JP2018062644A - Coloring composition and compound - Google Patents

Abstract

PROBLEM TO BE SOLVED: To solve the problem in which there is a high phase difference value in a color filter formed from a coloring curable resin composition containing C.I. Pigment Yellow 185, and provide a coloring composition that gives a color filter with small phase difference.SOLUTION: A coloring composition contains an isoindoline compound illustrated by formula (IZ3-1), and at least one of a resin and a solvent.SELECTED DRAWING: None

Description

  The present invention relates to colored compositions and compounds.

  Colored curable compositions are used in the manufacture of color filters used in display devices such as liquid crystal display devices and electroluminescence display devices. Examples of the colorant contained in such a colored curable composition include C.I. I. Pigment Yellow 185 is known (Patent Document 1).

Japanese Patent Laid-Open No. 2006-66020

  Conventionally known C.I. I. A color filter formed from a colored curable resin composition containing CI Pigment Yellow 185 has a problem of a large retardation value.

［式（ＩＺ１）中、
Ｒ^O1Z1は、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^1Z1、Ｒ^2Z1、Ｒ^3Z1、Ｒ^4Z1、Ｒ^5Z1、Ｒ^6Z1、及びＲ^7Z1は、互いに独立に、水素原子、−ＣＯ−Ｒ^102Z1、−ＣＯＯ−Ｒ^101Z1、−ＯＣＯ−Ｒ^102Z1、−ＣＯＣＯ−Ｒ^102Z1、−Ｏ−Ｒ^102Z1、−ＳＯ₂−Ｒ^101Z1、−ＳＯ₂Ｎ（Ｒ^102Z1）₂、−ＣＯＮ（Ｒ^102Z1）₂、−Ｎ（Ｒ^102Z1）₂、−ＮＨＣＯ−Ｒ^102Z1、−ＮＨＣＯ−Ｎ（Ｒ^102Z1）₂、−ＮＨＣＯＯＲ^102Z1、−ＯＣＯＮ（Ｒ^102Z1）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^2Z1とＲ^3Z1、Ｒ^3Z1とＲ^4Z1、及びＲ^4Z1とＲ^5Z1は、それぞれ互いに結合して環を形成してもよい。
Ｒ^101Z1は、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102Z1は、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、水素原子又はアルカリ金属原子を表す。
Ｒ^101Z1、Ｒ^102Z1及びＭが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
波線は、Ｅ体又はＺ体を表す。］

［式（ＩＺ２）中、
Ｒ^CO1Z2及びＲ^CO2Z2は、互いに独立に、−Ｏ−Ｒ^O1Z2又は−ＮＲ^N1Z2Ｒ^N2Z2を表す。
Ｒ^N1Z2、Ｒ^N2Z2、Ｒ^1Z2、Ｒ^2Z2、Ｒ^3Z2、Ｒ^4Z2、及びＲ^5Z2は、互いに独立に、水素原子、−ＣＯ−Ｒ^102Z2、−ＣＯＯ−Ｒ^101Z2、−ＯＣＯ−Ｒ^102Z2、−ＣＯＣＯ−Ｒ^102Z2、−Ｏ−Ｒ^102Z2、−ＳＯ₂−Ｒ^101Z2、−ＳＯ₂Ｎ（Ｒ^102Z2）₂、−ＣＯＮ（Ｒ^102Z2）₂、−Ｎ（Ｒ^102Z2）₂、−ＮＨＣＯ−Ｒ^102Z2、−ＮＨＣＯ−Ｎ（Ｒ^102Z2）₂、−ＮＨＣＯＯＲ^102Z2、−ＯＣＯＮ（Ｒ^102Z2）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^2Z2とＲ^3Z2、Ｒ^3Z2とＲ^4Z2、及びＲ^4Z2とＲ^5Z2は、それぞれ互いに結合して環を形成してもよい。
Ｒ^101Z2は、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^O1Z2及びＲ^102Z2は、互いに独立に、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、水素原子又はアルカリ金属原子を表す。
Ｒ^O1Z2、Ｒ^N1Z2、Ｒ^N2Z2、Ｒ^101Z2、Ｒ^102Z2及びＭが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
波線は、Ｅ体又はＺ体を表す。］

［式（ＩＺ３）中、
Ｒ^1Z3、Ｒ^2Z3、Ｒ^3Z3、Ｒ^4Z3、Ｒ^5Z3、Ｒ^6Z3、及びＲ^7Z3は、互いに独立に、水素原子、−ＣＯ−Ｒ^102Z3、−ＣＯＯ−Ｒ^101Z3、−ＯＣＯ−Ｒ^102Z3、−ＣＯＣＯ−Ｒ^102Z3、−Ｏ−Ｒ^102Z3、−ＳＯ₂−Ｒ^101Z3、−ＳＯ₂Ｎ（Ｒ^102Z3）₂、−ＣＯＮ（Ｒ^102Z3）₂、−Ｎ（Ｒ^102Z3）₂、−ＮＨＣＯ−Ｒ^102Z3、−ＮＨＣＯ−Ｎ（Ｒ^102Z3）₂、−ＮＨＣＯＯＲ^102Z3、−ＯＣＯＮ（Ｒ^102Z3）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^2Z3とＲ^3Z3、Ｒ^3Z3とＲ^4Z3、及びＲ^4Z3とＲ^5Z3は、それぞれ互いに結合して環を形成してもよい。
Ｒ^101Z3は、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102Z3は、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、水素原子又はアルカリ金属原子を表す。
Ｒ^101Z3、Ｒ^102Z3及びＭが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
波線は、Ｅ体又はＺ体を表す。］

［式（ＩＺ４）中、
Ｒ^N1Z4及びＲ^N2Z4は、互いに独立に、−ＣＯ−Ｒ^102Z4、−ＣＯＯ−Ｒ^101Z4、−ＯＣＯ−Ｒ^102Z4、−ＣＯＣＯ−Ｒ^102Z4、−Ｏ−Ｒ^102Z4、−ＳＯ₂−Ｒ^101Z4、−ＳＯ₂Ｎ（Ｒ^102Z4）₂、−ＣＯＮ（Ｒ^102Z4）₂、−Ｎ（Ｒ^102Z4）₂、−ＮＨＣＯ−Ｒ^102Z4、−ＮＨＣＯ−Ｎ（Ｒ^102Z4）₂、−ＮＨＣＯＯＲ^102Z4、−ＯＣＯＮ（Ｒ^102Z4）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^1Z4、Ｒ^2Z4、Ｒ^3Z4、Ｒ^4Z4、Ｒ^5Z4、Ｒ^6Z4、及びＲ^7Z4は、互いに独立に、水素原子、−ＣＯ−Ｒ^102Z4、−ＣＯＯ−Ｒ^101Z4、−ＯＣＯ−Ｒ^102Z4、−ＣＯＣＯ−Ｒ^102Z4、−Ｏ−Ｒ^102Z4、−ＳＯ₂−Ｒ^101Z4、−ＳＯ₂Ｎ（Ｒ^102Z4）₂、−ＣＯＮ（Ｒ^102Z4）₂、−Ｎ（Ｒ^102Z4）₂、−ＮＨＣＯ−Ｒ^102Z4、−ＮＨＣＯ−Ｎ（Ｒ^102Z4）₂、−ＮＨＣＯＯＲ^102Z4、−ＯＣＯＮ（Ｒ^102Z4）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^2Z4とＲ^3Z4、Ｒ^3Z4とＲ^4Z4、及びＲ^4Z4とＲ^5Z4は、それぞれ互いに結合して環を形成してもよい。
Ｒ^101Z4は、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102Z4は、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、水素原子又はアルカリ金属原子を表す。
Ｒ^101Z4、Ｒ^102Z4及びＭが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
波線は、Ｅ体又はＺ体を表す。］

［式（ＩＺ５）中、
Ｒ^N1Z5は、−ＣＯ−Ｒ^102Z5、−ＣＯＯ−Ｒ^101Z5、−ＯＣＯ−Ｒ^102Z5、−ＣＯＣＯ−Ｒ^102Z5、−Ｏ−Ｒ^102Z5、−ＳＯ₂−Ｒ^101Z5、−ＳＯ₂Ｎ（Ｒ^102Z5）₂、−ＣＯＮ（Ｒ^102Z5）₂、−Ｎ（Ｒ^102Z5）₂、−ＮＨＣＯ−Ｒ^102Z5、−ＮＨＣＯ−Ｎ（Ｒ^102Z5）₂、−ＮＨＣＯＯＲ^102Z5、−ＯＣＯＮ（Ｒ^102Z5）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^1Z5、Ｒ^2Z5、Ｒ^3Z5、Ｒ^4Z5、Ｒ^5Z5、Ｒ^6Z5、及びＲ^7Z5は、互いに独立に、水素原子、−ＣＯ−Ｒ^102Z5、−ＣＯＯ−Ｒ^101Z5、−ＯＣＯ−Ｒ^102Z5、−ＣＯＣＯ−Ｒ^102Z5、−Ｏ−Ｒ^102Z5、−ＳＯ₂−Ｒ^101Z5、−ＳＯ₂Ｎ（Ｒ^102Z5）₂、−ＣＯＮ（Ｒ^102Z5）₂、−Ｎ（Ｒ^102Z5）₂、−ＮＨＣＯ−Ｒ^102Z5、−ＮＨＣＯ−Ｎ（Ｒ^102Z5）₂、−ＮＨＣＯＯＲ^102Z5、−ＯＣＯＮ（Ｒ^102Z5）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表し、Ｒ^2Z5とＲ^3Z5、Ｒ^3Z5とＲ^4Z5、及びＲ^4Z5とＲ^5Z5は、それぞれ互いに結合して環を形成してもよく、Ｒ^2Z5、Ｒ^3Z5、Ｒ^4Z5及びＲ^5Z5の少なくとも一つは、−ＣＯ−Ｒ^102Z5、−ＣＯＯ−Ｒ^101Z5、−ＯＣＯ−Ｒ^102Z5、−ＣＯＣＯ−Ｒ^102Z5、−Ｏ−Ｒ^102Z5、−ＳＯ₂−Ｒ^101Z5、−ＳＯ₂Ｎ（Ｒ^102Z5）₂、−ＣＯＮ（Ｒ^102Z5）₂、−Ｎ（Ｒ^102Z5）₂、−ＮＨＣＯ−Ｒ^102Z5、−ＮＨＣＯ−Ｎ（Ｒ^102Z5）₂、−ＮＨＣＯＯＲ^102Z5、−ＯＣＯＮ（Ｒ^102Z5）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基若しくは置換基を有していてもよい複素環基であるか、又はＲ^2Z5とＲ^3Z5、Ｒ^3Z5とＲ^4Z5、及びＲ^4Z5とＲ^5Z5の少なくとも一組が、結合して環を形成している。
Ｒ^101Z5は、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102Z5は、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、水素原子又はアルカリ金属原子を表す。
Ｒ^101Z5、Ｒ^102Z5及びＭが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
波線は、Ｅ体又はＺ体を表す。］

［式（ＩＺ６）中、
Ｄは、イソインドリン骨格を有する構造を表す。
Ｚは、−ＳＯ₃ ^-又は−ＣＯ₂ ^-を表す。
Ａ^c+は、ｃ価の金属陽イオンを表す。
ａは、１〜１０の整数を表す。
ｂは、１以上の整数を表す。
ｃは、２〜１０の整数を表す。
ｄは、１以上の整数を表す。
Ｄ、Ｚ、ａ又はＡ^c+が複数存在する場合、それらはそれぞれ同一であってもよく、異なっていてもよい。
式（Ｉ’Ｚ６）及び式（Ｉ’’Ｚ６）は、それぞれ、式（ＩＺ６）の部分構造を表し、Ｄ、Ｚ、Ａ^c+、ａ、ｂ、ｃ及びｄは、式（ＩＺ６）におけるものと同じものを表す。
ただし、式（Ｉ’Ｚ６）で表される部分構造が有する負の価数と、式（Ｉ’’Ｚ６）で表される部分構造が有する正の価数の絶対値は同じである。］
［２］
式（ＩＺ１）で表される化合物、式（ＩＺ２）で表される化合物、又は式（ＩＺ３）で表される化合物と、樹脂とを含む［１］に記載の着色組成物。
［３］
式（ＩＺ４）で表される化合物、式（ＩＺ５）で表される化合物、又は式（ＩＺ６）で表される化合物と、溶剤とを含む［１］に記載の着色組成物。
［４］
式（ＩＺ１）で表される化合物を含み、Ｒ^1Z1、Ｒ^6Z1及びＲ^7Z1が、水素原子である［１］又は［２］に記載の着色組成物。
［５］
式（ＩＺ１）で表される化合物を含み、Ｒ^O1Z1が、水素原子或いは置換基を有していてもよい炭素数１〜１０の炭化水素基である［１］〜［２］又は［４］記載の着色組成物。
［６］
式（ＩＺ１）で表される化合物を含み、Ｒ^2Z1、Ｒ^3Z1、Ｒ^4Z1、及びＲ^5Z1の少なくとも一つが、
−ＣＯ−Ｒ^102Z1、−ＣＯＯ−Ｒ^101Z1、−ＯＣＯ−Ｒ^102Z1、−ＣＯＣＯ−Ｒ^102Z1、−Ｏ−Ｒ^102Z1、−ＳＯ₂−Ｒ^101Z1、−ＳＯ₂Ｎ（Ｒ^102Z1）₂、−ＣＯＮ（Ｒ^102Z1）₂、−Ｎ（Ｒ^102Z1）₂、−ＮＨＣＯ−Ｒ^102Z1、−ＮＨＣＯ−Ｎ（Ｒ^102Z1）₂、−ＮＨＣＯＯＲ^102Z1、−ＯＣＯＮ（Ｒ^102Z1）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基であるか、又はＲ^2Z1とＲ^3Z1、Ｒ^3Z1とＲ^4Z1、及びＲ^4Z1とＲ^5Z1の少なくとも一組が結合して環を形成している［１］〜［２］、［４］又は［５］に記載の着色組成物。
［７］
式（ＩＺ１）で表される化合物を含み、Ｒ^2Z1、Ｒ^3Z1、Ｒ^4Z1、及びＲ^5Z1の少なくとも一つが、ニトロ基又はｔｅｒｔ−ブチル基である［１］〜［２］又は［４］〜［６］のいずれかに記載の着色組成物。
［８］
式（ＩＺ２）で表される化合物を含み、Ｒ^O1Z2、Ｒ^N1Z2及びＲ^N2Z2が、互いに独立に、水素原子又は置換基を有していてもよい炭素数１〜１０の炭化水素基である［１］又は［２］に記載の着色組成物。
［９］
式（ＩＺ２）で表される化合物を含み、Ｒ^1Z2が水素原子である［１］〜［２］又は［８］に記載の着色組成物。
［１０］
式（ＩＺ２）で表される化合物を含み、Ｒ^2Z2、Ｒ^3Z2、Ｒ^4Z2、及びＲ^5Z2の少なくとも一つが、−ＣＯ−Ｒ^102Z2、−ＣＯＯ−Ｒ^101Z2、−ＯＣＯ−Ｒ^102Z2、−ＣＯＣＯ−Ｒ^102Z2、−Ｏ−Ｒ^102Z2、−ＳＯ₂−Ｒ^101Z2、−ＳＯ₂Ｎ（Ｒ^102Z2）₂、−ＣＯＮ（Ｒ^102Z2）₂、−Ｎ（Ｒ^102Z2）₂、−ＮＨＣＯ−Ｒ^102Z2、−ＮＨＣＯ−Ｎ（Ｒ^102Z2）₂、−ＮＨＣＯＯＲ^102Z2、−ＯＣＯＮ（Ｒ^102Z2）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基であるか、又はＲ^2Z2とＲ^3Z2、Ｒ^3Z2とＲ^4Z2、及びＲ^4Z2とＲ^5Z2の少なくとも一組が結合して環を形成している［１］〜［２］、［８］又は［９］に記載の着色組成物。
［１１］
式（ＩＺ２）で表される化合物を含み、Ｒ^2Z2、Ｒ^3Z2、Ｒ^4Z2、及びＲ^5Z2の少なくとも一つが、ニトロ基又はｔｅｒｔ−ブチル基である［１］〜［２］又は［８］〜［１０］のいずれかに記載の着色組成物。
［１２］
式（ＩＺ３）で表される化合物を含み、Ｒ^1Z3、Ｒ^6Z3及びＲ^7Z3が、水素原子である［１］又は［２］に記載の着色組成物。
［１３］
式（ＩＺ３）で表される化合物を含み、Ｒ^2Z3、Ｒ^3Z3、Ｒ^4Z3、及びＲ^5Z3の少なくとも一つが、−ＣＯ−Ｒ^102Z3、−ＣＯＯ−Ｒ^101Z3、−ＯＣＯ−Ｒ^102Z3、−ＣＯＣＯ−Ｒ^102Z3、−Ｏ−Ｒ^102Z3、−ＳＯ₂−Ｒ^101Z3、−ＳＯ₂Ｎ（Ｒ^102Z3）₂、−ＣＯＮ（Ｒ^102Z3）₂、−Ｎ（Ｒ^102Z3）₂、−ＮＨＣＯ−Ｒ^102Z3、−ＮＨＣＯ−Ｎ（Ｒ^102Z3）₂、−ＮＨＣＯＯＲ^102Z3、−ＯＣＯＮ（Ｒ^102Z3）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基或いは置換基を有していてもよい複素環基であるか、又はＲ^2Z3とＲ^3Z3、Ｒ^3Z3とＲ^4Z3、及びＲ^4Z3とＲ^5Z3の少なくとも一組が結合して環を形成している［１］〜［２］又は［１２］に記載の着色組成物。
［１４］
式（ＩＺ３）で表される化合物を含み、Ｒ^2Z3、Ｒ^3Z3、Ｒ^4Z3、及びＲ^5Z3の少なくとも一つが、ニトロ基又はｔｅｒｔ−ブチル基である［１］〜［２］、［１２］又は［１３］に記載の着色組成物。
［１５］
樹脂と溶剤の両方を含む［１］〜［１４］のいずれかに記載の着色組成物。
［１６］
さらに、黄色着色剤又は緑色着色剤を含む［１］〜［１５］のいずれかに記載の着色組成物。
［１７］
［１］〜［１６］のいずれか記載の着色組成物、及び重合性化合物を含む着色硬化性組成物。
［１８］
さらに、重合開始剤を含む［１７］に記載の着色硬化性組成物。
［１９］
［１］〜［１６］のいずれかに記載の着色組成物又は［１７］或いは［１８］に記載の着色硬化性組成物から形成されたカラーフィルタ。
［２０］
［１９］に記載のカラーフィルタを含む液晶表示装置。
［２１］
式（ＩＺ１−Ｂ）で表される化合物。

［式（ＩＺ１−Ｂ）中、
Ｒ^O11Z1は、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^1Z1、Ｒ^21Z1、Ｒ^31Z1、Ｒ^41Z1、Ｒ^51Z1、Ｒ^61Z1、及びＲ^71Z1は、互いに独立に、水素原子、−ＣＯ−Ｒ^102Z1、−ＣＯＯ−Ｒ^101Z1、−ＯＣＯ−Ｒ^102Z1、−ＣＯＣＯ−Ｒ^102Z1、−Ｏ−Ｒ^102Z1、−ＳＯ₂−Ｒ^101Z1、−ＳＯ₂Ｎ（Ｒ^102Z1）₂、−ＣＯＮ（Ｒ^102Z1）₂、−Ｎ（Ｒ^102Z1）₂、−ＮＨＣＯ−Ｒ^102Z1、−ＮＨＣＯ−Ｎ（Ｒ^102Z1）₂、−ＮＨＣＯＯＲ^102Z1、−ＯＣＯＮ（Ｒ^102Z1）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^21Z1とＲ^31Z1、Ｒ^31Z1とＲ^41Z1、及びＲ^41Z1とＲ^51Z1は、それぞれ互いに結合して環を形成してもよい。
ただし、Ｒ^21Z1、Ｒ^31Z1、Ｒ^41Z1、及びＲ^51Z1の少なくとも一つは、−ＣＯ−Ｒ^102Z1、−ＣＯＯ−Ｒ^101Z1、−ＯＣＯ−Ｒ^102Z1、−ＣＯＣＯ−Ｒ^102Z1、−Ｏ−Ｒ^102Z1、−ＳＯ₂−Ｒ^101Z1、−ＳＯ₂Ｎ（Ｒ^102Z1）₂、−ＣＯＮ（Ｒ^102Z1）₂、−Ｎ（Ｒ^102Z1）₂、−ＮＨＣＯ−Ｒ^102Z1、−ＮＨＣＯ−Ｎ（Ｒ^102Z1）₂、−ＮＨＣＯＯＲ^102Z1、−ＯＣＯＮ（Ｒ^102Z1）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基であるか、又はＲ^21Z1とＲ^31Z1、Ｒ^31Z1とＲ^41Z1、及びＲ^41Z1とＲ^51Z1の少なくとも一組が結合して環を形成している。
Ｒ^101Z1は、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102Z1は、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、水素原子又はアルカリ金属原子を表す。
Ｒ^101Z1、Ｒ^102Z1及びＭが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
波線は、Ｅ体又はＺ体を表す。］
［２２］
Ｒ^1Z1、Ｒ^61Z1及びＲ^71Z1が、水素原子である［２１］に記載の化合物。
［２３］
Ｒ^O11Z1が、水素原子或いは置換基を有していてもよい炭素数１〜１０の炭化水素基である［２１］又は［２２］に記載の化合物。
［２４］
Ｒ^21Z1、Ｒ^31Z1、Ｒ^41Z1、及びＲ^51Z1の少なくとも一つが、ニトロ基又はｔｅｒｔ−ブチル基である［２１］〜［２３］のいずれかに記載の化合物。
［２５］
式（ＩＺ２−Ｂ）で表される化合物。

［式（ＩＺ２−Ｂ）中、
Ｒ^CO11Z2及びＲ^CO21Z2は、互いに独立に、−Ｏ−Ｒ^O1Z2又は−ＮＲ^N1Z2Ｒ^N2Z2を表し、Ｒ^CO11Z2及びＲ^CO21Z2の少なくとも一つは、−ＮＲ^N1Z2Ｒ^N2Z2である。
Ｒ^N1Z2、Ｒ^N2Z2、Ｒ^1Z2、Ｒ^21Z2、Ｒ^31Z2、Ｒ^41Z2及びＲ^51Z2は、互いに独立に、水素原子、−ＣＯ−Ｒ^102Z2、−ＣＯＯ−Ｒ^101Z2、−ＯＣＯ−Ｒ^102Z2、−ＣＯＣＯ−Ｒ^102Z2、−Ｏ−Ｒ^102Z2、−ＳＯ₂−Ｒ^101Z2、−ＳＯ₂Ｎ（Ｒ^102Z2）₂、−ＣＯＮ（Ｒ^102Z2）₂、−Ｎ（Ｒ^102Z2）₂、−ＮＨＣＯ−Ｒ^102Z2、−ＮＨＣＯ−Ｎ（Ｒ^102Z2）₂、−ＮＨＣＯＯＲ^102Z2、−ＯＣＯＮ（Ｒ^102Z2）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表し、Ｒ^21Z2とＲ^31Z2、Ｒ^31Z2とＲ^41Z2、及びＲ^41Z2とＲ^51Z2は、それぞれ互いに結合して環を形成してもよく、
Ｒ^21Z2、Ｒ^31Z2、Ｒ^41Z2及びＲ^51Z2の少なくとも一つは、−ＣＯ−Ｒ^102Z2、−ＣＯＯ−Ｒ^101Z2、−ＯＣＯ−Ｒ^102Z2、−ＣＯＣＯ−Ｒ^102Z2、−Ｏ−Ｒ^102Z2、−ＳＯ₂−Ｒ^101Z2、−ＳＯ₂Ｎ（Ｒ^102Z2）₂、−ＣＯＮ（Ｒ^102Z2）₂、−Ｎ（Ｒ^102Z2）₂、−ＮＨＣＯ−Ｒ^102Z2、−ＮＨＣＯ−Ｎ（Ｒ^102Z2）₂、−ＮＨＣＯＯＲ^102Z2、−ＯＣＯＮ（Ｒ^102Z2）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基であるか、又はＲ^21Z2とＲ^31Z2、Ｒ^31Z2とＲ^41Z2、及びＲ^41Z2とＲ^51Z2の少なくとも一組が、結合して環を形成している。
Ｒ^101Z2は、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^O1Z2及びＲ^102Z2は、互いに独立に、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、水素原子又はアルカリ金属原子を表す。
Ｒ^O1Z2、Ｒ^N1Z2、Ｒ^N2Z2、Ｒ^101Z2、Ｒ^102Z2及びＭが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
波線は、Ｅ体又はＺ体を表す。］
［２６］
Ｒ^O1Z2、Ｒ^N1Z2及びＲ^N2Z2が、水素原子又は置換基を有していてもよい炭素数１〜１０の炭化水素基である［２５］に記載の化合物。
［２７］
Ｒ^1Z2が、水素原子である［２５］又は［２６］に記載の化合物。
［２８］
Ｒ^21Z2、Ｒ^31Z2、Ｒ^41Z2及びＲ^51Z2の少なくとも一つが、ニトロ基又はｔｅｒｔ−ブチル基である［２５］〜［２７］のいずれかに記載の化合物。
［２９］
式（ＩＺ３−Ｂ）で表される化合物。

［式（ＩＺ３−Ｂ）中、
Ｒ^1Z3、Ｒ^21Z3、Ｒ^31Z3、Ｒ^41Z3、Ｒ^51Z3、Ｒ^61Z3、及びＲ^71Z3は、互いに独立に、水素原子、−ＣＯ−Ｒ^102Z3、−ＣＯＯ−Ｒ^101Z3、−ＯＣＯ−Ｒ^102Z3、−ＣＯＣＯ−Ｒ^102Z3、−Ｏ−Ｒ^102Z3、−ＳＯ₂−Ｒ^101Z3、−ＳＯ₂Ｎ（Ｒ^102Z3）₂、−ＣＯＮ（Ｒ^102Z3）₂、−Ｎ（Ｒ^102Z3）₂、−ＮＨＣＯ−Ｒ^102Z3、−ＮＨＣＯ−Ｎ（Ｒ^102Z3）₂、−ＮＨＣＯＯＲ^102Z3、−ＯＣＯＮ（Ｒ^102Z3）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^21Z3とＲ^31Z3、Ｒ^31Z3とＲ^41Z3、及びＲ^41Z3とＲ^51Z3は、それぞれ互いに結合して環を形成してもよい。
ただし、Ｒ^21Z3、Ｒ^31Z3、Ｒ^41Z3、及びＲ^51Z3の少なくとも一つは、−ＣＯ−Ｒ^102Z3、−ＣＯＯ−Ｒ^101Z3、−ＯＣＯ−Ｒ^102Z3、−ＣＯＣＯ−Ｒ^102Z3、−Ｏ−Ｒ^102Z3、−ＳＯ₂−Ｒ^101Z3、−ＳＯ₂Ｎ（Ｒ^102Z3）₂、−ＣＯＮ（Ｒ^102Z3）₂、−Ｎ（Ｒ^102Z3）₂、−ＮＨＣＯ−Ｒ^102Z3、−ＮＨＣＯ−Ｎ（Ｒ^102Z3）₂、−ＮＨＣＯＯＲ^102Z3、−ＯＣＯＮ（Ｒ^102Z3）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基或いは置換基を有していてもよい複素環基であるか、又はＲ^21Z3とＲ^31Z3、Ｒ^31Z3とＲ^41Z3、及びＲ^41Z3とＲ^51Z3の少なくとも一組が結合して環を形成している。
Ｒ^101Z3は、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102Z3は、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、水素原子又はアルカリ金属原子を表す。
Ｒ^101Z3、Ｒ^102Z3及びＭが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
波線は、Ｅ体又はＺ体を表す。］
［３０］
Ｒ^1Z3、Ｒ^61Z3及びＲ^71Z3が、水素原子である［２９］に記載の化合物。
［３１］
Ｒ^21Z3、Ｒ^31Z3、Ｒ^41Z3、及びＲ^51Z3の少なくとも一つが、ニトロ基又はｔｅｒｔ−ブチル基である［２９］又は［３０］に記載の化合物。
［３２］
式（ＩＺ４）で表される化合物。

［式（ＩＺ４）中、
Ｒ^N1Z4及びＲ^N2Z4は、互いに独立に、−ＣＯ−Ｒ^102Z4、−ＣＯＯ−Ｒ^101Z4、−ＯＣＯ−Ｒ^102Z4、−ＣＯＣＯ−Ｒ^102Z4、−Ｏ−Ｒ^102Z4、−ＳＯ₂−Ｒ^101Z4、−ＳＯ₂Ｎ（Ｒ^102Z4）₂、−ＣＯＮ（Ｒ^102Z4）₂、−Ｎ（Ｒ^102Z4）₂、−ＮＨＣＯ−Ｒ^102Z4、−ＮＨＣＯ−Ｎ（Ｒ^102Z4）₂、−ＮＨＣＯＯＲ^102Z4、−ＯＣＯＮ（Ｒ^102Z4）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^1Z4、Ｒ^2Z4、Ｒ^3Z4、Ｒ^4Z4、Ｒ^5Z4、Ｒ^6Z4、及びＲ^7Z4は、互いに独立に、水素原子、−ＣＯ−Ｒ^102Z4、−ＣＯＯ−Ｒ^101Z4、−ＯＣＯ−Ｒ^102Z4、−ＣＯＣＯ−Ｒ^102Z4、−Ｏ−Ｒ^102Z4、−ＳＯ₂−Ｒ^101Z4、−ＳＯ₂Ｎ（Ｒ^102Z4）₂、−ＣＯＮ（Ｒ^102Z4）₂、−Ｎ（Ｒ^102Z4）₂、−ＮＨＣＯ−Ｒ^102Z4、−ＮＨＣＯ−Ｎ（Ｒ^102Z4）₂、−ＮＨＣＯＯＲ^102Z4、−ＯＣＯＮ（Ｒ^102Z4）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^2Z4とＲ^3Z4、Ｒ^3Z4とＲ^4Z4、及びＲ^4Z4とＲ^5Z4は、それぞれ互いに結合して環を形成してもよい。
Ｒ^101Z4は、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102Z4は、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、水素原子又はアルカリ金属原子を表す。
Ｒ^101Z4、Ｒ^102Z4及びＭが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
波線は、Ｅ体又はＺ体を表す。］
［３３］
Ｒ^1Z4、Ｒ^6Z4及びＲ^7Z4が、水素原子である［３２］に記載の化合物。
［３４］
Ｒ^N1Z4及びＲ^N2Z4が、互いに独立に、置換基を有していてもよい炭素数１〜１０の炭化水素基である［３２］又は［３３］に記載の化合物。
［３５］
Ｒ^2Z4、Ｒ^3Z4、Ｒ^4Z4、及びＲ^5Z4の少なくとも一つが、−ＣＯ−Ｒ^102Z4、−ＣＯＯ−Ｒ^101Z4、−ＯＣＯ−Ｒ^102Z4、ＣＯＣＯ−Ｒ^102Z4、−Ｏ−Ｒ^102Z4、−ＳＯ₂−Ｒ^101Z4、−ＳＯ₂Ｎ（Ｒ^102Z4）₂、−ＣＯＮ（Ｒ^102Z4）₂、−Ｎ（Ｒ^102Z4）₂、−ＮＨＣＯ−Ｒ^102Z4、−ＮＨＣＯ−Ｎ（Ｒ^102Z4）₂、−ＮＨＣＯＯＲ^102Z4、−ＯＣＯＮ（Ｒ^102Z4）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基或いは置換基を有していてもよい複素環基であるか、又はＲ^2Z4とＲ^3Z4、Ｒ^3Z4とＲ^4Z4、及びＲ^4Z4とＲ^5Z4の少なくとも一組が結合して環を形成している［３２］〜［３４］のいずれかに記載の化合物。
［３６］
Ｒ^2Z4、Ｒ^3Z4、Ｒ^4Z4、及びＲ^5Z4の少なくとも一つが、ニトロ基又はｔｅｒｔ−ブチル基である［３２］〜［３５］のいずれかに記載の化合物。
［３７］
式（ＩＺ５）で表される化合物。

［式（ＩＺ５）中、
Ｒ^N1Z5は、−ＣＯ−Ｒ^102Z5、−ＣＯＯ−Ｒ^101Z5、−ＯＣＯ−Ｒ^102Z5、−ＣＯＣＯ−Ｒ^102Z5、−Ｏ−Ｒ^102Z5、−ＳＯ₂−Ｒ^101Z5、−ＳＯ₂Ｎ（Ｒ^102Z5）₂、−ＣＯＮ（Ｒ^102Z5）₂、−Ｎ（Ｒ^102Z5）₂、−ＮＨＣＯ−Ｒ^102Z5、−ＮＨＣＯ−Ｎ（Ｒ^102Z5）₂、−ＮＨＣＯＯＲ^102Z5、−ＯＣＯＮ（Ｒ^102Z5）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^1Z5、Ｒ^2Z5、Ｒ^3Z5、Ｒ^4Z5、Ｒ^5Z5、Ｒ^6Z5、及びＲ^7Z5は、互いに独立に、水素原子、−ＣＯ−Ｒ^102Z5、−ＣＯＯ−Ｒ^101Z5、−ＯＣＯ−Ｒ^102Z5、−ＣＯＣＯ−Ｒ^102Z5、−Ｏ−Ｒ^102Z5、−ＳＯ₂−Ｒ^101Z5、−ＳＯ₂Ｎ（Ｒ^102Z5）₂、−ＣＯＮ（Ｒ^102Z5）₂、−Ｎ（Ｒ^102Z5）₂、−ＮＨＣＯ−Ｒ^102Z5、−ＮＨＣＯ−Ｎ（Ｒ^102Z5）₂、−ＮＨＣＯＯＲ^102Z5、−ＯＣＯＮ（Ｒ^102Z5）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表し、Ｒ^2Z5とＲ^3Z5、Ｒ^3Z5とＲ^4Z5、及びＲ^4Z5とＲ^5Z5は、それぞれ互いに結合して環を形成してもよく、Ｒ^2Z5、Ｒ^3Z5、Ｒ^4Z5及びＲ^5Z5の少なくとも一つは、−ＣＯ−Ｒ^102Z5、−ＣＯＯ−Ｒ^101Z5、−ＯＣＯ−Ｒ^102Z5、−ＣＯＣＯ−Ｒ^102Z5、−Ｏ−Ｒ^102Z5、−ＳＯ₂−Ｒ^101Z5、−ＳＯ₂Ｎ（Ｒ^102Z5）₂、−ＣＯＮ（Ｒ^102Z5）₂、−Ｎ（Ｒ^102Z5）₂、−ＮＨＣＯ−Ｒ^102Z5、−ＮＨＣＯ−Ｎ（Ｒ^102Z5）₂、−ＮＨＣＯＯＲ^102Z5、−ＯＣＯＮ（Ｒ^102Z5）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基若しくは置換基を有していてもよい複素環基であるか、又はＲ^2Z5とＲ^3Z5、Ｒ^3Z5とＲ^4Z5、及びＲ^4Z5とＲ^5Z5の少なくとも一組が、結合して環を形成している。
Ｒ^101Z5は、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102Z5は、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、水素原子又はアルカリ金属原子を表す。
Ｒ^101Z5、Ｒ^102Z5及びＭが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
波線は、Ｅ体又はＺ体を表す。］
［３８］
Ｒ^N1Z5が、置換基を有していてもよい炭素数１〜１０の炭化水素基である［３７］に記載の化合物。
［３９］
Ｒ^1Z5、Ｒ^6Z5及びＲ^7Z5が、水素原子である［３７］又は［３８］に記載の化合物。
［４０］
Ｒ^2Z5、Ｒ^3Z5、Ｒ^4Z5、及びＲ^5Z5の少なくとも一つが、ニトロ基又はｔｅｒｔ−ブチル基である［３７］〜［３９］のいずれかに記載の化合物。
［４１］
式（ＩＺ６）で表される化合物。

［式（ＩＺ６）中、
Ｄは、イソインドリン骨格を有する構造を表す。
Ｚは、−ＳＯ₃ ^-又は−ＣＯ₂ ^-を表す。
Ａ^c+は、ｃ価の金属陽イオンを表す。
ａは、１〜１０の整数を表す。
ｂは、１以上の整数を表す。
ｃは、２〜１０の整数を表す。
ｄは、１以上の整数を表す。
Ｄ、Ｚ、ａ又はＡ^c+が複数存在する場合、それらはそれぞれ同一であってもよく、異なっていてもよい。
式（Ｉ’Ｚ６）及び式（Ｉ’’Ｚ６）は、それぞれ、式（ＩＺ６）の部分構造を表し、Ｄ、Ｚ、Ａ^c+、ａ、ｂ、ｃ及びｄは、式（ＩＺ６）におけるものと同じものを表す。
ただし、式（Ｉ’Ｚ６）で表される部分構造が有する負の価数と、式（Ｉ’’Ｚ６）で表される部分構造が有する正の価数の絶対値は同じである。］
［４２］
式（ＩＺ６）で表される化合物が、式（ＩＺ６−Ａ）で表される化合物である［４１］に記載の化合物。

［式（ＩＺ６−Ａ）中、
Ａ^c+、ｂ、ｃ及びｄは、前記と同じ意味を表す。
Ｒ^1AZ6、Ｒ^2AZ6、Ｒ^3AZ6、Ｒ^4AZ6、Ｒ^5AZ6、Ｒ^AA1Z6、Ｒ^AA2Z6、Ｒ^12AZ6及びＲ^13AZ6は、互いに独立に、水素原子、−ＣＯ−Ｒ^102AZ6、−ＣＯＯ−Ｒ^101AZ6、−ＯＣＯ−Ｒ^102AZ6、−ＣＯＣＯ−Ｒ^102AZ6、−Ｏ−Ｒ^102AZ6、−ＳＯ₂−Ｒ^101AZ6、−ＳＯ₂Ｎ（Ｒ^102AZ6）₂、−ＣＯＮ（Ｒ^102AZ6）₂、−Ｎ（Ｒ^102AZ6）₂、−ＮＨＣＯ−Ｒ^102AZ6、−ＮＨＣＯ−Ｎ（Ｒ^102AZ6）₂、−ＮＨＣＯＯＲ^102AZ6、−ＯＣＯＮ（Ｒ^102AZ6）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、−ＳＯ₃ ^-、−ＣＯ₂ ^-、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^2AZ6とＲ^3AZ6、Ｒ^3AZ6とＲ^4AZ6、Ｒ^4AZ6とＲ^5AZ6、Ｒ^AA1Z6とＲ^AA2Z6及びＲ^12AZ6とＲ^13AZ6は、それぞれ互いに結合して環を形成してもよい。
Ｒ^101AZ6は、互いに独立に、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102AZ6は、互いに独立に、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、水素原子又はアルカリ金属原子を表す。
式（ＩＺ６−Ａ’）及び式（ＩＺ６−Ａ’’）は、それぞれ、式（ＩＺ６−Ａ）の部分構造を表し、Ａ^c+、ｂ、ｃ、ｄ、Ｒ^1AZ6、Ｒ^2AZ6、Ｒ^3AZ6、Ｒ^4AZ6、Ｒ^5AZ6、Ｒ^AA1Z6、Ｒ^AA2Z6、Ｒ^12AZ6及びＲ^13AZ6は、式（ＩＺ６−Ａ）におけるものと同じものを表す。
Ｒ^1AZ6、Ｒ^2AZ6、Ｒ^3AZ6、Ｒ^4AZ6、Ｒ^5AZ6、Ｒ^AA1Z6、Ｒ^AA2Z6、Ｒ^12AZ6、Ｒ^13AZ6、Ｒ^101AZ6、Ｒ^102AZ6、Ｍ、ｃ又はＡ^c+が複数存在する場合、それらはそれぞれ同一であってもよく、異なっていてもよい。
Ｒ^1AZ6、Ｒ^2AZ6、Ｒ^3AZ6、Ｒ^4AZ6、Ｒ^5AZ6、Ｒ^AA1Z6、Ｒ^AA2Z6、Ｒ^12AZ6、Ｒ^13AZ6、Ｒ^101AZ6及びＲ^102AZ6は、（ｒａ−ｉ）〜（ｒａ−ｉｉｉ）のうち少なくとも１つを充足しており、Ｒ^1AZ6、Ｒ^2AZ6、Ｒ^3AZ6、Ｒ^4AZ6、Ｒ^5AZ6、Ｒ^AA1Z6、Ｒ^AA2Z6、Ｒ^12AZ6、Ｒ^13AZ6、Ｒ^101AZ6及びＲ^102AZ6が有する−ＳＯ₃ ^-又は−ＣＯ₂ ^-の合計個数はａである。
（ｒａ−ｉ）Ｒ^1AZ6、Ｒ^2AZ6、Ｒ^3AZ6、Ｒ^4AZ6、Ｒ^5AZ6、Ｒ^AA1Z6、Ｒ^AA2Z6、Ｒ^12AZ6及びＲ^13AZ6の少なくとも一つが、−ＳＯ₃ ^-又は−ＣＯ₂ ^-である。
（ｒａ−ｉｉ）Ｒ^1AZ6、Ｒ^2AZ6、Ｒ^3AZ6、Ｒ^4AZ6、Ｒ^5AZ6、Ｒ^AA1Z6、Ｒ^AA2Z6、Ｒ^12AZ6及びＲ^13AZ6の少なくとも一つが、−ＣＯ−Ｒ^102AZ6、−ＣＯＯ−Ｒ^101AZ6、−ＯＣＯ−Ｒ^102AZ6、−ＣＯＣＯ−Ｒ^102AZ6、−Ｏ−Ｒ^102AZ6、−ＳＯ₂−Ｒ^101AZ6、−ＳＯ₂Ｎ（Ｒ^102AZ6）₂、−ＣＯＮ（Ｒ^102AZ6）₂、−Ｎ（Ｒ^102AZ6）₂、−ＮＨＣＯ−Ｒ^102AZ6、−ＮＨＣＯ−Ｎ（Ｒ^102AZ6）₂、−ＮＨＣＯＯＲ^102AZ6、又は−ＯＣＯＮ（Ｒ^102AZ6）₂であって、該Ｒ^101AZ6及びＲ^102AZ6が、−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する炭素数１〜４０の炭化水素基又は−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する複素環基である。ただし該炭化水素基又は該複素環基は、−ＳＯ₃ ^-及び−ＣＯ₂ ^-以外の置換基を有していてもよい。
（ｒａ−ｉｉｉ）Ｒ^1AZ6、Ｒ^2AZ6、Ｒ^3AZ6、Ｒ^4AZ6、Ｒ^5AZ6、Ｒ^AA1Z6、Ｒ^AA2Z6、Ｒ^12AZ6及びＲ^13AZ6の少なくとも一つが、−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する炭素数１〜４０の炭化水素基又は−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する複素環基である。ただし該炭化水素基及び該複素環基は、−ＳＯ₃ ^-又は−ＣＯ₂ ^-以外の置換基を有していてもよい。
ａは、式（ＩＺ６）におけるものと同じ意味を表す。ａが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
式（ＩＺ６−Ａ’）で表される部分構造が有する負の価数と、式（ＩＺ６−Ａ’’）で表される部分構造が有する正の価数の絶対値は同じである。
波線は、Ｅ体又はＺ体を表す。］
［４３］
式（ＩＺ６−Ａ）で表される化合物が、式（ＩＺ６−Ｂ）で表される化合物である［４２］に記載の化合物。

［式（ＩＺ６−Ｂ）中、
Ａ^c+、ｂ、ｃ、ｄ及び波線は、前記と同じ意味を表す。
Ｌ¹は、−ＣＯ−又は−ＳＯ₂−を表す。
Ｒ^1BZ6、Ｒ^2BZ6、Ｒ^3BZ6、Ｒ^4BZ6、Ｒ^5BZ6、Ｒ^11BZ6、Ｒ^12BZ6及びＲ^13BZ6は、互いに独立に、水素原子、−ＣＯ−Ｒ^102BZ6、−ＣＯＯ−Ｒ^101BZ6、−ＯＣＯ−Ｒ^102BZ6、−ＣＯＣＯ−Ｒ^102BZ6、−Ｏ−Ｒ^102BZ6、−ＳＯ₂−Ｒ^101BZ6、−ＳＯ₂Ｎ（Ｒ^102BZ6）₂、−ＣＯＮ（Ｒ^102BZ6）₂、−Ｎ（Ｒ^102BZ6）₂、−ＮＨＣＯ−Ｒ^102BZ6、−ＮＨＣＯ−Ｎ（Ｒ^102BZ6）₂、−ＮＨＣＯＯＲ^102BZ6、−ＯＣＯＮ（Ｒ^102BZ6）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、−ＳＯ₃ ^-、−ＣＯ₂ ^-、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^2BZ6とＲ^3BZ6、Ｒ^3BZ6とＲ^4BZ6、Ｒ^4BZ6とＲ^5BZ6、及びＲ^12BZ6とＲ^13BZ6は、それぞれ互いに結合して環を形成してもよい。
Ｒ^101BZ6は、互いに独立に、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102BZ6は、互いに独立に、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
式（ＩＺ６−Ｂ’）及び式（ＩＺ６−Ｂ’’）は、それぞれ、式（ＩＺ６−Ｂ）の部分構造を表し、Ａ^c+、ｂ、ｃ、ｄ、Ｒ^1BZ6、Ｒ^2BZ6、Ｒ^3BZ6、Ｒ^4BZ6、Ｒ^5BZ6、Ｒ^11BZ6、Ｒ^12BZ6、Ｒ^13BZ6及びＬ¹は、式（ＩＺ６−Ｂ）におけるものと同じものを表す。
Ｍは、前記と同じ意味を表す。
Ｒ^1BZ6、Ｒ^2BZ6、Ｒ^3BZ6、Ｒ^4BZ6、Ｒ^5BZ6、Ｒ^11BZ6、Ｒ^12BZ6、Ｒ^13BZ6、Ｒ^101BZ6、Ｒ^102BZ6、Ｌ¹、Ｍ、ｃ又はＡ^c+が複数存在する場合、それらはそれぞれ同一であってもよく、異なっていてもよい。
Ｒ^1BZ6、Ｒ^2BZ6、Ｒ^3BZ6、Ｒ^4BZ6、Ｒ^5BZ6、Ｒ^11BZ6、Ｒ^12BZ6、Ｒ^13BZ6、Ｒ^101BZ6及びＲ^102BZ6は、（ｒｂ−ｉ）〜（ｒｂ−ｉｉｉ）のうち少なくとも１つを充足しており、Ｒ^1BZ6、Ｒ^2BZ6、Ｒ^3BZ6、Ｒ^4BZ6、Ｒ^5BZ6、Ｒ^11BZ6、Ｒ^12BZ6、Ｒ^13BZ6、Ｒ^101BZ6及びＲ^102BZ6が有する−ＳＯ₃ ^-又は−ＣＯ₂ ^-の合計個数はａである。
（ｒｂ−ｉ）Ｒ^1BZ6、Ｒ^2BZ6、Ｒ^3BZ6、Ｒ^4BZ6、Ｒ^5BZ6、Ｒ^11BZ6、Ｒ^12BZ6及びＲ^13BZ6の少なくとも一つが、−ＳＯ₃ ^-又は−ＣＯ₂ ^-である。
（ｒｂ−ｉｉ）Ｒ^1BZ6、Ｒ^2BZ6、Ｒ^3BZ6、Ｒ^4BZ6、Ｒ^5BZ6、Ｒ^11BZ6、Ｒ^12BZ6及びＲ^13BZ6の少なくとも一つが、−ＣＯ−Ｒ^102BZ6、−ＣＯＯ−Ｒ^101BZ6、−ＯＣＯ−Ｒ^102BZ6、−ＣＯＣＯ−Ｒ^102BZ6、−Ｏ−Ｒ^102BZ6、−ＳＯ₂−Ｒ^101BZ6、−ＳＯ₂Ｎ（Ｒ^102BZ6）₂、又は−ＣＯＮ（Ｒ^102BZ6）₂、−Ｎ（Ｒ^102BZ6）₂、−ＮＨＣＯ−Ｒ^102BZ6、−ＮＨＣＯ−Ｎ（Ｒ^102BZ6）₂、−ＮＨＣＯＯＲ^102BZ6、又は−ＯＣＯＮ（Ｒ^102BZ6）₂であって、
該Ｒ^101BZ6及びＲ^102BZ6が、−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する炭素数１〜４０の炭化水素基又は−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する複素環基である。ただし該炭化水素基又は該複素環基は、−ＳＯ₃ ^-及び−ＣＯ₂ ^-以外の置換基を有していてもよい。
（ｒｂ−ｉｉｉ）Ｒ^1BZ6、Ｒ^2BZ6、Ｒ^3BZ6、Ｒ^4BZ6、Ｒ^5BZ6、Ｒ^11BZ6、Ｒ^12BZ6及びＲ^13BZ6の少なくとも一つが、−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する炭素数１〜４０の炭化水素基又は−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する複素環基である。ただし該炭化水素基又は該複素環基は、−ＳＯ₃ ^-及び−ＣＯ₂ ^-以外の置換基を有していてもよい。
ａは、式（ＩＺ６−Ａ）におけるものと同じ意味を表す。ａが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
式（ＩＺ６−Ｂ’）で表される部分構造が有する負の価数と、式（ＩＺ６−Ｂ’’）で表される部分構造が有する正の価数の絶対値は同じである。］
［４４］
Ｌ¹が、−ＣＯ−である［４３］に記載の化合物。
［４５］
Ｒ^11BZ6が、置換基を有していてもよい炭素数１〜４０の脂肪族炭化水素基、置換基を有していてもよいフェニル基、置換基を有していてもよいナフチル基、置換基を有していてもよいテトラヒドロナフチル基、置換基を有していてもよいチエニル基、置換基を有していてもよいフリル基又は置換基を有していてもよいピリジニル基である［４３］又は［４４］に記載の化合物。
［４６］
式（ＩＺ６−Ｂ）で表される化合物が、式（ＩＺ６−Ｃ）で表される化合物である［４３］に記載の化合物。

［式（ＩＺ６−Ｃ）中、
Ａ^c+、ｂ、ｃ、ｄ、Ｌ¹及び波線は、前記と同じ意味を表す。
Ｌ²は、−ＣＯ−又は−ＳＯ₂−を表す。
Ｒ^1CZ6、Ｒ^2CZ6、Ｒ^3CZ6、Ｒ^4CZ6、Ｒ^5CZ6、Ｒ^11CZ6及びＲ^14CZ6は、互いに独立に、水素原子、−ＣＯ−Ｒ^102CZ6、−ＣＯＯ−Ｒ^101CZ6、−ＯＣＯ−Ｒ^102CZ6、−ＣＯＣＯ−Ｒ^102CZ6、−Ｏ−Ｒ^102CZ6、−ＳＯ₂−Ｒ^101CZ6、−ＳＯ₂Ｎ（Ｒ^102CZ6）₂、−ＣＯＮ（Ｒ^102CZ6）₂、−Ｎ（Ｒ^102CZ6）₂、−ＮＨＣＯ−Ｒ^102CZ6、−ＮＨＣＯ−Ｎ（Ｒ^102CZ6）₂、−ＮＨＣＯＯＲ^102CZ6、−ＯＣＯＮ（Ｒ^102CZ6）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、−ＳＯ₃ ^-、−ＣＯ₂ ^-、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^2CZ6とＲ^3CZ6、Ｒ^3CZ6とＲ^4CZ6、及びＲ^4CZ6とＲ^5CZ6は、それぞれ互いに結合して環を形成してもよい。
Ｒ^101CZ6は、互いに独立に、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102CZ6は、互いに独立に、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、前記と同じ意味を表す。
式（ＩＺ６−Ｃ’）及び式（ＩＺ６−Ｃ’’）は、それぞれ、式（ＩＺ６−Ｃ）の部分構造を表し、Ａ^c+、ｂ、ｃ、ｄ、Ｒ^1CZ6、Ｒ^2CZ6、Ｒ^3CZ6、Ｒ^4CZ6、Ｒ^5CZ6、Ｒ^11CZ6、Ｒ^14CZ6、Ｌ¹及びＬ²は、式（ＩＺ６−Ｃ）におけるものと同じものを表す。
Ｒ^1CZ6、Ｒ^2CZ6、Ｒ^3CZ6、Ｒ^4CZ6、Ｒ^5CZ6、Ｒ^11CZ6、Ｒ^14CZ6、Ｒ^101CZ6、Ｒ^102CZ6、Ｌ¹、Ｌ²、Ｍ、ｃ又はＡ^c+が複数存在する場合、それらはそれぞれ同一であってもよく、異なっていてもよい。
Ｒ^1CZ6、Ｒ^2CZ6、Ｒ^3CZ6、Ｒ^4CZ6、Ｒ^5CZ6、Ｒ^11CZ6、Ｒ^14CZ6、Ｒ^101CZ6及びＲ^102CZ6は、（ｒｃ−ｉ）〜（ｒｃ−ｉｉｉ）のうち少なくとも１つを充足しており、Ｒ^1CZ6、Ｒ^2CZ6、Ｒ^3CZ6、Ｒ^4CZ6、Ｒ^5CZ6、Ｒ^11CZ6、Ｒ^14CZ6、Ｒ^101CZ6及びＲ^102CZ6が有する−ＳＯ₃ ^-又は−ＣＯ₂ ^-の合計個数はａである。
（ｒｃ−ｉ）Ｒ^1CZ6、Ｒ^2CZ6、Ｒ^3CZ6、Ｒ^4CZ6、Ｒ^5CZ6、Ｒ^11CZ6及びＲ^14CZ6の少なくとも一つが、−ＳＯ₃ ^-又は−ＣＯ₂ ^-である。
（ｒｃ−ｉｉ）Ｒ^1CZ6、Ｒ^2CZ6、Ｒ^3CZ6、Ｒ^4CZ6、Ｒ^5CZ6、Ｒ^11CZ6及びＲ^14CZ6の少なくとも一つが、−ＣＯ−Ｒ^102CZ6、−ＣＯＯ−Ｒ^101CZ6、−ＯＣＯ−Ｒ^102CZ6、−ＣＯＣＯ−Ｒ^102CZ6、−Ｏ−Ｒ^102CZ6、−ＳＯ₂−Ｒ^101CZ6、−ＳＯ₂Ｎ（Ｒ^102CZ6）₂、−ＣＯＮ（Ｒ^102CZ6）₂、−Ｎ（Ｒ^102CZ6）₂、−ＮＨＣＯ−Ｒ^102CZ6、−ＮＨＣＯ−Ｎ（Ｒ^102CZ6）₂、−ＮＨＣＯＯＲ^102CZ6、又は−ＯＣＯＮ（Ｒ^102CZ6）₂であって、該Ｒ^101CZ6及びＲ^102CZ6が、−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する炭素数１〜４０の炭化水素基又は−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する複素環基である。ただし該炭化水素基又は該複素環基は、−ＳＯ₃ ^-及び−ＣＯ₂ ^-以外の置換基を有していてもよい。
（ｒｃ−ｉｉｉ）Ｒ^1CZ6、Ｒ^2CZ6、Ｒ^3CZ6、Ｒ^4CZ6、Ｒ^5CZ6、Ｒ^11CZ6及びＲ^14CZ6の少なくとも一つが、−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する炭素数１〜４０の炭化水素基又は−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する複素環基である。ただし該炭化水素基又は該複素環基は、−ＳＯ₃ ^-及び−ＣＯ₂ ^-以外の置換基を有していてもよい。
ａは、式（ＩＺ６−Ｂ）におけるものと同じ意味を表す。ａが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
式（ＩＺ６−Ｃ’）で表される部分構造が有する負の価数と、式（ＩＺ６−Ｃ’’）で表される部分構造が有する正の価数の絶対値は同じである。］
［４７］
Ｒ^11CZ6とＲ^14CZ6とが同じ基であり、Ｌ¹とＬ²とが同じ基である［４６］に記載の化合物。
［４８］
Ｌ¹及びＬ²が、−ＣＯ−である［４６］又は［４７］に記載の化合物。
［４９］
Ｒ^11CZ6及びＲ^14CZ6が、置換基を有していてもよい炭素数１〜４０の脂肪族炭化水素基、置換基を有していてもよいフェニル基、置換基を有していてもよいナフチル基、置換基を有していてもよいテトラヒドロナフチル基、置換基を有していてもよいチエニル基、置換基を有していてもよいフリル基又は置換基を有していてもよいピリジニル基である［４６］〜［４８］のいずれかに記載の化合物。
［５０］
式（ＩＺ６−Ｂ）で表される化合物が、式（ＩＺ６−Ｄ）で表される化合物である［４３］に記載の化合物。

［式（ＩＺ６−Ｄ）中、
Ａ^c+、ｂ、ｃ、ｄ、Ｌ¹及び波線は、前記と同じ意味を表す。
Ｒ^20DZ6及びＲ^30DZ6は結合して環Ｑを形成する。
環Ｑは、置換基を有していてもよく、環の構成員数が５〜７の環であり、該環Ｑは、炭化水素環でもよく複素環でもよい。環Ｑには、炭化水素環及び複素環から選ばれる、環の構成員数が５〜７の置換基を有していてもよい単環又は該単環の２つ以上が縮合した縮環が縮合してもよい。
Ｒ^1DZ6、Ｒ^2DZ6、Ｒ^3DZ6、Ｒ^4DZ6、Ｒ^5DZ6及びＲ^11DZ6は、互いに独立に、水素原子、−ＣＯ−Ｒ^102DZ6、−ＣＯＯ−Ｒ^101DZ6、−ＯＣＯ−Ｒ^102DZ6、−ＣＯＣＯ−Ｒ^102DZ6、−Ｏ−Ｒ^102DZ6、−ＳＯ₂−Ｒ^101DZ6、−ＳＯ₂Ｎ（Ｒ^102DZ6）₂、−ＣＯＮ（Ｒ^102DZ6）₂、−Ｎ（Ｒ^102DZ6）₂、−ＮＨＣＯ−Ｒ^102DZ6、−ＮＨＣＯ−Ｎ（Ｒ^102DZ6）₂、−ＮＨＣＯＯＲ^102DZ6、−ＯＣＯＮ（Ｒ^102DZ6）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、−ＳＯ₃ ^-、−ＣＯ₂ ^-、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^2DZ6とＲ^3DZ6、Ｒ^3DZ6とＲ^4DZ6、及びＲ^4DZ6とＲ^5DZ6は、それぞれ互いに結合して環を形成してもよい。
Ｒ^101DZ6は、互いに独立に、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102DZ6は、互いに独立に、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、前記と同じ意味を表す。
式（ＩＺ６−Ｄ’）及び式（ＩＺ６−Ｄ’’）は、それぞれ、式（ＩＺ６−Ｄ）の部分構造を表し、Ａ^c+、ｂ、ｃ、ｄ、Ｒ^1DZ6、Ｒ^2DZ6、Ｒ^3DZ6、Ｒ^4DZ6、Ｒ^5DZ6、Ｒ^11DZ6、Ｒ^20DZ6、Ｒ^30DZ6及びＬ¹は、式（ＩＺ６−Ｄ）におけるものと同じものを表す。
Ｒ^1DZ6、Ｒ^2DZ6、Ｒ^3DZ6、Ｒ^4DZ6、Ｒ^5DZ6、Ｒ^11DZ6、Ｒ^101DZ6、Ｒ^102DZ6、Ｌ¹、Ｍ、Ｒ^20DZ6、Ｒ^30DZ6、環Ｑ、ｃ又はＡ^c+が複数存在する場合、それらはそれぞれ同一であってもよく、異なっていてもよい。
Ｒ^1DZ6、Ｒ^2DZ6、Ｒ^3DZ6、Ｒ^4DZ6、Ｒ^5DZ6、Ｒ^11DZ6、Ｒ^101DZ6、Ｒ^102DZ6及び環Ｑは、（ｒｄ−ｉ）〜（ｒｄ−ｉｖ）のうち少なくとも１つを充足しており、Ｒ^1DZ6、Ｒ^2DZ6、Ｒ^3DZ6、Ｒ^4DZ6、Ｒ^5DZ6、Ｒ^11DZ6、Ｒ^101DZ6、Ｒ^102DZ6及び環Ｑが有する−ＳＯ₃ ^-又は−ＣＯ₂ ^-の合計個数はａである。
（ｒｄ−ｉ）Ｒ^1DZ6、Ｒ^2DZ6、Ｒ^3DZ6、Ｒ^4DZ6、Ｒ^5DZ6及びＲ^11DZ6の少なくとも一つが、−ＳＯ₃ ^-又は−ＣＯ₂ ^-である。
（ｒｄ−ｉｉ）Ｒ^1DZ6、Ｒ^2DZ6、Ｒ^3DZ6、Ｒ^4DZ6、Ｒ^5DZ6及びＲ^11DZ6の少なくとも一つが、−ＣＯ−Ｒ^102DZ6、−ＣＯＯ−Ｒ^101DZ6、−ＯＣＯ−Ｒ^102DZ6、−ＣＯＣＯ−Ｒ^102DZ6、−Ｏ−Ｒ^102DZ6、−ＳＯ₂−Ｒ^101DZ6、−ＳＯ₂Ｎ（Ｒ^102DZ6）₂、−ＣＯＮ（Ｒ^102DZ6）₂、−Ｎ（Ｒ^102DZ6）₂、−ＮＨＣＯ−Ｒ^102DZ6、−ＮＨＣＯ−Ｎ（Ｒ^102DZ6）₂、−ＮＨＣＯＯＲ^102DZ6、又は−ＯＣＯＮ（Ｒ^102DZ6）₂であって、該Ｒ^101DZ6及びＲ^102DZ6が、−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する炭素数１〜４０の炭化水素基又は−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する複素環基である。ただし該炭化水素基又は該複素環基は、−ＳＯ₃ ^-及び−ＣＯ₂ ^-以外の置換基を有していてもよい。
（ｒｄ−ｉｉｉ）Ｒ^1DZ6、Ｒ^2DZ6、Ｒ^3DZ6、Ｒ^4DZ6、Ｒ^5DZ6及びＲ^11DZ6の少なくとも一つが、−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する炭素数１〜４０の炭化水素基又は−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する複素環基である。ただし該炭化水素基又は該複素環基は、−ＳＯ₃ ^-及び−ＣＯ₂ ^-以外の置換基を有していてもよい。
（ｒｄ−ｉｖ）環Ｑが、−ＳＯ₃ ^-又は−ＣＯ₂ ^-を有する
ａは、式（ＩＺ６−Ｂ）におけるものと同じ意味を表す。ａが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
式（ＩＺ６−Ｄ’）で表される部分構造が有する負の価数と、式（ＩＺ６−Ｄ’’）で表される部分構造が有する正の価数の絶対値は同じである。］
［５１］
Ｌ¹が、−ＣＯ−である［５０］に記載の化合物。
［５２］
Ｒ^11DZ6が、置換基を有していてもよい炭素数１〜４０の脂肪族炭化水素基、置換基を有していてもよいフェニル基、置換基を有していてもよいナフチル基、置換基を有していてもよいテトラヒドロナフチル基、置換基を有していてもよいチエニル基、置換基を有していてもよいフリル基又は置換基を有していてもよいピリジニル基である［５０］又は［５１］に記載の化合物。
［５３］
式（ＩＺ６−Ｄ）で表される化合物が、式（ＩＺ６−Ｅ）で表される化合物である［５０］に記載の化合物。

［式（ＩＺ６−Ｅ）中、
Ａ^c+、ｂ、ｃ、ｄ、Ｌ¹及び波線は、前記と同じ意味を表す。
Ｒ^1EZ6、Ｒ^2EZ6、Ｒ^3EZ6、Ｒ^4EZ6、Ｒ^5EZ6、Ｒ^6EZ6、Ｒ^7EZ6及びＲ^11EZ6は、互いに独立に、水素原子、−ＣＯ−Ｒ^102EZ6、−ＣＯＯ−Ｒ^101EZ6、−ＯＣＯ−Ｒ^102EZ6、−ＣＯＣＯ−Ｒ^102EZ6、−Ｏ−Ｒ^102EZ6、−ＳＯ₂−Ｒ^101EZ6、−ＳＯ₂Ｎ（Ｒ^102EZ6）₂、−ＣＯＮ（Ｒ^102EZ6）₂、−Ｎ（Ｒ^102EZ6）₂、−ＮＨＣＯ−Ｒ^102EZ6、−ＮＨＣＯ−Ｎ（Ｒ^102EZ6）₂、−ＮＨＣＯＯＲ^102EZ6、−ＯＣＯＮ（Ｒ^102EZ6）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、−ＳＯ₃ ^-、−ＣＯ₂ ^-、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^2EZ6とＲ^3EZ6、Ｒ^3EZ6とＲ^4EZ6、及びＲ^4EZ6とＲ^5EZ6は、それぞれ互いに結合して環を形成してもよい。
Ｒ^101EZ6は、互いに独立に、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102EZ6は、互いに独立に、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、前記と同じ意味を表す。
式（ＩＺ６−Ｅ’）及び式（ＩＺ６−Ｅ’’）は、それぞれ、式（ＩＺ６−Ｅ）の部分構造を表し、Ａ^c+、ｂ、ｃ、ｄ、Ｒ^1EZ6、Ｒ^2EZ6、Ｒ^3EZ6、Ｒ^4EZ6、Ｒ^5EZ6、Ｒ^6EZ6、Ｒ^7EZ6、Ｒ^11EZ6及びＬ¹は、式（ＩＺ６−Ｅ）におけるものと同じものを表す。
Ｒ^1EZ6、Ｒ^2EZ6、Ｒ^3EZ6、Ｒ^4EZ6、Ｒ^5EZ6、Ｒ^6EZ6、Ｒ^7EZ6、Ｒ^11EZ6、Ｒ^101EZ6、Ｒ^102EZ6、Ｌ¹、Ｍ、ｃ又はＡ^c+が複数存在する場合、それらはそれぞれ同一であってもよく、異なっていてもよい。
Ｒ^1EZ6、Ｒ^2EZ6、Ｒ^3EZ6、Ｒ^4EZ6、Ｒ^5EZ6、Ｒ^6EZ6、Ｒ^7EZ6、Ｒ^11EZ6、Ｒ^101EZ6及びＲ^102EZ6は、（ｒｅ−ｉ）〜（ｒｅ−ｉｉｉ）のうち少なくとも１つを充足しており、Ｒ^1EZ6、Ｒ^2EZ6、Ｒ^3EZ6、Ｒ^4EZ6、Ｒ^5EZ6、Ｒ^6EZ6、Ｒ^7EZ6、Ｒ^11EZ6、Ｒ^101EZ6及びＲ^102EZ6が有する−ＳＯ₃ ^-又は−ＣＯ₂ ^-の合計個数はａである。
（ｒｅ−ｉ）Ｒ^1EZ6、Ｒ^2EZ6、Ｒ^3EZ6、Ｒ^4EZ6、Ｒ^5EZ6、Ｒ^6EZ6、Ｒ^7EZ6及びＲ^11EZ6の少なくとも一つが、−ＳＯ₃ ^-又は−ＣＯ₂ ^-である。
（ｒｅ−ｉｉ）Ｒ^1EZ6、Ｒ^2EZ6、Ｒ^3EZ6、Ｒ^4EZ6、Ｒ^5EZ6、Ｒ^6EZ6、Ｒ^7EZ6及びＲ^11EZ6の少なくとも一つが、−ＣＯ−Ｒ^102EZ6、−ＣＯＯ−Ｒ^101EZ6、−ＯＣＯ−Ｒ^102EZ6、−ＣＯＣＯ−Ｒ^102EZ6、−Ｏ−Ｒ^102EZ6、−ＳＯ₂−Ｒ^101EZ6、−ＳＯ₂Ｎ（Ｒ^102EZ6）₂、−ＣＯＮ（Ｒ^102EZ6）₂、−Ｎ（Ｒ^102EZ6）₂、−ＮＨＣＯ−Ｒ^102EZ6、−ＮＨＣＯ−Ｎ（Ｒ^102EZ6）₂、−ＮＨＣＯＯＲ^102EZ6、又は−ＯＣＯＮ（Ｒ^102EZ6）₂であって、該Ｒ^101EZ6及びＲ^102EZ6が、−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する炭素数１〜４０の炭化水素基又は−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する複素環基である。ただし該炭化水素基又は該複素環基は、−ＳＯ₃ ^-及び−ＣＯ₂ ^-以外の置換基を有していてもよい。
（ｒｅ−ｉｉｉ）Ｒ^1EZ6、Ｒ^2EZ6、Ｒ^3EZ6、Ｒ^4EZ6、Ｒ^5EZ6、Ｒ^6EZ6、Ｒ^7EZ6及びＲ^11EZ6の少なくとも一つが、−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する炭素数１〜４０の炭化水素基又は−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する複素環基である。ただし該炭化水素基又は該複素環基は、−ＳＯ₃ ^-及び−ＣＯ₂ ^-以外の置換基を有していてもよい。
ａは、式（ＩＺ６−Ｄ）におけるものと同じ意味を表す。ａが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
式（ＩＺ６−Ｅ’）で表される部分構造が有する負の価数と、式（ＩＺ６−Ｅ’’）で表される部分構造が有する正の価数の絶対値は同じである。］
［５４］
Ｌ¹が、−ＣＯ−である［５３］に記載の化合物。
［５５］
Ｒ^11EZ6が、置換基を有していてもよい炭素数１〜４０の脂肪族炭化水素基、置換基を有していてもよいフェニル基、置換基を有していてもよいナフチル基、置換基を有していてもよいテトラヒドロナフチル基、置換基を有していてもよいチエニル基、置換基を有していてもよいフリル基又は置換基を有していてもよいピリジニル基である［５３］又は［５４］に記載の化合物。   The present invention includes the following inventions.
  [1]
  A compound represented by formula (IZ1), a compound represented by formula (IZ2), a compound represented by formula (IZ3), a compound represented by formula (IZ4), a compound represented by formula (IZ5), And at least one selected from compounds represented by formula (IZ6);
  A coloring composition comprising at least one of a resin and a solvent.

[In the formula (IZ1),
  R^O1Z1Represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
  R^1Z1, R^2Z1, R^3Z1, R^4Z1, R^5Z1, R^6Z1And R^7Z1Independently of one another, a hydrogen atom, -CO-R^102Z1, -COO-R^101Z1, -OCO-R^102Z1, -COCO-R^102Z1, -O-R^102Z1, -SO₂-R^101Z1, -SO₂N (R^102Z1)₂, -CON (R^102Z1)₂, -N (R^102Z1)₂, -NHCO-R^102Z1, -NHCO-N (R^102Z1)₂, -NHCOOR^102Z1, -OCON (R^102Z1)₂, Halogen atom, cyano group, nitro group, -SO_ThreeM, -CO₂M represents a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent.
  R^2Z1And R^3Z1, R^3Z1And R^4Z1And R^4Z1And R^5Z1May be bonded to each other to form a ring.
  R^101Z1Represents a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent.
  R^102Z1Represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
  M represents a hydrogen atom or an alkali metal atom.
  R^101Z1, R^102Z1And when there are a plurality of M, they may be the same or different.
  A wavy line represents an E body or a Z body. ]

[In the formula (IZ2),
  R^CO1Z2And R^CO2Z2Are independently of each other —O—R^O1Z2Or -NR^N1Z2R^N2Z2Represents.
  R^N1Z2, R^N2Z2, R^1Z2, R^2Z2, R^3Z2, R^4Z2And R^5Z2Independently of one another, a hydrogen atom, -CO-R^102Z2, -COO-R^101Z2, -OCO-R^102Z2, -COCO-R^102Z2, -O-R^102Z2, -SO₂-R^101Z2, -SO₂N (R^102Z2)₂, -CON (R^102Z2)₂, -N (R^102Z2)₂, -NHCO-R^102Z2, -NHCO-N (R^102Z2)₂, -NHCOOR^102Z2, -OCON (R^102Z2)₂, Halogen atom, cyano group, nitro group, -SO_ThreeM, -CO₂M represents a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent.
  R^2Z2And R^3Z2, R^3Z2And R^4Z2And R^4Z2And R^5Z2May be bonded to each other to form a ring.
  R^101Z2Represents a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent.
  R^O1Z2And R^102Z2Independently represent a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms, or an optionally substituted heterocyclic group.
  M represents a hydrogen atom or an alkali metal atom.
  R^O1Z2, R^N1Z2, R^N2Z2, R^101Z2, R^102Z2And when there are a plurality of M, they may be the same or different.
  A wavy line represents an E body or a Z body. ]

[In the formula (IZ3),
  R^1Z3, R^2Z3, R^3Z3, R^4Z3, R^5Z3, R^6Z3And R^7Z3Independently of one another, a hydrogen atom, -CO-R^102Z3, -COO-R^101Z3, -OCO-R^102Z3, -COCO-R^102Z3, -O-R^102Z3, -SO₂-R^101Z3, -SO₂N (R^102Z3)₂, -CON (R^102Z3)₂, -N (R^102Z3)₂, -NHCO-R^102Z3, -NHCO-N (R^102Z3)₂, -NHCOOR^102Z3, -OCON (R^102Z3)₂, Halogen atom, cyano group, nitro group, -SO_ThreeM, -CO₂M represents a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent.
  R^2Z3And R^3Z3, R^3Z3And R^4Z3And R^4Z3And R^5Z3May be bonded to each other to form a ring.
  R^101Z3Represents a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent.
  R^102Z3Represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
  M represents a hydrogen atom or an alkali metal atom.
  R^101Z3, R^102Z3And when there are a plurality of M, they may be the same or different.
  A wavy line represents an E body or a Z body. ]

[In the formula (IZ4),
  R^N1Z4And R^N2Z4Are independently of each other -CO-R^102Z4, -COO-R^101Z4, -OCO-R^102Z4, -COCO-R^102Z4, -O-R^102Z4, -SO₂-R^101Z4, -SO₂N (R^102Z4)₂, -CON (R^102Z4)₂, -N (R^102Z4)₂, -NHCO-R^102Z4, -NHCO-N (R^102Z4)₂, -NHCOOR^102Z4, -OCON (R^102Z4)₂, Halogen atom, cyano group, nitro group, -SO_ThreeM, -CO₂M represents a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent.
  R^1Z4, R^2Z4, R^3Z4, R^4Z4, R^5Z4, R^6Z4And R^7Z4Independently of one another, a hydrogen atom, -CO-R^102Z4, -COO-R^101Z4, -OCO-R^102Z4, -COCO-R^102Z4, -O-R^102Z4, -SO₂-R^101Z4, -SO₂N (R^102Z4)₂, -CON (R^102Z4)₂, -N (R^102Z4)₂, -NHCO-R^102Z4, -NHCO-N (R^102Z4)₂, -NHCOOR^102Z4, -OCON (R^102Z4)₂, Halogen atom, cyano group, nitro group, -SO_ThreeM, -CO₂M represents a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent.
  R^2Z4And R^3Z4, R^3Z4And R^4Z4And R^4Z4And R^5Z4May be bonded to each other to form a ring.
  R^101Z4Represents a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent.
  R^102Z4Represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
  M represents a hydrogen atom or an alkali metal atom.
  R^101Z4, R^102Z4And when there are a plurality of M, they may be the same or different.
  A wavy line represents an E body or a Z body. ]

[In the formula (IZ5)
  R^N1Z5Is -CO-R^102Z5, -COO-R^101Z5, -OCO-R^102Z5, -COCO-R^102Z5, -O-R^102Z5, -SO₂-R^101Z5, -SO₂N (R^102Z5)₂, -CON (R^102Z5)₂, -N (R^102Z5)₂, -NHCO-R^102Z5, -NHCO-N (R^102Z5)₂, -NHCOOR^102Z5, -OCON (R^102Z5)₂, Halogen atom, cyano group, nitro group, -SO_ThreeM, -CO₂M represents a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent.
  R^1Z5, R^2Z5, R^3Z5, R^4Z5, R^5Z5, R^6Z5And R^7Z5Independently of one another, a hydrogen atom, -CO-R^102Z5, -COO-R^101Z5, -OCO-R^102Z5, -COCO-R^102Z5, -O-R^102Z5, -SO₂-R^101Z5, -SO₂N (R^102Z5)₂, -CON (R^102Z5)₂, -N (R^102Z5)₂, -NHCO-R^102Z5, -NHCO-N (R^102Z5)₂, -NHCOOR^102Z5, -OCON (R^102Z5)₂, Halogen atom, cyano group, nitro group, -SO_ThreeM, -CO₂M represents an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group, and R^2Z5And R^3Z5, R^3Z5And R^4Z5And R^4Z5And R^5Z5May be bonded to each other to form a ring, and R^2Z5, R^3Z5, R^4Z5And R^5Z5At least one of -CO-R^102Z5, -COO-R^101Z5, -OCO-R^102Z5, -COCO-R^102Z5, -O-R^102Z5, -SO₂-R^101Z5, -SO₂N (R^102Z5)₂, -CON (R^102Z5)₂, -N (R^102Z5)₂, -NHCO-R^102Z5, -NHCO-N (R^102Z5)₂, -NHCOOR^102Z5, -OCON (R^102Z5)₂, Halogen atom, cyano group, nitro group, -SO_ThreeM, -CO₂M, a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent, or R^2Z5And R^3Z5, R^3Z5And R^4Z5And R^4Z5And R^5Z5At least one pair of these are bonded to form a ring.
  R^101Z5Represents a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent.
  R^102Z5Represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
  M represents a hydrogen atom or an alkali metal atom.
  R^101Z5, R^102Z5And when there are a plurality of M, they may be the same or different.
  A wavy line represents an E body or a Z body. ]

[In the formula (IZ6)
  D represents a structure having an isoindoline skeleton.
  Z is -SO_Three ^-Or -CO₂ ^-Represents.
  A^{c +}Represents a c-valent metal cation.
  a represents an integer of 1 to 10.
  b represents an integer of 1 or more.
  c represents an integer of 2 to 10.
  d represents an integer of 1 or more.
  D, Z, a or A^{c +}When a plurality of are present, they may be the same or different.
  Formula (I′Z6) and Formula (I ″ Z6) each represent a partial structure of Formula (IZ6), and D, Z, A^{c +}, A, b, c and d represent the same as in formula (IZ6).
  However, the negative valence of the partial structure represented by the formula (I′Z6) and the absolute value of the positive valence of the partial structure represented by the formula (I ″ Z6) are the same. ]
  [2]
  The colored composition according to [1], comprising a compound represented by the formula (IZ1), a compound represented by the formula (IZ2), or a compound represented by the formula (IZ3) and a resin.
  [3]
  The coloring composition according to [1], comprising a compound represented by the formula (IZ4), a compound represented by the formula (IZ5), or a compound represented by the formula (IZ6) and a solvent.
  [4]
  Including a compound represented by the formula (IZ1), R^1Z1, R^6Z1And R^7Z1The coloring composition according to [1] or [2], wherein is a hydrogen atom.
  [5]
  Including a compound represented by the formula (IZ1), R^O1Z1Is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent, [1] to [2] or [4].
  [6]
  Including a compound represented by the formula (IZ1), R^2Z1, R^3Z1, R^4Z1And R^5Z1At least one of
-CO-R^102Z1, -COO-R^101Z1, -OCO-R^102Z1, -COCO-R^102Z1, -O-R^102Z1, -SO₂-R^101Z1, -SO₂N (R^102Z1)₂, -CON (R^102Z1)₂, -N (R^102Z1)₂, -NHCO-R^102Z1, -NHCO-N (R^102Z1)₂, -NHCOOR^102Z1, -OCON (R^102Z1)₂, Halogen atom, cyano group, nitro group, -SO_ThreeM, -CO₂M, a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent, or R^2Z1And R^3Z1, R^3Z1And R^4Z1And R^4Z1And R^5Z1The coloring composition according to [1] to [2], [4] or [5], wherein at least one pair of is bonded to form a ring.
  [7]
  Including a compound represented by the formula (IZ1), R^2Z1, R^3Z1, R^4Z1And R^5Z1The coloring composition according to any one of [1] to [2] or [4] to [6], wherein at least one of is a nitro group or a tert-butyl group.
  [8]
  Including a compound represented by the formula (IZ2), R^O1Z2, R^N1Z2And R^N2Z2Are the coloring composition as described in [1] or [2] which is a C1-C10 hydrocarbon group which may have a hydrogen atom or a substituent mutually independently.
  [9]
  Including a compound represented by the formula (IZ2), R^1Z2The coloring composition according to [1] to [2] or [8], wherein is a hydrogen atom.
  [10]
  Including a compound represented by the formula (IZ2), R^2Z2, R^3Z2, R^4Z2And R^5Z2At least one of -CO-R^102Z2, -COO-R^101Z2, -OCO-R^102Z2, -COCO-R^102Z2, -O-R^102Z2, -SO₂-R^101Z2, -SO₂N (R^102Z2)₂, -CON (R^102Z2)₂, -N (R^102Z2)₂, -NHCO-R^102Z2, -NHCO-N (R^102Z2)₂, -NHCOOR^102Z2, -OCON (R^102Z2)₂, Halogen atom, cyano group, nitro group, -SO_ThreeM, -CO₂M, a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent, or R^2Z2And R^3Z2, R^3Z2And R^4Z2And R^4Z2And R^5Z2The coloring composition according to [1] to [2], [8] or [9], wherein at least one pair of is bonded to form a ring.
  [11]
  Including a compound represented by the formula (IZ2), R^2Z2, R^3Z2, R^4Z2And R^5Z2The coloring composition according to any one of [1] to [2] or [8] to [10], wherein at least one of is a nitro group or a tert-butyl group.
  [12]
  Including a compound represented by the formula (IZ3), R^1Z3, R^6Z3And R^7Z3The coloring composition according to [1] or [2], wherein is a hydrogen atom.
  [13]
  Including a compound represented by the formula (IZ3), R^2Z3, R^3Z3, R^4Z3And R^5Z3At least one of -CO-R^102Z3, -COO-R^101Z3, -OCO-R^102Z3, -COCO-R^102Z3, -O-R^102Z3, -SO₂-R^101Z3, -SO₂N (R^102Z3)₂, -CON (R^102Z3)₂, -N (R^102Z3)₂, -NHCO-R^102Z3, -NHCO-N (R^102Z3)₂, -NHCOOR^102Z3, -OCON (R^102Z3)₂, Halogen atom, cyano group, nitro group, -SO_ThreeM, -CO₂M, a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent, or R^2Z3And R^3Z3, R^3Z3And R^4Z3And R^4Z3And R^5Z3The coloring composition according to [1] to [2] or [12], wherein at least one pair of is bonded to form a ring.
  [14]
  Including a compound represented by the formula (IZ3), R^2Z3, R^3Z3, R^4Z3And R^5Z3The coloring composition according to [1] to [2], [12] or [13], wherein at least one of is a nitro group or a tert-butyl group.
  [15]
  The coloring composition in any one of [1]-[14] containing both resin and a solvent.
  [16]
  Furthermore, the coloring composition in any one of [1]-[15] containing a yellow coloring agent or a green coloring agent.
  [17]
  The colored curable composition containing the coloring composition in any one of [1]-[16], and a polymeric compound.
  [18]
  Furthermore, the coloring curable composition as described in [17] containing a polymerization initiator.
  [19]
  A color filter formed from the colored composition according to any one of [1] to [16] or the colored curable composition according to [17] or [18].
  [20]
  A liquid crystal display device comprising the color filter according to [19].
  [21]
  A compound represented by the formula (IZ1-B).

[In the formula (IZ1-B),
  R^O11Z1Represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
  R^1Z1, R^21Z1, R^31Z1, R^41Z1, R^51Z1, R^61Z1And R^71Z1Independently of one another, a hydrogen atom, -CO-R^102Z1, -COO-R^101Z1, -OCO-R^102Z1, -COCO-R^102Z1, -O-R^102Z1, -SO₂-R^101Z1, -SO₂N (R^102Z1)₂, -CON (R^102Z1)₂, -N (R^102Z1)₂, -NHCO-R^102Z1, -NHCO-N (R^102Z1)₂, -NHCOOR^102Z1, -OCON (R^102Z1)₂, Halogen atom, cyano group, nitro group, -SO_ThreeM, -CO₂M represents a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent.
  R^21Z1And R^31Z1, R^31Z1And R^41Z1And R^41Z1And R^51Z1May be bonded to each other to form a ring.
  However, R^21Z1, R^31Z1, R^41Z1And R^51Z1At least one of -CO-R^102Z1, -COO-R^101Z1, -OCO-R^102Z1, -COCO-R^102Z1, -O-R^102Z1, -SO₂-R^101Z1, -SO₂N (R^102Z1)₂, -CON (R^102Z1)₂, -N (R^102Z1)₂, -NHCO-R^102Z1, -NHCO-N (R^102Z1)₂, -NHCOOR^102Z1, -OCON (R^102Z1)₂, Halogen atom, cyano group, nitro group, -SO_ThreeM, -CO₂M, a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent, or R^21Z1And R^31Z1, R^31Z1And R^41Z1And R^41Z1And R^51Z1At least one pair of these forms a ring.
  R^101Z1Represents a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent.
  R^102Z1Represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
  M represents a hydrogen atom or an alkali metal atom.
  R^101Z1, R^102Z1And when there are a plurality of M, they may be the same or different.
  A wavy line represents an E body or a Z body. ]
  [22]
  R^1Z1, R^61Z1And R^71Z1[21] The compound according to [21], wherein is a hydrogen atom.
  [23]
  R^O11Z1[21] or [22], wherein is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent.
  [24]
  R^21Z1, R^31Z1, R^41Z1And R^51Z1The compound according to any one of [21] to [23], wherein at least one of is a nitro group or a tert-butyl group.
  [25]
  A compound represented by the formula (IZ2-B).

[In the formula (IZ2-B),
  R^CO11Z2And R^CO21Z2Are independently of each other —O—R^O1Z2Or -NR^N1Z2R^N2Z2Represents R^CO11Z2And R^CO21Z2At least one of -NR^N1Z2R^N2Z2It is.
  R^N1Z2, R^N2Z2, R^1Z2, R^21Z2, R^31Z2, R^41Z2And R^51Z2Independently of one another, a hydrogen atom, -CO-R^102Z2, -COO-R^101Z2, -OCO-R^102Z2, -COCO-R^102Z2, -O-R^102Z2, -SO₂-R^101Z2, -SO₂N (R^102Z2)₂, -CON (R^102Z2)₂, -N (R^102Z2)₂, -NHCO-R^102Z2, -NHCO-N (R^102Z2)₂, -NHCOOR^102Z2, -OCON (R^102Z2)₂, Halogen atom, cyano group, nitro group, -SO_ThreeM, -CO₂M represents an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group, and R^21Z2And R^31Z2, R^31Z2And R^41Z2And R^41Z2And R^51Z2Each may be bonded to each other to form a ring,
  R^21Z2, R^31Z2, R^41Z2And R^51Z2At least one of -CO-R^102Z2, -COO-R^101Z2, -OCO-R^102Z2, -COCO-R^102Z2, -O-R^102Z2, -SO₂-R^101Z2, -SO₂N (R^102Z2)₂, -CON (R^102Z2)₂, -N (R^102Z2)₂, -NHCO-R^102Z2, -NHCO-N (R^102Z2)₂, -NHCOOR^102Z2, -OCON (R^102Z2)₂, Halogen atom, cyano group, nitro group, -SO_ThreeM, -CO₂M, a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent, or R^21Z2And R^31Z2, R^31Z2And R^41Z2And R^41Z2And R^51Z2At least one pair of these are bonded to form a ring.
  R^101Z2Represents a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent.
  R^O1Z2And R^102Z2Independently represent a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms, or an optionally substituted heterocyclic group.
  M represents a hydrogen atom or an alkali metal atom.
  R^O1Z2, R^N1Z2, R^N2Z2, R^101Z2, R^102Z2And when there are a plurality of M, they may be the same or different.
  A wavy line represents an E body or a Z body. ]
  [26]
  R^O1Z2, R^N1Z2And R^N2Z2The compound as described in [25] which is a C1-C10 hydrocarbon group which may have a hydrogen atom or a substituent.
  [27]
  R^1Z2The compound according to [25] or [26], wherein is a hydrogen atom.
  [28]
  R^21Z2, R^31Z2, R^41Z2And R^51Z2The compound according to any one of [25] to [27], wherein at least one of is a nitro group or a tert-butyl group.
  [29]
  A compound represented by the formula (IZ3-B).

[In the formula (IZ3-B),
  R^1Z3, R^21Z3, R^31Z3, R^41Z3, R^51Z3, R^61Z3And R^71Z3Independently of one another, a hydrogen atom, -CO-R^102Z3, -COO-R^101Z3, -OCO-R^102Z3, -COCO-R^102Z3, -O-R^102Z3, -SO₂-R^101Z3, -SO₂N (R^102Z3)₂, -CON (R^102Z3)₂, -N (R^102Z3)₂, -NHCO-R^102Z3, -NHCO-N (R^102Z3)₂, -NHCOOR^102Z3, -OCON (R^102Z3)₂, Halogen atom, cyano group, nitro group, -SO_ThreeM, -CO₂M represents a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent.
  R^21Z3And R^31Z3, R^31Z3And R^41Z3And R^41Z3And R^51Z3May be bonded to each other to form a ring.
  However, R^21Z3, R^31Z3, R^41Z3And R^51Z3At least one of -CO-R^102Z3, -COO-R^101Z3, -OCO-R^102Z3, -COCO-R^102Z3, -O-R^102Z3, -SO₂-R^101Z3, -SO₂N (R^102Z3)₂, -CON (R^102Z3)₂, -N (R^102Z3)₂, -NHCO-R^102Z3, -NHCO-N (R^102Z3)₂, -NHCOOR^102Z3, -OCON (R^102Z3)₂, Halogen atom, cyano group, nitro group, -SO_ThreeM, -CO₂M, a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent, or R^21Z3And R^31Z3, R^31Z3And R^41Z3And R^41Z3And R^51Z3At least one pair of these forms a ring.
  R^101Z3Represents a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent.
  R^102Z3Represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
  M represents a hydrogen atom or an alkali metal atom.
  R^101Z3, R^102Z3And when there are a plurality of M, they may be the same or different.
  A wavy line represents an E body or a Z body. ]
  [30]
  R^1Z3, R^61Z3And R^71Z3The compound according to [29], wherein is a hydrogen atom.
  [31]
  R^21Z3, R^31Z3, R^41Z3And R^51Z3The compound according to [29] or [30], wherein at least one of is a nitro group or a tert-butyl group.
  [32]
  A compound represented by formula (IZ4).

[In the formula (IZ4),
  R^N1Z4And R^N2Z4Are independently of each other -CO-R^102Z4, -COO-R^101Z4, -OCO-R^102Z4, -COCO-R^102Z4, -O-R^102Z4, -SO₂-R^101Z4, -SO₂N (R^102Z4)₂, -CON (R^102Z4)₂, -N (R^102Z4)₂, -NHCO-R^102Z4, -NHCO-N (R^102Z4)₂, -NHCOOR^102Z4, -OCON (R^102Z4)₂, Halogen atom, cyano group, nitro group, -SO_ThreeM, -CO₂M represents a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent.
  R^1Z4, R^2Z4, R^3Z4, R^4Z4, R^5Z4, R^6Z4And R^7Z4Independently of one another, a hydrogen atom, -CO-R^102Z4, -COO-R^101Z4, -OCO-R^102Z4, -COCO-R^102Z4, -O-R^102Z4, -SO₂-R^101Z4, -SO₂N (R^102Z4)₂, -CON (R^102Z4)₂, -N (R^102Z4)₂, -NHCO-R^102Z4, -NHCO-N (R^102Z4)₂, -NHCOOR^102Z4, -OCON (R^102Z4)₂, Halogen atom, cyano group, nitro group, -SO_ThreeM, -CO₂M represents a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent.
  R^2Z4And R^3Z4, R^3Z4And R^4Z4And R^4Z4And R^5Z4May be bonded to each other to form a ring.
  R^101Z4Represents a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent.
  R^102Z4Represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
  M represents a hydrogen atom or an alkali metal atom.
  R^101Z4, R^102Z4And when there are a plurality of M, they may be the same or different.
  A wavy line represents an E body or a Z body. ]
  [33]
  R^1Z4, R^6Z4And R^7Z4The compound according to [32], wherein is a hydrogen atom.
  [34]
  R^N1Z4And R^N2Z4Are each independently a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent, [32] or [33].
  [35]
  R^2Z4, R^3Z4, R^4Z4And R^5Z4At least one of -CO-R^102Z4, -COO-R^101Z4, -OCO-R^102Z4, COCO-R^102Z4, -O-R^102Z4, -SO₂-R^101Z4, -SO₂N (R^102Z4)₂, -CON (R^102Z4)₂, -N (R^102Z4)₂, -NHCO-R^102Z4, -NHCO-N (R^102Z4)₂, -NHCOOR^102Z4, -OCON (R^102Z4)₂, Halogen atom, cyano group, nitro group, -SO_ThreeM, -CO₂M, a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent, or R^2Z4And R^3Z4, R^3Z4And R^4Z4And R^4Z4And R^5Z4The compound according to any one of [32] to [34], wherein at least one pair of is bonded to form a ring.
  [36]
  R^2Z4, R^3Z4, R^4Z4And R^5Z4The compound according to any one of [32] to [35], wherein at least one of is a nitro group or a tert-butyl group.
  [37]
  A compound represented by formula (IZ5).

[In the formula (IZ5)
  R^N1Z5Is -CO-R^102Z5, -COO-R^101Z5, -OCO-R^102Z5, -COCO-R^102Z5, -O-R^102Z5, -SO₂-R^101Z5, -SO₂N (R^102Z5)₂, -CON (R^102Z5)₂, -N (R^102Z5)₂, -NHCO-R^102Z5, -NHCO-N (R^102Z5)₂, -NHCOOR^102Z5, -OCON (R^102Z5)₂, Halogen atom, cyano group, nitro group, -SO_ThreeM, -CO₂M represents a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent.
  R^1Z5, R^2Z5, R^3Z5, R^4Z5, R^5Z5, R^6Z5And R^7Z5Independently of one another, a hydrogen atom, -CO-R^102Z5, -COO-R^101Z5, -OCO-R^102Z5, -COCO-R^102Z5, -O-R^102Z5, -SO₂-R^101Z5, -SO₂N (R^102Z5)₂, -CON (R^102Z5)₂, -N (R^102Z5)₂, -NHCO-R^102Z5, -NHCO-N (R^102Z5)₂, -NHCOOR^102Z5, -OCON (R^102Z5)₂, Halogen atom, cyano group, nitro group, -SO_ThreeM, -CO₂M represents an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group, and R^2Z5And R^3Z5, R^3Z5And R^4Z5And R^4Z5And R^5Z5May be bonded to each other to form a ring, and R^2Z5, R^3Z5, R^4Z5And R^5Z5At least one of -CO-R^102Z5, -COO-R^101Z5, -OCO-R^102Z5, -COCO-R^102Z5, -O-R^102Z5, -SO₂-R^101Z5, -SO₂N (R^102Z5)₂, -CON (R^102Z5)₂, -N (R^102Z5)₂, -NHCO-R^102Z5, -NHCO-N (R^102Z5)₂, -NHCOOR^102Z5, -OCON (R^102Z5)₂, Halogen atom, cyano group, nitro group, -SO_ThreeM, -CO₂M, a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent, or R^2Z5And R^3Z5, R^3Z5And R^4Z5And R^4Z5And R^5Z5At least one pair of these are bonded to form a ring.
  R^101Z5Represents a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent.
  R^102Z5Represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
  M represents a hydrogen atom or an alkali metal atom.
  R^101Z5, R^102Z5And when there are a plurality of M, they may be the same or different.
  A wavy line represents an E body or a Z body. ]
  [38]
  R^N1Z5Is a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent, [37].
  [39]
  R^1Z5, R^6Z5And R^7Z5[37] or [38], wherein is a hydrogen atom.
  [40]
  R^2Z5, R^3Z5, R^4Z5And R^5Z5The compound according to any one of [37] to [39], wherein at least one of is a nitro group or a tert-butyl group.
  [41]
  A compound represented by formula (IZ6).

[In the formula (IZ6)
  D represents a structure having an isoindoline skeleton.
  Z is -SO_Three ^-Or -CO₂ ^-Represents.
  A^{c +}Represents a c-valent metal cation.
  a represents an integer of 1 to 10.
  b represents an integer of 1 or more.
  c represents an integer of 2 to 10.
  d represents an integer of 1 or more.
  D, Z, a or A^{c +}When a plurality of are present, they may be the same or different.
  Formula (I′Z6) and Formula (I ″ Z6) each represent a partial structure of Formula (IZ6), and D, Z, A^{c +}, A, b, c and d represent the same as in formula (IZ6).
  However, the negative valence of the partial structure represented by the formula (I′Z6) and the absolute value of the positive valence of the partial structure represented by the formula (I ″ Z6) are the same. ]
  [42]
  The compound according to [41], wherein the compound represented by the formula (IZ6) is a compound represented by the formula (IZ6-A).

[In the formula (IZ6-A)
  A^{c +}, B, c and d have the same meaning as described above.
  R^1AZ6, R^2AZ6, R^3AZ6, R^4AZ6, R^5AZ6, R^AA1Z6, R^AA2Z6, R^12AZ6And R^13AZ6Independently of one another, a hydrogen atom, -CO-R^102AZ6, -COO-R^101AZ6, -OCO-R^102AZ6, -COCO-R^102AZ6, -O-R^102AZ6, -SO₂-R^101AZ6, -SO₂N (R^102AZ6)₂, -CON (R^102AZ6)₂, -N (R^102AZ6)₂, -NHCO-R^102AZ6, -NHCO-N (R^102AZ6)₂, -NHCOOR^102AZ6, -OCON (R^102AZ6)₂, Halogen atom, cyano group, nitro group, -SO_ThreeM, -CO₂M, -SO_Three ^-, -CO₂ ^-Represents a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent.
  R^2AZ6And R^3AZ6, R^3AZ6And R^4AZ6, R^4AZ6And R^5AZ6, R^AA1Z6And R^AA2Z6And R^12AZ6And R^13AZ6May be bonded to each other to form a ring.
  R^101AZ6Independently represent a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
  R^102AZ6Independently represent a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms, or an optionally substituted heterocyclic group.
  M represents a hydrogen atom or an alkali metal atom.
  Formula (IZ6-A ′) and Formula (IZ6-A ″) each represent a partial structure of Formula (IZ6-A), and A^{c +}, B, c, d, R^1AZ6, R^2AZ6, R^3AZ6, R^4AZ6, R^5AZ6, R^AA1Z6, R^AA2Z6, R^12AZ6And R^13AZ6Represents the same as in formula (IZ6-A).
  R^1AZ6, R^2AZ6, R^3AZ6, R^4AZ6, R^5AZ6, R^AA1Z6, R^AA2Z6, R^12AZ6, R^13AZ6, R^101AZ6, R^102AZ6, M, c or A^{c +}When a plurality of are present, they may be the same or different.
  R^1AZ6, R^2AZ6, R^3AZ6, R^4AZ6, R^5AZ6, R^AA1Z6, R^AA2Z6, R^12AZ6, R^13AZ6, R^101AZ6And R^102AZ6Satisfies at least one of (ra-i) to (ra-iii), and R^1AZ6, R^2AZ6, R^3AZ6, R^4AZ6, R^5AZ6, R^AA1Z6, R^AA2Z6, R^12AZ6, R^13AZ6, R^101AZ6And R^102AZ6-SO_Three ^-Or -CO₂ ^-The total number of is a.
  (Ra-i) R^1AZ6, R^2AZ6, R^3AZ6, R^4AZ6, R^5AZ6, R^AA1Z6, R^AA2Z6, R^12AZ6And R^13AZ6At least one of -SO_Three ^-Or -CO₂ ^-It is.
  (Ra-ii) R^1AZ6, R^2AZ6, R^3AZ6, R^4AZ6, R^5AZ6, R^AA1Z6, R^AA2Z6, R^12AZ6And R^13AZ6At least one of -CO-R^102AZ6, -COO-R^101AZ6, -OCO-R^102AZ6, -COCO-R^102AZ6, -O-R^102AZ6, -SO₂-R^101AZ6, -SO₂N (R^102AZ6)₂, -CON (R^102AZ6)₂, -N (R^102AZ6)₂, -NHCO-R^102AZ6, -NHCO-N (R^102AZ6)₂, -NHCOOR^102AZ6Or -OCON (R^102AZ6)₂And the R^101AZ6And R^102AZ6-SO_Three ^-Or -CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or -SO_Three ^-Or -CO₂ ^-Is a heterocyclic group having However, the hydrocarbon group or the heterocyclic group is -SO_Three ^-And -CO₂ ^-It may have a substituent other than.
  (Ra-iii) R^1AZ6, R^2AZ6, R^3AZ6, R^4AZ6, R^5AZ6, R^AA1Z6, R^AA2Z6, R^12AZ6And R^13AZ6At least one of -SO_Three ^-Or -CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or -SO_Three ^-Or -CO₂ ^-Is a heterocyclic group having However, the hydrocarbon group and the heterocyclic group are —SO_Three ^-Or -CO₂ ^-It may have a substituent other than.
  a represents the same meaning as in formula (IZ6). When a plurality of a are present, they may be the same or different.
  The absolute value of the negative valence of the partial structure represented by the formula (IZ6-A ′) and the positive valence of the partial structure represented by the formula (IZ6-A ″) are the same.
  A wavy line represents an E body or a Z body. ]
  [43]
  The compound according to [42], wherein the compound represented by the formula (IZ6-A) is a compound represented by the formula (IZ6-B).

[In the formula (IZ6-B)
  A^{c +}, B, c, d and wavy lines have the same meaning as described above.
  L¹Is —CO— or —SO₂-Represents.
  R^1BZ6, R^2BZ6, R^3BZ6, R^4BZ6, R^5BZ6, R^11BZ6, R^12BZ6And R^13BZ6Independently of one another, a hydrogen atom, -CO-R^102BZ6, -COO-R^101BZ6, -OCO-R^102BZ6, -COCO-R^102BZ6, -O-R^102BZ6, -SO₂-R^101BZ6, -SO₂N (R^102BZ6)₂, -CON (R^102BZ6)₂, -N (R^102BZ6)₂, -NHCO-R^102BZ6, -NHCO-N (R^102BZ6)₂, -NHCOOR^102BZ6, -OCON (R^102BZ6)₂, Halogen atom, cyano group, nitro group, -SO_ThreeM, -CO₂M, -SO_Three ^-, -CO₂ ^-Represents a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent.
  R^2BZ6And R^3BZ6, R^3BZ6And R^4BZ6, R^4BZ6And R^5BZ6And R^12BZ6And R^13BZ6May be bonded to each other to form a ring.
  R^101BZ6Independently represent a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
  R^102BZ6Independently represent a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms, or an optionally substituted heterocyclic group.
  Formula (IZ6-B ′) and Formula (IZ6-B ″) each represent a partial structure of Formula (IZ6-B), and A^{c +}, B, c, d, R^1BZ6, R^2BZ6, R^3BZ6, R^4BZ6, R^5BZ6, R^11BZ6, R^12BZ6, R^13BZ6And L¹Represents the same as in formula (IZ6-B).
  M represents the same meaning as described above.
  R^1BZ6, R^2BZ6, R^3BZ6, R^4BZ6, R^5BZ6, R^11BZ6, R^12BZ6, R^13BZ6, R^101BZ6, R^102BZ6, L¹, M, c or A^{c +}When a plurality of are present, they may be the same or different.
  R^1BZ6, R^2BZ6, R^3BZ6, R^4BZ6, R^5BZ6, R^11BZ6, R^12BZ6, R^13BZ6, R^101BZ6And R^102BZ6Satisfies at least one of (rb-i) to (rb-iii), and R^1BZ6, R^2BZ6, R^3BZ6, R^4BZ6, R^5BZ6, R^11BZ6, R^12BZ6, R^13BZ6, R^101BZ6And R^102BZ6-SO_Three ^-Or -CO₂ ^-The total number of is a.
  (Rb-i) R^1BZ6, R^2BZ6, R^3BZ6, R^4BZ6, R^5BZ6, R^11BZ6, R^12BZ6And R^13BZ6At least one of -SO_Three ^-Or -CO₂ ^-It is.
  (Rb-ii) R^1BZ6, R^2BZ6, R^3BZ6, R^4BZ6, R^5BZ6, R^11BZ6, R^12BZ6And R^13BZ6At least one of -CO-R^102BZ6, -COO-R^101BZ6, -OCO-R^102BZ6, -COCO-R^102BZ6, -O-R^102BZ6, -SO₂-R^101BZ6, -SO₂N (R^102BZ6)₂Or -CON (R^102BZ6)₂, -N (R^102BZ6)₂, -NHCO-R^102BZ6, -NHCO-N (R^102BZ6)₂, -NHCOOR^102BZ6Or -OCON (R^102BZ6)₂Because
  R^101BZ6And R^102BZ6-SO_Three ^-Or -CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or -SO_Three ^-Or -CO₂ ^-Is a heterocyclic group having However, the hydrocarbon group or the heterocyclic group is -SO_Three ^-And -CO₂ ^-It may have a substituent other than.
  (Rb-iii) R^1BZ6, R^2BZ6, R^3BZ6, R^4BZ6, R^5BZ6, R^11BZ6, R^12BZ6And R^13BZ6At least one of -SO_Three ^-Or -CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or -SO_Three ^-Or -CO₂ ^-Is a heterocyclic group having However, the hydrocarbon group or the heterocyclic group is -SO_Three ^-And -CO₂ ^-It may have a substituent other than.
  a represents the same meaning as in formula (IZ6-A). When a plurality of a are present, they may be the same or different.
  The absolute value of the negative valence of the partial structure represented by the formula (IZ6-B ′) and the positive valence of the partial structure represented by the formula (IZ6-B ″) are the same. ]
  [44]
  L¹The compound according to [43], wherein is -CO-.
  [45]
  R^11BZ6Are an optionally substituted aliphatic hydrocarbon group having 1 to 40 carbon atoms, an optionally substituted phenyl group, an optionally substituted naphthyl group, and a substituent. A tetrahydronaphthyl group which may have, a thienyl group which may have a substituent, a furyl group which may have a substituent or a pyridinyl group which may have a substituent [43] Or the compound according to [44].
[46]
  The compound according to [43], wherein the compound represented by the formula (IZ6-B) is a compound represented by the formula (IZ6-C).

[In the formula (IZ6-C)
  A^{c +}, B, c, d, L¹And wavy lines have the same meaning as described above.
  L²Is —CO— or —SO₂-Represents.
  R^1CZ6, R^2CZ6, R^3CZ6, R^4CZ6, R^5CZ6, R^11CZ6And R^14CZ6Independently of one another, a hydrogen atom, -CO-R^102CZ6, -COO-R^101CZ6, -OCO-R^102CZ6, -COCO-R^102CZ6, -O-R^102CZ6, -SO₂-R^101CZ6, -SO₂N (R^102CZ6)₂, -CON (R^102CZ6)₂, -N (R^102CZ6)₂, -NHCO-R^102CZ6, -NHCO-N (R^102CZ6)₂, -NHCOOR^102CZ6, -OCON (R^102CZ6)₂, Halogen atom, cyano group, nitro group, -SO_ThreeM, -CO₂M, -SO_Three ^-, -CO₂ ^-Represents a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent.
  R^2CZ6And R^3CZ6, R^3CZ6And R^4CZ6And R^4CZ6And R^5CZ6May be bonded to each other to form a ring.
  R^101CZ6Independently represent a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
  R^102CZ6Independently represent a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms, or an optionally substituted heterocyclic group.
  M represents the same meaning as described above.
  Formula (IZ6-C ′) and Formula (IZ6-C ″) each represent a partial structure of Formula (IZ6-C), and A^{c +}, B, c, d, R^1CZ6, R^2CZ6, R^3CZ6, R^4CZ6, R^5CZ6, R^11CZ6, R^14CZ6, L¹And L²Represents the same as in formula (IZ6-C).
  R^1CZ6, R^2CZ6, R^3CZ6, R^4CZ6, R^5CZ6, R^11CZ6, R^14CZ6, R^101CZ6, R^102CZ6, L¹, L², M, c or A^{c +}When a plurality of are present, they may be the same or different.
  R^1CZ6, R^2CZ6, R^3CZ6, R^4CZ6, R^5CZ6, R^11CZ6, R^14CZ6, R^101CZ6And R^102CZ6Satisfies at least one of (rc-i) to (rc-iii), and R^1CZ6, R^2CZ6, R^3CZ6, R^4CZ6, R^5CZ6, R^11CZ6, R^14CZ6, R^101CZ6And R^102CZ6-SO_Three ^-Or -CO₂ ^-The total number of is a.
  (Rc-i) R^1CZ6, R^2CZ6, R^3CZ6, R^4CZ6, R^5CZ6, R^11CZ6And R^14CZ6At least one of -SO_Three ^-Or -CO₂ ^-It is.
  (Rc-ii) R^1CZ6, R^2CZ6, R^3CZ6, R^4CZ6, R^5CZ6, R^11CZ6And R^14CZ6At least one of -CO-R^102CZ6, -COO-R^101CZ6, -OCO-R^102CZ6, -COCO-R^102CZ6, -O-R^102CZ6, -SO₂-R^101CZ6, -SO₂N (R^102CZ6)₂, -CON (R^102CZ6)₂, -N (R^102CZ6)₂, -NHCO-R^102CZ6, -NHCO-N (R^102CZ6)₂, -NHCOOR^102CZ6Or -OCON (R^102CZ6)₂And the R^101CZ6And R^102CZ6-SO_Three ^-Or -CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or -SO_Three ^-Or -CO₂ ^-Is a heterocyclic group having However, the hydrocarbon group or the heterocyclic group is -SO_Three ^-And -CO₂ ^-It may have a substituent other than.
  (Rc-iii) R^1CZ6, R^2CZ6, R^3CZ6, R^4CZ6, R^5CZ6, R^11CZ6And R^14CZ6At least one of -SO_Three ^-Or -CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or -SO_Three ^-Or -CO₂ ^-Is a heterocyclic group having However, the hydrocarbon group or the heterocyclic group is -SO_Three ^-And -CO₂ ^-It may have a substituent other than.
  a represents the same meaning as in formula (IZ6-B). When a plurality of a are present, they may be the same or different.
  The absolute value of the negative valence of the partial structure represented by the formula (IZ6-C ′) and the positive valence of the partial structure represented by the formula (IZ6-C ″) are the same. ]
  [47]
  R^11CZ6And R^14CZ6Are the same group and L¹And L²The compound according to [46], wherein and are the same groups.
  [48]
  L¹And L²[46] or [47], wherein is -CO-.
  [49]
  R^11CZ6And R^14CZ6Are an optionally substituted aliphatic hydrocarbon group having 1 to 40 carbon atoms, an optionally substituted phenyl group, an optionally substituted naphthyl group, and a substituent. A tetrahydronaphthyl group which may have, a thienyl group which may have a substituent, a furyl group which may have a substituent or a pyridinyl group which may have a substituent [46] To [48].
  [50]
  The compound according to [43], wherein the compound represented by the formula (IZ6-B) is a compound represented by the formula (IZ6-D).

[In the formula (IZ6-D),
  A^{c +}, B, c, d, L¹And wavy lines have the same meaning as described above.
  R^20DZ6And R^30DZ6Combine to form ring Q.
  The ring Q may have a substituent and is a ring having 5 to 7 members, and the ring Q may be a hydrocarbon ring or a heterocyclic ring. Ring Q is condensed with a monocyclic ring which may have a substituent having 5 to 7 ring members selected from hydrocarbon rings and heterocyclic rings, or a condensed ring in which two or more of the monocyclic rings are condensed. May be.
  R^1DZ6, R^2DZ6, R^3DZ6, R^4DZ6, R^5DZ6And R^11DZ6Independently of one another, a hydrogen atom, -CO-R^102DZ6, -COO-R^101DZ6, -OCO-R^102DZ6, -COCO-R^102DZ6, -O-R^102DZ6, -SO₂-R^101DZ6, -SO₂N (R^102DZ6)₂, -CON (R^102DZ6)₂, -N (R^102DZ6)₂, -NHCO-R^102DZ6, -NHCO-N (R^102DZ6)₂, -NHCOOR^102DZ6, -OCON (R^102DZ6)₂, Halogen atom, cyano group, nitro group, -SO_ThreeM, -CO₂M, -SO_Three ^-, -CO₂ ^-Represents a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent.
  R^2DZ6And R^3DZ6, R^3DZ6And R^4DZ6And R^4DZ6And R^5DZ6May be bonded to each other to form a ring.
  R^101DZ6Independently represent a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
  R^102DZ6Independently represent a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms, or an optionally substituted heterocyclic group.
  M represents the same meaning as described above.
  Formula (IZ6-D ′) and Formula (IZ6-D ″) each represent a partial structure of Formula (IZ6-D), and A^{c +}, B, c, d, R^1DZ6, R^2DZ6, R^3DZ6, R^4DZ6, R^5DZ6, R^11DZ6, R^20DZ6, R^30DZ6And L¹Represents the same as in formula (IZ6-D).
  R^1DZ6, R^2DZ6, R^3DZ6, R^4DZ6, R^5DZ6, R^11DZ6, R^101DZ6, R^102DZ6, L¹, M, R^20DZ6, R^30DZ6, Ring Q, c or A^{c +}When a plurality of are present, they may be the same or different.
  R^1DZ6, R^2DZ6, R^3DZ6, R^4DZ6, R^5DZ6, R^11DZ6, R^101DZ6, R^102DZ6And ring Q satisfies at least one of (rd-i) to (rd-iv), and R^1DZ6, R^2DZ6, R^3DZ6, R^4DZ6, R^5DZ6, R^11DZ6, R^101DZ6, R^102DZ6And -Q possessed by ring Q_Three ^-Or -CO₂ ^-The total number of is a.
  (Rd-i) R^1DZ6, R^2DZ6, R^3DZ6, R^4DZ6, R^5DZ6And R^11DZ6At least one of -SO_Three ^-Or -CO₂ ^-It is.
  (Rd-ii) R^1DZ6, R^2DZ6, R^3DZ6, R^4DZ6, R^5DZ6And R^11DZ6At least one of -CO-R^102DZ6, -COO-R^101DZ6, -OCO-R^102DZ6, -COCO-R^102DZ6, -O-R^102DZ6, -SO₂-R^101DZ6, -SO₂N (R^102DZ6)₂, -CON (R^102DZ6)₂, -N (R^102DZ6)₂, -NHCO-R^102DZ6, -NHCO-N (R^102DZ6)₂, -NHCOOR^102DZ6Or -OCON (R^102DZ6)₂And the R^101DZ6And R^102DZ6-SO_Three ^-Or -CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or -SO_Three ^-Or -CO₂ ^-Is a heterocyclic group having However, the hydrocarbon group or the heterocyclic group is -SO_Three ^-And -CO₂ ^-It may have a substituent other than.
  (Rd-iii) R^1DZ6, R^2DZ6, R^3DZ6, R^4DZ6, R^5DZ6And R^11DZ6At least one of -SO_Three ^-Or -CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or -SO_Three ^-Or -CO₂ ^-Is a heterocyclic group having However, the hydrocarbon group or the heterocyclic group is -SO_Three ^-And -CO₂ ^-It may have a substituent other than.
  (Rd-iv) Ring Q is -SO_Three ^-Or -CO₂ ^-Have
  a represents the same meaning as in formula (IZ6-B). When a plurality of a are present, they may be the same or different.
  The absolute value of the negative valence of the partial structure represented by the formula (IZ6-D ′) and the positive valence of the partial structure represented by the formula (IZ6-D ″) are the same. ]
  [51]
  L¹The compound according to [50], wherein is -CO-.
  [52]
  R^11DZ6Are an optionally substituted aliphatic hydrocarbon group having 1 to 40 carbon atoms, an optionally substituted phenyl group, an optionally substituted naphthyl group, and a substituent. A tetrahydronaphthyl group which may have, a thienyl group which may have a substituent, a furyl group which may have a substituent or a pyridinyl group which may have a substituent [50] Or the compound as described in [51].
  [53]
  The compound according to [50], wherein the compound represented by the formula (IZ6-D) is a compound represented by the formula (IZ6-E).

[In the formula (IZ6-E),
  A^{c +}, B, c, d, L¹And wavy lines have the same meaning as described above.
  R^1EZ6, R^2EZ6, R^3EZ6, R^4EZ6, R^5EZ6, R^6EZ6, R^7EZ6And R^11EZ6Independently of one another, a hydrogen atom, -CO-R^102EZ6, -COO-R^101EZ6, -OCO-R^102EZ6, -COCO-R^102EZ6, -O-R^102EZ6, -SO₂-R^101EZ6, -SO₂N (R^102EZ6)₂, -CON (R^102EZ6)₂, -N (R^102EZ6)₂, -NHCO-R^102EZ6, -NHCO-N (R^102EZ6)₂, -NHCOOR^102EZ6, -OCON (R^102EZ6)₂, Halogen atom, cyano group, nitro group, -SO_ThreeM, -CO₂M, -SO_Three ^-, -CO₂ ^-Represents a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent.
  R^2EZ6And R^3EZ6, R^3EZ6And R^4EZ6And R^4EZ6And R^5EZ6May be bonded to each other to form a ring.
  R^101EZ6Independently represent a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
  R^102EZ6Independently represent a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms, or an optionally substituted heterocyclic group.
  M represents the same meaning as described above.
  Formula (IZ6-E ′) and Formula (IZ6-E ″) each represent a partial structure of Formula (IZ6-E), and A^{c +}, B, c, d, R^1EZ6, R^2EZ6, R^3EZ6, R^4EZ6, R^5EZ6, R^6EZ6, R^7EZ6, R^11EZ6And L¹Represents the same as in formula (IZ6-E).
  R^1EZ6, R^2EZ6, R^3EZ6, R^4EZ6, R^5EZ6, R^6EZ6, R^7EZ6, R^11EZ6, R^101EZ6, R^102EZ6, L¹, M, c or A^{c +}When a plurality of are present, they may be the same or different.
  R^1EZ6, R^2EZ6, R^3EZ6, R^4EZ6, R^5EZ6, R^6EZ6, R^7EZ6, R^11EZ6, R^101EZ6And R^102EZ6Satisfies at least one of (re-i) to (re-iii), and R^1EZ6, R^2EZ6, R^3EZ6, R^4EZ6, R^5EZ6, R^6EZ6, R^7EZ6, R^11EZ6, R^101EZ6And R^102EZ6-SO_Three ^-Or -CO₂ ^-The total number of is a.
  (Re-i) R^1EZ6, R^2EZ6, R^3EZ6, R^4EZ6, R^5EZ6, R^6EZ6, R^7EZ6And R^11EZ6At least one of -SO_Three ^-Or -CO₂ ^-It is.
  (Re-ii) R^1EZ6, R^2EZ6, R^3EZ6, R^4EZ6, R^5EZ6, R^6EZ6, R^7EZ6And R^11EZ6At least one of -CO-R^102EZ6, -COO-R^101EZ6, -OCO-R^102EZ6, -COCO-R^102EZ6, -O-R^102EZ6, -SO₂-R^101EZ6, -SO₂N (R^102EZ6)₂, -CON (R^102EZ6)₂, -N (R^102EZ6)₂, -NHCO-R^102EZ6, -NHCO-N (R^102EZ6)₂, -NHCOOR^102EZ6Or -OCON (R^102EZ6)₂And the R^101EZ6And R^102EZ6-SO_Three ^-Or -CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or -SO_Three ^-Or -CO₂ ^-Is a heterocyclic group having However, the hydrocarbon group or the heterocyclic group is -SO_Three ^-And -CO₂ ^-It may have a substituent other than.
  (Re-iii) R^1EZ6, R^2EZ6, R^3EZ6, R^4EZ6, R^5EZ6, R^6EZ6, R^7EZ6And R^11EZ6At least one of -SO_Three ^-Or -CO₂ ^-A hydrocarbon group having 1 to 40 carbon atoms or -SO_Three ^-Or -CO₂ ^-Is a heterocyclic group having However, the hydrocarbon group or the heterocyclic group is -SO_Three ^-And -CO₂ ^-It may have a substituent other than.
  a represents the same meaning as in formula (IZ6-D). When a plurality of a are present, they may be the same or different.
  The negative valence of the partial structure represented by the formula (IZ6-E ′) and the absolute value of the positive valence of the partial structure represented by the formula (IZ6-E ″) are the same. ]
  [54]
  L¹The compound according to [53], wherein is -CO-.
  [55]
  R^11EZ6Are an optionally substituted aliphatic hydrocarbon group having 1 to 40 carbon atoms, an optionally substituted phenyl group, an optionally substituted naphthyl group, and a substituent. A tetrahydronaphthyl group which may have, a thienyl group which may have a substituent, a furyl group which may have a substituent or a pyridinyl group which may have a substituent [53] Or the compound according to [54].

  ADVANTAGE OF THE INVENTION According to this invention, the coloring composition and compound which can be used for formation of a color filter with a small phase difference value are provided.

  The colored composition of the present invention may be a compound represented by formula (IZ1) (hereinafter sometimes referred to as compound (IZ1)) or a compound represented by formula (IZ2) (hereinafter referred to as compound (IZ2)). A compound represented by formula (IZ3) (hereinafter sometimes referred to as compound (IZ3)), a compound represented by formula (IZ4) (hereinafter sometimes referred to as compound (IZ4)), formula (I One or more selected from a compound represented by IZ5) (hereinafter sometimes referred to as compound (IZ5)) and a compound represented by formula (IZ6) (hereinafter sometimes referred to as compound (IZ6)) , Compound (Z))) and at least one of a resin (hereinafter sometimes referred to as resin (B)) and a solvent (hereinafter sometimes referred to as solvent (E)).

The compound (IZ1), the compound (IZ2), the compound (IZ3), the compound (IZ4), the compound (IZ5), and the compound (IZ6) also include tautomers and salts thereof, respectively.
Compound (IZ1), Compound (IZ2), Compound (IZ3), Compound (IZ4), Compound (IZ5) and Compound (IZ6) can each be used as a colorant.
The colored composition of the present invention may contain one or more compounds (IZ1), may contain one or more compounds (IZ2), and may contain one or more compounds (IZ2). Two or more compounds (IZ3) may be contained, one or two or more compounds (IZ4) may be contained, and one or two or more compounds (IZ5) are contained. One or two or more compounds (IZ6) may be included.
When the coloring composition of this invention contains 1 or more types chosen from a compound (IZ1), a compound (IZ2), and a compound (IZ3), it is preferable that the resin (B) is necessarily included.
When the coloring composition of this invention contains 1 or more types chosen from a compound (IZ4), a compound (IZ5), and a compound (IZ6), it is preferable that the solvent (E) is necessarily included.
When the colored composition of the present invention contains a solvent, the compound (IZ1), the compound (IZ2), the compound (IZ3), the compound (IZ4), the compound (IZ5), and the compound (IZ6) are dispersed in the solvent (E). It is preferable.

When the colored composition of the present invention contains the compound (IZ1), the colored composition may be referred to as a colorant other than the compound (IZ1) (hereinafter referred to as a colorant (A1Z1). In the following, the compound (IZ1) and The colorant (A1Z1) may further be collectively referred to as “colorant (AZ1)”). The colorant (A1Z1) may contain one or more colorants.
When the colored composition of the present invention contains the compound (IZ2), the colored composition may be referred to as a colorant other than the compound (IZ2) (hereinafter referred to as a colorant (A1Z2). In the following, the compound (IZ2) and The colorant (A1Z2) may further be collectively referred to as “colorant (AZ2)”). The colorant (A1Z2) may contain one or more colorants.
When the colored composition of the present invention contains compound (IZ3), the colored composition may be referred to as a colorant other than compound (IZ3) (hereinafter referred to as colorant (A1Z3). In the following, compound (IZ3) and The colorant (A1Z3) may further be collectively referred to as “colorant (AZ3)”). The colorant (A1Z3) may contain one or more colorants.
When the colored composition of the present invention contains compound (IZ4), the colored composition may be referred to as a colorant other than compound (IZ4) (hereinafter referred to as colorant (A1Z4). In the following, compound (IZ4) and The colorant (A1Z4) may further be collectively referred to as “colorant (AZ4)”). The colorant (A1Z4) may contain one or more colorants.
When the colored composition of the present invention contains compound (IZ5), the colored composition may be referred to as a colorant other than compound (IZ5) (hereinafter referred to as colorant (A1Z5). In the following, compound (IZ5) and The colorant (A1Z5) may further be collectively referred to as “colorant (AZ5)”). The colorant (A1Z5) may contain one or more colorants.
When the colored composition of the present invention contains compound (IZ6), the colored composition may be referred to as a colorant other than compound (IZ6) (hereinafter referred to as colorant (A1Z6). In the following, compound (IZ6) and The colorant (A1Z6) may further be collectively referred to as “colorant (AZ6)”). The colorant (A1Z6) may contain one or more colorants.
One or more selected from the colorant (A1Z1), the colorant (A1Z2), the colorant (A1Z3), the colorant (A1Z4), the colorant (A1Z5), and the colorant (A1Z6) are hereinafter referred to as the colorant (ZZ). ). The colorant (ZZ) preferably contains a yellow colorant or a green colorant.
One or more kinds selected from the colorant (AZ1), the colorant (AZ2), the colorant (AZ3), the colorant (AZ4), the colorant (AZ5), and the colorant (AZ6) are hereinafter referred to as the colorant (ZZZ). ).

It is preferable that the coloring composition of this invention contains both resin (B) and a solvent (E).
Moreover, the colored curable composition of the present invention comprises:
A compound represented by formula (IZ1), a compound represented by formula (IZ2), a compound represented by formula (IZ3), a compound represented by formula (IZ4), a compound represented by formula (IZ5), And at least one selected from compounds represented by formula (IZ6);
It contains at least one of resin (B) and solvent (E) and a polymerizable compound (C).
In other words, the colored curable composition of the present invention includes a colored composition and a polymerizable compound (C).
The colored curable composition of the present invention may contain a polymerization initiator (D).
The colored curable composition of the present invention may contain a polymerization initiation assistant (D1).
The coloring composition of the present invention may further contain a leveling agent (F) and an antioxidant.

<Compound (IZ1)>
Compound (IZ1) is a compound represented by formula (IZ1).

[In the formula (IZ1),
R ^O1Z1 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
R ^1Z1 , R ^2Z1 , R ^3Z1 , R ^4Z1 , R ^5Z1 , R ^6Z1 and R ^7Z1 are each independently a hydrogen atom, —CO—R ^102Z1 , —COO—R ^101Z1 , —OCO—R ^102Z1 , —COCO ^{-R 102Z1, -O-R 102Z1,} -SO 2 -R 101Z1, -SO 2 N (R 102Z1) 2, -CON (R 102Z1) 2, -N (R 102Z1) 2, -NHCO-R 102Z1, - _{^{NHCO-N (R 102Z1) 2}} , -NHCOOR 102Z1, -OCON (R 102Z1) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , carbon atoms, which may have a substituent The heterocyclic group which may have a hydrocarbon group or a substituent of number 1-40 is represented.
R ^2Z1 and R ^3Z1 , R ^3Z1 and R ^4Z1 , and R ^4Z1 and R ^5Z1 may be bonded to each other to form a ring.
R ^101Z1 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102Z1 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
M represents a hydrogen atom or an alkali metal atom.
When a plurality of R ^101Z1 , R ^102Z1 and M are present, they may be the same or different.
A wavy line represents an E body or a Z body. ]

The hydrocarbon group represented by R ^O1Z1 , R ^1Z1 , R ^2Z1 , R ^3Z1 , R ^4Z1 , R ^5Z1 , R ^6Z1 , R ^7Z1 , R ^101Z1 and R ^102Z1 has 1 to 40 carbon atoms, preferably 1 It is -30, More preferably, it is 1-20, More preferably, it is 1-15, Most preferably, it is 1-10.

The hydrocarbon group having 1 to 40 carbon atoms represented by R ^O1Z1 , R ^1Z1 , R ^2Z1 , R ^3Z1 , R ^4Z1 , R ^5Z1 , R ^6Z1 , R ^7Z1 , R ^101Z1 and R ^102Z1 is an aliphatic hydrocarbon group and It may be an aromatic hydrocarbon group, and the aliphatic hydrocarbon group may be saturated or unsaturated, and may be a chain or an alicyclic ring.

Saturated or unsaturated chain hydrocarbon groups represented by R ^O1Z1 , R ^1Z1 , R ^2Z1 , R ^3Z1 , R ^4Z1 , R ^5Z1 , R ^6Z1 , R ^7Z1 , R ^101Z1 and R ^102Z1 are methyl group, ethyl group Linear alkyl groups such as propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, heptadecyl, octadecyl and icosyl; Group, isobutyl group, sec-butyl group, tert-butyl group, (2-ethyl) butyl group, isopentyl group, neopentyl group, tert-pentyl group, (1-methyl) pentyl group, (2-methyl) pentyl group, (1-ethyl) pentyl, (3-ethyl) pentyl, isohexyl, (5-methyl) hexyl, (2-ethyl) hexyl and (3-ethyl) hexyl A branched alkyl group such as til group; vinyl group, 1-propenyl group, 2-propenyl group (allyl group), (1-methyl) ethenyl group, 2-butenyl group, 3-butenyl group, 1,3 An alkenyl group such as a butadienyl group, a (1- (2-propenyl)) ethenyl group, a (1,2-dimethyl) propenyl group and a 2-pentenyl group; The carbon number of the saturated or unsaturated chain hydrocarbon group is preferably 1 to 30, more preferably 1 to 20, still more preferably 1 to 15, particularly preferably 1 to 10, More preferably, it is 1-8, More preferably, it is 1-5. Especially, it is especially preferable that it is a C1-C10, More preferably, it is a C1-C8 linear or branched alkyl group, and a methyl group, an ethyl group, and a tert- butyl group are especially preferable.

The saturated or unsaturated alicyclic hydrocarbon group represented by R ^O1Z1 , R ^1Z1 , R ^2Z1 , R ^3Z1 , R ^4Z1 , R ^5Z1 , R ^6Z1 , R ^7Z1 , R ^101Z1 and R ^102Z1 includes a cyclopropyl group, 1-methylcyclopropyl group, cyclobutyl group, cyclopentyl group, cyclohexyl group, cycloheptyl group, 1-methylcyclohexyl group, 2-methylcyclohexyl group, 3-methylcyclohexyl group, 4-methylcyclohexyl group, 1,2-dimethylcyclohexyl Group, 1,3-dimethylcyclohexyl group, 1,4-dimethylcyclohexyl group, 2,3-dimethylcyclohexyl group, 2,4-dimethylcyclohexyl group, 2,5-dimethylcyclohexyl group, 2,6-dimethylcyclohexyl group, 3,4-dimethylcyclohexyl group, 3,5-dimethylcyclohexyl group, 2,2 Dimethylcyclohexyl group, 3,3-dimethylcyclohexyl group, 4,4-dimethylcyclohexyl group, cyclooctyl group, 2,4,6-trimethylcyclohexyl group, 2,2,6,6-tetramethylcyclohexyl group and 3,3 , 5,5-tetramethylcyclohexyl group, 4-pentylcyclohexyl group, 4-octylcyclohexyl group, cycloalkyl group such as 4-cyclohexylcyclohexyl group; cyclohexenyl group (for example, cyclohex-2-ene, cyclohex-3-ene) And cycloalkenyl groups such as cycloheptenyl group and cyclooctenyl group; norbornane group, adamantyl group, bicyclo [2.2.2] octane and the like. The carbon number of the saturated or unsaturated alicyclic hydrocarbon group is preferably 3 to 30, more preferably 3 to 20, still more preferably 4 to 20, and still more preferably 4 to 15. More preferably 5 to 15 and most preferably 5 to 10. Of these, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, and a cyclooctyl group are particularly preferable.

The aromatic hydrocarbon groups represented by R ^O1Z1 , R ^1Z1 , R ^2Z1 , R ^3Z1 , R ^4Z1 , R ^5Z1 , R ^6Z1 , and R ^7Z1 , R ^101Z1 and R ^102Z1 include a phenyl group, an o-tolyl group, m-tolyl group, p-tolyl group, 2-ethylphenyl group, 3-ethylphenyl group, 4-ethylphenyl group, 2,3-dimethylphenyl group, 2,4-dimethylphenyl group, 2,5-dimethylphenyl Group, 2,6-dimethylphenyl group, 3,4-dimethylphenyl group, 3,5-dimethylphenyl group, 4-vinylphenyl group, o-isopropylphenyl group, m-isopropylphenyl group, p-isopropylphenyl group, o-tert-butylphenyl group, m-tert-butylphenyl group, p-tert-butylphenyl group, mesityl group, 4-ethylphenyl group, 4-butylphenyl group, 4- N-phenyl group, 2,6-bis (2-propyl) phenyl group, 4-cyclohexylphenyl group, 2,4,6-trimethylphenyl group, 4-octylphenyl group, 1-naphthyl group, 2-naphthyl group, 5, Aromatic hydrocarbon groups such as 6,7,8-tetrahydro-1-naphthyl group, 5,6,7,8-tetrahydro-2-naphthyl group, fluorenyl group, phenanthryl group and anthryl group, pyrenyl group; It is done. The number of carbon atoms of the aromatic hydrocarbon group is preferably 6-30, more preferably 6-20, and even more preferably 6-15.

The hydrocarbon groups represented by R ^O1Z1 , R ^1Z1 , R ^2Z1 , R ^3Z1 , R ^4Z1 , R ^5Z1 , R ^6Z1 , R ^7Z1 , R ^101Z1 and R ^102Z1 are the hydrocarbon groups listed above (for example, aromatic hydrocarbons). A hydrogen group and a group obtained by combining at least one of a chain hydrocarbon group and an alicyclic hydrocarbon group), and an aralkyl group such as a benzyl group, a phenethyl group, or a 1-methyl-1-phenylethyl group. An arylalkenyl group such as a phenylethenyl group (phenylvinyl group); an arylalkynyl group such as a phenylethynyl group; a phenyl group to which one or more phenyl groups such as a biphenylyl group or a terphenylyl group are bonded; a cyclohexylmethylphenyl group, a benzyl A phenyl group, a (dimethyl (phenyl) methyl) phenyl group, etc. are mentioned.
The ^{groups represented} by R ^O1Z1 , R ^1Z1 , R ^2Z1 , R ^3Z1 , R ^4Z1 , R ^5Z1 , R ^6Z1 , R ^7Z1 , R ^101Z1 and R ^102Z1 are the hydrocarbon groups listed above (for example, chain hydrocarbon groups) And alicyclic hydrocarbon group), for example, cyclopropylmethyl group, cyclopropylethyl group, cyclobutylmethyl group, cyclobutylethyl group, cyclopentylmethyl group, cyclopentylethyl group, cyclohexylmethyl group, 2- It may be an alkyl group to which one or more alicyclic hydrocarbon groups such as a methylcyclohexylmethyl group, a cyclohexylethyl group, and an adamantylmethyl group are bonded.
These carbon numbers are preferably 4-30, more preferably 6-30, still more preferably 6-20, and preferably 4-20, more preferably 4-15. Especially preferably, it is 6-15.

The hydrocarbon group represented by R ^O1Z1 , R ^1Z1 , R ^2Z1 , R ^3Z1 , R ^4Z1 , R ^5Z1 , R ^6Z1 , R ^7Z1 , R ^101Z1 and R ^102Z1 may have a substituent. The substituent may be monovalent or divalent. In the divalent substituent, two bonds are preferably bonded to the same carbon atom to form a double bond.
As the monovalent substituent,
Methoxy group, ethoxy group, propoxy group, isopropoxy group, butoxy group, isobutoxy group, sec-butoxy group, tert-butoxy group, pentyloxy group, hexyloxy group, (2-ethyl) hexyloxy group, heptyloxy group, Octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, dodecyloxy group, (2-ethyl) hexyloxy group, icosyloxy group, 1-phenylethoxy group, 1-methyl-1-phenylethoxy group, phenyloxy group O-Tolyloxy group, 2,3-dimethylphenyloxy group, 2,4-dimethylphenyloxy group, 2,5-dimethylphenyloxy group, 2,6-dimethylphenyloxy group, 3,4-dimethylphenyloxy group 3,5-dimethylphenyloxy group, 2,2-dicia Phenyloxy group, 2,3-dicyanophenyloxy group, 2,4-dicyanophenyloxy group, 2,5-dicyanophenyloxy group, 2,6-dicyanophenyloxy group, 3,4-dicyanophenyloxy group, 3 , 5-dicyanophenyloxy group, 4-methoxyphenyloxy group, 2-methoxyphenyloxy group, 3-methoxyphenyloxy group, 4-ethoxyphenyloxy group, 2-ethoxyphenyloxy group, 3-ethoxyphenyloxy group, etc. And a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group represented by the following formula or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen) (Preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl) Oxy group derivatized group) is bonded to one side the like);

  Methylthio, ethylthio, propylthio, butylthio, tert-butylthio, pentylthio, hexylthio, (2-ethyl) hexylthio, heptylthio, octylthio, nonylthio, decylthio, undecylthio, dodecylthio, icosylthio A sulfanyl group to which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group, a phenylthio group and an o-tolylthio group is bonded;

Epoxy group, oxetanyl group, tetrahydrofuryl group, tetrahydropyranyl group;
Formyl group;
Acetyl group, propanoyl group, butanoyl group, 2,2-dimethylpropanoyl group, pentanoyl group, hexanoyl group, (2-ethyl) hexanoyl group, heptanoyl group, octanoyl group, nonanoyl group, decanoyl group, undecanoyl group, dodecanoyl group, A hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 11 carbon atoms) or a derivatized group thereof (for example, a carboxy group or a sulfo group) such as a henicosanoyl group, a benzoyl group, or a group represented by the following formula: , A carbonyl group to which a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), a group derived from an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. When the carbonyl group is an alkanoyl group, the carbon number is preferably 2 to 12);

  Methoxycarbonyl group, ethoxycarbonyl group, propoxycarbonyl group, butoxycarbonyl group, tert-butoxycarbonyl group, pentyloxycarbonyl group, hexyloxycarbonyl group, (2-ethyl) hexyloxycarbonyl group, heptyloxycarbonyl group, octyloxycarbonyl Group, nonyloxycarbonyl group, decyloxycarbonyl group, undecyloxycarbonyl group, dodecyloxycarbonyl group, icosyloxycarbonyl group, phenyloxycarbonyl group, o-tolyloxycarbonyl group and the like, and the following formulas A hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon number 10 oxycarbonyl group alkylsulfamoyl group (preferably octyl sulfamoyl group) were derivatized with such groups) is bonded to;

An amino group;
N-methylamino group, N, N-dimethylamino group, N-ethylamino group, N, N-diethylamino group, N-propylamino group, N, N-dipropylamino group, N-isopropylamino group, N, N-diisopropylamino group, N-butylamino group, N, N-dibutylamino group, N-isobutylamino group, N, N-diisobutylamino group, N-sec-butylamino group, N, N-disec-butyl Amino group, N-tert-butylamino group, N, N-ditert-butylamino group, N-pentylamino group, N, N-dipentylamino group, N- (1-ethylpropyl) amino group, N, N -Di (1-ethylpropyl) amino group, N-hexylamino group, N, N-dihexylamino group, N- (2-ethyl) hexylamino group, N, N-di (2-ethyl) Xylamino group, N-heptylamino group, N, N-diheptylamino group, N-octylamino group, N, N-dioctylamino group, N-nonylamino group, N, N-dinonylamino group, N-phenylamino group, N, N-diphenylamino group, N, N-ethylmethylamino group, N, N-propylmethylamino group, N, N-isopropylmethylamino group, N, N-butylmethylamino group, N-decylamino group, N , N-decylmethylamino group, N-undecylamino group, N, N-undecylmethylamino group, N-dodecylamino group, N, N-dodecylmethylamino group, N-icosylamino group, N, N-ico One of a silmethylamino group, an N, N-tert-butylmethylamino group, an N, N-phenylmethylamino group, and a group represented by the following formula: Two hydrocarbon groups having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or derivatized groups thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), 1 carbon atom An amino group substituted with 10 to 10 alkylsulfamoyl groups (preferably a group derivatized with an octylsulfamoyl group or the like);

A sulfamoyl group;
N-methylsulfamoyl group, N, N-dimethylsulfamoyl group, N-ethylsulfamoyl group, N, N-diethylsulfamoyl group, N-propylsulfamoyl group, N, N-dipropyls Rufamoyl group, N-isopropylsulfamoyl group, N, N-diisopropylsulfamoyl group, N-butylsulfamoyl group, N, N-dibutylsulfamoyl group, N-isobutylsulfamoyl group, N, N-diisobutylsulfamoyl group, N-sec-butylsulfamoyl group, N, N-disec-butylsulfamoyl group, N-tert-butylsulfamoyl group, N, N-ditert-butylsulfur Famoyl group, N-pentylsulfamoyl group, N, N-dipentylsulfamoyl group, N- (1-ethylpropyl) sulfamoyl group, , N-di (1-ethylpropyl) sulfamoyl group, N-hexylsulfamoyl group, N, N-dihexylsulfamoyl group, N- (2-ethyl) hexylsulfamoyl group, N, N-di ( 2-ethyl) hexylsulfamoyl group, N-heptylsulfamoyl group, N, N-diheptylsulfamoyl group, N-octylsulfamoyl group, N, N-dioctylsulfamoyl group, N, N -Octylmethylsulfamoyl group, N-nonylsulfamoyl group, N, N-dinonylsulfamoyl group, N-phenylsulfamoyl group, N, N-diphenylsulfamoyl group, N, N-ethylmethyl Sulfamoyl group, N, N-propylmethylsulfamoyl group, N, N-isopropylmethylsulfamoyl group, N, N-butylmethylsulfamoyl group N-decylsulfamoyl group, N, N-decylmethylsulfamoyl group, N-undecylsulfamoyl group, N, N-undecylmethylsulfamoyl group, N-dodecylsulfamoyl group, N, N-dodecylmethylsulfamoyl group, N-icosylsulfamoyl group, N, N-icosylmethylsulfamoyl group, N, N-tert-butylmethylsulfamoyl group, N, N-phenylmethylsulfa 1 or 2 hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a moyl group and the group represented by the following formula or a derivatized group thereof (for example, carboxy group, sulfo group) , A nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. A sulfamoyl group substituted with

  Formylamino group; acetylamino group, propanoylamino group, butanoylamino group, 2,2-dimethylpropanoylamino group, pentanoylamino group, hexanoylamino group, (2-ethyl) hexanoylamino group, heptanoyl Amino group, octanoylamino group, nonanoylamino group, decanoylamino group, undecanoylamino group, dodecanoylamino group, heicosanoylamino group, benzoylamino group, etc., and groups represented by the following formulae Or a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 12 carbon atoms) or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon number 1 10 to 10 alkylsulfamoyl groups (preferably octylsulfamoyl groups) and the like) Carbonyl amino group (if the alkanoylamino group the carbonyl group, the carbon number is preferably 1 to 12);

A hydroxy group;
Halogen atoms such as fluorine atom, chlorine atom, bromine atom and iodine atom;
Carboxy group, —CO ₂ M ² (M ² is alkali metal, preferably lithium, sodium, potassium); sulfo group, —SO ₃ M ² (M ² is alkali metal, preferably lithium, sodium, potassium); Nitro group A cyano group;

  Formyloxy group; acetoxy group, propanoyloxy group, butanoyloxy group, 2,2-dimethylpropanoyloxy group, pentanoyloxy group, hexanoyloxy group, (2-ethyl) hexanoyloxy group, heptanoyloxy Carbon such as a group, octanoyloxy group, nonanoyloxy group, decanoyloxy group, undecanoyloxy group, dodecanoyloxy group, heicosanoyloxy group, benzoyloxy group, and the group represented by the following formula A hydrocarbon group having 1 to 20 (preferably 1 to 10 carbons) or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), A group to which an alkyl sulfamoyl group (preferably a group derivatized with an octyl sulfamoyl group) is bound. Boniruokishi group (if the alkanoyloxy group and the carbonyl group, the carbon number is preferably 1 to 10);

  Methylsulfonyl group, ethylsulfonyl group, propylsulfonyl group, butylsulfonyl group, pentylsulfonyl group, hexylsulfonyl group, (2-ethyl) hexylsulfonyl group, heptylsulfonyl group, octylsulfonyl group, nonylsulfonyl group, decylsulfonyl group, un Decylsulfonyl group, dodecylsulfonyl group, icosylsulfonyl group, phenylsulfonyl group, p-tolylsulfonyl group and the like, and groups having 1 to 20 carbon atoms (preferably having 1 to 10 carbon atoms) such as groups represented by the following formulae: Hydrocarbon group or derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group) A group derivatized with a sulfonyl group) ;

A carbamoyl group;
N-methylcarbamoyl group, N, N-dimethylcarbamoyl group, N-ethylcarbamoyl group, N, N-diethylcarbamoyl group, N-propylcarbamoyl group, N, N-dipropylcarbamoyl group, N-isopropylcarbamoyl group, N , N-diisopropylcarbamoyl group, N-butylcarbamoyl group, N, N-dibutylcarbamoyl group, N-isobutylcarbamoyl group, N, N-diisobutylcarbamoyl group, N-sec-butylcarbamoyl group, N, N-disec- Butylcarbamoyl group, N-tert-butylcarbamoyl group, N, N-ditert-butylcarbamoyl group, N-pentylcarbamoyl group, N, N-dipentylcarbamoyl group, N- (1-ethylpropyl) carbamoyl group, N, N-di (1-ethylpropyl) carba Yl group, N-hexylcarbamoyl group, N, N-dihexylcarbamoyl group, N- (2-ethyl) hexylcarbamoyl group, N, N-di (2-ethyl) hexylcarbamoyl group, N-heptylcarbamoyl group, N, N-diheptylcarbamoyl group, N-octylcarbamoyl group, N, N-dioctylcarbamoyl group, N-nonylcarbamoyl group, N, N-octylmethylcarbamoyl group, N, N-octylbutylcarbamoyl group, N, N-di Nonylcarbamoyl group, N-phenylcarbamoyl group, N, N-diphenylcarbamoyl group, N, N-ethylmethylcarbamoyl group, N, N-propylmethylcarbamoyl group, N, N-isopropylmethylcarbamoyl group, N, N-butyl Methylcarbamoyl group, N-decylcarbamoyl group, N, N Decylmethylcarbamoyl group, N-undecylcarbamoyl group, N, N-undecylmethylcarbamoyl group, N-dodecylcarbamoyl group, N, N-dodecylmethylcarbamoyl group, N-icosylcarbamoyl group, N, N-icosyl 1 or 2 carbon atoms (preferably carbon atoms) such as a methylcarbamoyl group, an N, N-tert-butylmethylcarbamoyl group, an N, N-phenylmethylcarbamoyl group, and a group represented by the following formula A hydrocarbon group having 1 to 10) or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably A carbamoyl group substituted with a group derivatized with an octylsulfamoyl group) or the like;

Trifluoromethyl group, perfluoroethyl group, perfluoropropyl group, perfluoroisopropyl group, perfluorobutyl group, perfluoropentyl group, perfluorohexyl group, perfluoroheptyl group, perfluorooctyl group, perfluorononyl group, A carbon atom having 1 to 20 carbon atoms in which all hydrogen atoms such as perfluorodecyl group, perfluoroundecyl group, perfluorododecyl group, perfluoroicosyl group, perfluorocyclohexyl group and perfluorophenyl group are substituted with fluorine atoms. A hydrogen group;
Perfluoroethylmethyl group, perfluoropropylmethyl group, perfluoroisopropylmethyl group, perfluorobutylmethyl group, perfluoropentylmethyl group, perfluorohexylmethyl group, perfluoroheptylmethyl group, perfluorooctylmethyl group, perfluoro A straight chain having 1 to 20 carbon atoms in which all hydrogen atoms such as nonylmethyl group, perfluorodecylmethyl group, perfluoroundecylmethyl group, perfluorododecylmethyl group and perfluoroicosylmethyl group are substituted with fluorine atoms Or a hydrocarbon group having 1 to 20 carbon atoms substituted by a branched alkyl group;

  1 to 20 carbon atoms (preferably carbon atoms) in which part of hydrogen atoms such as 2-fluorophenyl group, 3-fluorophenyl group, 4-fluorophenyl group and 2,4,6-trifluorophenyl group are substituted with fluorine. 1-10) hydrocarbon radicals;

-CO-SH, -CO-S- CH 3, -CO-S-CH 2 CH 3, -CO-S-CH 2 -CH 2 -CH 3, -CO-S-CH 2 -CH 2 -CH 2 A thiocarbonyl group bonded to an alkyl group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as —CH _3; and an aryl group having 6 to 20 carbon atoms such as —CO—S—C ₆ H _5. A thiocarbonyl group;

  * -COCO-R as represented by the following formula (wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, satisfying 1 to 20 carbon atoms among the hydrocarbon groups mentioned above) Or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably octyl sulfamoyl group) A group derived from, etc.)

* -NRCONR ₂ represented by the following formula (wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, those satisfying 1 to 20 carbon atoms among the hydrocarbon groups mentioned above) ) Or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group), etc. And the R may be the same or different from each other and may be bonded to each other to form a ring);

* -OCONR ₂ represented by the following formula (wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, those satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above) ) Or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group), etc. And the R may be the same or different from each other and may be bonded to each other to form a ring);

  * -NRCOOR as represented by the following formula (wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, those satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above)) Or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. A derivatized group), wherein the Rs may be the same or different from each other and may be bonded to each other to form a ring;

_{* -OP (O) (OCH 3} ) in such _{2 * -OP (O) (OR} ) 2 ( wherein, R represents a hydrogen atom, a hydrocarbon group (e.g., hydrocarbon groups mentioned above having 1 to 20 carbon atoms Or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms) A group derived from (preferably an octylsulfamoyl group) or the like, and the Rs may be the same or different from each other, and may be bonded to each other to form a ring;
* -SiR ₃ (* -Si (CH ₃ ) ₃ , * -Si (CH ₂ CH ₃ ) ₃ , * -Si (C ₆ H ₅ ) ₃ and * -Si (CH (CH ₃ ) ₂ ) ₃ In the formula, R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, those satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivatizing group thereof (for example, a carboxy group, sulfo group). A group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), a C1-C10 alkylsulfamoyl group (preferably an octylsulfamoyl group) and the like, and the R is Groups that may be the same or different from each other and may be bonded to each other to form a ring);
Etc.

As the divalent substituent, an oxo group, a thioxo group, an imino group, an imino group substituted with an alkyl group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms), and an aryl group having 6 to 20 carbon atoms are substituted. And imino groups. Examples of the imino group substituted with an alkyl group include CH ₃ —N═, CH ₃ —CH ₂ —N═, CH ₃ — (CH ₂ ) ₂ —N═, and CH ₃ — (CH ₂ ) ₃ —N =. Can be mentioned. Examples of the imino group substituted with an aryl group include C ₆ H ₅ —N═.

The substituent of the hydrocarbon group having 1 to 40 carbon atoms is preferably a substituent of group s1. The derivatizing groups shown below are a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), and the like. A derivatized group is preferred.
[Group s1]
An oxy group having a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof bonded to one side;
A carbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
An oxycarbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
An amino group;
An amino group substituted by one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
A sulfamoyl group;
A sulfamoyl group substituted with one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
A carbonylamino group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
A hydroxy group;
A halogen atom;
-CO ₂ M (preferably a carboxy group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom.);
-SO ₃ M (preferably a sulfo group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom.);
A nitro group;
A cyano group;
A carbonyloxy group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
A sulfonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
A carbamoyl group;
A carbamoyl group substituted with one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
A hydrocarbon group having 1 to 20 carbon atoms in which all of the hydrogen atoms are substituted by fluorine atoms;
A hydrocarbon group having 1 to 20 carbon atoms substituted with a linear or branched alkyl group having 1 to 20 carbon atoms in which all of the hydrogen atoms are substituted with fluorine atoms;
A hydrocarbon group having 1 to 20 carbon atoms in which a part of hydrogen atoms is substituted by fluorine;
Oxo group

The substituent of the hydrocarbon group having 1 to 40 carbon atoms is more preferably a substituent of group s2.
[Group s2]
An oxy group having a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof bonded to one side;
A carbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
An oxycarbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
An amino group;
An amino group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof;
A sulfamoyl group;
A sulfamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof;
A carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
A hydroxy group;
Fluorine atom, chlorine atom, bromine atom;
-CO ₂ M (preferably a carboxy group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom.);
-SO ₃ M (preferably a sulfo group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom.);
A nitro group;
A cyano group;
A carbonyloxy group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
A sulfonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
A carbamoyl group;
A carbamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof;
A hydrocarbon group having 1 to 10 carbon atoms in which all of the hydrogen atoms are substituted by fluorine atoms;
A hydrocarbon group having 1 to 10 carbon atoms substituted by a linear or branched alkyl group having 1 to 10 carbon atoms in which all of the hydrogen atoms are substituted with fluorine atoms;
A hydrocarbon group having 1 to 10 carbon atoms in which a part of hydrogen atoms is substituted by fluorine;
Oxo group

The hydrocarbon group having 1 to 40 carbon atoms having a substituent represented by R ^O1Z1 , R ^1Z1 , R ^2Z1 , R ^3Z1 , R ^4Z1 , R ^5Z1 , R ^6Z1 , R ^7Z1 , R ^101Z1 and R ^102Z1 is 1 And a C1-C40 hydrocarbon group having a monovalent or divalent substituent, preferably a C1-C30 saturated or unsaturated chain hydrocarbon group having a monovalent or divalent substituent. A saturated or unsaturated alicyclic hydrocarbon group having 3 to 30 carbon atoms having a monovalent or divalent substituent, or an aromatic hydrocarbon group having 6 to 30 carbon atoms having a monovalent or divalent substituent, or A group in which a hydrocarbon group is combined, and examples thereof include a group having 1 to 30 carbon atoms having a monovalent or divalent substituent,
More preferably, a saturated or unsaturated chain hydrocarbon group having 1 to 20 carbon atoms having a substituent of group s1, or a saturated or unsaturated alicyclic hydrocarbon group having 3 to 20 carbon atoms having a substituent of group s1. A group having 6 to 20 carbon atoms having a substituent of group s1 or a combination of hydrocarbon groups, and a group having 1 to 20 carbon atoms having a substituent of group s1,
Particularly preferably, it is a saturated or unsaturated chain hydrocarbon group having 1 to 15 carbon atoms having a substituent of group s2, or a saturated or unsaturated alicyclic hydrocarbon group having 3 to 15 carbon atoms having a substituent of group s2. , A group having a substituent of group s2 and a combination of an aromatic hydrocarbon group having 6 to 15 carbon atoms or a hydrocarbon group, and a group having 1 to 15 carbon atoms having a substituent of group s2.

The heterocyclic group represented by R ^O1Z1 , R ^1Z1 , R ^2Z1 , R ^3Z1 , R ^4Z1 , R ^5Z1 , R ^6Z1 , R ^7Z1 , R ^101Z1 and R ^102Z1 may be monocyclic or polycyclic. Preferably, it is a heterocyclic ring containing a hetero atom as a ring component. Examples of the hetero atom include a nitrogen atom, an oxygen atom, and a sulfur atom.
The number of carbon atoms of the heterocyclic group is preferably 3-30, more preferably 3-22, still more preferably 3-20, still more preferably 3-18, and even more preferably 3-3. 15 and particularly preferably 3-14.

As a heterocyclic ring containing a nitrogen atom,
Monocyclic saturated heterocycles such as aziridine, azetidine, pyrrolidine, piperidine and piperazine;
Pyrrol such as 2,5-dimethylpyrrole, pyrazole such as 2-methylpyrazole and 3-methylpyrazole, 5-membered unsaturated heterocyclic ring such as imidazole, 1,2,3-triazole and 1,2,4-triazole ;
6-membered unsaturated heterocycles such as pyrimidines such as pyridine, pyridazine, 6-methylpyrimidine, pyrazines and 1,3,5-triazines;
Indazole, indoline, isoindoline, indole, indolizine, benzimidazole, quinoline, isoquinoline, quinoxaline such as 5,6,7,8-tetrahydro (3-methyl) quinoxaline, 3-methylquinoxaline, quinazoline, cinnoline, phthalazine, naphthyridine , Condensed bicyclic heterocycles such as purine, pteridine, benzopyrazole, benzopiperidine;
And condensed tricyclic heterocycles such as carbazole, acridine and phenazine.

As a heterocyclic ring containing an oxygen atom,
Monocyclic saturated heterocycles such as oxirane, oxetane, tetrahydrofuran, tetrahydropyran, 1,3-dioxane and 1,4-dioxane, 1-cyclopentyldioxolane;
Bicyclic saturated heterocycles such as 1,4-dioxaspiro [4.5] decane, 1,4-dioxaspiro [4.5] nonane;
Lactone heterocycles such as α-acetolactone, β-propiolactone, γ-butyrolactone, γ-valerolactone and δ-valerolactone;
5-membered unsaturated heterocyclic rings such as furan such as 2,3-dimethylfuran and 2,5-dimethylfuran;
6-membered unsaturated heterocyclic rings such as 2H-pyran and 4H-pyran;
Fused bicyclic heterocycles such as 1-benzofuran, benzopyran such as 4-methylbenzopyran, benzodioxole, chroman and isochroman;
And condensed tricyclic heterocycles such as xanthene and dibenzofuran;

As a heterocyclic ring containing a sulfur atom,
5-membered saturated heterocyclic ring such as dithiolane;
6-membered saturated heterocyclic rings such as thiane, 1,3-dithiane, 2-methyl-1,3-dithiane;
5-membered unsaturated heterocyclic rings such as thiophene such as 3-methylthiophene and 2-carboxythiophene, benzothiopyran such as 4H-thiopyran and benzotetrahydrothiopyran;
Condensed bicyclic heterocycles such as benzothiophene;
And condensed tricyclic heterocycles such as thianthrene and dibenzothiophene.

As a heterocyclic ring containing a nitrogen atom and an oxygen atom,
Monocyclic saturated heterocycles such as morpholine, 2-pyrrolidone, 2-methyl-2-pyrrolidone, 2-piperidone and 2-methyl-2-piperidone;
Monocyclic unsaturated heterocycles such as oxazole such as 4-methyloxazole, isoxazole such as 2-methylisoxazole and 3-methylisoxazole;
Condensed bicyclic heterocycles such as benzoxazole, benzisoxazole, benzoxazine, benzodioxane, benzimidazoline;
And condensed tricyclic heterocycles such as phenoxazine.

As a heterocyclic ring containing a nitrogen atom and a sulfur atom,
Monocyclic heterocycles such as thiazole such as 3-methylthiazole and 2,4-dimethylthiazole;
Fused bicyclic heterocycles such as benzothiazole;
Condensed tricyclic heterocycles such as phenothiazine; and the like.

  The heterocycle may be a group in which the above-described hydrocarbon groups are combined, and examples thereof include a tetrahydrofurylmethyl group.

Furthermore, the heterocyclic ring may be represented by the following formula.

The heterocyclic group may be a heterocyclic group formed by combining two or more of R ^{1Z1 to} R ^5Z1 . Such a heterocyclic group has two or more ring structures together with a benzene ring to which R ^{1Z1 to} R ^5Z1 are bonded. Examples of the two or more ring structures include structures of the following formulas.

  In addition, the bonding position of the above heterocyclic ring is a portion from which an arbitrary hydrogen atom contained in each ring is eliminated.

The heterocyclic group represented by R ^O1Z1 , R ^1Z1 , R ^2Z1 , R ^3Z1 , R ^4Z1 , R ^5Z1 , R ^6Z1 , R ^7Z1 , R ^101Z1 and R ^102Z1 may have a substituent. As the substituent, a hydrocarbon group represented by R ^O1Z1 , R ^1Z1 , R ^2Z1 , R ^3Z1 , R ^4Z1 , R ^5Z1 , R ^6Z1 , R ^7Z1 , R ^101Z1 and R ^102Z1 may have The same thing as a group is mentioned. When the heterocyclic ring contains a nitrogen atom as a constituent element, the above-described hydrocarbon group may be bonded to the nitrogen atom as a substituent.

Preferred examples of the substituent include hydrocarbon groups represented by R ^O1Z1 , R ^1Z1 , R ^2Z1 , R ^3Z1 , R ^4Z1 , R ^5Z1 , R ^6Z1 , R ^7Z1 , R ^101Z1 and R ^102Z1. Examples of the preferred substituents are the same.
The heterocyclic group having a substituent represented by R ^O1Z1 , R ^1Z1 , R ^2Z1 , R ^3Z1 , R ^4Z1 , R ^5Z1 , R ^6Z1 , R ^7Z1 , R ^101Z1 and R ^102Z1 is monovalent or divalent substitution A heterocyclic group having a substituent, preferably a heterocyclic group having a substituent of group s1, more preferably a heterocyclic group having a substituent of group s2.
The hydrocarbon group or heterocyclic group may have one or more substituents (first substituent), and the two or more substituents are independent of each other. They may be the same or different. Further, the first substituent may have another substituent (second substituent) bonded to a hydrocarbon group contained in a part thereof. The second substituent can be selected from the same groups as the first substituent.

Hereinafter, R ^1Z1 , R ^2Z1 , R ^3Z1 , R ^4Z1 , R ^5Z1 , R ^6Z1 , R ^7Z1 -CO-R ^102Z1 , -COO-R ^101Z1 , -OCO-R ^102Z1 , -COCO-R ^102Z1 , -O- _{^{R 102Z1, -SO 2 -R 101Z1,}} -SO 2 N (R 102Z1) 2, -CON (R 102Z1) 2, -N (R 102Z1) 2, -NHCO-R 102Z1, -NHCO-N (R 102Z1) ^{_{2, -NHCOOR 102Z1, -OCON (R}} 102Z1) 2, halogen atom, -SO ₃ M, for -CO ₂ M will be described.

—CO—R ^102Z1 includes formyl group; acetyl group, propanoyl group, butanoyl group, 2,2-dimethylpropanoyl group, pentanoyl group, hexanoyl group, (2-ethyl) hexanoyl group, heptanoyl group, octanoyl group, nonanoyl A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof, such as a group, a decanoyl group, an undecanoyl group, a dodecanoyl group, a heicosanoyl group, a benzoyl group, and the like A derivatized group (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. Group), the number of carbon atoms is 2 to 41 when the carbonyl group is an acyl group. ) And include groups corresponding to the -CO-R ^102Z1 in the compounds shown in Table 1Z1~ Table 14Z1 -CO-R ^102Z1 Table 1-966 of the relevant group and Japanese Patent Application No. 2017-016290 to the compounds shown in Preferably, the hydrocarbon group having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms) or a carbonyl group to which the derivatizing group is bonded (when the carbonyl group is an alkanoyl group, the carbon number is more preferably 2 to 12) and groups corresponding to —CO—R ^102Z1 in the compounds shown in Tables 1Z1 to ^14Z1 .

-COO-R ^101Z1 includes methoxycarbonyl group, ethoxycarbonyl group, propoxycarbonyl group, tert-butoxycarbonyl group, butoxycarbonyl group, pentyloxycarbonyl group, hexyloxycarbonyl group, (2-ethyl) hexyloxycarbonyl group, Heptyloxycarbonyl group, octyloxycarbonyl group, nonyloxycarbonyl group, decyloxycarbonyl group, undecyloxycarbonyl group, dodecyloxycarbonyl group, phenyloxycarbonyl group, icosyloxycarbonyl group, etc. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon, etc. Number 1 0 alkylsulfamoyl group group (preferably octyl sulfamoyl group) corresponding to the -COO-R ^101Z1 in compounds derivatized groups) is shown in oxycarbonyl group and Tables 1Z1~ table 14Z1 bound by such And groups corresponding to —COO—R ^101Z1 in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290, preferably a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof bonded thereto. Examples include oxycarbonyl groups and groups corresponding to —COO—R ^101Z1 in the compounds shown in Tables 1Z1 to ^14Z1 .

-OCO-R ^102Z1 includes ^formyloxy group; acetoxy group, propanoyloxy group, butanoyloxy group, 2,2-dimethylpropanoyloxy group, pentanoyloxy group, hexanoyloxy group, (2-ethyl) Hexanoyloxy group, heptanoyloxy group, octanoyloxy group, nonanoyloxy group, decanoyloxy group, undecanoyloxy group, dodecanoyloxy group, heicosanoyloxy group, benzoyloxy group, and the above formula A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom) ), An alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. If the reduction radicals) is bonded to a carbonyl group (said carbonyl group to an acyloxy group, a carbon number of 2-41), as well as -OCO-R ^102Z1 in the compounds shown in Table 1Z1~ Table 14Z1 Corresponding groups and groups shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290 include groups corresponding to —OCO—R ^102Z1, and the like, preferably having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms). ) Or a carbonyloxy group to which the derivatizing group is bonded (when the carbonyloxy group is an acyloxy group, the carbon number is more preferably 2 to 12) and compounds shown in Tables 1Z1 to 14Z1 ^And the group corresponding to -OCO-R ^102Z1 .

-COCO-R ^102Z1 includes methyl oxalyl group, ethyl oxalyl group, propyl oxalyl group, butyl oxalyl group, pentyl oxalyl group, hexyl oxalyl group, (2-ethyl) hexyl oxalyl group, heptyl oxalyl group, octyl oxalyl group, nonyl Oxalyl group, decyloxalyl group, undecyloxalyl group, dodecyloxalyl group, icosyloxalyl group, cyclopentyloxalyl group, cyclohexyloxalyl group, phenyloxalyl group, p-tolyloxalyl group, etc., and groups represented by the above formula A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), 10 alkyl sulfamos Group and JP Le group (preferably octyl sulfamoyl group) corresponding to the -COCO-R ^102Z1 In the compound represented oxalyl groups, as well as Table 1Z1~ Table 14Z1 derivatized group, etc.) are bonded 2017-016290 In the compounds shown in Tables 1 to ⁹⁶⁶ , groups corresponding to —COCO—R ^102Z1 and the like can be mentioned.

-O-R ^102Z1 includes a hydroxy group; methoxy group, ethoxy group, propoxy group, isopropoxy group, butoxy group, isobutoxy group, sec-butoxy group, tert-butoxy group, pentyloxy group, hexyloxy group, heptyloxy Group, octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, dodecyloxy group, (2-ethyl) hexyloxy group, icosyloxy group, 1-phenylethoxy group, 1-methyl-1-phenylethoxy group, phenyl Oxy group, 2,3-dimethylphenyloxy group, 2,4-dimethylphenyloxy group, 2,5-dimethylphenyloxy group, 2,6-dimethylphenyloxy group, 3,4-dimethylphenyloxy group, 3, 5-dimethylphenyloxy group, 2,2-dicyanophenyloxy 2,3-dicyanophenyloxy group, 2,4-dicyanophenyloxy group, 2,5-dicyanophenyloxy group, 2,6-dicyanophenyloxy group, 3,4-dicyanophenyloxy group, 3,5- Dicyanophenyloxy group, 4-methoxyphenyloxy group, 2-methoxyphenyloxy group, 3-methoxyphenyloxy group, 4-ethoxyphenyloxy group, 2-ethoxyphenyloxy group, 3-ethoxyphenyloxy group, etc. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group represented by the formula: or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably Chlorine atoms), derivatized with alkyl sulfamoyl groups having 1 to 10 carbon atoms (preferably octylsulfamoyl groups), etc. Groups) -O-R ^102Z1 in the compound represented by -O-R ^102Z1 Table 1-966 of the relevant group and Japanese Patent Application No. 2017-016290 in the the compound represented in group and Table 1Z1~ table 14Z1 bound is A group corresponding to —O—R ^102Z1 in the compounds shown in Tables 1Z1 to 14Z1 and preferably an oxy group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded. Etc.

As —SO ₂ —R ^101Z1 , methylsulfonyl group, ethylsulfonyl group, propylsulfonyl group, butylsulfonyl group, pentylsulfonyl group, ^{hexylsulfonyl} group, (2-ethyl) ^{hexylsulfonyl} group, ^{heptylsulfonyl} group, octylsulfonyl group, 1 to 40 carbon atoms such as a nonylsulfonyl group, a decylsulfonyl group, an undecylsulfonyl group, a dodecylsulfonyl group, an icosylsulfonyl group, a phenylsulfonyl group, a p-tolylsulfonyl group, and a group represented by the above formula Preferably a hydrocarbon group having 1 to 20 carbon atoms or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms. (Preferably octylsulfamoyl group) -SO ₂ -R in the compounds represented by -SO ₂ -R ^101Z1 Table 1-966 of the relevant group and Japanese Patent Application No. 2017-016290 in the compound group) is shown in the sulfonyl group and Table 1Z1~ table 14Z1 bound ^Groups corresponding to ^101Z1, and the like, preferably sulfonyl groups to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded, and compounds represented by Table 1Z1 to Table ^14Z1 , corresponding to —SO ₂ —R ^101Z1 And the like.

—SO ₂ N (R ^102Z1 ) ₂ includes a sulfamoyl group;
N-methylsulfamoyl group, N-ethylsulfamoyl group, N-propylsulfamoyl group, N-isopropylsulfamoyl group, N-butylsulfamoyl group, N-isobutylsulfamoyl group, N- sec-butylsulfamoyl group, N-tert-butylsulfamoyl group, N-pentylsulfamoyl group, N- (1-ethylpropyl) sulfamoyl group, N-hexylsulfamoyl group, N- (2- Ethyl) hexylsulfamoyl group, N-heptylsulfamoyl group, N-octylsulfamoyl group, N-nonylsulfamoyl group, N-decylsulfamoyl group, N-undecylsulfamoyl group, N- Dodecylsulfamoyl group, N-icosylsulfamoyl group, N-phenylsulfamoyl group, etc., and groups represented by the above formula A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon number In a sulfamoyl group substituted with 1 to 10 alkylsulfamoyl groups (preferably a group derivatized with an octylsulfamoyl group, etc.) and the compounds shown in Tables 1Z1 to 14Z1, —SO ₂ NH (R ^102Z1X ) (Provided that R ^102Z1X is the same as R ^102Z1 except that it does not become a hydrogen atom) and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290, —SO ₂ NH (R ^102Z1X ) (Provided that R ^102Z1X is the same as R ^102Z1 except that it does not become a hydrogen atom);

N, N-dimethylsulfamoyl group, N, N-ethylmethylsulfamoyl group, N, N-diethylsulfamoyl group, N, N-propylmethylsulfamoyl group, N, N-dipropylsulfamoyl group Group, N, N-isopropylmethylsulfamoyl group, N, N-diisopropylsulfamoyl group, N, N-tert-butylmethylsulfamoyl group, N, N-diisobutylsulfamoyl group, N, N- Disec-butylsulfamoyl group, N, N-ditert-butylsulfamoyl group, N, N-butylmethylsulfamoyl group, N, N-dibutylsulfamoyl group, N, N-dipentylsulfa Moyl group, N, N-di (1-ethylpropyl) sulfamoyl group, N, N-dihexylsulfamoyl group, N, N-di (2-ethyl) hexyls Famoyl group, N, N-diheptylsulfamoyl group, N, N-octylmethylsulfamoyl group, N, N-dioctylsulfamoyl group, N, N-dinonylsulfamoyl group, N, N-decyl Methylsulfamoyl group, N, N-undecylmethylsulfamoyl group, N, N-dodecylmethylsulfamoyl group, N, N-icosylmethylsulfamoyl group, N, N-phenylmethylsulfamoyl Two hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group, N, N-diphenylsulfamoyl group, and the group represented by the above formula, or a derivatized group thereof ( For example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably octyl sulfamoyl) ^{_{) -SO 2 N (R 102Z1X)}} 2 ( provided that at sulfamoyl groups and compounds shown in Table 1Z1~ table 14Z1 substituted with derivatized groups) in such, except that R ^102Z1X is not a hydrogen atom, R in the compounds shown in Table 1 to 966 of the corresponding group and Japanese Patent Application No. 2017-016290 the same as is) and _{^{102Z1 -SO 2 N (R 102Z1X)}} 2 ( where except that R ^102Z1X is not a hydrogen atom, The same as R ^102Z1 ), and the like.
Preferably, it corresponds to —SO ₂ N (R ^102Z1 ) ₂ in the compounds shown in Table 1Z1 to Table 14Z1 and sulfamoyl groups substituted with one or two C 1-10 hydrocarbon groups or derivatized groups thereof. Groups and the like.

^—CON (R ^102Z1 ) ₂ includes a carbamoyl group;
N-methylcarbamoyl group, N-ethylcarbamoyl group, N-propylcarbamoyl group, N-isopropylcarbamoyl group, N-butylcarbamoyl group, N-isobutylcarbamoyl group, N-sec-butylcarbamoyl group, N-tert-butylcarbamoyl Group, N-pentylcarbamoyl group, N- (1-ethylpropyl) carbamoyl group, N-hexylcarbamoyl group, N- (2-ethyl) hexylcarbamoyl group, N-heptylcarbamoyl group, N-octylcarbamoyl group, N- One of nonylcarbamoyl group, N-decylcarbamoyl group, N-undecylcarbamoyl group, N-dodecylcarbamoyl group, N-icosylcarbamoyl group, N-phenylcarbamoyl group, etc., and a group represented by the above formula 1 to 40 carbon atoms (preferably carbon 1-20) hydrocarbon group or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably octyl) In the compounds shown in Tables 1Z1 to 14Z1, —CONH (R ^102Z1X ) (provided that R ^102Z1X does not become a hydrogen atom) -CONH the same in a) to the appropriate groups and compounds shown in Table 1 to 966 of Japanese Patent Application No. 2017-016290 and R ^102Z1 (R ^102Z1X) (where except that R ^102Z1X is not a hydrogen atom, R ^102Z1 And the like)

N, N-dimethylcarbamoyl group, N, N-ethylmethylcarbamoyl group, N, N-diethylcarbamoyl group, N, N-propylmethylcarbamoyl group, N, N-dipropylcarbamoyl group, N, N-isopropylmethylcarbamoyl Group, N, N-diisopropylcarbamoyl group, N, N-tert-butylmethylcarbamoyl group, N, N-diisobutylcarbamoyl group, N, N-disec-butylcarbamoyl group, N, N-ditert-butylcarbamoyl group N, N-butylmethylcarbamoyl group, N, N-dibutylcarbamoyl group, N, N-butyloctylcarbamoyl group, N, N-dipentylcarbamoyl group, N, N-di (1-ethylpropyl) carbamoyl group, N , N-dihexylcarbamoyl group, N, N-di (2-ethyl) hexyl Rucarbamoyl group, N, N-diheptylcarbamoyl group, N, N-octylmethylcarbamoyl group, N, N-dioctylcarbamoyl group, N, N-dinonylcarbamoyl group, N, N-decylmethylcarbamoyl group, N, N -Undecylmethylcarbamoyl group, N, N-dodecylmethylcarbamoyl group, N, N-icosylmethylcarbamoyl group, N, N-phenylmethylcarbamoyl group, N, N-diphenylcarbamoyl group and the like, and the above formula Two hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group to be synthesized or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom) ), Derivatization with an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group) -CON (R ^102Z1X) ₂ (except in the carbamoyl group and Tables 1Z1~ Table 14Z1 compounds shown in substituted with group), R ^102Z1X except that not a hydrogen atom, the same as is) and R ^102Z1 Applicable groups and compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290 -CON (R ^102Z1X ) ₂ (provided that R ^102Z1X is the same as R ^102Z1 except that it does not become a hydrogen atom) Group, etc.
Preferably, one or two hydrocarbon groups having 1 to 10 carbon atoms or a carbamoyl group substituted with a derivatizing group thereof, a group corresponding to ^—CON (R ^102Z1 ) ₂ in the compounds shown in Table 1Z1 to Table 14Z1, etc. Is mentioned.

—N (R ^102Z1 ) ₂ includes an amino group;
N-methylamino group, N-ethylamino group, N-propylamino group, N-isopropylamino group, N-butylamino group, N-isobutylamino group, N-sec-butylamino group, N-tert-butylamino Group, N-pentylamino group, N-hexylamino group, N- (2-ethyl) hexylamino group, N-heptylamino group, N-octylamino group, N-nonylamino group, N-decylamino group, N-un A decylamino group, an N-dodecylamino group, an N-icosylamino group, an N-phenylamino group, and the like, and one of 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group represented by the above formula A hydrocarbon group or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl group having 1 to 10 carbon atoms; -NH (R ^102Z1X) (provided that the amino group and Tables 1Z1~ Table 14Z1 compounds shown in substituted with Amoiru group (preferably octyl sulfamoyl group) were derivatized with such groups), R ^102Z1X a hydrogen atom -NH (R ^102Z1X ) (provided that R ^102Z1X does not become a hydrogen atom) in the group corresponding to R ^102Z1 except that it is not, and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290 Except for the ^above , it is the same as R ^102Z1 , etc.)

N, N-dimethylamino group, N, N-ethylmethylamino group, N, N-diethylamino group, N, N-propylmethylamino group, N, N-dipropylamino group, N, N-isopropylmethylamino group N, N-diisopropylamino group, N, N-tert-butylmethylamino group, N, N-diisobutylamino group, N, N-disec-butylamino group, N, N-ditert-butylamino group, N, N-butylmethylamino group, N, N-dibutylamino group, N, N-dipentylamino group, N, N-di (1-ethylpropyl) amino group, N, N-dihexylamino group, N, N -Di (2-ethyl) hexylamino group, N, N-diheptylamino group, N, N-dioctylamino group, N, N-dinonylamino group, N, N-decylmethylamino group, N, N- Ndecylmethylamino group, N, N-dodecylmethylamino group, N, N-icosylmethylamino group, N, N-phenylmethylamino group, N, N-diphenylamino group, etc., and the above formula Two hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom) In the compounds shown in Table 1Z1 to Table 14Z1, -N (R ^102Z1X) ₂ (where reduction except that R ^102Z1X is not a hydrogen atom, are shown in Table 1 to 966 groups and Japanese Patent Application No. 2017-016290 corresponding to same in a) and R ^102Z1 -N (R ^102Z1X) ₂ (provided that, R ^102Z1X, except that not a hydrogen atom, same as is the R ^102Z1) at the object and a group corresponding to the like,
Preferably, one or two hydrocarbon groups having 1 to 10 carbon atoms or an amino group substituted with a derivatizing group thereof, and a group corresponding to —N (R ^102Z1 ) ₂ in the compounds shown in Table 1Z1 to Table 14Z1 Is mentioned.

—NHCO—R ^102Z1 includes formylamino group; acetylamino group, propanoylamino group, butanoylamino group, 2,2-dimethylpropanoylamino group, pentanoylamino group, hexanoylamino group, (2-ethyl ) Hexanoylamino group, heptanoylamino group, octanoylamino group, nonanoylamino group, decanoylamino group, undecanoylamino group, dodecanoylamino group, heicosanoylamino group, benzoylamino group, etc. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group represented by the above formula or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably Is a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) In the case of a derivatized group) bonded to a carbonylamino group (an acylamino group the carbonyl amino group, -NHCO-R ^102Z1 in compound number of carbon atoms indicated in which) and Table 1Z1~ Table 14Z1 1 to 40 And groups corresponding to —NHCO—R ^102Z1 in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290, and the like.
Preferably, a carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded (when the carbonylamino group is an alkanoylamino group, the carbon number is more preferably 1 to 10) and Table 1Z1 To groups corresponding to -NHCO-R ^102Z1 in the compounds shown in Table 14Z1.

-NHCON (R ^102Z1 ) ₂ includes the groups listed above and the groups corresponding to -NHCON (R ^102Z1 ) ₂ in the compounds shown in Tables 1Z1 to 14Z1, Tables 1 to 966 of Japanese Patent Application No. 2017-016290. And a group corresponding to —NHCON (R ^102Z1 ) ₂ in the compound represented by

-NHCOOR ^102Z1 includes the above-described groups and the like, groups corresponding to -NHCOOR ^102Z1 in the compounds shown in Tables 1Z1 to 14Z1, and -NHCOOR 102Z1 in the compounds shown in Tables 1 to ⁹⁶⁶ of Japanese Patent Application No. ^2017-016290. And the like group.

^{Examples of} —OCON (R ^102Z1 ) ₂ include groups listed above and groups corresponding to —OCON (R ^102Z1 ) ₂ in the compounds shown in Tables 1Z1 to 14Z1, and Tables 1 to 966 of Japanese Patent Application No. 2017-016290. And a group corresponding to —OCON (R ^102Z1 ) ₂ in the compound represented by

As the halogen atom, a fluorine atom, a chlorine atom, a bromine atom and an iodine atom are preferable.
Examples of M in —SO ₃ M and —CO ₂ M include a hydrogen atom; an alkali metal atom such as a lithium atom, a sodium atom and a potassium atom, preferably a hydrogen atom, a sodium atom and a potassium atom.

The ^{-CO-R 102Z1, -COO-R} 102Z1, -OCO-R 102Z1, -COCO-R 102Z1, -O-R 102Z1, -SO 2 -R 102Z1, -SO 2 N (R 102Z1) 2, -CON ^{Substituent contained in} ( ^R102Z1 ) ₂ , -N ( ^R102Z1 ) ₂ , -NHCO- ^R102Z1 , -NHCON ( ^R102Z1 ) ₂ , ^-NHCOOR102Z1 , -OCON ( ^R102Z1 ) ₂ (first substituent) May be one or more, and the two or more substituents may be the same or different independently of each other.
Further, the first substituent may have another substituent (second substituent) bonded to a hydrocarbon group contained in a part thereof. The second substituent can be selected from the same groups as the first substituent.

The ring formed by R ^2Z1 and R ^3Z1 , R ^3Z1 and R ^4Z1 , and R ^4Z1 and R ^5Z1 is condensed with the benzene ring of the isoindoline skeleton of the compound represented by the formula (IZ1). The condensed ring structure of the ring formed by R ^2Z1 and R ^3Z1 , R ^3Z1 and R ^4Z1 , and R ^4Z1 and R ^5Z1 and the benzene ring includes indene, naphthalene, biphenylene, indacene, acenaphthylene, fluorene, phenalene, phenanthrene, Hydrocarbon condensed ring structures such as anthracene, fluoranthene, acephenanthrylene, aceanthrylene, triphenylene, pyrene, chrysene, N-methylphthalimide, N- (1-phenylethyl) phthalimide and tetracene, and their partially reduced forms ( For example, 9,10-dihydroanthracene, 1,2,3,4-tetrahydronaphthalene, etc.); indole, isoindole, indazole, quinoline, isoquinoline, phthalazine, quinoxaline, quinazoline, cinnoline, carbazole, carboline, phenant Jin, acridine, perimidine, nitrogen-containing condensed heterocyclic, and parts thereof reductant such as phenanthroline and phenazine; 3- oxygen-containing condensed such tetrahydrobenzo furan-2-one heterocyclic ring and its partially reduced products thereof.

When R ^2Z1 and R ^3Z1 , R ^3Z1 and R ^4Z1 , and R ^4Z1 and R ^5Z1 form a ring, the ring may have a substituent. As the substituent, a hydrocarbon group represented by R ^O1Z1 , R ^1Z1 , R ^2Z1 , R ^3Z1 , R ^4Z1 , R ^5Z1 , R ^6Z1 , R ^7Z1 , R ^101Z1 and R ^102Z1 may have The same thing as a group is mentioned. Preferred examples of the substituent include hydrocarbon groups represented by R ^O1Z1 , R ^1Z1 , R ^2Z1 , R ^3Z1 , R ^4Z1 , R ^5Z1 , R ^6Z1 , R ^7Z1 , R ^101Z1 and R ^102Z1. Examples of the preferred substituents are the same.

When R ^3Z1 and R ^4Z1 form a ring, R ^2Z1 and R ^5Z1 are preferably a hydrogen atom, an amino group, and a hydroxy group, independently of each other.
When R ^2Z1 and R ^3Z1 form a ring, R ^4Z1 and R ^5Z1 preferably do not form a ring, and R ^4Z1 and R ^5Z1 are more preferably hydrogen atoms.
When R ^4Z1 and R ^5Z1 form a ring, R ^2Z1 and R ^3Z1 preferably do not form a ring, and R ^2Z1 and R ^3Z1 are more preferably hydrogen atoms.

In the present invention, R ^1Z1 , R ^6Z1 and R ^7Z1 are preferably hydrogen atoms.

In the present invention, R ^O1Z1 is preferably a hydrogen atom or a hydrocarbon group having 1 to 30 carbon atoms which may have a substituent, and 1 carbon atom which may have a hydrogen atom or a substituent. It is more preferably a hydrocarbon group having ˜20, more preferably a hydrocarbon group having 1 to 15 carbon atoms which may have a hydrogen atom or a substituent, and having a hydrogen atom or a substituent. The hydrocarbon group having 1 to 10 carbon atoms may be particularly preferable, and may have a hydrocarbon atom or substituent having 1 to 6 carbon atoms which may have a hydrogen atom or a substituent. More preferably, it is a hydrocarbon group having 1 to 5 carbon atoms, particularly preferably a hydrogen atom, a methyl group, or an ethyl group, or a phenyl group, and most preferably a hydrogen atom, a methyl group, or an ethyl group. preferable.

From the viewpoint of reducing the retardation value of the color filter prepared from the colored composition, at least one of R ^2Z1 , R ^3Z1 , R ^4Z1 and R ^5Z1 is -CO-R ^102Z1 , -COO-R ^101Z1 ,- ^{OCO-R 102Z1, -COCO-R} 102Z1, -O-R 102Z1, -SO 2 -R 101Z1, -SO 2 N (R 102Z1) 2, -CON (R 102Z1) 2, -N (R 102Z1) 2, ^{-NHCO-R 102Z1, -NHCO-N} (R 102Z1) 2, -NHCOOR 102Z1, -OCON (R 102Z1) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , a substituent It is preferably a C1-C40 hydrocarbon group that may have or a heterocyclic group that may have a substituent,
1 to 40 carbon atoms in which all or part of the hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a halogen atom, -N (R ^102Z1 ) ₂ , a nitro group and a hydrogen atom are substituted by a fluorine atom. More preferably, it is 20 hydrocarbon groups, —NHCO—R ^102Z1 , —O—R ^102Z1 , —SO ₃ M or —CO ₂ M,
More preferably, it is a C1-C40 hydrocarbon group which may have a nitro group or a substituent,
Even more preferably, it is a nitro group or a tert-butyl group. Alternatively, at least one pair of R ^2Z1 and R ^3Z1 , R ^3Z1 and R ^4Z1 , or R ^4Z1 and R ^5Z1 preferably forms a ring.

In the compound (IZ1), at least one of R ^2Z1 , R ^3Z1 , R ^4Z1 , and R ^5Z1 is —CO—R ^102Z1 , —COO—R ^101Z1 , —OCO—R ^102Z1 , —COCO—R ^102Z1 , —O— _{^{R 102Z1, -SO 2 -R 101Z1,}} -SO 2 N (R 102Z1) 2, -CON (R 102Z1) 2, -N (R 102Z1) 2, -NHCO-R 102Z1, -NHCO-N (R 102Z1) ₂ , —NHCOOR ^102Z1 , —OCON (R ^102Z1 ) ₂ , a halogen atom, a cyano group, a nitro group, —SO ₃ M, —CO ₂ M, an ^optionally substituted hydrocarbon having 1 to 40 carbon atoms A heterocyclic group which may have a group or a substituent, or at least one pair of R ^2Z1 and R ^3Z1 , R ^3Z1 and R ^4Z1 , and R ^4Z1 and R ^5Z1 is bonded to form a ring. (Hereinafter, this compound may be referred to as “compound (IZ1-B)”). When the compound (IZ1) is the compound (IZ1-B), the retardation value of the color filter prepared from the colored composition is decreased.

From the viewpoint of reducing the retardation value of the color filter produced from the colored composition, at least one of R ^2Z1 , R ^3Z1 , R ^4Z1 , and R ^5Z1 may have a substituent. Hydrocarbon group, halogen atom, —N (R ^102Z1 ) ₂ , nitro group, hydrocarbon group having 1 to 20 carbon atoms in which all or part of the hydrogen atom is substituted with fluorine atom, —NHCO—R ^102Z1 , —O -R ^102Z1, is preferably -SO ₃ M or -CO ₂ M, more preferably a hydrocarbon group of carbon atoms which may 1 to 40 have a nitro group or a substituted group, a nitro group, or More preferably, it is a tert-butyl group. Particularly preferably, R ^3Z1 is a nitro group or tert-butyl group and R ^2Z1 , R ^4Z1 and R ^5Z1 are hydrogen atoms, or R ^2Z1 , R ^3Z1 and R ^5Z1 are hydrogen atoms and R ^4Z1. Is a nitro group or a tert-butyl group.

［式（ＩＺ１−Ｂ）中、
Ｒ^O11Z1は、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^1Z1、Ｒ^21Z1、Ｒ^31Z1、Ｒ^41Z1、Ｒ^51Z1、Ｒ^61Z1、及びＲ^71Z1は、互いに独立に、水素原子、−ＣＯ−Ｒ^102Z1、−ＣＯＯ−Ｒ^101Z1、−ＯＣＯ−Ｒ^102Z1、−ＣＯＣＯ−Ｒ^102Z1、−Ｏ−Ｒ^102Z1、−ＳＯ₂−Ｒ^101Z1、−ＳＯ₂Ｎ（Ｒ^102Z1）₂、−ＣＯＮ（Ｒ^102Z1）₂、−Ｎ（Ｒ^102Z1）₂、−ＮＨＣＯ−Ｒ^102Z1、−ＮＨＣＯ−Ｎ（Ｒ^102Z1）₂、−ＮＨＣＯＯＲ^102Z1、−ＯＣＯＮ（Ｒ^102Z1）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^21Z1とＲ^31Z1、Ｒ^31Z1とＲ^41Z1、及びＲ^41Z1とＲ^51Z1は、それぞれ互いに結合して環を形成してもよい。
ただし、Ｒ^21Z1、Ｒ^31Z1、Ｒ^41Z1、及びＲ^51Z1の少なくとも一つは、−ＣＯ−Ｒ^102Z1、−ＣＯＯ−Ｒ^101Z1、−ＯＣＯ−Ｒ^102Z1、−ＣＯＣＯ−Ｒ^102Z1、−Ｏ−Ｒ^102Z1、−ＳＯ₂−Ｒ^101Z1、−ＳＯ₂Ｎ（Ｒ^102Z1）₂、−ＣＯＮ（Ｒ^102Z1）₂、−Ｎ（Ｒ^102Z1）₂、−ＮＨＣＯ−Ｒ^102Z1、−ＮＨＣＯ−Ｎ（Ｒ^102Z1）₂、−ＮＨＣＯＯＲ^102Z1、−ＯＣＯＮ（Ｒ^102Z1）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基或いは置換基を有していてもよい複素環基であるか、又はＲ^21Z1とＲ^31Z1、Ｒ^31Z1とＲ^41Z1、及びＲ^41Z1とＲ^51Z1の少なくとも一組が結合して環を形成している。
Ｒ^101Z1は、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102Z1は、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、水素原子又はアルカリ金属原子を表す。
Ｒ^101Z1、Ｒ^102Z1及びＭが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
波線は、Ｅ体又はＺ体を表す。］ The compound (IZ1-B) is defined by the formula as follows.

[In the formula (IZ1-B),
R ^O11Z1 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
R ^1Z1 , R ^21Z1 , R ^31Z1 , R ^41Z1 , R ^51Z1 , R ^61Z1 , and R ^71Z1 are each independently a hydrogen atom, —CO—R ^102Z1 , —COO—R ^101Z1 , —OCO—R ^102Z1 , —COCO ^{-R 102Z1, -O-R 102Z1,} -SO 2 -R 101Z1, -SO 2 N (R 102Z1) 2, -CON (R 102Z1) 2, -N (R 102Z1) 2, -NHCO-R 102Z1, - _{^{NHCO-N (R 102Z1) 2}} , -NHCOOR 102Z1, -OCON (R 102Z1) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , carbon atoms, which may have a substituent The heterocyclic group which may have a hydrocarbon group or a substituent of number 1-40 is represented.
R ^21Z1 and R ^31Z1 , R ^31Z1 and R ^41Z1 , and R ^41Z1 and R ^51Z1 may be bonded to each other to form a ring.
However, at least one of R ^21Z1 , R ^31Z1 , R ^41Z1 , and R ^51Z1 is -CO-R ^102Z1 , -COO-R ^101Z1 , -OCO-R ^102Z1 , -COCO-R ^102Z1 , -O-R ^102Z1 , _{^{-SO 2 -R 101Z1, -SO 2 N}} (R 102Z1) 2, -CON (R 102Z1) 2, -N (R 102Z1) 2, -NHCO-R 102Z1, -NHCO-N (R 102Z1) 2, - ^{NHCOOR 102Z1, -OCON (R 102Z1)} 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , hydrocarbon group or substituted carbon atoms 1 to 40 which may have a substituent A heterocyclic group which may have a group, or at least one pair of R ^21Z1 and R ^31Z1 , R ^31Z1 and R ^41Z1 , and R ^41Z1 and R ^51Z1 is bonded to form a ring.
R ^101Z1 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102Z1 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
M represents a hydrogen atom or an alkali metal atom.
When a plurality of R ^101Z1 , R ^102Z1 and M are present, they may be the same or different.
A wavy line represents an E body or a Z body. ]

Wherein ^{(IZ1-B), R O11Z1} , R 21Z1, R 31Z1, R 41Z1, R 51Z1, R 61Z1, and R ^71Z1 are each, R ^O1Z1 in formula ^{(IZ1), R 2Z1, R} 3Z1, R 4Z1 , R ^5Z1 , R ^6Z1 , and R ^7Z1 are the same.

In the formula (IZ1-B), preferred R ^O11Z1 , R ^21Z1 , R ^31Z1 , R ^41Z1 , R ^51Z1 , R ^61Z1 , and R ^71Z1 are R ^O1Z1 , R ^2Z1 , R ^3Z1 , R in the formula (IZ1), respectively. ^The same thing as the preferable thing of ^4Z1 , ^R5Z1 , ^R6Z1 , and ^R7Z1 is mentioned.

In the formula (IZI-B), (Aspect 1) R ^1Z1 , R ^61Z1 and R ^71Z1 are preferably hydrogen atoms. (Aspect 2) It is also preferable that R ^O11Z1 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent. Further, (Aspect 3) It is also preferable that at least one of R ^21Z1 , R ^31Z1 , R ^41Z1 and R ^51Z1 is a nitro group or a tert-butyl group. The said aspects 1-3 may be employ | adopted independently and may be combined suitably.

Specific examples of the compound (IZ1) include, for example, in the formula (IZ1-aa), Table 1Z1, Table 2Z1, Table 3Z1, Table 4Z1, Table 5Z1, Table 6Z1, Table 7Z1, Table 8Z1, Table 9Z1, Table 10Z1, Examples thereof include compounds (IZ1-1) to (IZ1-529) having the substituents shown in Table 11Z1, Table 12Z1, Table 13Z1, and Table 14Z1, or alkali metal salts thereof.
B ^a1Z1 B ^a2Z1 is the formula (BB1) to formula (BB60), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1), formula (BBO8), formula (BBO10) , Any partial structure represented by formula (BBD1) and formula (BBJ2). B ^a1Z1 B ^a2Z1 includes formula (BB1), formula (BB6), formula (BB8), formula (BB11), formula (BB14), formula (BB19), formula (BB37), formula (BB58), formula (BBJ2) ), Formula (BBO8) and formula (BBO10) are preferred, and formula (BB1), formula (BB6) and formula (BB19) are more preferred.

Each symbol in Table 1Z1, Table 2Z1, Table 3Z1, Table 4Z1, Table 5Z1, Table 6Z1, Table 7Z1, Table 8Z1, Table 9Z1, Table 10Z1, Table 11Z1, Table 12Z1, Table 13Z1, and Table 14Z1 is as follows. Represents a partial structure. In the partial structure,
“Me” represents a methyl group,
“Et” represents an ethyl group;
“Bu” represents a butyl group,
“TBu” represents a tert-butyl group,
“Hex” represents a hexyl group,
“Oct” represents an octyl group;
“2EH” represents a 2-ethylhexyl group;
“CHM” represents a cyclohexylmethyl group,
“CH” represents a cyclohexyl group,
“PH” represents a phenyl group;
“BZ” represents a benzyl group;
“NPR” represents a propyl group;
“IPR” represents an isopropyl group;
“IBu” represents an isobutyl group,
“EOE” represents —CH ₂ CH ₂ OCH ₂ CH ₃ ,
“ALL” represents an allyl group,
“HYE” represents a 2-hydroxyethyl group,
“COM” represents —CO—CH ₃ ;
“COE” represents —COO—CH ₂ CH ₃ ;
“OCM” represents —OCO—CH ₃ ;
“OME” represents —O—CH ₃ ;
“SOT” represents a tosyl group;
“SNH” represents —SO ₂ NH—CH ₂ CH (CH ₂ CH ₃ ) ((CH ₂ ) ₃ CH ₃ );
“SN2” represents —SO ₂ N (CH ₃ ) ((CH ₂ ) ₇ CH ₃ ),
“CNM” represents —CONHCH ₃ ;
“CN2” represents —CON (CH ₃ ) C ₆ H ₅ ,
“NPH” represents —NHC ₆ H ₅ ,
"NOT" represents _{-N ((CH 2) 7 CH} 3) 2,
“NCO” represents —NHCO ((CH ₂ ) ₄ CH ₃ ),
“F” represents a fluorine atom,
“Cl” represents a chlorine atom,
“Br” represents a bromine atom;
“CN” represents a cyano group,
“NO2” represents a nitro group,
“SUA” represents —SO ₃ H;
“CBA” represents —CO ₂ H;
“CHO” represents —CHO,
“OCH” represents —OCOH;
“OH” represents —OH;
“SFM” represents —SO ₂ NH ₂ ;
“CBM” represents —CONH ₂ ;
“NH ₂ ” represents —NH ₂ ,
“NCH” is —NHCOH
Represents.
In the partial structure represented by the following formula, * represents a bond.

Also, B ^A1Z1 and B ^A2Z1 each represent a bond, bond B ^A2Z1 becomes less bond B ^2, B ^A1Z1 is less than B ² when B ^A1Z1 is a bond of the B ¹ or less In this case, B ^a2Z1 becomes a bond of B ¹ below.

  For example, compound (IZ1-1) is a compound represented by formula (IZ1-1).

As the compound (IZ1),
Compound (IZ1-1) to Compound (IZ1-171), Compound (IZ1-258) to Compound (IZ1-529) are preferred,
Compound (IZ1-1) to Compound (IZ1-171), Compound (IZ1-258) to Compound (IZ1-471) are more preferable,
Compound (IZ1-1) to Compound (IZ1-171) are more preferred, Compound (IZ1-1) to Compound (IZ1-111) are even more preferred, and Compound (IZ1-1) to Compound (IZ1-54) are especially preferred Compound (IZ1-2) to compound (IZ1-3), compound (IZ1-20) to compound (IZ1-21), compound (IZ1-38) to compound (IZ1-39) are particularly preferable.

Specific examples of the compound (IZ1) include Table 1Z1, Table 2Z1, Table 3Z1, Table 4Z1, Table 5Z1, Table 6Z1, Table 7Z1, Table 8Z1, Table 9Z1, Table 10Z1, Table 11Z1, Table 12Z1, Table 13Z1, and compound -SO ₃ M or -CO ₂ M is substituted with 1-3 of the hydrogen atoms contained in the compound represented in Table 14Z1 also included. For example, a compound in which 1 to 3 sulfo groups are bonded to the compound (IZ1-1) in Table 1Z1 is represented by the following structure. However, in the formula,-(SO ₃ H) means that any hydrogen atom of the compound (IZ1-1) in Table 1Z1 is substituted.

In the present invention,
Compound (IZ1-1) to Compound (IZ1-171), Compound (IZ1-258) to Compound (IZ1-529) are compounds in which 1 to 3 —SO ₃ M or —CO ₂ M is bonded. Preferably,
It is a compound in which 1 to 3 —SO ₃ M or —CO ₂ M is bound to Compound (IZ1-1) to Compound (IZ1-171) or Compound (IZ1 to 258) to Compound (IZ1 to 431). More preferably,
More preferably, it is a compound in which 1 to 3 —SO ₃ M or —CO ₂ M is bound to compound (IZ1-1) to compound (IZ1-171),
Compound (IZ1-1) ~ compound (IZ1-111), even more preferably from one to three compounds -SO ₃ M or -CO ₂ M is bond,
Particularly preferred is a compound in which 1 to 3 —SO ₃ M or —CO ₂ M is bound to compound (IZ1-1) to compound (IZ1-54),
The compound (IZ1-2) to the compound (IZ1-3), the compound (IZ1-20) to the compound (IZ1-21), and the compound (IZ1-38) to the compound (IZ1-39) have 1 to 3 − Particularly preferred is a compound to which SO ₃ M or —CO ₂ M is bound.

As the compound (IZ1), in the formula (IZ1),
R ^O1Z1 is a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M;
R ^1Z1 is a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent selected from the group consisting of a hydrogen atom, —SO ₃ M and —CO ₂ M, —SO ₃ M or —CO _2. M,
R ^{2Z1 to} R ^5Z1 are each independently a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogen atom, —N (R ^102Z1 ) ₂ , a nitro group, or a hydrogen atom, or a fluorine atom. A substituted hydrocarbon group having 1 to 20 carbon atoms, —NHCO—R ^102Z1 , —O—R ^102Z1 , —SO ₃ M or —CO ₂ M;
R ^6Z1 and R ^7Z1 each independently represent a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M; SO ₃ M or —CO ₂ M,
R ^102Z1 is a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M;
M is preferably a compound that is a hydrogen atom or an alkali metal atom,
R ^O1Z1 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M;
R ^1Z1 is a hydrogen atom,
R ^{2Z1 to} R ^5Z1 are each independently a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, —N (R ^102Z1 ) ₂ , a nitro group, or a hydrogen atom, or a fluorine atom. A substituted hydrocarbon group having 1 to 10 carbon atoms, —NHCO—R ^102Z1 , —O—R ^102Z1 , —SO ₃ M or —CO ₂ M;
R ^6Z1 and R ^7Z1 are the same group, and a hydrocarbon having 1 to 10 carbon atoms which may have a hydrogen atom or a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M Group,
R ^102Z1 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M;
M is more preferably a compound that is a hydrogen atom or an alkali metal atom,
R ^O1Z1 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M;
R ^1Z1 is a hydrogen atom,
R ^{2Z1 to} R ^5Z1 are each independently a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, —N (R ^102Z1 ) ₂ , a nitro group, a trifluoromethyl group, —O—R ^102Z1 , a -SO ₃ M or -CO ₂ M,
R ^6Z1 and R ^7Z1 are the same group, and are a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms,
R ^102Z1 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M;
A compound in which M is a hydrogen atom or an alkali metal atom is more preferable.

Compound (IZ1) is a compound represented by the formula (pt1Z1) (hereinafter may be referred to as a phthalonitrile compound) when R ^1Z1 is a hydrogen atom (hereinafter referred to as an alkoxide compound). In some cases, the compound represented by the formula (pt3Z1) and the compound represented by the formula (pt4Z1) can be further reacted in the presence of an acid. When R ^1Z1 is other than a hydrogen atom, compound (IZ1) can be produced by further reacting with a compound represented by the formula (pt5Z1).

[In the formula (pt1Z1), formula (pt2Z1), formula (pt3Z1), formula (pt4Z1), formula (pt5Z1) and formula (IZ1), R ^O1Z1 , R ^1Z1 , R ^2Z1 , R ^3Z1 , R ^4Z1 , R ^5Z1 , R ^6Z1 and R ^7Z1 represent the same meaning as described above.
R ^14Z1 represents an alkyl group having 1 to 20 carbon atoms.
M ^1Z1 represents an alkali metal atom.
LG represents a halogen atom, a methanesulfonyloxy group, a toluenesulfonyloxy group, or a trifluoromethanesulfonyloxy group. ]

^Examples of the alkyl group having 1 to 20 carbon atoms represented by R ^14Z1 include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, a sec-butyl group, and a tert-butyl group. Is an alkyl group having 1 to 6 carbon atoms.
^Examples of the alkali metal atom represented by M ^1Z1 include a lithium atom, a sodium atom, and a potassium atom.

  The amount of the alkoxide compound used is usually 0.1 to 10 mol, preferably 0.2 to 5 mol, more preferably 0.3 to 3 mol, relative to 1 mol of the phthalonitrile compound. More preferably, it is 0.4-2 mol.

The amount of compound (pt3Z1) to be used is generally 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, further preferably 1 to 1 mol of phthalonitrile compound. ~ 2 moles.
The amount of compound (pt4Z1) to be used is generally 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, further preferably 1 to 1 mol of phthalonitrile compound. ~ 2 moles.

Examples of the acid include inorganic acids such as hydrochloric acid, hydrobromic acid, hydroiodic acid, sulfuric acid, nitric acid, fluorosulfonic acid and phosphoric acid; sulfonic acids such as methanesulfonic acid, trifluoromethanesulfonic acid and p-toluenesulfonic acid; Examples thereof include carboxylic acids such as acetic acid, citric acid, formic acid, gluconic acid, lactic acid, oxalic acid and tartaric acid, and preferably hydrochloric acid, hydrobromic acid, sulfuric acid, methanesulfonic acid, trifluoromethanesulfonic acid, p-toluenesulfonic acid and A carboxylic acid is mentioned, More preferably, an acetic acid is mentioned.
The usage-amount of an acid is 1-20 mol normally with respect to 1 mol of phthalonitrile compounds, Preferably it is 1-10 mol, More preferably, it is 1-8 mol, More preferably, it is 1-6 mol. is there.

The reaction of a phthalonitrile compound, an alkoxide compound, a compound (pt3Z1) and a compound (pt4Z1) is usually performed in the presence of a solvent.
Solvents include water; nitrile solvents such as acetonitrile; alcohol solvents such as methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol and 1-octanol; ether solvents such as tetrahydrofuran; ketone solvents such as acetone; Ester solvents such as ethyl; aliphatic hydrocarbon solvents such as hexane; aromatic hydrocarbon solvents such as toluene; halogenated hydrocarbon solvents such as methylene chloride and chloroform; amides such as N, N-dimethylformaldehyde and N-methylpyrrolidone Solvent: Sulfoxide solvents such as dimethyl sulfoxide are mentioned, preferably water, nitrile solvent, alcohol solvent, ether solvent, ketone solvent, ester solvent, aromatic hydrocarbon solvent, halogenated hydrocarbon solvent, amide solvent and sulfoxide solvent. And More preferably, water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, tetrahydrofuran, acetone, ethyl acetate, toluene, methylene chloride, chloroform, N, N-dimethylformaldehyde, N -Methylpyrrolidone and dimethyl sulfoxide are mentioned, More preferably, water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, acetone, methylene chloride, chloroform, N, N-dimethyl Examples include formaldehyde, N-methylpyrrolidone and dimethyl sulfoxide, with water, acetonitrile, methanol, ethanol and 2-propanol being particularly preferred.
The usage-amount of a solvent is 1-1000 mass parts normally with respect to 1 mass part of phthalonitrile compounds.

  The reaction temperature is usually 0 to 200 ° C, preferably 0 to 100 ° C, more preferably 0 to 70 ° C, and further preferably 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

The amount of compound (pt5Z1) to be used is generally 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, per 1 mol of compound (IZ1) in which R ^1Z1 is a hydrogen atom. More preferably, it is 1-2 mol.

  Moreover, when making a compound (pt5Z1) react, it is preferable that a base coexists. Examples of the base include organic bases such as triethylamine, 4- (N, N-dimethylamino) pyridine, pyridine and piperidine; metal alkoxides such as sodium methoxide, sodium ethoxide, sodium tert-butoxide and potassium tert-butoxide; butyllithium Organic metal compounds such as tert-butyl lithium and phenyl lithium; inorganic bases such as lithium hydroxide, sodium hydroxide and potassium hydroxide.

The amount of the base to be used is generally 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, per 1 mol of compound (IZ1) in which R ^1Z1 is a hydrogen atom. Preferably it is 1-2 mol.

The reaction of the compound (pt5Z1) is usually performed in the presence of a solvent. The solvent can be selected from the same range as described above.
The usage-amount of a solvent is ^1-1000 mass parts normally with respect to 1 mass part of compounds (IZ1) whose R ^{<1Z> Z1} is a hydrogen atom. The reaction temperature of the compound (pt5) is usually -90 to 200 ° C, preferably -80 to 100 ° C, more preferably 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

When the compound (IZ1) does not have a sulfo group or —SO ₃ M ²² , the compound (IZ1) is reacted with a sulfonating agent such as fuming sulfuric acid or chlorosulfonic acid to thereby form a sulfo group or —SO ₃ M ^22. Can be introduced.
M ²² represents an alkali metal atom.
Examples of the alkali metal atom represented by M ²² include a lithium atom, a sodium atom, and a potassium atom.

The amount of SO ₃ in the oleum, the compound (IZ1) relative to 1 mol, usually 1 to 50 moles, preferably from 5 to 40 moles, more preferably from 5 to 30 moles, more preferably 5 to 25 mol.
The usage-amount of the sulfuric acid in fuming sulfuric acid is 1-200 mol normally with respect to 1 mol of compounds (IZ1), Preferably it is 10-100 mol, More preferably, it is 10-75 mol, More preferably, it is 10 ~ 50 moles.

  The amount of chlorosulfonic acid to be used is generally 1 to 500 mol, preferably 10 to 300 mol, more preferably 10 to 200 mol, further preferably 10 to 150 mol, per 1 mol of compound (IZ1). Is a mole.

  The reaction temperature of the sulfonation is usually from -20 to 200 ° C, preferably from -10 to 100 ° C, more preferably from 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

  The method for taking out the compound (IZ1) from the reaction mixture is not particularly limited, and it can be taken out by various known methods. For example, after completion of the reaction, the compound (IZ1) can be taken out by filtering the reaction mixture. Further, after filtration, the obtained residue may be subjected to column chromatography or recrystallization. Further, after completion of the reaction, the solvent of the reaction mixture may be distilled off and then purified by column chromatography.

<Compound (IZ2)>
Compound (IZ2) is a compound represented by Formula (IZ2).

[In the formula (IZ2),
R ^CO1Z2 and R ^CO2Z2 each independently represent —O—R ^O1Z2 or —NR ^N1Z2 R ^N2Z2 .
^{R N1Z2, R N2Z2, R 1Z2} , R 2Z2, R 3Z2, R 4Z2, and R ^5Z2, independently of each other, hydrogen ^{atom, -CO-R 102Z2, -COO-} R 101Z2, -OCO-R 102Z2, -COCO ^{-R 102Z2, -O-R 102Z2,} -SO 2 -R 101Z2, -SO 2 N (R 102Z2) 2, -CON (R 102Z2) 2, -N (R 102Z2) 2, -NHCO-R 102Z2, - _{^{NHCO-N (R 102Z2) 2}} , -NHCOOR 102Z2, -OCON (R 102Z2) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , carbon atoms, which may have a substituent The heterocyclic group which may have a hydrocarbon group or a substituent of number 1-40 is represented.
R ^2Z2 and R ^3Z2, R ^3Z2 and R ^4Z2, and R ^4Z2 and R ^5Z2 may each be bonded to each other to form a ring.
R ^101Z2 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^O1Z2 and R ^102Z2 each independently represent a hydrogen atom, an ^optionally substituted hydrocarbon group having 1 to 40 carbon atoms, or an ^optionally substituted heterocyclic group.
M represents a hydrogen atom or an alkali metal atom.
When there are a plurality of R ^O1Z2 , R ^N1Z2 , R ^N2Z2 , R ^101Z2 , R ^102Z2 and M, they may be the same or different.
A wavy line represents an E body or a Z body. ]

^{R O1Z2, R N1Z2, R N2Z2} , R 1Z2, R 2Z2, R 3Z2, R 4Z2, R 5Z2, R 101Z2 and the carbon number of the hydrocarbon group which may have a substituent represented by R ^102Z2 is It is 1-40, Preferably it is 1-30, More preferably, it is 1-20, More preferably, it is 1-15, Most preferably, it is 1-10, More preferably, it is 1-5.

^{R O1Z2, R N1Z2, R N2Z2} , R 1Z2, R 2Z2, R 3Z2, R 4Z2, a hydrocarbon group of R ^5Z2, R ^101Z2 and C1-40 represented by R ^102Z2 is an aliphatic hydrocarbon group and It may be an aromatic hydrocarbon group, and the aliphatic hydrocarbon group may be saturated or unsaturated, and may be a chain or an alicyclic ring.

The ^{R O1Z2, R N1Z2, R N2Z2} , R 1Z2, R 2Z2, R 3Z2, R 4Z2, R 5Z2, saturated or unsaturated chain hydrocarbon group represented by R ^101Z2 and R ^102Z2, a methyl group, an ethyl group Linear alkyl groups such as propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, heptadecyl, octadecyl and icosyl; Group, isobutyl group, sec-butyl group, tert-butyl group, (2-ethyl) butyl group, isopentyl group, neopentyl group, tert-pentyl group, (1-methyl) pentyl group, (2-methyl) pentyl group, (1-ethyl) pentyl, (3-ethyl) pentyl, isohexyl, (5-methyl) hexyl, (2-ethyl) hexyl and (3-ethyl) hexyl A branched alkyl group such as a butyl group; vinyl group, 1-propenyl group, 2-propenyl group (allyl group), (1-methyl) ethenyl group, 2-butenyl group, 3-butenyl group, 1,3 An alkenyl group such as a butadienyl group, a (1- (2-propenyl)) ethenyl group, a (1,2-dimethyl) propenyl group and a 2-pentenyl group; The carbon number of the saturated or unsaturated chain hydrocarbon group is preferably 1 to 30, more preferably 1 to 20, still more preferably 1 to 15, particularly preferably 1 to 10, More preferably, it is 1-8, More preferably, it is 1-5. Especially, it is especially preferable that it is a C1-C10, More preferably, it is a C1-C8 linear or branched alkyl group, and a methyl group, an ethyl group, and a tert- butyl group are especially preferable.

R ^O1Z2, as the ^{R N1Z2, R N2Z2, R 1Z2} , R 2Z2, R 3Z2, R 4Z2, R 5Z2, saturated or unsaturated alicyclic hydrocarbon group represented by R ^101Z2 and R ^102Z2, cyclopropyl group, 1-methylcyclopropyl group, cyclobutyl group, cyclopentyl group, cyclohexyl group, cycloheptyl group, 1-methylcyclohexyl group, 2-methylcyclohexyl group, 3-methylcyclohexyl group, 4-methylcyclohexyl group, 1,2-dimethylcyclohexyl Group, 1,3-dimethylcyclohexyl group, 1,4-dimethylcyclohexyl group, 2,3-dimethylcyclohexyl group, 2,4-dimethylcyclohexyl group, 2,5-dimethylcyclohexyl group, 2,6-dimethylcyclohexyl group, 3,4-dimethylcyclohexyl group, 3,5-dimethylcyclohexyl group, 2,2 -Dimethylcyclohexyl group, 3,3-dimethylcyclohexyl group, 4,4-dimethylcyclohexyl group, cyclooctyl group, 2,4,6-trimethylcyclohexyl group, 2,2,6,6-tetramethylcyclohexyl group and 3, Cycloalkyl groups such as 3,5,5-tetramethylcyclohexyl group, 4-pentylcyclohexyl group, 4-octylcyclohexyl group, 4-cyclohexylcyclohexyl group; cyclohexenyl groups (for example, cyclohex-2-ene, cyclohex-3-ene) ), A cycloalkenyl group such as a cycloheptenyl group and a cyclooctenyl group; a norbornane group, an adamantyl group, and bicyclo [2.2.2] octane. The carbon number of the saturated or unsaturated alicyclic hydrocarbon group is preferably 3 to 30, more preferably 3 to 20, still more preferably 4 to 20, and still more preferably 4 to 15. More preferably 5 to 15 and most preferably 5 to 10. Of these, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, and a cyclooctyl group are particularly preferable.

The ^{R O1Z2, R N1Z2, R N2Z2} , R 1Z2, R 2Z2, R 3Z2, R 4Z2, R 5Z2, aromatic hydrocarbon groups represented by R ^101Z2 and R ^102Z2, phenyl, o- tolyl group, m -Tolyl group, p-tolyl group, 2-ethylphenyl group, 3-ethylphenyl group, 4-ethylphenyl group, 2,3-dimethylphenyl group, 2,4-dimethylphenyl group, 2,5-dimethylphenyl group 2,6-dimethylphenyl group, 3,4-dimethylphenyl group, 3,5-dimethylphenyl group, 4-vinylphenyl group, o-isopropylphenyl group, m-isopropylphenyl group, p-isopropylphenyl group, o -Tert-butylphenyl group, m-tert-butylphenyl group, p-tert-butylphenyl group, mesityl group, 4-ethylphenyl group, 4-butylphenyl group, 4-pen Tilphenyl group, 2,6-bis (2-propyl) phenyl group, 4-cyclohexylphenyl group, 2,4,6-trimethylphenyl group, 4-octylphenyl group, 1-naphthyl group, 2-naphthyl group, 5, Aromatic hydrocarbon groups such as 6,7,8-tetrahydro-1-naphthyl group, 5,6,7,8-tetrahydro-2-naphthyl group, fluorenyl group, phenanthryl group and anthryl group, pyrenyl group; It is done. The number of carbon atoms of the aromatic hydrocarbon group is preferably 6-30, more preferably 6-20, and even more preferably 6-15.

^{R O1Z2, R N1Z2, R N2Z2} , R 1Z2, R 2Z2, R 3Z2, R 4Z2, R 5Z2, hydrocarbon groups represented by R ^101Z2 and R ^102Z2 is a hydrocarbon group (e.g. an aromatic listed above carbonized A hydrogen group and a group obtained by combining at least one of a chain hydrocarbon group and an alicyclic hydrocarbon group), and an aralkyl group such as a benzyl group, a phenethyl group, or a 1-methyl-1-phenylethyl group. An arylalkenyl group such as a phenylethenyl group (phenylvinyl group); an arylalkynyl group such as a phenylethynyl group; a phenyl group to which one or more phenyl groups such as a biphenylyl group or a terphenylyl group are bonded; a cyclohexylmethylphenyl group, a benzyl A phenyl group, a (dimethyl (phenyl) methyl) phenyl group, etc. are mentioned.
^{R O1Z2, R N1Z2, R N2Z2} , R 1Z2, R 2Z2, R 3Z2, R 4Z2, R 5Z2, groups represented by R ^101Z2 and R ^102Z2 is a hydrocarbon group (e.g., a chain hydrocarbon group listed above And alicyclic hydrocarbon group), for example, cyclopropylmethyl group, cyclopropylethyl group, cyclobutylmethyl group, cyclobutylethyl group, cyclopentylmethyl group, cyclopentylethyl group, cyclohexylmethyl group, 2- It may be an alkyl group to which one or more alicyclic hydrocarbon groups such as a methylcyclohexylmethyl group, a cyclohexylethyl group, and an adamantylmethyl group are bonded.
These carbon numbers are preferably 4-30, more preferably 6-30, still more preferably 6-20, and preferably 4-20, more preferably 4-15. Especially preferably, it is 6-15.

^{R O1Z2, R N1Z2, R N2Z2} , R 1Z2, R 2Z2, R 3Z2, R 4Z2, hydrocarbon groups represented by R ^5Z2, R ^101Z2 and R ^102Z2 may have a substituent. The substituent may be monovalent or divalent. In the divalent substituent, two bonds are preferably bonded to the same carbon atom to form a double bond.
As the monovalent substituent,
Methoxy group, ethoxy group, propoxy group, isopropoxy group, butoxy group, isobutoxy group, sec-butoxy group, tert-butoxy group, pentyloxy group, hexyloxy group, (2-ethyl) hexyloxy group, heptyloxy group, Octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, dodecyloxy group, (2-ethyl) hexyloxy group, icosyloxy group, 1-phenylethoxy group, 1-methyl-1-phenylethoxy group, phenyloxy group O-Tolyloxy group, 2,3-dimethylphenyloxy group, 2,4-dimethylphenyloxy group, 2,5-dimethylphenyloxy group, 2,6-dimethylphenyloxy group, 3,4-dimethylphenyloxy group 3,5-dimethylphenyloxy group, 2,2-dicia Phenyloxy group, 2,3-dicyanophenyloxy group, 2,4-dicyanophenyloxy group, 2,5-dicyanophenyloxy group, 2,6-dicyanophenyloxy group, 3,4-dicyanophenyloxy group, 3 , 5-dicyanophenyloxy group, 4-methoxyphenyloxy group, 2-methoxyphenyloxy group, 3-methoxyphenyloxy group, 4-ethoxyphenyloxy group, 2-ethoxyphenyloxy group, 3-ethoxyphenyloxy group, etc. And a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group represented by the following formula or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen) (Preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl) Oxy group derivatized group group)) is bonded to one side;

  Methylthio, ethylthio, propylthio, butylthio, tert-butylthio, pentylthio, hexylthio, (2-ethyl) hexylthio, heptylthio, octylthio, nonylthio, decylthio, undecylthio, dodecylthio, icosylthio A sulfanyl group to which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group, a phenylthio group and an o-tolylthio group is bonded;

Epoxy group, oxetanyl group, tetrahydrofuryl group, tetrahydropyranyl group;
Formyl group;
Acetyl group, propanoyl group, butanoyl group, 2,2-dimethylpropanoyl group, pentanoyl group, hexanoyl group, (2-ethyl) hexanoyl group, heptanoyl group, octanoyl group, nonanoyl group, decanoyl group, undecanoyl group, dodecanoyl group, Henicosanoyl group, benzoyl group and the like, and groups represented by the following formulas, etc., a hydrocarbon group having 1 to 20 carbon atoms (preferably having 1 to 11 carbon atoms) or a derivatized group thereof (for example, carboxy group, sulfo group) , A carbonyl group to which a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), a group derived from an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. When the carbonyl group is an alkanoyl group, the carbon number is preferably 2 to 12);

  Methoxycarbonyl group, ethoxycarbonyl group, propoxycarbonyl group, butoxycarbonyl group, tert-butoxycarbonyl group, pentyloxycarbonyl group, hexyloxycarbonyl group, (2-ethyl) hexyloxycarbonyl group, heptyloxycarbonyl group, octyloxycarbonyl Group, nonyloxycarbonyl group, decyloxycarbonyl group, undecyloxycarbonyl group, dodecyloxycarbonyl group, icosyloxycarbonyl group, phenyloxycarbonyl group, o-tolyloxycarbonyl group and the like, and the following formulas A hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon number 10 oxycarbonyl group alkylsulfamoyl group (preferably octyl sulfamoyl group) were derivatized with such groups) is bonded to;

アミノ基；
Ｎ−メチルアミノ基、Ｎ，Ｎ−ジメチルアミノ基、Ｎ−エチルアミノ基、Ｎ，Ｎ−ジエチルアミノ基、Ｎ−プロピルアミノ基、Ｎ，Ｎ−ジプロピルアミノ基、Ｎ−イソプロピルアミノ基、Ｎ，Ｎ−ジイソプロピルアミノ基、Ｎ−ブチルアミノ基、Ｎ，Ｎ−ジブチルアミノ基、Ｎ−イソブチルアミノ基、Ｎ，Ｎ−ジイソブチルアミノ基、Ｎ−ｓｅｃ−ブチルアミノ基、Ｎ，Ｎ−ジｓｅｃ−ブチルアミノ基、Ｎ−ｔｅｒｔ−ブチルアミノ基、Ｎ，Ｎ−ジｔｅｒｔ−ブチルアミノ基、Ｎ−ペンチルアミノ基、Ｎ，Ｎ−ジペンチルアミノ基、Ｎ−（１−エチルプロピル）アミノ基、Ｎ，Ｎ−ジ（１−エチルプロピル）アミノ基、Ｎ−ヘキシルアミノ基、Ｎ，Ｎ−ジヘキシルアミノ基、Ｎ−（２−エチル）ヘキシルアミノ基、Ｎ，Ｎ−ジ（２−エチル）ヘキシルアミノ基、Ｎ−ヘプチルアミノ基、Ｎ，Ｎ−ジヘプチルアミノ基、Ｎ−オクチルアミノ基、Ｎ，Ｎ−ジオクチルアミノ基、Ｎ−ノニルアミノ基、Ｎ，Ｎ−ジノニルアミノ基、Ｎ−フェニルアミノ基、Ｎ，Ｎ−ジフェニルアミノ基、Ｎ，Ｎ−エチルメチルアミノ基、Ｎ，Ｎ−プロピルメチルアミノ基、Ｎ，Ｎ−イソプロピルメチルアミノ基、Ｎ，Ｎ−ブチルメチルアミノ基、Ｎ−デシルアミノ基、Ｎ，Ｎ−デシルメチルアミノ基、Ｎ−ウンデシルアミノ基、Ｎ，Ｎ−ウンデシルメチルアミノ基、Ｎ−ドデシルアミノ基、Ｎ，Ｎ−ドデシルメチルアミノ基、Ｎ−イコシルアミノ基、Ｎ，Ｎ−イコシルメチルアミノ基、Ｎ，Ｎ−ｔｅｒｔ−ブチルメチルアミノ基及びＮ，Ｎ−フェニルメチルアミノ基等、及び以下の式で表される基等の１つ又は２つの炭素数１〜２０（好ましくは炭素数１〜１０）の炭化水素基又はその誘導化基（例えばカルボキシ基、スルホ基、ニトロ基、ヒドロキシ基、ハロゲン（好ましくは塩素原子）、炭素数１〜１０のアルキルスルファモイル基（好ましくはオクチルスルファモイル基）等で誘導化された基）で置換されたアミノ基；

An amino group;
N-methylamino group, N, N-dimethylamino group, N-ethylamino group, N, N-diethylamino group, N-propylamino group, N, N-dipropylamino group, N-isopropylamino group, N, N-diisopropylamino group, N-butylamino group, N, N-dibutylamino group, N-isobutylamino group, N, N-diisobutylamino group, N-sec-butylamino group, N, N-disec-butyl Amino group, N-tert-butylamino group, N, N-ditert-butylamino group, N-pentylamino group, N, N-dipentylamino group, N- (1-ethylpropyl) amino group, N, N -Di (1-ethylpropyl) amino group, N-hexylamino group, N, N-dihexylamino group, N- (2-ethyl) hexylamino group, N, N-di (2-ethyl) Xylamino group, N-heptylamino group, N, N-diheptylamino group, N-octylamino group, N, N-dioctylamino group, N-nonylamino group, N, N-dinonylamino group, N-phenylamino group, N, N-diphenylamino group, N, N-ethylmethylamino group, N, N-propylmethylamino group, N, N-isopropylmethylamino group, N, N-butylmethylamino group, N-decylamino group, N , N-decylmethylamino group, N-undecylamino group, N, N-undecylmethylamino group, N-dodecylamino group, N, N-dodecylmethylamino group, N-icosylamino group, N, N-ico One of a silmethylamino group, an N, N-tert-butylmethylamino group, an N, N-phenylmethylamino group, etc., and a group represented by the following formula Are two hydrocarbon groups having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or derivatized groups thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon number An amino group substituted with 1 to 10 alkylsulfamoyl groups (preferably a group derivatized with an octylsulfamoyl group or the like);

スルファモイル基；
Ｎ−メチルスルファモイル基、Ｎ，Ｎ−ジメチルスルファモイル基、Ｎ−エチルスルファモイル基、Ｎ，Ｎ−ジエチルスルファモイル基、Ｎ−プロピルスルファモイル基、Ｎ，Ｎ−ジプロピルスルファモイル基、Ｎ−イソプロピルスルファモイル基、Ｎ，Ｎ−ジイソプロピルスルファモイル基、Ｎ−ブチルスルファモイル基、Ｎ，Ｎ−ジブチルスルファモイル基、Ｎ−イソブチルスルファモイル基、Ｎ，Ｎ−ジイソブチルスルファモイル基、Ｎ−ｓｅｃ−ブチルスルファモイル基、Ｎ，Ｎ−ジｓｅｃ−ブチルスルファモイル基、Ｎ−ｔｅｒｔ−ブチルスルファモイル基、Ｎ，Ｎ−ジｔｅｒｔ−ブチルスルファモイル基、Ｎ−ペンチルスルファモイル基、Ｎ，Ｎ−ジペンチルスルファモイル基、Ｎ−（１−エチルプロピル）スルファモイル基、Ｎ，Ｎ−ジ（１−エチルプロピル）スルファモイル基、Ｎ−ヘキシルスルファモイル基、Ｎ，Ｎ−ジヘキシルスルファモイル基、Ｎ−（２−エチル）ヘキシルスルファモイル基、Ｎ，Ｎ−ジ（２−エチル）ヘキシルスルファモイル基、Ｎ−ヘプチルスルファモイル基、Ｎ，Ｎ−ジヘプチルスルファモイル基、Ｎ−オクチルスルファモイル基、Ｎ，Ｎ−ジオクチルスルファモイル基、Ｎ，Ｎ−オクチルメチルスルファモイル基、Ｎ−ノニルスルファモイル基、Ｎ，Ｎ−ジノニルスルファモイル基、Ｎ−フェニルスルファモイル基、Ｎ，Ｎ−ジフェニルスルファモイル基、Ｎ，Ｎ−エチルメチルスルファモイル基、Ｎ，Ｎ−プロピルメチルスルファモイル基、Ｎ，Ｎ−イソプロピルメチルスルファモイル基、Ｎ，Ｎ−ブチルメチルスルファモイル基、Ｎ−デシルスルファモイル基、Ｎ，Ｎ−デシルメチルスルファモイル基、Ｎ−ウンデシルスルファモイル基、Ｎ，Ｎ−ウンデシルメチルスルファモイル基、Ｎ−ドデシルスルファモイル基、Ｎ，Ｎ−ドデシルメチルスルファモイル基、Ｎ−イコシルスルファモイル基、Ｎ，Ｎ−イコシルメチルスルファモイル基、Ｎ，Ｎ−ｔｅｒｔ−ブチルメチルスルファモイル基及びＮ，Ｎ−フェニルメチルスルファモイル基等、及び以下の式で表される基等の１つ又は２つの炭素数１〜２０（好ましくは炭素数１〜１０）の炭化水素基またはその誘導化基（例えばカルボキシ基、スルホ基、ニトロ基、ヒドロキシ基、ハロゲン（好ましくは塩素原子）、炭素数１〜１０のアルキルスルファモイル基（好ましくはオクチルスルファモイル基）等で誘導化された基）で置換されたスルファモイル基；

A sulfamoyl group;
N-methylsulfamoyl group, N, N-dimethylsulfamoyl group, N-ethylsulfamoyl group, N, N-diethylsulfamoyl group, N-propylsulfamoyl group, N, N-dipropyls Rufamoyl group, N-isopropylsulfamoyl group, N, N-diisopropylsulfamoyl group, N-butylsulfamoyl group, N, N-dibutylsulfamoyl group, N-isobutylsulfamoyl group, N, N-diisobutylsulfamoyl group, N-sec-butylsulfamoyl group, N, N-disec-butylsulfamoyl group, N-tert-butylsulfamoyl group, N, N-ditert-butylsulfur Famoyl group, N-pentylsulfamoyl group, N, N-dipentylsulfamoyl group, N- (1-ethylpropyl) sulfamoyl group, , N-di (1-ethylpropyl) sulfamoyl group, N-hexylsulfamoyl group, N, N-dihexylsulfamoyl group, N- (2-ethyl) hexylsulfamoyl group, N, N-di ( 2-ethyl) hexylsulfamoyl group, N-heptylsulfamoyl group, N, N-diheptylsulfamoyl group, N-octylsulfamoyl group, N, N-dioctylsulfamoyl group, N, N -Octylmethylsulfamoyl group, N-nonylsulfamoyl group, N, N-dinonylsulfamoyl group, N-phenylsulfamoyl group, N, N-diphenylsulfamoyl group, N, N-ethylmethyl Sulfamoyl group, N, N-propylmethylsulfamoyl group, N, N-isopropylmethylsulfamoyl group, N, N-butylmethylsulfamoyl group N-decylsulfamoyl group, N, N-decylmethylsulfamoyl group, N-undecylsulfamoyl group, N, N-undecylmethylsulfamoyl group, N-dodecylsulfamoyl group, N, N-dodecylmethylsulfamoyl group, N-icosylsulfamoyl group, N, N-icosylmethylsulfamoyl group, N, N-tert-butylmethylsulfamoyl group and N, N-phenylmethylsulfa 1 or 2 hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a moyl group and the group represented by the following formula or a derivatized group thereof (for example, carboxy group, sulfo group) , A nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. Sulfamoyl group substituted with

  Formylamino group; acetylamino group, propanoylamino group, butanoylamino group, 2,2-dimethylpropanoylamino group, pentanoylamino group, hexanoylamino group, (2-ethyl) hexanoylamino group, heptanoyl Amino group, octanoylamino group, nonanoylamino group, decanoylamino group, undecanoylamino group, dodecanoylamino group, heicosanoylamino group, benzoylamino group, etc., and groups represented by the following formulae Or a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 12 carbon atoms) or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon number 1 10 to 10 alkylsulfamoyl groups (preferably octylsulfamoyl groups) and the like) Carbonyl amino group (if the alkanoylamino group the carbonyl group, the carbon number is preferably 1 to 12);

ヒドロキシ基；
フッ素原子、塩素原子、臭素原子及びヨウ素原子等のハロゲン原子；
カルボキシ基、−ＣＯ₂Ｍ²（Ｍ²はアルカリ金属、好ましくはリチウム、ナトリウム、カリウム）；スルホ基、−ＳＯ₃Ｍ²（Ｍ²はアルカリ金属、好ましくはリチウム、ナトリウム、カリウム）；ニトロ基；シアノ基；
ホルミルオキシ基；アセトキシ基、プロパノイルオキシ基、ブタノイルオキシ基、２，２−ジメチルプロパノイルオキシ基、ペンタノイルオキシ基、ヘキサノイルオキシ基、（２−エチル）ヘキサノイルオキシ基、ヘプタノイルオキシ基、オクタノイルオキシ基、ノナノイルオキシ基、デカノイルオキシ基、ウンデカノイルオキシ基、ドデカノイルオキシ基、ヘンイコサノイルオキシ基、ベンゾイルオキシ基等、及び以下の式で表される基等の炭素数１〜２０（好ましくは炭素数１〜１０）の炭化水素基又はその誘導化基（例えばカルボキシ基、スルホ基、ニトロ基、ヒドロキシ基、ハロゲン（好ましくは塩素原子）、炭素数１〜１０のアルキルスルファモイル基（好ましくはオクチルスルファモイル基）等で誘導化された基）が結合したカルボニルオキシ基（該カルボニルオキシ基をアルカノイルオキシ基とする場合、炭素数は好ましくは１〜１０である）；

A hydroxy group;
Halogen atoms such as fluorine atom, chlorine atom, bromine atom and iodine atom;
Carboxy group, —CO ₂ M ² (M ² is alkali metal, preferably lithium, sodium, potassium); sulfo group, —SO ₃ M ² (M ² is alkali metal, preferably lithium, sodium, potassium); Nitro group A cyano group;
Formyloxy group; acetoxy group, propanoyloxy group, butanoyloxy group, 2,2-dimethylpropanoyloxy group, pentanoyloxy group, hexanoyloxy group, (2-ethyl) hexanoyloxy group, heptanoyloxy Carbon such as a group, octanoyloxy group, nonanoyloxy group, decanoyloxy group, undecanoyloxy group, dodecanoyloxy group, heicosanoyloxy group, benzoyloxy group, and the group represented by the following formula A hydrocarbon group having 1 to 20 (preferably 1 to 10 carbons) or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), A group to which an alkyl sulfamoyl group (preferably a group derivatized with an octyl sulfamoyl group) is bound. Boniruokishi group (if the alkanoyloxy group and the carbonyl group, the carbon number is preferably 1 to 10);

メチルスルホニル基、エチルスルホニル基、プロピルスルホニル基、ブチルスルホニル基、ペンチルスルホニル基、ヘキシルスルホニル基、（２−エチル）ヘキシルスルホニル基、ヘプチルスルホニル基、オクチルスルホニル基、ノニルスルホニル基、デシルスルホニル基、ウンデシルスルホニル基、ドデシルスルホニル基、イコシルスルホニル基、フェニルスルホニル基、ｐ−トリルスルホニル基等、及び以下の式で表される基等の炭素数１〜２０（好ましくは炭素数１〜１０）の炭化水素基又はその誘導化基（例えばカルボキシ基、スルホ基、ニトロ基、ヒドロキシ基、ハロゲン（好ましくは塩素原子）、炭素数１〜１０のアルキルスルファモイル基（好ましくはオクチルスルファモイル基）等で誘導化された基）が結合したスルホニル基；

Methylsulfonyl group, ethylsulfonyl group, propylsulfonyl group, butylsulfonyl group, pentylsulfonyl group, hexylsulfonyl group, (2-ethyl) hexylsulfonyl group, heptylsulfonyl group, octylsulfonyl group, nonylsulfonyl group, decylsulfonyl group, un Decylsulfonyl group, dodecylsulfonyl group, icosylsulfonyl group, phenylsulfonyl group, p-tolylsulfonyl group and the like, and groups having 1 to 20 carbon atoms (preferably having 1 to 10 carbon atoms) such as groups represented by the following formulae: Hydrocarbon group or derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group) A group derivatized with a sulfonyl group) ;

A carbamoyl group;
N-methylcarbamoyl group, N, N-dimethylcarbamoyl group, N-ethylcarbamoyl group, N, N-diethylcarbamoyl group, N-propylcarbamoyl group, N, N-dipropylcarbamoyl group, N-isopropylcarbamoyl group, N , N-diisopropylcarbamoyl group, N-butylcarbamoyl group, N, N-dibutylcarbamoyl group, N-isobutylcarbamoyl group, N, N-diisobutylcarbamoyl group, N-sec-butylcarbamoyl group, N, N-disec- Butylcarbamoyl group, N-tert-butylcarbamoyl group, N, N-ditert-butylcarbamoyl group, N-pentylcarbamoyl group, N, N-dipentylcarbamoyl group, N- (1-ethylpropyl) carbamoyl group, N, N-di (1-ethylpropyl) carba Yl group, N-hexylcarbamoyl group, N, N-dihexylcarbamoyl group, N- (2-ethyl) hexylcarbamoyl group, N, N-di (2-ethyl) hexylcarbamoyl group, N-heptylcarbamoyl group, N, N-diheptylcarbamoyl group, N-octylcarbamoyl group, N, N-dioctylcarbamoyl group, N-nonylcarbamoyl group, N, N-octylmethylcarbamoyl group, N, N-octylbutylcarbamoyl group, N, N-di Nonylcarbamoyl group, N-phenylcarbamoyl group, N, N-diphenylcarbamoyl group, N, N-ethylmethylcarbamoyl group, N, N-propylmethylcarbamoyl group, N, N-isopropylmethylcarbamoyl group, N, N-butyl Methylcarbamoyl group, N-decylcarbamoyl group, N, N Decylmethylcarbamoyl group, N-undecylcarbamoyl group, N, N-undecylmethylcarbamoyl group, N-dodecylcarbamoyl group, N, N-dodecylmethylcarbamoyl group, N-icosylcarbamoyl group, N, N-icosyl 1 or 2 carbon atoms (preferably carbon atoms) such as a methylcarbamoyl group, an N, N-tert-butylmethylcarbamoyl group, an N, N-phenylmethylcarbamoyl group, and a group represented by the following formula A hydrocarbon group having 1 to 10) or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably A carbamoyl group substituted with a group derivatized with an octylsulfamoyl group) or the like;

Trifluoromethyl group, perfluoroethyl group, perfluoropropyl group, perfluoroisopropyl group, perfluorobutyl group, perfluoropentyl group, perfluorohexyl group, perfluoroheptyl group, perfluorooctyl group, perfluorononyl group, A carbon atom having 1 to 20 carbon atoms in which all hydrogen atoms such as perfluorodecyl group, perfluoroundecyl group, perfluorododecyl group, perfluoroicosyl group, perfluorocyclohexyl group and perfluorophenyl group are substituted with fluorine atoms. A hydrogen group;
Perfluoroethylmethyl group, perfluoropropylmethyl group, perfluoroisopropylmethyl group, perfluorobutylmethyl group, perfluoropentylmethyl group, perfluorohexylmethyl group, perfluoroheptylmethyl group, perfluorooctylmethyl group, perfluoro A straight chain having 1 to 20 carbon atoms in which all hydrogen atoms such as nonylmethyl group, perfluorodecylmethyl group, perfluoroundecylmethyl group, perfluorododecylmethyl group and perfluoroicosylmethyl group are substituted with fluorine atoms Or a hydrocarbon group having 1 to 20 carbon atoms substituted by a branched alkyl group;
1 to 20 carbon atoms (preferably carbon atoms) in which part of hydrogen atoms such as 2-fluorophenyl group, 3-fluorophenyl group, 4-fluorophenyl group and 2,4,6-trifluorophenyl group are substituted with fluorine. 1-10) hydrocarbon radicals;
-CO-SH, -CO-S- CH 3, -CO-S-CH 2 CH 3, -CO-S-CH 2 -CH 2 -CH 3 and _{-CO-S-CH 2 -CH 2} -CH 2 A thiocarbonyl group bonded to an alkyl group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as —CH _3; and an aryl group having 6 to 20 carbon atoms such as —CO—S—C ₆ H _5. A thiocarbonyl group;

  * -COCO-R as represented by the following formula (wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, satisfying 1 to 20 carbon atoms among the hydrocarbon groups mentioned above) Or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably octyl sulfamoyl group) A group derived from, etc.)

* -NRCONR ₂ represented by the following formula (wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, those satisfying 1 to 20 carbon atoms among the hydrocarbon groups mentioned above) ) Or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group), etc. And the R may be the same or different from each other and may be bonded to each other to form a ring);

* -OCONR ₂ represented by the following formula (wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, those satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above) ) Or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group), etc. And the R may be the same or different from each other and may be bonded to each other to form a ring);

  * -NRCOOR as represented by the following formula (wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, those satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above)) Or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. A derivatized group), wherein the Rs may be the same or different from each other and may be bonded to each other to form a ring;

_{* -OP (O) (OCH 3} ) in such _{2 * -OP (O) (OR} ) 2 ( wherein, R represents a hydrogen atom, a hydrocarbon group (e.g., hydrocarbon groups mentioned above having 1 to 20 carbon atoms Or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms) A group derived from (preferably an octylsulfamoyl group) or the like, and the Rs may be the same or different from each other, and may be bonded to each other to form a ring;
* -SiR ₃ (* -Si (CH ₃ ) ₃ , * -Si (CH ₂ CH ₃ ) ₃ , * -Si (C ₆ H ₅ ) ₃ and * -Si (CH (CH ₃ ) ₂ ) ₃ In the formula, R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, those satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivatizing group thereof (for example, a carboxy group, sulfo group). A group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), a C1-C10 alkylsulfamoyl group (preferably an octylsulfamoyl group) and the like, and the R is Groups that may be the same or different from each other and may be bonded to each other to form a ring);
Etc.

As the divalent substituent, an oxo group, a thioxo group, an imino group, an imino group substituted with an alkyl group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms), and an aryl group having 6 to 20 carbon atoms are substituted. And imino groups. Examples of the imino group substituted with an alkyl group include CH ₃ —N═, CH ₃ —CH ₂ —N═, CH ₃ — (CH ₂ ) ₂ —N═, and CH ₃ — (CH ₂ ) ₃ —N =. Can be mentioned. Examples of the imino group substituted with an aryl group include C ₆ H ₅ —N═.

The substituent of the hydrocarbon group having 1 to 40 carbon atoms is preferably a substituent of group s1. The derivatizing groups shown below are a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), and the like. A derivatized group is preferred.
[Group s1]
An oxy group having a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof bonded to one side;
A carbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
An oxycarbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
An amino group;
An amino group substituted by one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
A sulfamoyl group;
A sulfamoyl group substituted with one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
A carbonylamino group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
A hydroxy group;
A halogen atom;
-CO ₂ M (preferably a carboxy group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom.);
-SO ₃ M (preferably a sulfo group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom.);
A nitro group;
A cyano group;
A carbonyloxy group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
A sulfonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
A carbamoyl group;
A carbamoyl group substituted with one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
A hydrocarbon group having 1 to 20 carbon atoms in which all of the hydrogen atoms are substituted by fluorine atoms;
A hydrocarbon group having 1 to 20 carbon atoms substituted with a linear or branched alkyl group having 1 to 20 carbon atoms in which all of the hydrogen atoms are substituted with fluorine atoms;
A hydrocarbon group having 1 to 20 carbon atoms in which a part of hydrogen atoms is substituted by fluorine;
Oxo group

The substituent of the hydrocarbon group having 1 to 40 carbon atoms is more preferably a substituent of group s2.
[Group s2]
An oxy group having a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof bonded to one side;
A carbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
An oxycarbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
An amino group;
An amino group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof;
A sulfamoyl group;
A sulfamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof;
A carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
A hydroxy group;
Fluorine atom, chlorine atom, bromine atom;
-CO ₂ M (preferably a carboxy group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom.);
-SO ₃ M (preferably a sulfo group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom.);
A nitro group;
A cyano group;
A carbonyloxy group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
A sulfonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
A carbamoyl group;
A carbamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof;
A hydrocarbon group having 1 to 10 carbon atoms in which all of the hydrogen atoms are substituted by fluorine atoms;
A hydrocarbon group having 1 to 10 carbon atoms substituted by a linear or branched alkyl group having 1 to 10 carbon atoms in which all of the hydrogen atoms are substituted with fluorine atoms;
A hydrocarbon group having 1 to 10 carbon atoms in which a part of hydrogen atoms is substituted by fluorine;
Oxo group

Examples of the hydrocarbon group ^{R O1Z2, R N1Z2, R N2Z2} , R 1Z2, R 2Z2, R 3Z2, R 4Z2, R 5Z2, carbon atoms having a substituent represented by R ^101Z2 and R ^102Z2 1~40, 1 And a C1-C40 hydrocarbon group having a monovalent or divalent substituent, preferably a C1-C30 saturated or unsaturated chain hydrocarbon group having a monovalent or divalent substituent. A saturated or unsaturated alicyclic hydrocarbon group having 3 to 30 carbon atoms having a monovalent or divalent substituent, or an aromatic hydrocarbon group having 6 to 30 carbon atoms having a monovalent or divalent substituent, or A group in which a hydrocarbon group is combined, and examples thereof include a group having 1 to 30 carbon atoms having a monovalent or divalent substituent,
More preferably, a saturated or unsaturated chain hydrocarbon group having 1 to 20 carbon atoms having a substituent of group s1, or a saturated or unsaturated alicyclic hydrocarbon group having 3 to 20 carbon atoms having a substituent of group s1. A group having 6 to 20 carbon atoms having a substituent of group s1 or a combination of hydrocarbon groups, and a group having 1 to 20 carbon atoms having a substituent of group s1,
Particularly preferably, it is a saturated or unsaturated chain hydrocarbon group having 1 to 15 carbon atoms having a substituent of group s2, or a saturated or unsaturated alicyclic hydrocarbon group having 3 to 15 carbon atoms having a substituent of group s2. , A group having a substituent of group s2 and a combination of an aromatic hydrocarbon group having 6 to 15 carbon atoms or a hydrocarbon group, and a group having 1 to 15 carbon atoms having a substituent of group s2.

In Examples ^{R O1Z2, R N1Z2, R N2Z2} , R 1Z2, R 2Z2, R 3Z2, R 4Z2, heterocyclic group represented by R ^5Z2, R ^101Z2 and R ^102Z2, may be monocyclic polycyclic Preferably, it is a heterocyclic ring containing a hetero atom as a ring component. Examples of the hetero atom include a nitrogen atom, an oxygen atom, and a sulfur atom.
The number of carbon atoms of the heterocyclic group is preferably 3 to 30, more preferably 3 to 22, still more preferably 3 to 20, still more preferably 3 to 18, still more preferably 3 ~ 15, particularly preferably 3-14.

As a heterocyclic ring containing a nitrogen atom,
Monocyclic saturated heterocycles such as aziridine, azetidine, pyrrolidine, piperidine and piperazine;
Pyrrol such as 2,5-dimethylpyrrole, pyrazole such as 2-methylpyrazole and 3-methylpyrazole, 5-membered unsaturated heterocyclic ring such as imidazole, 1,2,3-triazole and 1,2,4-triazole ;
6-membered unsaturated heterocycles such as pyrimidines such as pyridine, pyridazine, 6-methylpyrimidine, pyrazines and 1,3,5-triazines;
Indazole, indoline, isoindoline, indole, indolizine, benzimidazole, quinoline, isoquinoline, quinoxaline such as 5,6,7,8-tetrahydro (3-methyl) quinoxaline, 3-methylquinoxaline, quinazoline, cinnoline, phthalazine, naphthyridine , Condensed bicyclic heterocycles such as purine, pteridine, benzopyrazole, benzopiperidine;
And condensed tricyclic heterocycles such as carbazole, acridine and phenazine.

As a heterocyclic ring containing an oxygen atom,
Monocyclic saturated heterocycles such as oxirane, oxetane, tetrahydrofuran, tetrahydropyran, 1,3-dioxane and 1,4-dioxane, 1-cyclopentyldioxolane;
Bicyclic saturated heterocycles such as 1,4-dioxaspiro [4.5] decane, 1,4-dioxaspiro [4.5] nonane;
Lactone heterocycles such as α-acetolactone, β-propiolactone, γ-butyrolactone, γ-valerolactone and δ-valerolactone;
5-membered unsaturated heterocyclic rings such as furan such as 2,3-dimethylfuran and 2,5-dimethylfuran;
6-membered unsaturated heterocyclic rings such as 2H-pyran and 4H-pyran;
Fused bicyclic heterocycles such as 1-benzofuran, benzopyran such as 4-methylbenzopyran, benzodioxole, chroman and isochroman;
And condensed tricyclic heterocycles such as xanthene and dibenzofuran;

As a heterocyclic ring containing a sulfur atom,
5-membered saturated heterocyclic ring such as dithiolane;
6-membered saturated heterocyclic rings such as thiane, 1,3-dithiane, 2-methyl-1,3-dithiane;
5-membered unsaturated heterocyclic rings such as thiophene such as 3-methylthiophene and 2-carboxythiophene, benzothiopyran such as 4H-thiopyran and benzotetrahydrothiopyran;
Condensed bicyclic heterocycles such as benzothiophene;
And condensed tricyclic heterocycles such as thianthrene and dibenzothiophene.

As a heterocyclic ring containing a nitrogen atom and an oxygen atom,
Monocyclic saturated heterocycles such as morpholine, 2-pyrrolidone, 2-methyl-2-pyrrolidone, 2-piperidone and 2-methyl-2-piperidone;
Monocyclic unsaturated heterocycles such as oxazole such as 4-methyloxazole, isoxazole such as 2-methylisoxazole and 3-methylisoxazole;
Condensed bicyclic heterocycles such as benzoxazole, benzisoxazole, benzoxazine, benzodioxane, benzimidazoline;
And condensed tricyclic heterocycles such as phenoxazine.

As a heterocyclic ring containing a nitrogen atom and a sulfur atom,
Monocyclic heterocycles such as thiazole such as 3-methylthiazole and 2,4-dimethylthiazole;
Fused bicyclic heterocycles such as benzothiazole;
Condensed tricyclic heterocycles such as phenothiazine; and the like.

  The heterocycle may be a group in which the above-described hydrocarbon groups are combined, and examples thereof include a tetrahydrofurylmethyl group.

Furthermore, the heterocyclic ring may be represented by the following formula.

The heterocyclic group may be a heterocyclic group formed by combining two or more of R ^{1Z2 to} R ^5Z2 . Such a heterocyclic group has two or more ring structures together with a benzene ring to which R ^{1Z2 to} R ^5Z2 are bonded. Examples of the two or more ring structures include structures of the following formulas.

  In addition, the bonding position of the above heterocyclic ring is a portion from which an arbitrary hydrogen atom contained in each ring is eliminated.

^{R O1Z2, R N1Z2, R N2Z2} , R 1Z2, R 2Z2, R 3Z2, R 4Z2, heterocyclic group represented by R ^5Z2, R ^101Z2 and R ^102Z2 may have a substituent. Examples of the ^{substituent, R O1Z2, R N1Z2, R} N2Z2, R 1Z2, R 2Z2, R 3Z2, R 4Z2, R 5Z2, which may have a hydrocarbon group represented by R ^101Z2 and R ^102Z2 substituted The same thing as a group is mentioned. When the heterocyclic ring contains a nitrogen atom as a constituent element, the above-described hydrocarbon group may be bonded to the nitrogen atom as a substituent.
Preferred examples of the substituent, and ^{R O1Z2, R N1Z2, R N2Z2} , R 1Z2, R 2Z2, R 3Z2, R 4Z2, R 5Z2, have a hydrocarbon group represented by R ^101Z2 and R ^102Z2 Examples of the preferred substituents are the same.
Examples of the heterocyclic group having a ^{R O1Z2, R N1Z2, R N2Z2} , R 1Z2, R 2Z2, R 3Z2, R 4Z2, R 5Z2, substituents represented by R ^101Z2 and R ^102Z2, 1 monovalent or divalent substituent A heterocyclic group having a substituent, preferably a heterocyclic group having a substituent of group s1, more preferably a heterocyclic group having a substituent of group s2.
The hydrocarbon group or heterocyclic group may have one or more substituents (first substituent), and the two or more substituents are independent of each other. They may be the same or different. Further, the first substituent may have another substituent (second substituent) bonded to a hydrocarbon group contained in a part thereof. The second substituent can be selected from the same groups as the first substituent.

^{Hereinafter, R N1Z2, R N2Z2, R} 1Z2, R 2Z2, R 3Z2, R 4Z2, -CO-R 102Z2 of ^{R 5Z2, -COO-R 101Z2,} -OCO-R 102Z2, -COCO-R 102Z2, -O- _{^{R 102Z2, -SO 2 -R 101Z2,}} -SO 2 N (R 102Z2) 2, -CON (R 102Z2) 2, -N (R 102Z2) 2, -NHCO-R 102Z2, -NHCO-N (R 102Z2) ^{_{2, -NHCOOR 102Z2, -OCON (R}} 102Z2) 2, halogen atom, -SO ₃ M, for -CO ₂ M will be described.
As —CO—R ^102Z2 , formyl group; acetyl group, propanoyl group, butanoyl group, 2,2-dimethylpropanoyl group, pentanoyl group, hexanoyl group, (2-ethyl) hexanoyl group, heptanoyl group, octanoyl group, nonanoyl A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof, such as a group, a decanoyl group, an undecanoyl group, a dodecanoyl group, a heicosanoyl group, a benzoyl group, and the like A derivatized group (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. Group), the number of carbon atoms is 2 to 41 when the carbonyl group is an acyl group. ) And include groups corresponding to the -CO-R ^102Z2 in the compounds shown in Table 1Z2~ Table 43Z2 -CO-R ^102Z2 Table 1-966 of the relevant group and Japanese Patent Application No. 2017-016290 to the compounds shown in Preferably, the hydrocarbon group having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms) or a carbonyl group to which the derivatizing group is bonded (when the carbonyl group is an alkanoyl group, the carbon number is more preferably 2 to 12) and groups corresponding to —CO—R ^102Z2 in the compounds shown in Table 1Z2 to Table 43Z2.

-COO-R ^101Z2 includes methoxycarbonyl group, ethoxycarbonyl group, propoxycarbonyl group, tert-butoxycarbonyl group, butoxycarbonyl group, pentyloxycarbonyl group, hexyloxycarbonyl group, (2-ethyl) hexyloxycarbonyl group, Heptyloxycarbonyl group, octyloxycarbonyl group, nonyloxycarbonyl group, decyloxycarbonyl group, undecyloxycarbonyl group, dodecyloxycarbonyl group, phenyloxycarbonyl group, icosyloxycarbonyl group, etc. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon, etc. Number 1 0 alkylsulfamoyl group group (preferably octyl sulfamoyl group) corresponding to the -COO-R ^101Z2 in compounds derivatized groups) is shown in oxycarbonyl group and Tables 1Z2~ table 43Z2 bound by such And groups corresponding to -COO-R ^101Z2 in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290, preferably a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof bonded thereto. Examples include oxycarbonyl groups and groups corresponding to —COO—R ^101Z2 in the compounds shown in Tables 1Z2 to ^43Z2 .

-OCO-R ^102Z2 includes ^formyloxy group; acetoxy group, propanoyloxy group, butanoyloxy group, 2,2-dimethylpropanoyloxy group, pentanoyloxy group, hexanoyloxy group, (2-ethyl) Hexanoyloxy group, heptanoyloxy group, octanoyloxy group, nonanoyloxy group, decanoyloxy group, undecanoyloxy group, dodecanoyloxy group, heicosanoyloxy group, benzoyloxy group, and the above formula A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom) ), An alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. If the reduction radicals) is bonded to a carbonyl group (said carbonyl group to an acyloxy group, a carbon number of 2-41), as well as -OCO-R ^102Z2 in the compounds shown in Table 1Z2~ Table 43Z2 Examples of the corresponding group and the group shown in Tables 1 to 966 of Japanese Patent Application No. ^2017-016290 include a group corresponding to —OCO—R ^102Z2 , preferably 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms). ) Or a carbonyloxy group to which the derivatizing group is bonded (when the carbonyloxy group is an acyloxy group, the carbon number is more preferably 2 to 12), and Tables 1Z2 to 43Z2 ^Examples of the compound include a group corresponding to -OCO-R ^102Z2 .

-COCO-R ^102Z2 includes methyl oxalyl group, ethyl oxalyl group, propyl oxalyl group, butyl oxalyl group, pentyl oxalyl group, hexyl oxalyl group, (2-ethyl) hexyl oxalyl group, heptyl oxalyl group, octyl oxalyl group, nonyl Oxalyl group, decyloxalyl group, undecyloxalyl group, dodecyloxalyl group, icosyloxalyl group, cyclopentyloxalyl group, cyclohexyloxalyl group, phenyloxalyl group, p-tolyloxalyl group, etc., and groups represented by the above formula A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), 10 alkyl sulfamos Group and JP Le group (preferably octyl sulfamoyl group) corresponding to the -COCO-R ^102Z2 In the compound represented oxalyl groups, as well as Table 1Z2~ Table 43Z2 derivatized group, etc.) are bonded 2017-016290 In the compounds shown in Tables 1 to 966 of the No., groups corresponding to -COCO-R ^102Z2 and the like can be mentioned.

As —O—R ^102Z2 group, hydroxy group; methoxy group, ethoxy group, propoxy group, isopropoxy group, butoxy group, isobutoxy group, sec-butoxy group, tert-butoxy group, pentyloxy group, hexyloxy group, heptyl Oxy group, octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, dodecyloxy group, (2-ethyl) hexyloxy group, icosyloxy group, 1-phenylethoxy group, 1-methyl-1-phenylethoxy group, Phenyloxy group, 2,3-dimethylphenyloxy group, 2,4-dimethylphenyloxy group, 2,5-dimethylphenyloxy group, 2,6-dimethylphenyloxy group, 3,4-dimethylphenyloxy group, 3 , 5-dimethylphenyloxy group, 2,2-dicyanophenyloxy Group, 2,3-dicyanophenyloxy group, 2,4-dicyanophenyloxy group, 2,5-dicyanophenyloxy group, 2,6-dicyanophenyloxy group, 3,4-dicyanophenyloxy group, 3,5 -Dicyanophenyloxy group, 4-methoxyphenyloxy group, 2-methoxyphenyloxy group, 3-methoxyphenyloxy group, 4-ethoxyphenyloxy group, 2-ethoxyphenyloxy group, 3-ethoxyphenyloxy group and the like, and A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group represented by the above formula or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably Is a chlorine atom), derivatized with an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. -O-R in the group) oxy group and Tables 1Z2~ table in the compound represented by 43Z2 shown in Table 1 to 966 groups and Japanese Patent Application No. 2017-016290 corresponding to -O-R ^102Z2 compound bound ^And a group corresponding to ^102Z2 , preferably an oxy group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded, or a compound shown in Table 1Z2 to Table ^43Z2 , corresponding to —O—R ^102Z2 Groups and the like.

As —SO ₂ —R ^101Z2 , methylsulfonyl group, ethylsulfonyl group, propylsulfonyl group, butylsulfonyl group, pentylsulfonyl group, ^{hexylsulfonyl} group, (2-ethyl) ^{hexylsulfonyl} group, ^{heptylsulfonyl} group, octylsulfonyl group, 1 to 40 carbon atoms such as a nonylsulfonyl group, a decylsulfonyl group, an undecylsulfonyl group, a dodecylsulfonyl group, an icosylsulfonyl group, a phenylsulfonyl group, a p-tolylsulfonyl group, and a group represented by the above formula Preferably a hydrocarbon group having 1 to 20 carbon atoms or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms. (Preferably octylsulfamoyl group) -SO ₂ -R in the compounds represented by -SO ₂ -R ^101Z2 Table 1-966 of the relevant group and Japanese Patent Application No. 2017-016290 in the compound group) is shown in the sulfonyl group and Table 1Z2~ table 43Z2 bound ^Examples include groups corresponding to ^101Z2 , preferably sulfonyl groups to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded, and compounds represented by Table 1Z2 to Table 43Z2, which correspond to —SO ₂ —R ^101Z2 And the like.

—SO ₂ N (R ^102Z2 ) ₂ includes a sulfamoyl group;
N-methylsulfamoyl group, N-ethylsulfamoyl group, N-propylsulfamoyl group, N-isopropylsulfamoyl group, N-butylsulfamoyl group, N-isobutylsulfamoyl group, N- sec-butylsulfamoyl group, N-tert-butylsulfamoyl group, N-pentylsulfamoyl group, N- (1-ethylpropyl) sulfamoyl group, N-hexylsulfamoyl group, N- (2- Ethyl) hexylsulfamoyl group, N-heptylsulfamoyl group, N-octylsulfamoyl group, N-nonylsulfamoyl group, N-decylsulfamoyl group, N-undecylsulfamoyl group, N- Dodecylsulfamoyl group, N-icosylsulfamoyl group, N-phenylsulfamoyl group, etc., and groups represented by the above formula A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon number In a sulfamoyl group substituted with 1 to 10 alkylsulfamoyl groups (preferably a group derivatized with an octylsulfamoyl group, etc.) and compounds shown in Tables 1Z2 to 43Z2, —SO ₂ NH (R ^102Z2X ) (Provided that R ^102Z2X is the same as R ^102Z2 except that R ^102Z2X is not a hydrogen atom) and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290, —SO ₂ NH (R ^102Z2X ) (However, R ^102Z2X is the same as R ^102Z2 except that it does not become a hydrogen atom), etc .;
N, N-dimethylsulfamoyl group, N, N-ethylmethylsulfamoyl group, N, N-diethylsulfamoyl group, N, N-propylmethylsulfamoyl group, N, N-dipropylsulfamoyl group Group, N, N-isopropylmethylsulfamoyl group, N, N-diisopropylsulfamoyl group, N, N-tert-butylmethylsulfamoyl group, N, N-diisobutylsulfamoyl group, N, N- Disec-butylsulfamoyl group, N, N-ditert-butylsulfamoyl group, N, N-butylmethylsulfamoyl group, N, N-dibutylsulfamoyl group, N, N-dipentylsulfa Moyl group, N, N-di (1-ethylpropyl) sulfamoyl group, N, N-dihexylsulfamoyl group, N, N-di (2-ethyl) hexyls Famoyl group, N, N-diheptylsulfamoyl group, N, N-octylmethylsulfamoyl group, N, N-dioctylsulfamoyl group, N, N-dinonylsulfamoyl group, N, N-decyl Methylsulfamoyl group, N, N-undecylmethylsulfamoyl group, N, N-dodecylmethylsulfamoyl group, N, N-icosylmethylsulfamoyl group, N, N-phenylmethylsulfamoyl Two hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group, N, N-diphenylsulfamoyl group, and the group represented by the above formula, or a derivatized group thereof ( For example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably octyl sulfamoyl) ^{_{) -SO 2 N (R 102Z2X)}} 2 ( provided that at sulfamoyl groups and compounds shown in Table 1Z2~ table 43Z2 substituted with derivatized groups) in such, except that R ^102Z2X is not a hydrogen atom, R in the compounds shown in Table 1 to 966 of the corresponding group and Japanese Patent Application No. 2017-016290 the same as is) and ^{_{102Z2 -SO 2 N (R 102Z2X)}} 2 ( where except that R ^102Z2X is not a hydrogen atom, The same as R ^102Z2 ), and the like.
Preferably, it corresponds to —SO ₂ N (R ^102Z2 ) ₂ in one or two sulfamoyl groups substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof, and compounds shown in Tables 1Z2 to ^43Z2. Groups and the like.

^—CON (R ^102Z2 ) ₂ includes a carbamoyl group;
N-methylcarbamoyl group, N-ethylcarbamoyl group, N-propylcarbamoyl group, N-isopropylcarbamoyl group, N-butylcarbamoyl group, N-isobutylcarbamoyl group, N-sec-butylcarbamoyl group, N-tert-butylcarbamoyl Group, N-pentylcarbamoyl group, N- (1-ethylpropyl) carbamoyl group, N-hexylcarbamoyl group, N- (2-ethyl) hexylcarbamoyl group, N-heptylcarbamoyl group, N-octylcarbamoyl group, N- One of nonylcarbamoyl group, N-decylcarbamoyl group, N-undecylcarbamoyl group, N-dodecylcarbamoyl group, N-icosylcarbamoyl group, N-phenylcarbamoyl group, etc., and a group represented by the above formula 1 to 40 carbon atoms (preferably carbon 1-20) hydrocarbon group or derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably octyl) In the compounds shown in Tables 1Z2 to 43Z2, -CONH (R ^102Z2X ) (provided that R ^102Z2X does not become a hydrogen atom) -CONH the same in a) to the appropriate groups and compounds shown in Table 1 to 966 of Japanese Patent Application No. 2017-016290 and R ^102Z2 (R ^102Z2X) (where except that R ^102Z2X is not a hydrogen atom, R ^102Z2 And the like)
N, N-dimethylcarbamoyl group, N, N-ethylmethylcarbamoyl group, N, N-diethylcarbamoyl group, N, N-propylmethylcarbamoyl group, N, N-dipropylcarbamoyl group, N, N-isopropylmethylcarbamoyl Group, N, N-diisopropylcarbamoyl group, N, N-tert-butylmethylcarbamoyl group, N, N-diisobutylcarbamoyl group, N, N-disec-butylcarbamoyl group, N, N-ditert-butylcarbamoyl group N, N-butylmethylcarbamoyl group, N, N-dibutylcarbamoyl group, N, N-butyloctylcarbamoyl group, N, N-dipentylcarbamoyl group, N, N-di (1-ethylpropyl) carbamoyl group, N , N-dihexylcarbamoyl group, N, N-di (2-ethyl) hexyl Rucarbamoyl group, N, N-diheptylcarbamoyl group, N, N-octylmethylcarbamoyl group, N, N-dioctylcarbamoyl group, N, N-dinonylcarbamoyl group, N, N-decylmethylcarbamoyl group, N, N -Undecylmethylcarbamoyl group, N, N-dodecylmethylcarbamoyl group, N, N-icosylmethylcarbamoyl group, N, N-phenylmethylcarbamoyl group, N, N-diphenylcarbamoyl group, etc. Two hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group to be synthesized or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom) ), A C 1-10 alkylsulfamoyl group (preferably an octylsulfamoyl group), etc. Groups) -CON In the compounds shown in carbamoyl group and Tables 1Z2~ table 43Z2 substituted with (R ^102Z2X) ₂ (where except that R ^102Z2X is not a hydrogen atom, corresponding to the same in a) and R ^102Z2 And -CON ( ^R102Z2X ) ₂ (provided that ^R102Z2X is the same as ^R102Z2 except that it does not become a hydrogen atom) in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290 Groups, etc.
Preferably, one or two hydrocarbon groups having 1 to 10 carbon atoms or a carbamoyl group substituted with a derivatizing group thereof, or a group corresponding to ^—CON (R ^102Z2 ) ₂ in the compounds shown in Tables 1Z2 to ^43Z2 Is mentioned.

—N (R ^102Z2 ) ₂ is an amino group;
N-methylamino group, N-ethylamino group, N-propylamino group, N-isopropylamino group, N-butylamino group, N-isobutylamino group, N-sec-butylamino group, N-tert-butylamino Group, N-pentylamino group, N-hexylamino group, N- (2-ethyl) hexylamino group, N-heptylamino group, N-octylamino group, N-nonylamino group, N-decylamino group, N-un A decylamino group, an N-dodecylamino group, an N-icosylamino group, an N-phenylamino group, and the like, and one of 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group represented by the above formula A hydrocarbon group or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl group having 1 to 10 carbon atoms; -NH (R ^102Z2X) (provided that the amino group and Tables 1Z2~ Table 43Z2 compounds shown in substituted with Amoiru group (preferably octyl sulfamoyl group) were derivatized with such groups), R ^102Z2X a hydrogen atom do not except that become, in the compounds shown in Table 1 to 966 groups and Japanese Patent Application No. 2017-016290 corresponding to same in a) and R ^102Z2 -NH (R ^102Z2X) (provided that, R ^102Z2X is not a hydrogen atom Except for the ^above , the same as R ^102Z2 , etc.)

N, N-dimethylamino group, N, N-ethylmethylamino group, N, N-diethylamino group, N, N-propylmethylamino group, N, N-dipropylamino group, N, N-isopropylmethylamino group N, N-diisopropylamino group, N, N-tert-butylmethylamino group, N, N-diisobutylamino group, N, N-disec-butylamino group, N, N-ditert-butylamino group, N, N-butylmethylamino group, N, N-dibutylamino group, N, N-dipentylamino group, N, N-di (1-ethylpropyl) amino group, N, N-dihexylamino group, N, N -Di (2-ethyl) hexylamino group, N, N-diheptylamino group, N, N-dioctylamino group, N, N-dinonylamino group, N, N-decylmethylamino group, N, N- Ndecylmethylamino group, N, N-dodecylmethylamino group, N, N-icosylmethylamino group, N, N-phenylmethylamino group, N, N-diphenylamino group, etc., and the above formula Two hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom) -N (R) in the amino group substituted with an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably a group derivatized with an octylsulfamoyl group or the like) and the compounds shown in Tables 1Z2 to 43Z2. ^102Z2X) ₂ (where reduction except that R ^102Z2X is not a hydrogen atom, are shown in Table 1 to 966 groups and Japanese Patent Application No. 2017-016290 corresponding to same in a) and R ^102Z2 -N (R ^102Z2X) ₂ (provided that, R ^102Z2X, except that not a hydrogen atom, same as is the R ^102Z2) at the object and a group corresponding to the like,
Preferably, one or two hydrocarbon groups having 1 to 10 carbon atoms or an amino group substituted by a derivatizing group thereof, and a group corresponding to —N (R ^102Z2 ) ₂ in the compounds shown in Table 1Z2 to Table 43Z2 Is mentioned.

—NHCO—R ^102Z2 includes formylamino group; acetylamino group, propanoylamino group, butanoylamino group, 2,2-dimethylpropanoylamino group, pentanoylamino group, hexanoylamino group, (2-ethyl ) Hexanoylamino group, heptanoylamino group, octanoylamino group, nonanoylamino group, decanoylamino group, undecanoylamino group, dodecanoylamino group, heicosanoylamino group, benzoylamino group, etc. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group represented by the above formula or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably Is a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) In the case of a derivatized group) bonded to a carbonylamino group (an acylamino group the carbonyl amino group, -NHCO-R ^102Z2 in compound number of carbon atoms indicated in which) and Table 1Z2~ Table 43Z2 1 to 40 And groups corresponding to —NHCO—R ^102Z2 in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290, and the like.
Preferably a carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded (when the carbonylamino group is an alkanoylamino group, the carbon number is more preferably 1 to 10) and Table 1Z2 To groups corresponding to —NHCO—R ^102Z2 in the compounds shown in Table 43Z2.

-NHCON (R ^102Z2 ) ₂ includes the groups listed above and the groups corresponding to -NHCON (R ^102Z2 ) ₂ in the compounds shown in Tables 1Z2 to 43Z2, and Tables 1 to 966 of Japanese Patent Application No. 2017-016290. And a group corresponding to —NHCON (R ^102Z2 ) ₂ in the compound represented by

-NHCOOR ^102Z2 includes the groups listed above and the groups corresponding to -NHCOOR ^102Z2 in the compounds shown in Tables 1Z2 to 43Z2, and -NHCOOR 102Z2 in the compounds shown in Tables 1 to ⁹⁶⁶ of Japanese Patent Application No. ^2017-016290. And the like group.

^{Examples of} —OCON (R ^102Z2 ) ₂ include groups listed above, groups corresponding to —OCON (R ^102Z2 ) ₂ in the compounds shown in Tables 1Z2 to 43Z2, and Tables 1 to 966 of Japanese Patent Application No. 2017-016290. And a group corresponding to —OCON (R ^102Z2 ) ₂ in the compound represented by

As the halogen atom, a fluorine atom, a chlorine atom, a bromine atom and an iodine atom are preferable.
Examples of M in —SO ₃ M and —CO ₂ M include a hydrogen atom; an alkali metal atom such as a lithium atom, a sodium atom and a potassium atom, preferably a hydrogen atom, a sodium atom and a potassium atom.

The ^{-CO-R 102Z2, -COO-R} 102Z2, -OCO-R 102Z2, -COCO-R 102Z2, -O-R 102Z2, -SO 2 -R 102Z2, -SO 2 N (R 102Z2) 2, -CON ^{Substituents contained in} ( ^R102Z2 ) ₂ , -N ( ^R102Z2 ) ₂ , -NHCO- ^R102Z2 , -NHCON ( ^R102Z2 ) ₂ , ^-NHCOOR102Z2 , -OCON ( ^R102Z2 ) ₂ (first substituent) May be one or more, and the two or more substituents may be the same or different independently of each other.
Further, the first substituent may have another substituent (second substituent) bonded to a hydrocarbon group contained in a part thereof. The second substituent can be selected from the same groups as the first substituent.

Ring R ^2Z2 and R ^3Z2, R ^3Z2 and R ^4Z2, and the R ^4Z2 and R ^5Z2 form is condensed with the benzene ring of the isoindoline skeleton of the compound represented by the formula (Iz2). The fused ring structure of R ^2Z2 and R ^3Z2, R ^3Z2 and R ^4Z2, and the ring R ^4Z2 and R ^5Z2 form said benzene ring, indene, naphthalene, biphenylene, indacene, acenaphthylene, fluorene, phenalene, phenanthrene, Hydrocarbon condensed ring structures such as anthracene, fluoranthene, acephenanthrylene, aceanthrylene, triphenylene, pyrene, chrysene, N-methylphthalimide, N- (1-phenylethyl) phthalimide and tetracene, and their partially reduced forms ( For example, 9,10-dihydroanthracene, 1,2,3,4-tetrahydronaphthalene, etc.); indole, isoindole, indazole, quinoline, isoquinoline, phthalazine, quinoxaline, quinazoline, cinnoline, carbazole, carboline, phenant Jin, acridine, perimidine, nitrogen-containing condensed heterocyclic, and parts thereof reductant such as phenanthroline and phenazine; 3- oxygen-containing condensed such tetrahydrobenzo furan-2-one heterocyclic ring and its partially reduced products thereof.

If R ^2Z2 and R ^3Z2, R ^3Z2 and R ^4Z2, and the R ^4Z2 and R ^5Z2 form a ring, the ring may have a substituent. Examples of the ^{substituent, R O1Z2, R N1Z2, R} N2Z2, R 1Z2, R 2Z2, R 3Z2, R 4Z2, R 5Z2, which may have a hydrocarbon group represented by R ^101Z2 and R ^102Z2 substituted The same thing as a group is mentioned. Preferred examples of the substituent, and ^{R O1Z2, R N1Z2, R N2Z2} , R 1Z2, R 2Z2, R 3Z2, R 4Z2, R 5Z2, have a hydrocarbon group represented by R ^101Z2 and R ^102Z2 Examples of the preferred substituents are the same.

If R ^3Z2 and R ^4Z2 form a ring, the R ^2Z2 and R ^5Z2, independently of one another, a hydrogen atom is preferably an amino group and hydroxy group.
If R ^2Z2 and R ^3Z2 form a ring, R ^4Z2 and R ^5Z2 is preferably not form a ring, and more preferably R ^4Z2 and R ^5Z2 is a hydrogen atom.
In the case where R ^4Z2 and R ^5Z2 form a ring, R ^2Z2 and R ^3Z2 is preferably not form a ring, and more preferably R ^2Z2 and R ^3Z2 is a hydrogen atom.

R ^1Z2 is preferably a hydrogen atom.

R ^O1Z2 is preferably a hydrogen atom or a hydrocarbon group having 1 to 30 carbon atoms which may have a substituent, and a carbon atom having 1 to 20 carbon atoms which may have a hydrogen atom or a substituent. It is more preferably a hydrogen group, more preferably a hydrogen atom or a hydrocarbon group having 1 to 15 carbon atoms which may have a substituent, and a carbon which may have a hydrogen atom or a substituent. It is particularly preferably a hydrocarbon group having 1 to 10 carbon atoms, and a hydrocarbon group having 1 to 6 carbon atoms which may have a hydrogen atom or a substituent or 1 to 1 carbon atoms which may have a substituent. 5 is more particularly preferred, a hydrogen atom, a methyl group, an ethyl group or a phenyl group is particularly preferred, and a hydrogen atom, a methyl group or an ethyl group is most preferred.
R ^N1Z2 and R ^N2Z2 is hydrogen ^{atom, -CO-R 102Z2, -COO-} R 101Z2, -CON (R 102Z2) 2, -N (R 102Z2) 2, have a -CO ₂ M or a substituent It is preferably a hydrocarbon group having 1 to 40 carbon atoms, more preferably a hydrogen atom or a hydrocarbon group having 1 to 30 carbon atoms which may have a substituent, and a hydrogen atom or substituent. It is more preferably a hydrocarbon group having 1 to 20 carbon atoms which may have a hydrogen atom, and particularly preferably a hydrocarbon group having 1 to 15 carbon atoms which may have a hydrogen atom or a substituent. More preferably a hydrocarbon group having 1 to 10 carbon atoms which may have a hydrogen atom or a substituent, and a hydrocarbon having 1 to 6 carbon atoms which may have a hydrogen atom or a substituent Carbon having 1 to 5 carbons which may have a group or a substituent Particularly preferably a hydrogen group, a hydrogen atom, a methyl group, an ethyl group or more especially preferably a phenyl group, a hydrogen atom, and most preferably a methyl group or an ethyl group,. R ^N1Z2 and R ^N2Z2 may be the same group or different groups, but are preferably the same group.

From the viewpoint of the phase difference value of the color filter formed from the colored composition is ^{reduced, R 2Z2, R 2Z2, R} 3Z2, at least one of R ^4Z2, R ^{5Z2 is, -CO-R 102Z2, -COO-} R ^{101Z2, -OCO-R 102Z2, -COCO} -R 102Z2, -O-R 102Z2, -SO 2 -R 101Z2, -SO 2 N (R 102Z2) 2, -CON (R 102Z2) 2, -N (R 102Z2 ^{_{) 2, -NHCO-R 102Z2,}} -NHCO-N (R 102Z2) 2, -NHCOOR 102Z2, -OCON (R 102Z2) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , It is preferably a C1-C40 hydrocarbon group which may have a substituent or a heterocyclic group which may have a substituent,
A hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a halogen atom, —N (R ^102Z2 ) ₂ , a nitro group, or a hydrogen atom in which all or part of the hydrogen atom is substituted with a fluorine atom. More preferably, it is 20 hydrocarbon groups, —NHCO—R ^102Z2 , —O—R ^102Z2 , —SO ₃ M or —CO ₂ M,
It is more preferable that it is a C1-C40 hydrocarbon group which may have a nitro group or a substituent, and it is still more preferable that it is a nitro group or a tert-butyl group. Or, R ^2Z2 and R ^3Z2, R ^3Z2 and R ^4Z2, or R ^4Z2 and at least one pair of R ^5Z2 is, it is preferable to form a ring.

From the viewpoint of the phase difference value of the color filter formed from the colored composition is ^{reduced, R 2Z2, R 2Z2, R} 3Z2, R 4Z2, at least one of R ^5Z2 is carbon atoms, which may have a substituent A hydrocarbon group having 1 to 40 carbon atoms, a halogen atom, -N (R ^102Z2 ) ₂ , a nitro group, a hydrocarbon group having 1 to 20 carbon atoms in which all or part of the hydrogen atoms are substituted with fluorine atoms, -NHCO-R ^102Z2 , —O—R ^102Z2 , —SO ₃ M or —CO ₂ M, more preferably a nitro group or a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, More preferably, it is a nitro group or a tert-butyl group. Among them, either R ^2Z2 R ^3Z2 is a nitro group or a tert- butyl group, R ^4Z2 and R ^5Z2 is a hydrogen atom, or an R ^2Z2, R ^3Z2 and R ^5Z2 is a hydrogen atom R ^4Z2 nitro Even more preferred is a group or a tert-butyl group.

  The compound (IZ2) is preferably a compound represented by the formula (IZ2-B) (hereinafter sometimes referred to as the compound (IZ2-B)). When the compound (IZ2) is the compound (IZ2-B), the retardation value of the color filter formed from the colored composition containing the compound (IZ2-B) becomes smaller.

[In the formula (IZ2-B),
R ^CO11Z2 and R ^CO21Z2 each independently represent —O—R ^O1Z2 or —NR ^N1Z2 R ^N2Z2 , and at least one of R ^CO11Z2 and R ^CO21Z2 is —NR ^N1Z2 R ^N2Z2 .
R ^N1Z2 , R ^N2Z2 , R ^1Z2 , R ^21Z2 , R ^31Z2 , R ^41Z2 , R ^51Z2 are each independently a hydrogen atom, —CO—R ^102Z2 , —COO—R ^101Z2 , —OCO—R ^102Z2 , —COCO— ^{R 102Z2, -O-R 102Z2,} -SO 2 -R 101Z2, -SO 2 N (R 102Z2) 2, -CON (R 102Z2) 2, -N (R 102Z2) 2, -NHCO-R 102Z2, -NHCO _{^{-N (R 102Z2) 2, -NHCOOR}} 102Z2, -OCON (R 102Z2) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , the number of carbon atoms which may have a substituent 1 to 40 hydrocarbon groups or heterocyclic groups which may have a substituent, R ^21Z2 and R ^31Z2 , R ^31Z2 and R ^41Z2 , and R ^41Z2 and R ^51Z2 are bonded to each other to form a ring. it may be formed, at least one of R ^21Z2, R ^31Z2, R ^41Z2 and R ^51Z2 is, -CO-R ^102Z2, -C ^{O-R 101Z2, -OCO-R} 102Z2, -COCO-R 102Z2, -O-R 102Z2, -SO 2 -R 101Z2, -SO 2 N (R 102Z2) 2, -CON (R 102Z2) 2, -N _{^{(R 102Z2) 2, -NHCO-}} R 102Z2, -NHCO-N (R 102Z2) 2, -NHCOOR 102Z2, -OCON (R 102Z2) 2, halogen atom, a cyano group, a nitro group, -SO ₃ M, -CO ₂ M, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent, or R ^21Z2 and R ^31Z2 , R ^31Z2 and R ^41Z2 , ^And at least one pair of R ^41Z2 and R ^51Z2 is bonded to form a ring.
R ^101Z2 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^O1Z2 and R ^102Z2 each independently represent a hydrogen atom, an ^optionally substituted hydrocarbon group having 1 to 40 carbon atoms, or an ^optionally substituted heterocyclic group.
M represents a hydrogen atom or an alkali metal atom.
When there are a plurality of R ^O1Z2 , R ^N1Z2 , R ^N2Z2 , R ^101Z2 , R ^102Z2 and M, they may be the same or different.
A wavy line represents an E body or a Z body. ]

Wherein ^{(IZ2-B), R CO11Z2} , CO21Z2, R 21Z2, R 31Z2, as the R ^41Z2 and R ^51Z2, R ^CO1Z2 in formula ^{(IZ2), CO2Z2, R 2Z2} , R 3Z2, R 4Z2, and R ^5Z2 The same thing is mentioned.

Wherein (IZ2-B), preferred ^{R CO11Z2, CO21Z2, R 21Z2,} R 31Z2, as the R ^41Z2 and R ^51Z2, R ^CO1Z2 in formula ^{(IZ2), CO2Z2, R 2Z2} , R 3Z2, R 4Z2, and R ^The same thing as the preferable thing of ^5Z2 is mentioned.

From the viewpoint of ease of synthesis, in the formula (IZ2-B), R ^1Z2 is preferably a hydrogen atom.

In the formula (IZ2-B),
R ^O1Z2 is preferably a hydrogen atom or a hydrocarbon group having 1 to 30 carbon atoms which may have a substituent, and a carbon atom having 1 to 20 carbon atoms which may have a hydrogen atom or a substituent. It is more preferably a hydrogen group, more preferably a hydrogen atom or a hydrocarbon group having 1 to 15 carbon atoms which may have a substituent, and a carbon which may have a hydrogen atom or a substituent. It is particularly preferably a hydrocarbon group having 1 to 10 carbon atoms, and a hydrocarbon group having 1 to 6 carbon atoms which may have a hydrogen atom or a substituent or 1 to 1 carbon atoms which may have a substituent. 5 is particularly preferable, a hydrogen atom, a methyl group, an ethyl group, or a phenyl group is particularly preferable, and a hydrogen atom, a methyl group, or an ethyl group is most preferable.
R ^N1Z2 and R ^N2Z2 is hydrogen ^{atom, -CO-R 102Z2, -COO-} R 101Z2, -CON (R 102Z2) 2, -N (R 102Z2) 2, have a -CO ₂ M or a substituent It is preferably a hydrocarbon group having 1 to 40 carbon atoms, more preferably a hydrogen atom or an optionally substituted hydrocarbon group having 1 to 30 carbon atoms, a hydrogen atom or a substituent. It is more preferably a hydrocarbon group having 1 to 20 carbon atoms which may have a hydrogen atom, and particularly preferably a hydrocarbon group having 1 to 15 carbon atoms which may have a hydrogen atom or a substituent. More preferably a hydrocarbon group having 1 to 10 carbon atoms which may have a hydrogen atom or a substituent, and a hydrocarbon having 1 to 6 carbon atoms which may have a hydrogen atom or a substituent C1-C5 which may have a group or a substituent Particularly preferably a hydrocarbon group, a hydrogen atom, a methyl group, an ethyl group or more especially preferably a phenyl group, a hydrogen atom, and most preferably a methyl group or an ethyl group,. R ^N1Z2 and R ^N2Z2 may be the same group or different groups, but are preferably the same group.

From the viewpoint of reducing the retardation value of the color filter formed from the colored composition, at least one of R ^21Z2 , R ^31Z2 , R ^41Z2 and R ^51Z2 has a substituent in the formula (IZ2-B). An ^optionally substituted hydrocarbon group having 1 to 40 carbon atoms, a halogen atom, —N (R ^102Z2 ) ₂ , a nitro group, a hydrocarbon group having 1 to 20 carbon atoms in which all or part of the hydrogen atoms are substituted with fluorine atoms, —NHCO—R ^102Z2 , —O—R ^102Z2 , —SO ₃ M or —CO ₂ M is preferable, and a hydrocarbon group having 1 to 40 carbon atoms which may have a nitro group or a substituent. More preferred is a nitro group or a tert-butyl group. Among them, R ^31Z2 is a nitro group or tert-butyl group and R ^21Z2 , R ^41Z2 and R ^51Z2 are hydrogen atoms, or R ^21Z2 , R ^31Z2 and R ^51Z2 are hydrogen atoms and R ^41Z2 is nitro. Even more preferred is a group or a tert-butyl group.

Specific examples of compound (IZ2) include, for example,
In formula (IaZ2), compounds (IaZ2-1) to (IaZ2-494) having the substituents shown in Table 1Z2 to Table 13Z2 or alkali metal salts thereof;
In the formula (IbZ2), the compounds (IbZ2-1) to (IbZ2-840) having the substituents shown in Table 14Z2 to Table 35Z2 or alkali metal salts thereof;
In formula (IcZ2), compounds (IcZ2-1) to (IcZ2-296) having a substituent shown in Table 36Z2 to Table 43Z2 or an alkali metal salt thereof can be used.
B ^a1Z2 B ^a2Z2 is the formula (BB1) to the formula (BB60), the formula (BBK2), the formula (BBK3), the formula (BBK4), the formula (BBK14), the formula (BBI1), the formula (BBO8), and the formula (BBO10). , Any partial structure represented by formula (BBD1) and formula (BBJ2). Formula (BB1) to Formula (BB60), Formula (BBK2), Formula (BBK3), Formula (BBK4), Formula (BBK14), Formula (BBI1), Formula (BBO8), Formula (BBO10), Formula (BBD1) and Formula (BBJ2) represents B ^a1Z1 B ^a2Z1 of Formula (IZ1-aa), (BB1) to (BB60), Formula (BBK2), Formula (BBK3), Formula (BBK4), Formula (BBK14), Formula (BBI1) ), Formula (BBO8), formula (BBO10), formula (BBD1), and formula (BBJ2). B ^A1Z2 and B ^A2Z2 each represent a bond, B ^A1Z2 the expression (BB1) ~ formula (BB60), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1) , Formula (BBO8), formula (BBO10), formula (BBD1), and formula (BBJ2), when B ^{1 is} a bond, B ^a2Z2 is a bond of B ² , and B ^a1Z2 is a formula (BB1) to formula ( ^BB60 ). ), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1), formula (BBO8), formula (BBO10), formula (BBD1) and formula B ² of (BBJ2) When it is a bond, B ^a2Z2 is a bond of B ¹ .
B ^a1Z2 B ^a2Z2 includes formula (BB1), formula (BB6), formula (BB8), formula (BB11), formula (BB14), formula (BB19), formula (BB37), formula (BB58), formula (BBJ2) ), Formula (BBO8) and formula (BBO10) are preferred, and formula (BB1), formula (BB6) and formula (BB19) are more preferred.

Each symbol in Table 1Z2 to Table 43Z2 represents the following partial structure. In the partial structure,
“Me” represents a methyl group,
“Et” represents an ethyl group;
“Bu” represents a butyl group,
“TBu” represents a tert-butyl group,
“Hex” represents a hexyl group,
“Oct” represents an octyl group;
“2EH” represents a 2-ethylhexyl group;
“CHM” represents a cyclohexylmethyl group,
“CH” represents a cyclohexyl group,
“PH” represents a phenyl group;
“BZ” represents a benzyl group;
“NPR” represents a propyl group;
“IPR” represents an isopropyl group;
“IBu” represents an isobutyl group,
“EOE” represents —CH ₂ CH ₂ OCH ₂ CH ₃ ,
“ALL” represents an allyl group,
“HYE” represents a 2-hydroxyethyl group,
“COM” represents —CO—CH ₃ ;
“COE” represents —COO—CH ₂ CH ₃ ;
“CBA” represents —CO ₂ H;
“CBM” represents —CONH ₂ ;
“NH ₂ ” represents —NH ₂ .
In the partial structure represented by the following formula, * represents a bond.

  For example, the compound (IaZ2-1) is a compound represented by the formula (IaZ2-1).

Compound (IaZ2-1) to Compound (IaZ2-165), (IaZ2-223) to Compound (IaZ2-494), Compound (IbZ2-1) to Compound (IbZ2-248), Compound (IbZ2-311) to Compound (I) IbZ2-840), compound (IcZ2-1) to compound (IcZ2-234) are preferred,
Compound (IaZ2-1) to Compound (IaZ2-165), (IaZ2-223) to Compound (IaZ2-436), Compound (IbZ2-1) to Compound (IbZ2-248), Compound (IbZ2-311) to Compound (I) IbZ2-782), compound (IcZ2-1) to compound (IcZ2-234) are more preferred,
Compound (IaZ2-1) to Compound (IaZ2-165), Compound (IbZ2-1) to Compound (IbZ2-248), and Compound (IcZ2-1) to Compound (IcZ2-234) are more preferable.
Compound (IaZ2-1) to Compound (IaZ2-111), Compound (IbZ2-1) to Compound (IbZ2-248), and Compound (IcZ2-1) to Compound (IcZ2-234) are even more preferable.
Compound (IaZ2-1) to compound (IaZ2-54) and compound (IbZ2-1) to compound (IbZ2-186) are particularly preferred.

Specific examples of the compound (Iz2) is mentioned in the compounds represented in Table 1Z2~ Table 43Z2, also compounds -SO ₃ M or -CO ₂ M is substituted with 1-3 hydrogen atoms contained in the compound It is done. For example, a compound in which 1 to 3 sulfo groups are bonded to the compound (IaZ2-1) in Table 1Z2 is represented by the following structure. However, in the formula, — (SO ₃ H) means that any hydrogen atom of the compound (IaZ2-1) in Table 1Z2 is substituted.

Compound (IaZ2-1) to Compound (IaZ2-165), (IaZ2-223) to Compound (IaZ2-494), Compound (IbZ2-1) to Compound (IbZ2-248), Compound (IbZ2-311) to Compound (I) IbZ2-840), a compound in which 1 to 3 —SO ₃ M or —CO ₂ M is bonded to compound (IcZ2-1) to compound (IcZ2-234) are preferred,
Compound (IaZ2-1) to Compound (IaZ2-165), (IaZ2-223) to Compound (IaZ2-436), Compound (IbZ2-1) to Compound (IbZ2-248), Compound (IbZ2-311) to Compound (I) IbZ2-782), a compound in which 1 to 3 —SO ₃ M or —CO ₂ M is bonded to compound (IcZ2-1) to compound (IcZ2-234) are more preferable,
Compound (IaZ2-1) to Compound (IaZ2-165), Compound (IbZ2-1) to Compound (IbZ2-248), and Compound (IcZ2-1) to Compound (IcZ2-234) have 1 to 3 SO More preferred is a compound to which ₃ M or —CO ₂ M is bound,
Compound (IaZ2-1) to Compound (IaZ2-111), Compound (IbZ2-1) to Compound (IbZ2-248), and Compound (IcZ2-1) to Compound (IcZ2-234) have 1 to 3 SO Even more preferred are compounds to which ₃ M or —CO ₂ M is bound,
Compounds in which 1 to 3 —SO ₃ M or —CO ₂ M are bound to Compound (IaZ2-1) to Compound (IaZ2-54) and Compound (IbZ2-1) to Compound (IbZ2-186) are particularly preferable.

Examples of the compound to which —CO ₂ M is bonded include compound (IbZ2-2), compound (IbZ2-3), compound (IbZ2-4), compound (IbZ2-12), compound (IbZ2-126), and compound (IbZ2). -127), compound (IbZ2-687), compound (IbZ2-370) compound in which two -CO ₂ H is coupled to the like, in particular compound (IbZ2-317), compound (IbZ2-318), compound (IbZ2 -319), compound (IbZ2-320), compound (IbZ2-515), compound (IbZ2-516), compound (IbZ2-706), compound (IbZ2-389) and the like are particularly preferable.

As the compound (IZ2), in the formula (IZ2),
R ^CO1Z2 and R ^CO1Z2 are the same group,
R ^O1Z2 is a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M;
R ^N1Z2 and R ^N2Z2 are independently selected from the group consisting of a hydrogen atom, —CO—R ^102Z2 , —COO—R ^101Z2 , ^—CON (R ^102Z2 ) ₂ , or —SO ₃ M and —CO ₂ M. A hydrocarbon group having 1 to 20 carbon atoms that may have a substituent,
R ^1Z2 is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M, —SO ₃ M or —CO _2. M,
R ^{2Z2 to} R ^5Z2 are each independently a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogen atom, —N (R ^102Z2 ) ₂ , a nitro group, or a hydrogen atom, or a fluorine atom. A substituted hydrocarbon group having 1 to 20 carbon atoms, —NHCO—R ^102Z2 , —O—R ^102Z2 , —SO ₃ M or —CO ₂ M;
R ^102Z2 is a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M;
R ^101Z2 is a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M;
M is preferably a compound that is a hydrogen atom or an alkali metal atom,
R ^CO1Z2 and R ^CO1Z2 are the same group,
R ^O1Z2 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M;
R ^N1Z2 and R ^N2Z2 each independently have a hydrogen atom, —CO—R ^102Z2 , ^—CON (R ^102Z2 ) ₂ , or a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M. A hydrocarbon group having 1 to 10 carbon atoms,
R ^1Z2 is a hydrogen atom,
R ^{2Z2 to} R ^5Z2 are each independently a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, —N (R ^102Z2 ) ₂ , a nitro group, or a hydrogen atom, or a fluorine atom. A substituted hydrocarbon group having 1 to 10 carbon atoms, —NHCO—R ^102Z2 , —O—R ^102Z2 , —SO ₃ M or —CO ₂ M;
R ^102Z2 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M;
R ^101Z2 is a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M;
M is more preferably a compound that is a hydrogen atom or an alkali metal atom,
R ^CO1Z2 and R ^CO1Z2 are the same group,
R ^O1Z2 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M;
R ^N1Z2 and R ^N2Z2 each independently have a hydrogen atom, —CO—R ^102Z2 , ^—CON (R ^102Z2 ) ₂ , or a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M. A hydrocarbon group having 1 to 10 carbon atoms,
R ^1Z2 is a hydrogen atom,
R ^{2Z2 to} R ^5Z2 are each independently a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, —N (R ^102Z2 ) ₂ , a nitro group, a trifluoromethyl group, —O—R ^102Z2 , a -SO ₃ M or -CO ₂ M,
R ^102Z2 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M;
R ^101Z2 is a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M;
A compound in which M is a hydrogen atom or an alkali metal atom is more preferable.

In the compound (IZ2), when R ^1Z2 is a hydrogen atom, a compound represented by the formula (pt1Z2) (hereinafter sometimes referred to as a phthalonitrile compound) is represented by a compound represented by the formula (pt2Z2) (hereinafter referred to as an alkoxide compound). In some cases, the compound represented by the formula (pt3Z2) and the compound represented by the formula (pt4Z2) can be further reacted in the presence of an acid. When R ^1Z2 is other than a hydrogen atom, the compound (IZ2) can be produced by further reacting with a compound represented by the formula (pt5Z2).

Expression (pt1Z2), formula (pt2Z2), formula (pt3Z2), formula (pt4Z2), wherein (pt5Z2) and formula ^{(IZ2), R CO1Z2, R} CO2Z2, R 1Z2, R 2Z2, R 3Z2, R 4Z2, And R ^5Z2 represents the same meaning as described above.
R ^14Z2 represents an alkyl group having 1 to 20 carbon atoms.
M ^1Z2 represents an alkali metal atom.
LG represents a halogen atom, a methanesulfonyloxy group, a toluenesulfonyloxy group, or a trifluoromethanesulfonyloxy group. ]

^Examples of the alkyl group having 1 to 20 carbon atoms represented by R ^14Z2 include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, a sec-butyl group, and a tert-butyl group. Is an alkyl group having 1 to 6 carbon atoms.
^Examples of the alkali metal atom represented by M ^1Z2 include a lithium atom, a sodium atom, and a potassium atom.

  The amount of the alkoxide compound used is usually 0.1 to 10 mol, preferably 0.2 to 5 mol, more preferably 0.3 to 3 mol, relative to 1 mol of the phthalonitrile compound. More preferably, it is 0.4-2 mol.

The amount of compound (pt3Z2) to be used is generally 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, further preferably 1 to 1 mol of phthalonitrile compound. ~ 2 moles.
The amount of compound (pt4Z2) to be used is generally 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, further preferably 1 to 1 mol of phthalonitrile compound. ~ 2 moles.

Examples of the acid include inorganic acids such as hydrochloric acid, hydrobromic acid, hydroiodic acid, sulfuric acid, nitric acid, fluorosulfonic acid and phosphoric acid; sulfonic acids such as methanesulfonic acid, trifluoromethanesulfonic acid and p-toluenesulfonic acid; Examples thereof include carboxylic acids such as acetic acid, citric acid, formic acid, gluconic acid, lactic acid, oxalic acid and tartaric acid, and preferably hydrochloric acid, hydrobromic acid, sulfuric acid, methanesulfonic acid, trifluoromethanesulfonic acid, p-toluenesulfonic acid and A carboxylic acid is mentioned, More preferably, an acetic acid is mentioned.
The usage-amount of an acid is 1-20 mol normally with respect to 1 mol of phthalonitrile compounds, Preferably it is 1-10 mol, More preferably, it is 1-8 mol, More preferably, it is 1-6 mol. is there.

The reaction of a phthalonitrile compound, an alkoxide compound, a compound (pt3Z2) and a compound (pt4Z2) is usually performed in the presence of a solvent.
Solvents include water; nitrile solvents such as acetonitrile; alcohol solvents such as methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol and 1-octanol; ether solvents such as tetrahydrofuran; ketone solvents such as acetone; Ester solvents such as ethyl; aliphatic hydrocarbon solvents such as hexane; aromatic hydrocarbon solvents such as toluene; halogenated hydrocarbon solvents such as methylene chloride and chloroform; amides such as N, N-dimethylformaldehyde and N-methylpyrrolidone Solvent: Sulfoxide solvents such as dimethyl sulfoxide are mentioned, preferably water, nitrile solvent, alcohol solvent, ether solvent, ketone solvent, ester solvent, aromatic hydrocarbon solvent, halogenated hydrocarbon solvent, amide solvent and sulfoxide solvent. And More preferably, water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, tetrahydrofuran, acetone, ethyl acetate, toluene, methylene chloride, chloroform, N, N-dimethylformaldehyde, N -Methylpyrrolidone and dimethyl sulfoxide are mentioned, More preferably, water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, acetone, methylene chloride, chloroform, N, N-dimethyl Examples include formaldehyde, N-methylpyrrolidone and dimethyl sulfoxide, with water, acetonitrile, methanol, ethanol and 2-propanol being particularly preferred.
The usage-amount of a solvent is 1-1000 mass parts normally with respect to 1 mass part of phthalonitrile compounds.

  The reaction temperature is usually 0 to 200 ° C, preferably 0 to 100 ° C, more preferably 0 to 70 ° C, and further preferably 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

The amount of compound (pt5Z2) to be used is generally 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, per 1 mol of compound (IZ2) in which R ^1Z2 is a hydrogen atom. More preferably, it is 1-2 mol.

  Moreover, when making a compound (pt5Z2) react, it is preferable that a base coexists. Examples of the base include organic bases such as triethylamine, 4- (N, N-dimethylamino) pyridine, pyridine and piperidine; metal alkoxides such as sodium methoxide, sodium ethoxide, sodium tert-butoxide and potassium tert-butoxide; butyllithium Organic metal compounds such as tert-butyl lithium and phenyl lithium; inorganic bases such as lithium hydroxide, sodium hydroxide and potassium hydroxide.

The amount of the base to be used is generally 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, per 1 mol of compound (IZ2) in which R ^1Z2 is a hydrogen atom. Preferably it is 1-2 mol.

The reaction of the compound (pt5Z2) is usually performed in the presence of a solvent. The solvent can be selected from the same range as described above.
The usage-amount of a solvent is ^1-1000 mass parts normally with respect to 1 mass part of compounds (IZ2) whose R ^<1ZZ2> is a hydrogen atom. The reaction temperature of the compound (pt5Z2) is usually -90 to 200 ° C, preferably -80 to 100 ° C, more preferably 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

When the compound (IZ2) does not have a sulfo group or —SO ₃ M ²² , the compound (IZ2) is reacted with a sulfonating agent such as fuming sulfuric acid or chlorosulfonic acid to thereby form a sulfo group or —SO ₃ M ^22. Can be introduced.
M ²² represents an alkali metal atom.
Examples of the alkali metal atom represented by M ²² include a lithium atom, a sodium atom, and a potassium atom.

The amount of SO ₃ in the oleum, the compound (Iz2) relative to 1 mol, usually 1 to 50 moles, preferably from 5 to 40 moles, more preferably from 5 to 30 moles, more preferably 5 to 25 mol.
The usage-amount of the sulfuric acid in fuming sulfuric acid is 1-200 mol normally with respect to 1 mol of compounds (IZ2), Preferably it is 10-100 mol, More preferably, it is 10-75 mol, More preferably, it is 10 ~ 50 moles.

  The amount of chlorosulfonic acid to be used is generally 1 to 500 mol, preferably 10 to 300 mol, more preferably 10 to 200 mol, further preferably 10 to 150 mol, per 1 mol of compound (IZ2). Is a mole.

  The reaction temperature of the sulfonation is usually from -20 to 200 ° C, preferably from -10 to 100 ° C, more preferably from 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

  The method for taking out the compound (IZ2) from the reaction mixture is not particularly limited, and it can be taken out by various known methods. For example, after completion of the reaction, the compound (IZ2) can be removed by filtering the reaction mixture. Further, after filtration, the obtained residue may be subjected to column chromatography or recrystallization. Further, after completion of the reaction, the solvent of the reaction mixture may be distilled off and purified by column chromatography.

<Compound (IZ3)>
Compound (IZ3) is a compound represented by Formula (IZ3).

[In the formula (IZ3),
R ^1Z3 , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , and R ^7Z3 are each independently a hydrogen atom, —CO—R ^102Z3 , —COO—R ^101Z3 , —OCO—R ^102Z3 , —COCO ^{-R 102Z3, -O-R 102Z3,} -SO 2 -R 101Z3, -SO 2 N (R 102Z3) 2, -CON (R 102Z3) 2, -N (R 102Z3) 2, -NHCO-R 102Z3, - _{^{NHCO-N (R 102Z3) 2}} , -NHCOOR 102Z3, -OCON (R 102Z3) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , carbon atoms, which may have a substituent The heterocyclic group which may have a hydrocarbon group or a substituent of number 1-40 is represented.
R ^2Z3 and R ^3Z3 , R ^3Z3 and R ^4Z3 , and R ^4Z3 and R ^5Z3 may be bonded to each other to form a ring.
R ^101Z3 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102Z3 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
M represents a hydrogen atom or an alkali metal atom.
When a plurality of R ^101Z3 , R ^102Z3 and M are present, they may be the same or different.
A wavy line represents an E body or a Z body. ]

The hydrocarbon group represented by R ^1Z3 , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^102Z3 has 1 to 40 carbon atoms, preferably 1 to 30 carbon atoms. Yes, more preferably 1-20, still more preferably 1-15, and particularly preferably 1-10.

The hydrocarbon group having 1 to 40 carbon atoms represented by R ^1Z3 , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^102Z3 is an aliphatic hydrocarbon group and an aromatic carbon group. It may be a hydrogen group, and the aliphatic hydrocarbon group may be saturated or unsaturated, and may be a chain or an alicyclic ring.

The saturated or unsaturated chain hydrocarbon groups represented by R ^1Z3 , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^102Z3 include methyl group, ethyl group, propyl group , Butyl group, pentyl group, hexyl group, heptyl group, octyl group, nonyl group, decyl group, undecyl group, dodecyl group, heptadecyl group, octadecyl group, icosyl group and the like linear alkyl group, etc .; isopropyl group, isobutyl Group, sec-butyl group, tert-butyl group, (2-ethyl) butyl group, isopentyl group, neopentyl group, tert-pentyl group, (1-methyl) pentyl group, (2-methyl) pentyl group, (1- Ethyl) pentyl group, (3-ethyl) pentyl group, isohexyl group, (5-methyl) hexyl group, (2-ethyl) hexyl group and (3-ethyl) heptyl group Branched chain alkyl group, etc .; vinyl group, 1-propenyl group, 2-propenyl group (allyl group), (1-methyl) ethenyl group, 2-butenyl group, 3-butenyl group, 1,3-butadienyl group , (1- (2-propenyl)) ethenyl group, (1,2-dimethyl) propenyl group and alkenyl group such as 2-pentenyl group; and the like. The carbon number of the saturated or unsaturated chain hydrocarbon group is preferably 1 to 30, more preferably 1 to 20, still more preferably 1 to 15, particularly preferably 1 to 10, More preferably, it is 1-8, More preferably, it is 1-5. Especially, it is especially preferable that it is a C1-C10, More preferably, it is a C1-C8 linear or branched alkyl group, and a methyl group, an ethyl group, and a tert- butyl group are especially preferable.

Saturated or unsaturated alicyclic hydrocarbon groups represented by R ^1Z3 , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^102Z3 include cyclopropyl group, 1-methyl Cyclopropyl group, cyclobutyl group, cyclopentyl group, cyclohexyl group, cycloheptyl group, 1-methylcyclohexyl group, 2-methylcyclohexyl group, 3-methylcyclohexyl group, 4-methylcyclohexyl group, 1,2-dimethylcyclohexyl group, 1 , 3-dimethylcyclohexyl group, 1,4-dimethylcyclohexyl group, 2,3-dimethylcyclohexyl group, 2,4-dimethylcyclohexyl group, 2,5-dimethylcyclohexyl group, 2,6-dimethylcyclohexyl group, 3,4 -Dimethylcyclohexyl group, 3,5-dimethylcyclohexyl group, 2,2-dimethyl Cyclohexyl group, 3,3-dimethylcyclohexyl group, 4,4-dimethylcyclohexyl group, cyclooctyl group, 2,4,6-trimethylcyclohexyl group, 2,2,6,6-tetramethylcyclohexyl group and 3,3,3 A cycloalkyl group such as a 5,5-tetramethylcyclohexyl group, a 4-pentylcyclohexyl group, a 4-octylcyclohexyl group, a 4-cyclohexylcyclohexyl group; a cyclohexenyl group (for example, cyclohex-2-ene, cyclohex-3-ene), And cycloalkenyl groups such as cycloheptenyl and cyclooctenyl; norbornane, adamantyl, bicyclo [2.2.2] octane and the like. The carbon number of the saturated or unsaturated alicyclic hydrocarbon group is preferably 3 to 30, more preferably 3 to 20, still more preferably 4 to 20, and still more preferably 4 to 15. More preferably 5 to 15 and most preferably 5 to 10. Of these, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, and a cyclooctyl group are particularly preferable.

The aromatic hydrocarbon groups represented by R ^1Z3 , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^102Z3 include a phenyl group, an o-tolyl group, and an m-tolyl group. P-tolyl group, 2-ethylphenyl group, 3-ethylphenyl group, 4-ethylphenyl group, 2,3-dimethylphenyl group, 2,4-dimethylphenyl group, 2,5-dimethylphenyl group, 2, 6-dimethylphenyl group, 3,4-dimethylphenyl group, 3,5-dimethylphenyl group, 4-vinylphenyl group, o-isopropylphenyl group, m-isopropylphenyl group, p-isopropylphenyl group, o-tert- Butylphenyl group, m-tert-butylphenyl group, p-tert-butylphenyl group, mesityl group, 4-ethylphenyl group, 4-butylphenyl group, 4-pentylphenol Group, 2,6-bis (2-propyl) phenyl group, 4-cyclohexylphenyl group, 2,4,6-trimethylphenyl group, 4-octylphenyl group, 1-naphthyl group, 2-naphthyl group, 5, Aromatic hydrocarbon groups such as 6,7,8-tetrahydro-1-naphthyl group, 5,6,7,8-tetrahydro-2-naphthyl group, fluorenyl group, phenanthryl group and anthryl group, pyrenyl group; It is done. The number of carbon atoms of the aromatic hydrocarbon group is preferably 6-30, more preferably 6-20, and even more preferably 6-15.

The hydrocarbon groups represented by R ^1Z3 , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^102Z3 are the hydrocarbon groups mentioned above (for example, aromatic hydrocarbon groups and , At least one of a chain hydrocarbon group and an alicyclic hydrocarbon group), an aralkyl group such as a benzyl group, a phenethyl group, or a 1-methyl-1-phenylethyl group; An arylalkenyl group such as a phenyl group (phenylvinyl group); an arylalkynyl group such as a phenylethynyl group; a phenyl group to which one or more phenyl groups such as a biphenylyl group or a terphenylyl group are bonded; a cyclohexylmethylphenyl group, a benzylphenyl group; (Dimethyl (phenyl) methyl) phenyl group etc. are mentioned.
The groups represented by R ^1Z3 , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^102Z3 are the hydrocarbon groups mentioned above (for example, chain hydrocarbon groups and alicyclic rings). As the group in combination with the formula (hydrocarbon group), for example, cyclopropylmethyl group, cyclopropylethyl group, cyclobutylmethyl group, cyclobutylethyl group, cyclopentylmethyl group, cyclopentylethyl group, cyclohexylmethyl group, 2-methylcyclohexylmethyl It may be an alkyl group to which one or more alicyclic hydrocarbon groups such as a group, a cyclohexylethyl group, an adamantylmethyl group and the like are bonded.
These carbon numbers are preferably 4-30, more preferably 6-30, still more preferably 6-20, and preferably 4-20, more preferably 4-15. Especially preferably, it is 6-15.

The hydrocarbon groups represented by R ^1Z3 , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^102Z3 may have a substituent. The substituent may be monovalent or divalent. In the divalent substituent, two bonds are preferably bonded to the same carbon atom to form a double bond.
As the monovalent substituent,
Methoxy group, ethoxy group, propoxy group, isopropoxy group, butoxy group, isobutoxy group, sec-butoxy group, tert-butoxy group, pentyloxy group, hexyloxy group, (2-ethyl) hexyloxy group, heptyloxy group, Octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, dodecyloxy group, (2-ethyl) hexyloxy group, icosyloxy group, 1-phenylethoxy group, 1-methyl-1-phenylethoxy group, phenyloxy group O-Tolyloxy group, 2,3-dimethylphenyloxy group, 2,4-dimethylphenyloxy group, 2,5-dimethylphenyloxy group, 2,6-dimethylphenyloxy group, 3,4-dimethylphenyloxy group 3,5-dimethylphenyloxy group, 2,2-dicia Phenyloxy group, 2,3-dicyanophenyloxy group, 2,4-dicyanophenyloxy group, 2,5-dicyanophenyloxy group, 2,6-dicyanophenyloxy group, 3,4-dicyanophenyloxy group, 3 , 5-dicyanophenyloxy group, 4-methoxyphenyloxy group, 2-methoxyphenyloxy group, 3-methoxyphenyloxy group, 4-ethoxyphenyloxy group, 2-ethoxyphenyloxy group, 3-ethoxyphenyloxy group, etc. And a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group represented by the following formula or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen) (Preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl) Oxy group derivatized group) is bonded to one side the like);

  Methylthio, ethylthio, propylthio, butylthio, tert-butylthio, pentylthio, hexylthio, (2-ethyl) hexylthio, heptylthio, octylthio, nonylthio, decylthio, undecylthio, dodecylthio, icosylthio A sulfanyl group to which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group, a phenylthio group and an o-tolylthio group is bonded;

Epoxy group, oxetanyl group, tetrahydrofuryl group, tetrahydropyranyl group;
Formyl group;
Acetyl group, propanoyl group, butanoyl group, 2,2-dimethylpropanoyl group, pentanoyl group, hexanoyl group, (2-ethyl) hexanoyl group, heptanoyl group, octanoyl group, nonanoyl group, decanoyl group, undecanoyl group, dodecanoyl group, A hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 11 carbon atoms) or a derivatized group thereof (for example, a carboxy group or a sulfo group) such as a henicosanoyl group, a benzoyl group, or a group represented by the following formula: , A carbonyl group to which a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), a group derived from an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. When the carbonyl group is an alkanoyl group, the carbon number is preferably 2 to 12);

  Methoxycarbonyl group, ethoxycarbonyl group, propoxycarbonyl group, butoxycarbonyl group, tert-butoxycarbonyl group, pentyloxycarbonyl group, hexyloxycarbonyl group, (2-ethyl) hexyloxycarbonyl group, heptyloxycarbonyl group, octyloxycarbonyl Group, nonyloxycarbonyl group, decyloxycarbonyl group, undecyloxycarbonyl group, dodecyloxycarbonyl group, icosyloxycarbonyl group, phenyloxycarbonyl group, o-tolyloxycarbonyl group and the like, and the following formulas A hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon number 10 oxycarbonyl group alkylsulfamoyl group (preferably octyl sulfamoyl group) were derivatized with such groups) is bonded to;

An amino group;
N-methylamino group, N, N-dimethylamino group, N-ethylamino group, N, N-diethylamino group, N-propylamino group, N, N-dipropylamino group, N-isopropylamino group, N, N-diisopropylamino group, N-butylamino group, N, N-dibutylamino group, N-isobutylamino group, N, N-diisobutylamino group, N-sec-butylamino group, N, N-disec-butyl Amino group, N-tert-butylamino group, N, N-ditert-butylamino group, N-pentylamino group, N, N-dipentylamino group, N- (1-ethylpropyl) amino group, N, N -Di (1-ethylpropyl) amino group, N-hexylamino group, N, N-dihexylamino group, N- (2-ethyl) hexylamino group, N, N-di (2-ethyl) Xylamino group, N-heptylamino group, N, N-diheptylamino group, N-octylamino group, N, N-dioctylamino group, N-nonylamino group, N, N-dinonylamino group, N-phenylamino group, N, N-diphenylamino group, N, N-ethylmethylamino group, N, N-propylmethylamino group, N, N-isopropylmethylamino group, N, N-butylmethylamino group, N-decylamino group, N , N-decylmethylamino group, N-undecylamino group, N, N-undecylmethylamino group, N-dodecylamino group, N, N-dodecylmethylamino group, N-icosylamino group, N, N-ico One of a silmethylamino group, an N, N-tert-butylmethylamino group, an N, N-phenylmethylamino group, and a group represented by the following formula: Two hydrocarbon groups having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or derivatized groups thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), 1 carbon atom An amino group substituted with 10 to 10 alkylsulfamoyl groups (preferably a group derivatized with an octylsulfamoyl group or the like);

A sulfamoyl group;
N-methylsulfamoyl group, N, N-dimethylsulfamoyl group, N-ethylsulfamoyl group, N, N-diethylsulfamoyl group, N-propylsulfamoyl group, N, N-dipropyls Rufamoyl group, N-isopropylsulfamoyl group, N, N-diisopropylsulfamoyl group, N-butylsulfamoyl group, N, N-dibutylsulfamoyl group, N-isobutylsulfamoyl group, N, N-diisobutylsulfamoyl group, N-sec-butylsulfamoyl group, N, N-disec-butylsulfamoyl group, N-tert-butylsulfamoyl group, N, N-ditert-butylsulfur Famoyl group, N-pentylsulfamoyl group, N, N-dipentylsulfamoyl group, N- (1-ethylpropyl) sulfamoyl group, , N-di (1-ethylpropyl) sulfamoyl group, N-hexylsulfamoyl group, N, N-dihexylsulfamoyl group, N- (2-ethyl) hexylsulfamoyl group, N, N-di ( 2-ethyl) hexylsulfamoyl group, N-heptylsulfamoyl group, N, N-diheptylsulfamoyl group, N-octylsulfamoyl group, N, N-dioctylsulfamoyl group, N, N -Octylmethylsulfamoyl group, N-nonylsulfamoyl group, N, N-dinonylsulfamoyl group, N-phenylsulfamoyl group, N, N-diphenylsulfamoyl group, N, N-ethylmethyl Sulfamoyl group, N, N-propylmethylsulfamoyl group, N, N-isopropylmethylsulfamoyl group, N, N-butylmethylsulfamoyl group N-decylsulfamoyl group, N, N-decylmethylsulfamoyl group, N-undecylsulfamoyl group, N, N-undecylmethylsulfamoyl group, N-dodecylsulfamoyl group, N, N-dodecylmethylsulfamoyl group, N-icosylsulfamoyl group, N, N-icosylmethylsulfamoyl group, N, N-tert-butylmethylsulfamoyl group, N, N-phenylmethylsulfa 1 or 2 hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a moyl group and the group represented by the following formula or a derivatized group thereof (for example, carboxy group, sulfo group) , A nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. A sulfamoyl group substituted with

  Formylamino group; acetylamino group, propanoylamino group, butanoylamino group, 2,2-dimethylpropanoylamino group, pentanoylamino group, hexanoylamino group, (2-ethyl) hexanoylamino group, heptanoyl Amino group, octanoylamino group, nonanoylamino group, decanoylamino group, undecanoylamino group, dodecanoylamino group, heicosanoylamino group, benzoylamino group, etc., and groups represented by the following formulae Or a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 12 carbon atoms) or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon number 1 10 to 10 alkylsulfamoyl groups (preferably octylsulfamoyl groups) and the like) Carbonyl amino group (if the alkanoylamino group the carbonyl group, the carbon number is preferably 1 to 12);

A hydroxy group;
Halogen atoms such as fluorine atom, chlorine atom, bromine atom and iodine atom;
Carboxy group, —CO ₂ M ² (M ² is alkali metal, preferably lithium, sodium, potassium); sulfo group, —SO ₃ M ² (M ² is alkali metal, preferably lithium, sodium, potassium); Nitro group A cyano group;

  Formyloxy group; acetoxy group, propanoyloxy group, butanoyloxy group, 2,2-dimethylpropanoyloxy group, pentanoyloxy group, hexanoyloxy group, (2-ethyl) hexanoyloxy group, heptanoyloxy Carbon such as a group, octanoyloxy group, nonanoyloxy group, decanoyloxy group, undecanoyloxy group, dodecanoyloxy group, heicosanoyloxy group, benzoyloxy group, and the group represented by the following formula A hydrocarbon group having 1 to 20 (preferably 1 to 10 carbons) or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), A group to which an alkyl sulfamoyl group (preferably a group derivatized with an octyl sulfamoyl group) is bound. Boniruokishi group (if the alkanoyloxy group and the carbonyl group, the carbon number is preferably 1 to 10);

  Methylsulfonyl group, ethylsulfonyl group, propylsulfonyl group, butylsulfonyl group, pentylsulfonyl group, hexylsulfonyl group, (2-ethyl) hexylsulfonyl group, heptylsulfonyl group, octylsulfonyl group, nonylsulfonyl group, decylsulfonyl group, un Decylsulfonyl group, dodecylsulfonyl group, icosylsulfonyl group, phenylsulfonyl group, p-tolylsulfonyl group and the like, and groups having 1 to 20 carbon atoms (preferably having 1 to 10 carbon atoms) such as groups represented by the following formulae: Hydrocarbon group or derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group) A group derivatized with a sulfonyl group) ;

A carbamoyl group;
N-methylcarbamoyl group, N, N-dimethylcarbamoyl group, N-ethylcarbamoyl group, N, N-diethylcarbamoyl group, N-propylcarbamoyl group, N, N-dipropylcarbamoyl group, N-isopropylcarbamoyl group, N , N-diisopropylcarbamoyl group, N-butylcarbamoyl group, N, N-dibutylcarbamoyl group, N-isobutylcarbamoyl group, N, N-diisobutylcarbamoyl group, N-sec-butylcarbamoyl group, N, N-disec- Butylcarbamoyl group, N-tert-butylcarbamoyl group, N, N-ditert-butylcarbamoyl group, N-pentylcarbamoyl group, N, N-dipentylcarbamoyl group, N- (1-ethylpropyl) carbamoyl group, N, N-di (1-ethylpropyl) carba Yl group, N-hexylcarbamoyl group, N, N-dihexylcarbamoyl group, N- (2-ethyl) hexylcarbamoyl group, N, N-di (2-ethyl) hexylcarbamoyl group, N-heptylcarbamoyl group, N, N-diheptylcarbamoyl group, N-octylcarbamoyl group, N, N-dioctylcarbamoyl group, N-nonylcarbamoyl group, N, N-octylmethylcarbamoyl group, N, N-octylbutylcarbamoyl group, N, N-di Nonylcarbamoyl group, N-phenylcarbamoyl group, N, N-diphenylcarbamoyl group, N, N-ethylmethylcarbamoyl group, N, N-propylmethylcarbamoyl group, N, N-isopropylmethylcarbamoyl group, N, N-butyl Methylcarbamoyl group, N-decylcarbamoyl group, N, N Decylmethylcarbamoyl group, N-undecylcarbamoyl group, N, N-undecylmethylcarbamoyl group, N-dodecylcarbamoyl group, N, N-dodecylmethylcarbamoyl group, N-icosylcarbamoyl group, N, N-icosyl 1 or 2 carbon atoms (preferably carbon atoms) such as a methylcarbamoyl group, an N, N-tert-butylmethylcarbamoyl group, an N, N-phenylmethylcarbamoyl group, and a group represented by the following formula A hydrocarbon group having 1 to 10) or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably A carbamoyl group substituted with a group derivatized with an octylsulfamoyl group) or the like;

Trifluoromethyl group, perfluoroethyl group, perfluoropropyl group, perfluoroisopropyl group, perfluorobutyl group, perfluoropentyl group, perfluorohexyl group, perfluoroheptyl group, perfluorooctyl group, perfluorononyl group, A carbon atom having 1 to 20 carbon atoms in which all hydrogen atoms such as perfluorodecyl group, perfluoroundecyl group, perfluorododecyl group, perfluoroicosyl group, perfluorocyclohexyl group and perfluorophenyl group are substituted with fluorine atoms. A hydrogen group;
Perfluoroethylmethyl group, perfluoropropylmethyl group, perfluoroisopropylmethyl group, perfluorobutylmethyl group, perfluoropentylmethyl group, perfluorohexylmethyl group, perfluoroheptylmethyl group, perfluorooctylmethyl group, perfluoro A straight chain having 1 to 20 carbon atoms in which all hydrogen atoms such as nonylmethyl group, perfluorodecylmethyl group, perfluoroundecylmethyl group, perfluorododecylmethyl group and perfluoroicosylmethyl group are substituted with fluorine atoms Or a hydrocarbon group having 1 to 20 carbon atoms substituted by a branched alkyl group;

  1 to 20 carbon atoms (preferably carbon atoms) in which part of hydrogen atoms such as 2-fluorophenyl group, 3-fluorophenyl group, 4-fluorophenyl group and 2,4,6-trifluorophenyl group are substituted with fluorine. 1-10) hydrocarbon radicals;

-CO-SH, -CO-S- CH 3, -CO-S-CH 2 CH 3, -CO-S-CH 2 -CH 2 -CH 3, -CO-S-CH 2 -CH 2 -CH 2 A thiocarbonyl group bonded to an alkyl group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as —CH _3; and an aryl group having 6 to 20 carbon atoms such as —CO—S—C ₆ H _5. A thiocarbonyl group;

  * -COCO-R as represented by the following formula (wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, satisfying 1 to 20 carbon atoms among the hydrocarbon groups mentioned above) Or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably octyl sulfamoyl group) A group derived from, etc.)

* -NRCONR ₂ represented by the following formula (wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, those satisfying 1 to 20 carbon atoms among the hydrocarbon groups mentioned above) ) Or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group), etc. And the R may be the same or different from each other and may be bonded to each other to form a ring);

* -OCONR ₂ represented by the following formula (wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, those satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above) ) Or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group), etc. And the R may be the same or different from each other and may be bonded to each other to form a ring);

  * -NRCOOR as represented by the following formula (wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, those satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above)) Or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. A derivatized group), wherein the Rs may be the same or different from each other and may be bonded to each other to form a ring;

_{* -OP (O) (OCH 3} ) in such _{2 * -OP (O) (OR} ) 2 ( wherein, R represents a hydrogen atom, a hydrocarbon group (e.g., hydrocarbon groups mentioned above having 1 to 20 carbon atoms Or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms) A group derived from (preferably an octylsulfamoyl group) or the like, and the Rs may be the same or different from each other, and may be bonded to each other to form a ring;
* -SiR ₃ (* -Si (CH ₃ ) ₃ , * -Si (CH ₂ CH ₃ ) ₃ , * -Si (C ₆ H ₅ ) ₃ and * -Si (CH (CH ₃ ) ₂ ) ₃ In the formula, R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, those satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivatizing group thereof (for example, a carboxy group, sulfo group). A group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), a C1-C10 alkylsulfamoyl group (preferably an octylsulfamoyl group) and the like, and the R is Groups that may be the same or different from each other and may be bonded to each other to form a ring);
Etc.

As the divalent substituent, an oxo group, a thioxo group, an imino group, an imino group substituted with an alkyl group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms), and an aryl group having 6 to 20 carbon atoms are substituted. And imino groups. Examples of the imino group substituted with an alkyl group include CH ₃ —N═, CH ₃ —CH ₂ —N═, CH ₃ — (CH ₂ ) ₂ —N═, and CH ₃ — (CH ₂ ) ₃ —N =. Can be mentioned. Examples of the imino group substituted with an aryl group include C ₆ H ₅ —N═.

The substituent of the hydrocarbon group having 1 to 40 carbon atoms is preferably a substituent of group s1. The derivatizing groups shown below are a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), and the like. A derivatized group is preferred.
[Group s1]
An oxy group having a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof bonded to one side;
A carbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
An oxycarbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
An amino group;
An amino group substituted by one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
A sulfamoyl group;
A sulfamoyl group substituted with one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
A carbonylamino group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
A hydroxy group;
A halogen atom;
-CO ₂ M (preferably a carboxy group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom.);
-SO ₃ M (preferably a sulfo group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom.);
A nitro group;
A cyano group;
A carbonyloxy group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
A sulfonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
A carbamoyl group;
A carbamoyl group substituted with one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
A hydrocarbon group having 1 to 20 carbon atoms in which all of the hydrogen atoms are substituted by fluorine atoms;
A hydrocarbon group having 1 to 20 carbon atoms substituted with a linear or branched alkyl group having 1 to 20 carbon atoms in which all of the hydrogen atoms are substituted with fluorine atoms;
A hydrocarbon group having 1 to 20 carbon atoms in which a part of hydrogen atoms is substituted by fluorine;
Oxo group

The substituent of the hydrocarbon group having 1 to 40 carbon atoms is more preferably a substituent of group s2.
[Group s2]
An oxy group having a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof bonded to one side;
A carbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
An oxycarbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
An amino group;
An amino group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof;
A sulfamoyl group;
A sulfamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof;
A carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
A hydroxy group;
Fluorine atom, chlorine atom, bromine atom;
-CO ₂ M (preferably a carboxy group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom.);
-SO ₃ M (preferably a sulfo group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom.);
A nitro group;
A cyano group;
A carbonyloxy group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
A sulfonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
A carbamoyl group;
A carbamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof;
A hydrocarbon group having 1 to 10 carbon atoms in which all of the hydrogen atoms are substituted by fluorine atoms;
A hydrocarbon group having 1 to 10 carbon atoms substituted by a linear or branched alkyl group having 1 to 10 carbon atoms in which all of the hydrogen atoms are substituted with fluorine atoms;
A hydrocarbon group having 1 to 10 carbon atoms in which a part of hydrogen atoms is substituted by fluorine;
Oxo group

The hydrocarbon group having 1 to 40 carbon atoms having a substituent represented by R ^1Z3 , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^102Z3 is monovalent or 2 C1-C40 hydrocarbon group which has a valent substituent is mentioned, Preferably, it is C1-C30 saturated or unsaturated chain hydrocarbon group which has a monovalent or bivalent substituent, and monovalent. Or a saturated or unsaturated alicyclic hydrocarbon group having 3 to 30 carbon atoms having a divalent substituent, an aromatic hydrocarbon group having 6 to 30 carbon atoms or a hydrocarbon group having a monovalent or divalent substituent. A group having 1 to 30 carbon atoms and having a monovalent or divalent substituent,
More preferably, a saturated or unsaturated chain hydrocarbon group having 1 to 20 carbon atoms having a substituent of group s1, or a saturated or unsaturated alicyclic hydrocarbon group having 3 to 20 carbon atoms having a substituent of group s1. A group having 6 to 20 carbon atoms having a substituent of group s1 or a combination of hydrocarbon groups, and a group having 1 to 20 carbon atoms having a substituent of group s1,
Particularly preferably, it is a saturated or unsaturated chain hydrocarbon group having 1 to 15 carbon atoms having a substituent of group s2, or a saturated or unsaturated alicyclic hydrocarbon group having 3 to 15 carbon atoms having a substituent of group s2. , A group having a substituent of group s2 and a combination of an aromatic hydrocarbon group having 6 to 15 carbon atoms or a hydrocarbon group, and a group having 1 to 15 carbon atoms having a substituent of group s2.

The heterocyclic group represented by R ^1Z3 , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^102Z3 may be monocyclic or polycyclic. Of these, a heterocyclic ring containing a hetero atom as a ring component is preferable. Examples of the hetero atom include a nitrogen atom, an oxygen atom, and a sulfur atom.
The number of carbon atoms of the heterocyclic group is preferably 3-30, more preferably 3-22, still more preferably 3-20, still more preferably 3-18, and even more preferably 3-3. 15 and particularly preferably 3-14.

As a heterocyclic ring containing a nitrogen atom,
Monocyclic saturated heterocycles such as aziridine, azetidine, pyrrolidine, piperidine and piperazine;
Pyrrol such as 2,5-dimethylpyrrole, pyrazole such as 2-methylpyrazole and 3-methylpyrazole, 5-membered unsaturated heterocyclic ring such as imidazole, 1,2,3-triazole and 1,2,4-triazole ;
6-membered unsaturated heterocycles such as pyrimidines such as pyridine, pyridazine, 6-methylpyrimidine, pyrazines and 1,3,5-triazines;
Indazole, indoline, isoindoline, indole, indolizine, benzimidazole, quinoline, isoquinoline, quinoxaline such as 5,6,7,8-tetrahydro (3-methyl) quinoxaline, 3-methylquinoxaline, quinazoline, cinnoline, phthalazine, naphthyridine , Condensed bicyclic heterocycles such as purine, pteridine, benzopyrazole, benzopiperidine;
And condensed tricyclic heterocycles such as carbazole, acridine and phenazine.

As a heterocyclic ring containing an oxygen atom,
Monocyclic saturated heterocycles such as oxirane, oxetane, tetrahydrofuran, tetrahydropyran, 1,3-dioxane and 1,4-dioxane, 1-cyclopentyldioxolane;
Bicyclic saturated heterocycles such as 1,4-dioxaspiro [4.5] decane, 1,4-dioxaspiro [4.5] nonane;
Lactone heterocycles such as α-acetolactone, β-propiolactone, γ-butyrolactone, γ-valerolactone and δ-valerolactone;
5-membered unsaturated heterocyclic rings such as furan such as 2,3-dimethylfuran and 2,5-dimethylfuran;
6-membered unsaturated heterocyclic rings such as 2H-pyran and 4H-pyran;
Fused bicyclic heterocycles such as 1-benzofuran, benzopyran such as 4-methylbenzopyran, benzodioxole, chroman and isochroman;
And condensed tricyclic heterocycles such as xanthene and dibenzofuran;

As a heterocyclic ring containing a sulfur atom,
5-membered saturated heterocyclic ring such as dithiolane;
6-membered saturated heterocyclic rings such as thiane, 1,3-dithiane, 2-methyl-1,3-dithiane;
5-membered unsaturated heterocyclic rings such as thiophene such as 3-methylthiophene and 2-carboxythiophene, benzothiopyran such as 4H-thiopyran and benzotetrahydrothiopyran;
Condensed bicyclic heterocycles such as benzothiophene;
And condensed tricyclic heterocycles such as thianthrene and dibenzothiophene.

As a heterocyclic ring containing a nitrogen atom and an oxygen atom,
Monocyclic saturated heterocycles such as morpholine, 2-pyrrolidone, 2-methyl-2-pyrrolidone, 2-piperidone and 2-methyl-2-piperidone;
Monocyclic unsaturated heterocycles such as oxazole such as 4-methyloxazole, isoxazole such as 2-methylisoxazole and 3-methylisoxazole;
Condensed bicyclic heterocycles such as benzoxazole, benzisoxazole, benzoxazine, benzodioxane, benzimidazoline;
And condensed tricyclic heterocycles such as phenoxazine.

As a heterocyclic ring containing a nitrogen atom and a sulfur atom,
Monocyclic heterocycles such as thiazole such as 3-methylthiazole and 2,4-dimethylthiazole;
Fused bicyclic heterocycles such as benzothiazole;
Condensed tricyclic heterocycles such as phenothiazine; and the like.

  The heterocycle may be a group in which the above-described hydrocarbon groups are combined, and examples thereof include a tetrahydrofurylmethyl group.

Furthermore, the heterocyclic ring may be represented by the following formula.

The heterocyclic group may be a heterocyclic group formed by combining two or more of R ^{1Z3 to} R ^5Z3 . Such a heterocyclic group has two or more ring structures together with a benzene ring to which R ^{1Z3 to} R ^5Z3 are bonded. Examples of the two or more ring structures include structures of the following formulas.

  In addition, the bonding position of the above heterocyclic ring is a portion from which an arbitrary hydrogen atom contained in each ring is eliminated.

The heterocyclic group represented by R ^1Z3 , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^102Z3 may have a substituent. The substituent is the same as the substituent which the hydrocarbon group represented by R ^1Z3 , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^102Z3 may have. Things. When the heterocyclic ring contains a nitrogen atom as a constituent element, the above-described hydrocarbon group may be bonded to the nitrogen atom as a substituent.
Preferred examples of the substituent include a substituent which the hydrocarbon group represented by R ^1Z3 , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^102Z3 may have. The same thing as the preferable thing of a group is mentioned.
The heterocyclic group having a substituent represented by R ^1Z3 , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^102Z3 has a monovalent or divalent substituent. A heterocyclic group, preferably a heterocyclic group having a substituent of group s1, and more preferably a heterocyclic group having a substituent of group s2.
The hydrocarbon group or heterocyclic group may have one or more substituents (first substituent), and the two or more substituents are independent of each other. They may be the same or different. Further, the first substituent may have another substituent (second substituent) bonded to a hydrocarbon group contained in a part thereof. The second substituent can be selected from the same groups as the first substituent.

Hereinafter, R ^1Z3 , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , and R ^7Z3 -CO-R ^102Z3 , -COO-R ^101Z3 , -OCO-R ^102Z3 , -COCO-R ^102Z3 , -O _{^{-R 102Z3, -SO 2 -R 101Z3,}} -SO 2 N (R 102Z3) 2, -CON (R 102Z3) 2, -N (R 102Z3) 2, -NHCO-R 102Z3, -NHCO-N (R 102Z3 ) ₂ , —NHCOOR ^102Z3 , —OCON (R ^102Z3 ) ₂ , halogen atom, —SO ₃ M, —CO ₂ M will be described.
As —CO—R ^102Z3 , formyl group; acetyl group, propanoyl group, butanoyl group, 2,2-dimethylpropanoyl group, pentanoyl group, hexanoyl group, (2-ethyl) hexanoyl group, heptanoyl group, octanoyl group, nonanoyl A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof, such as a group, a decanoyl group, an undecanoyl group, a dodecanoyl group, a heicosanoyl group, a benzoyl group, and the like A derivatized group (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. Group), the number of carbon atoms is 2 to 41 when the carbonyl group is an acyl group. ) And include groups corresponding to the -CO-R ^102Z3 in the compounds shown in Table 1Z3~ Table 6Z3 -CO-R ^102Z3 Table 1-966 of the relevant group and Japanese Patent Application No. 2017-016290 to the compounds shown in Preferably, the hydrocarbon group having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms) or a carbonyl group to which the derivatizing group is bonded (when the carbonyl group is an alkanoyl group, the carbon number is more preferably 2 to 12) and groups corresponding to -CO-R ^102Z3 in the compounds shown in Tables 1Z3 to ^6Z3 .

—COO—R ^101Z3 includes a methoxycarbonyl group, an ethoxycarbonyl group, a propoxycarbonyl group, a tert-butoxycarbonyl group, a butoxycarbonyl group, a pentyloxycarbonyl group, a hexyloxycarbonyl group, a (2-ethyl) hexyloxycarbonyl group, Heptyloxycarbonyl group, octyloxycarbonyl group, nonyloxycarbonyl group, decyloxycarbonyl group, undecyloxycarbonyl group, dodecyloxycarbonyl group, phenyloxycarbonyl group, icosyloxycarbonyl group, etc. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon, etc. Number 1 0 alkylsulfamoyl group group (preferably octyl sulfamoyl group) corresponding to the -COO-R ^102Z3 in compounds derivatized groups) is shown in oxycarbonyl group and Tables 1Z3~ Table 6Z3 bound by such And groups corresponding to -COO-R ^102Z3 in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290, preferably a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof bonded thereto. Examples thereof include an oxycarbonyl group and groups corresponding to —COO—R ^102Z3 in the compounds shown in Tables 1Z3 to ^6Z3 .

-OCO-R ^102Z3 includes ^formyloxy group; acetoxy group, propanoyloxy group, butanoyloxy group, 2,2-dimethylpropanoyloxy group, pentanoyloxy group, hexanoyloxy group, (2-ethyl) Hexanoyloxy group, heptanoyloxy group, octanoyloxy group, nonanoyloxy group, decanoyloxy group, undecanoyloxy group, dodecanoyloxy group, heicosanoyloxy group, benzoyloxy group, and the above formula A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom) ), An alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. If the reduction radicals) is bonded to a carbonyl group (said carbonyl group to an acyloxy group, a carbon number of 2-41), as well as -OCO-R ^102Z3 in the compounds shown in Table 1Z3~ Table 6Z3 Examples of the corresponding group and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290 include groups corresponding to —OCO—R ^102Z3 , preferably 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms). ) Or a carbonyloxy group to which the derivatizing group is bonded (when the carbonyloxy group is an acyloxy group, the carbon number is more preferably 2 to 12), and Tables 1Z3 to 6Z3 ^Examples of the compound include a group corresponding to -OCO-R ^102Z3 .

-COCO-R ^102Z3 includes methyl oxalyl group, ethyl oxalyl group, propyl oxalyl group, butyl oxalyl group, pentyl oxalyl group, hexyl oxalyl group, (2-ethyl) hexyl oxalyl group, heptyl oxalyl group, octyl oxalyl group, nonyl Oxalyl group, decyloxalyl group, undecyloxalyl group, dodecyloxalyl group, icosyloxalyl group, cyclopentyloxalyl group, cyclohexyloxalyl group, phenyloxalyl group, p-tolyloxalyl group, etc., and groups represented by the above formula A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), 10 alkyl sulfamos Group and JP Le group (preferably octyl sulfamoyl group) corresponding to the -COCO-R ^102Z3 In the compound represented oxalyl groups, as well as Table 1Z3~ Table 6Z3 derivatized group, etc.) are bonded 2017-016290 In the compounds shown in Tables 1 to 966 of the No., groups corresponding to -COCO-R ^102Z3 and the like can be mentioned.

-O-R ^102Z3 includes a hydroxy group; a methoxy group, an ethoxy group, a propoxy group, an isopropoxy group, a butoxy group, an isobutoxy group, a sec-butoxy group, a tert-butoxy group, a pentyloxy group, a hexyloxy group, and heptyloxy Group, octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, dodecyloxy group, (2-ethyl) hexyloxy group, icosyloxy group, 1-phenylethoxy group, 1-methyl-1-phenylethoxy group, phenyl Oxy group, 2,3-dimethylphenyloxy group, 2,4-dimethylphenyloxy group, 2,5-dimethylphenyloxy group, 2,6-dimethylphenyloxy group, 3,4-dimethylphenyloxy group, 3, 5-dimethylphenyloxy group, 2,2-dicyanophenyloxy 2,3-dicyanophenyloxy group, 2,4-dicyanophenyloxy group, 2,5-dicyanophenyloxy group, 2,6-dicyanophenyloxy group, 3,4-dicyanophenyloxy group, 3,5- Dicyanophenyloxy group, 4-methoxyphenyloxy group, 2-methoxyphenyloxy group, 3-methoxyphenyloxy group, 4-ethoxyphenyloxy group, 2-ethoxyphenyloxy group, 3-ethoxyphenyloxy group, etc. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group represented by the formula: or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably Chlorine atoms), derivatized with alkyl sulfamoyl groups having 1 to 10 carbon atoms (preferably octylsulfamoyl groups), etc. Groups) -O-R ^102Z3 in the compound represented by -O-R ^102Z3 Table 1-966 of the relevant group and Japanese Patent Application No. 2017-016290 in the the compound represented in group and Table 1Z3~ Table 6Z3 bound is A group corresponding to —O—R ^102Z3 in the compounds shown in Tables 1Z3 to 6Z3 and preferably an oxy group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded. Etc.

As —SO ₂ —R ^101Z3 , methylsulfonyl group, ethylsulfonyl group, propylsulfonyl group, butylsulfonyl group, pentylsulfonyl group, ^{hexylsulfonyl} group, (2-ethyl) ^{hexylsulfonyl} group, ^{heptylsulfonyl} group, octylsulfonyl group, 1 to 40 carbon atoms such as a nonylsulfonyl group, a decylsulfonyl group, an undecylsulfonyl group, a dodecylsulfonyl group, an icosylsulfonyl group, a phenylsulfonyl group, a p-tolylsulfonyl group, and a group represented by the above formula Preferably a hydrocarbon group having 1 to 20 carbon atoms or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms. (Preferably octylsulfamoyl group) -SO ₂ -R in the compounds represented by -SO ₂ -R ^102Z3 Table 1-966 of the relevant group and Japanese Patent Application No. 2017-016290 in the compound group) is shown in the sulfonyl group and Table 1Z3~ Table 6Z3 bound ^102Z3 relevant group and the like, the preferably corresponds to -SO ₂ -R ^102Z3 in the compound represented by sulfonyl groups and Table 1Z3~ Table 6Z3 bonded hydrocarbon radical or a derivatized group having 1 to 10 carbon atoms And the like.

—SO ₂ N (R ^102Z3 ) ₂ includes a sulfamoyl group;
N-methylsulfamoyl group, N-ethylsulfamoyl group, N-propylsulfamoyl group, N-isopropylsulfamoyl group, N-butylsulfamoyl group, N-isobutylsulfamoyl group, N- sec-butylsulfamoyl group, N-tert-butylsulfamoyl group, N-pentylsulfamoyl group, N- (1-ethylpropyl) sulfamoyl group, N-hexylsulfamoyl group, N- (2- Ethyl) hexylsulfamoyl group, N-heptylsulfamoyl group, N-octylsulfamoyl group, N-nonylsulfamoyl group, N-decylsulfamoyl group, N-undecylsulfamoyl group, N- Dodecylsulfamoyl group, N-icosylsulfamoyl group, N-phenylsulfamoyl group, etc., and groups represented by the above formula A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon number In a sulfamoyl group substituted with 1 to 10 alkylsulfamoyl groups (preferably a group derivatized with an octylsulfamoyl group, etc.) and the compounds shown in Tables 1Z3 to 6Z3, —SO ₂ NH (R ^102Z3X ) (Provided that R ^102Z3X is the same as R ^102Z3 except that it does not become a hydrogen atom) and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290, —SO ₂ NH (R ^102Z3X ) (However, R ^102Z3X is the same as R ^102Z3 except that it does not become a hydrogen atom), etc.

N, N-dimethylsulfamoyl group, N, N-ethylmethylsulfamoyl group, N, N-diethylsulfamoyl group, N, N-propylmethylsulfamoyl group, N, N-dipropylsulfamoyl group Group, N, N-isopropylmethylsulfamoyl group, N, N-diisopropylsulfamoyl group, N, N-tert-butylmethylsulfamoyl group, N, N-diisobutylsulfamoyl group, N, N- Disec-butylsulfamoyl group, N, N-ditert-butylsulfamoyl group, N, N-butylmethylsulfamoyl group, N, N-dibutylsulfamoyl group, N, N-dipentylsulfa Moyl group, N, N-di (1-ethylpropyl) sulfamoyl group, N, N-dihexylsulfamoyl group, N, N-di (2-ethyl) hexyls Famoyl group, N, N-diheptylsulfamoyl group, N, N-octylmethylsulfamoyl group, N, N-dioctylsulfamoyl group, N, N-dinonylsulfamoyl group, N, N-decyl Methylsulfamoyl group, N, N-undecylmethylsulfamoyl group, N, N-dodecylmethylsulfamoyl group, N, N-icosylmethylsulfamoyl group, N, N-phenylmethylsulfamoyl Two hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group, N, N-diphenylsulfamoyl group, and the group represented by the above formula, or a derivatized group thereof ( For example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably octyl sulfamoyl) ^{_{) -SO 2 N (R 102Z3X)}} 2 ( provided that at sulfamoyl groups and compounds shown in Table 1Z3~ Table 6Z3 substituted with derivatized groups) in such, except that R ^102Z3X is not a hydrogen atom, R in the compounds shown in Table 1 to 966 of the corresponding group and Japanese Patent Application No. 2017-016290 the same as is) and _{^{102Z3 -SO 2 N (R 102Z3X)}} 2 ( where except that R ^102Z3X is not a hydrogen atom, The same as R ^102Z3 ), and the like.
Preferably, it corresponds to —SO ₂ N (R ^102Z3 ) ₂ in one or two sulfamoyl groups substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or derivatized groups thereof, and compounds shown in Tables 1Z3 to ^6Z3. Groups and the like.

^—CON (R ^102Z3 ) ₂ includes a carbamoyl group;
N-methylcarbamoyl group, N-ethylcarbamoyl group, N-propylcarbamoyl group, N-isopropylcarbamoyl group, N-butylcarbamoyl group, N-isobutylcarbamoyl group, N-sec-butylcarbamoyl group, N-tert-butylcarbamoyl Group, N-pentylcarbamoyl group, N- (1-ethylpropyl) carbamoyl group, N-hexylcarbamoyl group, N- (2-ethyl) hexylcarbamoyl group, N-heptylcarbamoyl group, N-octylcarbamoyl group, N- One of nonylcarbamoyl group, N-decylcarbamoyl group, N-undecylcarbamoyl group, N-dodecylcarbamoyl group, N-icosylcarbamoyl group, N-phenylcarbamoyl group, etc., and a group represented by the above formula 1 to 40 carbon atoms (preferably carbon 1-20) hydrocarbon group or derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably octyl) In the compounds shown in Tables 1Z3 to 6Z3, —CONH (R ^102Z3X ) (provided that R ^102Z3X does not become a hydrogen atom) -CONH the same in a) to the appropriate groups and compounds shown in Table 1 to 966 of Japanese Patent Application No. 2017-016290 and R ^102Z3 (R ^102Z3X) (where except that R ^102Z3X is not a hydrogen atom, R ^102Z3 And the like)

N, N-dimethylcarbamoyl group, N, N-ethylmethylcarbamoyl group, N, N-diethylcarbamoyl group, N, N-propylmethylcarbamoyl group, N, N-dipropylcarbamoyl group, N, N-isopropylmethylcarbamoyl Group, N, N-diisopropylcarbamoyl group, N, N-tert-butylmethylcarbamoyl group, N, N-diisobutylcarbamoyl group, N, N-disec-butylcarbamoyl group, N, N-ditert-butylcarbamoyl group N, N-butylmethylcarbamoyl group, N, N-dibutylcarbamoyl group, N, N-butyloctylcarbamoyl group, N, N-dipentylcarbamoyl group, N, N-di (1-ethylpropyl) carbamoyl group, N , N-dihexylcarbamoyl group, N, N-di (2-ethyl) hexyl Rucarbamoyl group, N, N-diheptylcarbamoyl group, N, N-octylmethylcarbamoyl group, N, N-dioctylcarbamoyl group, N, N-dinonylcarbamoyl group, N, N-decylmethylcarbamoyl group, N, N -Undecylmethylcarbamoyl group, N, N-dodecylmethylcarbamoyl group, N, N-icosylmethylcarbamoyl group, N, N-phenylmethylcarbamoyl group, N, N-diphenylcarbamoyl group, etc. Two hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group to be synthesized or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom) ), A C 1-10 alkylsulfamoyl group (preferably an octylsulfamoyl group), etc. Groups) -CON In the compounds shown in carbamoyl group and Tables 1Z3~ Table 6Z3 substituted with (R ^102Z3X) ₂ (where except that R ^102Z3X is not a hydrogen atom, corresponding to the same in a) and R ^102Z3 And -CON (R ^102Z3X ) ₂ (provided that R ^102Z3X is the same as R ^102Z3 except that it does not become a hydrogen atom) in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290. Groups, etc.
Preferably, one or two hydrocarbon groups having 1 to 10 carbon atoms or a carbamoyl group substituted with a derivatizing group thereof, and a group corresponding to ^—CON (R ^102Z3 ) ₂ in the compounds shown in Tables 1Z3 to 6Z3, etc. Is mentioned.

—N (R ^102Z3 ) ₂ includes an amino group;
N-methylamino group, N-ethylamino group, N-propylamino group, N-isopropylamino group, N-butylamino group, N-isobutylamino group, N-sec-butylamino group, N-tert-butylamino Group, N-pentylamino group, N-hexylamino group, N- (2-ethyl) hexylamino group, N-heptylamino group, N-octylamino group, N-nonylamino group, N-decylamino group, N-un A decylamino group, an N-dodecylamino group, an N-icosylamino group, an N-phenylamino group, and the like, and one of 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group represented by the above formula A hydrocarbon group or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl group having 1 to 10 carbon atoms; -NH (R ^102Z3X) (provided that the amino group and Tables 1Z3~ Table 6Z3 compounds shown in substituted with Amoiru group (preferably octyl sulfamoyl group) were derivatized with such groups), R ^102Z3X a hydrogen atom do not except that become, in the compounds shown in Table 1 to 966 groups and Japanese Patent Application No. 2017-016290 corresponding to same in a) and R ^102Z3 -NH (R ^102Z3X) (provided that, R ^102Z3X is not a hydrogen atom Except for the ^above , it is the same as R ^102Z3 ), etc.

N, N-dimethylamino group, N, N-ethylmethylamino group, N, N-diethylamino group, N, N-propylmethylamino group, N, N-dipropylamino group, N, N-isopropylmethylamino group N, N-diisopropylamino group, N, N-tert-butylmethylamino group, N, N-diisobutylamino group, N, N-disec-butylamino group, N, N-ditert-butylamino group, N, N-butylmethylamino group, N, N-dibutylamino group, N, N-dipentylamino group, N, N-di (1-ethylpropyl) amino group, N, N-dihexylamino group, N, N -Di (2-ethyl) hexylamino group, N, N-diheptylamino group, N, N-dioctylamino group, N, N-dinonylamino group, N, N-decylmethylamino group, N, N- Ndecylmethylamino group, N, N-dodecylmethylamino group, N, N-icosylmethylamino group, N, N-phenylmethylamino group, N, N-diphenylamino group, etc., and the above formula Two hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom) In the compounds shown in Tables 1Z3 to 6Z3, and —N (R), an amino group substituted with a C 1-10 alkylsulfamoyl group (preferably a group derivatized with an octylsulfamoyl group) or the like) ^102Z3X) ₂ (provided that, R ^102Z3X, except that not a hydrogen atom, are shown in Table 1 to 966 groups and Japanese Patent Application No. 2017-016290 corresponding to same in a) and R ^102Z3 compound -N (R ^102Z3X) ₂ (provided that, R ^102Z3X, except that not a hydrogen atom, same as is the R ^102Z3) in group corresponding to group corresponding to the like,
Preferably, one or two hydrocarbon groups having 1 to 10 carbon atoms or an amino group substituted by a derivatizing group thereof, and a group corresponding to —N (R ^102Z3 ) ₂ in the compounds shown in Tables 1Z3 to 6Z3, etc. Is mentioned.

—NHCO—R ^102Z3 includes formylamino group; acetylamino group, propanoylamino group, butanoylamino group, 2,2-dimethylpropanoylamino group, pentanoylamino group, hexanoylamino group, (2-ethyl ) Hexanoylamino group, heptanoylamino group, octanoylamino group, nonanoylamino group, decanoylamino group, undecanoylamino group, dodecanoylamino group, heicosanoylamino group, benzoylamino group, etc. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group represented by the above formula or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably Is a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) In the case of a derivatized group) bonded to a carbonylamino group (an acylamino group the carbonyl amino group, -NHCO-R ^102Z3 in compound number of carbon atoms indicated in which) and Table 1Z3~ Table 6Z3 1 to 40 And groups corresponding to —NHCO—R ^102Z3 in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290, and the like.
Preferably, a carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded (when the carbonylamino group is an alkanoylamino group, the carbon number is more preferably 1 to 10) and Table 1Z3 In the compounds shown in Table 6Z3, groups corresponding to -NHCO-R ^102Z3 and the like can be mentioned.

As —NHCON (R ^102Z3 ) ₂ , groups listed above and the groups corresponding to —NHCON (R ^102Z3 ) ₂ in the compounds shown in Tables 1Z3 to 6Z3, Tables 1 to 966 of Japanese Patent Application No. 2017-016290 And a group corresponding to —NHCON (R ^102Z3 ) ₂ in the compound represented by

-NHCOOR ^102Z3 includes the groups listed above and the groups corresponding to -NHCOOR ^102Z3 in the compounds shown in Tables 1Z3 to 6Z3, and -NHCOOR 102Z3 in the compounds shown in Tables 1-966 of Japanese Patent Application No. ^2017-016290. And the like group.

^{Examples of} —OCON (R ^102Z3 ) ₂ include groups listed above and groups corresponding to —OCON (R ^102Z3 ) ₂ in the compounds shown in Tables 1Z3 to 6Z3, Tables 1 to 966 of Japanese Patent Application No. 2017-016290. And a group corresponding to —OCON (R ^102Z3 ) ₂ in the compound represented by

As the halogen atom, a fluorine atom, a chlorine atom, a bromine atom and an iodine atom are preferable.
Examples of M in —SO ₃ M and —CO ₂ M include a hydrogen atom; an alkali metal atom such as a lithium atom, a sodium atom and a potassium atom, preferably a hydrogen atom, a sodium atom and a potassium atom.

The ^{-CO-R 102Z3, -COO-R} 102Z3, -OCO-R 102Z3, -COCO-R 102Z3, -O-R 102Z3, -SO 2 -R 102Z3, -SO 2 N (R 102Z3) 2, -CON ^{Substituent contained in} ( ^R102Z3 ) ₂ , -N ( ^R102Z3 ) ₂ , -NHCO- ^R102Z3 , -NHCON ( ^R102Z3 ) ₂ , ^-NHCOOR102Z3 , -OCON ( ^R102Z3 ) ₂ (first substituent) May be one or more, and the two or more substituents may be the same or different independently of each other.
Further, the first substituent may have another substituent (second substituent) bonded to a hydrocarbon group contained in a part thereof. The second substituent can be selected from the same groups as the first substituent.

The ring formed by R ^2Z3 and R ^3Z3 , R ^3Z3 and R ^4Z3 , and R ^4Z3 and R ^5Z3 is condensed with the benzene ring of the isoindoline skeleton of the compound represented by the formula (IZ3). The condensed ring structure of the ring formed by R ^2Z3 and R ^3Z3 , R ^3Z3 and R ^4Z3 , and R ^4Z3 and R ^5Z3 and the benzene ring includes indene, naphthalene, biphenylene, indacene, acenaphthylene, fluorene, phenalene, phenanthrene, Hydrocarbon condensed ring structures such as anthracene, fluoranthene, acephenanthrylene, aceanthrylene, triphenylene, pyrene, chrysene, N-methylphthalimide, N- (1-phenylethyl) phthalimide and tetracene, and their partially reduced forms ( For example, 9,10-dihydroanthracene, 1,2,3,4-tetrahydronaphthalene, etc.); indole, isoindole, indazole, quinoline, isoquinoline, phthalazine, quinoxaline, quinazoline, cinnoline, carbazole, carboline, phenant Jin, acridine, perimidine, nitrogen-containing condensed heterocyclic, and parts thereof reductant such as phenanthroline and phenazine; 3- oxygen-containing condensed such tetrahydrobenzo furan-2-one heterocyclic ring and its partially reduced products thereof.

When R ^2Z3 and R ^3Z3 , R ^3Z3 and R ^4Z3 , and R ^4Z3 and R ^5Z3 form a ring, the ring may have a substituent. The substituent is the same as the substituent which the hydrocarbon group represented by R ^1Z3 , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^102Z3 may have. Things. Preferred examples of the substituent include a substituent which the hydrocarbon group represented by R ^1Z3 , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , R ^7Z3 , R ^101Z3 and R ^102Z3 may have. The same thing as the preferable thing of a group is mentioned.

When R ^3Z3 and R ^4Z3 form a ring, R ^2Z3 and R ^5Z3 are preferably a hydrogen atom, an amino group, and a hydroxy group, independently of each other.
When R ^2Z3 and R ^3Z3 form a ring, R ^4Z3 and R ^5Z3 preferably do not form a ring, and R ^4Z3 and R ^5Z3 are more preferably hydrogen atoms.
When R ^4Z3 and R ^5Z3 form a ring, R ^2Z3 and R ^3Z3 preferably do not form a ring, and R ^2Z3 and R ^3Z3 are more preferably hydrogen atoms.

In the present invention, R ^1Z3 , R ^6Z3 and R ^7Z3 are preferably hydrogen atoms.

From the viewpoint of reducing the retardation value of the color filter produced from the coloring composition, at least one of R ^2Z3 , R ^3Z3 , R ^4Z3 , and R ^5Z3 is -CO-R ^102Z3 , -COO-R ^101Z3 ,- ^{OCO-R 102Z3, -COCO-R} 102Z3, -O-R 102Z3, -SO 2 -R 101Z3, -SO 2 N (R 102Z3) 2, -CON (R 102Z3) 2, -N (R 102Z3) 2, ^{-NHCO-R 102Z3, -NHCO-N} (R 102Z3) 2, -NHCOOR 102Z3, -OCON (R 102Z3) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , a substituent It is preferably a C1-C40 hydrocarbon group that may have or a heterocyclic group that may have a substituent,
1 to 40 carbon atoms in which all or part of the hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a halogen atom, -N (R ^102Z3 ) ₂ , a nitro group or a hydrogen atom are substituted 20 hydrocarbon groups, —NHCO—R ^102Z3 , —O—R ^102Z3 , —SO ₃ M or —CO ₂ M are more preferred,
It is more preferable that it is a C1-C40 hydrocarbon group which may have a nitro group or a substituent, and it is still more preferable that it is a nitro group or a tert-butyl group. Alternatively, at least one pair of R ^2Z3 and R ^3Z3 , R ^3Z3 and R ^4Z3 , or R ^4Z3 and R ^5Z3 preferably forms a ring.

In the compound (IZ3), at least one of R ^2Z3 , R ^3Z3 , R ^4Z3 , and R ^5Z3 is -CO-R ^102Z3 , -COO-R ^101Z3 , -OCO-R ^102Z3 , -COCO-R ^102Z3 , -O- _{^{R 102Z3, -SO 2 -R 101Z3,}} -SO 2 N (R 102Z3) 2, -CON (R 102Z3) 2, -N (R 102Z3) 2, -NHCO-R 102Z3, -NHCO-N (R 102Z3) ₂ , —NHCOOR ^102Z3 , —OCON (R ^102Z3 ) ₂ , halogen atom, cyano group, nitro group, —SO ₃ M, —CO ₂ M, an ^optionally substituted hydrocarbon having 1 to 40 carbon atoms A heterocyclic group which may have a group or a substituent, or at least one pair of R ^2Z3 and R ^3Z3 , R ^3Z3 and R ^4Z3 , and R ^4Z3 and R ^5Z3 is bonded to form a ring. (Hereinafter, this compound may be referred to as “compound (IZ3-B)”). When the compound (IZ3) is the compound (IZ3-B), the retardation value of the color filter prepared from the colored composition is small.

［式（ＩＺ３−Ｂ）中、
Ｒ^1Z3、Ｒ^21Z3、Ｒ^31Z3、Ｒ^41Z3、Ｒ^51Z3、Ｒ^61Z3、及びＲ^71Z3は、互いに独立に、水素原子、−ＣＯ−Ｒ^102Z3、−ＣＯＯ−Ｒ^101Z3、−ＯＣＯ−Ｒ^102Z3、−ＣＯＣＯ−Ｒ^102Z3、−Ｏ−Ｒ^102Z3、−ＳＯ₂−Ｒ^101Z3、−ＳＯ₂Ｎ（Ｒ^102Z3）₂、−ＣＯＮ（Ｒ^102Z3）₂、−Ｎ（Ｒ^102Z3）₂、−ＮＨＣＯ−Ｒ^102Z3、−ＮＨＣＯ−Ｎ（Ｒ^102Z3）₂、−ＮＨＣＯＯＲ^102Z3、−ＯＣＯＮ（Ｒ^102Z3）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^21Z3とＲ^31Z3、Ｒ^31Z3とＲ^41Z3、及びＲ^41Z3とＲ^51Z3は、それぞれ互いに結合して環を形成してもよい。
ただし、Ｒ^21Z3、Ｒ^31Z3、Ｒ^41Z3、及びＲ^51Z3の少なくとも一つは、−ＣＯ−Ｒ^102Z3、−ＣＯＯ−Ｒ^101Z3、−ＯＣＯ−Ｒ^102Z3、−ＣＯＣＯ−Ｒ^102Z3、−Ｏ−Ｒ^102Z3、−ＳＯ₂−Ｒ^101Z3、−ＳＯ₂Ｎ（Ｒ^102Z3）₂、−ＣＯＮ（Ｒ^102Z3）₂、−Ｎ（Ｒ^102Z3）₂、−ＮＨＣＯ−Ｒ^102Z3、−ＮＨＣＯ−Ｎ（Ｒ^102Z3）₂、−ＮＨＣＯＯＲ^102Z3、−ＯＣＯＮ（Ｒ^102Z3）₂、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基或いは置換基を有していてもよい複素環基であるか、又はＲ^21Z3とＲ^31Z3、Ｒ^31Z3とＲ^41Z3、及びＲ^41Z3とＲ^51Z3の少なくとも一組が結合して環を形成している。
Ｒ^101Z3は、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102Z3は、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、水素原子又はアルカリ金属原子を表す。
Ｒ^101Z3、Ｒ^102Z3及びＭが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
波線は、Ｅ体又はＺ体を表す。］ The compound (IZ3-B) is defined by the formula as follows.

[In the formula (IZ3-B),
R ^1Z3 , R ^21Z3 , R ^31Z3 , R ^41Z3 , R ^51Z3 , R ^61Z3 , and R ^71Z3 are each independently a hydrogen atom, —CO—R ^102Z3 , —COO—R ^101Z3 , —OCO—R ^102Z3 , —COCO ^{-R 102Z3, -O-R 102Z3,} -SO 2 -R 101Z3, -SO 2 N (R 102Z3) 2, -CON (R 102Z3) 2, -N (R 102Z3) 2, -NHCO-R 102Z3, - _{^{NHCO-N (R 102Z3) 2}} , -NHCOOR 102Z3, -OCON (R 102Z3) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , carbon atoms, which may have a substituent The heterocyclic group which may have a hydrocarbon group or a substituent of number 1-40 is represented.
R ^21Z3 and R ^31Z3 , R ^31Z3 and R ^41Z3 , and R ^41Z3 and R ^51Z3 may be bonded to each other to form a ring.
However, at least one of R ^21Z3 , R ^31Z3 , R ^41Z3 , and R ^51Z3 is —CO—R ^102Z3 , —COO—R ^101Z3 , —OCO—R ^102Z3 , —COCO—R ^102Z3 , —O—R ^102Z3 , _{^{-SO 2 -R 101Z3, -SO 2 N}} (R 102Z3) 2, -CON (R 102Z3) 2, -N (R 102Z3) 2, -NHCO-R 102Z3, -NHCO-N (R 102Z3) 2, - ^{NHCOOR 102Z3, -OCON (R 102Z3)} 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , hydrocarbon group or substituted carbon atoms 1 to 40 which may have a substituent A heterocyclic group which may have a group, or at least one pair of R ^21Z3 and R ^31Z3 , R ^31Z3 and R ^41Z3 , and R ^41Z3 and R ^51Z3 is bonded to form a ring.
R ^101Z3 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102Z3 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
M represents a hydrogen atom or an alkali metal atom.
When a plurality of R ^101Z3 , R ^102Z3 and M are present, they may be the same or different.
A wavy line represents an E body or a Z body. ]

Wherein ^{(IZ3-B), R 21Z3} , R 31Z3, R 41Z3, R 51Z3, R 61Z3, and R ^71Z3 are each, R ^2Z3 in formula ^{(IZ3), R 3Z3, R} 4Z3, R 5Z3, R 6Z3 And the same as R ^7Z3 .

In formula (IZ3-B), preferred R ^21Z3 , R ^31Z3 , R ^41Z3 , R ^51Z3 , R ^61Z3 , and R ^71Z3 are R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R in formula (IZ3), respectively. ^The same thing as the preferable thing of ^6Z3 and ^R7Z3 is mentioned.

In the formula (IZ3-B), (Aspect 1) R ^1Z3 , R ^61Z3 and R ^71Z3 are preferably hydrogen atoms. (Aspect 2) It is preferable that at least one of R ^21Z3 , R ^31Z3 , R ^41Z3 , and R ^51Z3 is a nitro group or a tert-butyl group. One of modes 1 and 2 may be employed, or both may be employed.

From the viewpoint of reducing the retardation value of the color filter produced from the colored composition, at least one of R ^2Z3 , R ^3Z3 , R ^4Z3 , and R ^5Z3 may have a substituent. Hydrocarbon group, halogen atom, —N (R ^102Z3 ) ₂ , nitro group, hydrocarbon group having 1 to 20 carbon atoms in which all or part of the hydrogen atom is substituted with fluorine atom, —NHCO—R ^102Z3 , —O —R ^102Z3 , —SO ₃ M or —CO ₂ M is preferable, and a nitro group or an ^optionally substituted hydrocarbon group having 1 to 40 carbon atoms is more preferable. More preferably, it is a tert-butyl group. Particularly preferably, R ^3Z3 is a nitro group or tert-butyl group and R ^2Z3 , R ^4Z3 and R ^5Z3 are hydrogen atoms, or R ^2Z3 , R ^3Z3 and R ^5Z3 are hydrogen atoms and R ^4Z3. Is a nitro group or a tert-butyl group.

Specific examples of compound (IZ3) include, for example, compound (IZ3-1) having the substituents shown in Table 1Z3, Table 2Z3, Table 3Z3, Table 4Z3, Table 5Z3, and Table 6Z3 in formula (IZ3-aa) -Compound (IZ3-212) or its alkali metal salt is mentioned.
B ^a1Z3 B ^a2Z3 is the formula (BB1) to formula (BB60), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1), formula (BBO8), formula (BBO10) , Any partial structure represented by formula (BBD1) and formula (BBJ2). Formula (BB1) to Formula (BB60), Formula (BBK2), Formula (BBK3), Formula (BBK4), Formula (BBK14), Formula (BBI1), Formula (BBO8), Formula (BBO10), Formula (BBD1) and Formula (BBJ2) represents B ^a1Z1 B ^a2Z1 of Formula (IZ1-aa), (BB1) to (BB60), Formula (BBK2), Formula (BBK3), Formula (BBK4), Formula (BBK14), Formula (BBI1) ), Formula (BBO8), formula (BBO10), formula (BBD1), and formula (BBJ2). B ^A1Z3 and B ^A2Z3 each represent a bond, B ^A1Z3 the expression (BB1) ~ formula (BB60), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1) , Formula (BBO8), formula (BBO10), formula (BBD1), and formula (BBJ2), when B ^{1 is} a bond, B ^a2Z3 is a bond of B ² , and B ^a1Z3 is a formula (BB1) to formula ( ^BB60 ). ), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1), formula (BBO8), formula (BBO10), formula (BBD1) and formula B ² of (BBJ2) When it is a bond, B ^a2Z3 is a bond of B ¹ .
B ^a1Z3 B ^a2Z3 includes formula (BB1), formula (BB6), formula (BB8), formula (BB11), formula (BB14), formula (BB19), formula (BB37), formula (BB58), formula (BBJ2) ), Formula (BBO8) and formula (BBO10) are preferred, and formula (BB1), formula (BB6) and formula (BB19) are more preferred.

Each symbol in Table 1Z3, Table 2Z3, Table 3Z3, Table 4Z3, Table 5Z3, and Table 6Z3 represents the following partial structure. In the partial structure,
“Me” represents a methyl group,
“Et” represents an ethyl group;
“Bu” represents a butyl group,
“TBu” represents a tert-butyl group,
“Hex” represents a hexyl group,
“Oct” represents an octyl group;
“2EH” represents a 2-ethylhexyl group;
“CHM” represents a cyclohexylmethyl group,
“CH” represents a cyclohexyl group,
“PH” represents a phenyl group;
“BZ” represents a benzyl group;
“NPR” represents a propyl group;
“IPR” represents an isopropyl group;
“IBu” represents an isobutyl group,
“EOE” represents —CH ₂ CH ₂ OCH ₂ CH ₃ ,
“ALL” represents an allyl group,
“HYE” represents a 2-hydroxyethyl group,
“COM” represents —CO—CH ₃ ;
“COE” represents —COO—CH ₂ CH ₃ ;
“OCM” represents —OCO—CH ₃ ;
“OME” represents —O—CH ₃ ;
“SOT” represents a tosyl group;
“SNH” represents —SO ₂ NH—CH ₂ CH (CH ₂ CH ₃ ) ((CH ₂ ) ₃ CH ₃ );
“SN2” represents —SO ₂ N (CH ₃ ) ((CH ₂ ) ₇ CH ₃ ),
“CNM” represents —CONHCH ₃ ;
“CN2” represents —CON (CH ₃ ) C ₆ H ₅ ,
“NPH” represents —NHC ₆ H ₅ ,
"NOT" represents _{-N ((CH 2) 7 CH} 3) 2,
“NCO” represents —NHCO ((CH ₂ ) ₄ CH ₃ ),
“F” represents a fluorine atom,
“Cl” represents a chlorine atom,
“Br” represents a bromine atom;
“CN” represents a cyano group,
“NO2” represents a nitro group,
“SUA” represents —SO ₃ H;
“CBA” represents —CO ₂ H;
“CHO” represents —CHO,
“OCH” represents —OCOH;
“OH” represents —OH;
“SFM” represents —SO ₂ NH ₂ ;
“CBM” represents —CONH ₂ ;
“NH ₂ ” represents —NH ₂ ,
“NCH” represents —NHCOH.

  For example, compound (IZ3-1) is a compound represented by formula (IZ3-1).

As the compound (IZ3),
Compound (IZ3-1) to Compound (IZ3-120) and (IZ3-207) to Compound (IZ3-212) are preferred,
Compound (IZ3-1) to Compound (IZ3-120) are more preferable,
Compound (IZ3-1) to Compound (IZ3-60) are more preferable,
Compound (IZ3-1) to Compound (IZ3-36), Compound (IZ3-37) and Compound (IZ3-58) are even more preferable,
Compound (IZ3-1) to compound (IZ3-36) are particularly preferable, and compound (IZ3-1), compound (IZ3-6), compound (IZ3-8), compound (IZ3-11), compound (IZ3-14) ) And compound (IZ3-19) are more particularly preferred,
Compound (IZ3-1), compound (IZ3-6), and compound (IZ3-19) are particularly preferred.

Specific examples of the compound (IZ3) include compounds in which —SO ₃ M or —CO ₂ M is substituted on 1 to 3 hydrogen atoms contained in the compounds represented in Tables 1Z3 to 6Z3. For example, a compound in which 1 to 3 sulfo groups are bonded to the compound (IZ3-1) in Table 1Z3 is represented by the following structure. However, in the formula, — (SO ₃ H) means that any hydrogen atom of the compound (IZ3-1) in Table 1Z3 is substituted.

In the present invention,
Compounds in which 1 to 3 —SO ₃ M or —CO ₂ M are bonded to Compound (IZ3-1) to Compound (IZ3-120) and (IZ3-207) to Compound (IZ3-212) are preferable,
A compound in which 1 to 3 —SO ₃ M or —CO ₂ M is bonded to the compound (IZ3-1) to the compound (IZ3-120) is more preferable,
More preferred is a compound in which 1 to 3 —SO ₃ M or —CO ₂ M is bound to compound (IZ3-1) to compound (IZ3-60),
A compound in which 1 to 3 —SO ₃ M or —CO ₂ M is bonded to Compound (IZ3-1) to Compound (IZ3-36), Compound (IZ3-37) and Compound (IZ3-58) is further added. More preferred,
Particularly preferred is a compound in which 1 to 3 —SO ₃ M or —CO ₂ M is bound to compound (IZ3-1) to compound (IZ3-36),
The compound (IZ3-1), the compound (IZ3-6), the compound (IZ3-8), the compound (IZ3-11), the compound (IZ3-14) and the compound (IZ3-19) have 1 to 3 —SO More particularly preferred are compounds in which ₃ M or —CO ₂ M is bound,
A compound in which 1 to 3 —SO ₃ M or —CO ₂ M is bonded to the compound (IZ3-1), the compound (IZ3-6) or the compound (IZ3-19) is particularly preferable.

As the compound (IZ3), in the formula (IZ3),
R ^1Z3 is a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent selected from the group consisting of a hydrogen atom, —SO ₃ M and —CO ₂ M, —SO ₃ M or —CO _2. M,
R ^{2Z3 to} R ^5Z3 are each independently a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogen atom, —N (R ^102Z3 ) ₂ , a nitro group, or a hydrogen atom. A substituted hydrocarbon group having 1 to 20 carbon atoms, —NHCO—R ^102Z3 , —O—R ^102Z3 , —SO ₃ M or —CO ₂ M;
R ^6Z3 and R ^7Z3 each independently represent a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M; SO ₃ M or —CO ₂ M,
R ^102Z3 is a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M;
M is preferably a compound that is a hydrogen atom or an alkali metal atom,
R ^1Z3 is a hydrogen atom,
R ^{2Z3 to} R ^5Z3 are each independently a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, —N (R ^102Z3 ) ₂ , a nitro group, or a hydrogen atom, or a fluorine atom. A substituted hydrocarbon group having 1 to 10 carbon atoms, —NHCO—R ^102Z3 , —O—R ^102Z3 , —SO ₃ M or —CO ₂ M;
R ^6Z3 and R ^7Z3 are the same group, and a hydrocarbon having 1 to 10 carbon atoms which may have a hydrogen atom or a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M Group,
R ^102Z3 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M;
M is more preferably a compound that is a hydrogen atom or an alkali metal atom,
R ^1Z3 is a hydrogen atom,
R ^{2Z3 to} R ^5Z3 are each independently a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, —N (R ^102Z3 ) ₂ , a nitro group, a trifluoromethyl group, —O—R ^102Z3 , a -SO ₃ M or -CO ₂ M,
R ^6Z3 and R ^7Z3 are the same group, and are a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms,
R ^102Z3 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M;
A compound in which M is a hydrogen atom or an alkali metal atom is more preferable.

Compound (IZ3) is a compound represented by the formula (pt1Z3) (hereinafter may be referred to as a phthalonitrile compound) when R ^1Z3 is a hydrogen atom (hereinafter referred to as an alkoxide compound). In some cases, the compound represented by the formula (pt3Z3) and the compound represented by the formula (pt4Z3) can be further reacted in the presence of an acid. When R ^1Z3 is other than a hydrogen atom, the compound (IZ3) can be produced by further reacting with a compound represented by the formula (pt5Z3).

[In formula (pt1Z3), formula (pt2Z3), formula (pt3Z3), formula (pt4Z3), formula (pt5Z3) and formula (IZ3), R ^{1Z3 to} R ^7Z3 represent the same meaning as described above.
R ^14Z3 represents an alkyl group having 1 to 20 carbon atoms.
M ^1Z3 represents an alkali metal atom.
LG represents a halogen atom, a methanesulfonyloxy group, a toluenesulfonyloxy group, or a trifluoromethanesulfonyloxy group. ]

^Examples of the alkyl group having 1 to 20 carbon atoms represented by R ^14Z3 include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, a sec-butyl group, and a tert-butyl group. Is an alkyl group having 1 to 6 carbon atoms.
^Examples of the alkali metal atom represented by M ^1Z3 include a lithium atom, a sodium atom, and a potassium atom.

  The amount of the alkoxide compound used is usually 0.1 to 10 mol, preferably 0.2 to 5 mol, more preferably 0.3 to 3 mol, relative to 1 mol of the phthalonitrile compound. More preferably, it is 0.4-2 mol.

The amount of compound (pt3Z3) to be used is generally 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, further preferably 1 to 1 mol of phthalonitrile compound. ~ 2 moles.
The amount of compound (pt4Z3) to be used is generally 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, further preferably 1 to 1 mol of phthalonitrile compound. ~ 2 moles.

Examples of the acid include inorganic acids such as hydrochloric acid, hydrobromic acid, hydroiodic acid, sulfuric acid, nitric acid, fluorosulfonic acid and phosphoric acid; sulfonic acids such as methanesulfonic acid, trifluoromethanesulfonic acid and p-toluenesulfonic acid; Examples thereof include carboxylic acids such as acetic acid, citric acid, formic acid, gluconic acid, lactic acid, oxalic acid and tartaric acid, and preferably hydrochloric acid, hydrobromic acid, sulfuric acid, methanesulfonic acid, trifluoromethanesulfonic acid, p-toluenesulfonic acid and A carboxylic acid is mentioned, More preferably, an acetic acid is mentioned.
The usage-amount of an acid is 1-20 mol normally with respect to 1 mol of phthalonitrile compounds, Preferably it is 1-10 mol, More preferably, it is 1-8 mol, More preferably, it is 1-6 mol. is there.

The reaction of a phthalonitrile compound, an alkoxide compound, a compound (pt3Z3) and a compound (pt4Z3) is usually performed in the presence of a solvent.
Solvents include water; nitrile solvents such as acetonitrile; alcohol solvents such as methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol and 1-octanol; ether solvents such as tetrahydrofuran; ketone solvents such as acetone; Ester solvents such as ethyl; aliphatic hydrocarbon solvents such as hexane; aromatic hydrocarbon solvents such as toluene; halogenated hydrocarbon solvents such as methylene chloride and chloroform; amides such as N, N-dimethylformaldehyde and N-methylpyrrolidone Solvent: Sulfoxide solvents such as dimethyl sulfoxide are mentioned, preferably water, nitrile solvent, alcohol solvent, ether solvent, ketone solvent, ester solvent, aromatic hydrocarbon solvent, halogenated hydrocarbon solvent, amide solvent and sulfoxide solvent. And More preferably, water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, tetrahydrofuran, acetone, ethyl acetate, toluene, methylene chloride, chloroform, N, N-dimethylformaldehyde, N -Methylpyrrolidone and dimethyl sulfoxide are mentioned, More preferably, water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, acetone, methylene chloride, chloroform, N, N-dimethyl Examples include formaldehyde, N-methylpyrrolidone and dimethyl sulfoxide, with water, acetonitrile, methanol, ethanol and 2-propanol being particularly preferred.
The usage-amount of a solvent is 1-1000 mass parts normally with respect to 1 mass part of phthalonitrile compounds.

  The reaction temperature is usually 0 to 200 ° C, preferably 0 to 100 ° C, more preferably 0 to 70 ° C, and further preferably 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

The amount of compound (pt5Z3) to be used is generally 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, per 1 mol of compound (IZ3) in which R ^1Z3 is a hydrogen atom. More preferably, it is 1-2 mol.

  Moreover, when making a compound (pt5Z3) react, it is preferable that a base coexists. Examples of the base include organic bases such as triethylamine, 4- (N, N-dimethylamino) pyridine, pyridine and piperidine; metal alkoxides such as sodium methoxide, sodium ethoxide, sodium tert-butoxide and potassium tert-butoxide; butyllithium Organic metal compounds such as tert-butyl lithium and phenyl lithium; inorganic bases such as lithium hydroxide, sodium hydroxide and potassium hydroxide.

The amount of the base to be used is generally 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, per 1 mol of compound (IZ3) in which R ^1Z3 is a hydrogen atom. Preferably it is 1-2 mol.

The reaction of the compound (pt5Z3) is usually performed in the presence of a solvent. The solvent can be selected from the same range as described above.
The usage-amount of a solvent is ^1-1000 mass parts normally with respect to 1 mass part of compounds (IZ3) whose R ^<1Z3> is a hydrogen atom. The reaction temperature of the compound (pt5Z3) is usually -90 to 200 ° C, preferably -80 to 100 ° C, more preferably 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

When the compound (IZ3) does not have a sulfo group or —SO ₃ M ²² , the compound (IZ3) is reacted with a sulfonating agent such as fuming sulfuric acid or chlorosulfonic acid to react with the sulfo group or —SO ₃ M ^22. Can be introduced.
M ²² represents an alkali metal atom.
Examples of the alkali metal atom represented by M ²² include a lithium atom, a sodium atom, and a potassium atom.

The amount of SO ₃ in the oleum, the compound (IZ3) relative to 1 mol, usually 1 to 50 moles, preferably from 5 to 40 moles, more preferably from 5 to 30 moles, more preferably 5 to 25 mol.
The usage-amount of the sulfuric acid in fuming sulfuric acid is 1-200 mol normally with respect to 1 mol of compounds (IZ3), Preferably it is 10-100 mol, More preferably, it is 10-75 mol, More preferably, it is 10 ~ 50 moles.

  The amount of chlorosulfonic acid to be used is generally 1 to 500 mol, preferably 10 to 300 mol, more preferably 10 to 200 mol, further preferably 10 to 150 mol, per 1 mol of compound (IZ3). Is a mole.

  The reaction temperature of the sulfonation is usually from -20 to 200 ° C, preferably from -10 to 100 ° C, more preferably from 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

  The method for taking out the compound (IZ3) from the reaction mixture is not particularly limited, and it can be taken out by various known methods. For example, after completion of the reaction, the compound (IZ3) can be removed by filtering the reaction mixture. Further, after filtration, the obtained residue may be subjected to column chromatography or recrystallization. Further, after completion of the reaction, the solvent of the reaction mixture may be distilled off and purified by column chromatography.

<Compound (IZ4)>
Compound (IZ4) is a compound represented by Formula (IZ4).

[In the formula (IZ4),
R ^N1Z4 and R ^N2Z4 are independently of each other —CO—R ^102Z4 , —COO—R ^101Z4 , —OCO—R ^102Z4 , —COCO—R ^102Z4 , —O—R ^102Z4 , —SO ₂ —R ^101Z4 , —SO _{^{2 N (R 102Z4) 2,}} -CON (R 102Z4) 2, -N (R 102Z4) 2, -NHCO-R 102Z4, -NHCO-N (R 102Z4) 2, -NHCOOR 102Z4, -OCON (R 102Z4) ₂ , a halogen atom, a cyano group, a nitro group, —SO ₃ M, —CO ₂ M, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms, or an optionally substituted complex. Represents a cyclic group.
R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , and R ^7Z4 are each independently a hydrogen atom, —CO—R ^102Z4 , —COO—R ^101Z4 , —OCO—R ^102Z4 , —COCO ^{-R 102Z4, -O-R 102Z4,} -SO 2 -R 101Z4, -SO 2 N (R 102Z4) 2, -CON (R 102Z4) 2, -N (R 102Z4) 2, -NHCO-R 102Z4, - _{^{NHCO-N (R 102Z4) 2}} , -NHCOOR 102Z4, -OCON (R 102Z4) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , carbon atoms, which may have a substituent The heterocyclic group which may have a hydrocarbon group or a substituent of number 1-40 is represented.
R ^2Z4 and R ^3Z4 , R ^3Z4 and R ^4Z4 , and R ^4Z4 and R ^5Z4 may be bonded to each other to form a ring.
R ^101Z4 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102Z4 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
M represents a hydrogen atom or an alkali metal atom.
When a plurality of R ^101Z4 , R ^102Z4 and M are present, they may be the same or different.
A wavy line represents an E body or a Z body. ]

The hydrocarbon group represented by R ^N1Z4 , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^101Z4 and R ^102Z4 has 1 to 40 carbon atoms, Preferably it is 1-30, More preferably, it is 1-20, More preferably, it is 1-15, Most preferably, it is 1-10.

The hydrocarbon group having 1 to 40 carbon atoms represented by R ^N1Z4 , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^101Z4 and R ^102Z4 is an aliphatic carbon It may be a hydrogen group or an aromatic hydrocarbon group, and the aliphatic hydrocarbon group may be saturated or unsaturated, and may be a chain or an alicyclic ring.

The saturated or unsaturated chain hydrocarbon group represented by R ^N1Z4 , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^101Z4 and R ^102Z4 is a methyl group Linear alkyl groups such as ethyl group, propyl group, butyl group, pentyl group, hexyl group, heptyl group, octyl group, nonyl group, decyl group, undecyl group, dodecyl group, heptadecyl group, octadecyl group and icosyl group Etc .; Isopropyl group, isobutyl group, sec-butyl group, tert-butyl group, (2-ethyl) butyl group, isopentyl group, neopentyl group, tert-pentyl group, (1-methyl) pentyl group, (2-methyl) Pentyl, (1-ethyl) pentyl, (3-ethyl) pentyl, isohexyl, (5-methyl) hexyl, (2-ethyl) hexyl and (3-ethyl) E) Branched alkyl group such as heptyl group; vinyl group, 1-propenyl group, 2-propenyl group (allyl group), (1-methyl) ethenyl group, 2-butenyl group, 3-butenyl group, 1 , 3-butadienyl group, (1- (2-propenyl)) ethenyl group, (1,2-dimethyl) propenyl group, 2-pentenyl group and other alkenyl groups; The carbon number of the saturated or unsaturated chain hydrocarbon group is preferably 1 to 30, more preferably 1 to 20, still more preferably 1 to 15, particularly preferably 1 to 10, More preferably, it is 1-8, More preferably, it is 1-5. Especially, it is especially preferable that it is a C1-C10, More preferably, it is a C1-C8 linear or branched alkyl group, and a methyl group, an ethyl group, and a tert- butyl group are especially preferable.

The saturated or unsaturated alicyclic hydrocarbon group represented by R ^N1Z4 , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^101Z4 and R ^102Z4 is cyclo Propyl group, 1-methylcyclopropyl group, cyclobutyl group, cyclopentyl group, cyclohexyl group, cycloheptyl group, 1-methylcyclohexyl group, 2-methylcyclohexyl group, 3-methylcyclohexyl group, 4-methylcyclohexyl group, 1,2 -Dimethylcyclohexyl group, 1,3-dimethylcyclohexyl group, 1,4-dimethylcyclohexyl group, 2,3-dimethylcyclohexyl group, 2,4-dimethylcyclohexyl group, 2,5-dimethylcyclohexyl group, 2,6-dimethyl Cyclohexyl group, 3,4-dimethylcyclohexyl group, 3,5-dimethylcyclohexyl group 2,2-dimethylcyclohexyl group, 3,3-dimethylcyclohexyl group, 4,4-dimethylcyclohexyl group, cyclooctyl group, 2,4,6-trimethylcyclohexyl group, 2,2,6,6-tetramethylcyclohexyl group And cycloalkyl groups such as 3,3,5,5-tetramethylcyclohexyl group, 4-pentylcyclohexyl group, 4-octylcyclohexyl group, 4-cyclohexylcyclohexyl group; cyclohexenyl group (for example, cyclohex-2-ene, cyclohexa- 3-ene), cycloheptenyl group, cyclooctenyl group and other cycloalkenyl groups; norbornane group, adamantyl group, bicyclo [2.2.2] octane and the like. The carbon number of the saturated or unsaturated alicyclic hydrocarbon group is preferably 3 to 30, more preferably 3 to 20, still more preferably 4 to 20, and still more preferably 4 to 15. More preferably 5 to 15 and most preferably 5 to 10. Of these, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, and a cyclooctyl group are particularly preferable.

The aromatic hydrocarbon groups represented by R ^N1Z4 , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^101Z4 and R ^102Z4 include phenyl group, o-tolyl Group, m-tolyl group, p-tolyl group, 2-ethylphenyl group, 3-ethylphenyl group, 4-ethylphenyl group, 2,3-dimethylphenyl group, 2,4-dimethylphenyl group, 2,5- Dimethylphenyl group, 2,6-dimethylphenyl group, 3,4-dimethylphenyl group, 3,5-dimethylphenyl group, 4-vinylphenyl group, o-isopropylphenyl group, m-isopropylphenyl group, p-isopropylphenyl Group, o-tert-butylphenyl group, m-tert-butylphenyl group, p-tert-butylphenyl group, mesityl group, 4-ethylphenyl group, 4-butylphenyl group, -Pentylphenyl group, 2,6-bis (2-propyl) phenyl group, 4-cyclohexylphenyl group, 2,4,6-trimethylphenyl group, 4-octylphenyl group, 1-naphthyl group, 2-naphthyl group, Aromatic hydrocarbon groups such as 5,6,7,8-tetrahydro-1-naphthyl group, 5,6,7,8-tetrahydro-2-naphthyl group, fluorenyl group, phenanthryl group and anthryl group, pyrenyl group; etc. Is mentioned. The number of carbon atoms of the aromatic hydrocarbon group is preferably 6-30, more preferably 6-20, and even more preferably 6-15.

The hydrocarbon groups represented by R ^N1Z4 , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^101Z4 and R ^102Z4 are the hydrocarbon groups listed above (for example, A combination of an aromatic hydrocarbon group and at least one of a chain hydrocarbon group and an alicyclic hydrocarbon group), such as a benzyl group, a phenethyl group, a 1-methyl-1-phenylethyl group, etc. An arylalkenyl group such as a phenylethenyl group (phenylvinyl group); an arylalkynyl group such as a phenylethynyl group; a phenyl group to which one or more phenyl groups such as a biphenylyl group or a terphenylyl group are bonded; cyclohexylmethylphenyl Group, benzylphenyl group, (dimethyl (phenyl) methyl) phenyl group and the like.
The ^{groups represented} by R ^N1Z4 , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^101Z4 and R ^102Z4 are the hydrocarbon groups listed above (for example, chain-like) As a group combining a hydrocarbon group and an alicyclic hydrocarbon group), for example, a cyclopropylmethyl group, a cyclopropylethyl group, a cyclobutylmethyl group, a cyclobutylethyl group, a cyclopentylmethyl group, a cyclopentylethyl group, a cyclohexylmethyl group , An alkyl group to which one or more alicyclic hydrocarbon groups such as 2-methylcyclohexylmethyl group, cyclohexylethyl group, adamantylmethyl group and the like are bonded may be used.
These carbon numbers are preferably 4-30, more preferably 6-30, still more preferably 6-20, and preferably 4-20, more preferably 4-15. Especially preferably, it is 6-15.

The hydrocarbon groups represented by R ^N1Z4 , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^101Z4 and R ^102Z4 may have a substituent. . The substituent may be monovalent or divalent. In the divalent substituent, two bonds are preferably bonded to the same carbon atom to form a double bond.
As the monovalent substituent,
Methoxy group, ethoxy group, propoxy group, isopropoxy group, butoxy group, isobutoxy group, sec-butoxy group, tert-butoxy group, pentyloxy group, hexyloxy group, (2-ethyl) hexyloxy group, heptyloxy group, Octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, dodecyloxy group, (2-ethyl) hexyloxy group, icosyloxy group, 1-phenylethoxy group, 1-methyl-1-phenylethoxy group, phenyloxy group O-Tolyloxy group, 2,3-dimethylphenyloxy group, 2,4-dimethylphenyloxy group, 2,5-dimethylphenyloxy group, 2,6-dimethylphenyloxy group, 3,4-dimethylphenyloxy group 3,5-dimethylphenyloxy group, 2,2-dicia Phenyloxy group, 2,3-dicyanophenyloxy group, 2,4-dicyanophenyloxy group, 2,5-dicyanophenyloxy group, 2,6-dicyanophenyloxy group, 3,4-dicyanophenyloxy group, 3 , 5-dicyanophenyloxy group, 4-methoxyphenyloxy group, 2-methoxyphenyloxy group, 3-methoxyphenyloxy group, 4-ethoxyphenyloxy group, 2-ethoxyphenyloxy group, 3-ethoxyphenyloxy group, etc. And a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group represented by the following formula or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen) (Preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl) Oxy group derivatized group) is bonded to one side the like);

  Methylthio, ethylthio, propylthio, butylthio, tert-butylthio, pentylthio, hexylthio, (2-ethyl) hexylthio, heptylthio, octylthio, nonylthio, decylthio, undecylthio, dodecylthio, icosylthio A sulfanyl group to which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group, a phenylthio group and an o-tolylthio group is bonded;

Epoxy group, oxetanyl group, tetrahydrofuryl group, tetrahydropyranyl group;
Formyl group;
Acetyl group, propanoyl group, butanoyl group, 2,2-dimethylpropanoyl group, pentanoyl group, hexanoyl group, (2-ethyl) hexanoyl group, heptanoyl group, octanoyl group, nonanoyl group, decanoyl group, undecanoyl group, dodecanoyl group, A hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 11 carbon atoms) or a derivatized group thereof (for example, a carboxy group or a sulfo group) such as a henicosanoyl group, a benzoyl group, or a group represented by the following formula: , A carbonyl group to which a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), a group derived from an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. When the carbonyl group is an alkanoyl group, the carbon number is preferably 2 to 12);

  Methoxycarbonyl group, ethoxycarbonyl group, propoxycarbonyl group, butoxycarbonyl group, tert-butoxycarbonyl group, pentyloxycarbonyl group, hexyloxycarbonyl group, (2-ethyl) hexyloxycarbonyl group, heptyloxycarbonyl group, octyloxycarbonyl Group, nonyloxycarbonyl group, decyloxycarbonyl group, undecyloxycarbonyl group, dodecyloxycarbonyl group, icosyloxycarbonyl group, phenyloxycarbonyl group, o-tolyloxycarbonyl group and the like, and the following formulas A hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon number 10 oxycarbonyl group alkylsulfamoyl group (preferably octyl sulfamoyl group) were derivatized with such groups) is bonded to;

An amino group;
N-methylamino group, N, N-dimethylamino group, N-ethylamino group, N, N-diethylamino group, N-propylamino group, N, N-dipropylamino group, N-isopropylamino group, N, N-diisopropylamino group, N-butylamino group, N, N-dibutylamino group, N-isobutylamino group, N, N-diisobutylamino group, N-sec-butylamino group, N, N-disec-butyl Amino group, N-tert-butylamino group, N, N-ditert-butylamino group, N-pentylamino group, N, N-dipentylamino group, N- (1-ethylpropyl) amino group, N, N -Di (1-ethylpropyl) amino group, N-hexylamino group, N, N-dihexylamino group, N- (2-ethyl) hexylamino group, N, N-di (2-ethyl) Xylamino group, N-heptylamino group, N, N-diheptylamino group, N-octylamino group, N, N-dioctylamino group, N-nonylamino group, N, N-dinonylamino group, N-phenylamino group, N, N-diphenylamino group, N, N-ethylmethylamino group, N, N-propylmethylamino group, N, N-isopropylmethylamino group, N, N-butylmethylamino group, N-decylamino group, N , N-decylmethylamino group, N-undecylamino group, N, N-undecylmethylamino group, N-dodecylamino group, N, N-dodecylmethylamino group, N-icosylamino group, N, N-ico One of a silmethylamino group, an N, N-tert-butylmethylamino group, an N, N-phenylmethylamino group, and a group represented by the following formula: Two hydrocarbon groups having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or derivatized groups thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), 1 carbon atom An amino group substituted with 10 to 10 alkylsulfamoyl groups (preferably a group derivatized with an octylsulfamoyl group or the like);

A sulfamoyl group;
N-methylsulfamoyl group, N, N-dimethylsulfamoyl group, N-ethylsulfamoyl group, N, N-diethylsulfamoyl group, N-propylsulfamoyl group, N, N-dipropyls Rufamoyl group, N-isopropylsulfamoyl group, N, N-diisopropylsulfamoyl group, N-butylsulfamoyl group, N, N-dibutylsulfamoyl group, N-isobutylsulfamoyl group, N, N-diisobutylsulfamoyl group, N-sec-butylsulfamoyl group, N, N-disec-butylsulfamoyl group, N-tert-butylsulfamoyl group, N, N-ditert-butylsulfur Famoyl group, N-pentylsulfamoyl group, N, N-dipentylsulfamoyl group, N- (1-ethylpropyl) sulfamoyl group, , N-di (1-ethylpropyl) sulfamoyl group, N-hexylsulfamoyl group, N, N-dihexylsulfamoyl group, N- (2-ethyl) hexylsulfamoyl group, N, N-di ( 2-ethyl) hexylsulfamoyl group, N-heptylsulfamoyl group, N, N-diheptylsulfamoyl group, N-octylsulfamoyl group, N, N-dioctylsulfamoyl group, N, N -Octylmethylsulfamoyl group, N-nonylsulfamoyl group, N, N-dinonylsulfamoyl group, N-phenylsulfamoyl group, N, N-diphenylsulfamoyl group, N, N-ethylmethyl Sulfamoyl group, N, N-propylmethylsulfamoyl group, N, N-isopropylmethylsulfamoyl group, N, N-butylmethylsulfamoyl group N-decylsulfamoyl group, N, N-decylmethylsulfamoyl group, N-undecylsulfamoyl group, N, N-undecylmethylsulfamoyl group, N-dodecylsulfamoyl group, N, N-dodecylmethylsulfamoyl group, N-icosylsulfamoyl group, N, N-icosylmethylsulfamoyl group, N, N-tert-butylmethylsulfamoyl group, N, N-phenylmethylsulfa 1 or 2 hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a moyl group and the group represented by the following formula or a derivatized group thereof (for example, carboxy group, sulfo group) , A nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. A sulfamoyl group substituted with

  Formylamino group; acetylamino group, propanoylamino group, butanoylamino group, 2,2-dimethylpropanoylamino group, pentanoylamino group, hexanoylamino group, (2-ethyl) hexanoylamino group, heptanoyl Amino group, octanoylamino group, nonanoylamino group, decanoylamino group, undecanoylamino group, dodecanoylamino group, heicosanoylamino group, benzoylamino group, etc., and groups represented by the following formulae Or a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 12 carbon atoms) or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon number 1 10 to 10 alkylsulfamoyl groups (preferably octylsulfamoyl groups) and the like) Carbonyl amino group (if the alkanoylamino group the carbonyl group, the carbon number is preferably 1 to 12);

A hydroxy group;
Halogen atoms such as fluorine atom, chlorine atom, bromine atom and iodine atom;
Carboxy group, —CO ₂ M ² (M ² is alkali metal, preferably lithium, sodium, potassium); sulfo group, —SO ₃ M ² (M ² is alkali metal, preferably lithium, sodium, potassium); Nitro group A cyano group;

  Formyloxy group; acetoxy group, propanoyloxy group, butanoyloxy group, 2,2-dimethylpropanoyloxy group, pentanoyloxy group, hexanoyloxy group, (2-ethyl) hexanoyloxy group, heptanoyloxy Carbon such as a group, octanoyloxy group, nonanoyloxy group, decanoyloxy group, undecanoyloxy group, dodecanoyloxy group, heicosanoyloxy group, benzoyloxy group, and the group represented by the following formula A hydrocarbon group having 1 to 20 (preferably 1 to 10 carbons) or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), A group to which an alkyl sulfamoyl group (preferably a group derivatized with an octyl sulfamoyl group) is bound. Boniruokishi group (if the alkanoyloxy group and the carbonyl group, the carbon number is preferably 1 to 10);

  Methylsulfonyl group, ethylsulfonyl group, propylsulfonyl group, butylsulfonyl group, pentylsulfonyl group, hexylsulfonyl group, (2-ethyl) hexylsulfonyl group, heptylsulfonyl group, octylsulfonyl group, nonylsulfonyl group, decylsulfonyl group, un Decylsulfonyl group, dodecylsulfonyl group, icosylsulfonyl group, phenylsulfonyl group, p-tolylsulfonyl group and the like, and groups having 1 to 20 carbon atoms (preferably having 1 to 10 carbon atoms) such as groups represented by the following formulae: Hydrocarbon group or derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group) A group derivatized with a sulfonyl group) ;

A carbamoyl group;
N-methylcarbamoyl group, N, N-dimethylcarbamoyl group, N-ethylcarbamoyl group, N, N-diethylcarbamoyl group, N-propylcarbamoyl group, N, N-dipropylcarbamoyl group, N-isopropylcarbamoyl group, N , N-diisopropylcarbamoyl group, N-butylcarbamoyl group, N, N-dibutylcarbamoyl group, N-isobutylcarbamoyl group, N, N-diisobutylcarbamoyl group, N-sec-butylcarbamoyl group, N, N-disec- Butylcarbamoyl group, N-tert-butylcarbamoyl group, N, N-ditert-butylcarbamoyl group, N-pentylcarbamoyl group, N, N-dipentylcarbamoyl group, N- (1-ethylpropyl) carbamoyl group, N, N-di (1-ethylpropyl) carba Yl group, N-hexylcarbamoyl group, N, N-dihexylcarbamoyl group, N- (2-ethyl) hexylcarbamoyl group, N, N-di (2-ethyl) hexylcarbamoyl group, N-heptylcarbamoyl group, N, N-diheptylcarbamoyl group, N-octylcarbamoyl group, N, N-dioctylcarbamoyl group, N-nonylcarbamoyl group, N, N-octylmethylcarbamoyl group, N, N-octylbutylcarbamoyl group, N, N-di Nonylcarbamoyl group, N-phenylcarbamoyl group, N, N-diphenylcarbamoyl group, N, N-ethylmethylcarbamoyl group, N, N-propylmethylcarbamoyl group, N, N-isopropylmethylcarbamoyl group, N, N-butyl Methylcarbamoyl group, N-decylcarbamoyl group, N, N Decylmethylcarbamoyl group, N-undecylcarbamoyl group, N, N-undecylmethylcarbamoyl group, N-dodecylcarbamoyl group, N, N-dodecylmethylcarbamoyl group, N-icosylcarbamoyl group, N, N-icosyl 1 or 2 carbon atoms (preferably carbon atoms) such as a methylcarbamoyl group, an N, N-tert-butylmethylcarbamoyl group, an N, N-phenylmethylcarbamoyl group, and a group represented by the following formula A hydrocarbon group having 1 to 10) or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably A carbamoyl group substituted with a group derivatized with an octylsulfamoyl group) or the like;

  Trifluoromethyl group, perfluoroethyl group, perfluoropropyl group, perfluoroisopropyl group, perfluorobutyl group, perfluoropentyl group, perfluorohexyl group, perfluoroheptyl group, perfluorooctyl group, perfluorononyl group, A carbon atom having 1 to 20 carbon atoms in which all hydrogen atoms such as perfluorodecyl group, perfluoroundecyl group, perfluorododecyl group, perfluoroicosyl group, perfluorocyclohexyl group and perfluorophenyl group are substituted with fluorine atoms. A hydrogen group;

  Perfluoroethylmethyl group, perfluoropropylmethyl group, perfluoroisopropylmethyl group, perfluorobutylmethyl group, perfluoropentylmethyl group, perfluorohexylmethyl group, perfluoroheptylmethyl group, perfluorooctylmethyl group, perfluoro A straight chain having 1 to 20 carbon atoms in which all hydrogen atoms such as nonylmethyl group, perfluorodecylmethyl group, perfluoroundecylmethyl group, perfluorododecylmethyl group and perfluoroicosylmethyl group are substituted with fluorine atoms Or a hydrocarbon group having 1 to 20 carbon atoms substituted by a branched alkyl group;

  1 to 20 carbon atoms (preferably carbon atoms) in which part of hydrogen atoms such as 2-fluorophenyl group, 3-fluorophenyl group, 4-fluorophenyl group and 2,4,6-trifluorophenyl group are substituted with fluorine. 1-10) hydrocarbon radicals;

-CO-SH, -CO-S- CH 3, -CO-S-CH 2 CH 3, -CO-S-CH 2 -CH 2 -CH 3, -CO-S-CH 2 -CH 2 -CH 2 A thiocarbonyl group bonded to an alkyl group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as —CH _3; and an aryl group having 6 to 20 carbon atoms such as —CO—S—C ₆ H _5. A thiocarbonyl group;

  * -COCO-R as represented by the following formula (wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, satisfying 1 to 20 carbon atoms among the hydrocarbon groups mentioned above) Or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably octyl sulfamoyl group) A group derived from, etc.)

* -NRCONR ₂ represented by the following formula (wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, those satisfying 1 to 20 carbon atoms among the hydrocarbon groups mentioned above) ) Or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group), etc. And the R may be the same or different from each other and may be bonded to each other to form a ring);

* -OCONR ₂ represented by the following formula (wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, those satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above) ) Or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group), etc. And the R may be the same or different from each other and may be bonded to each other to form a ring);

  * -NRCOOR as represented by the following formula (wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, those satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above)) Or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. A derivatized group), wherein the Rs may be the same or different from each other and may be bonded to each other to form a ring;

_{* -OP (O) (OCH 3} ) in such _{2 * -OP (O) (OR} ) 2 ( wherein, R represents a hydrogen atom, a hydrocarbon group (e.g., hydrocarbon groups mentioned above having 1 to 20 carbon atoms Or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms) A group derived from (preferably an octylsulfamoyl group) or the like, and the Rs may be the same or different from each other, and may be bonded to each other to form a ring;
* -SiR ₃ (* -Si (CH ₃ ) ₃ , * -Si (CH ₂ CH ₃ ) ₃ , * -Si (C ₆ H ₅ ) ₃ and * -Si (CH (CH ₃ ) ₂ ) ₃ In the formula, R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, those satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivatizing group thereof (for example, a carboxy group, sulfo group). A group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), a C1-C10 alkylsulfamoyl group (preferably an octylsulfamoyl group) and the like, and the R is Groups that may be the same or different from each other and may be bonded to each other to form a ring);
Etc.

As the divalent substituent, an oxo group, a thioxo group, an imino group, an imino group substituted with an alkyl group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms), and an aryl group having 6 to 20 carbon atoms are substituted. And imino groups. Examples of the imino group substituted with an alkyl group include CH ₃ —N═, CH ₃ —CH ₂ —N═, CH ₃ — (CH ₂ ) ₂ —N═, and CH ₃ — (CH ₂ ) ₃ —N =. Can be mentioned. Examples of the imino group substituted with an aryl group include C ₆ H ₅ —N═.

The substituent of the hydrocarbon group having 1 to 40 carbon atoms is preferably a substituent of group s1. The derivatizing groups shown below are a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), and the like. A derivatized group is preferred.
[Group s1]
An oxy group having a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof bonded to one side;
A carbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
An oxycarbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
An amino group;
An amino group substituted by one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
A sulfamoyl group;
A sulfamoyl group substituted with one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
A carbonylamino group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
A hydroxy group;
A halogen atom;
-CO ₂ M (preferably a carboxy group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom.);
-SO ₃ M (preferably a sulfo group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom.);
A nitro group;
A cyano group;
A carbonyloxy group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
A sulfonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
A carbamoyl group;
A carbamoyl group substituted with one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
A hydrocarbon group having 1 to 20 carbon atoms in which all of the hydrogen atoms are substituted by fluorine atoms;
A hydrocarbon group having 1 to 20 carbon atoms substituted with a linear or branched alkyl group having 1 to 20 carbon atoms in which all of the hydrogen atoms are substituted with fluorine atoms;
A hydrocarbon group having 1 to 20 carbon atoms in which a part of hydrogen atoms is substituted by fluorine;
Oxo group

The substituent of the hydrocarbon group having 1 to 40 carbon atoms is more preferably a substituent of group s2.
[Group s2]
An oxy group having a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof bonded to one side;
A carbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
An oxycarbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
An amino group;
An amino group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof;
A sulfamoyl group;
A sulfamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof;
A carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
A hydroxy group;
Fluorine atom, chlorine atom, bromine atom;
-CO ₂ M (preferably a carboxy group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom.);
-SO ₃ M (preferably a sulfo group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom.);
A nitro group;
A cyano group;
A carbonyloxy group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
A sulfonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
A carbamoyl group;
A carbamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof;
A hydrocarbon group having 1 to 10 carbon atoms in which all of the hydrogen atoms are substituted by fluorine atoms;
A hydrocarbon group having 1 to 10 carbon atoms substituted by a linear or branched alkyl group having 1 to 10 carbon atoms in which all of the hydrogen atoms are substituted with fluorine atoms;
A hydrocarbon group having 1 to 10 carbon atoms in which a part of hydrogen atoms is substituted by fluorine;
Oxo group

As a hydrocarbon group having 1 to 40 carbon atoms having a substituent represented by R ^N1Z4 , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^101Z4 and R ^102Z4 Includes a C1-C40 hydrocarbon group having a monovalent or divalent substituent, preferably a saturated or unsaturated chain having 1 to 30 carbon atoms having a monovalent or divalent substituent. Hydrocarbon group, C3-C30 saturated or unsaturated alicyclic hydrocarbon group having a monovalent or divalent substituent, C6-C30 aromatic carbonization having a monovalent or divalent substituent A group in which a hydrogen group or a hydrocarbon group is combined, and examples thereof include a group having 1 to 30 carbon atoms having a monovalent or divalent substituent,
More preferably, a saturated or unsaturated chain hydrocarbon group having 1 to 20 carbon atoms having a substituent of group s1, or a saturated or unsaturated alicyclic hydrocarbon group having 3 to 20 carbon atoms having a substituent of group s1. A group having 6 to 20 carbon atoms having a substituent of group s1 or a combination of hydrocarbon groups, and a group having 1 to 20 carbon atoms having a substituent of group s1,
Particularly preferably, it is a saturated or unsaturated chain hydrocarbon group having 1 to 15 carbon atoms having a substituent of group s2, or a saturated or unsaturated alicyclic hydrocarbon group having 3 to 15 carbon atoms having a substituent of group s2. , A group having a substituent of group s2 and a combination of an aromatic hydrocarbon group having 6 to 15 carbon atoms or a hydrocarbon group, and a group having 1 to 15 carbon atoms having a substituent of group s2.

The heterocyclic group represented by R ^N1Z4 , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^101Z4 and R ^102Z4 may be a single ring. The ring may be polycyclic, and is preferably a heterocyclic ring containing a hetero atom as a ring component. Examples of the hetero atom include a nitrogen atom, an oxygen atom, and a sulfur atom.
The number of carbon atoms of the heterocyclic group is preferably 3-30, more preferably 3-22, still more preferably 3-20, still more preferably 3-18, and even more preferably 3-3. 15 and particularly preferably 3-14.

As a heterocyclic ring containing a nitrogen atom,
Monocyclic saturated heterocycles such as aziridine, azetidine, pyrrolidine, piperidine and piperazine;
Pyrrol such as 2,5-dimethylpyrrole, pyrazole such as 2-methylpyrazole and 3-methylpyrazole, 5-membered unsaturated heterocyclic ring such as imidazole, 1,2,3-triazole and 1,2,4-triazole ;
6-membered unsaturated heterocycles such as pyrimidines such as pyridine, pyridazine, 6-methylpyrimidine, pyrazines and 1,3,5-triazines;
Indazole, indoline, isoindoline, indole, indolizine, benzimidazole, quinoline, isoquinoline, quinoxaline such as 5,6,7,8-tetrahydro (3-methyl) quinoxaline, 3-methylquinoxaline, quinazoline, cinnoline, phthalazine, naphthyridine , Condensed bicyclic heterocycles such as purine, pteridine, benzopyrazole, benzopiperidine;
And condensed tricyclic heterocycles such as carbazole, acridine and phenazine.

As a heterocyclic ring containing an oxygen atom,
Monocyclic saturated heterocycles such as oxirane, oxetane, tetrahydrofuran, tetrahydropyran, 1,3-dioxane and 1,4-dioxane, 1-cyclopentyldioxolane;
Bicyclic saturated heterocycles such as 1,4-dioxaspiro [4.5] decane, 1,4-dioxaspiro [4.5] nonane;
Lactone heterocycles such as α-acetolactone, β-propiolactone, γ-butyrolactone, γ-valerolactone and δ-valerolactone;
5-membered unsaturated heterocyclic rings such as furan such as 2,3-dimethylfuran and 2,5-dimethylfuran;
6-membered unsaturated heterocyclic rings such as 2H-pyran and 4H-pyran;
Fused bicyclic heterocycles such as 1-benzofuran, benzopyran such as 4-methylbenzopyran, benzodioxole, chroman and isochroman;
And condensed tricyclic heterocycles such as xanthene and dibenzofuran;

As a heterocyclic ring containing a sulfur atom,
5-membered saturated heterocyclic ring such as dithiolane;
6-membered saturated heterocyclic rings such as thiane, 1,3-dithiane, 2-methyl-1,3-dithiane;
5-membered unsaturated heterocyclic rings such as thiophene such as 3-methylthiophene and 2-carboxythiophene, benzothiopyran such as 4H-thiopyran and benzotetrahydrothiopyran;
Condensed bicyclic heterocycles such as benzothiophene;
And condensed tricyclic heterocycles such as thianthrene and dibenzothiophene.

As a heterocyclic ring containing a nitrogen atom and an oxygen atom,
Monocyclic saturated heterocycles such as morpholine, 2-pyrrolidone, 2-methyl-2-pyrrolidone, 2-piperidone and 2-methyl-2-piperidone;
Monocyclic unsaturated heterocycles such as oxazole such as 4-methyloxazole, isoxazole such as 2-methylisoxazole and 3-methylisoxazole;
Condensed bicyclic heterocycles such as benzoxazole, benzisoxazole, benzoxazine, benzodioxane, benzimidazoline;
And condensed tricyclic heterocycles such as phenoxazine.

As a heterocyclic ring containing a nitrogen atom and a sulfur atom,
Monocyclic heterocycles such as thiazole such as 3-methylthiazole and 2,4-dimethylthiazole;
Fused bicyclic heterocycles such as benzothiazole;
Condensed tricyclic heterocycles such as phenothiazine; and the like.

  The heterocycle may be a group in which the above-described hydrocarbon groups are combined, and examples thereof include a tetrahydrofurylmethyl group.

Furthermore, the heterocyclic ring may be represented by the following formula.

The heterocyclic group may be a heterocyclic group formed by combining two or more of R ^{1Z4 to} R ^5Z4 . Such a heterocyclic group has two or more ring structures together with the benzene ring to which R ^{1Z4 to} R ^5Z4 are bonded. Examples of the two or more ring structures include structures of the following formulas.

  In addition, the bonding position of the above heterocyclic ring is a portion from which an arbitrary hydrogen atom contained in each ring is eliminated.

The heterocyclic group represented by R ^N1Z4 , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^101Z4 and R ^102Z4 may have a substituent. . The substituent has hydrocarbon groups represented by R ^N1Z4 , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^101Z4 and R ^102Z4. The same as the substituent which may be good. When the heterocyclic ring contains a nitrogen atom as a constituent element, the above-described hydrocarbon group may be bonded to the nitrogen atom as a substituent.
Preferred examples of the substituent include hydrocarbon groups represented by R ^N1Z4 , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^101Z4 and R ^102Z4. The same thing as the preferable thing of the substituent which may be carried out is mentioned.
The heterocyclic group having a substituent represented by R ^N1Z4 , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^101Z4 and R ^102Z4 is monovalent or 2 A heterocyclic group having a valent substituent, preferably a heterocyclic group having a substituent of group s1, and more preferably a heterocyclic group having a substituent of group s2.
The hydrocarbon group or heterocyclic group may have one or more substituents (first substituent), and the two or more substituents are independent of each other. They may be the same or different. Further, the first substituent may have another substituent (second substituent) bonded to a hydrocarbon group contained in a part thereof. The second substituent can be selected from the same groups as the first substituent.

R ^N1Z4 , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 -CO-R ^102Z4 , -COO-R ^101Z4 , -OCO-R ^102Z4 , -COCO- ^{R 102Z4, -O-R 102Z4,} -SO 2 -R 101Z4, -SO 2 N (R 102Z4) 2, -CON (R 102Z4) 2, -N (R 102Z4) 2, -NHCO-R 102Z4, -NHCO _{^{-N (R 102Z4) 2, -NHCOOR}} 102Z4, -OCON (R 102Z4) 2, halogen atom, -SO ₃ M, for -CO ₂ M will be described.

As —CO—R ^102Z4 , formyl group; acetyl group, propanoyl group, butanoyl group, 2,2-dimethylpropanoyl group, pentanoyl group, hexanoyl group, (2-ethyl) hexanoyl group, heptanoyl group, octanoyl group, nonanoyl A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof, such as a group, a decanoyl group, an undecanoyl group, a dodecanoyl group, a heicosanoyl group, a benzoyl group, and the like A derivatized group (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. Group), the number of carbon atoms is 2 to 41 when the carbonyl group is an acyl group. ) And include groups corresponding to the -CO-R ^102Z4 in the compounds shown in Table 1Z4~ Table 20Z4 -CO-R ^102Z4 Table 1-966 of the relevant group and Japanese Patent Application No. 2017-016290 to the compounds shown in Preferably, the hydrocarbon group having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms) or a carbonyl group to which the derivatizing group is bonded (when the carbonyl group is an alkanoyl group, the carbon number is more preferably 2 to 12) and groups corresponding to —CO—R ^102Z4 in the compounds shown in Tables 1Z4 to ^20Z4 .

-COO-R ^101Z4 includes a methoxycarbonyl group, an ethoxycarbonyl group, a propoxycarbonyl group, a tert-butoxycarbonyl group, a butoxycarbonyl group, a pentyloxycarbonyl group, a hexyloxycarbonyl group, a (2-ethyl) hexyloxycarbonyl group, Heptyloxycarbonyl group, octyloxycarbonyl group, nonyloxycarbonyl group, decyloxycarbonyl group, undecyloxycarbonyl group, dodecyloxycarbonyl group, phenyloxycarbonyl group, icosyloxycarbonyl group, etc. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon, etc. Number 1 0 alkylsulfamoyl group group (preferably octyl sulfamoyl group) corresponding to the -COO-R ^102Z4 in compounds derivatized groups) is shown in oxycarbonyl group and Tables 1Z4~ table 20Z4 bound by such And groups corresponding to —COO—R ^102Z4 in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290, preferably a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof bonded thereto. Examples thereof include an oxycarbonyl group and groups corresponding to —COO—R ^102Z4 in the compounds shown in Tables 1Z4 to ^20Z4 .

As -OCO-R ^102Z4 , ^formyloxy group; acetoxy group, propanoyloxy group, butanoyloxy group, 2,2-dimethylpropanoyloxy group, pentanoyloxy group, hexanoyloxy group, (2-ethyl) Hexanoyloxy group, heptanoyloxy group, octanoyloxy group, nonanoyloxy group, decanoyloxy group, undecanoyloxy group, dodecanoyloxy group, heicosanoyloxy group, benzoyloxy group, and the above formula A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom) ), An alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. If the reduction radicals) is bonded to a carbonyl group (said carbonyl group to an acyloxy group, a carbon number of 2-41), as well as -OCO-R ^102Z4 in the compounds shown in Table 1Z4~ Table 20Z4 Corresponding groups and groups shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290 include groups corresponding to —OCO—R ^102Z4 , preferably 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms). ) Or a carbonyloxy group to which the derivatizing group is bonded (when the carbonyloxy group is an acyloxy group, the number of carbon atoms is more preferably 2 to 12), and Tables 1Z4 to 20Z4. ^Examples of the compound include a group corresponding to -OCO-R ^102Z4 .

-COCO-R ^102Z4 includes methyl oxalyl group, ethyl oxalyl group, propyl oxalyl group, butyl oxalyl group, pentyl oxalyl group, hexyl oxalyl group, (2-ethyl) hexyl oxalyl group, heptyl oxalyl group, octyl oxalyl group, nonyl Oxalyl group, decyloxalyl group, undecyloxalyl group, dodecyloxalyl group, icosyloxalyl group, cyclopentyloxalyl group, cyclohexyloxalyl group, phenyloxalyl group, p-tolyloxalyl group, etc., and groups represented by the above formula A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), 10 alkyl sulfamos Group and JP Le group (preferably octyl sulfamoyl group) corresponding to the -COCO-R ^102Z4 In the compound represented oxalyl groups, as well as Table 1Z4~ Table 20Z4 derivatized group, etc.) are bonded 2017-016290 In the compounds shown in Tables 1 to ⁹⁶⁶ , groups corresponding to —COCO—R ^102Z4 are ^exemplified .

-O-R ^102Z4 includes a hydroxy group; a methoxy group, an ethoxy group, a propoxy group, an isopropoxy group, a butoxy group, an isobutoxy group, a sec-butoxy group, a tert-butoxy group, a pentyloxy group, a hexyloxy group, and heptyloxy Group, octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, dodecyloxy group, (2-ethyl) hexyloxy group, icosyloxy group, 1-phenylethoxy group, 1-methyl-1-phenylethoxy group, phenyl Oxy group, 2,3-dimethylphenyloxy group, 2,4-dimethylphenyloxy group, 2,5-dimethylphenyloxy group, 2,6-dimethylphenyloxy group, 3,4-dimethylphenyloxy group, 3, 5-dimethylphenyloxy group, 2,2-dicyanophenyloxy 2,3-dicyanophenyloxy group, 2,4-dicyanophenyloxy group, 2,5-dicyanophenyloxy group, 2,6-dicyanophenyloxy group, 3,4-dicyanophenyloxy group, 3,5- Dicyanophenyloxy group, 4-methoxyphenyloxy group, 2-methoxyphenyloxy group, 3-methoxyphenyloxy group, 4-ethoxyphenyloxy group, 2-ethoxyphenyloxy group, 3-ethoxyphenyloxy group, etc. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group represented by the formula: or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably Chlorine atoms), derivatized with alkyl sulfamoyl groups having 1 to 10 carbon atoms (preferably octylsulfamoyl groups), etc. Groups) -O-R ^102Z4 in the compound represented by -O-R ^102Z4 Table 1-966 of the relevant group and Japanese Patent Application No. 2017-016290 in the the compound represented in group and Table 1Z4~ table 20Z4 bound is A group corresponding to —O—R ^102Z4 in the compounds shown in Tables 1Z4 to 20Z4 and preferably an oxy group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded. Etc.

As —SO ₂ —R ^101Z4 , methylsulfonyl group, ethylsulfonyl group, propylsulfonyl group, butylsulfonyl group, pentylsulfonyl group, ^{hexylsulfonyl} group, (2-ethyl) ^{hexylsulfonyl} group, ^{heptylsulfonyl} group, octylsulfonyl group, 1 to 40 carbon atoms such as a nonylsulfonyl group, a decylsulfonyl group, an undecylsulfonyl group, a dodecylsulfonyl group, an icosylsulfonyl group, a phenylsulfonyl group, a p-tolylsulfonyl group, and a group represented by the above formula Preferably a hydrocarbon group having 1 to 20 carbon atoms or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms. (Preferably octylsulfamoyl group) -SO ₂ -R in the compounds represented by -SO ₂ -R ^102Z4 Table 1-966 of the relevant group and Japanese Patent Application No. 2017-016290 in the compound group) is shown in the sulfonyl group and Table 1Z4~ table 20Z4 bound ^And a group corresponding to ^102Z4 , preferably a hydrocarbon group having 1 to 10 carbon atoms or a sulfonyl group to which a derivatizing group thereof is bonded, or a compound shown in Tables 1Z4 to ^20Z4 , corresponding to —SO ₂ —R ^102Z4 And the like.

—SO ₂ N (R ^102Z4 ) ₂ includes a sulfamoyl group;
N-methylsulfamoyl group, N-ethylsulfamoyl group, N-propylsulfamoyl group, N-isopropylsulfamoyl group, N-butylsulfamoyl group, N-isobutylsulfamoyl group, N- sec-butylsulfamoyl group, N-tert-butylsulfamoyl group, N-pentylsulfamoyl group, N- (1-ethylpropyl) sulfamoyl group, N-hexylsulfamoyl group, N- (2- Ethyl) hexylsulfamoyl group, N-heptylsulfamoyl group, N-octylsulfamoyl group, N-nonylsulfamoyl group, N-decylsulfamoyl group, N-undecylsulfamoyl group, N- Dodecylsulfamoyl group, N-icosylsulfamoyl group, N-phenylsulfamoyl group, etc., and groups represented by the above formula A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon number In a sulfamoyl group substituted with 1 to 10 alkylsulfamoyl groups (preferably a group derivatized with an octylsulfamoyl group, etc.) and the compounds shown in Tables 1Z4 to 20Z4, —SO ₂ NH (R ^102Z4X ) (Provided that R ^102Z4X is the same as R ^102Z4 except that it does not become a hydrogen atom) and compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290, —SO ₂ NH (R ^102Z4X ) (However, R ^102Z4X is the same as R ^102Z4 except that it does not become a hydrogen atom), etc .;

N, N-dimethylsulfamoyl group, N, N-ethylmethylsulfamoyl group, N, N-diethylsulfamoyl group, N, N-propylmethylsulfamoyl group, N, N-dipropylsulfamoyl group Group, N, N-isopropylmethylsulfamoyl group, N, N-diisopropylsulfamoyl group, N, N-tert-butylmethylsulfamoyl group, N, N-diisobutylsulfamoyl group, N, N- Disec-butylsulfamoyl group, N, N-ditert-butylsulfamoyl group, N, N-butylmethylsulfamoyl group, N, N-dibutylsulfamoyl group, N, N-dipentylsulfa Moyl group, N, N-di (1-ethylpropyl) sulfamoyl group, N, N-dihexylsulfamoyl group, N, N-di (2-ethyl) hexyls Famoyl group, N, N-diheptylsulfamoyl group, N, N-octylmethylsulfamoyl group, N, N-dioctylsulfamoyl group, N, N-dinonylsulfamoyl group, N, N-decyl Methylsulfamoyl group, N, N-undecylmethylsulfamoyl group, N, N-dodecylmethylsulfamoyl group, N, N-icosylmethylsulfamoyl group, N, N-phenylmethylsulfamoyl Two hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group, N, N-diphenylsulfamoyl group, and the group represented by the above formula, or a derivatized group thereof ( For example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably octyl sulfamoyl) ^{_{) -SO 2 N (R 102Z4X)}} 2 ( provided that at sulfamoyl groups and compounds shown in Table 1Z4~ table 20Z4 substituted with derivatized groups) in such, except that R ^102Z4X is not a hydrogen atom, R in the compounds shown in Table 1 to 966 of the corresponding group and Japanese Patent Application No. 2017-016290 the same as is) and _{^{102Z4 -SO 2 N (R 102Z4X)}} 2 ( where except that R ^102Z4X is not a hydrogen atom, The same as R ^102Z4 ), and the like.
Preferably, it corresponds to —SO ₂ N (R ^102Z4 ) ₂ in one or two sulfamoyl groups substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or derivatized groups thereof, and compounds shown in Tables 1Z4 to ^20Z4. Groups and the like.

^—CON (R ^102Z4 ) ₂ includes a carbamoyl group;
N-methylcarbamoyl group, N-ethylcarbamoyl group, N-propylcarbamoyl group, N-isopropylcarbamoyl group, N-butylcarbamoyl group, N-isobutylcarbamoyl group, N-sec-butylcarbamoyl group, N-tert-butylcarbamoyl Group, N-pentylcarbamoyl group, N- (1-ethylpropyl) carbamoyl group, N-hexylcarbamoyl group, N- (2-ethyl) hexylcarbamoyl group, N-heptylcarbamoyl group, N-octylcarbamoyl group and N- One of nonylcarbamoyl group, N-decylcarbamoyl group, N-undecylcarbamoyl group, N-dodecylcarbamoyl group, N-icosylcarbamoyl group, N-phenylcarbamoyl group, etc., and a group represented by the above formula 1 to 40 carbon atoms (preferably charcoal A hydrocarbon group of 1 to 20) or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably In the compounds shown in Tables 1Z4 to 20Z4 and —CONH (R ^102Z4X ) (provided that R ^102Z4X does not become a hydrogen atom), the carbamoyl group substituted with a group derivatized with an octylsulfamoyl group) or the like) , -CONH (R ^102Z4X) (provided that the compounds shown in Table 1 to 966 groups and Japanese Patent Application No. 2017-016290 corresponding to same in a) and R ^102Z4, except that R ^102Z4X is not a hydrogen atom, R ^The same as ^102Z4 )

N, N-dimethylcarbamoyl group, N, N-ethylmethylcarbamoyl group, N, N-diethylcarbamoyl group, N, N-propylmethylcarbamoyl group, N, N-dipropylcarbamoyl group, N, N-isopropylmethylcarbamoyl Group, N, N-diisopropylcarbamoyl group, N, N-tert-butylmethylcarbamoyl group, N, N-diisobutylcarbamoyl group, N, N-disec-butylcarbamoyl group, N, N-ditert-butylcarbamoyl group N, N-butylmethylcarbamoyl group, N, N-dibutylcarbamoyl group, N, N-butyloctylcarbamoyl group, N, N-dipentylcarbamoyl group, N, N-di (1-ethylpropyl) carbamoyl group, N , N-dihexylcarbamoyl group, N, N-di (2-ethyl) hexyl Rucarbamoyl group, N, N-diheptylcarbamoyl group, N, N-octylmethylcarbamoyl group, N, N-dioctylcarbamoyl group, N, N-dinonylcarbamoyl group, N, N-decylmethylcarbamoyl group, N, N -Undecylmethylcarbamoyl group, N, N-dodecylmethylcarbamoyl group, N, N-icosylmethylcarbamoyl group, N, N-phenylmethylcarbamoyl group, N, N-diphenylcarbamoyl group, etc. Two hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group to be synthesized or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom) ), A C 1-10 alkylsulfamoyl group (preferably an octylsulfamoyl group), etc. Groups) -CON In the compounds shown in carbamoyl group and Tables 1Z4~ table 20Z4 substituted with (R ^102Z4X) ₂ (where except that R ^102Z4X is not a hydrogen atom, corresponding to the same in a) and R ^102Z4 And -CON (R ^102Z4X ) ₂ (provided that R ^102Z4X is the same as R ^102Z4 except that it does not become a hydrogen atom) in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290. Groups, etc.
Preferably, one or two hydrocarbon groups having 1 to 10 carbon atoms or a carbamoyl group substituted with a derivatizing group thereof, and a group corresponding to ^—CON (R ^102Z4 ) ₂ in the compounds shown in Tables 1Z4 to 20Z4, etc. Is mentioned.

—N (R ^102Z4 ) ₂ includes an amino group;
N-methylamino group, N-ethylamino group, N-propylamino group, N-isopropylamino group, N-butylamino group, N-isobutylamino group, N-sec-butylamino group, N-tert-butylamino Group, N-pentylamino group, N-hexylamino group, N- (2-ethyl) hexylamino group, N-heptylamino group, N-octylamino group, N-nonylamino group, N-decylamino group, N-un A decylamino group, an N-dodecylamino group, an N-icosylamino group, an N-phenylamino group, and the like, and one of 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group represented by the above formula A hydrocarbon group or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl group having 1 to 10 carbon atoms; -NH (R ^102Z4X) (provided that the amino group and Tables 1Z4~ Table 20Z4 compounds shown in substituted with Amoiru group (preferably octyl sulfamoyl group) were derivatized with such groups), R ^102Z4X a hydrogen atom do not except that become, in the compounds shown in Table 1 to 966 groups and Japanese Patent Application No. 2017-016290 corresponding to same in a) and R ^102Z4 -NH (R ^102Z4X) (provided that, R ^102Z4X is not a hydrogen atom Except for the ^above , the same as R ^102Z4 )

N, N-dimethylamino group, N, N-ethylmethylamino group, N, N-diethylamino group, N, N-propylmethylamino group, N, N-dipropylamino group, N, N-isopropylmethylamino group N, N-diisopropylamino group, N, N-tert-butylmethylamino group, N, N-diisobutylamino group, N, N-disec-butylamino group, N, N-ditert-butylamino group, N, N-butylmethylamino group, N, N-dibutylamino group, N, N-dipentylamino group, N, N-di (1-ethylpropyl) amino group, N, N-dihexylamino group, N, N -Di (2-ethyl) hexylamino group, N, N-diheptylamino group, N, N-dioctylamino group, N, N-dinonylamino group, N, N-decylmethylamino group, N, N- Ndecylmethylamino group, N, N-dodecylmethylamino group, N, N-icosylmethylamino group, N, N-phenylmethylamino group, N, N-diphenylamino group, etc., and the above formula Two hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom) In the compounds shown in Tables 1Z4 to 20Z4 and —N (R), an amino group substituted with an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably a group derivatized with an octylsulfamoyl group) or the like. ^102Z4X) ₂ (where reduction except that R ^102Z4X is not a hydrogen atom, are shown in Table 1 to 966 groups and Japanese Patent Application No. 2017-016290 corresponding to same in a) and R ^102Z4 -N (R ^102Z4X) ₂ (provided that, R ^102Z4X, except that not a hydrogen atom, same as is the R ^102Z4) at the object and a group corresponding to the like,
Preferably, one or two hydrocarbon groups having 1 to 10 carbon atoms or an amino group substituted with a derivatizing group thereof, and a group corresponding to —N (R ^102Z4 ) ₂ in the compounds shown in Tables 1Z4 to 20Z4, etc. Is mentioned.

—NHCO—R ^102Z4 includes formylamino group; acetylamino group, propanoylamino group, butanoylamino group, 2,2-dimethylpropanoylamino group, pentanoylamino group, hexanoylamino group, (2-ethyl ) Hexanoylamino group, heptanoylamino group, octanoylamino group, nonanoylamino group, decanoylamino group, undecanoylamino group, dodecanoylamino group, heicosanoylamino group, benzoylamino group, etc. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group represented by the above formula or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably Is a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) In the case of a derivatized group) bonded to a carbonylamino group (an acylamino group the carbonyl amino group, -NHCO-R ^102Z4 in compound number of carbon atoms indicated in which) and Table 1Z4~ Table 20Z4 1 to 40 And groups corresponding to —NHCO—R ^102Z4 in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290, and the like.
Preferably a carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded (when the carbonylamino group is an alkanoylamino group, the carbon number is more preferably 1 to 10) and Table 1Z4 To groups corresponding to —NHCO—R ^102Z4 in the compounds shown in Table 20Z4.

Examples of —NHCON (R ^102Z4 ) ₂ include the groups listed above, groups corresponding to —NHCON (R ^102Z4 ) ₂ in the compounds shown in Tables 1Z4 to 20Z4, and Tables 1 to 1 of Japanese Patent Application No. 2017-016290. And a group corresponding to —NHCON (R ^102Z4 ) ₂ in the compound represented by 966.

-NHCOOR ^102Z4 includes the groups listed above, the groups corresponding to -NHCOOR ^102Z4 in the compounds shown in Tables 1Z4 to 20Z4, and -NHCOOR in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290. ^Examples include groups corresponding to ^102Z4 .

^{Examples of} —OCON (R ^102Z4 ) ₂ include the groups listed above, groups corresponding to —OCON (R ^102Z4 ) ₂ in the compounds shown in Tables 1Z4 to ^20Z4 , and Tables 1 to 1 of Japanese Patent Application No. 2017-016290. And a group corresponding to —OCON (R ^102Z4 ) ₂ in the compound represented by 966.

As the halogen atom, a fluorine atom, a chlorine atom, a bromine atom and an iodine atom are preferable.
Examples of M in —SO ₃ M and —CO ₂ M include a hydrogen atom; an alkali metal atom such as a lithium atom, a sodium atom and a potassium atom, preferably a hydrogen atom, a sodium atom and a potassium atom.

The ^{-CO-R 102Z4, -COO-R} 102Z4, -OCO-R 102Z4, -COCO-R 102Z4, -O-R 102Z4, -SO 2 -R 102Z4, -SO 2 N (R 102Z4) 2, -CON ^{Substituents contained in} ( ^R102Z4 ) ₂ , -N ( ^R102Z4 ) ₂ , -NHCO- ^R102Z4 , -NHCON ( ^R102Z4 ) ₂ , ^-NHCOOR102Z4 , -OCON ( ^R102Z4 ) ₂ (first substituent) May be one or more, and the two or more substituents may be the same or different independently of each other.
Further, the first substituent may have another substituent (second substituent) bonded to a hydrocarbon group contained in a part thereof. The second substituent can be selected from the same groups as the first substituent.

The ring formed by R ^2Z4 and R ^3Z4 , R ^3Z4 and R ^4Z4 , and R ^4Z4 and R ^5Z4 is condensed with the benzene ring of the isoindoline skeleton of the compound represented by the formula (IZ4). The condensed ring structure of the ring formed by R ^2Z4 and R ^3Z4 , R ^3Z4 and R ^4Z4 , and R ^4Z4 and R ^5Z4 and the benzene ring includes indene, naphthalene, biphenylene, indacene, acenaphthylene, fluorene, phenalene, phenanthrene, Hydrocarbon condensed ring structures such as anthracene, fluoranthene, acephenanthrylene, aceanthrylene, triphenylene, pyrene, chrysene, N-methylphthalimide, N- (1-phenylethyl) phthalimide and tetracene, and their partially reduced forms ( For example, 9,10-dihydroanthracene, 1,2,3,4-tetrahydronaphthalene, etc.); indole, isoindole, indazole, quinoline, isoquinoline, phthalazine, quinoxaline, quinazoline, cinnoline, carbazole, carboline, phenant Jin, acridine, perimidine, nitrogen-containing condensed heterocyclic, and parts thereof reductant such as phenanthroline and phenazine; 3- oxygen-containing condensed such tetrahydrobenzo furan-2-one heterocyclic ring and its partially reduced products thereof.

When R ^2Z4 and R ^3Z4 , R ^3Z4 and R ^4Z4 , and R ^4Z4 and R ^5Z4 form a ring, the ring may have a substituent. The substituent has hydrocarbon groups represented by R ^N1Z4 , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^101Z4 and R ^102Z4. The same as the substituent which may be good. Preferred examples of the substituent include hydrocarbon groups represented by R ^N1Z4 , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , R ^7Z4 , R ^101Z4 and R ^102Z4. The same thing as the preferable thing of the substituent which may be carried out is mentioned.

When R ^3Z4 and R ^4Z4 form a ring, R ^2Z4 and R ^5Z4 are preferably independently of each other a hydrogen atom, an amino group, and a hydroxy group.
When R ^2Z4 and R ^3Z4 form a ring, R ^4Z4 and R ^5Z4 preferably do not form a ring, and R ^4Z4 and R ^5Z4 are more preferably hydrogen atoms.
When R ^4Z4 and R ^5Z4 form a ring, R ^2Z4 and R ^3Z4 preferably do not form a ring, and R ^2Z4 and R ^3Z4 are more preferably hydrogen atoms.

In the present invention, R ^1Z4 , R ^6Z4 and R ^7Z4 are preferably hydrogen atoms.

In the present invention, R ^N1Z4 and R ^N2Z4 are independently of each other —CO—R ^102Z4 , —COO—R ^101Z4 , ^—CON (R ^102Z4 ) ₂ , —N (R ^102Z4 ) ₂ , —CO ₂ M or a substituent. Is preferably a hydrocarbon group having 1 to 40 carbon atoms which may have a hydrocarbon group, more preferably a hydrocarbon group having 1 to 30 carbon atoms which may have a substituent group. The optionally substituted hydrocarbon group having 1 to 20 carbon atoms is more preferable, the optionally substituted hydrocarbon group having 1 to 15 carbon atoms is particularly preferable, and the optionally substituted hydrocarbon group may be substituted. A hydrocarbon group having 1 to 10 carbon atoms is more particularly preferable, and a hydrocarbon group having 1 to 6 carbon atoms which may have a substituent or a hydrocarbon having 1 to 5 carbon atoms which may have a substituent. Group is particularly preferred, methyl group, ethyl group, or phenyl group is more particularly preferred, And most preferably a methyl group or an ethyl group. R ^N1Z4 and R ^N2Z4 may be the same group or different groups, but are preferably the same group.

From the viewpoint of reducing the retardation value of the color filter prepared from the colored composition, at least one of R ^2Z4 , R ^3Z4 , R ^4Z4 , and R ^5Z4 is -CO-R ^102Z4 , -COO-R ^101Z4 ,- ^{OCO-R 102Z4, -COCO-R} 102Z4, -O-R 102Z4, -SO 2 -R 101Z4, -SO 2 N (R 102Z4) 2, -CON (R 102Z4) 2, -N (R 102Z4) 2, ^{-NHCO-R 102Z4, -NHCO-N} (R 102Z4) 2, -NHCOOR 102Z4, -OCON (R 102Z4) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , a substituent It is preferably a C1-C40 hydrocarbon group that may have or a heterocyclic group that may have a substituent,
1 to 40 carbon atoms in which all or part of the hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a halogen atom, -N (R ^102Z4 ) ₂ , a nitro group or a hydrogen atom is substituted with a fluorine atom. More preferably, it is 20 hydrocarbon groups, —NHCO—R ^102Z4 , —O—R ^102Z4 , —SO ₃ M or —CO ₂ M,
It is more preferable that it is a C1-C40 hydrocarbon group which may have a nitro group or a substituent, and it is still more preferable that it is a nitro group or a tert-butyl group. Alternatively, at least one pair of R ^2Z4 and R ^3Z4 , R ^3Z4 and R ^4Z4 , or R ^4Z4 and R ^5Z4 preferably forms a ring.

From the viewpoint of reducing the retardation value of the color filter produced from the coloring composition, at least one of R ^2Z4 , R ^3Z4 , R ^4Z4 , and R ^5Z4 may have a substituent. Hydrocarbon group, halogen atom, —N (R ^102Z4 ) ₂ , nitro group, hydrocarbon group having 1 to 20 carbon atoms in which all or part of the hydrogen atom is substituted with fluorine atom, —NHCO—R ^102Z4 , —O —R ^102Z4 , —SO ₃ M or —CO ₂ M is preferable, and a nitro group or an ^optionally substituted hydrocarbon group having 1 to 40 carbon atoms is more preferable. Even more preferred is a tert-butyl group. Particularly preferably, R ^3Z4 is a nitro group or tert-butyl group and R ^2Z4 , R ^4Z4 and R ^5Z4 are hydrogen atoms, or R ^2Z4 , R ^3Z4 and R ^5Z4 are hydrogen atoms and R ^4Z4. Is a nitro group or a tert-butyl group.

Specific examples of compound (IZ4) include, for example, compounds of formula (IZ4-aa) having the substituents shown in Table 1Z4 to Table 20Z4 (IZ4-1) to Compound (IZ4-769) or an alkali metal salt thereof. Can be mentioned.
B ^a1Z4 B ^a2Z4 is the formula (BB1) to formula (BB60), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1), formula (BBO8), formula (BBO10) , Any partial structure represented by formula (BBD1) and formula (BBJ2). Formula (BB1) to Formula (BB60), Formula (BBK2), Formula (BBK3), Formula (BBK4), Formula (BBK14), Formula (BBI1), Formula (BBO8), Formula (BBO10), Formula (BBD1) and Formula (BBJ2) represents B ^a1Z1 B ^a2Z1 of Formula (IZ1-aa), (BB1) to (BB60), Formula (BBK2), Formula (BBK3), Formula (BBK4), Formula (BBK14), Formula (BBI1) ), Formula (BBO8), formula (BBO10), formula (BBD1), and formula (BBJ2). B ^A1Z4 and B ^A2Z4 each represent a bond, B ^A1Z4 the expression (BB1) ~ formula (BB60), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1) , Formula (BBO8), formula (BBO10), formula (BBD1), and formula (BBJ2), when B ^{1 is} a bond, B ^a2Z4 is a bond of B ² , and B ^a1Z4 is a formula (BB1) to formula ( ^BB60 ). ), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1), formula (BBO8), formula (BBO10), formula (BBD1) and formula B ² of (BBJ2) When it is a bond, B ^a2Z4 is a bond of B ¹ .
B ^a1Z4 B ^a2Z4 includes formula (BB1), formula (BB6), formula (BB8), formula (BB11), formula (BB14), formula (BB19), formula (BB37), formula (BB58), formula (BBJ2) ), Formula (BBO8) and formula (BBO10) are preferred, and formula (BB1), formula (BB6) and formula (BB19) are more preferred.

Each symbol in Table 1Z4 to Table 20Z4 represents the following partial structure. In the partial structure,
“Me” represents a methyl group,
“Et” represents an ethyl group;
“Bu” represents a butyl group,
“TBu” represents a tert-butyl group,
“Hex” represents a hexyl group,
“Oct” represents an octyl group;
“2EH” represents a 2-ethylhexyl group;
“CHM” represents a cyclohexylmethyl group,
“CH” represents a cyclohexyl group,
“PH” represents a phenyl group;
“BZ” represents a benzyl group;
“NPR” represents a propyl group;
“IPR” represents an isopropyl group;
“IBu” represents an isobutyl group,
“EOE” represents —CH ₂ CH ₂ OCH ₂ CH ₃ ,
“ALL” represents an allyl group,
“HYE” represents a 2-hydroxyethyl group,
“COM” represents —CO—CH ₃ ;
“COE” represents —COO—CH ₂ CH ₃ ;
“OCM” represents —OCO—CH ₃ ;
“OME” represents —O—CH ₃ ;
“SOT” represents a tosyl group;
“SNH” represents —SO ₂ NH—CH ₂ CH (CH ₂ CH ₃ ) ((CH ₂ ) ₃ CH ₃ );
“SN2” represents —SO ₂ N (CH ₃ ) ((CH ₂ ) ₇ CH ₃ ),
“CNM” represents —CONHCH ₃ ;
“CN2” represents —CON (CH ₃ ) C ₆ H ₅ ,
“NPH” represents —NHC ₆ H ₅ ,
"NOT" represents _{-N ((CH 2) 7 CH} 3) 2,
“NCO” represents —NHCO ((CH ₂ ) ₄ CH ₃ ),
“F” represents a fluorine atom,
“Cl” represents a chlorine atom,
“Br” represents a bromine atom;
“CN” represents a cyano group,
“NO2” represents a nitro group,
“SUA” represents —SO ₃ H;
“CBA” represents —CO ₂ H;
“CHO” represents —CHO,
“OCH” represents —OCOH;
“OH” represents —OH;
“SFM” represents —SO ₂ NH ₂ ;
“CBM” represents —CONH ₂ ;
“NH ₂ ” represents —NH ₂ ,
“NCH” represents —NHCOH.
In the partial structure represented by the following formula, * represents a bond.

  For example, compound (IZ4-1) is a compound represented by formula (IZ4-1).

As the compound (IZ4),
Compound (IZ4-1) to Compound (IZ4-234) and Compound (IZ4-321) to Compound (IZ4-769) are preferred,
More preferred are compound (IZ4-1) to compound (IZ4-234) and compound (IZ4-321) to compound (IZ4-711),
More preferred are compound (IZ4-1) to compound (IZ4-234),
Compound (IZ4-1) to Compound (IZ4-174) are even more preferred,
Compound (IZ4-1) to Compound (IZ4-117) are particularly preferred,
Compound (IZ4-1) to compound (IZ4-2), compound (IZ4-40) to compound (IZ4-41), compound (IZ4-79) to compound (IZ4-80) are particularly preferred.

Specific examples of compound (IZ4) also include compounds in which 1 to 3 hydrogen atoms contained in the compounds represented by Tables 1Z4 to 20Z4 are substituted with —SO ₃ M or —CO ₂ M. For example, a compound in which 1 to 3 sulfo groups are bonded to the compound (IZ4-1) in Table 1Z4 is represented by the following structure. However, in the formula,-(SO ₃ H) means that any hydrogen atom of the compound (IZ4-1) in Table 1Z4 is substituted.

In the present invention,
A compound in which 1 to 3 —SO ₃ M or —CO ₂ M is bonded to Compound (IZ4-1) to Compound (IZ4-234) and Compound (IZ4-321) to Compound (IZ4-769) is preferable. ,
A compound in which 1 to 3 —SO ₃ M or —CO ₂ M is bonded to Compound (IZ4-1) to Compound (IZ4-234) and Compound (IZ4-321) to Compound (IZ4-711) is more Preferably
More preferably, a compound in which 1 to 3 —SO ₃ M or —CO ₂ M is bonded to the compound (IZ4-1) to the compound (IZ4-234),
More preferably, a compound in which 1 to 3 —SO ₃ M or —CO ₂ M is bonded to the compound (IZ4-1) to the compound (IZ4-174),
A compound in which 1 to 3 —SO ₃ M or —CO ₂ M is bound to compound (IZ4-1) to compound (IZ4-117) is particularly preferred,
Compound (IZ4-1) to Compound (IZ4-2), Compound (IZ4-40) to Compound (IZ4-41), and Compound (IZ4-79) to Compound (IZ4-80) have 1 to 3 − A compound to which SO ₃ M or —CO ₂ M is bound is particularly preferred.

As the compound (IZ4), in the formula (IZ4),
R ^N1Z4 and R ^N2Z4 are each independently a substituent selected from the group consisting of —CO—R ^102Z4 , —COO—R ^101Z4 , ^—CON (R ^102Z4 ) ₂ , or —SO ₃ M and —CO ₂ M. A hydrocarbon group having 1 to 20 carbon atoms, which may have
R ^1Z4 represents a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M, —SO ₃ M or —CO _2. M,
R ^{2Z4 to} R ^5Z4 are each independently a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogen atom, —N (R ^102Z4 ) ₂ , a nitro group, or a hydrogen atom. A substituted hydrocarbon group having 1 to 20 carbon atoms, —NHCO—R ^102Z4 , —O—R ^102Z4 , —SO ₃ M or —CO ₂ M;
R ^6Z4 and R ^7Z4 each independently represent a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M; SO ₃ M or —CO ₂ M,
R ^102Z4 is a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M;
R ^101Z4 is a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M;
M is preferably a compound that is a hydrogen atom or an alkali metal atom,
R ^N1Z4 and R ^N2Z4 may each independently have a substituent selected from the group consisting of —CO—R ^102Z4 , ^—CON (R ^102Z4 ) ₂ , or —SO ₃ M and —CO ₂ M. A good hydrocarbon group having 1 to 10 carbon atoms,
R ^1Z4 is a hydrogen atom,
R ^{2Z4 to} R ^5Z4 are each independently a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, —N (R ^102Z4 ) ₂ , a nitro group, or a hydrogen atom. A substituted hydrocarbon group having 1 to 10 carbon atoms, —NHCO—R ^102Z4 , —O—R ^102Z4 , —SO ₃ M or —CO ₂ M;
R ^6Z4 and R ^7Z4 are the same group, and a hydrocarbon having 1 to 10 carbon atoms which may have a hydrogen atom or a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M Group,
R ^102Z4 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M;
R ^101Z4 is a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M;
M is more preferably a compound that is a hydrogen atom or an alkali metal atom,
R ^N1Z4 and R ^N2Z4 may each independently have a substituent selected from the group consisting of —CO—R ^102Z4 , ^—CON (R ^102Z4 ) ₂ , or —SO ₃ M and —CO ₂ M. A good hydrocarbon group having 1 to 10 carbon atoms,
R ^1Z4 is a hydrogen atom,
R ^{2Z4 to} R ^5Z4 are each independently a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, —N (R ^102Z4 ) ₂ , a nitro group, a trifluoromethyl group, —O—R ^102Z4 , a -SO ₃ M or -CO ₂ M,
R ^6Z4 and R ^7Z4 are the same group, and are a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms,
R ^102Z4 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M;
R ^101Z4 is a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M;
A compound in which M is a hydrogen atom or an alkali metal atom is more preferable.

Compound (IZ4) is a compound represented by the formula (pt1Z4) (hereinafter may be referred to as a phthalonitrile compound) when R ^1Z4 is a hydrogen atom (hereinafter referred to as an alkoxide compound). The compound represented by the formula (pt3Z4) and the compound represented by the formula (pt4Z4) can be further reacted in the presence of an acid. When R ^1Z4 is other than a hydrogen atom, compound (IZ4) can be produced by further reacting with a compound represented by the formula (pt5Z4).

[In formula (pt1Z4), formula (pt2Z4), formula (pt3Z4), formula (pt4Z4), formula (pt5Z4) and formula (IZ4), R ^N1Z4 , R ^N2Z4 , R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 and R ^7Z4 represent the same meaning as described above.
R ^14Z4 represents an alkyl group having 1 to 20 carbon atoms.
M ^1Z4 represents an alkali metal atom.
LG represents a halogen atom, a methanesulfonyloxy group, a toluenesulfonyloxy group, or a trifluoromethanesulfonyloxy group. ]

^Examples of the alkyl group having 1 to 20 carbon atoms represented by R ^14Z4 include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, a sec-butyl group, and a tert-butyl group. Is an alkyl group having 1 to 6 carbon atoms.
^Examples of the alkali metal atom represented by M ^1Z4 include a lithium atom, a sodium atom, and a potassium atom.

  The amount of the alkoxide compound used is usually 0.1 to 10 mol, preferably 0.2 to 5 mol, more preferably 0.3 to 3 mol, relative to 1 mol of the phthalonitrile compound. More preferably, it is 0.4-2 mol.

The amount of compound (pt3Z4) to be used is generally 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, further preferably 1 to 1 mol of phthalonitrile compound. ~ 2 moles.
The amount of compound (pt4Z4) to be used is generally 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, still more preferably 1 mol, per 1 mol of phthalonitrile compound. ~ 2 moles.

Examples of the acid include inorganic acids such as hydrochloric acid, hydrobromic acid, hydroiodic acid, sulfuric acid, nitric acid, fluorosulfonic acid and phosphoric acid; sulfonic acids such as methanesulfonic acid, trifluoromethanesulfonic acid and p-toluenesulfonic acid; Examples thereof include carboxylic acids such as acetic acid, citric acid, formic acid, gluconic acid, lactic acid, oxalic acid and tartaric acid, and preferably hydrochloric acid, hydrobromic acid, sulfuric acid, methanesulfonic acid, trifluoromethanesulfonic acid, p-toluenesulfonic acid and A carboxylic acid is mentioned, More preferably, an acetic acid is mentioned.
The usage-amount of an acid is 1-20 mol normally with respect to 1 mol of phthalonitrile compounds, Preferably it is 1-10 mol, More preferably, it is 1-8 mol, More preferably, it is 1-6 mol. is there.

The reaction of the phthalonitrile compound, the alkoxide compound, the compound (pt3Z4) and the compound (pt4Z4) is usually carried out in the presence of a solvent.
Solvents include water; nitrile solvents such as acetonitrile; alcohol solvents such as methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol and 1-octanol; ether solvents such as tetrahydrofuran; ketone solvents such as acetone; Ester solvents such as ethyl; aliphatic hydrocarbon solvents such as hexane; aromatic hydrocarbon solvents such as toluene; halogenated hydrocarbon solvents such as methylene chloride and chloroform; amides such as N, N-dimethylformaldehyde and N-methylpyrrolidone Solvent: Sulfoxide solvents such as dimethyl sulfoxide are mentioned, preferably water, nitrile solvent, alcohol solvent, ether solvent, ketone solvent, ester solvent, aromatic hydrocarbon solvent, halogenated hydrocarbon solvent, amide solvent and sulfoxide solvent. And More preferably, water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, tetrahydrofuran, acetone, ethyl acetate, toluene, methylene chloride, chloroform, N, N-dimethylformaldehyde, N -Methylpyrrolidone and dimethyl sulfoxide are mentioned, More preferably, water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, acetone, methylene chloride, chloroform, N, N-dimethyl Examples include formaldehyde, N-methylpyrrolidone and dimethyl sulfoxide, with water, acetonitrile, methanol, ethanol and 2-propanol being particularly preferred.
The usage-amount of a solvent is 1-1000 mass parts normally with respect to 1 mass part of phthalonitrile compounds.

  The reaction temperature is usually 0 to 200 ° C, preferably 0 to 100 ° C, more preferably 0 to 70 ° C, and further preferably 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

The amount of compound (pt5Z4) to be used is generally 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, per 1 mol of compound (IZ4) in which R ^1Z4 is a hydrogen atom. More preferably, it is 1-2 mol.

  Moreover, when making a compound (pt5Z4) react, it is preferable that a base coexists. Examples of the base include organic bases such as triethylamine, 4- (N, N-dimethylamino) pyridine, pyridine and piperidine; metal alkoxides such as sodium methoxide, sodium ethoxide, sodium tert-butoxide and potassium tert-butoxide; butyllithium Organic metal compounds such as tert-butyl lithium and phenyl lithium; inorganic bases such as lithium hydroxide, sodium hydroxide and potassium hydroxide.

The amount of the base to be used is generally 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, per 1 mol of compound (IZ4) in which R ^1Z4 is a hydrogen atom. Preferably it is 1-2 mol.

The reaction of the compound (pt5Z4) is usually performed in the presence of a solvent. The solvent can be selected from the same range as described above.
The usage-amount of a solvent is ^1-1000 mass parts normally with respect to 1 mass part of compounds (IZ4) whose ^R1Z4 is a hydrogen atom. The reaction temperature of the compound (pt5Z4) is usually -90 to 200 ° C, preferably -80 to 100 ° C, more preferably 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

When the compound (IZ4) does not have a sulfo group or —SO ₃ M ²² , the compound (IZ4) is reacted with a sulfonating agent such as fuming sulfuric acid or chlorosulfonic acid to thereby form a sulfo group or —SO ₃ M ^22. Can be introduced.
M ²² represents an alkali metal atom.
Examples of the alkali metal atom represented by M ²² include a lithium atom, a sodium atom, and a potassium atom.

The amount of SO ₃ in the oleum, the compound (IZ4) relative to 1 mol, usually 1 to 50 moles, preferably from 5 to 40 moles, more preferably from 5 to 30 moles, more preferably 5 to 25 mol.
The usage-amount of the sulfuric acid in fuming sulfuric acid is 1-200 mol normally with respect to 1 mol of compounds (IZ4), Preferably it is 10-100 mol, More preferably, it is 10-75 mol, More preferably, it is 10 ~ 50 moles.

  The amount of chlorosulfonic acid to be used is generally 1 to 500 mol, preferably 10 to 300 mol, more preferably 10 to 200 mol, further preferably 10 to 150 mol, per 1 mol of compound (IZ4). Is a mole.

  The reaction temperature of the sulfonation is usually from -20 to 200 ° C, preferably from -10 to 100 ° C, more preferably from 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

  The method for taking out the compound (IZ4) from the reaction mixture is not particularly limited, and it can be taken out by various known methods. For example, after completion of the reaction, the compound (IZ4) can be taken out by filtering the reaction mixture. Further, after filtration, the obtained residue may be subjected to column chromatography or recrystallization. Further, after completion of the reaction, the solvent of the reaction mixture may be distilled off and purified by column chromatography.

<Compound (IZ5)>
Compound (IZ5) is represented by formula (IZ5).

[In the formula (IZ5)
R ^{N1Z5 is, -CO-R 102Z5, -COO-} R 101Z5, -OCO-R 102Z5, -COCO-R 102Z5, -O-R 102Z5, -SO 2 -R 101Z5, -SO 2 N (R 102Z5) 2 , ^-CON ( ^R102Z5 ) ₂ , -N ( ^R102Z5 ) ₂ , -NHCO- ^R102Z5 , -NHCO-N ( ^R102Z5 ) ₂ , ^-NHCOOR102Z5 , -OCON ( ^R102Z5 ) ₂ , halogen atom, cyano group , A nitro group, —SO ₃ M, —CO ₂ M, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group.
^{R 1Z5, R 2Z5, R 3Z5} , R 4Z5, R 5Z5, R 6Z5, and R ^7Z5, independently of each other, hydrogen ^{atom, -CO-R 102Z5, -COO-} R 101Z5, -OCO-R 102Z5, -COCO ^{-R 102Z5, -O-R 102Z5,} -SO 2 -R 101Z5, -SO 2 N (R 102Z5) 2, -CON (R 102Z5) 2, -N (R 102Z5) 2, -NHCO-R 102Z5, - _{^{NHCO-N (R 102Z5) 2}} , -NHCOOR 102Z5, -OCON (R 102Z5) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , carbon atoms, which may have a substituent ^{Represents a} heterocyclic group ^optionally having 1 to 40 hydrocarbon groups or a substituent, and R ^2Z5 and R ^3Z5 , R ^3Z5 and R ^4Z5 , and R ^4Z5 and R ^5Z5 are bonded to each other to form a ring It may form a, R ^2Z5, R ^3Z5, at least one of R ^4Z5 and R ^5Z5 is, -CO-R ^102Z5, -COO- ^{101Z5, -OCO-R 102Z5, -COCO} -R 102Z5, -O-R 102Z5, -SO 2 -R 101Z5, -SO 2 N (R 102Z5) 2, -CON (R 102Z5) 2, -N (R 102Z5 ) ₂ , -NHCO-R ^102Z5 , -NHCO-N (R ^102Z5 ) ₂ , -NHCOOR ^102Z5 , -OCON (R ^102Z5 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, A hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent, or R ^2Z5 and R ^3Z5 , R ^3Z5 and R ^4Z5 , and R ^At least one pair of ^4Z5 and R ^5Z5 is bonded to form a ring.
R ^101Z5 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102Z5 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
M represents a hydrogen atom or an alkali metal atom.
When a plurality of R ^101Z5 , R ^102Z5 and M are present, they may be the same or different.
A wavy line represents an E body or a Z body. ]

^{R N1Z5, R 1Z5, R 2Z5} , R 3Z5, R 4Z5, R 5Z5, R 6Z5, R 7Z5, R 101Z5 and the carbon number of the hydrocarbon group which may have a substituent represented by R ^102Z5 is It is 1-40, Preferably it is 1-30, More preferably, it is 1-20, More preferably, it is 1-15, Most preferably, it is 1-10, More preferably, it is 1-5.

^{R N1Z5, R 1Z5, R 2Z5} , R 3Z5, R 4Z5, R 5Z5, R 6Z5, a hydrocarbon group of R ^7Z5, R ^101Z5 and C1-40 represented by R ^102Z5 is an aliphatic hydrocarbon group and It may be an aromatic hydrocarbon group, and the aliphatic hydrocarbon group may be saturated or unsaturated, and may be a chain or an alicyclic ring.

The ^{R N1Z5, R 1Z5, R 2Z5} , R 3Z5, R 4Z5, R 5Z5, R 6Z5, R 7Z5, saturated or unsaturated chain hydrocarbon group represented by R ^101Z5 and R ^102Z5, a methyl group, an ethyl group Linear alkyl groups such as propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, heptadecyl, octadecyl and icosyl; , Isobutyl group, sec-butyl group, tert-butyl group, (2-ethyl) butyl group, isopentyl group, neopentyl group, tert-pentyl group, (1-methyl) pentyl group, (2-methyl) pentyl group, ( 1-ethyl) pentyl, (3-ethyl) pentyl, isohexyl, (5-methyl) hexyl, (2-ethyl) hexyl and (3-ethyl) hept A branched alkyl group such as a sulfur group; vinyl group, 1-propenyl group, 2-propenyl group (allyl group), (1-methyl) ethenyl group, 2-butenyl group, 3-butenyl group, 1,3 An alkenyl group such as a butadienyl group, a (1- (2-propenyl)) ethenyl group, a (1,2-dimethyl) propenyl group and a 2-pentenyl group; The carbon number of the saturated or unsaturated chain hydrocarbon group is preferably 1 to 30, more preferably 1 to 20, still more preferably 1 to 15, particularly preferably 1 to 10, More preferably, it is 1-8, More preferably, it is 1-5. Especially, it is especially preferable that it is a C1-C10, More preferably, it is a C1-C8 linear or branched alkyl group, and a methyl group, an ethyl group, and a tert- butyl group are especially preferable.

R ^N1Z5, as the ^{R 1Z5, R 2Z5, R 3Z5} , R 4Z5, R 5Z5, R 6Z5, R 7Z5, saturated or unsaturated alicyclic hydrocarbon group represented by R ^101Z5 and R ^102Z5, cyclopropyl group, 1-methylcyclopropyl group, cyclobutyl group, cyclopentyl group, cyclohexyl group, cycloheptyl group, 1-methylcyclohexyl group, 2-methylcyclohexyl group, 3-methylcyclohexyl group, 4-methylcyclohexyl group, 1,2-dimethylcyclohexyl Group, 1,3-dimethylcyclohexyl group, 1,4-dimethylcyclohexyl group, 2,3-dimethylcyclohexyl group, 2,4-dimethylcyclohexyl group, 2,5-dimethylcyclohexyl group, 2,6-dimethylcyclohexyl group, 3,4-dimethylcyclohexyl group, 3,5-dimethylcyclohexyl group, 2,2 Dimethylcyclohexyl group, 3,3-dimethylcyclohexyl group, 4,4-dimethylcyclohexyl group, cyclooctyl group, 2,4,6-trimethylcyclohexyl group, 2,2,6,6-tetramethylcyclohexyl group and 3,3 , 5,5-tetramethylcyclohexyl group, 4-pentylcyclohexyl group, 4-octylcyclohexyl group, cycloalkyl group such as 4-cyclohexylcyclohexyl group; cyclohexenyl group (for example, cyclohex-2-ene, cyclohex-3-ene) And cycloalkenyl groups such as cycloheptenyl group and cyclooctenyl group; norbornane group, adamantyl group, bicyclo [2.2.2] octane and the like. The carbon number of the saturated or unsaturated alicyclic hydrocarbon group is preferably 3 to 30, more preferably 3 to 20, still more preferably 4 to 20, and still more preferably 4 to 15. More preferably 5 to 15 and most preferably 5 to 10. Of these, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, and a cyclooctyl group are particularly preferable.

The ^{R N1Z5, R 1Z5, R 2Z5} , R 3Z5, R 4Z5, R 5Z5, R 6Z5, R 7Z5, aromatic hydrocarbon groups represented by R ^101Z5 and R ^102Z5, phenyl, o- tolyl group, m -Tolyl group, p-tolyl group, 2-ethylphenyl group, 3-ethylphenyl group, 4-ethylphenyl group, 2,3-dimethylphenyl group, 2,4-dimethylphenyl group, 2,5-dimethylphenyl group 2,6-dimethylphenyl group, 3,4-dimethylphenyl group, 3,5-dimethylphenyl group, 4-vinylphenyl group, o-isopropylphenyl group, m-isopropylphenyl group, p-isopropylphenyl group, o -Tert-butylphenyl group, m-tert-butylphenyl group, p-tert-butylphenyl group, mesityl group, 4-ethylphenyl group, 4-butylphenyl group, 4-pen Ruphenyl group, 2,6-bis (2-propyl) phenyl group, 4-cyclohexylphenyl group, 2,4,6-trimethylphenyl group, 4-octylphenyl group, 1-naphthyl group, 2-naphthyl group, 5, Aromatic hydrocarbon groups such as 6,7,8-tetrahydro-1-naphthyl group, 5,6,7,8-tetrahydro-2-naphthyl group, fluorenyl group, phenanthryl group and anthryl group, pyrenyl group; It is done. The number of carbon atoms of the aromatic hydrocarbon group is preferably 6-30, more preferably 6-20, and even more preferably 6-15.

^{R N1Z5, R 1Z5, R 2Z5} , R 3Z5, R 4Z5, R 5Z5, R 6Z5, R 7Z5, hydrocarbon groups represented by R ^101Z5 and R ^102Z5 is a hydrocarbon group (e.g. an aromatic listed above carbonized A hydrogen group and a group obtained by combining at least one of a chain hydrocarbon group and an alicyclic hydrocarbon group), and an aralkyl group such as a benzyl group, a phenethyl group, or a 1-methyl-1-phenylethyl group. An arylalkenyl group such as a phenylethenyl group (phenylvinyl group); an arylalkynyl group such as a phenylethynyl group; a phenyl group to which one or more phenyl groups such as a biphenylyl group or a terphenylyl group are bonded; a cyclohexylmethylphenyl group, a benzyl A phenyl group, a (dimethyl (phenyl) methyl) phenyl group, etc. are mentioned.
^{R N1Z5, R 1Z5, R 2Z5} , R 3Z5, R 4Z5, R 5Z5, R 6Z5, R 7Z5, groups represented by R ^101Z5 and R ^102Z5 is a hydrocarbon group (e.g., a chain hydrocarbon group listed above And alicyclic hydrocarbon group), for example, cyclopropylmethyl group, cyclopropylethyl group, cyclobutylmethyl group, cyclobutylethyl group, cyclopentylmethyl group, cyclopentylethyl group, cyclohexylmethyl group, 2- It may be an alkyl group to which one or more alicyclic hydrocarbon groups such as a methylcyclohexylmethyl group, a cyclohexylethyl group, and an adamantylmethyl group are bonded.
These carbon numbers are preferably 4-30, more preferably 6-30, still more preferably 6-20, and preferably 4-20, more preferably 4-15. Especially preferably, it is 6-15.

^{R N1Z5, R 1Z5, R 2Z5} , R 3Z5, R 4Z5, R 5Z5, R 6Z5, hydrocarbon groups represented by R ^7Z5, R ^101Z5 and R ^102Z5 may have a substituent. The substituent may be monovalent or divalent. In the divalent substituent, two bonds are preferably bonded to the same carbon atom to form a double bond.
As the monovalent substituent,
Methoxy group, ethoxy group, propoxy group, isopropoxy group, butoxy group, isobutoxy group, sec-butoxy group, tert-butoxy group, pentyloxy group, hexyloxy group, (2-ethyl) hexyloxy group, heptyloxy group, Octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, dodecyloxy group, (2-ethyl) hexyloxy group, icosyloxy group, 1-phenylethoxy group, 1-methyl-1-phenylethoxy group, phenyloxy group O-Tolyloxy group, 2,3-dimethylphenyloxy group, 2,4-dimethylphenyloxy group, 2,5-dimethylphenyloxy group, 2,6-dimethylphenyloxy group, 3,4-dimethylphenyloxy group 3,5-dimethylphenyloxy group, 2,2-dicia Phenyloxy group, 2,3-dicyanophenyloxy group, 2,4-dicyanophenyloxy group, 2,5-dicyanophenyloxy group, 2,6-dicyanophenyloxy group, 3,4-dicyanophenyloxy group, 3 , 5-dicyanophenyloxy group, 4-methoxyphenyloxy group, 2-methoxyphenyloxy group, 3-methoxyphenyloxy group, 4-ethoxyphenyloxy group, 2-ethoxyphenyloxy group, 3-ethoxyphenyloxy group, etc. And a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group represented by the following formula or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen) (Preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl) Oxy group derivatized group) is bonded to one side the like);

  Methylthio, ethylthio, propylthio, butylthio, tert-butylthio, pentylthio, hexylthio, (2-ethyl) hexylthio, heptylthio, octylthio, nonylthio, decylthio, undecylthio, dodecylthio, icosylthio A sulfanyl group to which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group, a phenylthio group and an o-tolylthio group is bonded;

Epoxy group, oxetanyl group, tetrahydrofuryl group, tetrahydropyranyl group;
Formyl group;
Acetyl group, propanoyl group, butanoyl group, 2,2-dimethylpropanoyl group, pentanoyl group, hexanoyl group, (2-ethyl) hexanoyl group, heptanoyl group, octanoyl group, nonanoyl group, decanoyl group, undecanoyl group, dodecanoyl group, A hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 11 carbon atoms) or a derivatized group thereof (for example, a carboxy group or a sulfo group) such as a henicosanoyl group, a benzoyl group, or a group represented by the following formula: , A carbonyl group to which a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), a group derived from an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. When the carbonyl group is an alkanoyl group, the carbon number is preferably 2 to 12);

  Methoxycarbonyl group, ethoxycarbonyl group, propoxycarbonyl group, butoxycarbonyl group, tert-butoxycarbonyl group, pentyloxycarbonyl group, hexyloxycarbonyl group, (2-ethyl) hexyloxycarbonyl group, heptyloxycarbonyl group, octyloxycarbonyl Group, nonyloxycarbonyl group, decyloxycarbonyl group, undecyloxycarbonyl group, dodecyloxycarbonyl group, icosyloxycarbonyl group, phenyloxycarbonyl group, o-tolyloxycarbonyl group and the like, and the following formulas A hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon number 10 oxycarbonyl group alkylsulfamoyl group (preferably octyl sulfamoyl group) were derivatized with such groups) is bonded to;

An amino group;
N-methylamino group, N, N-dimethylamino group, N-ethylamino group, N, N-diethylamino group, N-propylamino group, N, N-dipropylamino group, N-isopropylamino group, N, N-diisopropylamino group, N-butylamino group, N, N-dibutylamino group, N-isobutylamino group, N, N-diisobutylamino group, N-sec-butylamino group, N, N-disec-butyl Amino group, N-tert-butylamino group, N, N-ditert-butylamino group, N-pentylamino group, N, N-dipentylamino group, N- (1-ethylpropyl) amino group, N, N -Di (1-ethylpropyl) amino group, N-hexylamino group, N, N-dihexylamino group, N- (2-ethyl) hexylamino group, N, N-di (2-ethyl) Xylamino group, N-heptylamino group, N, N-diheptylamino group, N-octylamino group, N, N-dioctylamino group, N-nonylamino group, N, N-dinonylamino group, N-phenylamino group, N, N-diphenylamino group, N, N-ethylmethylamino group, N, N-propylmethylamino group, N, N-isopropylmethylamino group, N, N-butylmethylamino group, N-decylamino group, N , N-decylmethylamino group, N-undecylamino group, N, N-undecylmethylamino group, N-dodecylamino group, N, N-dodecylmethylamino group, N-icosylamino group, N, N-ico One of a silmethylamino group, an N, N-tert-butylmethylamino group, an N, N-phenylmethylamino group, and a group represented by the following formula: Two hydrocarbon groups having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or derivatized groups thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), 1 carbon atom An amino group substituted with 10 to 10 alkylsulfamoyl groups (preferably a group derivatized with an octylsulfamoyl group or the like);

A sulfamoyl group;
N-methylsulfamoyl group, N, N-dimethylsulfamoyl group, N-ethylsulfamoyl group, N, N-diethylsulfamoyl group, N-propylsulfamoyl group, N, N-dipropyls Rufamoyl group, N-isopropylsulfamoyl group, N, N-diisopropylsulfamoyl group, N-butylsulfamoyl group, N, N-dibutylsulfamoyl group, N-isobutylsulfamoyl group, N, N-diisobutylsulfamoyl group, N-sec-butylsulfamoyl group, N, N-disec-butylsulfamoyl group, N-tert-butylsulfamoyl group, N, N-ditert-butylsulfur Famoyl group, N-pentylsulfamoyl group, N, N-dipentylsulfamoyl group, N- (1-ethylpropyl) sulfamoyl group, , N-di (1-ethylpropyl) sulfamoyl group, N-hexylsulfamoyl group, N, N-dihexylsulfamoyl group, N- (2-ethyl) hexylsulfamoyl group, N, N-di ( 2-ethyl) hexylsulfamoyl group, N-heptylsulfamoyl group, N, N-diheptylsulfamoyl group, N-octylsulfamoyl group, N, N-dioctylsulfamoyl group, N, N -Octylmethylsulfamoyl group, N-nonylsulfamoyl group, N, N-dinonylsulfamoyl group, N-phenylsulfamoyl group, N, N-diphenylsulfamoyl group, N, N-ethylmethyl Sulfamoyl group, N, N-propylmethylsulfamoyl group, N, N-isopropylmethylsulfamoyl group, N, N-butylmethylsulfamoyl group N-decylsulfamoyl group, N, N-decylmethylsulfamoyl group, N-undecylsulfamoyl group, N, N-undecylmethylsulfamoyl group, N-dodecylsulfamoyl group, N, N-dodecylmethylsulfamoyl group, N-icosylsulfamoyl group, N, N-icosylmethylsulfamoyl group, N, N-tert-butylmethylsulfamoyl group, N, N-phenylmethylsulfa 1 or 2 hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a moyl group and the group represented by the following formula or a derivatized group thereof (for example, carboxy group, sulfo group) , A nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. A sulfamoyl group substituted with

  Formylamino group; acetylamino group, propanoylamino group, butanoylamino group, 2,2-dimethylpropanoylamino group, pentanoylamino group, hexanoylamino group, (2-ethyl) hexanoylamino group, heptanoyl Amino group, octanoylamino group, nonanoylamino group, decanoylamino group, undecanoylamino group, dodecanoylamino group, heicosanoylamino group, benzoylamino group, etc., and groups represented by the following formulae Or a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 12 carbon atoms) or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon number 1 10 to 10 alkylsulfamoyl groups (preferably octylsulfamoyl groups) and the like) Carbonyl amino group (if the alkanoylamino group the carbonyl group, the carbon number is preferably 1 to 12);

A hydroxy group;
Halogen atoms such as fluorine atom, chlorine atom, bromine atom and iodine atom;
Carboxy group, —CO ₂ M ² (M ² is alkali metal, preferably lithium, sodium, potassium); sulfo group, —SO ₃ M ² (M ² is alkali metal, preferably lithium, sodium, potassium); Nitro group A cyano group;

  Formyloxy group; acetoxy group, propanoyloxy group, butanoyloxy group, 2,2-dimethylpropanoyloxy group, pentanoyloxy group, hexanoyloxy group, (2-ethyl) hexanoyloxy group, heptanoyloxy Carbon such as a group, octanoyloxy group, nonanoyloxy group, decanoyloxy group, undecanoyloxy group, dodecanoyloxy group, heicosanoyloxy group, benzoyloxy group, and the group represented by the following formula A hydrocarbon group having 1 to 20 (preferably 1 to 10 carbons) or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), A group to which an alkyl sulfamoyl group (preferably a group derivatized with an octyl sulfamoyl group) is bound. Boniruokishi group (if the alkanoyloxy group and the carbonyl group, the carbon number is preferably 1 to 10);

  Methylsulfonyl group, ethylsulfonyl group, propylsulfonyl group, butylsulfonyl group, pentylsulfonyl group, hexylsulfonyl group, (2-ethyl) hexylsulfonyl group, heptylsulfonyl group, octylsulfonyl group, nonylsulfonyl group, decylsulfonyl group, un Decylsulfonyl group, dodecylsulfonyl group, icosylsulfonyl group, phenylsulfonyl group, p-tolylsulfonyl group and the like, and groups having 1 to 20 carbon atoms (preferably having 1 to 10 carbon atoms) such as groups represented by the following formulae: Hydrocarbon group or derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group) A group derivatized with a sulfonyl group) ;

A carbamoyl group;
N-methylcarbamoyl group, N, N-dimethylcarbamoyl group, N-ethylcarbamoyl group, N, N-diethylcarbamoyl group, N-propylcarbamoyl group, N, N-dipropylcarbamoyl group, N-isopropylcarbamoyl group, N , N-diisopropylcarbamoyl group, N-butylcarbamoyl group, N, N-dibutylcarbamoyl group, N-isobutylcarbamoyl group, N, N-diisobutylcarbamoyl group, N-sec-butylcarbamoyl group, N, N-disec- Butylcarbamoyl group, N-tert-butylcarbamoyl group, N, N-ditert-butylcarbamoyl group, N-pentylcarbamoyl group, N, N-dipentylcarbamoyl group, N- (1-ethylpropyl) carbamoyl group, N, N-di (1-ethylpropyl) carba Yl group, N-hexylcarbamoyl group, N, N-dihexylcarbamoyl group, N- (2-ethyl) hexylcarbamoyl group, N, N-di (2-ethyl) hexylcarbamoyl group, N-heptylcarbamoyl group, N, N-diheptylcarbamoyl group, N-octylcarbamoyl group, N, N-dioctylcarbamoyl group, N-nonylcarbamoyl group, N, N-octylmethylcarbamoyl group, N, N-octylbutylcarbamoyl group, N, N-di Nonylcarbamoyl group, N-phenylcarbamoyl group, N, N-diphenylcarbamoyl group, N, N-ethylmethylcarbamoyl group, N, N-propylmethylcarbamoyl group, N, N-isopropylmethylcarbamoyl group, N, N-butyl Methylcarbamoyl group, N-decylcarbamoyl group, N, N Decylmethylcarbamoyl group, N-undecylcarbamoyl group, N, N-undecylmethylcarbamoyl group, N-dodecylcarbamoyl group, N, N-dodecylmethylcarbamoyl group, N-icosylcarbamoyl group, N, N-icosyl 1 or 2 carbon atoms (preferably carbon atoms) such as a methylcarbamoyl group, an N, N-tert-butylmethylcarbamoyl group, an N, N-phenylmethylcarbamoyl group, and a group represented by the following formula A hydrocarbon group having 1 to 10) or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably A carbamoyl group substituted with a group derivatized with an octylsulfamoyl group) or the like;

Trifluoromethyl group, perfluoroethyl group, perfluoropropyl group, perfluoroisopropyl group, perfluorobutyl group, perfluoropentyl group, perfluorohexyl group, perfluoroheptyl group, perfluorooctyl group, perfluorononyl group, A carbon atom having 1 to 20 carbon atoms in which all hydrogen atoms such as perfluorodecyl group, perfluoroundecyl group, perfluorododecyl group, perfluoroicosyl group, perfluorocyclohexyl group and perfluorophenyl group are substituted with fluorine atoms. A hydrogen group;
Perfluoroethylmethyl group, perfluoropropylmethyl group, perfluoroisopropylmethyl group, perfluorobutylmethyl group, perfluoropentylmethyl group, perfluorohexylmethyl group, perfluoroheptylmethyl group, perfluorooctylmethyl group, perfluoro A straight chain having 1 to 20 carbon atoms in which all hydrogen atoms such as nonylmethyl group, perfluorodecylmethyl group, perfluoroundecylmethyl group, perfluorododecylmethyl group and perfluoroicosylmethyl group are substituted with fluorine atoms Or a hydrocarbon group having 1 to 20 carbon atoms substituted by a branched alkyl group;

  1 to 20 carbon atoms (preferably carbon atoms) in which part of hydrogen atoms such as 2-fluorophenyl group, 3-fluorophenyl group, 4-fluorophenyl group and 2,4,6-trifluorophenyl group are substituted with fluorine. 1-10) hydrocarbon radicals;

-CO-SH, -CO-S- CH 3, -CO-S-CH 2 CH 3, -CO-S-CH 2 -CH 2 -CH 3 and _{-CO-S-CH 2 -CH 2} -CH 2 A thiocarbonyl group bonded to an alkyl group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as —CH _3; and an aryl group having 6 to 20 carbon atoms such as —CO—S—C ₆ H _5. A thiocarbonyl group;

  * -COCO-R as represented by the following formula (wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, satisfying 1 to 20 carbon atoms among the hydrocarbon groups mentioned above) Or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably octyl sulfamoyl group) A group derived from, etc.)

* -NRCONR ₂ represented by the following formula (wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, those satisfying 1 to 20 carbon atoms among the hydrocarbon groups mentioned above) ) Or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group), etc. And the R may be the same or different from each other and may be bonded to each other to form a ring);

* -OCONR ₂ represented by the following formula (wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, those satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above) ) Or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group), etc. And the R may be the same or different from each other and may be bonded to each other to form a ring);

  * -NRCOOR as represented by the following formula (wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, those satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above)) Or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. A derivatized group), wherein the Rs may be the same or different from each other and may be bonded to each other to form a ring;

_{* -OP (O) (OCH 3} ) in such _{2 * -OP (O) (OR} ) 2 ( wherein, R represents a hydrogen atom, a hydrocarbon group (e.g., hydrocarbon groups mentioned above having 1 to 20 carbon atoms Or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms) A group derived from (preferably an octylsulfamoyl group) or the like, and the Rs may be the same or different from each other, and may be bonded to each other to form a ring;
* -SiR ₃ (* -Si (CH ₃ ) ₃ , * -Si (CH ₂ CH ₃ ) ₃ , * -Si (C ₆ H ₅ ) ₃ and * -Si (CH (CH ₃ ) ₂ ) ₃ In the formula, R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, those satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivatizing group thereof (for example, a carboxy group, sulfo group). A group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), a C1-C10 alkylsulfamoyl group (preferably an octylsulfamoyl group) and the like, and the R is Groups that may be the same or different from each other and may be bonded to each other to form a ring);
Etc.

As the divalent substituent, an oxo group, a thioxo group, an imino group, an imino group substituted with an alkyl group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms), and an aryl group having 6 to 20 carbon atoms are substituted. And imino groups. Examples of the imino group substituted with an alkyl group include CH ₃ —N═, CH ₃ —CH ₂ —N═, CH ₃ — (CH ₂ ) ₂ —N═, and CH ₃ — (CH ₂ ) ₃ —N =. Can be mentioned. Examples of the imino group substituted with an aryl group include C ₆ H ₅ —N═.

The substituent of the hydrocarbon group having 1 to 40 carbon atoms is preferably a substituent of group s1. The derivatizing groups shown below are a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), and the like. A derivatized group is preferred.
[Group s1]
An oxy group having a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof bonded to one side;
A carbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
An oxycarbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
An amino group;
An amino group substituted by one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
A sulfamoyl group;
A sulfamoyl group substituted with one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
A carbonylamino group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
A hydroxy group;
A halogen atom;
-CO ₂ M (preferably a carboxy group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom.);
-SO ₃ M (preferably a sulfo group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom.);
A nitro group;
A cyano group;
A carbonyloxy group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
A sulfonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
A carbamoyl group;
A carbamoyl group substituted with one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
A hydrocarbon group having 1 to 20 carbon atoms in which all of the hydrogen atoms are substituted by fluorine atoms;
A hydrocarbon group having 1 to 20 carbon atoms substituted with a linear or branched alkyl group having 1 to 20 carbon atoms in which all of the hydrogen atoms are substituted with fluorine atoms;
A hydrocarbon group having 1 to 20 carbon atoms in which a part of hydrogen atoms is substituted by fluorine;
Oxo group

The substituent of the hydrocarbon group having 1 to 40 carbon atoms is more preferably a substituent of group s2.
[Group s2]
An oxy group having a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof bonded to one side;
A carbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
An oxycarbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
An amino group;
An amino group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof;
A sulfamoyl group;
A sulfamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof;
A carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
A hydroxy group;
Fluorine atom, chlorine atom, bromine atom;
-CO ₂ M (preferably a carboxy group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom.);
-SO ₃ M (preferably a sulfo group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom.);
A nitro group;
A cyano group;
A carbonyloxy group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
A sulfonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
A carbamoyl group;
A carbamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof;
A hydrocarbon group having 1 to 10 carbon atoms in which all of the hydrogen atoms are substituted by fluorine atoms;
A hydrocarbon group having 1 to 10 carbon atoms substituted by a linear or branched alkyl group having 1 to 10 carbon atoms in which all of the hydrogen atoms are substituted with fluorine atoms;
A hydrocarbon group having 1 to 10 carbon atoms in which a part of hydrogen atoms is substituted by fluorine;
Oxo group

Examples of the hydrocarbon group ^{R N1Z5, R 1Z5, R 2Z5} , R 3Z5, R 4Z5, R 5Z5, R 6Z5, R 7Z5, carbon atoms having a substituent represented by R ^101Z5 and R ^102Z5 1~40, 1 And a C1-C40 hydrocarbon group having a monovalent or divalent substituent, preferably a C1-C30 saturated or unsaturated chain hydrocarbon group having a monovalent or divalent substituent. A saturated or unsaturated alicyclic hydrocarbon group having 3 to 30 carbon atoms having a monovalent or divalent substituent, or an aromatic hydrocarbon group having 6 to 30 carbon atoms having a monovalent or divalent substituent, or A group in which a hydrocarbon group is combined, and examples thereof include a group having 1 to 30 carbon atoms having a monovalent or divalent substituent,
More preferably, a saturated or unsaturated chain hydrocarbon group having 1 to 20 carbon atoms having a substituent of group s1, or a saturated or unsaturated alicyclic hydrocarbon group having 3 to 20 carbon atoms having a substituent of group s1. A group having 6 to 20 carbon atoms having a substituent of group s1 or a combination of hydrocarbon groups, and a group having 1 to 20 carbon atoms having a substituent of group s1,
Particularly preferably, it is a saturated or unsaturated chain hydrocarbon group having 1 to 15 carbon atoms having a substituent of group s2, or a saturated or unsaturated alicyclic hydrocarbon group having 3 to 15 carbon atoms having a substituent of group s2. , A group having a substituent of group s2 and a combination of an aromatic hydrocarbon group having 6 to 15 carbon atoms or a hydrocarbon group, and a group having 1 to 15 carbon atoms having a substituent of group s2.

In Examples ^{R N1Z5, R 1Z5, R 2Z5} , R 3Z5, R 4Z5, R 5Z5, R 6Z5, heterocyclic group represented by R ^7Z5, R ^101Z5 and R ^102Z5, may be monocyclic polycyclic Preferably, it is a heterocyclic ring containing a hetero atom as a ring component. Examples of the hetero atom include a nitrogen atom, an oxygen atom, and a sulfur atom.
The number of carbon atoms of the heterocyclic group is preferably 3-30, more preferably 3-22, still more preferably 3-20, still more preferably 3-18, and even more preferably 3-3. 15 and particularly preferably 3-14.

As a heterocyclic ring containing a nitrogen atom,
Monocyclic saturated heterocycles such as aziridine, azetidine, pyrrolidine, piperidine and piperazine;
Pyrrol such as 2,5-dimethylpyrrole, pyrazole such as 2-methylpyrazole and 3-methylpyrazole, 5-membered unsaturated heterocyclic ring such as imidazole, 1,2,3-triazole and 1,2,4-triazole ;
6-membered unsaturated heterocycles such as pyrimidines such as pyridine, pyridazine, 6-methylpyrimidine, pyrazines and 1,3,5-triazines;
Indazole, indoline, isoindoline, indole, indolizine, benzimidazole, quinoline, isoquinoline, quinoxaline such as 5,6,7,8-tetrahydro (3-methyl) quinoxaline, 3-methylquinoxaline, quinazoline, cinnoline, phthalazine, naphthyridine , Condensed bicyclic heterocycles such as purine, pteridine, benzopyrazole, benzopiperidine;
And condensed tricyclic heterocycles such as carbazole, acridine and phenazine.

As a heterocyclic ring containing an oxygen atom,
Monocyclic saturated heterocycles such as oxirane, oxetane, tetrahydrofuran, tetrahydropyran, 1,3-dioxane and 1,4-dioxane, 1-cyclopentyldioxolane;
Bicyclic saturated heterocycles such as 1,4-dioxaspiro [4.5] decane, 1,4-dioxaspiro [4.5] nonane;
Lactone heterocycles such as α-acetolactone, β-propiolactone, γ-butyrolactone, γ-valerolactone and δ-valerolactone;
5-membered unsaturated heterocyclic rings such as furan such as 2,3-dimethylfuran and 2,5-dimethylfuran;
6-membered unsaturated heterocyclic rings such as 2H-pyran and 4H-pyran;
Fused bicyclic heterocycles such as 1-benzofuran, benzopyran such as 4-methylbenzopyran, benzodioxole, chroman and isochroman;
And condensed tricyclic heterocycles such as xanthene and dibenzofuran;

As a heterocyclic ring containing a sulfur atom,
5-membered saturated heterocyclic ring such as dithiolane;
6-membered saturated heterocyclic rings such as thiane, 1,3-dithiane, 2-methyl-1,3-dithiane;
5-membered unsaturated heterocyclic rings such as thiophene such as 3-methylthiophene and 2-carboxythiophene, benzothiopyran such as 4H-thiopyran and benzotetrahydrothiopyran;
Condensed bicyclic heterocycles such as benzothiophene;
And condensed tricyclic heterocycles such as thianthrene and dibenzothiophene.

As a heterocyclic ring containing a nitrogen atom and an oxygen atom,
Monocyclic saturated heterocycles such as morpholine, 2-pyrrolidone, 2-methyl-2-pyrrolidone, 2-piperidone and 2-methyl-2-piperidone;
Monocyclic unsaturated heterocycles such as oxazole such as 4-methyloxazole, isoxazole such as 2-methylisoxazole and 3-methylisoxazole;
Condensed bicyclic heterocycles such as benzoxazole, benzisoxazole, benzoxazine, benzodioxane, benzimidazoline;
And condensed tricyclic heterocycles such as phenoxazine.

As a heterocyclic ring containing a nitrogen atom and a sulfur atom,
Monocyclic heterocycles such as thiazole such as 3-methylthiazole and 2,4-dimethylthiazole;
Fused bicyclic heterocycles such as benzothiazole;
Condensed tricyclic heterocycles such as phenothiazine; and the like.

  The heterocycle may be a group in which the above-described hydrocarbon groups are combined, and examples thereof include a tetrahydrofurylmethyl group.

Furthermore, the heterocyclic ring may be represented by the following formula.

The above heterocyclic group may be heterocyclic group or two of R ^1Z5 ~R ^5Z5 formed by bonding. Such heterocyclic groups can have two or more rings ring structure with the benzene ring to which R ^1Z5 ~R ^5Z5 binds. Examples of the two or more ring structures include structures of the following formulas.

  In addition, the bonding position of the above heterocyclic ring is a portion from which an arbitrary hydrogen atom contained in each ring is eliminated.

^{R N1Z5, R 1Z5, R 2Z5} , R 3Z5, R 4Z5, R 5Z5, R 6Z5, heterocyclic group represented by R ^7Z5, R ^101Z5 and R ^102Z5 may have a substituent. Examples of the ^{substituent, R N1Z5, R 1Z5, R} 2Z5, R 3Z5, R 4Z5, R 5Z5, R 6Z5, R 7Z5, which may have a hydrocarbon group represented by R ^101Z5 and R ^102Z5 substituted The same thing as a group is mentioned. When the heterocyclic ring contains a nitrogen atom as a constituent element, the above-described hydrocarbon group may be bonded to the nitrogen atom as a substituent.
Preferred examples of the substituent, and ^{R N1Z5, R 1Z5, R 2Z5} , R 3Z5, R 4Z5, R 5Z5, R 6Z5, R 7Z5, have a hydrocarbon group represented by R ^101Z5 and R ^102Z5 Examples of the preferred substituents are the same.
Examples of the heterocyclic group having a ^{R N1Z5, R 1Z5, R 2Z5} , R 3Z5, R 4Z5, R 5Z5, R 6Z5, R 7Z5, substituents represented by R ^101Z5 and R ^102Z5, 1 monovalent or divalent substituent A heterocyclic group having a substituent, preferably a heterocyclic group having a substituent of group s1, more preferably a heterocyclic group having a substituent of group s2.
The hydrocarbon group or heterocyclic group may have one or more substituents (first substituent), and the two or more substituents are independent of each other. They may be the same or different. Further, the first substituent may have another substituent (second substituent) bonded to a hydrocarbon group contained in a part thereof. The second substituent can be selected from the same groups as the first substituent.

^{Hereinafter, R N1Z5, R 1Z5, R} 2Z5, R 3Z5, R 4Z5, R 5Z5, R 6Z5, and -CO-R ^102Z5 of ^{R 7Z5, -COO-R 101Z5,} -OCO-R 102Z5, -COCO-R 102Z5 _{^{, -O-R 102Z5, -SO 2}} -R 101Z5, -SO 2 N (R 102Z5) 2, -CON (R 102Z5) 2, -N (R 102Z5) 2, -NHCO-R 102Z5, -NHCO-N _{^{(R 102Z5) 2, -NHCOOR 102Z5}} , -OCON (R 102Z5) 2, halogen atom, -SO ₃ M, for -CO ₂ M will be described.

As —CO—R ^102Z5 , formyl group; acetyl group, propanoyl group, butanoyl group, 2,2-dimethylpropanoyl group, pentanoyl group, hexanoyl group, (2-ethyl) hexanoyl group, heptanoyl group, octanoyl group, nonanoyl A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof, such as a group, a decanoyl group, an undecanoyl group, a dodecanoyl group, a heicosanoyl group, a benzoyl group, and the like A derivatized group (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. Group), the number of carbon atoms is 2 to 41 when the carbonyl group is an acyl group. ) And include groups corresponding to the -CO-R ^102Z5 in the compounds shown in Table 1Z5~ Table 15Z5 -CO-R ^102Z5 Table 1-966 of the relevant group and Japanese Patent Application No. 2017-016290 to the compounds shown in Preferably, the hydrocarbon group having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms) or a carbonyl group to which the derivatizing group is bonded (when the carbonyl group is an alkanoyl group, the carbon number is more preferably And groups corresponding to -CO- ^R102Z5 in the compounds shown in Tables 1Z5 to ^15Z5 .

-COO-R ^101Z5 includes methoxycarbonyl group, ethoxycarbonyl group, propoxycarbonyl group, tert-butoxycarbonyl group, butoxycarbonyl group, pentyloxycarbonyl group, hexyloxycarbonyl group, (2-ethyl) hexyloxycarbonyl group, Heptyloxycarbonyl group, octyloxycarbonyl group, nonyloxycarbonyl group, decyloxycarbonyl group, undecyloxycarbonyl group, dodecyloxycarbonyl group, phenyloxycarbonyl group, icosyloxycarbonyl group, etc. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon, etc. Number 1 0 alkylsulfamoyl group group (preferably octyl sulfamoyl group) corresponding to the -COO-R ^102Z5 in compounds derivatized groups) is shown in oxycarbonyl group and Tables 1Z5~ table 15Z5 bound by such And groups corresponding to —COO—R ^102Z5 in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290, preferably a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof bonded thereto. Examples include oxycarbonyl groups and groups corresponding to —COO—R ^102Z5 in the compounds shown in Tables 1Z5 to ^15Z5 .

-OCO-R ^102Z5 includes ^formyloxy group; acetoxy group, propanoyloxy group, butanoyloxy group, 2,2-dimethylpropanoyloxy group, pentanoyloxy group, hexanoyloxy group, (2-ethyl) Hexanoyloxy group, heptanoyloxy group, octanoyloxy group, nonanoyloxy group, decanoyloxy group, undecanoyloxy group, dodecanoyloxy group, heicosanoyloxy group, benzoyloxy group, and the above formula A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom) ), An alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. If the reduction radicals) is bonded to a carbonyl group (said carbonyl group to an acyloxy group, a carbon number of 2-41), as well as -OCO-R ^102Z5 in the compounds shown in Table 1Z5~ Table 15Z5 Examples of the corresponding group and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. ^2017-016290 include a group corresponding to —OCO—R ^102Z5 , preferably 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms). ) Or a carbonyloxy group to which the derivatizing group is bonded (when the carbonyloxy group is an acyloxy group, the carbon number is more preferably 2 to 12), and Tables 1Z5 to 15Z5 ^Examples of the compound include a group corresponding to -OCO-R ^102Z5 .

-COCO-R ^102Z5 includes methyl oxalyl group, ethyl oxalyl group, propyl oxalyl group, butyl oxalyl group, pentyl oxalyl group, hexyl oxalyl group, (2-ethyl) hexyl oxalyl group, heptyl oxalyl group, octyl oxalyl group, nonyl Oxalyl group, decyloxalyl group, undecyloxalyl group, dodecyloxalyl group, icosyloxalyl group, cyclopentyloxalyl group, cyclohexyloxalyl group, phenyloxalyl group, p-tolyloxalyl group, etc., and groups represented by the above formula A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), 10 alkyl sulfamos Group and JP Le group (preferably octyl sulfamoyl group) corresponding to the -COCO-R ^102Z5 In the compound represented oxalyl groups, as well as Table 1Z5~ Table 15Z5 derivatized group, etc.) are bonded 2017-016290 In the compounds shown in Tables 1 to ⁹⁶⁶ , groups corresponding to —COCO—R ^102Z5 and the like can be mentioned.

As —O—R ^102Z5 group, hydroxy group; methoxy group, ethoxy group, propoxy group, isopropoxy group, butoxy group, isobutoxy group, sec-butoxy group, tert-butoxy group, pentyloxy group, hexyloxy group, heptyl Oxy group, octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, dodecyloxy group, (2-ethyl) hexyloxy group, icosyloxy group, 1-phenylethoxy group, 1-methyl-1-phenylethoxy group, Phenyloxy group, 2,3-dimethylphenyloxy group, 2,4-dimethylphenyloxy group, 2,5-dimethylphenyloxy group, 2,6-dimethylphenyloxy group, 3,4-dimethylphenyloxy group, 3 , 5-dimethylphenyloxy group, 2,2-dicyanophenyloxy Group, 2,3-dicyanophenyloxy group, 2,4-dicyanophenyloxy group, 2,5-dicyanophenyloxy group, 2,6-dicyanophenyloxy group, 3,4-dicyanophenyloxy group, 3,5 -Dicyanophenyloxy group, 4-methoxyphenyloxy group, 2-methoxyphenyloxy group, 3-methoxyphenyloxy group, 4-ethoxyphenyloxy group, 2-ethoxyphenyloxy group, 3-ethoxyphenyloxy group and the like, and A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group represented by the above formula or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably Is a chlorine atom), derivatized with an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. -O-R in the group) oxy group and Tables 1Z5~ table in the compound represented by 15Z5 shown in Table 1 to 966 groups and Japanese Patent Application No. 2017-016290 corresponding to -O-R ^102Z5 compound bound ^The group etc. which correspond to ^102Z5 are mentioned, Preferably it corresponds to -O-R ^102Z5 in the compound shown by the oxy group which the C1-C10 hydrocarbon group or its derivatization group couple | bonded, and Table 1Z5-Table 15Z5. Groups and the like.

As —SO ₂ —R ^101Z5 , methylsulfonyl group, ethylsulfonyl group, propylsulfonyl group, butylsulfonyl group, pentylsulfonyl group, ^{hexylsulfonyl} group, (2-ethyl) ^{hexylsulfonyl} group, ^{heptylsulfonyl} group, octylsulfonyl group, 1 to 40 carbon atoms such as a nonylsulfonyl group, a decylsulfonyl group, an undecylsulfonyl group, a dodecylsulfonyl group, an icosylsulfonyl group, a phenylsulfonyl group, a p-tolylsulfonyl group, and a group represented by the above formula Preferably a hydrocarbon group having 1 to 20 carbon atoms or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms. (Preferably octylsulfamoyl group) -SO ₂ In the compounds shown in Table 1 to 966 groups and and Japanese Patent Application No. 2017-016290 corresponding to -SO ₂ -R ^102Z5 in the compound group) is shown in the sulfonyl group and Table 1Z5~ table 15Z5 bound - ^Groups corresponding to R ^102Z5, and the like. Preferably, in the sulfonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded and the compounds shown in Table 1Z5 to Table 15Z5, —SO ₂ —R ^102Z5 Applicable groups and the like can be mentioned.

—SO ₂ N (R ^102Z5 ) ₂ includes a sulfamoyl group;
N-methylsulfamoyl group, N-ethylsulfamoyl group, N-propylsulfamoyl group, N-isopropylsulfamoyl group, N-butylsulfamoyl group, N-isobutylsulfamoyl group, N- sec-butylsulfamoyl group, N-tert-butylsulfamoyl group, N-pentylsulfamoyl group, N- (1-ethylpropyl) sulfamoyl group, N-hexylsulfamoyl group, N- (2- Ethyl) hexylsulfamoyl group, N-heptylsulfamoyl group, N-octylsulfamoyl group, N-nonylsulfamoyl group, N-decylsulfamoyl group, N-undecylsulfamoyl group, N- Dodecylsulfamoyl group, N-icosylsulfamoyl group, N-phenylsulfamoyl group, etc., and groups represented by the above formula A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon number In a sulfamoyl group substituted with 1 to 10 alkylsulfamoyl groups (preferably a group derivatized with an octylsulfamoyl group, etc.) and the compounds shown in Tables 1Z5 to 15Z5, —SO ₂ NH (R ^102Z5X ) (Provided that R ^102Z5X is the same as R ^102Z5 except that R ^102Z5X is not a hydrogen atom) and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290, —SO ₂ NH (R ^102Z5X ) (Provided that R ^102Z5X is the same as R ^102Z5 except that it does not become a hydrogen atom);

N, N-dimethylsulfamoyl group, N, N-ethylmethylsulfamoyl group, N, N-diethylsulfamoyl group, N, N-propylmethylsulfamoyl group, N, N-dipropylsulfamoyl group Group, N, N-isopropylmethylsulfamoyl group, N, N-diisopropylsulfamoyl group, N, N-tert-butylmethylsulfamoyl group, N, N-diisobutylsulfamoyl group, N, N- Disec-butylsulfamoyl group, N, N-ditert-butylsulfamoyl group, N, N-butylmethylsulfamoyl group, N, N-dibutylsulfamoyl group, N, N-dipentylsulfa Moyl group, N, N-di (1-ethylpropyl) sulfamoyl group, N, N-dihexylsulfamoyl group, N, N-di (2-ethyl) hexyls Famoyl group, N, N-diheptylsulfamoyl group, N, N-octylmethylsulfamoyl group, N, N-dioctylsulfamoyl group, N, N-dinonylsulfamoyl group, N, N-decyl Methylsulfamoyl group, N, N-undecylmethylsulfamoyl group, N, N-dodecylmethylsulfamoyl group, N, N-icosylmethylsulfamoyl group, N, N-phenylmethylsulfamoyl Two hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group, N, N-diphenylsulfamoyl group, and the group represented by the above formula, or a derivatized group thereof ( For example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably octyl sulfamoyl) ^{_{) -SO 2 N (R 102Z5X)}} 2 ( provided that at sulfamoyl groups and compounds shown in Table 1Z5~ table 15Z5 substituted with derivatized groups) in such, except that R ^102Z5X is not a hydrogen atom, R in the compounds shown in Table 1 to 966 of the corresponding group and Japanese Patent Application No. 2017-016290 the same as is) and _{^{102Z5 -SO 2 N (R 102Z5X)}} 2 ( where except that R ^102Z5X is not a hydrogen atom, The same as R ^102Z5 ), and the like.
Preferably, it corresponds to —SO ₂ N (R ^102Z5 ) ₂ in the compounds shown in Table 1Z5 to Table 15Z5 and sulfamoyl groups substituted with one or two C 1-10 hydrocarbon groups or derivatized groups thereof. Groups and the like.

^—CON (R ^102Z5 ) ₂ includes a carbamoyl group;
N-methylcarbamoyl group, N-ethylcarbamoyl group, N-propylcarbamoyl group, N-isopropylcarbamoyl group, N-butylcarbamoyl group, N-isobutylcarbamoyl group, N-sec-butylcarbamoyl group, N-tert-butylcarbamoyl Group, N-pentylcarbamoyl group, N- (1-ethylpropyl) carbamoyl group, N-hexylcarbamoyl group, N- (2-ethyl) hexylcarbamoyl group, N-heptylcarbamoyl group, N-octylcarbamoyl group and N- One of nonylcarbamoyl group, N-decylcarbamoyl group, N-undecylcarbamoyl group, N-dodecylcarbamoyl group, N-icosylcarbamoyl group, N-phenylcarbamoyl group, etc., and a group represented by the above formula 1 to 40 carbon atoms (preferably charcoal A hydrocarbon group of 1 to 20) or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably In the compounds shown in Table 1Z5 to Table 15Z5, -CONH (R ^102Z5X ) (provided that R ^102Z5X is not a hydrogen atom) , -CONH (R ^102Z5X) (provided that the group and and compounds shown in Table 1 to 966 of Japanese Patent Application No. 2017-016290 corresponding to same in a) and R ^102Z5, except that R ^102Z5X is not a hydrogen atom, The same as R ^102Z5 )

N, N-dimethylcarbamoyl group, N, N-ethylmethylcarbamoyl group, N, N-diethylcarbamoyl group, N, N-propylmethylcarbamoyl group, N, N-dipropylcarbamoyl group, N, N-isopropylmethylcarbamoyl Group, N, N-diisopropylcarbamoyl group, N, N-tert-butylmethylcarbamoyl group, N, N-diisobutylcarbamoyl group, N, N-disec-butylcarbamoyl group, N, N-ditert-butylcarbamoyl group N, N-butylmethylcarbamoyl group, N, N-dibutylcarbamoyl group, N, N-butyloctylcarbamoyl group, N, N-dipentylcarbamoyl group, N, N-di (1-ethylpropyl) carbamoyl group, N , N-dihexylcarbamoyl group, N, N-di (2-ethyl) hexyl Rucarbamoyl group, N, N-diheptylcarbamoyl group, N, N-octylmethylcarbamoyl group, N, N-dioctylcarbamoyl group, N, N-dinonylcarbamoyl group, N, N-decylmethylcarbamoyl group, N, N -Undecylmethylcarbamoyl group, N, N-dodecylmethylcarbamoyl group, N, N-icosylmethylcarbamoyl group, N, N-phenylmethylcarbamoyl group, N, N-diphenylcarbamoyl group, etc. Two hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group to be synthesized or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom) ), A C 1-10 alkylsulfamoyl group (preferably an octylsulfamoyl group), etc. Groups) -CON In the compounds shown in carbamoyl group and Tables 1Z5~ table 15Z5 substituted with (R ^102Z5X) ₂ (where except that R ^102Z5X is not a hydrogen atom, corresponding to the same in a) and R ^102Z5 And -CON (R ^102Z5X ) ₂ (provided that R ^102Z5X is the same as R ^102Z5 except that it is not a hydrogen atom) in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290 Group, etc.
Preferably, one or two hydrocarbon groups having 1 to 10 carbon atoms or a carbamoyl group substituted with a derivatizing group thereof, and a group corresponding to ^—CON (R ^102Z5 ) ₂ in the compounds shown in Tables 1Z5 to 15Z5, etc. Is mentioned.

—N (R ^102Z5 ) ₂ includes an amino group;
N-methylamino group, N-ethylamino group, N-propylamino group, N-isopropylamino group, N-butylamino group, N-isobutylamino group, N-sec-butylamino group, N-tert-butylamino Group, N-pentylamino group, N-hexylamino group, N- (2-ethyl) hexylamino group, N-heptylamino group, N-octylamino group, N-nonylamino group, N-decylamino group, N-un A decylamino group, an N-dodecylamino group, an N-icosylamino group, an N-phenylamino group, and the like, and one of 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group represented by the above formula A hydrocarbon group or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl group having 1 to 10 carbon atoms; -NH (R ^102Z5X) (provided that the amino group and Tables 1Z5~ Table 15Z5 compounds shown in substituted with Amoiru group (preferably octyl sulfamoyl group) were derivatized with such groups), R ^102Z5X a hydrogen atom -NH (R ^102Z5X ) (provided that R ^102Z5X is a hydrogen atom) in the group corresponding to R ^102Z5 and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290. The same as R ^102Z5 except that it is not)

N, N-dimethylamino group, N, N-ethylmethylamino group, N, N-diethylamino group, N, N-propylmethylamino group, N, N-dipropylamino group, N, N-isopropylmethylamino group N, N-diisopropylamino group, N, N-tert-butylmethylamino group, N, N-diisobutylamino group, N, N-disec-butylamino group, N, N-ditert-butylamino group, N, N-butylmethylamino group, N, N-dibutylamino group, N, N-dipentylamino group, N, N-di (1-ethylpropyl) amino group, N, N-dihexylamino group, N, N -Di (2-ethyl) hexylamino group, N, N-diheptylamino group, N, N-dioctylamino group, N, N-dinonylamino group, N, N-decylmethylamino group, N, N- Ndecylmethylamino group, N, N-dodecylmethylamino group, N, N-icosylmethylamino group, N, N-phenylmethylamino group, N, N-diphenylamino group, etc., and the above formula Two hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom) In the compounds shown in Tables 1Z5 to 15Z5 and —N (R), an amino group substituted with a C 1-10 alkylsulfamoyl group (preferably a group derivatized with an octylsulfamoyl group) or the like. ^102Z5X) ₂ (where reduction except that R ^102Z5X is not a hydrogen atom, are shown in Table 1 to 966 groups and Japanese Patent Application No. 2017-016290 corresponding to same in a) and R ^102Z5 -N (R ^102Z5X) ₂ (provided that, R ^102Z5X, except that not a hydrogen atom, same as is the R ^102Z5) at the object and a group corresponding to the like,
Preferably, one or two hydrocarbon groups having 1 to 10 carbon atoms or an amino group substituted with a derivatizing group thereof, and a group corresponding to —N (R ^102Z5 ) ₂ in the compounds shown in Tables 1Z5 to 15Z5, etc. Is mentioned.

-NHCO-R ^102Z5 includes formylamino group; acetylamino group, propanoylamino group, butanoylamino group, 2,2-dimethylpropanoylamino group, pentanoylamino group, hexanoylamino group, (2-ethyl ) Hexanoylamino group, heptanoylamino group, octanoylamino group, nonanoylamino group, decanoylamino group, undecanoylamino group, dodecanoylamino group, heicosanoylamino group, benzoylamino group, etc. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group represented by the above formula or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably Is a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) In the case of a derivatized group) bonded to a carbonylamino group (an acylamino group the carbonyl amino group, -NHCO-R ^102Z5 in compound number of carbon atoms indicated in which) and Table 1Z5~ Table 15Z5 1 to 40 And groups corresponding to —NHCO—R ^102Z5 in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290, and the like.
Preferably, a carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded (when the carbonylamino group is an alkanoylamino group, the carbon number is more preferably 1 to 10) and Table 1Z5 In the compounds shown in Table 15Z5, groups corresponding to -NHCO-R ^102Z5 and the like can be mentioned.

Examples of —NHCON (R ^102Z5 ) ₂ include groups listed above, groups corresponding to —NHCON (R ^102Z5 ) ₂ in the compounds shown in Tables 1Z5 to 15Z5, and Tables 1 to 1 of Japanese Patent Application No. 2017-016290. And a group corresponding to —NHCON (R ^102Z5 ) ₂ in the compound represented by 966.

-NHCOOR ^102Z5 includes the groups listed above, the groups corresponding to -NHCOOR ^102Z5 in the compounds shown in Tables 1Z5 to 15Z5, and -NHCOOR in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290. ^Examples include groups corresponding to ^102Z5 .

^{Examples of} —OCON (R ^102Z5 ) ₂ include groups listed above, groups corresponding to —OCON (R ^102Z5 ) ₂ in the compounds shown in Tables 1Z5 to ^15Z5 , and Tables 1 to 1 of Japanese Patent Application No. 2017-016290. And a group corresponding to —OCON (R ^102Z5 ) ₂ in the compound represented by 966.

As the halogen atom, a fluorine atom, a chlorine atom, a bromine atom and an iodine atom are preferable.
Examples of M in —SO ₃ M and —CO ₂ M include a hydrogen atom; an alkali metal atom such as a lithium atom, a sodium atom and a potassium atom, preferably a hydrogen atom, a sodium atom and a potassium atom.

The ^{-CO-R 102Z5, -COO-R} 102Z5, -OCO-R 102Z5, -COCO-R 102Z5, -O-R 102Z5, -SO 2 -R 102Z5, -SO 2 N (R 102Z5) 2, -CON ^{Substituents contained in} ( ^R102Z5 ) ₂ , -N ( ^R102Z5 ) ₂ , -NHCO- ^R102Z5 , -NHCON ( ^R102Z5 ) ₂ , ^-NHCOOR102Z5 , -OCON ( ^R102Z5 ) ₂ (first substituent) May be one or more, and the two or more substituents may be the same or different independently of each other.
Further, the first substituent may have another substituent (second substituent) bonded to a hydrocarbon group contained in a part thereof. The second substituent can be selected from the same groups as the first substituent.

The ring formed by R ^2Z5 and R ^3Z5 , R ^3Z5 and R ^4Z5 , and R ^4Z5 and R ^5Z5 is condensed with the benzene ring of the isoindoline skeleton of the compound represented by formula (IZ5). The condensed ring structure of the ring formed by R ^2Z5 and R ^3Z5 , R ^3Z5 and R ^4Z5 , and R ^4Z5 and R ^5Z5 and the benzene ring includes indene, naphthalene, biphenylene, indacene, acenaphthylene, fluorene, phenalene, phenanthrene, Hydrocarbon condensed ring structures such as anthracene, fluoranthene, acephenanthrylene, aceanthrylene, triphenylene, pyrene, chrysene, N-methylphthalimide, N- (1-phenylethyl) phthalimide and tetracene, and their partially reduced forms ( For example, 9,10-dihydroanthracene, 1,2,3,4-tetrahydronaphthalene, etc.); indole, isoindole, indazole, quinoline, isoquinoline, phthalazine, quinoxaline, quinazoline, cinnoline, carbazole, carboline, phenant Jin, acridine, perimidine, nitrogen-containing condensed heterocyclic, and parts thereof reductant such as phenanthroline and phenazine; 3- oxygen-containing condensed such tetrahydrobenzo furan-2-one heterocyclic ring and its partially reduced products thereof.

When R ^2Z5 and R ^3Z5 , R ^3Z5 and R ^4Z5 , and R ^4Z5 and R ^5Z5 form a ring, the ring may have a substituent. Examples of the ^{substituent, R N1Z5, R 1Z5, R} 2Z5, R 3Z5, R 4Z5, R 5Z5, R 6Z5, R 7Z5, which may have a hydrocarbon group represented by R ^101Z5 and R ^102Z5 substituted The same thing as a group is mentioned. Preferred examples of the substituent, and ^{R N1Z5, R 1Z5, R 2Z5} , R 3Z5, R 4Z5, R 5Z5, R 6Z5, R 7Z5, have a hydrocarbon group represented by R ^101Z5 and R ^102Z5 Examples of the preferred substituents are the same.

When R ^3Z5 and R ^4Z5 form a ring, R ^2Z5 and R ^5Z5 are preferably a hydrogen atom, an amino group, and a hydroxy group, independently of each other.
When R ^2Z5 and R ^3Z5 form a ring, R ^4Z5 and R ^5Z5 preferably do not form a ring, more preferably R ^4Z5 and R ^5Z5 are hydrogen atoms.
When R ^4Z5 and R ^5Z5 form a ring, R ^2Z5 and R ^3Z5 preferably do not form a ring, and more preferably R ^2Z5 and R ^3Z5 are hydrogen atoms.

R ^1Z5, R ^6Z5 and R ^7Z5 is preferably a hydrogen atom.

R ^N1Z5 is —CO—R ^102Z5 , —COO—R ^101Z5 , ^—CON (R ^102Z5 ) ₂ , —N (R ^102Z5 ) ₂ , —CO ₂ M, or ^optionally having 1 to C carbon atoms. The hydrocarbon group is preferably 40 hydrocarbon groups, more preferably a hydrocarbon group having 1 to 30 carbon atoms which may have a substituent, and 1 to 20 carbon atoms which may have a substituent. The hydrocarbon group is more preferably a hydrocarbon group having 1 to 15 carbon atoms which may have a substituent, and particularly preferably 1 to 10 carbon atoms which may have a substituent. It is more particularly preferable that it is a hydrocarbon group having 1 to 6 carbon atoms which may have a substituent or a hydrocarbon group having 1 to 5 carbon atoms which may have a substituent. Particularly preferred is a methyl group, an ethyl group, or a phenyl group. Preferably, and most preferably a methyl group or an ethyl group.

From the viewpoint of reducing the retardation value of the color filter formed from the coloring composition, at least one of R ^2Z5 , R ^3Z5 , R ^4Z5 , and R ^5Z5 is -CO-R ^102Z5 , -COO-R ^101Z5 , ^{-OCO-R 102Z5, -COCO-R} 102Z5, -O-R 102Z5, -SO 2 -R 101Z5, -SO 2 N (R 102Z5) 2, -CON (R 102Z5) 2, -N (R 102Z5) 2 ^{, -NHCO-R 102Z5, -NHCO-} N (R 102Z5) 2, -NHCOOR 102Z5, -OCON (R 102Z5) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , substituents It is preferably a hydrocarbon group having 1 to 40 carbon atoms which may have a heterocyclic group which may have a substituent,
1 to 40 carbon atoms having 1 to 40 carbon atoms which may be substituted, 1 to 40 carbon atoms, halogen atoms, -N (R ^102Z5 ) ₂ , nitro groups and hydrogen atoms all or part of which are substituted with fluorine atoms. More preferably, it is 20 hydrocarbon groups, —NHCO—R ^102Z5 , —O—R ^102Z5 , —SO ₃ M or —CO ₂ M,
It is more preferable that it is a C1-C40 hydrocarbon group which may have a nitro group or a substituent, and it is still more preferable that it is a nitro group or a tert-butyl group. Alternatively, at least one pair of R ^2Z5 and R ^3Z5 , R ^3Z5 and R ^4Z5 , or R ^4Z5 and R ^5Z5 preferably forms a ring.

From the viewpoint of reducing the retardation value of the color filter formed from the coloring composition, at least one of R ^2Z5 , R ^3Z5 , R ^4Z5 , and R ^5Z5 is
1 to 40 carbon atoms having 1 to 40 carbon atoms which may be substituted, 1 to 40 carbon atoms, halogen atoms, -N (R ^102Z5 ) ₂ , nitro groups and hydrogen atoms all or part of which are substituted with fluorine atoms. Preferably 20 hydrocarbon groups, —NHCO—R ^102Z5 , —O—R ^102Z5 , —SO ₃ M or —CO ₂ M;
It is more preferably a nitro group or a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, and even more preferably a nitro group or a tert-butyl group. Among them, R ^3Z5 is a nitro group or tert-butyl group and R ^2Z5 , R ^4Z5 and R ^5Z5 are hydrogen atoms, or R ^2Z5 , R ^3Z5 and R ^5Z5 are hydrogen atoms and R ^4Z5 is nitro. Even more preferred is a group or a tert-butyl group.

Specific examples of compound (IZ5) include, for example, compounds of formula (IZ5-aa) having the substituents shown in Table 1Z5 to Table 15Z5 (IZ5-1) to Compound (IZ5-542) or an alkali metal salt thereof. Can be mentioned.
B ^a1Z5 B ^a2Z5 is the formula (BB2) to formula (BB60), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1), formula (BBO8), formula (BBO10) , Any partial structure represented by formula (BBD1) and formula (BBJ2). Formula (BB2) to Formula (BB60), Formula (BBK2), Formula (BBK3), Formula (BBK4), Formula (BBK14), Formula (BBI1), Formula (BBO8), Formula (BBO10), Formula (BBD1) and Formula (BBJ2) represents B ^a1Z1 B ^a2Z1 of Formula (IZ1-aa), (BB2) to (BB60), Formula (BBK2), Formula (BBK3), Formula (BBK4), Formula (BBK14), Formula (BBI1) ), Formula (BBO8), formula (BBO10), formula (BBD1), and formula (BBJ2). B ^A1Z5 and B ^A2Z5 each represent a bond, B ^A1Z5 the expression (BB2) ~ formula (BB60), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1) , Formula (BBO8), formula (BBO10), formula (BBD1), and formula (BBJ2), when B ^{1 is} a bond, B ^a2Z5 is a bond of B ² , and B ^a1Z5 is a formula (BB2) to formula ( ^BB60 ). ), formula (BBK2), formula (BBK3), formula (BBK4), formula (BBK14), formula (BBI1), formula (BBO8), formula (BBO10), formula (BBD1) and formula B ² of (BBJ2) When it is a bond, B ^a2Z5 is the bond of B ¹ .
B ^a1Z5 B ^a2Z5 includes formula (BB6), formula (BB8), formula (BB11), formula (BB14), formula (BB19), formula (BB37), formula (BB58), formula (BBJ2), formula (BBO8). ) And formula (BBO10) are preferred, and formula (BB6) and formula (BB19) are more preferred.

Each symbol in Table 1Z5 to Table 15Z5 represents the following partial structure. In the partial structure,
“Me” represents a methyl group,
“Et” represents an ethyl group;
“Bu” represents a butyl group,
“TBu” represents a tert-butyl group,
“Hex” represents a hexyl group,
“Oct” represents an octyl group;
“2EH” represents a 2-ethylhexyl group;
“CHM” represents a cyclohexylmethyl group,
“CH” represents a cyclohexyl group,
“PH” represents a phenyl group;
“BZ” represents a benzyl group;
“NPR” represents a propyl group;
“IPR” represents an isopropyl group;
“IBu” represents an isobutyl group,
“EOE” represents —CH ₂ CH ₂ OCH ₂ CH ₃ ,
“ALL” represents an allyl group,
“HYE” represents a 2-hydroxyethyl group,
“COM” represents —CO—CH ₃ ;
“COE” represents —COO—CH ₂ CH ₃ ;
“OCM” represents —OCO—CH ₃ ;
“OME” represents —O—CH ₃ ;
“SOT” represents a tosyl group;
“SNH” represents —SO ₂ NH—CH ₂ CH (CH ₂ CH ₃ ) ((CH ₂ ) ₃ CH ₃ );
“SN2” represents —SO ₂ N (CH ₃ ) ((CH ₂ ) ₇ CH ₃ ),
“CNM” represents —CONHCH ₃ ;
“CN2” represents —CON (CH ₃ ) C ₆ H ₅ ,
“NPH” represents —NHC ₆ H ₅ ,
"NOT" represents _{-N ((CH 2) 7 CH} 3) 2,
“NCO” represents —NHCO ((CH ₂ ) ₄ CH ₃ ),
“F” represents a fluorine atom,
“Cl” represents a chlorine atom,
“Br” represents a bromine atom;
“CN” represents a cyano group,
“NO2” represents a nitro group,
“SUA” represents —SO ₃ H;
“CBA” represents —CO ₂ H;
“CHO” represents —CHO,
“OCH” represents —OCOH;
“OH” represents —OH;
“SFM” represents —SO ₂ NH ₂ ;
“CBM” represents —CONH ₂ ;
“NH ₂ ” represents —NH ₂ ,
“NCH” represents —NHCOH.
In the partial structure represented by the following formula, * represents a bond.

  For example, compound (IZ5-1) is a compound represented by the following formula (IZ5-1).

Compound (IZ5-1) to Compound (IZ5-160) and Compound (IZ5-247) to Compound (IZ5-542) are preferred,
Compound (IZ5-1) to Compound (IZ5-160) and Compound (IZ5-247) to Compound (IZ5-484) are more preferable,
Compound (IZ5-1) to Compound (IZ5-160) are more preferred,
Compound (IZ5-1) to Compound (IZ5-101) are even more preferred,
Compound (IZ5-1) to compound (IZ5-44) are particularly preferred.

Specific examples of the compound (IZ5) also include compounds in which 1 to 3 hydrogen atoms contained in the compounds represented by Tables 1Z5 to 15Z5 are substituted with —SO ₃ M or —CO ₂ M. For example, a compound in which 1 to 3 sulfo groups are bonded to the compound (IZ5-1) in Table 1Z5 is represented by the following structure. However, in the formula,-(SO ₃ H) means that any hydrogen atom of the compound (IZ5-1) in Table 1Z5 is substituted.

Compounds in which 1 to 3 —SO ₃ M or —CO ₂ M are bound to compound (IZ5-1) to compound (IZ5-160) and compound (IZ5-247) to compound (IZ5-542) are preferable. ,
Compound (IZ5-1) to compound (IZ5-160) and compound (IZ5-247) to compound (IZ5-484) to which 1 to 3 —SO ₃ M or —CO ₂ M is bonded are more Preferably
More preferred is a compound in which 1 to 3 —SO ₃ M or —CO ₂ M is bound to compound (IZ5-1) to compound (IZ5-160),
Even more preferred is a compound in which 1 to 3 —SO ₃ M or —CO ₂ M is bound to compound (IZ5-1) to compound (IZ5-101),
A compound in which 1 to 3 —SO ₃ M or —CO ₂ M is bonded to Compound (IZ5-1) to Compound (IZ5-44) is particularly preferable.

As the compound (IZ5), in the formula (IZ5),
R ^N1Z5 may have a substituent selected from the group consisting of —CO—R ^102Z5 , —COO—R ^101Z5 , ^—CON (R ^102Z5 ) ₂ , or —SO ₃ M and —CO ₂ M. A hydrocarbon group having 1 to 20 carbon atoms,
R ^1Z5 is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M, —SO ₃ M or —CO _2. M,
R ^{2Z5 to} R ^5Z5 are each independently a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogen atom, —N (R ^102Z5 ) ₂ , a nitro group, or a hydrogen atom, or a fluorine atom. A substituted hydrocarbon group having 1 to 20 carbon atoms, —NHCO—R ^102Z5 , —O—R ^102Z5 , —SO ₃ M or —CO ₂ M;
At least one of R ^{2Z5 to} R ^5Z5 is a carbon number in which all or part of a hydrocarbon group having 1 to 20 carbon atoms, a halogen atom, —N (R ^102Z5 ) ₂ , a nitro group, or a hydrogen atom is substituted with a fluorine atom. 1 to 20 hydrocarbon groups, —NHCO—R ^102Z5 , —O—R ^102Z5 , —SO ₃ M or —CO ₂ M;
R ^6Z5 and R ^7Z5 each independently represent a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M; SO ₃ M or —CO ₂ M,
R ^102Z5 is a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M;
R ^101Z5 is a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M;
M is preferably a compound that is a hydrogen atom or an alkali metal atom,
R ^N1Z5 has 1 to 10 carbon atoms which may have a substituent selected from the group consisting of —CO—R ^102Z5 , ^—CON (R ^102Z5 ) ₂ , or —SO ₃ M and —CO ₂ M. A hydrocarbon group,
R ^1Z5 is a hydrogen atom,
R ^{2Z5 to} R ^5Z5 are each independently a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, —N (R ^102Z5 ) ₂ , a nitro group, or a hydrogen atom, or a fluorine atom. A substituted hydrocarbon group having 1 to 10 carbon atoms, —NHCO—R ^102Z5 , —O—R ^102Z5 , —SO ₃ M or —CO ₂ M;
At least one of R ^{2Z5 to} R ^5Z5 is a carbon number in which all or part of a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, —N (R ^102Z5 ) ₂ , a nitro group, or a hydrogen atom is substituted with a fluorine atom. 1 to 10 hydrocarbon groups, —NHCO—R ^102Z5 , —O—R ^102Z5 , —SO ₃ M or —CO ₂ M;
R ^6Z5 and R ^7Z5 are the same group, and a hydrocarbon having 1 to 10 carbon atoms which may have a hydrogen atom or a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M Group,
R ^102Z5 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M;
R ^101Z5 is a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M;
M is more preferably a compound that is a hydrogen atom or an alkali metal atom,
R ^N1Z5 has 1 to 10 carbon atoms which may have a substituent selected from the group consisting of —CO—R ^102Z5 , ^—CON (R ^102Z5 ) ₂ , or —SO ₃ M and —CO ₂ M. A hydrocarbon group,
R ^1Z5 is a hydrogen atom,
R ^{2Z5 to} R ^5Z5 are each independently a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, —N (R ^102Z5 ) ₂ , a nitro group, a trifluoromethyl group, —O—R ^102Z5 , a -SO ₃ M or -CO ₂ M,
At least one of R ^{2Z5 to} R ^5Z5 is a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, —N (R ^102Z5 ) ₂ , a nitro group, a trifluoromethyl group, —O—R ^102Z5 , —SO ₃ M. or a -CO ₂ M,
R ^6Z5 and R ^7Z5 are the same group, and are a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms,
R ^102Z5 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M;
R ^101Z5 is a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ M and —CO ₂ M;
A compound in which M is a hydrogen atom or an alkali metal atom is more preferable.

Compound (IZ5) when R ^1Z5 is a hydrogen atom, the compound represented by the formula (pt1Z5) (hereinafter sometimes referred to phthalonitrile compound) a compound represented by the formula (pt2Z5) (hereinafter, referred alkoxide compound The compound represented by the formula (pt3Z5) and the compound represented by the formula (pt4Z5) can be further reacted in the presence of an acid. Also when R ^1Z5 is other than hydrogen atom, can be prepared a compound (IZ5) by further reacting a compound of formula (pt5Z5).

Expression (pt1Z5), formula (pt2Z5), formula (pt3Z5), wherein (pt4Z5) ,, formula (pt5Z5) and formula ^{(IZ5), R N1Z5, R} 1Z5, R 2Z5, R 3Z5, R 4Z5, R 5Z5 , R ^6Z5 , and R ^7Z5 represent the same meaning as described above.
R ^14Z5 represents an alkyl group having 1 to 20 carbon atoms.
M ^1Z5 represents an alkali metal atom.
LG represents a halogen atom, a methanesulfonyloxy group, a toluenesulfonyloxy group, or a trifluoromethanesulfonyloxy group. ]

^Examples of the alkyl group having 1 to 20 carbon atoms represented by R ^14Z5 include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, a sec-butyl group, and a tert-butyl group. Is an alkyl group having 1 to 6 carbon atoms.
^Examples of the alkali metal atom represented by M ^1Z5 include a lithium atom, a sodium atom, and a potassium atom.

  The amount of the alkoxide compound used is usually 0.1 to 10 mol, preferably 0.2 to 5 mol, more preferably 0.3 to 3 mol, relative to 1 mol of the phthalonitrile compound. More preferably, it is 0.4-2 mol.

The amount of compound (pt3Z5) to be used is generally 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, further preferably 1 to 1 mol of phthalonitrile compound. ~ 2 moles.
The amount of compound (pt4Z5) to be used is generally 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, further preferably 1 to 1 mol of phthalonitrile compound. ~ 2 moles.

Examples of the acid include inorganic acids such as hydrochloric acid, hydrobromic acid, hydroiodic acid, sulfuric acid, nitric acid, fluorosulfonic acid and phosphoric acid; sulfonic acids such as methanesulfonic acid, trifluoromethanesulfonic acid and p-toluenesulfonic acid; Examples thereof include carboxylic acids such as acetic acid, citric acid, formic acid, gluconic acid, lactic acid, oxalic acid and tartaric acid, and preferably hydrochloric acid, hydrobromic acid, sulfuric acid, methanesulfonic acid, trifluoromethanesulfonic acid, p-toluenesulfonic acid and A carboxylic acid is mentioned, More preferably, an acetic acid is mentioned.
The usage-amount of an acid is 1-20 mol normally with respect to 1 mol of phthalonitrile compounds, Preferably it is 1-10 mol, More preferably, it is 1-8 mol, More preferably, it is 1-6 mol. is there.

The reaction of a phthalonitrile compound, an alkoxide compound, a compound (pt3Z5) and a compound (pt4Z5) is usually performed in the presence of a solvent.
Solvents include water; nitrile solvents such as acetonitrile; alcohol solvents such as methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol and 1-octanol; ether solvents such as tetrahydrofuran; ketone solvents such as acetone; Ester solvents such as ethyl; aliphatic hydrocarbon solvents such as hexane; aromatic hydrocarbon solvents such as toluene; halogenated hydrocarbon solvents such as methylene chloride and chloroform; amides such as N, N-dimethylformaldehyde and N-methylpyrrolidone Solvent: Sulfoxide solvents such as dimethyl sulfoxide are mentioned, preferably water, nitrile solvent, alcohol solvent, ether solvent, ketone solvent, ester solvent, aromatic hydrocarbon solvent, halogenated hydrocarbon solvent, amide solvent and sulfoxide solvent. And More preferably, water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, tetrahydrofuran, acetone, ethyl acetate, toluene, methylene chloride, chloroform, N, N-dimethylformaldehyde, N -Methylpyrrolidone and dimethyl sulfoxide are mentioned, More preferably, water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, acetone, methylene chloride, chloroform, N, N-dimethyl Examples include formaldehyde, N-methylpyrrolidone and dimethyl sulfoxide, with water, acetonitrile, methanol, ethanol and 2-propanol being particularly preferred.
The usage-amount of a solvent is 1-1000 mass parts normally with respect to 1 mass part of phthalonitrile compounds.

  The reaction temperature is usually 0 to 200 ° C, preferably 0 to 100 ° C, more preferably 0 to 70 ° C, and further preferably 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

The amount of compound (pt5Z5) the compound R ^1Z5 is a hydrogen atom (IZ5) relative to 1 mol, usually 1 to 10 moles, preferably 1 to 5 mol, more preferably 1 to 3 moles More preferably, it is 1-2 mol.

  Moreover, when making a compound (pt5Z5) react, it is preferable that a base coexists. Examples of the base include organic bases such as triethylamine, 4- (N, N-dimethylamino) pyridine, pyridine and piperidine; metal alkoxides such as sodium methoxide, sodium ethoxide, sodium tert-butoxide and potassium tert-butoxide; butyllithium Organic metal compounds such as tert-butyl lithium and phenyl lithium; inorganic bases such as lithium hydroxide, sodium hydroxide and potassium hydroxide.

The amount of the base to be used, the compound R ^1Z5 is a hydrogen atom (IZ5) relative to 1 mol, usually 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 moles, more Preferably it is 1-2 mol.

Moreover, reaction of a compound (pt5Z5) is normally implemented in presence of a solvent. The solvent can be selected from the same range as described above.
The amount of solvent used relative to the compound R ^1Z5 is a hydrogen atom (IZ5) 1 part by weight, it is usually 1 to 1000 parts by weight. The reaction temperature of the compound (pt5Z5) is usually -90 to 200 ° C, preferably -80 to 100 ° C, more preferably 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

When the compound (IZ5) does not have a sulfo group or —SO ₃ M ²² , the compound (IZ5) is reacted with a sulfonating agent such as fuming sulfuric acid or chlorosulfonic acid to thereby form a sulfo group or —SO ₃ M ^22. Can be introduced.
M ²² represents an alkali metal atom.
Examples of the alkali metal atom represented by M ²² include a lithium atom, a sodium atom, and a potassium atom.

The amount of SO ₃ in the oleum, the compound (IZ5) relative to 1 mol, usually 1 to 50 moles, preferably from 5 to 40 moles, more preferably from 5 to 30 moles, more preferably 5 to 25 mol.
The usage-amount of the sulfuric acid in fuming sulfuric acid is 1-200 mol normally with respect to 1 mol of compounds (IZ5), Preferably it is 10-100 mol, More preferably, it is 10-75 mol, More preferably, it is 10 ~ 50 moles.

  The amount of chlorosulfonic acid to be used is generally 1 to 500 mol, preferably 10 to 300 mol, more preferably 10 to 200 mol, further preferably 10 to 150 mol, per 1 mol of compound (IZ5). Is a mole.

  The reaction temperature of the sulfonation is usually from -20 to 200 ° C, preferably from -10 to 100 ° C, more preferably from 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

  The method for taking out the compound (IZ5) from the reaction mixture is not particularly limited, and it can be taken out by various known methods. For example, after completion of the reaction, the compound (IZ5) can be removed by filtering the reaction mixture. Further, after filtration, the obtained residue may be subjected to column chromatography or recrystallization. Further, after completion of the reaction, the solvent of the reaction mixture may be distilled off and then purified by column chromatography.

<Compound (IZ6)>
Compound (IZ6) is represented by formula (IZ6).

[In the formula (IZ6), D represents a structure having an isoindoline skeleton. Z represents —SO ₃ ^— or —CO ₂ ^— . A ^{c +} represents a c-valent metal cation. a represents an integer of 1 to 10. b represents an integer of 1 or more. c represents an integer of 2 to 10. d represents an integer of 1 or more.
When there are a plurality of D, Z, a, or A ^{c +} , they may be the same or different.
Formula (I′Z6) and Formula (I ″ Z6) each represent a partial structure of Formula (IZ6), and D, Z, A ^{c +} , a, b, c, and d are those in Formula (IZ6) Represents the same thing.
However, the absolute value of the negative valence of the partial structure represented by the formula (I′Z6) and the positive valence of the partial structure represented by the formula (I ″ Z6) are the same. ]

  The integer represented by a is 1 to 10, preferably 1 to 8, more preferably 1 to 6, and further preferably 1 to 4.

  The integer represented by b is 1 or more, preferably 1 to 10, more preferably 1 to 8.

  The integer represented by c is 2 to 10, preferably 2 to 8, more preferably 2 to 6, and further preferably 2 to 4.

  The integer represented by d is 1 or more, preferably 1 to 10, more preferably 1 to 8.

Z is preferably —CO ₂ ^— .

A ^{c +} represents a metal cation having a valence of 2 or more.
As a metal cation more than bivalent,
Examples include cations of metals of Groups 2 to 15 of the periodic table of elements, preferably Mg ²⁺ , Ca ²⁺ , Sr ²⁺ , Ba ²⁺ , Cd ²⁺ , Ni ²⁺ , Zn ²⁺ , Divalent metal cations such as Cu ²⁺ , Hg ²⁺ , Fe ²⁺ , Co ²⁺ , Sn ²⁺ , Pb ²⁺ and Mn ²⁺ ;
Trivalent metal cations such as Al ³⁺ , Fe ³⁺ and Cr ³⁺ ;
And tetravalent metal cations such as Sn ⁴⁺ and Mn ⁴⁺ , more preferably Mg ²⁺ , Ca ²⁺ , Sr ²⁺ , Ba ²⁺ , Ni ²⁺ , Zn ²⁺ , Cu ²⁺ , Fe ²⁺ , Co ²⁺ , Sn ²⁺ , Mn ²⁺ , Al ³⁺ , Fe ³⁺ , Cr ³⁺ , Sn ⁴⁺ and Mn ⁴⁺ , more preferably Mg ²⁺ , Ca ²⁺ , Sr ²⁺ , Ba ²⁺ , Zn ²⁺ , Cu ²⁺ , Fe ²⁺ , Mn ²⁺ , Al ³⁺ , Fe ³⁺ , Cr ³⁺ and Mn ⁴⁺ .

  The compound represented by formula (IZ6) is preferably a compound represented by formula (IZ6-A) (hereinafter sometimes referred to as compound (IZ6-A)).

[In the formula (IZ6-A)
A ^{c +} , b, c and d represent the same meaning as described above.
R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 and R ^13AZ6 are independently of each other a hydrogen atom, —CO—R ^102AZ6 , —COO—R ^101AZ6 , —OCO— ^{R 102AZ6, -COCO-R 102AZ6,} -O-R 102AZ6, -SO 2 -R 101AZ6, -SO 2 N (R 102AZ6) 2, -CON (R 102AZ6) 2, -N (R 102AZ6) 2, -NHCO ^{-R 102AZ6, -NHCO-N (R} 102AZ6) 2, -NHCOOR 102AZ6, -OCON (R 102AZ6) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , -SO 3 -, —CO ₂ ⁻ represents an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group.
R ^2AZ6 and R ^3AZ6 , R ^3AZ6 and R ^4AZ6 , R ^4AZ6 and R ^5AZ6 , R ^AA1Z6 and R ^AA2Z6, and R ^12AZ6 and R ^13AZ6 may be bonded to each other to form a ring.
R ^101AZ6 represents, independently of each other, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102AZ6 represents, independently of each other, a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
M represents a hydrogen atom or an alkali metal atom.
Formula (IZ6-A ′) and Formula (IZ6-A ″) each represent a partial structure of Formula (IZ6-A), and A ^{c +} , b, c, d, R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 and R ^13AZ6 represent the same as those in formula (IZ6-A).
R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 , R ^102AZ6 , M, c or A ^{c +} May be different or different.
R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6 are at least one of (ra-i) to (ra-iii) R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6 have —SO ₃ ^— or —CO ₂ ^— The total number is a.
( ^Ra -i) At least one of R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 and R ^13AZ6 is —SO ₃ ^— or —CO ₂ ^— .
( ^Ra -ii) At least one of R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 and R ^13AZ6 is -CO-R ^102AZ6 , -COO-R ^101AZ6 , -OCO ^{-R 102AZ6, -COCO-R 102AZ6,} -O-R 102AZ6, -SO 2 -R 101AZ6, -SO 2 N (R 102AZ6) 2, -CON (R 102AZ6) 2, -N (R 102AZ6) 2, - NHCO—R ^102AZ6 _, —NHCO—N (R ^102AZ6 ) ₂ , —NHCOOR ^102AZ6 , or —OCON (R ^102AZ6 ) ₂ , wherein R ^101AZ6 and R ^102AZ6 have —SO ₃ ^— or —CO ₂ ^— . A hydrocarbon group having 1 to 40 carbon atoms or a heterocyclic group having —SO ₃ ^— or —CO ₂ ^— . However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .
( ^Ra -iii) Carbon number 1 in which at least one of R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 and R ^13AZ6 has —SO ₃ ^— or —CO ₂ ^—. It is a heterocyclic group having ˜40 hydrocarbon groups or —SO ₃ ^— or —CO ₂ ^— . However, the hydrocarbon group and the heterocyclic group may have a substituent other than —SO ₃ ^— or —CO ₂ ^— .
a represents the same meaning as in formula (IZ6). When a plurality of a are present, they may be the same or different.
The absolute value of the negative valence of the partial structure represented by the formula (IZ6-A ′) and the positive valence of the partial structure represented by the formula (IZ6-A ″) are the same.
A wavy line represents an E body or a Z body. ]

The hydrocarbon group represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6 has 1 to 40 carbon atoms, Preferably it is 1-30, More preferably, it is 1-20, More preferably, it is 1-15, Most preferably, it is 1-10.

The hydrocarbon group having 1 to 40 carbon atoms represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6 is aliphatic carbonized. It may be a hydrogen group or an aromatic hydrocarbon group, and the aliphatic hydrocarbon group may be saturated or unsaturated, and may be a chain or an alicyclic ring.

The saturated or unsaturated chain hydrocarbon group represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6 is a methyl group Linear alkyl groups such as ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, heptadecyl, octadecyl and icosyl Isopropyl group, isobutyl group, sec-butyl group, tert-butyl group, (2-ethyl) butyl group, isopentyl group, neopentyl group, tert-pentyl group, (1-methyl) pentyl group, (2-methyl) pentyl Group, (1-ethyl) pentyl group, (3-ethyl) pentyl group, isohexyl group, (5-methyl) hexyl group, (2-ethyl) hexyl group and ( -Ethyl) branched chain alkyl group such as heptyl group, etc .; vinyl group, 1-propenyl group, 2-propenyl group (allyl group), (1-methyl) ethenyl group, 2-butenyl group, 3-butenyl group, Alkenyl groups such as 1,3-butadienyl group, (1- (2-propenyl)) ethenyl group, (1,2-dimethyl) propenyl group and 2-pentenyl group; and the like. Carbon number of a saturated or unsaturated chain hydrocarbon group becomes like this. Preferably it is 1-30, More preferably, it is 1-20, More preferably, it is 1-15. Especially, it is especially preferable that it is a C1-C10, More preferably, it is a C1-C8, More preferably, it is a C1-C5 linear or branched alkyl group.

The saturated or unsaturated alicyclic hydrocarbon group represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6 is cyclo Propyl group, 1-methylcyclopropyl group, cyclobutyl group, cyclopentyl group, cyclohexyl group, cycloheptyl group, 1-methylcyclohexyl group, 2-methylcyclohexyl group, 3-methylcyclohexyl group, 4-methylcyclohexyl group, 1,2 -Dimethylcyclohexyl group, 1,3-dimethylcyclohexyl group, 1,4-dimethylcyclohexyl group, 2,3-dimethylcyclohexyl group, 2,4-dimethylcyclohexyl group, 2,5-dimethylcyclohexyl group, 2,6-dimethyl Cyclohexyl, 3,4-dimethylcyclohexyl, 3,5-dimethylcyclohexyl Sil group, 2,2-dimethylcyclohexyl group, 3,3-dimethylcyclohexyl group, 4,4-dimethylcyclohexyl group, cyclooctyl group, 2,4,6-trimethylcyclohexyl group, 2,2,6,6-tetra Cycloalkyl groups such as methylcyclohexyl group and 3,3,5,5-tetramethylcyclohexyl group, 4-pentylcyclohexyl group, 4-octylcyclohexyl group, 4-cyclohexylcyclohexyl group; cyclohexenyl group (for example, cyclohex-2-ene) Cyclohex-3-ene), cycloalkenyl groups such as cycloheptenyl group and cyclooctenyl group; norbornane group, adamantyl group, bicyclo [2.2.2] octane and the like. The carbon number of the saturated or unsaturated alicyclic hydrocarbon group is preferably 3 to 30, more preferably 3 to 20, still more preferably 4 to 20, and still more preferably 4 to 15. More preferably 5 to 15 and most preferably 5 to 10. Of these, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, and a cyclooctyl group are particularly preferable.

The aromatic hydrocarbon group represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6 includes a phenyl group and o-tolyl. Group, m-tolyl group, p-tolyl group, 2-ethylphenyl group, 3-ethylphenyl group, 4-ethylphenyl group, 2,3-dimethylphenyl group, 2,4-dimethylphenyl group, 2,5- Dimethylphenyl group, 2,6-dimethylphenyl group, 3,4-dimethylphenyl group, 3,5-dimethylphenyl group, 4-vinylphenyl group, o-isopropylphenyl group, m-isopropylphenyl group, p-isopropylphenyl Group, o-tert-butylphenyl group, m-tert-butylphenyl group, p-tert-butylphenyl group, mesityl group, 4-ethylphenyl group, 4-butylphenol Group, 4-pentylphenyl group, 2,6-bis (2-propyl) phenyl group, 4-cyclohexylphenyl group, 2,4,6-trimethylphenyl group, 4-octylphenyl group, 1-naphthyl group, 2 -Aromatic carbonization such as naphthyl group, 5,6,7,8-tetrahydro-1-naphthyl group, 5,6,7,8-tetrahydro-2-naphthyl group, fluorenyl group, phenanthryl group and anthryl group, pyrenyl group A hydrogen group; and the like. The number of carbon atoms of the aromatic hydrocarbon group is preferably 6-30, more preferably 6-20, and even more preferably 6-15.

The hydrocarbon groups represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6 are the hydrocarbon groups listed above (for example, A combination of an aromatic hydrocarbon group and at least one of a chain hydrocarbon group and an alicyclic hydrocarbon group), such as a benzyl group, a phenethyl group, and a 1-methyl-1-phenylethyl group. An arylalkenyl group such as a phenylethenyl group (phenylvinyl group); an arylalkynyl group such as a phenylethynyl group; a phenyl group to which one or more phenyl groups such as a biphenylyl group and a terphenylyl group are bonded; cyclohexylmethylphenyl Group, benzylphenyl group, (dimethyl (phenyl) methyl) phenyl group and the like.
The ^{groups represented} by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6 are the hydrocarbon groups listed above (for example, chain-like) As a group combining a hydrocarbon group and an alicyclic hydrocarbon group), for example, a cyclopropylmethyl group, a cyclopropylethyl group, a cyclobutylmethyl group, a cyclobutylethyl group, a cyclopentylmethyl group, a cyclopentylethyl group, a cyclohexylmethyl group , An alkyl group to which one or more alicyclic hydrocarbon groups such as 2-methylcyclohexylmethyl group, cyclohexylethyl group, adamantylmethyl group and the like are bonded may be used.
These carbon numbers are preferably 4-30, more preferably 6-30, still more preferably 6-20, and preferably 4-20, more preferably 4-15. Especially preferably, it is 6-15.

The hydrocarbon group represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6 may have a substituent. . The substituent may be monovalent or divalent. In the divalent substituent, two bonds are preferably bonded to the same carbon atom to form a double bond.
As the monovalent substituent,
Methoxy group, ethoxy group, propoxy group, isopropoxy group, butoxy group, isobutoxy group, sec-butoxy group, tert-butoxy group, pentyloxy group, hexyloxy group, (2-ethyl) hexyloxy group, heptyloxy group, Octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, dodecyloxy group, (2-ethyl) hexyloxy group, icosyloxy group, 1-phenylethoxy group, 1-methyl-1-phenylethoxy group, phenyloxy group O-Tolyloxy group, 2,3-dimethylphenyloxy group, 2,4-dimethylphenyloxy group, 2,5-dimethylphenyloxy group, 2,6-dimethylphenyloxy group, 3,4-dimethylphenyloxy group 3,5-dimethylphenyloxy group, 2,2-dicia Phenyloxy group, 2,3-dicyanophenyloxy group, 2,4-dicyanophenyloxy group, 2,5-dicyanophenyloxy group, 2,6-dicyanophenyloxy group, 3,4-dicyanophenyloxy group, 3 , 5-dicyanophenyloxy group, 4-methoxyphenyloxy group, 2-methoxyphenyloxy group, 3-methoxyphenyloxy group, 4-ethoxyphenyloxy group, 2-ethoxyphenyloxy group, 3-ethoxyphenyloxy group, etc. And a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group represented by the following formula or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen) (Preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl) Oxy group derivatized group) is bonded to one side the like);

  Methylthio, ethylthio, propylthio, butylthio, tert-butylthio, pentylthio, hexylthio, (2-ethyl) hexylthio, heptylthio, octylthio, nonylthio, decylthio, undecylthio, dodecylthio, icosylthio A sulfanyl group to which a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group, a phenylthio group and an o-tolylthio group is bonded;

Epoxy group, oxetanyl group, tetrahydrofuryl group, tetrahydropyranyl group;
Formyl group;
Acetyl group, propanoyl group, butanoyl group, 2,2-dimethylpropanoyl group, pentanoyl group, hexanoyl group, (2-ethyl) hexanoyl group, heptanoyl group, octanoyl group, nonanoyl group, decanoyl group, undecanoyl group, dodecanoyl group, A hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 11 carbon atoms) or a derivatized group thereof (for example, a carboxy group or a sulfo group) such as a henicosanoyl group, a benzoyl group, or a group represented by the following formula: , A carbonyl group to which a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), a group derived from an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. When the carbonyl group is an alkanoyl group, the carbon number is preferably 2 to 12);

  Methoxycarbonyl group, ethoxycarbonyl group, propoxycarbonyl group, butoxycarbonyl group, tert-butoxycarbonyl group, pentyloxycarbonyl group, hexyloxycarbonyl group, (2-ethyl) hexyloxycarbonyl group, heptyloxycarbonyl group, octyloxycarbonyl Group, nonyloxycarbonyl group, decyloxycarbonyl group, undecyloxycarbonyl group, dodecyloxycarbonyl group, icosyloxycarbonyl group, phenyloxycarbonyl group, o-tolyloxycarbonyl group and the like, and the following formulas A hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a group or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon number 10 oxycarbonyl group alkylsulfamoyl group (preferably octyl sulfamoyl group) were derivatized with such groups) is bonded to;

An amino group;
N-methylamino group, N, N-dimethylamino group, N-ethylamino group, N, N-diethylamino group, N-propylamino group, N, N-dipropylamino group, N-isopropylamino group, N, N-diisopropylamino group, N-butylamino group, N, N-dibutylamino group, N-isobutylamino group, N, N-diisobutylamino group, N-sec-butylamino group, N, N-disec-butyl Amino group, N-tert-butylamino group, N, N-ditert-butylamino group, N-pentylamino group, N, N-dipentylamino group, N- (1-ethylpropyl) amino group, N, N -Di (1-ethylpropyl) amino group, N-hexylamino group, N, N-dihexylamino group, N- (2-ethyl) hexylamino group, N, N-di (2-ethyl) Xylamino group, N-heptylamino group, N, N-diheptylamino group, N-octylamino group, N, N-dioctylamino group, N-nonylamino group, N, N-dinonylamino group, N-phenylamino group, N, N-diphenylamino group, N, N-ethylmethylamino group, N, N-propylmethylamino group, N, N-isopropylmethylamino group, N, N-butylmethylamino group, N-decylamino group, N , N-decylmethylamino group, N-undecylamino group, N, N-undecylmethylamino group, N-dodecylamino group, N, N-dodecylmethylamino group, N-icosylamino group, N, N-ico One of a silmethylamino group, an N, N-tert-butylmethylamino group, an N, N-phenylmethylamino group, and a group represented by the following formula: Two hydrocarbon groups having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) or derivatized groups thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), 1 carbon atom An amino group substituted with 10 to 10 alkylsulfamoyl groups (preferably a group derivatized with an octylsulfamoyl group or the like);

A sulfamoyl group;
N-methylsulfamoyl group, N, N-dimethylsulfamoyl group, N-ethylsulfamoyl group, N, N-diethylsulfamoyl group, N-propylsulfamoyl group, N, N-dipropyls Rufamoyl group, N-isopropylsulfamoyl group, N, N-diisopropylsulfamoyl group, N-butylsulfamoyl group, N, N-dibutylsulfamoyl group, N-isobutylsulfamoyl group, N, N-diisobutylsulfamoyl group, N-sec-butylsulfamoyl group, N, N-disec-butylsulfamoyl group, N-tert-butylsulfamoyl group, N, N-ditert-butylsulfur Famoyl group, N-pentylsulfamoyl group, N, N-dipentylsulfamoyl group, N- (1-ethylpropyl) sulfamoyl group, , N-di (1-ethylpropyl) sulfamoyl group, N-hexylsulfamoyl group, N, N-dihexylsulfamoyl group, N- (2-ethyl) hexylsulfamoyl group, N, N-di ( 2-ethyl) hexylsulfamoyl group, N-heptylsulfamoyl group, N, N-diheptylsulfamoyl group, N-octylsulfamoyl group, N, N-dioctylsulfamoyl group, N, N -Octylmethylsulfamoyl group, N-nonylsulfamoyl group, N, N-dinonylsulfamoyl group, N-phenylsulfamoyl group, N, N-diphenylsulfamoyl group, N, N-ethylmethyl Sulfamoyl group, N, N-propylmethylsulfamoyl group, N, N-isopropylmethylsulfamoyl group, N, N-butylmethylsulfamoyl group N-decylsulfamoyl group, N, N-decylmethylsulfamoyl group, N-undecylsulfamoyl group, N, N-undecylmethylsulfamoyl group, N-dodecylsulfamoyl group, N, N-dodecylmethylsulfamoyl group, N-icosylsulfamoyl group, N, N-icosylmethylsulfamoyl group, N, N-tert-butylmethylsulfamoyl group, N, N-phenylmethylsulfa 1 or 2 hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as a moyl group and the group represented by the following formula or a derivatized group thereof (for example, carboxy group, sulfo group) , A nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. A sulfamoyl group substituted with

  Formylamino group; acetylamino group, propanoylamino group, butanoylamino group, 2,2-dimethylpropanoylamino group, pentanoylamino group, hexanoylamino group, (2-ethyl) hexanoylamino group, heptanoyl Amino group, octanoylamino group, nonanoylamino group, decanoylamino group, undecanoylamino group, dodecanoylamino group, heicosanoylamino group, benzoylamino group, etc., and groups represented by the following formulae Or a hydrocarbon group having 1 to 20 carbon atoms (preferably 1 to 12 carbon atoms) or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon number 1 10 to 10 alkylsulfamoyl groups (preferably octylsulfamoyl groups) and the like) Carbonyl amino group (if the alkanoylamino group the carbonyl group, the carbon number is preferably 1 to 12);

A hydroxy group;
Halogen atoms such as fluorine atom, chlorine atom, bromine atom and iodine atom;
Carboxy group, —CO ₂ M ² (M ² is alkali metal, preferably lithium, sodium, potassium); sulfo group, —SO ₃ M ² (M ² is alkali metal, preferably lithium, sodium, potassium); Nitro group A cyano group;

  Formyloxy group; acetoxy group, propanoyloxy group, butanoyloxy group, 2,2-dimethylpropanoyloxy group, pentanoyloxy group, hexanoyloxy group, (2-ethyl) hexanoyloxy group, heptanoyloxy Carbon such as a group, octanoyloxy group, nonanoyloxy group, decanoyloxy group, undecanoyloxy group, dodecanoyloxy group, heicosanoyloxy group, benzoyloxy group, and the group represented by the following formula A hydrocarbon group having 1 to 20 (preferably 1 to 10 carbons) or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), A group to which an alkyl sulfamoyl group (preferably a group derivatized with an octyl sulfamoyl group) is bound. Boniruokishi group (if the alkanoyloxy group and the carbonyl group, the carbon number is preferably 1 to 10);

  Methylsulfonyl group, ethylsulfonyl group, propylsulfonyl group, butylsulfonyl group, pentylsulfonyl group, hexylsulfonyl group, (2-ethyl) hexylsulfonyl group, heptylsulfonyl group, octylsulfonyl group, nonylsulfonyl group, decylsulfonyl group, un Decylsulfonyl group, dodecylsulfonyl group, icosylsulfonyl group, phenylsulfonyl group, p-tolylsulfonyl group and the like, and groups having 1 to 20 carbon atoms (preferably having 1 to 10 carbon atoms) such as groups represented by the following formulae: Hydrocarbon group or derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group) A group derivatized with a sulfonyl group) ;

A carbamoyl group;
N-methylcarbamoyl group, N, N-dimethylcarbamoyl group, N-ethylcarbamoyl group, N, N-diethylcarbamoyl group, N-propylcarbamoyl group, N, N-dipropylcarbamoyl group, N-isopropylcarbamoyl group, N , N-diisopropylcarbamoyl group, N-butylcarbamoyl group, N, N-dibutylcarbamoyl group, N-isobutylcarbamoyl group, N, N-diisobutylcarbamoyl group, N-sec-butylcarbamoyl group, N, N-disec- Butylcarbamoyl group, N-tert-butylcarbamoyl group, N, N-ditert-butylcarbamoyl group, N-pentylcarbamoyl group, N, N-dipentylcarbamoyl group, N- (1-ethylpropyl) carbamoyl group, N, N-di (1-ethylpropyl) carba Yl group, N-hexylcarbamoyl group, N, N-dihexylcarbamoyl group, N- (2-ethyl) hexylcarbamoyl group, N, N-di (2-ethyl) hexylcarbamoyl group, N-heptylcarbamoyl group, N, N-diheptylcarbamoyl group, N-octylcarbamoyl group, N, N-dioctylcarbamoyl group, N-nonylcarbamoyl group, N, N-octylmethylcarbamoyl group, N, N-octylbutylcarbamoyl group, N, N-di Nonylcarbamoyl group, N-phenylcarbamoyl group, N, N-diphenylcarbamoyl group, N, N-ethylmethylcarbamoyl group, N, N-propylmethylcarbamoyl group, N, N-isopropylmethylcarbamoyl group, N, N-butyl Methylcarbamoyl group, N-decylcarbamoyl group, N, N Decylmethylcarbamoyl group, N-undecylcarbamoyl group, N, N-undecylmethylcarbamoyl group, N-dodecylcarbamoyl group, N, N-dodecylmethylcarbamoyl group, N-icosylcarbamoyl group, N, N-icosyl 1 or 2 carbon atoms (preferably carbon atoms) such as a methylcarbamoyl group, an N, N-tert-butylmethylcarbamoyl group, an N, N-phenylmethylcarbamoyl group, and a group represented by the following formula A hydrocarbon group having 1 to 10) or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably A carbamoyl group substituted with a group derivatized with an octylsulfamoyl group) or the like;

Trifluoromethyl group, perfluoroethyl group, perfluoropropyl group, perfluoroisopropyl group, perfluorobutyl group, perfluoropentyl group, perfluorohexyl group, perfluoroheptyl group, perfluorooctyl group, perfluorononyl group, A carbon atom having 1 to 20 carbon atoms in which all hydrogen atoms such as perfluorodecyl group, perfluoroundecyl group, perfluorododecyl group, perfluoroicosyl group, perfluorocyclohexyl group and perfluorophenyl group are substituted with fluorine atoms. A hydrogen group;
Perfluoroethylmethyl group, perfluoropropylmethyl group, perfluoroisopropylmethyl group, perfluorobutylmethyl group, perfluoropentylmethyl group, perfluorohexylmethyl group, perfluoroheptylmethyl group, perfluorooctylmethyl group, perfluoro A straight chain having 1 to 20 carbon atoms in which all hydrogen atoms such as nonylmethyl group, perfluorodecylmethyl group, perfluoroundecylmethyl group, perfluorododecylmethyl group and perfluoroicosylmethyl group are substituted with fluorine atoms Or a hydrocarbon group having 1 to 20 carbon atoms substituted by a branched alkyl group;

  1 to 20 carbon atoms (preferably carbon atoms) in which part of hydrogen atoms such as 2-fluorophenyl group, 3-fluorophenyl group, 4-fluorophenyl group and 2,4,6-trifluorophenyl group are substituted with fluorine. 1-10) hydrocarbon radicals;

-CO-SH, -CO-S- CH 3, -CO-S-CH 2 CH 3, -CO-S-CH 2 -CH 2 -CH 3 and _{-CO-S-CH 2 -CH 2} -CH 2 An alkylthiocarbonyl group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms) such as —CH ₃ ; and an arylthiocarbonyl group having 6 to 20 carbon atoms such as —CO—S—C ₆ H ₅ ;

  * -COCO-R as represented by the following formula (wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, satisfying 1 to 20 carbon atoms among the hydrocarbon groups mentioned above) Or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably octyl sulfamoyl group) A group derived from, etc.)

* -NRCONR ₂ represented by the following formula (wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, those satisfying 1 to 20 carbon atoms among the hydrocarbon groups mentioned above) ) Or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group), etc. And the R may be the same or different from each other and may be bonded to each other to form a ring);

* -OCONR ₂ represented by the following formula (wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, those satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above) ) Or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkylsulfamoyl group having 1 to 10 carbon atoms (preferably octylsulfamoyl group), etc. And the R may be the same or different from each other and may be bonded to each other to form a ring);

  * -NRCOOR as represented by the following formula (wherein R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, those satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above)) Or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. A derivatized group), wherein the Rs may be the same or different from each other and may be bonded to each other to form a ring;

_{* -OP (O) (OCH 3} ) in such _{2 * -OP (O) (OR} ) 2 ( wherein, R represents a hydrogen atom, a hydrocarbon group (e.g., hydrocarbon groups mentioned above having 1 to 20 carbon atoms Or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms) A group derived from (preferably an octylsulfamoyl group) or the like, and the Rs may be the same or different from each other, and may be bonded to each other to form a ring;
* -SiR ₃ (* -Si (CH ₃ ) ₃ , * -Si (CH ₂ CH ₃ ) ₃ , * -Si (C ₆ H ₅ ) ₃ and * -Si (CH (CH ₃ ) ₂ ) ₃ In the formula, R is a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms (for example, those satisfying 1 to 20 carbon atoms among the hydrocarbon groups listed above), or a derivatizing group thereof (for example, a carboxy group, sulfo group). A group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), a C1-C10 alkylsulfamoyl group (preferably an octylsulfamoyl group) and the like, and the R is Groups that may be the same or different from each other and may be bonded to each other to form a ring);

-SO ₃ ^-; -CO ₂ ^-; and the like.

As the divalent substituent, an oxo group, a thioxo group, an imino group, an imino group substituted with an alkyl group having 1 to 20 carbon atoms (preferably 1 to 10 carbon atoms), and an aryl group having 6 to 20 carbon atoms are substituted. And imino groups. Examples of the imino group substituted with an alkyl group include CH ₃ —N═, CH ₃ —CH ₂ —N═, CH ₃ — (CH ₂ ) ₂ —N═, and CH ₃ — (CH ₂ ) ₃ —N =. Can be mentioned. Examples of the imino group substituted with an aryl group include C ₆ H ₅ —N═.

The substituent of the hydrocarbon group having 1 to 40 carbon atoms is preferably a substituent of group s1. The derivatizing groups shown below are a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), and the like. A derivatized group is preferred.
[Group s1]
An oxy group having a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof bonded to one side;
A carbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
An oxycarbonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
An amino group;
An amino group substituted by one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
A sulfamoyl group;
A sulfamoyl group substituted with one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
A carbonylamino group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
A hydroxy group;
A halogen atom;
-CO ₂ M (preferably a carboxy group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom.);
-SO ₃ M (preferably a sulfo group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom.);
A nitro group;
A cyano group;
A carbonyloxy group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
A sulfonyl group to which a hydrocarbon group having 1 to 20 carbon atoms or a derivatizing group thereof is bonded;
A carbamoyl group;
A carbamoyl group substituted with one or two hydrocarbon groups having 1 to 20 carbon atoms or a derivatizing group thereof;
A hydrocarbon group having 1 to 20 carbon atoms in which all of the hydrogen atoms are substituted by fluorine atoms;
A hydrocarbon group having 1 to 20 carbon atoms substituted with a linear or branched alkyl group having 1 to 20 carbon atoms in which all of the hydrogen atoms are substituted with fluorine atoms;
A hydrocarbon group having 1 to 20 carbon atoms in which a part of hydrogen atoms is substituted by fluorine;
An oxo group;
—SO ₃ ⁻ ;
-CO ₂ ^-

The substituent of the hydrocarbon group having 1 to 40 carbon atoms is more preferably a substituent of group s2.
[Group s2]
An oxy group having a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof bonded to one side;
A carbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
An oxycarbonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
An amino group;
An amino group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof;
A sulfamoyl group;
A sulfamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof;
A carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
A hydroxy group;
Fluorine atom, chlorine atom, bromine atom;
-CO ₂ M (preferably a carboxy group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom.);
-SO ₃ M (preferably a sulfo group) (M represents a hydrogen atom or an alkali metal atom, preferably a hydrogen atom.);
A nitro group;
A cyano group;
A carbonyloxy group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
A sulfonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded;
A carbamoyl group;
A carbamoyl group substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or a derivatizing group thereof;
A hydrocarbon group having 1 to 10 carbon atoms in which all of the hydrogen atoms are substituted by fluorine atoms;
A hydrocarbon group having 1 to 10 carbon atoms substituted by a linear or branched alkyl group having 1 to 10 carbon atoms in which all of the hydrogen atoms are substituted with fluorine atoms;
A hydrocarbon group having 1 to 10 carbon atoms in which a part of hydrogen atoms is substituted by fluorine;
An oxo group;
—SO ₃ ⁻ ;
-CO ₂ ^-

As a hydrocarbon group having 1 to 40 carbon atoms having a substituent represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6 Includes a C1-C40 hydrocarbon group having a monovalent or divalent substituent; preferably, a C1-C30 saturated or unsaturated chain having a monovalent or divalent substituent Hydrocarbon group, C3-C30 saturated or unsaturated alicyclic hydrocarbon group having a monovalent or divalent substituent, C6-C30 aromatic carbonization having a monovalent or divalent substituent A group obtained by combining a hydrogen group or a hydrocarbon group, and a group having 4 to 30 carbon atoms having a monovalent or divalent substituent;
More preferably, a saturated or unsaturated chain hydrocarbon group having 1 to 20 carbon atoms having a substituent of group s1, or a saturated or unsaturated alicyclic hydrocarbon group having 3 to 20 carbon atoms having a substituent of group s1. A group having 6 to 20 carbon atoms having a substituent of group s1 or a combination of hydrocarbon groups, and a group having 4 to 20 carbon atoms having a substituent of group s1;
Particularly preferably, it is a saturated or unsaturated chain hydrocarbon group having 1 to 15 carbon atoms having a substituent of group s2, or a saturated or unsaturated alicyclic hydrocarbon group having 3 to 15 carbon atoms having a substituent of group s2. , A group having 6 to 15 carbon atoms having a substituent of group s2 or a combination of hydrocarbon groups, and a group having 4 to 15 carbon atoms having a substituent of group s2.

The heterocyclic group represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6 may be a single ring. The ring may be polycyclic, and is preferably a heterocyclic ring containing a hetero atom as a ring component. Examples of the hetero atom include a nitrogen atom, an oxygen atom, and a sulfur atom.
The number of carbon atoms of the heterocyclic group is preferably 3-30, more preferably 3-22, still more preferably 3-20, still more preferably 3-18, and even more preferably 3-3. 15 and particularly preferably 3-14.

As a heterocyclic ring containing a nitrogen atom,
Monocyclic saturated heterocycles such as aziridine, azetidine, pyrrolidine, piperidine and piperazine;
Pyrrol such as 2,5-dimethylpyrrole, pyrazole such as 2-methylpyrazole and 3-methylpyrazole, 5-membered unsaturated heterocyclic ring such as imidazole, 1,2,3-triazole and 1,2,4-triazole ;
6-membered unsaturated heterocycles such as pyrimidines such as pyridine, pyridazine, 6-methylpyrimidine, pyrazines and 1,3,5-triazines;
Indazole, indoline, isoindoline, indole, indolizine, benzimidazole, quinoline, isoquinoline, quinoxaline such as 5,6,7,8-tetrahydro (3-methyl) quinoxaline, 3-methylquinoxaline, quinazoline, cinnoline, phthalazine, naphthyridine , Condensed bicyclic heterocycles such as purine, pteridine, benzopyrazole, benzopiperidine;
And condensed tricyclic heterocycles such as carbazole, acridine and phenazine.

As a heterocyclic ring containing an oxygen atom,
Monocyclic saturated heterocycles such as oxirane, oxetane, tetrahydrofuran, tetrahydropyran, 1,3-dioxane and 1,4-dioxane, 1-cyclopentyldioxolane;
Bicyclic saturated heterocycles such as 1,4-dioxaspiro [4.5] decane, 1,4-dioxaspiro [4.5] nonane;
Lactone heterocycles such as α-acetolactone, β-propiolactone, γ-butyrolactone, γ-valerolactone and δ-valerolactone;
5-membered unsaturated heterocyclic rings such as furan such as 2,3-dimethylfuran and 2,5-dimethylfuran;
6-membered unsaturated heterocyclic rings such as 2H-pyran and 4H-pyran;
Fused bicyclic heterocycles such as 1-benzofuran, benzopyran such as 4-methylbenzopyran, benzodioxole, chroman and isochroman;
And condensed tricyclic heterocycles such as xanthene and dibenzofuran;

As a heterocyclic ring containing a sulfur atom,
5-membered saturated heterocyclic ring such as dithiolane;
6-membered saturated heterocyclic rings such as thiane, 1,3-dithiane, 2-methyl-1,3-dithiane;
5-membered unsaturated heterocyclic rings such as thiophene such as 3-methylthiophene and 2-carboxythiophene, benzothiopyran such as 4H-thiopyran and benzotetrahydrothiopyran;
Condensed bicyclic heterocycles such as benzothiophene;
And condensed tricyclic heterocycles such as thianthrene and dibenzothiophene.

As a heterocyclic ring containing a nitrogen atom and an oxygen atom,
Monocyclic saturated heterocycles such as morpholine, 2-pyrrolidone, 2-methyl-2-pyrrolidone, 2-piperidone and 2-methyl-2-piperidone;
Monocyclic unsaturated heterocycles such as oxazole such as 4-methyloxazole, isoxazole such as 2-methylisoxazole and 3-methylisoxazole;
Condensed bicyclic heterocycles such as benzoxazole, benzisoxazole, benzoxazine, benzodioxane, benzimidazoline;
And condensed tricyclic heterocycles such as phenoxazine.

As a heterocyclic ring containing a nitrogen atom and a sulfur atom,
Monocyclic heterocycles such as thiazole such as 3-methylthiazole and 2,4-dimethylthiazole;
Fused bicyclic heterocycles such as benzothiazole;
Condensed tricyclic heterocycles such as phenothiazine; and the like.

  The heterocycle may be a group in which the above-described hydrocarbon groups are combined, and examples thereof include a tetrahydrofurylmethyl group.

Furthermore, the heterocyclic ring may be represented by the following formula.

The heterocyclic group may be a heterocyclic group formed by combining two or more of R ^{1AZ6 to} R ^5AZ6 . Such a heterocyclic group has two or more ring structures together with a benzene ring to which R ^{1AZ6 to} R ^5AZ6 are bonded. Examples of the two or more ring structures include structures of the following formulas.

  In addition, the bonding position of the above heterocyclic ring is a portion from which an arbitrary hydrogen atom contained in each ring is eliminated.

The heterocyclic group represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6 may have a substituent. . The substituent has a hydrocarbon group represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. The same as the substituent which may be good. When the heterocyclic ring contains a nitrogen atom as a constituent element, the above-described hydrocarbon group may be bonded to the nitrogen atom as a substituent.
Preferred examples of the substituent include hydrocarbon groups represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. The same thing as the preferable thing of the substituent which may be carried out is mentioned.
The heterocyclic group having a substituent represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6 is monovalent or 2 A heterocyclic group having a valent substituent, preferably a heterocyclic group having a substituent of group s1, and more preferably a heterocyclic group having a substituent of group s2.
The hydrocarbon group or heterocyclic group may have one or more substituents (first substituent), and the two or more substituents are independent of each other. They may be the same or different. Further, the first substituent may have another substituent (second substituent) bonded to a hydrocarbon group contained in a part thereof. The second substituent can be selected from the same groups as the first substituent.

R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 and R ^13AZ6 -CO-R ^102AZ6 , -COO-R ^101AZ6 , -OCO-R ^102AZ6 , -COCO- ^{R 102AZ6, -O-R 102AZ6,} -SO 2 -R 101AZ6, -SO 2 N (R 102AZ6) 2, -CON (R 102AZ6) 2, -N (R 102AZ6) 2, -NHCO-R 102AZ6, -NHCO _{^{-N (R 102AZ6) 2, -NHCOOR}} 102AZ6, -OCON (R 102AZ6) 2, halogen atom, -SO ₃ M, for -CO ₂ M will be described. -CO-R ^102AZ6 exemplified ^{below, -COO-R 101AZ6, -OCO-} R 102AZ6, -COCO-R 102AZ6, -O-R 102AZ6, -SO 2 -R 101AZ6, -SO 2 N (R 102AZ6) 2 , ^-CON ( ^R102AZ6 ) ₂ , -N ( ^R102AZ6 ) ₂ , -NHCO- ^R102AZ6 , -NHCO-N ( ^R102AZ6 ) ₂ , ^{-NHCOOR102AZ6} , -OCON ( ^R102AZ6 ) ₂ , ^R101AZ6 , R ^{It is preferable} that a substituent of the group s2, particularly —SO ₃ ⁻ , —CO ₂ ^— or the like, is bonded to a portion corresponding to ^102AZ6 .

As —CO—R ^102AZ6 , formyl group; acetyl group, propanoyl group, butanoyl group, 2,2-dimethylpropanoyl group, pentanoyl group, hexanoyl group, (2-ethyl) hexanoyl group, heptanoyl group, octanoyl group, nonanoyl A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivative thereof, such as a group, a decanoyl group, an undecanoyl group, a dodecanoyl group, a heicosanoyl group, a benzoyl group, and the like A derivatized group (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. Group), the number of carbon atoms is 2 to 41 when the carbonyl group is an acyl group. And groups corresponding to —CO—R ^102AZ6 in the compounds shown in Tables 1Z6 to ^4Z6 and groups corresponding to —CO—R ^102AZ6 in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290, etc. Preferably, a carbonyl group to which a hydrocarbon group having 1 to 11 carbon atoms (more preferably 1 to 10 carbon atoms) or a derivatized group thereof is bonded (when the carbonyl group is an alkanoyl group, the carbon number is more And preferably a group corresponding to —CO—R ^102AZ6 in the compounds shown in Tables 1Z6 to ^4Z6 .

-COO-R ^101AZ6 includes a methoxycarbonyl group, an ethoxycarbonyl group, a propoxycarbonyl group, a tert-butoxycarbonyl group, a butoxycarbonyl group, a pentyloxycarbonyl group, a hexyloxycarbonyl group, a (2-ethyl) hexyloxycarbonyl group, Heptyloxycarbonyl group, octyloxycarbonyl group, nonyloxycarbonyl group, decyloxycarbonyl group, undecyloxycarbonyl group, dodecyloxycarbonyl group, phenyloxycarbonyl group, icosyloxycarbonyl group, etc. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon, etc. Number 1 An oxycarbonyl group to which 10 alkylsulfamoyl groups (preferably a group derivatized with octylsulfamoyl group) and the like are bonded, and a group corresponding to —COO—R ^102AZ6 in the compounds shown in Tables 1Z6 to ^4Z6 And groups corresponding to —COO—R ^102AZ6 in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290, preferably a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof bonded thereto. Examples include oxycarbonyl groups and groups corresponding to —COO—R ^102AZ6 in the compounds shown in Tables 1Z6 to ^4Z6 .

-OCO-R ^102AZ6 includes ^formyloxy group; acetoxy group, propanoyloxy group, butanoyloxy group, 2,2-dimethylpropanoyloxy group, pentanoyloxy group, hexanoyloxy group, (2-ethyl) Hexanoyloxy group, heptanoyloxy group, octanoyloxy group, nonanoyloxy group, decanoyloxy group, undecanoyloxy group, dodecanoyloxy group, heicosanoyloxy group, benzoyloxy group, and the above formula A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom) ), An alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. In the compounds shown in Tables 1Z6 to 4Z6, and —OCO—R ^102AZ6, a carbonyloxy group to which a derivatized group is bonded (when the carbonyloxy group is an acyloxy group, the number of carbon atoms is 2 to 41) And groups corresponding to —OCO—R ^102AZ6 in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290, preferably 1 to 11 carbon atoms (more preferably 1 to 1 carbon atoms). 10) A carbonyloxy group to which a hydrocarbon group or a derivatizing group thereof is bonded (when the carbonyloxy group is an acyloxy group, the carbon number is more preferably 2 to 12) and Tables 1Z6 to 4Z6 ^Examples of the compound include a group corresponding to -OCO-R ^102AZ6 .

-COCO-R ^102AZ6 includes methyl oxalyl group, ethyl oxalyl group, propyl oxalyl group, butyl oxalyl group, pentyl oxalyl group, hexyl oxalyl group, (2-ethyl) hexyl oxalyl group, heptyl oxalyl group, octyl oxalyl group, nonyl Oxalyl group, decyloxalyl group, undecyloxalyl group, dodecyloxalyl group, icosyloxalyl group, cyclopentyloxalyl group, cyclohexyloxalyl group, phenyloxalyl group, p-tolyloxalyl group, etc., and groups represented by the above formula A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), 10 alkyl sulfamos A group corresponding to -COCO-R ^102AZ6 in the compounds shown in Tables 1Z6 to 4Z6 and Japanese Patent Application No. 2017-016290. In the compounds shown in Tables 1 to 966 of the No., groups corresponding to -COCO-R ^102AZ6 and the like can be mentioned.

-O-R ^102AZ6 includes a hydroxy group; methoxy group, ethoxy group, propoxy group, isopropoxy group, butoxy group, isobutoxy group, sec-butoxy group, tert-butoxy group, pentyloxy group, hexyloxy group, heptyloxy Group, octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, dodecyloxy group, (2-ethyl) hexyloxy group, icosyloxy group, 1-phenylethoxy group, 1-methyl-1-phenylethoxy group, phenyl Oxy group, 2,3-dimethylphenyloxy group, 2,4-dimethylphenyloxy group, 2,5-dimethylphenyloxy group, 2,6-dimethylphenyloxy group, 3,4-dimethylphenyloxy group, 3, 5-dimethylphenyloxy group, 2,2-dicyanophenyloxy Group, 2,3-dicyanophenyloxy group, 2,4-dicyanophenyloxy group, 2,5-dicyanophenyloxy group, 2,6-dicyanophenyloxy group, 3,4-dicyanophenyloxy group, 3,5 -Dicyanophenyloxy group, 4-methoxyphenyloxy group, 2-methoxyphenyloxy group, 3-methoxyphenyloxy group, 4-ethoxyphenyloxy group, 2-ethoxyphenyloxy group, 3-ethoxyphenyloxy group and the like, and A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group represented by the above formula or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably Is a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group), etc. Groups) -O-R ^102AZ6 in the compound represented by -O-R ^102AZ6 Table 1-966 of the relevant group and Japanese Patent Application No. 2017-016290 in the the compound represented in group and Table 1Z6~ Table 4Z6 bound is A group corresponding to —O—R ^102AZ6 in the compounds shown in Tables 1Z6 to 4Z6 and preferably an oxy group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded. Etc.

As —SO ₂ —R ^101AZ6 , a methylsulfonyl group, an ethylsulfonyl group, a propylsulfonyl group, a butylsulfonyl group, a pentylsulfonyl group, a ^{hexylsulfonyl} group, a (2-ethyl) ^{hexylsulfonyl} group, a ^{heptylsulfonyl} group, an octylsulfonyl group, 1 to 40 carbon atoms such as a nonylsulfonyl group, a decylsulfonyl group, an undecylsulfonyl group, a dodecylsulfonyl group, an icosylsulfonyl group, a phenylsulfonyl group, a p-tolylsulfonyl group, and a group represented by the above formula Preferably a hydrocarbon group having 1 to 20 carbon atoms or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms. (Preferably octylsulfamoyl group) In the compounds shown in Tables 1Z6 to ^4Z6 and groups corresponding to —SO ₂ —R ^102AZ6 and compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290, —SO ₂ — ^Groups corresponding to R ^102AZ6 and the like. Preferably, in a sulfonyl group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded and a compound shown in Table 1Z6 to Table 4Z6, —SO ₂ —R ^102AZ6 Applicable groups and the like can be mentioned.

—SO ₂ N (R ^102AZ6 ) ₂ includes a sulfamoyl group;
N-methylsulfamoyl group, N-ethylsulfamoyl group, N-propylsulfamoyl group, N-isopropylsulfamoyl group, N-butylsulfamoyl group, N-isobutylsulfamoyl group, N- sec-butylsulfamoyl group, N-tert-butylsulfamoyl group, N-pentylsulfamoyl group, N- (1-ethylpropyl) sulfamoyl group, N-hexylsulfamoyl group, N- (2- Ethyl) hexylsulfamoyl group, N-heptylsulfamoyl group, N-octylsulfamoyl group, N-nonylsulfamoyl group, N-decylsulfamoyl group, N-undecylsulfamoyl group, N- Dodecylsulfamoyl group, N-icosylsulfamoyl group, N-phenylsulfamoyl group, etc., and groups represented by the above formula A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), carbon number In the compounds shown in Tables 1Z6 to 4Z6 and —SO ₂ NH (R ^102AZ6X ) substituted with 1 to 10 alkylsulfamoyl groups (preferably a group derivatized with an octylsulfamoyl group) or the like. ) (Provided that R ^102AZ6X is the same as R ^102AZ6 except that R ^102AZ6X does not become a hydrogen atom) and the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290, —SO ₂ NH (R ^102AZ6X ) (However, R ^102AZ6X is the same as R ^102AZ6 except that it does not become a hydrogen atom), etc .;

N, N-dimethylsulfamoyl group, N, N-ethylmethylsulfamoyl group, N, N-diethylsulfamoyl group, N, N-propylmethylsulfamoyl group, N, N-dipropylsulfamoyl group Group, N, N-isopropylmethylsulfamoyl group, N, N-diisopropylsulfamoyl group, N, N-tert-butylmethylsulfamoyl group, N, N-diisobutylsulfamoyl group, N, N- Disec-butylsulfamoyl group, N, N-ditert-butylsulfamoyl group, N, N-butylmethylsulfamoyl group, N, N-dibutylsulfamoyl group, N, N-dipentylsulfa Moyl group, N, N-di (1-ethylpropyl) sulfamoyl group, N, N-dihexylsulfamoyl group, N, N-di (2-ethyl) hexyls Famoyl group, N, N-diheptylsulfamoyl group, N, N-octylmethylsulfamoyl group, N, N-dioctylsulfamoyl group, N, N-dinonylsulfamoyl group, N, N-decyl Methylsulfamoyl group, N, N-undecylmethylsulfamoyl group, N, N-dodecylmethylsulfamoyl group, N, N-icosylmethylsulfamoyl group, N, N-phenylmethylsulfamoyl Two hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group, N, N-diphenylsulfamoyl group, and the group represented by the above formula, or a derivatized group thereof ( For example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom), alkyl sulfamoyl group having 1 to 10 carbon atoms (preferably octyl sulfamoyl) ^{_{) -SO 2 N (R 102AZ6X)}} 2 ( provided that at sulfamoyl groups and compounds shown in Table 1Z6~ Table 4Z6 substituted with derivatized groups) in such, except that R ^102AZ6X is not a hydrogen atom, R in the compounds shown in Table 1 to 966 of the corresponding group and Japanese Patent Application No. 2017-016290 the same as is) and _{^{102AZ6 -SO 2 N (R 102AZ6X)}} 2 ( where except that R ^102AZ6X is not a hydrogen atom, The same as R ^102AZ6 ), and the like.
Preferably, it corresponds to —SO ₂ N (R ^102AZ6 ) ₂ in one or two sulfamoyl groups substituted with one or two hydrocarbon groups having 1 to 10 carbon atoms or derivatized groups thereof, and compounds shown in Tables 1Z6 to ^4Z6. Groups and the like.

^—CON (R ^102AZ6 ) ₂ includes a carbamoyl group;
N-methylcarbamoyl group, N-ethylcarbamoyl group, N-propylcarbamoyl group, N-isopropylcarbamoyl group, N-butylcarbamoyl group, N-isobutylcarbamoyl group, N-sec-butylcarbamoyl group, N-tert-butylcarbamoyl Group, N-pentylcarbamoyl group, N- (1-ethylpropyl) carbamoyl group, N-hexylcarbamoyl group, N- (2-ethyl) hexylcarbamoyl group, N-heptylcarbamoyl group, N-octylcarbamoyl group and N- One of nonylcarbamoyl group, N-decylcarbamoyl group, N-undecylcarbamoyl group, N-dodecylcarbamoyl group, N-icosylcarbamoyl group, N-phenylcarbamoyl group, etc., and a group represented by the above formula 1 to 40 carbon atoms (preferably charcoal A hydrocarbon group of 1 to 20) or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably In the compounds shown in Tables 1Z6 to 4Z6, —CONH (R ^102AZ6X ) (provided that R ^102AZ6X does not become a hydrogen atom), and carbamoyl groups substituted with groups derivatized with octylsulfamoyl groups) etc. , -CONH (R ^102AZ6X) (provided that the compounds shown in Table 1 to 966 groups and Japanese Patent Application No. 2017-016290 corresponding to same in a) and R ^102AZ6, except that R ^102AZ6X is not a hydrogen atom, R ^The same as ^102AZ6 )

N, N-dimethylcarbamoyl group, N, N-ethylmethylcarbamoyl group, N, N-diethylcarbamoyl group, N, N-propylmethylcarbamoyl group, N, N-dipropylcarbamoyl group, N, N-isopropylmethylcarbamoyl Group, N, N-diisopropylcarbamoyl group, N, N-tert-butylmethylcarbamoyl group, N, N-diisobutylcarbamoyl group, N, N-disec-butylcarbamoyl group, N, N-ditert-butylcarbamoyl group N, N-butylmethylcarbamoyl group, N, N-dibutylcarbamoyl group, N, N-butyloctylcarbamoyl group, N, N-dipentylcarbamoyl group, N, N-di (1-ethylpropyl) carbamoyl group, N , N-dihexylcarbamoyl group, N, N-di (2-ethyl) hexyl Rucarbamoyl group, N, N-diheptylcarbamoyl group, N, N-octylmethylcarbamoyl group, N, N-dioctylcarbamoyl group, N, N-dinonylcarbamoyl group, N, N-decylmethylcarbamoyl group, N, N -Undecylmethylcarbamoyl group, N, N-dodecylmethylcarbamoyl group, N, N-icosylmethylcarbamoyl group, N, N-phenylmethylcarbamoyl group, N, N-diphenylcarbamoyl group, etc. Two hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group to be synthesized or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom) ), A C 1-10 alkylsulfamoyl group (preferably an octylsulfamoyl group), etc. Groups) -CON In the compounds shown in carbamoyl group and Tables 1Z6~ Table 4Z6 substituted with (R ^102AZ6X) ₂ (where except that R ^102AZ6X is not a hydrogen atom, corresponding to the same in a) and R ^102AZ6 And -CON (R ^102AZ6X ) ₂ (provided that R ^102AZ6X is the same as R ^102AZ6 except that it does not become a hydrogen atom) in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290 Groups, etc.
Preferably, one or two hydrocarbon groups having 1 to 10 carbon atoms or a carbamoyl group substituted with a derivatizing group thereof, and a group corresponding to ^—CON (R ^102AZ6 ) ₂ in the compounds shown in Tables 1Z6 to 4Z6, etc. Is mentioned.

—N (R ^102AZ6 ) ₂ includes an amino group;
N-methylamino group, N-ethylamino group, N-propylamino group, N-isopropylamino group, N-butylamino group, N-isobutylamino group, N-sec-butylamino group, N-tert-butylamino Group, N-pentylamino group, N-hexylamino group, N- (2-ethyl) hexylamino group, N-heptylamino group, N-octylamino group, N-nonylamino group, N-decylamino group, N-un A decylamino group, an N-dodecylamino group, an N-icosylamino group, an N-phenylamino group, and the like, and one of 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group represented by the above formula A hydrocarbon group or a derivatized group thereof (for example, a carboxy group, a sulfo group, a nitro group, a hydroxy group, a halogen (preferably a chlorine atom), an alkyl group having 1 to 10 carbon atoms; -NH (R ^102AZ6X) (provided that the amino group and Tables 1Z6~ Table 4Z6 compounds shown in substituted with Amoiru group (preferably octyl sulfamoyl group) were derivatized with such groups), R ^102AZ6X a hydrogen atom do not except that become, in the compounds shown in Table 1 to 966 groups and Japanese Patent Application No. 2017-016290 corresponding to same in a) and R ^102AZ6 -NH (R ^102AZ6X) (provided that, R ^102AZ6X is not a hydrogen atom Except for the ^above , it is the same as R ^102AZ6 ), etc.

N, N-dimethylamino group, N, N-ethylmethylamino group, N, N-diethylamino group, N, N-propylmethylamino group, N, N-dipropylamino group, N, N-isopropylmethylamino group N, N-diisopropylamino group, N, N-tert-butylmethylamino group, N, N-diisobutylamino group, N, N-disec-butylamino group, N, N-ditert-butylamino group, N, N-butylmethylamino group, N, N-dibutylamino group, N, N-dipentylamino group, N, N-di (1-ethylpropyl) amino group, N, N-dihexylamino group, N, N -Di (2-ethyl) hexylamino group, N, N-diheptylamino group, N, N-dioctylamino group, N, N-dinonylamino group, N, N-decylmethylamino group, N, N- Ndecylmethylamino group, N, N-dodecylmethylamino group, N, N-icosylmethylamino group, N, N-phenylmethylamino group, N, N-diphenylamino group, etc., and the above formula Two hydrocarbon groups having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably chlorine atom) -N (R) in the amino group substituted with an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably a group derivatized with an octylsulfamoyl group or the like) and the compounds shown in Tables 1Z6 to 4Z6 ^102AZ6X) ₂ (where reduction except that R ^102AZ6X is not a hydrogen atom, are shown in Table 1 to 966 groups and Japanese Patent Application No. 2017-016290 corresponding to same in a) and R ^102AZ6 -N (R ^102AZ6X) ₂ (provided that, R ^102AZ6X, except that not a hydrogen atom, same as is the R ^102AZ6) in the object group corresponding to the like,
Preferably, one or two hydrocarbon groups having 1 to 10 carbon atoms or an amino group substituted with a derivatizing group thereof, and a group corresponding to —N (R ^102AZ6 ) ₂ in the compounds shown in Tables 1Z6 to 4Z6, etc. Is mentioned.

—NHCO—R ^102AZ6 includes formylamino group; acetylamino group, propanoylamino group, butanoylamino group, 2,2-dimethylpropanoylamino group, pentanoylamino group, hexanoylamino group, (2-ethyl ) Hexanoylamino group, heptanoylamino group, octanoylamino group, nonanoylamino group, decanoylamino group, undecanoylamino group, dodecanoylamino group, heicosanoylamino group, benzoylamino group, etc. A hydrocarbon group having 1 to 40 carbon atoms (preferably 1 to 20 carbon atoms) such as a group represented by the above formula or a derivatized group thereof (for example, carboxy group, sulfo group, nitro group, hydroxy group, halogen (preferably Is a chlorine atom), an alkylsulfamoyl group having 1 to 10 carbon atoms (preferably an octylsulfamoyl group) -NHCO-R in the compounds shown in Tables 1Z6 to 4Z6 and carbonylamino groups to which the carbonylamino group is bonded (when the carbonylamino group is an acylamino group, the number of carbons is 1 to 40). A group corresponding to ^102AZ6 and a group corresponding to -NHCO-R ^102AZ6 in the compounds shown in Tables 1 to 966 of Japanese Patent Application No. 2017-016290,
Preferably a carbonylamino group to which a hydrocarbon group having 1 to 10 carbon atoms or a derivatizing group thereof is bonded (when the carbonylamino group is an alkanoylamino group, the carbon number is more preferably 1 to 10) and Table 1Z6 To groups corresponding to —NHCO—R ^102AZ6 in the compounds shown in Table 4Z6.

As —NHCON (R ^102AZ6 ) ₂ , the groups listed above and the groups corresponding to —NHCON (R ^102AZ6 ) ₂ in the compounds shown in Tables 1Z6 to 4Z6, Tables 1 to 966 of Japanese Patent Application No. 2017-016290 And a group corresponding to —NHCON (R ^102AZ6 ) ₂ in the compound represented by

-NHCOOR ^102AZ6 includes the above-described groups and the like, groups corresponding to -NHCOOR ^102AZ6 in the compounds shown in Tables 1Z6 to 4Z6, and -NHCOOR 102AZ6 in the compounds shown in Tables 1 to ⁹⁶⁶ of Japanese Patent Application No. ^2017-016290. And the like group.

^{Examples of} —OCON (R ^102AZ6 ) ₂ include groups listed above and groups corresponding to —OCON (R ^102AZ6 ) ₂ in the compounds shown in Tables 1Z6 to 4Z6, And a group corresponding to —OCON (R ^102AZ6 ) ₂ in the compound represented by

As the halogen atom, a fluorine atom, a chlorine atom, a bromine atom and an iodine atom are preferable.
Examples of M in —SO ₃ M and —CO ₂ M include a hydrogen atom; an alkali metal atom such as a lithium atom, a sodium atom and a potassium atom, preferably a hydrogen atom, a sodium atom and a potassium atom.

The ^{-CO-R 102AZ6, -COO-R} 102AZ6, -OCO-R 102AZ6, -COCO-R 102AZ6, -O-R 102AZ6, -SO 2 -R 102AZ6, -SO 2 N (R 102AZ6) 2, -CON ^{Substituent contained in} ( ^R102AZ6 ) ₂ , -N ( ^R102AZ6 ) ₂ , -NHCO- ^R102AZ6 , -NHCON ( ^R102AZ6 ) ₂ , ^{-NHCOOR102AZ6} , -OCON ( ^R102AZ6 ) ₂ (first substituent) May be one or more, and the two or more substituents may be the same or different independently of each other.
Further, the first substituent may have another substituent (second substituent) bonded to a hydrocarbon group contained in a part thereof. The second substituent can be selected from the same groups as the first substituent.

R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 and R ^13AZ6 include a hydrogen atom, —CO—R ^102AZ6 , —COO—R ^101AZ6 , —COCO—R ^102AZ6 , _{^{-O-R 102AZ6, -SO 2 -R}} 101AZ6, -SO 2 N (R 102AZ6) 2, -CON (R 102AZ6) 2, -N (R 102AZ6) 2, -NHCO-N (R 102AZ6) 2, - NHCOOR ^102AZ6 , —OCON (R ^102AZ6 ) ₂ , halogen atom, cyano group, nitro group, —SO ₃ M, —CO ₂ M, —SO ₃ ⁻ , —CO ₂ ⁻ , ^optionally substituted carbon A heterocyclic group optionally having 1 to 40 hydrocarbon groups or substituents is preferred.
R ^101AZ6 is preferably a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent.
R ^102AZ6 is preferably a hydrogen atom or a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent.

The ring formed by R ^2AZ6 and R ^3AZ6 , R ^3AZ6 and R ^4AZ6 , and R ^4AZ6 and R ^5AZ6 is condensed with the benzene ring of the isoindoline skeleton of the compound represented by the formula (IZ6). The condensed ring structure of the ring formed by R ^2AZ6 and R ^3AZ6 , R ^3AZ6 and R ^4AZ6 , and R ^4AZ6 and R ^5AZ6 and the benzene ring includes indene, naphthalene, biphenylene, indacene, acenaphthylene, fluorene, phenalene, phenanthrene, Hydrocarbon condensed ring structures such as anthracene, fluoranthene, acephenanthrylene, aceanthrylene, triphenylene, pyrene, chrysene, N-methylphthalimide, N- (1-phenylethyl) phthalimide and tetracene, and their partially reduced forms ( Such as 9,10-dihydroanthracene, 1,2,3,4-tetrahydronaphthalene); indole, isoindole, indazole, quinoline, isoquinoline, phthalazine, quinoxaline, quinazoline, cinnoline, carbazole, carboline, phenaline Tolidine, acridine, perimidine, nitrogen-containing condensed heterocyclic ring and that part reductant such as phenanthroline and phenazine; 3- oxygen-containing condensed such tetrahydrobenzo furan-2-one heterocyclic ring and its partially reduced products thereof.

When R ^2AZ6 and R ^3AZ6 , R ^3AZ6 and R ^4AZ6 , and R ^4AZ6 and R ^5AZ6 form a ring, the ring may have a substituent. The substituent has a hydrocarbon group represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. The same as the substituent which may be good. Preferred examples of the substituent include hydrocarbon groups represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. The same thing as the preferable thing of the substituent which may be carried out is mentioned.

When R ^3AZ6 and R ^4AZ6 form a ring, R ^2AZ6 and R ^5AZ6 are independently of each other preferably a hydrogen atom, an amino group or a hydroxy group.
When R ^2AZ6 and R ^3AZ6 form a ring, R ^4AZ6 and R ^5AZ6 preferably do not form a ring, and R ^4AZ6 and R ^5AZ6 are more preferably hydrogen atoms.
When R ^4AZ6 and R ^5AZ6 form a ring, R ^2AZ6 and R ^3AZ6 preferably do not form a ring, and more preferably R ^2AZ6 and R ^3AZ6 are hydrogen atoms.

Ring R ^AA1Z6 and R ^AA2Z6, and the R ^12AZ6 and R ^13AZ6 form is coupled with isoindoline skeleton of exomethylene (C = CH ₂₎ of formula (IZ6), R ^AA1Z6 and R ^AA2Z6, and R ^12AZ6 And the ring formed by R ^13AZ6 is a structure containing this ^exomethylene (C═CH ₂ ). The structure can be exemplified. ** represents a bond to the isoindoline skeleton.
[Group A]

[Group B]

R ^104AZ6 , R ^105AZ6 , R ^106AZ6 , and R ^107AZ6 are each independently a hydrogen atom, —CO—R ^102AZ6 , —COO—R ^101AZ6 , —OCO—R ^102AZ6 , —COCO—R ^102AZ6 , —O—R ^{102AZ6 _{, -SO 2 -R 101AZ6, -SO 2}} N (R 102AZ6) 2, -CON (R 102AZ6) 2, -N (R 102AZ6) 2, -NHCO-R 102AZ6, -NHCO-N (R 102AZ6) 2, ^{-NHCOOR 102AZ6, -OCON (R 102AZ6)} 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , -SO 3 -, -CO 2 -, which may have a substituent The C1-C40 hydrocarbon group or the heterocyclic group which may have a substituent is represented.

^{R 104AZ6, R 105AZ6, R 106AZ6} , and represented by ^{R 107AZ6, -CO-R 102AZ6,} -COO-R 101AZ6, -OCO-R 102AZ6, -COCO-R 102AZ6, -O-R 102AZ6, -SO 2 _{^{-R 101AZ6, -SO 2 N (R}} 102AZ6) 2, -CON (R 102AZ6) 2, -N (R 102AZ6) 2, -NHCO-R 102AZ6, -NHCO-N (R 102AZ6) 2, -NHCOOR 102AZ6, -OCON (R ^102AZ6) _2, halogen atom, -SO ₃ M and -CO ₂ M, the table in ^{R 1AZ6, R 2AZ6, R 3AZ6} , R 4AZ6, R 5AZ6, R AA1Z6, R AA2Z6, R 12AZ6 and R ^13AZ6 -CO-R ^{102AZ6 being, -COO-R 101AZ6, -OCO-} R 102AZ6, -COCO-R 102AZ6, -O-R 102AZ6, -SO 2 -R 101AZ6, -SO 2 N (R 102AZ6) 2, - CON (R ^102AZ6 ) ₂ , -N (R ^102AZ6 ) ₂ , -NHCO-R ^102AZ6 , -NHCO- _{^{N (R 102AZ6) 2, -NHCOOR}} 102AZ6, -OCON (R 102AZ6) 2, halogen atom, include those similar to the -SO ₃ M and -CO ₂ M.

^{Examples of} the ^optionally substituted hydrocarbon group having 1 to 40 carbon atoms and the ^optionally substituted heterocyclic group represented by R ^104AZ6 , R ^105AZ6 , R ^106AZ6 , and R ^107AZ6 R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6 The same thing as the heterocyclic group which may have 40 hydrocarbon groups or a substituent is mentioned.

The hydrocarbon group and heterocyclic group having 1 to 40 carbon atoms represented by R ^104AZ6 , R ^105AZ6 , R ^106AZ6 , and R ^107AZ6 may have a substituent. The substituent has a hydrocarbon group represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. The same as the substituent which may be good. Preferred examples of the substituent include hydrocarbon groups represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. The same thing as the preferable thing of the substituent which may be carried out is mentioned.

^{R 104AZ6, R 105AZ6, R 106AZ6} , and as the R ^107AZ6, preferably those same as preferred in the ^{R 1AZ6, R 2AZ6, R 3AZ6} , R 4AZ6, R 5AZ6, R AA1Z6, R AA2Z6, R 12AZ6 and R ^13AZ6 Can be mentioned.
R ^104AZ6 , R ^105AZ6 , R ^106AZ6 , and R ^107AZ6 are more preferably a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, a tert-butyl group, a pentyl group, a hexyl group, and (2-ethyl) hexyl. A hydrocarbon group having 1 to 10 carbon atoms such as a group, heptyl group, octyl group, nonyl group, cyclohexyl group and phenyl group, and a hydrogen atom.

The groups exemplified in Group A and Group B may be those in which a hydrogen atom bonded to the ring structure is substituted with a substituent.
The substituent has a hydrocarbon group represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. The same as the substituent which may be good.
Of these substituents, preferred are hydrocarbon groups represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. The same thing as the preferable thing of the substituent which may have is mentioned.

R ^1AZ6 is a hydrogen atom, and R ^2AZ6 , R ^3AZ6 , R ^4AZ6 and R ^5AZ6 are independently of each other,
A hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogen atom, -N (R ^102AZ6 ) ₂ , a nitro group, a hydrocarbon group having 1 to 20 carbon atoms in which all or part of the hydrogen atoms are substituted by fluorine atoms, ^{-NHCO-R 102AZ6, -O-R} 102AZ6, is preferably -SO ₃ M or -CO ₂ M,
More preferably, they are a hydrogen atom, a tert-butyl group, or a nitro group.

R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6 are at least one of (raa-i) to (raa-iii) R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6 have —SO ₃ ^— or —CO ₂ ^—. The total number of is a.
(Raa-i) At least one of R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 and R ^13AZ6 is —SO ₃ ^— or —CO ₂ ^— .
(Raa-ii) At least one of R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 and R ^13AZ6 is —CO—R ^102AZ6 , —COO—R ^101AZ6 , —O _{^{-R 102AZ6, -SO 2 -R 101AZ6,}} -SO 2 N (R 102AZ6) 2, -CON (R 102AZ6) a ₂ or -N (R ^102AZ6) _2, wherein R ^101AZ6 and R ^102AZ6 is, -SO ₃ ^- or -CO ₂ ^- 1 to 40 carbon atoms having a hydrocarbon group or a -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .
(Raa-iii) at least one of R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 and R ^13AZ6 has 1 carbon atom having —SO ₃ ^— or —CO ₂ ^—. A heterocyclic group having ˜40 hydrocarbon groups or —SO ₃ ^— or —CO ₂ ^— . However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .

  Examples of Group A and Group B include rings represented by Formula (QQ1) to Formula (QQ25) and Formula (QQA1) to Formula (QQA36).

  The compound represented by the formula (IZ6-A) is preferably a compound represented by the formula (IZ6-B) (hereinafter sometimes referred to as the compound (IZ6-B)).

[In the formula (IZ6-B)
A ^{c +} , b, c, d and wavy line have the same meaning as described above.
L ¹ represents —CO— or —SO ₂ —.
R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 and R ^13BZ6 are each independently a hydrogen atom, —CO—R ^102BZ6 , —COO—R ^101BZ6 , —OCO—R ^102BZ6 , ^{-COCO-R 102BZ6, -O-R} 102BZ6, -SO 2 -R 101BZ6, -SO 2 N (R 102BZ6) 2, -CON (R 102BZ6) 2, -N (R 102BZ6) 2, -NHCO-R 102BZ6 , —NHCO—N (R ^102BZ6 ) ₂ , —NHCOOR ^102BZ6 , —OCON (R ^102BZ6 ) ₂ , halogen atom, cyano group, nitro group, —SO ₃ M, —CO ₂ M, —SO ₃ ⁻ , —CO ₂ ^- represents a hydrocarbon group or optionally substituted heterocyclic group having carbon atoms of 1 to 40 which may have a substituent.
R ^2BZ6 and R ^3BZ6 , R ^3BZ6 and R ^4BZ6 , R ^4BZ6 and R ^5BZ6 , and R ^12BZ6 and R ^13BZ6 may be bonded to each other to form a ring.
R ^101BZ6 represents, independently of each other, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102BZ6 represents, independently of each other, a hydrogen atom, an ^optionally substituted hydrocarbon group having 1 to 40 carbon atoms, or an ^optionally substituted heterocyclic group.
Formula (IZ6-B ′) and Formula (IZ6-B ″) each represent a partial structure of Formula (IZ6-B), and A ^{c +} , b, c, d, R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 , R ^13BZ6 and L ¹ represent the same as those in formula (IZ6-B).
M represents the same meaning as described above.
When there are a ^{plurality of} R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 , R ^13BZ6 , R ^101BZ6 , R ^102BZ6 , L ¹ , M, c or A ^{c +} , they are the same May be different or different.
R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 , R ^13BZ6 , R ^101BZ6 and R ^102BZ6 satisfy at least one of (rb-i) to (rb-iii). The total number of —SO ₃ ^— or —CO ₂ ^{— contained} in R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 , R ^13BZ6 , R ^101BZ6 and R ^102BZ6 is a. .
( ^Rb -i) At least one of R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 and R ^13BZ6 is —SO ₃ ^— or —CO ₂ ^— .
^{(Rb-ii) R 1BZ6,} R 2BZ6, R 3BZ6, R 4BZ6, R 5BZ6, R 11BZ6, at least one of R ^12BZ6 and R ^{13BZ6 is, -CO-R 102BZ6, -COO-} R 101BZ6, -OCO-R 102BZ6 ^{, -COCO-R 102BZ6, -O-} R 102BZ6, -SO 2 -R 101BZ6, -SO 2 N (R 102BZ6) 2, or _{^{-CON (R 102BZ6) 2, -N}} (R 102BZ6) 2, -NHCO- R ^102BZ6 , —NHCO—N (R ^102BZ6 ) ₂ , —NHCOOR ^102BZ6 , or —OCON (R ^102BZ6 ) ₂ , wherein R ^101BZ6 and R ^102BZ6 have —SO ₃ ^— or —CO ₂ ^—. It is a heterocyclic group having 1 to 40 hydrocarbon groups or —SO ₃ ^— or —CO ₂ ^— . However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .
( ^Rb -iii) at least one of R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 and R ^13BZ6 has 1 to 40 carbon atoms having —SO ₃ ^— or —CO ₂ ^— . It is a hydrocarbon group or a heterocyclic group having —SO ₃ ^— or —CO ₂ ^— . However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .
a represents the same meaning as in formula (IZ6-A). When a plurality of a are present, they may be the same or different.
The absolute value of the negative valence of the partial structure represented by the formula (IZ6-B ′) and the positive valence of the partial structure represented by the formula (IZ6-B ″) are the same. ]

R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 and R ^13BZ6 are R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^A2Z6 , R ^A2Z6 , R ^A2Z6 The same thing as ^R13AZ6 is mentioned.
^{Preferred examples of} R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 and R ^13BZ6 include R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA1Z6 , R ^AA1Z6 The same thing as the preferable thing of ^R12AZ6 and ^R13AZ6 is mentioned.

R ^101BZ6 may be the same as R ^101AZ6 .
Preferable examples of R ^101BZ6 may be the same as those preferred for R ^101AZ6.

^Examples of R ^102BZ6 include the same as R ^102AZ6 .
Preferable examples of R ^102BZ6 may be the same as those preferred for R ^102AZ6.

The hydrocarbon group and heterocyclic group having 1 to 40 carbon atoms represented by R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 , R ^13BZ6 , R ^101BZ6 and R ^102BZ6 are substituents. You may have. The substituent has a hydrocarbon group represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. The same as the substituent which may be good. Preferred examples of the substituent include hydrocarbon groups represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. The same thing as the preferable thing of the substituent which may be carried out is mentioned.

L ¹ is preferably —CO—.

R ^11BZ6 is an ^optionally substituted aliphatic hydrocarbon group having 1 to 40 carbon atoms, an ^optionally substituted phenyl group, an ^optionally substituted naphthyl group, a substituted group. A tetrahydronaphthyl group which may have a group, a thienyl group which may have a substituent, a furyl group which may have a substituent or a pyridinyl group which may have a substituent. Is preferred.

The carbon number of the aliphatic hydrocarbon group represented by R ^11BZ6 is 1 to 40, preferably 1 to 30, more preferably 1 to 20, and further preferably 1 to 15.

  The aliphatic hydrocarbon group may be saturated or unsaturated, and may be chain or alicyclic.

^Examples of the saturated or unsaturated chain aliphatic hydrocarbon group represented by R ^11BZ6 include methyl group, ethyl group, propyl group, butyl group, pentyl group, hexyl group, heptyl group, octyl group, nonyl group, decyl group, Linear alkyl groups such as undecyl, dodecyl, heptadecyl, octadecyl and icosyl; isopropyl, isobutyl, sec-butyl, tert-butyl, (2-ethyl) butyl, isopentyl, Neopentyl group, tert-pentyl group, (1-methyl) pentyl group, (2-methyl) pentyl group, (1-ethyl) pentyl group, (3-ethyl) pentyl group, isohexyl group, (5-methyl) hexyl group Branched alkyl groups such as (2-ethyl) hexyl group and (3-ethyl) heptyl group; vinyl group, 1-propenyl group, 2- Lopenyl (allyl), (1-methyl) ethenyl, 2-butenyl, 3-butenyl, 1,3-butadienyl, (1- (2-propenyl)) ethenyl, (1,2-dimethyl) ) Alkenyl groups such as propenyl group and 2-pentenyl group; Carbon number of a saturated or unsaturated chain hydrocarbon group becomes like this. Preferably it is 1-30, More preferably, it is 1-20, More preferably, it is 1-15, Most preferably, it is 1-10.

^Examples of the saturated or unsaturated alicyclic hydrocarbon group represented by R ^11BZ6 include a cyclopropyl group, 1-methylcyclopropyl group, cyclobutyl group, cyclopentyl group, cyclohexyl group, cycloheptyl group, 1-methylcyclohexyl group, 2 -Methylcyclohexyl group, 3-methylcyclohexyl group, 4-methylcyclohexyl group, 1,2-dimethylcyclohexyl group, 1,3-dimethylcyclohexyl group, 1,4-dimethylcyclohexyl group, 2,3-dimethylcyclohexyl group, 2 , 4-dimethylcyclohexyl group, 2,5-dimethylcyclohexyl group, 2,6-dimethylcyclohexyl group, 3,4-dimethylcyclohexyl group, 3,5-dimethylcyclohexyl group, 2,2-dimethylcyclohexyl group, 3,3 -Dimethylcyclohexyl group, 4,4- Methylcyclohexyl group, cyclooctyl group, 2,4,6-trimethylcyclohexyl group, 2,2,6,6-tetramethylcyclohexyl group and 3,3,5,5-tetramethylcyclohexyl group, 4-pentylcyclohexyl group, Cycloalkenyl groups such as 4-octylcyclohexyl group and 4-cyclohexylcyclohexyl group; Cycloalkenyl groups such as cyclohexenyl group (for example, cyclohex-2-ene, cyclohex-3-ene), cycloheptenyl group, cyclooctenyl group; norbornane group, adamantyl Group, bicyclo [2.2.2] octane and the like. The carbon number of the saturated or unsaturated alicyclic hydrocarbon group is preferably 3-30, more preferably 3-20, still more preferably 4-20, and even more preferably 4-15. More preferably 5 to 15 and most preferably 5 to 10. Of these, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, and a cyclooctyl group are particularly preferable.

The aliphatic hydrocarbon group represented by R ^11BZ6 is a group in which a hydrogen atom contained in the above-mentioned aliphatic hydrocarbon group is substituted with an aromatic hydrocarbon group having 1 to 40 carbon atoms or the above-described aliphatic The group may be a combination of group hydrocarbon groups.
Such aromatic hydrocarbon groups include phenyl, o-tolyl, m-tolyl, p-tolyl, 2-ethylphenyl, 3-ethylphenyl, 4-ethylphenyl, 2,3-dimethyl. Phenyl group, 2,4-dimethylphenyl group, 2,5-dimethylphenyl group, 2,6-dimethylphenyl group, 3,4-dimethylphenyl group, 3,5-dimethylphenyl group, o-isopropylphenyl group, m -Isopropylphenyl group, p-isopropylphenyl group, o-tert-butylphenyl group, m-tert-butylphenyl group, p-tert-butylphenyl group, mesityl group, 2,6-bis (2-propyl) phenyl group 2,4,6-trimethylphenyl group, 1-naphthyl group, 2-naphthyl group, 5,6,7,8-tetrahydro-1-naphthyl group, 5 6,7,8-tetrahydro-2-naphthyl group, a fluorenyl group, an aromatic hydrocarbon group such as a phenanthryl group and an anthryl group; and the like. Carbon number of this aromatic hydrocarbon group becomes like this. Preferably it is 6-30, More preferably, it is 6-20, More preferably, it is 6-15.
Examples of the group in which the aromatic hydrocarbon group having 1 to 40 carbon atoms is substituted for the hydrogen atom contained in the aliphatic hydrocarbon group listed above include benzyl group, phenethyl group, and 1-methyl-1-phenylethyl group. An aralkyl group is mentioned. Examples of the group obtained by combining the above aliphatic hydrocarbon groups include (cycloalkyl) alkyl groups such as a cyclohexylmethyl group. The number of carbon atoms of a group in which a hydrogen atom contained in an aliphatic hydrocarbon group is substituted with a group having an aromatic hydrocarbon group substituted with 1 to 40 carbon atoms or an aliphatic hydrocarbon group is preferably 4 to 30, and more Preferably it is 4-20, More preferably, it is 4-15.

The aliphatic hydrocarbon group having 1 to 40 carbon atoms represented by R ^11BZ6 , phenyl group, naphthyl group, tetrahydronaphthyl group, thienyl group, furyl group and pyridinyl group may have a substituent.
The substituent has a hydrocarbon group represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. The same as the substituent which may be good.
Preferred examples of the substituent include hydrocarbon groups represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. The same thing as the preferable thing of the substituent which may be carried out is mentioned.

In the compound (IZ6-B), R ^1BZ6 is preferably a hydrogen atom.
R ^2BZ6 , R ^3BZ6 , R ^4BZ6 or R ^5BZ6 are independent of each other,
A hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogen atom, —N (R ^102BZ6 ) ₂ , a nitro group, a hydrocarbon group having 1 to 20 carbon atoms in which all or part of the hydrogen atoms are substituted with fluorine atoms, ^{-NHCO-R 102BZ6, -O-R} 102BZ6, is preferably -SO ₃ M or -CO ₂ M,
It is more preferably a hydrogen atom or a nitro group. The number of nitro groups is preferably 0 to 2, more preferably 0 or 1.

R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 , R ^13BZ6 , R ^101BZ6 and R ^102BZ6 satisfy at least one of (rbb-i) to (rbb-iii). R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 , R ^13BZ6 , R ^101BZ6 and R ^102BZ6 have a total number of —SO ₃ ^— or —CO ₂ ^— of a. is there.
( ^Rbb -i) At least one of R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 and R ^13BZ6 is —SO ₃ ^— or —CO ₂ ^— .
( ^Rbb -ii) At least one of R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 and R ^13BZ6 is -CO-R ^102BZ6 , -COO-R ^101BZ6 , -O-R ^102BZ6 , —SO ₂ —R ^101BZ6 , —SO ₂ N (R ^102BZ6 ) ₂ , ^—CON (R ^102BZ6 ) _2, or —N (R ^102BZ6 ) ₂ , wherein R ^101BZ6 and R ^102BZ6 are —SO ₃ ^— or -CO ₂ ^- 1 to 40 carbon atoms having a hydrocarbon group or a -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .
( ^Rbb -iii) at least one of R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 and R ^13BZ6 has 1 to 40 carbon atoms having —SO ₃ ^— or —CO ₂ ^— . It is a hydrocarbon group or a heterocyclic group having —SO ₃ ^— or —CO ₂ ^— . However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .

In the formula (IZ6-B), when R ^12BZ6 and R ^13BZ6 do not form a ring, the compound (IZ6-B) is a compound represented by the formula (IZ6-C) (hereinafter referred to as the compound (IZ6-C)). In some cases).

[In the formula (IZ6-C)
A ^{c +} , b, c, d, L ¹ and the wavy line have the same meaning as described above.
L ² represents —CO— or —SO ₂ —.
R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 and R ^14CZ6 are each independently a hydrogen atom, -CO-R ^102CZ6 , -COO-R ^101CZ6 , -OCO-R ^102CZ6 , -COCO- ^{R 102CZ6, -O-R 102CZ6,} -SO 2 -R 101CZ6, -SO 2 N (R 102CZ6) 2, -CON (R 102CZ6) 2, -N (R 102CZ6) 2, -NHCO-R 102CZ6, -NHCO _{^{-N (R 102CZ6) 2, -NHCOOR}} 102CZ6, -OCON (R 102CZ6) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , -SO 3 -, -CO 2 -, substituted The C1-C40 hydrocarbon group which may have a group, or the heterocyclic group which may have a substituent is represented.
R ^2CZ6 and R ^3CZ6 , R ^3CZ6 and R ^4CZ6 , and R ^4CZ6 and R ^5CZ6 may be bonded to each other to form a ring.
R ^101CZ6 represents, independently of each other, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
^R102CZ6 represents a hydrogen atom, a ^C1-C40 hydrocarbon group which may have a substituent, or a heterocyclic group which may have a substituent, independently of each other.
M represents the same meaning as described above.
Formula (IZ6-C ′) and Formula (IZ6-C ″) each represent a partial structure of Formula (IZ6-C), and A ^{c +} , b, c, d, R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 , R ^14CZ6 , L ¹ and L ² represent the same as those in formula (IZ6-C).
When there are a ^{plurality of} R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 , R ^14CZ6 , R ^101CZ6 , R ^102CZ6 , L ¹ , L ² , M, c or A ^{c +} , they are the same May be different or different.
^R1CZ6 , ^R2CZ6 , ^R3CZ6 , ^R4CZ6 , ^R5CZ6 , ^R11CZ6 , ^R14CZ6 , ^R101CZ6 and ^R102CZ6 satisfy at least one of (rc-i) to (rc-iii), The total number of —SO ₃ ^— or —CO ₂ ^{— contained} in R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 , R ^14CZ6 , R ^101CZ6 and R ^102CZ6 is a.
(Rc-i) At least one of R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 and R ^14CZ6 is —SO ₃ ^— or —CO ₂ ^— .
^{(Rc-ii) R 1CZ6,} R 2CZ6, R 3CZ6, R 4CZ6, R 5CZ6, at least one of R ^11CZ6 and R ^{14CZ6 is, -CO-R 102CZ6, -COO-} R 101CZ6, -OCO-R 102CZ6, -COCO ^{-R 102CZ6, -O-R 102CZ6,} -SO 2 -R 101CZ6, -SO 2 N (R 102CZ6) 2, -CON (R 102CZ6) 2, -N (R 102CZ6) 2, -NHCO-R 102CZ6, - NHCO—N (R ^102CZ6 ) ₂ , —NHCOOR ^102CZ6 , or —OCON (R ^102CZ6 ) ₂ , wherein R ^101CZ6 and R ^102CZ6 have 1 to 40 carbon atoms having —SO ₃ ^— or —CO ₂ ^— . It is a hydrocarbon group or a heterocyclic group having —SO ₃ ^— or —CO ₂ ^— . However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .
(Rc-iii) a hydrocarbon group having 1 to 40 carbon atoms in which at least one of R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 and R ^14CZ6 has —SO ₃ ^— or —CO ₂ ^—. Or a heterocyclic group having —SO ₃ ^— or —CO ₂ ^— . However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .
a represents the same meaning as in formula (IZ6-B). When a plurality of a are present, they may be the same or different.
The absolute value of the negative valence that the partial structure represented by the formula (IZ6-C ′) has and the positive valence that the partial structure represented by the formula (IZ6-C ″) have are the same. ]

The ^{R 1CZ6, R 2CZ6, R 3CZ6} , R 4CZ6, R 5CZ6, R 11CZ6 and R ^14CZ6, and ^{R 1AZ6, R 2AZ6, R 3AZ6} , R 4AZ6, R 5AZ6, R AA1Z6, R AA2Z6, R 12AZ6 and R ^13AZ6 The same can be mentioned.
^{Preferred examples of} R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 and R ^14CZ6 include R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^AA2Z6 The same thing as the preferable thing of ^R13AZ6 is mentioned.

^Examples of R ^101CZ6 include the same as R ^101AZ6 .
Preferable examples of R ^101CZ6 may be the same as those preferred for R ^101AZ6.

^Examples of R ^102CZ6 include the same as R ^102AZ6 .
Preferable examples of R ^102CZ6 may be the same as those preferred for R ^102AZ6.

The hydrocarbon group and heterocyclic group having 1 to 40 carbon atoms represented by R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 , R ^14CZ6 , R ^101CZ6 and R ^102CZ6 have a substituent. It may be. The substituent has a hydrocarbon group represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. The same as the substituent which may be good. Preferred examples of the substituent include hydrocarbon groups represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. The same thing as the preferable thing of the substituent which may be carried out is mentioned.

L ¹ or L ² is preferably —CO—.

R ^11CZ6 and R ^14CZ6 are preferably the same group, and L ¹ and L ² are preferably the same group.

L ¹ and L ² are preferably —CO—.

R ^11CZ6 and R ^14CZ6 have, independently of each other, an ^optionally substituted aliphatic hydrocarbon group having 1 to 40 carbon atoms, an ^optionally substituted phenyl group, and a substituent. A naphthyl group which may have a substituent, a tetrahydronaphthyl group which may have a substituent, a thienyl group which may have a substituent, a furyl group which may have a substituent or a substituent. It is preferably a good pyridinyl group.

Such an aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a phenyl group which may have a substituent, a naphthyl group which may have a substituent, and a substituent. As the tetrahydronaphthyl group which may be substituted, the thienyl group which may have a substituent, the furyl group which may have a substituent or the pyridinyl group which may have a substituent, a compound (IZ6 -B) the above-mentioned aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a phenyl group which may have a substituent, which are listed as preferred for R ^11BZ6 in -B), A naphthyl group which may have a substituent, a tetrahydronaphthyl group which may have a substituent, a thienyl group which may have a substituent, a furyl group which may have a substituent or a substituent The same as the pyridinyl group optionally having And the like of it.

In the compound (IZ6-C), R ^1CZ6 is preferably a hydrogen atom.
R ^2CZ6 , R ^3CZ6 , R ^4CZ6 and R ^5CZ6 are independent of each other,
A hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogen atom, -N ( ^R102CZ6 ) ₂ , a nitro group, a hydrocarbon group having 1 to 20 carbon atoms in which all or part of the hydrogen atoms are substituted with fluorine atoms, ^{-NHCO-R 102CZ6, -O-R} 102CZ6, is preferably -SO ₃ M or -CO ₂ M,
It is more preferably a hydrogen atom or a nitro group. The number of nitro groups is preferably 0 to 2, more preferably 0 or 1.

R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 , R ^14CZ6 , R ^101CZ6 and R ^102CZ6 preferably satisfy at least one of (rcc-i) to (rcc-iii). , R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 , R ^14CZ6 , R ^101CZ6 and R ^102CZ6 have a total number of —SO ₃ ^— or —CO ₂ ^— of a.
(Rcc-i) At least one of R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 , and R ^14CZ6 is —SO ₃ ^— or —CO ₂ ^— .
^{(Rcc-ii) R 1CZ6,} R 2CZ6, R 3CZ6, R 4CZ6, R 5CZ6, at least one of R ^11CZ6 and R ^{14CZ6 is, -CO-R 102CZ6, -COO-} R 101CZ6, -COCO-R 102CZ6, -O _{^{-R 102CZ6, -SO 2 -R 101CZ6,}} -SO 2 N (R 102CZ6) 2, -CON (R 102CZ6) 2, -N (R 102CZ6) 2, -NHCO-N (R 102CZ6) 2, -NHCOOR 102CZ6 Or —OCON (R ^102CZ6 ) ₂ , wherein R ^101CZ6 and R ^102CZ6 are a hydrocarbon group having 1 to 40 carbon atoms having —SO ₃ ^— or —CO ₂ ^— , or —SO ₃ ^— or —CO _2. ^- a heterocyclic group having. However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .
(Rcc-iii) a hydrocarbon group having 1 to 40 carbon atoms in which at least one of R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 and R ^14C has —SO ₃ ^— or —CO ₂ ^—. Or a heterocyclic group having —SO ₃ ^— or —CO ₂ ^— . However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .

R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 , R ^14CZ6 , R ^101CZ6 and R ^102CZ6 preferably satisfy at least one of (rc-I) and (rc-II). .
(Rc-I) At least one of R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , and R ^5CZ6 is —SO ₃ ^— or —CO ₂ ^— .
(Rc-II) a hydrocarbon group having 1 to 40 carbon atoms, at least one of R ^1CZ6 , R ^11CZ6 and R ^14CZ6 may have a substituent having —SO ₃ ^— or —CO ₂ ^— , or —SO ₃ A heterocyclic group having ^— or —CO ₂ ^— ; However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .
R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 , R ^14CZ6 , R ^101CZ6 and R ^102CZ6 preferably satisfy at least one of (rcc-I) and (rcc-II). .
(Rcc-I) At least one of R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , and R ^5CZ6 is —SO ₃ ^— or —CO ₂ ^— .
(Rcc-II) At least one of R ^1CZ6 , R ^11CZ6 and R ^14CZ6 is a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent having —SO ₃ ^— or —CO ₂ ^— . However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .
However, the total number of —SO ₃ ^— or —CO ₂ ^{— contained} in R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 , R ^14CZ6 , R ^101CZ6 and R ^102CZ6 is a.

In the compound (IZ6-B), when R ^12BZ6 and R ^13BZ6 form a ring, the compound (IZ6-B) is referred to as a compound represented by the formula (IZ6-D) (hereinafter referred to as compound (IZ6-D)). In some cases).

[In the formula (IZ6-D),
A ^{c +} , b, c, d, L ¹ and the wavy line have the same meaning as described above.
R ^20DZ6 and R ^30DZ6 combine to form ring Q.
The ring Q may have a substituent and is a ring having 5 to 7 members, and the ring Q may be a hydrocarbon ring or a heterocyclic ring. Ring Q is condensed with a monocyclic ring which may have a substituent having 5 to 7 ring members selected from a hydrocarbon ring and a heterocyclic ring, or a condensed ring in which two or more of the monocyclic rings are condensed. May be.
R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 and R ^11DZ6 are each independently a hydrogen atom, —CO—R ^102DZ6 , —COO—R ^101DZ6 , —OCO—R ^102DZ6 , —COCO—R ^102DZ6 , _{^{-O-R 102DZ6, -SO 2 -R}} 101DZ6, -SO 2 N (R 102DZ6) 2, -CON (R 102DZ6) 2, -N (R 102DZ6) 2, -NHCO-R 102DZ6, -NHCO-N ( _{^{R 102DZ6) 2, -NHCOOR 102DZ6,}} -OCON (R 102DZ6) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , -SO 3 -, -CO 2 -, have a substituent The C1-C40 hydrocarbon group which may be represented, or the heterocyclic group which may have a substituent is represented.
R ^2DZ6 and R ^3DZ6 , R ^3DZ6 and R ^4DZ6 , and R ^4DZ6 and R ^5DZ6 may be bonded to each other to form a ring.
R ^101DZ6 represents, independently of each other, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102DZ6 represents, independently of each other, a hydrogen atom, an ^optionally substituted hydrocarbon group having 1 to 40 carbon atoms, or an ^optionally substituted heterocyclic group.
M represents the same meaning as described above.
Formula (IZ6-D ′) and Formula (IZ6-D ″) each represent a partial structure of Formula (IZ6-D), and A ^{c +} , b, c, d, R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 , R ^11DZ6 , R ^20DZ6 , R ^30DZ6 and L ¹ represent the same as those in formula (IZ6-D).
When there are a ^{plurality of} R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 , R ^11DZ6 , R ^101DZ6 , R ^102DZ6 , L ¹ , M, R ^20DZ6 , R ^30DZ6 , ring Q, c or A ^{c +} Each may be the same or different.
R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 , R ^11DZ6 , R ^101DZ6 , R ^102DZ6 and ring Q satisfy at least one of (rd-i) to (rd-iv), The total number of —SO ₃ ^— or —CO ₂ ^{— contained} in R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 , R ^11DZ6 , R ^101DZ6 , R ^102DZ6 and ring Q is a.
( ^Rd -i) At least one of R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 and R ^11DZ6 is —SO ₃ ^— or —CO ₂ ^— .
( ^Rd -ii) At least one of ^R1DZ6 , ^R2DZ6 , ^R3DZ6 , ^R4DZ6 , ^R5DZ6 and ^R11DZ6 is -CO- ^R102DZ6 , -COO- ^R101DZ6 , -OCO- ^R102DZ6 , -COCO- ^R102DZ6 , -O-R ^102DZ6 , -SO ₂ -R ^101DZ6 , -SO ₂ N (R ^102DZ6 ) ₂ , ^-CON (R ^102DZ6 ) ₂ , -N (R ^102DZ6 ) ₂ , -NHCO-R ^102DZ6 , -NHCO-N (R ^102DZ6 ) ₂ , —NHCOOR ^102DZ6 , or —OCON (R ^102DZ6 ) ₂ , wherein R ^101DZ6 and R ^102DZ6 are hydrocarbon groups having 1 to 40 carbon atoms having —SO ₃ ^— or —CO ₂ ^—. Or a heterocyclic group having —SO ₃ ^— or —CO ₂ ^— . However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .
( ^Rd -iii) a hydrocarbon group having 1 to 40 carbon atoms in which at least one of R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 and R ^11DZ6 has —SO ₃ ^— or —CO ₂ ^— , or —SO ₃ ^- or -CO ₂ ^- I am a heterocyclic group having. However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .
(Rd-iv) Ring Q has —SO ₃ ^— or —CO ₂ ^— a represents the same meaning as in formula (IZ6-B). When a plurality of a are present, they may be the same or different.
The absolute value of the negative valence of the partial structure represented by the formula (IZ6-D ′) and the positive valence of the partial structure represented by the formula (IZ6-D ″) are the same. ]

The number of members of the ring is preferably 5-6.
These monocycles or condensed rings are preferably bonded to the ring Q at two positions to form a condensed ring.
Examples of the ring Q and a ring obtained by condensing a single ring or condensed ring thereon include the same groups as those in the group A.
Among these, Preferably a formula (Q1), a formula (Q4), a formula (Q7), a formula (Q8), and a formula (Q18) are mentioned, More preferably, a formula (Q8) and a formula (Q18) are mentioned.

The ring Q and the monocyclic ring which is selected from hydrocarbon rings and heterocyclic rings which may be condensed to the ring Q and may have a substituent having 5 to 7 ring members, or two or more of the monocyclic rings The condensed ring condensed with may have a substituent. The substituent has a hydrocarbon group represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. The same as the substituent which may be good.
Preferred examples of the substituent include hydrocarbon groups represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. The same thing as the preferable thing of the substituent which may be carried out is mentioned.

R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 and R ^11DZ6 include R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 and R ^13AZ6. Can be mentioned.
^{Preferred examples of} R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 and R ^11DZ6 include R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 and R ^12AZ6 and R ¹³ The same thing as a preferable thing is mentioned.

^Examples of R ^101DZ6 include the same as R ^101AZ6 .
Preferable examples of R ^101DZ6 may be the same as those preferred for R ^101AZ6.

^Examples of R ^102DZ6 include the same as R ^102AZ6 .
Preferable examples of R ^102DZ6 may be the same as those preferred for R ^102AZ6.

The hydrocarbon group and heterocyclic group having 1 to 40 carbon atoms represented by R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 , R ^11DZ6 , R ^101DZ6 and R ^102DZ6 may have a substituent. Good. The substituent has a hydrocarbon group represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. The same as the substituent which may be good. Preferred examples of the substituent include hydrocarbon groups represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. The same thing as the preferable thing of the substituent which may be carried out is mentioned.

L ¹ is preferably —CO—.

R ^11DZ6 may have, independently of each other, an ^optionally substituted aliphatic hydrocarbon group having 1 to 40 carbon atoms, an ^optionally substituted phenyl group, and an ^optionally substituted group. A naphthyl group, an optionally substituted tetrahydronaphthyl group, an optionally substituted thienyl group, an optionally substituted furyl group or an optionally substituted pyridinyl It is preferably a group.

Such an aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a phenyl group which may have a substituent, a naphthyl group which may have a substituent, and a substituent. As the tetrahydronaphthyl group which may be substituted, the thienyl group which may have a substituent, the furyl group which may have a substituent or the pyridinyl group which may have a substituent, a compound (IZ6 -B) the above-mentioned aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a phenyl group which may have a substituent, which are listed as preferred for R ^11BZ6 in -B), A naphthyl group which may have a substituent, a tetrahydronaphthyl group which may have a substituent, a thienyl group which may have a substituent, a furyl group which may have a substituent or a substituent The same as the pyridinyl group optionally having And the like of it.

In the compound (IZ6-D), R ^1DZ6 is preferably a hydrogen atom.
R ^2DZ6 , R ^3DZ6 , R ^4DZ6 and R ^5DZ6 are independent of each other,
A hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogen atom, -N (R ^102DZ6 ) ₂ , a nitro group, a hydrocarbon group having 1 to 20 carbon atoms in which all or part of the hydrogen atoms are substituted by fluorine atoms, -NHCO-R ^102DZ6 , -O-R ^102DZ6 , -SO ₃ M or -CO ₂ M is preferred,
It is more preferably a hydrogen atom or a nitro group. The number of nitro groups is preferably 0 to 2, more preferably 0 or 1.

R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 , R ^11DZ6 , R ^101DZ6 , R ^102DZ6 and ring Q preferably satisfy at least one of (rdd-i) to (rdd-iv). , R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 , R ^11DZ6 , R ^101DZ6 , R ^102DZ6 and —SO ₃ ^— or —CO ₂ ^{— in} the ring Q is a.
( ^Rdd -i) At least one of R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 and R ^11DZ6 is —SO ₃ ^— or —CO ₂ ^— .
^{(Rdd-ii) R 1DZ6,} R 2DZ6, R 3DZ6, R 4DZ6, at least one of R ^5DZ6 and R ^{11DZ6 is, -CO-R 102DZ6, -COO-} R 101DZ6, -O-R 102DZ6, -SO 2 -R _{^{101DZ6, -SO 2 N (R 102DZ6}} ) 2, -CON (R 102DZ6) 2 or -N (R ^102DZ6) a _2, wherein R ^101DZ6 and R ^102DZ6 is, -SO ₃ ^- having ^- or -CO ₂ A hydrocarbon group having 1 to 40 carbon atoms or a heterocyclic group having —SO ₃ ^— or —CO ₂ ^— . However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .
( ^Rdd -iii) a hydrocarbon group having 1 to 40 carbon atoms in which at least one of R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 and R ^11DZ6 has —SO ₃ ^— or —CO ₂ ^— , or —SO ₃ ^- or -CO ₂ ^- it is a heterocyclic group having. However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .
(Rdd-iv) Ring Q has —SO ₃ ^— or —CO ₂ ^— .

  The compound (IZ6-D) is more preferably a compound represented by the formula (IZ6-E) (hereinafter sometimes referred to as the compound (IZ6-E)).

[In the formula (IZ6-E),
A ^{c +} , b, c, d, L ¹ and the wavy line have the same meaning as described above.
R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 and R ^11EZ6 are each independently a hydrogen atom, -CO-R ^102EZ6 , -COO-R ^101EZ6 , -OCO-R ^102EZ6 , ^{-COCO-R 102EZ6, -O-R} 102EZ6, -SO 2 -R 101EZ6, -SO 2 N (R 102EZ6) 2, -CON (R 102EZ6) 2, -N (R 102EZ6) 2, -NHCO-R 102EZ6 , —NHCO—N (R ^102EZ6 ) ₂ , —NHCOOR ^102EZ6 , —OCON (R ^102EZ6 ) ₂ , halogen atom, cyano group, nitro group, —SO ₃ M, —CO ₂ M, —SO ₃ ⁻ , —CO ₂ ^- represents a hydrocarbon group or optionally substituted heterocyclic group having carbon atoms of 1 to 40 which may have a substituent.
R ^2EZ6 and R ^3EZ6 , R ^3EZ6 and R ^4EZ6 , and R ^4EZ6 and R ^5EZ6 may be bonded to each other to form a ring.
R ^101EZ6 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent, independently of each other.
R ^102EZ6 represents, independently of each other, a hydrogen atom, an ^optionally substituted hydrocarbon group having 1 to 40 carbon atoms, or an ^optionally substituted heterocyclic group.
M represents the same meaning as described above.
Formula (IZ6-E ′) and Formula (IZ6-E ″) each represent a partial structure of Formula (IZ6-E), and A ^{c +} , b, c, d, R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 , R ^11EZ6 and L ¹ represent the same as those in formula (IZ6-E).
When there are a ^{plurality of} R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 , R ^11EZ6 , R ^101EZ6 , R ^102EZ6 , L ¹ , M, c or A ^{c +} , they are the same May be different or different.
^R1EZ6 , ^R2EZ6 , ^R3EZ6 , ^R4EZ6 , ^R5EZ6 , ^R6EZ6 , ^R7EZ6 , ^R11EZ6 , ^R101EZ6, and ^R102EZ6 satisfy at least one of (re-i) to (re-iii) The total number of —SO ₃ ^— or —CO ₂ ^{— contained} in R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 , R ^11EZ6 , R ^101EZ6 and R ^102EZ6 is a. .
(Re-i) At least one of R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 and R ^11EZ6 is —SO ₃ ^— or —CO ₂ ^— .
(Re-ii) At least one of R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 and R ^11EZ6 is -CO-R ^102EZ6 , -COO-R ^101EZ6 , -OCO-R ^{102EZ6 , -COCO-R 102EZ6, -O-} R 102EZ6, -SO 2 -R 101EZ6, -SO 2 N (R 102EZ6) 2, -CON (R 102EZ6) 2, -N (R 102EZ6) 2, -NHCO-R ^{102EZ6, -NHCO-N (R 102EZ6} ) 2, -NHCOOR 102EZ6, or -OCON a (R ^102EZ6) _2, wherein R ^101EZ6 and R ^102EZ6 is, -SO ₃ ^- or -CO ₂ ^- carbons having 1 It is a heterocyclic group having ˜40 hydrocarbon groups or —SO ₃ ^— or —CO ₂ ^— . However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .
(Re-iii) at least one of R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 and R ^11EZ6 has 1 to 40 carbon atoms having —SO ₃ ^— or —CO ₂ ^— . It is a hydrocarbon group or a heterocyclic group having —SO ₃ ^— or —CO ₂ ^— . However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .
a represents the same meaning as in formula (IZ6-D). When a plurality of a are present, they may be the same or different.
The absolute value of the negative valence of the partial structure represented by the formula (IZ6-E ′) and the positive valence of the partial structure represented by the formula (IZ6-E ″) are the same. ]

R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 and R ^11EZ6 are R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^A2Z6 , R ^A2Z6 The same thing as ^R13AZ6 is mentioned.
^{Preferred examples of} R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 and R ^11EZ6 include R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA1Z6 The same thing as the preferable thing of ^R12AZ6 and ^R13AZ6 is mentioned.

R ^6EZ6 and R ^7EZ6 are each independently a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, a tert-butyl group, a pentyl group, a hexyl group, a (2-ethyl) hexyl group, a heptyl group, or an octyl group. , A non-yl group, a cyclohexyl group, a phenyl group or the like, or a hydrocarbon group having 1 to 10 carbon atoms or a hydrogen atom.

^Examples of R ^101EZ6 include the same as R ^101AZ6 .
Preferable examples of R ^101EZ6 may be the same as those preferred for R ^101AZ6.

^Examples of R ^102EZ6 include the same as R ^102AZ6 .
Preferable examples of R ^102EZ6 may be the same as those preferred for R ^102AZ6.

The hydrocarbon group and heterocyclic group having 1 to 40 carbon atoms represented by R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 , R ^11EZ6 , R ^101EZ6 and R ^102EZ6 are substituents. You may have. The substituent has a hydrocarbon group represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. The same as the substituent which may be good. Preferred examples of the substituent include hydrocarbon groups represented by R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6. The same thing as the preferable thing of the substituent which may be carried out is mentioned.

L ¹ is preferably —CO—.

R ^11EZ6 may have, independently of each other, an ^optionally substituted aliphatic hydrocarbon group having 1 to 40 carbon atoms, an ^optionally substituted phenyl group, or an ^optionally substituted group. A naphthyl group, an optionally substituted tetrahydronaphthyl group, an optionally substituted thienyl group, an optionally substituted furyl group or an optionally substituted pyridinyl It is preferably a group.

Such an aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a phenyl group which may have a substituent, a naphthyl group which may have a substituent, and a substituent. As the tetrahydronaphthyl group which may be substituted, the thienyl group which may have a substituent, the furyl group which may have a substituent or the pyridinyl group which may have a substituent, a compound (IZ6 -B) the above-mentioned aliphatic hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, a phenyl group which may have a substituent, which are listed as preferred for R ^11BZ6 in -B), A naphthyl group which may have a substituent, a tetrahydronaphthyl group which may have a substituent, a thienyl group which may have a substituent, a furyl group which may have a substituent or a substituent The same as the pyridinyl group optionally having And the like of it.

In the compound (IZ6-E), R ^1EZ6 is preferably a hydrogen atom.
R ^2EZ6 , R ^3EZ6 , R ^4EZ6 and R ^5EZ6 are independent of each other,
A hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogen atom, —N (R ^102EZ6 ) ₂ , a nitro group, a hydrocarbon group having 1 to 20 carbon atoms in which all or part of the hydrogen atoms are substituted by fluorine atoms, ^{-NHCO-R 102EZ6, -O-R} 102EZ6, is preferably -SO ₃ M or -CO ₂ M,
It is more preferably a hydrogen atom or a nitro group. The number of nitro groups is preferably 0 to 2, more preferably 0 or 1.

^R1EZ6 , ^R2EZ6 , ^R3EZ6 , ^R4EZ6 , ^R5EZ6 , ^R6EZ6 , ^R7EZ6 , ^R11EZ6 , ^R101EZ6 and ^R102EZ6 satisfy at least one of (ree-i) to (ree-iii). R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 , R ^11EZ6 , R ^101EZ6 and R ^102EZ6 have a total number of —SO ₃ ^— or —CO ₂ ^— of a. is there.
( ^Ree -i) At least one of R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 and R ^11EZ6 is —SO ₃ ^— or —CO ₂ ^— .
( ^Ree -ii) At least one of R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 and R ^11EZ6 is -CO-R ^102EZ6 , -COO-R ^101EZ6 , -O-R ^102EZ6 , -SO ₂ -R ^101EZ6 , -SO ₂ N (R ^102EZ6 ) ₂ , ^-CON (R ^102EZ6 ) ₂ or -N (R ^102EZ6 ) ₂ , wherein R ^101EZ6 and R ^102EZ6 are -SO ₃ ^- or -CO ₂ ^- 1 to 40 carbon atoms having a hydrocarbon group or a -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .
( ^Ree -iii) at least one of R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 and R ^11EZ6 has 1 to 40 carbon atoms having —SO ₃ ^— or —CO ₂ ^— . It is a hydrocarbon group or a heterocyclic group having —SO ₃ ^— or —CO ₂ ^— . However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .

Specific examples of compound (IZ6) include, for example, compounds (IFZ6-1) to (IFZ6) shown in Tables 1Z6 to 4Z6 in formula (IFZ6), formula (IGZ6), formula (IHZ6) and formula (IJZ6). -32), compound (IGZ6-1) to compound (IGZ6-32), compound (IHZ6-1) to compound (IHZ6-32), and compound (IJZ6-1) to compound (IJZ6-32).
In the formula (IFZ6), the formula (IGZ6), the formula (IHZ6), and the formula (IJZ6), “-SO ₃ ⁻ ” represents that each of hydrogen atoms contained in the partial structure in parentheses is substituted. Shall mean.

  For example, the compound (IFZ6-1) is a compound represented by the formula (IFZ6-1).

As the compound (IZ6),
Compound (IFZ6-1) to Compound (IFZ6-4), Compound (IFZ6-6) to Compound (IFZ6-7), Compound (IFZ6-10) to Compound (IFZ6-13), Compound (IFZ6-15) to Compound (IFZ6-19), compound (IFZ6-21) to compound (IFZ6-22), compound (IFZ6-25) to compound (IFZ6-28) and compound (IFZ6-30) to compound (IFZ6-32);
Compound (IGZ6-1) to Compound (IGZ6-4), Compound (IGZ6-6) to Compound (IGZ6-7), Compound (IGZ6-10) to Compound (IGZ6-13), Compound (IGZ6-15) to Compound (IGZ6-19), compound (IGZ6-21) to compound (IGZ6-22), compound (IGZ6-25) to compound (IGZ6-28) and compound (IGZ6-30) to compound (IGZ6-32);
Compound (IHZ6-1) to Compound (IHZ6-4), Compound (IHZ6-6) to Compound (IHZ6-7), Compound (IHZ6-10) to Compound (IHZ6-13), Compound (IHZ6-15) to Compound (IHZ6-19), Compound (IHZ6-21) to Compound (IHZ6-22), Compound (IHZ6-25) to Compound (IHZ6-28) and Compound (IHZ6-30) to Compound (IHZ6-32); and Compound (IJZ6-1) to compound (IJZ6-4), compound (IJZ6-6) to compound (IJZ6-7), compound (IJZ6-10) to compound (IJZ6-13), compound (IJZ6-15) to compound ( IJZ6-19), compound (IJZ6-21) to compound (IJZ6-22), compound (IJZ6-25) to compound (IJZ6-28) And compound (IJZ6-30) to compound (IJZ6-32) are preferred,
Compound (IFZ6-1) to Compound (IFZ6-4), Compound (IFZ6-6) to Compound (IFZ6-7), Compound (IFZ6-10) to Compound (IFZ6-13), Compound (IFZ6-15) to Compound (IFZ6-19), compound (IFZ6-21) to compound (IFZ6-22), compound (IFZ6-25) to compound (IFZ6-28) and compound (IFZ6-30);
Compound (IGZ6-1) to Compound (IGZ6-4), Compound (IGZ6-6) to Compound (IGZ6-7), Compound (IGZ6-10) to Compound (IGZ6-13), Compound (IGZ6-15) to Compound (IGZ6-19), compound (IGZ6-21) to compound (IGZ6-22), compound (IGZ6-25) to compound (IGZ6-28) and compound (IGZ6-30);
Compound (IHZ6-1) to Compound (IHZ6-4), Compound (IHZ6-6) to Compound (IHZ6-7), Compound (IHZ6-10) to Compound (IHZ6-13), Compound (IHZ6-15) to Compound (IHZ6-19), Compound (IHZ6-21) to Compound (IHZ6-22), Compound (IHZ6-25) to Compound (IHZ6-28) and Compound (IHZ6-30); and Compound (IJZ6-1) to Compound (IJZ6-4), Compound (IJZ6-6) to Compound (IJZ6-7), Compound (IJZ6-10) to Compound (IJZ6-13), Compound (IJZ6-15) to Compound (IJZ6-19), Compound ( IJZ6-21) to compound (IJZ6-22), compound (IJZ6-25) to compound (IJZ6-28) and compound (IJZ6-30) ) Is more preferable,
Compound (IFZ6-1) to Compound (IFZ6-4), Compound (IFZ6-6) to Compound (IFZ6-7), Compound (IFZ6-10) to Compound (IFZ6-13), Compound (IFZ6-15) to Compound (IFZ6-19), Compound (IFZ6-21) to Compound (IFZ6-22), Compound (IFZ6-25) to Compound (IFZ6-28) and Compound (IFZ6-30); and Compound (IJZ6-1) to Compound (IJZ6-4), Compound (IJZ6-6) to Compound (IJZ6-7), Compound (IJZ6-10) to Compound (IJZ6-13), Compound (IJZ6-15) to Compound (IJZ6-19), Compound ( IJZ6-21) to compound (IJZ6-22), compound (IJZ6-25) to compound (IJZ6-28) and compound (IJZ6-30) Is more preferable.

As the compound (IZ6), in the formula (IZ6-C),
L ¹ and L ² are the same group, —CO— or —SO ₂ —, preferably —CO—,
R ^11CZ6 and R ^14CZ6 are the same group, and are a hydroxy group, —O ⁻ , or a substituent selected from the group consisting of —SO ₃ ⁻ , —CO ₂ ⁻ , —SO ₃ M and —CO ₂ M. A hydrocarbon group having 1 to 20 carbon atoms that may have,
R ^1CZ6 is a carbon atom having 1 to 20 carbon atoms which may have a hydrogen atom or a substituent selected from the group consisting of —SO ₃ ⁻ , —CO ₂ ⁻ , —SO ₃ M and —CO ₂ M. A hydrogen group, —SO ₃ ⁻ , —CO ₂ ⁻ , —SO ₃ M or —CO ₂ M;
R ^{2CZ6 to} R ^5CZ6 are each independently a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogen atom, —N (R ^102CZ6 ) ₂ , a nitro group, or a hydrogen atom, or a fluorine atom. A substituted hydrocarbon group having 1 to 20 carbon atoms, —NHCO—R ^102CZ6 , —O—R ^102CZ6 , —SO ₃ ⁻ , —CO ₂ ⁻ , —SO ₃ M or —CO ₂ M;
R ^102CZ6 is a carbon atom having 1 to 20 carbon atoms which may have a hydrogen atom or a substituent selected from the group consisting of —SO ₃ ⁻ , —CO ₂ ⁻ , —SO ₃ M and —CO ₂ M. A hydrogen group,
A ^{c +} is Mg ²⁺ , Ca ²⁺ , Sr ²⁺ , Ba ²⁺ , Cd ²⁺ , Ni ²⁺ , Zn ²⁺ , Cu ²⁺ , Hg ²⁺ , Fe ²⁺ , Co ²⁺ , Sn ^2. Divalent metal cations such as ⁺ , Pb ²⁺ and Mn ²⁺ , trivalent metal cations such as Al ³⁺ , Fe ³⁺ and Cr ^3+, and tetravalent metal cations such as Sn ⁴⁺ and Mn ⁴⁺ A metal cation,
M is preferably a compound that is a hydrogen atom or an alkali metal atom,
L ¹ and L ² are the same group, —CO— or —SO ₂ —, preferably —CO—,
R ^11CZ6 and R ^14CZ6 are the same group, and are a hydroxy group, —O ⁻ , or a substituent selected from the group consisting of —SO ₃ ⁻ , —CO ₂ ⁻ , —SO ₃ M and —CO ₂ M. A hydrocarbon group having 1 to 10 carbon atoms that may have,
R ^1CZ6 is a hydrogen atom,
R ^{2CZ6 to} R ^5CZ6 are each independently a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, —N (R ^102CZ6 ) ₂ , a nitro group, or a hydrogen atom, all or part of which is a fluorine atom. substituted hydrocarbon group having 1 to 10 carbon ^{atoms, -NHCO-R 102CZ6, -O-} R 102CZ6, -SO 3 -, -CO 2 -, a -SO ₃ M or -CO ₂ M,
R ^102CZ6 is a carbon atom having 1 to 10 carbon atoms which may have a hydrogen atom or a substituent selected from the group consisting of —SO ₃ ⁻ , —CO ₂ ⁻ , —SO ₃ M and —CO ₂ M. A hydrogen group,
A ^{c +} is Mg ²⁺ , Ca ²⁺ , Sr ²⁺ , Ba ²⁺ , Ni ²⁺ , Zn ²⁺ , Cu ²⁺ , Fe ²⁺ , Co ²⁺ , Sn ²⁺ , Mn ²⁺ , Al ^{3 +} , Fe ³⁺ , Cr ³⁺ , Sn ⁴⁺ or Mn ⁴⁺
M is more preferably a compound that is a hydrogen atom or an alkali metal atom,
L ¹ and L ² are the same group, —CO— or —SO ₂ —, preferably —CO—,
R ^11CZ6 and R ^14CZ6 are the same group, and are a hydroxy group, —O ⁻ , or a substituent selected from the group consisting of —SO ₃ ⁻ , —CO ₂ ⁻ , —SO ₃ M and —CO ₂ M. A hydrocarbon group having 1 to 10 carbon atoms that may have,
R ^1CZ6 is a hydrogen atom,
R ^{2CZ6 to} R ^5CZ6 are each independently a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, —N (R ^102CZ6 ) ₂ , a nitro group, a trifluoromethyl group, —O—R ^102CZ6 , -SO ₃ ^-, -CO ₂ ^-, a -SO ₃ M or -CO ₂ M,
R ^102CZ6 is a carbon atom having 1 to 10 carbon atoms which may have a hydrogen atom or a substituent selected from the group consisting of —SO ₃ ⁻ , —CO ₂ ⁻ , —SO ₃ M and —CO ₂ M. A hydrogen group,
A ^{c +} is Mg ²⁺ , Ca ²⁺ , Sr ²⁺ , Ba ²⁺ , Zn ²⁺ , Cu ²⁺ , Fe ²⁺ , Mn ²⁺ , Al ³⁺ , Fe ³⁺ , Cr ³⁺ or Mn ^{4 +}
A compound in which M is a hydrogen atom or an alkali metal atom is more preferable.

As the compound (IZ6), in the formula (IZ6-E),
L ¹ is —CO— or —SO ₂ —, preferably —CO—.
R ^11EZ6 may have a substituent selected from the group consisting of a hydroxy group, —O ⁻ , or —SO ₃ ⁻ , —CO ₂ ⁻ , —SO ₃ M, and —CO ₂ M. ~ 20 hydrocarbon groups,
R ^1EZ6 is a carbon atom having 1 to 20 carbon atoms which may have a hydrogen atom or a substituent selected from the group consisting of —SO ₃ ⁻ , —CO ₂ ⁻ , —SO ₃ M and —CO ₂ M. A hydrogen group, —SO ₃ ⁻ , —CO ₂ ⁻ , —SO ₃ M or —CO ₂ M;
R ^{2EZ6 to} R ^5EZ6 are each independently a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogen atom, —N (R ^102EZ6 ) ₂ , a nitro group, or a hydrogen atom, all or part of which is a fluorine atom. A substituted hydrocarbon group having 1 to 20 carbon atoms, —NHCO—R ^102EZ6 , —O—R ^102EZ6 , —SO ₃ ⁻ , —CO ₂ ⁻ , —SO ₃ M or —CO ₂ M;
R ^102EZ6 represents a hydrogen atom or a carbon atom having 1 to 20 carbon atoms which may have a substituent selected from the group consisting of —SO ₃ ⁻ , —CO ₂ ⁻ , —SO ₃ M and —CO ₂ M. A hydrogen group,
R ^6EZ6 and R ^7EZ6 may each independently have a hydrogen atom or a substituent selected from the group consisting of —SO ₃ ⁻ , —CO ₂ ⁻ , —SO ₃ M and —CO ₂ M. A hydrocarbon group having 1 to 20 carbon atoms, —SO ₃ ⁻ , —CO ₂ ⁻ , —SO ₃ M or —CO ₂ M;
A ^{c +} is Mg ²⁺ , Ca ²⁺ , Sr ²⁺ , Ba ²⁺ , Cd ²⁺ , Ni ²⁺ , Zn ²⁺ , Cu ²⁺ , Hg ²⁺ , Fe ²⁺ , Co ²⁺ , Sn ^2. Divalent metal cations such as ⁺ , Pb ²⁺ and Mn ²⁺ , trivalent metal cations such as Al ³⁺ , Fe ³⁺ and Cr ^3+, and tetravalent metal cations such as Sn ⁴⁺ and Mn ⁴⁺ A metal cation,
M is preferably a compound that is a hydrogen atom or an alkali metal atom,
L ¹ is —CO— or —SO ₂ —, preferably —CO—.
R ^11EZ6 may have a substituent selected from the group consisting of a hydroxy group, —O ⁻ , or —SO ₃ ⁻ , —CO ₂ ⁻ , —SO ₃ M, and —CO ₂ M. 10 hydrocarbon groups,
R ^1EZ6 is a hydrogen atom,
R ^{2EZ6 to} R ^5EZ6 are each independently a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, —N (R ^102EZ6 ) ₂ , a nitro group, or a hydrogen atom, all or part of which is a fluorine atom. A substituted hydrocarbon group having 1 to 10 carbon atoms, —NHCO—R ^102EZ6 , —O—R ^102EZ6 , —SO ₃ ⁻ , —CO ₂ ⁻ , —SO ₃ M or —CO ₂ M;
R ^102EZ6 is a carbon atom having 1 to 10 carbon atoms which may have a hydrogen atom or a substituent selected from the group consisting of —SO ₃ ⁻ , —CO ₂ ⁻ , —SO ₃ M and —CO ₂ M. A hydrogen group,
R ^6EZ6 and R ^7EZ6 may each independently have a hydrogen atom or a substituent selected from the group consisting of —SO ₃ ⁻ , —CO ₂ ⁻ , —SO ₃ M and —CO ₂ M. A hydrocarbon group having 1 to 10 carbon atoms,
A ^{c +} is Mg ²⁺ , Ca ²⁺ , Sr ²⁺ , Ba ²⁺ , Ni ²⁺ , Zn ²⁺ , Cu ²⁺ , Fe ²⁺ , Co ²⁺ , Sn ²⁺ , Mn ²⁺ , Al ^{3 +} , Fe ³⁺ , Cr ³⁺ , Sn ⁴⁺ or Mn ⁴⁺
M is more preferably a compound that is a hydrogen atom or an alkali metal atom,
L ¹ is —CO— or —SO ₂ —, preferably —CO—.
R ^11EZ6 may have a substituent selected from the group consisting of a hydroxy group, —O ⁻ , or —SO ₃ ⁻ , —CO ₂ ⁻ , —SO ₃ M, and —CO ₂ M. 10 hydrocarbon groups,
R ^1EZ6 is a hydrogen atom,
R ^{2EZ6 to} R ^5EZ6 are each independently a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, —N (R ^102EZ6 ) ₂ , a nitro group, a trifluoromethyl group, —O—R ^102EZ6 , -SO ₃ ^-, -CO ₂ ^-, a -SO ₃ M or -CO ₂ M,
R ^102EZ6 is a carbon atom having 1 to 10 carbon atoms which may have a hydrogen atom or a substituent selected from the group consisting of —SO ₃ ⁻ , —CO ₂ ⁻ , —SO ₃ M and —CO ₂ M. A hydrogen group,
R ^6EZ6 and R ^7EZ6 are each independently a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms,
A ^{c +} is Mg ²⁺ , Ca ²⁺ , Sr ²⁺ , Ba ²⁺ , Zn ²⁺ , Cu ²⁺ , Fe ²⁺ , Mn ²⁺ , Al ³⁺ , Fe ³⁺ , Cr ³⁺ or Mn ^{4 +}
A compound in which M is a hydrogen atom or an alkali metal atom is more preferable.

  The compound represented by the formula (IZ6) can be produced by reacting the compound represented by the formula (JZ6) with the compound represented by the formula (KZ6). However, the compound represented by the formula (JZ6) and the compound represented by the formula (KZ6) can each be used alone or in combination of two or more.

[In formula (JZ6), formula (KZ6) and formula (IZ6),
a, b, c, d, D, Z and A ^{c +} have the same meaning as described above.
ZZ represents -SO ₃ M or -CO ₂ M.
M has the same meaning as described above.
MM represents a compound containing a metal in which 0 to c electrons are given to A ^{c +} .
When there are a plurality of compounds represented by formula (JZ6), D, ZZ, a, MM, and M, they may be the same or different. ]

As the compound represented by the formula (KZ6),
Inorganic compounds such as chlorides, bromides, iodides, sulfates, nitrates, fluorosulfonates, phosphates, and the like, containing a metal having 0 to c electrons given to A ^{c +} ;
Sulfonates such as methanesulfonate, trifluoromethanesulfonate, p-toluenesulfonate, and the like, containing a metal having 0 to c electrons given to A ^{c +} ;
Carboxylates such as acetates, citrates, formates, gluconates, lactates, oxalates, tartrates, etc., containing metals that have given 0 to c electrons in A ^{c +} ;
A metal in which an alkoxy group such as a methoxy group, an ethoxy group, or a tert-butoxy group is substituted, and A ^{c +} is given 0 or more and c or less electrons;
A metal substituted with 0 to c electrons in A ^{c +} substituted by a butyl group, a tert-butyl group, a phenyl group, or the like;
Examples thereof include metals substituted with a hydroxy group and having 0 to c electrons given to A ^{c +} .

  The usage-amount of the compound represented by a formula (KZ6) is 0.05-20 mol normally with respect to 1 mol of compounds represented by a formula (JZ6), 0.06-15 mol is preferable, 0.1 10 mol is more preferable.

  When the compound represented by the formula (JZ6) and the compound represented by the formula (KZ6) are reacted, it is preferable that a base coexists. Bases include organic bases such as triethylamine, 4- (N, N-dimethylamino) pyridine, pyridine, piperidine, metal alkoxides such as sodium methoxide, sodium ethoxide, sodium tert-butoxide, potassium tert-butoxide, butyllithium Organic metal compounds such as tert-butyllithium and phenyllithium, and inorganic bases such as lithium hydroxide, sodium hydroxide and potassium hydroxide.

  The amount of the base to be used is generally 0.0001 to 10 mol, preferably 0.0001 to 8 mol, more preferably 0.0001 to 5 mol, per 1 mol of the compound represented by the formula (JZ6), 0 0.0001 to 4 mol is more preferable.

The reaction of the compound represented by the formula (JZ6) and the compound represented by the formula (KZ6) is usually performed in the presence of a solvent.
Solvents include water; nitrile solvents such as acetonitrile; alcohol solvents such as methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol and 1-octanol; ether solvents such as tetrahydrofuran; ketone solvents such as acetone; Ester solvents such as ethyl; aliphatic hydrocarbon solvents such as hexane; aromatic hydrocarbon solvents such as toluene; halogenated hydrocarbon solvents such as methylene chloride and chloroform; amides such as N, N-dimethylformaldehyde and N-methylpyrrolidone And sulfoxide solvents such as dimethyl sulfoxide, preferably water, nitrile solvent, alcohol solvent, ether solvent, ketone solvent, ester solvent, aromatic hydrocarbon solvent, halogenated hydrocarbon solvent, amide solvent, and sulfoxide Solvent More preferably, water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, tetrahydrofuran, acetone, ethyl acetate, toluene, methylene chloride, chloroform, N, N-dimethyl Formaldehyde, N-methylpyrrolidone and dimethyl sulfoxide, and more preferably water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, acetone, methylene chloride, chloroform, N, N-dimethylformaldehyde, N-methylpyrrolidone and dimethylsulfoxide are mentioned, and water, acetonitrile, methanol, ethanol and 2-propanol are particularly preferable.
The usage-amount of a solvent is 1-1000 mass parts normally with respect to 1 mass part of compounds represented by a formula (JZ6).

  The reaction temperature of the compound represented by the formula (JZ6) and the compound represented by the formula (KZ6) is usually -20 to 200 ° C, preferably -10 to 100 ° C, more preferably 0 to 50 ° C. It is. The reaction time is usually 0.5 to 300 hours.

  When the compound represented by the formula (IZ6) is a compound represented by the formula (IZ6-A), it can be produced in the same manner as described above. Specifically, it can be produced by reacting a compound represented by the formula (JJZ6) with a compound represented by the formula (KZ6). However, the compound represented by the formula (JJZ6) and the compound represented by the formula (KZ6) can each be used alone or in combination of two or more.

［式（ＪＪＺ６）、式（ＫＺ６）及び式（ＩＺ６−Ａ）中、
Ａ^c+、ｂ、ｃ、ｄ、Ｒ^1AZ6、Ｒ^2AZ6、Ｒ^3AZ6、Ｒ^4AZ6、Ｒ^5AZ6、Ｒ^AA1Z6、Ｒ^AA2Z6、Ｒ^12AZ6、Ｒ^13AZ6及び波線は、前記と同じ意味を表す。
Ｒ^1AAZ6、Ｒ^2AAZ6、Ｒ^3AAZ6、Ｒ^4AAZ6、Ｒ^5AAZ6、Ｒ^AAA1Z6、Ｒ^AAA2Z6、Ｒ^12AAZ6及びＲ^13AAZ6は、互いに独立に、水素原子、−ＣＯ−Ｒ^102AAZ6、−ＣＯＯ−Ｒ^101AAZ6、−ＯＣＯ−Ｒ^102AAZ6、−Ｏ−Ｒ^102AAZ6、−ＳＯ₂−Ｒ^101AAZ6、−ＳＯ₂Ｎ（Ｒ^102AAZ6）₂、−ＣＯＮ（Ｒ^102AAZ6）₂、−Ｎ（Ｒ^102AAZ6）₂、−ＮＨＣＯ−Ｒ^102AAZ6、ハロゲン原子、シアノ基、ニトロ基、−ＳＯ₃Ｍ、−ＣＯ₂Ｍ、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^2AAZ6とＲ^3AAZ6、Ｒ^3AAZ6とＲ^4AAZ6、Ｒ^4AAZ6とＲ^5AZ6、Ｒ^AAA1Z6とＲ^AAA2Z6及びＲ^12AAZ6とＲ^13AAZ6は、それぞれ互いに結合して環を形成してもよい。
Ｒ^101AAZ6は、互いに独立に、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｒ^102AAZ6は、互いに独立に、水素原子、置換基を有していてもよい炭素数１〜４０の炭化水素基又は置換基を有していてもよい複素環基を表す。
Ｍは、前記と同じ意味を表す。
Ｒ^1AAZ6、Ｒ^2AAZ6、Ｒ^3AAZ6、Ｒ^4AAZ6、Ｒ^5AAZ6、Ｒ^AAA1Z6、Ｒ^AAA2Z6、Ｒ^12AAZ6、Ｒ^13AAZ6、Ｒ^101AAZ6、Ｒ^102AAZ6又はＭが複数存在する場合、それらは同一であってもよく、異なっていてもよい。
Ｒ^1AAZ6、Ｒ^2AAZ6、Ｒ^3AAZ6、Ｒ^4AAZ6、Ｒ^5AAZ6、Ｒ^AAA1Z6、Ｒ^AAA2Z6、Ｒ^12AAZ6、Ｒ^13AAZ6、Ｒ^101AAZ6及びＲ^102AAZ6は、（ｊ−ｉ）〜（ｊ−ｉｉｉ）のうち少なくとも１つを充足しており、Ｒ^1AAZ6、Ｒ^2AAZ6、Ｒ^3AAZ6、Ｒ^4AAZ6、Ｒ^5AAZ6、Ｒ^AAA1Z6、Ｒ^AAA2Z6、Ｒ^12AAZ6、Ｒ^13AAZ6、Ｒ^101AAZ6及びＲ^102AAZ6が有する−ＳＯ₃Ｍ又は−ＣＯ₂Ｍの合計個数はａ以上である。
（ｊ−ｉ）Ｒ^1AAZ6、Ｒ^2AAZ6、Ｒ^3AAZ6、Ｒ^4AAZ6、Ｒ^5AAZ6、Ｒ^AAA1Z6、Ｒ^AAA2Z6、Ｒ^12AAZ6及びＲ^13AAZ6の少なくとも一つが、−ＳＯ₃Ｍ又は−ＣＯ₂Ｍである。
（ｊ−ｉｉ）Ｒ^1AAZ6、Ｒ^2AAZ6、Ｒ^3AAZ6、Ｒ^4AAZ6、Ｒ^5AAZ6、Ｒ^AAA1Z6、Ｒ^AAA2Z6、Ｒ^12AAZ6及びＲ^13AAZ6の少なくとも一つが、−ＣＯ−Ｒ^102AAZ6、−ＣＯＯ−Ｒ^101AAZ6、−ＯＣＯ−Ｒ^102AAZ6、−Ｏ−Ｒ^102AAZ6、−ＳＯ₂−Ｒ^101AAZ6、−ＳＯ₂Ｎ（Ｒ^102AAZ6）₂、−ＣＯＮ（Ｒ^102AAZ6）₂、−Ｎ（Ｒ^102AAZ6）₂又は−ＮＨＣＯ−Ｒ^102AAZ6であって、該Ｒ^101AAZ6及びＲ^102AAZ6が、−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する炭素数１〜４０の炭化水素基又は−ＳＯ₃ ^-若しくは−ＣＯ₂ ^-を有する複素環基である。ただし該炭化水素基又は該複素環基は、−ＳＯ₃ ^-及び−ＣＯ₂ ^-以外の置換基を有していてもよい。
（ｊ−ｉｉｉ）Ｒ^1AAZ6、Ｒ^2AAZ6、Ｒ^3AAZ6、Ｒ^4AAZ6、Ｒ^5AAZ6、Ｒ^AAA1Z6、Ｒ^AAA2Z6、Ｒ^12AAZ6及びＲ^13AAZ6の少なくとも一つが、−ＳＯ₃Ｍ若しくは−ＣＯ₂Ｍを有する炭素数１〜４０の炭化水素基又は−ＳＯ₃Ｍ若しくは−ＣＯ₂Ｍを有する複素環基である。ただし該炭化水素基又は該複素環基は、−ＳＯ₃ ^-及び−ＣＯ₂ ^-以外の置換基を有していてもよい。
ａは、式（ＩＺ６）におけるものと同じ意味を表す。ａが複数存在する場合、それらは同一であってもよく、異なっていてもよい。］

[In formula (JJZ6), formula (KZ6) and formula (IZ6-A),
A ^{c +} , b, c, d, R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 and the wavy line have the same meaning as described above.
R ^1AAZ6 , R ^2AAZ6 , R ^3AAZ6 , R ^4AAZ6 , R ^5AAZ6 , R ^AAA1Z6 , R ^AAA2Z6 , R ^12AAZ6 and R ^13AAZ6 are each independently a hydrogen atom, -CO-R ^102AAZ6 , -COO-R ^101AAZ6 , -OCO- ^{R 102AAZ6, -O-R 102AAZ6,} -SO 2 -R 101AAZ6, -SO 2 N (R 102AAZ6) 2, -CON (R 102AAZ6) 2, -N (R 102AAZ6) 2, -NHCO-R 102AAZ6, halogen atom , A cyano group, a nitro group, —SO ₃ M, —CO ₂ M, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group. .
R ^2AAZ6 and R ^3AAZ6 , R ^3AAZ6 and R ^4AAZ6 , R ^4AAZ6 and R ^5AZ6 , R ^AAA1Z6 and R ^AAA2Z6, and R ^12AAZ6 and R ^13AAZ6 may be bonded to each other to form a ring.
R ^101AAZ6 represents, independently of each other, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102AAZ6 represents, independently of each other, a hydrogen atom, an ^optionally substituted hydrocarbon group having 1 to 40 carbon atoms, or an ^optionally substituted heterocyclic group.
M represents the same meaning as described above.
R ^1AAZ6 , R ^2AAZ6 , R ^3AAZ6 , R ^4AAZ6 , R ^5AAZ6 , R ^AAA1Z6 , R ^AAA2Z6 , R ^12AAZ6 , R ^13AAZ6 , R ^101AAZ6 , R ^102AAZ6, or M may be the same or different It may be.
R ^1AAZ6 , R ^2AAZ6 , R ^3AAZ6 , R ^4AAZ6 , R ^5AAZ6 , R ^AAA1Z6 , R ^AAA2Z6 , R ^12AAZ6 , R ^13AAZ6 , R ^101AAZ6 and R ^102AAZ6 are at least one of (j-i) to (j-iii) R ^1AAZ6 , R ^2AAZ6 , R ^3AAZ6 , R ^4AAZ6 , R ^5AAZ6 , R ^AAA1Z6 , R ^AAA2Z6 , R ^12AAZ6 , R ^13AAZ6 , R ^101AAZ6 and R ^102AAZ6 have —SO ₃ M or —CO ₂ M The total number is a or more.
( ^Ji ) At least one of R ^1AAZ6 , R ^2AAZ6 , R ^3AAZ6 , R ^4AAZ6 , R ^5AAZ6 , R ^AAA1Z6 , R ^AAA2Z6 , R ^12AAZ6 and R ^13AAZ6 is —SO ₃ M or —CO ₂ M.
(J-ii) At least one of R ^1AAZ6 , R ^2AAZ6 , R ^3AAZ6 , R ^4AAZ6 , R ^5AAZ6 , R ^AAA1Z6 , R ^AAA2Z6 , R ^12AAZ6 and R ^13AAZ6 is -CO-R ^102AAZ6 , -COO-R ^101AAZ6 , -OCO ^{-R 102AAZ6, -O-R 102AAZ6,} -SO 2 -R 101AAZ6, -SO 2 N (R 102AAZ6) 2, -CON (R 102AAZ6) 2, -N (R 102AAZ6) 2 or -NHCO-R ^102AAZ6 met Te, wherein R ^101AAZ6 and R ^102AAZ6 is, -SO ₃ ^- or -CO ₂ ^- 1 to 40 carbon atoms having a hydrocarbon group or a -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .
(J-iii) Carbon number 1 in which at least one of R ^1AAZ6 , R ^2AAZ6 , R ^3AAZ6 , R ^4AAZ6 , R ^5AAZ6 , R ^AAA1Z6 , R ^AAA2Z6 , R ^12AAZ6 and R ^13AAZ6 has —SO ₃ M or —CO ₂ M It is a heterocyclic group having ˜40 hydrocarbon groups or —SO ₃ M or —CO ₂ M. However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .
a represents the same meaning as in formula (IZ6). When a plurality of a are present, they may be the same or different. ]

A compound represented by the formula (JJZ6) (hereinafter sometimes referred to as a compound (JJZ6)) is a compound represented by the formula (pt1Z6) (hereinafter referred to as a phthalonitrile compound) when R ^1AAZ6 is a hydrogen atom. After reacting with a compound represented by the formula (pt2Z6) (hereinafter sometimes referred to as an alkoxide compound), the compound represented by the formula (pt3Z6) (hereinafter sometimes referred to as the compound (pt3Z6)). And a compound represented by the formula (pt4Z6) (hereinafter sometimes referred to as a compound (pt4Z6)) may be further reacted in the presence of an acid. When R ^1AAZ6 is other than a hydrogen atom, a compound represented by the formula (JJZ6) is produced by further reacting with a compound represented by the formula (pt5Z6) (hereinafter sometimes referred to as a compound (pt5Z6)). it can.
Here, the compounds represented by the formula (pt1Z6), the formula (pt1Z6), the formula (pt3Z6), the formula (pt4Z6), and the formula (pt5Z6) may be independent from each other or may be different compounds. It may be a mixture.

[In formula (pt1Z6), formula (pt1Z6), formula (pt3Z6), formula (pt4Z6), formula (pt5Z6) and formula (JJZ6), R ^1AAZ6 , R ^2AAZ6 , R ^3AAZ6 , R ^4AAZ6 , R ^5AAZ6 , R ^AAA1Z6 R ^AAA2Z6 , R ^12AAZ6 and R ^13AAZ6 represent the same meaning as described above.
R ^50Z6 represents an alkyl group having 1 to 20 carbon atoms.
M ^1Z6 represents an alkali metal atom.
LG represents a halogen atom, a methanesulfonyloxy group, a toluenesulfonyloxy group, or a trifluoromethanesulfonyloxy group. ]

^Examples of the alkyl group having 1 to 20 carbon atoms represented by R ^50Z6 include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, a sec-butyl group, and a tert-butyl group. Is an alkyl group having 1 to 6 carbon atoms.
^Examples of the alkali metal atom represented by M ^1Z6 include a lithium atom, a sodium atom, and a potassium atom.

  The amount of the alkoxide compound used is usually 0.1 to 10 mol, preferably 0.2 to 5 mol, more preferably 0.3 to 3 mol, relative to 1 mol of the phthalonitrile compound. More preferably, it is 0.4-2 mol.

The amount of compound (pt3Z6) to be used is generally 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, still more preferably 1 mol, per 1 mol of phthalonitrile compound. ~ 2 moles.
The amount of compound (pt4Z6) to be used is generally 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, further preferably 1 to 1 mol of phthalonitrile compound. ~ 2 moles.

Examples of acids include inorganic acids such as hydrochloric acid, hydrobromic acid, hydroiodic acid, sulfuric acid, nitric acid, fluorosulfonic acid, and phosphoric acid; sulfonic acids such as methanesulfonic acid, trifluoromethanesulfonic acid, and p-toluenesulfonic acid; Examples thereof include carboxylic acids such as acetic acid, citric acid, formic acid, gluconic acid, lactic acid, oxalic acid and tartaric acid, and preferably hydrochloric acid, hydrobromic acid, sulfuric acid, methanesulfonic acid, trifluoromethanesulfonic acid, p-toluenesulfonic acid and A carboxylic acid is mentioned, More preferably, an acetic acid is mentioned.
The usage-amount of an acid is 1-20 mol normally with respect to 1 mol of phthalonitrile compounds, Preferably it is 1-10 mol, More preferably, it is 1-8 mol, More preferably, it is 1-6 mol. is there.

The reaction of a phthalonitrile compound, an alkoxide compound, a compound (pt3Z6) and a compound (pt4Z6) is usually performed in the presence of a solvent.
Solvents include water; nitrile solvents such as acetonitrile; alcohol solvents such as methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol and 1-octanol; ether solvents such as tetrahydrofuran; ketone solvents such as acetone; Ester solvents such as ethyl; aliphatic hydrocarbon solvents such as hexane; aromatic hydrocarbon solvents such as toluene; halogenated hydrocarbon solvents such as methylene chloride and chloroform; amides such as N, N-dimethylformaldehyde and N-methylpyrrolidone Solvent: Sulfoxide solvents such as dimethyl sulfoxide are mentioned, preferably water, nitrile solvent, alcohol solvent, ether solvent, ketone solvent, ester solvent, aromatic hydrocarbon solvent, halogenated hydrocarbon solvent, amide solvent and sulfoxide solvent. And More preferably, water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, tetrahydrofuran, acetone, ethyl acetate, toluene, methylene chloride, chloroform, N, N-dimethylformaldehyde, N -Methylpyrrolidone and dimethyl sulfoxide are mentioned, More preferably, water, acetonitrile, methanol, ethanol, 2-propanol, 1-butanol, 1-pentanol, 1-octanol, acetone, methylene chloride, chloroform, N, N-dimethyl Examples include formaldehyde, N-methylpyrrolidone and dimethyl sulfoxide, with water, acetonitrile, methanol, ethanol and 2-propanol being particularly preferred.
The usage-amount of a solvent is 1-1000 mass parts normally with respect to 1 mass part of phthalonitrile compounds.

  The reaction temperature is usually 0 to 200 ° C, preferably 0 to 100 ° C, more preferably 0 to 70 ° C, and further preferably 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

The amount of compound (pt5Z6) to be used is generally 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, per 1 mol of compound (JJZ6) in which R ^1AAZ6 is a hydrogen atom. More preferably, it is 1-2 mol.

  Moreover, when making a compound (pt5Z6) react, it is preferable that a base coexists. Bases include organic bases such as triethylamine, 4- (N, N-dimethylamino) pyridine, pyridine, piperidine, metal alkoxides such as sodium methoxide, sodium ethoxide, sodium tert-butoxide, potassium tert-butoxide, butyllithium Organic metal compounds such as tert-butyl lithium and phenyl lithium; inorganic bases such as lithium hydroxide, sodium hydroxide and potassium hydroxide.

The amount of the base used is usually 1 to 10 mol, preferably 1 to 5 mol, more preferably 1 to 3 mol, relative to 1 mol of the compound (JJZ6) in which R ^1AAZ6 is a hydrogen atom. Preferably it is 1-2 mol.

Moreover, reaction of a compound (pt5Z6) is normally implemented in presence of a solvent. The solvent can be selected from the same range as described above.
The usage-amount of a solvent is ^1-1000 mass parts normally with respect to 1 mass part of compounds (JJZ6) whose R ^<1AAZ6> is a hydrogen atom. The reaction temperature of the compound (pt5Z6) is usually -90 to 200 ° C, preferably -80 to 100 ° C, more preferably 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

Compound (JJZ6) does not have a -SO ₃ M compound if (hereinafter, compound (sometimes referred JJJZ6)), compound (JJJZ6) and fuming sulfuric acid or reacting a sulfonation agent such as chlorosulfonic acid by, it can be introduced -SO ₃ M.

The amount of SO ₃ in the oleum, the compound (JJJZ6) relative to 1 mol, usually 1 to 50 moles, preferably from 5 to 40 moles, more preferably from 5 to 30 moles, more preferably 5 to 25 mol.
The usage-amount of the sulfuric acid in fuming sulfuric acid is 1-200 mol normally with respect to 1 mol of compounds (JJJJ6), Preferably it is 10-100 mol, More preferably, it is 10-75 mol, More preferably, it is 10 ~ 50 moles.

  The usage-amount of chlorosulfonic acid is 1-500 mol normally with respect to 1 mol of compounds (JJZZ6), Preferably it is 10-300 mol, More preferably, it is 10-200 mol, More preferably, it is 10-150. Is a mole.

  The reaction temperature of the sulfonation is usually from -20 to 200 ° C, preferably from -10 to 100 ° C, more preferably from 0 to 50 ° C. The reaction time is usually 0.5 to 300 hours.

  The method for taking out the compound (JJZ6) from the reaction mixture is not particularly limited, and it can be taken out by various known methods. For example, after completion of the reaction, the compound (JJZ6) can be taken out by filtering the reaction mixture. Further, after filtration, the obtained residue may be subjected to column chromatography or recrystallization. Further, after completion of the reaction, the solvent of the reaction mixture may be distilled off and then purified by column chromatography.

  The coloring composition of the present invention contains the compound (Z) and at least one of the resin (B) and the solvent (E), and includes both the compound (Z), the resin (B), and the solvent (E). It is preferable to include.

  The colored composition of the present invention preferably contains a resin (hereinafter sometimes referred to as “resin (B)”). A coloring composition may further improve dispersion stability by including resin (B).

<Resin (B)>
The resin (B) is preferably an alkali-soluble resin, and is at least one monomer (a) selected from the group consisting of an unsaturated carboxylic acid and an unsaturated carboxylic anhydride (hereinafter referred to as “(a)”). In some cases, the polymer is preferably a polymer having a structural unit derived from.
The resin (B) is a structural unit derived from the monomer (b) having a C2-C4 cyclic ether structure and an ethylenically unsaturated bond (hereinafter sometimes referred to as “(b)”), and others. A copolymer having the following structural unit is preferable.
As other structural units, the monomer (c) copolymerizable with the monomer (a) (however, different from the monomer (a) and the monomer (b). Hereinafter, “(c)”) And a structural unit having an ethylenically unsaturated bond, and the like.

Examples of (a) include acrylic acid, methacrylic acid, crotonic acid, and unsaturated monocarboxylic acids such as o-, m-, and p-vinylbenzoic acid;
Maleic acid, fumaric acid, citraconic acid, mesaconic acid, itaconic acid, 3-vinylphthalic acid, 4-vinylphthalic acid, 3,4,5,6-tetrahydrophthalic acid, 1,2,3,6-tetrahydrophthalic acid, dimethyl Unsaturated dicarboxylic acids such as tetrahydrophthalic acid and 1,4-cyclohexene dicarboxylic acid;
Methyl-5-norbornene-2,3-dicarboxylic acid, 5-carboxybicyclo [2.2.1] hept-2-ene, 5,6-dicarboxybicyclo [2.2.1] hept-2-ene, Bicyclounsaturated compounds containing a carboxy group such as 5-carboxymethylbicyclo [2.2.1] hept-2-ene and 5-carboxyethylbicyclo [2.2.1] hept-2-ene;
Carboxylic anhydrides such as the above unsaturated dicarboxylic acid anhydrides excluding fumaric acid and mesaconic acid;
Unsaturated mono [(meth) acryloyloxyalkyl] esters of divalent or higher polyvalent carboxylic acids such as succinic acid mono [2- (meth) acryloyloxyethyl] and phthalic acid mono [2- (meth) acryloyloxyethyl] Kind;
Examples thereof include unsaturated acrylates containing a hydroxy group and a carboxy group in the same molecule, such as α- (hydroxymethyl) acrylic acid.
Of these, acrylic acid, methacrylic acid, maleic anhydride, and the like are preferable from the viewpoint of copolymerization reactivity and the solubility of the resulting resin in an alkaline aqueous solution.

(B) refers to a polymerizable compound having a C2-C4 cyclic ether structure (for example, at least one selected from the group consisting of an oxirane ring, an oxetane ring and a tetrahydrofuran ring) and an ethylenically unsaturated bond. (B) is preferably a monomer having a C2-C4 cyclic ether and a (meth) acryloyloxy group.
Examples of (b) include a monomer (b1) having an oxiranyl group and an ethylenically unsaturated bond (hereinafter sometimes referred to as “(b1)”), and a single monomer having an oxetanyl group and an ethylenically unsaturated bond. Monomer (b2) (hereinafter sometimes referred to as “(b2)”) and monomer (b3) having a tetrahydrofuryl group and an ethylenically unsaturated bond (hereinafter sometimes referred to as “(b3)”) Can be mentioned.

  Examples of (b1) include a monomer (b1-1) having a structure in which a linear or branched aliphatic unsaturated hydrocarbon is epoxidized (hereinafter referred to as “(b1-1)”). And a monomer (b1-2) having a structure in which an alicyclic unsaturated hydrocarbon is epoxidized (hereinafter sometimes referred to as “(b1-2)”).

(B1-1) is preferably a monomer having a glycidyl group and an ethylenically unsaturated bond. Specifically as (b1-1), glycidyl (meth) acrylate, β-methylglycidyl (meth) acrylate, β-ethylglycidyl (meth) acrylate, glycidyl vinyl ether, vinylbenzyl glycidyl ether, α-methylvinylbenzyl Glycidyl ether, 2,3-bis (glycidyloxymethyl) styrene, 2,4-bis (glycidyloxymethyl) styrene, 2,5-bis (glycidyloxymethyl) styrene, 2,6-bis (glycidyloxymethyl) styrene 2,3,4-tris (glycidyloxymethyl) styrene, 2,3,5-tris (glycidyloxymethyl) styrene, 2,3,6-tris (glycidyloxymethyl) styrene, 3,4,5-tris (Glycidyloxymethyl) styrene and 2, , 6- tris (glycidyloxy) styrene, and the like.
Examples of (b1-2) include vinylcyclohexene monoxide, 1,2-epoxy-4-vinylcyclohexane (for example, Celoxide (registered trademark) 2000; manufactured by Daicel Corporation), 3,4-epoxycyclohexylmethyl (meth) Acrylate (for example, Cyclomer (registered trademark) A400; manufactured by Daicel Corporation), 3,4-epoxycyclohexylmethyl (meth) acrylate (for example, Cyclomer (registered trademark) M100; manufactured by Daicel Corporation), formula ( A compound represented by BI) and a compound represented by formula (BII).

[In Formula (BI) and Formula (BII), R ^a and R ^b each independently represent a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and the hydrogen atom contained in the alkyl group is a hydroxy group May be substituted.
X ^a and X ^b are each independently a single ^{bond, * - R c -, *} - R c -O -, * - represents the R ^c -S- or * -R ^c -NH-.
R ^c represents an alkanediyl group having 1 to 6 carbon atoms.
* Represents a bond with O. ]

  Examples of the compound represented by the formula (BI) include compounds represented by any one of the formulas (BI-1) to (BI-15), preferably the formula (BI-1) and the formula (BI -3), formula (BI-5), formula (BI-7), formula (BI-9), and compounds represented by formula (BI-11) to formula (BI-15), more preferably And compounds represented by formula (BI-1), formula (BI-7), formula (BI-9) and formula (BI-15).

  Examples of the compound represented by the formula (BII) include compounds represented by any one of the formulas (BII-1) to (BII-15), preferably the formula (BII-1) and the formula (BII). -3), compounds represented by formula (BII-5), formula (BII-7), formula (BII-9) and formula (BII-11) to formula (BII-15), more preferably Examples thereof include compounds represented by formula (BII-1), formula (BII-7), formula (BII-9) and formula (BII-15).

  The compound represented by formula (BI) and the compound represented by formula (BII) may be used alone or in combination with a compound represented by formula (BI) and a compound represented by formula (BII). May be. When these are used in combination, the content ratio of the compound represented by Formula (BI) and the compound represented by Formula (BII) is preferably 5:95 to 95: 5, more preferably 10: It is 90-90: 10, More preferably, it is 20: 80-80: 20.

Examples of (c) include methyl (meth) acrylate, ethyl (meth) acrylate, n-butyl (meth) acrylate, sec-butyl (meth) acrylate, tert-butyl (meth) acrylate, and 2-ethylhexyl (meth). Acrylate, dodecyl (meth) acrylate, lauryl (meth) acrylate, stearyl (meth) acrylate, cyclopentyl (meth) acrylate, tricyclo [5.2.1.0 ^2,6 ] decan-8-yl (meth) acrylate, tricyclo [5.2.1.0 ^2,6 ] decan-9-yl (meth) acrylate, tricyclo [5.2.1.0 ^2,6 ] decen-8-yl (meth) acrylate, tricyclo [5.2 .1.0 ^2,6] decene-9-yl (meth) acrylate, dicyclopentanyl oxyethyl (main ) Acrylates, isobornyl (meth) acrylates, adamantyl (meth) acrylates, allyl (meth) acrylates, propargyl (meth) acrylates, phenyl (meth) acrylates, naphthyl (meth) acrylates, and benzyl (meth) acrylates Acid esters;
Hydroxy group-containing (meth) acrylic acid esters such as 2-hydroxyethyl (meth) acrylate and 2-hydroxypropyl (meth) acrylate;
Dicarboxylic acid diesters such as diethyl maleate, diethyl fumarate and diethyl itaconate;
Bicyclo [2.2.1] hept-2-ene, 5-methylbicyclo [2.2.1] hept-2-ene, 5-ethylbicyclo [2.2.1] hept-2-ene, 5- Hydroxybicyclo [2.2.1] hept-2-ene, 5-hydroxymethylbicyclo [2.2.1] hept-2-ene, 5- (2′-hydroxyethyl) bicyclo [2.2.1] Hept-2-ene, 5-methoxybicyclo [2.2.1] hept-2-ene, 5-ethoxybicyclo [2.2.1] hept-2-ene, 5,6-dihydroxybicyclo [2.2 .1] Hept-2-ene, 5,6-di (hydroxymethyl) bicyclo [2.2.1] hept-2-ene, 5,6-di (2′-hydroxyethyl) bicyclo [2.2. 1] hept-2-ene, 5,6-dimethoxybicyclo [2.2 1] hept-2-ene, 5,6-diethoxybicyclo [2.2.1] hept-2-ene, 5-hydroxy-5-methylbicyclo [2.2.1] hept-2-ene, 5 -Hydroxy-5-ethylbicyclo [2.2.1] hept-2-ene, 5-hydroxymethyl-5-methylbicyclo [2.2.1] hept-2-ene, 5-tert-butoxycarbonylbicyclo [ 2.2.1] Hept-2-ene, 5-cyclohexyloxycarbonylbicyclo [2.2.1] hept-2-ene, 5-phenoxycarbonylbicyclo [2.2.1] hept-2-ene, 5 , 6-bis (tert-butoxycarbonyl) bicyclo [2.2.1] hept-2-ene, 5,6-bis (cyclohexyloxycarbonyl) bicyclo [2.2.1] hept-2-ene, etc. A bicyclo unsaturated compound;
N-phenylmaleimide, N-cyclohexylmaleimide, N-benzylmaleimide, N-succinimidyl-3-maleimidobenzoate, N-succinimidyl-4-maleimidobutyrate, N-succinimidyl-6-maleimidocaproate, N-succinimidyl-3 -Dicarbonylimide derivatives such as maleimide propionate and N- (9-acridinyl) maleimide;
Vinyl group-containing aromatic compounds such as styrene, α-methylstyrene, vinyltoluene and p-methoxystyrene; vinyl group-containing nitriles such as (meth) acrylonitrile; halogenated hydrocarbons such as vinyl chloride and vinylidene chloride; (meth) acrylamide Vinyl group-containing amides such as; esters such as vinyl acetate; dienes such as 1,3-butadiene, isoprene and 2,3-dimethyl-1,3-butadiene;
Of these, styrene, vinyltoluene, tricyclo [5.2.1.0 ^2,6 ] decan-8-yl (meth) acrylate, tricyclo [5.2.1] from the viewpoints of copolymerization reactivity and heat resistance. .0 ^2,6] decan-9-yl (meth) acrylate, tricyclo [5.2.1.0 ^2,6] decene-8-yl (meth) acrylate, tricyclo [5.2.1.0 ^{2, 6} ] Decen-9-yl (meth) acrylate, N-phenylmaleimide, N-cyclohexylmaleimide, N-benzylmaleimide, bicyclo [2.2.1] hept-2-ene and benzyl (meth) acrylate are preferred.

The structural unit having an ethylenically unsaturated bond is preferably a structural unit having a (meth) acryloyl group. Resins having such a structural unit include a polymer having a structural unit derived from (a) or (b), an ethylenically unsaturated bond and a group capable of reacting with the group (a) or (b). It can obtain by adding the monomer which has.
Such structural units include a structural unit obtained by adding glycidyl (meth) acrylate to a (meth) acrylic acid unit, a structural unit obtained by adding 2-hydroxyethyl (meth) acrylate to a maleic anhydride unit, and glycidyl (meta And a structural unit obtained by adding (meth) acrylic acid to an acrylate unit. Moreover, when these structural units have a hydroxy group, the structural unit which further added the carboxylic acid anhydride is also mentioned as a structural unit which has an ethylenically unsaturated bond.

  The polymer having the structural unit derived from (a) can be produced, for example, by polymerizing a monomer constituting the structural unit of the polymer in a solvent in the presence of a polymerization initiator. A polymerization initiator, a solvent, etc. are not specifically limited, What is normally used in the said field | area can be used. For example, as polymerization initiators, azo compounds (2,2′-azobisisobutyronitrile, 2,2′-azobis (2,4-dimethylvaleronitrile), etc.) and organic peroxides (benzoyl peroxide, etc.) As the solvent, any solvent that dissolves each monomer may be used.

In addition, the obtained polymer may use the solution after the reaction as it is, may use a concentrated or diluted solution, or is taken out as a solid (powder) by a method such as reprecipitation. May be used.
If necessary, a reaction catalyst (for example, tris (dimethylaminomethyl) phenol) of a carboxylic acid or carboxylic acid anhydride and a cyclic ether, a polymerization inhibitor (for example, hydroquinone) or the like may be used.
Carboxylic anhydrides include maleic anhydride, citraconic anhydride, itaconic anhydride, 3-vinylphthalic anhydride, 4-vinylphthalic anhydride, 3,4,5,6-tetrahydrophthalic anhydride, 1 2,3,6-tetrahydrophthalic anhydride, dimethyltetrahydrophthalic anhydride, 5,6-dicarboxybicyclo [2.2.1] hept-2-ene anhydride, and the like.

As the resin (B), specifically, 3,4-epoxycyclohexylmethyl (meth) acrylate / (meth) acrylic acid copolymer, 3,4-epoxytricyclo [5.2.1.0 ^2,6 ] Decyl (meth) acrylate / (meth) acrylic acid copolymer, glycidyl (meth)
Acrylate / benzyl (meth) acrylate / (meth) acrylic acid copolymer, glycidyl (meth) acrylate / styrene / (meth) acrylic acid copolymer, 3,4-epoxytricyclo [5.2.1.0 ^{2 , 6} ] decyl (meth) acrylate / (meth) acrylic acid / N-cyclohexylmaleimide copolymer, 3,4-epoxytricyclo [5.2.1.0 ^2,6 ] decyl (meth) acrylate / (meta ) Acrylic acid / N-cyclohexylmaleimide / 2-hydroxyethyl (meth) acrylate copolymer, 3,4-epoxytricyclo [5.2.1.0 ^2,6 ] decyl (meth) acrylate / (meth) acrylic acid / vinyl toluene copolymer, 3,4-epoxytricyclo [5.2.1.0 ^2,6] decyl (meth) acrylate / (meth) acrylic acid / - ethylhexyl (meth) acrylate copolymer, 3,4-epoxytricyclo [5.2.1.0 ^2,6] decyl (meth) acrylate / tricyclo [5.2.1.0 ^{2, 6]} decenyl ( (Meth) acrylate / (meth) acrylic acid / N-cyclohexylmaleimide copolymer, 3-methyl-3- (meth) acryloyloxymethyloxetane / (meth) acrylic acid / styrene copolymer, benzyl (meth) acrylate / (Meth) acrylic acid copolymer, styrene / (meth) acrylic acid copolymer, and resins described in JP-A-9-106071, JP-A-2004-29518 and JP-A-2004-361455 Is mentioned.
Especially, as resin (B), the copolymer containing the structural unit derived from (a) and the structural unit derived from (b) is preferable.
Two or more kinds of the resin (B) may be combined. In this case, the resin (B) is at least 3,4-epoxytricyclo [5.2.1.0 ^2,6 ] decyl (meth) acrylate. / (Meth) acrylic acid copolymer, 3,4-epoxytricyclo [5.2.1.0 ^2,6 ] decyl (meth) acrylate / (meth) acrylic acid / N-cyclohexylmaleimide / 2-hydroxyethyl (Meth) acrylate copolymer, 3,4-epoxytricyclo [5.2.1.0 ^2,6 ] decyl (meth) acrylate / (meth) acrylic acid / vinyltoluene copolymer, 3,4-epoxy It is preferable to include one or more selected from tricyclo [5.2.1.0 ^2,6 ] decyl (meth) acrylate / (meth) acrylic acid / 2-ethylhexyl (meth) acrylate copolymer.

  The polystyrene equivalent weight average molecular weight (Mw) of the resin (B) is preferably 3,000 to 100,000, more preferably 5,000 to 50,000, and still more preferably 5,000 to 30,000. 000. The dispersity [weight average molecular weight (Mw) / number average molecular weight (Mn)] of the resin (B) is preferably 1.1 to 6, and more preferably 1.2 to 4.

  The acid value (solid value converted value) of the resin (B) is preferably 10 to 300 mg-KOH / g, more preferably 20 to 250 mg-KOH / g, and still more preferably 30 to 200 mg-KOH / g. It is. Here, the acid value is a value measured as the amount (mg) of potassium hydroxide necessary to neutralize 1 g of the resin (B), and can be determined by titration with an aqueous potassium hydroxide solution, for example. .

  In the coloring composition, the content of the resin (B) is preferably 3 to 99% by mass, more preferably 5 to 99% by mass, and further preferably 7 to 95% by mass with respect to the total amount of the solid content. %.

  The colored composition of the present invention preferably contains a solvent (hereinafter sometimes referred to as a solvent (E)). A coloring composition may further improve dispersion stability by including a solvent (E).

<Solvent (E)>
Solvent (E) is, for example, an ester solvent (a solvent containing —COO— in the molecule and not containing —O—), an ether solvent (a solvent containing —O— in the molecule and not containing —COO—), Ether ester solvent (solvent containing -COO- and -O- in the molecule), ketone solvent (solvent containing -CO- in the molecule and not containing -COO-), alcohol solvent (containing OH in the molecule) , -O-, -CO- and -COO-), aromatic hydrocarbon solvents, amide solvents and dimethyl sulfoxide.

  As ester solvents, methyl lactate, ethyl lactate, butyl lactate, methyl 2-hydroxyisobutanoate, ethyl acetate, n-butyl acetate, isobutyl acetate, pentyl formate, isopentyl acetate, butyl propionate, isopropyl butyrate, ethyl butyrate, butyl butyrate Methyl pyruvate, ethyl pyruvate, propyl pyruvate, methyl acetoacetate, ethyl acetoacetate, cyclohexanol acetate, and γ-butyrolactone.

  Ether solvents include ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monopropyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether , Propylene glycol monopropyl ether, propylene glycol monobutyl ether, 3-methoxy-1-butanol, 3-methoxy-3-methylbutanol, tetrahydrofuran, tetrahydropyran, 1,4-dioxane, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethyl Glycol methyl ethyl ether, diethylene glycol dipropyl ether, diethylene glycol dibutyl ether, anisole, include phenetol and methyl anisole and the like.

  Examples of ether ester solvents include methyl methoxyacetate, ethyl methoxyacetate, butyl methoxyacetate, methyl ethoxyacetate, ethyl ethoxyacetate, methyl 3-methoxypropionate, ethyl 3-methoxypropionate, methyl 3-ethoxypropionate, 3-ethoxy Ethyl propionate, methyl 2-methoxypropionate, ethyl 2-methoxypropionate, propyl 2-methoxypropionate, methyl 2-ethoxypropionate, ethyl 2-ethoxypropionate, methyl 2-methoxy-2-methylpropionate, Ethyl 2-ethoxy-2-methylpropionate, 3-methoxybutyl acetate, 3-methyl-3-methoxybutyl acetate, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether Acetate, propylene glycol monopropyl ether acetate, ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether acetate and dipropylene glycol methyl ether acetate and the like.

  Examples of ketone solvents include 4-hydroxy-4-methyl-2-pentanone, acetone, 2-butanone, 2-heptanone, 3-heptanone, 4-heptanone, 4-methyl-2-pentanone, cyclopentanone, cyclohexanone and isophorone. Etc.

Examples of the alcohol solvent include methanol, ethanol, propanol, butanol, hexanol, cyclohexanol, ethylene glycol, propylene glycol, and glycerin.
Examples of the aromatic hydrocarbon solvent include benzene, toluene, xylene and mesitylene.
Examples of the amide solvent include N, N-dimethylformamide, N, N-dimethylacetamide and N-methylpyrrolidone.
Two or more of these solvents may be used in combination.
The content of the solvent (E) is preferably 40 to 99% by mass, more preferably 50 to 95% by mass, based on the total amount of the colored composition.

  In the colored composition of the present invention, the compound (Z) is preferably dispersed in the solvent (E).

  Compound (Z) is optionally treated with rosin, surface treatment using a derivative having an acidic group or basic group introduced, graft treatment on the surface of compound (Z) with a polymer compound, etc., and atomization of sulfuric acid Atomization treatment by a method or the like, cleaning treatment with an organic solvent or water for removing impurities, removal treatment by an ion exchange method of ionic impurities, or the like may be performed. The particle size of the compound (Z) is preferably substantially uniform. The compound (Z) can be made to be in a state where the compound (Z) is uniformly dispersed in the dispersion by carrying out a dispersion treatment by containing a dispersant.

  Examples of the dispersant include surfactants, and any of cationic, anionic, nonionic, and amphoteric surfactants may be used. Specific examples include polyester-based, polyamine-based, and acrylic surfactants. These dispersants may be used alone or in combination of two or more. As the dispersant, KP (manufactured by Shin-Etsu Chemical Co., Ltd.), Floren (manufactured by Kyoeisha Chemical Co., Ltd.), Solsperse (registered trademark) (manufactured by Geneca Corporation), EFKA (registered trademark) (Manufactured by BASF Corp.), Ajisper (registered trademark) (manufactured by Ajinomoto Fine Techno Co., Ltd.), Disperbyk (registered trademark) (manufactured by BYK Chemie Corp.), BYK (registered trademark) (manufactured by BYK Chemie Corp.), etc. Can be mentioned.

  When the dispersant is used, the amount of the dispersant (solid content) used is preferably 300 parts by mass or less, more preferably 5 parts by mass or more and 100 parts by mass or less with respect to 100 parts by mass of the compound (Z). . When the usage-amount of a dispersing agent exists in the said range, there exists a tendency for the coloring composition of a more uniform dispersion state to be obtained.

  The content rate of the compound (Z) in a coloring composition is 0.1-60 mass% normally in the total amount of a coloring composition, Preferably it is 0.5-50 mass%, More preferably, it is 1-40. % By mass.

  In the coloring composition, the content of the compound (Z) is usually 1% by mass or more and 90% by mass or less, preferably 1% by mass or more and 80% by mass or less, more preferably, based on the total amount of the solid content. It is 2 mass% or more and 75 mass% or less.

When the coloring composition of the present invention contains the compound (Z), the coloring composition is a coloring agent other than the compound (Z) (that is, the above-described coloring agent (A1Z1), coloring agent (A1Z2), coloring agent (A1Z3)). , A colorant (A1Z4), a colorant (A1Z5), a colorant (A1Z6), and the like) may be further included. Hereinafter, the colorant (A1Z1), the colorant (A1Z2), the colorant (A1Z3), the colorant (A1Z4), the colorant (A1Z5), and the colorant (A1Z6) are collectively referred to as “colorant (ZZ)”. The colorant (ZZ) may contain one or more colorants, and the colorant (ZZ) preferably contains a yellow colorant or a green colorant.

<Colorant (ZZ)>
The colorant (ZZ) may be a dye or a pigment. As the dye, known dyes can be used, and examples thereof include dyes described in Color Index (published by The Society of Dyers and Colorists) and dyeing notes (Color Dyeing). Further, according to the chemical structure, azo dyes, anthraquinone dyes, triphenylmethane dyes, xanthene dyes, phthalocyanine dyes, and the like can be given. These dyes may be used alone or in combination of two or more.

Specific examples include dyes having the following color index (CI) numbers. C. I. Solvent Yellow 14, 15, 23, 24, 25, 38, 62, 63, 68, 79, 81, 82, 83, 89, 94, 98, 99, 162;
C. I. Acid Yellow 1, 3, 7, 9, 11, 17, 23, 25, 29, 34, 36, 38, 40, 42, 54, 65, 72, 73, 76, 79, 98, 99, 111, 112, 113, 114, 116, 119, 123, 128, 134, 135, 138, 139, 140, 144, 150, 155, 157, 160, 161, 163, 168, 169, 172, 177, 178, 179, 184, 190, 193, 196, 197, 199, 202, 203, 204, 205, 207, 212, 214, 220, 221, 228, 230, 232, 235, 238, 240, 242, 243, 251;
C. I. Reactive Yellow 2, 76, 116;
C. I. Direct Yellow 2, 4, 28, 33, 34, 35, 38, 39, 43, 44, 47, 50, 54, 58, 68, 69, 70, 71, 86, 93, 94, 95, 98, 102, 108, 109, 129, 132, 136, 138, 141;
C. I. Disperse Yellow 51, 54, 76;
C. I. Solvent Orange 2, 7, 11, 15, 26, 41, 54, 56, 99;
C. I. Acid Orange 6, 7, 8, 10, 12, 26, 50, 51, 52, 56, 62, 63, 64, 74, 75, 94, 95, 107, 108, 149, 162, 169, 173;
C. I. Reactive Orange 16;
C. I. Direct Orange 26, 34, 39, 41, 46, 50, 52, 56, 57, 61, 64, 65, 68, 70, 96, 97, 106, 107;
C. I. Solvent Red 24, 49, 90, 91, 111, 118, 119, 122, 124, 125, 127, 130, 132, 143, 145, 146, 150, 151, 155, 160, 168, 169, 172, 175, 181, 207, 218, 222, 227, 230, 245, 247;
C. I. Acid Red 52, 73, 80, 91, 92, 97, 138, 151, 211, 274, 289;
C. I. Acid Violet 34, 102;
C. I. Disperse violet 26, 27;
C. I. Solvent violet 11, 13, 14, 26, 31, 36, 37, 38, 45, 47, 48, 51, 59, 60;
C. I. Solvent Blue 14, 18, 35, 36, 45, 58, 59, 59: 1, 63, 68, 69, 78, 79, 83, 94, 97, 98, 100, 101, 102, 104, 105, 111, 112, 122, 128, 132, 136, 139;
C. I. Acid Blue 25, 27, 40, 45, 78, 80, 112;
C. I. Direct blue 40;
C. I. Disperse Blue 1, 14, 56, 60;
C. I. Solvent Green 1, 3, 5, 28, 29, 32, 33;
C. I. Acid Green 3, 5, 9, 25, 27, 28, 41;
C. I. Basic Green 1;
C. I. Bat Green 1 etc.

As the pigment, known pigments can be used, and examples thereof include pigments classified as pigments according to a color index (published by The Society of Dyers and Colorists). These can be used alone or in combination of two or more.
Specifically, C.I. I. Pigment Yellow 1, 3, 12, 13, 14, 15, 16, 17, 20, 24, 31, 53, 83, 86, 93, 94, 109, 110, 117, 125, 128, 129, 137, 138, Yellow pigments such as 139, 147, 148, 150, 153, 154, 166, 173, 185, 194, 214;
C. I. Orange pigments such as CI Pigment Orange 13, 31, 36, 38, 40, 42, 43, 51, 55, 59, 61, 64, 65, 71, 73;
C. I. Pigment Red 9, 97, 105, 122, 123, 144, 149, 166, 168, 176, 177, 179, 180, 192, 209, 215, 216, 224, 242, 254, 255, 264, 265, 266, Red pigments such as 268, 269, 273;
C. I. Blue pigments such as CI Pigment Blue 15, 15: 3, 15: 4, 15: 6, 60;
C. I. Violet color pigments such as CI Pigment Violet 1, 19, 23, 29, 32, 36, 38;
C. I. And green pigments such as CI Pigment Green 7, 36, 58, and 59.

Examples of the colorant (ZZ) include yellow dyes and yellow pigments (hereinafter sometimes collectively referred to as “yellow colorants”), green dyes and green pigments (hereinafter collectively referred to as “green colorants”). May be preferred), yellow pigments and green pigments are more preferred, and green pigments are even more preferred.
Examples of the yellow dye include dyes whose hue is classified as yellow among the dyes, and examples of the yellow pigment include pigments whose hue is classified as yellow among the pigments.
Among the yellow pigments, quinophthalone yellow pigments, metal-containing yellow pigments, and isoindoline yellow pigments are preferable. I. Pigment Yellow 129, 138, 139, 150, and 185 are more preferable. I. Pigment Yellow 138, 139, 150, and 185 are more preferable.
Examples of the green dye include dyes whose hue is classified as green among the dyes, and examples of the green pigment include pigments whose hue is classified as green among the pigments.
Among the green pigments, a phthalocyanine pigment is preferable, and at least one selected from the group consisting of a halogenated copper phthalocyanine pigment and a halogenated zinc phthalocyanine pigment is more preferable. I. More preferred is at least one selected from the group consisting of CI Pigment Green 7, 36, 58 and 59.

  When the coloring composition of the present invention contains the colorant (ZZ) and the solvent (E), after preparing a colorant (ZZ) -containing liquid containing the colorant (ZZ) and the solvent (E) in advance, the coloration You may prepare a coloring composition using an agent (ZZ) containing liquid. When the colorant (ZZ) does not dissolve in the solvent (E), the colorant (ZZ) -containing liquid can be prepared by dispersing the colorant (ZZ) in the solvent (E) and mixing. The coloring agent (ZZ) -containing liquid may contain a part or all of the solvent (E) contained in the coloring composition.

The coloring composition of the present invention comprises:
Produced by mixing the compound (Z), the resin (B), and a colorant (ZZ) -containing liquid containing the colorant (ZZ) and the solvent (E),
Produced by mixing the compound (Z), the solvent (E), and the colorant (ZZ) -containing liquid containing the colorant (ZZ) and the solvent (E),
It is preferably produced by mixing the compound (Z), the resin (B) and the solvent (E), and the colorant (ZZ) -containing liquid containing the colorant (ZZ) and the solvent (E). As the manufacturing method,
Compound (Z) and resin (B) are mixed by a bead mill or the like to prepare a colored composition, and the resulting colored composition, a colorant (ZZ) containing colorant (ZZ) and solvent (E) A method of mixing the containing liquid,
A compound (Z) and a solvent (E) are mixed by a bead mill or the like to prepare a colored composition, and the resulting colored composition, a colorant (ZZ) containing the colorant (ZZ) and the solvent (E) (ZZ) A method of mixing the containing liquid,
Compound (Z), resin (B) and solvent (E) are mixed by a bead mill or the like to prepare a colored composition, and the resulting colored composition, colorant (ZZ) and solvent (E) are contained. A method of mixing the colorant (ZZ) -containing liquid is preferable.

  The colorant (ZZ) is preferably a colorant containing at least one selected from a green colorant and a yellow colorant.

  If necessary, the colorant (ZZ) is rosin treatment, surface treatment using a colorant derivative having an acidic group or basic group introduced, or graft treatment to the surface of the colorant (ZZ) with a polymer compound or the like. Further, atomization treatment by a sulfuric acid atomization method or the like, cleaning treatment with an organic solvent or water for removing impurities, removal treatment by an ion exchange method of ionic impurities, or the like may be performed. The particle size of the colorant (ZZ) is preferably substantially uniform. The colorant (ZZ) can be in a state in which the colorant (ZZ) is uniformly dispersed in the colorant (ZZ) -containing liquid by carrying out a dispersion treatment by containing a dispersant. Each of the colorants (ZZ) may be dispersed alone, or a plurality of kinds may be mixed and dispersed.

  Examples of the dispersant include surfactants, and any of cationic, anionic, nonionic and amphoteric surfactants may be used. Specific examples include polyester-based, polyamine-based, and acrylic surfactants. These dispersants may be used alone or in combination of two or more. As the dispersant, KP (manufactured by Shin-Etsu Chemical Co., Ltd.), Floren (manufactured by Kyoeisha Chemical Co., Ltd.), Solsperse (registered trademark) (manufactured by Geneca Corporation), EFKA (registered trademark) (Manufactured by BASF Corp.), Ajisper (registered trademark) (manufactured by Ajinomoto Fine Techno Co., Ltd.), Disperbyk (registered trademark) (manufactured by BYK Chemie Corp.), BYK (registered trademark) (manufactured by BYK Chemie Corp.) Can be mentioned.

  In order to prepare the colorant (ZZ) -containing liquid, when a dispersant is used, the amount of the dispersant (solid content) used is preferably 300 parts by mass or less with respect to 100 parts by mass of the colorant (ZZ). Yes, more preferably 5 parts by mass or more and 100 parts by mass or less. When the amount of the dispersant used is in the above range, a colorant (ZZ) -containing liquid in a more uniform dispersion state tends to be obtained.

  The content of the colorant (ZZ) in the colorant (ZZ) -containing liquid is usually 0.1 to 60% by mass, preferably 0.5 to 50% by mass in the total amount of the colorant (ZZ) -containing liquid. More preferably, it is 1-40 mass%.

  In the colorant (ZZ) -containing liquid, the content of the colorant (ZZ) is usually 1% by mass or more and 90% by mass or less, and preferably 1% by mass or more and 80% by mass or less, based on the total amount of solids. More preferably, it is 2 mass% or more and 75 mass% or less.

The coloring composition of the present invention contains the resin (B), and after preparing a colorant (ZZ) -containing liquid containing a colorant (ZZ) and a solvent in advance, the colorant (ZZ) -containing liquid is used. When preparing the coloring composition of the present invention, the colorant (ZZ) -containing liquid is
Part or all of the resin (B) contained in the coloring composition, preferably part may be included in advance,
A part or all of the solvent (E) contained in the coloring composition, preferably part may be included in advance,
Part or all of the resin (B) and the solvent (E) contained in the coloring composition, preferably a part thereof, may be included in advance.
By including resin (B) in advance, the dispersion stability of the colorant (ZZ) -containing liquid can be further improved.
Content of resin (B) in a colorant (ZZ) containing liquid is 1-500 mass parts with respect to 100 mass parts of colorants (ZZ), Preferably it is 5-200 mass parts, More preferably, it is 10-100 mass parts.

In the coloring composition, the content of the colorant (ZZZ) in which the compound (Z) and the colorant (ZZ) are combined is usually 1% by mass or more and 90% by mass or less, preferably based on the total amount of solids. It is 1 mass% or more and 80 mass% or less, More preferably, it is 2 mass% or more and 75 mass% or less.
The content of the compound (Z) is usually 0.001% by mass or more, preferably 0.003% by mass or more, more preferably 0.005% by mass or more, in the total amount of the colorant (ZZZ). Is 100% by mass or less, preferably 99.999% by mass or less, more preferably 99.997% by mass or less.
The content rate of a compound (Z) is 0.001 mass% or more normally in the total amount of a yellow coloring agent, Preferably it is 40 mass% or more, More preferably, it is 50 mass% or more, More preferably, it is 60. The upper limit is 100% by mass or less, preferably 99.999% by mass or less, and more preferably 99.997% by mass or less.
When the colorant (ZZ) is contained, the content of the colorant (ZZ) is preferably 0.1 parts by mass or more, more preferably 0.5 parts by mass or more, relative to 100 parts by mass of the compound (Z). More preferably, it is 1 part by mass or more, preferably 10,000 parts by mass or less, more preferably 5000 parts by mass or less.

  The colored curable composition of the present invention contains a compound (Z), at least one of a resin (B) and a solvent (E), and a polymerizable compound (C).

<Polymerizable compound (C)>
The polymerizable compound (C) is a compound that can be polymerized by active radicals and / or acids generated from the polymerization initiator (D), such as a compound having a polymerizable ethylenically unsaturated bond, preferably It is a (meth) acrylic acid ester compound.

  Examples of the polymerizable compound having one ethylenically unsaturated bond include nonylphenyl carbitol acrylate, 2-hydroxy-3-phenoxypropyl acrylate, 2-ethylhexyl carbitol acrylate, 2-hydroxyethyl acrylate, and N-vinylpyrrolidone. And the above-mentioned monomer (a), monomer (b) and monomer (c).

  Examples of the polymerizable compound having two ethylenically unsaturated bonds include 1,6-hexanediol di (meth) acrylate, ethylene glycol di (meth) acrylate, neopentyl glycol di (meth) acrylate, and triethylene glycol di (Meth) acrylate, bis (acryloyloxyethyl) ether of bisphenol A, 3-methylpentanediol di (meth) acrylate, and the like.

  Especially, it is preferable that a polymeric compound (C) is a polymeric compound which has 3 or more of ethylenically unsaturated bonds. Examples of such polymerizable compounds include trimethylolpropane tri (meth) acrylate, pentaerythritol tri (meth) acrylate, pentaerythritol tetra (meth) acrylate, dipentaerythritol penta (meth) acrylate, dipentaerythritol hexa ( (Meth) acrylate, tripentaerythritol octa (meth) acrylate, tripentaerythritol hepta (meth) acrylate, tetrapentaerythritol deca (meth) acrylate, tetrapentaerythritol nona (meth) acrylate, tris (2- (meth) acryloyloxyethyl) ) Isocyanurate, ethylene glycol modified pentaerythritol tetra (meth) acrylate, ethylene glycol modified dipentaerythritol Hexa (meth) acrylate, propylene glycol modified pentaerythritol tetra (meth) acrylate, propylene glycol modified dipentaerythritol hexa (meth) acrylate, caprolactone modified pentaerythritol tetra (meth) acrylate, caprolactone modified dipentaerythritol hexa (meth) acrylate, etc. Preferably, dipentaerythritol penta (meth) acrylate and dipentaerythritol hexa (meth) acrylate are used.

  The weight average molecular weight of the polymerizable compound (C) is preferably from 150 to 2,900, more preferably from 250 to 1,500.

  The content of the polymerizable compound (C) is preferably 1 to 65% by mass, more preferably 3 to 60% by mass, with respect to the total amount of solids in the colored curable composition, and 5 More preferably, it is -55 mass%.

  The colored curable composition of the present invention may contain a polymerization initiator (D).

<Polymerization initiator (D)>
The polymerization initiator (D) is not particularly limited as long as it is a compound capable of generating an active radical, an acid or the like by the action of light or heat and initiating polymerization, and a known polymerization initiator can be used.
Examples of the polymerization initiator (D) include O-acyloxime compounds, alkylphenone compounds, biimidazole compounds, triazine compounds, and acylphosphine oxide compounds.

  Examples of the O-acyloxime compound include N-benzoyloxy-1- (4-phenylsulfanylphenyl) butan-1-one-2-imine, N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane- 1-one-2-imine, N-benzoyloxy-1- (4-phenylsulfanylphenyl) -3-cyclopentylpropane-1-one-2-imine, N-acetoxy-1- (4-phenylsulfanylphenyl)- 3-cyclopentylpropane-1-one-2-imine, N-acetoxy-1- (4-phenylsulfanylphenyl) -3-cyclohexylpropan-1-one-2-imine, N-acetoxy-1- [9-ethyl -6- (2-Methylbenzoyl) -9H-carbazol-3-yl] ethane-1-y N-acetoxy-1- [9-ethyl-6- {2-methyl-4- (3,3-dimethyl-2,4-dioxacyclopentanylmethyloxy) benzoyl} -9H-carbazole-3- Yl] ethane-1-imine, N-acetoxy-1- [9-ethyl-6- (2-methylbenzoyl) -9H-carbazol-3-yl] -3-cyclopentylpropane-1-imine and N-benzoyloxy Examples include -1- [9-ethyl-6- (2-methylbenzoyl) -9H-carbazol-3-yl] -3-cyclopentylpropan-1-one-2-imine. Moreover, as O-acyl oxime compounds, commercially available products such as Irgacure OXE01, OXE02 (above, manufactured by BASF Corporation) and N-1919 (produced by ADEKA Corporation) may be used. Among these, as O-acyloxime compounds, N-benzoyloxy-1- (4-phenylsulfanylphenyl) butan-1-one-2-imine, N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane- Preferred is at least one selected from the group consisting of 1-one-2-imine and N-benzoyloxy-1- (4-phenylsulfanylphenyl) -3-cyclopentylpropane-1-one-2-imine, and N-benzoyl Oxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine is more preferred.

Examples of the alkylphenone compound include 2-methyl-2-morpholino-1- (4-methylsulfanylphenyl) propan-1-one, 2-dimethylamino-1- (4-morpholinophenyl) -2-benzylbutane-1- ON and 2- (dimethylamino) -2-[(4-methylphenyl) methyl] -1- [4- (4-morpholinyl) phenyl] butan-1-one. Commercial products such as Irgacure 369, 907, 379 (above, manufactured by BASF Corporation) may be used as the alkylphenone compound.
Examples of the alkylphenone compound include 2-hydroxy-2-methyl-1-phenylpropan-1-one, 2-hydroxy-2-methyl-1- [4- (2-hydroxyethoxy) phenyl] propan-1-one, Mention may also be made of 1-hydroxycyclohexyl phenyl ketone, oligomers of 2-hydroxy-2-methyl-1- (4-isopropenylphenyl) propan-1-one, α, α-diethoxyacetophenone and benzyldimethyl ketal.

  Examples of the biimidazole compound include 2,2′-bis (2-chlorophenyl) -4,4 ′, 5,5′-tetraphenylbiimidazole and 2,2′-bis (2,3-dichlorophenyl) -4. , 4 ′, 5,5′-tetraphenylbiimidazole (see, for example, JP-A-6-75372 and JP-A-6-75373), 2,2′-bis (2-chlorophenyl) -4, 4 ′, 5,5′-tetra (alkoxyphenyl) biimidazole, 2,2′-bis (2-chlorophenyl) -4,4 ′, 5,5′-tetra (dialkoxyphenyl) biimidazole, 2,2 '-Bis (2-chlorophenyl) -4,4', 5,5'-tetra (trialkoxyphenyl) biimidazole (for example, Japanese Patent Publication No. 48-38403, Japanese Patent Laid-Open No. 62-17420) No. See Publication.) And 4,4 ', imidazole compounds phenyl group 5,5'-position is substituted by carbalkoxy group (for example, see Publication No. Hei 7-10913) and the like.

  As triazine compounds, 2,4-bis (trichloromethyl) -6- (4-methoxyphenyl) -1,3,5-triazine, 2,4-bis (trichloromethyl) -6- (4-methoxynaphthyl) -1,3,5-triazine, 2,4-bis (trichloromethyl) -6-piperonyl-1,3,5-triazine, 2,4-bis (trichloromethyl) -6- (4-methoxystyryl)- 1,3,5-triazine, 2,4-bis (trichloromethyl) -6- [2- (5-methylfuran-2-yl) ethenyl] -1,3,5-triazine, 2,4-bis ( Trichloromethyl) -6- [2- (furan-2-yl) ethenyl] -1,3,5-triazine, 2,4-bis (trichloromethyl) -6- [2- (4-diethylamino-2-methyl) Phenyl) ethenyl ] -1,3,5-triazine and 2,4-bis (trichloromethyl) -6- [2- (3,4-dimethoxyphenyl) ethenyl] -1,3,5-triazine.

  Examples of the acylphosphine oxide compound include 2,4,6-trimethylbenzoyldiphenylphosphine oxide.

Furthermore, as the polymerization initiator (D), benzoin compounds such as benzoin, benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether, benzoin isobutyl ether; benzophenone, methyl o-benzoylbenzoate, 4-phenylbenzophenone, 4-benzoyl- Benzophenone compounds such as 4′-methyldiphenyl sulfide, 3,3 ′, 4,4′-tetra (tert-butylperoxycarbonyl) benzophenone and 2,4,6-trimethylbenzophenone; 9,10-phenanthrenequinone, Examples include quinone compounds such as 2-ethylanthraquinone and camphorquinone; 10-butyl-2-chloroacridone, benzyl, methyl phenylglyoxylate, and titanocene compounds.
These are preferably used in combination with a polymerization initiation assistant (D1) (particularly amines) described later.

  The polymerization initiator (D) is preferably a polymerization initiator containing at least one selected from the group consisting of alkylphenone compounds, triazine compounds, acylphosphine oxide compounds, O-acyloxime compounds and biimidazole compounds, more preferably It is a polymerization initiator containing an O-acyloxime compound.

  The content of the polymerization initiator (D) is preferably 0.001 to 40% by mass and more preferably 0.01 to 30% by mass in the total amount of solid content in the colored curable composition.

  The colored curable composition of the present invention may contain a polymerization initiation assistant (D1).

<Polymerization initiation aid (D1)>
The polymerization initiation assistant (D1) is a compound or a sensitizer used for accelerating the polymerization of the polymerizable compound that has been polymerized by the polymerization initiator. When the polymerization initiation assistant (D1) is contained, it is usually used in combination with the polymerization initiator (D).
Examples of the polymerization initiation aid (D1) include amine compounds, alkoxyanthracene compounds, thioxanthone compounds, and carboxylic acid compounds.

  Examples of amine compounds include triethanolamine, methyldiethanolamine, triisopropanolamine, methyl 4-dimethylaminobenzoate, ethyl 4-dimethylaminobenzoate, isoamyl 4-dimethylaminobenzoate, 2-dimethylaminoethyl benzoate, 4- 2-ethylhexyl dimethylaminobenzoate, N, N-dimethylparatoluidine, 4,4′-bis (dimethylamino) benzophenone (commonly known as Michler's ketone), 4,4′-bis (diethylamino) benzophenone and 4,4′-bis ( Ethylmethylamino) benzophenone and the like, preferably 4,4′-bis (diethylamino) benzophenone. Moreover, you may use commercial items, such as EAB-F (made by Hodogaya Chemical Co., Ltd.), as an amine compound.

  Examples of the alkoxyanthracene compound include 9,10-dimethoxyanthracene, 2-ethyl-9,10-dimethoxyanthracene, 9,10-diethoxyanthracene, 2-ethyl-9,10-diethoxyanthracene, and 9,10-dibutoxy. Anthracene and 2-ethyl-9,10-dibutoxyanthracene are exemplified.

  Examples of the thioxanthone compound include 2-isopropylthioxanthone, 4-isopropylthioxanthone, 2,4-diethylthioxanthone, 2,4-dichlorothioxanthone, and 1-chloro-4-propoxythioxanthone.

  Carboxylic acid compounds include phenylsulfanyl acetic acid, methylphenylsulfanyl acetic acid, ethylphenylsulfanyl acetic acid, methylethylphenylsulfanyl acetic acid, dimethylphenylsulfanyl acetic acid, methoxyphenylsulfanyl acetic acid, dimethoxyphenylsulfanyl acetic acid, chlorophenylsulfanyl acetic acid, dichlorophenylsulfanyl acetic acid, N -Phenylglycine, phenoxyacetic acid, naphthylthioacetic acid, N-naphthylglycine, naphthoxyacetic acid and the like.

  When using these polymerization initiation assistants (D1), the content is preferably 0.001 to 30% by mass, more preferably 0.01 to 30% by mass in the total amount of solids in the colored curable composition. 20% by mass.

  The coloring composition of the present invention may further contain a leveling agent (F) and an antioxidant.

<Leveling agent (F)>
Examples of the leveling agent (F) include silicone surfactants, fluorine surfactants, and silicone surfactants having a fluorine atom. These may have a polymerizable group in the side chain.
Examples of the silicone surfactant include a surfactant having a siloxane bond in the molecule. Specifically, Torre Silicone DC3PA, SH7PA, DC11PA, SH21PA, SH28PA, SH29PA, SH30PA, SH8400 (trade names: manufactured by Toray Dow Corning Co., Ltd.), KP321, KP322, KP323, KP324 , KP326, KP340, KP341 (manufactured by Shin-Etsu Chemical Co., Ltd.), TSF400, TSF401, TSF410, TSF4300, TSF4440, TSF4445, TSF4446, TSF4452 and TSF4460 (made by Momentive Performance Materials Japan GK) .

  Examples of the fluorosurfactant include a surfactant having a fluorocarbon chain in the molecule. Specifically, Florard (registered trademark) FC430, FC431 (manufactured by Sumitomo 3M Co., Ltd.), MegaFac (registered trademark) F142D, F171, F172, F173, F177, F183, F183, F554, R30, RS-718-K (manufactured by DIC Corporation), Ftop (registered trademark) EF301, EF303, EF351, EF352 (manufactured by Mitsubishi Materials Electronic Chemicals), Surflon (registered trademark) S381, S382, SC101, SC105 (Asahi Glass Co., Ltd.) and E5844 (Daikin Fine Chemical Laboratory Co., Ltd.).

  Examples of the silicone-based surfactant having a fluorine atom include a surfactant having a siloxane bond and a fluorocarbon chain in the molecule. Specifically, Megafac (registered trademark) R08, BL20, F475, F477, F443 (manufactured by DIC Corporation), and the like can be given.

  When the leveling agent (F) is contained, the content is usually 0.0005% by mass or more and 1% by mass or less, preferably 0.001% by mass or more and 0.5% by mass with respect to the total amount of the colored composition. % Or less, more preferably 0.001% by mass or more and 0.2% by mass or less, further preferably 0.002% by mass or more and 0.1% by mass or less, and particularly preferably 0.005% by mass or more. It is 0.1 mass% or less. When the content of the leveling agent (F) is in the above range, the flatness of the color filter can be improved.

<Antioxidant>
From the viewpoint of improving the heat resistance and light resistance of the colorant, it is preferable to use an antioxidant alone or in combination of two or more. The antioxidant is not particularly limited as long as it is an antioxidant generally used industrially, and a phenol-based antioxidant, a phosphorus-based antioxidant, a sulfur-based antioxidant, and the like can be used.

  Examples of the phenol-based antioxidant include Irganox 1010 (Irganox 1010: pentaerythritol tetrakis [3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate], manufactured by BASF Corporation). Irganox 1076 (Irganox 1076: octadecyl-3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate, manufactured by BASF Corporation), Irganox 1330 (Irganox 1330: 3, 3 ′, 3 ′ ', 5,5', 5 ''-hexa-tert-butyl-a, a ', a' '-(mesitylene-2,4,6-triyl) tri-p-cresol, manufactured by BASF Corporation), Irganox 3114: 1,3,5-Tris (3,5 Di-tert-butyl-4-hydroxybenzyl) -1,3,5-triazine-2,4,6 (1H, 3H, 5H) -trione, manufactured by BASF Corp.), Irganox 3790: 1 , 3,5-tris ((4-tert-butyl-3-hydroxy-2,6-xylyl) methyl) -1,3,5-triazine-2,4,6 (1H, 3H, 5H) -trione, BASF Corp.), Irganox 1035 (Irganox 1035: Thiodiethylenebis [3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate], BASF Corp.), Irganox 1135 ( Irganox 1135: benzenepropanoic acid, 3,5-bis (1,1-dimethylethyl) -4-hydroxy, C7-C9 side chain Rukirester, manufactured by BASF), Irganox 1520L (Irganox 1520L: 4,6-bis (octylthiomethyl) -o-cresol, manufactured by BASF), Irganox 3125 (Irganox 3125, BASF) Irganox 565: 2,4-bis (n-octylthio) -6- (4-hydroxy3 ′, 5′-di-tert-butylanilino) -1,3,5-triazine, BASF ( Adeka Stub AO-80 (Adeka Stub AO-80: 3,9-bis (2- (3- (3-tert-butyl-4-hydroxy-5-methylphenyl) propionyloxy) -1,1- Dimethylethyl) -2,4,8,10-tetraoxaspiro (5,5) undecane, AD Co., Ltd. KA), Sumilizer BHT (Sumilizer BHT, manufactured by Sumitomo Chemical Co., Ltd.), Sumilizer GA-80 (Sumizer GA-80, manufactured by Sumitomo Chemical Co., Ltd.), Sumizer GS (Sumizer GS, manufactured by Sumitomo Chemical Co., Ltd.), Examples include Cyanox 1790 (Cyanox 1790, manufactured by Cytec Co., Ltd.) and Vitamin E (produced by Eisai Co., Ltd.).

  Examples of the phosphorus antioxidant include Irgafos 168 (Irgafos 168: Tris (2,4-di-tert-butylphenyl) phosphite, manufactured by BASF Corporation), Irgafos 12 (Irgafos 12: Tris [2- [[2,4,8,10-tetra-tert-butyldibenzo [d, f] [1,3,2] dioxaphosphin-6-yl] oxy] ethyl] amine, manufactured by BASF Corp.) Irgafos 38 (Irgafos 38: bis (2,4-bis (1,1-dimethylethyl) -6-methylphenyl) ethyl ester phosphorous acid, manufactured by BASF Corp.), Adekastab 329K (produced by ADEKA Corp.), ADK STAB PEP36 (manufactured by ADEKA), ADK STAB PEP-8 (manufactured by ADEKA), Sandst b P-EPQ (manufactured by Clariant), Weston 618 (manufactured by Weston 618, GE), Weston 619G (manufactured by Weston 619G, GE), Ultranox 626 (manufactured by Ultranox 626, manufactured by GE) and Sumilizer GP (Sumilizer GP): 6- [3- (3-tert-Butyl-4-hydroxy-5-methylphenyl) propoxy] -2,4,8,10-tetra-tert-butyldibenz [d, f] [1.3.2] di Oxaphosphepine) (manufactured by Sumitomo Chemical Co., Ltd.).

  Examples of the sulfur-based antioxidant include dialkylthiodipropionate compounds such as dilauryl thiodipropionate, dimyristyl, and distearyl, and β-alkyl mercaptopropion of polyols such as tetrakis [methylene (3-dodecylthio) propionate] methane. Examples include acid ester compounds.

<Other ingredients>
The coloring composition of the present invention may contain additives known in the art, such as a filler, other polymer compound, an adhesion promoter, a light stabilizer, and a chain transfer agent, if necessary.
Examples of the adhesion promoter include vinyltrimethoxysilane, vinyltriethoxysilane, vinyltris (2-methoxyethoxy) silane, 3-glycidyloxypropyltrimethoxysilane, 3-glycidoxypropylmethyldimethoxysilane, and 3-glycid. Xylpropylmethyldimethoxysilane, 3-glycidoxypropylmethyldiethoxysilane, 2- (3,4-epoxycyclohexyl) ethyltrimethoxysilane, 3-chloropropylmethyldimethoxysilane, 3-chloropropyltrimethoxysilane, 3- Methacryloyloxypropyltrimethoxysilane, 3-mercaptopropyltrimethoxysilane, 3-sulfanylpropyltrimethoxysilane, 3-isocyanatopropyltriethoxysilane, N-2- (aminoethyl) -3-aminopropylmethyldimethoxysilane, N-2- (aminoethyl) -3-aminopropylmethyldiethoxysilane, N-2- (aminoethyl) -3-aminopropyltrimethoxysilane, N-2- (amino Ethyl) -3-aminopropylmethyldiethoxysilane, 3-aminopropyltrimethoxysilane, 3-aminopropyltriethoxysilane, N-phenyl-3-aminopropyltrimethoxysilane, N-phenyl-3-aminopropyltriethoxy Silane etc. are mentioned.

<Color filter>
A color filter can be formed from the colored composition or colored curable composition of the present invention. Examples of the method for forming the colored pattern include a photolithographic method, an ink jet method, a printing method, and the like, and a photolithographic method is preferable. In the photolithographic method, the colored curable composition is applied to a substrate, dried to form a colored curable composition layer, and the colored curable composition layer is exposed through a photomask and developed. It is. In the photolithographic method, the colored curable composition preferably contains a polymerization initiator (D). In the photolithography method, a colored coating film that is a cured product of the colored curable composition layer can be formed by not using a photomask and / or not developing during exposure. The colored pattern and the colored coating film thus formed can be used as the color filter of the present invention.
The film thickness of the color filter to be produced is not particularly limited, and can be appropriately adjusted according to the purpose and application, for example, 0.1 to 30 μm, preferably 0.1 to 20 μm, and more preferably. Is 0.5-6 μm.

  As the substrate, a glass plate, a resin plate, silicon, or an aluminum, silver, silver / copper / palladium alloy thin film formed on the substrate is used. On these substrates, another color filter layer, a resin layer, a transistor, a circuit, or the like may be formed.

Formation of each color pixel by the photolithographic method can be performed by a known or commonly used apparatus and conditions. For example, it can be produced as follows.
First, a colored curable composition is applied onto a substrate, dried by heating (prebaking) and / or drying under reduced pressure to remove volatile components such as a solvent, and a smooth colored curable composition layer is obtained.
Examples of the coating method include spin coating, slit coating, and slit and spin coating.

  Next, the colored curable composition layer is exposed through a photomask for forming a target colored pattern. An exposure apparatus such as a mask aligner and a stepper can be used to irradiate parallel light uniformly on the entire exposure surface and to perform accurate alignment between the photomask and the substrate on which the colored curable composition layer is formed. It is preferable to use it.

A colored pattern is formed on the substrate by developing the exposed colored curable composition layer in contact with a developer. By the development, the unexposed portion of the colored curable composition layer is dissolved and removed in the developer.
As the developer, for example, an aqueous solution of an alkaline compound such as potassium hydroxide, sodium hydrogen carbonate, sodium carbonate and tetramethylammonium hydroxide is preferable.
The developing method may be any of paddle method, dipping method, spray method and the like. Further, the substrate may be tilted at an arbitrary angle during development.
The substrate after development is preferably washed with water.
Furthermore, it is preferable to post-bake the obtained colored pattern.

  The color filter is useful as a color filter used for a display device (for example, a liquid crystal display device, an organic EL device, electronic paper, etc.) and a solid-state imaging device, and particularly as a color filter used for a liquid crystal display device.

  EXAMPLES Hereinafter, the present invention will be described more specifically with reference to examples. However, the present invention is not limited by the following examples, but may be appropriately modified within a range that can meet the purpose described above and below. Of course, it is possible to implement them, and they are all included in the technical scope of the present invention. In the following, “part” means “part by mass” and “%” means “mass%” unless otherwise specified.

  In the following synthesis examples, the structure of the compound was confirmed by NMR (JMM-ECA-500; manufactured by JEOL Ltd.) or mass spectrometry (LC; Agilent 1200 model, MASS; Agilent LC / MSD6130 model).

The polystyrene-reduced weight average molecular weight (Mw) and number average molecular weight (Mn) of the resin were measured by the GPC method under the following conditions.
Apparatus: HLC-8120GPC (manufactured by Tosoh Corporation)
Column: TSK-GELG2000HXL
Column temperature: 40 ° C
Solvent: Tetrahydrofuran Flow rate: 1.0 mL / min Analysis sample solid content concentration: 0.001 to 0.01% by mass
Injection volume: 50 μL
Detector: RI
Calibration standard materials: TSK STANDARD POLYSTYRENE F-40, F-4, F-288, A-2500, A-500 (manufactured by Tosoh Corporation)
The ratio (Mw / Mn) of the weight average molecular weight (Mw) and number average molecular weight (Mn) in terms of polystyrene obtained above was defined as the dispersity.

[Example Z1]
Example 1Z1
36.2 parts of 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 526 parts of methanol were mixed.
While maintaining the temperature at 5 ° C., a mixture of 20.9 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 10 parts of methanol was added dropwise to the obtained mixture over 1 hour.
The resulting mixture was stirred at 5 ° C. for 4 hours.
While maintaining the temperature at 5 ° C. or lower, 13.1 parts of acetic acid and 23.7 parts of ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) were added to the obtained mixture.
The resulting mixture was stirred at 5 ° C. for 1 hour and then at room temperature for 3 days.
To the obtained mixture, 2.37 parts of ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) and 231 parts of methanol were added and stirred at room temperature for 1 day.
To the obtained mixture, 0.496 parts of ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) and 26 parts of methanol were added and stirred at 40 ° C. for 2 hours and 30 minutes.
To the obtained mixture, 17.1 parts of acetic acid, 26.9 parts of barbituric acid and 793 parts of water were added and stirred at 40 ° C. for 2 hours.
17.0 parts of acetic acid, 26.9 parts of barbituric acid, 12 parts of methanol and 12 parts of water were added to the resulting mixture, and the mixture was stirred at 40 ° C. for 30 minutes and then stirred at room temperature for 2 days.
The resulting mixture was filtered, and the residue was washed once with 915 parts of 50% aqueous methanol solution, once with 950 parts of 50% aqueous methanol solution, once with 1600 parts of 50% aqueous methanol solution and once with 1800 parts of water.
The obtained residue was recrystallized using N, N-dimethylformamide to obtain 30.7 parts of a mixture of the compound represented by the formula (IZ1-38) and the compound represented by the formula (IZ1-39). .

<Identification of compound represented by formula (IZ1-38)>
(Mass spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 384
Exact Mass: 383

<Identification of Compound Represented by Formula (IZ1-39)>
(Mass Spectrometry) Ionization Mode = ESI +: m / z = [M + H] ⁺ 398
Exact Mass: 397

Example 2Z1
The same procedure as in Example 1Z1 was conducted except that 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) was replaced with 4-tert-butylphthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.), and the formula (IZ1 A mixture of the compound represented by −20) and the compound represented by formula (IZ1-21) was obtained.

<Identification of Compound Represented by Formula (IZ1-20)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 395
Exact Mass: 394

<Identification of Compound Represented by Formula (IZ1-21)>
(Mass spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 409
Exact Mass: 408

Example 3Z1
The same procedure as in Example 1Z1 was conducted except that 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) was replaced by phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.), and represented by the formula (IZ1-2) To a compound of the formula (IZ1-3).

<Identification of Compound Represented by Formula (IZ1-2)>
(Mass spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 339
Exact Mass: 338

<Identification of compound represented by formula (IZ1-3)>
(Mass Spectrometry) ionization mode = ESI +: m / z = [M + H] + 353
Exact Mass: 352

Example 4Z1
Except for replacing ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) with methyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.), this is carried out in the same manner as in Example 1Z1 and represented by the formula (IZ1-38). A compound was obtained.

<Identification of compound represented by formula (IZ1-38)>
(Mass spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 384
Exact Mass: 383

Example 5Z1
4-Nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) is replaced with 4-tert-butylphthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.), and ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) is used. The compound represented by the formula (IZ1-20) was obtained in the same manner as in Example 1Z1 except that methyl cyanoacetate (Tokyo Chemical Industry Co., Ltd.) was used.

<Identification of Compound Represented by Formula (IZ1-20)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 395
Exact Mass: 394

Example 6Z1
4-Nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) is replaced with phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.), and ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) is replaced by methyl cyanoacetate (Tokyo Chemical Industry Co., Ltd.). Except having replaced with Kogyo Co., Ltd., it implemented similarly to Example 1Z1 and obtained the compound represented by a formula (IZ1-2).

<Identification of Compound Represented by Formula (IZ1-2)>
(Mass spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 339
Exact Mass: 338

Example 7Z1
10.0 parts of 4-tert-butylphthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 84 parts of methanol were mixed. While maintaining the temperature at 5 ° C. or lower, a mixture of 8.15 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 73 parts of methanol was dropped into the obtained mixture over 1 hour. The resulting mixture was stirred at 5-20 ° C. for 2 days.
Under 10 to 20 ° C., 5.42 parts of acetic acid and 6.14 parts of ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) were added to the obtained mixture. The resulting mixture was stirred at 65 ° C. for 3 days. To the obtained mixture, 2.69 parts of acetic acid and 3.07 ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) were added and stirred at 65 ° C. for 3 days. By this time, a total of 206 parts of methanol was added in addition to the methanol described above.
To the obtained mixture, 5.36 parts of acetic acid, 7.25 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.) and 363 parts of water were added and stirred at 65 ° C. for 9 days.
After distilling off the solvent of the obtained mixture with a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ1-20) and a compound represented by the formula (IZ1-21). A mixture was obtained.

<Identification of Compound Represented by Formula (IZ1-20)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 395
Exact Mass: 394

<Identification of Compound Represented by Formula (IZ1-21)>
(Mass spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 409
Exact Mass: 408

Example 8Z1
2.57 parts of phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 24.5 parts of methanol were mixed.
Under room temperature, 2.00 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) was added to the obtained mixture.
The resulting mixture was stirred at 43 ° C. for 1 hour 30 minutes.
To the obtained mixture, 2.53 parts of ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.), 1.26 parts of acetic acid and 54.5 parts of methanol were added and stirred at 40 ° C. for 1 hour and 30 minutes.
To the obtained mixture, 2.84 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.), 1.63 parts of acetic acid and 9 parts of methanol were added and stirred at 40 ° C. for 1 hour.
After distilling off the solvent of the obtained mixture with a rotary evaporator, the obtained residue was purified by column chromatography. A mixture was obtained.

<Identification of Compound Represented by Formula (IZ1-2)>
(Mass spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 339
Exact Mass: 338

<Identification of compound represented by formula (IZ1-3)>
(Mass Spectrometry) ionization mode = ESI +: m / z = [M + H] + 353
Exact Mass: 352

Example 9Z1
10.0 parts of 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 149 parts of methanol were mixed. While maintaining the temperature at 2 to 6 ° C., 5.86 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) was dropped into the obtained mixture over 20 minutes. The resulting mixture was stirred for 5 hours while maintaining at 5 ° C. or lower.
While maintaining the resulting mixture at 5 ° C. or lower, 5.79 parts of acetic acid, 5.72 parts of methyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) and 74 parts of methanol were added. The resulting mixture was stirred at 65 ° C. for 3 days.
To the obtained mixture, 2.88 parts of acetic acid and 2.86 parts of methyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) were added.
The resulting mixture was stirred at 65 ° C. for 3 days.
By this time, in addition to the methanol described above, a total of 140 parts of methanol was added.
To the obtained mixture, 24.0 parts of acetic acid, 15.3 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.) and 363 parts of water were added and stirred at 65 ° C. for 9 days.
After distilling off the solvent of the obtained mixture with a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ1-38).

<Identification of compound represented by formula (IZ1-38)>
(Mass spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 384
Exact Mass: 383

Example 10Z1
10.0 parts of 4-tert-butylphthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 84 parts of methanol were mixed. While maintaining the temperature at 5 ° C. or lower, a mixture of 8.15 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 73 parts of methanol was dropped into the obtained mixture over 1 hour. The resulting mixture was stirred at 5-20 ° C. for 2 days.
Under 10 to 20 ° C., 5.42 parts of acetic acid and 5.38 parts of methyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) were added to the obtained mixture. The resulting mixture was stirred at 65 ° C. for 3 days.
To the obtained mixture, 2.69 parts of acetic acid and 2.69 of methyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) were added and stirred at 65 ° C. for 3 days.
By this time, a total of 206 parts of methanol was added in addition to the methanol described above.
To the obtained mixture, 5.36 parts of acetic acid, 7.25 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.) and 363 parts of water were added and stirred at 65 ° C. for 9 days.
After distilling off the solvent of the obtained mixture with a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ1-20).

<Identification of Compound Represented by Formula (IZ1-20)>
(Mass spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 395
Exact Mass: 394

Example 11Z1
60.0 parts of phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 501 parts of methanol were mixed.
While maintaining the temperature at 2 ° C., 46.7 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) was dropped into the obtained mixture over 15 minutes.
The resulting mixture was stirred for 5 hours while keeping the temperature at 2 ° C to 6 ° C.
While maintaining the temperature at 5 ° C. or lower, 556 parts of methanol was added to the mixture.
To this mixture, 29.3 parts of acetic acid, 46.5 parts of methyl cyanoacetate and 22 parts of methanol were added.
The mixture was stirred at room temperature for 12 hours and then stirred at 40 ° C. for 3 hours and 20 minutes.
This mixture was mixed with 3.00 parts of acetic acid and 4.71 parts of methyl cyanoacetate and stirred at 40 ° C. for 1 hour and 25 minutes.
This mixture was mixed with 2.98 parts of acetic acid and 4.71 parts of methyl cyanoacetate and stirred at 40 ° C. for 2 hours.
This mixture was mixed with 2.96 parts of acetic acid and 4.70 parts of methyl cyanoacetate, and stirred at 40 ° C. for 2 hours.
This mixture was mixed with 1.50 parts of acetic acid and 2.40 parts of methyl cyanoacetate.
By this time, a total of 111 parts of methanol was added in addition to the methanol described above.
The resulting mixture was stirred at 40 ° C. for 1 hour and 40 minutes.
To the obtained mixture, 38.1 parts of acetic acid and 60.6 parts of barbituric acid were added and stirred at 40 ° C. for 42 hours.
By this time, a total of 66 parts of methanol was added in addition to the methanol described above.
The mixture was filtered and the residue was washed 6 times with 400 parts of methanol.
This residue was purified by column chromatography to obtain a compound represented by the formula (IZ1-2).

<Identification of Compound Represented by Formula (IZ1-2)>
(Mass Spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 339
Exact Mass: 338

Example 12Z1
5.0 parts of 4,5-dichlorophthalonitrile and 62 parts of methanol were mixed.
While maintaining this mixture at 5 ° C. or lower, a 25% sodium methoxide methanol solution containing sodium methoxide having a mole number 0.5 times that of 5.0 parts of 4,5-dichlorophthalonitrile was added.
The mixture was stirred at 5 ° C. or lower for 5 hours.
While maintaining the temperature at 5 ° C. or lower, methyl cyanoacetate and 6.1 parts of acetic acid having a mole number 1.5 times that of 5.0 parts of 4,5-dichlorophthalonitrile were added to the mixture.
The mixture was stirred at 65 ° C. for 3 days.
This mixture was mixed with 4.2 parts of acetic acid, 5.2 parts of barbituric acid, 500 parts of methanol and 562 parts of water, and stirred at 65 ° C. for 9 days.
After the solvent of this mixture was distilled off with a rotary evaporator, the obtained residue was purified by column chromatography to obtain 0.297 parts of a compound represented by the formula (IZ1-258).

<Identification of Compound Represented by Formula (IZ1-258)>
(Mass spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 407
Exact Mass: 406

Example 13Z1
25.9 parts of phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 513 parts of methanol were mixed.
While maintaining the temperature at 3 ° C to 5 ° C, a mixture of 30.3 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 12 parts of methanol was added dropwise over 10 minutes. .
The resulting mixture was stirred for 6 hours while maintaining at 3 ° C to 5 ° C.
While maintaining the temperature at 3 ° C. to 5 ° C., 19.8 parts of acetic acid, 28.5 parts of tert-butyl cyanoacetate and 26 parts of methanol were added to the obtained mixture.
The resulting mixture was stirred at room temperature for 2 days and then stirred at 40 ° C. for 3 hours.
To the resulting mixture, 5.09 parts of acetic acid and 7.17 parts of tert-butyl cyanoacetate were added and stirred at 40 ° C. for 4 hours.
To the obtained mixture, 4.95 parts of acetic acid, 7.15 parts of tert-butyl cyanoacetate and 38 parts of methanol were added and stirred at 40 ° C. for 16 hours.
To the obtained mixture, 19.9 parts of acetic acid, 25.8 parts of barbituric acid, 209 parts of methanol, and 800 parts of water were added and stirred at 40 ° C. for 3 hours.
The resulting mixture was filtered to obtain a residue.
This residue was purified by column chromatography to obtain a compound represented by the formula (IZ1-5).

<Identification of Compound Represented by Formula (IZ1-5)>
(Mass spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 381
Exact Mass: 380

Example 14Z1
15.1 parts of 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 284 parts of methanol were mixed.
While maintaining the temperature at 5 ° C. or lower, a mixture of 8.81 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 18 parts of methanol was dropped into the obtained mixture over 10 minutes.
The resulting mixture was stirred for 4 hours while maintaining the temperature at 5 ° C. or lower.
While maintaining the temperature at 5 ° C. or lower, 5.55 parts of acetic acid was added to the obtained mixture and stirred for 30 minutes.
This mixture was mixed with 12.3 parts of tert-butyl cyanoacetate and stirred at 40 ° C. for 14 hours.
This mixture was mixed with 0.654 parts of acetic acid and 1.24 parts of tert-butyl cyanoacetate and stirred at 40 ° C. for 4 hours.
This mixture was mixed with 0.613 parts of acetic acid and 1.23 parts of tert-butyl cyanoacetate and stirred at 40 ° C. for 3 hours.
This mixture was mixed with 0.647 parts of acetic acid and 1.24 parts of tert-butyl cyanoacetate. By this time, a total of 89 parts of methanol was added in addition to the methanol described above.
The mixture was stirred at 40 ° C. for 17 hours.
This mixture was mixed with 7.14 parts of acetic acid, 11.3 parts of barbituric acid, and 508 parts of water. By this time, in addition to the methanol described above, a total of 117 parts of methanol was added.
The mixture was stirred at 40 ° C. for 24 hours.
This mixture was mixed with 3.65 parts of acetic acid and 5.61 parts of barbituric acid, and stirred at 40 ° C. for 9 hours and at room temperature for 2 days.
The mixture was filtered, and the residue was washed 3 times with 1330 parts of 50% aqueous methanol.
The obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ1-41).

<Identification of Compound Represented by Formula (IZ1-41)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 426
Exact Mass: 425

Synthesis example 1
An appropriate amount of nitrogen was passed through a flask equipped with a reflux condenser, a dropping funnel and a stirrer to replace the nitrogen atmosphere, and 280 parts of propylene glycol monomethyl ether acetate was added and heated to 80 ° C. with stirring. Next, 38 parts of acrylic acid, 3,4-epoxytricyclo [5.2.1.0 ^2,6 ] decan-8-yl acrylate and 3,4-epoxytricyclo [5.2.1.0 ^{2, 6} ] A mixed solution of 289 parts of decan-9-yl acrylate and 125 parts of propylene glycol monomethyl ether acetate was added dropwise over 5 hours. On the other hand, a mixed solution prepared by dissolving 33 parts of 2,2-azobis (2,4-dimethylvaleronitrile) in 235 parts of propylene glycol monomethyl ether acetate was added dropwise over 6 hours. After the completion of dropping, the mixture was kept at the same temperature for 4 hours, and then cooled to room temperature to obtain a copolymer (resin B1) solution having a solid content of 35.0%. The obtained resin B1 had a weight average molecular weight (Mw) of 8,800, a dispersity of 2.1, and a solution acid value of 28 mg-KOH / g.

Synthesis example 2
A suitable amount of nitrogen was passed through a flask equipped with a reflux condenser, a dropping funnel and a stirrer to replace the nitrogen atmosphere, and 371 parts of propylene glycol monomethyl ether acetate was added and heated to 85 ° C. with stirring. Then 54 parts acrylic acid, 3,4-epoxy tricyclo [5.2.1.0 ^2,6 ] decan-8-yl acrylate and 3,4-epoxy tricyclo [5.2.1.0 ^{2, 6} ] A mixed solution of 225 parts of decan-9-yl acrylate, 81 parts of vinyltoluene (isomer mixture) and 80 parts of propylene glycol monomethyl ether acetate was added dropwise over 4 hours. On the other hand, a solution prepared by dissolving 30 parts of a polymerization initiator 2,2-azobis (2,4-dimethylvaleronitrile) in 160 parts of propylene glycol monomethyl ether acetate was added dropwise over 5 hours. After completion of the dropwise addition of the initiator solution, the solution was kept at the same temperature for 4 hours and then cooled to room temperature to obtain a copolymer (resin B3) solution having a solid content of 37.5%. The obtained resin B3 had a weight average molecular weight (Mw) of 10,600, a dispersity of 2.01, and a solution acid value of 43 mg-KOH / g.

Synthesis example 3
An appropriate amount of nitrogen was passed through a flask equipped with a reflux condenser, a dropping funnel and a stirrer to replace the nitrogen atmosphere, and 350 parts of propylene glycol monomethyl ether acetate was added and heated to 85 ° C. with stirring. Then 70 parts acrylic acid, 3,4-epoxytricyclo [5.2.1.0 ^2,6 ] decan-8-yl acrylate and 3,4-epoxytricyclo [5.2.1.0 ^{2, 6} ] A mixed solution of 202 parts of decan-9-yl acrylate, 78 parts of vinyltoluene (isomer mixture) and 100 parts of propylene glycol monomethyl ether acetate was added dropwise over 4 hours. On the other hand, a solution obtained by dissolving 33 parts of a polymerization initiator 2,2-azobis (2,4-dimethylvaleronitrile) in 167 parts of propylene glycol monomethyl ether acetate was added dropwise over 5 hours. After completion of the dropwise addition of the initiator solution, the solution was kept at the same temperature for 4 hours and then cooled to room temperature to obtain a copolymer (resin B5) solution having a solid content of 38.1%. The obtained resin B5 had a weight average molecular weight (Mw) of 10,400, a dispersity of 2.03, and a solution acid value of 53 mg-KOH / g.

Example 101Z1
Pigment: C.I. I. Pigment Green 58 60 parts,
8.1 parts of an acrylic pigment dispersant,
Resin (B): 73 parts of resin B5 solution and solvent (E): 290 parts of propylene glycol monomethyl ether acetate were mixed, and a pigment dispersion (colorant (A1Z1) -containing liquid) in which the pigment was dispersed using a bead mill was prepared. Prepared.
Separately
Colorant (AZ1): 50 parts of a mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39)
Dispersant (BYK-LPN6919; manufactured by Big Chemie Japan Co., Ltd.) 58 parts,
Compound represented by formula (IZ1-38) obtained in Example 1Z1 by mixing resin (B): 93 parts of resin B3 solution and solvent (E): 800 parts of propylene glycol monomethyl ether acetate and using a bead mill. And a mixture of the compound represented by the formula (IZ1-39) were dispersed to obtain a colored composition.
Then
Total amount of the obtained pigment dispersion (colorant (A1Z1) -containing liquid);
400 parts of the resulting colored composition;
Resin (B): Resin B1 solution 45 parts;
Polymerizable compound (C): 25 parts of dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kayaku Co., Ltd.);
Polymerization initiator (D): N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure (registered trademark) OXE-01; manufactured by BASF Corporation) 15 parts;
Solvent (E): 86 parts of propylene glycol monomethyl ether acetate; and leveling agent: polyether-modified silicone oil (Toray Silicone SH8400; manufactured by Toray Dow Corning Co., Ltd.) 0.12 parts;
Were mixed to obtain a colored curable composition 1Z1.

[Preparation of colored pattern]
A colored curable composition 1Z1 was applied by spin coating on a 2-inch square glass substrate (Eagle XG; manufactured by Corning), and then pre-baked at 100 ° C. for 3 minutes to form a colored curable composition layer. After cooling, the distance between the substrate on which the colored curable composition layer is formed and the quartz glass photomask is set to 200 μm, and an exposure machine (TME-150RSK; manufactured by Topcon Co., Ltd.) is used in an air atmosphere at 80 mJ / It exposed with an exposure amount of cm ² (365 nm reference). A photomask having a 100 μm line and space pattern was used. The colored curable composition layer after exposure was developed by being immersed in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ° C. for 70 seconds, and washed with water. The colored curable composition layer was post-baked at 230 ° C. for 30 minutes to obtain a colored pattern.

[Phase difference measurement]
A colored curable composition 1Z1 was applied by spin coating on a 2-inch square glass substrate (Eagle XG; manufactured by Corning), and then pre-baked at 100 ° C. for 3 minutes to form a colored curable composition layer. After cooling, the colored curable composition layer was exposed using an exposure machine (TME-150RSK; manufactured by Topcon Corporation) at an exposure amount of 80 mJ / cm ² (based on 365 nm) in an air atmosphere. The colored curable composition layer after exposure was developed by being immersed in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ° C. for 70 seconds, and washed with water. This colored coating film was post-baked at 230 ° C. for 30 minutes to obtain a colored coating film.
The film thickness of the obtained colored coating film was measured using DEKTAK3 (manufactured by Nippon Vacuum Technology Co., Ltd.).
Using an ellipsometer (M-220 type spectroscopic ellipsometer; manufactured by JASCO Corporation), the retardation value of the colored coating film at an angle of 45 ° was measured. Light having a wavelength of 550 nm was used for measuring the phase difference value. The results are shown in Table 15Z1.

Example 102Z1
A mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) is obtained with the compound represented by the formula (IZ1-20) obtained in Example 2Z1. A colored curable composition 2Z1 was obtained in the same manner as in Example 101Z1 except that the mixture of compounds represented by formula (IZ1-21) was used, to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 15Z1.

Example 103Z1
A mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was obtained from the compound represented by the formula (IZ1-2) obtained in Example 3Z1. A colored curable composition 3Z1 was obtained in the same manner as in Example 101Z1 except that the mixture of compounds represented by formula (IZ1-3) was used, to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 15Z1.

Example 104Z1
A mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was converted into the compound represented by the formula (IZ1-38) obtained in Example 4Z1. A colored curable composition 4Z1 was obtained in the same manner as in Example 101Z1 except that the colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 15Z1.

Example 105Z1
A mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was converted into the compound represented by the formula (IZ1-20) obtained in Example 5Z1. A colored curable composition 5Z1 was obtained in the same manner as Example 101Z1 except that the colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 15Z1.

Example 106Z1
A mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was converted into the compound represented by the formula (IZ1-2) obtained in Example 6Z1. A colored curable composition 6Z1 was obtained in the same manner as in Example 101Z1 except that the colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 15Z1.

Example 107Z1
C. I. Pigment Green 58 is a C.I. I. A colored curable composition 7Z1 was obtained and a colored pattern was obtained in the same manner as in Example 101Z1 except that the pigment green 7 was used. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 15Z1.

Example 108Z1
C. I. Pigment Green 58 is a C.I. I. In place of Pigment Green 7, a mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was obtained by the formula (IZ1-20) obtained in Example 2Z1. A colored curable composition 8Z1 was obtained in the same manner as in Example 101Z1 except that a mixture of the compound represented by formula (IZ1-21) and the compound represented by the formula (IZ1-21) was used to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 15Z1.

Example 109Z1
C. I. Pigment Green 58 is a C.I. I. Instead of Pigment Green 7, a mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was obtained by the formula (IZ1-2) obtained in Example 3Z1. A colored curable composition 9Z1 was obtained in the same manner as in Example 101Z1 except that a mixture of the compound represented by formula (IZ1-3) and the compound represented by the formula (IZ1-3) was used to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 15Z1.

Example 110Z1
C. I. Pigment Green 58 is a C.I. I. Instead of Pigment Green 7, a mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was obtained by the formula (IZ1-38) obtained in Example 4Z1. A colored curable composition 10Z1 was obtained and a colored pattern was obtained in the same manner as in Example 101Z1 except that the compound represented by formula (1) was used. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 15Z1.

Example 111Z1
C. I. Pigment Green 58 is a C.I. I. In place of Pigment Green 7, a mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was obtained by the formula (IZ1-20) obtained in Example 5Z1. A colored curable composition 11Z1 was obtained and a colored pattern was obtained in the same manner as in Example 101Z1 except that the compound represented by formula (1) was used. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 15Z1.

Example 112Z1
C. I. Pigment Green 58 is a C.I. I. In place of Pigment Green 7, a mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was obtained by the formula (IZ1-2) obtained in Example 6Z1. A colored curable composition 12Z1 was obtained and a colored pattern was obtained in the same manner as in Example 101Z1 except that the compound represented by formula (1) was used. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 15Z1.

Example 113Z1
C. I. Pigment Green 58 is a C.I. I. A colored curable composition 13Z1 was obtained in the same manner as in Example 101Z1 except that the pigment green 59 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 15Z1.

Example 114Z1
C. I. Pigment Green 58 is a C.I. I. Instead of Pigment Green 59, a mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was obtained by the formula (IZ1-20) obtained in Example 2Z1. A colored curable composition 14Z1 was obtained in the same manner as in Example 101Z1 except that a mixture of the compound represented by formula (IZ1-21) and the compound represented by the formula (IZ1-21) was used to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 15Z1.

Example 115Z1
C. I. Pigment Green 58 is a C.I. I. In place of Pigment Green 59, a mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was obtained by the formula (IZ1-2) obtained in Example 3Z1. A colored curable composition 15Z1 was obtained and a colored pattern was obtained in the same manner as in Example 101Z1, except that the mixture of the compound represented by formula (IZ1-3) and the compound represented by formula (IZ1-3) was used. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 15Z1.

Example 116Z1
C. I. Pigment Green 58 is a C.I. I. Instead of Pigment Green 59, a mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was obtained by the formula (IZ1-38) obtained in Example 4Z1. A colored curable composition 16Z1 was obtained and a colored pattern was obtained in the same manner as in Example 101Z1 except that the compound represented by formula (1) was used. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 15Z1.

Example 117Z1
C. I. Pigment Green 58 is a C.I. I. Instead of CI Pigment Green 59, a mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was obtained by the formula (IZ1-20) obtained in Example 5Z1. A colored curable composition 17Z1 was obtained and a colored pattern was obtained in the same manner as in Example 101Z1 except that the compound represented by formula (1) was used. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 15Z1.

Example 118Z1
C. I. Pigment Green 58 is a C.I. I. In place of Pigment Green 59, a mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was obtained by the formula (IZ1-2) obtained in Example 6Z1. A colored curable composition 18Z1 was obtained and a colored pattern was obtained in the same manner as in Example 101Z1 except that the compound represented by formula (1) was used. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 15Z1.

Comparative Example 1Z1
A mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was prepared by C.I. I. A colored curable composition C1Z1 was obtained in the same manner as in Example 101Z1 except that it was replaced with CI Pigment Yellow 185 to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 15Z1.

Comparative Example 2Z1
C. I. Pigment Green 58 is a C.I. I. Instead of CI Pigment Green 7, a mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was prepared as C.I. I. A colored curable composition C2Z1 was obtained in the same manner as in Example 101Z1 except that the pigment yellow 185 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 15Z1.

Comparative Example 3Z1
C. I. Pigment Green 58 is a C.I. I. Instead of CI Pigment Green 59, a mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was prepared as C.I. I. A colored curable composition C3Z1 was obtained in the same manner as in Example 101Z1 except that the pigment yellow 185 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 15Z1.

Example 119Z1
Pigment: C.I. I. Pigment Green 58 60 parts,
8.1 parts of an acrylic pigment dispersant,
Resin (B): 73 parts of resin B5 solution and solvent (E): 290 parts of propylene glycol monomethyl ether acetate were mixed, and a pigment dispersion (colorant (A1Z1) -containing liquid) in which the pigment was dispersed using a bead mill was prepared. Prepared.
Separately
Colorant (AZ1): 50 parts of a mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39)
58 parts of a dispersant solution (solid content 60%),
Compound represented by formula (IZ1-38) obtained in Example 1Z1 by mixing resin (B): 93 parts of resin B3 solution and solvent (E): 800 parts of propylene glycol monomethyl ether acetate and using a bead mill. And a mixture of the compound represented by the formula (IZ1-39) were dispersed to obtain a colored composition.
Then
Total amount of the obtained pigment dispersion (colorant (A1Z1) -containing liquid);
400 parts of the resulting colored composition;
Resin (B): Resin B1 solution 45 parts;
Polymerizable compound (C): 25 parts of dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kayaku Co., Ltd.);
Polymerization initiator (D): N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure (registered trademark) OXE-01; manufactured by BASF Corporation) 15 parts;
Solvent (E): 86 parts of propylene glycol monomethyl ether acetate; and leveling agent: polyether-modified silicone oil (Toray Silicone SH8400; manufactured by Toray Dow Corning Co., Ltd.) 0.12 parts;
Were mixed to obtain a colored curable composition 19Z1.

  A colored pattern was prepared in the same manner as in Example 101Z1 except that the colored curable composition 19Z1 was used instead of the colored curable composition 1Z1. Moreover, it replaced with colored curable composition 1Z1, and except using colored curable composition 19Z1, it carried out similarly to Example 101Z1, and obtained the colored coating film, and performed the film thickness measurement and the phase difference value measurement. The results are shown in Table 16Z1.

Example 120Z1-Example 127Z1
Except that the mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) is replaced with the colorant shown in the “Colorant” column of Table 16Z1, A colored pattern was obtained in the same manner as Example 119Z1. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 16Z1.

Example 128Z1-Example 136Z1
The mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was replaced with the compound shown in the “Colorant” column of Table 16Z1, and C.I. I. Pigment Green 58 is a C.I. I. A colored pattern was obtained in the same manner as in Example 119Z1 except that the pigment green 7 was used. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 16Z1.

Example 137Z1-Example 145Z1
The mixture of the compound represented by the formula (IZ1-38) obtained in Example 1Z1 and the compound represented by the formula (IZ1-39) was replaced with the compound shown in the “Colorant” column of Table 16Z1, and C.I. I. Pigment Green 58 is a C.I. I. A colored pattern was obtained in the same manner as in Example 119Z1 except that the pigment green 59 was used instead. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 16Z1.

  In the examination of Example Z1, from the above results, in the colored coating film formed from the colored curable composition containing the compound of the present invention, C.I. I. It was found that the retardation value was smaller than that of a colored coating film formed from a colored curable composition containing Pigment Yellow 185.

[Example Z2]
Example 1Z2
5.02 parts of 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 22 parts of methanol were mixed.
To the obtained mixture, 2.90 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) was added and stirred at 25 ° C. for 3 hours.
To the obtained mixture, 3.67 parts of ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.), 1.83 parts of acetic acid and 30 parts of methanol were added and stirred at 25 ° C. for 1 hour and 30 minutes.
To the obtained mixture, 3.62 parts of ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.), 2.37 parts of acetic acid and 30 parts of methanol were added and stirred at 63 ° C. for 3 hours.
To the obtained mixture, 3.63 parts of ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.), 2.36 parts of acetic acid and 30 parts of methanol were added and stirred at 63 ° C. for 2 hours.
To the obtained mixture, 3.62 parts of ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) and 2.40 parts of acetic acid were added, 1 hour at 63 ° C., 11 hours at room temperature, and 6 hours at 63 ° C. Stir.
The temperature of the obtained mixture was lowered to room temperature and then filtered.
The obtained residue was dried, and 10.0 parts of a mixture of the compound represented by formula (IaZ2-39), the compound represented by formula (IaZ2-38), and the compound represented by formula (IaZ2-149) was added. Obtained.

<Identification of compound represented by formula (IaZ2-39)>
(Mass spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 383
Exact Mass: 382

<Identification of compound represented by formula (IaZ2-38)>
(Mass spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 355
Exact Mass: 354

<Identification of Compound Represented by Formula (IaZ2-149)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 369
Exact Mass: 368

Example 2Z2
This was carried out in the same manner as in Example 1Z2 except that ethyl cyanoacetate (Tokyo Chemical Industry Co., Ltd.) was replaced with 2-cyanoacetamide (Tokyo Chemical Industry Co., Ltd.), and represented by the formula (IbZ2-125). A compound was obtained.

<Identification of compound represented by formula (IbZ2-125)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 325
Exact Mass: 324

Example 3Z2
The compound represented by the formula (IbZ2-126) was obtained in the same manner as in Example 1Z2 except that ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) was replaced with 2-cyano-N-methylacetamide. .

<Identification of Compound Represented by Formula (IbZ2-126)>
(Mass Spectrometry) ionization mode = ESI +: m / z = [M + H] + 353
Exact Mass: 352

Example 4Z2
The same procedure as in Example 1Z2 was performed except that ethyl cyanoacetate (Tokyo Chemical Industry Co., Ltd.) was replaced with 2-cyano-N, N-dimethylacetamide (Tokyo Chemical Industry Co., Ltd.), and the compound of formula (IbZ2 -148) was obtained.

<Identification of Compound Represented by Formula (IbZ2-148)>
(Mass Spectrometry) Ionization Mode = ESI +: m / z = [M + H] ⁺ 381
Exact Mass: 380

Example 5Z2
The same procedure as in Example 1Z2 was performed except that ethyl cyanoacetate (Tokyo Chemical Industry Co., Ltd.) was replaced with 2-cyano-N, N-diethylacetamide (Tokyo Chemical Industry Co., Ltd.), and the compound of formula (IbZ2 -149) was obtained.

<Identification of Compound Represented by Formula (IbZ2-149)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 437
Exact Mass: 436

Example 6Z2
Except that ethyl cyanoacetate (manufactured by Tokyo Chemical Industry Co., Ltd.) is replaced with 2-cyanoacetanilide (manufactured by Tokyo Chemical Industry Co., Ltd.), this is carried out in the same manner as in Example 1Z2 and represented by the formula (IbZ2-128). A compound was obtained.

<Identification of Compound Represented by Formula (IbZ2-128)>
(Mass Spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 477
Exact Mass: 476

Example 7Z2
2.55 parts of 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 84 parts of methanol were mixed.
While maintaining this mixture at 5 ° C. or lower, a mixture of 1.47 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 30 parts of methanol was added. The mixture was stirred at 5 ° C. or lower for 5 hours.
To this mixture, 2.16 parts of acetic acid, 2.92 parts of 2-cyano-N-methylacetamide and 21 parts of methanol were added and stirred at 40 ° C. for 3 hours.
To this mixture, 13.5 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) was added, and the mixture was stirred at 40 ° C. for 12 hours and at 62 ° C. for 9 hours.
To this mixture, 1.50 parts of 2-cyano-N-methylacetamide and 3.05 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) were added, and the mixture was kept at 62 ° C. for 5 hours at 40 ° C. Stirred under for 17 hours.
By this time, a total of 6 parts of methanol was added in addition to the methanol described above.
After the solvent of this mixture was distilled off with a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IbZ2-126).

<Identification of Compound Represented by Formula (IbZ2-126)>
(Mass Spectrometry) ionization mode = ESI +: m / z = [M + H] + 353
Exact Mass: 352

Example 8Z2
10 parts of 4-nitrophthalonitrile and 80 parts of methanol were mixed.
While maintaining this mixture at 0 ° C., a 25% sodium methoxide methanol solution containing sodium methoxide having a mole number 0.5 times the mole number of 10 parts of 4-nitrophthalonitrile was added.
The mixture was stirred at 0 ° C. for 5 hours.
To this mixture, 2-cyanoacetamide having a mole number 3.3 times that of 10 parts of 4-nitrophthalonitrile and 16 parts of acetic acid were added and stirred at 60 ° C. for 21 days.
After the solvent of this mixture was distilled off using a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IbZ2-125).

<Identification of compound represented by formula (IbZ2-125)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 325
Exact Mass: 324

Example 9Z2
10 parts of 4-nitrophthalonitrile and 80 parts of methanol were mixed.
While maintaining this mixture at 0 ° C., a 25% sodium methoxide methanol solution containing sodium methoxide having a mole number 0.5 times the mole number of 10 parts of 4-nitrophthalonitrile was added.
The mixture was stirred at 0 ° C. for 5 hours.
To this mixture were added 2-cyano-N, N-dimethylacetamide and 16 parts of acetic acid, 3.3 times the number of moles of 10 parts of 4-nitrophthalonitrile, and the mixture was stirred at 60 ° C. for 21 days.
After the solvent of this mixture was distilled off with a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IbZ2-148).

<Identification of Compound Represented by Formula (IbZ2-148)>
(Mass Spectrometry) Ionization Mode = ESI +: m / z = [M + H] ⁺ 381
Exact Mass: 380

Example 10Z2
10 parts of 4-nitrophthalonitrile and 80 parts of methanol were mixed.
While maintaining this mixture at 0 ° C., a 25% sodium methoxide methanol solution containing sodium methoxide having a mole number 0.5 times the mole number of 10 parts of 4-nitrophthalonitrile was added.
The mixture was stirred at 0 ° C. for 5 hours.
To this mixture were added 2-cyano-N, N-diethylacetamide and 16 parts of acetic acid, 3.3 times the number of moles of 10 parts of 4-nitrophthalonitrile, and the mixture was stirred at 60 ° C. for 21 days.
After the solvent of this mixture was distilled off using a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IbZ2-149).

<Identification of Compound Represented by Formula (IbZ2-149)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 437
Exact Mass: 436

Example 11Z2
1.25 parts of 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 41 parts of methanol were mixed. While maintaining the temperature at 5 ° C. or lower, a mixture of 0.722 part of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 19 parts of methanol was dropped into the obtained mixture over 5 minutes. The resulting mixture was stirred for 4 hours while maintaining the temperature at 5 ° C. or lower.
While maintaining the resulting mixture at 5 ° C. or lower, 1.21 parts of acetic acid, 2.33 parts of 2-cyanoacetanilide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 18 parts of methanol were added. The resulting mixture was stirred at 40 ° C. for 21 hours.
To the obtained mixture, 0.596 parts of acetic acid, 1.17 parts of 2-cyanoacetanilide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 17 parts of methanol were added. The resulting mixture was stirred at 40 ° C. for 3 hours.
To the obtained mixture, 2.09 parts of acetic acid was added, and the mixture was stirred at 50 ° C. for 2 hours, at 60 ° C. for 2 hours, at room temperature for 15 hours, and at 62 ° C. for 3 hours.
To the obtained mixture, 0.981 part of trifluoroacetic acid was added and stirred at 62 ° C. for 2 hours.
To the obtained mixture, 11.5 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) was added and stirred at 62 ° C. for 2 hours, at room temperature for 14 hours, and at 62 ° C. for 5 hours. did.
By this time, a total of 10 parts of methanol was added in addition to the methanol described above.
The resulting mixture was cooled to 23 ° C. and added to 1100 parts of a 50% aqueous acetic acid solution.
40 parts of methanol and 400 parts of a 50% aqueous acetic acid solution were added to the resulting mixture.
The resulting mixture was filtered, and the resulting residue was washed 6 times with 250 parts of 50% aqueous acetic acid and 3 times with 250 parts of water.
The obtained residue was dried under reduced pressure at 60 ° C., to obtain 3.32 parts of a compound represented by the formula (IbZ2-128).

<Identification of Compound Represented by Formula (IbZ2-128)>
(Mass Spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 477
Exact Mass: 476

Example 12Z2
25.2 parts of 4-tert-butylphthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 212 parts of methanol were mixed. While maintaining the temperature at 5 ° C. or lower, a mixture of 20.5 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 184 parts of methanol was dropped into the obtained mixture over 1 hour. The resulting mixture was stirred at 5-20 ° C. for 2 days.
Under 10 to 20 ° C., 13.7 parts of acetic acid and 13.5 parts of 2-cyano-N-methylacetamide were added to the obtained mixture. The obtained mixture was stirred at 10 to 20 ° C. for 5 hours, and then stirred at 40 ° C. for 16 hours.
To the obtained mixture, 6.79 parts of acetic acid and 6.75 parts of 2-cyano-N-methylacetamide were added and stirred at 40 ° C. for 6 hours and at 50 ° C. for 65 hours.
By this time, in addition to the methanol described above, a total of 201 parts of methanol was added.
To the obtained mixture, 13.5 parts of acetic acid, 18.3 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.) and 604 parts of water were added and stirred at 40 ° C. for 53 hours.
The resulting mixture was filtered and the residue was washed with 50% aqueous methanol. The obtained residue was purified by column chromatography to obtain a compound represented by the formula (IbZ2-64).

<Identification of compound represented by formula (IbZ2-64)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 364
Exact Mass: 363

Example 13Z2
25.9 parts of phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 513 parts of methanol were mixed.
While maintaining the temperature at 3 ° C to 5 ° C, a mixture of 30.3 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 12 parts of methanol was added dropwise over 10 minutes. .
The resulting mixture was stirred for 6 hours while maintaining at 3 ° C to 5 ° C.
While maintaining the temperature at 3 ° C. to 5 ° C., 19.8 parts of acetic acid, 28.5 parts of tert-butyl cyanoacetate and 26 parts of methanol were added to the obtained mixture.
The resulting mixture was stirred at room temperature for 2 days and then stirred at 40 ° C. for 3 hours.
To the resulting mixture, 5.09 parts of acetic acid and 7.17 parts of tert-butyl cyanoacetate were added and stirred at 40 ° C. for 4 hours.
To the obtained mixture, 4.95 parts of acetic acid, 7.15 parts of tert-butyl cyanoacetate and 38 parts of methanol were added and stirred at 40 ° C. for 16 hours.
To the obtained mixture, 19.9 parts of acetic acid, 25.8 parts of barbituric acid, 209 parts of methanol, and 800 parts of water were added and stirred at 40 ° C. for 3 hours.
The resulting mixture was filtered to obtain a residue.
This residue was purified by column chromatography to obtain a compound represented by the formula (IaZ2-5).

<Identification of Compound Represented by Formula (IaZ2-5)>
(Mass spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 394
Exact Mass: 393

Example 14Z2
15.1 parts of 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 284 parts of methanol were mixed.
While maintaining the temperature at 5 ° C. or lower, a mixture of 8.81 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 18 parts of methanol was dropped into the obtained mixture over 10 minutes.
The resulting mixture was stirred for 4 hours while maintaining the temperature at 5 ° C. or lower.
While maintaining the temperature at 5 ° C. or lower, 5.55 parts of acetic acid was added to the obtained mixture and stirred for 30 minutes.
This mixture was mixed with 12.3 parts of tert-butyl cyanoacetate and stirred at 40 ° C. for 14 hours.
This mixture was mixed with 0.654 parts of acetic acid and 1.24 parts of tert-butyl cyanoacetate and stirred at 40 ° C. for 4 hours.
This mixture was mixed with 0.613 parts of acetic acid and 1.23 parts of tert-butyl cyanoacetate and stirred at 40 ° C. for 3 hours.
This mixture was mixed with 0.647 parts of acetic acid and 1.24 parts of tert-butyl cyanoacetate. By this time, a total of 89 parts of methanol was added in addition to the methanol described above.
The mixture was stirred at 40 ° C. for 17 hours.
This mixture was mixed with 7.14 parts of acetic acid, 11.3 parts of barbituric acid, and 508 parts of water. By this time, in addition to the methanol described above, a total of 117 parts of methanol was added.
The mixture was stirred at 40 ° C. for 24 hours.
This mixture was mixed with 3.65 parts of acetic acid and 5.61 parts of barbituric acid, and stirred at 40 ° C. for 9 hours and at room temperature for 2 days.
The mixture was filtered, and the residue was washed 3 times with 1330 parts of 50% aqueous methanol.
The obtained residue was purified by column chromatography to obtain a compound represented by the formula (IaZ2-41).

<Identification of compound represented by formula (IaZ2-41)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 439
Exact Mass: 438

Example 15Z2
5.44 parts of 3,4,5,6-tetrafluorophthalonitrile and 23.6 parts of methanol were mixed.
A mixture of 2.70 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 10 parts of methanol was added to this mixture at 20 to 25 ° C.
The mixture was stirred at 20 ° C to 25 ° C for 4 hours and 20 minutes.
To this mixture, 3.36 parts of acetic acid, 5.99 parts of methyl cyanoacetate and 7.5 parts of methanol were added.
The mixture was stirred at 63 ° C. for 2 hours.
The solvent of the obtained mixture was distilled off with a rotary evaporator, and then the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IaZ2-223).

<Identification of compound represented by formula (IaZ2-223)>
(Mass Spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 382
Exact Mass: 381

Example 16Z2
2.52 parts of phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 22.8 parts of methanol were mixed.
Under room temperature, 1.98 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) was added to this mixture.
The mixture was stirred at 38 ° C. for 3 hours.
To this mixture, 2.79 parts of cyanoacetyl urea (manufactured by Tokyo Chemical Industry Co., Ltd.) and 1.26 parts of acetic acid were added.
The mixture was stirred at 40 ° C. for 1 hour 30 minutes.
To this mixture, 2.77 parts of cyanoacetyl urea (manufactured by Tokyo Chemical Industry Co., Ltd.) and 1.61 parts of acetic acid were added.
By this time, a total of 39.2 parts of methanol was added in addition to the methanol described above.
The mixture was stirred at 40 ° C. for 1 hour.
To this mixture, 65.2 parts of water was added and stirred at 40 ° C. for 2 hours and 30 minutes.
To this mixture, 2.80 parts of cyanoacetylurea (manufactured by Tokyo Chemical Industry Co., Ltd.) and 1.60 parts of acetic acid were added and stirred at 40 ° C. for 20 hours.
By this time, a total of 31 parts of methanol was added in addition to the methanol described above.
After the solvent of this mixture was distilled off with a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IbZ2-19).

<Identification of compound represented by formula (IbZ2-19)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 366
Exact Mass: 365

Example 17Z2
8 parts of phthalonitrile and 63 parts of ethanol were mixed.
To this mixture was added a 21% sodium ethoxide ethanol solution containing 1 mole of sodium ethoxide, 8 moles of phthalonitrile.
The mixture was stirred at room temperature for 2 hours.
To this mixture, a compound represented by the formula (ppp1) having a mole number 2.3 times the mole number of 25 parts of acetic acid and 8 parts of phthalonitrile was added and stirred at 90 ° C. for 64 hours.
The mixture was cooled to room temperature and filtered.
The obtained residue was washed with 160 parts of methanol and dried.
24 parts of the obtained residue and 230 parts of N, N-dimethylformamide were mixed.
To this mixture was added 210 parts of acetic acid.
This mixture was filtered.
The obtained residue was washed with 79 parts of methanol and dried to obtain 17 parts of a compound represented by the formula (IbZ2-311).

<Identification of Compound Represented by Formula (IbZ2-311)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 508
Exact Mass: 507

To 15 parts of the compound represented by the formula (IbZ2-311), 200 parts of dichloromethane and 150 parts of trifluoroacetic acid were added and stirred at room temperature for 50 hours.
160 parts of methanol was added to the obtained mixture and filtered.
The obtained residue was dried to obtain 13 parts of a residue.
12 parts of this residue and 230 parts of N, N-dimethylformamide were mixed, stirred for 1 hour, and then filtered.
The obtained residue and 160 parts of methanol were mixed and stirred at 70 ° C.
The resulting mixture was filtered.
This residue was dried to obtain 9 parts of a compound represented by the formula (IbZ2-317).

<Identification of Compound Represented by Formula (IbZ2-317)>
(Mass spectrometry) Ionization mode = ESI−: m / z = [M−H] ⁻ 394
Exact Mass: 395

Example 18Z2
4-Nitrophthalonitrile 5 parts and ethanol 39 parts were mixed.
While maintaining this mixture at 0 ° C., a 21% sodium ethoxide ethanol solution containing 0.5 moles of sodium ethoxide in moles of 5 parts of 4-nitrophthalonitrile was added.
The mixture was stirred at 0 ° C. for 3 hours.
To this mixture, a compound represented by the formula (ppp1) having a mole number 3.3 times the mole number of 16 parts of acetic acid and 5 parts of 4-nitrophthalonitrile was added.
The mixture was sealed and stirred at 90 ° C. for 56 hours.
The mixture was cooled to room temperature and filtered.
This residue was washed with ethanol to obtain 8 parts of residue A.
10 parts of 4-nitrophthalonitrile and 79 parts of ethanol were mixed.
While maintaining this mixture at 0 ° C., a 21% sodium ethoxide ethanol solution containing sodium ethoxide having a mole number of 0.5 times the mole number of 10 parts of 4-nitrophthalonitrile was added.
The mixture was stirred at 0 ° C. for 3 hours.
To this mixture, a compound represented by the formula (ppp1) having a mole number 3.3 times the mole number of 31 parts of acetic acid and 10 parts of 4-nitrophthalonitrile was added.
The mixture was sealed and stirred at 90 ° C. for 56 hours.
The mixture was cooled to room temperature and filtered.
The obtained residue was washed with ethanol to obtain 15 parts of residue B.
4 parts of residue A, 14 parts of residue B, and 170 parts of N, N-dimethylformamide were mixed.
This mixture and 710 parts of methanol were mixed and stirred at room temperature for 16 hours.
This mixture was filtered to obtain 13 parts of a residue containing a compound represented by the formula (IbZ2-312).

<Identification of compound represented by formula (IbZ2-312)>
(Mass spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 553
Exact Mass: 552

13 parts of the residue containing the compound represented by the formula (IbZ2-312), 170 parts of dichloromethane and 130 parts of trifluoroacetic acid were mixed and stirred at room temperature for 16 hours.
After distilling off the solvent, 190 parts of N, N-dimethylformamide was added to 12 parts of the resulting residue, followed by stirring at 90 ° C. for 10 minutes, followed by filtration.
The obtained filtrate was allowed to stand at room temperature for 16 hours.
The filtrate was filtered to obtain 8.0 parts of a residue.
8.0 parts of this residue and 22 parts of tetrahydrofuran were mixed, stirred at 70 ° C. for 3 hours, and then filtered.
7.2 parts of the obtained residue and 21 parts of acetic acid were mixed, stirred at 80 ° C. for 2 hours, and then filtered.
6.2 parts of the obtained residue and 170 parts of toluene were mixed, stirred at 95 ° C. for 3 hours, and then filtered.
5.6 parts of the obtained residue and 50 parts of water were mixed, stirred at 90 ° C. for 16 hours, and then filtered.
The obtained residue was dried to obtain 5.4 parts of a compound represented by the formula (IbZ2-515).

<Identification of compound represented by formula (IbZ2-515)>
(Mass Spectrometry) ionization mode = ESI-: m / z = [ M-H] - 439
Exact Mass: 440

Example 19Z2
2 parts of phthalonitrile and 16 parts of methanol were mixed.
While maintaining this mixture at 0 ° C., a 25% sodium methoxide methanol solution containing 0.5 moles of sodium methoxide in moles of 2 parts of phthalonitrile was added.
The mixture was stirred at 0 ° C. for 5 hours.
To this mixture, a compound represented by the formula (ppp2) having a mole number 3.3 times the mole number of 2 parts of phthalonitrile and 4.2 parts of acetic acid were added and stirred at 60 ° C. for 6 days.
The mixture was cooled to room temperature and filtered.
The obtained residue was washed with methanol to obtain 4 parts of a residue Aa containing a compound represented by the formula (IbZ2-313).
8 parts of phthalonitrile and 63 parts of methanol were mixed.
While maintaining this mixture at 0 ° C., a 25% sodium methoxide methanol solution containing 0.5 moles of sodium methoxide in moles of 8 parts of phthalonitrile was added.
The mixture was stirred at 0 ° C. for 5 hours.
To this mixture, a compound represented by the formula (ppp2) having a mole number 3.3 times the mole number of 8 parts of phthalonitrile and 17 parts of acetic acid were added and stirred at 60 ° C. for 10 days.
The mixture was cooled to room temperature and filtered.
The obtained residue was washed with methanol to obtain 16 parts of residue Bb containing a compound represented by the formula (IbZ2-313).

<Identification of Compound Represented by Formula (IbZ2-313)>
(Mass spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 536
Exact Mass: 535

2 parts of the residue Aa containing the compound represented by the formula (IbZ2-313), 27 parts of dichloromethane and 22 parts of trifluoroacetic acid were mixed and stirred at room temperature for 16 hours.
The mixture was evaporated to obtain 2 parts of residue Aaa.
2 parts of the residue Aa containing the compound represented by the formula (IbZ2-313), 16 parts of the residue Bb containing the compound represented by the formula (IbZ2-313), 240 parts of dichloromethane, and 190 parts of trifluoroacetic acid were mixed at room temperature. Stir for 16 hours.
The mixture was evaporated to obtain 16 parts of residue Ccc.
The residue Aaa 1.7 parts, the residue Ccc 16 parts and acetic acid 210 parts were mixed and stirred at 80 ° C. for 16 hours.
This mixture was filtered to obtain 13 parts of a residue.
This residue and 71 parts of diethyl ether were mixed and stirred at room temperature for 16 hours.
This mixture was filtered, and the resulting residue was dried to obtain 12 parts of a compound represented by the formula (IbZ2-318).

<Identification of Compound Represented by Formula (IbZ2-318)>
(Mass spectrometry) Ionization mode = ESI−: m / z = [M−H] ⁻ 422
Exact Mass: 423

Example 20Z2
2 parts of 4-nitrophthalonitrile and 16 parts of methanol were mixed.
While maintaining this mixture at 0 ° C., a 25% sodium methoxide methanol solution containing 0.5 moles of sodium methoxide in moles of 2 parts of 4-nitrophthalonitrile was added.
The mixture was stirred at 0 ° C. for 3 hours.
To this mixture, a compound represented by the formula (ppp2) having a mole number 3.3 times the mole number of 2 parts of 4-nitrophthalonitrile and 2.1 parts of acetic acid were added and stirred at 60 ° C. for 15 days.
The mixture was cooled to room temperature and filtered.
The obtained residue was washed with 48 parts of methanol to obtain 8.4 parts of a residue containing a compound represented by the formula (IbZ2-314).

<Identification of Compound Represented by Formula (IbZ2-314)>
(Mass spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 581
Exact Mass: 580

8.4 parts of the residue containing the compound represented by the formula (IbZ2-314), 110 parts of dichloromethane, and 89 parts of trifluoroacetic acid were mixed and stirred at room temperature for 16 hours.
The mixture was evaporated to obtain 6.9 parts of residue.
6.1 parts of this residue and 34 parts of dimethyl sulfoxide were mixed and stirred at room temperature for 5 minutes.
This mixture and 190 parts of acetic acid were mixed and stirred at room temperature for 30 minutes.
This mixture and 290 parts of methanol were mixed and stirred at room temperature for 1 hour.
This mixture was filtered to obtain 5.7 parts of a residue.
5.6 parts of this residue and 150 parts of water were mixed, stirred at 80 ° C. for 2 hours, and filtered.
The obtained residue was dried to obtain 5.4 parts of a compound represented by the formula (IbZ2-516).

<Identification of Compound Represented by Formula (IbZ2-516)>
(Mass spectrometry) Ionization mode = ESI−: m / z = [M−H] ⁻ 467
Exact Mass: 468

Example 21Z2
A compound represented by the formula (ppp3) having a number of moles 1.1 times the number of moles of 6 parts of phthalonitrile, 66 parts of dimethyl sulfoxide, and tert-butoxy potassium having a mole number of 1 times the number of moles of 6 parts of phthalonitrile Were mixed and stirred at room temperature for 10 minutes.
To this mixture, 6 parts of phthalonitrile was added and stirred at 80 ° C. for 2 hours.
To this mixture, a compound represented by the formula (ppp3) having a mole number 1.1 times the mole number of 6 parts of phthalonitrile was added and stirred at 180 ° C. for 2 hours.
The mixture was cooled to room temperature and filtered to give 5.3 parts of residue.
5.0 parts of this residue, 55 parts of dimethyl sulfoxide and 47 parts of N, N-dimethylformamide were mixed and stirred at 80 ° C. for 30 minutes.
This mixture and 240 parts of methanol were mixed and stirred at 80 ° C. for 30 minutes.
The mixture was cooled to room temperature and filtered.
The obtained residue, 55 parts of dimethyl sulfoxide and 47 parts of N, N-dimethylformamide were mixed and stirred at 80 ° C. for 30 minutes.
This mixture and 240 parts of methanol were mixed and stirred at 80 ° C. for 30 minutes.
The mixture was cooled to room temperature and filtered to give 4.6 parts of residue.
This residue and methanol were mixed and stirred at 80 ° C. for 2 hours.
This mixture was filtered, and the resulting residue was dried to obtain 4.5 parts of a compound represented by the formula (IbZ2-319).

<Identification of Compound Represented by Formula (IbZ2-319)>
(Mass spectrometry) Ionization mode = ESI−: m / z = [M−H] ⁻ 518
Exact Mass: 519

Example 22Z2
The number of moles of cyanoacetic acid 1.2 times the number of moles of 50 parts of 4-aminomethylbenzoic acid and 50 parts of 4-aminomethylbenzoic acid, 0.9 times the number of moles of 50 parts of 4-aminomethylbenzoic acid Numerous N, N′-dicyclohexylcarbodiimide and 890 parts of tetrahydrofuran were mixed and stirred at room temperature for 16 hours.
The mixture was filtered and the filtrate was evaporated to give a residue.
The obtained residue and 270 parts of ethyl acetate were mixed and filtered.
The obtained residue was dried to obtain 30 parts of a compound represented by the formula (ppp4).

<Identification of compound represented by formula (ppp4)>
(Mass Spectrometry) Ionization mode = ESI−: m / z = [M−H] ⁻ 217
Exact Mass: 218

3 parts of phthalonitrile and 110 parts of ethylene glycol were mixed.
To this mixture was added a 25% sodium methoxide methanol solution containing sodium methoxide at a mole number 1.5 times the moles of 3 parts of phthalonitrile at room temperature.
The mixture was stirred at room temperature for 4 hours.
To this mixture, a compound represented by the formula (ppp4) having a molar number 3.1 times the molar number of 3 parts of phthalonitrile and 110 parts of ethylene glycol were added and stirred at 110 ° C. for 16 hours.
After the mixture was cooled to room temperature, 630 parts of methanol was added.
This mixture was mixed with 26 parts of acetic acid.
This mixture was filtered to obtain 11 parts of a residue.
This residue was mixed with 220 parts of dimethyl sulfoxide.
This mixture was mixed with 630 parts of methanol.
This mixture was filtered to obtain 9.5 parts of a residue.
This residue was mixed with 220 parts of dimethyl sulfoxide.
This mixture was mixed with 630 parts of methanol.
This mixture was filtered to obtain 9 parts of a residue.
This residue and 200 parts of water were mixed and stirred at 80 ° C. for 2 hours.
This mixture was mixed with 2.1 parts of acetic acid.
This mixture was filtered to obtain 8.5 parts of a residue.
8.1 parts of this residue and 260 parts of dimethyl sulfoxide were mixed and stirred at 60 ° C. for 20 minutes.
The mixture was cooled to room temperature, allowed to stand at room temperature for 2 hours, and filtered.
The obtained residue was washed with a 2% aqueous acetic acid solution to obtain 6.2 parts of a residue.
This residue and 150 parts of water were mixed and stirred at 80 ° C. for 30 minutes.
The mixture was cooled to room temperature and filtered.
The obtained residue was washed with 200 parts of water.
This residue was dried to obtain 6 parts of a compound represented by the formula (IbZ2-320).

<Identification of compound represented by formula (IbZ2-320)>
(Mass spectrometry) Ionization mode = ESI−: m / z = [M−H] ⁻ 546
Exact Mass: 547

Example 23Z2
4,5-Dibromophthalonitrile (5 parts) and 2-ethoxyethanol (93 parts) were mixed.
To this mixture was added a 25% sodium methoxide methanol solution containing 1 mole of sodium methoxide, 5 moles of 4,5-dibromophthalonitrile.
The mixture was stirred at room temperature for 6 hours.
To this mixture was added a compound represented by the formula (ppp1) having a mole number of 6 times 5 moles of 4,5-dibromophthalonitrile, and the mixture was stirred at 90 ° C. for 65 hours and then at 100 ° C. for 10 hours. Stir for hours.
This mixture was mixed with 300 parts of water and 21 parts of acetic acid.
This mixture was filtered to obtain 10 parts of a residue.
This residue was mixed with 120 parts of methanol and 10 parts of acetic acid.
This mixture was filtered to obtain 5.5 parts of a residue containing a compound represented by the formula (IbZ2-315).

<Identification of compound represented by formula (IbZ2-315)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 664
Exact Mass: 663

5.5 parts of a residue containing a compound represented by the formula (IbZ2-315), 45 parts of trifluoroacetic acid and 80 parts of dichloromethane were mixed and stirred at room temperature for 16 hours.
This mixture was evaporated to obtain 6 parts of a residue.
This residue was mixed with 79 parts of methanol.
This mixture was filtered to obtain 4 parts of a residue.
This residue was mixed with 0.24 part of lithium hydroxide, 36 parts of tetrahydrofuran and 12 parts of water, and stirred at room temperature for 6 hours.
Tetrahydrofuran was distilled off from this mixture using an evaporator. Water and 1.5N hydrochloric acid were added to the resulting mixture.
This mixture was filtered to obtain 3.5 parts of a residue.
This residue was mixed with 40 parts of methanol.
This mixture was filtered, and the residue was washed with 13 parts of hexane to obtain 3 parts of a residue.
2.8 parts of this residue and 33 parts of dimethyl sulfoxide were mixed and stirred at 70 ° C. for 20 minutes.
The mixture was cooled to room temperature and filtered.
The obtained residue was washed with 40 parts of methanol and then with 50 parts of water.
This residue was dried to obtain 1.8 parts of a compound represented by the formula (IbZ2-706).

<Identification of Compound Represented by Formula (IbZ2-706)>
(Mass spectrometry) Ionization mode = ESI−: m / z = [M−H] ⁻ 550
Exact Mass: 551

Example 24Z2
13 parts of 4,5-dichlorophthalonitrile and 160 parts of methanol were mixed.
While maintaining this mixture at 0 ° C., a 25% sodium methoxide methanol solution containing sodium methoxide in a mole number 0.5 times the mole number of 13 parts of 4,5-dichlorophthalonitrile was added.
The mixture was stirred at 0 ° C. for 5 hours.
To this mixture, a compound represented by the formula (ppp1) having a mole number 4.4 times the mole number of 13 parts of 4,5-dichlorophthalonitrile and 16 parts of acetic acid were added and stirred at 75 ° C. for 7 days.
To this mixture, 14 parts of acetic acid and 13 parts of 4,5-dichlorophthalonitrile were added, and the compound represented by the formula (ppp1) having a mole number three times that of moles was stirred at 75 ° C. for 11 days.
This mixture was filtered.
The obtained residue was washed with 320 parts of methanol to obtain 26 parts of a residue.
13 parts of this residue, 100 parts of methanol, 16 parts of acetic acid and 26.3 parts of the compound represented by the formula (ppp1) were mixed and stirred at 75 ° C. for 48 hours.
This mixture was filtered.
The obtained residue was washed with 40 parts of methanol to obtain 12 parts of a residue containing a compound represented by the formula (IbZ2-316).

<Identification of compound represented by formula (IbZ2-316)>
(Mass spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 576
Exact Mass: 575

12 parts of the residue containing the compound represented by the formula (IbZ2-316), 160 parts of dichloromethane and 130 parts of trifluoroacetic acid were mixed and stirred at room temperature for 16 hours.
This mixture was filtered to obtain 6.2 parts of a residue.
This residue and 73 parts of acetic acid were mixed and stirred at 80 ° C. for 2 hours.
This mixture was filtered to obtain 5.3 parts of a residue.
This residue and 60 parts of water were mixed and stirred at 80 ° C. for 2 hours.
This mixture was filtered, and the obtained residue was dried to obtain 5 parts of a compound represented by the formula (IbZ2-389).

<Identification of Compound Represented by Formula (IbZ2-389)>
(Mass spectrometry) ionization mode = ESI−: m / z = [M−H] ⁻ 462
Exact Mass: 463

Example 101Z2
Pigment: C.I. I. Pigment Green 58 60 parts,
8.1 parts of an acrylic pigment dispersant,
Resin (B): 73 parts of resin B5 solution, and solvent (E): 290 parts of propylene glycol monomethyl ether acetate, and a pigment dispersion (colorant (A1Z2) -containing liquid) in which the pigment is dispersed using a bead mill. Prepared.
Separately
Colorant (AZ2): mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in Example 1Z2. Part,
Dispersant (BYK-LPN6919; manufactured by Big Chemie Japan Co., Ltd.) 58 parts,
Compound (IaZ2-39) obtained in Example 1Z2 by mixing resin (B): 93 parts of resin B3 solution and solvent (E): 800 parts of propylene glycol monomethyl ether acetate and using a bead mill A colored composition was obtained by dispersing a mixture of the compound represented by formula (IaZ2-38) and the compound represented by formula (IaZ2-149).
Then
Total amount of the obtained pigment dispersion (colorant (A1Z2) -containing liquid);
400 parts of the resulting colored composition;
Resin (B): Resin B1 solution 45 parts;
Polymerizable compound (C): 25 parts of dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kayaku Co., Ltd.);
Polymerization initiator (D): N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure (registered trademark) OXE-01; manufactured by BASF Corporation) 15 parts;
Solvent (E): 86 parts of propylene glycol monomethyl ether acetate; and leveling agent: polyether-modified silicone oil (Toray Silicone SH8400; manufactured by Toray Dow Corning Co., Ltd.) 0.12 parts;
Were mixed to obtain a colored curable composition 1Z2.

[Preparation of colored pattern]
The colored curable composition 1Z2 was applied by spin coating on a 2-inch square glass substrate (Eagle XG; manufactured by Corning), and then pre-baked at 100 ° C. for 3 minutes to form a colored curable composition layer. After cooling, the distance between the substrate on which the colored curable composition layer is formed and the quartz glass photomask is set to 200 μm, and an exposure machine (TME-150RSK; manufactured by Topcon Co., Ltd.) is used in an air atmosphere at 80 mJ / It exposed with an exposure amount of cm ² (365 nm reference). A photomask having a 100 μm line and space pattern was used. The colored curable composition layer after exposure was developed by being immersed in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ° C. for 70 seconds, and washed with water. The colored curable composition layer was post-baked at 230 ° C. for 30 minutes to obtain a colored pattern.

[Phase difference measurement]
The colored curable composition 1Z2 was applied by spin coating on a 2-inch square glass substrate (Eagle XG; manufactured by Corning), and then pre-baked at 100 ° C. for 3 minutes to form a colored curable composition layer. After cooling, the colored curable composition layer was exposed using an exposure machine (TME-150RSK; manufactured by Topcon Corporation) at an exposure amount of 80 mJ / cm ² (based on 365 nm) in an air atmosphere. The colored curable composition layer after exposure was developed by being immersed in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ° C. for 70 seconds, and washed with water. The colored curable composition layer was post-baked at 230 ° C. for 30 minutes to obtain a colored coating film.
The film thickness of the obtained colored coating film was measured using DEKTAK3 (manufactured by Nippon Vacuum Technology Co., Ltd.).
Using an ellipsometer (M-220 type spectroscopic ellipsometer; manufactured by JASCO Corporation), the retardation value of the colored coating film at an angle of 45 ° was measured. Light having a wavelength of 550 nm was used for measuring the phase difference value. The results are shown in Table 44Z2.

Example 102Z2
A mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in Example 1Z2 was obtained in Example 2Z2. A colored curable composition 2Z2 was obtained in the same manner as in Example 101Z2 except that the compound represented by the formula (IbZ2-125) was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 44Z2.

Example 103Z2
A mixture of the compound represented by the formula (IaZ2-39) obtained in Example 1Z2, the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) was obtained in Example 3Z2. A colored curable composition 3Z2 was obtained in the same manner as in Example 101Z2 except that the compound represented by the formula (IbZ2-126) was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 44Z2.

Example 104Z2
A mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in Example 1Z2 was obtained in Example 4Z2. A colored curable composition 4Z2 was obtained and a colored pattern was obtained in the same manner as in Example 101Z2 except that the compound represented by the formula (IbZ2-148) was used. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 44Z2.

Example 105Z2
A mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in Example 1Z2 was obtained in Example 5Z2. A colored curable composition 5Z2 was obtained in the same manner as in Example 101Z2 except that the compound represented by the formula (IbZ2-149) was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 44Z2.

Example 106Z2
A mixture of the compound represented by the formula (IaZ2-39) obtained in Example 1Z2, the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) was obtained in Example 6Z2. A colored curable composition 6Z2 was obtained in the same manner as in Example 101Z2 except that the compound represented by the formula (IbZ2-128) was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 44Z2.

Example 107Z2
C. I. Pigment Green 58 is a C.I. I. A colored curable composition 7Z2 was obtained in the same manner as in Example 101Z2 except that it was replaced with CI Pigment Green 7, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 44Z2.

Example 108Z2
C. I. Pigment Green 58 is a C.I. I. Instead of Pigment Green 7, a mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in Example 1Z2. A colored curable composition 8Z2 was obtained in the same manner as in Example 101Z2 except that the compound represented by the formula (IbZ2-125) obtained in Example 2Z2 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 44Z2.

Example 109Z2
C. I. Pigment Green 58 is a C.I. I. Instead of Pigment Green 7, a mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in Example 1Z2. A colored curable composition 9Z2 was obtained and a colored pattern was obtained in the same manner as in Example 101Z2, except that the compound represented by the formula (IbZ2-126) obtained in Example 3Z2 was used. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 44Z2.

Example 110Z2
C. I. Pigment Green 58 is a C.I. I. Instead of Pigment Green 7, a mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in Example 1Z2. A colored curable composition 10Z2 was obtained and a colored pattern was obtained in the same manner as in Example 101Z2, except that the compound represented by the formula (IbZ2-148) obtained in Example 4Z2 was used. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 44Z2.

Example 111Z2
C. I. Pigment Green 58 is a C.I. I. Instead of Pigment Green 7, a mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in Example 1Z2. A colored curable composition 11Z2 was obtained in the same manner as in Example 101Z2, except that the compound represented by the formula (IbZ2-149) obtained in Example 5Z2 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 44Z2.

Example 112Z2
C. I. Pigment Green 58 is a C.I. I. Instead of Pigment Green 7, a mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in Example 1Z2. A colored curable composition 12Z2 was obtained in the same manner as in Example 101Z2, except that the compound represented by the formula (IbZ2-128) obtained in Example 6Z2 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 44Z2.

Example 113Z2
C. I. Pigment Green 58 is a C.I. I. A colored curable composition 13Z2 was obtained in the same manner as in Example 101Z2 except that the pigment green 59 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 44Z2.

Example 114Z2
C. I. Pigment Green 58 is a C.I. I. Instead of Pigment Green 59, a mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in Example 1Z2. A colored curable composition 14Z2 was obtained in the same manner as in Example 101Z2 except that the compound represented by the formula (IbZ2-125) obtained in Example 2Z2 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 44Z2.

Example 115Z2
C. I. Pigment Green 58 is a C.I. I. Instead of Pigment Green 59, a mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in Example 1Z2. A colored curable composition 15Z2 was obtained and a colored pattern was obtained in the same manner as in Example 101Z2 except that the compound represented by the formula (IbZ2-126) obtained in Example 3Z2 was used. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 44Z2.

Example 116Z2
C. I. Pigment Green 58 is a C.I. I. Instead of Pigment Green 59, a mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in Example 1Z2. A colored curable composition 16Z2 was obtained in the same manner as in Example 101Z2 except that the compound represented by the formula (IbZ2-148) obtained in Example 4Z2 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 44Z2.

Example 117Z2
C. I. Pigment Green 58 is a C.I. I. Instead of Pigment Green 59, a mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in Example 1Z2. A colored curable composition 17Z2 was obtained in the same manner as in Example 101Z2 except that the compound represented by the formula (IbZ2-149) obtained in Example 5Z2 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 44Z2.

Example 118Z2
C. I. Pigment Green 58 is a C.I. I. Instead of Pigment Green 59, a mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in Example 1Z2. A colored curable composition 18Z2 was obtained in the same manner as in Example 101Z2 except that the compound represented by the formula (IbZ2-128) obtained in Example 6Z2 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 44Z2.

Comparative Example 1Z2
A mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in Example 1Z2. I. A colored curable composition C1Z2 was obtained in the same manner as in Example 101Z2 except that it was replaced with CI Pigment Yellow 185 to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 44Z2.

Comparative Example 2Z2
C. I. Pigment Green 58 is a C.I. I. Instead of Pigment Green 7, a mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in Example 1Z2. C. I. A colored curable composition C2Z2 was obtained in the same manner as in Example 101Z2 except that it was replaced with CI Pigment Yellow 185 to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 44Z2.

Comparative Example 3Z2
C. I. Pigment Green 58 is a C.I. I. Instead of Pigment Green 59, a mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in Example 1Z2. C. I. A colored curable composition C3Z2 was obtained in the same manner as in Example 101Z2 except that it was replaced with CI Pigment Yellow 185 to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 44Z2.

Example 119Z2
Pigment: C.I. I. Pigment Green 58 60 parts,
8.1 parts of an acrylic pigment dispersant,
Resin (B): 73 parts of resin B5 solution, and solvent (E): 290 parts of propylene glycol monomethyl ether acetate, and a pigment dispersion (colorant (A1Z2) -containing liquid) in which the pigment is dispersed using a bead mill. Prepared.
Separately
Colorant (AZ2): mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in Example 1Z2. Part,
58 parts of a dispersant solution (solid content 60%),
Compound (IaZ2-39) obtained in Example 1Z2 by mixing resin (B): 93 parts of resin B3 solution and solvent (E): 800 parts of propylene glycol monomethyl ether acetate and using a bead mill A colored composition was obtained by dispersing a mixture of the compound represented by formula (IaZ2-38) and the compound represented by formula (IaZ2-149).
Then
Total amount of the obtained pigment dispersion (colorant (A1Z2) -containing liquid);
400 parts of the resulting colored composition;
Resin (B): Resin B1 solution 45 parts;
Polymerizable compound (C): 25 parts of dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kayaku Co., Ltd.);
Polymerization initiator (D): N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure (registered trademark) OXE-01; manufactured by BASF Corporation) 15 parts;
Solvent (E): 86 parts of propylene glycol monomethyl ether acetate; and leveling agent: polyether-modified silicone oil (Toray Silicone SH8400; manufactured by Toray Dow Corning Co., Ltd.) 0.12 parts;
Were mixed to obtain a colored curable composition 19Z2.

  A colored pattern was produced in the same manner as in Example 101Z2 except that the colored curable composition 19Z2 was used instead of the colored curable composition 1Z2. Moreover, it replaced with the colored curable composition 1Z2, and except using the colored curable composition 19Z2, it carried out similarly to Example 101Z2, and obtained the colored coating film, and performed the film thickness measurement and the phase difference value measurement. The results are shown in Table 45Z2.

Example 120Z2-Example 138Z2
A mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in Example 1Z2 is represented by “Colorant of Table 45Z2”. A colored pattern was obtained in the same manner as in Example 119Z2 except that the colorant shown in the column "" was used. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 45Z2.

Example 139Z2-Example 158Z2
A mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38) and the compound represented by the formula (IaZ2-149) obtained in Example 1Z2 is represented by “Colorant of Table 46Z2”. In place of the compounds shown in the column "." I. Pigment Green 58 is a C.I. I. A colored pattern was obtained in the same manner as in Example 119Z2 except that the pigment green 7 was used. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 46Z2.

Example 159Z2-Example 178Z2
A mixture of the compound represented by the formula (IaZ2-39), the compound represented by the formula (IaZ2-38), and the compound represented by the formula (IaZ2-149) obtained in Example 1Z2 is shown in Table 47Z2. In place of the compounds shown in the column "." I. Pigment Green 58 is a C.I. I. A colored pattern was obtained in the same manner as in Example 119Z2 except that it was replaced with Pigment Green 59. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 47Z2.

  In Table 45Z2, Table 46Z2, and Table 47Z2, chemical formulas of the compounds represented by formula (IaZ2-1) are shown.

  In the examination of Example Z2, from the above results, in the colored coating film formed from the colored curable composition containing the compound of the present invention, C.I. I. It was found that the retardation value was smaller than that of a colored coating film formed from a colored curable composition containing Pigment Yellow 185.

[Example Z3]
Example 1Z3
10.3 parts of phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 44.8 parts of methanol were mixed.
While maintaining the temperature at 20 to 25 ° C., 8.01 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) was added dropwise to the obtained mixture.
The resulting mixture was stirred at 20-25 ° C. for 2 hours.
While maintaining the temperature at 20 to 25 ° C., 10 parts of methanol was added to the obtained mixture.
The resulting mixture was stirred at 20-25 ° C. for 2 hours.
To the obtained mixture, 7.49 parts of 2-cyanoacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 4.98 parts of acetic acid were added, and the resulting mixture was heated at 40 ° C. for 2 hours and then at 65 ° C. for 2 hours. Stir.
To the obtained mixture, 11.3 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.), 6.53 parts of acetic acid and 160 parts of water were added, and the resulting mixture was stirred at 65 ° C. for 3 hours at room temperature. The mixture was stirred at 75 ° C. for 2 hours for 2 days.
230 parts of methanol was added to the obtained mixture at room temperature.
The obtained compound was filtered, and the obtained residue was washed once with 170 parts of methanol, twice with 400 parts of methanol, once with 1000 parts of water, and 11 times with 200 parts of methanol.
To the obtained residue, 641 parts of a 5% aqueous sodium hydroxide solution was added and stirred at room temperature.
The resulting mixture was filtered, and the resulting residue was washed with 1000 parts of water.
To the obtained residue, 478 parts of water was added and stirred at room temperature.
The resulting mixture was filtered and the resulting residue was washed with 500 parts of water.
The obtained residue was dried to obtain 19.1 parts of a compound represented by the formula (IZ3-1).

<Identification of Compound Represented by Formula (IZ3-1)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 324
Exact Mass: 323

Example 2Z3
Except for replacing phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) with 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.), the same procedure as in Example 1Z3 was carried out and represented by the formula (IZ3-19) A compound was obtained.

<Identification of Compound Represented by Formula (IZ3-19)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 369
Exact Mass: 368

Example 3Z3
Except for replacing phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) with 4-tert-butylphthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.), the same procedure as in Example 1Z3 was carried out, and formula (IZ3-6) The compound represented was obtained.

<Identification of Compound Represented by Formula (IZ3-6)>
(Mass spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 380
Exact Mass: 379

Example 4Z3
10.3 parts of phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 44.8 parts of methanol were mixed.
While maintaining the temperature at 20 to 25 ° C., 8.01 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) was added dropwise to the obtained mixture.
The resulting mixture was stirred at 20-25 ° C. for 2 hours.
While maintaining the temperature at 20 to 25 ° C., 10 parts of methanol was added to the obtained mixture.
The resulting mixture was stirred at 20-25 ° C. for 2 hours.
To the obtained mixture, 7.49 parts of 2-cyanoacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 4.98 parts of acetic acid were added, and the resulting mixture was heated at 40 ° C. for 2 hours and then at 65 ° C. for 2 hours. Stir.
To the obtained mixture, 11.3 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.), 6.53 parts of acetic acid and 160 parts of water were added, and the resulting mixture was stirred at 65 ° C. for 3 hours at room temperature. The mixture was stirred at 75 ° C. for 2 hours for 2 days.
230 parts of methanol was added to the obtained mixture at room temperature.
The obtained compound was filtered, and the obtained residue was washed once with 170 parts of methanol, twice with 400 parts of methanol, once with 1000 parts of water, and 11 times with 200 parts of methanol.
To the obtained residue, 641 parts of a 5% aqueous sodium hydroxide solution was added and stirred at room temperature.
The resulting mixture was filtered, and the resulting residue was washed with 1000 parts of water.
To the obtained residue, 478 parts of water was added and stirred at room temperature.
The resulting mixture was filtered and the resulting residue was washed with 500 parts of water.
The obtained residue was purified by column chromatography to obtain a compound part represented by the formula (IZ3-1).

<Identification of Compound Represented by Formula (IZ3-1)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 324
Exact Mass: 323

Example 5Z3
10.0 parts of 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 149 parts of methanol were mixed. While maintaining the temperature at 2 to 6 ° C., 5.86 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) was dropped into the obtained mixture over 20 minutes. The resulting mixture was stirred for 5 hours while maintaining at 5 ° C. or lower.
While maintaining the obtained mixture at 5 ° C. or lower, 5.79 parts of acetic acid, 4.86 parts of 2-cyanoacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 74 parts of methanol were added. The resulting mixture was stirred at 65 ° C. for 3 days.
To the obtained mixture, 2.88 parts of acetic acid and 2.43 parts of 2-cyanoacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) were added.
The resulting mixture was stirred at 65 ° C. for 3 days.
By this time, in addition to the methanol described above, a total of 140 parts of methanol was added.
To the obtained mixture, 24.0 parts of acetic acid, 15.3 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.) and 363 parts of water were added and stirred at 65 ° C. for 9 days.
The solvent of the obtained mixture was distilled off with a rotary evaporator, and then the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ3-19).

<Identification of Compound Represented by Formula (IZ3-19)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 369
Exact Mass: 368

Example 6Z3
10.0 parts of 4-tert-butylphthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 84 parts of methanol were mixed. While maintaining the temperature at 5 ° C. or lower, a mixture of 8.15 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 73 parts of methanol was dropped into the obtained mixture over 1 hour. The resulting mixture was stirred at 5-20 ° C. for 2 days.
Under 10 to 20 ° C., 5.42 parts of acetic acid and 4.56 parts of 2-cyanoacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) were added to the obtained mixture. The resulting mixture was stirred at 65 ° C. for 3 days.
To the obtained mixture, 2.69 parts of acetic acid and 2.28 of 2-cyanoacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) were added and stirred at 65 ° C. for 3 days.
By this time, a total of 206 parts of methanol was added in addition to the methanol described above.
To the obtained mixture, 5.36 parts of acetic acid, 7.25 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.) and 363 parts of water were added and stirred at 65 ° C. for 9 days.
After distilling off the solvent of the obtained mixture with a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ3-6).

<Identification of Compound Represented by Formula (IZ3-6)>
(Mass spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 380
Exact Mass: 379

Example 7Z3
5.0 parts of 4,5-dichlorophthalonitrile and 62 parts of methanol were mixed.
While maintaining this mixture at 5 ° C. or lower, a 25% sodium methoxide methanol solution containing sodium methoxide having a mole number 0.5 times that of 5.0 parts of 4,5-dichlorophthalonitrile was added.
The mixture was stirred at 5 ° C. or lower for 5 hours.
While maintaining this mixture at 5 ° C. or lower, 2-cyanoacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) and acetic acid 6 having a molar number 1.5 times the molar number of 5.0 parts of 4,5-dichlorophthalonitrile. .1 part was added.
The mixture was stirred at 65 ° C. for 3 days.
This mixture was mixed with 4.2 parts of acetic acid, 5.2 parts of barbituric acid, 500 parts of methanol and 562 parts of water, and stirred at 65 ° C. for 9 days.
After the solvent of this mixture was distilled off with a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ3-8).

<Identification of Compound Represented by Formula (IZ3-8)>
(Mass spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 392
Exact Mass: 391

Example 101Z3
Pigment: C.I. I. Pigment Green 58 60 parts,
8.1 parts of an acrylic pigment dispersant,
Resin (B): 73 parts of resin B5 solution,
And Solvent (E): 290 parts of propylene glycol monomethyl ether acetate was mixed, and a pigment dispersion (colorant (A1Z3) -containing solution) in which the pigment was dispersed using a bead mill was prepared.
Separately
Colorant (AZ3): 50 parts of the compound represented by the formula (IZ3-1) obtained in Example 1Z3,
Dispersant (BYK-LPN6919; manufactured by Big Chemie Japan Co., Ltd.) 58 parts,
Resin (B): 93 parts of resin B3 solution,
And Solvent (E): 800 parts of propylene glycol monomethyl ether acetate was mixed, and the compound represented by the formula (IZ3-1) obtained in Example 1Z3 was dispersed using a bead mill to obtain a colored composition.
Then
Total amount of the obtained pigment dispersion (colorant (A1Z3) -containing liquid);
400 parts of the resulting colored composition;
Resin (B): Resin B1 solution 45 parts;
Polymerizable compound (C): 25 parts of dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kayaku Co., Ltd.);
Polymerization initiator (D): N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure (registered trademark) OXE-01; manufactured by BASF Corporation) 15 parts;
Solvent (E): 86 parts of propylene glycol monomethyl ether acetate;
And leveling agent: polyether-modified silicone oil (Toray Silicone SH8400; manufactured by Toray Dow Corning Co., Ltd.) 0.12 parts;
Were mixed to obtain a colored curable composition 1Z3.

[Preparation of colored pattern]
The colored curable composition 1Z3 was applied by spin coating on a 2 inch square glass substrate (Eagle XG; manufactured by Corning), and then pre-baked at 100 ° C. for 3 minutes to form a colored curable composition layer. After cooling, the distance between the substrate on which the colored curable composition layer is formed and the quartz glass photomask is set to 200 μm, and an exposure machine (TME-150RSK; manufactured by Topcon Co., Ltd.) is used in an air atmosphere at 80 mJ / It exposed with an exposure amount of cm ² (365 nm reference). A photomask having a 100 μm line and space pattern was used. The colored curable composition layer after exposure was developed by being immersed in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ° C. for 70 seconds, and washed with water. The colored curable composition layer was post-baked at 230 ° C. for 30 minutes to obtain a colored pattern.

[Phase difference measurement]
The colored curable composition 1Z3 was applied by spin coating on a 2 inch square glass substrate (Eagle XG; manufactured by Corning), and then pre-baked at 100 ° C. for 3 minutes to form a colored curable composition layer. After cooling, the colored curable composition layer was exposed using an exposure machine (TME-150RSK; manufactured by Topcon Corporation) at an exposure amount of 80 mJ / cm ² (based on 365 nm) in an air atmosphere. The colored curable composition layer after exposure was developed by being immersed in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ° C. for 70 seconds, and washed with water. The colored curable composition layer was post-baked at 230 ° C. for 30 minutes to obtain a colored coating film.
The film thickness of the obtained colored coating film was measured using DEKTAK3 (manufactured by Nippon Vacuum Technology Co., Ltd.).
Using an ellipsometer (M-220 type spectroscopic ellipsometer; manufactured by JASCO Corporation), the retardation value of the colored coating film at an angle of 45 ° was measured. Light having a wavelength of 550 nm was used for measuring the phase difference value. The results are shown in Table 7Z3.

Example 102Z3
Coloring and curing in the same manner as in Example 101Z3, except that the compound represented by the formula (IZ3-1) obtained in Example 1Z3 is replaced with the compound represented by the formula (IZ3-19) obtained in Example 2Z3. Composition 2Z3 was obtained to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 7Z3.

Example 103Z3
Coloring and curing in the same manner as in Example 101Z3, except that the compound represented by the formula (IZ3-1) obtained in Example 1Z3 is replaced with the compound represented by the formula (IZ3-6) obtained in Example 3Z3. Composition 3Z3 was obtained to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 7Z3.

Example 104Z3
C. I. Pigment Green 58 is a C.I. I. A colored curable composition 4Z3 was obtained and a colored pattern was obtained in the same manner as in Example 101Z3 except that the pigment green 7 was used. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 7Z3.

Example 105Z3
C. I. Pigment Green 58 is a C.I. I. Example 101Z3 except that the compound represented by the formula (IZ3-1) obtained in Example 1Z3 is replaced with the compound represented by the formula (IZ3-19) obtained in Example 2Z3 in place of Pigment Green 7. Similarly, a colored curable composition 5Z3 was obtained to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 7Z3.

Example 106Z3
C. I. Pigment Green 58 is a C.I. I. Example 101Z3 except that the compound represented by the formula (IZ3-1) obtained in Example 1Z3 is replaced with the compound represented by the formula (IZ3-6) obtained in Example 3Z3 in place of Pigment Green 7. Similarly, a colored curable composition 6Z3 was obtained to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 7Z3.

Example 107Z3
C. I. Pigment Green 58 is a C.I. I. A colored curable composition 7Z3 was obtained in the same manner as in Example 101Z3 except that the pigment green 59 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 7Z3.

Example 108Z3
C. I. Pigment Green 58 is a C.I. I. Example 101Z3 except that the compound represented by the formula (IZ3-1) obtained in Example 1Z3 was replaced with the compound represented by the formula (IZ3-19) obtained in Example 2Z3 in place of Pigment Green 59. Similarly, a colored curable composition 8Z3 was obtained to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 7Z3.

Example 109Z3
C. I. Pigment Green 58 is a C.I. I. Example 101Z3 except that the compound represented by the formula (IZ3-1) obtained in Example 1Z3 was replaced with the compound represented by the formula (IZ3-6) obtained in Example 3Z3 in place of Pigment Green 59. Similarly, a colored curable composition 9Z3 was obtained to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 7Z3.

Comparative Example 1Z3
The compound represented by the formula (IZ3-1) obtained in Example 1Z3 was prepared by C.I. I. A colored curable composition C1Z3 was obtained in the same manner as in Example 101Z3 except that the pigment yellow 185 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 7Z3.

Comparative Example 2Z3
C. I. Pigment Green 58 is a C.I. I. Instead of CI Pigment Green 7, the compound represented by the formula (IZ3-1) obtained in Example 1Z3 was used as C.I. I. A colored curable composition C2Z3 was obtained in the same manner as in Example 101Z3 except that the pigment yellow 185 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 7Z3.

Comparative Example 3Z3
C. I. Pigment Green 58 is a C.I. I. Instead of CI Pigment Green 59, the compound represented by the formula (IZ3-1) obtained in Example 1Z3 was used as C.I. I. A colored curable composition C3Z3 was obtained in the same manner as in Example 101Z3 except that the pigment yellow 185 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 7Z3.

Example 110Z3
Pigment: C.I. I. Pigment Green 58 60 parts,
8.1 parts of an acrylic pigment dispersant,
Resin (B): 73 parts of resin B5 solution,
And Solvent (E): 290 parts of propylene glycol monomethyl ether acetate was mixed, and a pigment dispersion (colorant (A1Z3) -containing solution) in which the pigment was dispersed using a bead mill was prepared.
Separately
Colorant (AZ3): 50 parts of a compound represented by the formula (IZ3-1),
58 parts of a dispersant solution (solid content 60%),
Resin (B): 93 parts of resin B3 solution,
And Solvent (E): 800 parts of propylene glycol monomethyl ether acetate was mixed, and the compound represented by formula (IZ3-1) was dispersed using a bead mill to obtain a colored composition.
Then
Total amount of the obtained pigment dispersion (colorant (A1Z3) -containing liquid);
400 parts of the resulting colored composition;
Resin (B): Resin B1 solution 45 parts;
Polymerizable compound (C): 25 parts of dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kayaku Co., Ltd.);
Polymerization initiator (D): N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure (registered trademark) OXE-01; manufactured by BASF Corporation) 15 parts;
Solvent (E): 86 parts of propylene glycol monomethyl ether acetate;
And leveling agent: polyether-modified silicone oil (Toray Silicone SH8400; manufactured by Toray Dow Corning Co., Ltd.) 0.12 parts;
Were mixed to obtain a colored curable composition 10Z3.

  A colored pattern was produced in the same manner as in Example 101Z3 except that the colored curable composition 10Z3 was used instead of the colored curable composition 1Z3. Moreover, it replaced with colored curable composition 1Z3, and except using colored curable composition 10Z3, it carried out similarly to Example 101Z3, obtained the colored coating film, and performed the film thickness measurement and the phase difference value measurement. The results are shown in Table 8Z3.

Example 111Z3-Example 113Z3
A colored pattern was obtained in the same manner as in Example 110Z3 except that the compound represented by the formula (IZ3-1) was replaced with the colorant shown in the “Colorant” column of Table 8Z3. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 8Z3.

Example 114Z3-Example 117Z3
The compound represented by the formula (IZ3-1) was replaced with the compound shown in the “Colorant” column of Table 8Z3, and C.I. I. Pigment Green 58 is a C.I. I. A colored pattern was obtained in the same manner as in Example 110Z3 except that the pigment green 7 was used. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 8Z3.

Example 118Z3-Example 121Z3
The compound represented by the formula (IZ3-1) was replaced with the compound shown in the “Colorant” column of Table 8Z3, and C.I. I. Pigment Green 58 is a C.I. I. A colored pattern was obtained in the same manner as in Example 110Z3 except that it was replaced with Pigment Green 59. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 8Z3.

  In Example Z3, from the above results, in the colored coating film formed from the colored curable composition containing the compound of the present invention, C.I. I. It was found that the retardation value was smaller than that of a colored coating film formed from a colored curable composition containing Pigment Yellow 185.

[Example Z4]
Example 1Z4
20.5 parts of phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 171 parts of methanol were mixed.
While maintaining the temperature at 5 ° C., a mixture of 23.9 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 215 parts of methanol was dropped into the obtained mixture over 1 hour and 20 minutes. did.
The resulting mixture was stirred at 2-6 ° C. for 7 hours.
To the obtained mixture, 15.6 parts of acetic acid, 17.9 parts of 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 118 parts of methanol were added, and the mixture was stirred at 40 ° C. for 15 hours. Stir at 7 ° C. for 7 hours.
To the obtained mixture, 7.82 parts of acetic acid, 8.97 parts of 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 80 parts of methanol were added, and the mixture was stirred at 40 ° C. for 17 hours, 65 hours. Stir at 4 ° C. for 4 hours.
To the obtained mixture, 12.6 parts of acetic acid, 14.3 parts of 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 104 parts of methanol were added, and the mixture was added at 40 ° C. for 16 hours, 60 hours. Stir at 9 ° C. for 9 hours.
To the obtained mixture, 6.32 parts of acetic acid, 7.19 parts of 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 40 parts of methanol were added, and the mixture was heated at 60 ° C. for 3 hours at room temperature. For 59 hours.
To the obtained mixture, 15.7 parts of acetic acid, 20.5 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.), 16 parts of methanol and 744 parts of water were added and stirred at 60 ° C. for 24 hours.
The resulting mixture was filtered and the residue was washed with 50% aqueous methanol.
The obtained residue was dried under reduced pressure at 60 ° C. to obtain 43.1 parts of a compound represented by the formula (IZ4-1).

<Identification of Compound Represented by Formula (IZ4-1)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 352
Exact Mass: 351

Example 2Z4
Except that 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) is replaced with 2-cyano-N, N-diethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.), it is the same as Example 1Z4. The compound represented by Formula (IZ4-2) was obtained.

<Identification of Compound Represented by Formula (IZ4-2)>
(Mass spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 380
Exact Mass: 379

Example 3Z4
The same procedure as in Example 1Z4 was performed except that phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) was replaced with 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.), and represented by the formula (IZ4-79). A compound was obtained.

<Identification of Compound Represented by Formula (IZ4-79)>
(Mass Spectrometry) ionization mode = ESI +: m / z = [M + H] + 397
Exact Mass: 396

Example 4Z4
Instead of phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) with 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.), 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) The compound represented by the formula (IZ4-80) was obtained in the same manner as in Example 1Z4 except that -cyano-N, N-diethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) was used.

<Identification of Compound Represented by Formula (IZ4-80)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 425
Exact Mass: 424

Example 5Z4
Except for replacing phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) with 4-tert-butylphthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.), the same procedure as in Example 1Z4 was performed, and the formula (IZ4-40) was used. The compound represented was obtained.

<Identification of Compound Represented by Formula (IZ4-40)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 408
Exact Mass: 407

Example 6Z4
2-Cyano-N, N-dimethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) instead of 4-tert-butylphthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) instead of phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) Was carried out in the same manner as in Example 1Z4 except that 2-cyano-N, N-diethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) was obtained, to obtain a compound represented by the formula (IZ4-41).

<Identification of Compound Represented by Formula (IZ4-41)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 436
Exact Mass: 435

Example 7Z4
20.5 parts of phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 171 parts of methanol were mixed.
While maintaining the temperature at 2 to 5 ° C., a mixture of 23.9 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 215 parts of methanol was added to the obtained mixture over 1 hour and 20 minutes. And dripped.
The resulting mixture was stirred at 2-6 ° C. for 7 hours.
To the obtained mixture, 15.6 parts of acetic acid, 17.9 parts of 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 46.9 parts of methanol were added.
By this time, a total of 71 parts of methanol was added in addition to the methanol described above.
The resulting mixture was stirred at 40 ° C. for 15 hours and at 65 ° C. for 7 hours.
To the obtained mixture, 7.82 parts of acetic acid, 8.97 parts of 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 80 parts of methanol were added, and the mixture was stirred at 40 ° C. for 17 hours, 65 hours. Stir at 4 ° C. for 4 hours.
To the obtained mixture, 12.6 parts of acetic acid, 14.3 parts of 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 104 parts of methanol were added, and the mixture was added at 40 ° C. for 16 hours, 60 hours. Stir at 9 ° C. for 9 hours.
To the obtained mixture, 6.32 parts of acetic acid, 7.19 parts of 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 40 parts of methanol were added, and the mixture was heated at 60 ° C. for 3 hours at room temperature. For 59 hours.
To the obtained mixture, 15.7 parts of acetic acid, 20.5 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.), 16 parts of methanol and 744 parts of water were added and stirred at 60 ° C. for 9 days.
The resulting mixture was filtered and the residue was washed with 50% aqueous methanol.
The obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ4-1).

<Identification of Compound Represented by Formula (IZ4-1)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 352
Exact Mass: 351

Example 8Z4
10.0 parts of phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 83 parts of methanol were mixed.
While maintaining the temperature at 2 to 5 ° C., a mixture of 11.7 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 105 parts of methanol was added to the obtained mixture over 1 hour and 30 minutes. And dripped.
The resulting mixture was stirred at 2-6 ° C. for 7 hours.
To the obtained mixture, 7.62 parts of acetic acid, 10.9 parts of 2-cyano-N, N-diethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 140 parts of methanol were added.
By this time, a total of 35 parts of methanol was added in addition to the methanol described above.
The resulting mixture was stirred at 65 ° C. for 3 days.
To the obtained mixture, 3.82 parts of acetic acid and 5.48 parts of 2-cyano-N, N-diethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) were added and stirred at 65 ° C. for 3 days.
To the obtained mixture, 7.65 parts of acetic acid, 10.0 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.) and 363 parts of water were added and stirred at 65 ° C. for 9 days.
After distilling off the solvent of the obtained mixture with a rotary evaporator, the obtained residue was purified by column chromatography and carried out in the same manner as in Example 1Z4 to obtain a compound represented by the formula (IZ4-2). .

<Identification of Compound Represented by Formula (IZ4-2)>
(Mass spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 380
Exact Mass: 379

Example 9Z4
2.56 parts of 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 22 parts of methanol were mixed. 2.96 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) was added to the resulting mixture while maintaining the temperature at 5 ° C. or lower. The resulting mixture was stirred for 3 hours while maintaining at 5 ° C. or lower.
While maintaining the obtained mixture at 5 ° C. or lower, 1.84 parts of 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 1.90 parts of acetic acid were added. The resulting mixture was stirred at 40 ° C. for 1 hour and at 65 ° C. for 1 hour.
To the obtained mixture, 2.09 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.), 2.48 parts of acetic acid and 41 parts of water were added.
By this time, a total of 24 parts of methanol was added in addition to the methanol described above.
The resulting mixture was stirred at 65 ° C. for 15 hours.
After distilling off the solvent of the obtained mixture with a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ4-79).

<Identification of Compound Represented by Formula (IZ4-79)>
(Mass Spectrometry) ionization mode = ESI +: m / z = [M + H] + 397
Exact Mass: 396

Example 10Z4
10.0 parts of 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 149 parts of methanol were mixed. While maintaining the temperature at 2 to 6 ° C., 5.86 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) was dropped into the obtained mixture over 20 minutes. The resulting mixture was stirred for 5 hours while maintaining at 5 ° C. or lower.
While maintaining the obtained mixture at 5 ° C. or lower, 5.79 parts of acetic acid, 8.10 parts of 2-cyano-N, N-diethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 74 parts of methanol were added. The resulting mixture was stirred at 65 ° C. for 3 days.
To the obtained mixture, 2.88 parts of acetic acid and 4.05 parts of 2-cyano-N, N-diethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) were added.
The resulting mixture was stirred at 65 ° C. for 3 days.
By this time, in addition to the methanol described above, a total of 140 parts of methanol was added.
To the obtained mixture, 24.0 parts of acetic acid, 15.3 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.) and 363 parts of water were added and stirred at 65 ° C. for 9 days.
After distilling off the solvent of the obtained mixture with a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ4-80).

<Identification of Compound Represented by Formula (IZ4-80)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 425
Exact Mass: 424

Example 11Z4
10.0 parts of 4-tert-butylphthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 84 parts of methanol were mixed. While maintaining the temperature at 5 ° C. or lower, a mixture of 8.15 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 73 parts of methanol was dropped into the obtained mixture over 1 hour. The resulting mixture was stirred at 5-20 ° C. for 2 days.
Under 10 to 20 ° C., 5.42 parts of acetic acid and 6.09 parts of 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) were added to the obtained mixture. The resulting mixture was stirred at 65 ° C. for 3 days.
To the obtained mixture, 2.69 parts of acetic acid and 3.04 of 2-cyano-N, N-dimethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) were added and stirred at 65 ° C. for 3 days.
By this time, a total of 206 parts of methanol was added in addition to the methanol described above.
To the obtained mixture, 5.36 parts of acetic acid, 7.25 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.) and 363 parts of water were added and stirred at 65 ° C. for 9 days.
After the solvent of the obtained mixture was distilled off with a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ4-40).

<Identification of Compound Represented by Formula (IZ4-40)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 408
Exact Mass: 407

Example 12Z4
10.0 parts of 4-tert-butylphthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 84 parts of methanol were mixed. While maintaining the temperature at 5 ° C. or lower, a mixture of 8.15 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 73 parts of methanol was dropped into the obtained mixture over 1 hour. The resulting mixture was stirred at 5-20 ° C. for 2 days.
Under 10 to 20 ° C., 5.42 parts of acetic acid and 7.61 parts of 2-cyano-N, N-diethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) were added to the obtained mixture. The resulting mixture was stirred at 65 ° C. for 3 days.
To the obtained mixture, 2.69 parts of acetic acid and 3.80 of 2-cyano-N, N-diethylacetamide (manufactured by Tokyo Chemical Industry Co., Ltd.) were added and stirred at 65 ° C. for 3 days.
By this time, a total of 206 parts of methanol was added in addition to the methanol described above.
To the obtained mixture, 5.36 parts of acetic acid, 7.25 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.) and 363 parts of water were added and stirred at 65 ° C. for 9 days.
After distilling off the solvent of the obtained mixture with a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ4-41).

<Identification of Compound Represented by Formula (IZ4-41)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 436
Exact Mass: 435

Example 13Z4
5.0 parts of 4,5-dichlorophthalonitrile and 62 parts of methanol were mixed.
While maintaining this mixture at 5 ° C. or lower, a 25% sodium methoxide methanol solution containing sodium methoxide having a mole number 0.5 times that of 5.0 parts of 4,5-dichlorophthalonitrile was added.
The mixture was stirred at 5 ° C. or lower for 5 hours.
While maintaining the temperature at 5 ° C. or lower, this mixture was mixed with 2-cyano-N, N-dimethylacetamide (Tokyo Chemical Industry Co., Ltd.) having a molar number 1.5 times the molar number of 5.0 parts of 4,5-dichlorophthalonitrile. )) And 6.1 parts of acetic acid.
The mixture was stirred at 65 ° C. for 3 days.
This mixture was mixed with 4.2 parts of acetic acid, 5.2 parts of barbituric acid, 500 parts of methanol and 562 parts of water, and stirred at 65 ° C. for 9 days.
After the solvent of this mixture was distilled off with a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ4-321).

<Identification of Compound Represented by Formula (IZ4-321)>
(Mass spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 420
Exact Mass: 419

Example 101Z4
Pigment: C.I. I. Pigment Green 58 60 parts,
8.1 parts of an acrylic pigment dispersant,
Resin (B): 73 parts of resin B5 solution, and solvent (E): 290 parts of propylene glycol monomethyl ether acetate, and a pigment dispersion (colorant (A1Z4) -containing liquid) in which the pigment is dispersed using a bead mill. Prepared.
Separately
Colorant (AZ4): 50 parts of the compound represented by the formula (IZ4-1) obtained in Example 1Z4,
Dispersant (BYK-LPN6919; manufactured by Big Chemie Japan Co., Ltd.) 58 parts,
Compound represented by formula (IZ4-1) obtained in Example 1Z4 by mixing resin (B): 93 parts of resin B3 solution and solvent (E): 800 parts of propylene glycol monomethyl ether acetate and using a bead mill. Was dispersed to obtain a colored composition.
Then
Total amount of the obtained pigment dispersion (colorant (A1Z4) -containing liquid);
400 parts of the resulting colored composition;
Resin (B): Resin B1 solution 45 parts;
Polymerizable compound (C): 25 parts of dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kayaku Co., Ltd.);
Polymerization initiator (D): N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure (registered trademark) OXE-01; manufactured by BASF Corporation) 15 parts;
Solvent (E): 86 parts of propylene glycol monomethyl ether acetate; and leveling agent: polyether-modified silicone oil (Toray Silicone SH8400; manufactured by Toray Dow Corning Co., Ltd.) 0.12 parts; Got.

[Preparation of colored pattern]
The colored curable composition 1Z4 was applied by spin coating on a 2-inch square glass substrate (Eagle XG; manufactured by Corning), and then pre-baked at 100 ° C. for 3 minutes to form a colored curable composition layer. After cooling, the distance between the substrate on which the colored curable composition layer is formed and the quartz glass photomask is set to 200 μm, and an exposure machine (TME-150RSK; manufactured by Topcon Co., Ltd.) is used in an air atmosphere at 80 mJ / It exposed with an exposure amount of cm ² (365 nm reference). A photomask having a 100 μm line and space pattern was used. The colored curable composition layer after exposure was developed by being immersed in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ° C. for 70 seconds, and washed with water. The colored curable composition layer was post-baked at 230 ° C. for 30 minutes to obtain a colored pattern.

[Phase difference measurement]
The colored curable composition 1Z4 was applied by spin coating on a 2-inch square glass substrate (Eagle XG; manufactured by Corning), and then pre-baked at 100 ° C. for 3 minutes to form a colored curable composition layer. After cooling, the colored curable composition layer was exposed using an exposure machine (TME-150RSK; manufactured by Topcon Corporation) at an exposure amount of 80 mJ / cm ² (based on 365 nm) in an air atmosphere. The colored curable composition layer after exposure was developed by being immersed in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ° C. for 70 seconds, and washed with water. The colored curable composition layer was post-baked at 230 ° C. for 30 minutes to obtain a colored coating film.
The film thickness of the obtained colored coating film was measured using DEKTAK3 (manufactured by Nippon Vacuum Technology Co., Ltd.).
Using an ellipsometer (M-220 type spectroscopic ellipsometer; manufactured by JASCO Corporation), the retardation value of the colored coating film at an angle of 45 ° was measured. Light having a wavelength of 550 nm was used for measuring the phase difference value. The results are shown in Table 21Z4.

Example 102Z4
Coloring and curing in the same manner as in Example 101Z4, except that the compound represented by the formula (IZ4-1) obtained in Example 1Z4 is replaced with the compound represented by the formula (IZ4-2) obtained in Example 2Z4. Composition 2Z4 was obtained to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 21Z4.

Example 103Z4
Coloring and curing in the same manner as in Example 101Z4, except that the compound represented by the formula (IZ4-1) obtained in Example 1Z4 is replaced with the compound represented by the formula (IZ4-79) obtained in Example 3Z4. Property composition 3Z4 was obtained to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 21Z4.

Example 104Z4
Coloring and curing in the same manner as in Example 101Z4, except that the compound represented by the formula (IZ4-1) obtained in Example 1Z4 is replaced with the compound represented by the formula (IZ4-80) obtained in Example 4Z4. Composition 4Z4 was obtained to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 21Z4.

Example 105Z4
Coloring and curing in the same manner as in Example 101Z4, except that the compound represented by the formula (IZ4-1) obtained in Example 1Z4 is replaced with the compound represented by the formula (IZ4-40) obtained in Example 5Z4. Composition 5Z4 was obtained to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 21Z4.

Example 106Z4
Coloring and curing in the same manner as in Example 101Z4, except that the compound represented by the formula (IZ4-1) obtained in Example 1Z4 is replaced with the compound represented by the formula (IZ4-41) obtained in Example 6Z4. Composition 6Z4 was obtained to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 21Z4.

Example 107Z4
C. I. Pigment Green 58 is a C.I. I. A colored curable composition 7Z4 was obtained in the same manner as in Example 101Z4 except that the pigment green 7 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 21Z4.

Example 108Z4
C. I. Pigment Green 58 is a C.I. I. Example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in Example 1Z4 is replaced with the compound represented by the formula (IZ4-2) obtained in Example 2Z4 in place of Pigment Green 7. Similarly, a colored curable composition 8Z4 was obtained to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 21Z4.

Example 109Z4
C. I. Pigment Green 58 is a C.I. I. Example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in Example 1Z4 is replaced with the compound represented by the formula (IZ4-79) obtained in Example 3Z4 in place of Pigment Green 7. Similarly, a colored curable composition 9Z4 was obtained to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 21Z4.

Example 110Z4
C. I. Pigment Green 58 is a C.I. I. Example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in Example 1Z4 is replaced with the compound represented by the formula (IZ4-80) obtained in Example 4Z4 in place of Pigment Green 7. Similarly, a colored curable composition 10Z4 was obtained to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 21Z4.

Example 111Z4
C. I. Pigment Green 58 is a C.I. I. Example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in Example 1Z4 is replaced with the compound represented by the formula (IZ4-40) obtained in Example 5Z4 in place of Pigment Green 7. Similarly, a colored curable composition 11Z4 was obtained to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 21Z4.

Example 112Z4
C. I. Pigment Green 58 is a C.I. I. Example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in Example 1Z4 is replaced with the compound represented by the formula (IZ4-41) obtained in Example 6Z4 in place of Pigment Green 7. Similarly, a colored curable composition 12Z4 was obtained to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 21Z4.

Example 113Z4
C. I. Pigment Green 58 is a C.I. I. Except having replaced with the pigment green 59, it carried out similarly to Example 101Z4, and obtained the colored curable composition 13Z4, and obtained the coloring pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 21Z4.

Example 114Z4
C. I. Pigment Green 58 is a C.I. I. Example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in Example 1Z4 is replaced with the compound represented by the formula (IZ4-2) obtained in Example 2Z4 in place of Pigment Green 59. Similarly, a colored curable composition 14Z4 was obtained to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 21Z4.

Example 115Z4
C. I. Pigment Green 58 is a C.I. I. Example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in Example 1Z4 was replaced with the compound represented by the formula (IZ4-79) obtained in Example 3Z4 in place of Pigment Green 59. Similarly, a colored curable composition 15Z4 was obtained to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 21Z4.

Example 116Z4
C. I. Pigment Green 58 is a C.I. I. Example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in Example 1Z4 was replaced with the compound represented by the formula (IZ4-80) obtained in Example 4Z4 in place of Pigment Green 59. Similarly, a colored curable composition 16Z4 was obtained to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 21Z4.

Example 117Z4
C. I. Pigment Green 58 is a C.I. I. Example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in Example 1Z4 is replaced with the compound represented by the formula (IZ4-40) obtained in Example 5Z4 in place of Pigment Green 59. Similarly, a colored curable composition 17Z4 was obtained to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 21Z4.

Example 118Z4
C. I. Pigment Green 58 is a C.I. I. Example 101Z4 except that the compound represented by the formula (IZ4-1) obtained in Example 1Z4 was replaced with the compound represented by the formula (IZ4-41) obtained in Example 6Z4 instead of Pigment Green 59. Similarly, a colored curable composition 18Z4 was obtained to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 21Z4.

Comparative Example 1Z4
The compound represented by the formula (IZ4-1) obtained in Example 1Z4 was obtained by C.I. I. A colored curable composition C1Z4 was obtained in the same manner as in Example 101Z4 except that it was replaced with CI Pigment Yellow 185 to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 21Z4.

Comparative Example 2Z4
C. I. Pigment Green 58 is a C.I. I. Instead of CI Pigment Green 7, the compound represented by the formula (IZ4-1) obtained in Example 1Z4 was converted to C.I. I. A colored curable composition C2Z4 was obtained in the same manner as in Example 101Z4 except that the pigment yellow 185 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 21Z4.

Comparative Example 3Z4
C. I. Pigment Green 58 is a C.I. I. Instead of CI Pigment Green 59, the compound represented by the formula (IZ4-1) obtained in Example 1Z4 was used as C.I. I. A colored curable composition C3Z4 was obtained in the same manner as in Example 101Z4 except that it was replaced with CI Pigment Yellow 185 to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 21Z4.

Example 119Z4
Pigment: C.I. I. Pigment Green 58 60 parts,
8.1 parts of an acrylic pigment dispersant,
Resin (B): 73 parts of resin B5 solution, and solvent (E): 290 parts of propylene glycol monomethyl ether acetate, and a pigment dispersion (colorant (A1Z4) -containing liquid) in which the pigment is dispersed using a bead mill. Prepared.
Separately
Colorant (AZ4): 50 parts of a compound represented by the formula (IZ4-1)
58 parts of a dispersant solution (solid content 60%),
Resin (B): 93 parts of resin B3 solution, and solvent (E): 800 parts of propylene glycol monomethyl ether acetate are mixed, and the compound represented by formula (IZ4-1) is dispersed using a bead mill to give a colored composition. I got a thing.
Then
Total amount of the obtained pigment dispersion (colorant (A1Z4) -containing liquid);
400 parts of the resulting colored composition;
Resin (B): Resin B1 solution 45 parts;
Polymerizable compound (C): 25 parts of dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kayaku Co., Ltd.);
Polymerization initiator (D): N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure (registered trademark) OXE-01; manufactured by BASF Corporation) 15 parts;
Solvent (E): 86 parts of propylene glycol monomethyl ether acetate; and leveling agent: polyether-modified silicone oil (Toray Silicone SH8400; manufactured by Toray Dow Corning Co., Ltd.) 0.12 parts; Got.

  A colored pattern was produced in the same manner as in Example 101Z4 except that the colored curable composition 19Z4 was used instead of the colored curable composition 1Z4. Moreover, it replaced with colored curable composition 1Z4, and except using colored curable composition 19Z4, it carried out similarly to Example 101Z4, and obtained the colored coating film, and performed the film thickness measurement and the phase difference value measurement. The results are shown in Table 22Z4.

Example 120Z4 to Example 125Z4
A colored pattern was obtained in the same manner as in Example 119Z4 except that the compound represented by the formula (IZ4-1) was replaced with the colorant shown in the “Colorant” column of Table 22Z4. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 22Z4.

Example 126Z4 to Example 132Z4
The compound represented by the formula (IZ4-1) was replaced with the compound shown in the “colorant” column of Table 22Z4, and C.I. I. Pigment Green 58 is a C.I. I. A colored pattern was obtained in the same manner as in Example 119Z4 except that the pigment green 7 was used. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 22Z4.

Example 133Z4 to Example 139Z4
The compound represented by the formula (IZ4-1) was replaced with the compound shown in the “colorant” column of Table 22Z4, and C.I. I. Pigment Green 58 is a C.I. I. A colored pattern was obtained in the same manner as in Example 119Z4 except that it was replaced with Pigment Green 59. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 22Z4.

  In Example Z4, from the above results, in the colored coating film formed from the colored curable composition containing the compound of the present invention, C.I. I. It was found that the retardation value was smaller than that of a colored coating film formed from a colored curable composition containing Pigment Yellow 185.

[Example Z5]
Example 1Z5
25.2 parts of 4-tert-butylphthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 212 parts of methanol were mixed. While maintaining the temperature at 5 ° C., a mixture of 20.5 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 184 parts of methanol was dropped into the obtained mixture over 1 hour. The resulting mixture was stirred at 5-20 ° C. for 2 days.
Under 10 to 20 ° C., 13.7 parts of acetic acid and 13.5 parts of 2-cyano-N-methylacetamide were added to the obtained mixture. The obtained mixture was stirred at 10 to 20 ° C. for 5 hours, and then stirred at 40 ° C. for 16 hours. To the obtained mixture, 6.79 parts of acetic acid, 6.75 parts of 2-cyano-N-methylacetamide and 201 parts of methanol were added and stirred at 40 ° C. for 6 hours and at 50 ° C. for 65 hours. To the obtained mixture, 13.5 parts of acetic acid, 18.3 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.) and 604 parts of water were added and stirred at 40 ° C. for 52 hours. The resulting mixture was filtered and the residue was washed with 50% aqueous methanol. The obtained residue was dried under reduced pressure at 60 ° C. to obtain 49.9 parts of a compound represented by the formula (IZ5-1).

<Identification of Compound Represented by Formula (IZ5-1)>
(Mass spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 394
Exact Mass: 393

Example 2Z5
The compound represented by the formula (IZ5-3) is obtained in the same manner as in Example 1Z5 except that 2-cyano-N-methylacetamide is replaced with 2-cyanoacetanilide (manufactured by Tokyo Chemical Industry Co., Ltd.). It was.

<Identification of Compound Represented by Formula (IZ5-3)>
(Mass Spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 456
Exact Mass: 455

Example 3Z5
The same procedure as in Example 1Z5 was performed except that 4-tert-butylphthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) was replaced by 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.), and the compound of formula (IZ5- The compound represented by 23) was obtained.

<Identification of Compound Represented by Formula (IZ5-23)>
(Mass spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 383
Exact Mass: 382

Example 4Z5
4-tert-butylphthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) is replaced by 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.), and 2-cyano-N-methylacetamide is replaced by 2-cyanoacetanilide (Tokyo Chemical Industry). Except having replaced with Kogyo Co., Ltd., it implemented similarly to Example 1Z5 and obtained the compound represented by a formula (IZ5-25).

<Identification of Compound Represented by Formula (IZ5-25)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 445
Exact Mass: 444

Example 5Z5
25.2 parts of 4-tert-butylphthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 212 parts of methanol were mixed. While maintaining the temperature at 5 ° C. or lower, a mixture of 20.5 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 184 parts of methanol was dropped into the obtained mixture over 1 hour. The resulting mixture was stirred at 5-20 ° C. for 2 days.
Under 10 to 20 ° C., 13.7 parts of acetic acid and 13.5 parts of 2-cyano-N-methylacetamide were added to the obtained mixture. The obtained mixture was stirred at 10 to 20 ° C. for 5 hours, and then stirred at 40 ° C. for 16 hours.
To the resulting mixture, 6.79 parts of acetic acid and 6.75 parts of 2-cyano-N-methylacetamide were added and stirred at 40 ° C. for 6 hours and at 50 ° C. for 65 hours. By this time, in addition to the methanol described above, a total of 201 parts of methanol was added.
To the obtained mixture, 13.5 parts of acetic acid, 18.3 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.) and 604 parts of water were added and stirred at 40 ° C. for 53 hours.
The resulting mixture was filtered and the residue was washed with 50% aqueous methanol. The obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ5-1).

<Identification of Compound Represented by Formula (IZ5-1)>
(Mass spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 394
Exact Mass: 393

Example 6Z5
10.0 parts of 4-tert-butylphthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 84 parts of methanol were mixed. While maintaining the temperature at 5 ° C. or lower, a mixture of 8.15 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 73 parts of methanol was dropped into the obtained mixture over 1 hour. The resulting mixture was stirred at 5-20 ° C. for 2 days.
Under 10 to 20 ° C., 5.42 parts of acetic acid and 8.69 parts of 2-cyanoacetanilide (manufactured by Tokyo Chemical Industry Co., Ltd.) were added to the obtained mixture. The resulting mixture was stirred at 65 ° C. for 3 days.
To the obtained mixture, 2.69 parts of acetic acid and 4.35 of 2-cyanoacetanilide (manufactured by Tokyo Chemical Industry Co., Ltd.) were added and stirred at 65 ° C. for 3 days.
By this time, a total of 206 parts of methanol was added in addition to the methanol described above.
To the obtained mixture, 5.36 parts of acetic acid, 7.25 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.) and 363 parts of water were added and stirred at 65 ° C. for 9 days.
The solvent of the obtained mixture was distilled off using a rotary evaporator, and then the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ5-3).

<Identification of Compound Represented by Formula (IZ5-3)>
(Mass Spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 456
Exact Mass: 455

Example 7Z5
25.2 parts of 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 376 parts of methanol were mixed. While maintaining the temperature at 2 to 6 ° C., 14.8 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) was added dropwise to the obtained mixture over 20 minutes. The resulting mixture was stirred for 5 hours while maintaining at 5 ° C. or lower.
While maintaining the resulting mixture at 5 ° C. or lower, 9.31 parts of acetic acid and 14.4 parts of 2-cyano-N-methylacetamide were added. The resulting mixture was stirred at room temperature for 14 hours and at 40 ° C. for 29 hours.
To the obtained mixture, 1.50 parts of acetic acid and 2.24 parts of 2-cyano-N-methylacetamide were added. The resulting mixture was stirred at 40 ° C. for 19 hours.
To the resulting mixture, 4.83 parts of acetic acid and 7.36 parts of 2-cyano-N-methylacetamide were added. The resulting mixture was stirred at 40 ° C. for 79 hours.
To the obtained mixture, 4.60 parts of acetic acid and 7.30 parts of 2-cyano-N-methylacetamide were added. The resulting mixture was stirred at 40 ° C. for 24 hours.
By this time, a total of 259 parts of methanol was added in addition to the methanol described above.
To the obtained mixture, 12.1 parts of acetic acid, 19.1 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.), 635 parts of water, 14.2 parts of methanol, and 20 parts of 50% aqueous methanol solution were added, and 40 ° C. The mixture was stirred for 21 hours at 63 ° C for 5 hours at 63 ° C.
To the obtained mixture, 23.4 parts of acetic acid was added and stirred at 63 ° C. for 18 hours.
To the obtained mixture, 24.9 parts of acetic acid, 19.4 parts of barbituric acid and 32.8 parts of methanol were added and stirred at 63 ° C. for 7 hours.
To the obtained mixture was added 259 parts of a 50% aqueous methanol solution, and the mixture was stirred at 63 ° C. for 7 days.
The resulting mixture was filtered.
To the obtained residue, 902 parts of tetrahydrofuran was added and stirred at room temperature.
The mixture was filtered, and the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ5-23).

<Identification of Compound Represented by Formula (IZ5-23)>
(Mass spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 383
Exact Mass: 382

Example 8Z5
10.0 parts of 4-nitrophthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 149 parts of methanol were mixed. While maintaining the temperature at 2 to 6 ° C., 5.86 parts of a 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) was dropped into the obtained mixture over 20 minutes. The resulting mixture was stirred for 5 hours while maintaining at 5 ° C. or lower.
While maintaining the resulting mixture at 5 ° C. or lower, 5.79 parts of acetic acid, 9.25 parts of 2-cyanoacetanilide (manufactured by Tokyo Chemical Industry Co., Ltd.) and 74 parts of methanol were added. The resulting mixture was stirred at 65 ° C. for 3 days.
To the obtained mixture, 2.88 parts of acetic acid and 4.63 parts of 2-cyanoacetanilide (manufactured by Tokyo Chemical Industry Co., Ltd.) were added.
The resulting mixture was stirred at 65 ° C. for 3 days.
By this time, in addition to the methanol described above, a total of 140 parts of methanol was added.
To the obtained mixture, 24.0 parts of acetic acid, 15.3 parts of barbituric acid (manufactured by Tokyo Chemical Industry Co., Ltd.) and 363 parts of water were added and stirred at 65 ° C. for 9 days.
After distilling off the solvent of the obtained mixture with a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ5-25).

<Identification of Compound Represented by Formula (IZ5-25)>
(Mass spectrometry) Ionization mode = ESI +: m / z = [M + H] ⁺ 445
Exact Mass: 444

Example 9Z5
5.0 parts of 4,5-dichlorophthalonitrile and 62 parts of methanol were mixed.
While maintaining this mixture at 5 ° C. or lower, a 25% sodium methoxide methanol solution containing sodium methoxide having a mole number 0.5 times that of 5.0 parts of 4,5-dichlorophthalonitrile was added.
The mixture was stirred at 5 ° C. or lower for 5 hours.
While maintaining the temperature at 5 ° C. or lower, to this mixture was added 1.5 parts of 2-cyano-N-methylacetamide and 6.1 parts of acetic acid, 1.5 times the number of moles of 5.0 parts of 4,5-dichlorophthalonitrile. It was.
The mixture was stirred at 65 ° C. for 3 days.
This mixture was mixed with 4.2 parts of acetic acid, 5.2 parts of barbituric acid, 500 parts of methanol and 562 parts of water, and stirred at 65 ° C. for 9 days.
After the solvent of this mixture was distilled off with a rotary evaporator, the obtained residue was purified by column chromatography to obtain a compound represented by the formula (IZ5-247).

<Identification of Compound Represented by Formula (IZ5-247)>
(Mass spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 406
Exact Mass: 405

Example 101Z5
Pigment: C.I. I. Pigment Green 58 60 parts,
8.1 parts of an acrylic pigment dispersant,
Resin (B): 73 parts of resin B5 solution and solvent (E): 290 parts of propylene glycol monomethyl ether acetate were mixed, and a pigment dispersion (colorant (A1Z5) -containing liquid) in which the pigment was dispersed using a bead mill was prepared. Prepared.
Separately
Colorant (AZ5): 50 parts of a compound represented by the formula (IZ5-1) obtained in Example 1Z5,
Dispersant (BYK-LPN6919; manufactured by Big Chemie Japan Co., Ltd.) 58 parts,
Compound represented by formula (IZ5-1) obtained in Example 1Z5 by mixing resin (B): 93 parts of resin B3 solution and solvent (E): 800 parts of propylene glycol monomethyl ether acetate and using a bead mill. Was dispersed to obtain a colored composition.
Then
Total amount of the obtained pigment dispersion (colorant (A1Z5) -containing liquid);
400 parts of the resulting colored composition;
Resin (B): Resin B1 solution 45 parts;
Polymerizable compound (C): 25 parts of dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kayaku Co., Ltd.);
Polymerization initiator (D): N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure (registered trademark) OXE-01; manufactured by BASF Corporation) 15 parts;
Solvent (E): 86 parts of propylene glycol monomethyl ether acetate; and leveling agent: polyether-modified silicone oil (Toray Silicone SH8400; manufactured by Toray Dow Corning Co., Ltd.) 0.12 parts;
Were mixed to obtain a colored curable composition 1Z5.

[Preparation of colored pattern]
The colored curable composition 1Z5 was applied by spin coating on a 2 inch square glass substrate (Eagle XG; manufactured by Corning), and then pre-baked at 100 ° C. for 3 minutes to form a colored curable composition layer. After cooling, the distance between the substrate on which the colored curable composition layer is formed and the quartz glass photomask is set to 200 μm, and an exposure machine (TME-150RSK; manufactured by Topcon Co., Ltd.) is used in an air atmosphere at 80 mJ / It exposed with an exposure amount of cm ² (365 nm reference). A photomask having a 100 μm line and space pattern was used. The colored curable composition layer after exposure was developed by being immersed in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ° C. for 70 seconds, and washed with water. The colored curable composition layer was post-baked at 230 ° C. for 30 minutes to obtain a colored pattern.

[Phase difference measurement]
The colored curable composition 1Z5 was applied by spin coating on a 2 inch square glass substrate (Eagle XG; manufactured by Corning), and then pre-baked at 100 ° C. for 3 minutes to form a colored curable composition layer. After cooling, the colored curable composition layer was exposed using an exposure machine (TME-150RSK; manufactured by Topcon Corporation) at an exposure amount of 80 mJ / cm ² (based on 365 nm) in an air atmosphere. The colored curable composition layer after exposure was developed by being immersed in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ° C. for 70 seconds, and washed with water. The colored curable composition layer was post-baked at 230 ° C. for 30 minutes to obtain a colored coating film.
The film thickness of the obtained colored coating film was measured using DEKTAK3 (manufactured by Nippon Vacuum Technology Co., Ltd.).
Using an ellipsometer (M-220 type spectroscopic ellipsometer; manufactured by JASCO Corporation), the retardation value of the colored coating film at an angle of 45 ° was measured. Light having a wavelength of 550 nm was used for measuring the phase difference value. The results are shown in Table 16Z5.

Example 102Z5
Coloring and curing in the same manner as in Example 101Z5, except that the compound represented by the formula (IZ5-1) obtained in Example 1Z5 is replaced with the compound represented by the formula (IZ5-3) obtained in Example 2Z5. Composition 2Z5 was obtained to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 16Z5.

Example 103Z5
Coloring and curing in the same manner as in Example 101Z5, except that the compound represented by the formula (IZ5-1) obtained in Example 1Z5 is replaced with the compound represented by the formula (IZ5-23) obtained in Example 3Z5. Property composition 3Z5 was obtained to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 16Z5.

Example 104Z5
Coloring and curing in the same manner as in Example 101Z5 except that the compound represented by the formula (IZ5-1) obtained in Example 1Z5 is replaced with the compound represented by the formula (IZ5-25) obtained in Example 4Z5. Composition 4Z5 was obtained to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 16Z5.

Example 105Z5
C. I. Pigment Green 58 is a C.I. I. A colored curable composition 5Z5 was obtained in the same manner as in Example 101Z5 except that the pigment green 7 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 16Z5.

Example 106Z5
C. I. Pigment Green 58 is a C.I. I. Example 101Z5 except that the compound represented by the formula (IZ5-1) obtained in Example 1Z5 is replaced with the compound represented by the formula (IZ5-3) obtained in Example 2Z5 in place of Pigment Green 7. Similarly, a colored curable composition 6Z5 was obtained to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 16Z5.

Example 107Z5
C. I. Pigment Green 58 is a C.I. I. Example 101Z5 except that the compound represented by the formula (IZ5-1) obtained in Example 1Z5 was replaced with the compound represented by the formula (IZ5-23) obtained in Example 3Z5 instead of Pigment Green 7. Similarly, a colored curable composition 7Z5 was obtained to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 16Z5.

Example 108Z5
C. I. Pigment Green 58 is a C.I. I. Example 101Z5 except that the compound represented by the formula (IZ5-1) obtained in Example 1Z5 is replaced with the compound represented by the formula (IZ5-25) obtained in Example 4Z5 in place of Pigment Green 7. Similarly, a colored curable composition 8Z5 was obtained to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 16Z5.

Example 109Z5
C. I. Pigment Green 58 is a C.I. I. A colored curable composition 9Z5 was obtained in the same manner as in Example 101Z5 except that the pigment green 59 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 16Z5.

Example 110Z5
C. I. Pigment Green 58 is a C.I. I. Example 101Z5 except that in place of Pigment Green 59, the compound represented by the formula (IZ5-1) obtained in Example 1Z5 was replaced with the compound represented by the formula (IZ5-3) obtained in Example 2Z5. Similarly, a colored curable composition 10Z5 was obtained to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 16Z5.

Example 111Z5
C. I. Pigment Green 58 is a C.I. I. Example 101Z5 except that the compound represented by the formula (IZ5-1) obtained in Example 1Z5 was replaced with the compound represented by the formula (IZ5-23) obtained in Example 3Z5 in place of Pigment Green 59. Similarly, a colored curable composition 11Z5 was obtained to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 16Z5.

Example 112Z5
C. I. Pigment Green 58 is a C.I. I. Example 101Z5 except that the compound represented by the formula (IZ5-1) obtained in Example 1Z5 was replaced with the compound represented by the formula (IZ5-25) obtained in Example 4Z5 in place of Pigment Green 59. Similarly, a colored curable composition 12Z5 was obtained to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 16Z5.

Comparative Example 1Z5
The compound represented by the formula (IZ5-1) obtained in Example 1Z5 was obtained as C.I. I. A colored curable composition C1Z5 was obtained in the same manner as in Example 101Z5 except that the pigment yellow 185 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 16Z5.

Comparative Example 2Z5
C. I. Pigment Green 58 is a C.I. I. Instead of CI Pigment Green 7, the compound represented by the formula (IZ5-1) obtained in Example 1Z5 was used as C.I. I. A colored curable composition C2Z5 was obtained in the same manner as in Example 101Z5 except that the pigment yellow 185 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 16Z5.

Comparative Example 3Z5
C. I. Pigment Green 58 is a C.I. I. Instead of CI Pigment Green 59, the compound represented by the formula (IZ5-1) obtained in Example 1Z5 was used as C.I. I. A colored curable composition C3Z5 was obtained in the same manner as in Example 101Z5 except that the pigment yellow 185 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 16Z5.

Example 113Z5
Pigment: C.I. I. Pigment Green 58 60 parts,
8.1 parts of an acrylic pigment dispersant,
Resin (B): 73 parts of resin B5 solution and solvent (E): 290 parts of propylene glycol monomethyl ether acetate were mixed, and a pigment dispersion (colorant (A1Z5) -containing liquid) in which the pigment was dispersed using a bead mill was prepared. Prepared.
Separately
Colorant (AZ5): 50 parts of a compound represented by formula (IZ5-1)
58 parts of a dispersant solution (solid content 60%),
Resin (B): 93 parts of resin B3 solution, and solvent (E): 800 parts of propylene glycol monomethyl ether acetate are mixed, and a compound represented by formula (IZ5-1) is dispersed using a bead mill to give a colored composition. I got a thing.
Then
Total amount of the obtained pigment dispersion (colorant (A1Z5) -containing liquid);
400 parts of the resulting colored composition;
Resin (B): Resin B1 solution 45 parts;
Polymerizable compound (C): 25 parts of dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kayaku Co., Ltd.);
Polymerization initiator (D): N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure (registered trademark) OXE-01; manufactured by BASF Corporation) 15 parts;
Solvent (E): 86 parts of propylene glycol monomethyl ether acetate;
And leveling agent: polyether-modified silicone oil (Toray Silicone SH8400; manufactured by Toray Dow Corning Co., Ltd.) 0.12 parts;
Were mixed to obtain a colored curable composition 13Z5.

  A colored pattern was produced in the same manner as in Example 101Z5 except that the colored curable composition 13Z5 was used instead of the colored curable composition 1Z5. Moreover, it replaced with colored curable composition 1Z5, and except using colored curable composition 13Z5, it carried out similarly to Example 101Z5, obtained the colored coating film, and performed the film thickness measurement and the phase difference value measurement. The results are shown in Table 17Z5.

Example 114Z5-Example 117Z5
A colored pattern was obtained in the same manner as in Example 113Z5 except that the compound represented by the formula (IZ5-1) was replaced with the colorant shown in the “Colorant” column of Table 17Z5. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 17Z5.

Example 118Z5-Example 122Z5
The compound represented by the formula (IZ5-1) was replaced with the compound shown in the “Colorant” column of Table 17Z5, and C.I. I. Pigment Green 58 is a C.I. I. A colored pattern was obtained in the same manner as in Example 113Z5 except that the pigment green 7 was used. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 17Z5.

Example 123Z5-Example 127Z5
The compound represented by the formula (IZ5-1) was replaced with the compound shown in the “Colorant” column of Table 17Z5, and C.I. I. Pigment Green 58 is a C.I. I. A colored pattern was obtained in the same manner as in Example 113Z5 except that the pigment green 59 was used. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 17Z5.

  In Example Z5, from the above results, in the colored coating film formed from the colored curable composition containing the compound of the present invention, C.I. I. It was found that the retardation value was smaller than that of a colored coating film formed from a colored curable composition containing Pigment Yellow 185.

[Example Z6]
Example 1Z6
7.02 parts of phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 61.6 parts of methanol were mixed. While maintaining the temperature of the obtained mixture at 2 ° C., a mixture of 8.20 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 74.6 parts of methanol was added for 1 hour 30 minutes. It was dripped over. The resulting mixture was stirred at 2 ° C. for 6 hours and 15 minutes. While maintaining the temperature of the resulting mixture at 4 ° C. or lower, 10.7 parts of acetic acid was added. 17.6 parts of benzoylacetonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) was added to the resulting mixture and stirred at room temperature for 44 hours. The resulting mixture was filtered and the residue was washed with 800 parts of methanol. The obtained residue was dried under reduced pressure at 60 ° C. to obtain 18.0 parts of a compound represented by the formula (IFFZ6-1).

<Identification of Compound Represented by Formula (IFFZ6-1)>
(Mass spectrometry) ionization mode = ESI +: m / z = [M + H] ⁺ 402
Exact Mass: 401

  While stirring 7.6 parts of fuming sulfuric acid (25%) (manufactured by Wako Pure Chemical Industries, Ltd.) at 3 ° C., the compound 0.513 represented by the formula (IFFZ6-1) obtained in Example 2Z6 Part was added. Fuming sulfuric acid (25%) (manufactured by Wako Pure Chemical Industries, Ltd.) 3.8 parts was added to the obtained mixture. The resulting mixture was raised to 15 ° C. over 3 hours 30 minutes with stirring. 139 parts of ice water was added to the resulting mixture, and 38.2 parts of sodium chloride was further added. The resulting mixture was filtered, and the resulting residue was washed with 64 parts of a 21.5% aqueous sodium chloride solution. The obtained residue was dried under reduced pressure at 60 ° C. to obtain 1.02 parts of a compound represented by the formula (IFFZ6-2).

<Identification of Compound Represented by Formula (IFFZ6-2)>
(Mass spectrometry) Ionization mode = ESI−: m / z = [M−H] ⁻ 560
Exact Mass: 561

  Under room temperature, 5.11 parts of the compound represented by the formula (IFFZ6-2) and 511 parts of water were mixed. To the resulting mixture, a mixture of 6.72 parts of barium chloride dihydrate (manufactured by Wako Pure Chemical Industries, Ltd.) and 60 parts of water was added. The resulting mixture was filtered and the resulting residue was washed with water. The obtained residue was dried under reduced pressure at 60 ° C. to obtain 2.98 parts of a compound represented by the formula (IFZ6-4).

<Identification of compound represented by formula (IFZ6-4)>
(Mass spectrometry) Ionization mode = ESI−: m / z = [M−Ba ²⁺ + H] ⁻ 560
Exact Mass: 697

Example 2Z6
Under room temperature, 10.0 parts of the compound represented by the formula (IFFZ6-2) and 1000 parts of water were mixed. A 5% aqueous sodium hydroxide solution was added dropwise to the resulting mixture to obtain a uniform solution. To this homogeneous solution, 87.0 parts of a 10% barium chloride dihydrate aqueous solution was added. The resulting mixture was filtered and the resulting residue was washed with water. The obtained residue was dried under reduced pressure at 60 ° C. to obtain 9.43 parts of a compound represented by the formula (IFZ6-4).

<Identification of compound represented by formula (IFZ6-4)>
(Mass Spectrometry) Ionization mode = ESI−: m / z = [M−Ba + H] ⁻ 560
Exact Mass: 697

Example 3Z6
Under room temperature, 5.02 parts of the compound represented by the formula (IFFZ6-2) and 500 parts of 50% aqueous methanol solution were mixed. A 5% aqueous sodium hydroxide solution was added dropwise to the resulting mixture to obtain a uniform solution. To this homogeneous solution was added 95.0 parts of a 10% strontium chloride hexahydrate aqueous solution. The resulting mixture was filtered, and the resulting residue was washed with 50% aqueous methanol. The obtained residue was dried under reduced pressure at 60 ° C. to obtain 4.00 parts of a compound represented by the formula (IFZ6-3).

<Identification of compound represented by formula (IFZ6-3)>
(Mass spectrometry) Ionization mode = ESI−: m / z = [M−Sr + H] ⁻ 560
Exact Mass: 647

Example 4Z6
Under room temperature, 0.501 part of a compound represented by the formula (IFFZ6-2) and 50.0 parts of water were mixed. A 5% aqueous sodium hydroxide solution was added dropwise to the resulting mixture to obtain a uniform solution. To this homogeneous solution was added 12.6 parts of a 10% aqueous calcium chloride solution. The resulting mixture was filtered and the resulting residue was washed with water. The obtained residue was dried under reduced pressure at 60 ° C. to obtain 0.024 part of a compound represented by the formula (IFZ6-2).

<Identification of Compound Represented by Formula (IFZ6-2)>
(Mass Spectrometry) Ionization Mode = ESI−: m / z = [M−Ca + H] ⁻ 560
Exact Mass: 599

Example 5Z6
Under room temperature, 0.500 parts of the compound represented by the formula (IFFZ6-2) and 50.0 parts of water were mixed. A 5% aqueous sodium hydroxide solution was added dropwise to the resulting mixture to obtain a uniform solution. To this homogeneous solution was added 3.52 parts of a 10% manganese chloride tetrahydrate aqueous solution. The resulting mixture was filtered and the resulting residue was washed with water. The obtained residue was dried under reduced pressure at 60 ° C. to obtain 0.015 part of a compound represented by the formula (IFZ6-10).

<Identification of compound represented by formula (IFZ6-10)>
(Mass spectrometry) ionization mode = ESI−: m / z = [M−Mn + H] ⁻ 560
Exact Mass: 614

Example 6Z6
A compound represented by the formula (IFZ6-6) was obtained in the same manner as in Example 2Z6 except that barium chloride dihydrate was replaced with zinc nitrate hexahydrate.

<Identification of Compound Represented by Formula (IFZ6-6)>
(Mass Spectrometry) Ionization Mode = ESI−: m / z = [M−Zn + H] ⁻ 560
Exact Mass: 623

Example 7Z6
Under room temperature, 5.00 parts of the compound represented by the formula (IFFZ6-2) and 500 parts of water were mixed. A 5% aqueous sodium hydroxide solution was added dropwise to the resulting mixture to obtain a uniform solution. To this homogeneous solution was added 23.7 parts of a 10% aqueous aluminum chloride solution. The resulting mixture was filtered and the resulting residue was washed with water. The obtained residue was dried under reduced pressure at 60 ° C. to obtain 0.474 parts of a compound represented by the formula (IFZ6-11).

<Identification of Compound Represented by Formula (IFZ6-11)>
(Mass spectrometry) Ionization mode = ESI−: m / z = [(M−2Al) / 3 + H] ⁻ 56
0
Exact Mass: 1731

Example 8Z6
Under room temperature, 5.01 parts of the compound represented by the formula (IFFZ6-2) and 500 parts of water were mixed. A 5% aqueous sodium hydroxide solution was added dropwise to the resulting mixture to obtain a uniform solution. To this homogeneous solution was added 36.0 parts of a 10% aqueous iron nitrate nonahydrate solution. The resulting mixture was filtered and the resulting residue was washed with water. The obtained residue was dried under reduced pressure at 60 ° C. to obtain 3.80 parts of a compound represented by the formula (IFZ6-12).

<Identification of Compound Represented by Formula (IFZ6-12)>
(Mass Spectrometry) Ionization mode = ESI−: m / z = [(M−2Fe) / 3 + H] ⁻ 56
0
Exact Mass: 1789

Example 9Z6
Under room temperature, 0.498 parts of the compound represented by the formula (IFFZ6-2) and 49.9 parts of water were mixed. A 5% aqueous sodium hydroxide solution was added dropwise to the resulting mixture to obtain a uniform solution. To this homogeneous solution was added 4.45 parts of a 10% copper sulfate pentahydrate aqueous solution. The resulting mixture was filtered and the resulting residue was washed with water. The obtained residue was dried under reduced pressure at 60 ° C. to obtain 0.018 part of a compound represented by the formula (IFZ6-31).

<Identification of compound represented by formula (IFZ6-31)>
(Mass spectrometry) ionization mode = ESI−: m / z = [M−Cu + H] ⁻ 560
Exact Mass: 622

Example 10Z6
Except for replacing benzoylacetonitrile with 4-cyanoacetylbenzoic acid, the same procedure as in Example 1Z6 for obtaining a compound represented by formula (IFFZ6-1) is carried out, and represented by formula (IJJZ6-1). A compound was obtained.

<Identification of Compound Represented by Formula (IJJZ6-1)>
(Mass Spectrometry) Ionization mode = ESI−: m / z = [M−H] ⁻ 488
Exact Mass: 489

  Under room temperature, 16.3 parts of a compound represented by the formula (IJJZ6-1) and 1630 parts of water were mixed. A 5% aqueous sodium hydroxide solution was added dropwise to the resulting mixture to obtain a uniform solution. To the obtained homogeneous solution, 163 parts of a 10% barium chloride dihydrate aqueous solution was added. The resulting mixture was filtered and the resulting residue was washed with water. The obtained residue was dried under reduced pressure at 60 ° C. to obtain 7.49 parts of a compound represented by the formula (IJZ6-4).

<Identification of Compound Represented by Formula (IJZ6-4)>
(Mass spectrometry) Ionization mode = ESI−: m / z = [M−Ba + H] ⁻ 488
Exact Mass: 625

Example 11Z6
A compound represented by the formula (IJZ6-3) was obtained in the same manner as in Example 10Z6 except that barium chloride dihydrate was replaced with strontium chloride hexahydrate.

<Identification of Compound Represented by Formula (IJZ6-3)>
(Mass Spectrometry) Ionization Mode = ESI−: m / z = [M−Sr + H] ⁻ 488
Exact Mass: 575

Example 12Z6
Except having replaced barium chloride dihydrate with calcium chloride, it implemented similarly to Example 10Z6 and obtained the compound represented by a formula (IJZ6-2).

<Identification of Compound Represented by Formula (IJZ6-2)>
(Mass Spectrometry) Ionization Mode = ESI−: m / z = [M−Ca + H] ⁻ 488
Exact Mass: 527

Example 13Z6
A compound represented by the formula (IJZ6-10) was obtained in the same manner as in Example 10Z6 except that barium chloride dihydrate was replaced with manganese chloride tetrahydrate.

<Identification of compound represented by formula (IJZ6-10)>
(Mass spectrometry) ionization mode = ESI−: m / z = [M−Mn + H] ⁻ 488
Exact Mass: 542

Example 14Z6
A compound represented by the formula (IJZ6-31) was obtained in the same manner as in Example 10Z6 except that barium chloride dihydrate was replaced with copper sulfate pentahydrate.

<Identification of compound represented by formula (IJZ6-31)>
(Mass spectrometry) Ionization mode = ESI−: m / z = [M−Cu + H] ⁻ 488
Exact Mass: 550

Example 15Z6
A compound represented by the formula (IJZ6-6) was obtained in the same manner as in Example 10Z6 except that barium chloride dihydrate was replaced with zinc nitrate hexahydrate.

<Identification of Compound Represented by Formula (IJZ6-6)>
(Mass Spectrometry) Ionization Mode = ESI−: m / z = [M−Zn + H] ⁻ 488
Exact Mass: 551

Example 16Z6
Except having replaced barium chloride dihydrate with aluminum chloride, it carried out like Example 10Z6 and obtained the compound represented by a formula (IJZ6-11).

<Identification of Compound Represented by Formula (IJZ6-11)>
(Mass spectrometry) ionization mode = ESI−: m / z = [(M−2Al) / 3 + H] ⁻ 488
Exact Mass: 1515

Example 17Z6
A compound represented by the formula (IJZ6-12) was obtained in the same manner as in Example 10Z6 except that barium chloride dihydrate was replaced with iron nitrate nonahydrate.

<Identification of Compound Represented by Formula (IJZ6-12)>
(Mass spectrometry) ionization mode = ESI−: m / z = [(M−2Fe) / 3 + H] ⁻ 488
Exact Mass: 1573

Example 18Z6
Except having replaced barium chloride dihydrate with magnesium chloride, it implemented like Example 10Z6 and obtained the compound represented by a formula (IJZ6-1).

<Identification of Compound Represented by Formula (IJZ6-1)>
(Mass spectrometry) ionization mode = ESI−: m / z = [M−Mg + H] ⁻ 488
Exact Mass: 511

Synthesis Example 19Z6
5.00 parts of phthalonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.) and 44 parts of methanol were mixed. While maintaining the temperature at 5 ° C. or less, a mixture of 5.84 parts of 28% sodium methoxide methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) and 54 parts of methanol was dropped into the obtained mixture over 1 hour and 30 minutes. . The resulting mixture was stirred at 5 ° C. or lower for 12 hours. While maintaining the temperature at 5 ° C. or lower, 11.5 parts of acetic acid was added to the obtained mixture, and 24.5 parts of 4-cyanoacetylbenzoic acid and 712 parts of methanol were further added. The resulting mixture was stirred at room temperature for 4 hours and then stirred at 40 ° C. for 96 hours. The solvent of the obtained mixture was distilled off using a rotary evaporator, and then the resulting residue was purified by column chromatography to obtain 0.471 part of a compound represented by the formula (IJJZ6-1).

<Identification of Compound Represented by Formula (IJJZ6-1)>
(Mass Spectrometry) Ionization mode = ESI−: m / z = [M−H] ⁻ 488
Exact Mass: 489

Example 101Z6
Pigment: C.I. I. Pigment Green 58 60 parts,
8.1 parts of an acrylic pigment dispersant,
Resin (B): 73 parts of resin B5 solution and solvent (E): 290 parts of propylene glycol monomethyl ether acetate were mixed, and a pigment dispersion (colorant (A1Z6) -containing liquid) in which the pigment was dispersed using a bead mill was prepared. Prepared.
Separately
Colorant (AZ6): 50 parts of a compound represented by the formula (IFZ6-4),
Dispersant (BYK-LPN6919; manufactured by Big Chemie Japan Co., Ltd.) 58 parts,
Resin (B): 93 parts of resin B3 solution and solvent (E): 800 parts of propylene glycol monomethyl ether acetate are mixed, and a compound represented by formula (IFZ6-4) is dispersed using a bead mill to give a colored composition I got a thing.
Then
Total amount of the obtained pigment dispersion (colorant (A1Z6) -containing liquid);
400 parts of the resulting colored composition;
Resin (B): Resin B1 solution 45 parts;
Polymerizable compound (C): 25 parts of dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kayaku Co., Ltd.);
Polymerization initiator (D): N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure (registered trademark) OXE-01; manufactured by BASF Corporation) 15 parts;
Solvent (E): 86 parts of propylene glycol monomethyl ether acetate; and leveling agent: polyether-modified silicone oil (Toray Silicone SH8400; manufactured by Toray Dow Corning Co., Ltd.) 0.12 parts;
Were mixed to obtain a colored curable composition 1Z6.

[Preparation of colored pattern]
The colored curable composition 1Z6 was applied by spin coating on a 2 inch square glass substrate (Eagle XG; manufactured by Corning), and then pre-baked at 100 ° C. for 3 minutes to form a colored curable composition layer. After cooling, the distance between the substrate on which the colored curable composition layer is formed and the quartz glass photomask is set to 200 μm, and an exposure machine (TME-150RSK; manufactured by Topcon Co., Ltd.) is used in an air atmosphere at 80 mJ / It exposed with an exposure amount of cm ² (365 nm reference). A photomask having a 100 μm line and space pattern was used. The colored curable composition layer after exposure was developed by being immersed in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ° C. for 70 seconds, and washed with water. The colored curable composition layer was post-baked at 230 ° C. for 30 minutes to obtain a colored pattern.

[Phase difference measurement]
The colored curable composition 1Z6 was applied by spin coating on a 2 inch square glass substrate (Eagle XG; manufactured by Corning), and then pre-baked at 100 ° C. for 3 minutes to form a colored curable composition layer. After cooling, the colored curable composition layer was exposed using an exposure machine (TME-150RSK; manufactured by Topcon Corporation) at an exposure amount of 80 mJ / cm ² (based on 365 nm) in an air atmosphere. The colored curable composition layer after exposure was developed by immersing it in an aqueous solution containing 0.12% of a nonionic surfactant and 0.04% of potassium hydroxide at 25 ° C. for 70 seconds, washed with water, and dried. . The colored curable composition layer after drying was post-baked at 230 ° C. for 30 minutes to obtain a colored coating film.
The film thickness of the obtained colored coating film was measured using DEKTAK3 (manufactured by Nippon Vacuum Technology Co., Ltd.).
Using an ellipsometer (M-220 type spectroscopic ellipsometer; manufactured by JASCO Corporation), the retardation value of the colored coating film at an angle of 45 ° was measured. Light having a wavelength of 550 nm was used for measuring the phase difference value. The results are shown in Table 5Z6.

Example 102Z6
A colored curable composition 2Z6 was obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-2) to obtain a colored pattern. It was. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 5Z6.

Example 103Z6
A colored curable composition 3Z6 was obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-3) to obtain a colored pattern. It was. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 5Z6.

Example 104Z6
A colored curable composition 4Z6 was obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-6) to obtain a colored pattern. It was. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 5Z6.

Example 105Z6
A colored curable composition 5Z6 was obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-10) to obtain a colored pattern. It was. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 5Z6.

Example 106Z6
A colored curable composition 6Z6 was obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-11) to obtain a colored pattern. It was. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 5Z6.

Example 107Z6
A colored curable composition 7Z6 was obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-12) to obtain a colored pattern. It was. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 5Z6.

Example 108Z6
A colored curable composition 8Z6 was obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IFZ6-31) to obtain a colored pattern. It was. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 5Z6.

Example 109Z6
A colored curable composition 9Z6 is obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) is replaced with the compound represented by the formula (IJZ6-1) to obtain a colored pattern. It was. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 5Z6.

Example 110Z6
A colored curable composition 10Z6 was obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-2) to obtain a colored pattern. It was. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 5Z6.

Example 111Z6
A colored curable composition 11Z6 was obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-3) to obtain a colored pattern. It was. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 5Z6.

Example 112Z6
A colored curable composition 12Z6 was obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-4) to obtain a colored pattern. It was. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 5Z6.

Example 113Z6
A colored curable composition 13Z6 was obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-6) to obtain a colored pattern. It was. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 5Z6.

Example 114Z6
A colored curable composition 14Z6 was obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-10) to obtain a colored pattern. It was. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 5Z6.

Example 115Z6
A colored curable composition 15Z6 was obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-11) to obtain a colored pattern. It was. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 5Z6.

Example 116Z6
A colored curable composition 16Z6 was obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-12) to obtain a colored pattern. It was. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 5Z6.

Example 117Z6
A colored curable composition 17Z6 was obtained in the same manner as in Example 101Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-31) to obtain a colored pattern. It was. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 5Z6.

Example 118Z6
Replacing the compound represented by the formula (IFZ6-4) with the compound represented by the formula (IFZ6-2), C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 18Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with CI Pigment Green 7, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 6Z6.

Example 119Z6
Replacing the compound represented by the formula (IFZ6-4) with the compound represented by the formula (IFZ6-3), C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 19Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with CI Pigment Green 7, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 6Z6.

Example 120Z6
C. I. Pigment Green 58 is a C.I. I. A colored curable composition 20Z6 was obtained in the same manner as in Example 101Z6 except that the pigment green 7 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 6Z6.

Example 121Z6
Replacing the compound represented by the formula (IFZ6-4) with the compound represented by the formula (IFZ6-6), C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 21Z6 was obtained in the same manner as in Example 101Z6 except that the pigment green 7 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 6Z6.

Example 122Z6
Replacing the compound represented by the formula (IFZ6-4) with the compound represented by the formula (IFZ6-10), C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 22Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with CI Pigment Green 7, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 6Z6.

Example 123Z6
Replacing the compound represented by the formula (IFZ6-4) with the compound represented by the formula (IFZ6-11), C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 23Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with CI Pigment Green 7, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 6Z6.

Example 124Z6
Replacing the compound represented by the formula (IFZ6-4) with the compound represented by the formula (IFZ6-12), C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 24Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with CI Pigment Green 7, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 6Z6.

Example 125Z6
Replacing the compound represented by the formula (IFZ6-4) with the compound represented by the formula (IFZ6-31), C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 25Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with CI Pigment Green 7, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 6Z6.

Example 126Z6
The compound represented by the formula (IFZ6-4) is replaced with the compound represented by the formula (IJZ6-1), and C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 26Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with CI Pigment Green 7, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 6Z6.

Example 127Z6
The compound represented by the formula (IFZ6-4) is replaced with the compound represented by the formula (IJZ6-2), and C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 27Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with CI Pigment Green 7, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 6Z6.

Example 128Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-3), and C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 28Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with CI Pigment Green 7, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 6Z6.

Example 129Z6
Replacing the compound represented by the formula (IFZ6-4) with the compound represented by the formula (IJZ6-4), C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 29Z6 was obtained and a colored pattern was obtained in the same manner as in Example 101Z6 except that the pigment green 7 was used. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 6Z6.

Example 130Z6
Replacing the compound represented by the formula (IFZ6-4) with the compound represented by the formula (IJZ6-6), C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 30Z6 was obtained in the same manner as in Example 101Z6 except that the pigment green 7 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 6Z6.

Example 131Z6
The compound represented by the formula (IFZ6-4) is replaced with the compound represented by the formula (IJZ6-10), and C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 31Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with CI Pigment Green 7, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 6Z6.

Example 132Z6
Replacing the compound represented by the formula (IFZ6-4) with the compound represented by the formula (IJZ6-11), C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 32Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with CI Pigment Green 7, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 6Z6.

Example 133Z6
Replacing the compound represented by the formula (IFZ6-4) with the compound represented by the formula (IJZ6-12), C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 33Z6 was obtained and a colored pattern was obtained in the same manner as in Example 101Z6 except that the pigment green 7 was used. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 6Z6.

Example 134Z6
Replacing the compound represented by the formula (IFZ6-4) with the compound represented by the formula (IJZ6-31), C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 34Z6 was obtained and a colored pattern was obtained in the same manner as in Example 101Z6, except that the pigment green 7 was used. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 6Z6.

Example 135Z6
Replacing the compound represented by the formula (IFZ6-4) with the compound represented by the formula (IFZ6-2), C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 35Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with CI Pigment Green 59 to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 7Z6.

Example 136Z6
Replacing the compound represented by the formula (IFZ6-4) with the compound represented by the formula (IFZ6-3), C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 36Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with CI Pigment Green 59 to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 7Z6.

Example 137Z6
C. I. Pigment Green 58 is a C.I. I. A colored curable composition 37Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with CI Pigment Green 59 to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 7Z6.

Example 138Z6
Replacing the compound represented by the formula (IFZ6-4) with the compound represented by the formula (IFZ6-6), C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 38Z6 was obtained in the same manner as in Example 101Z6 except that the pigment green 59 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 7Z6.

Example 139Z6
Replacing the compound represented by the formula (IFZ6-4) with the compound represented by the formula (IFZ6-10), C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 39Z6 was obtained in the same manner as in Example 101Z6 except that the pigment green 59 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 7Z6.

Example 140Z6
Replacing the compound represented by the formula (IFZ6-4) with the compound represented by the formula (IFZ6-11), C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 40Z6 was obtained in the same manner as in Example 101Z6 except that the pigment green 59 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 7Z6.

Example 141Z6
Replacing the compound represented by the formula (IFZ6-4) with the compound represented by the formula (IFZ6-12), C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 41Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with CI Pigment Green 59 to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 7Z6.

Example 142Z6
Replacing the compound represented by the formula (IFZ6-4) with the compound represented by the formula (IFZ6-31), C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 42Z6 was obtained in the same manner as in Example 101Z6 except that the pigment green 59 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 7Z6.

Example 143Z6
The compound represented by the formula (IFZ6-4) is replaced with the compound represented by the formula (IJZ6-1), and C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 43Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with CI Pigment Green 59 to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 7Z6.

Example 144Z6
The compound represented by the formula (IFZ6-4) is replaced with the compound represented by the formula (IJZ6-2), and C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 44Z6 was obtained in the same manner as in Example 101Z6 except that the pigment green 59 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 7Z6.

Example 145Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound represented by the formula (IJZ6-3), and C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 45Z6 was obtained in the same manner as in Example 101Z6 except that the pigment green 59 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 7Z6.

Example 146Z6
Replacing the compound represented by the formula (IFZ6-4) with the compound represented by the formula (IJZ6-4), C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 46Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with CI Pigment Green 59 to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 7Z6.

Example 147Z6
Replacing the compound represented by the formula (IFZ6-4) with the compound represented by the formula (IJZ6-6), C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 47Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with CI Pigment Green 59 to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 7Z6.

Example 148Z6
The compound represented by the formula (IFZ6-4) is replaced with the compound represented by the formula (IJZ6-10), and C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 48Z6 was obtained in the same manner as in Example 101Z6 except that the pigment green 59 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 7Z6.

Example 149Z6
Replacing the compound represented by the formula (IFZ6-4) with the compound represented by the formula (IJZ6-11), C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 49Z6 was obtained in the same manner as in Example 101Z6 except that the pigment green 59 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 7Z6.

Example 150Z6
Replacing the compound represented by the formula (IFZ6-4) with the compound represented by the formula (IJZ6-12), C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 50Z6 was obtained in the same manner as in Example 101Z6 except that the pigment green 59 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 7Z6.

Example 151Z6
Replacing the compound represented by the formula (IFZ6-4) with the compound represented by the formula (IJZ6-31), C.I. I. Pigment Green 58 is a C.I. I. A colored curable composition 51Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with CI Pigment Green 59 to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 7Z6.

Comparative Example 1Z6
The compound represented by the formula (IFZ6-4) is C.I. I. A colored curable composition C1Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with CI Pigment Yellow 185 to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 8Z6.

Comparative Example 2Z6
C. I. Pigment Green 58 is a C.I. I. Instead of CI Pigment Green 7, the compound represented by the formula (IFZ6-4) was converted to C.I. I. A colored curable composition C2Z6 was obtained in the same manner as in Example 101Z6 except that the pigment yellow 185 was used, and a colored pattern was obtained. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 8Z6.

Comparative Example 3Z6
C. I. Pigment Green 58 is a C.I. I. Instead of CI Pigment Green 59, a compound represented by the formula (IFZ6-4) was converted to C.I. I. A colored curable composition C3Z6 was obtained in the same manner as in Example 101Z6 except that it was replaced with CI Pigment Yellow 185 to obtain a colored pattern. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 8Z6.

Example 152Z6
Pigment: C.I. I. Pigment Green 58 60 parts,
8.1 parts of an acrylic pigment dispersant,
Resin (B): 73 parts of resin B5 solution and solvent (E): 290 parts of propylene glycol monomethyl ether acetate were mixed, and a pigment dispersion (colorant (A1Z6) -containing liquid) in which the pigment was dispersed using a bead mill was prepared. Prepared.
Separately
Colorant (AZ6): 50 parts of a compound represented by the formula (IFZ6-4),
58 parts of a dispersant solution (solid content 60%),
Resin (B): 93 parts of resin B3 solution and solvent (E): 800 parts of propylene glycol monomethyl ether acetate are mixed, and a compound represented by formula (IFZ6-4) is dispersed using a bead mill to give a colored composition I got a thing.
Then
Total amount of the obtained pigment dispersion (colorant (A1Z6) -containing liquid);
400 parts of the resulting colored composition;
Resin (B): Resin B1 solution 45 parts;
Polymerizable compound (C): 25 parts of dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA; manufactured by Nippon Kayaku Co., Ltd.);
Polymerization initiator (D): N-benzoyloxy-1- (4-phenylsulfanylphenyl) octane-1-one-2-imine (Irgacure (registered trademark) OXE-01; manufactured by BASF Corporation) 15 parts;
Solvent (E): 86 parts of propylene glycol monomethyl ether acetate; and leveling agent: polyether-modified silicone oil (Toray Silicone SH8400; manufactured by Toray Dow Corning Co., Ltd.) 0.12 parts;
Were mixed to obtain a colored curable composition 52Z6.

  A colored pattern was produced in the same manner as in Example 101Z6 except that the colored curable composition 52Z6 was used instead of the colored curable composition 1Z6. Moreover, it replaced with colored curable composition 1Z6, and except using colored curable composition 52Z6, it carried out similarly to Example 101Z6, and obtained the colored coating film, and performed the film thickness measurement and the phase difference value measurement. The results are shown in Table 9Z6.

Example 153Z6 to Example 168Z6
A colored pattern was obtained in the same manner as in Example 152Z6 except that the compound represented by the formula (IFZ6-4) was replaced with the colorant shown in the “Colorant” column of Table 9Z6. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 9Z6.

Example 169Z6 to Example 185Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound shown in the “Colorant” column of Table 10Z6, and C.I. I. Pigment Green 58 is a C.I. I. A colored pattern was obtained in the same manner as in Example 152Z6 except that the pigment green 7 was used instead. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 10Z6.

Example 186Z6 to Example 202Z6
The compound represented by the formula (IFZ6-4) was replaced with the compound shown in the “Colorant” column of Table 11Z6, and C.I. I. Pigment Green 58 is a C.I. I. A colored pattern was obtained in the same manner as in Example 152Z6 except that the pigment green 59 was used instead. Moreover, the colored coating film was obtained and the film thickness measurement and the phase difference value measurement were performed. The results are shown in Table 11Z6.

  In Example Z6, from the above results, in the colored coating film formed from the colored curable composition containing the compound of the present invention, C.I. I. It was found that the retardation value was smaller than that of a colored coating film formed from a colored curable composition containing Pigment Yellow 185.

  Since the coloring composition and the compound of the present invention can be used for forming a color filter having a small retardation value, they are suitably used for display devices such as a color filter and a liquid crystal display device.

Claims (55)

A compound represented by formula (IZ1), a compound represented by formula (IZ2), a compound represented by formula (IZ3), a compound represented by formula (IZ4), a compound represented by formula (IZ5), And at least one selected from compounds represented by formula (IZ6);
A coloring composition comprising at least one of a resin and a solvent.

[In the formula (IZ1),
R ^O1Z1 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
R ^1Z1 , R ^2Z1 , R ^3Z1 , R ^4Z1 , R ^5Z1 , R ^6Z1 and R ^7Z1 are each independently a hydrogen atom, —CO—R ^102Z1 , —COO—R ^101Z1 , —OCO—R ^102Z1 , —COCO ^{-R 102Z1, -O-R 102Z1,} -SO 2 -R 101Z1, -SO 2 N (R 102Z1) 2, -CON (R 102Z1) 2, -N (R 102Z1) 2, -NHCO-R 102Z1, - _{^{NHCO-N (R 102Z1) 2}} , -NHCOOR 102Z1, -OCON (R 102Z1) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , carbon atoms, which may have a substituent The heterocyclic group which may have a hydrocarbon group or a substituent of number 1-40 is represented.
R ^2Z1 and R ^3Z1 , R ^3Z1 and R ^4Z1 , and R ^4Z1 and R ^5Z1 may be bonded to each other to form a ring.
R ^101Z1 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102Z1 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
M represents a hydrogen atom or an alkali metal atom.
When a plurality of R ^101Z1 , R ^102Z1 and M are present, they may be the same or different.
A wavy line represents an E body or a Z body. ]

[In the formula (IZ2),
R ^CO1Z2 and R ^CO2Z2 each independently represent —O—R ^O1Z2 or —NR ^N1Z2 R ^N2Z2 .
^{R N1Z2, R N2Z2, R 1Z2} , R 2Z2, R 3Z2, R 4Z2, and R ^5Z2, independently of each other, hydrogen ^{atom, -CO-R 102Z2, -COO-} R 101Z2, -OCO-R 102Z2, -COCO ^{-R 102Z2, -O-R 102Z2,} -SO 2 -R 101Z2, -SO 2 N (R 102Z2) 2, -CON (R 102Z2) 2, -N (R 102Z2) 2, -NHCO-R 102Z2, - _{^{NHCO-N (R 102Z2) 2}} , -NHCOOR 102Z2, -OCON (R 102Z2) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , carbon atoms, which may have a substituent The heterocyclic group which may have a hydrocarbon group or a substituent of number 1-40 is represented.
R ^2Z2 and R ^3Z2, R ^3Z2 and R ^4Z2, and R ^4Z2 and R ^5Z2 may each be bonded to each other to form a ring.
R ^101Z2 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^O1Z2 and R ^102Z2 each independently represent a hydrogen atom, an ^optionally substituted hydrocarbon group having 1 to 40 carbon atoms, or an ^optionally substituted heterocyclic group.
M represents a hydrogen atom or an alkali metal atom.
When there are a plurality of R ^O1Z2 , R ^N1Z2 , R ^N2Z2 , R ^101Z2 , R ^102Z2 and M, they may be the same or different.
A wavy line represents an E body or a Z body. ]

[In the formula (IZ3),
R ^1Z3 , R ^2Z3 , R ^3Z3 , R ^4Z3 , R ^5Z3 , R ^6Z3 , and R ^7Z3 are each independently a hydrogen atom, —CO—R ^102Z3 , —COO—R ^101Z3 , —OCO—R ^102Z3 , —COCO ^{-R 102Z3, -O-R 102Z3,} -SO 2 -R 101Z3, -SO 2 N (R 102Z3) 2, -CON (R 102Z3) 2, -N (R 102Z3) 2, -NHCO-R 102Z3, - _{^{NHCO-N (R 102Z3) 2}} , -NHCOOR 102Z3, -OCON (R 102Z3) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , carbon atoms, which may have a substituent The heterocyclic group which may have a hydrocarbon group or a substituent of number 1-40 is represented.
R ^2Z3 and R ^3Z3 , R ^3Z3 and R ^4Z3 , and R ^4Z3 and R ^5Z3 may be bonded to each other to form a ring.
R ^101Z3 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102Z3 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
M represents a hydrogen atom or an alkali metal atom.
When a plurality of R ^101Z3 , R ^102Z3 and M are present, they may be the same or different.
A wavy line represents an E body or a Z body. ]

[In the formula (IZ4),
R ^N1Z4 and R ^N2Z4 are independently of each other —CO—R ^102Z4 , —COO—R ^101Z4 , —OCO—R ^102Z4 , —COCO—R ^102Z4 , —O—R ^102Z4 , —SO ₂ —R ^101Z4 , —SO _{^{2 N (R 102Z4) 2,}} -CON (R 102Z4) 2, -N (R 102Z4) 2, -NHCO-R 102Z4, -NHCO-N (R 102Z4) 2, -NHCOOR 102Z4, -OCON (R 102Z4) ₂ , a halogen atom, a cyano group, a nitro group, —SO ₃ M, —CO ₂ M, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms, or an optionally substituted complex. Represents a cyclic group.
R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , and R ^7Z4 are each independently a hydrogen atom, —CO—R ^102Z4 , —COO—R ^101Z4 , —OCO—R ^102Z4 , —COCO ^{-R 102Z4, -O-R 102Z4,} -SO 2 -R 101Z4, -SO 2 N (R 102Z4) 2, -CON (R 102Z4) 2, -N (R 102Z4) 2, -NHCO-R 102Z4, - _{^{NHCO-N (R 102Z4) 2}} , -NHCOOR 102Z4, -OCON (R 102Z4) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , carbon atoms, which may have a substituent The heterocyclic group which may have a hydrocarbon group or a substituent of number 1-40 is represented.
R ^2Z4 and R ^3Z4 , R ^3Z4 and R ^4Z4 , and R ^4Z4 and R ^5Z4 may be bonded to each other to form a ring.
R ^101Z4 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102Z4 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
M represents a hydrogen atom or an alkali metal atom.
When a plurality of R ^101Z4 , R ^102Z4 and M are present, they may be the same or different.
A wavy line represents an E body or a Z body. ]

[In the formula (IZ5)
R ^{N1Z5 is, -CO-R 102Z5, -COO-} R 101Z5, -OCO-R 102Z5, -COCO-R 102Z5, -O-R 102Z5, -SO 2 -R 101Z5, -SO 2 N (R 102Z5) 2 , ^-CON ( ^R102Z5 ) ₂ , -N ( ^R102Z5 ) ₂ , -NHCO- ^R102Z5 , -NHCO-N ( ^R102Z5 ) ₂ , ^-NHCOOR102Z5 , -OCON ( ^R102Z5 ) ₂ , halogen atom, cyano group , A nitro group, —SO ₃ M, —CO ₂ M, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group.
^{R 1Z5, R 2Z5, R 3Z5} , R 4Z5, R 5Z5, R 6Z5, and R ^7Z5, independently of each other, hydrogen ^{atom, -CO-R 102Z5, -COO-} R 101Z5, -OCO-R 102Z5, -COCO ^{-R 102Z5, -O-R 102Z5,} -SO 2 -R 101Z5, -SO 2 N (R 102Z5) 2, -CON (R 102Z5) 2, -N (R 102Z5) 2, -NHCO-R 102Z5, - _{^{NHCO-N (R 102Z5) 2}} , -NHCOOR 102Z5, -OCON (R 102Z5) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , carbon atoms, which may have a substituent ^{Represents a} heterocyclic group ^optionally having 1 to 40 hydrocarbon groups or a substituent, and R ^2Z5 and R ^3Z5 , R ^3Z5 and R ^4Z5 , and R ^4Z5 and R ^5Z5 are bonded to each other to form a ring It may form a, R ^2Z5, R ^3Z5, at least one of R ^4Z5 and R ^5Z5 is, -CO-R ^102Z5, -COO- ^{101Z5, -OCO-R 102Z5, -COCO} -R 102Z5, -O-R 102Z5, -SO 2 -R 101Z5, -SO 2 N (R 102Z5) 2, -CON (R 102Z5) 2, -N (R 102Z5 ) ₂ , -NHCO-R ^102Z5 , -NHCO-N (R ^102Z5 ) ₂ , -NHCOOR ^102Z5 , -OCON (R ^102Z5 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, A hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent, or R ^2Z5 and R ^3Z5 , R ^3Z5 and R ^4Z5 , and R ^At least one pair of ^4Z5 and R ^5Z5 is bonded to form a ring.
R ^101Z5 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102Z5 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
M represents a hydrogen atom or an alkali metal atom.
When a plurality of R ^101Z5 , R ^102Z5 and M are present, they may be the same or different.
A wavy line represents an E body or a Z body. ]

[In the formula (IZ6)
D represents a structure having an isoindoline skeleton.
Z represents —SO ₃ ^— or —CO ₂ ^— .
A ^{c +} represents a c-valent metal cation.
a represents an integer of 1 to 10.
b represents an integer of 1 or more.
c represents an integer of 2 to 10.
d represents an integer of 1 or more.
When there are a plurality of D, Z, a, or A ^{c +} , they may be the same or different.
Formula (I′Z6) and Formula (I ″ Z6) each represent a partial structure of Formula (IZ6), and D, Z, A ^{c +} , a, b, c, and d are those in Formula (IZ6) Represents the same thing.
However, the absolute value of the negative valence of the partial structure represented by the formula (I′Z6) and the positive valence of the partial structure represented by the formula (I ″ Z6) are the same. ]   The coloring composition according to claim 1, comprising a compound represented by the formula (IZ1), a compound represented by the formula (IZ2), or a compound represented by the formula (IZ3), and a resin. The coloring composition according to claim 1, comprising a compound represented by the formula (IZ4), a compound represented by the formula (IZ5), or a compound represented by the formula (IZ6), and a solvent.
The coloring composition according to claim 1 or 2, comprising a compound represented by the formula (IZ1), wherein R ^1Z1 , R ^6Z1 and R ^7Z1 are hydrogen atoms. The compound represented by the formula (IZ1), wherein R ^O1Z1 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent. The coloring composition as described. Including a compound represented by the formula (IZ1), ^wherein at least one of R ^2Z1 , R ^3Z1 , R ^4Z1 , and R ^5Z1 is
^{-CO-R 102Z1, -COO-R} 101Z1, -OCO-R 102Z1, -COCO-R 102Z1, -O-R 102Z1, -SO 2 -R 101Z1, -SO 2 N (R 102Z1) 2, -CON ( ^R102Z1 ) ₂ , -N ( ^R102Z1 ) ₂ , -NHCO- ^R102Z1 , -NHCO-N ( ^R102Z1 ) ₂ , ^-NHCOOR102Z1 , -OCON ( ^R102Z1 ) ₂ , halogen atom, cyano group, nitro group, —SO ₃ M, —CO ₂ M, an ^optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an ^optionally substituted heterocyclic group, or R ^2Z1 and R The colored composition according to claim 1, wherein at least one pair of ^3Z1 , R ^3Z1 and R ^4Z1 , and R ^4Z1 and R ^5Z1 is bonded to form a ring. A compound represented by the formula (IZ1), ^wherein at least one of R ^2Z1 , R ^3Z1 , R ^4Z1 and R ^5Z1 is a nitro group or a tert-butyl group. The coloring composition as described in. Including the compound represented by the formula (IZ2), R ^O1Z2 , R ^N1Z2 and R ^N2Z2 are each independently a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent. Item 3. The colored composition according to Item 1 or 2. The colored composition according to claim 1, ^comprising a compound represented by formula (IZ2), wherein R ^1Z2 is a hydrogen atom. Comprise a compound represented by formula ^{(IZ2), R 2Z2, R} 3Z2, R 4Z2, and at least one of R ^{5Z2 is, -CO-R 102Z2, -COO-} R 101Z2, -OCO-R 102Z2, -COCO- ^{R 102Z2, -O-R 102Z2,} -SO 2 -R 101Z2, -SO 2 N (R 102Z2) 2, -CON (R 102Z2) 2, -N (R 102Z2) 2, -NHCO-R 102Z2, -NHCO _{^{-N (R 102Z2) 2, -NHCOOR}} 102Z2, -OCON (R 102Z2) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , the number of carbon atoms which may have a substituent 1-40 hydrocarbon group or have a substituent is also heterocyclic group, or R ^2Z2 and R ^3Z2, R ^3Z2 and R ^4Z2, and at least one pair binding of R ^4Z2 and R ^5Z2 The colored composition according to claim 1, 2, 8, or 9 forming a ring. Includes a compound represented by a formula ^{(IZ2), R 2Z2, R} 3Z2, R 4Z2, and at least one of R ^5Z2 is, any one of claims 1-2 also 8-10 a nitro group or a tert- butyl group The coloring composition as described in. The coloring composition according to claim 1 or 2, comprising a compound represented by the formula (IZ3), wherein R ^1Z3 , R ^6Z3 and R ^7Z3 are hydrogen atoms. A compound represented by the formula (IZ3), ^wherein at least one of R ^2Z3 , R ^3Z3 , R ^4Z3 , and R ^5Z3 is —CO—R ^102Z3 , —COO—R ^101Z3 , —OCO—R ^102Z3 , —COCO— ^{R 102Z3, -O-R 102Z3,} -SO 2 -R 101Z3, -SO 2 N (R 102Z3) 2, -CON (R 102Z3) 2, -N (R 102Z3) 2, -NHCO-R 102Z3, -NHCO _{^{-N (R 102Z3) 2, -NHCOOR}} 102Z3, -OCON (R 102Z3) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , the number of carbon atoms which may have a substituent 1 to 40 hydrocarbon groups or heterocyclic groups which may have a substituent, or at least one pair of R ^2Z3 and R ^3Z3 , R ^3Z3 and R ^4Z3 , and R ^4Z3 and R ^5Z3 is bonded. The coloring composition in any one of Claims 1-2 or 12 which has formed the ring. The compound represented by formula (IZ3), ^wherein at least one of R ^2Z3 , R ^3Z3 , R ^4Z3 and R ^5Z3 is a nitro group or a tert-butyl group. The coloring composition as described in.   The coloring composition in any one of Claims 1-14 containing both resin and a solvent.   Furthermore, the coloring composition in any one of Claims 1-15 containing a yellow coloring agent or a green coloring agent.   A colored curable composition comprising the colored composition according to claim 1 and a polymerizable compound.   Furthermore, the colored curable composition of Claim 17 containing a polymerization initiator.   A color filter formed from the colored composition according to claim 1 or the colored curable composition according to claim 17 or 18.   A liquid crystal display device comprising the color filter according to claim 19. A compound represented by the formula (IZ1-B).

[In the formula (IZ1-B),
R ^O11Z1 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
R ^1Z1 , R ^21Z1 , R ^31Z1 , R ^41Z1 , R ^51Z1 , R ^61Z1 , and R ^71Z1 are each independently a hydrogen atom, —CO—R ^102Z1 , —COO—R ^101Z1 , —OCO—R ^102Z1 , —COCO ^{-R 102Z1, -O-R 102Z1,} -SO 2 -R 101Z1, -SO 2 N (R 102Z1) 2, -CON (R 102Z1) 2, -N (R 102Z1) 2, -NHCO-R 102Z1, - _{^{NHCO-N (R 102Z1) 2}} , -NHCOOR 102Z1, -OCON (R 102Z1) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , carbon atoms, which may have a substituent The heterocyclic group which may have a hydrocarbon group or a substituent of number 1-40 is represented.
R ^21Z1 and R ^31Z1 , R ^31Z1 and R ^41Z1 , and R ^41Z1 and R ^51Z1 may be bonded to each other to form a ring.
^{However, R 21Z1, R 31Z1, R} 41Z1, and at least one of R ^{51Z1 is, -CO-R 102Z1, -COO-} R 101Z1, -OCO-R 102Z1, -COCO-R 102Z1, -O-R 102Z1, _{^{-SO 2 -R 101Z1, -SO 2 N}} (R 102Z1) 2, -CON (R 102Z1) 2, -N (R 102Z1) 2, -NHCO-R 102Z1, -NHCO-N (R 102Z1) 2, - ^{NHCOOR 102Z1, -OCON (R 102Z1)} 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , hydrocarbon group or a substituted carbon atoms 1 to 40 which may have a substituent A heterocyclic group which may have a group, or at least one pair of R ^21Z1 and R ^31Z1 , R ^31Z1 and R ^41Z1 , and R ^41Z1 and R ^51Z1 is bonded to form a ring.
R ^101Z1 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102Z1 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
M represents a hydrogen atom or an alkali metal atom.
When a plurality of R ^101Z1 , R ^102Z1 and M are present, they may be the same or different.
A wavy line represents an E body or a Z body. ] The compound according to claim 21, wherein R ^1Z1 , R ^61Z1 and R ^71Z1 are hydrogen atoms. ^23. The compound according to claim 21 or 22, wherein R ^O11Z1 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent. ^24. The compound according to any one of claims 21 to 23, wherein at least one of ^R21Z1 , ^R31Z1 , ^R41Z1 and ^R51Z1 is a nitro group or a tert-butyl group. A compound represented by the formula (IZ2-B).

[In the formula (IZ2-B),
R ^CO11Z2 and R ^CO21Z2 each independently represent —O—R ^O1Z2 or —NR ^N1Z2 R ^N2Z2 , and at least one of R ^CO11Z2 and R ^CO21Z2 is —NR ^N1Z2 R ^N2Z2 .
R ^N1Z2 , R ^N2Z2 , R ^1Z2 , R ^21Z2 , R ^31Z2 , R ^41Z2 and R ^51Z2 are each independently a hydrogen atom, —CO—R ^102Z2 , —COO—R ^101Z2 , —OCO—R ^102Z2 , —COCO— ^{R 102Z2, -O-R 102Z2,} -SO 2 -R 101Z2, -SO 2 N (R 102Z2) 2, -CON (R 102Z2) 2, -N (R 102Z2) 2, -NHCO-R 102Z2, -NHCO _{^{-N (R 102Z2) 2, -NHCOOR}} 102Z2, -OCON (R 102Z2) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , the number of carbon atoms which may have a substituent 1 to 40 hydrocarbon groups or heterocyclic groups which may have a substituent, R ^21Z2 and R ^31Z2 , R ^31Z2 and R ^41Z2 , and R ^41Z2 and R ^51Z2 are bonded to each other to form a ring. May form,
R ^21Z2, R ^31Z2, at least one of R ^41Z2 and R ^{51Z2 is, -CO-R 102Z2, -COO-} R 101Z2, -OCO-R 102Z2, -COCO-R 102Z2, -O-R 102Z2, -SO 2 _{^{-R 101Z2, -SO 2 N (R}} 102Z2) 2, -CON (R 102Z2) 2, -N (R 102Z2) 2, -NHCO-R 102Z2, -NHCO-N (R 102Z2) 2, -NHCOOR 102Z2, —OCON (R ^102Z2 ) ₂ , halogen atom, cyano group, nitro group, —SO ₃ M, —CO ₂ M, ^optionally having a hydrocarbon group having 1 to 40 carbon atoms or a substituent. ^Or at least one pair of R ^21Z2 and R ^31Z2 , R ^31Z2 and R ^41Z2 , and R ^41Z2 and R ^51Z2 is bonded to form a ring.
R ^101Z2 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^O1Z2 and R ^102Z2 each independently represent a hydrogen atom, an ^optionally substituted hydrocarbon group having 1 to 40 carbon atoms, or an ^optionally substituted heterocyclic group.
M represents a hydrogen atom or an alkali metal atom.
When there are a plurality of R ^O1Z2 , R ^N1Z2 , R ^N2Z2 , R ^101Z2 , R ^102Z2 and M, they may be the same or different.
A wavy line represents an E body or a Z body. ] ^26. The compound according to claim 25, wherein R ^O1Z2 , R ^N1Z2 and R ^N2Z2 are a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent. ^27. The compound according to claim 25 or 26, wherein R ^1Z2 is a hydrogen atom. 28. The compound according to any one of claims 25 to 27, wherein at least one of ^R21Z2 , ^R31Z2 , ^R41Z2 and ^R51Z2 is a nitro group or a tert-butyl group. A compound represented by the formula (IZ3-B).

[In the formula (IZ3-B),
R ^1Z3 , R ^21Z3 , R ^31Z3 , R ^41Z3 , R ^51Z3 , R ^61Z3 , and R ^71Z3 are each independently a hydrogen atom, —CO—R ^102Z3 , —COO—R ^101Z3 , —OCO—R ^102Z3 , —COCO ^{-R 102Z3, -O-R 102Z3,} -SO 2 -R 101Z3, -SO 2 N (R 102Z3) 2, -CON (R 102Z3) 2, -N (R 102Z3) 2, -NHCO-R 102Z3, - _{^{NHCO-N (R 102Z3) 2}} , -NHCOOR 102Z3, -OCON (R 102Z3) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , carbon atoms, which may have a substituent The heterocyclic group which may have a hydrocarbon group or a substituent of number 1-40 is represented.
R ^21Z3 and R ^31Z3 , R ^31Z3 and R ^41Z3 , and R ^41Z3 and R ^51Z3 may be bonded to each other to form a ring.
However, at least one of R ^21Z3 , R ^31Z3 , R ^41Z3 , and R ^51Z3 is —CO—R ^102Z3 , —COO—R ^101Z3 , —OCO—R ^102Z3 , —COCO—R ^102Z3 , —O—R ^102Z3 , _{^{-SO 2 -R 101Z3, -SO 2 N}} (R 102Z3) 2, -CON (R 102Z3) 2, -N (R 102Z3) 2, -NHCO-R 102Z3, -NHCO-N (R 102Z3) 2, - ^{NHCOOR 102Z3, -OCON (R 102Z3)} 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , hydrocarbon group or substituted carbon atoms 1 to 40 which may have a substituent A heterocyclic group which may have a group, or at least one pair of R ^21Z3 and R ^31Z3 , R ^31Z3 and R ^41Z3 , and R ^41Z3 and R ^51Z3 is bonded to form a ring.
R ^101Z3 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102Z3 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
M represents a hydrogen atom or an alkali metal atom.
When a plurality of R ^101Z3 , R ^102Z3 and M are present, they may be the same or different.
A wavy line represents an E body or a Z body. ] ^30. The compound according to claim 29, wherein ^R1Z3 , ^R61Z3 and ^R71Z3 are hydrogen atoms. The compound according to claim 29 or 30, wherein at least one of R ^21Z3 , R ^31Z3 , R ^41Z3 , and R ^51Z3 is a nitro group or a tert-butyl group. A compound represented by formula (IZ4).

[In the formula (IZ4),
R ^N1Z4 and R ^N2Z4 are independently of each other —CO—R ^102Z4 , —COO—R ^101Z4 , —OCO—R ^102Z4 , —COCO—R ^102Z4 , —O—R ^102Z4 , —SO ₂ —R ^101Z4 , —SO _{^{2 N (R 102Z4) 2,}} -CON (R 102Z4) 2, -N (R 102Z4) 2, -NHCO-R 102Z4, -NHCO-N (R 102Z4) 2, -NHCOOR 102Z4, -OCON (R 102Z4) ₂ , a halogen atom, a cyano group, a nitro group, —SO ₃ M, —CO ₂ M, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms, or an optionally substituted complex. Represents a cyclic group.
R ^1Z4 , R ^2Z4 , R ^3Z4 , R ^4Z4 , R ^5Z4 , R ^6Z4 , and R ^7Z4 are each independently a hydrogen atom, —CO—R ^102Z4 , —COO—R ^101Z4 , —OCO—R ^102Z4 , —COCO ^{-R 102Z4, -O-R 102Z4,} -SO 2 -R 101Z4, -SO 2 N (R 102Z4) 2, -CON (R 102Z4) 2, -N (R 102Z4) 2, -NHCO-R 102Z4, - _{^{NHCO-N (R 102Z4) 2}} , -NHCOOR 102Z4, -OCON (R 102Z4) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , carbon atoms, which may have a substituent The heterocyclic group which may have a hydrocarbon group or a substituent of number 1-40 is represented.
R ^2Z4 and R ^3Z4 , R ^3Z4 and R ^4Z4 , and R ^4Z4 and R ^5Z4 may be bonded to each other to form a ring.
R ^101Z4 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102Z4 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
M represents a hydrogen atom or an alkali metal atom.
When a plurality of R ^101Z4 , R ^102Z4 and M are present, they may be the same or different.
A wavy line represents an E body or a Z body. ] The compound according to claim 32, wherein R ^1Z4 , R ^6Z4 and R ^7Z4 are hydrogen atoms. The compound according to claim 32 or 33, wherein R ^N1Z4 and R ^N2Z4 are each independently a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent. At least one of R ^2Z4 , R ^3Z4 , R ^4Z4 , and R ^5Z4 is —CO—R ^102Z4 , —COO—R ^101Z4 , —OCO—R ^102Z4 , COCO—R ^102Z4 , —O—R ^102Z4 , —SO ₂ —. _{^{R 101Z4, -SO 2 N (R}} 102Z4) 2, -CON (R 102Z4) 2, -N (R 102Z4) 2, -NHCO-R 102Z4, -NHCO-N (R 102Z4) 2, -NHCOOR 102Z4, - OCON (R ^102Z4 ) ₂ , halogen atom, cyano group, nitro group, —SO ₃ M, —CO ₂ M, ^optionally having a hydrocarbon group having 1 to 40 carbon atoms or a substituent ^{35. The} heterocyclic group as ^{described above} , wherein at least one pair of R ^2Z4 and R ^3Z4 , R ^3Z4 and R ^4Z4 , and R ^4Z4 and R ^5Z4 is bonded to form a ring. A compound according to any one. ^{R 2Z4, R 3Z4, R 4Z4} , and at least one of R ^5Z4 A compound according to any one of claims 32 to 35 is a nitro group or a tert- butyl group. A compound represented by formula (IZ5).

[In the formula (IZ5)
R ^{N1Z5 is, -CO-R 102Z5, -COO-} R 101Z5, -OCO-R 102Z5, -COCO-R 102Z5, -O-R 102Z5, -SO 2 -R 101Z5, -SO 2 N (R 102Z5) 2 , ^-CON ( ^R102Z5 ) ₂ , -N ( ^R102Z5 ) ₂ , -NHCO- ^R102Z5 , -NHCO-N ( ^R102Z5 ) ₂ , ^-NHCOOR102Z5 , -OCON ( ^R102Z5 ) ₂ , halogen atom, cyano group , A nitro group, —SO ₃ M, —CO ₂ M, an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group.
^{R 1Z5, R 2Z5, R 3Z5} , R 4Z5, R 5Z5, R 6Z5, and R ^7Z5, independently of each other, hydrogen ^{atom, -CO-R 102Z5, -COO-} R 101Z5, -OCO-R 102Z5, -COCO ^{-R 102Z5, -O-R 102Z5,} -SO 2 -R 101Z5, -SO 2 N (R 102Z5) 2, -CON (R 102Z5) 2, -N (R 102Z5) 2, -NHCO-R 102Z5, - _{^{NHCO-N (R 102Z5) 2}} , -NHCOOR 102Z5, -OCON (R 102Z5) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , carbon atoms, which may have a substituent ^{Represents a} heterocyclic group ^optionally having 1 to 40 hydrocarbon groups or a substituent, and R ^2Z5 and R ^3Z5 , R ^3Z5 and R ^4Z5 , and R ^4Z5 and R ^5Z5 are bonded to each other to form a ring It may form a, R ^2Z5, R ^3Z5, at least one of R ^4Z5 and R ^5Z5 is, -CO-R ^102Z5, -COO- ^{101Z5, -OCO-R 102Z5, -COCO} -R 102Z5, -O-R 102Z5, -SO 2 -R 101Z5, -SO 2 N (R 102Z5) 2, -CON (R 102Z5) 2, -N (R 102Z5 ) ₂ , -NHCO-R ^102Z5 , -NHCO-N (R ^102Z5 ) ₂ , -NHCOOR ^102Z5 , -OCON (R ^102Z5 ) ₂ , halogen atom, cyano group, nitro group, -SO ₃ M, -CO ₂ M, A hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent, or R ^2Z5 and R ^3Z5 , R ^3Z5 and R ^4Z5 , and R ^At least one pair of ^4Z5 and R ^5Z5 is bonded to form a ring.
R ^101Z5 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102Z5 represents a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
M represents a hydrogen atom or an alkali metal atom.
When a plurality of R ^101Z5 , R ^102Z5 and M are present, they may be the same or different.
A wavy line represents an E body or a Z body. ] The compound according to claim 37, wherein R ^N1Z5 is an ^optionally substituted hydrocarbon group having 1 to 10 carbon atoms. R ^1Z5, R ^6Z5 and R ^7Z5 A compound according to claim 37 or 38 is a hydrogen atom. ^40. The compound according to any one of claims 37 to 39, wherein at least one of ^R2Z5 , ^R3Z5 , ^R4Z5 and ^R5Z5 is a nitro group or a tert-butyl group. A compound represented by formula (IZ6).

[In the formula (IZ6)
D represents a structure having an isoindoline skeleton.
Z represents —SO ₃ ^— or —CO ₂ ^— .
A ^{c +} represents a c-valent metal cation.
a represents an integer of 1 to 10.
b represents an integer of 1 or more.
c represents an integer of 2 to 10.
d represents an integer of 1 or more.
When there are a plurality of D, Z, a, or A ^{c +} , they may be the same or different.
Formula (I′Z6) and Formula (I ″ Z6) each represent a partial structure of Formula (IZ6), and D, Z, A ^{c +} , a, b, c, and d are those in Formula (IZ6) Represents the same thing.
However, the absolute value of the negative valence of the partial structure represented by the formula (I′Z6) and the positive valence of the partial structure represented by the formula (I ″ Z6) are the same. ] 42. The compound according to claim 41, wherein the compound represented by the formula (IZ6) is a compound represented by the formula (IZ6-A).

[In the formula (IZ6-A)
A ^{c +} , b, c and d represent the same meaning as described above.
R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 and R ^13AZ6 are independently of each other a hydrogen atom, —CO—R ^102AZ6 , —COO—R ^101AZ6 , —OCO— ^{R 102AZ6, -COCO-R 102AZ6,} -O-R 102AZ6, -SO 2 -R 101AZ6, -SO 2 N (R 102AZ6) 2, -CON (R 102AZ6) 2, -N (R 102AZ6) 2, -NHCO ^{-R 102AZ6, -NHCO-N (R} 102AZ6) 2, -NHCOOR 102AZ6, -OCON (R 102AZ6) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , -SO 3 -, —CO ₂ ⁻ represents an optionally substituted hydrocarbon group having 1 to 40 carbon atoms or an optionally substituted heterocyclic group.
R ^2AZ6 and R ^3AZ6 , R ^3AZ6 and R ^4AZ6 , R ^4AZ6 and R ^5AZ6 , R ^AA1Z6 and R ^AA2Z6, and R ^12AZ6 and R ^13AZ6 may be bonded to each other to form a ring.
R ^101AZ6 represents, independently of each other, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102AZ6 represents, independently of each other, a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent, or a heterocyclic group which may have a substituent.
M represents a hydrogen atom or an alkali metal atom.
Formula (IZ6-A ′) and Formula (IZ6-A ″) each represent a partial structure of Formula (IZ6-A), and A ^{c +} , b, c, d, R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 and R ^13AZ6 represent the same as those in formula (IZ6-A).
R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 , R ^102AZ6 , M, c or A ^{c +} May be different or different.
R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6 are at least one of (ra-i) to (ra-iii) R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 , R ^13AZ6 , R ^101AZ6 and R ^102AZ6 have —SO ₃ ^— or —CO ₂ ^— The total number is a.
( ^Ra -i) At least one of R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 and R ^13AZ6 is —SO ₃ ^— or —CO ₂ ^— .
( ^Ra -ii) At least one of R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 and R ^13AZ6 is -CO-R ^102AZ6 , -COO-R ^101AZ6 , -OCO ^{-R 102AZ6, -COCO-R 102AZ6,} -O-R 102AZ6, -SO 2 -R 101AZ6, -SO 2 N (R 102AZ6) 2, -CON (R 102AZ6) 2, -N (R 102AZ6) 2, - ^{NHCO-R 102AZ6, -NHCO-N} (R 102AZ6) 2, -NHCOOR 102AZ6, or -OCON (R ^102AZ6) a _2, wherein R ^101AZ6 and R ^102AZ6 is, -SO ₃ ^- having ^- or -CO ₂ A hydrocarbon group having 1 to 40 carbon atoms or a heterocyclic group having —SO ₃ ^— or —CO ₂ ^— . However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .
( ^Ra -iii) Carbon number 1 in which at least one of R ^1AZ6 , R ^2AZ6 , R ^3AZ6 , R ^4AZ6 , R ^5AZ6 , R ^AA1Z6 , R ^AA2Z6 , R ^12AZ6 and R ^13AZ6 has —SO ₃ ^— or —CO ₂ ^—. It is a heterocyclic group having ˜40 hydrocarbon groups or —SO ₃ ^— or —CO ₂ ^— . However, the hydrocarbon group and the heterocyclic group may have a substituent other than —SO ₃ ^— or —CO ₂ ^— .
a represents the same meaning as in formula (IZ6). When a plurality of a are present, they may be the same or different.
The absolute value of the negative valence of the partial structure represented by the formula (IZ6-A ′) and the positive valence of the partial structure represented by the formula (IZ6-A ″) are the same.
A wavy line represents an E body or a Z body. ] 43. The compound according to claim 42, wherein the compound represented by the formula (IZ6-A) is a compound represented by the formula (IZ6-B).

[In the formula (IZ6-B)
A ^{c +} , b, c, d and wavy line have the same meaning as described above.
L ¹ represents —CO— or —SO ₂ —.
R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 and R ^13BZ6 are each independently a hydrogen atom, —CO—R ^102BZ6 , —COO—R ^101BZ6 , —OCO—R ^102BZ6 , ^{-COCO-R 102BZ6, -O-R} 102BZ6, -SO 2 -R 101BZ6, -SO 2 N (R 102BZ6) 2, -CON (R 102BZ6) 2, -N (R 102BZ6) 2, -NHCO-R 102BZ6 , —NHCO—N (R ^102BZ6 ) ₂ , —NHCOOR ^102BZ6 , —OCON (R ^102BZ6 ) ₂ , halogen atom, cyano group, nitro group, —SO ₃ M, —CO ₂ M, —SO ₃ ⁻ , —CO ₂ ^- represents a hydrocarbon group or optionally substituted heterocyclic group having carbon atoms of 1 to 40 which may have a substituent.
R ^2BZ6 and R ^3BZ6 , R ^3BZ6 and R ^4BZ6 , R ^4BZ6 and R ^5BZ6 , and R ^12BZ6 and R ^13BZ6 may be bonded to each other to form a ring.
R ^101BZ6 represents, independently of each other, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102BZ6 represents, independently of each other, a hydrogen atom, an ^optionally substituted hydrocarbon group having 1 to 40 carbon atoms, or an ^optionally substituted heterocyclic group.
Formula (IZ6-B ′) and Formula (IZ6-B ″) each represent a partial structure of Formula (IZ6-B), and A ^{c +} , b, c, d, R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 , R ^13BZ6 and L ¹ represent the same as those in formula (IZ6-B).
M represents the same meaning as described above.
When there are a ^{plurality of} R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 , R ^13BZ6 , R ^101BZ6 , R ^102BZ6 , L ¹ , M, c or A ^{c +} , they are the same May be different or different.
R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 , R ^13BZ6 , R ^101BZ6 and R ^102BZ6 satisfy at least one of (rb-i) to (rb-iii). The total number of —SO ₃ ^— or —CO ₂ ^{— contained} in R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 , R ^13BZ6 , R ^101BZ6 and R ^102BZ6 is a. .
( ^Rb -i) At least one of R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 and R ^13BZ6 is —SO ₃ ^— or —CO ₂ ^— .
^{(Rb-ii) R 1BZ6,} R 2BZ6, R 3BZ6, R 4BZ6, R 5BZ6, R 11BZ6, at least one of R ^12BZ6 and R ^{13BZ6 is, -CO-R 102BZ6, -COO-} R 101BZ6, -OCO-R 102BZ6 ^{, -COCO-R 102BZ6, -O-} R 102BZ6, -SO 2 -R 101BZ6, -SO 2 N (R 102BZ6) 2, or _{^{-CON (R 102BZ6) 2, -N}} (R 102BZ6) 2, -NHCO- ^R102BZ6 , -NHCO-N ( ^R102BZ6 ) ₂ , ^{-NHCOOR102BZ6} , or -OCON ( ^R102BZ6 ) ₂ ,
The R ^101BZ6 and R ^102BZ6 is, -SO ₃ ^- or -CO ₂ ^- 1 to 40 carbon atoms having a hydrocarbon group or a -SO ₃ ^- or -CO ₂ ^- is a heterocyclic group having. However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .
( ^Rb -iii) at least one of R ^1BZ6 , R ^2BZ6 , R ^3BZ6 , R ^4BZ6 , R ^5BZ6 , R ^11BZ6 , R ^12BZ6 and R ^13BZ6 has 1 to 40 carbon atoms having —SO ₃ ^— or —CO ₂ ^— . It is a hydrocarbon group or a heterocyclic group having —SO ₃ ^— or —CO ₂ ^— . However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .
a represents the same meaning as in formula (IZ6-A). When a plurality of a are present, they may be the same or different.
The absolute value of the negative valence of the partial structure represented by the formula (IZ6-B ′) and the positive valence of the partial structure represented by the formula (IZ6-B ″) are the same. ] L ¹ is The compound of claim 43 which is -CO-. R ^11BZ6 is an ^optionally substituted aliphatic hydrocarbon group having 1 to 40 carbon atoms, an ^optionally substituted phenyl group, an ^optionally substituted naphthyl group, a substituted group. A tetrahydronaphthyl group which may have a group, a thienyl group which may have a substituent, a furyl group which may have a substituent or a pyridinyl group which may have a substituent. Item 45. The compound according to item 43 or 44. 44. The compound according to claim 43, wherein the compound represented by the formula (IZ6-B) is a compound represented by the formula (IZ6-C).

[In the formula (IZ6-C)
A ^{c +} , b, c, d, L ¹ and the wavy line have the same meaning as described above.
L ² represents —CO— or —SO ₂ —.
R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 and R ^14CZ6 are each independently a hydrogen atom, -CO-R ^102CZ6 , -COO-R ^101CZ6 , -OCO-R ^102CZ6 , -COCO- ^{R 102CZ6, -O-R 102CZ6,} -SO 2 -R 101CZ6, -SO 2 N (R 102CZ6) 2, -CON (R 102CZ6) 2, -N (R 102CZ6) 2, -NHCO-R 102CZ6, -NHCO _{^{-N (R 102CZ6) 2, -NHCOOR}} 102CZ6, -OCON (R 102CZ6) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , -SO 3 -, -CO 2 -, substituted The C1-C40 hydrocarbon group which may have a group, or the heterocyclic group which may have a substituent is represented.
R ^2CZ6 and R ^3CZ6 , R ^3CZ6 and R ^4CZ6 , and R ^4CZ6 and R ^5CZ6 may be bonded to each other to form a ring.
R ^101CZ6 represents, independently of each other, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
^R102CZ6 represents a hydrogen atom, a ^C1-C40 hydrocarbon group which may have a substituent, or a heterocyclic group which may have a substituent, independently of each other.
M represents the same meaning as described above.
Formula (IZ6-C ′) and Formula (IZ6-C ″) each represent a partial structure of Formula (IZ6-C), and A ^{c +} , b, c, d, R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 , R ^14CZ6 , L ¹ and L ² represent the same as those in formula (IZ6-C).
When there are a ^{plurality of} R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 , R ^14CZ6 , R ^101CZ6 , R ^102CZ6 , L ¹ , L ² , M, c or A ^{c +} , they are the same May be different or different.
^R1CZ6 , ^R2CZ6 , ^R3CZ6 , ^R4CZ6 , ^R5CZ6 , ^R11CZ6 , ^R14CZ6 , ^R101CZ6 and ^R102CZ6 satisfy at least one of (rc-i) to (rc-iii), The total number of —SO ₃ ^— or —CO ₂ ^{— contained} in R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 , R ^14CZ6 , R ^101CZ6 and R ^102CZ6 is a.
(Rc-i) At least one of R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 and R ^14CZ6 is —SO ₃ ^— or —CO ₂ ^— .
^{(Rc-ii) R 1CZ6,} R 2CZ6, R 3CZ6, R 4CZ6, R 5CZ6, at least one of R ^11CZ6 and R ^{14CZ6 is, -CO-R 102CZ6, -COO-} R 101CZ6, -OCO-R 102CZ6, -COCO ^{-R 102CZ6, -O-R 102CZ6,} -SO 2 -R 101CZ6, -SO 2 N (R 102CZ6) 2, -CON (R 102CZ6) 2, -N (R 102CZ6) 2, -NHCO-R 102CZ6, - NHCO—N (R ^102CZ6 ) ₂ , —NHCOOR ^102CZ6 , or —OCON (R ^102CZ6 ) ₂ , wherein R ^101CZ6 and R ^102CZ6 have 1 to 40 carbon atoms having —SO ₃ ^— or —CO ₂ ^— . It is a hydrocarbon group or a heterocyclic group having —SO ₃ ^— or —CO ₂ ^— . However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .
(Rc-iii) a hydrocarbon group having 1 to 40 carbon atoms in which at least one of R ^1CZ6 , R ^2CZ6 , R ^3CZ6 , R ^4CZ6 , R ^5CZ6 , R ^11CZ6 and R ^14CZ6 has —SO ₃ ^— or —CO ₂ ^—. Or a heterocyclic group having —SO ₃ ^— or —CO ₂ ^— . However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .
a represents the same meaning as in formula (IZ6-B). When a plurality of a are present, they may be the same or different.
The absolute value of the negative valence that the partial structure represented by the formula (IZ6-C ′) has and the positive valence that the partial structure represented by the formula (IZ6-C ″) have are the same. ] The compound according to claim 46, wherein R ^11CZ6 and R ^14CZ6 are the same group, and L ¹ and L ² are the same group. L ¹ and L ^2, A compound according to claim 46 or 47 is -CO-. R ^11CZ6 and R ^14CZ6 may have an ^optionally substituted aliphatic hydrocarbon group having 1 to 40 carbon atoms, an ^optionally substituted phenyl group, and an ^optionally substituted naphthyl. Group, tetrahydronaphthyl group optionally having substituent, thienyl group optionally having substituent, furyl group optionally having substituent or pyridinyl group optionally having substituent 49. A compound according to any one of claims 46 to 48. 44. The compound according to claim 43, wherein the compound represented by the formula (IZ6-B) is a compound represented by the formula (IZ6-D).

[In the formula (IZ6-D),
A ^{c +} , b, c, d, L ¹ and the wavy line have the same meaning as described above.
R ^20DZ6 and R ^30DZ6 combine to form ring Q.
The ring Q may have a substituent and is a ring having 5 to 7 members, and the ring Q may be a hydrocarbon ring or a heterocyclic ring. Ring Q is condensed with a monocyclic ring which may have a substituent having 5 to 7 ring members selected from a hydrocarbon ring and a heterocyclic ring, or a condensed ring in which two or more of the monocyclic rings are condensed. May be.
R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 and R ^11DZ6 are each independently a hydrogen atom, —CO—R ^102DZ6 , —COO—R ^101DZ6 , —OCO—R ^102DZ6 , —COCO—R ^102DZ6 , _{^{-O-R 102DZ6, -SO 2 -R}} 101DZ6, -SO 2 N (R 102DZ6) 2, -CON (R 102DZ6) 2, -N (R 102DZ6) 2, -NHCO-R 102DZ6, -NHCO-N ( _{^{R 102DZ6) 2, -NHCOOR 102DZ6,}} -OCON (R 102DZ6) 2, halogen atom, a cyano group, a nitro _{group, -SO 3 M, -CO 2 M} , -SO 3 -, -CO 2 -, have a substituent The C1-C40 hydrocarbon group which may be represented, or the heterocyclic group which may have a substituent is represented.
R ^2DZ6 and R ^3DZ6 , R ^3DZ6 and R ^4DZ6 , and R ^4DZ6 and R ^5DZ6 may be bonded to each other to form a ring.
R ^101DZ6 represents, independently of each other, a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent.
R ^102DZ6 represents, independently of each other, a hydrogen atom, an ^optionally substituted hydrocarbon group having 1 to 40 carbon atoms, or an ^optionally substituted heterocyclic group.
M represents the same meaning as described above.
Formula (IZ6-D ′) and Formula (IZ6-D ″) each represent a partial structure of Formula (IZ6-D), and A ^{c +} , b, c, d, R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 , R ^11DZ6 , R ^20DZ6 , R ^30DZ6 and L ¹ represent the same as those in formula (IZ6-D).
When there are a ^{plurality of} R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 , R ^11DZ6 , R ^101DZ6 , R ^102DZ6 , L ¹ , M, R ^20DZ6 , R ^30DZ6 , ring Q, c or A ^{c +} Each may be the same or different.
R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 , R ^11DZ6 , R ^101DZ6 , R ^102DZ6 and ring Q satisfy at least one of (rd-i) to (rd-iv), The total number of —SO ₃ ^— or —CO ₂ ^{— contained} in R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 , R ^11DZ6 , R ^101DZ6 , R ^102DZ6 and ring Q is a.
( ^Rd -i) At least one of R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 and R ^11DZ6 is —SO ₃ ^— or —CO ₂ ^— .
( ^Rd -ii) At least one of ^R1DZ6 , ^R2DZ6 , ^R3DZ6 , ^R4DZ6 , ^R5DZ6 and ^R11DZ6 is -CO- ^R102DZ6 , -COO- ^R101DZ6 , -OCO- ^R102DZ6 , -COCO- ^R102DZ6 , -O-R ^102DZ6 , -SO ₂ -R ^101DZ6 , -SO ₂ N (R ^102DZ6 ) ₂ , ^-CON (R ^102DZ6 ) ₂ , -N (R ^102DZ6 ) ₂ , -NHCO-R ^102DZ6 , -NHCO-N (R ^102DZ6 ) ₂ , —NHCOOR ^102DZ6 , or —OCON (R ^102DZ6 ) ₂ , wherein R ^101DZ6 and R ^102DZ6 are hydrocarbon groups having 1 to 40 carbon atoms having —SO ₃ ^— or —CO ₂ ^—. Or a heterocyclic group having —SO ₃ ^— or —CO ₂ ^— . However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .
( ^Rd -iii) a hydrocarbon group having 1 to 40 carbon atoms in which at least one of R ^1DZ6 , R ^2DZ6 , R ^3DZ6 , R ^4DZ6 , R ^5DZ6 and R ^11DZ6 has —SO ₃ ^— or —CO ₂ ^— , or —SO ₃ ^- or -CO ₂ ^- I am a heterocyclic group having. However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .
(Rd-iv) Ring Q has —SO ₃ ^— or —CO ₂ ^— .
a represents the same meaning as in formula (IZ6-B). When a plurality of a are present, they may be the same or different.
The absolute value of the negative valence of the partial structure represented by the formula (IZ6-D ′) and the positive valence of the partial structure represented by the formula (IZ6-D ″) are the same. ] L ¹ is The compound of claim 50 which is -CO-. R ^11DZ6 is an ^optionally substituted aliphatic hydrocarbon group having 1 to 40 carbon atoms, an ^optionally substituted phenyl group, an ^optionally substituted naphthyl group, a substituted group. A tetrahydronaphthyl group which may have a group, a thienyl group which may have a substituent, a furyl group which may have a substituent or a pyridinyl group which may have a substituent. Item 52. The compound according to Item 50 or 51. 51. The compound according to claim 50, wherein the compound represented by the formula (IZ6-D) is a compound represented by the formula (IZ6-E).

[In the formula (IZ6-E),
A ^{c +} , b, c, d, L ¹ and the wavy line have the same meaning as described above.
R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 and R ^11EZ6 are each independently a hydrogen atom, -CO-R ^102EZ6 , -COO-R ^101EZ6 , -OCO-R ^102EZ6 , ^{-COCO-R 102EZ6, -O-R} 102EZ6, -SO 2 -R 101EZ6, -SO 2 N (R 102EZ6) 2, -CON (R 102EZ6) 2, -N (R 102EZ6) 2, -NHCO-R 102EZ6 , —NHCO—N (R ^102EZ6 ) ₂ , —NHCOOR ^102EZ6 , —OCON (R ^102EZ6 ) ₂ , halogen atom, cyano group, nitro group, —SO ₃ M, —CO ₂ M, —SO ₃ ⁻ , —CO ₂ ^- represents a hydrocarbon group or optionally substituted heterocyclic group having carbon atoms of 1 to 40 which may have a substituent.
R ^2EZ6 and R ^3EZ6 , R ^3EZ6 and R ^4EZ6 , and R ^4EZ6 and R ^5EZ6 may be bonded to each other to form a ring.
R ^101EZ6 represents a hydrocarbon group having 1 to 40 carbon atoms which may have a substituent or a heterocyclic group which may have a substituent, independently of each other.
R ^102EZ6 represents, independently of each other, a hydrogen atom, an ^optionally substituted hydrocarbon group having 1 to 40 carbon atoms, or an ^optionally substituted heterocyclic group.
M represents the same meaning as described above.
Formula (IZ6-E ′) and Formula (IZ6-E ″) each represent a partial structure of Formula (IZ6-E), and A ^{c +} , b, c, d, R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 , R ^11EZ6 and L ¹ represent the same as those in formula (IZ6-E).
When there are a ^{plurality of} R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 , R ^11EZ6 , R ^101EZ6 , R ^102EZ6 , L ¹ , M, c or A ^{c +} , they are the same May be different or different.
^R1EZ6 , ^R2EZ6 , ^R3EZ6 , ^R4EZ6 , ^R5EZ6 , ^R6EZ6 , ^R7EZ6 , ^R11EZ6 , ^R101EZ6, and ^R102EZ6 satisfy at least one of (re-i) to (re-iii) The total number of —SO ₃ ^— or —CO ₂ ^{— contained} in R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 , R ^11EZ6 , R ^101EZ6 and R ^102EZ6 is a. .
(Re-i) At least one of R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 and R ^11EZ6 is —SO ₃ ^— or —CO ₂ ^— .
(Re-ii) At least one of R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 and R ^11EZ6 is -CO-R ^102EZ6 , -COO-R ^101EZ6 , -OCO-R ^{102EZ6 , -COCO-R 102EZ6, -O-} R 102EZ6, -SO 2 -R 101EZ6, -SO 2 N (R 102EZ6) 2, -CON (R 102EZ6) 2, -N (R 102EZ6) 2, -NHCO-R ^{102EZ6, -NHCO-N (R 102EZ6} ) 2, -NHCOOR 102EZ6, or -OCON a (R ^102EZ6) _2, wherein R ^101EZ6 and R ^102EZ6 is, -SO ₃ ^- or -CO ₂ ^- carbons having 1 It is a heterocyclic group having ˜40 hydrocarbon groups or —SO ₃ ^— or —CO ₂ ^— . However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .
(Re-iii) at least one of R ^1EZ6 , R ^2EZ6 , R ^3EZ6 , R ^4EZ6 , R ^5EZ6 , R ^6EZ6 , R ^7EZ6 and R ^11EZ6 has 1 to 40 carbon atoms having —SO ₃ ^— or —CO ₂ ^— . It is a hydrocarbon group or a heterocyclic group having —SO ₃ ^— or —CO ₂ ^— . However, the hydrocarbon group or the heterocyclic group may have a substituent other than —SO ₃ ^— and —CO ₂ ^— .
a represents the same meaning as in formula (IZ6-D). When a plurality of a are present, they may be the same or different.
The absolute value of the negative valence of the partial structure represented by the formula (IZ6-E ′) and the positive valence of the partial structure represented by the formula (IZ6-E ″) are the same. ] L ¹ is The compound of claim 53 which is -CO-. R ^11EZ6 is an ^optionally substituted aliphatic hydrocarbon group having 1 to 40 carbon atoms, an ^optionally substituted phenyl group, an ^optionally substituted naphthyl group, a substituted group. A tetrahydronaphthyl group which may have a group, a thienyl group which may have a substituent, a furyl group which may have a substituent or a pyridinyl group which may have a substituent. Item 55. The compound according to item 53 or 54.