JP2019123868A - Curable composition and coating film waterproofing agent - Google Patents
Curable composition and coating film waterproofing agent Download PDFInfo
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- JP2019123868A JP2019123868A JP2019003885A JP2019003885A JP2019123868A JP 2019123868 A JP2019123868 A JP 2019123868A JP 2019003885 A JP2019003885 A JP 2019003885A JP 2019003885 A JP2019003885 A JP 2019003885A JP 2019123868 A JP2019123868 A JP 2019123868A
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- curable composition
- mass
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- polyalkylene oxide
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- 239000000203 mixture Substances 0.000 title claims abstract description 99
- 239000003795 chemical substances by application Substances 0.000 title claims description 10
- 238000004078 waterproofing Methods 0.000 title claims description 8
- 239000011248 coating agent Substances 0.000 title abstract description 32
- 238000000576 coating method Methods 0.000 title abstract description 32
- 229920000233 poly(alkylene oxides) Polymers 0.000 claims abstract description 40
- 239000010433 feldspar Substances 0.000 claims abstract description 33
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 claims abstract description 26
- 239000002245 particle Substances 0.000 claims abstract description 13
- 239000011521 glass Substances 0.000 claims description 24
- 239000003973 paint Substances 0.000 claims description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract description 26
- 229920001971 elastomer Polymers 0.000 abstract description 21
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract description 13
- 229910052664 nepheline Inorganic materials 0.000 abstract description 8
- 239000010434 nepheline Substances 0.000 abstract description 8
- 239000000758 substrate Substances 0.000 abstract description 6
- 239000010435 syenite Substances 0.000 abstract description 5
- -1 trimethoxysilyl group Chemical group 0.000 description 32
- 239000000945 filler Substances 0.000 description 20
- 239000004611 light stabiliser Substances 0.000 description 16
- 150000001412 amines Chemical class 0.000 description 13
- 239000003054 catalyst Substances 0.000 description 13
- 238000009833 condensation Methods 0.000 description 12
- 230000005494 condensation Effects 0.000 description 12
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 12
- 239000006096 absorbing agent Substances 0.000 description 11
- 239000003963 antioxidant agent Substances 0.000 description 10
- 239000002585 base Substances 0.000 description 10
- 239000012024 dehydrating agents Substances 0.000 description 9
- 229920001451 polypropylene glycol Polymers 0.000 description 9
- 125000000217 alkyl group Chemical group 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 238000005227 gel permeation chromatography Methods 0.000 description 7
- 239000013008 thixotropic agent Substances 0.000 description 7
- 229910000838 Al alloy Inorganic materials 0.000 description 6
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 6
- 239000012964 benzotriazole Substances 0.000 description 6
- 239000004014 plasticizer Substances 0.000 description 6
- 229920001515 polyalkylene glycol Polymers 0.000 description 6
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
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- 230000003078 antioxidant effect Effects 0.000 description 4
- 230000005540 biological transmission Effects 0.000 description 4
- 239000007822 coupling agent Substances 0.000 description 4
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 229910052661 anorthite Inorganic materials 0.000 description 3
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- GWWPLLOVYSCJIO-UHFFFAOYSA-N dialuminum;calcium;disilicate Chemical compound [Al+3].[Al+3].[Ca+2].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] GWWPLLOVYSCJIO-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 3
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 2
- 229910021532 Calcite Inorganic materials 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
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- 125000002723 alicyclic group Chemical group 0.000 description 2
- 125000005370 alkoxysilyl group Chemical group 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
- 239000012965 benzophenone Substances 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
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- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000008602 contraction Effects 0.000 description 2
- 125000006165 cyclic alkyl group Chemical group 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
- JWZHRZRGJXUNGR-UHFFFAOYSA-N dodecyl [dibutyl-[dibutyl(dodecoxycarbonyl)stannyl]oxystannyl]formate Chemical compound CCCCCCCCCCCCOC(=O)[Sn](CCCC)(CCCC)O[Sn](CCCC)(CCCC)C(=O)OCCCCCCCCCCCC JWZHRZRGJXUNGR-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 238000010191 image analysis Methods 0.000 description 2
- 125000001841 imino group Chemical group [H]N=* 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 229910052907 leucite Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 description 2
- 239000005365 phosphate glass Substances 0.000 description 2
- 229920001748 polybutylene Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
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- 239000004575 stone Substances 0.000 description 2
- 230000009974 thixotropic effect Effects 0.000 description 2
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 2
- PYOKUURKVVELLB-UHFFFAOYSA-N trimethyl orthoformate Chemical compound COC(OC)OC PYOKUURKVVELLB-UHFFFAOYSA-N 0.000 description 2
- 239000010455 vermiculite Substances 0.000 description 2
- 229910052902 vermiculite Inorganic materials 0.000 description 2
- 235000019354 vermiculite Nutrition 0.000 description 2
- UVDDHYAAWVNATK-VGKOASNMSA-L (z)-4-[dibutyl-[(z)-4-oxopent-2-en-2-yl]oxystannyl]oxypent-3-en-2-one Chemical compound CC(=O)\C=C(C)/O[Sn](CCCC)(CCCC)O\C(C)=C/C(C)=O UVDDHYAAWVNATK-VGKOASNMSA-L 0.000 description 1
- NDQXKKFRNOPRDW-UHFFFAOYSA-N 1,1,1-triethoxyethane Chemical compound CCOC(C)(OCC)OCC NDQXKKFRNOPRDW-UHFFFAOYSA-N 0.000 description 1
- HDPNBNXLBDFELL-UHFFFAOYSA-N 1,1,1-trimethoxyethane Chemical compound COC(C)(OC)OC HDPNBNXLBDFELL-UHFFFAOYSA-N 0.000 description 1
- JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical compound C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 description 1
- 238000005160 1H NMR spectroscopy Methods 0.000 description 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- VYVFQBFOMKEKBG-UHFFFAOYSA-L 3,3-dibutyl-2,4,3-benzodioxastannepine-1,5-dione Chemical compound O=C1O[Sn](CCCC)(CCCC)OC(=O)C2=CC=CC=C21 VYVFQBFOMKEKBG-UHFFFAOYSA-L 0.000 description 1
- STEYNUVPFMIUOY-UHFFFAOYSA-N 4-Hydroxy-1-(2-hydroxyethyl)-2,2,6,6-tetramethylpiperidine Chemical compound CC1(C)CC(O)CC(C)(C)N1CCO STEYNUVPFMIUOY-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910015902 Bi 2 O 3 Inorganic materials 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- MVYMUGGNHUNHDM-UHFFFAOYSA-N C(CCCCCCCCC(=O)OC1CC(NC(C1)(C)C)(C)C)(=O)OC1CC(NC(C1)(C)C)(C)C.C(CCCCCCCCC(=O)OC1CC(N(C(C1)(C)C)C)(C)C)(=O)OC Chemical compound C(CCCCCCCCC(=O)OC1CC(NC(C1)(C)C)(C)C)(=O)OC1CC(NC(C1)(C)C)(C)C.C(CCCCCCCCC(=O)OC1CC(N(C(C1)(C)C)C)(C)C)(=O)OC MVYMUGGNHUNHDM-UHFFFAOYSA-N 0.000 description 1
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- DFPAKSUCGFBDDF-UHFFFAOYSA-N Nicotinamide Chemical group NC(=O)C1=CC=CN=C1 DFPAKSUCGFBDDF-UHFFFAOYSA-N 0.000 description 1
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- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 241001147388 Uncia Species 0.000 description 1
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- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
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- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
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- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
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- HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 description 1
- JJQZDUKDJDQPMQ-UHFFFAOYSA-N dimethoxy(dimethyl)silane Chemical compound CO[Si](C)(C)OC JJQZDUKDJDQPMQ-UHFFFAOYSA-N 0.000 description 1
- AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 description 1
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 description 1
- 229960001826 dimethylphthalate Drugs 0.000 description 1
- LQRUPWUPINJLMU-UHFFFAOYSA-N dioctyl(oxo)tin Chemical compound CCCCCCCC[Sn](=O)CCCCCCCC LQRUPWUPINJLMU-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- WBJINCZRORDGAQ-UHFFFAOYSA-N formic acid ethyl ester Natural products CCOC=O WBJINCZRORDGAQ-UHFFFAOYSA-N 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 229940049920 malate Drugs 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N malic acid Chemical compound OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- VASIZKWUTCETSD-UHFFFAOYSA-N manganese(II) oxide Inorganic materials [Mn]=O VASIZKWUTCETSD-UHFFFAOYSA-N 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 229910001719 melilite Inorganic materials 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 description 1
- 229910052651 microcline Inorganic materials 0.000 description 1
- XOSNGXNHDRYFEF-UHFFFAOYSA-N monohexyl phthalate Chemical compound CCCCCCOC(=O)C1=CC=CC=C1C(O)=O XOSNGXNHDRYFEF-UHFFFAOYSA-N 0.000 description 1
- FTQWRYSLUYAIRQ-UHFFFAOYSA-N n-[(octadecanoylamino)methyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCNC(=O)CCCCCCCCCCCCCCCCC FTQWRYSLUYAIRQ-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
- 229910052652 orthoclase Inorganic materials 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- ZFACJPAPCXRZMQ-UHFFFAOYSA-N phthalic acid Chemical class OC(=O)C1=CC=CC=C1C(O)=O.OC(=O)C1=CC=CC=C1C(O)=O ZFACJPAPCXRZMQ-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 125000003386 piperidinyl group Chemical group 0.000 description 1
- 229910052655 plagioclase feldspar Inorganic materials 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000003566 sealing material Substances 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 229910052665 sodalite Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical class [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 125000005369 trialkoxysilyl group Chemical group 0.000 description 1
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 1
- GKASDNZWUGIAMG-UHFFFAOYSA-N triethyl orthoformate Chemical compound CCOC(OCC)OCC GKASDNZWUGIAMG-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 description 1
- 229940124543 ultraviolet light absorber Drugs 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/32—Polymers modified by chemical after-treatment
- C08G65/329—Polymers modified by chemical after-treatment with organic compounds
- C08G65/336—Polymers modified by chemical after-treatment with organic compounds containing silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D171/00—Coating compositions based on polyethers obtained by reactions forming an ether link in the main chain; Coating compositions based on derivatives of such polymers
- C09D171/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
Description
本発明は、硬化性組成物及び塗膜防水剤に関する。 The present invention relates to a curable composition and a coating waterproofer.
従来からコンクリート構築物の屋上に防水のために塗膜を形成することが行われている。特許文献１には、ウレタン弾性発泡体から構成され、このウレタン弾性発泡体が、発泡倍率２〜１０倍、伸び２００〜１０００％、引張強度２０〜１００ｋｇ／ｃｍ2であるウレタン防水材が開示されている。 It has been customary to form a coating on the roof of a concrete construction for waterproofing. Patent Document 1 discloses a urethane waterproofing material which is composed of a urethane elastic foam, and the urethane elastic foam has an expansion ratio of 2 to 10 times, an elongation of 200 to 1000%, and a tensile strength of 20 to 100 kg / cm 2. ing.
しかしながら、特許文献１で開示されているウレタン防水材の構築に用いられるウレタン材料は、溶剤を含むため、作業環境及び地球環境への負担軽減のために、無溶剤系の材料を用いることが検討されている。 However, since the urethane material used to construct the urethane waterproofing material disclosed in Patent Document 1 contains a solvent, it is considered to use a solventless material to reduce the burden on the working environment and the global environment. It is done.
又、上記防水塗膜は、防水下地となるコンクリート構築物の温度変化に伴う伸縮の他、経時劣化に伴う亀裂による防水下地の伸長にも順応することができるゴム弾性が要求される。更に、防水塗膜は、防水下地に対する密着性が要求される。 Further, the waterproof coating is required to have rubber elasticity capable of adapting to the expansion of the waterproof base due to the cracks caused by the deterioration with time, in addition to the expansion and contraction due to the temperature change of the concrete structure to be the waterproof base. Furthermore, the waterproof coating is required to have adhesion to the waterproof substrate.
そこで、無溶剤系の材料の中でも、変性シリコーン樹脂を用いることが考えられる。 Therefore, among non-solvent materials, it is conceivable to use a modified silicone resin.
ところが、変性シリコーン樹脂は、ゴム弾性に優れているものの、塗膜強度が低い。そこで、塗膜強度を向上させるために充填材を添加すると、塗工性が低下するという別の問題を生じる。 However, although the modified silicone resin is excellent in rubber elasticity, the coating film strength is low. Therefore, if a filler is added to improve the coating strength, another problem arises that the coatability is reduced.
本発明は、ゴム弾性、塗膜強度、塗工性、及び、防水下地などに対する密着性に優れた硬化性組成物を提供する。 The present invention provides a curable composition excellent in rubber elasticity, coating film strength, coatability, and adhesion to a waterproof base and the like.
本発明の硬化性組成物は、
加水分解性シリル基を有するポリアルキレンオキサイドと、
平均粒子径が０．０１〜１００μｍの長石類を含むことを特徴とする。
The curable composition of the present invention is
A polyalkylene oxide having a hydrolyzable silyl group,
It is characterized in that it contains feldspar having an average particle size of 0.01 to 100 μm.
［ポリアルキレンオキサイド］
硬化性組成物に含まれているポリアルキレンオキサイドは、加水分解性シリル基を有している。加水分解性シリル基とは、珪素原子に１〜３個の加水分解性基が結合してなる基である。
[Polyalkylene oxide]
The polyalkylene oxide contained in the curable composition has a hydrolyzable silyl group. The hydrolyzable silyl group is a group formed by bonding 1 to 3 hydrolyzable groups to a silicon atom.
加水分解性シリル基の加水分解性基としては、特に限定されず、例えば、水素原子、ハロゲン原子、アルコキシ基、アシルオキシ基、ケトキシメート基、アミノ基、アミド基、酸アミド基、アミノオキシ基、メルカプト基、アルケニルオキシ基などが挙げられる。 The hydrolyzable group of the hydrolyzable silyl group is not particularly limited. For example, a hydrogen atom, a halogen atom, an alkoxy group, an acyloxy group, a ketoxime group, an amino group, an amide group, an acid amide group, an aminooxy group, mercapto And alkenyloxy groups.
なかでも、加水分解性シリル基としては、加水分解反応が穏やかであることから、アルコキシシリル基が好ましい。アルコキシシリル基としては、トリメトキシシリル基、トリエトキシシリル基、トリイソプロポキシシリル基、及びトリフェノキシシリル基などのトリアルコキシシリル基；ジメトキシシリル基、ジエトキシシリル基、メチルジメトキシシリル基、及びメチルジエトキシシリル基などのジアルコキシシリル基；並びに、ジメチルメトキシシリル基、及びジメチルエトキシシリル基などのモノアルコキシシリル基が挙げられる。なかでも、ジアルコキシシリル基がより好ましく、メチルジメトキシシリル基が特に好ましい。 Among them, an alkoxysilyl group is preferable as the hydrolyzable silyl group because the hydrolysis reaction is mild. Examples of alkoxysilyl groups include trialkoxysilyl groups such as trimethoxysilyl group, triethoxysilyl group, triisopropoxysilyl group, and triphenoxysilyl group; dimethoxysilyl group, diethoxysilyl group, methyldimethoxysilyl group, and methyl And dialkoxysilyl groups such as diethoxysilyl group; and monoalkoxysilyl groups such as dimethylmethoxysilyl group and dimethylethoxysilyl group. Among them, a dialkoxysilyl group is more preferable, and a methyldimethoxysilyl group is particularly preferable.
ポリアルキレンオキサイドは、１分子中に平均して、１〜４個の加水分解性シリル基を有していることが好ましい。ポリアルキレンオキサイドにおける加水分解性シリル基の数が１個以上であると、硬化性組成物の硬化性が向上する。ポリアルキレンオキサイドにおける加水分解性シリル基の数が４個以下であると、硬化性組成物は、優れたゴム弾性を有する硬化物を生成することができる。 The polyalkylene oxide preferably has 1 to 4 hydrolyzable silyl groups on average in one molecule. When the number of hydrolyzable silyl groups in the polyalkylene oxide is one or more, the curability of the curable composition is improved. When the number of hydrolyzable silyl groups in the polyalkylene oxide is 4 or less, the curable composition can form a cured product having excellent rubber elasticity.
なお、ポリアルキレンオキサイド中における、１分子当たりの加水分解性シリル基の平均個数は、1Ｈ−ＮＭＲにより求められるポリアルキレンオキサイド中の加水分解性シリル基の濃度、及びＧＰＣ法により求められるポリアルキレンオキサイドの数平均分子量に基づいて算出することができる。 The average number of hydrolyzable silyl groups per molecule in the polyalkylene oxide is the concentration of hydrolyzable silyl groups in the polyalkylene oxide determined by 1 H-NMR, and the polyalkylene determined by the GPC method It can be calculated based on the number average molecular weight of the oxide.
ポリアルキレンオキサイドとしては、主鎖が、一般式：−（Ｒ−Ｏ）n−（式中、Ｒは炭素数が１〜１４のアルキレン基を表し、ｎは、繰り返し単位の数であって正の整数である。）で表される繰り返し単位を含有する重合体が好ましく挙げられる。ポリアルキレンオキサイドの主鎖骨格は一種のみの繰り返し単位からなっていてもよいし、二種以上の繰り返し単位からなっていてもよい。 As the polyalkylene oxide, the main chain is a general formula:-(R-O) n- (wherein R represents an alkylene group having 1 to 14 carbon atoms, n is the number of repeating units and is positive) The polymer containing the repeating unit represented by this is an integer of is preferably mentioned. The main chain skeleton of the polyalkylene oxide may be composed of only one kind of repeating unit, or may be composed of two or more kinds of repeating units.
ポリアルキレンオキサイドの主鎖骨格としては、ポリエチレンオキサイド、ポリプロピレンオキサイド、ポリブチレンオキサイド、ポリテトラメチレンオキサイド、ポリエチレンオキサイド−ポリプロピレンオキサイド共重合体、及びポリプロピレンオキサイド−ポリブチレンオキサイド共重合体などが挙げられる。なかでも、ポリプロピレンオキサイドが好ましい。ポリプロピレンオキサイドによれば、硬化性組成物は、優れたゴム弾性を有する硬化物を生成することができる。 Examples of the main chain skeleton of the polyalkylene oxide include polyethylene oxide, polypropylene oxide, polybutylene oxide, polytetramethylene oxide, polyethylene oxide-polypropylene oxide copolymer, and polypropylene oxide-polybutylene oxide copolymer. Among them, polypropylene oxide is preferable. According to polypropylene oxide, the curable composition can produce a cured product having excellent rubber elasticity.
ポリアルキレンオキサイドの数平均分子量は、３０００〜５００００が好ましく、１００００〜３００００がより好ましい。ポリアルキレンオキサイドの数平均分子量が１００００以上であると、硬化性組成物の硬化物のゴム弾性が向上する。ポリアルキレンオキサイドの数平均分子量が５００００以下であると、硬化性組成物の塗工性が向上する。 3000-50000 are preferable and, as for the number average molecular weight of a polyalkylene oxide, 10000-30000 are more preferable. The rubber elasticity of the hardened | cured material of a curable composition improves that the number average molecular weight of a polyalkylene oxide is 10000 or more. When the number average molecular weight of the polyalkylene oxide is 50000 or less, the coatability of the curable composition is improved.
なお、本発明において、ポリアルキレンオキサイドの数平均分子量とは、ＧＰＣ（ゲルパーミエーションクロマトグラフィー）法によって測定されたポリスチレン換算した値を意味する。ＧＰＣ法による測定においては、例えば、ＧＰＣカラムとして東ソー製Ｓｈｏｄｅｘ ＫＦ８００Ｄを用い、溶媒としてクロロホルムなどを用いることができる。 In the present invention, the number average molecular weight of the polyalkylene oxide means a value in terms of polystyrene measured by GPC (gel permeation chromatography) method. In the measurement by the GPC method, for example, Shodex KF800D manufactured by Tosoh Corporation can be used as a GPC column, and chloroform or the like can be used as a solvent.
加水分解性シリル基を有するポリアルキレンオキサイドは、市販されている製品を用いることができる。例えば、カネカ社製 商品名 ＭＳポリマー Ｓ−２０３、Ｓ−３０３；サイリルポリマー ＳＡＴ−２００、ＳＡＴ−３５０、ＳＡＴ−４００；旭硝子社製 商品名 エクセスター ＥＳＳ−３６２０、ＥＳＳ−２４２０、ＥＳＳ２４１０、ＥＳＳ３４３０などが挙げられる。 As the polyalkylene oxide having a hydrolyzable silyl group, a commercially available product can be used. For example, Kaneka company product name MS polymer S-203, S-303; syryl polymer SAT-200, SAT-350, SAT-400; product name Asahi Glass Co., Ltd. trade name Exester ESS-3620, ESS-2420, ESS 2410, ESS 3430 Etc.
［長石類］
硬化性組成物は、長石類を含有している。長石類は、長石及び準長石を含有しており、準長石が好ましい。
[Feldspars]
The curable composition contains feldspars. The feldspars contain feldspar and semi-feldspar, and semi-feldspar is preferred.
長石としては、例えば、正長石、サニディン、微斜長石、アノーソクレースなどのアルカリ長石；曹長石、灰曹長石、中性長石、曹灰長石、亜灰長石、灰長石などの斜長石などが挙げられる。 As feldspar, for example, alkali feldspar such as orthoclase, sanidin, microcline feldspar, anorthoclase, etc .; albite, anorthite, neutral feldspar, caustic feldspar, anorthite, plagioclase such as anorthite, etc. are listed. Be
準長石としては、例えば、カリ霞石（カルシライト）、灰霞石（カンクリナイト）などの霞石（ネフェリン）、霞石閃長石（ネフェリンサイアナイト）、白榴石（リューサイト）、方ソーダ石（ソーダライト）、藍方石（アウイン）、青金石（ラズライト）、黝方石（ノゼアン）、黄長石（メリライト）などが挙げられ、霞石閃長石（ネフェリンサイアナイト）が好ましい。なお、霞石閃長石は、閃長石と記載されることもある。 As the semi-feldspar, for example, calcite (calcylite), meteorites (nepheline) such as calcite (cancrinite), nepheline syenite (nepheline sianite), leucite (leucite), soda Stones (sodalite), vermiculite (auin), blue gold stone (lazite), vermiculite (nozean), yellow feldspar (melilite), etc. are mentioned, and nepheline syenite (nepheline sianite) is preferred. In addition, nepheline syenite may be described as syenite.
長石類の平均粒子径は、０．０１〜１００μｍであり、０．１〜５０μｍが好ましく、１〜２５μｍがより好ましく、２〜１５μｍが特に好ましく、３〜１０μｍが特に好ましい。長石類の平均粒子径が０．０１μｍ以上であると、硬化性組成物は、優れた塗膜強度を有する硬化物を生成することができる。長石類の平均粒子径が１００μｍ以下であると、硬化性組成物中に均一に分散させることができ、硬化性組成物は、優れた塗膜強度を有する硬化物を生成することができる。なお、長石類の平均粒子径は、透過型電子顕微鏡による画像解析によって測定された値をいう。具体的には、長石類を透過型電子顕微鏡を用いて倍率１００倍の拡大写真を撮影し、任意の５０個の長石類を抽出し、各長石類の直径を測定し、各長石類の直径の相加平均値を長石類の平均粒子径とする。なお、長石類の直径は、長石類を包囲し得る最小径の真円の直径をいう。 The average particle diameter of the feldspar is 0.01 to 100 μm, preferably 0.1 to 50 μm, more preferably 1 to 25 μm, particularly preferably 2 to 15 μm, and particularly preferably 3 to 10 μm. The curable composition can produce the hardened | cured material which has the outstanding coating film strength as average particle diameter of feldspars is 0.01 micrometer or more. When the average particle size of the feldspar is 100 μm or less, it can be uniformly dispersed in the curable composition, and the curable composition can form a cured product having excellent coating film strength. In addition, the average particle diameter of feldspar refers to the value measured by the image analysis by a transmission electron microscope. Specifically, the feldspars are photographed at a magnification of 100 times using a transmission electron microscope, 50 arbitrary feldspars are extracted, the diameter of each feldspar is measured, and the diameter of each feldspar The arithmetic mean value of is taken as the average particle size of feldspars. In addition, the diameter of the feldspar means the diameter of the perfect circle of the smallest diameter which can surround the feldspar.
硬化性組成物中における長石類の含有量は、加水分解性シリル基を有するポリアルキレンオキサイド１００質量部に対して１〜８００質量部が好ましく、３０〜６００質量部が好ましく、５０〜４５０質量部がより好ましく、８０〜３００質量部が特に好ましい。長石類の含有量が上記範囲内であると、硬化性組成物は、優れた塗工性を有していると共に、優れたゴム弾性及び塗膜強度を有する硬化物を生成することができる。 The content of feldspars in the curable composition is preferably 1 to 800 parts by mass, preferably 30 to 600 parts by mass, and 50 to 450 parts by mass with respect to 100 parts by mass of the polyalkylene oxide having a hydrolyzable silyl group. Is more preferable, and 80 to 300 parts by mass is particularly preferable. When the content of the feldspar is in the above range, the curable composition has excellent coatability and can produce a cured product having excellent rubber elasticity and coating film strength.
［ガラスフリット］
硬化性組成物は、ガラスフリットを含有していてもよい。ガラスフリットを構成しているガラスとしては、たとえば、リン酸系ガラス、ホウ酸系ガラス、酸化ビスマス系ガラス、珪酸系ガラス、酸化ナトリウム系ガラスなどが挙げられ、リン酸系ガラス、ホウ酸系ガラスが好ましく、リン酸系ガラスがより好ましい。これらのガラスフリットは、Ｂ2Ｏ3、Ｐ2Ｏ5、ＺｎＯ、ＳｉＯ2、Ｂｉ2Ｏ3、Ａｌ2Ｏ3、ＢａＯ、ＣａＯ、ＭｇＯ、ＭｎＯ2、ＺｒＯ2、ＴｉＯ2、ＣｅＯ2、ＳｒＯ、Ｖ2Ｏ5、ＳｎＯ2、Ｌｉ2Ｏ、Ｎａ2Ｏ、Ｋ2Ｏ、ＣｕＯ、Ｆｅ2Ｏ3などを所定の成分割合で調整して得ることができる。なお、ガラスフリットは、単独で用いられても二種以上が併用されてもよい。
[Glass frit]
The curable composition may contain a glass frit. Examples of the glass constituting the glass frit include phosphoric acid based glass, boric acid based glass, bismuth oxide based glass, silica based glass, sodium oxide based glass and the like, and phosphoric acid based glass and boric acid based glass Is preferable, and phosphate glass is more preferable. These glass frits include B 2 O 3 , P 2 O 5 , ZnO, SiO 2 , Bi 2 O 3 , Al 2 O 3 , BaO, CaO, MgO, MnO 2 , ZrO 2 , TiO 2 , CeO 2 , SrO , V 2 O 5 , SnO 2 , Li 2 O, Na 2 O, K 2 O, CuO, Fe 2 O 3 or the like at a predetermined component ratio. The glass frit may be used alone or in combination of two or more.
ガラスフリットを構成しているガラスの軟化点は３５０〜６５０℃が好ましく、３６０〜５６０℃がより好ましく、３７０〜５４０℃が特に好ましく、３８０〜５２０℃が最も好ましい。なお、ガラスフリットを構成しているガラスの軟化点は、ガラスの粘度が１０７．６ｄＰａ・ｓ（ｌｏｇη＝７．６）となる温度である。 350-650 degreeC is preferable, as for the softening point of the glass which comprises glass frit, 360-560 degreeC is more preferable, 370-540 degreeC is especially preferable, and 380-520 degreeC is the most preferable. The softening point of the glass constituting the glass frit is a temperature at which the viscosity of the glass is 107.6 dPa · s (log == 7.6).
硬化性組成物中におけるガラスフリットの含有量は、加水分解性シリル基を有するポリアルキレンオキサイド１００質量部に対して２〜１２０質量部が好ましく、５〜１００質量部がより好ましく、８〜９０質量部がより好ましく、２５〜９０質量部がより好ましく、２５〜７０質量部がより好ましく、３０〜６０質量部が特に好ましい。ガラスフリットの含有量が上記範囲内にあると、硬化性組成物は、優れた塗工性を有していると共に、優れたゴム弾性及び塗膜強度を有する硬化物を生成することができる。 The content of the glass frit in the curable composition is preferably 2 to 120 parts by mass, more preferably 5 to 100 parts by mass, and 8 to 90 parts by mass with respect to 100 parts by mass of the polyalkylene oxide having a hydrolyzable silyl group. Part is more preferable, 25 to 90 parts by mass is more preferable, 25 to 70 parts by mass is more preferable, and 30 to 60 parts by mass is particularly preferable. When the content of the glass frit is in the above range, the curable composition has excellent coatability and can produce a cured product having excellent rubber elasticity and coating film strength.
［可塑剤］
硬化性組成物は、可塑剤を更に含有していることが好ましい。可塑剤を含んでいる硬化性組成物は、優れたゴム弾性を有して追従性に優れた硬化物を生成することができる。
[Plasticizer]
The curable composition preferably further contains a plasticizer. The curable composition containing a plasticizer can produce a cured product having excellent rubber elasticity and excellent tracking performance.
可塑剤としては、例えば、フタル酸ジメチル、フタル酸ジエチル、フタル酸ジブチル、フタル酸ジイソブチル、フタル酸ジノルマルヘキシル、フタル酸ビス（２−エチルヘキシル）、フタル酸ジノルマルオクチル、フタル酸ジイソノニル、フタル酸ジノニル、フタル酸ジイソデシル、フタル酸ジイソウンデシル、及びフタル酸ビスブチルベンジルなどのフタル酸エステル；ジエチレングリコール、トリエチレングリコール、テトラエチレングリコール、ジプロピレングリコール、トリプロピレングリコール、及びテトラプロピレングリコールなどのポリアルキレングリコールが挙げられる。なかでも、ポリアルキレングリコールが好ましく、ポリプロピレングリコールがより好ましい。 As the plasticizer, for example, dimethyl phthalate, diethyl phthalate, dibutyl phthalate, diisobutyl phthalate, dinormal hexyl phthalate, bis (2-ethylhexyl) phthalate, dinormal octyl phthalate, diisononyl phthalate, phthalic acid Phthalates such as dinonyl, diisodecyl phthalate, diisoundecyl phthalate and bis butyl benzyl phthalate; polyalkylene glycols such as diethylene glycol, triethylene glycol, tetraethylene glycol, dipropylene glycol, tripropylene glycol, and tetrapropylene glycol It can be mentioned. Among them, polyalkylene glycol is preferable, and polypropylene glycol is more preferable.
ポリアルキレングリコールの数平均分子量は、１０００〜１００００が好ましく、２０００〜５０００がより好ましい。ポリアルキレングリコールの数平均分子量が上記範囲内である場合、このようなポリアルキレングリコールを含んでいる硬化性組成物は、硬化性組成物は、優れたゴム弾性を有して追従性に優れた硬化物を生成することができる。 1000-10000 are preferable and, as for the number average molecular weight of polyalkylene glycol, 2000-5000 are more preferable. When the number average molecular weight of the polyalkylene glycol is in the above range, the curable composition containing such a polyalkylene glycol has excellent rubber elasticity and excellent followability. A cured product can be produced.
なお、ポリアルキレングリコールの数平均分子量は、ＧＰＣ（ゲルパーミエーションクロマトグラフィー）法によって、ポリスチレン換算されて測定された値である。具体的な測定方法や測定条件は、上述した加水分解性シリル基を有するポリアルキレンオキサイドと同様である。 The number average molecular weight of the polyalkylene glycol is a value measured by polystyrene conversion by GPC (gel permeation chromatography) method. The specific measurement method and measurement conditions are the same as those of the polyalkylene oxide having a hydrolyzable silyl group described above.
硬化性組成物中における可塑剤の含有量は、加水分解性シリル基を有するポリアルキレンオキサイド１００質量部に対して、１〜１００質量部が好ましく、１０〜８０質量部がより好ましく、１５〜６０質量部が特に好ましく、２０〜５０質量部が最も好ましい。 The content of the plasticizer in the curable composition is preferably 1 to 100 parts by mass, more preferably 10 to 80 parts by mass, with respect to 100 parts by mass of the polyalkylene oxide having a hydrolyzable silyl group. Parts by weight are particularly preferred, and 20 to 50 parts by weight are most preferred.
［充填剤］
硬化性組成物は、充填剤を更に含有していてもよい。硬化性組成物が充填剤を含有していると、優れたゴム弾性を有している硬化物を得ることが可能な硬化性組成物を提供することができる。
[filler]
The curable composition may further contain a filler. When the curable composition contains a filler, it is possible to provide a curable composition capable of obtaining a cured product having excellent rubber elasticity.
充填剤としては、特に限定されず、例えば、炭酸カルシウム、炭酸マグネシウム、酸化カルシウム、含水ケイ酸、無水ケイ酸、微粉末シリカ、ケイ酸カルシウム、二酸化チタン、クレー、タルク、カーボンブラック及びガラスバルーンなどを挙げることができ、炭酸カルシウムが好ましく、重質炭酸カルシウムがより好ましい。充填剤は、単独で用いられても二種以上が併用されてもよい。 The filler is not particularly limited and, for example, calcium carbonate, magnesium carbonate, calcium oxide, hydrous silicic acid, anhydrous silicic acid, finely powdered silica, calcium silicate, titanium dioxide, clay, talc, carbon black and glass balloon etc. And calcium carbonate is preferred, and ground calcium carbonate is more preferred. The fillers may be used alone or in combination of two or more.
充填剤の平均粒子径は、０．０１〜５μｍが好ましく、０．０５〜２．５μｍがより好ましい。このような平均粒子径を有している充填剤によれば、防水下地などに対する密着性に優れた硬化物を生成することができる硬化性組成物を得ることができる。なお、充填剤の平均粒子径は、透過型電子顕微鏡による画像解析によって測定された値をいう。具体的には、充填剤を透過型電子顕微鏡を用いて倍率１００倍の拡大写真を撮影し、任意の５０個の充填剤を抽出し、各充填剤の直径を測定し、各充填剤の直径の相加平均値を充填剤の平均粒子径とする。なお、充填剤の直径は、充填剤を包囲し得る最小径の真円の直径をいう。 0.01-5 micrometers is preferable and, as for the average particle diameter of a filler, 0.05-2.5 micrometers is more preferable. According to the filler having such an average particle diameter, it is possible to obtain a curable composition capable of producing a cured product excellent in adhesion to a waterproof base or the like. In addition, the average particle diameter of a filler says the value measured by the image analysis by a transmission electron microscope. Specifically, the filler is photographed with a transmission electron microscope at a magnification of 100 times, any 50 fillers are extracted, the diameter of each filler is measured, and the diameter of each filler The arithmetic mean value of is taken as the average particle size of the filler. In addition, the diameter of a filler means the diameter of the perfect circle of the smallest diameter which can enclose a filler.
また、炭酸カルシウムは、脂肪酸や脂肪酸エステルなどにより表面処理されていることが好ましい。脂肪酸や脂肪酸エステルなどにより表面処理されている炭酸カルシウムによれば、硬化性組成物にチキソトロピー性を付与できると共に炭酸カルシムが凝集することを抑制することができる。 In addition, calcium carbonate is preferably surface-treated with a fatty acid or fatty acid ester. According to calcium carbonate surface-treated with a fatty acid or fatty acid ester or the like, thixotropy can be imparted to the curable composition, and aggregation of calcium carbonate can be suppressed.
硬化性組成物中における充填剤の含有量は、加水分解性シリル基を有するポリアルキレンオキサイド１００質量部に対して１〜７００質量部が好ましく、１０〜２００質量部がより好ましく、２０〜１５０質量部が特に好ましい。硬化性組成物中における充填剤の含有量が１質量部以上であると、充填剤の添加による効果が十分に得られる。また、硬化性組成物中における充填剤の含有量が７００質量部以下であると、硬化性組成物を硬化させて得られる硬化物が、防水下地などに対する優れた密着性を有する。 The content of the filler in the curable composition is preferably 1 to 700 parts by mass, more preferably 10 to 200 parts by mass, and 20 to 150 parts by mass with respect to 100 parts by mass of the polyalkylene oxide having a hydrolyzable silyl group. Parts are particularly preferred. When the content of the filler in the curable composition is 1 part by mass or more, the effect of the addition of the filler is sufficiently obtained. In addition, when the content of the filler in the curable composition is 700 parts by mass or less, a cured product obtained by curing the curable composition has excellent adhesion to a waterproof base and the like.
［脱水剤］
硬化性組成物は、脱水剤を更に含有していることが好ましい。脱水剤によれば、硬化性組成物を保存している際に、空気中などに含まれている水分によって硬化性組成物が硬化することを抑制することができる。
[Dehydrating agent]
The curable composition preferably further contains a dehydrating agent. According to the dehydrating agent, when the curable composition is stored, it is possible to suppress that the curable composition is cured by water contained in the air or the like.
脱水剤としては、ビニルトリメトキシシラン、ジメチルジメトキシシラン、テトラエトキシシラン、メチルトリメトキシシラン、メチルトリエトキシシラン、テトラメトキシシラン、フェニルトリメトキシシラン、及びジフェニルジメトキシシランなどのシラン化合物；並びにオルトギ酸メチル、オルトギ酸エチル、オルト酢酸メチル、及びオルト酢酸エチル等のエステル化合物などを挙げることができる。これらの脱水剤は、単独で用いられても二種以上が併用されてもよい。なかでも、ビニルトリメトキシシランが好ましい。 As a dehydrating agent, silane compounds such as vinyltrimethoxysilane, dimethyldimethoxysilane, tetraethoxysilane, methyltrimethoxysilane, methyltriethoxysilane, tetramethoxysilane, phenyltrimethoxysilane, and diphenyldimethoxysilane; and methyl orthoformate And ester compounds such as ethyl orthoformate, methyl orthoacetate, and ethyl orthoacetate. These dehydrating agents may be used alone or in combination of two or more. Among them, vinyltrimethoxysilane is preferable.
硬化性組成物中における脱水剤の含有量は、加水分解性シリル基を有するポリアルキレンオキサイド１００質量部に対して０．５〜２０質量部が好ましく、１〜１５質量部がより好ましい。硬化性組成物中における脱水剤の含有量が０．５質量部以上であると、脱水剤により得られる効果が十分に得られる。また、硬化性組成物中における脱水剤の含有量が２０質量部以下であると、硬化性組成物が優れた硬化性を有する。 The content of the dehydrating agent in the curable composition is preferably 0.5 to 20 parts by mass, and more preferably 1 to 15 parts by mass with respect to 100 parts by mass of the polyalkylene oxide having a hydrolyzable silyl group. When the content of the dehydrating agent in the curable composition is 0.5 parts by mass or more, the effects obtained by the dehydrating agent are sufficiently obtained. In addition, the curable composition has excellent curability when the content of the dehydrating agent in the curable composition is 20 parts by mass or less.
［シラノール縮合触媒］
硬化性組成物は、シラノール縮合触媒を含有していることが好ましい。シラノール縮合触媒とは、ポリアルキレンオキサイドが含有する加水分解性シリル基などが加水分解することにより形成されたシラノール基同士の脱水縮合反応を促進させるための触媒である。
[Silanol condensation catalyst]
The curable composition preferably contains a silanol condensation catalyst. The silanol condensation catalyst is a catalyst for promoting the dehydration condensation reaction of silanol groups formed by hydrolysis of a hydrolyzable silyl group or the like contained in a polyalkylene oxide.
シラノール縮合触媒としては、１，１，３，３−テトラブチル−１，３−ジラウリルオキシカルボニル−ジスタノキサン、ジブチル錫ジラウレート、ジブチル錫オキサイド、ジブチル錫ジアセテート、ジブチル錫フタレート、ビス（ジブチル錫ラウリン酸）オキサイド、ジブチル錫ビス（アセチルアセトナート）、ジブチル錫ビス（モノエステルマレート）、オクチル酸錫、ジブチル錫オクトエート、ジオクチル錫オキサイド、ジブチル錫ビス（トリエトキシシリケート）、ビス（ジブチル錫ビストリエトキシシリケート）オキサイド、及びジブチル錫オキシビスエトキシシリケートなどの有機錫系化合物；テトラ−ｎ−ブトキシチタネート、及びテトライソプロポキシチタネートなどの有機チタン系化合物などが挙げられる。これらのシラノール縮合触媒は、単独で用いられても二種以上が併用されてもよい。 As a silanol condensation catalyst, 1,1,3,3-tetrabutyl-1,3-dilauryloxycarbonyl-distanoxane, dibutyltin dilaurate, dibutyltin oxide, dibutyltin diacetate, dibutyltin phthalate, bis (dibutyltin lauric acid) ) Oxide, dibutyltin bis (acetylacetonate), dibutyltin bis (monoester malate), tin octylate, dibutyltin octoate, dioctyltin oxide, dibutyltin bis (triethoxy silicate), bis (dibutyltin bis triethoxy silicate) And organic tin compounds such as dibutyltin oxybisethoxy silicate; and organic titanium compounds such as tetra-n-butoxytitanate and tetraisopropoxytitanate. These silanol condensation catalysts may be used alone or in combination of two or more.
シラノール縮合触媒としては、１，１，３，３−テトラブチル−１，３−ジラウリルオキシカルボニル−ジスタノキサンが好ましい。このようなシラノール縮合触媒によれば、硬化性組成物の硬化速度を容易に調整することができる。 As a silanol condensation catalyst, 1,1,3,3-tetrabutyl-1,3-dilauryloxycarbonyl-distannoxane is preferable. According to such a silanol condensation catalyst, the curing rate of the curable composition can be easily adjusted.
硬化性組成物中におけるシラノール縮合触媒の含有量は、加水分解性シリル基を有するポリアルキレンオキサイド１００質量部に対して１〜１０質量部が好ましく、１〜５質量部がより好ましい。硬化性組成物中におけるシラノール縮合触媒の含有量が１質量部以上であると、硬化性組成物の硬化速度を速くして、硬化性組成物の硬化に要する時間の短縮化を図ることができる。また、硬化性組成物中におけるシラノール縮合触媒の含有量が１０質量部以下であると、硬化性組成物が適度な硬化速度を有し、硬化性組成物の貯蔵安定性及び取扱性を向上させることができる。 The content of the silanol condensation catalyst in the curable composition is preferably 1 to 10 parts by mass, and more preferably 1 to 5 parts by mass with respect to 100 parts by mass of the polyalkylene oxide having a hydrolyzable silyl group. When the content of the silanol condensation catalyst in the curable composition is 1 part by mass or more, the curing rate of the curable composition can be increased, and the time required for curing of the curable composition can be shortened. . In addition, when the content of the silanol condensation catalyst in the curable composition is 10 parts by mass or less, the curable composition has an appropriate curing rate to improve the storage stability and the handleability of the curable composition. be able to.
［他の添加剤］
硬化性組成物は、チキソ性付与剤、酸化防止剤、紫外線吸収剤、顔料、染料、沈降防止剤、及び溶剤など他の添加剤を含んでいてもよい。なかでも、チキソ性付与剤、紫外線吸収剤、及び酸化防止剤が好ましく挙げられる。
[Other additives]
The curable composition may contain other additives such as a thixotropic agent, an antioxidant, a UV absorber, a pigment, a dye, an antisettling agent, and a solvent. Among them, a thixotropic agent, a UV absorber, and an antioxidant are preferably mentioned.
チキソ性付与剤は、硬化性組成物にチキソトロピー性を発現せることができるものであればよい。チキソ性付与剤としては、水添ひまし油、脂肪酸ビスアマイド、ヒュームドシリカなどが好ましく挙げられる。 The thixotropic agent may be any agent capable of exhibiting thixotropic properties in the curable composition. As a thixotropic agent, hydrogenated castor oil, fatty acid bisamide, fumed silica and the like are preferably mentioned.
硬化性組成物中におけるチキソ性付与剤の含有量は、加水分解性シリル基を有するポリアルキレンオキサイド１００質量部に対して０．１〜２００質量部が好ましく、１〜１５０質量部がより好ましい。硬化性組成物中におけるチキソ性付与剤の含有量が０．１質量部以上であると、硬化性組成物にチキソトロピー性を効果的に付与することができる。また、硬化性組成物中におけるチキソ性付与剤の含有量が２００質量部以下であると、硬化性組成物が適度な粘度を有し、硬化性組成物の取扱性が向上する。 The content of the thixotropic agent in the curable composition is preferably 0.1 to 200 parts by mass, and more preferably 1 to 150 parts by mass with respect to 100 parts by mass of the polyalkylene oxide having a hydrolyzable silyl group. When the content of the thixotropic agent in the curable composition is 0.1 parts by mass or more, thixotropic properties can be effectively imparted to the curable composition. In addition, when the content of the thixotropic agent in the curable composition is 200 parts by mass or less, the curable composition has an appropriate viscosity, and the handleability of the curable composition is improved.
紫外線吸収剤としては、トリアジン系紫外線吸収剤、ベンゾトリアゾール系紫外線吸収剤、ベンゾフェノン系紫外線吸収剤などが挙げられ、ベンゾトリアゾール系紫外線吸収剤、ベンゾフェノン系紫外線吸収剤が好ましく、ベンゾトリアゾール系紫外線吸収剤がより好ましい。硬化性組成物中における紫外線吸収剤の含有量は、加水分解性シリル基を有するポリアルキレンオキサイド１００質量部に対して０．１〜２０質量部が好ましく、０．１〜１０質量部がより好ましい。 The UV absorbers include triazine based UV absorbers, benzotriazole based UV absorbers, benzophenone based UV absorbers and the like, and benzotriazole based UV absorbers and benzophenone based UV absorbers are preferable, and benzotriazole based UV absorbers. Is more preferred. The content of the ultraviolet light absorber in the curable composition is preferably 0.1 to 20 parts by mass, more preferably 0.1 to 10 parts by mass with respect to 100 parts by mass of the polyalkylene oxide having a hydrolyzable silyl group. .
酸化防止剤としては、例えば、ヒンダードフェノール系酸化防止剤、モノフェノール系酸化防止剤、ビスフェノール系酸化防止剤、及びポリフェノール系酸化防止剤などが挙げられ、ヒンダードフェノール系酸化防止剤が好ましく挙げられる。硬化性組成物中における酸化防止剤の含有量は、加水分解性シリル基を有するポリアルキレンオキサイド１００質量部に対して０．１〜２０質量部が好ましく、０．３〜１０質量部がより好ましい。 Examples of the antioxidant include hindered phenol-based antioxidants, monophenol-based antioxidants, bisphenol-based antioxidants, polyphenol-based antioxidants and the like, and hindered phenol-based antioxidants are preferably mentioned. Be The content of the antioxidant in the curable composition is preferably 0.1 to 20 parts by mass, and more preferably 0.3 to 10 parts by mass with respect to 100 parts by mass of the polyalkylene oxide having a hydrolyzable silyl group. .
［光安定剤］
硬化性組成物は光安定剤を含有していることが好ましく、ヒンダードアミン系光安定剤を含んでいることがより好ましい。ヒンダードアミン系光安定剤によれば、硬化後に優れたゴム弾性及び塗膜強度をより長期間に亘って維持することができる硬化性組成物を提供することができる。
[Light stabilizer]
The curable composition preferably contains a light stabilizer, and more preferably contains a hindered amine light stabilizer. According to the hindered amine light stabilizer, it is possible to provide a curable composition capable of maintaining excellent rubber elasticity and film strength for a longer period of time after curing.
ヒンダードアミン系光安定剤としては、例えば、ビス（１，２，２，６，６−ペンタメチル−４−ピペリジル）セバケート及びメチル１，２，２，６，６−ペンタメチル−４−ピペリジルセバケートの混合物、ビス（２，２，６，６−テトラメチル−４−ピペリジル）セバケート、ジブチルアミン・１，３，５−トリアジン・Ｎ，Ｎ’−ビス（２，２，６，６−テトラメチル−４−ピペリジル−１，６−ヘキサメチレンジアミンとＮ−（２，２，６，６−テトラメチル−４−ピペリジル）ブチルアミンとの重縮合物、ポリ［｛６−（１，１，３，３−テトラメチルブチル）アミノ−１，３，５−トリアジン−２，４−ジイル｝｛（２，２，６，６−テトラメチル−４−ピペリジル）イミノ｝ヘキサメチレン｛（２，２，６，６−テトラメチル−４−ピペリジル）イミノ｝］、コハク酸ジメチルと４−ヒドロキシ−２，２，６，６−テトラメチル−１−ピペリジンエタノールとの重縮合物などが挙げられる。 As a hindered amine light stabilizer, for example, a mixture of bis (1,2,2,6,6-pentamethyl-4-piperidyl) sebacate and methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate Bis (2,2,6,6-tetramethyl-4-piperidyl) sebacate, dibutylamine · 1,3,5-triazine · N, N′-bis (2,2,6,6-tetramethyl-4 Polycondensate of piperidyl-1,6-hexamethylenediamine with N- (2,2,6,6-tetramethyl-4-piperidyl) butylamine, poly [{6- (1,1,3,3- Tetramethylbutyl) amino-1,3,5-triazine-2,4-diyl} {(2,2,6,6-tetramethyl-4-piperidyl) imino} hexamethylene {(2,2,6,6) -Tetramethyl 4-piperidyl) imino}], etc. polycondensate of dimethyl succinate and 4-hydroxy-2,2,6,6-tetramethyl-1-piperidine ethanol.
ヒンダードアミン系光安定剤としては、ＮＯＲ型ヒンダードアミン系光安定剤が好ましく挙げられる。ＮＯＲ型ヒンダードアミン系光安定剤によれば、硬化後に経時的なゴム弾性及び塗膜強度の低下が抑制されている硬化性組成物を提供することができる。 As a hindered amine light stabilizer, NOR type hindered amine light stabilizer is mentioned preferably. According to the NOR type hindered amine light stabilizer, it is possible to provide a curable composition in which a decrease in rubber elasticity and coating film strength with time after curing is suppressed.
ＮＯＲ型ヒンダードアミン系光安定剤は、ピペリジン環骨格に含まれている窒素原子（Ｎ）に酸素原子（Ｏ）を介してアルキル基（Ｒ）が結合しているＮＯＲ構造を有している。ＮＯＲ構造におけるアルキル基の炭素数は、１〜２０が好ましく、１〜１８がより好ましく、１８が特に好ましい。アルキル基としては、直鎖状のアルキル基、分岐鎖状のアルキル基、及び、環状のアルキル基（飽和脂環式炭化水素基）が挙げられる。 The NOR type hindered amine light stabilizer has a NOR structure in which an alkyl group (R) is bonded to a nitrogen atom (N) contained in a piperidine ring skeleton via an oxygen atom (O). 1-20 are preferable, as for carbon number of the alkyl group in NOR structure, 1-18 are more preferable, and 18 is especially preferable. Examples of the alkyl group include linear alkyl groups, branched alkyl groups, and cyclic alkyl groups (saturated alicyclic hydrocarbon groups).
直鎖状のアルキル基としては、例えば、メチル基、エチル基、ｎ−プロピル基、ｎ−ブチル基、ｎ−ペンチル基、ｎ−ヘキシル基、ｎ−オクチル基、ｎ−ノニル基、ｎ−デシル基などが挙げられる。分岐鎖状のアルキル基としては、例えば、イソプロピル、イソブチル、ｓｅｃ−ブチル、ｔｅｒｔ−ブチルなどが挙げられる。環状のアルキル基（飽和脂環式炭化水素基）としては、例えば、シクロペンチル基、シクロヘキシル基、シクロオクチル基などが挙げられる。また、アルキル基を構成している水素原子が、ハロゲン原子（例えば、フッ素原子、塩素原子、臭素原子等）又はヒドロキシル基などで置換されていてもよい。 As a linear alkyl group, for example, methyl group, ethyl group, n-propyl group, n-butyl group, n-pentyl group, n-hexyl group, n-octyl group, n-nonyl group, n-decyl group Groups and the like. Examples of branched alkyl groups include isopropyl, isobutyl, sec-butyl, tert-butyl and the like. As a cyclic alkyl group (saturated alicyclic hydrocarbon group), a cyclopentyl group, a cyclohexyl group, a cyclooctyl group etc. are mentioned, for example. In addition, a hydrogen atom constituting an alkyl group may be substituted by a halogen atom (for example, a fluorine atom, a chlorine atom, a bromine atom or the like) or a hydroxyl group.
ＮＯＲ型ヒンダードアミン系光安定剤としては、下記式（Ｉ）で示されるヒンダードアミン系光安定剤が挙げられる。 Examples of the NOR type hindered amine light stabilizer include hindered amine light stabilizers represented by the following formula (I).
ＮＯＲ型ヒンダードアミン系光安定剤を用いる場合、ＮＯＲ型ヒンダードアミン系光安定剤と、ベンゾトリアゾール系紫外線吸収剤又はトリアジン系紫外線吸収剤とを組み合わせて用いることが好ましい。これにより、硬化後に経時的なゴム弾性及び塗膜強度の低下がより抑制されている硬化性組成物を提供することができる。 When a NOR type hindered amine light stabilizer is used, it is preferable to use a combination of a NOR type hindered amine light stabilizer and a benzotriazole type ultraviolet absorber or a triazine type ultraviolet absorber. This makes it possible to provide a curable composition in which a decrease in rubber elasticity and film strength with time after curing is further suppressed.
硬化性組成物中における光安定剤の含有量は、加水分解性シリル基を有するポリアルキレンオキサイド１００質量部に対して０．０１〜２０質量部が好ましく、０．１〜１０質量部がより好ましい。 The content of the light stabilizer in the curable composition is preferably 0.01 to 20 parts by mass, and more preferably 0.1 to 10 parts by mass with respect to 100 parts by mass of the polyalkylene oxide having a hydrolyzable silyl group. .
硬化性組成物は、加水分解性シリル基を有するポリアルキレンオキサイド及び長石類と、必要に応じて添加される添加剤とを均一に混合することによって製造することができる。硬化性組成物は、溶媒（例えば、アルコール、キシレン、トルエンなど）を含有していないことが好ましい。 The curable composition can be produced by uniformly mixing the polyalkylene oxide having a hydrolyzable silyl group and the feldspar with an additive which is optionally added. The curable composition preferably does not contain a solvent (eg, alcohol, xylene, toluene, etc.).
硬化性組成物は、接着性に優れていると共に、優れたゴム弾性及び塗膜強度を長期間に亘って維持することができる硬化物を形成することができることから、塗膜防水剤、シーリング材、コーティング材、接着剤、及び塗料など各種用途に使用することができる。なかでも、塗膜防水剤として用いられることが好ましい。 A curable composition is excellent in adhesiveness and can form a cured product capable of maintaining excellent rubber elasticity and coating strength over a long period of time, and thus a coating waterproofing agent and a sealing material It can be used in various applications such as coating materials, adhesives, and paints. Especially, it is preferable to use as a coating film waterproofing agent.
硬化性組成物は、上述の通り、塗膜防水剤として用いられることが好ましく、具体的には、硬化性組成物を、コンクリート構築物の屋上などの防水下地となるコンクリート表面に塗工する。この際、硬化性組成物は塗工性に優れていることから、防水下地上に円滑に且つ均一に塗工することができる。そして、硬化性組成物を養生させて硬化させることによって防水塗膜を形成することができる。 As described above, the curable composition is preferably used as a paint film waterproofing agent. Specifically, the curable composition is applied to a concrete surface to be a waterproof foundation such as a roof of a concrete construction. Under the present circumstances, since a curable composition is excellent in coating property, it can coat smoothly and uniformly on a waterproof base. And a waterproof coating film can be formed by curing and hardening a curable composition.
硬化性組成物を用いることによって、防水下地と、上記防水下地の表面に設けられ且つ硬化性組成物の硬化物を含む防水塗膜を含む防水構造を構成することができる。 By using the curable composition, it is possible to constitute a waterproof structure including a waterproof substrate, and a waterproof coating film provided on the surface of the above-mentioned waterproof substrate and containing a cured product of the curable composition.
得られた防水塗膜は、優れたゴム弾性、塗膜強度、及び、防水下地などに対する優れた密着性を有していることから、防水下地の温度変化による伸縮の他、防水下地の経時劣化に伴う亀裂による防水下地の伸長に円滑に追従し、防水塗膜は長期間に亘って亀裂などを生じることなく、優れた防水性能を維持することができる。 Since the obtained waterproof coating film has excellent rubber elasticity, coating film strength, and excellent adhesion to a waterproof base, etc., in addition to the expansion and contraction due to the temperature change of the waterproof base, the temporal deterioration of the waterproof base It smoothly follows the extension of the waterproof substrate due to the cracks that accompany it, and the waterproof coating can maintain excellent waterproof performance without cracking for a long period of time.
本発明の硬化性組成物は、低粘度で塗工性に優れていると共に、優れたゴム弾性及び塗膜強度を有し且つ優れた密着性を有する硬化物を形成することができる。 The curable composition of the present invention can form a cured product having low viscosity and excellent coatability, as well as excellent rubber elasticity and coating film strength and excellent adhesion.
以下に、本発明を実施例を用いてより具体的に説明するが、本発明はこれに限定されない。 Hereinafter, the present invention will be more specifically described using examples, but the present invention is not limited thereto.
実施例及び比較例において下記の化合物を用いた。
・ポリアルキレンオキサイド１（主鎖骨格がポリプロピレンオキサイドからなり且つ主鎖の末端にプロピルジメトキシシリル基を有するポリアルキレンオキサイド、一分子あたりのメチルジメトキシシリル基の平均個数：１．４個、数平均分子量：１４０００、カネカ社製 商品名「ＭＳポリマー ＳＡＴ３５０」）
・ポリアルキレンオキサイド２（主鎖骨格がポリプロピレンオキサイドからなり且つ主鎖の末端にメチルジメトキシシリル基を有するポリアルキレンオキサイド、数平均分子量：９０００、カネカ社製 商品名「ＭＳポリマー ＥＳＴ２８０」）
・ポリアルキレンオキサイド３（主鎖骨格がポリプロピレンオキサイドからなり且つ主鎖の末端にメチルジメトキシシリル基を有するポリアルキレンオキサイド、数平均分子量：１６０００、旭硝子社製 商品名「エクセスターＳ３４３０」）
・長石類 （ネフェリンサイアナイト、平均粒子径：５μｍ、白石カルシウム社製 商品名「ネスパー」）
・シラノール縮合触媒（１，１，３，３−テトラブチル−１，３−ジラウリルオキシカルボニル−ジスタノキサン、日東化成社製 商品名「ネオスタンＵ−１３０」）
・アミノシランカップリング剤［Ｎ−（２−アミノエチル）−３−アミノプロピルトリメトキシシラン、信越化学社製 商品名 ＫＢＭ−６０３」］
・エポキシシランカップリング剤（３−グリシドキシプロピルトリメトキシシラン、（信越化学社製 商品名「ＫＢＭ−４０３」）
・コロイダル炭酸カルシウム（白石工業社製 商品名「ＣＣＲ」）
・重質炭酸カルシウム１（石原産業社製 商品名「ＮＣＣ２３１０」）
・重質炭酸カルシウム２（白石カルシウム社製 商品名「μ−ｐｏｗｄｅｒ ３Ｓ」）
・カオリン（林化成社製 商品名「ＡＳＰ１７０」）
・カーボンブラック（旭カーボン社製 商品名「８５００Ｆ」）
・ガラスフリット（リン酸系ガラス、日本フリット社製 「ＶＹ０１４４」、主成分：Ｐ2Ｏ5、ＡＩ2Ｏ3及びＲ2Ｏ、Ｒはアルカリ金属原子、軟化点：４０４℃）
・可塑剤（ポリプロピレングリコール、数平均分子量：３０００、旭電化社製 商品名「Ｐ−３０００」）
・脱水剤（ビニルトリメトキシシラン、日本ユニカ社製 商品名「ＮＵＣシリコーンＡ１７１」）
・ベンゾトリアゾール系紫外線吸収剤（ＢＡＳＦジャパン社製 製品名「チヌビン３２６」）
・ヒンダードフェノール系酸化防止剤（ＢＡＳＦジャパン社製 製品名「イルガノックス１０１０」）
・ヒンダードアミン系光安定剤（ＢＡＳＦジャパン社製 製品名「チヌビン７７０」）
The following compounds were used in Examples and Comparative Examples.
· Polyalkylene oxide 1 (Polyalkylene oxide whose main chain skeleton is composed of polypropylene oxide and has a propyldimethoxysilyl group at the end of the main chain, average number of methyldimethoxysilyl groups per molecule: 1.4, number average molecular weight : 14000, manufactured by Kaneka Corp. Brand name “MS polymer SAT 350”)
Polyalkylene oxide 2 (polyalkylene oxide having a main chain skeleton made of polypropylene oxide and having a methyldimethoxysilyl group at the end of the main chain, number average molecular weight: 9000, manufactured by Kaneka, trade name “MS polymer EST 280”)
· Polyalkylene oxide 3 (Polyalkylene oxide whose main chain skeleton is made of polypropylene oxide and has a methyldimethoxysilyl group at the end of the main chain, number average molecular weight: 16000, manufactured by Asahi Glass Co., Ltd., trade name "Exester S3430")
・ Feldspar (nepheline sianite, average particle size: 5 μm, manufactured by Shiraishi Calcium Co., Ltd., trade name "Nesper")
· Silanol condensation catalyst (1,1,3,3-tetrabutyl-1,3-dilauryloxycarbonyl-distannoxane, trade name "Neostan U-130" manufactured by Nitto Kasei Co., Ltd.)
· Aminosilane coupling agent [N- (2-aminoethyl) -3-aminopropyltrimethoxysilane, manufactured by Shin-Etsu Chemical Co., Ltd. trade name KBM-603 "]
・ Epoxysilane coupling agent (3-glycidoxypropyltrimethoxysilane, (manufactured by Shin-Etsu Chemical Co., Ltd., trade name "KBM-403")
-Colloidal calcium carbonate (manufactured by Shiraishi Kogyo Co., Ltd., trade name "CCR")
・ Heavy calcium carbonate 1 (manufactured by Ishihara Sangyo Co., Ltd., trade name “NCC 2310”)
・ Heavy calcium carbonate 2 (manufactured by Shiroishi Calcium Co., Ltd., trade name "μ-powder 3S")
・ Kaolin (trade name "ASP 170" manufactured by Hayashi Kasei Co., Ltd.)
-Carbon black (trade name "8500F" manufactured by Asahi Carbon Co., Ltd.)
Glass frit (phosphate glass, manufactured by Nippon Frit Co., Ltd. “VY0144”, main components: P 2 O 5 , AI 2 O 3 and R 2 O, R is an alkali metal atom, softening point: 404 ° C.)
・ Plasticizer (polypropylene glycol, number average molecular weight: 3000, manufactured by Asahi Denka Co., Ltd., trade name "P-3000")
Dehydrating agent (vinyltrimethoxysilane, manufactured by Nippon Unica, trade name "NUC silicone A 171")
・ Benzotriazole-based UV absorber (manufactured by BASF Japan Ltd., product name "Tinubin 326")
・ Hindered phenolic antioxidant (manufactured by BASF Japan, product name “Irganox 1010”)
・ Hindered amine light stabilizer (manufactured by BASF Japan Ltd., product name “Tinubin 770”)
（実施例１〜１３及び比較例１〜７）
ポリアルキレンオキサイド１〜３、長石類、シラノール縮合触媒、アミノシランカップリング剤、エポキシシランカップリング剤、コロイダル炭酸カルシウム、重質炭酸カルシウム１、重質炭酸カルシウム２、カオリン、カーボンブラック、ガラスフリット、可塑剤、脱水剤、ベンゾトリアゾール系紫外線吸収剤、ヒンダードフェノール系酸化防止剤及びヒンダードアミン系光安定剤を表１に示した所定量ずつプラネタリーミキサーに供給して真空雰囲気下にて６０分間混練することによって硬化性組成物を得た。
(Examples 1 to 13 and Comparative Examples 1 to 7)
Polyalkylene oxides 1 to 3, feldspars, silanol condensation catalyst, aminosilane coupling agent, epoxysilane coupling agent, colloidal calcium carbonate, calcium carbonate 1, calcium carbonate 2, kaolin, carbon black, glass frit, plastic Agents, dehydrating agents, benzotriazole type ultraviolet absorbers, hindered phenol type antioxidants and hindered amine type light stabilizers are supplied to the planetary mixer in predetermined amounts shown in Table 1 and kneaded for 60 minutes in a vacuum atmosphere Thus, a curable composition was obtained.
得られた硬化性組成物について、粘度、Ｔｉ値、最大応力、破断伸び及び圧縮せん断強度を下記の要領で測定し、その結果を表１に示した。 The obtained curable composition was measured for viscosity, Ti value, maximum stress, elongation at break and compressive shear strength in the following manner, and the results are shown in Table 1.
（塗工性評価：粘度）
硬化性組成物の粘度を２３℃、１０ｒｐｍの条件下にＨ型粘度計にて測定した。
(Applicability evaluation: viscosity)
The viscosity of the curable composition was measured with an H-type viscometer under conditions of 23 ° C. and 10 rpm.
（塗工性評価：Ｔｉ値）
硬化性組成物の粘度（１０ｒｐｍ）を２３℃、１０ｒｐｍの条件下にてＢＨ型粘度計にてローターＮｏ．５を用いて測定した。硬化性組成物の粘度（１ｒｐｍ）を２３℃、１ｒｐｍの条件下にてＢＨ型粘度計にてローターＮｏ．５を用いて測定した。硬化性組成物のＴｉ値を下記式に基づいて算出した。
Ｔｉ値＝粘度（１ｒｐｍ）／粘度（１０ｒｐｍ）
(Coating evaluation: Ti value)
The viscosity (10 rpm) of the curable composition was measured using a BH viscometer under conditions of 23 ° C. and 10 rpm as rotor No. It measured using 5. The viscosity (1 rpm) of the curable composition was measured using a BH viscometer at 23 ° C. and 1 rpm with a rotor No. 1 rotor. It measured using 5. The Ti value of the curable composition was calculated based on the following formula.
Ti value = viscosity (1 rpm) / viscosity (10 rpm)
（塗膜強度及びゴム弾性評価：最大応力及び破断伸び）
硬化性組成物を離型処理された基板上に厚みが３ｍｍとなるように塗工した後、硬化性組成物を２３℃、相対湿度５０％にて１カ月間養生した。硬化性組成物の硬化物をＪＩＳ Ｋ６２５１準拠の３号ダンベルに切り出して試験片を作製した。
(Coating film strength and rubber elasticity evaluation: maximum stress and elongation at break)
After the curable composition was applied onto the release-treated substrate to a thickness of 3 mm, the curable composition was cured at 23 ° C. and 50% relative humidity for one month. The cured product of the curable composition was cut into No. 3 dumbbells in accordance with JIS K6251 to prepare a test piece.
試験片の表面に、引張方向に直交し且つ互いに平行な一対の直線を標線として描いた。標線間の距離（初期標線間距離）は２０ｍｍであった。試験片を２３℃湿度、相対湿度５０％の条件下で５００ｍｍ/分の速度で引っ張った。 On the surface of the test piece, a pair of straight lines perpendicular to the tensile direction and parallel to each other were drawn as marked lines. The distance between marks (initial distance between marks) was 20 mm. The test piece was pulled at a speed of 500 mm / min under conditions of 23 ° C. humidity and 50% relative humidity.
試験片に亀裂が生じた時点における引張応力を測定し、その値を最大応力（Ｎ／ｍｍ2）とした。 The tensile stress at the time of the crack in the test piece was measured, and the value was taken as the maximum stress (N / mm 2 ).
試験片に亀裂が生じた時点における標線間の距離（破断時標線間距離）を測定した。破断伸び（％）を下記式に基づいて算出した。
破断伸び（％）＝１００×（破断時標線間距離−初期標線間距離）／初期標線間距離
The distance between marked lines (the distance between marked lines at break) at the time when the test piece cracked was measured. Elongation at break (%) was calculated based on the following formula.
Elongation at break (%) = 100 × (distance between marks at break-distance between initial marks) / distance between initial marks
（密着性評価：圧縮せん断強度）
ＪＩＳ Ｈ４０００ Ａ５０５２に規定するアルミニウム合金板を２枚用意した。アルミニウム合金板は、縦１２ｍｍ、横５０ｍｍ、厚み４．０ｍｍであって平面長方形状であった。
(Adhesive evaluation: compressive shear strength)
Two aluminum alloy plates specified in JIS H4000 A5052 were prepared. The aluminum alloy plate was 12 mm long, 50 mm wide, and 4.0 mm thick, and had a flat rectangular shape.
一方のアルミニウム合金板の表面に硬化性組成物を塗工し、硬化性組成物の塗工面上に他方のアルミニウム合金板を重ね合わせて積層体を作製した。硬化性組成物は、塗工幅（縦方向）が１２ｍｍ、塗工長さ（横方向）が１０ｍｍ、塗工厚みが０．３ｍｍとなるようにアルミニウム合金板上に塗工された。 The curable composition was coated on the surface of one of the aluminum alloy sheets, and the other aluminum alloy sheet was superposed on the coated surface of the curable composition to prepare a laminate. The curable composition was applied onto the aluminum alloy sheet such that the coating width (longitudinal direction) was 12 mm, the coating length (horizontal direction) was 10 mm, and the coating thickness was 0.3 mm.
積層体を２３℃、相対湿度５０％の環境下に７日間放置して硬化性組成物を硬化させて、二枚のアルミニウム合金板を硬化性組成物によって接着一体化させて試験体を作製した。 The laminate was allowed to stand in an environment of 23 ° C. and 50% relative humidity for 7 days to cure the curable composition, and the two aluminum alloy plates were bonded and integrated by the curable composition to prepare a test body .
得られた試験体を用いて万能引張試験機（インストロン社製）を用いて、３ｍｍ／分の速度で圧縮試験を行い、試験体を構成している硬化性組成物の硬化物が破断した時の圧縮せん断強度を測定した。 A compression test was carried out at a speed of 3 mm / min using a universal tensile tester (manufactured by Instron) using the obtained test body, and the cured product of the curable composition constituting the test body was broken. Compressive shear strength was measured.
硬化性組成物は、ゴム弾性及び塗膜強度に優れた硬化物を形成することができ、硬化物は、防水下地などの被着体に対する密着性に優れている。硬化性組成物は、例えば、防水性に優れた防水構造を構築することができる。 The curable composition can form a cured product excellent in rubber elasticity and coating film strength, and the cured product is excellent in adhesion to an adherend such as a waterproof base. The curable composition can, for example, construct a waterproof structure excellent in waterproofness.
Claims (4)
平均粒子径が０．０１〜１００μｍの長石類を含むことを特徴とする硬化性組成物。 A polyalkylene oxide having a hydrolyzable silyl group,
Curable composition characterized by containing feldspar having an average particle size of 0.01 to 100 μm.
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| WO2023182346A1 (en) * | 2022-03-25 | 2023-09-28 | 積水フーラー株式会社 | Curable resin composition for electronic material |
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