JP2020150863A - Carbonated drink - Google Patents

Carbonated drink Download PDF

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JP2020150863A
JP2020150863A JP2019053032A JP2019053032A JP2020150863A JP 2020150863 A JP2020150863 A JP 2020150863A JP 2019053032 A JP2019053032 A JP 2019053032A JP 2019053032 A JP2019053032 A JP 2019053032A JP 2020150863 A JP2020150863 A JP 2020150863A
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carbonated beverage
acidity
citric acid
citric
acid
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JP6592630B1 (en
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悟 片柳
Satoru KATAYANAGI
悟 片柳
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Asahi Soft Drinks Co Ltd
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Abstract

To provide a carbonated drink in which mellowness, bubble fineness and feeling of stimulation of carbonic acid are all favorable.SOLUTION: A carbonated drink comprises milk solids-not-fat, citric acid, and lactic acid. The content of the milk solids-not-fat relative to the carbonated drink is from 1.0 mass% to 3.0 mass% inclusive, the citric acid acidity of the carbonated drink is from 0.15% to 0.45% inclusive, the pH of the carbonated drink is from 3.2 to 4.0 inclusive, and the carbonic acid gas volume of the carbonated drink is from 2.0 gas volumes to 3.5 gas volumes inclusive.SELECTED DRAWING: None

Description

本発明は、炭酸飲料に関する。 The present invention relates to a sparkling beverage.

消費者に広く受け入れられている嗜好性飲料のひとつとして、サイダーやラムネ等の炭酸飲料が挙げられる。炭酸飲料とは、飲料中に炭酸ガスを過飽和状態で溶解させた飲料である。 One of the favorite beverages widely accepted by consumers is carbonated beverages such as cider and ramune. A sparkling beverage is a beverage in which carbon dioxide gas is dissolved in a beverage in a supersaturated state.

他方で、消費者の嗜好の多様化にともない、様々な味わいを有する炭酸飲料等へのニーズがある。このような炭酸飲料として、乳成分等が配合されたまろやかな味わいを有するものが挙げられる(例えば、特許文献1)。 On the other hand, with the diversification of consumer tastes, there is a need for carbonated beverages having various tastes. Examples of such a carbonated beverage include those having a mellow taste containing a milk component and the like (for example, Patent Document 1).

特開2014−183771号公報Japanese Unexamined Patent Publication No. 2014-183771

しかし、炭酸飲料特有の味わい(泡のきめ細やかさ、及び炭酸の刺激感)を損なわずに、より良好なまろやかさが付与された炭酸飲料に対するニーズがある。 However, there is a need for a sparkling beverage to which a better mellowness is imparted without impairing the taste (fineness of foam and stimulating feeling of carbonic acid) peculiar to the carbonated beverage.

本発明は、以上の実情に鑑みてなされたものであり、まろやかさ、泡のきめ細やかさ、及び炭酸の刺激感のいずれもが良好な炭酸飲料を提供することを目的とする。 The present invention has been made in view of the above circumstances, and an object of the present invention is to provide a sparkling beverage having good mellowness, fineness of foam, and stimulating feeling of carbonic acid.

本発明者らは、所定量の無脂乳固形分とともに、乳酸、及びクエン酸が配合された炭酸飲料において、該炭酸飲料のクエン酸酸度等を調整することで上記課題を解決できることを見出し、本発明を完成するに至った。より具体的には、本発明は、以下のようなものを提供する。 The present inventors have found that in a sparkling beverage containing lactic acid and citric acid together with a predetermined amount of non-fat milk solids, the above problem can be solved by adjusting the citric acidity and the like of the sparkling beverage. The present invention has been completed. More specifically, the present invention provides the following.

(1) 無脂乳固形分、クエン酸、及び乳酸を含む炭酸飲料であって、
前記炭酸飲料に対する前記無脂乳固形分の含量が1.0質量%以上3.0質量%以下であり、
前記炭酸飲料のクエン酸酸度が0.15%以上0.45%以下であり、
前記炭酸飲料のpHが3.2以上4.0以下であり、かつ、
前記炭酸飲料の炭酸ガスボリュームが2.0ガス容量以上3.5ガス容量以下である、
炭酸飲料。
(1) A carbonated beverage containing non-fat milk solids, citric acid, and lactic acid.
The content of the non-fat milk solid content with respect to the carbonated beverage is 1.0% by mass or more and 3.0% by mass or less.
The citric acidity of the carbonated beverage is 0.15% or more and 0.45% or less.
The pH of the carbonated beverage is 3.2 or more and 4.0 or less, and
The carbon dioxide gas volume of the carbonated beverage is 2.0 gas capacity or more and 3.5 gas capacity or less.
Carbonated drinks.

(2) 前記炭酸飲料のクエン酸酸度に占める前記クエン酸由来のクエン酸酸度の割合が20%以上である、(1)に記載の炭酸飲料。 (2) The carbonated beverage according to (1), wherein the ratio of the citric acid acidity derived from the citric acid to the citric acid acidity of the carbonated beverage is 20% or more.

(3) 前記炭酸飲料のクエン酸酸度に占める前記乳酸由来のクエン酸酸度の割合が0.5%以上である、(1)又は(2)に記載の炭酸飲料。 (3) The carbonated beverage according to (1) or (2), wherein the ratio of the citric acidity derived from lactic acid to the citric acidity of the carbonated beverage is 0.5% or more.

(4) 前記クエン酸由来のクエン酸酸度に対する、前記乳酸由来のクエン酸酸度の比が、1/199〜50/50である、(1)から(3)のいずれかに記載の炭酸飲料。 (4) The carbonated beverage according to any one of (1) to (3), wherein the ratio of the citric acidity derived from lactic acid to the citric acid acidity derived from citric acid is 1/199 to 50/50.

本発明によれば、まろやかさ、泡のきめ細やかさ、及び炭酸の刺激感のいずれもが良好な炭酸飲料が提供される。 According to the present invention, a sparkling beverage having good mellowness, fineness of foam, and a stimulating feeling of carbonic acid is provided.

以下、本発明の実施形態について説明するが、本発明はこれに特に限定されるものではない。 Hereinafter, embodiments of the present invention will be described, but the present invention is not particularly limited thereto.

<本発明の炭酸飲料>
本発明の炭酸飲料は、無脂乳固形分、クエン酸、及び乳酸を含み、炭酸飲料に対する無脂乳固形分の含量が1.0質量%以上3.0質量%以下であり、炭酸飲料のクエン酸酸度が0.15%以上0.45%以下であり、炭酸飲料のpHが3.2以上4.0以下であり、かつ、炭酸飲料の炭酸ガスボリュームが2.0ガス容量以上3.5ガス容量以下である。炭酸飲料の組成等をこのように調整することにより、まろやかさ、泡のきめ細やかさ、及び炭酸の刺激感のいずれもが良好な炭酸飲料を得ることができる。
<Sparkling beverage of the present invention>
The carbonated beverage of the present invention contains a non-fat milk solid content, citric acid, and lactic acid, and the content of the non-fat milk solid content with respect to the carbonated beverage is 1.0% by mass or more and 3.0% by mass or less. 2. The citric acidity is 0.15% or more and 0.45% or less, the pH of the sparkling beverage is 3.2 or more and 4.0 or less, and the carbonic acid gas volume of the sparkling beverage is 2.0 gas capacity or more. 5 Gas capacity or less. By adjusting the composition of the carbonated beverage in this way, it is possible to obtain a carbonated beverage having good mellowness, fineness of foam, and a stimulating feeling of carbonic acid.

以下、本発明の炭酸飲料の構成について詳述する。 Hereinafter, the composition of the carbonated beverage of the present invention will be described in detail.

(無脂乳固形分)
「無脂乳固形分」とは、乳の成分のうち水分及び乳脂肪分を除いた成分であり、蛋白質、乳糖、及び無機質等により構成される。本発明における無脂乳固形分は、炭酸飲料に乳由来のまろやかさを付与する成分である。
(Non-fat milk solids)
The "non-fat milk solid content" is a component of milk excluding water and milk fat, and is composed of protein, lactose, an inorganic substance, and the like. The non-fat milk solid content in the present invention is a component that imparts milk-derived mellowness to a carbonated beverage.

本発明の炭酸飲料には、炭酸飲料に対して、1.0質量%以上3.0質量%以下という比較的多量の無脂乳固形分が配合される。 The carbonated beverage of the present invention contains a relatively large amount of non-fat milk solids of 1.0% by mass or more and 3.0% by mass or less with respect to the carbonated beverage.

飲料における無脂乳固形分量は、例えば、原材料として使用される乳の形態や量を調整することで調整できる。また、飲料中の無脂乳固形分量は、例えば、製造に用いられる原材料に基づく算出や、ケルダール法等により特定することができる。 The amount of non-fat milk solids in a beverage can be adjusted, for example, by adjusting the form and amount of milk used as a raw material. In addition, the amount of non-fat milk solids in the beverage can be specified, for example, by calculation based on the raw materials used for production, the Kjeldahl method, or the like.

無脂乳固形分は炭酸飲料にまろやかさを付与できる一方、炭酸飲料特有の味わい(泡のきめ細やかさ、及び炭酸の刺激感)を損ないやすい成分である。しかし、本発明者の検討の結果、上記量の無脂乳固形分とともに、後述する乳酸、及びクエン酸を配合し、かつ、炭酸飲料のクエン酸酸度、pH及びガス容量が所定範囲になるように調整することで、炭酸飲料特有の味わい(泡のきめ細やかさ、及び炭酸の刺激感)が損なわれることを抑制しつつ、良好なまろやかさを炭酸飲料に付与できることが見出された。 The non-fat milk solid content can impart mellowness to the carbonated beverage, but is a component that easily impairs the taste (fineness of foam and stimulating feeling of carbonic acid) peculiar to the carbonated beverage. However, as a result of the study by the present inventor, the above amount of non-fat milk solid content is blended with lactic acid and citric acid, which will be described later, and the citric acid acidity, pH and gas capacity of the carbonated beverage are within a predetermined range. It was found that by adjusting the pH to, it is possible to impart good mellowness to the sparkling beverage while suppressing the deterioration of the taste (fineness of foam and stimulus of carbonic acid) peculiar to the carbonated beverage.

無脂乳固形分の含量の下限は、炭酸飲料に十分なまろやかさを付与する観点から、炭酸飲料に対して、好ましくは1.2質量%超、より好ましくは1.4質量%以上である。無脂乳固形分の含量の上限は、炭酸飲料特有の味わいを損ないにくいという観点から、炭酸飲料に対して、好ましくは2.5質量%以下、より好ましくは2.0質量%以下である。 The lower limit of the content of the non-fat milk solid content is preferably more than 1.2% by mass, more preferably 1.4% by mass or more with respect to the carbonated beverage from the viewpoint of imparting sufficient mellowness to the carbonated beverage. .. The upper limit of the content of the non-fat milk solid content is preferably 2.5% by mass or less, more preferably 2.0% by mass or less, based on the carbonated beverage, from the viewpoint of not easily impairing the taste peculiar to the carbonated beverage.

原材料として用いる乳は、動物又は植物由来のいずれの乳であってもよい。例えば、牛乳、山羊乳、羊乳、馬乳等の獣乳、豆乳等の植物乳を用いることができ、牛乳が好ましい。これらの乳は、単独又は2種類以上の混合物として用いることができる。また、これらの乳を、乳酸菌や酵母、ビフィズス菌等の微生物を用いて発酵させた発酵乳として用いることもできる。 The milk used as a raw material may be either animal or plant-derived milk. For example, animal milk such as milk, goat milk, sheep milk and mare milk, and vegetable milk such as soy milk can be used, and milk is preferable. These milks can be used alone or as a mixture of two or more. Further, these milks can also be used as fermented milk fermented using microorganisms such as lactic acid bacteria, yeast and bifidobacteria.

乳の形態は特に限定されず、例えば、全脂乳、脱脂乳、乳清、乳蛋白濃縮物が挙げられ、また、粉乳や濃縮乳から還元した乳も使用でき、好ましくは脱脂粉乳を使用できる。 The form of milk is not particularly limited, and examples thereof include whole fat milk, skim milk, whey, and milk protein concentrate. Milk powder or milk reduced from concentrated milk can also be used, and skim milk powder can be preferably used. ..

(クエン酸及び乳酸)
本発明の炭酸飲料は、クエン酸及び乳酸を含む。クエン酸及び乳酸を併用することで、いずれかしか配合しない場合と比較し、すっきりとした爽やかな酸味や、ボディ感を炭酸飲料に付与できる。
(Citric acid and lactic acid)
The sparkling beverage of the present invention contains citric acid and lactic acid. By using citric acid and lactic acid in combination, a refreshing sourness and a body feeling can be given to the carbonated beverage as compared with the case where only one of them is blended.

本発明の炭酸飲料には、クエン酸及び乳酸以外の酸(リンゴ酸、酒石酸、酢酸等の有機酸、リン酸)が含まれていてもよいが、本発明の炭酸飲料は、好ましくは、クエン酸及び乳酸以外の酸を含まない。 The carbonated beverage of the present invention may contain acids other than citric acid and lactic acid (organic acids such as citric acid, tartaric acid and acetic acid, phosphoric acid), but the carbonated beverage of the present invention is preferably citric acid. Contains no acids other than acids and lactic acids.

本発明の炭酸飲料に配合されるクエン酸の形態は、通常飲食品に配合されるものであれば特に限定されず、無水クエン酸、果汁等が挙げられる。 The form of citric acid blended in the carbonated beverage of the present invention is not particularly limited as long as it is usually blended in foods and drinks, and examples thereof include anhydrous citric acid and fruit juice.

本発明の炭酸飲料に配合される乳酸の形態は、通常飲食品に配合されるものであれば特に限定されず、L体又はD体の乳酸、発酵乳等が挙げられる。 The form of lactic acid blended in the carbonated beverage of the present invention is not particularly limited as long as it is usually blended in foods and drinks, and examples thereof include L-form or D-form lactic acid and fermented milk.

(クエン酸酸度)
本発明の炭酸飲料に含まれる各酸の含量は、クエン酸酸度として特定される。本発明において「クエン酸酸度」とは、飲料中に含まれている酸の量を、クエン酸相当量として換算した値(単位:%)を意味する。クエン酸酸度は実施例に示した方法で特定される。
(Citric acid acidity)
The content of each acid contained in the sparkling beverage of the present invention is specified as the citric acidity. In the present invention, the "citric acid acidity" means a value (unit:%) obtained by converting the amount of acid contained in a beverage as an equivalent amount of citric acid. The citric acidity is specified by the method shown in the examples.

本発明の炭酸飲料のクエン酸酸度は0.15%以上0.45%以下である。炭酸飲料のクエン酸酸度をこの範囲に調整することで、無脂乳固形分が配合されても、炭酸飲料特有の味わい(泡のきめ細やかさ、及び炭酸の刺激感)が損なわれることを抑制できる。 The citric acidity of the carbonated beverage of the present invention is 0.15% or more and 0.45% or less. By adjusting the citric acidity of the sparkling beverage within this range, it is possible to prevent the taste (fineness of foam and stimulating feeling of carbonic acid) peculiar to the sparkling beverage from being impaired even if the non-fat milk solid content is blended. it can.

本発明の炭酸飲料のクエン酸酸度の下限は、まろやかさや泡のきめ細やかさを損なわずに炭酸の刺激感を高めやすいという観点から、好ましくは0.20%以上、より好ましくは0.26%以上である。本発明の炭酸飲料のクエン酸酸度の上限は、まろやかさを損ないにくいという観点から、好ましくは0.40%以下、より好ましくは0.35%以下である。 The lower limit of the citric acid acidity of the carbonated beverage of the present invention is preferably 0.20% or more, more preferably 0.26%, from the viewpoint that it is easy to enhance the stimulating feeling of carbonic acid without impairing the mellowness and fineness of foam. That is all. The upper limit of the citric acidity of the carbonated beverage of the present invention is preferably 0.40% or less, more preferably 0.35% or less, from the viewpoint of not easily impairing the mellowness.

本発明の炭酸飲料のクエン酸酸度は、配合する酸の量等を調整することで、上記範囲に調整することができる。 The citric acidity of the carbonated beverage of the present invention can be adjusted within the above range by adjusting the amount of acid to be blended.

本発明においては、炭酸飲料のクエン酸酸度において各酸に由来する酸度が占める比率を調整することで良好なまろやかさや泡のきめ細やかさ等を実現し得る。より具体的には、炭酸飲料のクエン酸酸度に占めるクエン酸由来のクエン酸酸度(以下、単に「クエン酸由来クエン酸酸度」ともいう。)を、炭酸飲料のクエン酸酸度に占める乳酸由来のクエン酸酸度(以下、単に「乳酸由来クエン酸酸度」ともいう。)と同等以上になるように調整することで、より良好なまろやかさや泡のきめ細やかさ等を実現し得る。 In the present invention, good mellowness, fineness of foam, and the like can be realized by adjusting the ratio of the acidity derived from each acid to the citric acidity of the carbonated beverage. More specifically, the citric acid-derived citric acidity (hereinafter, also simply referred to as "citric acid-derived citric acidity") in the citric acidity of the carbonated beverage is derived from lactic acid in the citric acidity of the carbonated beverage. By adjusting the citric acidity (hereinafter, also simply referred to as "lactic acid-derived citric acidity") to be equal to or higher than that of citric acid, better mellowness and fineness of bubbles can be realized.

クエン酸由来クエン酸酸度は、飲料中のクエン酸量(定量分析又は処方量から算出される。)に相当する。乳酸由来クエン酸酸度は、飲料中の乳酸量(定量分析又は処方量から算出される。)に0.71を乗じて算出される。 Citric acid-derived citric acid acidity corresponds to the amount of citric acid in a beverage (calculated from a quantitative analysis or a prescribed amount). The lactic acid-derived citric acid acidity is calculated by multiplying the amount of lactic acid in the beverage (calculated from the quantitative analysis or the prescribed amount) by 0.71.

本発明の炭酸飲料において、クエン酸由来クエン酸酸度の下限は、炭酸飲料のクエン酸酸度に対して、好ましくは20%以上、より好ましくは40%以上、さらに好ましくは60%以上、さらに好ましくは80%以上、さらに好ましくは90%以上である。クエン酸由来クエン酸酸度の上限は、炭酸飲料のクエン酸酸度に対して、好ましくは99.5%以下であり、さらに好ましくは99%以下であり、より好ましくは95%以下である。 In the carbonated beverage of the present invention, the lower limit of the citric acid acidity derived from citric acid is preferably 20% or more, more preferably 40% or more, still more preferably 60% or more, still more preferably 60% or more, based on the citric acid acidity of the carbonated beverage. It is 80% or more, more preferably 90% or more. The upper limit of the citric acid acidity derived from citric acid is preferably 99.5% or less, more preferably 99% or less, and more preferably 95% or less with respect to the citric acid acidity of the carbonated beverage.

本発明の炭酸飲料において、乳酸由来クエン酸酸度の下限は、炭酸飲料のクエン酸酸度に対して、好ましくは0.5%以上であり、より好ましくは1.0%以上であり、さらに好ましくは5.0%以上である。乳酸由来クエン酸酸度の上限は、炭酸飲料のクエン酸酸度に対して、好ましくは80%以下、より好ましくは60%以下、さらに好ましくは40%以下、さらに好ましくは20%以下、さらに好ましくは10%以下である。 In the carbonated beverage of the present invention, the lower limit of the citric acidity derived from lactic acid is preferably 0.5% or more, more preferably 1.0% or more, still more preferably 1.0% or more, based on the citric acid acidity of the carbonated beverage. It is 5.0% or more. The upper limit of the citric acidity derived from lactic acid is preferably 80% or less, more preferably 60% or less, still more preferably 40% or less, still more preferably 20% or less, still more preferably 10 with respect to the citric acid acidity of the carbonated beverage. % Or less.

クエン酸由来クエン酸酸度に対する、乳酸由来クエン酸酸度の比(乳酸由来クエン酸酸度/クエン酸由来クエン酸酸度)は、好ましくは1/199〜50/50、より好ましくは1/99〜20/80である。 The ratio of lactic acid-derived citric acid acidity to citric acid-derived citric acid acidity (lactic acid-derived citric acid acidity / citric acid-derived citric acid acidity) is preferably 1/199 to 50/50, more preferably 1/99 to 20/50. It is 80.

(pH)
本発明の炭酸飲料のpHは3.2以上4.0以下である。炭酸飲料のpHをこの範囲に調整することで、良好な炭酸の刺激感を有する炭酸飲料が得られる。pHの下限は、好ましくは3.4以上、より好ましくは3.6以上である。pHの上限は、好ましくは3.9である。
(PH)
The pH of the carbonated beverage of the present invention is 3.2 or more and 4.0 or less. By adjusting the pH of the carbonated beverage to this range, a carbonated beverage having a good carbonic acid stimulus can be obtained. The lower limit of pH is preferably 3.4 or higher, more preferably 3.6 or higher. The upper limit of pH is preferably 3.9.

炭酸飲料のpHは、実施例に示した方法で特定される。 The pH of the sparkling beverage is specified by the method shown in the Examples.

(炭酸ガス圧)
本発明の炭酸飲料の炭酸ガスボリュームは、2.0ガス容量以上3.5ガス容量以下である。炭酸飲料の炭酸ガス圧をこの範囲に調整することで、飲料に炭酸特有の味わいが十分に付与される。炭酸ガスの圧入方法は、公知の方法を用いることができる。また、炭酸飲料中のガスボリュームは公知の方法で測定することができる。例えば、市販の測定器(京都電子工業製ガスボリューム測定装置GVA−500A)を用いて測定することができる。
(Carbon dioxide pressure)
The carbon dioxide gas volume of the carbonated beverage of the present invention is 2.0 gas capacity or more and 3.5 gas capacity or less. By adjusting the carbon dioxide gas pressure of the carbonated beverage within this range, the beverage is sufficiently imparted with a taste peculiar to carbonic acid. As a method for press-fitting carbon dioxide gas, a known method can be used. In addition, the gas volume in the carbonated beverage can be measured by a known method. For example, it can be measured using a commercially available measuring device (gas volume measuring device GVA-500A manufactured by Kyoto Electronics Industry).

また、本発明において、炭酸ガスボリューム(炭酸ガス容量)とは、1気圧、20℃における、炭酸飲料全体の体積に対する、炭酸飲料に溶解している炭酸ガスの体積の比率をいう。 Further, in the present invention, the carbon dioxide gas volume (carbon dioxide gas capacity) refers to the ratio of the volume of carbon dioxide gas dissolved in the carbonated beverage to the volume of the entire carbonated beverage at 1 atm and 20 ° C.

炭酸ガスボリュームの下限は、良好な炭酸感を得られやすいという観点から、好ましくは2.4ガス容量以上である。炭酸ガスボリュームの上限は、まろやかさを損ないにくいという観点から、好ましくは3.0ガス容量以下、より好ましくは2.7ガス容量以下である。 The lower limit of the carbon dioxide gas volume is preferably 2.4 gas capacity or more from the viewpoint that a good carbon dioxide feeling can be easily obtained. The upper limit of the carbon dioxide gas volume is preferably 3.0 gas capacity or less, more preferably 2.7 gas capacity or less, from the viewpoint that the mellowness is not easily impaired.

(その他の成分)
本発明の炭酸飲料には、本発明の効果を阻害しない範囲で、一般的な飲料に通常用いられる他の原材料や添加剤を適宜配合することができる。配合量は得ようとする効果に応じて適宜設定できる。
(Other ingredients)
The carbonated beverage of the present invention may be appropriately blended with other raw materials and additives usually used in general beverages as long as the effects of the present invention are not impaired. The blending amount can be appropriately set according to the effect to be obtained.

本発明の炭酸飲料に配合し得る成分としては、下記のものが挙げられる;溶媒(水、アルコール等)、糖類(果糖ぶどう糖液糖、高果糖液糖、ショ糖、砂糖、果糖、ぶどう糖、乳糖、麦芽糖等の単糖や二糖)、糖アルコール(オリゴ糖、エリスリトールやマルチトール等)、異性化糖(果糖ぶどう糖液糖等)、高甘味度甘味料(ステビア、アスパルテーム、アセスルファムカリウム、スクラロース等)、果汁(レモン、オレンジ、ブドウ、リンゴ、モモ等)、野菜汁、乳化剤(ショ糖脂肪酸エステル、レシチン等)、増粘安定剤(大豆多糖類、ペクチン、カラギーナン、ジェランガム、キサンタンガム、グアーガム等)、酸化防止剤(トコフェロール、塩酸システイン等)、色素(カロチノイド色素、アントシアニン色素、カラメル色素、各種合成着色料等)、香料(ナリンジン等)、保存料、防腐剤、防かび剤、ビタミン類(ビタミンA、ビタミンB1、ビタミンB2、ビタミンB6、ビタミンB12、ビタミンE等)やミネラル類(カリウム、カルシウム、マグネシウム等)、食物繊維等。 Ingredients that can be blended in the carbonated beverage of the present invention include the following; solvents (water, alcohol, etc.), sugars (high fructose corn syrup, high fructose corn syrup, sucrose, sugar, fructose, glucose, lactose). , Monosaccharides and disaccharides such as maltose), sugar alcohols (oligosaccharides, erythritol, martitol, etc.), high fructose corn syrup (fructose corn syrup, etc.) ), Fruit juice (lemon, orange, grape, apple, peach, etc.), vegetable juice, emulsifier (sucrose fatty acid ester, lecithin, etc.), thickening stabilizer (soy polysaccharide, pectin, carrageenan, gellan gum, xanthan gum, guar gum, etc.) , Antioxidants (tocopherol, cysteine hydrochloride, etc.), pigments (carotinoid pigments, anthocyanin pigments, caramel pigments, various synthetic colorants, etc.), fragrances (narindine, etc.), preservatives, preservatives, fungicides, vitamins (vitamins) A, vitamin B1, vitamin B2, vitamin B6, vitamin B12, vitamin E, etc.), minerals (potassium, calcium, magnesium, etc.), dietary fiber, etc.

上記成分のうち、果糖ぶどう糖液糖、高甘味度甘味料は、炭酸飲料の風味や炭酸感を損なわずに甘味を付与しやすいため好ましい。上記成分のうち、ショ糖は、炭酸飲料に配合すると風味が重くなり、炭酸感が損なわれる可能性があるため含まれないことが好ましい。 Of the above components, high fructose corn syrup and high-sweetness sweeteners are preferable because they can easily impart sweetness without impairing the flavor and carbonation of the carbonated beverage. Of the above components, sucrose is preferably not contained because the flavor becomes heavy and the feeling of carbonation may be impaired when blended in a carbonated beverage.

<本発明の炭酸飲料の特性>
本発明の炭酸飲料は、まろやかさ、泡のきめ細やかさ、及び炭酸の刺激感がいずれも良好である。炭酸飲料のまろやかさ、泡のきめ細やかさ、及び炭酸の刺激感は、実施例に示した方法で評価される。
<Characteristics of the carbonated beverage of the present invention>
The sparkling beverage of the present invention has good mellowness, fine foam, and a stimulating feeling of carbonic acid. The mellowness of the carbonated beverage, the fineness of the foam, and the stimulating feeling of carbonic acid are evaluated by the methods shown in the examples.

本発明の炭酸飲料は、保存(例えば、55℃6日間の保存)後の香りの劣化、香味の劣化、変色(褐変、退色)が抑制され得る。 The carbonated beverage of the present invention can suppress deterioration of aroma, deterioration of flavor, and discoloration (browning, fading) after storage (for example, storage at 55 ° C. for 6 days).

<本発明の炭酸飲料の製造方法>
本発明の炭酸飲料は、飲料の製造において採用される任意の条件や方法を用いて製造できる。例えば、本発明の炭酸飲料は、上記成分を配合した水溶液を調製し、これを炭酸ガスとともに容器に充填することで得られる。したがって、本発明の炭酸飲料は、通常、容器詰め炭酸飲料として調製される。
<Manufacturing method of carbonated beverage of the present invention>
The carbonated beverage of the present invention can be produced using any conditions and methods adopted in the production of beverages. For example, the carbonated beverage of the present invention can be obtained by preparing an aqueous solution containing the above components and filling the container with carbon dioxide gas. Therefore, the sparkling beverage of the present invention is usually prepared as a packaged sparkling beverage.

以下、本発明を実施例に基づいて説明するが、本発明はこれら実施例に限定されるものではない。 Hereinafter, the present invention will be described based on examples, but the present invention is not limited to these examples.

表1及び2に示す組成を有する水溶液(200g)を調製した。得られた各水溶液を、炭酸ガスボリュームが表3及び4に示すガス容量となるように200mlの缶に充填し、容器詰め炭酸飲料を得た。なお、表1及び2の数値の単位は「質量%」である。 An aqueous solution (200 g) having the compositions shown in Tables 1 and 2 was prepared. Each of the obtained aqueous solutions was filled in a 200 ml can so that the carbon dioxide gas volume had the gas volume shown in Tables 3 and 4, and a bottled carbonated beverage was obtained. The unit of the numerical values in Tables 1 and 2 is "mass%".

得られた容器詰め炭酸飲料について以下の測定及び評価を行った。その結果を表3及び4に示す。 The following measurements and evaluations were carried out on the obtained packaged carbonated beverage. The results are shown in Tables 3 and 4.

(無脂乳固形分)
無脂乳固形分の含量は、炭酸飲料に配合した成分のうち、「脱脂粉乳」の含量に対応する。
(Non-fat milk solids)
The content of non-fat milk solids corresponds to the content of "skimmed milk powder" among the components blended in the carbonated beverage.

(pH)
飲料を20℃に調整後、pHメーターにて測定した。
(PH)
The beverage was adjusted to 20 ° C. and then measured with a pH meter.

(クエン酸酸度)
炭酸飲料全体のクエン酸酸度を以下の方法(滴定法)で測定した。
クエン酸酸度は、フェノールフタレイン指示薬と水酸化ナトリウムとを用いて、以下の手順で滴定することにより求めた。
(1)200mL三角フラスコに対して5〜15gの飲料を正確に秤量し、水を用いて50mL程度まで希釈する。
(2)希釈した前記飲料に対して1%フェノールフタレイン指示薬を数滴加えて撹拌する。
(3)三角フラスコ内の希釈飲料溶液をマグネティックスターラーで撹拌しながら、25mL容ビューレットに入れた0.1Mの水酸化ナトリウムを前記飲料溶液に滴下し、滴定試験を実施する。この滴定試験は、三角フラスコ内の飲料溶液の色が、30秒間赤色を持続した点を終点とする。
(4)クエン酸酸度(%)の値を、滴定試験の結果に基づき、次式によって算出する。
クエン酸酸度(%)=A×f×(100/W)×0.0064 式(1)
[(式1)において、Aは、0.1M 水酸化ナトリウム溶液の滴定量(mL)を、fは、0.1M 水酸化ナトリウム溶液の力価を、Wは、飲料試料の質量(g)を示す。また、式(1)において乗算している「0.0064」という値は、1mLの0.1M 水酸化ナトリウム溶液に相当する無水クエン酸の質量(g)を指す。]
なお、前記滴定試験においては、フェノールフタレイン指示薬に代えて、水素イオン濃度計を用いて実施してもよい。この場合、滴定試験の終点は、三角フラスコ内の飲料溶液のpHが8.1になった時とする。
(Citric acid acidity)
The citric acidity of the entire sparkling beverage was measured by the following method (titration method).
The acidity of citric acid was determined by titrating with a phenolphthalein indicator and sodium hydroxide according to the following procedure.
(1) Accurately weigh 5 to 15 g of a beverage in a 200 mL Erlenmeyer flask and dilute it to about 50 mL with water.
(2) Add a few drops of 1% phenolphthalein indicator to the diluted beverage and stir.
(3) While stirring the diluted beverage solution in the Erlenmeyer flask with a magnetic stirrer, 0.1 M sodium hydroxide contained in a 25 mL volume burette is added dropwise to the beverage solution to carry out a titration test. The titration test ends at the point where the color of the beverage solution in the Erlenmeyer flask remains red for 30 seconds.
(4) The value of citric acid acidity (%) is calculated by the following formula based on the result of the titration test.
Citric acid acidity (%) = A × f × (100 / W) × 0.0064 Equation (1)
[In (Formula 1), A is the titer (mL) of the 0.1 M sodium hydroxide solution, f is the titer of the 0.1 M sodium hydroxide solution, and W is the mass (g) of the beverage sample. Is shown. Further, the value "0.0064" multiplied in the formula (1) refers to the mass (g) of anhydrous citric acid corresponding to 1 mL of 0.1 M sodium hydroxide solution. ]
In the titration test, a hydrogen ion densitometer may be used instead of the phenolphthalein indicator. In this case, the end point of the titration test is when the pH of the beverage solution in the Erlenmeyer flask reaches 8.1.

なお、表3及び4中、「クエン酸酸度」の項は、炭酸飲料全体のクエン酸酸度を示す。「酸度比率」は、乳酸由来のクエン酸酸度及びクエン酸由来のクエン酸酸度の合計に対する、乳酸由来のクエン酸酸度、又はクエン酸由来のクエン酸酸度の比率を示す。 In addition, in Tables 3 and 4, the section of "citric acid acidity" shows the citric acid acidity of the whole carbonated beverage. The "acidity ratio" indicates the ratio of the citric acid acidity derived from lactic acid or the citric acid acidity derived from citric acid to the total of the citric acid acidity derived from lactic acid and the citric acid acidity derived from citric acid.

炭酸飲料における、各酸(クエン酸、乳酸)に由来するクエン酸酸度は、処方量から特定した。 The acidity of citric acid derived from each acid (citric acid, lactic acid) in the carbonated beverage was specified from the prescribed amount.

(糖度)
糖用屈折計(商品名「デジタル屈折計Rx−5000」、ATAGO社製)を用い、温度20℃における示度を炭酸飲料の糖度(単位:%)として測定した。
(sugar content)
Using a sugar refractometer (trade name "Digital Refractometer Rx-5000", manufactured by ATAGO), the reading at a temperature of 20 ° C. was measured as the sugar content (unit:%) of the carbonated beverage.

(官能評価)
6人のパネリストによって、以下の基準に基づき各炭酸飲料を評価し、各パネルが付けた評価点数の平均値を算出した。
(sensory evaluation)
Each carbonated beverage was evaluated by six panelists based on the following criteria, and the average value of the evaluation points given by each panel was calculated.

(まろやかさ、泡のきめ細かさ、炭酸の刺激感)
0点:全く感じられない
2点:わずかに感じられる
4点:やや感じられる
6点:明確に感じられる
8点:かなり感じられる
(Mellowness, fineness of bubbles, stimulating feeling of carbonic acid)
0 points: not felt at all 2 points: slightly felt 4 points: slightly felt 6 points: clearly felt 8 points: quite felt

(風味)
0点:悪い
2点:やや悪い
4点:どちらともいえない
6点:やや良い
8点:良い
(Flavor)
0 points: bad 2 points: slightly bad 4 points: neither can be said 6 points: slightly good 8 points: good

(総合評価)
◎:まろやかさ、泡のきめ細かさ、及び炭酸の刺激感の評価結果がいずれも6点以上である
○:まろやかさ、泡のきめ細かさ、及び炭酸の刺激感の評価結果がいずれも4点超であるが、◎の基準を満たさない
×:まろやかさ、泡のきめ細かさ、及び炭酸の刺激感の評価結果のうち1以上が4点以下である
(Comprehensive evaluation)
◎: The evaluation results of mellowness, fineness of foam, and stimulus of carbonic acid are all 6 points or more. ○: Evaluation results of mellowness, fineness of foam, and stimulus of carbonic acid are all over 4 points. However, it does not meet the criteria of ◎. ×: 1 or more of the evaluation results of mellowness, fineness of bubbles, and stimulus of carbonic acid is 4 points or less.

Figure 2020150863
Figure 2020150863

Figure 2020150863
Figure 2020150863

Figure 2020150863
Figure 2020150863

Figure 2020150863
Figure 2020150863

いずれの実施例においても、まろやかさ、泡のきめ細やかさ、及び炭酸の刺激感がいずれも良好だった。 In all the examples, the mellowness, the fineness of the foam, and the stimulating feeling of carbonic acid were all good.

実施例1と実施例7との比較から、本発明において規定される範囲内でクエン酸酸度を相対的に高めると、まろやかさや泡のきめ細やかさを損なわずに炭酸の刺激感を高められることがわかった。 From the comparison between Example 1 and Example 7, when the citric acid acidity is relatively increased within the range specified in the present invention, the stimulus feeling of carbonic acid can be enhanced without impairing the mellowness and the fineness of the foam. I understood.

実施例5と実施例8等との比較から、クエン酸由来のクエン酸酸度に対する、乳酸由来のクエン酸酸度の比が相対的に小さいほうが、まろやかさや泡のきめ細やかさを良好にしやすいことがわかった。 From the comparison between Example 5 and Example 8 and the like, it is easier to improve the mellowness and the fineness of the foam when the ratio of the citric acidity derived from lactic acid to the citric acidity derived from citric acid is relatively small. all right.

他方で、比較例に示されるとおり、本発明における要件のいずれかを満たさない炭酸飲料は、まろやかさ、泡のきめ細やかさ、及び炭酸の刺激感のいずれか又は全てが劣っていた。 On the other hand, as shown in the comparative example, the carbonated beverage that does not meet any of the requirements in the present invention was inferior in any or all of the mellowness, the fineness of the foam, and the stimulating feeling of carbonic acid.

実施例1等と比較例1との比較から、クエン酸及び乳酸を併用することで、まろやかさ、泡のきめ細やかさ、及び炭酸の刺激感だけではなく、風味をも良好にできることがわかった。 From the comparison between Example 1 and the like and Comparative Example 1, it was found that the combined use of citric acid and lactic acid can improve not only the mellowness, the fineness of the foam, and the stimulating feeling of carbonic acid, but also the flavor. ..

(加速劣化試験)
実施例1、及び比較例1の炭酸飲料を、それぞれ55℃で6日間保存する試験を行った結果を表5に示す。なお、表中の(S)は保存試験前を、(P)は55℃で6日間保存した保存試験後を示し、数値が小さいほど香りの劣化、香味の劣化、変色(褐変、退色)が大きいことを示す。
(Accelerated deterioration test)
Table 5 shows the results of a test in which the carbonated beverages of Example 1 and Comparative Example 1 were stored at 55 ° C. for 6 days, respectively. In the table, (S) shows before the storage test, (P) shows after the storage test stored at 55 ° C. for 6 days, and the smaller the value, the more the aroma deterioration, flavor deterioration, and discoloration (browning, fading). Indicates that it is large.

その結果、実施例1の炭酸飲料は、香りの劣化、香味の劣化、変色(褐変、退色)が抑制されている傾向にあった。一方で、比較例1の炭酸飲料は、香りの劣化、香味の劣化、変色(褐変、退色)が大きい傾向にあった。 As a result, the carbonated beverage of Example 1 tended to suppress deterioration of aroma, deterioration of flavor, and discoloration (browning, fading). On the other hand, the carbonated beverage of Comparative Example 1 tended to have a large deterioration of aroma, deterioration of flavor, and discoloration (browning, fading).

Figure 2020150863
Figure 2020150863

Claims (4)

無脂乳固形分、クエン酸、及び乳酸を含む炭酸飲料であって、
前記炭酸飲料に対する前記無脂乳固形分の含量が1.0質量%以上3.0質量%以下であり、
前記炭酸飲料のクエン酸酸度が0.15%以上0.45%以下であり、
前記炭酸飲料のpHが3.2以上4.0以下であり、かつ、
前記炭酸飲料の炭酸ガスボリュームが2.0ガス容量以上3.5ガス容量以下である、
炭酸飲料。
A carbonated beverage containing non-fat milk solids, citric acid, and lactic acid.
The content of the non-fat milk solid content with respect to the carbonated beverage is 1.0% by mass or more and 3.0% by mass or less.
The citric acidity of the carbonated beverage is 0.15% or more and 0.45% or less.
The pH of the carbonated beverage is 3.2 or more and 4.0 or less, and
The carbon dioxide gas volume of the carbonated beverage is 2.0 gas capacity or more and 3.5 gas capacity or less.
Carbonated drinks.
前記炭酸飲料のクエン酸酸度に占める前記クエン酸由来のクエン酸酸度の割合が20%以上である、請求項1に記載の炭酸飲料。 The carbonated beverage according to claim 1, wherein the ratio of the citric acid acidity derived from the citric acid to the citric acid acidity of the carbonated beverage is 20% or more. 前記炭酸飲料のクエン酸酸度に占める前記乳酸由来のクエン酸酸度の割合が0.5%以上である、請求項1又は2に記載の炭酸飲料。 The carbonated beverage according to claim 1 or 2, wherein the ratio of the citric acidity derived from lactic acid to the citric acidity of the carbonated beverage is 0.5% or more. 前記クエン酸由来のクエン酸酸度に対する、前記乳酸由来のクエン酸酸度の比が、1/199〜50/50である、請求項1から3のいずれかに記載の炭酸飲料。 The carbonated beverage according to any one of claims 1 to 3, wherein the ratio of the citric acidity derived from lactic acid to the citric acid acidity derived from citric acid is 1/199 to 50/50.
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