JP2020100415A - Flexible container and manufacturing method for the same - Google Patents

Flexible container and manufacturing method for the same Download PDF

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JP2020100415A
JP2020100415A JP2018238470A JP2018238470A JP2020100415A JP 2020100415 A JP2020100415 A JP 2020100415A JP 2018238470 A JP2018238470 A JP 2018238470A JP 2018238470 A JP2018238470 A JP 2018238470A JP 2020100415 A JP2020100415 A JP 2020100415A
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conductive
flexible container
peripheral wall
ground wire
resin layer
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JP7298148B2 (en
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彰 國分
Akira Kokubu
彰 國分
和博 後藤
Kazuhiro Goto
和博 後藤
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Mitsubishi Chemical Infratec Co Ltd
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Mitsubishi Chemical Infratec Co Ltd
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Abstract

To provide a flexible container excellent in durability of a conductive resin layer of an earth cable connection part, and a manufacturing method for the same.SOLUTION: An earth cable connection part 7 is extended from an outer periphery part 4a. A conductive sheet 8 is interposed between the outer periphery part 4a and a peripheral wall part 2. When subjecting conductive tarpaulin of the peripheral wall part 2 and the outer periphery part 4a of conductive tarpaulin of a lower lid part 4 to high-frequency welding, the peripheral wall part 2, the conductive sheet 8 and the outer periphery part 4a are subjected to high-frequency welding in a state where a lower part of the conductive sheet 8 is sandwiched between an upper part of the outer periphery part 4a and the peripheral wall part 2.SELECTED DRAWING: Figure 4

Description

本発明は、前面に非導電性樹脂層が形成され、裏面に導電性樹脂層が形成されたターポリン同士を接合してなるフレキシブルコンテナと、その製造方法とに関する。 The present invention relates to a flexible container in which a non-conductive resin layer is formed on a front surface, and a tarpaulin having a conductive resin layer formed on a back surface is joined, and a manufacturing method thereof.

粉粒体の輸送、保管に広く用いられているフレキシブルコンテナは、収納される粉粒体の性状により、粉粒体の注入口と排出口の注排出時、輸送時の振動、衝撃などによって、粉粒体同士または粉粒体とフレキシブルコンテナ内面との摩擦によって静電気が発生することが知られている。 Flexible containers, which are widely used for transporting and storing powders and granules, are subject to the properties of the powders and granules that are stored, and when pouring and discharging the powder granules at the inlet and outlet, vibration during transport, shock, etc. It is known that static electricity is generated by friction between powder particles or between the powder particles and the inner surface of the flexible container.

静電気をアースに逃がすために、フレキシブルコンテナの基布表面を、カーボンブラックを練り混んだ導電性付与型のゴム製素材(熱可塑性樹脂からなる素材を含む)よりなる層で被覆した導電性ターポリンが用いられている。また、ターポリンの一部を延出させて舌片状のアース線接続部を設け、このアース線接続部をアース線先端のクリップで挟持可能としたフレキシブルコンテナが用いられている。 In order to release static electricity to the ground, the conductive tarpaulin is coated on the surface of the base fabric of the flexible container with a layer made of a rubber material (including a material made of thermoplastic resin) of conductivity-imparting type that is kneaded and mixed with carbon black. It is used. Further, a flexible container is used in which a part of the tarpaulin is extended to provide a tongue-shaped ground wire connecting portion, and the ground wire connecting portion can be held by a clip at the tip of the ground wire.

図5は、市販のフレキシブルコンテナの概略的な側面図(左半分を切断してある。)、図6は図5のVI部分の拡大図である。また、図7はアース線接続部が劣化した状態を示す図6と同一部分の断面である。 5 is a schematic side view of a commercially available flexible container (the left half is cut), and FIG. 6 is an enlarged view of a VI portion of FIG. Further, FIG. 7 is a sectional view of the same portion as FIG. 6 showing a state in which the ground wire connecting portion is deteriorated.

このフレキシブルコンテナ1は、略円筒状の周壁部2と、該周壁部2の上端側を覆う上蓋部3と、該周壁部2の下端側を覆う下蓋部4と、該上蓋部3に設けられた注入口5と、該下蓋部4に設けられた排出口6と、該フレキシブルコンテナ1の外面に設けられたアース線接続部7’等を備えている。注入口5及び排出口6は、それぞれ、周壁部2よりも小径の略円筒状となっており、該注入口5は上蓋部3の中央から上方に延出し、排出口6は下蓋部4の中央から下方に延出している。周壁部2の下部外周面にアース線接続部7’が配設されている。 The flexible container 1 is provided on the substantially cylindrical peripheral wall portion 2, an upper lid portion 3 that covers the upper end side of the peripheral wall portion 2, a lower lid portion 4 that covers the lower end side of the peripheral wall portion 2, and the upper lid portion 3. The inlet 5 is provided, the outlet 6 provided in the lower lid 4, the earth wire connecting portion 7 ′ provided on the outer surface of the flexible container 1, and the like. Each of the inlet 5 and the outlet 6 has a substantially cylindrical shape having a diameter smaller than that of the peripheral wall portion 2. The inlet 5 extends upward from the center of the upper lid portion 3, and the outlet 6 is the lower lid portion 4. It extends downward from the center of. A ground wire connecting portion 7 ′ is provided on the lower outer peripheral surface of the peripheral wall portion 2.

フレキシブルコンテナ1の各部は、それぞれ導電性ターポリンにより構成されている。導電性ターポリンは、図示の通り、基布の一方の面に導電性樹脂層11を形成し、他方の面に非導電性樹脂層を形成してなるものである。この導電性ターポリンは、該導電性樹脂層をフレキシブルコンテナ1の内部側として配材されている。なお、図5〜7では、基布及び非導電性樹脂層を一体的に図示し、符号10を付してある。 Each part of the flexible container 1 is made of a conductive tarpaulin. As shown in the figure, the conductive tarpaulin has a conductive resin layer 11 formed on one surface of a base fabric and a non-conductive resin layer formed on the other surface. The conductive tarpaulin is provided with the conductive resin layer inside the flexible container 1. 5 to 7, the base cloth and the non-conductive resin layer are integrally shown and denoted by reference numeral 10.

図6の通り、下蓋部4を構成する導電性ターポリンの外周部4aは、周壁部2の下部外周面に回り込み、該下部外周面に高周波溶着等により接合されている。 As shown in FIG. 6, the outer peripheral portion 4 a of the conductive tarpaulin forming the lower lid portion 4 wraps around the lower outer peripheral surface of the peripheral wall portion 2 and is joined to the lower outer peripheral surface by high frequency welding or the like.

アース線接続部7’は、この導電性ターポリンの外周部4aから延出した舌状片よりなる。フレキシブルコンテナ1内に粉粒体を収容する場合は、アース線先端のアースクリップ(図示略)で該アース線接続部7’を挟み、アースをとる。 The ground wire connecting portion 7'is made of a tongue piece extending from the outer peripheral portion 4a of the conductive tarpaulin. When the powdery or granular material is stored in the flexible container 1, the grounding wire connecting portion 7'is sandwiched by a grounding clip (not shown) at the tip of the grounding wire and grounded.

特開2012−250753号公報JP2012-250753A

アース線接続部7’は、本来、上記のようにアース線先端のアースクリップで挟んでフレキシブルコンテナ1のアースをとるためのものである。しかしながら、実際の作業時には、作業者がフレキシブルコンテナ1を移動させようとしてアース線接続部7’を掴んで図6の矢印F方向等にアース線接続部7’を引っ張ることがある。このようにアース線接続部7’を引っ張ると、導電性樹脂層11に強い引張力が負荷され、図7のように、アース線接続部7’の付け根付近で導電性樹脂層11に亀裂Cが生じ、アース線接続部7’の導電性樹脂層11とフレキシブルコンテナ1の導電性樹脂層11との間の電気抵抗が増大するおそれがある。なお、アース端子からの接地間抵抗はJIS C 61340−4−4で1×10Ω未満と規定されている。 The ground wire connecting portion 7'is originally intended to ground the flexible container 1 by sandwiching it with the ground clip at the tip of the ground wire as described above. However, at the time of actual work, an operator may try to move the flexible container 1 by grasping the ground wire connecting portion 7′ and pulling the ground wire connecting portion 7′ in the direction of arrow F in FIG. When the ground wire connecting portion 7'is pulled in this way, a strong tensile force is applied to the conductive resin layer 11, and as shown in FIG. 7, the conductive resin layer 11 cracks C near the root of the ground wire connecting portion 7'. May occur, and the electrical resistance between the conductive resin layer 11 of the ground wire connecting portion 7′ and the conductive resin layer 11 of the flexible container 1 may increase. The ground resistance from the ground terminal is specified by JIS C 61340-4-4 to be less than 1×10 8 Ω.

本発明は、アース線接続部の導電性樹脂層の耐久性に優れたフレキシブルコンテナ及びその製造方法を提供することを目的とする。 An object of the present invention is to provide a flexible container having excellent durability of a conductive resin layer of a ground wire connecting portion and a method for manufacturing the flexible container.

第1発明のフレキシブルコンテナは、導電性ターポリンよりなる周壁部、下蓋部及び上蓋部を接合してなるフレキシブルコンテナであって、該導電性ターポリンは、前面に非導電性樹脂層が形成され、裏面に導電性樹脂層が形成されており、該導電性ターポリンは、該導電性樹脂層を該フレキシブルコンテナの内部側として配材されており、前記下蓋部又は上蓋部を構成する導電性ターポリンの外周部が前記周壁部の外周面に沿って延出し、該周壁部の外周面に接合されているフレキシブルコンテナにおいて、該下蓋部又は上蓋部からアース線接続部が延出しており、該アース線接続部と周壁部との間に導電性シートが介在しており、前記外周部と周壁部との間に、該導電性シートの基部が挟み込まれて該外周部及び周壁部に対し接合されていることを特徴とするものである。 A flexible container of the first invention is a flexible container in which a peripheral wall portion made of a conductive tarpaulin, a lower lid portion and an upper lid portion are joined, and the conductive tarpaulin has a non-conductive resin layer formed on a front surface thereof, A conductive resin layer is formed on the back surface, and the conductive tarpaulin is provided with the conductive resin layer as the inner side of the flexible container, and the conductive tarpaulin forming the lower lid part or the upper lid part is formed. An outer peripheral portion of the flexible container joined to the outer peripheral surface of the peripheral wall portion, the ground wire connection portion extends from the lower lid portion or the upper lid portion, A conductive sheet is interposed between the ground wire connecting portion and the peripheral wall portion, and the base portion of the conductive sheet is sandwiched between the outer peripheral portion and the peripheral wall portion and bonded to the outer peripheral portion and the peripheral wall portion. It is characterized by being.

第1発明の一態様では、前記導電性シートのうち、前記基部以外は、前記外周部から延出した自由片となっており、該自由片の延出長さは前記アース線接続部の延出長さよりも小さい。 1 aspect of 1st invention WHEREIN: Except for the said base part among the said electroconductive sheets, it is the free piece extended from the said outer peripheral part, and the extension length of this free piece is the extension of the said earth wire connection part. It is smaller than the protruding length.

第1発明の一態様では、前記アース線接続部の左右幅は基端側が先端側よりも大きい。 In one aspect of the first invention, the width of the ground wire connecting portion on the base end side is larger than that on the tip end side.

第2発明のフレキシブルコンテナは、導電性ターポリンよりなる周壁部、下蓋部及び上蓋部を接合してなるフレキシブルコンテナであって、該導電性ターポリンは、前面に非導電性樹脂層が形成され、裏面に導電性樹脂層が形成されており、該導電性ターポリンは、該導電性樹脂層を該フレキシブルコンテナの内部側として配材されており、前記下蓋部又は上蓋部を構成する導電性ターポリンの外周部が前記周壁部の外周面に沿って延出し、該周壁部の外周面に接合されているフレキシブルコンテナにおいて、該下蓋部又は上蓋部からアース線接続部が延出しており、前記アース線接続部の左右幅は、基端側が先端側よりも大きいことを特徴とするものである。 A flexible container according to a second aspect of the invention is a flexible container in which a peripheral wall portion made of a conductive tarpaulin, a lower lid portion and an upper lid portion are joined, and the conductive tarpaulin has a non-conductive resin layer formed on a front surface thereof. A conductive resin layer is formed on the back surface, and the conductive tarpaulin is provided with the conductive resin layer as the inner side of the flexible container, and the conductive tarpaulin forming the lower lid part or the upper lid part is formed. An outer peripheral portion of the peripheral wall portion extends along the outer peripheral surface of the peripheral wall portion, in the flexible container joined to the outer peripheral surface of the peripheral wall portion, the ground wire connecting portion extends from the lower lid portion or the upper lid portion, The right and left width of the ground wire connecting portion is characterized in that the base end side is larger than the tip end side.

本発明のフレキシブルコンテナの製造方法は、第1発明のフレキシブルコンテナを製造する方法であって、前記周壁部を構成する導電性ターポリンと下蓋部又は上蓋部を構成する導電性ターポリンの外周部との間に前記導電性シートの基部を挟み、該周壁部と、導電性シートの基部と、下蓋部又は上蓋部とを高周波溶着する工程を有するものである。 A method for manufacturing a flexible container according to the present invention is a method for manufacturing a flexible container according to the first aspect of the present invention, wherein a conductive tarpaulin that constitutes the peripheral wall portion and an outer peripheral portion of the conductive tarpaulin that constitutes a lower lid portion or an upper lid portion are provided. And a step of sandwiching the base portion of the conductive sheet between them and high-frequency welding the peripheral wall portion, the base portion of the conductive sheet, and the lower lid portion or the upper lid portion.

第1発明のフレキシブルコンテナにあっては、アース線接続部が外周部から延出し、このアース線接続部と周壁部との間に導電性シートが介在し、該導電性シートの基部が外周部と周壁部との間に挟み込まれて接合されているので、アース線接続部の導電性樹脂層とフレキシブルコンテナ本体側の導電性樹脂層とが導電性シートを介して電気的に導通した状態となる。そのため、作業者がアース線接続部を引っ張ることが度重なり、アース線接続部の基端側においてその導電性樹脂層に亀裂が生じたとしても、導電性シートを介して十分なアースをとることができる。 In the flexible container of the first invention, the ground wire connecting portion extends from the outer peripheral portion, the conductive sheet is interposed between the ground wire connecting portion and the peripheral wall portion, and the base portion of the conductive sheet is the outer peripheral portion. Since it is sandwiched between and bonded to the peripheral wall portion, the conductive resin layer of the ground wire connecting portion and the conductive resin layer of the flexible container body side are electrically connected via the conductive sheet. Become. Therefore, even if the worker repeatedly pulls the ground wire connecting part, and even if the conductive resin layer on the base end side of the ground wire connecting part is cracked, it is necessary to take sufficient ground through the conductive sheet. You can

第2発明のフレキシブルコンテナによると、作業者がアース線接続部を引っ張ることが度重なっても、アース線接続部の基端側に生じる引張応力が分散され、その導電性樹脂層に亀裂が生じることが抑制される。 According to the flexible container of the second invention, even if an operator frequently pulls the ground wire connecting portion, the tensile stress generated on the base end side of the ground wire connecting portion is dispersed and a crack is generated in the conductive resin layer. Is suppressed.

実施の形態に係るフレキシブルコンテナのアース線接続部付近の断面斜視図である。It is a cross-sectional perspective view of the flexible container according to the embodiment in the vicinity of the ground wire connecting portion. 図1のII−II線断面図である。It is the II-II sectional view taken on the line of FIG. 図1のIII−III線断面図である。It is the III-III sectional view taken on the line of FIG. 別の実施の形態に係るフレキシブルコンテナのアース線接続部付近の断面斜視図である。It is a cross-sectional perspective view of the earth wire connection part vicinity of the flexible container which concerns on another embodiment. 従来のフレキシブルコンテナの側面図である。It is a side view of the conventional flexible container. 図5のVI部分の拡大図である。FIG. 6 is an enlarged view of a VI portion of FIG. 5. 導電性樹脂層の劣化状態を示す断面図である。It is sectional drawing which shows the deterioration state of a conductive resin layer.

以下、図1〜4を参照して実施の形態について説明する。 Hereinafter, embodiments will be described with reference to FIGS.

図1〜3は第1の実施の形態を示している。この実施の形態に係るフレキシブルコンテナも、前記図5のフレキシブルコンテナ1と同様に、周壁部2、上蓋部3、下蓋部4、注入口5、排出口6及びアース線接続部7を有している(上蓋部3、注入口5、排出口6は、図1〜3では図示略。)。下蓋部4の外周部4aは、周壁部2の外周面に沿って立ち上がり、該周壁部2の外周面に高周波溶着等によって接合されている。なお、高周波溶着以外の接合法を採用してもよい。 1 to 3 show the first embodiment. Like the flexible container 1 of FIG. 5, the flexible container according to this embodiment also has a peripheral wall portion 2, an upper lid portion 3, a lower lid portion 4, an inlet 5, an outlet 6, and a ground wire connecting portion 7. (The upper lid part 3, the inlet 5, and the outlet 6 are not shown in FIGS. 1 to 3.). The outer peripheral portion 4a of the lower lid portion 4 rises along the outer peripheral surface of the peripheral wall portion 2 and is joined to the outer peripheral surface of the peripheral wall portion 2 by high frequency welding or the like. A joining method other than high frequency welding may be adopted.

この実施の形態でも、周壁部2、上蓋部3及び下蓋部4はいずれも導電性ターポリンよりなる。周壁部2の導電性樹脂層11は、フレキシブルコンテナの内面側に位置し、上蓋部3の導電性樹脂層11は上蓋部3の下面側に位置し、下蓋部4の導電性樹脂層11は下蓋部4の上面側に位置している。 Also in this embodiment, each of the peripheral wall portion 2, the upper lid portion 3 and the lower lid portion 4 is made of a conductive tarpaulin. The conductive resin layer 11 of the peripheral wall portion 2 is located on the inner surface side of the flexible container, the conductive resin layer 11 of the upper lid portion 3 is located on the lower surface side of the upper lid portion 3, and the conductive resin layer 11 of the lower lid portion 4 is located. Is located on the upper surface side of the lower lid portion 4.

この実施の形態では、アース線接続部7は、下蓋部4を構成する導電性ターポリンと一連一体のものであり、該外周部4aから延出する自由片状の舌状片よりなる。 In this embodiment, the ground wire connecting portion 7 is integrally formed with a conductive tarpaulin that constitutes the lower lid portion 4 and is a tongue-shaped piece of a free piece extending from the outer peripheral portion 4a.

アース線接続部7は、例えば左右幅20〜200mm、上下長さL(図2)30〜100mm程度であるが、その形状及び寸法はこれに限定されない。なお、この実施の形態では、アース線接続部7は、基端側ほど左右幅が大きくなる台形となっている。この場合、台形の上辺部分に相当する先端部の幅Wは15〜100mm、特に25〜75mm程度が好ましく、台形の底辺部分に相当するアース線接続部7の基部の幅Wは30〜200mm、特に50〜150mm程度が好ましい。 The ground wire connecting portion 7 has, for example, a lateral width of 20 to 200 mm and a vertical length L 1 (FIG. 2) of 30 to 100 mm, but the shape and dimensions thereof are not limited thereto. In addition, in this embodiment, the ground wire connecting portion 7 has a trapezoidal shape in which the left-right width increases toward the base end side. In this case, the width W 2 of the tip portion corresponding to the upper side portion of the trapezoid is preferably 15 to 100 mm, particularly about 25 to 75 mm, and the width W 1 of the base portion of the ground wire connecting portion 7 corresponding to the bottom side portion of the trapezoid is 30 to. 200 mm, especially about 50 to 150 mm is preferable.

アース線接続部7と周壁部2との間に導電性シート8が介在している。この導電性シート8の下部(基部)は、下蓋部4の外周部4aと、周壁部2の下部との間に挟み込まれ、高周波溶着等によって外周部4aと周壁部2との双方に接合されている。 A conductive sheet 8 is interposed between the ground wire connecting portion 7 and the peripheral wall portion 2. The lower portion (base portion) of the conductive sheet 8 is sandwiched between the outer peripheral portion 4a of the lower lid portion 4 and the lower portion of the peripheral wall portion 2 and joined to both the outer peripheral portion 4a and the peripheral wall portion 2 by high frequency welding or the like. Has been done.

導電性シート8の左右幅Wは、アース線接続部7の左右幅よりも小さい。導電性シート8の外周部4aからの延出長さL(図2)は、アース線接続部7の外周部4aからの延出長さLの10〜100%、特に25〜75%程度が好ましい。導電性シート8の外周部4aと周壁部2との挟み込み部分の長さ(深さ)Lは3〜50mm、特に5〜20mm程度が好ましい。 The lateral width W 3 of the conductive sheet 8 is smaller than the lateral width of the ground wire connecting portion 7. The extension length L 2 (FIG. 2) of the conductive sheet 8 from the outer peripheral portion 4a is 10 to 100%, particularly 25 to 75% of the extension length L 1 of the ground wire connecting portion 7 from the outer peripheral portion 4a. A degree is preferable. The length (depth) L3 of the sandwiched portion between the outer peripheral portion 4a and the peripheral wall portion 2 of the conductive sheet 8 is preferably 3 to 50 mm, particularly preferably 5 to 20 mm.

このフレキシブルコンテナのその他の構成は前記図5〜7に示したフレキシブルコンテナ1と同一である。 The other construction of this flexible container is the same as that of the flexible container 1 shown in FIGS.

この実施の形態に係るフレキシブルコンテナにおいても、アース線接続部7と、さらに好ましくは導電性シート8とを挟むようにアース線先端のアースクリップが装着されることにより、アースが取られる。 Also in the flexible container according to this embodiment, grounding is performed by mounting a grounding clip at the tip of the grounding wire so as to sandwich the grounding wire connecting portion 7 and more preferably the conductive sheet 8.

この実施の形態においても、作業者がアース線接続部7を引っ張ることがありうる。作業者がアース線接続部7を引っ張ることが度重なると、図7と同様に、アース線接続部7の基端側においてその導電性樹脂層11に亀裂が入る可能性がある。 Also in this embodiment, an operator may pull the ground wire connecting portion 7. If the worker repeatedly pulls the ground wire connecting portion 7, the conductive resin layer 11 may be cracked on the base end side of the ground wire connecting portion 7 as in the case of FIG. 7.

この実施の形態では、導電性シート8の自由片部分はアース線接続部7と共にアースクリップに挟み込まれるので、アース線接続部7の基端部において導電性樹脂層11に亀裂が生じたとしても、アース線接続部7の導電性樹脂層11は、導電性シート8を介して外周部4aの導電性樹脂層11に導通するので、アースクリップはフレキシブルコンテナ全体の導電性樹脂層11に低抵抗にて導通し、十分なアースをとることができる。 In this embodiment, since the free piece portion of the conductive sheet 8 is sandwiched between the ground wire connecting portion 7 and the ground clip, even if the conductive resin layer 11 is cracked at the base end portion of the ground wire connecting portion 7. Since the conductive resin layer 11 of the ground wire connecting portion 7 is electrically connected to the conductive resin layer 11 of the outer peripheral portion 4a through the conductive sheet 8, the ground clip has a low resistance to the conductive resin layer 11 of the entire flexible container. It conducts electricity at and can be grounded sufficiently.

また、アース線接続部7と外周部4aとの境界付近に導電性シート8が溶着されることにより、アース線接続部7の基端部付近において、導電性樹脂層11と導電性シート8との合計の厚みを有した導電層が構成される。これにより、導電層の引張強度が大きくなり、アース線接続部7を引っ張ったときに、該導電層に亀裂が生じることが抑制される。このため、アースクリップがアース線接続部7のみを挟んだ場合でも、十分なアースをとることができる。 Further, since the conductive sheet 8 is welded near the boundary between the ground wire connecting portion 7 and the outer peripheral portion 4a, the conductive resin layer 11 and the conductive sheet 8 are formed near the base end portion of the ground wire connecting portion 7. A conductive layer having a total thickness of This increases the tensile strength of the conductive layer and suppresses cracking of the conductive layer when the ground wire connecting portion 7 is pulled. Therefore, even if the ground clip sandwiches only the ground wire connecting portion 7, sufficient grounding can be achieved.

また、この実施の形態では、アース線接続部7が台形となっているので、アース線接続部7が作業者によって引っ張られたときの応力がアース線接続部7の基端側で分散され、アース線接続部7の基端側において導電性樹脂層11に亀裂が入ることが抑制される。 Further, in this embodiment, since the ground wire connecting portion 7 has a trapezoidal shape, stress when the ground wire connecting portion 7 is pulled by an operator is dispersed on the base end side of the ground wire connecting portion 7, The conductive resin layer 11 is prevented from cracking on the base end side of the ground wire connecting portion 7.

従って、本発明では、図4の通り、導電性シート8を省略し、台形のアース線接続部7のみを形成した場合でも、相応の効果が奏される。 Therefore, according to the present invention, as shown in FIG. 4, even when the conductive sheet 8 is omitted and only the trapezoidal ground wire connecting portion 7 is formed, a corresponding effect can be obtained.

図1,4では、アース線接続部7は台形となっているが、アース線接続部7の側辺は裾野を引くような凹曲線や、それに近似した折れ曲り線で構成されてもよい。 In FIGS. 1 and 4, the ground wire connecting portion 7 has a trapezoidal shape, but the side of the ground wire connecting portion 7 may be formed by a concave curve that draws a skirt or a bent line that is similar to that.

なお、導電性ターポリンの導電性樹脂層11の厚みは0.01〜1mm、特に0.02〜0.1mmであることが好ましく、非導電性樹脂層12の厚みは0.1〜3mm、特に0.2〜1mmであることが好ましい。導電性シート8の厚みは0.01〜1mm、特に0.02〜0.1mm程度が好ましい。 The thickness of the conductive resin layer 11 of the conductive tarpaulin is 0.01 to 1 mm, preferably 0.02 to 0.1 mm, and the thickness of the non-conductive resin layer 12 is 0.1 to 3 mm, particularly It is preferably 0.2 to 1 mm. The thickness of the conductive sheet 8 is preferably 0.01 to 1 mm, particularly preferably 0.02 to 0.1 mm.

[材質等]
フレキシブルコンテナ1の各部を構成する導電性ターポリンの材質の一例として次のものが挙げられるが、これらに限定されるものではない。
[Material, etc.]
Examples of the material of the conductive tarpaulin forming each part of the flexible container 1 include the following, but the material is not limited to these.

導電性ターポリンの基布としては、木綿及び麻などの天然繊維や、ポリエステル繊維、ポリアミド繊維及びビニロン繊維などの合成繊維製の織布が挙げられる。基布は、これらの繊維を単独でまたは2種以上を組み合わせて構成したフィラメントまたはスティーブルであってもよい。なお、織布とは、これらの繊維を平織、綾織、朱子織などに織った織物や編み物を意味し、編織物の種類や構造は、導電性ターポリンのフレキシビリティを阻害しないものであれば、特に制限はない。 Examples of the base fabric of the conductive tarpaulin include woven fabrics made of natural fibers such as cotton and hemp, and synthetic fibers such as polyester fibers, polyamide fibers and vinylon fibers. The base fabric may be a filament or steebles formed by using these fibers alone or in combination of two or more kinds. The woven fabric means a woven fabric or knitted fabric in which these fibers are woven into a plain woven fabric, a twill woven fabric, a satin woven fabric, etc., and the kind and structure of the knitted woven fabric is one that does not impair the flexibility of the conductive tarpaulin, There is no particular limitation.

基布を構成する織布としては、繊維の太さが500〜1000デニールであり、打ち込み本数が15〜30本/インチの平織物が好適である。ポリエステル繊維又はポリアミド繊維よりなる織布を用いる場合には、この織布としては、繊維の太さが750デニールであり、打ち込み本数20本×20本/インチの平織物が好適である。このような織布は、厚さが0.2〜2mmであり、幅が0.5〜3m程度のものが一般である。 As the woven fabric constituting the base fabric, a plain woven fabric having a fiber thickness of 500 to 1000 denier and a driving number of 15 to 30 fibers/inch is preferable. When a woven fabric made of polyester fibers or polyamide fibers is used, a flat woven fabric having a fiber thickness of 750 denier and a striking number of 20×20/inch is suitable as the woven fabric. Such a woven fabric generally has a thickness of 0.2 to 2 mm and a width of about 0.5 to 3 m.

非導電性樹脂層は、熱可塑性樹脂組成物よりなることが好ましく、特にエチレンと酢酸ビニルとの共重合体層を含む樹脂層によって構成されていることが好ましい。エチレンと酢酸ビニルとの共重合体層を含む樹脂層とは、エチレンと酢酸ビニルとの共重合体層の単層よりなる樹脂層のほか、エチレンと酢酸ビニルとの共重合体層と他の樹脂層とが積層された多層の樹脂層であってもよい。他の樹脂層を形成する樹脂としては、ポリ塩化ビニル、塩化ビニルを主成分とした塩化ビニル系共重合体などのポリ塩化ビニル系樹脂、低密度ポリエチレン、高密度ポリエチレン、塩素化ポリエチレンなどのポリエチレン系樹脂、エチレン−アクリル酸メチル共重合体(EMA)、エチレン−メタクリル酸メチル共重合体(EMMA)、エチレン−アクリル酸エチル共重合体(EEA)などのエチレン−アクリル酸系共重合体、ポリウレタン、ポリ酢酸ビニルなどが挙げられるが、これに限定されない。 The non-conductive resin layer is preferably composed of a thermoplastic resin composition, and particularly preferably composed of a resin layer containing a copolymer layer of ethylene and vinyl acetate. The resin layer containing a copolymer layer of ethylene and vinyl acetate includes a resin layer consisting of a single layer of a copolymer layer of ethylene and vinyl acetate, a copolymer layer of ethylene and vinyl acetate and other layers. It may be a multilayer resin layer in which a resin layer is laminated. As the resin forming the other resin layer, polyvinyl chloride, polyvinyl chloride resin such as vinyl chloride copolymer containing vinyl chloride as a main component, polyethylene such as low density polyethylene, high density polyethylene and chlorinated polyethylene. -Based resins, ethylene-acrylic acid copolymers (EMA), ethylene-methyl methacrylate copolymers (EMMA), ethylene-acrylic acid copolymers such as ethylene-ethyl acrylate copolymer (EEA), polyurethanes , Polyvinyl acetate and the like, but are not limited thereto.

エチレン−酢酸ビニル共重合体としては、エチレンと酢酸ビニルの成分重合比が90:10〜70:30のものが好適である。酢酸ビニルの割合が10質量%未満であると高周波溶着加工が困難となり、また30質量%を超えると耐熱性が悪くなり、いずれも好ましくない。エチレンと酢酸ビニルの成分重合比の特に好ましい範囲は、85:15〜75:25である。エチレン−酢酸ビニル共重合体としては、JIS K7210に準拠して温度190℃、荷重21.28N(2.16kgf)の条件で測定したメルトフローレート(MFR)が0.1〜5.0の範囲のものが好ましく、中でも0.5〜2.0の範囲のものが特に好ましい。 As the ethylene-vinyl acetate copolymer, those having a component polymerization ratio of ethylene and vinyl acetate of 90:10 to 70:30 are preferable. If the proportion of vinyl acetate is less than 10% by mass, the high frequency welding process becomes difficult, and if it exceeds 30% by mass, the heat resistance becomes poor, which is not preferable. A particularly preferred range of the component polymerization ratio of ethylene and vinyl acetate is 85:15 to 75:25. As the ethylene-vinyl acetate copolymer, the melt flow rate (MFR) measured under the conditions of a temperature of 190° C. and a load of 21.28 N (2.16 kgf) according to JIS K7210 is in the range of 0.1 to 5.0. Those in the range of 0.5 to 2.0 are particularly preferable.

導電性樹脂層11は、導電性カーボンブラックを含む熱可塑性樹脂組成物よりなることが好ましく、特に導電性カーボンブラックおよび主成分としてエチレン−酢酸ビニル共重合体層を含む樹脂層により構成されていることが好ましい。導電性カーボンブラックおよび主成分としてエチレン−酢酸ビニル共重合体層を含む樹脂層とは、導電性カーボンブラックを含む主成分としてエチレン−酢酸ビニル共重合体層(ポリオレフィン系樹脂層)の単層よりなる樹脂層のほか、この層に他の樹脂層が積層された多層の樹脂層であってもよい。他の樹脂層樹脂層を形成する樹脂としては、低密度ポリエチレン、高密度ポリエチレン、塩素化ポリエチレンなどのポリエチレン系樹脂、ポリプロピレン、プロピレン−エチレン共重合体などのポリプロピレン系樹脂、エチレン−アクリル酸メチル共重合体、エチレン−メタクリル酸メチル共重合体、エチレン−アクリル酸エチル共重合体などのエチレン−アクリル系共重合体などが挙げられる。その他、他の樹脂層は、導電性カーボンブラックを特定量配合した熱可塑性樹脂層を含むものであってもよい。 The conductive resin layer 11 is preferably made of a thermoplastic resin composition containing conductive carbon black, and is particularly composed of a conductive carbon black and a resin layer containing an ethylene-vinyl acetate copolymer layer as a main component. It is preferable. The resin layer containing the conductive carbon black and the ethylene-vinyl acetate copolymer layer as the main component means a single layer of the ethylene-vinyl acetate copolymer layer (polyolefin resin layer) as the main component containing the conductive carbon black. In addition to the above resin layer, it may be a multilayer resin layer in which another resin layer is laminated on this layer. Other resin layers As the resin forming the resin layer, polyethylene resin such as low density polyethylene, high density polyethylene, chlorinated polyethylene, polypropylene, polypropylene resin such as propylene-ethylene copolymer, ethylene-methyl acrylate copolymer Examples of the polymer include ethylene-acrylic copolymers such as ethylene-methyl methacrylate copolymer and ethylene-ethyl acrylate copolymer. In addition, the other resin layer may include a thermoplastic resin layer containing a specific amount of conductive carbon black.

上記導電性樹脂層に配合される導電性カーボンブラックには特に制限はないが、導電性カーボンブラックの平均表面積が比較的小さい場合には、該導電性カーボンブラックの使用量が多量となり、これにより熱可塑性樹脂をフィルム化する際の流動性が悪化したり、フィルムの強度が極端に低下したりするなどの欠点が顕著になる。導電性カーボンブラックとしては、物性上の観点から、平均表面積30m/g以上のものが好ましく、中でも平均表面積100m/g以上のものが特に好適である。 There is no particular limitation on the conductive carbon black blended in the conductive resin layer, but when the average surface area of the conductive carbon black is relatively small, the amount of the conductive carbon black used becomes large, Disadvantages such as deterioration of fluidity when the thermoplastic resin is formed into a film and extreme decrease in strength of the film are significant. From the viewpoint of physical properties, the conductive carbon black preferably has an average surface area of 30 m 2 /g or more, and particularly preferably an average surface area of 100 m 2 /g or more.

熱可塑性樹脂、好ましくはエチレン−酢酸ビニル共重合体を含む樹脂に対する導電性カーボンブラックの配合量は、熱可塑性樹脂100質量部に対し0.1〜25質量部であることが好ましい。導電性カーボンブラックの配合量が0.1質量部未満であると、導電性樹脂層11の表面固有抵抗が大きくなり、導電性が改良されにくいため、好ましくない。導電性カーボンブラックの配合量が25質量部を越えると、導電性樹脂層11の表面固有抵抗が小さくなり、導電性は改良されるが、ターポリンの柔軟性が損なわれたり、高周波溶着加工する際にスパークが発生するおそれが高まったりするので、好ましくない。熱可塑性樹脂100質量部に対する導電性カーボンブラックの特に好ましい配合量は、3〜15質量部である。 The amount of conductive carbon black compounded with respect to the thermoplastic resin, preferably a resin containing an ethylene-vinyl acetate copolymer, is preferably 0.1 to 25 parts by mass with respect to 100 parts by mass of the thermoplastic resin. When the blending amount of the conductive carbon black is less than 0.1 parts by mass, the surface specific resistance of the conductive resin layer 11 becomes large and the conductivity is hard to be improved, which is not preferable. When the blending amount of the conductive carbon black exceeds 25 parts by mass, the surface specific resistance of the conductive resin layer 11 becomes small and the conductivity is improved, but the flexibility of the tarpaulin is impaired and the high frequency welding process is performed. This is not preferable because it may increase the risk of sparks. A particularly preferable blending amount of the conductive carbon black with respect to 100 parts by mass of the thermoplastic resin is 3 to 15 parts by mass.

導電性シート8は、上記の基布の両面に、上記の導電性樹脂層11と同様の導電性樹脂層を設けたものが好ましい。 It is preferable that the conductive sheet 8 has conductive resin layers similar to the conductive resin layer 11 provided on both surfaces of the base cloth.

本発明のフレキシブルコンテナを製造するには、周壁部2の導電性ターポリンと下蓋部4の導電性ターポリンの外周部4aとを高周波溶着するに際し、外周部4aの上部と周壁部2との間に導電性シート8の下部を挟んで該周壁部2、導電性シート8の下部及び外周部4aを高周波溶着すればよい。 In order to manufacture the flexible container of the present invention, during high frequency welding of the conductive tarpaulin of the peripheral wall portion 2 and the outer peripheral portion 4a of the conductive tarpaulin of the lower lid portion 4, between the upper portion of the outer peripheral portion 4a and the peripheral wall portion 2 is performed. The peripheral wall portion 2, the lower portion of the conductive sheet 8 and the outer peripheral portion 4a may be high frequency welded with the lower portion of the conductive sheet 8 interposed therebetween.

なお、このように導電性シート8の下部を周壁部2と外周部4aとの間で挟んで高周波溶着すると、アース線接続部を挟んだ部分では厚さ(周壁部2の内面から外周部4aの外面までの厚み)が大きくなる。そして、図3に示されるように、この導電性シート8を挟んだ部分と、その周囲との間に段差が生じる。この段差を小さくするために、導電性シート8の厚さを、周壁部2及び下蓋部4を構成するターポリンの厚さよりも小さくすることが好ましい。 In addition, when the lower portion of the conductive sheet 8 is sandwiched between the peripheral wall portion 2 and the outer peripheral portion 4a in this way and high-frequency welding is performed, the thickness (from the inner surface of the peripheral wall portion 2 to the outer peripheral portion 4a of the peripheral wall portion 2) is sandwiched between the ground wire connecting portions. The thickness up to the outer surface) becomes large. Then, as shown in FIG. 3, a step is formed between the portion sandwiching the conductive sheet 8 and the periphery thereof. In order to reduce this step, it is preferable that the thickness of the conductive sheet 8 be smaller than the thickness of the tarpaulin forming the peripheral wall portion 2 and the lower lid portion 4.

上記実施の形態は本発明の一例であり、本発明は図示以外の形態とされてもよい。例えば、上記実施の形態では、導電性シート8は略長方形状となっているが、アース線接続部7を台形等とする場合、それに倣った(例えば相似形の)台形としてもよい。 The above-described embodiment is an example of the present invention, and the present invention may have a mode other than that shown in the drawings. For example, in the above-described embodiment, the conductive sheet 8 has a substantially rectangular shape, but when the ground wire connecting portion 7 has a trapezoidal shape or the like, it may have a trapezoidal shape (for example, a similar shape).

上記実施の形態では、アース線接続部7、導電性シート8は下蓋部4側に配置されているが、アース線接続部、導電性シートを上蓋部3側に配置してもよい。この場合の構成は、図1,2,4において上下対称のものとなる。 In the above embodiment, the ground wire connecting portion 7 and the conductive sheet 8 are arranged on the lower lid portion 4 side, but the ground wire connecting portion and the conductive sheet may be arranged on the upper lid portion 3 side. The configuration in this case is vertically symmetrical in FIGS.

[実施例1]
周壁部2及び下蓋部4を厚さ0.80mmのターポリン製とし、導電性シート8を厚さ0.05mmとした図1〜3に示すフレキシブルコンテナを製造した。アース線接続部7はW=100mm、W=50mm、L=60mmの台形である。導電性シート8はW=50mm、L=40mm、L=10mmの正方形であり、基端側10mmの範囲を外周部4aと周壁部2との間に挟み込んで高周波溶着した。
[Example 1]
A flexible container shown in FIGS. 1 to 3 was manufactured in which the peripheral wall portion 2 and the lower lid portion 4 were made of tarpaulin having a thickness of 0.80 mm, and the conductive sheet 8 was made to have a thickness of 0.05 mm. The ground wire connecting portion 7 has a trapezoidal shape with W 1 =100 mm, W 2 =50 mm, and L 1 =60 mm. The conductive sheet 8 was a square with W 3 =50 mm, L 2 =40 mm, and L 3 =10 mm, and the range of 10 mm on the base end side was sandwiched between the outer peripheral portion 4 a and the peripheral wall portion 2 and subjected to high frequency welding.

このアース線接続部7を外周部4aと直角方向(図5のF方向)に294N(30kg)又は392N(40kg)で10回引っ張った(500N/minのスピードで荷重をかけ、294N、392Nに達したところで1回の引っ張りを終了した)。引っ張り前後に、アース線接続部7及び導電性シート8を挟むようにアースクリップを装着して接地間抵抗を測定した。結果を表1に示す。 The earth wire connecting portion 7 was pulled 10 times in the direction perpendicular to the outer peripheral portion 4a (direction F in FIG. 5) at 294N (30 kg) or 392N (40 kg) (load was applied at a speed of 500 N/min to 294 N and 392 N). When it reached, it finished pulling once). Before and after the pulling, a grounding clip was attached so as to sandwich the grounding wire connecting portion 7 and the conductive sheet 8, and the resistance between grounds was measured. The results are shown in Table 1.

[実施例2]
実施例1と同一のフレキシブルコンテナを製造し、引っ張り試験時の引っ張り方向をアース線接続部7及び延出部8が外周部4aに沿うように180°折り返される方向(図2において鉛直下向き方向)として引っ張り試験を行い、接地間抵抗を測定した。結果を表1に示す。
[Example 2]
The same flexible container as in Example 1 was manufactured, and the pulling direction during the pulling test was a direction in which the ground wire connecting portion 7 and the extending portion 8 were folded back 180° along the outer peripheral portion 4a (vertically downward direction in FIG. 2). As a result, a tensile test was performed to measure the resistance between grounds. The results are shown in Table 1.

[実施例3,4]
導電性シート8を省略したこと以外は実施例1,2とそれぞれ同一の引っ張り試験を行った。結果を表1に示す。
[Examples 3 and 4]
The same tensile tests as in Examples 1 and 2 were performed except that the conductive sheet 8 was omitted. The results are shown in Table 1.

[比較例1]
アース線接続部を図6の構成(幅50mm、突出長さ40mm)としたこと以外は実施例4とそれぞれ同一の引っ張り試験を行った。結果を表1に示す。
[Comparative Example 1]
The same tensile test as in Example 4 was performed except that the ground wire connecting portion had the configuration of FIG. 6 (width 50 mm, protrusion length 40 mm). The results are shown in Table 1.

Figure 2020100415
Figure 2020100415

[考察]
表1の通り、実施例1〜4では、アース線接続部を繰り返し引っ張っても接地間抵抗は全く又は殆ど増加しない(実施例4の接地間抵抗3.3MΩも実用上問題とならない程度の低い値である。)。これに対し、比較例1のようにアース線接続部の折り返し角度が大きくなる方向に引っ張られた場合、接地間抵抗の増大が顕著になることが認められる。
[Discussion]
As shown in Table 1, in Examples 1 to 4, even if the ground wire connection portion is repeatedly pulled, the resistance to ground does not increase at all or hardly (the resistance to ground of 3.3 MΩ in Example 4 is low enough to cause no practical problem). It is a value.). On the other hand, when it is pulled in the direction in which the turn-back angle of the ground wire connection portion increases as in Comparative Example 1, it is recognized that the resistance between the grounds increases remarkably.

1 フレキシブルコンテナ
2 周壁部
3 上蓋部
4 下蓋部
5 投入口
6 排出口
7,7’ アース線接続部
8 導電性シート
10 基布及び非導電性樹脂層
11 導電性樹脂層
1 flexible container 2 peripheral wall part 3 upper cover part 4 lower cover part 5 input port 6 discharge port 7, 7'ground wire connection part 8 conductive sheet 10 base cloth and non-conductive resin layer 11 conductive resin layer

Claims (6)

導電性ターポリンよりなる周壁部、下蓋部及び上蓋部を接合してなるフレキシブルコンテナであって、
該導電性ターポリンは、前面に非導電性樹脂層が形成され、裏面に導電性樹脂層が形成されており、
該導電性ターポリンは、該導電性樹脂層を該フレキシブルコンテナの内部側として配材されており、
前記下蓋部又は上蓋部を構成する導電性ターポリンの外周部が前記周壁部の外周面に沿って延出し、該周壁部の外周面に接合されているフレキシブルコンテナにおいて、
該下蓋部又は上蓋部からアース線接続部が延出しており、該アース線接続部と周壁部との間に導電性シートが介在しており、前記外周部と周壁部との間に、該導電性シートの基部が挟み込まれて該外周部及び周壁部に対し接合されていることを特徴とするフレキシブルコンテナ。
A flexible container formed by joining a peripheral wall portion made of a conductive tarpaulin, a lower lid portion and an upper lid portion,
The conductive tarpaulin has a non-conductive resin layer formed on the front surface and a conductive resin layer formed on the back surface,
The conductive tarpaulin is provided with the conductive resin layer as the inner side of the flexible container,
In a flexible container in which an outer peripheral portion of a conductive tarpaulin forming the lower lid portion or the upper lid portion extends along an outer peripheral surface of the peripheral wall portion and is joined to an outer peripheral surface of the peripheral wall portion,
A ground wire connecting portion extends from the lower lid portion or the upper lid portion, a conductive sheet is interposed between the ground wire connecting portion and the peripheral wall portion, and between the outer peripheral portion and the peripheral wall portion, A flexible container in which a base portion of the conductive sheet is sandwiched and joined to the outer peripheral portion and the peripheral wall portion.
前記導電性シートのうち、前記基部以外は、前記外周部から延出した自由片となっており、
該自由片の延出長さは前記アース線接続部の延出長さよりも小さいことを特徴とする請求項1のフレキシブルコンテナ。
Of the conductive sheet, other than the base portion is a free piece extending from the outer peripheral portion,
The flexible container according to claim 1, wherein the extension length of the free piece is smaller than the extension length of the ground wire connecting portion.
前記アース線接続部の左右幅は、基端側が先端側よりも大きいことを特徴とする請求項1又は2のフレキシブルコンテナ。 3. The flexible container according to claim 1, wherein the ground wire connecting portion has a lateral width that is larger on the proximal side than on the distal side. 導電性ターポリンよりなる周壁部、下蓋部及び上蓋部を接合してなるフレキシブルコンテナであって、
該導電性ターポリンは、前面に非導電性樹脂層が形成され、裏面に導電性樹脂層が形成されており、
該導電性ターポリンは、該導電性樹脂層を該フレキシブルコンテナの内部側として配材されており、
前記下蓋部又は上蓋部を構成する導電性ターポリンの外周部が前記周壁部の外周面に沿って延出し、該周壁部の外周面に接合されているフレキシブルコンテナにおいて、
該下蓋部又は上蓋部からアース線接続部が延出しており、
前記アース線接続部の左右幅は、基端側が先端側よりも大きいことを特徴とするフレキシブルコンテナ。
A flexible container formed by joining a peripheral wall portion made of a conductive tarpaulin, a lower lid portion and an upper lid portion,
The conductive tarpaulin has a non-conductive resin layer formed on the front surface and a conductive resin layer formed on the back surface,
The conductive tarpaulin is provided with the conductive resin layer as the inner side of the flexible container,
In a flexible container in which the outer peripheral portion of the conductive tarpaulin forming the lower lid portion or the upper lid portion extends along the outer peripheral surface of the peripheral wall portion, and is joined to the outer peripheral surface of the peripheral wall portion,
A ground wire connecting portion extends from the lower lid portion or the upper lid portion,
The flexible container is characterized in that the left and right widths of the ground wire connecting portion are larger on the proximal side than on the distal side.
前記アース線接続部は台形であることを特徴とする請求項4のフレキシブルコンテナ。 The flexible container according to claim 4, wherein the ground wire connection portion has a trapezoidal shape. 請求項1ないし3のいずれか1項に記載のフレキシブルコンテナを製造する方法であって、
前記周壁部を構成する導電性ターポリンと下蓋部又は上蓋部を構成する導電性ターポリンの外周部との間に前記導電性シートの基部を挟み、該周壁部と、導電性シートの基部と、下蓋部又は上蓋部とを高周波溶着する工程を有する
フレキシブルコンテナの製造方法。
A method of manufacturing a flexible container according to any one of claims 1 to 3, comprising:
Sandwiching the base portion of the conductive sheet between the conductive tarpaulin forming the peripheral wall portion and the outer peripheral portion of the conductive tarpaulin forming the lower lid portion or the upper lid portion, the peripheral wall portion, and the base portion of the conductive sheet, A method of manufacturing a flexible container, comprising a step of high-frequency welding a lower lid portion or an upper lid portion.
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5951076A (en) * 1982-08-30 1984-03-24 シバタ工業株式会社 Flexible container
JP2002358827A (en) * 2001-06-04 2002-12-13 Mitsubishi Kagaku Sanshi Corp Conductive tape for flexible container, and conductive flexible container
JP2012250753A (en) * 2011-06-06 2012-12-20 Mitsubishi Plastics Inc Flexible container and method of manufacturing the same
US20140270594A1 (en) * 2013-03-15 2014-09-18 Texene Llc Anti-incendiary flexible intermediate bulk container with induction control

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5951076A (en) * 1982-08-30 1984-03-24 シバタ工業株式会社 Flexible container
JP2002358827A (en) * 2001-06-04 2002-12-13 Mitsubishi Kagaku Sanshi Corp Conductive tape for flexible container, and conductive flexible container
JP2012250753A (en) * 2011-06-06 2012-12-20 Mitsubishi Plastics Inc Flexible container and method of manufacturing the same
US20140270594A1 (en) * 2013-03-15 2014-09-18 Texene Llc Anti-incendiary flexible intermediate bulk container with induction control

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