JP2019182957A - Liquid composition - Google Patents
Liquid composition Download PDFInfo
- Publication number
- JP2019182957A JP2019182957A JP2018073154A JP2018073154A JP2019182957A JP 2019182957 A JP2019182957 A JP 2019182957A JP 2018073154 A JP2018073154 A JP 2018073154A JP 2018073154 A JP2018073154 A JP 2018073154A JP 2019182957 A JP2019182957 A JP 2019182957A
- Authority
- JP
- Japan
- Prior art keywords
- liquid composition
- stabilizer
- stabilizers
- mass
- hcfo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 57
- 239000007788 liquid Substances 0.000 title claims abstract description 51
- 239000003381 stabilizer Substances 0.000 claims abstract description 54
- ZHJBJVPTRJNNIK-UPHRSURJSA-N (z)-1,2-dichloro-3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)C(\Cl)=C\Cl ZHJBJVPTRJNNIK-UPHRSURJSA-N 0.000 claims abstract description 4
- AYRPZBVEKSYAAD-UHFFFAOYSA-N 1,1,3-trichloro-2,3,3-trifluoroprop-1-ene Chemical compound ClC(Cl)=C(F)C(F)(F)Cl AYRPZBVEKSYAAD-UHFFFAOYSA-N 0.000 claims abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 9
- 239000004593 Epoxy Substances 0.000 claims description 7
- ACIAHEMYLLBZOI-ZZXKWVIFSA-N Unsaturated alcohol Chemical compound CC\C(CO)=C/C ACIAHEMYLLBZOI-ZZXKWVIFSA-N 0.000 claims description 7
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 7
- 239000012459 cleaning agent Substances 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 230000007797 corrosion Effects 0.000 abstract description 17
- 238000005260 corrosion Methods 0.000 abstract description 17
- 239000002184 metal Substances 0.000 abstract description 14
- 229910052751 metal Inorganic materials 0.000 abstract description 14
- 150000001875 compounds Chemical class 0.000 description 17
- 239000002253 acid Substances 0.000 description 7
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- 239000003921 oil Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000003507 refrigerant Substances 0.000 description 4
- -1 4-propen-1-ol Chemical compound 0.000 description 3
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 230000000087 stabilizing effect Effects 0.000 description 3
- ZHJBJVPTRJNNIK-OWOJBTEDSA-N (e)-1,2-dichloro-3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)C(\Cl)=C/Cl ZHJBJVPTRJNNIK-OWOJBTEDSA-N 0.000 description 2
- KDSNLYIMUZNERS-UHFFFAOYSA-N 2-methylpropanamine Chemical compound CC(C)CN KDSNLYIMUZNERS-UHFFFAOYSA-N 0.000 description 2
- HNVRRHSXBLFLIG-UHFFFAOYSA-N 3-hydroxy-3-methylbut-1-ene Chemical compound CC(C)(O)C=C HNVRRHSXBLFLIG-UHFFFAOYSA-N 0.000 description 2
- VVJKKWFAADXIJK-UHFFFAOYSA-N Allylamine Chemical compound NCC=C VVJKKWFAADXIJK-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 2
- AFBPFSWMIHJQDM-UHFFFAOYSA-N N-methylaniline Chemical compound CNC1=CC=CC=C1 AFBPFSWMIHJQDM-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- WGQKYBSKWIADBV-UHFFFAOYSA-N benzylamine Chemical compound NCC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-N 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- SBUXRMKDJWEXRL-ROUUACIJSA-N cis-body Chemical compound O=C([C@H]1N(C2=O)[C@H](C3=C(C4=CC=CC=C4N3)C1)CC)N2C1=CC=C(F)C=C1 SBUXRMKDJWEXRL-ROUUACIJSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 2
- GGSUCNLOZRCGPQ-UHFFFAOYSA-N diethylaniline Chemical compound CCN(CC)C1=CC=CC=C1 GGSUCNLOZRCGPQ-UHFFFAOYSA-N 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical compound CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000004088 foaming agent Substances 0.000 description 2
- LHGVFZTZFXWLCP-UHFFFAOYSA-N guaiacol Chemical compound COC1=CC=CC=C1O LHGVFZTZFXWLCP-UHFFFAOYSA-N 0.000 description 2
- 239000010687 lubricating oil Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000008204 material by function Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- MKUWVMRNQOOSAT-UHFFFAOYSA-N methylvinylmethanol Natural products CC(O)C=C MKUWVMRNQOOSAT-UHFFFAOYSA-N 0.000 description 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 2
- DPBLXKKOBLCELK-UHFFFAOYSA-N pentan-1-amine Chemical compound CCCCCN DPBLXKKOBLCELK-UHFFFAOYSA-N 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- ASUAYTHWZCLXAN-UHFFFAOYSA-N prenol Chemical compound CC(C)=CCO ASUAYTHWZCLXAN-UHFFFAOYSA-N 0.000 description 2
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 description 2
- SBUXRMKDJWEXRL-ZWKOTPCHSA-N trans-body Chemical compound O=C([C@@H]1N(C2=O)[C@H](C3=C(C4=CC=CC=C4N3)C1)CC)N2C1=CC=C(F)C=C1 SBUXRMKDJWEXRL-ZWKOTPCHSA-N 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- JEYLKNVLTAPJAF-UHFFFAOYSA-N xi-3-Methyl-3-buten-2-ol Chemical compound CC(O)C(C)=C JEYLKNVLTAPJAF-UHFFFAOYSA-N 0.000 description 2
- MEIRRNXMZYDVDW-MQQKCMAXSA-N (2E,4E)-2,4-hexadien-1-ol Chemical compound C\C=C\C=C\CO MEIRRNXMZYDVDW-MQQKCMAXSA-N 0.000 description 1
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- 239000001714 (E)-hex-2-en-1-ol Substances 0.000 description 1
- RBACIKXCRWGCBB-UHFFFAOYSA-N 1,2-Epoxybutane Chemical compound CCC1CO1 RBACIKXCRWGCBB-UHFFFAOYSA-N 0.000 description 1
- FVHAWXWFPBPFOS-UHFFFAOYSA-N 1,2-dimethyl-3-nitrobenzene Chemical compound CC1=CC=CC([N+]([O-])=O)=C1C FVHAWXWFPBPFOS-UHFFFAOYSA-N 0.000 description 1
- IZUKQUVSCNEFMJ-UHFFFAOYSA-N 1,2-dinitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1[N+]([O-])=O IZUKQUVSCNEFMJ-UHFFFAOYSA-N 0.000 description 1
- WDCYWAQPCXBPJA-UHFFFAOYSA-N 1,3-dinitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC([N+]([O-])=O)=C1 WDCYWAQPCXBPJA-UHFFFAOYSA-N 0.000 description 1
- FYFDQJRXFWGIBS-UHFFFAOYSA-N 1,4-dinitrobenzene Chemical compound [O-][N+](=O)C1=CC=C([N+]([O-])=O)C=C1 FYFDQJRXFWGIBS-UHFFFAOYSA-N 0.000 description 1
- ARKIFHPFTHVKDT-UHFFFAOYSA-N 1-(3-nitrophenyl)ethanone Chemical compound CC(=O)C1=CC=CC([N+]([O-])=O)=C1 ARKIFHPFTHVKDT-UHFFFAOYSA-N 0.000 description 1
- BMVXCPBXGZKUPN-UHFFFAOYSA-N 1-hexanamine Chemical compound CCCCCCN BMVXCPBXGZKUPN-UHFFFAOYSA-N 0.000 description 1
- JSZOAYXJRCEYSX-UHFFFAOYSA-N 1-nitropropane Chemical compound CCC[N+]([O-])=O JSZOAYXJRCEYSX-UHFFFAOYSA-N 0.000 description 1
- RQEUFEKYXDPUSK-UHFFFAOYSA-N 1-phenylethylamine Chemical compound CC(N)C1=CC=CC=C1 RQEUFEKYXDPUSK-UHFFFAOYSA-N 0.000 description 1
- YSUQLAYJZDEMOT-UHFFFAOYSA-N 2-(butoxymethyl)oxirane Chemical compound CCCCOCC1CO1 YSUQLAYJZDEMOT-UHFFFAOYSA-N 0.000 description 1
- WCASXYBKJHWFMY-NSCUHMNNSA-N 2-Buten-1-ol Chemical compound C\C=C\CO WCASXYBKJHWFMY-NSCUHMNNSA-N 0.000 description 1
- ZCHHRLHTBGRGOT-SNAWJCMRSA-N 2-Hexen-1-ol Natural products CCC\C=C\CO ZCHHRLHTBGRGOT-SNAWJCMRSA-N 0.000 description 1
- BZAZNULYLRVMSW-UHFFFAOYSA-N 2-Methyl-2-buten-3-ol Natural products CC(C)=C(C)O BZAZNULYLRVMSW-UHFFFAOYSA-N 0.000 description 1
- SEFYJVFBMNOLBK-UHFFFAOYSA-N 2-[2-[2-(oxiran-2-ylmethoxy)ethoxy]ethoxymethyl]oxirane Chemical compound C1OC1COCCOCCOCC1CO1 SEFYJVFBMNOLBK-UHFFFAOYSA-N 0.000 description 1
- LTHNHFOGQMKPOV-UHFFFAOYSA-N 2-ethylhexan-1-amine Chemical compound CCCCC(CC)CN LTHNHFOGQMKPOV-UHFFFAOYSA-N 0.000 description 1
- ZCHHRLHTBGRGOT-UHFFFAOYSA-N 2-hexen-1-ol Chemical compound CCCC=CCO ZCHHRLHTBGRGOT-UHFFFAOYSA-N 0.000 description 1
- NJBCRXCAPCODGX-UHFFFAOYSA-N 2-methyl-n-(2-methylpropyl)propan-1-amine Chemical compound CC(C)CNCC(C)C NJBCRXCAPCODGX-UHFFFAOYSA-N 0.000 description 1
- CFBYEGUGFPZCNF-UHFFFAOYSA-N 2-nitroanisole Chemical compound COC1=CC=CC=C1[N+]([O-])=O CFBYEGUGFPZCNF-UHFFFAOYSA-N 0.000 description 1
- IQUPABOKLQSFBK-UHFFFAOYSA-N 2-nitrophenol Chemical compound OC1=CC=CC=C1[N+]([O-])=O IQUPABOKLQSFBK-UHFFFAOYSA-N 0.000 description 1
- FGLBSLMDCBOPQK-UHFFFAOYSA-N 2-nitropropane Chemical compound CC(C)[N+]([O-])=O FGLBSLMDCBOPQK-UHFFFAOYSA-N 0.000 description 1
- PLAZTCDQAHEYBI-UHFFFAOYSA-N 2-nitrotoluene Chemical compound CC1=CC=CC=C1[N+]([O-])=O PLAZTCDQAHEYBI-UHFFFAOYSA-N 0.000 description 1
- FDMFUZHCIRHGRG-UHFFFAOYSA-N 3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)C=C FDMFUZHCIRHGRG-UHFFFAOYSA-N 0.000 description 1
- NSPPRYXGGYQMPY-UHFFFAOYSA-N 3-Methylbuten-2-ol-1 Natural products CC(C)C(O)=C NSPPRYXGGYQMPY-UHFFFAOYSA-N 0.000 description 1
- WGYFINWERLNPHR-UHFFFAOYSA-N 3-nitroanisole Chemical compound COC1=CC=CC([N+]([O-])=O)=C1 WGYFINWERLNPHR-UHFFFAOYSA-N 0.000 description 1
- RTZZCYNQPHTPPL-UHFFFAOYSA-N 3-nitrophenol Chemical compound OC1=CC=CC([N+]([O-])=O)=C1 RTZZCYNQPHTPPL-UHFFFAOYSA-N 0.000 description 1
- QZYHIOPPLUPUJF-UHFFFAOYSA-N 3-nitrotoluene Chemical compound CC1=CC=CC([N+]([O-])=O)=C1 QZYHIOPPLUPUJF-UHFFFAOYSA-N 0.000 description 1
- BTJIUGUIPKRLHP-UHFFFAOYSA-N 4-nitrophenol Chemical compound OC1=CC=C([N+]([O-])=O)C=C1 BTJIUGUIPKRLHP-UHFFFAOYSA-N 0.000 description 1
- ZPTVNYMJQHSSEA-UHFFFAOYSA-N 4-nitrotoluene Chemical compound CC1=CC=C([N+]([O-])=O)C=C1 ZPTVNYMJQHSSEA-UHFFFAOYSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- BWLUMTFWVZZZND-UHFFFAOYSA-N Dibenzylamine Chemical compound C=1C=CC=CC=1CNCC1=CC=CC=C1 BWLUMTFWVZZZND-UHFFFAOYSA-N 0.000 description 1
- 229920001174 Diethylhydroxylamine Polymers 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- BNUHAJGCKIQFGE-UHFFFAOYSA-N Nitroanisol Chemical compound COC1=CC=C([N+]([O-])=O)C=C1 BNUHAJGCKIQFGE-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- FQYUMYWMJTYZTK-UHFFFAOYSA-N Phenyl glycidyl ether Chemical compound C1OC1COC1=CC=CC=C1 FQYUMYWMJTYZTK-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- FVCOIAYSJZGECG-UHFFFAOYSA-N diethylhydroxylamine Chemical compound CCN(O)CC FVCOIAYSJZGECG-UHFFFAOYSA-N 0.000 description 1
- 229940043279 diisopropylamine Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229960001867 guaiacol Drugs 0.000 description 1
- 125000001475 halogen functional group Chemical group 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 1
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- DYUWTXWIYMHBQS-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCNCC=C DYUWTXWIYMHBQS-UHFFFAOYSA-N 0.000 description 1
- MCSAJNNLRCFZED-UHFFFAOYSA-N nitroethane Chemical compound CC[N+]([O-])=O MCSAJNNLRCFZED-UHFFFAOYSA-N 0.000 description 1
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 229940100684 pentylamine Drugs 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- VPYJNCGUESNPMV-UHFFFAOYSA-N triallylamine Chemical compound C=CCN(CC=C)CC=C VPYJNCGUESNPMV-UHFFFAOYSA-N 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
Description
本開示は、液状組成物に関する。 The present disclosure relates to liquid compositions.
近年、冷媒、洗浄剤、溶剤、スプレー剤、発泡剤、作動流体、各種機能性材料等の分野においてオゾン層破壊の影響、及び、地球温暖化係数（Global Warming Potential；以下、単にＧＷＰという。）が低い液状組成物が提案されている。具体的には、二重結合及び塩素を有するＨＣＦＯ及びＣＦＯといったハロオレフィン系化合物を含有する液状組成物が提案されている。特許文献１においては、（Ｚ）−１，２−ジクロロ−３，３，３−トリフルオロプロペン（１２２３ｘｄ）及び（Ｅ）−１，２−ジクロロ−３，３，３−トリフルオロプロペン（１２２３ｘｄ）を含む共沸（様）組成物が提案されている。 In recent years, in the fields of refrigerants, cleaning agents, solvents, spray agents, foaming agents, working fluids, various functional materials, etc., the effects of ozone depletion and the Global Warming Potential (hereinafter simply referred to as GWP). A liquid composition having a low value has been proposed. Specifically, liquid compositions containing haloolefin compounds such as HCFO and CFO having a double bond and chlorine have been proposed. In Patent Document 1, (Z) -1,2-dichloro-3,3,3-trifluoropropene (1223xd) and (E) -1,2-dichloro-3,3,3-trifluoropropene (1223xd) are disclosed. ) Azeotropic (like) compositions have been proposed.
特許文献１において提案されている組成物は、上記の２成分を所定の比率で配合した際に、共沸（様）の性質を有するというものであり、開放条件で使用しても、その組成が変化しにくいとされている。 The composition proposed in Patent Document 1 has an azeotropic (like) property when the above two components are blended at a predetermined ratio. Is said to be difficult to change.
また、特許文献２記載されている組成物は、安定性に優れるとされている。ハロオレフィン系化合物を含有する液状組成物は、その安定性において、課題を有している。冷媒や洗浄剤等の用途に使用されるに際して、ハロオレフィン系化合物が金属面に接触することは、ほぼ不可避であるが、ハロオレフィン系化合物から酸が遊離し、金属表面に接触すると、金属表面を腐食させることとなる。 Further, the composition described in Patent Document 2 is said to be excellent in stability. The liquid composition containing a haloolefin compound has a problem in its stability. When used in applications such as refrigerants and cleaning agents, it is almost inevitable that the haloolefin compound comes into contact with the metal surface, but when the acid is released from the haloolefin compound and comes into contact with the metal surface, the metal surface Will be corroded.
例えば液状組成物を冷媒として使用するような場合、金属配管内表面を腐食させることとなり、配管の劣化を促進することとなってしまう。また、洗浄液として使用するような場合、被洗浄面を洗浄するどころか、腐食させてしまう。特許文献２において提案されている組成物は、かかる不具合の発生を抑制できるものとして期待される。 For example, when a liquid composition is used as a refrigerant, the inner surface of the metal pipe is corroded, and the deterioration of the pipe is promoted. Further, when used as a cleaning liquid, the surface to be cleaned is corroded rather than cleaned. The composition proposed in Patent Document 2 is expected to be able to suppress the occurrence of such problems.
しかしながら、上記特許文献２に記載されているような組成物をもってしても、安定性に関して十分な性能を有しているとは言い切れず、より優れた安定性を有し、金属と接触しても金属表面における腐食発生が抑制された液状組成物が求められている。 However, even with a composition such as that described in Patent Document 2, it cannot be said that it has sufficient performance in terms of stability, has better stability, and is in contact with metal. However, there is a demand for a liquid composition in which the occurrence of corrosion on the metal surface is suppressed.
上記のような事情に鑑み、本開示は、金属の腐食発生が抑制された液状組成物を提案する。 In view of the above circumstances, the present disclosure proposes a liquid composition in which the occurrence of metal corrosion is suppressed.
即ち、本開示は、以下の液状組成物を提供する。
項１．
１，２−ジクロロ−３，３，３−トリフルオロプロペン（ＨＣＦＯ−１２２３ｘｄ）及び／又は１,１,３−トリクロロ−２,３,３−トリフルオロプロペン（ＣＦＯ−１２１３ｙａ）、並びに安定剤を含むことを特徴とする、液状組成物。
項２．
前記安定剤は、不飽和アルコール系安定剤、ニトロ系安定剤、アミン系安定剤、フェノール系安定剤、及びエポキシ系安定剤からなる群より選ばれる１種以上である、項１に記載の液状組成物。
項３．
前記安定剤が、
エポキシ系安定剤並びに、
不飽和アルコール系安定剤、ニトロ系安定剤、及びフェノール系安定剤からなる群より選ばれる１種以上からなる、項１に記載の液状組成物。
項４．
水を２００ｐｐｍ以下含有する、項１〜３の何れかに記載の液状組成物。
項５．
項１〜４の何れかに記載の液状組成物を含有する溶剤。
項６．
項１〜４の何れかに記載の液状組成物を含有する洗浄剤。
That is, the present disclosure provides the following liquid composition.
Item 1.
1,2-dichloro-3,3,3-trifluoropropene (HCFO-1223xd) and / or 1,1,3-trichloro-2,3,3-trifluoropropene (CFO-1213ya), and stabilizer A liquid composition characterized by comprising.
Item 2.
Item 2. The liquid according to Item 1, wherein the stabilizer is at least one selected from the group consisting of an unsaturated alcohol stabilizer, a nitro stabilizer, an amine stabilizer, a phenol stabilizer, and an epoxy stabilizer. Composition.
Item 3.
The stabilizer is
Epoxy stabilizers,
Item 2. The liquid composition according to Item 1, comprising at least one selected from the group consisting of unsaturated alcohol stabilizers, nitro stabilizers, and phenol stabilizers.
Item 4.
Item 4. The liquid composition according to any one of Items 1 to 3, containing 200 ppm or less of water.
Item 5.
Item 5. A solvent containing the liquid composition according to any one of Items 1 to 4.
Item 6.
Item 5. A cleaning agent comprising the liquid composition according to any one of Items 1 to 4.
本開示の液状組成物によれば、金属の腐食発生が少ない。 According to the liquid composition of the present disclosure, the occurrence of metal corrosion is small.
本発明者らは上記課題を解決すべく鋭意研究を重ねた結果、所定のハロオレフィン系化合物を、安定剤と共に使用した液状組成物とすることで金属の腐食発生を抑制できることを見出した。本開示は、かかる知見に基づきさらに研究を重ね、得られたものである。 As a result of intensive studies to solve the above problems, the present inventors have found that the occurrence of metal corrosion can be suppressed by using a predetermined haloolefin compound as a liquid composition using a stabilizer. The present disclosure has been obtained by further research based on such knowledge.
本開示における液状組成物は、１，２−ジクロロ−３，３，３−トリフルオロプロペン（以下、単にＨＣＦＯ−１２２３ｘｄという。）及び／又は１,１,３−トリクロロ−２,３,３−トリフルオロプロペン（以下、単にＣＦＯ−１２１３ｙａという。）、並びに安定剤を含むことを特徴とする。 The liquid composition in the present disclosure includes 1,2-dichloro-3,3,3-trifluoropropene (hereinafter simply referred to as HCFO-1223xd) and / or 1,1,3-trichloro-2,3,3-. It includes trifluoropropene (hereinafter simply referred to as CFO-1213ya) and a stabilizer.
ハロオレフィン系化合物
ＨＣＦＯ−１２２３ｘｄは、C(CF3)Cl=CHClで表わされるハロオレフィン系化合物である。当該化合物は、例えば、特開２０１４−２１０７６５号公報に開示される方法など、公知の製造方法により得ることが可能である。また、ＨＣＦＯ−１２２３ｘｄは、ｃｉｓ体（Ｚ体）であっても、ｔｒａｎｓ体（Ｅ体）であってもよい。また、ｃｉｓ体及びｔｒａｎｓ体が共存する態様であってもよい。
The haloolefin compound HCFO-1223xd is a haloolefin compound represented by C (CF 3 ) Cl═CHCl. The compound can be obtained by a known production method such as the method disclosed in Japanese Patent Application Laid-Open No. 2014-210765. HCFO-1223xd may be a cis body (Z body) or a trans body (E body). Moreover, the aspect which a cis body and a trans body coexist may be sufficient.
ＣＦＯ−１２１３ｙａは、C(CF2Cl)F=CCl2で表わされるハロオレフィン系化合物である。当該化合物は、例えば、特開２０１０−２４１８０７号公報に開示される方法など、公知の製造方法により得ることが可能である。 CFO-1213ya is halo olefinic compound represented by C (CF 2 Cl) F = CCl 2. The compound can be obtained by a known production method such as the method disclosed in JP2010-241807A.
本開示における液状組成物は、該液状組成物１００質量％中に、ＨＣＦＯ−１２２３ｘｄ及び／又はＣＦＯ−１２１３ｙａを、７５質量％以上含むことが好ましく、９０質量％以上含むことがより好ましい。ＨＣＦＯ−１２２３ｘｄ及び／又はＣＦＯ−１２１３ｙａが７５質量％以上含まれることにより、ＨＣＦＯ−１２２３ｘｄが持つ優れた溶解性と乾燥性を発揮できる。 The liquid composition in the present disclosure preferably contains 75 mass% or more, more preferably 90 mass% or more of HCFO-1223xd and / or CFO-1213ya in 100 mass% of the liquid composition. By including 75 mass% or more of HCFO-1223xd and / or CFO-1213ya, the excellent solubility and drying property of HCFO-1223xd can be exhibited.
一方、本開示における液状組成物は、該液状組成物１００質量％中に、ＨＣＦＯ−１２２３ｘｄ及び／又はＣＦＯ−１２１３ｙａが９９．９９９９質量％以下含まれることが好ましく、９９．９９質量％以下含まれることがより好ましい。 On the other hand, the liquid composition in the present disclosure preferably contains 99.9999% by mass or less of HCFO-1223xd and / or CFO-1213ya and 100.99% by mass or less in 100% by mass of the liquid composition. It is more preferable.
安定剤
安定剤は、安定化効果を発揮することでいわゆる受酸剤又は酸化防止剤としての機能を発揮するものである。安定化効果としては、系内に発生するラジカルを補足することでＨＣＦＯ−１２２３ｘｄ及び／又はＣＦＯ−１２１３ｙａの分解を防止する効果、系内に発生した酸を捕捉することで、酸によるさらなるＨＣＦＯ−１２２３ｘｄ及び／又はＣＦＯ−１２１３ｙａの分解等を防止する受酸効果などが主要なものとしてあげられる。かかる安定剤としては、公知の安定剤を広く採用することが可能である。中でも、液状組成物による金属の腐食発生を効果的に抑制できることから、不飽和アルコール系安定剤、ニトロ系安定剤、アミン系安定剤、フェノール系安定剤、及びエポキシ系安定剤からなる群より選ばれる１種以上の安定剤を使用することが好ましい。
The stabilizer stabilizer exhibits a function as a so-called acid acceptor or antioxidant by exhibiting a stabilizing effect. As a stabilizing effect, an effect of preventing decomposition of HCFO-1223xd and / or CFO-1213ya by capturing radicals generated in the system, and an additional HCFO- by acid by capturing the acid generated in the system An acid accepting effect that prevents decomposition of 1223xd and / or CFO-1213ya is a major one. As such a stabilizer, known stabilizers can be widely used. Among them, since it can effectively suppress the occurrence of metal corrosion due to the liquid composition, it is selected from the group consisting of unsaturated alcohol stabilizers, nitro stabilizers, amine stabilizers, phenol stabilizers, and epoxy stabilizers. It is preferred to use one or more stabilizers.
不飽和アルコール系安定剤としては、公知のものを広く採用することが可能である。特に限定はなく、例えば、３−ブテン−２−オール、２−ブテン−１−オール、４−プロペン−１−オール、１−プロペン−３−オール、２−メチル−３−ブテン−２−オール、３−メチル−３−ブテン−２−オール、３−メチル−２−ブテン−１−オール、２−ヘキセン−１−オール、２，４−ヘキサジエン−１−オール、及びオレイルアルコールからなる群より選択される１種以上を使用することができる。 A wide variety of known unsaturated alcohol stabilizers can be used. There is no particular limitation, for example, 3-buten-2-ol, 2-buten-1-ol, 4-propen-1-ol, 1-propen-3-ol, 2-methyl-3-buten-2-ol , 3-methyl-3-buten-2-ol, 3-methyl-2-buten-1-ol, 2-hexen-1-ol, 2,4-hexadien-1-ol, and oleyl alcohol One or more selected can be used.
ニトロ系安定剤としては、公知のものを広く採用することが可能である。特に限定はなく、例えば、脂肪族ニトロ化合物として、例えば、ニトロメタン、ニトロエタン、１−ニトロプロパン、２−ニトロプロパン等が挙げられる。芳香族ニトロ化合物として、例えば、ニトロベンゼン、ｏ−、ｍ−又はｐ−ジニトロベンゼン、ｏ−、ｍ−又はｐ−ニトロトルエン、ジメチルニトロベンゼン、ｍ−ニトロアセトフェノン、ｏ−、ｍ−又はｐ−ニトロフェノール、ｏ−ニトロアニソール、ｍ−ニトロアニソール、及びｐ−ニトロアニソールからなる群より選択される１種以上を使用することができる。 A wide variety of known nitro stabilizers can be used. There is no particular limitation, and examples of the aliphatic nitro compound include nitromethane, nitroethane, 1-nitropropane, 2-nitropropane and the like. As aromatic nitro compounds, for example, nitrobenzene, o-, m- or p-dinitrobenzene, o-, m- or p-nitrotoluene, dimethylnitrobenzene, m-nitroacetophenone, o-, m- or p-nitrophenol, One or more selected from the group consisting of o-nitroanisole, m-nitroanisole, and p-nitroanisole can be used.
アミン系安定剤としては、公知のものを広く採用することが可能である。特に限定はなく、例えば、ペンチルアミン、ヘキシルアミン、ジイソプロピルアミン、ジイソブチルアミン、ジ−ｎ−プロピルアミン、ジアリルアミン、トリエチルアミン、Ｎ−メチルアニリン、ピリジン、モルホリン、Ｎ−メチルモルホリン、トリアリルアミン、アリルアミン、α−メチルベンジルアミン、ジメチルアミン、トリメチルアミン、エチルアミン、ジエチルアミン、トリエチルアミン、プロピルアミン、イソプロピルアミン、ジプロピルアミン、トリプロピルアミン、ブチルアミン、イソブチルアミン、ジブチルアミン、トリブチルアミン、ジベンチルアミン、トリベンチルアミン、２−エチルヘキシルアミン、アニリン、Ｎ，Ｎ−ジメチルアニリン、Ｎ，Ｎ−ジエチルアニリン、エチレンジアミン、プロピレンジアミン、ジエチレントリアミン、テトラエチレンペンタミン、ベンジルアミン、ジベンジルアミン、ジフェニルアミン、及びジエチルヒドロキシルアミンからなる群より選択される１種以上を使用することができる。 A wide variety of known stabilizers can be used as the amine stabilizer. There is no particular limitation, for example, pentylamine, hexylamine, diisopropylamine, diisobutylamine, di-n-propylamine, diallylamine, triethylamine, N-methylaniline, pyridine, morpholine, N-methylmorpholine, triallylamine, allylamine, α -Methylbenzylamine, dimethylamine, trimethylamine, ethylamine, diethylamine, triethylamine, propylamine, isopropylamine, dipropylamine, tripropylamine, butylamine, isobutylamine, dibutylamine, tributylamine, diventylamine, triventylamine, 2 -Ethylhexylamine, aniline, N, N-dimethylaniline, N, N-diethylaniline, ethylenediamine, propylenediamine, di Chirentoriamin, can be used tetraethylenepentamine, benzylamine, dibenzylamine, diphenylamine, and at least one selected from the group consisting of diethylhydroxylamine.
フェノール系安定剤としては、公知のものを広く採用することが可能である。特に限定はなく、例えば、２，６−ジターシャリーブチル−４−メチルフェノール、３−クレゾール、フェノール、１，２−ベンゼンジオール、２−イソプロピル−５−メチルフェノール、及び２−メトキシフェノールからなる群より選択される１種以上を使用することができる。 Known phenolic stabilizers can be widely used. There is no particular limitation, for example, a group consisting of 2,6-ditertiarybutyl-4-methylphenol, 3-cresol, phenol, 1,2-benzenediol, 2-isopropyl-5-methylphenol, and 2-methoxyphenol One or more selected from more can be used.
エポキシ系安定剤としては、公知のものを広く採用することが可能である。特に限定はなく、例えば、ブチレンオキシド、１，２−プロピレンオキシド、１，２−ブチレンオキシド、ブチルグリシジルエーテル、ジエチレングリコールジグリシジルエーテル、及び１，２−エポキシ−３−フェノキシプロパンからなる群より選択される１種以上を使用することができる。 A wide variety of known epoxy-based stabilizers can be used. There is no particular limitation, for example, selected from the group consisting of butylene oxide, 1,2-propylene oxide, 1,2-butylene oxide, butyl glycidyl ether, diethylene glycol diglycidyl ether, and 1,2-epoxy-3-phenoxypropane. One or more can be used.
異なる安定化効果を有する安定剤を組み合わせて用いることで、様々な原因で起こりうるハロオレフィン系化合物の分解をより広範な安定化効果効果的に防止するという理由から、上記したエポキシ系安定剤、並びに、不飽和アルコール系安定剤、ニトロ系安定剤、及びフェノール系安定剤からなる群より選択される１種以上からなることが好ましい。 By using a combination of stabilizers having different stabilizing effects, the above-mentioned epoxy stabilizers can be effectively prevented from decomposing the haloolefin compounds that may occur due to various causes. And it is preferable to consist of 1 or more types selected from the group which consists of an unsaturated alcohol stabilizer, a nitro stabilizer, and a phenol stabilizer.
上記ハロオレフィン系化合物からの酸遊離を効果的に抑制し、液状組成物による金属の腐食を抑制するという観点から、液状組成物１００質量％中における安定剤の含有量は、０．０００１質量％以上であることが好ましく、０．０１質量％以上であることがより好ましい。一方、安定剤の過剰な添加による液状組成物の好ましくない物性変化を避けるという点を考慮すれば、液状組成物１００質量％中における安定剤の含有量は、１０質量％以下であることが好ましく、５質量％以下であることがより好ましい。 From the viewpoint of effectively suppressing acid release from the haloolefin compound and suppressing metal corrosion by the liquid composition, the content of the stabilizer in 100% by mass of the liquid composition is 0.0001% by mass. It is preferable that it is above, and it is more preferable that it is 0.01 mass% or more. On the other hand, in view of avoiding an undesirable change in physical properties of the liquid composition due to excessive addition of the stabilizer, the content of the stabilizer in 100% by mass of the liquid composition is preferably 10% by mass or less. More preferably, it is 5 mass% or less.
水
本開示における液状組成物には、水が含まれていてもよい。但し、水が含まれることにより、ハロオレフィン系化合物が分解し、酸が遊離し、その結果、液状組成物を使用した際に金属の腐食を発生させる可能性がある。そのため、ハロオレフィン系化合物の安定性を確保するという観点から、液状組成物中における水の含有量は１０００ｐｐｍ以下であることが好ましく、２００ｐｐｍ以下であることがより好ましく、１００ｐｐｍ以下であることがさらに好ましい。水の含有量の下限値は特に設定されないが、例えば、０．１ｐｐｍであることが好ましい。
In the liquid composition in water present disclosure, it may contain water. However, when water is contained, the haloolefin compound is decomposed and the acid is liberated. As a result, when the liquid composition is used, corrosion of the metal may occur. Therefore, from the viewpoint of ensuring the stability of the haloolefin compound, the content of water in the liquid composition is preferably 1000 ppm or less, more preferably 200 ppm or less, and even more preferably 100 ppm or less. preferable. The lower limit of the water content is not particularly set, but is preferably 0.1 ppm, for example.
その他
上述した以外に、液状組成物の用途に応じ、任意の追加成分を液状組成物に加えてもよい。これらの成分としては、界面活性剤、潤滑油類といった油類、コーティングに用いる重合体類、並びに防腐剤を挙げることができる。これらは液状組成物の用途に応じ、１種を単独で添加してもよいし、複数種を添加してもよい。これらは、公知のものを広く使用することができ、たとえば、潤滑油などの油類並びにコーティングに用いる重合体類の例として、シリコーン系、フッ素系オイルもしくは重合体、鉱物油系オイル、グリース及びワックス等が挙げられる。液状組成物中におけるこれら追加成分の含有量の上限ないし下限は、特に限定されず、追加成分の種類によってその追加成分を添加する効果を発揮するために適当な上限ないし下限を選べばよいが、例として、シリコーン系、フッ素系オイルについてはその添加量の上限は、液状組成物全体を１００質量％として５０質量％以下が好ましく、下限については１質量％以上であることが好ましい。
In addition to the above, any additional component may be added to the liquid composition depending on the use of the liquid composition. Examples of these components include oils such as surfactants and lubricating oils, polymers used for coating, and preservatives. These may be added individually by 1 type according to the use of a liquid composition, and may add multiple types. These can be widely used, for example, oils such as lubricating oils and polymers used for coating, such as silicone-based, fluorine-based oils or polymers, mineral oil-based oils, greases and A wax etc. are mentioned. The upper limit or lower limit of the content of these additional components in the liquid composition is not particularly limited, and an appropriate upper limit or lower limit may be selected in order to exert the effect of adding the additional component depending on the type of the additional component, As an example, the upper limit of the addition amount of silicone-based and fluorine-based oils is preferably 50% by mass or less with respect to 100% by mass of the entire liquid composition, and the lower limit is preferably 1% by mass or more.
以上にしてなる本開示における液状組成物は、冷媒、洗浄剤、溶剤、スプレー剤、発泡剤、作動流体、または各種機能性材料等の液状組成物として、好適に使用することが可能である。 The liquid composition in the present disclosure as described above can be suitably used as a liquid composition such as a refrigerant, a cleaning agent, a solvent, a spray agent, a foaming agent, a working fluid, or various functional materials.
また、本発明の液状組成物は、上述した含有成分を混合することにより、得ることができる。 Further, the liquid composition of the present invention can be obtained by mixing the above-described components.
以上、本発明の実施形態について説明したが、本発明はこうした例に何ら限定されるものではなく、本発明の要旨を逸脱しない範囲において種々なる形態で実施し得ることは勿論である。 The embodiments of the present invention have been described above, but the present invention is not limited to these examples, and can of course be implemented in various forms without departing from the gist of the present invention.
以下、実施例に基づき、本発明の実施形態をより具体的に説明するが、本発明がこれらに限定されるものではない。 Hereinafter, based on an Example, Embodiment of this invention is described more concretely, This invention is not limited to these.
（実施例及び比較例）
下記表１に示す組成でハロオレフィン系化合物、安定剤、及び水をガラス容器内で混合し、各実施例及び各比較例の液状組成物を得た。具体的には、ハロオレフィン系化合物５０ｇ（但し、水を添加する場合には、ハロオレフィン系化合物に水を添加して５０ｇとする。）に対し、表１に示す質量％で安定剤を混合した。
(Examples and Comparative Examples)
A haloolefin compound, a stabilizer, and water were mixed in a glass container with the composition shown in Table 1 below to obtain liquid compositions of Examples and Comparative Examples. Specifically, a stabilizer is mixed at 50% by mass shown in Table 1 with respect to 50 g of a haloolefin compound (however, when water is added, water is added to the haloolefin compound to make 50 g). did.
腐食試験
各実施例及び各比較例の液状組成物に、鉄（ＳＳＰＣ）、銅、亜鉛の試験片（長さ５０ｍｍ、直径１．５ｍｍ）を入れ、１２１３ｙａは９０℃、１２２３ｘｄは６０℃の温度条件で、表１に示した時間で、還流した。その後放冷して約２５℃とした後、試験片の状態を確認した。腐食評価の評価基準は、下記の通りであり、還流開始から２４時間経過時点において、目視で腐食が認められない場合に合格とした。
＜評価基準＞
○：目視で腐食が認められない
×：目視で腐食が認められる
Corrosion test In each liquid composition of each example and each comparative example, test pieces (length: 50 mm, diameter: 1.5 mm) of iron (SSPC), copper, and zinc are put, 1213ya is 90 ° C, and 1223xd is 60 ° C. Under the conditions, the mixture was refluxed for the time shown in Table 1. Then, after standing to cool to about 25 ° C., the state of the test piece was confirmed. The evaluation criteria for the corrosion evaluation are as follows, and when the corrosion was not visually observed after 24 hours from the start of reflux, the evaluation was accepted.
<Evaluation criteria>
○: Corrosion is not visually recognized ×: Corrosion is visually observed
腐食試験結果
表１に示すように、各実施例の液状組成物を使用して腐食試験を実施しても、腐食が殆ど確認されなかった。一方、各比較例の液状組成物を使用した場合には、金属の腐食が確認された。
Corrosion test results As shown in Table 1, even when the corrosion test was carried out using the liquid composition of each example, corrosion was hardly confirmed. On the other hand, when the liquid composition of each comparative example was used, corrosion of the metal was confirmed.
Claims (6)
エポキシ系安定剤並びに、
不飽和アルコール系安定剤、ニトロ系安定剤、及びフェノール系安定剤からなる群より選ばれる１種以上からなる、請求項１に記載の液状組成物。 The stabilizer is
Epoxy stabilizers,
The liquid composition of Claim 1 which consists of 1 or more types chosen from the group which consists of an unsaturated alcohol stabilizer, a nitro stabilizer, and a phenol stabilizer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2018073154A JP7299453B2 (en) | 2018-04-05 | 2018-04-05 | liquid composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2018073154A JP7299453B2 (en) | 2018-04-05 | 2018-04-05 | liquid composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2019182957A true JP2019182957A (en) | 2019-10-24 |
| JP7299453B2 JP7299453B2 (en) | 2023-06-28 |
Family
ID=68339695
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018073154A Active JP7299453B2 (en) | 2018-04-05 | 2018-04-05 | liquid composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP7299453B2 (en) |
Citations (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02221389A (en) * | 1989-02-23 | 1990-09-04 | Asahi Glass Co Ltd | Buffing detergent |
| JPH02222496A (en) * | 1989-02-23 | 1990-09-05 | Asahi Glass Co Ltd | Cleaning agent for dry cleaning |
| JPH03152198A (en) * | 1989-11-09 | 1991-06-28 | Asahi Chem Ind Co Ltd | 1,1,1-trichloroethane composition |
| JPH1046197A (en) * | 1996-08-02 | 1998-02-17 | Tosoh Corp | Nonflammable detergent composition |
| JP2000506211A (en) * | 1996-03-04 | 2000-05-23 | アルベマール・コーポレーシヨン | Stabilized alkane bromide solvent |
| US20050096246A1 (en) * | 2003-11-04 | 2005-05-05 | Johnson Robert C. | Solvent compositions containing chlorofluoroolefins |
| JP2013087187A (en) * | 2011-10-18 | 2013-05-13 | Central Glass Co Ltd | Working medium for heat cycle |
| WO2013165895A1 (en) * | 2012-04-30 | 2013-11-07 | Trane International Inc. | Refrigeration system with purge using enrivonmentally-suitable chiller refrigerant |
| JP2014523928A (en) * | 2011-05-19 | 2014-09-18 | アーケマ・インコーポレイテッド | Non-flammable composition of chloro-trifluoropropene |
| JP2016141730A (en) * | 2015-02-02 | 2016-08-08 | セントラル硝子株式会社 | Azeotrope-like composition containing fluorine-containing olefin as component |
| JP2016194377A (en) * | 2015-03-31 | 2016-11-17 | 三菱重工業株式会社 | Refrigerant circulation device, refrigerant circulation method, refrigerant charging method, and operational method of refrigerant circulation device |
| JP2016216477A (en) * | 2014-09-26 | 2016-12-22 | ダイキン工業株式会社 | Method for stabilizing haloolefins |
| JP2017043742A (en) * | 2015-08-28 | 2017-03-02 | 旭硝子株式会社 | Solvent composition |
| WO2017122517A1 (en) * | 2016-01-12 | 2017-07-20 | 旭硝子株式会社 | Refrigeration cycle device and heat cycle system |
-
2018
- 2018-04-05 JP JP2018073154A patent/JP7299453B2/en active Active
Patent Citations (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02222496A (en) * | 1989-02-23 | 1990-09-05 | Asahi Glass Co Ltd | Cleaning agent for dry cleaning |
| JPH02221389A (en) * | 1989-02-23 | 1990-09-04 | Asahi Glass Co Ltd | Buffing detergent |
| JPH03152198A (en) * | 1989-11-09 | 1991-06-28 | Asahi Chem Ind Co Ltd | 1,1,1-trichloroethane composition |
| JP2000506211A (en) * | 1996-03-04 | 2000-05-23 | アルベマール・コーポレーシヨン | Stabilized alkane bromide solvent |
| JPH1046197A (en) * | 1996-08-02 | 1998-02-17 | Tosoh Corp | Nonflammable detergent composition |
| US20050096246A1 (en) * | 2003-11-04 | 2005-05-05 | Johnson Robert C. | Solvent compositions containing chlorofluoroolefins |
| JP2014523928A (en) * | 2011-05-19 | 2014-09-18 | アーケマ・インコーポレイテッド | Non-flammable composition of chloro-trifluoropropene |
| JP2013087187A (en) * | 2011-10-18 | 2013-05-13 | Central Glass Co Ltd | Working medium for heat cycle |
| WO2013165895A1 (en) * | 2012-04-30 | 2013-11-07 | Trane International Inc. | Refrigeration system with purge using enrivonmentally-suitable chiller refrigerant |
| JP2016216477A (en) * | 2014-09-26 | 2016-12-22 | ダイキン工業株式会社 | Method for stabilizing haloolefins |
| JP2016141730A (en) * | 2015-02-02 | 2016-08-08 | セントラル硝子株式会社 | Azeotrope-like composition containing fluorine-containing olefin as component |
| JP2016194377A (en) * | 2015-03-31 | 2016-11-17 | 三菱重工業株式会社 | Refrigerant circulation device, refrigerant circulation method, refrigerant charging method, and operational method of refrigerant circulation device |
| JP2017043742A (en) * | 2015-08-28 | 2017-03-02 | 旭硝子株式会社 | Solvent composition |
| WO2017122517A1 (en) * | 2016-01-12 | 2017-07-20 | 旭硝子株式会社 | Refrigeration cycle device and heat cycle system |
Also Published As
| Publication number | Publication date |
|---|---|
| JP7299453B2 (en) | 2023-06-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TWI707033B (en) | Cleaning agent composition, rinse agent composition and cleaning method | |
| JP2576933B2 (en) | Cleaning solvent composition | |
| BE1007699A3 (en) | Composition containing pentafluorobutane and use thereof. | |
| JP4448137B2 (en) | Use of quaternary ammonium carbonate and quaternary ammonium bicarbonate as anticorrosives, methods for inhibiting corrosion, and anticorrosive coatings using these agents | |
| JP6432306B2 (en) | Azeotropic-like composition comprising fluorine-containing olefin as a constituent | |
| WO2016125550A1 (en) | Azeotrope-like composition containing fluorinated olefin as component | |
| US5707954A (en) | Stabilized brominated alkane solvent | |
| JPH07150197A (en) | Cleaning solvent composition | |
| JP2018150502A (en) | Detergent composition, rinse agent composition, and cleaning method | |
| JP7299453B2 (en) | liquid composition | |
| JP2002241796A (en) | Solvent composition for cleaning | |
| CN115461426B (en) | Composition containing fluorine-containing oil | |
| JP2576942B2 (en) | Cleaning solvent composition | |
| WO2016129319A1 (en) | Azeotrope-like composition having fluorine-containing olefin as constituent | |
| US5990071A (en) | Method for inhibiting tarnish formation when cleaning silver with ether stabilized, N-propyl bromide-based solvent systems | |
| JPH02286796A (en) | Mixed solvent composition | |
| WO2018012581A1 (en) | Cleaning solvent composition | |
| JP2019112649A (en) | Composition, liquid composition, cleaning solvent, production method and recovery method thereof, and cleaning method using cleaning solvent | |
| JPH02286797A (en) | Azeotropic composition | |
| JP2014159523A (en) | Detergent composition for removing polyamideimide resin | |
| WO2003025109A1 (en) | Cleaning or drying compositions based on n-perfluorobutyl-ethylene and hfc 365mfc |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20210201 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20210928 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20211129 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20220405 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20220603 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20220803 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20221122 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20230123 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20230320 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20230516 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20230529 |
|
| R151 | Written notification of patent or utility model registration |
Ref document number: 7299453 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R151 |