JPH11171729A - Hair cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a titanated mica-containing hair cosmetic improved in redispersibility and capable of preventing hair from giving a feeling of unnatural brilliance and changing a color of the hair sufficiently when applied to the hair. SOLUTION: This hair cosmetic is obtained by including (A) 0.5 to 10 wt.% of titanated mica, (B) 0.01 to 0.2 wt.% of carboxyvinyl polymer and (C) 0.2 to 3 wt.% of amphoteric high-molecular compounds. As the mica titan, it contains <=20 vol.% titanated mica particles having each sizes of >=20 μm.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hair cosmetic which can temporarily change the color of hair, and more particularly to a hair cosmetic which can stably disperse mica titanium and apply it to hair. The present invention relates to a hair cosmetic capable of changing the color of a hair to a natural feeling.

[0002]

2. Description of the Related Art Conventionally, as a hair cosmetic for giving a change to the color of hair, from the viewpoint of the persistence of the changed color,
Permanent hair dyes (hair color, bleach and color), bleaching agents (bleach), semi-permanent hair dyes (hair manicure), or temporary hair dyes are used.

[0003] Among them, when a permanent hair dye, a semi-permanent hair dye or a bleaching agent is used, problems such as damage to the hair and staining to the skin are likely to occur. It is difficult to handle for treatment,
There is a problem that it is practically impossible to immediately restore the color tone when it is changed to an unintended color tone.

On the other hand, when a temporary hair dye is used, there is no damage to the hair and no staining to the skin, and the temporary hair dye attached to the hair is easily washed off by shampooing the colored hair. There is an advantage that the original color tone can be restored.

Recently, as a kind of such a temporary hair dye, titanium mica having a high hiding power, which has long been used as a pearl gloss imparting agent in cosmetics and hair products, has a high effect of preventing sedimentation of titanium mica. A propellant is added to a stock solution mixed in a mixed solvent of ethanol and water together with a carboxyvinyl polymer as a thickener and an anionic resin as a binder for fixing mica titanium on hair, and a propellant is added. (Japanese Patent Application Laid-Open No. Sho 62-2554) has been proposed.
No. 14). According to the color foam aerosol for hair, an undiluted solution having good redispersibility of titanium mica and hardly caked is obtained, and when applied to hair, titanium mica can be fixed to hair.

[0006]

However, in the case of the color foam aerosol for hair described in JP-A-62-255414, the redispersibility of mica titanium in the stock solution is good, but the agglutination on the hair is difficult. There is a problem that the hair color is not easily changed because the mica titanium is not sufficiently colored, and the hair color cannot be sufficiently changed. In addition, there is a problem that unnaturally strong pearly glitter is imparted to the hair.

The present invention is intended to solve the above-mentioned problems of the prior art, and has a good redispersibility to a hair cosmetic containing titanium mica and an unnatural hair color when applied to hair. It is an object of the present invention to be able to sufficiently change the brightness without causing glitter.

[0008]

Means for Solving the Problems The inventors of the present invention have conducted intensive studies in order to achieve the above object, and have obtained the following findings (1) to (3). Based on these findings, the present inventors have completed the present invention. Was.

(1) In conventional hair cosmetics containing titanium mica, attention was paid to the fact that no consideration was given to the relationship between the particle size of titanium mica and the glittering feeling given to the hair by mica titanium, When relatively small particle diameter titanium mica is used, the proportion of which is relatively small in the total amount of titanium mica used, the hair has a natural feeling without giving the hair a glittering feeling. The ability to change color.

(2) In addition, when such mica titanium having a relatively small particle size is blended into hair cosmetics, it is easy to coagulate, has insufficient redispersibility, easily causes caking, and develops color on hair. Is also inadequate.

(3) Even in the case of using titanium mica having a relatively small particle size, the redispersibility of titanium mica is improved by using a carboxyvinyl polymer and an amphoteric polymer in combination, and hair is improved. The ability to change the color of the hair in a natural way without giving it a sparkling feel.

That is, the present invention attained on the basis of the above findings provides the following components (A), (B) and (C): (A) titanium mica (B) carboxyvinyl polymer (C) amphoteric polymer The content of titanium mica having a particle diameter of 20 μm or more in the total amount of the titanium mica contained in the component (A) is 10% by volume.
A hair cosmetic characterized by the following is provided.

[0013]

DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described below in detail.

The hair cosmetic composition of the present invention contains titanium mica as the component (A), a carboxyvinyl polymer as the component (B), and an amphoteric polymer as the component (C). Preferred combinations of the amounts of these components are 0.5 to 10% by weight of titanium (mica) as component (A), 0.01 to 0.2% by weight of carboxyvinyl polymer as component (B), and A combination in which the amphoteric polymer (C) is used in an amount of 0.2 to 3% by weight can be given.

First, the reason for using titanium mica as the component (A) will be described in more detail.

That is, in general, mica titanium has a maximum dimension of about several μm to about 100 μm and a thickness of about 0.05 to 1 μm.
Flaky natural mica (Mica, biotite, phlogopite, etc.)
Also, the maximum dimension is about 0.1 to about 30 μm and the thickness is about 0.0
The surface of a synthetic mica of 5 to 50 μm is coated with a titanium dioxide layer. Such mica titanium itself has a white appearance, but develops interference colors such as yellow, red, blue, and green depending on the thickness of the titanium dioxide layer. Therefore, by blending titanium mica into a hair cosmetic, when the cosmetic is applied to black hair, the titanium mica adhering to the hair surface develops a very vivid color against a black surface.

The particle size of titanium mica is various, such as a maximum size measured by a microscope or an average value obtained by a light scattering method. The particle size of titanium means a value obtained by the Coulter method. The particle size distribution by the Coulter method can be easily measured, for example, by using a Coulter Multisizer 020487 (with an aperture of 100 μm in diameter) manufactured by Coulter Co., Ltd. as a particle size measuring device. For the calibration, a monodispersed silica latex can be used.
However, in order to measure without aggregating titanium mica particles,
It is necessary to dilute with a surfactant solution (for example, a 0.03% aqueous solution of polyoxyethylene alkyl ether) and perform measurement after sonication.

Commonly available mica titanium is 1-2 μm.
m and a relatively large particle diameter of 20 μm or more. According to the findings discovered by the present inventors, it is a relatively large particle diameter of 20 μm or more that strongly imparts a glittering pearly feeling to hair, and moreover, a mica titanium particle having a particle diameter of 20 μm or more in the total amount of titanium mica. Is more than 10% by volume.

Therefore, in the hair cosmetic of the present invention,
The proportion of titanium mica having a particle size of 20 μm or more in the total amount of titanium mica contained is 10% by volume or less, preferably 7% by volume or less, more preferably 5% by volume or less, and still more preferably 1% by volume or less. By using such titanium mica, the color tone of the hair can be changed in a natural color tone without giving the hair an unnatural glittering pearly feeling.

The structure of titanium oxide in titanium mica includes a rutile type and an anatase type. The rutile type, which has a high refractive index and excellent reflectivity, has a large color change and a vivid hair color. Is preferable.

As a method for forming rutile type titanium oxide on the surface of mica, a method using tin oxide (US Pat. No. 403)
8099 and 4086100), a method using iron and at least one of calcium oxide, magnesium oxide and zinc oxide (JP-A-7-31646).
No. 4) is known, but the latter method is more preferable from the viewpoint of safety.

The titanium mica produced by the latter method contains iron and at least one of calcium oxide, magnesium oxide and zinc oxide. Here, if the content of iron in mica titanium is too small, the interference color of mica titanium is not sufficient, and if it is too large, mica titanium changes to light brown, and the color change when applied to hair becomes beautiful. The amount is preferably 0.125 to 1% by weight based on the weight of the mica particles coated with titanium dioxide. Further, if the content of at least one of calcium, magnesium and zinc in titanium mica is too small, formation of rutile type titanium dioxide becomes insufficient and color change and gloss when applied to hair become poor, so Preferred is at least 0.05% by weight based on the weight of the mica particles coated with titanium.

Various titanium mica can be used as the titanium mica used in the present invention. For example, titanium mica simply coated with titanium dioxide, red mica-coated mica titanium, zinc oxide-coated mica titanium, konjo coated mica titanium, carmine-coated mica titanium, black iron oxide-coated mica titanium, red 226 coated mica titanium, barium sulfate Colored mica titanium, such as coated mica titanium,
There may be mentioned colored mica titanium having a lower titanium oxide layer as disclosed in JP-A-43417.

Specific examples of titanium mica used in the present invention include, for example, a commercially available product,
enco Satin Gold (the ratio of particles having a diameter of 20 μm or more is 0.1% by volume).

As titanium mica, in order to improve its stability and dispersibility in hair cosmetics, for example, silicone oil, aliphatic metal salts, alkyl phosphates, alkali metal salts or alkyl phosphates of alkyl phosphates, N-mono long chain (C8 ~
C22) An aliphatic acyl basic amino acid or a fluorine compound having a perfluoroalkyl group that has been subjected to a surface hydrophobic treatment can be used.

If the content of titanium mica in the hair cosmetic composition of the present invention is too small, the change in hair color is not sufficient, and if it is too large, a rough feel is obtained.
10 to 10% by weight, more preferably 1 to 7% by weight, even more preferably 2 to 5% by weight.

[0027] The hair cosmetic composition of the present invention contains a carboxyvinyl polymer as the component (B). By using a carboxyvinyl polymer, it is generally possible to prevent sedimentation and caking of titanium mica having a relatively high specific gravity among the components of hair cosmetics.

Examples of the carboxyvinyl polymer include, for example, Carbopol 980 and Carbopol 981 (above,
BF Goodrich Co., Ltd.).

When the amount of the carboxyvinyl polymer in the hair cosmetic is too small, the redispersibility of mica titanium is insufficient, and when the amount is too large, the hair cosmetic has a sticky feel. To 0.2% by weight, preferably 0.03 to 0.1% by weight.

The hair cosmetic composition of the present invention contains an amphoteric polymer as the component (C). By using an amphoteric polymer, it is possible to prevent the aggregation of titanium mica on the hair which occurs when other resins such as an anionic resin are used, and to remove the titanium mica without deteriorating the coloring property of the titanium mica. Can be fixed on.

The amphoteric polymer which can be preferably used in the present invention is represented by the formula (1) having a molecular weight of 40,000 to 300,000.

[0032]

Embedded image

(Wherein R ¹ and R ³ are each independently a hydrogen atom or a methyl group, and R ² and R ^{4 each} have 1 to 4 carbon atoms.
Alkylene group (e.g., methylene, ethylene, propylene, etc.) in a, R ⁵ is a saturated or unsaturated hydrocarbon group (e.g. an ethyl group having 1 to 24 carbon atoms, butyl group, octyl group, lauryl group, stearyl A) is absent or an oxygen atom or an NH group, and m and n are numbers satisfying m: n = 20: 80 to 90:10. )). In particular,
Yuka Former 202, Yuka Former SM (all manufactured by Mitsubishi Chemical Corporation) and the like can be mentioned.

If the amount of the amphoteric compound in the hair cosmetic is too small, titanium mica cannot be sufficiently fixed on the hair, and if the amount is too large, the hair may be roughened. % By weight, more preferably 0.5 to 1% by weight
It is.

The hair cosmetic composition of the present invention preferably further contains one or both of a nonionic activator and an anionic activator for the purpose of improving the dispersibility of titanium mica.

Examples of such a nonionic activator include polyoxyethylene alkyl ether, glycerin fatty acid ester, polyoxyethylene hydrogenated castor oil, polyoxyethylene sorbitol fatty acid ester, polyoxyethylene fatty acid ester, and coconut oil diethanolamide. be able to. Examples of the anionic activator include polyoxyethylene alkyl ether phosphate, polyoxyethylene alkyl ether sulfate, alkyl sulfate, and fatty acid salt.

If the total amount of the nonionic activator and the anionic activator in the hair cosmetic is too small, the contribution to the dispersion stability of titanium mica is small, and if it is too large, a sticky feel is obtained. It is 0.1 to 3% by weight, more preferably 0.3 to 1% by weight.

In addition to the amphoteric polymer of the component (C), the hair cosmetic composition of the present invention may contain a polymer for fixing a pigment in order to stably fix titanium mica to hair. . Since the pigment fixing polymer also functions as a hair fixing polymer, a hair cosmetic containing the pigment fixing polymer exhibits a hair styling effect. As such a pigment fixing polymer, an acrylic resin, polyvinylpyrrolidone-
Examples thereof include a vinyl acetate copolymer.

The amount of such a pigment fixing polymer is as follows:
Preferably from 1 to 1000 per 100 parts by weight of mica titanium
Parts by weight, more preferably 10 to 100 parts by weight, even more preferably 20 to 50 parts by weight.

The hair cosmetic composition of the present invention further comprises a cationic surfactant such as stearyltrimethylammonium chloride, an amphoteric surfactant such as laurylbetaine, hydrocarbons such as squalane and liquid paraffin, dimethylpolysiloxane, methyl Silicones such as phenylpolysiloxane and amino-modified silicone, polyols such as glycerin and propylene glycol, thickeners such as xanthan gum, dispersion stabilizers such as clay minerals, oils such as higher alcohols, higher fatty acid esters, animal and vegetable oils, and moisturizing Agents, neutralizers, preservatives, ultraviolet absorbers, antioxidants, vitamins, extracts, fragrances, and the like can be appropriately added as necessary.

The hair cosmetic composition of the present invention may further contain various pigments. Such dyes include, for example, Red No. 3, Red No. 104, Red No. 106, Red No. 20
No. 1, Red No. 202, Red No. 204, Red No. 205, Red No. 220, Red No. 226, Red No. 227, Red No. 228
No. 230, Red No. 401, Red No. 505, Yellow No. 4, Yellow No. 5, Yellow No. 202, Yellow No. 203, Yellow No. 2
04, Yellow 401, Blue 1, Blue 2, Blue 20
No. 1, Blue No. 404, Green No. 3, Green No. 201, Green No. 2
No. 04, green No. 205, orange No. 201, orange No. 203,
Tar dyes such as orange No. 204, orange No. 206 and orange No. 207; dyes commonly used in cosmetics such as natural dyes such as carminic acid, laccaic acid, pradiline and crocin; Further, a pearling agent such as titanium mica, muscovite or synthetic mica having a large particle size can be appropriately blended for a purpose of fashion different from everyday use.

The hair cosmetic composition of the present invention preferably contains water, ethanol, or both as a dispersion medium in addition to the above essential and optional components.

The hair cosmetic composition of the present invention is desired to be in the form of an aerosol in consideration of the form of use. In such a case, it is preferable to include a propellant in addition to titanium mica. . Such propellants include liquefied petroleum gas (LPG), dimethyl ether, carbon dioxide, compressed nitrogen, compressed air and the like. These are 2
More than one species can be used in combination.

In the case of liquefied petroleum gas or dimethyl ether, the amount of the propellant used is the components (A), (B),
(C), preferably 5 to 50% by weight, more preferably 7 to 20% by weight, based on a mixture of other optional components and a dispersion medium.
It is.

Examples of the dosage form suitable for the hair cosmetic composition of the present invention include gel, spray, cream, lotion, foam, wax, spray foam, and post-foaming gel, and among them, foam is preferred.

The hair cosmetic composition of the present invention is preferably used by foaming the foamable contents and filling the foaming tool with an application tool for applying the foam to the object to be coated. By such a combination, it is possible to constitute a foamy hair cosmetic application article that can easily apply the hair cosmetic in the form of a foam to hair. It is preferable that a comb is provided on the application tool of such an application article so that the foamed hair cosmetic is ejected from the tip region of the teeth of the comb. As an example of such a coating tool, the one shown in FIG. 1 can be mentioned. This application tool contains a foamable content (for example, the hair cosmetic of the present invention), and has a spout for ejecting the content and a spout operation unit for spouting the content from the spout. And mounting member 2
And the comb body 3 is attached via the. Here, the comb body 3 has a plurality of hollow comb teeth 4 and a base 5 is provided with a filling chamber in which contents to be jetted are filled. Further, the filling chamber and the hollow portion in the hollow comb teeth 4 have a structure communicating with each other, and an opening 6 for ejecting the contents is provided at the tip of the hollow comb teeth 4.
By configuring in this way, accurately and without waste,
It is possible to apply foamed hair cosmetics to the hair, and at the same time, to style the hair.

[0047]

The present invention will be described below in more detail with reference to examples.

Examples 1 to 5 and Comparative Examples 1 to 4 The components shown in Table 1 were mixed according to a conventional method, and the pH was adjusted to 7.5. 45 g of the obtained mixture and about 1 g of stainless steel balls were put in a commercially available aerosol can, and further 5 g of a propellant (liquefied petroleum gas 0.4 MPa) was charged to prepare an aerosol (foam) type hair cosmetic.

(Evaluation Method) The redispersibility of the hair cosmetics in aerosol cans prepared in the respective Examples and Comparative Examples and the change in hair color when applied to hair were evaluated as described below.

Redispersibility test After the hair cosmetic in which mica titanium was sufficiently dispersed was allowed to stand for 3 days, the aerosol can was shaken up and down, and the number of times the stainless steel ball in the can was shaken was measured. Was evaluated according to the following criteria. In addition, one reciprocation up and down was counted as one time. Table 1 shows the obtained results.

(Redispersibility Evaluation Criteria) Rank: Criteria A: The number of times the stainless steel ball starts moving is within 3 times B: The number of times the stainless steel ball starts moving 4 to 10 times C: The number of times the stainless steel ball starts moving 11 times or more

Hair color change test A foam of hair cosmetics was spouted from an aerosol can, and about 1 g of the foam was applied to a hair tress of 15 cm (about 5 g) in length, combed through and dried. After the drying, the hair color change was visually scored by 10 professional panelists according to the following evaluation criteria, and the average score of the obtained 10 professional panelists was ranked according to the following evaluation criteria. Table 1 shows the obtained results.

It is desirable that the ranking result is A or B for practical purposes.

(Change in hair color) 2 points that have changed greatly 1 point that has changed slightly 0 point that has hardly changed

(Evaluation criteria) Rank: Average point A: 1.5 or more and 2 or less B: 1 or more and less than 1.5 C: 0.5 or more and less than 1 D: less than 0.5

[0056]

(Table 1) (% by weight) Ingredients of Examples Comparative Examples 1 2 3 4 5 1 2 3 4 Titanium Mica A * 1 3.0 5.0 3.0-3.0 3.0 3.0--Titanium Mica B * 2---5.0---5.0- Titanium mica C * 3 − − − − − − − − − 3.0 Carboxyvinyl polymer * 4 0.05 0.03 0.03 0.03 0.15 − 0.05 0.5 0.05 Amphoteric polymer * 5 3.0 5.0 2.5 2.5 2.5 3.0 − − 3.0 Anionic polymer * 6 − − − − − − 2.0 2.0 − Nonionic activator * 7 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Anion activator * 8 − − 0.3 0.3 0.3 − − − − Sodium hydroxide pH adjustment ← ← ← ← ← ← ← ← Ethate acid Disodium 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 Ethanol 15.0 10.0 15.0 15.0 15.0 15.0 15.0 27.0 15.0 Purified water Balance ← ← ← ← ← ← ← ← ← Total 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 (Evaluation) Redispersibility A A A A A C A A A hair color change A A A B A A D D (Table 1 Note) * 1 Flamenco Satin Gold (Mearl Corporation, rutile type), average particle size: 5.2 .mu.m, the proportion of higher particle size 20 [mu] m 0.1 vol% * 2 Timiron Super Gold (Merk Co., anatase) Was classified using an MDS classifier manufactured by Nippon Pneumatic Industries, Ltd .: average particle size 8.7 μm, particle size 20 μm
The above ratio 7.3% by volume * 3 Timiron Super Gold (Merk, anatase type):
14 vol% of average particle diameter 13 μm and particle diameter 20 μm or more * 4 Carbopol 980, manufactured by BF Goodrich Co., Ltd. * 5 Yuka Former 202 (act. 30%), manufactured by Mitsubishi Chemical Corporation * 6 Plus size L-75CB (act. * 7 Polyoxyethylene tridecyl ether (Sophthanol 90, manufactured by Nippon Shokubai Co., Ltd.) * 8 Polyoxyethylene (EO4) lauryl ether phosphate

As shown in Table 1, the hair cosmetics of Examples 1 to 5 had good redispersibility and could sufficiently change the hair color. Moreover, it did not give the hair an unnaturally sparkling feeling.

However, in the case of the hair cosmetic of Comparative Example 1 containing no carboxyvinyl polymer, titanium mica was easily precipitated and redispersibility was insufficient. In addition, in the case of the hair cosmetics of Comparative Example 2 or 3 containing no amphoteric polymer, the change in hair color was poor because titanium mica was easily aggregated on the hair. Further, in the case of Comparative Example 4 using titanium mica having a particle diameter of 20 μm or more and more than 10% by volume, the hair color change was poor, the glittering feeling was strong, and the feeling was unnatural.

Example 6 The components shown in Table 2 were mixed according to a conventional method, and the mixture 45 was used.
g and about 1 g of stainless steel balls were placed in a commercially available aerosol can, and further charged with 5 g of a propellant (liquefied petroleum gas, 0.45 MPa) to obtain a hair cosmetic in a form filled in a hair foam container. About the obtained hair cosmetics,
The redispersibility and hair color change were evaluated in the same manner as in Example 1. Table 2 shows the results. As can be seen from Table 2, Example 6
Showed good results in both redispersibility and hair color change. Moreover, it did not give the hair an unnaturally sparkling feeling.

[0060]

[Table 2] (Table 2 Note) * 9 Flamenco Satin Orange (Mearl, rutile type):
Average particle size 5.4 μm, ratio of particle size 20 μm or more 0.1
Volume% or less * 10 Silicone SH-3775M, manufactured by Dow Corning Toray

Example 7 The components shown in Table 3 were mixed according to a conventional method, and the mixture 45 was used.
g and about 1 g of stainless steel balls were placed in a commercially available aerosol can, and further charged with 5 g of a propellant (liquefied petroleum gas, 0.45 MPa) to obtain a hair cosmetic in a form filled in a hair foam container. About the obtained hair cosmetics,
The redispersibility and hair color change were evaluated in the same manner as in Example 1. Table 3 shows the results. As can be seen from Table 3, Example 7
Showed good results in both redispersibility and hair color change. Moreover, it did not give the hair an unnaturally sparkling feel.

[0062]

[Table 3] (Table 3 note) * 11 Flamenco Satin Red (Mearl, rutile type): average particle size 5.2 μm, particle size 20 μm or more, 0.1% by volume or less

Example 8 The components shown in Table 4 were mixed according to a conventional method, and the mixture 45 was used.
g and about 1 g of stainless steel balls are poured into the coating container with a comb shown in FIG.
By filling with g, a foamed hair cosmetic application product was obtained. The redispersibility and the change in hair color of the obtained foamed hair cosmetic application product were evaluated in the same manner as in Example 1. Table 4 shows the results. As can be seen from Table 4, the foam hair cosmetic application product of Example 8 showed good results in both redispersibility and hair color change. Moreover, it did not give the hair an unnaturally sparkling feel.

[0064]

[Table 4] (Table 4 Note) * 12 Flamenco Satin Blue (Mearl, rutile type):
Average particle size 5.2 μm, ratio of particle size 20 μm or more 0.1
volume%

[0065]

Industrial Applicability The hair cosmetic composition of the present invention containing titanium mica has excellent redispersibility, and when applied to hair, changes the hair color sufficiently without giving an unnatural sparkle. Can be done.

[Brief description of the drawings]

FIG. 1 is a perspective view of a foam hair cosmetic application tool.

[Explanation of symbols]

 Reference Signs List 1 container 2 mounting member 3 comb body 4 hollow comb tooth 5 base 6 opening

 ──────────────────────────────────────────────────続 き Continued on the front page (72) Inventor Rei Hirano 2-1-3 Bunka, Sumida-ku, Tokyo Inside Kao Corporation Research Laboratory (72) Inventor Yoshiaki Ito 2-1-3 Bunka, Sumida-ku, Tokyo Kao Inside the Research Laboratories

Claims (10)

[Claims] 1. A composition comprising the following components (A), (B) and (C): (A) titanium mica (B) carboxyvinyl polymer (C) amphoteric polymer; A hair cosmetic, characterized in that the ratio of titanium mica having a particle diameter of 20 μm or more is 10% by volume or less. 2. Component (A) having a mica titanium content of 0.5 to 10
% By weight of the carboxyvinyl polymer of the component (B)
1 to 0.2% by weight and 0.2% of the amphoteric polymer of the component (C)
The hair cosmetic composition according to claim 1, which contains about 3% by weight. 3. A particle diameter of 20 μm in the total amount of mica titanium.
The hair cosmetic according to claim 1 or 2, wherein the ratio of mica titanium or more is 1% by volume or less. 4. The hair cosmetic according to claim 1, wherein the titanium oxide layer on the surface of the mica titanium is of a rutile type. 5. The hair cosmetic according to claim 4, wherein the mica titanium contains iron and at least one of calcium oxide, magnesium oxide and zinc oxide. 6. The content of iron in the titanium mica is 0.125 to 1% by weight based on the weight of the mica particles, and the content of at least one of calcium, magnesium and zinc is at least 0.05% by weight. The hair cosmetic according to claim 5, which is: 7. The hair cosmetic composition according to claim 1, comprising 0.03 to 0.1% by weight of the carboxyvinyl polymer as the component (B). 8. The amphoteric polymer of the component (C) has a molecular weight of from 40,000 to 300,000. (Wherein, R ¹ and R ³ are each independently a hydrogen atom or a methyl group, R ² and R ⁴ are an alkylene group having 1 to ⁴ carbon atoms, and R ⁵ is a saturated or A is an unsaturated hydrocarbon group, A is absent or an oxygen atom or an NH group, and m and n are m: n = 20: 80-9
This is a number that satisfies 0:10. The hair cosmetic according to any one of claims 1 to 7, which is a compound of the formula (1). 9. The hair cosmetic composition according to claim 1, further comprising one or both of a nonionic activator and an anionic activator. 10. The hair cosmetic composition according to claim 1, further comprising a propellant.