JP2020509110A - エチレン−α−オレフィンコポリマー−リン酸トリアリル組成物 - Google Patents
エチレン−α−オレフィンコポリマー−リン酸トリアリル組成物 Download PDFInfo
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- JP2020509110A JP2020509110A JP2019543114A JP2019543114A JP2020509110A JP 2020509110 A JP2020509110 A JP 2020509110A JP 2019543114 A JP2019543114 A JP 2019543114A JP 2019543114 A JP2019543114 A JP 2019543114A JP 2020509110 A JP2020509110 A JP 2020509110A
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- Prior art keywords
- ethylene
- peroxide
- weight
- olefin
- bis
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- 239000000203 mixture Substances 0.000 title claims abstract description 176
- 239000004711 α-olefin Substances 0.000 title claims abstract description 150
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 145
- 239000005977 Ethylene Substances 0.000 claims abstract description 145
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims abstract description 91
- 229920001038 ethylene copolymer Polymers 0.000 claims abstract description 83
- XHGIFBQQEGRTPB-UHFFFAOYSA-N tris(prop-2-enyl) phosphate Chemical compound C=CCOP(=O)(OCC=C)OCC=C XHGIFBQQEGRTPB-UHFFFAOYSA-N 0.000 claims abstract description 71
- 229920000642 polymer Polymers 0.000 claims abstract description 41
- 239000003054 catalyst Substances 0.000 claims abstract description 37
- 238000000034 method Methods 0.000 claims abstract description 33
- 150000001451 organic peroxides Chemical class 0.000 claims abstract description 26
- 239000004020 conductor Substances 0.000 claims description 59
- 150000002978 peroxides Chemical class 0.000 claims description 56
- 229920001577 copolymer Polymers 0.000 claims description 47
- -1 isopropylcumyl t-butyl peroxide Chemical compound 0.000 claims description 44
- 150000001993 dienes Chemical class 0.000 claims description 34
- 229920001897 terpolymer Polymers 0.000 claims description 25
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 24
- 238000000113 differential scanning calorimetry Methods 0.000 claims description 18
- 229920002943 EPDM rubber Polymers 0.000 claims description 16
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 16
- OJOWICOBYCXEKR-APPZFPTMSA-N (1S,4R)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical group CC=C1C[C@@H]2C[C@@H]1C=C2 OJOWICOBYCXEKR-APPZFPTMSA-N 0.000 claims description 13
- 150000001875 compounds Chemical class 0.000 claims description 13
- 150000001412 amines Chemical class 0.000 claims description 12
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 10
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 10
- 230000009477 glass transition Effects 0.000 claims description 10
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 10
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 9
- 239000003963 antioxidant agent Substances 0.000 claims description 9
- 239000003063 flame retardant Substances 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 9
- 239000003381 stabilizer Substances 0.000 claims description 9
- 230000003078 antioxidant effect Effects 0.000 claims description 8
- 239000012530 fluid Substances 0.000 claims description 8
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 8
- 229920005638 polyethylene monopolymer Polymers 0.000 claims description 8
- MQWCQFCZUNBTCM-UHFFFAOYSA-N 2-tert-butyl-6-(3-tert-butyl-2-hydroxy-5-methylphenyl)sulfanyl-4-methylphenol Chemical compound CC(C)(C)C1=CC(C)=CC(SC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O MQWCQFCZUNBTCM-UHFFFAOYSA-N 0.000 claims description 7
- 230000005611 electricity Effects 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 7
- 239000000155 melt Substances 0.000 claims description 7
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical group C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 claims description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
- 239000000945 filler Substances 0.000 claims description 6
- HIACAHMKXQESOV-UHFFFAOYSA-N 1,2-bis(prop-1-en-2-yl)benzene Chemical compound CC(=C)C1=CC=CC=C1C(C)=C HIACAHMKXQESOV-UHFFFAOYSA-N 0.000 claims description 5
- 125000003118 aryl group Chemical group 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 229920001223 polyethylene glycol Polymers 0.000 claims description 5
- FZYCEURIEDTWNS-UHFFFAOYSA-N prop-1-en-2-ylbenzene Chemical compound CC(=C)C1=CC=CC=C1.CC(=C)C1=CC=CC=C1 FZYCEURIEDTWNS-UHFFFAOYSA-N 0.000 claims description 5
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- 125000006736 (C6-C20) aryl group Chemical group 0.000 claims description 4
- NALFRYPTRXKZPN-UHFFFAOYSA-N 1,1-bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane Chemical compound CC1CC(C)(C)CC(OOC(C)(C)C)(OOC(C)(C)C)C1 NALFRYPTRXKZPN-UHFFFAOYSA-N 0.000 claims description 4
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 claims description 4
- JJRDRFZYKKFYMO-UHFFFAOYSA-N 2-methyl-2-(2-methylbutan-2-ylperoxy)butane Chemical compound CCC(C)(C)OOC(C)(C)CC JJRDRFZYKKFYMO-UHFFFAOYSA-N 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- 239000003086 colorant Substances 0.000 claims description 4
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical group CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims description 4
- PWWSSIYVTQUJQQ-UHFFFAOYSA-N distearyl thiodipropionate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCCCCCC PWWSSIYVTQUJQQ-UHFFFAOYSA-N 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 150000002903 organophosphorus compounds Chemical class 0.000 claims description 4
- 229920005629 polypropylene homopolymer Polymers 0.000 claims description 4
- 229930195734 saturated hydrocarbon Natural products 0.000 claims description 4
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 claims description 3
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 claims description 3
- XOUQAVYLRNOXDO-UHFFFAOYSA-N 2-tert-butyl-5-methylphenol Chemical compound CC1=CC=C(C(C)(C)C)C(O)=C1 XOUQAVYLRNOXDO-UHFFFAOYSA-N 0.000 claims description 3
- BIISIZOQPWZPPS-UHFFFAOYSA-N 2-tert-butylperoxypropan-2-ylbenzene Chemical compound CC(C)(C)OOC(C)(C)C1=CC=CC=C1 BIISIZOQPWZPPS-UHFFFAOYSA-N 0.000 claims description 3
- UJZVNZUDZDRBSO-UHFFFAOYSA-N 6-tert-butyl-6-(1-tert-butyl-6-hydroxy-4-methylcyclohexa-2,4-dien-1-yl)sulfanyl-3-methylcyclohexa-2,4-dien-1-ol Chemical compound C1=CC(C)=CC(O)C1(C(C)(C)C)SC1(C(C)(C)C)C(O)C=C(C)C=C1 UJZVNZUDZDRBSO-UHFFFAOYSA-N 0.000 claims description 3
- 239000002656 Distearyl thiodipropionate Substances 0.000 claims description 3
- 235000019305 distearyl thiodipropionate Nutrition 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical compound [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 claims description 3
- 239000002516 radical scavenger Substances 0.000 claims description 3
- ODBCKCWTWALFKM-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhex-3-yne Chemical compound CC(C)(C)OOC(C)(C)C#CC(C)(C)OOC(C)(C)C ODBCKCWTWALFKM-UHFFFAOYSA-N 0.000 claims description 2
- WPMYUUITDBHVQZ-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoic acid Chemical compound CC(C)(C)C1=CC(CCC(O)=O)=CC(C(C)(C)C)=C1O WPMYUUITDBHVQZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 2
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 2
- 239000007983 Tris buffer Substances 0.000 claims description 2
- XSHJLFOMGJTADT-UHFFFAOYSA-N [4-methyl-2-(4-methyl-2-phenylpentan-2-yl)peroxypentan-2-yl]benzene Chemical compound C=1C=CC=CC=1C(C)(CC(C)C)OOC(C)(CC(C)C)C1=CC=CC=C1 XSHJLFOMGJTADT-UHFFFAOYSA-N 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 125000003368 amide group Chemical group 0.000 claims description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 2
- BXIQXYOPGBXIEM-UHFFFAOYSA-N butyl 4,4-bis(tert-butylperoxy)pentanoate Chemical compound CCCCOC(=O)CCC(C)(OOC(C)(C)C)OOC(C)(C)C BXIQXYOPGBXIEM-UHFFFAOYSA-N 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 2
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 claims description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
- ZTWTYVWXUKTLCP-UHFFFAOYSA-N vinylphosphonic acid Chemical compound OP(O)(=O)C=C ZTWTYVWXUKTLCP-UHFFFAOYSA-N 0.000 claims description 2
- DDYHLQYSGDGSED-UHFFFAOYSA-N 2-dimethoxyphosphorylpropanamide Chemical compound COP(=O)(OC)C(C)C(N)=O DDYHLQYSGDGSED-UHFFFAOYSA-N 0.000 claims 1
- 241001441571 Hiodontidae Species 0.000 claims 1
- 229910019142 PO4 Inorganic materials 0.000 claims 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- 239000000047 product Substances 0.000 description 42
- 239000010410 layer Substances 0.000 description 38
- 238000000576 coating method Methods 0.000 description 26
- 239000000178 monomer Substances 0.000 description 25
- 230000000052 comparative effect Effects 0.000 description 24
- 229920000098 polyolefin Polymers 0.000 description 23
- 238000007906 compression Methods 0.000 description 18
- 230000006835 compression Effects 0.000 description 18
- 239000011248 coating agent Substances 0.000 description 16
- 238000012360 testing method Methods 0.000 description 16
- 239000000654 additive Substances 0.000 description 15
- 229910052751 metal Inorganic materials 0.000 description 13
- 239000002184 metal Substances 0.000 description 13
- 239000013307 optical fiber Substances 0.000 description 13
- 230000005540 biological transmission Effects 0.000 description 12
- 239000008188 pellet Substances 0.000 description 11
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 9
- 238000009472 formulation Methods 0.000 description 9
- 230000001590 oxidative effect Effects 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 9
- 229910000077 silane Inorganic materials 0.000 description 9
- 238000010998 test method Methods 0.000 description 9
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 8
- 239000004596 additive masterbatch Substances 0.000 description 8
- 150000001336 alkenes Chemical class 0.000 description 8
- 238000004132 cross linking Methods 0.000 description 8
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 8
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 7
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- 150000003254 radicals Chemical class 0.000 description 7
- 238000007655 standard test method Methods 0.000 description 7
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 6
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
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- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 5
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
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- 239000011574 phosphorus Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- ZOKCNEIWFQCSCM-UHFFFAOYSA-N (2-methyl-4-phenylpent-4-en-2-yl)benzene Chemical compound C=1C=CC=CC=1C(C)(C)CC(=C)C1=CC=CC=C1 ZOKCNEIWFQCSCM-UHFFFAOYSA-N 0.000 description 3
- INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
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- XYXJKPCGSGVSBO-UHFFFAOYSA-N 1,3,5-tris[(4-tert-butyl-3-hydroxy-2,6-dimethylphenyl)methyl]-1,3,5-triazinane-2,4,6-trione Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C)=C1CN1C(=O)N(CC=2C(=C(O)C(=CC=2C)C(C)(C)C)C)C(=O)N(CC=2C(=C(O)C(=CC=2C)C(C)(C)C)C)C1=O XYXJKPCGSGVSBO-UHFFFAOYSA-N 0.000 description 2
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- UJAWGGOCYUPCPS-UHFFFAOYSA-N 4-(2-phenylpropan-2-yl)-n-[4-(2-phenylpropan-2-yl)phenyl]aniline Chemical compound C=1C=C(NC=2C=CC(=CC=2)C(C)(C)C=2C=CC=CC=2)C=CC=1C(C)(C)C1=CC=CC=C1 UJAWGGOCYUPCPS-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- WTQBISBWKRKLIJ-UHFFFAOYSA-N 5-methylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C)CC1C=C2 WTQBISBWKRKLIJ-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
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Classifications
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K5/005—Stabilisers against oxidation, heat, light, ozone
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K5/3435—Piperidines
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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Abstract
Description
Claims (15)
- 過酸化物硬化性エチレンコポリマー組成物であって、54.00〜99.00重量パーセント(重量%)の(A)架橋性エチレン/α−オレフィンコポリマーであって、有用な分子触媒の存在下で、エチレンとα−オレフィンコモノマー、ならびに任意選択的に非共役ジエンおよび第2のα−オレフィンから選択される別のコモノマーとを共重合させることを含むプロセスによって製造され、前記(A)架橋性エチレン/α−オレフィンコポリマーは、特性(a)〜(d)のうちの少なくとも1つによって特徴付けられる:(a1)ASTM D790−15e2に従って測定される>0〜6,500psi(>0〜45MPa)の曲げ弾性率(2%割線)および/または(a2)ASTM D792に従って測定される1立方センチメートル当たり0.850〜0.890グラム(g/cm3)の密度、(b)ASTM 3418−15に従って示差走査熱量測定(DSC)により測定される−130℃〜−20℃のガラス転移温度(Tg)、(c)ASTM D1238−04に従って測定される毎分0.5デシグラム(dg/分)〜50dg/分のメルトインデックス(190℃、2.16キログラム(kg)、「I2」)、ならびに(d)1分間の予熱時間および4分間のローター作動時間で、ASTM D1646−15に従って測定される15〜170のムーニー粘度(125℃でML1+4)、架橋性エチレン/α−オレフィンコポリマーと、0.950〜5.00重量%の(B)リン酸トリアリル(TAP)と、0.050〜5.00重量%の(C)有機過酸化物と、0.00〜40重量%の(D)エチレン/不飽和カルボン酸エステルコポリマー、ポリエチレンホモポリマー、非(分子触媒)形成エチレン/α−オレフィンコポリマー、およびプロピレン系ポリマーから選択される補助ポリマーと、を含み、但し、成分(A)および(D)の総重量は80.00〜99.00重量%であるものとし、全ての重量%は、前記過酸化物硬化性エチレンコポリマー組成物の総重量に基づいており、前記過酸化物硬化性エチレンコポリマー組成物の総重量は100.0重量%である、組成物。
- 制約(i)〜(ii)のいずれか1つによってさらに説明される、請求項1に記載の組成物:(i)前記α−オレフィンコモノマーは(C3−C20)α−オレフィンであり、前記(A)架橋性エチレン/α−オレフィンコポリマーは、特性(a)〜(c)のうちの少なくとも1つによって特徴付けられるエチレン−(C3−C20)α−オレフィンコポリマー(例えば、バイポリマー(別のコモノマーなしで共重合する)もしくはターポリマー(第2のα−オレフィンコモノマーと共重合する))である:(a1)ASTM D790−15e2に従って測定される>0〜6,500psi(>0〜45MPa)の曲げ弾性率(2%割線)および/または(a2)ASTM D792に従って測定される1立方センチメートル当たり0.850〜0.890グラム(g/cm3)の密度、(b)ASTM 3418−15に従って示差走査熱量測定(DSC)により測定される−130℃〜−20℃のガラス転移温度(Tg)、ならびに(c)ASTM D1238−04に従って測定される毎分0.5デシグラム(dg/分)〜50dg/分のメルトインデックス(190℃、2.16キログラム(kg)、「I2」)、あるいは(ii)前記α−オレフィンコモノマーはプロピレンであり、別のコモノマーが使用され、それは非共役(C6−C20)ジエンであり、前記(A)架橋性エチレン/α−オレフィンコポリマーは、特性(a)〜(d)のうちの少なくとも1つによって特徴付けられるエチレン−プロピレン−(C6−C20)ジエンコポリマー(例えばターポリマー)(EPDM)である:(a1)ASTM D790−15e2に従って測定される>0〜6,500psi(>0〜45MPa)の曲げ弾性率(2%割線)および/または(a2)ASTM D792に従って測定される0.850〜0.890g/cm3の密度、(b)ASTM 3418−15に従って示差走査熱量測定(DSC)により測定される−130℃〜−20℃のガラス転移温度(Tg)、(c)ASTM D1238−04に従って測定される毎分0.1デシグラム(dg/分)〜50dg/分のメルトインデックス(190℃、2.16キログラム(kg)、「I2」)、ならびに(d)1分間の予熱時間および4分間のローター作動時間で、ASTM D1646−15に従って測定される15〜170のムーニー粘度(125℃でML1+4)。
- 制約(i)〜(iv)のいずれか1つによってさらに説明される、請求項1または2に記載の組成物:(i)前記(A)架橋性エチレン/α−オレフィンコポリマーは前記過酸化物硬化性エチレンコポリマー組成物の90〜99重量%であり、前記過酸化物硬化性エチレンコポリマー組成物は前記(D)補助ポリマーを含まない(欠く)、(ii)前記(A)架橋性エチレン/α−オレフィンコポリマーは前記過酸化物硬化性エチレンコポリマー組成物の58.00〜90.00重量%であり、前記(D)補助ポリマーは前記過酸化物硬化性エチレンコポリマー組成物の40.0〜1.0重量%である、(iii)前記(D)補助ポリマーはポリプロピレンホモポリマーである、ならびに(iv):(ii)および(iii)の両方。
- 制約(i)〜(iv)のいずれか1つによってさらに説明される、請求項1〜3のいずれか一項に記載の組成物:(i)前記(B)リン酸トリアリル(TAP)は1.01〜4.54重量%である、(ii)前記(B)リン酸トリアリル(TAP)は1.05〜4.00重量%である、(iii)前記(B)リン酸トリアリル(TAP)は1.10〜3.00重量%である、(iv)前記(B)リン酸トリアリル(TAP)は1.50〜4.600重量%である(全ての重量%は、前記過酸化物硬化性エチレンコポリマー組成物の総重量に基づく)。
- 制約(i)〜(v)のいずれか1つによってさらに説明される、請求項1〜4のいずれか一項に記載の組成物:(i)前記(C)有機過酸化物は、前記過酸化物硬化性エチレンコポリマー組成物の総重量に基づいて1.0〜4.0重量%である、(ii)前記(C)有機過酸化物は式RO−O−O−ROの化合物であり、式中、各ROは独立して(C1−C20)アルキル基または(C6−C20)アリール基である、(iii)前記(C)有機過酸化物は、ビス(1,1−ジメチルエチル)過酸化物、ビス(1,1−ジメチルプロピル)ペルオキシド、2,5−ジメチル−2,5−ビス(1,1−ジメチルエチルペルオキシ)ヘキサン、2,5−ジメチル−2,5−ビス(1,1−ジメチルエチルペルオキシ)ヘキシン、4,4−ビス(1,1−ジメチルエチルペルオキシ)吉草酸、ブチルエステル、1,1−ビス(1,1−ジメチルエチルペルオキシ)−3,3,5−トリメチルシクロヘキサン、過酸化ベンゾイル、tert−ブチルペルオキシベンゾエート、ジ−tert−アミルペルオキシド(「DTAP」)、ビス(α−t−ブチル−ペルオキシイソプロピル)ベンゼン(「BIPB」)、イソプロピルクミルt−ブチルペルオキシド、t−ブチルクミルペルオキシド、ジ−t−ブチルペルオキシド、2,5−ビス(t−ブチルペルオキシ)−2,5−ジメチルヘキサン、2,5−ビス(t−ブチルペルオキシ)−2,5−ジメチルヘキシン−3,1,1−ビス(t−ブチルペルオキシ)−3,3,5−トリメチルシクロヘキサン、イソプロピルクミルクミルペルオキシド、ブチル4,4−ジ(tert−ブチルペルオキシ)バレラート、またはジ(イソプロピルクミル)ペルオキシド、またはジクミルペルオキシドである、(iv)前記(C)有機過酸化物はジクミルペルオキシドである、および(v):(i)と(ii)〜(iv)のいずれか1つとの組み合わせ。
- 制約(i)または(ii)によってさらに説明される、請求項1〜5のいずれか一項に記載の組成物:(i)成分(A)〜(D)の合計量はその100重量%である、または(ii)成分(A)〜(D)の前記合計量は100重量%未満であり、前記過酸化物硬化性エチレンコポリマー組成物は、成分(E)〜(O)のうちの少なくとも1つをさらに含む:(E)酸化防止剤、(F)TAPではない助剤、(G)ポリジメチルシロキサン(PDMS)流体、(H)ヒンダードアミン安定剤、(I)難燃剤、(J)トリー遅延剤、(K)着色剤、(L)液体芳香族または飽和炭化水素(LASH)、(M)メチルラジカル捕捉剤、(N)スコーチ遅延剤、および(O)充填剤。
- 制約(i)〜(vi)のいずれか1つによってさらに説明される、請求項6に記載の組成物:(i)前記過酸化物硬化性エチレンコポリマー組成物は成分(E)酸化防止剤をさらに含み、前記(E)酸化防止剤は、ビス(4−(1))−メチル−1−(フェニルエチル)フェニル)アミン、2,2’−メチレン−ビス(4−メチル−6−t−ブチルフェノール)、2,2’−チオビス(2−t−ブチル−5−メチルフェノール;2,2’−チオビス(6−t−ブチル−4−メチルフェノール);トリス[(4−tert−ブチル−3−ヒドロキシ−2,6−(ジメチルフェニル)メチル]−1,3,5−トリアジン−2,4,6−トリオン;ペンタエリスリトールテトラキス(3−(3,5−ビス(1,1−ジメチルエチル)−4−ヒドロキシフェニル)プロピオネート);3,5−ビス(1,1−ジメチルエチル)−4−ヒドロキシベンゼンプロパン酸2,2’−チオジエタンジイルエステル;またはジステアリルチオジプロピオネートである、(ii)前記過酸化物硬化性エチレンコポリマー組成物は、成分(F)TAPではない助剤をさらに含み、前記(F)TAPではない助剤は、トリアリルイソシアヌレート;トリアリルリン酸トリアミド、N−ヒドロキシメチル−3−ジメチルホスホノプロピオンアミド、2−エチル−メタクリレートリン酸、ヒドロキシルエチルメタクリレートのリン酸エステル、またはビニルホスホン酸等の不飽和有機リン化合物;またはα−メチルスチレンダイマー(AMSD)もしくはジイソプロペニルベンゼン(DIPB)である、(iii)前記過酸化物硬化性エチレンコポリマー組成物は、成分(H)ヒンダードアミン安定剤をさらに含み、前記(H)ヒンダードアミン安定剤は、1,3,5−トリアジン−2,4,6−トリアミン、N2,N2’’−1,2−エタンジイルビス[N2−[3−[[4,6−ビス[ブチル(1,2,2,6,6−ペンタメチル−4−ピペリジニル)アミノ]−1,3,5−トリアジン−2−イル]アミノ]プロピル]−N’、N’’−ジブチル−N’、N’’−ビス(1,2,2,6,6−ペンタメチル−4−ピペリジニル)−である、(iv)前記過酸化物硬化性エチレンコポリマー組成物は、成分(J)トリー遅延剤をさらに含み、前記(J)トリー遅延剤は、10,000〜30,000グラム/モルの数平均分子量(Mn)を有するポリ(エチレングリコール)(PEG)である、(v)前記過酸化物硬化性エチレンコポリマー組成物は、制約(i)〜(iv)の組み合わせをさらに含む、ならびに(vi)前記過酸化物硬化性エチレンコポリマー組成物は、0.20〜0.50重量%の成分(E)((E)は2,2’−チオビス(2−t−ブチル−5−メチルフェノール)である)、0.30〜0.50重量%の成分(F)((F)はα−メチルスチレンダイマー(AMSD)である)、0.10〜0.30重量%の構成要素(H)((H)は1,3,5−トリアジン−2,4,6−トリアミン,N2,N2’’−1,2−エタンジイルビス[N2−[3−[[4,6−ビス[ブチル(1,2,2,6,6−ペンタメチル−4−ピペリジニル)アミノ]−1,3,5−トリアジン−2−イル]アミノ]プロピル]−N’,N’’−ジブチル−N’,N’’−ビス(1,2,2,6,6−ペンタメチル−4−ピペリジニル)−である]、および0.40〜0.80重量%の構成要素(J)((J)は15,000〜25,000g/モルのMnを有するPEGである)をさらに含む。
- 前記コポリマー(A)はエチレン/プロピレン/ジエンターポリマーであり、前記ジエンは5−エチリデン−2−ノルボルネンである、請求項1〜7のいずれか一項に記載の組成物。
- 請求項1〜8のいずれか一項に記載の過酸化物硬化性エチレンコポリマー組成物を製造する方法であって、有効量の成分(A)〜(C)と、いずれか任意の成分(D)〜(O)とを接触させて、前記過酸化物硬化性エチレンコポリマー組成物を得ることを含む、方法。
- 前記接触させることは、前記成分(A)〜(C)およびいずれか任意の成分(D)〜(O)を内部混合すること、または前記成分(B)、(C)およびいずれか任意の成分(D)〜(O)のうちの少なくとも1つを成分(A)に浸漬することを含む、請求項9記載の方法。
- 請求項1〜8のいずれか一項に記載の過酸化物硬化性エチレンコポリマー組成物を硬化してなる生成物である、架橋エチレン/α−オレフィンコポリマー生成物。
- 前記(A)架橋性エチレン/α−オレフィンコポリマーはエチレン/プロピレン/ジエンターポリマーであり、前記ジエンは5−エチリデン−2−ノルボルネンであり、前記架橋エチレン/α−オレフィンコポリマー生成物は、オーブン内で3日間177℃で加熱した後、30%〜90%の引張伸びを有するか、またはオーブン内で7日間177℃で加熱した後、15%〜80%の引張伸びを有する、請求項11に記載の生成物。
- 請求項11または12に記載の前記生成物の成形体を含む、製造品。
- 導電性コアと、前記導電性コアを少なくとも部分的に覆う絶縁層と、を備える、被覆導体であって、前記絶縁層の少なくとも一部分が請求項11または12に記載の架橋エチレン/α−オレフィンコポリマー生成物を含む、被覆導体。
- 電気を伝導する方法であって、請求項14に記載の被覆導体の前記導電性コア全体に電圧を印加して、前記導電性コアを通る電気の流れを発生させることを含む、方法。
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