyanoacetamide (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 74 parts of methanol were added. The resulting mixture was stirred at 65 ℃ for 3 days.

To the obtained mixture were added 2.88 parts of acetic acid and 2.43 parts of 2-cyanoacetamide (manufactured by Tokyo Kasei Kogyo Co., Ltd.). The resulting mixture was stirred at 65 ℃ for 3 days. In addition, up to this point in time, a total of 140 parts of methanol was added in addition to the above-mentioned methanol.

To the obtained mixture were added 24.0 parts of acetic acid, 15.3 parts of barbituric acid (manufactured by Tokyo chemical industry Co., Ltd.) and 363 parts of water, and the mixture was stirred at 65 ℃ for 9 days.

The solvent of the resulting mixture was distilled off by a rotary evaporator, and then the resulting residue was purified by column chromatography to give a compound represented by the formula (IZ 3-19).

Identification of Compound represented by the formula (IZ3-19)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺369

Exact molecular weight (Exact masses): 368

Example 6Z3XXX

10.0 parts of 4-tert-butyl phthalonitrile (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 84 parts of methanol were mixed. While keeping the temperature at 5 ℃ or lower, a mixture of 8.15 parts of 28% sodium methoxide methanol solution (manufactured by Wako pure chemical industries, Ltd.) and 73 parts of methanol was added dropwise to the obtained mixture over 1 hour. The resulting mixture was stirred at 5-20 ℃ for 2 days.

To the obtained mixture, 5.42 parts of acetic acid and 4.56 parts of 2-cyanoacetamide (manufactured by Tokyo Kasei Kogyo Co., Ltd.) were added at 10 to 20 ℃. The resulting mixture was stirred at 65 ℃ for 3 days.

To the obtained mixture were added 2.69 parts of acetic acid and 2.28 parts of 2-cyanoacetamide (manufactured by Tokyo Kasei Kogyo Co., Ltd.), and the mixture was stirred at 65 ℃ for 3 days. In addition, up to this point in time, a total of 206 parts of methanol were added in addition to the above-mentioned methanol. To the obtained mixture were added 5.36 parts of acetic acid, 7.25 parts of barbituric acid (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 363 parts of water, and the mixture was stirred at 65 ℃ for 9 days.

The solvent of the resulting mixture was distilled off by a rotary evaporator, and then the resulting residue was purified by column chromatography to give a compound represented by the formula (IZ 3-6).

Identification of Compound represented by the formula (IZ3-6)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺380

Exact molecular weight (Exact masses): 379

Example 7Z3

5.0 parts of 4, 5-dichlorophthalonitrile and 62 parts of methanol were mixed. While the mixture was kept at 5 ℃ or lower, a 25% sodium methoxide methanol solution containing sodium methoxide in an amount of 0.5 times the molar amount of 5.0 parts by mole of 4, 5-dichlorophthalonitrile was added. The mixture was stirred at 5 ℃ or below for 5 hours. To the mixture were added 2-cyanoacetamide (manufactured by Tokyo chemical industries, Ltd.) in an amount of 1.5 times the molar amount of 4, 5-dichlorophthalonitrile 5.0 parts and 6.1 parts of acetic acid while keeping the temperature at 5 ℃ or lower. The mixture was stirred at 65 ℃ for 3 days.

This mixture was mixed with 4.2 parts of acetic acid, 5.2 parts of barbituric acid, 500 parts of methanol and 562 parts of water, and stirred at 65 ℃ for 9 days.

After the solvent was distilled off from the mixture by a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ 3-8).

Identification of Compound represented by the formula (IZ3-8)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺392

Exact molecular weight (Exact masses): 391

Example 101Z3

The following substances are mixed together and then,

pigment: 5860 portions of C.I. pigment green,

8.1 parts of acrylic pigment dispersing agent,

resin (B): 73 parts of resin B5 solution, and

solvent (E): 290 parts of propylene glycol monomethyl ether acetate

The pigment dispersion liquid (liquid containing colorant A1Z 3) was prepared by dispersing the pigment using a bead mill. In addition, the following substances were mixed,

colorant AZ 3: 50 parts of the compound represented by the formula (IZ3-1) obtained in example 1Z3,

58 parts of a dispersant (BYK-LPN 6919; manufactured by BYK-Chemie Japan, Ltd.),

resin (B): 93 parts of resin B3 solution, and

solvent (E): propylene glycol monomethyl ether acetate 800 parts

The compound represented by the formula (IZ3-1) obtained in example 1Z3 was dispersed using a bead mill to obtain a colored composition. Next, the following were mixed to obtain colored curable composition 1Z3,

the total amount of the obtained pigment dispersion (the liquid containing the colorant A1Z 3);

400 parts of the obtained coloring composition;

resin (B): 45 parts of resin B1 solution;

polymerizable compound (C): 25 parts of dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kagaku Co., Ltd.);

polymerization initiator (D): 15 parts of N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure (registered trademark) OXE-01; manufactured by BASF corporation);

solvent (E): 86 parts of propylene glycol monomethyl ether acetate; and

leveling agent: 0.12 part of polyether-modified Silicone oil (Toray Silicone SH 8400; manufactured by Dow Corning Toray Co., Ltd.).

[ preparation of colored Pattern ]

A colored curable composition 1Z3 was applied to a 2-inch square glass substrate (EAGLE XG; manufactured by Corning corporation) by a spin coating method, and then prebaked at 100 ℃ for 3 minutes to form a colored curable composition layer. After cooling, the substrate on which the colored curable composition layer was formed and a photomask made of quartz glass were spaced at a distance of 200 μm, and exposed to an exposure apparatus (TME-150 RSK; manufactured by Topcon Corporation) at a rate of 80mJ/cm in an atmospheric atmosphere ²Exposure was carried out with the exposure amount (based on 365 nm). As the photomask, a photomask in which a line-and-space pattern of 100 μm was formed was used. The colored curable composition layer after exposure is mixed with a nonionic surfactant at 25 deg.CThe resultant was immersed in an aqueous solution containing 0.12% surfactant and 0.04% potassium hydroxide for 70 seconds to develop the resist, and then washed with water. The colored curable composition layer was post-baked at 230 ℃ for 30 minutes, whereby a colored pattern was obtained.

[ measurement of phase difference value ]

A colored curable composition 1Z3 was applied to a 2-inch square glass substrate (EAGLE XG; manufactured by Corning corporation) by a spin coating method, and then prebaked at 100 ℃ for 3 minutes to form a colored curable composition layer. After cooling, an exposure machine (TME-150 RSK; manufactured by Topcon Corporation) was used for the colored curable composition layer under an atmospheric atmosphere at 80mJ/cm²Exposure was carried out with the exposure amount (based on 365 nm). The colored curable composition layer after exposure was immersed in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ℃ for 70 seconds, developed, and washed with water. The colored curable composition layer was post-baked at 230 ℃ for 30 minutes, thereby obtaining a colored coating film.

The film thickness of the obtained colored coating film was measured using DEKTAK3 (manufactured by japan vacuum technology corporation). The phase difference value at an inclination angle of 45 ° of the colored coating film was measured using an ellipsometer (M-220 type spectroscopic ellipsometer; manufactured by japan spectro (ltd.)). For the measurement of the retardation value, light having a wavelength of 550nm was used. The results are shown in Table 7Z 3.

Example 102Z3

A colored curable composition 2Z3 was obtained in the same manner as in example 101Z3 except that the compound represented by the formula (IZ3-1) obtained in example 1Z3 was replaced with the compound represented by the formula (IZ3-19) obtained in example 2Z3, and a colored pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z 3.

Example 103Z3

A colored curable composition 3Z3 was obtained in the same manner as in example 101Z3 except that the compound represented by the formula (IZ3-1) obtained in example 1Z3 was replaced with the compound represented by the formula (IZ3-6) obtained in example 3Z3, and a colored pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z 3.

Example 104Z3

A colored curable composition 4Z3 was obtained and a colored pattern was obtained in the same manner as in example 101Z3, except that c.i. pigment green 58 was replaced with c.i. pigment green 7. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z 3.

Example 105Z3

A colored curable composition 5Z3 was obtained in the same manner as in example 101Z3 except that the compound represented by the formula (IZ3-1) obtained in example 1Z3 was replaced with c.i. pigment green 58 and the compound represented by the formula (IZ3-19) obtained in example 2Z3 was replaced with c.i. pigment green 7, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z 3.

Example 106Z3

A colored curable composition 6Z3 was obtained in the same manner as in example 101Z3 except that the compound represented by the formula (IZ3-1) obtained in example 1Z3 was replaced with c.i. pigment green 58 and the compound represented by the formula (IZ3-1) obtained in example 3Z3 was replaced with the compound represented by the formula (IZ3-6) obtained in example 3Z3, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z 3.

Example 107Z3

A colored curable composition 7Z3 was obtained and a colored pattern was obtained in the same manner as in example 101Z3, except that c.i. pigment green 58 was replaced with c.i. pigment green 59. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z 3.

Example 108Z3

A colored curable composition 8Z3 was obtained in the same manner as in example 101Z3 except that the compound represented by the formula (IZ3-1) obtained in example 1Z3 was replaced with c.i. pigment green 58 and the compound represented by the formula (IZ3-19) obtained in example 2Z3 was replaced with c.i. pigment green 59, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z 3.

Example 109Z3

A colored curable composition 9Z3 was obtained in the same manner as in example 101Z3 except that the compound represented by the formula (IZ3-1) obtained in example 1Z3 was replaced with c.i. pigment green 58 and the compound represented by the formula (IZ3-1) obtained in example 3Z3 was replaced with the compound represented by the formula (IZ3-6) obtained in example 3Z 3826, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z 3.

Comparative example 1Z3

A colored curable composition C1Z3 was obtained and a colored pattern was obtained in the same manner as in example 101Z3 except that the compound represented by the formula (IZ3-1) obtained in example 1Z3 was replaced with c.i. pigment yellow 185. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z 3.

Comparative example 2Z3

A colored curable composition C2Z3 was obtained in the same manner as in example 101Z3, except that the c.i. pigment green 58 was replaced with the c.i. pigment green 7, and the compound represented by the formula (IZ3-1) obtained in example 1Z3 was replaced with the c.i. pigment yellow 185, to obtain a colored curable composition C2Z3, and a colored pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z 3.

Comparative example 3Z3

A colored curable composition C3Z3 was obtained in the same manner as in example 101Z3, except that the c.i. pigment green 58 was replaced with the c.i. pigment green 59, and the compound represented by the formula (IZ3-1) obtained in example 1Z3 was replaced with the c.i. pigment yellow 185, to obtain a colored curable composition C3Z3, and a colored pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z 3.

[ Table 7Z3]

TABLE 7Z3

	Film thickness (mum)	Phase difference value (nm)
			Example 101Z3	2.3	4
Example 102Z3	2.3	3
			Example 103Z3	2.3	3
Example 104Z3	2.3	4
			Example 105Z3	2.3	3
Example 106Z3	2.3	3
			Example 107Z3	2.3	4
Example 108Z3	2.3	3
			Example 109Z3	2.3	3
Comparative example 1Z3	2.3	15
			Comparative example 2Z3	2.3	15
Comparative example 3Z3	2.3	15

Example 110Z3

The following substances are mixed together and then,

pigment: 5860 portions of C.I. pigment green,

8.1 parts of acrylic pigment dispersing agent,

Resin (B): 73 parts of resin B5 solution, and

solvent (E): 290 parts of propylene glycol monomethyl ether acetate

The pigment dispersion liquid (liquid containing colorant A1Z 3) was prepared by dispersing the pigment using a bead mill. In addition, the following substances were mixed,

colorant AZ 3: 50 parts of a compound represented by the formula (IZ3-1),

58 parts of a dispersant solution (solid content: 60%),

resin (B): 93 parts of resin B3 solution, and

solvent (E): propylene glycol monomethyl ether acetate 800 parts

The compound represented by formula (IZ3-1) was dispersed using a bead mill to obtain a coloring composition. Next, the following were mixed to obtain a colored curable composition 10Z3,

the total amount of the obtained pigment dispersion (the liquid containing the colorant A1Z 3);

400 parts of the obtained coloring composition;

resin (B): 45 parts of resin B1 solution;

polymerizable compound (C): 25 parts of dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kagaku Co., Ltd.);

polymerization initiator (D): 15 parts of N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure (registered trademark) OXE-01; manufactured by BASF corporation);

Solvent (E): 86 parts of propylene glycol monomethyl ether acetate; and

leveling agent: 0.12 part of polyether-modified Silicone oil (Toray Silicone SH 8400; manufactured by Dow Corning Toray Co., Ltd.).

A colored pattern was produced in the same manner as in example 101Z3 except that a colored curable composition 10Z3 was used instead of the colored curable composition 1Z 3. A colored coating film was obtained in the same manner as in example 101Z3 except that a colored curable composition 10Z3 was used in place of the colored curable composition 1Z3, and the film thickness and the retardation value were measured. The results are shown in Table 8Z 3.

Example 111Z3 to example 113Z3

A colored pattern was obtained in the same manner as in example 110Z3, except that the compound represented by the formula (IZ3-1) was replaced with the colorant shown in the column of "colorant" of table 8Z 3. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 3.

Example 114Z3 to example 117Z3

A colored pattern was obtained in the same manner as in example 110Z3, except that the compound represented by formula (IZ3-1) was replaced with the compound shown in the column of "colorant" in table 8Z3, and c.i. pigment green 58 was replaced with c.i. pigment green 7. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 3.

Example 118Z3 to example 121Z3

A colored pattern was obtained in the same manner as in example 110Z3, except that the compound represented by formula (IZ3-1) was replaced with the compound shown in the column of "colorant" in table 8Z3, and c.i. pigment green 58 was replaced with c.i. pigment green 59. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 3.

[ Table 8Z3]

TABLE 8Z3

	Coloring agent	Film thickness (mum)	Phase difference value (nm)
				Example 110Z3	A compound represented by the formula (IZ3-1)	2.3	4
Example 111Z3	A compound represented by the formula (IZ3-19)	2.3	3
				Example 112Z3	A compound represented by the formula (IZ3-6)	2.3	3
Example 113Z3	A compound represented by the formula (IZ3-8)	2.3	3
				Example 114Z3	A compound represented by the formula (IZ3-1)	2.3	4
Example 115Z3	A compound represented by the formula (IZ3-19)	2.3	3
				Example 116Z3	A compound represented by the formula (IZ3-6)	2.3	3
Example 117Z3	A compound represented by the formula (IZ3-8)	2.3	3
				Example 118Z3	A compound represented by the formula (IZ3-1)	2.3	4
Example 119Z3	A compound represented by the formula (IZ3-19)	2.3	3
				Example 120Z3	A compound represented by the formula (IZ3-6)	2.3	3
Example 121Z3	A compound represented by the formula (IZ3-8)	2.3	3

In example Z3, it is understood from the above results that the retardation value of the colored coating film formed from the colored curable composition containing the compound of the present invention is smaller than that of the colored coating film formed from the colored curable composition containing c.i. pigment yellow 185.

Example Z4

Example 1Z4

20.5 parts of phthalonitrile (manufactured by Tokyo chemical Co., Ltd.) and 171 parts of methanol were mixed. While keeping the temperature at 5 ℃ for 1 hour and 20 minutes, a mixture of 23.9 parts of 28% sodium methoxide methanol solution (manufactured by Wako pure chemical industries, Ltd.) and 215 parts of methanol was added dropwise to the obtained mixture.

The resulting mixture was stirred at 2-6 ℃ for 7 hours.

To the obtained mixture were added acetic acid (15.6 parts), 2-cyano-N, N-dimethylacetamide (17.9 parts, manufactured by Tokyo chemical industry Co., Ltd.) and methanol (118 parts), and the mixture was stirred at 40 ℃ for 15 hours and at 65 ℃ for 7 hours. To the obtained mixture were added 7.82 parts of acetic acid, 8.97 parts of 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo chemical industry Co., Ltd.) and 80 parts of methanol, and the mixture was stirred at 40 ℃ for 17 hours and at 65 ℃ for 4 hours. To the obtained mixture were added 12.6 parts of acetic acid, 14.3 parts of 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo chemical industry Co., Ltd.) and 104 parts of methanol, and the mixture was stirred at 40 ℃ for 16 hours and at 60 ℃ for 9 hours. To the obtained mixture were added acetic acid 6.32 parts, 2-cyano-N, N-dimethylacetamide (manufactured by tokyo chemical industry co., ltd.) 7.19 parts, and methanol 40 parts, and the mixture was stirred at 60 ℃ for 3 hours and at room temperature for 59 hours. To the obtained mixture were added acetic acid 15.7 parts, barbituric acid (manufactured by tokyo chemical industry corporation) 20.5 parts, methanol 16 parts, and water 744 parts, and the mixture was stirred at 60 ℃ for 24 hours. The resulting mixture was filtered, and the residue was washed with 50% aqueous methanol. The obtained residue was dried under reduced pressure at 60 ℃ to obtain 43.1 parts of a compound represented by the formula (IZ 4-1).

Identification of Compound represented by the formula (IZ4-1)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺352

Exact molecular weight (Exact masses): 351

Example 2Z4

The procedure of example 1Z4 was repeated except for replacing 2-cyano-N, N-dimethylacetamide (manufactured by tokyo chemical industry co.) with 2-cyano-N, N-diethylacetamide (manufactured by tokyo chemical industry co.), to obtain a compound represented by the formula (IZ 4-2).

Identification of Compound represented by the formula (IZ4-2)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺380

Exact molecular weight (Exact masses): 379

Example 3Z4

The procedure of example 1Z4 was repeated except for replacing phthalonitrile (manufactured by tokyo chemical industry co.) with 4-nitrophthalonitrile (manufactured by tokyo chemical industry co.) to obtain compounds represented by the formula (IZ 4-79).

Identification of Compound represented by the formula (IZ4-79)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺397

Exact molecular weight (Exact masses): 396

Example 4Z4

A compound represented by formula (IZ4-80) was obtained in the same manner as in example 1Z4, except that phthalonitrile (manufactured by tokyo chemical industry co.) was replaced with 4-nitrophthalonitrile (manufactured by tokyo chemical industry co.) and 2-cyano-N, N-dimethylacetamide (manufactured by tokyo chemical industry co.) was replaced with 2-cyano-N, N-diethylacetamide (manufactured by tokyo chemical industry co.).

Identification of Compound represented by the formula (IZ4-80)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺425

Exact molecular weight (Exact masses): 424

Example 5Z4

A compound represented by the formula (IZ4-40) was obtained in the same manner as in example 1Z4, except that phthalonitrile (manufactured by Tokyo chemical industry Co., Ltd.) was replaced with 4-tert-butylphthalonitrile (manufactured by Tokyo chemical industry Co., Ltd.).

Identification of Compound represented by the formula (IZ4-40)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺408

Exact molecular weight (Exact masses): 407

Example 6Z4

The procedure of example 1Z4 was repeated except for replacing phthalonitrile (manufactured by tokyo chemical industry co.) with 4-tert-butylphthalonitrile (manufactured by tokyo chemical industry co.) and replacing 2-cyano-N, N-dimethylacetamide (manufactured by tokyo chemical industry co.) with 2-cyano-N, N-diethylacetamide (manufactured by tokyo chemical industry co.) to obtain a compound represented by formula (IZ 4-41).

Identification of Compound represented by the formula (IZ4-41)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺436

Exact molecular weight (Exact masses): 435

Example 7Z4XXX (651)

20.5 parts of phthalonitrile (manufactured by Tokyo chemical Co., Ltd.) and 171 parts of methanol were mixed.

While maintaining the temperature at 2 to 5 ℃, a mixture of 23.9 parts of 28% sodium methoxide methanol solution (manufactured by Wako pure chemical industries, Ltd.) and 215 parts of methanol was added dropwise to the obtained mixture over 1 hour and 20 minutes. The resulting mixture was stirred at 2-6 ℃ for 7 hours. To the obtained mixture were added acetic acid 15.6 parts, 2-cyano-N, N-dimethylacetamide (manufactured by tokyo chemical industry co.) 17.9 parts, and methanol 46.9 parts. Further, up to this point in time, a total of 71 parts of methanol was added in addition to the above-mentioned methanol. The resulting mixture was stirred at 40 ℃ for 15 hours and at 65 ℃ for 7 hours. To the obtained mixture were added 7.82 parts of acetic acid, 8.97 parts of 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo chemical industry Co., Ltd.) and 80 parts of methanol, and the mixture was stirred at 40 ℃ for 17 hours and at 65 ℃ for 4 hours. To the obtained mixture were added 12.6 parts of acetic acid, 14.3 parts of 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo chemical industry Co., Ltd.) and 104 parts of methanol, and the mixture was stirred at 40 ℃ for 16 hours and at 60 ℃ for 9 hours. To the obtained mixture were added acetic acid 6.32 parts, 2-cyano-N, N-dimethylacetamide (manufactured by tokyo chemical industry co., ltd.) 7.19 parts, and methanol 40 parts, and the mixture was stirred at 60 ℃ for 3 hours and at room temperature for 59 hours. To the obtained mixture were added acetic acid 15.7 parts, barbituric acid (manufactured by tokyo chemical industry co., ltd.) 20.5 parts, methanol 16 parts, and water 744 parts, and the mixture was stirred at 60 ℃ for 9 days.

The resulting mixture was filtered, and the residue was washed with 50% aqueous methanol.

The obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ 4-1).

Identification of Compound represented by the formula (IZ4-1)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺352

Exact molecular weight (Exact masses): 351

Example 8Z4XXX

10.0 parts of phthalonitrile (manufactured by Tokyo chemical Co., Ltd.) and 83 parts of methanol were mixed.

To the obtained mixture, a mixture of 11.7 parts of 28% sodium methoxide methanol solution (manufactured by Wako pure chemical industries, Ltd.) and 105 parts of methanol was added dropwise over 1 hour and 30 minutes while maintaining the temperature at 2 to 5 ℃. The resulting mixture was stirred at 2-6 ℃ for 7 hours. To the obtained mixture were added 7.62 parts of acetic acid, 10.9 parts of 2-cyano-N, N-diethylacetamide (manufactured by tokyo chemical industry co., ltd.) and 140 parts of methanol. In addition, up to this point, a total of 35 parts of methanol was added in addition to the above-mentioned methanol.

The resulting mixture was stirred at 65 ℃ for 3 days. To the obtained mixture were added 3.82 parts of acetic acid and 5.48 parts of 2-cyano-N, N-diethylacetamide (manufactured by Tokyo Kasei Kogyo Co., Ltd.), and the mixture was stirred at 65 ℃ for 3 days. To the obtained mixture were added 7.65 parts of acetic acid, 10.0 parts of barbituric acid (manufactured by Tokyo chemical industry Co., Ltd.) and 363 parts of water, and the mixture was stirred at 65 ℃ for 9 days. The solvent of the resulting mixture was distilled off by a rotary evaporator, and the obtained residue was purified by column chromatography in the same manner as in example 1Z4 to obtain a compound represented by the formula (IZ 4-2).

Identification of Compound represented by the formula (IZ4-2)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺380

Exact molecular weight (Exact masses): 379

Example 9Z4XXX (529)

2.56 parts of 4-nitrophthalonitrile (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 22 parts of methanol were mixed. To the obtained mixture was added 2.96 parts of 28% sodium methoxide methanol solution (manufactured by Wako pure chemical industries, Ltd.) while keeping the temperature at 5 ℃ or lower. The resulting mixture was stirred for 3 hours while being kept at 5 ℃ or lower. While the resulting mixture was kept at 5 ℃ or lower, 1.84 parts of 2-cyano-N, N-dimethylacetamide (manufactured by tokyo chemical industry) and 1.90 parts of acetic acid were added. The resulting mixture was stirred at 40 ℃ for 1 hour and at 65 ℃ for 1 hour. To the obtained mixture, 2.09 parts of barbituric acid (manufactured by tokyo chemical industry Co., Ltd.), 2.48 parts of acetic acid and 41 parts of water were added. In addition, a total of 24 parts of methanol was added up to this time point, in addition to the above-mentioned methanol. The resulting mixture was stirred at 65 ℃ for 15 hours. The solvent of the resulting mixture was distilled off by a rotary evaporator, and then the resulting residue was purified by column chromatography to obtain a compound represented by the formula (IZ 4-79).

Identification of Compound represented by the formula (IZ4-79)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺397

Exact molecular weight (Exact masses): 396

Example 10Z4XXX

10.0 parts of 4-nitrophthalonitrile (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 149 parts of methanol were mixed. While keeping the temperature at 2 to 6 ℃, 5.86 parts of 28% sodium methoxide methanol solution (manufactured by Wako pure chemical industries, Ltd.) was added dropwise to the obtained mixture over 20 minutes. The resulting mixture was stirred for 5 hours while being kept at 5 ℃ or lower. While the resulting mixture was kept at 5 ℃ or lower, 5.79 parts of acetic acid, 8.10 parts of 2-cyano-N, N-diethylacetamide (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 74 parts of methanol were added. The resulting mixture was stirred at 65 ℃ for 3 days. To the obtained mixture were added 2.88 parts of acetic acid and 4.05 parts of 2-cyano-N, N-diethylacetamide (manufactured by tokyo chemical industry co.). The resulting mixture was stirred at 65 ℃ for 3 days. In addition, up to this point in time, a total of 140 parts of methanol was added in addition to the above-mentioned methanol. To the obtained mixture were added 24.0 parts of acetic acid, 15.3 parts of barbituric acid (manufactured by Tokyo chemical industry Co., Ltd.) and 363 parts of water, and the mixture was stirred at 65 ℃ for 9 days. The solvent of the resulting mixture was distilled off by a rotary evaporator, and then the resulting residue was purified by column chromatography to obtain a compound represented by the formula (IZ 4-80).

Identification of Compound represented by the formula (IZ4-80)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺425

Exact molecular weight (Exact masses): 424

Example 11Z4XXX

10.0 parts of 4-tert-butyl phthalonitrile (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 84 parts of methanol were mixed. While keeping the temperature at 5 ℃ or lower, a mixture of 8.15 parts of 28% sodium methoxide methanol solution (manufactured by Wako pure chemical industries, Ltd.) and 73 parts of methanol was added dropwise to the obtained mixture over 1 hour. The resulting mixture was stirred at 5-20 ℃ for 2 days. To the obtained mixture, 5.42 parts of acetic acid and 6.09 parts of 2-cyano-N, N-dimethylacetamide (manufactured by tokyo chemical industry co.) were added at 10 to 20 ℃. The resulting mixture was stirred at 65 ℃ for 3 days. To the obtained mixture were added 2.69 parts of acetic acid and 3.04 parts of 2-cyano-N, N-dimethylacetamide (manufactured by tokyo chemical industry co., ltd.) and the mixture was stirred at 65 ℃ for 3 days. In addition, up to this point in time, a total of 206 parts of methanol were added in addition to the above-mentioned methanol. To the obtained mixture were added 5.36 parts of acetic acid, 7.25 parts of barbituric acid (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 363 parts of water, and the mixture was stirred at 65 ℃ for 9 days. The solvent of the resulting mixture was distilled off by a rotary evaporator, and then the resulting residue was purified by column chromatography to obtain a compound represented by the formula (IZ 4-40).

Identification of Compound represented by the formula (IZ4-40)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺408

Exact molecular weight (Exact masses): 407

Example 12Z4XXX

10.0 parts of 4-tert-butyl phthalonitrile (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 84 parts of methanol were mixed. While keeping the temperature at 5 ℃ or lower, a mixture of 8.15 parts of 28% sodium methoxide methanol solution (manufactured by Wako pure chemical industries, Ltd.) and 73 parts of methanol was added dropwise to the obtained mixture over 1 hour. The resulting mixture was stirred at 5-20 ℃ for 2 days. To the obtained mixture, 5.42 parts of acetic acid and 7.61 parts of 2-cyano-N, N-diethylacetamide (manufactured by tokyo chemical industries, ltd.) were added at 10 to 20 ℃. The resulting mixture was stirred at 65 ℃ for 3 days. To the obtained mixture were added 2.69 parts of acetic acid and 3.80 parts of 2-cyano-N, N-diethylacetamide (manufactured by Tokyo Kasei Kogyo Co., Ltd.), and the mixture was stirred at 65 ℃ for 3 days. In addition, up to this point in time, a total of 206 parts of methanol were added in addition to the above-mentioned methanol. To the obtained mixture were added 5.36 parts of acetic acid, 7.25 parts of barbituric acid (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 363 parts of water, and the mixture was stirred at 65 ℃ for 9 days. The solvent of the resulting mixture was distilled off by a rotary evaporator, and then the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ 4-41).

Identification of Compound represented by the formula (IZ4-41)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺436

Exact molecular weight (Exact masses): 435

Example 13Z4

5.0 parts of 4, 5-dichlorophthalonitrile and 62 parts of methanol were mixed. While the mixture was kept at 5 ℃ or lower, a 25% sodium methoxide methanol solution containing sodium methoxide in an amount of 0.5 times the molar amount of 5.0 parts by mole of 4, 5-dichlorophthalonitrile was added.

The mixture was stirred at 5 ℃ or below for 5 hours. To the mixture, while keeping the temperature at 5 ℃ or lower, 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo chemical industry Co., Ltd.) having a molar amount 1.5 times that of 5.0 parts of 4, 5-dichlorophthalonitrile and 6.1 parts of acetic acid were added. The mixture was stirred at 65 ℃ for 3 days. This mixture was mixed with 4.2 parts of acetic acid, 5.2 parts of barbituric acid, 500 parts of methanol and 562 parts of water, and stirred at 65 ℃ for 9 days. The solvent was distilled off from the mixture by a rotary evaporator, and the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ 4-321).

Identification of Compound represented by the formula (IZ4-321)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H ]⁺420

Exact molecular weight (Exact masses): 419

Example 101Z4

The following substances are mixed together and then,

pigment: 5860 portions of C.I. pigment green,

8.1 parts of acrylic pigment dispersing agent,

resin (B): 73 parts of resin B5 solution, and

solvent (E): 290 parts of propylene glycol monomethyl ether acetate

The pigment dispersion liquid (liquid containing colorant A1Z 4) was prepared by dispersing the pigment using a bead mill. In addition, the following substances were mixed,

colorant AZ 4: 50 parts of the compound represented by the formula (IZ4-1) obtained in example 1Z4,

58 parts of a dispersant (BYK-LPN 6919; manufactured by BYK-Chemie Japan, Ltd.),

resin (B): 93 parts of resin B3 solution, and

solvent (E): propylene glycol monomethyl ether acetate 800 parts

The compound represented by the formula (IZ4-1) obtained in example 1Z4 was dispersed using a bead mill to obtain a colored composition. Next, the following were mixed to obtain colored curable composition 1Z4,

the total amount of the obtained pigment dispersion (the liquid containing the colorant A1Z 4);

400 parts of the obtained coloring composition;

resin (B): 45 parts of resin B1 solution;

Polymerizable compound (C): 25 parts of dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kagaku Co., Ltd.);

polymerization initiator (D): 15 parts of N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure (registered trademark) OXE-01; manufactured by BASF corporation);

solvent (E): 86 parts of propylene glycol monomethyl ether acetate; and

leveling agent: 0.12 part of polyether-modified Silicone oil (Toray Silicone SH 8400; manufactured by Dow Corning Toray Co., Ltd.).

[ preparation of colored Pattern ]

A colored curable composition 1Z4 was applied to a 2-inch square glass substrate (EAGLE XG; manufactured by Corning corporation) by a spin coating method, and then prebaked at 100 ℃ for 3 minutes to form a colored curable composition layer. After cooling, the substrate on which the colored curable composition layer was formed and a photomask made of quartz glass were spaced at a distance of 200 μm, and exposed to an exposure apparatus (TME-150 RSK; manufactured by Topcon Corporation) at a rate of 80mJ/cm in an atmospheric atmosphere²Exposure was carried out with the exposure amount (based on 365 nm). As the photomask, a photomask in which a line-and-space pattern of 100 μm was formed was used. The colored curable composition layer after exposure was immersed in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ℃ for 70 seconds, developed, and washed with water. The colored curable composition layer was post-baked at 230 ℃ for 30 minutes, whereby a colored pattern was obtained.

[ measurement of phase difference value ]

A colored curable composition 1Z4 was applied to a 2-inch square glass substrate (EAGLE XG; manufactured by Corning corporation) by a spin coating method, and then prebaked at 100 ℃ for 3 minutes to form a colored curable composition layer. After cooling, an exposure machine (TME-150 RSK; manufactured by Topcon Corporation) was used for the colored curable composition layer under an atmospheric atmosphere at 80mJ/cm²Exposure was carried out with the exposure amount (based on 365 nm). The colored curable composition layer after exposure was immersed in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ℃ for 70 seconds, developed, and washed with water. The colored curable composition layer was post-baked at 230 ℃ for 30 minutes, thereby obtaining a coloringAnd (6) coating.

The film thickness of the obtained colored coating film was measured using DEKTAK3 (manufactured by japan vacuum technology corporation).

The phase difference value at an inclination angle of 45 ° of the colored coating film was measured using an ellipsometer (M-220 type spectroscopic ellipsometer; manufactured by japan spectro (ltd.)). For the measurement of the retardation value, light having a wavelength of 550nm was used. The results are shown in Table 9Z 4.

Example 102Z4

A colored curable composition 2Z4 was obtained in the same manner as in example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in example 1Z4 was replaced with the compound represented by the formula (IZ4-2) obtained in example 2Z4, and a colored pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 9Z 4.

Example 103Z4

A colored curable composition 3Z4 was obtained in the same manner as in example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in example 1Z4 was replaced with the compound represented by the formula (IZ4-79) obtained in example 3Z4, and a colored pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 9Z 4.

Example 104Z4

A colored curable composition 4Z4 was obtained in the same manner as in example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in example 1Z4 was replaced with the compound represented by the formula (IZ4-80) obtained in example 4Z4, and a colored pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 9Z 4.

Example 105Z4

A colored curable composition 5Z4 was obtained in the same manner as in example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in example 1Z4 was replaced with the compound represented by the formula (IZ4-40) obtained in example 5Z4, and a colored pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 9Z 4.

Example 106Z4

A colored curable composition 6Z4 was obtained in the same manner as in example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in example 1Z4 was replaced with the compound represented by the formula (IZ4-41) obtained in example 6Z4, and a colored pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 9Z 4.

Example 107Z4

A colored curable composition 7Z4 was obtained and a colored pattern was obtained in the same manner as in example 101Z4, except that c.i. pigment green 58 was replaced with c.i. pigment green 7. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 9Z 4.

Example 108Z4

A colored curable composition 8Z4 was obtained in the same manner as in example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in example 1Z4 was replaced with c.i. pigment green 58 and the compound represented by the formula (IZ4-1) obtained in example 2Z4 was replaced with the compound represented by the formula (IZ4-2) obtained in example 2Z4, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 9Z 4.

Example 109Z4

A colored curable composition 9Z4 was obtained in the same manner as in example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in example 1Z4 was replaced with c.i. pigment green 58 and the compound represented by the formula (IZ4-79) obtained in example 3Z4 was replaced with c.i. pigment green 7, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 9Z 4.

Example 110Z4

A colored curable composition 10Z4 was obtained in the same manner as in example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in example 1Z4 was replaced with c.i. pigment green 58 and the compound represented by the formula (IZ4-1) obtained in example 4Z4 was replaced with the compound represented by the formula (IZ4-80) obtained in example 4Z4, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 9Z 4.

Example 111Z4

A colored curable composition 11Z4 was obtained in the same manner as in example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in example 1Z4 was replaced with c.i. pigment green 58 and the compound represented by the formula (IZ4-40) obtained in example 5Z4 was replaced with c.i. pigment green 7, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 9Z 4.

Example 112Z4

A colored curable composition 12Z4 was obtained in the same manner as in example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in example 1Z4 was replaced with c.i. pigment green 58 and the compound represented by the formula (IZ4-41) obtained in example 6Z4 was replaced with c.i. pigment green 7, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 9Z 4.

Example 113Z4

A colored curable composition 13Z4 was obtained in the same manner as in example 101Z4 except that c.i. pigment green 58 was replaced with c.i. pigment green 59, and a colored pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 9Z 4.

Example 114Z4

A colored curable composition 14Z4 was obtained in the same manner as in example 101Z4 except that c.i. pigment green 58 was replaced with c.i. pigment green 59 and the compound represented by the formula (IZ4-1) obtained in example 1Z4 was replaced with the compound represented by the formula (IZ4-2) obtained in example 2Z4, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 9Z 4.

Example 115Z4

A colored curable composition 15Z4 was obtained in the same manner as in example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in example 1Z4 was replaced with c.i. pigment green 58 and the compound represented by the formula (IZ4-79) obtained in example 3Z4 was replaced with c.i. pigment green 59, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 9Z 4.

Example 116Z4

A colored curable composition 16Z4 was obtained in the same manner as in example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in example 1Z4 was replaced with c.i. pigment green 58 and the compound represented by the formula (IZ4-80) obtained in example 4Z4 was replaced with c.i. pigment green 59, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 9Z 4.

Example 117Z4

A colored curable composition 17Z4 was obtained in the same manner as in example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in example 1Z4 was replaced with c.i. pigment green 58 and the compound represented by the formula (IZ4-40) obtained in example 5Z4 was replaced with c.i. pigment green 59, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 9Z 4.

Example 118Z4

A colored curable composition 18Z4 was obtained in the same manner as in example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in example 1Z4 was replaced with c.i. pigment green 58 and the compound represented by the formula (IZ4-41) obtained in example 6Z4 was replaced with c.i. pigment green 59, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 9Z 4.

Comparative example 1Z4

A colored curable composition C1Z4 was obtained and a colored pattern was obtained in the same manner as in example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in example 1Z4 was replaced with c.i. pigment yellow 185. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 9Z 4.

Comparative example 2Z4

A colored curable composition C2Z4 was obtained in the same manner as in example 101Z4, except that the c.i. pigment green 58 was replaced with the c.i. pigment green 7, and the compound represented by the formula (IZ4-1) obtained in example 1Z4 was replaced with the c.i. pigment yellow 185, to obtain a colored curable composition C2Z4, and a colored pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 9Z 4.

Comparative example 3Z4

A colored curable composition C3Z4 was obtained in the same manner as in example 101Z4, except that the c.i. pigment green 58 was replaced with the c.i. pigment green 59, and the compound represented by the formula (IZ4-1) obtained in example 1Z4 was replaced with the c.i. pigment yellow 185, to obtain a colored curable composition C3Z4, and a colored pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 9Z 4.

[ Table 9Z4]

TABLE 9Z4

	Film thickness (mum)	Phase difference value (nm)
			Example 101Z4	2.3	4
Example 102Z4	2.3	4
			Example 103Z4	2.3	3
Example 104Z4	2.3	3
			Example 105Z4	2.3	3
Example 106Z4	2.3	3
			Example 107Z4	2.3	4
Example 108Z4	2.3	4
			Example 109Z4	2.3	3
Example 110Z4	2.3	3
			Example 111Z4	2.3	3
Example 112Z4	2.3	3
			Example 113Z4	2.3	4
Example 114Z4	2.3	4
			Example 115Z4	2.3	3
Example 116Z4	2.3	3
			Example 117Z4	2.3	3
Example 118Z4	2.3	3
			Comparative example 1Z4	2.3	15
Comparative example 2Z4	2.3	15
			Comparative example 3Z4	2.3	15

Example 119Z4

The following substances are mixed together and then,

pigment: 5860 portions of C.I. pigment green,

8.1 parts of acrylic pigment dispersing agent,

resin (B): 73 parts of resin B5 solution, and

solvent (E): 290 parts of propylene glycol monomethyl ether acetate

The pigment dispersion liquid (liquid containing colorant A1Z 4) was prepared by dispersing the pigment using a bead mill. In addition, the following substances were mixed,

colorant AZ 4: 50 parts of a compound represented by the formula (IZ4-1),

58 parts of a dispersant solution (solid content: 60%),

resin (B): 93 parts of resin B3 solution, and

solvent (E): propylene glycol monomethyl ether acetate 800 parts

The compound represented by formula (IZ4-1) was dispersed using a bead mill to obtain a coloring composition. Next, the following were mixed to obtain a colored curable composition 19Z4,

The total amount of the obtained pigment dispersion (the liquid containing the colorant A1Z 4);

400 parts of the obtained coloring composition;

resin (B): 45 parts of resin B1 solution;

polymerizable compound (C): 25 parts of dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kagaku Co., Ltd.);

polymerization initiator (D): 15 parts of N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure (registered trademark) OXE-01; manufactured by BASF corporation);

solvent (E): 86 parts of propylene glycol monomethyl ether acetate; and

leveling agent: 0.12 part of polyether-modified Silicone oil (Toray Silicone SH 8400; manufactured by Dow Corning Toray Co., Ltd.).

A colored pattern was produced in the same manner as in example 101Z4 except that a colored curable composition 19Z4 was used instead of the colored curable composition 1Z 4. A colored coating film was obtained in the same manner as in example 101Z4 except that a colored curable composition 19Z4 was used in place of the colored curable composition 1Z4, and the film thickness and the retardation value were measured. The results are shown in Table 10Z 4.

Example 120Z4 to example 125Z4

A colored pattern was obtained in the same manner as in example 119Z4 except that the compound represented by the formula (IZ4-1) was replaced with the colorant shown in the column of "colorant" in table 10Z 4. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 10Z 4.

Example 126Z4 to example 132Z4

A colored pattern was obtained in the same manner as in example 119Z4 except that the compound represented by the formula (IZ4-1) was replaced with the compound shown in the column of "colorant" in table 10Z4 and the c.i. pigment green 58 was replaced with c.i. pigment green 7. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 10Z 4.

Example 133Z4 to example 139Z4

A colored pattern was obtained in the same manner as in example 119Z4 except that the compound represented by the formula (IZ4-1) was replaced with the compound shown in the column of "colorant" in table 10Z4 and the c.i. pigment green 58 was replaced with the c.i. pigment green 59. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 10Z 4.

[ Table 10Z4]

TABLE 10Z4

	Coloring agent	Film thickness (mum)	Phase difference value (nm)
				Example 119Z4	A compound represented by the formula (IZ4-1)	2.3	4
Example 120Z4	A compound represented by the formula (IZ4-2)	2.3	4
				Example 121Z4	A compound represented by the formula (IZ4-79)	2.3	3
Example 122Z4	A compound represented by the formula (IZ4-80)	2.3	3
				Example 123Z4	A compound represented by the formula (IZ4-40)	2.3	3
Example 124Z4	A compound represented by the formula (IZ4-41)	2.3	3
				Example 125Z4	A compound represented by the formula (IZ4-321)	2.3	3
Example 126Z4	A compound represented by the formula (IZ4-1)	2.3	4
				Example 127Z4	A compound represented by the formula (IZ4-2)	2.3	4
Example 128Z4	A compound represented by the formula (IZ4-79)	2.3	3
				Example 129Z4	A compound represented by the formula (IZ4-80)	2.3	3
Example 130Z4	A compound represented by the formula (IZ4-40)	2.3	3
				Example 131Z4	A compound represented by the formula (IZ4-41)	2.3	3
Example 132Z4	A compound represented by the formula (IZ4-321)	2.3	3
				Example 133Z4	A compound represented by the formula (IZ4-1)	2.3	4
Example 134Z4	A compound represented by the formula (IZ4-2)	2.3	4
				Example 135Z4	A compound represented by the formula (IZ4-79)	2.3	3
Example 136Z4	A compound represented by the formula (IZ4-80)	2.3	3
				Example 137Z4	A compound represented by the formula (IZ4-40)	2.3	3
Example 138Z4	A compound represented by the formula (IZ4-41)	2.3	3
				Example 139Z4	A compound represented by the formula (IZ4-321)	2.3	3

In example Z4, it is understood from the above results that the retardation value of the colored coating film formed from the colored curable composition containing the compound of the present invention is smaller than that of the colored coating film formed from the colored curable composition containing c.i. pigment yellow 185.

Example Z5

Example 1Z5

25.2 parts of 4-tert-butylphthalonitrile (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 212 parts of methanol were mixed. While keeping the temperature at 5 ℃, a mixture of 20.5 parts of 28% sodium methoxide methanol solution (manufactured by Wako pure chemical industries, Ltd.) and 184 parts of methanol was added dropwise to the obtained mixture over 1 hour. The resulting mixture was stirred at 5-20 ℃ for 2 days.

To the resulting mixture, 13.7 parts of acetic acid and 13.5 parts of 2-cyano-N-methylacetamide were added at 10 to 20 ℃. The obtained mixture was stirred at 10 to 20 ℃ for 5 hours and then at 40 ℃ for 16 hours. To the resulting mixture, 6.79 parts of acetic acid, 6.75 parts of 2-cyano-N-methylacetamide and 201 parts of methanol were added, and the mixture was stirred at 40 ℃ for 6 hours and at 50 ℃ for 65 hours. To the obtained mixture were added 13.5 parts of acetic acid, 18.3 parts of barbituric acid (manufactured by Tokyo chemical industry Co., Ltd.) and 604 parts of water, and the mixture was stirred at 40 ℃ for 52 hours. The resulting mixture was filtered, and the residue was washed with 50% aqueous methanol. The obtained residue was dried under reduced pressure at 60 ℃ to obtain 49.9 parts of a compound represented by the formula (IZ 5-1).

Identification of Compound represented by the formula (IZ5-1)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺394

Exact molecular weight (Exact masses): 393

Example 2Z5

The procedure of example 1Z5 was repeated except for replacing 2-cyano-N-methylacetamide with 2-cyanoacetanilide (manufactured by tokyo chemical industry co., ltd.) to obtain a compound represented by the formula (IZ 5-3).

Identification of Compound represented by the formula (IZ5-3)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺456

Exact molecular weight (Exact masses): 455

Example 3Z5

A compound represented by the formula (IZ5-23) was obtained in the same manner as in example 1Z5, except that 4-t-butylphthalonitrile (manufactured by Tokyo chemical industry Co., Ltd.) was replaced with 4-nitrophthalonitrile (manufactured by Tokyo chemical industry Co., Ltd.).

Identification of Compound represented by the formula (IZ5-23)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺383

Exact molecular weight (Exact masses): 382

Example 4Z5

The procedure of example 1Z5 was repeated except for replacing 4-tert-butylphthalonitrile (manufactured by tokyo chemical industry co.) with 4-nitrophthalonitrile (manufactured by tokyo chemical industry co.) and replacing 2-cyano-N-methylacetamide with 2-cyanoacetanilide (manufactured by tokyo chemical industry co.) to obtain a compound represented by formula (IZ 5-25).

Identification of Compound represented by the formula (IZ5-25)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺445

Exact molecular weight (Exact masses): 444

Example 5Z5XXX (653)

25.2 parts of 4-tert-butylphthalonitrile (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 212 parts of methanol were mixed. While keeping the temperature at 5 ℃ or lower, a mixture of 20.5 parts of 28% sodium methoxide methanol solution (manufactured by Wako pure chemical industries, Ltd.) and 184 parts of methanol was added dropwise to the obtained mixture over 1 hour. The resulting mixture was stirred at 5-20 ℃ for 2 days. To the resulting mixture, 13.7 parts of acetic acid and 13.5 parts of 2-cyano-N-methylacetamide were added at 10 to 20 ℃. The obtained mixture was stirred at 10 to 20 ℃ for 5 hours and then at 40 ℃ for 16 hours. To the resulting mixture, 6.79 parts of acetic acid and 6.75 parts of 2-cyano-N-methylacetamide were added, and stirring was performed at 40 ℃ for 6 hours and at 50 ℃ for 65 hours. In addition, a total of 201 parts of methanol was added up to this time point, in addition to the above-mentioned methanol.

To the resulting mixture were added 13.5 parts of acetic acid, 18.3 parts of barbituric acid (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 604 parts of water, and the mixture was stirred at 40 ℃ for 53 hours. The resulting mixture was filtered, and the residue was washed with 50% aqueous methanol. The obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ 5-1).

Identification of Compound represented by the formula (IZ5-1)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺394

Exact molecular weight (Exact masses): 393

Example 6Z5XXX

10.0 parts of 4-tert-butyl phthalonitrile (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 84 parts of methanol were mixed. While keeping the temperature at 5 ℃ or lower, a mixture of 8.15 parts of 28% sodium methoxide methanol solution (manufactured by Wako pure chemical industries, Ltd.) and 73 parts of methanol was added dropwise to the obtained mixture over 1 hour. The resulting mixture was stirred at 5-20 ℃ for 2 days.

To the obtained mixture, 5.42 parts of acetic acid and 8.69 parts of 2-cyanoacetanilide (manufactured by Tokyo Kasei Kogyo Co., Ltd.) were added at 10 to 20 ℃. The resulting mixture was stirred at 65 ℃ for 3 days.

To the resulting mixture were added 2.69 parts of acetic acid and 4.35 parts of 2-cyanoacetanilide (manufactured by Tokyo chemical industry Co., Ltd.), and the mixture was stirred at 65 ℃ for 3 days. In addition, up to this point in time, a total of 206 parts of methanol were added in addition to the above-mentioned methanol. To the obtained mixture were added 5.36 parts of acetic acid, 7.25 parts of barbituric acid (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 363 parts of water, and the mixture was stirred at 65 ℃ for 9 days.

The solvent of the resulting mixture was distilled off by a rotary evaporator, and then the resulting residue was purified by column chromatography to obtain a compound represented by the formula (IZ 5-3).

Identification of Compound represented by the formula (IZ5-3)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺456

Exact molecular weight (Exact masses): 455

Example 7Z5XXX (654)

25.2 parts of 4-nitrophthalonitrile (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 376 parts of methanol were mixed together. 14.8 parts of 28% sodium methoxide methanol solution (manufactured by Wako pure chemical industries, Ltd.) was added dropwise to the obtained mixture over 20 minutes while keeping the temperature at 2 to 6 ℃. The resulting mixture was stirred for 5 hours while being kept at 5 ℃ or lower.

While the resulting mixture was kept at 5 ℃ or lower, 9.31 parts of acetic acid and 14.4 parts of 2-cyano-N-methylacetamide were added. The resulting mixture was stirred at room temperature for 14 hours and at 40 ℃ for 29 hours.

To the resulting mixture, 1.50 parts of acetic acid and 2.24 parts of 2-cyano-N-methylacetamide were added. The resulting mixture was stirred at 40 ℃ for 19 hours.

To the resulting mixture, 4.83 parts of acetic acid and 7.36 parts of 2-cyano-N-methylacetamide were added. The resulting mixture was stirred at 40 ℃ for 79 hours.

To the resulting mixture, 4.60 parts of acetic acid and 7.30 parts of 2-cyano-N-methylacetamide were added. The resulting mixture was stirred at 40 ℃ for 24 hours. In addition, a total of 259 parts of methanol were added to the reaction mixture up to this point in time, in addition to the above-mentioned methanol. To the resulting mixture were added 12.1 parts of acetic acid, 19.1 parts of barbituric acid (manufactured by Tokyo chemical industry Co., Ltd.), 635 parts of water, 14.2 parts of methanol and 20 parts of 50% methanol aqueous solution, followed by stirring at 40 ℃ for 21 hours and at 63 ℃ for 5 hours.

To the resulting mixture was added 23.4 parts of acetic acid, and the mixture was stirred at 63 ℃ for 18 hours. To the resulting mixture were added 24.9 parts of acetic acid, 19.4 parts of barbituric acid and 32.8 parts of methanol, and the mixture was stirred at 63 ℃ for 7 hours. To the resulting mixture was added 259 parts of a 50% methanol aqueous solution, and the mixture was stirred at 63 ℃ for 7 days. The resulting mixture was filtered. To the resulting residue, 902 parts of tetrahydrofuran was added, and the mixture was stirred at room temperature. The mixture was filtered, and the resulting residue was purified by column chromatography to give a compound represented by the formula (IZ 5-23).

Identification of Compound represented by the formula (IZ5-23)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺383

Exact molecular weight (Exact masses): 382

Example 8Z5XXX

10.0 parts of 4-nitrophthalonitrile (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 149 parts of methanol were mixed. While keeping the temperature at 2 to 6 ℃, 5.86 parts of 28% sodium methoxide methanol solution (manufactured by Wako pure chemical industries, Ltd.) was added dropwise to the obtained mixture over 20 minutes. The resulting mixture was stirred for 5 hours while being kept at 5 ℃ or lower.

While the resulting mixture was kept at 5 ℃ or lower, 5.79 parts of acetic acid, 9.25 parts of 2-cyanoacetanilide (manufactured by Tokyo Kasei Kogyo Co., Ltd.) and 74 parts of methanol were added. The resulting mixture was stirred at 65 ℃ for 3 days. To the obtained mixture were added 2.88 parts of acetic acid and 4.63 parts of 2-cyanoacetanilide (manufactured by Tokyo Kasei Kogyo Co., Ltd.). The resulting mixture was stirred at 65 ℃ for 3 days. In addition, up to this point in time, a total of 140 parts of methanol was added in addition to the above-mentioned methanol.

To the obtained mixture were added 24.0 parts of acetic acid, 15.3 parts of barbituric acid (manufactured by Tokyo chemical industry Co., Ltd.) and 363 parts of water, and the mixture was stirred at 65 ℃ for 9 days. The solvent of the resulting mixture was distilled off by a rotary evaporator, and then the resulting residue was purified by column chromatography to obtain a compound represented by the formula (IZ 5-25).

Identification of Compound represented by the formula (IZ5-25)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺445

Exact molecular weight (Exact masses): 444

Example 9Z5

5.0 parts of 4, 5-dichlorophthalonitrile and 62 parts of methanol were mixed.

While the mixture was kept at 5 ℃ or lower, a 25% sodium methoxide methanol solution containing sodium methoxide in an amount of 0.5 times the molar amount of 5.0 parts by mole of 4, 5-dichlorophthalonitrile was added. The mixture was stirred at 5 ℃ or below for 5 hours. To the mixture were added 2-cyano-N-methylacetamide and 6.1 parts of acetic acid in an amount of 1.5 times the molar amount of 5.0 parts of 4, 5-dichlorophthalonitrile, while keeping the mixture at 5 ℃ or lower. The mixture was stirred at 65 ℃ for 3 days.

This mixture was mixed with 4.2 parts of acetic acid, 5.2 parts of barbituric acid, 500 parts of methanol and 562 parts of water, and stirred at 65 ℃ for 9 days. After the solvent was distilled off from the mixture by a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ 5-247).

Identification of Compound represented by the formula (IZ5-247)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺406

Exact molecular weight (Exact masses): 405

Example 101Z5

The following substances are mixed together and then,

pigment: 5860 portions of C.I. pigment green,

8.1 parts of acrylic pigment dispersing agent,

resin (B): 73 parts of resin B5 solution, and

solvent (E): 290 parts of propylene glycol monomethyl ether acetate

The pigment dispersion liquid (liquid containing colorant A1Z 5) was prepared by dispersing the pigment using a bead mill. In addition, the following substances were mixed,

colorant AZ 5: the compound represented by the formula (IZ5-1) obtained in example 1Z5

50 parts of (a) a mixture of (b),

dispersant (BYK-LPN 6919; manufactured by BYK-Chemie Japan, Ltd.)

58 parts of (a) to (b),

resin (B): 93 parts of resin B3 solution, and

solvent (E): propylene glycol monomethyl ether acetate 800 parts

The compound represented by the formula (IZ5-1) obtained in example 1Z5 was dispersed using a bead mill to obtain a colored composition.

Next, the following were mixed to obtain colored curable composition 1Z5,

the total amount of the obtained pigment dispersion (the liquid containing the colorant A1Z 5);

400 parts of the obtained coloring composition;

Resin (B): 45 parts of resin B1 solution;

polymerizable compound (C): 25 parts of dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kagaku Co., Ltd.);

polymerization initiator (D): n-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure (registered trademark) OXE-01, manufactured by BASF corporation)

15 parts of (1);

solvent (E): 86 parts of propylene glycol monomethyl ether acetate; and

leveling agent: 0.12 part of polyether-modified Silicone oil (Toray Silicone SH 8400; manufactured by Dow Corning Toray Co., Ltd.).

[ preparation of colored Pattern ]

A colored curable composition 1Z5 was applied to a 2-inch square glass substrate (EAGLE XG; manufactured by Corning corporation) by a spin coating method, and then prebaked at 100 ℃ for 3 minutes to form a colored curable composition layer. After cooling, the substrate on which the colored curable composition layer was formed and a photomask made of quartz glass were spaced at a distance of 200 μm, and exposed to an exposure apparatus (TME-150 RSK; manufactured by Topcon Corporation) at a rate of 80mJ/cm in an atmospheric atmosphere²Exposure was carried out with the exposure amount (based on 365 nm). As the photomask, a photomask in which a line-and-space pattern of 100 μm was formed was used. Exposing the colored curable composition layer to a solution containing a nonionic surfactant 0.12 at 25 deg.C % and 0.04% potassium hydroxide aqueous solution for 70 seconds, followed by development and water washing. The colored curable composition layer was post-baked at 230 ℃ for 30 minutes, whereby a colored pattern was obtained.

[ measurement of phase difference value ]

A colored curable composition 1Z5 was applied to a 2-inch square glass substrate (EAGLE XG; manufactured by Corning corporation) by a spin coating method, and then prebaked at 100 ℃ for 3 minutes to form a colored curable composition layer. After cooling, an exposure machine (TME-150 RSK; manufactured by Topcon Corporation) was used for the colored curable composition layer under an atmospheric atmosphere at 80mJ/cm²Exposure was carried out with the exposure amount (based on 365 nm). The colored curable composition layer after exposure was immersed in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ℃ for 70 seconds, developed, and washed with water. The colored curable composition layer was post-baked at 230 ℃ for 30 minutes, thereby obtaining a colored coating film.

The film thickness of the obtained colored coating film was measured using DEKTAK3 (manufactured by japan vacuum technology corporation).

The phase difference value at an inclination angle of 45 ° of the colored coating film was measured using an ellipsometer (M-220 type spectroscopic ellipsometer; manufactured by japan spectro (ltd.)). For the measurement of the retardation value, light having a wavelength of 550nm was used. The results are shown in Table 8Z 5.

Example 102Z5

A colored curable composition 2Z5 was obtained in the same manner as in example 101Z5 except that the compound represented by the formula (IZ5-1) obtained in example 1Z5 was replaced with the compound represented by the formula (IZ5-3) obtained in example 2Z5, and a colored pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 5.

Example 103Z5

A colored curable composition 3Z5 was obtained in the same manner as in example 101Z5 except that the compound represented by the formula (IZ5-1) obtained in example 1Z5 was replaced with the compound represented by the formula (IZ5-23) obtained in example 3Z5, and a colored pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 5.

Example 104Z5

A colored curable composition 4Z5 was obtained in the same manner as in example 101Z5 except that the compound represented by the formula (IZ5-1) obtained in example 1Z5 was replaced with the compound represented by the formula (IZ5-25) obtained in example 4Z5, and a colored pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 5.

Example 105Z5

A colored curable composition 5Z5 was obtained in the same manner as in example 101Z5 except that c.i. pigment green 58 was replaced with c.i. pigment green 7, and a colored pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 5.

Example 106Z5

A colored curable composition 6Z5 was obtained in the same manner as in example 101Z5 except that the compound represented by the formula (IZ5-1) obtained in example 1Z5 was replaced with c.i. pigment green 58 and the compound represented by the formula (IZ5-1) obtained in example 2Z5 was replaced with the compound represented by the formula (IZ5-3) obtained in example 2Z5, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 5.

Example 107Z5

A colored curable composition 7Z5 was obtained in the same manner as in example 101Z5 except that the compound represented by the formula (IZ5-1) obtained in example 1Z5 was replaced with c.i. pigment green 58 and the compound represented by the formula (IZ5-1) obtained in example 3Z5 was replaced with the compound represented by the formula (IZ5-23) obtained in example 3Z5, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 5.

Example 108Z5

A colored curable composition 8Z5 was obtained in the same manner as in example 101Z5 except that the compound represented by the formula (IZ5-1) obtained in example 1Z5 was replaced with c.i. pigment green 58 and the compound represented by the formula (IZ5-25) obtained in example 4Z5 was replaced with c.i. pigment green 7, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 5.

Example 109Z5

A colored curable composition 9Z5 was obtained in the same manner as in example 101Z5 except that c.i. pigment green 58 was replaced with c.i. pigment green 59, and a colored pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 5.

Example 110Z5

A colored curable composition 10Z5 was obtained in the same manner as in example 101Z5 except that the compound represented by the formula (IZ5-1) obtained in example 1Z5 was replaced with c.i. pigment green 58 and the compound represented by the formula (IZ5-1) obtained in example 2Z5 was replaced with the compound represented by the formula (IZ5-3) obtained in example 2Z5, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 5.

Example 111Z5

A colored curable composition 11Z5 was obtained in the same manner as in example 101Z5 except that the compound represented by the formula (IZ5-1) obtained in example 1Z5 was replaced with c.i. pigment green 58 and the compound represented by the formula (IZ5-1) obtained in example 3Z5 was replaced with the compound represented by the formula (IZ5-23) obtained in example 3Z5, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 5.

Example 112Z5

A colored curable composition 12Z5 was obtained in the same manner as in example 101Z5 except that the compound represented by the formula (IZ5-1) obtained in example 1Z5 was replaced with c.i. pigment green 58 and the compound represented by the formula (IZ5-25) obtained in example 4Z5 was replaced with c.i. pigment green 59, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 5.

Comparative example 1Z5

A colored curable composition C1Z5 was obtained and a colored pattern was obtained in the same manner as in example 101Z5 except that the compound represented by the formula (IZ5-1) obtained in example 1Z5 was replaced with c.i. pigment yellow 185. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 5.

Comparative example 2Z5

A colored curable composition C2Z5 was obtained in the same manner as in example 101Z5, except that the c.i. pigment green 58 was replaced with the c.i. pigment green 7, and the compound represented by the formula (IZ5-1) obtained in example 1Z5 was replaced with the c.i. pigment yellow 185, to obtain a colored curable composition C2Z5, and a colored pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 5.

Comparative example 3Z5

A colored curable composition C3Z5 was obtained in the same manner as in example 101Z5, except that the c.i. pigment green 58 was replaced with the c.i. pigment green 59, and the compound represented by the formula (IZ5-1) obtained in example 1Z5 was replaced with the c.i. pigment yellow 185, to obtain a colored curable composition C3Z5, and a colored pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 5.

[ Table 8Z5]

TABLE 8Z5

	Film thickness (mum)	Phase difference value (nm)
			Example 101Z5	2.3	3
Example 102Z5	2.3	3
			Example 103Z5	2.3	3
Example 104Z5	2.3	3
			Example 105Z5	2.3	3
Example 106Z5	2.3	3
			Example 107Z5	2.3	3
Example 108Z5	2.3	3
			Example 109Z5	2.3	3
Example 110Z5	2.3	3
			Example 111Z5	2.3	3
Example 112Z5	2.3	3
			Comparative example 1Z5	2.3	15
Comparative example 2Z5	2.3	15
			Comparative example 3Z5	2.3	15

Example 113Z5

The following substances are mixed together and then,

pigment: 5860 portions of C.I. pigment green,

8.1 parts of acrylic pigment dispersing agent,

resin (B): 73 parts of resin B5 solution, and

solvent (E): 290 parts of propylene glycol monomethyl ether acetate

The pigment dispersion liquid (liquid containing colorant A1Z 5) was prepared by dispersing the pigment using a bead mill. In addition, the following substances were mixed,

colorant AZ 5: 50 parts of a compound represented by the formula (IZ5-1),

58 parts of a dispersant solution (solid content: 60%),

resin (B): 93 parts of resin B3 solution, and

solvent (E): propylene glycol monomethyl ether acetate 800 parts

The compound represented by formula (IZ5-1) was dispersed using a bead mill to obtain a coloring composition.

Next, the following were mixed to obtain a colored curable composition 13Z5,

the total amount of the obtained pigment dispersion (the liquid containing the colorant A1Z 5);

400 parts of the obtained coloring composition;

resin (B): 45 parts of resin B1 solution;

polymerizable compound (C): 25 parts of dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kagaku Co., Ltd.);

polymerization initiator (D): 15 parts of N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure (registered trademark) OXE-01; manufactured by BASF corporation);

Solvent (E): 86 parts of propylene glycol monomethyl ether acetate; and

leveling agent: 0.12 part of polyether-modified Silicone oil (Toray Silicone SH 8400; manufactured by Dow Corning Toray Co., Ltd.).

A colored pattern was produced in the same manner as in example 101Z5 except that a colored curable composition 13Z5 was used instead of the colored curable composition 1Z 5. A colored coating film was obtained in the same manner as in example 101Z5 except that a colored curable composition 13Z5 was used in place of the colored curable composition 1Z5, and the film thickness and the retardation value were measured. The results are shown in Table 9Z 5.

Example 114Z5 to example 117Z5

A colored pattern was obtained in the same manner as in example 113Z5, except that the compound represented by the formula (IZ5-1) was replaced with the colorant shown in the column of "colorant" in table 9Z 5. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 9Z 5.

Example 118Z5 to example 122Z5

A colored pattern was obtained in the same manner as in example 113Z5 except that the compound represented by the formula (IZ5-1) was replaced with the compound shown in the column of "colorant" in table 9Z5 and the c.i. pigment green 58 was replaced with c.i. pigment green 7. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 9Z 5.

Example 123Z5 to example 127Z5

A colored pattern was obtained in the same manner as in example 113Z5 except that the compound represented by the formula (IZ5-1) was replaced with the compound shown in the column of "colorant" in table 9Z5 and the c.i. pigment green 58 was replaced with the c.i. pigment green 59. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 9Z 5.

[ Table 9Z5]

TABLE 9Z5

	Coloring agent	Film thickness (mum)	Phase difference value (nm)
				Example 113Z5	A compound represented by the formula (IZ5-1)	2.3	3
Example 114Z5	A compound represented by the formula (IZ5-3)	2.3	3
				Example 115Z5	A compound represented by the formula (IZ5-23)	2.3	3
Example 116Z5	A compound represented by the formula (IZ5-25)	2.3	3
				Example 117Z5	A compound represented by the formula (IZ5-247)	2.3	3
Example 118Z5	A compound represented by the formula (IZ5-1)	2.3	3
				Example 119Z5	A compound represented by the formula (IZ5-3)	2.3	3
Example 120Z5	A compound represented by the formula (IZ5-23)	2.3	3
				Example 121Z5	A compound represented by the formula (IZ5-25)	2.3	3
Example 122Z5	A compound represented by the formula (IZ5-247)	2.3	3
				Example 123Z5	A compound represented by the formula (IZ5-1)	2.3	3
Example 124Z5	A compound represented by the formula (IZ5-3)	2.3	3
				Example 125Z5	A compound represented by the formula (IZ5-23)	2.3	3
Example 126Z5	A compound represented by the formula (IZ5-25)	2.3	3
				Example 127Z5	A compound represented by the formula (IZ5-247)	2.3	3

In example Z5, it is understood from the above results that the retardation value of the colored coating film formed from the colored curable composition containing the compound of the present invention is smaller than that of the colored coating film formed from the colored curable composition containing c.i. pigment yellow 185.

Example Z6

Example 1Z6

7.02 parts of phthalonitrile (manufactured by Tokyo chemical Co., Ltd.) and 61.6 parts of methanol were mixed. While the temperature of the obtained mixture was kept at 2 ℃, a mixture of 8.20 parts of 28% sodium methoxide methanol solution (manufactured by Wako pure chemical industries, Ltd.) and 74.6 parts of methanol was added dropwise over 1 hour and 30 minutes. The resulting mixture was stirred at 2 ℃ for 6 hours and 15 minutes. While the temperature of the obtained mixture was kept at 4 ℃ or lower, 10.7 parts of acetic acid was added. To the resulting mixture, 17.6 parts of benzoylacetonitrile (benzophenonitrile) (manufactured by tokyo chemical industry Co., Ltd.) was added, and the mixture was stirred at room temperature for 44 hours. The resulting mixture was filtered, and the residue was washed with 800 parts of methanol. The obtained residue was dried under reduced pressure at 60 ℃ to obtain 18.0 parts of a compound represented by the formula (IFFZ 6-1).

Identification of Compound represented by the formula (IFFZ6-1)

(Mass Spectrometry) ionization mode ESI +: m/z ═ M + H]⁺402

Exact molecular weight (Exact masses): 401

While 7.6 parts of fuming sulfuric acid (25%) at 3 ℃ (manufactured by Wako pure chemical industries, Ltd.) was stirred, 0.513 part of the compound represented by the formula (IFFZ6-1) obtained in example 2Z6 was added. To the resulting mixture was added 3.8 parts of fuming sulfuric acid (25%) (manufactured by Wako pure chemical industries, Ltd.). The resulting mixture was stirred and heated to 15 ℃ over 3 hours and 30 minutes. 139 parts of ice water and 38.2 parts of sodium chloride were added to the obtained mixture. The resulting mixture was filtered, and the resulting residue was washed with 64 parts of a 21.5% aqueous sodium chloride solution. The obtained residue was dried under reduced pressure at 60 ℃ to obtain 1.02 parts of a compound represented by the formula (IFFZ 6-2).

Identification of Compound represented by the formula (IFFZ6-2)

(Mass Spectrometry) ionization mode-ESI-: m/z ═ M-H]^-560

Exact molecular weight (Exact masses): 561

5.11 parts of a compound represented by the formula (IFFZ6-2) and 511 parts of water were mixed at room temperature. To the obtained mixture, a mixture of 6.72 parts of barium chloride dihydrate (manufactured by Wako pure chemical industries, Ltd.) and 60 parts of water was added. The resulting mixture was filtered, and the resulting residue was washed with water. The obtained residue was dried under reduced pressure at 60 ℃ to obtain 2.98 parts of a compound represented by the formula (IFZ 6-4).

Identification of Compound represented by the formula (IFZ6-4)

(Mass Spectrometry) ionization mode-ESI-: m/z ═ M-Ba⁺+H]^-560

Exact molecular weight (Exact masses): 697

Example 2Z6

10.0 parts of a compound represented by the formula (IFFZ6-2) and 1000 parts of water were mixed at room temperature. To the resulting mixture, a 5% aqueous solution of sodium hydroxide was added dropwise to obtain a homogeneous solution. To the homogeneous solution was added 87.0 parts of a 10% aqueous solution of barium chloride dihydrate. The resulting mixture was filtered, and the resulting residue was washed with water. The obtained residue was dried under reduced pressure at 60 ℃ to obtain 9.43 parts of a compound represented by the formula (IFZ 6-4).

Identification of Compound represented by the formula (IFZ6-4)

(Mass Spectrometry) ionization modeThe formula is ESI-: m/z ═ M-Ba + H]^-560

Exact molecular weight (Exact masses): 697

Example 3Z6

5.02 parts of a compound represented by the formula (IFFZ6-2) and 500 parts of a 50% aqueous methanol solution were mixed at room temperature. To the resulting mixture, a 5% aqueous solution of sodium hydroxide was added dropwise to obtain a homogeneous solution. To the homogeneous solution was added 95.0 parts of a 10% strontium chloride hexahydrate aqueous solution. The resulting mixture was filtered, and the resulting residue was washed with 50% aqueous methanol. The obtained residue was dried under reduced pressure at 60 ℃ to obtain 4.00 parts of a compound represented by the formula (IFZ 6-3).

Identification of Compound represented by the formula (IFZ6-3)

(Mass Spectrometry) ionization mode-ESI-: m/z ═ M-Sr + H]^-560

Exact molecular weight (Exact masses): 647

Example 4Z6

0.501 part of a compound represented by the formula (IFFZ6-2) and 50.0 parts of water were mixed at room temperature. To the resulting mixture, a 5% aqueous solution of sodium hydroxide was added dropwise to obtain a homogeneous solution. To the homogeneous solution was added 12.6 parts of a 10% aqueous calcium chloride solution. The resulting mixture was filtered, and the resulting residue was washed with water. The obtained residue was dried under reduced pressure at 60 ℃ to obtain 0.024 part of a compound represented by the formula (IFZ 6-2).

Identification of Compound represented by the formula (IFZ6-2)

(Mass Spectrometry) ionization mode-ESI-: m/z ═ M-Ca + H]^-560

Exact molecular weight (Exact masses): 599

Example 5Z6

0.500 parts of a compound represented by the formula (IFFZ6-2) and 50.0 parts of water were mixed at room temperature. To the resulting mixture, a 5% aqueous solution of sodium hydroxide was added dropwise to obtain a homogeneous solution. To the homogeneous solution was added 3.52 parts of a 10% aqueous solution of manganese chloride tetrahydrate. The resulting mixture was filtered, and the resulting residue was washed with water. The obtained residue was dried under reduced pressure at 60 ℃ to obtain 0.015 part of a compound represented by the formula (IFZ 6-10).

Identification of Compound represented by the formula (IFZ6-10)

(Mass Spectrometry) ionization mode-ESI-: m/z ═ M-Mn + H]^-560

Exact molecular weight (Exact masses): 614

Example 6Z6

A compound represented by the formula (IFZ6-6) was obtained in the same manner as in example 2Z6, except that barium chloride dihydrate was replaced with zinc nitrate hexahydrate.

Identification of Compound represented by the formula (IFZ6-6)

(Mass Spectrometry) ionization mode-ESI-: m/z ═ M-Zn + H]^-560

Exact molecular weight (Exact masses): 623

Example 7Z6

5.00 parts of a compound represented by the formula (IFFZ6-2) and 500 parts of water were mixed at room temperature. To the resulting mixture, a 5% aqueous solution of sodium hydroxide was added dropwise to obtain a homogeneous solution. To the homogeneous solution was added 23.7 parts of a 10% aqueous aluminum chloride solution. The resulting mixture was filtered, and the resulting residue was washed with water. The obtained residue was dried under reduced pressure at 60 ℃ to obtain 0.474 parts of a compound represented by the formula (IFZ 6-11).

Identification of Compound represented by the formula (IFZ6-11)

(Mass Spectrometry) ionization mode-ESI-: m/z ═ [ (M-2Al)/3+ H]^-560

Exact molecular weight (Exact masses): 1731

Example 8Z6

5.01 parts of a compound represented by the formula (IFFZ6-2) and 500 parts of water were mixed at room temperature. To the resulting mixture, a 5% aqueous solution of sodium hydroxide was added dropwise to obtain a homogeneous solution. To the homogeneous solution was added 36.0 parts of a 10% aqueous solution of ferric nitrate nonahydrate. The resulting mixture was filtered, and the resulting residue was washed with water. The obtained residue was dried under reduced pressure at 60 ℃ to obtain 3.80 parts of a compound represented by the formula (IFZ 6-12).

Identification of Compound represented by the formula (IFZ6-12)

(Mass Spectrometry) ionization mode-ESI-: m/z ═ [ (M-2Fe)/3+ H]^-560

Exact molecular weight (Exact masses): 1789

Example 9Z6

0.498 part of the compound represented by the formula (IFFZ6-2) and 49.9 parts of water were mixed at room temperature. To the resulting mixture, a 5% aqueous solution of sodium hydroxide was added dropwise to obtain a homogeneous solution. To the homogeneous solution was added 4.45 parts of a 10% aqueous copper sulfate pentahydrate solution. The resulting mixture was filtered, and the resulting residue was washed with water. The obtained residue was dried under reduced pressure at 60 ℃ to obtain 0.018 parts of a compound represented by the formula (IFZ 6-31).

Identification of Compound represented by the formula (IFZ6-31)

(Mass Spectrometry) ionization mode-ESI-: m/z ═ M-Cu + H]^-560

Exact molecular weight (Exact masses): 622

Example 10Z6

The procedure was carried out in the same manner as in example 1Z6 except that benzoylacetonitrile was replaced with 4-cyanoacetylbenzoic acid to give a compound represented by the formula (IFFZ6-1), thereby giving a compound represented by the formula (IJZ 6-1).

Identification of Compound represented by the formula (IJJZ6-1)

(Mass Spectrometry) ionization mode-ESI-: m/z ═ M-H]^-488

Exact molecular weight (Exact masses): 489

16.3 parts of a compound represented by the formula (IJZ 6-1) and 1630 parts of water were mixed at room temperature. To the resulting mixture, a 5% aqueous solution of sodium hydroxide was added dropwise to obtain a homogeneous solution. To the resulting homogeneous solution, 163 parts of a 10% barium chloride dihydrate aqueous solution was added. The resulting mixture was filtered, and the resulting residue was washed with water. The obtained residue was dried under reduced pressure at 60 ℃ to obtain 7.49 parts of a compound represented by the formula (IJZ 6-4).

Identification of Compound represented by the formula (IJZ6-4)

(Mass Spectrometry) ionization mode-ESI-: m/z ═ M-Ba + H]^-488

Exact molecular weight (Exact masses): 625

Example 11Z6

A compound represented by the formula (IJZ6-3) was obtained in the same manner as in example 10Z6, except that barium chloride dihydrate was replaced with strontium chloride hexahydrate.

Identification of Compound represented by the formula (IJZ6-3)

(Mass Spectrometry) ionization mode-ESI-: m/z ═ M-Sr + H]^-488

Exact molecular weight (Exact masses): 575

Example 12Z6

A compound represented by the formula (IJZ6-2) was obtained in the same manner as in example 10Z6, except that barium chloride dihydrate was replaced with calcium chloride.

Identification of Compound represented by the formula (IJZ6-2)

(Mass Spectrometry) ionization mode-ESI-: m/z ═ M-Ca + H ]^-488

Exact molecular weight (Exact masses): 527

Example 13Z6

A compound represented by the formula (IJZ6-10) was obtained by the same operation as in example 10Z6, except that barium chloride dihydrate was replaced with manganese chloride tetrahydrate.

Identification of Compound represented by the formula (IJZ6-10)

(Mass Spectrometry) ionization mode-ESI-: m/z ═ M-Mn + H]^-488

Exact molecular weight (Exact masses): 542

Example 14Z6

A compound represented by the formula (IJZ6-31) was obtained by the same operation as in example 10Z6, except that barium chloride dihydrate was replaced with copper sulfate pentahydrate.

Identification of Compound represented by the formula (IJZ6-31)

(Mass Spectrometry) ionization mode-ESI-: m/z ═ M-Cu + H]^-488

Exact molecular weight (Exact masses): 550

Example 15Z6

A compound represented by the formula (IJZ6-6) was obtained in the same manner as in example 10Z6, except that barium chloride dihydrate was replaced with zinc nitrate hexahydrate.

Identification of Compound represented by the formula (IJZ6-6)

(Mass Spectrometry) ionization mode-ESI-: m/z ═ M-Zn + H]^-488

Exact molecular weight (Exact masses): 551

Example 16Z6

A compound represented by the formula (IJZ6-11) was obtained in the same manner as in example 10Z6, except that barium chloride dihydrate was replaced with aluminum chloride.

Identification of Compound represented by the formula (IJZ6-11)

(Mass Spectrometry) ionization mode-ESI-: m/z ═ [ (M-2Al)/3+ H]^-488

Exact molecular weight (Exact masses): 1515

Example 17Z6

A compound represented by the formula (IJZ6-12) was obtained in the same manner as in example 10Z6, except that barium chloride dihydrate was replaced with iron nitrate nonahydrate.

Identification of Compound represented by the formula (IJZ6-12)

(Mass Spectrometry) ionization mode-ESI-: m/z ═ [ (M-2Fe)/3+ H]^-488

Exact molecular weight (Exact masses): 1573

Example 18Z6

A compound represented by the formula (IJZ6-1) was obtained in the same manner as in example 10Z6, except that barium chloride dihydrate was replaced with magnesium chloride.

Identification of Compound represented by the formula (IJZ6-1)

(Mass Spectrometry) ionization mode-ESI-: m/z ═ M-Mg + H]^-488

Exact molecular weight (Exact masses): 511

Example 19Z6

5.00 parts of phthalonitrile (manufactured by Tokyo chemical Co., Ltd.) and 44 parts of methanol were mixed. To the obtained mixture, a mixture of 5.84 parts of 28% sodium methoxide methanol solution (manufactured by Wako pure chemical industries, Ltd.) and 54 parts of methanol was added dropwise over 1 hour and 30 minutes while keeping the temperature at 5 ℃ or lower. The resulting mixture was stirred at 5 ℃ or lower for 12 hours. To the resulting mixture, 11.5 parts of acetic acid, 24.5 parts of 4-cyanoacetylbenzoic acid and 712 parts of methanol were added while keeping the temperature at 5 ℃ or lower. The resulting mixture was stirred at room temperature for 4 hours and then at 40 ℃ for 96 hours. The solvent was distilled off from the obtained mixture by a rotary evaporator, and the obtained residue was purified by column chromatography to obtain 0.471 part of a compound represented by the formula (IJJZ 6-1).

Identification of Compound represented by the formula (IJJZ6-1)

(Mass Spectrometry) ionization mode-ESI-: m/z ═ M-H]^-488

Exact molecular weight (Exact masses): 489

Example 101Z6

The following substances are mixed together and then,

pigment: 5860 portions of C.I. pigment green,

8.1 parts of acrylic pigment dispersing agent,

resin (B): 73 parts of resin B5 solution, and

solvent (E): 290 parts of propylene glycol monomethyl ether acetate

The pigment dispersion liquid (liquid containing colorant A1Z 6) was prepared by dispersing the pigment using a bead mill. In addition, the following substances were mixed,

colorant AZ 6: 50 parts of a compound represented by the formula (IFZ6-4),

58 parts of a dispersant (BYK-LPN 6919; manufactured by BYK-Chemie Japan, Ltd.),

resin (B): 93 parts of resin B3 solution, and

solvent (E): propylene glycol monomethyl ether acetate 800 parts

The compound represented by formula (IFZ6-4) was dispersed using a bead mill, to thereby obtain a coloring composition. Next, the following were mixed to obtain colored curable composition 1Z6,

the total amount of the obtained pigment dispersion (the liquid containing the colorant A1Z 6);

400 parts of the obtained coloring composition;

Resin (B): 45 parts of resin B1 solution;

polymerizable compound (C): 25 parts of dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kagaku Co., Ltd.);

polymerization initiator (D): 15 parts of N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure (registered trademark) OXE-01; manufactured by BASF corporation);

solvent (E): 86 parts of propylene glycol monomethyl ether acetate; and

leveling agent: 0.12 part of polyether-modified Silicone oil (Toray Silicone SH 8400; manufactured by Dow Corning Toray Co., Ltd.).

[ preparation of colored Pattern ]

A colored curable composition 1Z6 was applied to a 2-inch square glass substrate (EAGLE XG; manufactured by Corning corporation) by a spin coating method, and then prebaked at 100 ℃ for 3 minutes to form a colored curable composition layer. After cooling, the substrate on which the colored curable composition layer was formed and a photomask made of quartz glass were spaced at a distance of 200 μm, and exposed to an exposure apparatus (TME-150 RSK; manufactured by Topcon Corporation) at a rate of 80mJ/cm in an atmospheric atmosphere²Exposure was carried out with the exposure amount (based on 365 nm). As the photomask, a photomask in which a line-and-space pattern of 100 μm was formed was used. The colored curable composition layer after exposure was immersed in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ℃ for 70 seconds, developed, and washed with water. The colored curable composition layer was post-baked at 230 ℃ for 30 minutes, whereby a colored pattern was obtained.

[ measurement of phase difference value ]

A colored curable composition 1Z6 was applied to a 2-inch square glass substrate (EAGLE XG; manufactured by Corning corporation) by a spin coating method, and then prebaked at 100 ℃ for 3 minutes to form a colored curable composition layer. After cooling, an exposure machine (TME-150 RSK; manufactured by Topcon Corporation) was used for the colored curable composition layer under an atmospheric atmosphere at 80mJ/cm²Exposure was carried out with the exposure amount (based on 365 nm). The colored curable composition layer after exposure was immersed in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ℃ for 70 seconds, developed, washed with water, and dried. Subjecting the dried colored curable composition layer to 3 at 230 ℃And baked after 0 minute, thereby obtaining a colored coating film.

The film thickness of the obtained colored coating film was measured using DEKTAK3 (manufactured by japan vacuum technology corporation).

The phase difference value at an inclination angle of 45 ° of the colored coating film was measured using an ellipsometer (M-220 type spectroscopic ellipsometer; manufactured by japan spectro (ltd.)). For the measurement of the retardation value, light having a wavelength of 550nm was used. The results are shown in Table 5Z 6.

Example 102Z6

A colored curable composition 2Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ 6-2). Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z 6.

Example 103Z6

A colored curable composition 3Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ 6-3). Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z 6.

Example 104Z6

A colored curable composition 4Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ 6-6). Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z 6.

Example 105Z6

A colored curable composition 5Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ 6-10). Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z 6.

Example 106Z6

A colored curable composition 6Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ 6-11). Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z 6.

Example 107Z6

A colored curable composition 7Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ 6-12). Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z 6.

Example 108Z6

A colored curable composition 8Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ 6-31). Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z 6.

Example 109Z6

A colored curable composition 9Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ 6-1). Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z 6.

Example 110Z6

A colored curable composition 10Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ 6-2). Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z 6.

Example 111Z6

A colored curable composition 11Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ 6-3). Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z 6.

Example 112Z6

A colored curable composition 12Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ 6-4). Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z 6.

Example 113Z6

A colored curable composition 13Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ 6-6). Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z 6.

Example 114Z6

A colored curable composition 14Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ 6-10). Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z 6.

Example 115Z6

A colored curable composition 15Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ 6-11). Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z 6.

Example 116Z6

A colored curable composition 16Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ 6-12). Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z 6.

Example 117Z6

A colored curable composition 17Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ 6-31). Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 5Z 6.

Example 118Z6

A colored curable composition 18Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-2) and the c.i. pigment green 58 was replaced with the c.i. pigment green 7. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z 6.

Example 119Z6

A colored curable composition 19Z6 was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-3) and the c.i. pigment green 58 was replaced with the c.i. pigment green 7, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z 6.

Example 120Z6

A colored curable composition 20Z6 was obtained in the same manner as in example 101Z6, except that c.i. pigment green 58 was replaced with c.i. pigment green 7, and a colored pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z 6.

Example 121Z6

A colored curable composition 21Z6 was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-6) and the c.i. pigment green 58 was replaced with the c.i. pigment green 7, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z 6.

Example 122Z6

A colored curable composition 22Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-10) and the c.i. pigment green 58 was replaced with the c.i. pigment green 7. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z 6.

Example 123Z6

A colored curable composition 23Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-11) and the c.i. pigment green 58 was replaced with the c.i. pigment green 7. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z 6.

Example 124Z6

A colored curable composition 24Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-12) and the c.i. pigment green 58 was replaced with the c.i. pigment green 7. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z 6.

Example 125Z6

A colored curable composition 25Z6 was obtained in the same manner as in example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-31) and the c.i. pigment green 58 was replaced with the c.i. pigment green 7, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z 6.

Example 126Z6

A colored curable composition 26Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-1) and the c.i. pigment green 58 was replaced with the c.i. pigment green 7. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z 6.

Example 127Z6

A colored curable composition 27Z6 was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-2) and the c.i. pigment green 58 was replaced with the c.i. pigment green 7, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z 6.

Example 128Z6

A colored curable composition 28Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-3) and the c.i. pigment green 58 was replaced with the c.i. pigment green 7. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z 6.

Example 129Z6

A colored curable composition 29Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-4) and the c.i. pigment green 58 was replaced with the c.i. pigment green 7. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z 6.

Example 130Z6

A colored curable composition 30Z6 was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-6) and the c.i. pigment green 58 was replaced with the c.i. pigment green 7, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z 6.

Example 131Z6

A colored curable composition 31Z6 was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-10) and the c.i. pigment green 58 was replaced with the c.i. pigment green 7, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z 6.

Example 132Z6

A colored curable composition 32Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-11) and the c.i. pigment green 58 was replaced with the c.i. pigment green 7. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z 6.

Example 133Z6

A colored curable composition 33Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-12) and the c.i. pigment green 58 was replaced with the c.i. pigment green 7. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z 6.

Example 134Z6

A colored curable composition 34Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-31) and the c.i. pigment green 58 was replaced with the c.i. pigment green 7. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 6Z 6.

Example 135Z6

A colored curable composition 35Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-2) and the c.i. pigment green 58 was replaced with the c.i. pigment green 59. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z 6.

Example 136Z6

A colored curable composition 36Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-3) and the c.i. pigment green 58 was replaced with the c.i. pigment green 59. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z 6.

Example 137Z6

A colored curable composition 37Z6 was obtained in the same manner as in example 101Z6 except that the c.i. pigment green 58 was replaced with c.i. pigment green 59, and a colored pattern was obtained. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z 6.

Example 138Z6

A colored curable composition 38Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-6) and the c.i. pigment green 58 was replaced with the c.i. pigment green 59. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z 6.

Example 139Z6

A colored curable composition 39Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-10) and the c.i. pigment green 58 was replaced with the c.i. pigment green 59. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z 6.

Example 140Z6

A colored curable composition 40Z6 was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-11), and the c.i. pigment green 58 was replaced with the c.i. pigment green 59, to obtain a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z 6.

Example 141Z6

A colored curable composition 41Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-12) and the c.i. pigment green 58 was replaced with the c.i. pigment green 59. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z 6.

Example 142Z6

A colored curable composition 42Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-31) and the c.i. pigment green 58 was replaced with the c.i. pigment green 59. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z 6.

Example 143Z6

A colored curable composition 43Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-1) and the c.i. pigment green 58 was replaced with the c.i. pigment green 59. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z 6.

Example 144Z6

A colored curable composition 44Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-2) and the c.i. pigment green 58 was replaced with the c.i. pigment green 59. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z 6.

Example 145Z6

A colored curable composition 45Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-3) and the c.i. pigment green 58 was replaced with the c.i. pigment green 59. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z 6.

Example 146Z6

A colored curable composition 46Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-4), and the c.i. pigment green 58 was replaced with the c.i. pigment green 59. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z 6.

Example 147Z6

A colored curable composition 47Z6 was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-6) and the c.i. pigment green 58 was replaced with the c.i. pigment green 59, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z 6.

Example 148Z6

A colored curable composition 48Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-10) and the c.i. pigment green 58 was replaced with the c.i. pigment green 59. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z 6.

Example 149Z6

A colored curable composition 49Z6 was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-11), and the c.i. pigment green 58 was replaced with the c.i. pigment green 59, to obtain a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z 6.

Example 150Z6

A colored curable composition 50Z6 was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-12), and the c.i. pigment green 58 was replaced with the c.i. pigment green 59, to obtain a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z 6.

Example 151Z6

A colored curable composition 51Z6 was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-31) and the c.i. pigment green 58 was replaced with the c.i. pigment green 59, thereby obtaining a colored pattern. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 7Z 6.

Comparative example 1Z6

A colored curable composition C1Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6, except that the compound represented by the formula (IFZ6-4) was replaced with c.i. pigment yellow 185. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 6.

Comparative example 2Z6

A colored curable composition C2Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6, except that c.i. pigment green 58 was replaced with c.i. pigment green 7 and the compound represented by formula (IFZ6-4) was replaced with c.i. pigment yellow 185. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 6.

Comparative example 3Z6

A colored curable composition C3Z6 was obtained and a colored pattern was obtained in the same manner as in example 101Z6, except that c.i. pigment green 58 was replaced with c.i. pigment green 59, and the compound represented by formula (IFZ6-4) was replaced with c.i. pigment yellow 185. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 8Z 6.

[ Table 5Z6]

TABLE 5Z6

	Film thickness (mum)	Phase difference value (nm)
			Example 101Z6	2.3	2
Example 102Z6	2.3	3
			Example 103Z6	2.3	2
Example 104Z6	2.3	3
			Example 105Z6	2.3	2
Example 106Z6	2.3	2
			Example 107Z6	2.3	3
Example 108Z6	2.3	3
			Example 109Z6	2.3	2
Example 110Z6	2.3	2
			Example 111Z6	2.3	2
Example 112Z6	2.3	2
			Example 113Z6	2.3	2
Example 114Z6	2.3	2
			Example 115Z6	2.3	2
Example 116Z6	2.3	3
			Example 117Z6	2.3	3

[ Table 6Z6]

TABLE 6Z6

	Film thickness (mum)	Phase difference value (nm)
			Example 118Z6	2.3	2
Example 119Z6	2.3	3
			Example 120Z6	2.3	2
Example 121Z6	2.3	2
			Example 122Z6	2.3	2
Example 123Z6	2.3	2
			Example 124Z6	2.3	2
Example 125Z6	2.3	3
			Example 126Z6	2.3	2
Example 127Z6	2.3	2
			Example 128Z6	2.3	2
Example 129Z6	2.3	2
			Example 130Z6	2.3	3
Example 131Z6	2.3	3
			Example 132Z6	2.3	2
Example 133Z6	2.3	2
			Example 134Z6	2.3	3

[ Table 7Z6]

TABLE 7Z6

	Film thickness (mum)	Phase difference value (nm)
			Example 135Z6	2.3	2
Example 136Z6	2.3	2
			Example 137Z6	2.3	2
Example 138Z6	2.3	2
			Example 139Z6	2.3	2
Example 140Z6	2.3	2
			Example 141Z6	2.3	2
Example 142Z6	2.3	3
			Example 143Z6	2.3	2
Example 144Z6	2.3	2
			Example 145Z6	2.3	2
Example 146Z6	2.3	2
			Example 147Z6	2.3	2
Example 148Z6	2.3	2
			Example 149Z6	2.3	2
Example 150Z6	2.3	2
			Example 151Z6	2.3	2

[ Table 8Z6]

TABLE 8Z6

	Film thickness (mum)	Phase difference value (nm)
			Comparative example 1Z6	2.3	15
Comparative example 2Z6	2.3	15
			Comparative example 3Z6	2.3	15

Example 152Z6

The following substances are mixed together and then,

pigment: 5860 portions of C.I. pigment green,

8.1 parts of acrylic pigment dispersing agent,

resin (B): 73 parts of resin B5 solution, and

solvent (E): 290 parts of propylene glycol monomethyl ether acetate

The pigment dispersion liquid (liquid containing colorant A1Z 6) was prepared by dispersing the pigment using a bead mill. In addition, the following substances were mixed,

colorant AZ 6: 50 parts of a compound represented by the formula (IFZ6-4),

58 parts of a dispersant solution (solid content: 60%),

resin (B): 93 parts of resin B3 solution, and

solvent (E): propylene glycol monomethyl ether acetate 800 parts

The compound represented by formula (IFZ6-4) was dispersed using a bead mill to obtain a coloring composition. Next, the following were mixed to obtain colored curable composition 52Z6,

the total amount of the obtained pigment dispersion (the liquid containing the colorant A1Z 6);

400 parts of the obtained coloring composition;

resin (B): 45 parts of resin B1 solution;

polymerizable compound (C): 25 parts of dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kagaku Co., Ltd.);

polymerization initiator (D): 15 parts of N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure (registered trademark) OXE-01; manufactured by BASF corporation);

Solvent (E): 86 parts of propylene glycol monomethyl ether acetate; and

leveling agent: 0.12 part of polyether-modified Silicone oil (Toray Silicone SH 8400; manufactured by Dow Corning Toray Co., Ltd.).

A colored pattern was produced in the same manner as in example 101Z6 except that a colored curable composition 52Z6 was used instead of the colored curable composition 1Z 6. A colored coating film was obtained in the same manner as in example 101Z6 except that a colored curable composition 52Z6 was used in place of the colored curable composition 1Z6, and the film thickness and the retardation value were measured. The results are shown in Table 9Z 6.

Example 153Z6 to example 168Z6

A colored pattern was obtained in the same manner as in example 152Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the colorant shown in the column of "colorant" in table 9Z 6. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 9Z 6.

Example 169Z6 to example 185Z6

A colored pattern was obtained in the same manner as in example 152Z6, except that the compound represented by formula (IFZ6-4) was replaced with the compound shown in the column of "colorant" in table 10Z6, and that c.i. pigment green 58 was replaced with c.i. pigment green 7. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 10Z 6.

Example 186Z6 to example 202Z6

A colored pattern was obtained in the same manner as in example 152Z6, except that the compound represented by formula (IFZ6-4) was replaced with the compound shown in the column of "colorant" in table 11Z6, and that c.i. pigment green 58 was replaced with c.i. pigment green 59. Further, a colored coating film was obtained, and film thickness measurement and retardation value measurement were performed. The results are shown in Table 11Z 6.

[ Table 9Z6]

TABLE 9Z6

		Film thickness (mum)	Phase difference value (nm)
				Example 186Z6	A compound represented by the formula (IFZ6-4)	2.3	3
Example 187Z6	A compound represented by the formula (IFZ6-2)	2.3	3
				Example 188Z6	A compound represented by the formula (IFZ6-3)	2.3	3
Example 189Z6	A compound represented by the formula (IFZ6-6)	2.3	3
				Example 190Z6	A compound represented by the formula (IFZ6-10)	2.3	3
Example 191Z6	A compound represented by the formula (IFZ6-11)	2.3	3
				Example 192Z6	A compound represented by the formula (IFZ6-12)	2.3	3
Example 193Z6	A compound represented by the formula (IFZ6-31)	2.3	3
				Example 194Z6	A compound represented by the formula (IJZ6-1)	2.3	3
Example 195Z6	A compound represented by the formula (IJZ6-2)	2.3	3
				Example 196Z6	A compound represented by the formula (IJZ6-3)	2.3	3
Example 197Z6	A compound represented by the formula (IJZ6-4)	2.3	3
				Example 198Z6	A compound represented by the formula (IJZ6-6)	2.3	3
Example 199Z6	A compound represented by the formula (IJZ6-10)	2.3	3
				Example 200Z6	A compound represented by the formula (IJZ6-11)	2.3	3
Example 201Z6	A compound represented by the formula (IJZ6-12)	2.3	3
				Example 202Z6	A compound represented by the formula (IJZ6-31)	2.3	3

[ Table 10Z6]

TABLE 10Z6

		Film thickness (mum)	Phase difference value (nm)
				Example 169Z6	A compound represented by the formula (IFZ6-4)	2.3	3
Example 170Z6	A compound represented by the formula (IFZ6-2)	2.3	3
				Example 171Z6	A compound represented by the formula (IFZ6-3)	2.3	3
Example 172Z6	A compound represented by the formula (IFZ6-6)	2.3	3
				Example 173Z6	A compound represented by the formula (IFZ6-10)	2.3	3
Example 174Z6	A compound represented by the formula (IFZ6-11)	2.3	3
				Example 175Z6	A compound represented by the formula (IFZ6-12)	2.3	3
Example 176Z6	A compound represented by the formula (IFZ6-31)	2.3	3
				Example 177Z6	A compound represented by the formula (IJZ6-1)	2.3	3
Example 178Z6	A compound represented by the formula (IJZ6-2)	2.3	3
				Example 179Z6	A compound represented by the formula (IJZ6-3)	2.3	3
Example 180Z6	A compound represented by the formula (IJZ6-4)	2.3	3
				Example 181Z6	A compound represented by the formula (IJZ6-6)	2.3	3
Example 182Z6	A compound represented by the formula (IJZ6-10)	2.3	3
				Example 183Z6	A compound represented by the formula (IJZ6-11)	2.3	3
Example 184Z6	A compound represented by the formula (IJZ6-12)	2.3	3
				Example 185Z6	A compound represented by the formula (IJZ6-31)	2.3	3

[ Table 11Z6]

TABLE 11Z6

		Film thickness (mum)	Phase difference value (nm)
				Example 186Z6	A compound represented by the formula (IFZ6-4)	2.3	3
Example 187Z6	A compound represented by the formula (IFZ6-2)	2.3	3
				Example 188Z6	A compound represented by the formula (IFZ6-3)	2.3	3
Example 189Z6	A compound represented by the formula (IFZ6-6)	2.3	3
				Example 190Z6	A compound represented by the formula (IFZ6-10)	2.3	3
Example 191Z6	A compound represented by the formula (IFZ6-11)	2.3	3
				Example 192Z6	A compound represented by the formula (IFZ6-12)	2.3	3
Example 193Z6	A compound represented by the formula (IFZ6-31)	2.3	3
				Example 194Z6	A compound represented by the formula (IJZ6-1)	2.3	3
Example 195Z6	A compound represented by the formula (IJZ6-2)	2.3	3
				Example 196Z6	A compound represented by the formula (IJZ6-3)	2.3	3
Example 197Z6	A compound represented by the formula (IJZ6-4)	2.3	3
				Example 198Z6	A compound represented by the formula (IJZ6-6)	2.3	3
Example 199Z6	A compound represented by the formula (IJZ6-10)	2.3	3
				Example 200Z6	A compound represented by the formula (IJZ6-11)	2.3	3
Example 201Z6	A compound represented by the formula (IJZ6-12)	2.3	3
				Example 202Z6	A compound represented by the formula (IJZ6-31)	2.3	3

In example Z6, it is understood from the above results that the retardation value of the colored coating film formed from the colored curable composition containing the compound of the present invention is smaller than that of the colored coating film formed from the colored curable composition containing c.i. pigment yellow 185.

Industrial applicability

The coloring composition and the compound of the present invention can be used for forming a color filter having a small phase difference value, and thus can be suitably used for a display device such as a color filter and a liquid crystal display device.

Claims (13)

1. A coloring composition comprising:

an alkali-soluble resin, and

a compound represented by formula (IZ 3);

in the formula (IZ3), R^1Z3、R^2Z3、R^3Z3、R^4Z3、R^5Z3、R^6Z3And R^7Z3Independently of one another, represents a hydrogen atom, -CO-R^102Z3、-COO-R^101Z3、-OCO-R^102Z3、-COCO-R^102Z3、-O-R^102Z3、-SO₂-R^101Z3、-SO₂N(R^102Z3)₂、-CON(R^102Z3)₂、-N(R^102Z3)₂、-NHCO-R^102Z3、-NHCO-N(R^102Z3)₂、-NHCOOR^102Z3、-OCON(R^102Z3)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent;

R^2Z3and R^3Z3、R^3Z3And R^4Z3And R^4Z3And R^5Z3May be bonded to each other to form a ring;

R^101Z3represents an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group;

R^102Z3represents a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group;

m represents a hydrogen atom or an alkali metal atom;

R^101Z3、R^102Z3and when there are a plurality of M, they may be the same or different; the wavy line indicates the E-body or the Z-body.

2. The coloring composition according to claim 1, wherein R^1Z3、R^6Z3And R^7Z3Is a hydrogen atom.

3. The coloring composition according to claim 1 or 2, wherein R^2Z3、R^3Z3、R^4Z3And R^5Z3At least one of which is-CO-R^102Z3、-COO-R^101Z3、-OCO-R^102Z3、-COCO-R^102Z3、-O-R^102Z3、-SO₂-R^101Z3、-SO₂N(R^102Z3)₂、-CON(R^102Z3)₂、-N(R^102Z3)₂、-NHCO-R^102Z3、-NHCO-N(R^102Z3)₂、-NHCOOR^102Z3、-OCON(R^102Z3)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent, or R is^2Z3And R^3Z3、R^3Z3And R ^4Z3And R^4Z3And R^5Z3At least one group of them is bonded to form a ring.

4. A coloring composition according to any one of claims 1 to 3, wherein R^2Z3、R^3Z3、R^4Z3And R^5Z3At least one of which is nitro or tert-butyl.

5. The coloring composition according to any one of claims 1 to 4, further comprising a solvent.

6. The coloring composition according to any one of claims 1 to 5, further comprising a yellow colorant or a green colorant.

7. A colored curable composition comprising a polymerizable compound and the colored composition according to any one of claims 1 to 6.

8. The colored curable composition according to claim 7, further comprising a polymerization initiator.

9. A color filter comprising the colored composition according to any one of claims 1 to 6 or the colored curable composition according to claim 7 or 8.

10. A liquid crystal display device comprising the color filter of claim 9.

11. A compound represented by the formula (IZ 3-B);

in the formula (IZ3-B), R^1Z3、R^21Z3、R^31Z3、R^41Z3、R^51Z3、R^61Z3And R^71Z3Independently of one another, represents a hydrogen atom, -CO-R^102Z3、-COO-R^101Z3、-OCO-R^102Z3、-COCO-R^102Z3、-O-R^102Z3、-SO₂-R^101Z3、-SO₂N(R^102Z3)₂、-CON(R^102Z3)₂、-N(R^102Z3)₂、-NHCO-R^102Z3、-NHCO-N(R^102Z3)₂、-NHCOOR^102Z3、-OCON(R^102Z3)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent;

R^21Z3And R^31Z3、R^31Z3And R^41Z3And R^41Z3And R^51Z3May be bonded to each other to form a ring;

wherein R is^21Z3、R^31Z3、R^41Z3And R^51Z3At least one of which is-CO-R^102Z3、-COO-R^101Z3、-OCO-R^102Z3、-COCO-R^102Z3、-O-R^102Z3、-SO₂-R^101Z3、-SO₂N(R^102Z3)₂、-CON(R^102Z3)₂、-N(R^102Z3)₂、-NHCO-R^102Z3、-NHCO-N(R^102Z3)₂、-NHCOOR^102Z3、-OCON(R^102Z3)₂Halogen atom, cyano group, nitro group, -SO₃M、-CO₂M is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent, or R is^21Z3And R^31Z3、R^31Z3And R^41Z3And R^41Z3And R^51Z3At least one group of them is bonded to form a ring;

R^101Z3represents an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group;

R^102Z3represents a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group;

m represents a hydrogen atom or an alkali metal atom;

R^101Z3、R^102Z3and when there are a plurality of M, they may be the same or different; the wavy line indicates the E-body or the Z-body.

12. The compound of claim 11Wherein R is^1Z3、R^61Z3And R^71Z3Is a hydrogen atom.

13. The compound of claim 11 or 12, wherein R^21Z3、R^31Z3、R^41Z3And R^51Z3At least one of which is nitro or tert-butyl.