JP2020079214A - Aerosol type hair temporary colorant composition - Google Patents

Abstract

To provide an aerosol type hair temporary colorant composition which does not make a clothing and a surrounding dirty when a pigment is applied to hair, the pigment on the hair is in a uniform state, which does not make a clothing and a surrounding dirty due to peeling of the pigment after the pigment is applied to hair, which does not cause stiffening in hair after drying and achieves preferable touch and finger passing property capable of achieving softness, and which is excellent in stability in a low temperature condition.SOLUTION: There is provided an aerosol type hair temporary colorant composition comprising: an aerosol stock solution containing (A) a pigment, (B) an alkyl glucose derivative, (C) an anionic surface active agent and (D) an amphoteric polymeric resin compound; and (E) a propellant.SELECTED DRAWING: None

Description

The present invention relates to an aerosol type hair color temporary coloring agent composition.

Aerosol-type temporary hair colorant compositions that use propellants can easily attach pigments and other colorants to hair, produce metallic luster such as "lame" and pearl-like subtle nuances. It is widely used because it can give hair a deep luster and can be easily washed off by washing.

Conventionally, the aerosol type temporary hair colorant composition not only can be easily applied to hair, but in order to improve abrasion resistance and water resistance after drying, in addition to a colorant, a film forming agent or a film forming agent. Some use a polymer thickener (for example, Patent Documents 1 and 2).

JP, 2003-81762, A JP, 2003-26553, A

However, in the conventional technique, there is a problem that when the aerosol type temporary hair coloring composition is applied on the hair, the clothes and the surroundings are soiled due to the scattering. In particular, pearlescent pigments for giving "lame" and "pearl" are light and easily scattered around, and clothes that are applied to the hair or stains around it, and clothes that are peeled off after coloring the hair There was a problem with the surrounding dirt. In addition, since the aerosol type temporary hair colorant composition is applied on the hair and a film forming agent or a polymer thickener is used for the purpose of improving the abrasion resistance and the water resistance after drying, the hair is not stiff. It was easy to occur, and the finger passage and touch were sometimes bad. Further, as a conventional general technique, it is known to use an anionic polymer resin compound as a film forming agent, but there is still room for improvement because a precipitate may be generated under low temperature conditions.

As a result of extensive studies to solve the above problems, the present invention provides an aerosol stock solution containing (A) pigment, (B) alkyl glucose derivative, (C) anionic surfactant and (D) amphoteric polymer resin compound. , (E) a propellant, and it has been found that an aerosol type temporary hair colorant composition can be provided.

The present invention does not stain clothes or surroundings when applying a pigment on hair, the pigment on the hair after application is uniform, and there is no stain on clothes or surroundings due to peeling off after application to hair, It is possible to obtain an aerosol-type temporary hair colorant composition which is capable of obtaining a good feel of the finger and a feeling that the dried hair has no stiffness and feels softness, and is further excellent in stability under low temperature conditions.

Hereinafter, the present invention will be described in detail. The present invention contains (A) a pigment, (B) an alkyl glucose derivative, (C) an anionic surfactant, and (D) an aerosol stock solution containing an amphoteric polymer resin compound, and (E) a propellant. An aerosol type temporary hair colorant composition characterized by:

The aerosol stock solution according to the present invention contains the pigment (A). This has the effect of coloring the hair.

The (A) pigment may be contained in the aerosol undiluted solution, preferably 0.01 to 2% by mass, more preferably 0.05 to 1.5% by mass. When the content of the (A) pigment is less than 0.01% by mass, coloring of hair may not be felt firmly. On the other hand, if it exceeds 2% by mass, problems such as clogging during ejection may occur, and it may not be possible to apply it uniformly on the hair.

The (A) pigment used in the present invention is not particularly limited, and examples thereof include a pearl pigment, an inorganic pigment, an organic pigment, a natural pigment, and the like, and may contain one kind or two or more kinds selected from these. .. In particular, the pearlescent pigment that can give the hair a luster like metal, a subtle nuance like pearl and a deep luster to the hair is light and easily scatters around the hair. And stains around it, and stains around clothes and surroundings due to peeling off after coloring the hair are likely to cause metal-like luster with a pearl pigment, or delicate nuance and deep luster on hair. The present invention is particularly effective for the aerosol type temporary hair coloring composition to be applied.

Specific examples of the pearl pigment include mica titanium, benzalra-coated mica, red iron oxide-coated mica titanium, black iron oxide-coated mica titanium, chromium oxide-coated mica, titanium oxide-coated glass flake, and oxidization that impart pearly luster or metallic luster. Examples thereof include iron-coated glass flakes, bismuth oxychloride, polyethylene terephthalate/polymethyl methacrylate laminated film powder, polyethylene terephthalate/polyolefin laminated film powder, epoxy resin-coated aluminum vapor-deposited polyethylene terephthalate, and acrylic resin-coated aluminum powder. These pearl pigments may contain one kind or two or more kinds.

Specific examples of the inorganic pigment include ultramarine, chromium oxide, red iron oxide, yellow iron oxide, titanium oxide, aluminum hydroxide, zinc oxide, cobalt oxide, black iron oxide, chromium hydroxide, aluminum hydroxide, dark blue, barium sulfate, Examples thereof include hydrous silicate, silicic acid anhydride, aluminum silicate, mica, magnesium carbonate, manganese violet, carbon black, aluminum, copper and gold. These inorganic pigments may contain one kind or two or more kinds.

Specific examples of the organic pigment include red color 202, 203, 204, 205, 206, 207, 208, 219, 220, 221, 228, 404, 405, and daidai color 203, 204, 401. Yellow 205, 401, blue 404, red 104 aluminum lake, yellow 4 aluminum lake, yellow 203 aluminum lake, blue 1 aluminum lake and the like. These organic pigments may contain one kind or two or more kinds.

Specific examples of the natural pigment include mineral pigments such as clay, natural dye lakes such as mudder lake and cochineal lake, azo pigments and phthalocyanine pigments. These natural pigments may contain one kind or two or more kinds.

The aerosol stock solution according to the present invention contains (B) an alkyl glucose derivative. When the alkyl glucose derivative (B) is used in combination with the amphoteric polymer resin compound (D), a coating film having a very good feel and hardly peeling off is formed on the dried hair surface. This has the effect of preventing stains on clothes and the surroundings due to peeling off after coloring the hair, and further, applying the aerosol type temporary hair coloring composition on the hair and making the hair stiff after drying. You can get a good feel and feel that you can feel the softness. As a conventional general technique, it is known to use an oily component such as mineral oil or silicone oil in order to obtain good finger touch and feel that the hair can be felt without being stiff, but ( By using the B) alkyl glucose derivative in combination with the (D) amphoteric polymer resin compound, it is possible to feel softness without stiffening the hair, which is as good as conventional conventional techniques cannot. It is possible to obtain a smooth finger touch and feel, and it is possible to obtain an effect of preventing stains on clothes and the surroundings due to peeling off after coloring the hair.

The alkyl glucose derivative (B) may be contained in the aerosol stock solution, and is preferably 0.01 to 2% by mass, more preferably 0.05 to 1.5% by mass. When the content of the (B) alkyl glucose derivative is less than 0.01% by mass, it may not be possible to sufficiently feel the finger passage of the hair, the feel of the hair, and the softness. If it exceeds 2% by mass, stickiness may be felt.

The (B) alkyl glucose derivative used in the present invention is not particularly limited, but a polyalkylene oxide alkyl glucose derivative is preferable, and polyoxyethylene is preferable, from the viewpoint of providing better effect of finger touch on the hair, touch feeling, and softness. Methyl glucoside, polyoxypropylene methyl glucoside, stearic acid polyoxyethylene methyl glucoside, stearic acid polyoxypropylene methyl glucoside, distearic acid polyoxyethylene methyl glucoside, distearic acid polyoxypropylene methyl glucoside, polyoxyethylene dioleic acid methyl glucoside, etc. And one or more selected from these can be contained.

The undiluted aerosol solution according to the present invention contains (C) an anionic surfactant. As a result, the dispersibility is improved and stable jetting can be performed, so that the pigment can be applied to the hair without soiling the surroundings or clothes.

The (C) anionic surfactant may be contained in the aerosol stock solution, and is preferably 0.01 to 2% by mass, more preferably 0.05 to 1.5% by mass. When the content of the (C) anionic surfactant is less than 0.01% by mass, dispersibility may not be improved and the colorant may not be sprayed cleanly. On the other hand, if the amount exceeds 2% by mass, the viscosity of the entire composition may increase, which may cause problems during ejection.

The (C) anionic surfactant used in the present invention is not particularly limited, but includes polyoxyethylene lauryl ether phosphate, polyoxyethylene alkyl (12-15) ether phosphate, sodium polyoxyethylene lauryl ether phosphate, Examples thereof include sodium polyoxyethylene oleyl ether phosphate, sodium polyoxyethylene cetyl ether phosphate and the like, and one or more selected from these may be contained. Among them, polyoxyethylene lauryl ether phosphoric acid or a salt thereof is preferable from the viewpoint of performing stable injection.

The aerosol stock solution according to the present invention contains (D) an amphoteric polymer resin compound. As described above, the amphoteric polymer resin compound (D) is used in combination with the alkyl glucose derivative (B) to form a coating film on the hair surface after drying, which has a very good feel and does not easily come off. This has the effect of preventing stains on clothes and the surroundings due to peeling off after coloring the hair. Further, the amphoteric polymer resin compound (D) has an effect of improving the stability of the aerosol type temporary hair colorant composition under low temperature conditions.

The amphoteric polymer resin compound (D) may be contained in the aerosol stock solution, and is preferably 0.1 to 10% by mass, more preferably 0.5 to 8% by mass. When the content of the (D) amphoteric polymer resin compound is less than 0.1% by mass, the adhesion of the coloring agent to the hair becomes weak, and the pigment may peel off after drying to stain clothes or the surroundings. There is. On the other hand, if it exceeds 10% by mass, the stability of the aerosol type temporary hair colorant composition under low temperature conditions may be deteriorated.

The amphoteric polymer resin compound (D) used in the present invention is not particularly limited, but from the viewpoint of stability under low temperature conditions, N-methacryloyloxyethyl N,N-dimethylammonium-α-N-methylcarboxybetaine is used. And a copolymer of an alkyl chain with an alkyl methacrylate selected from C1 to 18 are preferable, and one or more selected from them can be contained.

The aerosol type temporary hair coloring composition according to the present invention contains (E) a propellant. The mass ratio of the aerosol stock solution containing the components (A) to (D) and the propellant (E) is preferably aerosol stock solution/propellant=50/50 to 80/20, more preferably 60/40 to 70. The range is /30. When the mass ratio of the (E) propellant is less than 20, ejection may not be performed firmly, and the pigment may not be uniformly applied on the hair. Further, when the mass ratio of the (E) propellant exceeds 50, the momentum of the jetting becomes strong, and the coloring agent may scatter to stain clothes and the surroundings.

The (E) propellant used in the present invention is not particularly limited, but includes liquefied petroleum gas, dimethyl ether, compressed gas and the like, and may contain one kind or two or more kinds selected from these. Among them, liquefied petroleum gas is preferable from the viewpoints of jettability and solubility with an undiluted aerosol solution.

The (E) propellant used in the present invention preferably has an initial internal pressure at 20° C. of 0.2 to 0.6 MPa. The liquefied petroleum gas can be adjusted to an arbitrary initial internal pressure by changing the composition, or can be adjusted by combining liquefied petroleum gas and dimethyl ether.

The aerosol type temporary hair colorant composition according to the present invention may contain, in a range that does not impair the effects of the present invention, components other than the above components, which are usually used in cosmetics. For example, higher alcohols, oils such as higher fatty acids, lower alcohols, humectants, polymer compounds, antioxidants, ultraviolet absorbers, chelating agents, preservatives, antibacterial agents, fragrances, animal and vegetable oils, vitamins, plant extracts, Inorganic salts and the like can be used, and these can contain one kind or two or more kinds depending on the purpose.

Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited to these examples.

The results of various experiments conducted in the evaluation test shown in this specification while changing the components contained in the aerosol stock solution, the content thereof, and the mass ratio of the aerosol stock solution and the propellant are shown below. Here, the unit showing the content of each component of the aerosol type temporary hair coloring agent composition is mass%, and this was prepared by a conventional method.

In the invention described in the present specification, "surroundings at the time of application", "uniformity of pigment on hair after application", "peeling off of pigment after drying", "finger passage and feel of dried hair" And "stability under low temperature conditions".

In the invention shown in the present specification, "surrounding stains upon application", "uniformity of pigment on hair after application", "peeling off of pigment after drying" and "finger passage, feel of dried hair" In the test "," the obtained aerosol stock solution was filled in an aluminum can (Takeuchi Press Kogyo Co., Ltd., outer diameter: 35 mm, shoulder size: 120 mm, inner surface coat: TPL-419), and 2 glass beads (11φ) were filled. An individual container, an aerosol valve and an aerosol button were loaded, a propellant was filled, and an aerosol type temporary hair colorant composition adjusted to 50 g was evaluated.

In the invention shown in the present specification, in the tests of "dirt stains on application", "uniformity of pigment on hair after application" and "finger passage and touch of hair after drying", the obtained aerosol type was used. The temporary hair colorant composition was sprayed on a hair test doll ("Cut mannequin NO.775N" manufactured by Burex Co., Ltd.) at a position of 15 cm for 5 seconds under a condition of 25° C., then sufficiently dried and sprayed. The state was visually confirmed by a specialized panelist, and the feel of the hair was also confirmed for comparative evaluation.

In the invention shown in the present specification, in the test of “peeling off of pigment after drying”, the obtained aerosol type temporary hair colorant composition was subjected to a hair test doll under the condition of 25° C. (manufactured by Beaulux Co., Ltd. Cut mannequin No. 775N”) is sprayed from a position of 15 cm for 5 seconds, dried for 24 hours, and the dried hair test doll is dropped 5 times from a position of 1 cm above the ground, and vibration is applied. The peeling off was visually confirmed by a specialized panel.

In the invention shown in the present specification, in the "stability under low temperature condition" test, the obtained aerosol stock solution was filled in a glass pressure resistant bottle, a valve was attached, a propellant was filled, and the mixture was shaken 10 times. After that, the state after left at 5° C. for 1 month was confirmed.

Evaluation criteria for "dirty stains around the application" ◎: No splattering around 〇: Almost no splattering around △: Slightly splattering around ×: Very splattering around ing

Evaluation criteria for "uniformity of pigment on hair after application" ◎: Pigment can be applied evenly on hair 〇: Pigment can be applied almost evenly on hair △: Pigment is too much on hair Not evenly applied ×: Pigment cannot be applied uniformly on the hair, resulting in uneven color

Evaluation Criteria for "Peeling of Pigment After Drying" ◎: Pigment does not peel off from the hair at all, and there is no stain around it. Pigment is slightly peeled off from the hair, and there is some dirt around it. ×: The pigment is very peeled off from the hair and around it is very dirty.

Evaluation criteria for "passage and feel of hair after drying" ◎: No stiffness of hair, very good softness 〇: No stiffness of hair, good softness △: Roughness of hair, softness Poor x: The hair is stiff and the softness is very bad.

Evaluation criteria for "stability under low temperature conditions" ◎: No change in contents at all under low temperature conditions and no abnormalities 〇: Very slight haze in contents under low temperature conditions, but no problem △ : Abnormality causing slight precipitation in the contents under low temperature conditions x: Abnormality causing precipitation in the contents under low temperature conditions

First Evaluation Test In the first evaluation test, the aerosol type temporary hair colorant composition in which the type and the content of the (A) pigment were changed variously was evaluated. Table 1 shows components, contents and evaluation results of the aerosol type temporary hair coloring composition.

In Examples 1 to 7, good results were obtained even if the type and content of the (A) pigment were variously changed. Further, from Examples 1 to 6, it can be seen that the content of the (A) pigment is preferably 0.01 to 2% by mass, more preferably 0.05 to 1.5% by mass.

Second Evaluation Test In the second evaluation test, the aerosol hair temporary colorant composition in which the type and content of the (B) alkylglucose derivative was variously changed was evaluated. Table 2 shows components, contents and evaluation results of the aerosol type temporary hair coloring composition.

In Examples 8 to 16, good results were obtained even if the type and content of the (B) alkyl glucose derivative were variously changed. Further, from Examples 8 to 14, it can be seen that the content of the (B) alkyl glucose derivative is preferably 0.01 to 2% by mass, more preferably 0.05 to 1.5% by mass.

In Comparative Example 1, when the (B) alkyl glucose derivative was not contained, good results were not obtained.

In Comparative Examples 2-3, good results were not obtained when mineral oil or silicone oil of the prior art was contained instead of the (B) alkyl glucose derivative.

Third Evaluation Test In the third evaluation test, the aerosol type temporary hair colorant composition in which the type and content of the (C) anionic surfactant was variously changed was evaluated. Table 3 shows the components, content and evaluation results of the aerosol type temporary hair coloring composition.

In Examples 17 to 25, good results were obtained even if the type and content of the (C) anionic surfactant were variously changed. Further, from Examples 17 to 23, it is found that the content of the (C) anionic surfactant is preferably 0.01 to 2% by mass, more preferably 0.05 to 1.5% by mass.

In Comparative Example 4, good results were not obtained when the (C) anionic surfactant was not contained.

Fourth Evaluation Test In the fourth evaluation test, the aerosol type temporary hair colorant composition having various contents of the (D) amphoteric polymer resin compound was evaluated. Table 4 shows components, contents and evaluation results of the aerosol type temporary hair coloring composition.

In Examples 26 to 31, good results were obtained even if the content of the (D) amphoteric polymer resin compound was variously changed. Also, it can be seen that the content of the (D) amphoteric polymer resin compound is preferably 0.1 to 10% by mass, more preferably 0.5 to 8% by mass.

In Comparative Example 5, good results were not obtained when the amphoteric polymer resin compound (D) was not contained.

In Comparative Example 6, good results were not obtained when an anionic polymer resin compound of the prior art was contained instead of the (D) amphoteric polymer resin compound.

Fifth Evaluation Test In the fifth evaluation test, the aerosol type temporary hair colorant composition in which the mass ratio of the undiluted aerosol solution and the (E) propellant was changed was evaluated. Table 5 shows components, contents and evaluation results of the aerosol type temporary hair coloring composition.

In Examples 32 to 35, good results were obtained even if the mass ratio of the aerosol stock solution and the (E) propellant was changed variously. Further, the mass ratio of the aerosol stock solution containing the components (A) to (D) and the propellant which is the propellant (E) is preferably aerosol stock solution/propellant=50/50 to 80/20, more preferably It can be seen that is in the range of 60/40 to 70/30.

Prescription examples are given below.

(Example 36)
<Aerosol stock solution>
Component content (mass%)
(A) Mica titanium 0.250
(B) Polyoxypropylene (20) methyl glucoside 0.100
(C) Polyoxyethylene (10) sodium lauryl ether phosphate 0.200
(D) N-methacryloyloxyethyl N,N-dimethylammonium-α-N-methylcarboxybetaine/alkyl methacrylate copolymer 3.135
Perfume 0.050
Ethanol 96.265
Total 100.000
Aerosol stock solution/(E) Liquefied petroleum gas (0.30 MPa)=65/35

From the results of Example 36, even when various tests were performed on the aerosol type temporary hair colorant composition of the present invention, "surrounding stain on application", "uniformity of pigment on hair after application", "drying" Good results were obtained with respect to "after-pigment peeling off", "passage and feel of hair after drying" and "stability under low temperature conditions".

The present invention does not stain clothes or surroundings when applying a pigment on hair, the pigment on the hair after application is uniform, and there is no stain on clothes or surroundings due to peeling off after application to hair, To provide an aerosol-type temporary hair colorant composition capable of obtaining good finger passage and feel, which allows the dried hair to have no stiffness and feel softness, and further has excellent stability under low temperature conditions. You can

Claims (8)

An aerosol stock solution containing (A) pigment, (B) alkyl glucose derivative, (C) anionic surfactant and (D) amphoteric polymer resin compound, and (E) propellant. Aerosol hair temporary colorant composition. The aerosol type temporary hair coloring composition according to claim 1, wherein the (A) pigment is a pearl pigment. Content of the said (B) alkyl glucose derivative is 0.01-2 mass %, The aerosol type temporary hair coloring agent composition of Claim 1 or Claim 2 characterized by the above-mentioned. The aerosol type temporary hair coloring composition according to any one of claims 1 to 3, wherein the (B) alkyl glucose derivative is polyoxypropylene methyl glucoside. Content of the said (C) anionic surfactant is 0.01-2 mass %, The aerosol type temporary coloring agent composition in any one of Claim 1 to 4 characterized by the above-mentioned. Content of the said (D) amphoteric polymer resin compound is 0.1-10 mass %, The aerosol type temporary hair colorant composition in any one of Claim 1 to 5 characterized by the above-mentioned. The mass ratio of the aerosol stock solution and the (E) propellant is aerosol stock solution/propellant=50/50 to 80/20. The aerosol type hair temporary hair according to any one of claims 1 to 6, wherein Colorant composition. (A) a pigment, (B) an alkyl glucose derivative, (C) an anionic surfactant, and (D) an aerosol stock solution containing an amphoteric polymer resin compound, and (E) a propellant. An aerosol type temporary hair colorant composition for imparting pearlescent or metallic luster to hair, wherein the pigment (A) is a pearl pigment.