JP2021115347A - Deodorant pairing agent - Google Patents
Deodorant pairing agent Download PDFInfo
- Publication number
- JP2021115347A JP2021115347A JP2020012085A JP2020012085A JP2021115347A JP 2021115347 A JP2021115347 A JP 2021115347A JP 2020012085 A JP2020012085 A JP 2020012085A JP 2020012085 A JP2020012085 A JP 2020012085A JP 2021115347 A JP2021115347 A JP 2021115347A
- Authority
- JP
- Japan
- Prior art keywords
- deodorant
- pairing
- component
- mass
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002781 deodorant agent Substances 0.000 title claims abstract description 90
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 51
- 239000002904 solvent Substances 0.000 claims abstract description 41
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- 150000001413 amino acids Chemical class 0.000 claims abstract description 23
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000012046 mixed solvent Substances 0.000 claims abstract description 4
- 239000011701 zinc Substances 0.000 claims description 21
- 229910052725 zinc Inorganic materials 0.000 claims description 21
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 17
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract description 16
- 150000001875 compounds Chemical class 0.000 abstract description 8
- 239000011787 zinc oxide Substances 0.000 abstract description 8
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 abstract description 5
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- 235000004416 zinc carbonate Nutrition 0.000 abstract description 5
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- 241000272173 Calidris Species 0.000 abstract 1
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- 230000001877 deodorizing effect Effects 0.000 description 18
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Landscapes
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Abstract
Description
本発明は、悪臭を取り込み該悪臭の濃度を減少させる消臭機能と、該悪臭を良い香りに変換するペアリング機能とを併せ持つペアリング剤に関する。 The present invention relates to a pairing agent having both a deodorizing function of taking in a bad odor and reducing the concentration of the bad odor and a pairing function of converting the bad odor into a good scent.
日常生活や、各種産業においては、様々な悪臭が発生し、人々を悩ませている。これらの悪臭を生じる悪臭物質としては、硫化水素、メチルメルカプタン等の硫黄系化合物；アンモニア、アミン類等の窒素系化合物；酢酸、イソ吉草酸、カプロン酸等の低級脂肪酸；ホルムアルデヒド、アセトアルデヒド等のアルデヒド系化合物；等がある。 In daily life and various industries, various foul odors are generated and bother people. Examples of the malodorous substances that cause these malodors include sulfur compounds such as hydrogen sulfide and methyl mercaptan; nitrogen compounds such as ammonia and amines; lower fatty acids such as acetic acid, isovaleric acid and caproic acid; and aldehydes such as formaldehyde and acetaldehyde. System compounds; etc.
このような悪臭の問題を解消すべく、悪臭を取り込むことによって、該悪臭の濃度を減少させる消臭剤が、種々提案されている。 In order to solve such a problem of bad odor, various deodorants have been proposed that reduce the concentration of the bad odor by taking in the bad odor.
特許文献１においては、過酸化物を、オキシ安息香酸エステル、ハロゲン酸、ハロゲン酸のアルカリ金属塩、タンニン酸、サリチルアルデヒド、ｐ−クロロアセトフェノンから選ばれた少なくとも１種の化合物と組み合わせて使用した硫黄系悪臭物質の脱臭剤が開示されており、汚泥等から発生する硫化水素、メチルメルカプタン等の硫黄系悪臭物質の発生を、長時間に亘って抑えることができるとされている。 In Patent Document 1, the peroxide was used in combination with at least one compound selected from oxybenzoic acid ester, halogen acid, alkali metal salt of halogen acid, tannic acid, salicylaldehyde, and p-chloroacetophenone. A deodorant for a sulfur-based malodorous substance is disclosed, and it is said that the generation of sulfur-based malodorous substances such as hydrogen sulfide and methyl mercaptan generated from sludge and the like can be suppressed for a long period of time.
特許文献２においては、銅、亜鉛、マンガン、コバルト、ニッケルから選ばれる少なくとも１種類の金属塩と珪酸塩との無定形複合体であり、細孔容積が０．３〜０．５ｍｌ／ｇである硫黄系ガス消臭剤が開示されている。 In Patent Document 2, it is an amorphous composite of at least one metal salt selected from copper, zinc, manganese, cobalt, and nickel and a silicate, and has a pore volume of 0.3 to 0.5 ml / g. A sulfur-based gas deodorant is disclosed.
特許文献３においては、クロロフィリンと柿タンニンを含有してなることを特徴とする消臭石鹸が開示されており、アルカリ性であるクロロフィリンが、酸性ガスであるメチルメルカプタンと硫化水素に対して強い効果を発揮する旨記載されている。 Patent Document 3 discloses a deodorant soap characterized by containing chlorophyllin and persimmon tannin, and alkaline chlorophyllin has a strong effect on acid gases such as methyl mercaptan and hydrogen sulfide. It is stated that it will be exerted.
特許文献４においては、亜鉛、銅、アルミニウム、鉄等の金属を含んだ複合金属ケイ酸塩や、それと酸化チタンを併用する剤を有効成分として含有する消臭剤が開示され、アンモニア等のアルカリ性悪臭と、硫化水素やメチルメルカプタン等のイオウ系悪臭の両方に対して効果があるとされている。 Patent Document 4 discloses a composite metal silicate containing a metal such as zinc, copper, aluminum, and iron, and a deodorant containing an agent in which it is used in combination with titanium oxide as an active ingredient, and is alkaline such as ammonia. It is said to be effective against both malodor and sulfur-based malodor such as hydrogen sulfide and methyl mercaptan.
特許文献５においては、金属フタロシアニン錯体等の消臭剤を、乾燥ケナフ等の坦持体に坦持させた消臭材が開示されており、アンモニア、硫化水素、メチルメルカプタン等の臭気に対して優れた消臭性能を発揮し、消臭性能の持続性も優れているとされている。 Patent Document 5 discloses a deodorant in which a deodorant such as a metal phthalocyanine complex is carried on a carrier such as dried kenaf, and is used against odors such as ammonia, hydrogen sulfide, and methyl mercaptan. It exhibits excellent deodorant performance and is said to have excellent sustainability of deodorant performance.
特許文献６においては、ミルラ樹脂をエタノール及びグリセリンを含有する溶媒で抽出したミルラ抽出液を有効成分とする消臭用組成物が開示されており、特に酢酸臭に対して優れた消臭効果を発揮するとされている。 Patent Document 6 discloses a deodorizing composition containing a myrrh extract obtained by extracting myrrh resin with a solvent containing ethanol and glycerin as an active ingredient, and particularly has an excellent deodorizing effect on acetic acid odor. It is said that it will be demonstrated.
特許文献７においては、アンモニウム塩及び尿素を含むアルデヒド消臭性組成物が開示されており、安全性が高く、ホルムアルデヒドやアセトアルデヒドについて高性能な消臭性を示すとされている。 Patent Document 7 discloses an aldehyde deodorant composition containing an ammonium salt and urea, which is said to be highly safe and exhibit high-performance deodorant properties for formaldehyde and acetaldehyde.
また、悪臭物質を取り込むことで除去するのではなく、悪臭を異なる臭気に変調することによって、悪臭による不快感を低減するという試みもなされている。 Attempts have also been made to reduce the discomfort caused by bad odors by modulating the bad odors with different odors, instead of removing them by taking in the bad odor substances.
例えば、特許文献８においては、フラン化合物、ピラン化合物及びシクロペンタノン誘導体から選択される少なくとも一種の含酸素環状化合物を含有することを特徴とする臭気変調剤が開示されており、畜産業や水産業において発生する悪臭に効果があるとされている。
また、特許文献９においては、エステル類、アルデヒド類、アルコール類、及びピラン類を含有することを特徴とする生ゴミ用臭気変調剤が開示されている。
For example, Patent Document 8 discloses an odor modifier containing at least one oxygen-containing cyclic compound selected from a furan compound, a pyran compound, and a cyclopentanone derivative, which is used in the livestock industry and water. It is said to be effective against bad odors generated in the industry.
Further, Patent Document 9 discloses an odor modifier for kitchen waste, which is characterized by containing esters, aldehydes, alcohols, and pyrans.
しかし、悪臭物質の大気中における濃度が高い場合、これらの公知技術を用いたとしても、悪臭を感じる場合があり、更なる改善の余地があった。 However, when the concentration of the malodorous substance in the atmosphere is high, even if these known techniques are used, a malodor may be felt, and there is room for further improvement.
本発明は上記背景技術に鑑みてなされたものであり、その課題は、悪臭を取り込み該悪臭の濃度を減少させる消臭機能と、該悪臭を良い香りに変換するペアリング機能とを併せ持つ消臭ペアリング剤を提供することにある。 The present invention has been made in view of the above background technology, and the subject thereof is deodorization having both a deodorizing function of taking in a bad odor and reducing the concentration of the bad odor and a pairing function of converting the bad odor into a good scent. The purpose is to provide a pairing agent.
本発明者は、上記の課題を解決すべく鋭意検討を重ねた結果、消臭機能を持つ成分（消臭成分）と、ペアリング機能を持つ成分（ペアリング成分）をともに含有する消臭ペアリング剤であれば、悪臭の濃度が高い場合であっても、悪臭を良い香りに変換でき、爽快感を与えることができることを見出した。 As a result of diligent studies to solve the above problems, the present inventor has deodorized pair containing both a component having a deodorizing function (deodorizing component) and a component having a pairing function (pairing component). It has been found that a ring agent can convert a bad odor into a good scent and give a refreshing feeling even when the concentration of the bad odor is high.
通常、消臭成分とペアリング成分を組み合わせると、互いに効果を減殺し、消臭成分もペアリング成分も減少又は消失してしまうと考えられる。しかし、本発明者は、特定の可溶化剤を使用することで、これら２つの成分が共存可能となり、消臭機能及びペアリング機能を、消臭成分又はペアリング成分を単独で含有する場合と同等に発揮することができることを見出して、本発明を完成するに至った。 Usually, it is considered that when the deodorant component and the pairing component are combined, the effects are diminished with each other, and both the deodorant component and the pairing component are reduced or eliminated. However, the present inventor makes it possible for these two components to coexist by using a specific solubilizer, and has a deodorant function and a pairing function when the deodorant component or the pairing component is contained alone. We have found that they can be exhibited equally, and have completed the present invention.
すなわち、本発明は、悪臭を取り込み該悪臭の濃度を減少させる消臭成分と、該悪臭を良い香りに変換するペアリング成分と、溶媒とを含有する消臭ペアリング剤であって、更に、ＨＬＢ値が１０以上１６以下である可溶化剤を含有しており、該消臭成分が、亜鉛及びアミノ酸を含むものであることを特徴とする消臭ペアリング剤を提供するものである。 That is, the present invention is a deodorant pairing agent containing a deodorant component that takes in a bad odor and reduces the concentration of the bad odor, a pairing component that converts the bad odor into a good scent, and a solvent. It contains a solubilizer having an HLB value of 10 or more and 16 or less, and provides a deodorant pairing agent characterized in that the deodorant component contains zinc and an amino acid.
本発明によれば、悪臭を取り込み該悪臭の濃度を減少させる消臭機能と、該悪臭を良い香りに変換するペアリング機能とを併せ持つ消臭ペアリング剤を提供することができる。 According to the present invention, it is possible to provide a deodorant pairing agent having both a deodorizing function of taking in a bad odor and reducing the concentration of the bad odor and a pairing function of converting the bad odor into a good scent.
特に、大気中の悪臭の濃度が高い場合、公知の方法で悪臭を異なる臭気に変調しようとしても、十分に悪臭を変調できない場合があったが、本発明では、悪臭の濃度自体を減少させた上で、微量に残存する悪臭を、良い香りに変換することができるので、本発明の消臭ペアリング剤は、広範囲の濃度の悪臭に対して対応することができる。 In particular, when the concentration of malodor in the atmosphere is high, even if an attempt is made to modulate the malodor with a different odor by a known method, the malodor may not be sufficiently modulated, but in the present invention, the concentration of the malodor itself is reduced. Since the malodor remaining in a small amount can be converted into a good odor, the deodorant pairing agent of the present invention can cope with a wide range of malodors.
以下、本発明について説明するが、本発明は以下の実施の形態に限定されるものではなく、任意に変形して実施することができる。 Hereinafter, the present invention will be described, but the present invention is not limited to the following embodiments, and can be arbitrarily modified and carried out.
本発明は、消臭ペアリング剤に関する。「消臭ペアリング剤」とは、大気中の悪臭を取り込み該悪臭の濃度を減少させる機能（消臭機能）と、大気中の悪臭物質と共存することで、悪臭物質単独の臭いを、異なるにおいに変換する機能（ペアリング機能）を併せ持つ剤をいう。 The present invention relates to a deodorant pairing agent. The "deodorant pairing agent" has a function of taking in bad odors in the air and reducing the concentration of the bad odors (deodorant function), and by coexisting with the bad odor substances in the air, the odor of the bad odor substances alone is different. An agent that also has a function to convert to odor (pairing function).
通常、消臭機能を持つ成分とペアリング機能を持つ成分とが共存すると、互いに効果を減殺し、どちらの効果も失われてしまうところ、本発明の消臭ペアリング剤では、特定の可溶化剤を使用することによって、両機能をともに発揮することができる。 Normally, when a component having a deodorant function and a component having a pairing function coexist, the effects are diminished with each other and both effects are lost. However, in the deodorant pairing agent of the present invention, specific solubilization By using an agent, both functions can be exhibited.
＜消臭成分＞
本発明の消臭ペアリング剤は、悪臭を取り込み該悪臭の濃度を減少させる消臭成分を含有する。該消臭成分は、亜鉛及びアミノ酸を含んでいる。亜鉛は、本発明の消臭ペアリング剤の溶媒中に、アミノ酸が配位した錯体として存在する。以下、亜鉛にアミノ酸が配位した錯体を、「亜鉛アミノ酸錯体」という場合がある。
<Deodorant ingredient>
The deodorant pairing agent of the present invention contains a deodorant component that takes in malodor and reduces the concentration of the malodor. The deodorant component contains zinc and amino acids. Zinc exists as a complex in which amino acids are coordinated in the solvent of the deodorant pairing agent of the present invention. Hereinafter, a complex in which an amino acid is coordinated with zinc may be referred to as a "zinc amino acid complex".
本発明の消臭ペアリング剤が含有する亜鉛は、金属亜鉛であってもよいし、亜鉛化合物であってもよい。亜鉛化合物としては、酸化亜鉛、炭酸亜鉛、水酸化亜鉛、塩化亜鉛、硫酸亜鉛、硝酸亜鉛、酢酸亜鉛、等が例示できる。
入手のしやすさや、安全性等の点から、酸化亜鉛、炭酸亜鉛が好ましい。酸化亜鉛は、化粧品や医薬品等の原料として使用される人体に無害な物質であり、消臭作用の他に抗菌作用を有しているため、本発明の消臭ペアリング剤に含有させる亜鉛化合物として特に好ましい。
これらの亜鉛（金属亜鉛又は亜鉛化合物）は、１種単独で使用してもよいし、２種以上を混合して使用してもよい。
The zinc contained in the deodorant pairing agent of the present invention may be metallic zinc or a zinc compound. Examples of the zinc compound include zinc oxide, zinc carbonate, zinc hydroxide, zinc chloride, zinc sulfate, zinc nitrate, zinc acetate and the like.
Zinc oxide and zinc carbonate are preferable from the viewpoint of availability and safety. Zinc oxide is a substance that is harmless to the human body and is used as a raw material for cosmetics and pharmaceuticals, and has an antibacterial effect in addition to a deodorant effect. Is particularly preferable.
These zincs (metallic zinc or zinc compounds) may be used alone or in admixture of two or more.
本発明の消臭ペアリング剤が含有するアミノ酸は、アミノ基（−ＮＨ２）とカルボキシル基（−ＣＯＯＨ）を分子内に有し、これらの官能基の存在により、アンモニア、酢酸、ホルムアルデヒド等に対して、消臭効果を発揮する。 The amino acid contained in the deodorant pairing agent of the present invention has an amino group (-NH 2 ) and a carboxyl group (-COOH) in the molecule, and due to the presence of these functional groups, it becomes ammonia, acetic acid, formaldehyde, etc. On the other hand, it exerts a deodorizing effect.
アミノ酸の例としては、グリシン、ジメチルグリシン、トリメチルグリシン、サルコシン、アラニン、バリン、ロイシン、イソロイシン、セリン、トレオニン、フェニルアラニン、チロシン、トリプトファン、シスチン、システイン、メチオニン、プロリン、ヒドロキシプロリン、グルタミン、アスパラギン、アルギニン、グルタミン酸、アスパラギン酸、ヒスチジン、リジン等が挙げられ、Ｄ体、Ｌ体、ラセミ体の何れも使用可能である。また、これらのアミノ酸の塩も使用可能である。
これらのアミノ酸は、１種単独で使用してもよいし、２種以上を混合して使用してもよい。
Examples of amino acids include glycine, dimethylglycine, trimethylglycine, sarcosin, alanine, valine, leucine, isoleucine, serine, threonine, phenylalanine, tyrosine, tryptophan, cystine, cysteine, methionine, proline, hydroxyproline, glutamine, aspartic acid, arginine. , Glutamic acid, aspartic acid, histidine, lysine and the like, and any of D-form, L-form, and racemic-form can be used. Salts of these amino acids can also be used.
These amino acids may be used alone or in combination of two or more.
入手の容易さやコスト、消臭性能等の観点から、上記したアミノ酸の中でも、グリシン、サルコシン、アラニン、フェニルアラニン、グルタミン酸が好ましく、グリシンが特に好ましい。 Among the above-mentioned amino acids, glycine, sarcosine, alanine, phenylalanine, and glutamic acid are preferable, and glycine is particularly preferable, from the viewpoint of easy availability, cost, deodorant performance, and the like.
酸化亜鉛や、炭酸亜鉛は、通常、難水溶性であるが、アミノ酸がある程度の量共存する場合、亜鉛アミノ酸錯体を形成し、水等の水性溶媒に溶解するようになる。
なお、本発明の消臭ペアリング剤に含有されるアミノ酸は、必ずしも全てが亜鉛に配位している必要はなく、亜鉛に配位していないアミノ酸が存在していてもよい。
Zinc oxide and zinc carbonate are usually poorly water-soluble, but when amino acids coexist in a certain amount, they form a zinc amino acid complex and become soluble in an aqueous solvent such as water.
The amino acids contained in the deodorant pairing agent of the present invention do not necessarily have to be all coordinated to zinc, and amino acids not coordinated to zinc may be present.
本発明の消臭ペアリング剤において、亜鉛とアミノ酸の含有比率は、亜鉛１モルに対して、アミノ酸が２モル以上であることが好ましく、３モル以上であることがより好ましく、６モル以上であることが特に好ましい。また、５０モル以下であることが好ましく、２０モル以下であることがより好ましく、１０モル以下であることが特に好ましい。
アミノ酸の含有比率が上記下限以上であると、難水溶性の亜鉛化合物が十分に水性溶媒に溶解するようになる。また、アンモニアやアルデヒドに対する消臭性能が十分に発揮されるようになる。
アミノ酸の含有比率が上記上限以下であると、コスト的に有利であり、また、硫化水素等の硫黄系悪臭ガスに対する消臭性能が十分に発揮されるようになる。
In the deodorant pairing agent of the present invention, the content ratio of zinc and amino acid is preferably 2 mol or more, more preferably 3 mol or more, and 6 mol or more, based on 1 mol of zinc. It is particularly preferable to have. Further, it is preferably 50 mol or less, more preferably 20 mol or less, and particularly preferably 10 mol or less.
When the amino acid content ratio is at least the above lower limit, the poorly water-soluble zinc compound is sufficiently dissolved in the aqueous solvent. In addition, the deodorant performance against ammonia and aldehydes will be fully exhibited.
When the content ratio of amino acids is not more than the above upper limit, it is advantageous in terms of cost, and the deodorizing performance against sulfur-based malodorous gas such as hydrogen sulfide is sufficiently exhibited.
本発明の消臭ペアリング剤を調製する際には、亜鉛とアミノ酸を混合した溶液（亜鉛アミノ酸錯体を含有する溶液）を先に調製してもよいし、亜鉛やアミノ酸を、消臭ペアリング剤の他の成分とともに混合してもよい。 When preparing the deodorant pairing agent of the present invention, a solution in which zinc and an amino acid are mixed (a solution containing a zinc amino acid complex) may be prepared first, or zinc or an amino acid may be deodorized and paired. It may be mixed with other components of the agent.
酸化亜鉛や炭酸亜鉛のような難水溶性の亜鉛化合物を使用する場合、亜鉛アミノ酸錯体を含有する溶液の調製方法としては、所定濃度の亜鉛化合物の懸濁液と所定濃度のアミノ酸水性溶液を予め調製し、両者を所定の併用割合となるように混合する；亜鉛化合物の微粒子とアミノ酸とを所定の割合で混合した後、混合物を水性媒体に溶解して所定濃度にする；所定濃度のアミノ酸水性溶液に亜鉛化合物の微粒子をアミノ酸に対して所定の割合で添加・混合し、所定の濃度とする；等の方法があるが、これらに限定されるものではない。 When a poorly water-soluble zinc compound such as zinc oxide or zinc carbonate is used, as a method for preparing a solution containing the zinc amino acid complex, a suspension of the zinc compound having a predetermined concentration and an aqueous solution of the amino acid having a predetermined concentration are prepared in advance. Prepare and mix the two in a predetermined combination ratio; after mixing the zinc compound fine particles and the amino acid in a predetermined ratio, dissolve the mixture in an aqueous medium to a predetermined concentration; a predetermined concentration of amino acid aqueous. Fine particles of the zinc compound are added to and mixed with the amino acid in a predetermined ratio to the solution to obtain a predetermined concentration; and the like, but the method is not limited thereto.
本発明の消臭ペアリング剤における消臭成分の含有量（亜鉛としての含有量）は、０．０１質量％以上であることが好ましく、０．０２質量％以上であることがより好ましく、０．０３質量％以上であることが特に好ましい。また、１０質量％以下であることが好ましく、５質量％以下であることがより好ましく、３質量％以下であることが特に好ましい。
上記範囲内とすることで、消臭機能が十分に発揮される。また、上記範囲内であると、ペアリング機能を阻害しにくい。
The content of the deodorant component (content as zinc) in the deodorant pairing agent of the present invention is preferably 0.01% by mass or more, more preferably 0.02% by mass or more, and is 0. It is particularly preferable that the content is 0.03% by mass or more. Further, it is preferably 10% by mass or less, more preferably 5% by mass or less, and particularly preferably 3% by mass or less.
Within the above range, the deodorant function is fully exhibited. Further, when it is within the above range, the pairing function is less likely to be impaired.
＜ペアリング成分＞
本発明の消臭ペアリング剤は、悪臭を良い香りに変換するペアリング成分を含有する。ペアリング成分は、大気中の悪臭物質と共存することで、悪臭物質単独の臭いを、異なるにおい（良い香り）に変換する。
<Pairing component>
The deodorant pairing agent of the present invention contains a pairing component that converts a bad odor into a good scent. By coexisting with the malodorous substance in the atmosphere, the pairing component converts the odor of the malodorous substance alone into a different odor (good scent).
ペアリング成分としては、香料等に使用されている公知の香気成分を適宜使用することができる。例えば、下記のような化合物が例示できるが、これらに限定されるものではない。
ペアリング成分は、１種単独で使用してもよいし、２種以上を混合して使用してもよい。
As the pairing component, a known aroma component used in a fragrance or the like can be appropriately used. For example, the following compounds can be exemplified, but are not limited thereto.
The pairing component may be used alone or in combination of two or more.
［脂肪族カルボン酸エステル系化合物］
酢酸メチル、酢酸エチル、酢酸イソプロピル、酢酸イソブチル、酢酸ペンチル、酢酸ヘキシル、酢酸ｃｉｓ−３−ヘキセニル、酢酸リナリル、酢酸ゲラニル、酢酸プレニル、酢酸トリシクロデセニル、酢酸２−ｔｅｒｔ−ブチルシクロヘキシル、酢酸４−ｔｅｒｔ−ブチルシクロヘキシル、酢酸イソボルニル、酢酸ベンジル、酢酸スチラリル、酢酸１，１−ジメチル−２−フェニルエチル、プロピオン酸メチル、プロピオン酸エチル、酪酸メチル、酪酸エチル、イソ酪酸エチル、イソ酪酸プロピル、イソ吉草酸エチル、イソ酪酸プロピル、イソ吉草酸イソペンチル、２−メチル酪酸エチル、カプロン酸メチル、カプロン酸エチル、カプロン酸アリル、エナント酸メチル、エナント酸エチル、カプリル酸メチル、カプリル酸エチル。
[Aliphatic carboxylic acid ester compound]
Methyl acetate, ethyl acetate, isopropyl acetate, isobutyl acetate, pentyl acetate, hexyl acetate, cis-3-hexenyl acetate, linaryl acetate, geranyl acetate, prenyl acetate, tricyclodecenyl acetate, 2-tert-butylcyclohexyl acetate, acetic acid 4-tert-Butylcyclohexyl, isobornyl acetate, benzyl acetate, styralyl acetate, 1,1-dimethyl-2-phenylethyl acetate, methyl propionate, ethyl propionate, methyl butyrate, ethyl butyrate, ethyl isobutyrate, propyl isobutyrate, Ethyl isovalerate, propyl isobutyrate, isopentyl isovalerate, ethyl 2-methylbutyrate, methyl caproate, ethyl caproate, allyl caproate, methyl enanthate, ethyl enanthate, methyl caprylate, ethyl caprylate.
［脂環式カルボン酸エステル系化合物］
シクロヘキシルプロピオン酸アリル、ジヒドロジャスモン酸メチル。
[Alicyclic carboxylic acid ester compound]
Allyl cyclohexylpropionate, methyl dihydrojasmonate.
［芳香族カルボン酸エステル系化合物］
安息香酸エチル、安息香酸ベンジル、サリチル酸イソペンチル。
[Aromatic carboxylic acid ester compound]
Ethyl benzoate, benzyl benzoate, isopentyl salicylate.
［脂肪族アルコール系化合物］
ヘキサノール、ｔｒａｎｓ−２−ヘキセノール、２−エチルヘキサノール。
[Alphatic alcohol compounds]
Hexanol, trans-2-hexanol, 2-ethylhexanol.
［芳香族アルコール系化合物］
ベンジルアルコール、β−フェニルエチルアルコール、３−フェニルプロパノール、フェニルエチルジメチルカービノール、シンナミックアルコール、アニスアルコール。
[Aromatic alcohol compounds]
Benzyl alcohol, β-phenylethyl alcohol, 3-phenylpropanol, phenylethyldimethylcarbinol, synnamic alcohol, anisyl alcohol.
［テルペン系アルコール系化合物］
リナロール、ターピネオール、ネロール、ジヒドロミルセノール、シトロネロール、ゲラニオール、Ｌ−メントール、ヒドロキシシトロネラール、シトラール、シトロネラール。
[Terpene alcohol compounds]
Linalool, terpineol, nerol, dihydromilsenol, citronellol, geraniol, L-menthol, hydroxycitronellal, citral, citronellal.
［脂肪族アルデヒド系化合物］
ヘキサナール、オクタナール、デカナール、ドデカナール、２−メチルウンデカナール、ｔｒａｎｓ−２−ヘキセナール、１０−ウンデセナール、２−ノネナール。
[Aliphatic aldehyde compound]
Hexanal, octanal, decanal, dodecanal, 2-methylundecanal, trans-2-hexenal, 10-undecanal, 2-nonenal.
［脂環式アルデヒド系化合物］
リグシトラール、リラール、トリプラール。
[Alicyclic aldehyde compound]
Rig citral, rilar, triplar.
［芳香族アルデヒド系化合物］
バニリン、エチルバニリン、アニスアルデヒド、ヘリオトロピン、ヘキシルシンナミックアルデヒド、アミルシンナミックアルデヒド、リリアール。
[Aromatic aldehyde compounds]
Vanillin, ethylvanillin, anisaldehyde, heliotropin, hexyl cinnamic aldehyde, amyl cinnamic aldehyde, lilial.
［テルペン系アルデヒド系化合物］
シトラール、シトロネラール、ヒドロキシシトロネラール。
[Terpene-based aldehyde-based compounds]
Citral, citronellal, hydroxycitronellal.
［脂環式ケトン系化合物］
α−ヨノン、β−ヨノン、γ−メチルヨノン、α−ダマスコン、β−ダマスコン、イソラルデイン。
[Alicyclic ketone compound]
α-Ionone, β-Ionone, γ-Methylionone, α-Damascone, β-Damascone, Isolardane.
［テルペン系ケトン系化合物］
メチルセドリルケトン、ＤＬカンフル。
[Terpene-based ketone compounds]
Methyl sedrill ketone, DL camphor.
［ラクトン系化合物］
クマリン、γ−ノナラクトン、γ−デカラクトン、γ−ウンデカラクトン。
[Lactone compounds]
Coumarin, γ-nononalactone, γ-decalactone, γ-undecalactone.
［環状テルペン系炭化水素化合物］
α−ピネン、β−ピネン、Ｄ−リモネン。
[Cyclic terpene hydrocarbon compound]
α-Pinene, β-Pinene, D-Limonene.
［フェノール誘導体系化合物］
アネトール、オイゲノール、メチルオイゲノール、メチルイソオイゲノール、ジフェニルオキサイド。
[Phenol derivative compounds]
Anethole, eugenol, methyl eugenol, methyl isoeugenol, diphenyl oxide.
［アセタール系化合物］
フェニルアセトアルデヒドジメチルアセタール。
[Acetal compounds]
Phenylacetaldehyde dimethyl acetal.
［合成ムスク系化合物］
トナリッド、ガラクソリド、ファンソリド、トラセオライド、セレストリド、ベルサリド。
[Synthetic musk compounds]
Tonalid, Galaxolide, Fansolide, Traseolide, Celestride, Versalid.
［含窒素系化合物］
インドール、シトロネリルニトリル。
[Nitrogen-containing compounds]
Indole, citronellyl nitrile.
［天然精油］
オリーブオイル、セリーシードオイル、ローズマリーオイル、オレンジオイル、シダーウッドオイル、シダーリーフオイル、ハッカオイル、テレビンオイル、ユーカリオイル、ベチバーオイル、ブルガリアラベンダーオイル、レモンオイル、シトロネラオイル、ホワイトカンファーオイル、スペアミントオイル、ローズオイル、オークモスオイル。
[Natural essential oil]
Olive oil, cely seed oil, rosemary oil, orange oil, cedar wood oil, cedar leaf oil, peppermint oil, television oil, eucalyptus oil, vetiver oil, bulgarian lavender oil, lemon oil, citronella oil, white camphor oil, spare mint oil, Rose oil, oak moss oil.
本発明の消臭ペアリング剤におけるペアリング成分の含有量は、０．００１質量％以上であることが好ましく、０．００２質量％以上であることがより好ましく、０．００３質量％以上であることが特に好ましい。また、５質量％以下であることが好ましく、３質量％以下であることがより好ましく、１質量％以下であることが特に好ましい。
上記範囲内とすることで、ペアリング機能が十分に発揮され、また、コストを抑えられる。
The content of the pairing component in the deodorant pairing agent of the present invention is preferably 0.001% by mass or more, more preferably 0.002% by mass or more, and 0.003% by mass or more. Is particularly preferred. Further, it is preferably 5% by mass or less, more preferably 3% by mass or less, and particularly preferably 1% by mass or less.
By setting it within the above range, the pairing function can be fully exhibited and the cost can be suppressed.
＜可溶化剤＞
本発明の消臭ペアリング剤は、ＨＬＢ値が１０以上１６以下である可溶化剤を含有する。
<Solubilizer>
The deodorant pairing agent of the present invention contains a solubilizer having an HLB value of 10 or more and 16 or less.
ＨＬＢ（Ｈｙｄｒｏｐｈｉｌｅ−Ｌｉｐｏｐｈｉｌｅ Ｂａｌａｎｃｅ；親水−親油平衡）値は、界面活性剤の疎水性と親水性のバランスを表す数値であり、下記の式（ａ）により定義される。
なお、混合物のＨＬＢ値は各成分のＨＬＢ値の加重平均となる。
The HLB (Hydrophile-Lipophile Balance) value is a numerical value representing the balance between hydrophobicity and hydrophilicity of a surfactant, and is defined by the following formula (a).
The HLB value of the mixture is a weighted average of the HLB values of each component.
ＨＬＢ値＝２０×親水部の式量の総和／分子量 （ａ） HLB value = 20 x total formula of hydrophilic part / molecular weight (a)
通常、消臭成分とペアリング成分は相性が悪く、両成分を共存させた場合、互いに効果を減殺してしまう。しかし、ＨＬＢ値が１０以上１６以下の可溶化剤の存在下で両成分を共存させた場合、それぞれの成分単独の場合と遜色なく消臭機能とペアリング機能を発揮することができる。 Normally, the deodorant component and the pairing component are incompatible with each other, and when both components coexist, the effects of each component are diminished. However, when both components coexist in the presence of a solubilizer having an HLB value of 10 or more and 16 or less, the deodorizing function and the pairing function can be exhibited as well as the case of each component alone.
本発明の消臭ペアリング剤のＨＬＢ値は、１０．５以上であることが好ましく、１１以上であることがより好ましく、１２以上であることが特に好ましい。また、１５．７以下であることが好ましく、１５．５以下であることが特に好ましい。
上記範囲内であると、前記した効果をより奏しやすい。
The HLB value of the deodorant pairing agent of the present invention is preferably 10.5 or more, more preferably 11 or more, and particularly preferably 12 or more. Further, it is preferably 15.7 or less, and particularly preferably 15.5 or less.
When it is within the above range, the above-mentioned effect can be more easily achieved.
本発明の消臭ペアリング剤に含有させる可溶化剤としては、前記したＨＬＢ値の範囲を満たす市販の界面活性剤等を適宜使用することができる。また、前記したＨＬＢ値の範囲を満たす界面活性剤を１種単独で使用してもよいし、２種以上の界面活性剤を、前記したＨＬＢ値の範囲を満たすように、混合して使用してもよい。 As the solubilizing agent contained in the deodorant pairing agent of the present invention, a commercially available surfactant or the like satisfying the above-mentioned HLB value range can be appropriately used. Further, one type of surfactant satisfying the above-mentioned HLB value range may be used alone, or two or more types of surfactants may be mixed and used so as to satisfy the above-mentioned HLB value range. You may.
本発明の消臭ペアリング剤における可溶化剤の含有量は、０．０１質量％以上であることが好ましく、０．０２質量％以上であることがより好ましく、０．０３質量％以上であることが特に好ましい。また、２０質量％以下であることが好ましく、１０質量％以下であることがより好ましく、５質量％以下であることが特に好ましい。
上記範囲内とすることで、溶解性が良好となり、消臭機能とペアリング機能がともに良好に発揮される。
The content of the solubilizer in the deodorant pairing agent of the present invention is preferably 0.01% by mass or more, more preferably 0.02% by mass or more, and 0.03% by mass or more. Is particularly preferred. Further, it is preferably 20% by mass or less, more preferably 10% by mass or less, and particularly preferably 5% by mass or less.
Within the above range, the solubility becomes good, and both the deodorizing function and the pairing function are exhibited well.
＜溶媒＞
本発明の消臭ペアリング剤は、各成分が溶媒中に溶解又は分散した状態であるのが、取り扱い性等の点から望ましい。特に、本発明の消臭ペアリング剤は、溶媒中に溶解した溶液の形態であることが、スプレー噴霧を行う際にノズルに詰まることを避けられる、人の手の届かない配管内消臭に使用する際にも詰まりを避けられる、ペアリング成分が一定割合で揮発することでペアリング効果を過不足なく発揮できる、等の点から望ましい。
<Solvent>
In the deodorant pairing agent of the present invention, it is desirable that each component is dissolved or dispersed in a solvent from the viewpoint of handleability and the like. In particular, the deodorant pairing agent of the present invention is in the form of a solution dissolved in a solvent, which avoids clogging of the nozzle when spraying, and deodorizes in a pipe that is out of reach of humans. It is desirable from the viewpoints that clogging can be avoided even when used, and that the pairing component can be volatilized at a constant ratio so that the pairing effect can be exhibited without excess or deficiency.
本発明の消臭ペアリング剤が含有する溶媒の具体例としては、水；メタノール、エタノール、プロパノール、イソプロパノール等のモノアルコール系溶媒；エチレングリコール、プロピレングリコール、ジエチレングリコール、ジプロピレングリコール、ポリエチレングリコール、ポリプロピレングリコール等のグリコール系溶媒；グリセリン等のポリオール系溶媒；等が挙げられる。
これらの溶媒は、１種単独で用いてもよいし、２種以上を併用してもよい。
Specific examples of the solvent contained in the deodorant pairing agent of the present invention include water; monoalcoholic solvents such as methanol, ethanol, propanol and isopropanol; ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, polyethylene glycol and polypropylene. Glycol-based solvents such as glycol; polyol-based solvents such as glycerin; and the like can be mentioned.
These solvents may be used alone or in combination of two or more.
安全性、揮発性、コスト等の観点から、本発明の消臭ペアリング剤が含有する溶媒は、水及び／又はグリコール系溶媒を含んでいるのが望ましい。
グリコール系溶媒の中では、プロピレングリコールやジプロピレングリコールが好ましく、プロピレングリコールが特に好ましい。
From the viewpoint of safety, volatility, cost and the like, it is desirable that the solvent contained in the deodorant pairing agent of the present invention contains water and / or a glycol-based solvent.
Among the glycol-based solvents, propylene glycol and dipropylene glycol are preferable, and propylene glycol is particularly preferable.
本発明の消臭ペアリング剤が含有する溶媒は、水とグリコール系溶媒とからなる混合溶媒であることが特に好ましい。
かかる混合溶媒における水とグリコール系溶媒の含有比率は、グリコール系溶媒１質量部に対して、水が１０質量部以上であることが好ましく、３０質量部以上であることがより好ましく、５０質量部以上であることが特に好ましい。また、５０００質量部以下であることが好ましく、４０００質量部以下であることがより好ましく、３０００質量部以下であることが特に好ましい。
上記範囲内であると、溶解性が良好となり、また、長期保存してもペアリング成分の活性が失われにくくなる。
The solvent contained in the deodorant pairing agent of the present invention is particularly preferably a mixed solvent composed of water and a glycol-based solvent.
The content ratio of water to the glycol solvent in such a mixed solvent is preferably 10 parts by mass or more, more preferably 30 parts by mass or more, and 50 parts by mass with respect to 1 part by mass of the glycol solvent. The above is particularly preferable. Further, it is preferably 5000 parts by mass or less, more preferably 4000 parts by mass or less, and particularly preferably 3000 parts by mass or less.
When it is within the above range, the solubility becomes good, and the activity of the pairing component is less likely to be lost even after long-term storage.
本発明の消臭ペアリング剤における溶媒の含有量は、１０質量％以上であることが好ましく、１５質量％以上であることがより好ましく、２０質量％以上であることが特に好ましい。また、９９．９９質量％以下であることが好ましく、９９質量％以下であることがより好ましく、９７質量％以下であることが特に好ましく、９５質量％以下であることが最も好ましい。
上記範囲内とすることで、溶解性が良好となり、また、長期保存してもペアリング成分の活性が失われにくくなる。
The content of the solvent in the deodorant pairing agent of the present invention is preferably 10% by mass or more, more preferably 15% by mass or more, and particularly preferably 20% by mass or more. Further, it is preferably 99.99% by mass or less, more preferably 99% by mass or less, particularly preferably 97% by mass or less, and most preferably 95% by mass or less.
Within the above range, the solubility becomes good, and the activity of the pairing component is less likely to be lost even after long-term storage.
＜その他の成分＞
本発明の消臭ペアリング剤は、本発明の効果を阻害しない範囲内において、揮発防止剤、防腐剤等の添加剤を必要に応じて配合してもよい。
<Other ingredients>
The deodorant pairing agent of the present invention may contain additives such as anti-volatile agents and preservatives, if necessary, as long as the effects of the present invention are not impaired.
本発明の消臭ペアリング剤の使用の形態に特に限定はなく、例えば、スプレー噴霧してもよいし、閉鎖された空間に溶液のまま静置してもよいし、担体に担持させて使用してもよい。 The form of use of the deodorant pairing agent of the present invention is not particularly limited, and for example, it may be sprayed, left as a solution in a closed space, or supported on a carrier for use. You may.
本発明の消臭ペアリング剤の適用対象となる悪臭としては、硫化水素、メチルメルカプタン、硫化メチル、二硫化メチル等の硫黄系化合物；アンモニア、アミン類等の窒素系化合物；酢酸、イソ吉草酸，カプロン酸等の低級脂肪酸；ホルムアルデヒド、アセトアルデヒド等のアルデヒド系化合物；等が例示できるが、これらに限定されるものではない。 The malodor to which the deodorant pairing agent of the present invention is applied includes sulfur compounds such as hydrogen sulfide, methyl mercaptan, methyl sulfide and methyl disulfide; nitrogen compounds such as ammonia and amines; acetaldehyde and isovaleric acid. , Lower fatty acids such as caproic acid; aldehyde compounds such as formaldehyde and acetaldehyde; etc., but are not limited thereto.
本発明の消臭ペアリング剤は、消臭成分とペアリング成分をともに含有するので、悪臭物質の濃度が高い場合に、悪臭物質を除去して濃度を下げることができる。更に、除去しきれなかった微量の悪臭物質と、ペアリング成分との相互作用により、残存した微量の悪臭物質を良い香りに変換し、爽快感を与えることができる。通常、消臭成分とペアリング成分は相性が悪く、互いに効果を減殺してしまうが、本発明の消臭ペアリング剤は、特定のＨＬＢ値を持つ可溶化剤を含有させることにより、消臭効果とペアリング効果が減殺されることなく発揮される。 Since the deodorant pairing agent of the present invention contains both the deodorant component and the pairing component, when the concentration of the malodorous substance is high, the malodorous substance can be removed to reduce the concentration. Furthermore, the interaction between the trace amount of malodorous substance that could not be completely removed and the pairing component can convert the remaining trace amount of malodorous substance into a good scent and give a refreshing feeling. Normally, the deodorant component and the pairing component are incompatible with each other and their effects are diminished, but the deodorant pairing agent of the present invention deodorizes by containing a solubilizer having a specific HLB value. The effect and pairing effect are exhibited without being diminished.
以下に、実施例及び比較例を挙げて本発明を更に具体的に説明するが、本発明は、その要旨を超えない限りこれらの実施例に限定されるものではない。 Hereinafter, the present invention will be described in more detail with reference to Examples and Comparative Examples, but the present invention is not limited to these Examples as long as the gist thereof is not exceeded.
調製例１（ペアリング成分を含有する原液の調製）
下記表１及び表２に示す組成の消臭ペアリング成分を含有する原液１ないし原液９の調製を試みた。
Preparation Example 1 (Preparation of undiluted solution containing pairing component)
An attempt was made to prepare a stock solution 1 to a stock solution 9 containing a deodorant pairing component having the compositions shown in Tables 1 and 2 below.
表１の「可溶化剤」の詳細については、下記の通りであり、何れも、日光ケミカルズ株式会社から市販されている。 The details of the "solubilizer" in Table 1 are as follows, and all of them are commercially available from Nikko Chemicals Co., Ltd.
［ＮＩＫＫＯＬ ＴＩ−１０Ｖ］
化粧品表示名称：イソステアリン酸ＰＥＧ−２０ソルビタン
医薬部外品表示名称：イソステアリン酸ポリオキシエチレンソルビタン（２０Ｅ．０．）
[NIKKOL TI-10V]
Cosmetics Labeling name: PEG-20 sorbitan isostearate Quasi-drug Labeling name: Polyoxyethylene sorbitan isostearate (20E.0.)
［ＮＩＫＫＯＬ ＨＣＯ−４０］
化粧品表示名称：ＰＥＧ−４０水添ヒマシ油
医薬部外品表示名称：ポリオキシエチレン硬化ヒマシ油
[NIKKOL HCO-40]
Cosmetics Labeling name: PEG-40 Hydrogenated castor oil Quasi-drug Labeling name: Polyoxyethylene hydrogenated castor oil
［ＮＩＫＫＯＬ ＨＣＯ−６０］
化粧品表示名称：ＰＥＧ−６０水添ヒマシ油
医薬部外品表示名称：ポリオキシエチレン硬化ヒマシ油
[NIKKOL HCO-60]
Cosmetics Labeling name: PEG-60 Hydrogenated castor oil Quasi-drug Labeling name: Polyoxyethylene hydrogenated castor oil
［ＮＩＫＫＯＬ ＢＰＳ−２０］
化粧品表示名称：ＰＥＧ−２０フィトステロール
医薬部外品表示名称：ポリオキシエチレンフィトステロール
[NIKKOL BPS-20]
Cosmetic label name: PEG-20 phytosterol Quasi-drug label name: Polyoxyethylene phytosterol
［ＮＩＫＫＯＬ ＴＳ−１０６Ｖ］
化粧品表示名称：ステアリン酸ＰＥＧ−６ソルビタン
医薬部外品表示名称：モノステアリン酸ポリオキシエチレンソルビタン
[NIKKOL TS-106V]
Cosmetics Labeling name: PEG-6 sorbitan stearate Pharmaceutical non-medicinal product Labeling name: Polyoxyethylene sorbitan monostearate
［ＮＩＫＫＯＬ ＳＧ−Ｃ４２０］
化粧品表示名称：ＰＰＧ−４セテス−２０
医薬部外品表示名称：ポリオキシエチレンポリオキシプロピレンセチルエーテル
（２０Ｅ．０．）（４Ｐ．０．）
[NIKKOL SG-C420]
Cosmetic label name: PPG-4 Setes-20
Quasi-drug Labeling name: Polyoxyethylene Polyoxypropylene cetyl ether
(20E.0.) (4P.0.)
原液１〜４、６〜９は、均一な透明溶液となった。これに対して、「原液５」の各成分は相溶せず、透明溶液を得ることはできなかった。特に、可溶化剤とイオン交換水を混合すると、可溶化剤が固化してしまった。 The stock solutions 1 to 4 and 6 to 9 became a uniform transparent solution. On the other hand, each component of "stock solution 5" was incompatible with each other, and a transparent solution could not be obtained. In particular, when the solubilizer and ion-exchanged water were mixed, the solubilizer solidified.
また、調製した透明溶液を、常温で１０日間保存したところ、原液１〜４、６、８〜９には、特に変化は見られず、臭気強度にも変化はなかった。これに対して、プロピレングリコールの含有量が少ない原液７は、やや濁りを生じており、臭気強度も低下していた。 When the prepared transparent solution was stored at room temperature for 10 days, no particular change was observed in the stock solutions 1-4, 6, 8-9, and the odor intensity did not change. On the other hand, the undiluted solution 7 having a low content of propylene glycol was slightly turbid and had a reduced odor intensity.
調製例２（消臭成分を含有する原液の調製）
酸化亜鉛１質量部、グリシン４質量部、イオン交換水９５質量部を混合して、７０℃で３０分間加熱撹拌することにより、消臭成分を含有する溶液（以下、「消臭成分原液」という。）を得た。
Preparation Example 2 (Preparation of undiluted solution containing deodorant component)
A solution containing a deodorant component (hereinafter referred to as "deodorant component stock solution") is obtained by mixing 1 part by mass of zinc oxide, 4 parts by mass of glycine, and 95 parts by mass of ion-exchanged water and heating and stirring at 70 ° C. for 30 minutes. .) Was obtained.
調製例３（消臭ペアリング剤溶液の調製）
以下に示す組成の消臭ペアリング剤のサンプル溶液１を調製した。
Preparation Example 3 (Preparation of deodorant pairing agent solution)
A sample solution 1 of a deodorant pairing agent having the composition shown below was prepared.
・原液１ ２質量部
・消臭成分原液 ３０質量部
・防腐剤 ０．１質量部
・イオン交換水 ６７．９質量部
・ 1 2 parts by mass of undiluted solution ・ 30 parts by mass of undiluted solution of deodorant component ・ 0.1 part by mass of preservative ・ 67.9 parts by mass of ion-exchanged water
また、上記組成における「原液１」に代えて、「原液ｎ」を使用して、「サンプル溶液ｎ」を調製した（ｎ＝２〜４、６、８〜９）。 Further, instead of the "stock solution 1" in the above composition, the "stock solution n" was used to prepare a "sample solution n" (n = 2-4, 6, 8-9).
消臭試験例１（硫化水素）
ガス注入口、圧力調整口、検知管測定口及び予備口を備えた容量３Ｌのガラス製セパラブルフラスコ（以下、単に「フラスコ」という。）を用意し、硫化水素をフラスコ内にシリンジで注入し、エアポンプを使用して、フラスコ内を撹拌した。１０分間静置後、フラスコ内の硫化水素の初期濃度を検知管にて測定した。
Deodorant Test Example 1 (Hydrogen Sulfide)
Prepare a glass separable flask with a capacity of 3 L (hereinafter, simply referred to as “flask”) equipped with a gas injection port, a pressure adjustment port, a detector tube measurement port, and a spare port, and inject hydrogen sulfide into the flask with a syringe. , The inside of the flask was stirred using an air pump. After standing for 10 minutes, the initial concentration of hydrogen sulfide in the flask was measured with a detector tube.
次いで、サンプル溶液１を水で３％に希釈した溶液を３ｍＬ、フラスコの中に注入し、消臭試験を開始した。
所定時間経過時点におけるフラスコ内の硫化水素の濃度を測定し、下記式（１）により、消臭率（％）を算出した。
Then, 3 mL of a solution obtained by diluting the sample solution 1 with water to 3% was poured into a flask, and the deodorization test was started.
The concentration of hydrogen sulfide in the flask was measured after a lapse of a predetermined time, and the deodorizing rate (%) was calculated by the following formula (1).
なお、検知管の測定限界濃度は１ｐｐｍである。１ｐｐｍ未満の微量なガスは、検知管では検出することができない。 The measurement limit concentration of the detector tube is 1 ppm. A trace amount of gas less than 1 ppm cannot be detected by the detector tube.
また、サンプル溶液１の代わりに、サンプル溶液８、サンプル溶液９を使用して、同様の測定をした。 Further, the same measurement was performed using the sample solution 8 and the sample solution 9 instead of the sample solution 1.
更に、サンプル溶液１の代わりに、消臭成分原液を使用して同様の測定をした。消臭成分原液を使用する際には、酸化亜鉛やグリシンの含有量がサンプル溶液１と同じになるように、水で１％に希釈して使用した。 Further, the same measurement was performed using the deodorant component stock solution instead of the sample solution 1. When the deodorant component stock solution was used, it was diluted with water to 1% so that the content of zinc oxide and glycine was the same as that of the sample solution 1.
硫化水素消臭試験の結果を表３に示す。 The results of the hydrogen sulfide deodorization test are shown in Table 3.
何れのサンプル溶液を使用した場合も、ペアリング成分を添加したことによる消臭機能の減殺は無く、硫化水素に対して十分な消臭性能を発揮した。 When any of the sample solutions was used, the deodorizing function was not diminished by the addition of the pairing component, and sufficient deodorizing performance was exhibited for hydrogen sulfide.
消臭試験例２（酢酸）
悪臭ガスとして、硫化水素の代わりに酢酸を使用した以外は、消臭試験例１と同様にした。結果を表４に示す。
Deodorant test example 2 (acetic acid)
The same procedure as in Deodorant Test Example 1 was carried out except that acetic acid was used instead of hydrogen sulfide as the malodorous gas. The results are shown in Table 4.
何れのサンプル溶液を使用した場合も、ペアリング成分を添加したことによる消臭機能の減殺は無く、酢酸に対して十分な消臭性能を発揮した。 When any of the sample solutions was used, the deodorizing function was not diminished by the addition of the pairing component, and sufficient deodorizing performance was exhibited against acetic acid.
消臭試験例３（アンモニア）
悪臭ガスとして、硫化水素の代わりにアンモニアを使用した以外は、消臭試験例１と同様にした。結果を表５に示す。
Deodorant test example 3 (ammonia)
The same procedure as in Deodorant Test Example 1 was carried out except that ammonia was used instead of hydrogen sulfide as the malodorous gas. The results are shown in Table 5.
サンプル溶液１、８、９の何れを使用した場合も、ペアリング成分を添加したことによる消臭機能の減殺は無く、アンモニアに対して十分な消臭性能を発揮した。 When any of the sample solutions 1, 8 and 9 was used, the deodorizing function was not diminished by the addition of the pairing component, and sufficient deodorizing performance was exhibited with respect to ammonia.
ペアリング試験例１（硫化水素）
消臭試験例１と同様にして、フラスコ内に硫化水素を注入し、次いで、サンプル溶液を水で希釈した溶液を注入した。検知管の示す硫化水素の濃度は減少していった。
Pairing Test Example 1 (Hydrogen Sulfide)
Hydrogen sulfide was injected into the flask in the same manner as in Deodorization Test Example 1, and then a solution obtained by diluting the sample solution with water was injected. The concentration of hydrogen sulfide indicated by the detector tube decreased.
検知管の示す濃度が０ｐｐｍとなった直後に（測定限界である１ｐｐｍ未満の硫化水素がフラスコ内に残存した状態で）、フラスコを開放し、６名の被験者に、表６に示す基準で、においの質を評価させた。 Immediately after the concentration indicated by the detector tube reached 0 ppm (with hydrogen sulfide remaining at less than 1 ppm, which is the measurement limit), the flask was opened, and 6 subjects were asked according to the criteria shown in Table 6. The quality of the odor was evaluated.
表６は、「嗅覚概論 においの評価の基礎」（公益財団法人におい・かおり環境協会）の１６１頁の図７．１．１−１の基準に基づくものである。 Table 6 is based on the criteria shown in Figure 7.1.1-1 on page 161 of "Introduction to Smell Sense: Basics of Smell Evaluation" (Odor and Kaori Environmental Association).
更に、サンプル溶液１の代わりに、サンプル溶液２〜４、６、８を使用して同様の測定をした。結果を表７及び表８に示す。 Further, the same measurement was performed using sample solutions 2 to 4, 6 and 8 instead of sample solution 1. The results are shown in Tables 7 and 8.
ＨＬＢ値の大きい可溶化剤を含有するサンプル溶液６を使用した場合、硫化水素に対するペアリング効果を発揮しなかったが、それ以外のサンプル溶液を使用した場合、ペアリング効果を発揮することが確認できた。 It was confirmed that when the sample solution 6 containing a solubilizer having a large HLB value was used, the pairing effect on hydrogen sulfide was not exhibited, but when other sample solutions were used, the pairing effect was exhibited. did it.
ペアリング試験例２（酢酸）
サンプル溶液１、８、９を使用して、悪臭ガスとして、硫化水素の代わりに酢酸を使用した以外は、ペアリング試験例１と同様にした。結果を表９に示す。
Pairing Test Example 2 (Acetic Acid)
The sample solutions 1, 8 and 9 were used in the same manner as in Pairing Test Example 1 except that acetic acid was used instead of hydrogen sulfide as the malodorous gas. The results are shown in Table 9.
ペアリング試験例３（アンモニア）
サンプル溶液８、９を使用して、悪臭ガスとして、硫化水素の代わりにアンモニアを使用した以外は、ペアリング試験例１と同様にした。結果を表１０に示す。
Pairing Test Example 3 (Ammonia)
The sample solutions 8 and 9 were used in the same manner as in Pairing Test Example 1 except that ammonia was used instead of hydrogen sulfide as the malodorous gas. The results are shown in Table 10.
ペアリング試験例４（メチルメルカプタン）
サンプル溶液１を使用して、悪臭ガスとして、硫化水素の代わりにメチルメルカプタンを使用した以外は、ペアリング試験例１と同様にした。結果を表１１に示す。
Pairing Test Example 4 (Methyl mercaptan)
The sample solution 1 was used, and the same procedure as in Pairing Test Example 1 was carried out except that methyl mercaptan was used as the malodorous gas instead of hydrogen sulfide. The results are shown in Table 11.
ペアリング試験例５（アセトアルデヒド）
サンプル溶液１を使用して、悪臭ガスとして、硫化水素の代わりにアセトアルデヒドを使用した以外は、ペアリング試験例１と同様にした。結果を表１２に示す。
Pairing Test Example 5 (Acetaldehyde)
The sample solution 1 was used, and the same procedure as in Pairing Test Example 1 was carried out except that acetaldehyde was used as the malodorous gas instead of hydrogen sulfide. The results are shown in Table 12.
本発明の消臭ペアリング剤は、悪臭の濃度自体を減少させた上で、微量に残存する悪臭を、良い香りに変換することができ、広範囲の濃度の悪臭に対して対応することができるので、下水処理場、ごみ処理場、石油化学工場等の施設や、一般家庭における悪臭の対策に広く利用されるものである。 The deodorant pairing agent of the present invention can reduce the concentration of malodor itself and convert a small amount of residual malodor into a good odor, and can cope with a wide range of malodor. Therefore, it is widely used in facilities such as sewage treatment plants, waste treatment plants, petrochemical factories, and as a countermeasure against bad odors in ordinary households.
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