JP2019077584A - Glass melting furnace, and production method of glass article - Google Patents

Glass melting furnace, and production method of glass article Download PDF

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JP2019077584A
JP2019077584A JP2017205301A JP2017205301A JP2019077584A JP 2019077584 A JP2019077584 A JP 2019077584A JP 2017205301 A JP2017205301 A JP 2017205301A JP 2017205301 A JP2017205301 A JP 2017205301A JP 2019077584 A JP2019077584 A JP 2019077584A
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glass
throat
molten glass
melting
tank
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JP6943136B2 (en
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俊明 松山
Toshiaki MATSUYAMA
俊明 松山
一樹 内田
Kazuki Uchida
一樹 内田
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AGC Inc
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Asahi Glass Co Ltd
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Priority to JP2017205301A priority Critical patent/JP6943136B2/en
Priority to KR1020180126526A priority patent/KR102540619B1/en
Priority to CN201811241255.1A priority patent/CN109694176B/en
Priority to TW107137482A priority patent/TWI833713B/en
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/26Outlets, e.g. drains, siphons; Overflows, e.g. for supplying the float tank, tweels
    • C03B5/262Drains, i.e. means to dump glass melt or remove unwanted materials
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/02Melting in furnaces; Furnaces so far as specially adapted for glass manufacture in electric furnaces, e.g. by dielectric heating
    • C03B5/027Melting in furnaces; Furnaces so far as specially adapted for glass manufacture in electric furnaces, e.g. by dielectric heating by passing an electric current between electrodes immersed in the glass bath, i.e. by direct resistance heating
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/225Refining
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/26Outlets, e.g. drains, siphons; Overflows, e.g. for supplying the float tank, tweels
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/42Details of construction of furnace walls, e.g. to prevent corrosion; Use of materials for furnace walls
    • C03B5/43Use of materials for furnace walls, e.g. fire-bricks
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B7/00Distributors for the molten glass; Means for taking-off charges of molten glass; Producing the gob, e.g. controlling the gob shape, weight or delivery tact
    • C03B7/08Feeder spouts, e.g. gob feeders
    • C03B7/088Outlets, e.g. orifice rings
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/50Glass production, e.g. reusing waste heat during processing or shaping
    • Y02P40/57Improving the yield, e-g- reduction of reject rates

Abstract

To provide a glass melting furnace capable of suppressing contamination of a glass article with heterogeneous glass, and a production method of a glass article.SOLUTION: A glass melting furnace 10 includes a melting vessel 20 and a throat 30. The melting vessel 20 is equipped with a partition wall 40 and a discharge port 50 and melts glass at a temperature Tof 1,580°C or higher where the viscosity η is 10poise. The partition wall 40 is set in the width direction of the melting vessel 20 and blocks a part of a flow of molten glass G. The discharge port 50 is set in the bottom 21 of the melting vessel 20 between the throat 30 and the partition wall 40 and discharges the molten glass G. The height Hof the lower edge of the entrance of the throat 30 is 20 [mm] or more from the bottom 21.SELECTED DRAWING: Figure 1

Description

本発明は、ガラス溶解炉、及びガラス物品の製造方法に関する。   The present invention relates to a glass melting furnace and a method of manufacturing a glass article.

ガラス溶解炉を構成する耐火物は、高温の溶融ガラスと接触して侵食され、溶融ガラスに溶出する。これにより、溶融ガラスとは異なる組成、比重の異質ガラスが生成する。一方、溶融ガラスと接触する部分の耐火物は、溶融ガラスに対して耐食性に優れる電鋳煉瓦を使用することが多い。このうち、ジルコニア系電鋳煉瓦は、他の電鋳煉瓦よりもジルコニア(ZrO)含有率が高く、他の電鋳煉瓦よりも耐食性に優れる。しかし、ジルコニア(ZrO)は、ガラス組成には含まれない成分であり、溶融ガラスよりも比重が高いため、溶融ガラスに溶出すると、異質ガラスの生成が助長される。このような異質ガラスが、最終的に得られるガラス物品に混入すると、所望の品質を満たさないため、生産歩留が低下するという問題が起きる。 The refractory constituting the glass melting furnace is corroded in contact with the high temperature molten glass and is eluted into the molten glass. As a result, extraneous glass different in composition and specific gravity from molten glass is produced. On the other hand, the refractory in the portion in contact with the molten glass often uses an electroformed brick which is excellent in corrosion resistance with respect to the molten glass. Among these, zirconia-based electroformed bricks have a higher zirconia (ZrO 2 ) content than other electroformed bricks, and are more excellent in corrosion resistance than other electroformed bricks. However, zirconia (ZrO 2 ) is a component not included in the glass composition, and has a specific gravity higher than that of the molten glass, and therefore elution to the molten glass promotes the formation of foreign glass. When such foreign glass is mixed into the finally obtained glass article, the desired quality is not satisfied, which causes a problem that the production yield is lowered.

このような異質ガラスをガラス物品に混入させないように、特許文献1には、底部に異質ガラスを排出するためのガラス排出部を具備したガラス溶解炉が開示されている。   Patent Document 1 discloses a glass melting furnace provided with a glass discharge part for discharging the foreign glass at the bottom so as not to mix such foreign glass into the glass article.

特開2006−62903号公報JP, 2006-62903, A

しかし、底部にガラス排出部を設けるだけでは、異質ガラスがガラス物品に混入することを充分に抑制できない。ガラス溶解炉内における溶融ガラスは、ガラス溶解炉内で循環流を形成しながら下流側に流動する。溶融ガラスの循環流が大きい場合や、循環流の移動速度が速い場合は、底部に停滞している異質ガラスが、ガラス排出部へ流れにくくなる。そのため、溶融ガラスを清澄槽又は成形炉に向けて移送させるスロートに異質ガラスが混入し、最終的に得られるガラス物品にも異質ガラスが混入する。   However, simply providing the glass discharge portion at the bottom can not sufficiently suppress foreign glass from being mixed into the glass article. The molten glass in the glass melting furnace flows downstream while forming a circulating flow in the glass melting furnace. In the case where the circulating flow of the molten glass is large or the moving speed of the circulating flow is high, the foreign glass stagnating at the bottom becomes difficult to flow to the glass discharge part. Therefore, foreign glass mixes in the throat which transfers molten glass toward a clarification tank or a forming furnace, and foreign glass also mixes in the glass article finally obtained.

特に、粘度ηが10ポイズとなる温度Tが1580℃以上のガラスは、ガラス溶解炉内における溶融ガラスの温度が高くなるため、ガラス溶解炉を構成する耐火物が侵食され、溶融ガラスに溶出しやすい。そのため、異質ガラスがガラス物品に混入する問題が顕在化する。 In particular, the temperature T 2 is 1580 ° C. or more glass viscosity η is 10 2 poise, the temperature of the molten glass in the glass melting furnace is increased, refractory constituting the glass melting furnace is eroded, the molten glass It is easy to elute. Therefore, the problem that foreign glass mixes in a glass article becomes apparent.

本発明は、上記課題に鑑みてなされたものであって、異質ガラスがガラス物品に混入することを抑制できるガラス溶解炉、及びガラス物品の製造方法を提供することを目的とする。   This invention is made in view of the said subject, Comprising: It aims at providing the manufacturing method of a glass melting furnace which can suppress that foreign glass mixes in a glass article, and a glass article.

本発明のガラス溶解炉は、ガラス原料を溶解し、得られた溶融ガラスを下流側に流動させる溶解槽と、前記溶解槽に連通して設けられ、前記溶融ガラスを清澄槽又は成形炉に向けて移送させるスロートとを備えるガラス溶解炉であって、前記溶解槽は、仕切壁と、排出部とを備え、粘度ηが10ポイズとなる温度Tが1580℃以上のガラスを溶解し、前記仕切壁は、前記溶解槽の幅方向にわたって設けられ、前記溶融ガラスの流れの一部を遮り、前記排出部は、前記スロートと前記仕切壁との間における前記溶解槽の底部に設けられ、前記溶融ガラスを排出し、前記底部から前記スロートの入口の下端までの高さが20[mm]以上であることを特徴とする。 The glass melting furnace of the present invention is provided in communication with the melting tank for melting the glass raw material and causing the obtained molten glass to flow downstream, and the melting tank, and directs the molten glass to the clarification tank or the forming furnace a glass melting furnace and a throat for transferring Te, the dissolver was dissolved and the partition wall, and a discharge portion, temperature T 2 at which the viscosity η is 10 2 poise to 1580 ° C. or more glass, The partition wall is provided across the width direction of the dissolution tank and blocks a part of the flow of the molten glass, and the discharge part is provided at the bottom of the dissolution tank between the throat and the partition wall. The molten glass is discharged, and the height from the bottom to the lower end of the throat inlet is 20 mm or more.

また、本発明のガラス物品の製造方法は、溶解工程と、成形工程と、徐冷工程とを含むガラス物品の製造方法であって、前記溶解工程は、溶解槽において、ガラス原料を溶解させ、得られた溶融ガラスを下流側に流動させ、粘度ηが10ポイズとなる温度Tが1580℃以上のガラスを溶解し、前記溶解槽は、前記溶解槽の幅方向にわたって設けられる仕切壁を備え、さらに前記スロートと前記仕切壁との間における前記溶解槽の底部に排出部を備え、前記仕切壁は、前記溶融ガラスの流れの一部を遮り、前記溶融ガラスは、前記溶解槽に連通して設けられるスロートを介して、清澄工程又は前記成形工程に向けて移送され、前記排出部は、前記溶融ガラスを排出し、前記底部から前記スロートの入口の下端までの高さが20[mm]以上であることを特徴とする。 The method for producing a glass article according to the present invention is a method for producing a glass article comprising a melting step, a forming step, and a slow cooling step, and the melting step dissolves the glass raw material in the melting tank, the resulting molten glass to flow to the downstream side, the viscosity η is dissolved temperature T 2 is 1580 ° C. or more glass becomes 10 2 poises, the melting tank, a partition wall provided across the width of the melting tank The apparatus further comprises a discharge part at the bottom of the dissolution tank between the throat and the partition wall, the partition wall interrupting a part of the flow of the molten glass, and the molten glass is in communication with the dissolution tank Through the provided throat, it is transported towards the clarification step or the forming step, the discharge part discharges the molten glass, and the height from the bottom to the lower end of the inlet of the throat is 20 mm ] It is characterized by being above.

本発明のガラス溶解炉、及びガラス物品の製造方法によれば、異質ガラスがガラス物品に混入することを抑制できる。   According to the glass melting furnace of this invention, and the manufacturing method of a glass article, it can suppress that foreign glass mixes in a glass article.

本発明に係る第一実施形態におけるガラス溶解炉のY軸垂直面での断面図である。It is sectional drawing in the Y-axis perpendicular | vertical surface of the glass melting furnace in 1st embodiment which concerns on this invention. 本発明に係る第一実施形態におけるガラス溶解炉のX軸垂直面での断面図であり、図1のI−I矢視断面図である。It is sectional drawing in the X-axis perpendicular | vertical surface of the glass melting furnace in 1st embodiment which concerns on this invention, and is an II arrow directional cross-sectional view of FIG. 本発明に係る第二実施形態におけるガラス溶解炉のY軸垂直面での断面図である。It is sectional drawing in the Y-axis perpendicular | vertical surface of the glass melting furnace in 2nd embodiment which concerns on this invention. 本発明に係る第二実施形態におけるガラス溶解炉のX軸垂直面での断面図であり、図1のII−II矢視断面図である。It is sectional drawing in the X-axis perpendicular | vertical surface of the glass melting furnace in 2nd embodiment which concerns on this invention, and is II-II arrow sectional drawing of FIG. 本発明に係る第一実施形態におけるガラス物品の製造方法を示すフローチャートである。It is a flowchart which shows the manufacturing method of the glass article in 1st embodiment which concerns on this invention.

以下、本発明に係る各種実施形態について、図面を用いて説明する。本明細書において、数値範囲を表す「〜」はその前後の数値を含む範囲を意味する。   Hereinafter, various embodiments according to the present invention will be described using the drawings. In the present specification, “to” representing a numerical range means a range including the numerical values before and after that.

なお、各図面の基準の方向は、記号、数字の方向に対応する。図面においては、適宜3次元直交座標系としてXYZ座標系を示し、Z軸方向を図1〜4における上下方向とし、X軸方向を図1,3に示すガラス溶解炉10,110の長さ方向(左右方向)とし、Y軸方向を図2,4に示すガラス溶解炉10,110の幅方向(左右方向)とする。本明細書においては、X軸方向は平面視における溶融ガラスGの流れ方向であり、Y軸方向は溶融ガラスGの流れ方向と直交する。   The direction of the reference of each drawing corresponds to the direction of the symbol and the numeral. In the drawings, the XYZ coordinate system is appropriately shown as a three-dimensional orthogonal coordinate system, the Z axis direction is the vertical direction in FIGS. 1 to 4, and the X axis direction is the length direction of the glass melting furnaces 10 and 110 shown in FIGS. The Y-axis direction is taken as the width direction (left-right direction) of the glass melting furnace 10, 110 shown in FIGS. In the present specification, the X-axis direction is the flow direction of the molten glass G in plan view, and the Y-axis direction is orthogonal to the flow direction of the molten glass G.

また、本明細書において、上流側及び下流側とは、ガラス溶解炉10,110内における溶融ガラスGの流れ方向(X軸方向)に対するものであり、+X側が下流側、−X側が上流側である。   Further, in the present specification, the upstream side and the downstream side refer to the flow direction (X axis direction) of the molten glass G in the glass melting furnace 10, 110, and the + X side is the downstream side and the -X side is the upstream side. is there.

[ガラス溶解炉]
「第一実施形態」
図1は、本発明に係る第一実施形態におけるガラス溶解炉のY軸垂直面での断面図である。図2は、本発明に係る第一実施形態におけるガラス溶解炉のX軸垂直面での断面図であり、図1のI−I矢視断面図である。本発明に係るガラス溶解炉の第一実施形態について、図1及び図2を参照して説明する。
[Glass melting furnace]
"First embodiment"
FIG. 1 is a cross-sectional view of a glass melting furnace according to a first embodiment of the present invention in a plane perpendicular to the Y-axis. FIG. 2 is a cross-sectional view taken along a plane perpendicular to the X-axis of the glass melting furnace according to the first embodiment of the present invention, and is a cross-sectional view taken along the line II in FIG. A first embodiment of a glass melting furnace according to the present invention will be described with reference to FIGS. 1 and 2.

本実施形態のガラス溶解炉10は、原料供給装置(不図示)によって供給されたガラス原料を溶解し、得られた溶融ガラスGを下流側(+X側)に流動させる溶解槽20と、溶解槽20に連通して設けられ、溶融ガラスGを清澄槽(不図示)又は成形炉(不図示)に向けて移送させるスロート30とを備える。   The glass melting furnace 10 of the present embodiment melts a glass raw material supplied by a raw material supply device (not shown), and causes the obtained molten glass G to flow downstream (+ X side), and a melting tank 20 and provided with a throat 30 for transferring the molten glass G toward a clarification tank (not shown) or a forming furnace (not shown).

溶解槽20は、仕切壁40と、排出部50とを備え、粘度ηが10ポイズとなる温度Tが1580℃以上のガラスを溶解する。仕切壁40は、溶解槽20の幅方向(Y軸方向)にわたって設けられ、溶融ガラスGの流れの一部を遮る。排出部50は、スロート30と仕切壁40との間における溶解槽20の底部21に設けられ、溶融ガラスGを排出する。 Dissolution tank 20, the partition wall 40, and a discharge unit 50, temperature T 2 at which the viscosity η is 10 2 poise dissolving 1580 ° C. or more glass. The partition wall 40 is provided across the width direction (Y-axis direction) of the melting tank 20 and blocks part of the flow of the molten glass G. The discharge part 50 is provided in the bottom part 21 of the dissolution tank 20 between the throat 30 and the partition wall 40, and discharges the molten glass G.

溶解槽20は、溶融ガラスGの上側(+Z側)に位置する壁部にバーナー(不図示)を備えており、燃料及びガスを用いるバーナー燃焼によって、溶解槽20の内部に供給されたガラス原料を溶解して溶融ガラスGを得る。燃料は天然ガス又は重油が用いられ、ガスは酸素又は空気が用いられる。溶解槽20は、底部21と側壁部22とを備え、溶融ガラスGを保持する。底部21及び側壁部22は、内側が溶融ガラスGと接触するため、耐食性に優れる電鋳煉瓦から形成される。電鋳煉瓦の例としては、ジルコニア系煉瓦、アルミナ・ジルコニア・シリカ(AZS)系煉瓦、アルミナ系煉瓦が挙げられる。底部21又は側壁部22は、通電電極(不図示)を備えてもよい。通電電極は、電圧を印加することよってジュール熱を発生させ、ガラス原料を溶解して溶融ガラスGを得る。   The melting tank 20 is provided with a burner (not shown) on the wall located on the upper side (+ Z side) of the molten glass G, and the glass raw material supplied to the inside of the melting tank 20 by burner combustion using fuel and gas. Are melted to obtain a molten glass G. The fuel is natural gas or heavy oil, and the gas is oxygen or air. The melting tank 20 includes a bottom 21 and a side wall 22 and holds the molten glass G. The bottom portion 21 and the side wall portion 22 are formed of an electroformed brick which is excellent in corrosion resistance since the inside is in contact with the molten glass G. Examples of electroformed bricks include zirconia-based bricks, alumina-zirconia-silica (AZS) -based bricks, and alumina-based bricks. The bottom 21 or the side wall 22 may be provided with a current-carrying electrode (not shown). The current-carrying electrode generates Joule heat by applying a voltage and melts the glass material to obtain a molten glass G.

溶解槽20は、溶融ガラスGと接触するため、溶解槽20を構成する電鋳煉瓦の一部が溶融ガラスGに溶出する。溶解槽20にジルコニア(ZrO)を含んだ電鋳煉瓦を用いた場合、比重が高いジルコニア(ZrO)成分が溶融ガラスGに溶出する。そのため、溶解槽20の底部21近傍には、ジルコニア(ZrO)濃度が高く、比重が高い異質ガラスG1が滞在している。 Since the melting tank 20 is in contact with the molten glass G, a portion of the electroformed brick constituting the melting tank 20 is eluted into the molten glass G. When an electroformed brick containing zirconia (ZrO 2 ) is used for the dissolution tank 20, the zirconia (ZrO 2 ) component having a high specific gravity is eluted into the molten glass G. Therefore, in the vicinity of the bottom portion 21 of the melting tank 20, the foreign glass G1 having a high concentration of zirconia (ZrO 2 ) and a high specific gravity is retained.

底部21からスロート30の入口の下端までの高さをHとする。高さHは、20[mm]以上である。高さHは、好ましくは200[mm]以下、より好ましくは40〜150[mm]、さらに好ましくは60〜100[mm]である。高さHを20[mm]以上とすることにより、異質ガラスG1がスロート30を通って下流側(+X側)へ流出することを抑制できる。また、高さHを200[mm]以下とすることにより、異質ガラスG1を除く溶融ガラスGを効率良くスロート30より下流側(+X側)に移送させることができる。 The height from the bottom 21 to the lower end of the throat 30 inlet is H S. The height H S is at least 20 mm. The height H S is preferably 200 mm or less, more preferably 40 to 150 mm, and still more preferably 60 to 100 mm. By setting the height H S to 20 [mm] or more, it is possible to suppress the foreign glass G1 from flowing out to the downstream side (+ X side) through the throat 30. Further, by setting the height H S to 200 [mm] or less, the molten glass G excluding the foreign glass G1 can be efficiently transferred to the downstream side (+ X side) from the throat 30.

図2に示すように、スロート30は、溶解槽20の幅方向(Y軸方向)中央部に連通して設けられる。そのため、溶融ガラスGの流れが幅方向(Y軸方向)で対称となり、図1に示す下流側循環流102を制御しやすくなる。   As shown in FIG. 2, the throat 30 is provided in communication with the central portion in the width direction (Y-axis direction) of the dissolution tank 20. Therefore, the flow of the molten glass G becomes symmetrical in the width direction (Y-axis direction), and it becomes easy to control the downstream circulation flow 102 shown in FIG.

仕切壁40は、底部21より上側(+Z側)に延在して設けられ、溶融ガラスGの下層の流れを遮るダム構造である。仕切壁40は、仕切壁40の上側(+Z側)、上流側(−X側)、下流側(+X側)の溶融ガラスGに対して、それぞれ前進流100、上流側循環流101、下流側循環流102を形成する。前進流100は、溶解槽20内の上流側(−X側)から下流側(+X側)に向かって流れる。上流側循環流101は、溶融ガラスGの上部において、溶解槽20内の上流側(−X側)に向かって流れ、溶融ガラスGの下部において、溶解槽20内の下流側(+X側)に向かって流れる循環流である。下流側循環流102は、溶融ガラスGの上部において、溶解槽20内の下流側(+X側)に向かって流れ、溶融ガラスGの下部において、溶解槽20内の上流側(−X側)に向かって流れる循環流である。仕切壁40は、電鋳煉瓦、白金、白金合金、イリジウム、モリブデンなど、溶融ガラスGに対して耐食性に優れる材料によって構成される。   The partition wall 40 is provided to extend above the bottom portion 21 (+ Z side) and has a dam structure that blocks the flow of the lower layer of the molten glass G. The partition wall 40 is the forward flow 100, the upstream circulation flow 101, and the downstream side with respect to the molten glass G on the upper side (+ Z side), the upstream side (−X side), and the downstream side (+ X side) of the partition wall 40, respectively. A circulating flow 102 is formed. The forward flow 100 flows from the upstream side (−X side) in the dissolution tank 20 to the downstream side (+ X side). The upstream circulation flow 101 flows toward the upstream side (−X side) in the melting tank 20 in the upper part of the molten glass G, and on the downstream side (+ X side) in the melting tank 20 in the lower part of the molten glass G It is a circulating flow that flows toward. The downstream circulation flow 102 flows toward the downstream side (+ X side) in the melting tank 20 in the upper part of the molten glass G, and on the upstream side (-X side) in the melting tank 20 in the lower part of the molten glass G It is a circulating flow that flows toward. The partition wall 40 is made of a material having excellent corrosion resistance to the molten glass G, such as electroformed brick, platinum, platinum alloy, iridium, or molybdenum.

排出部50は、スロート30と仕切壁40との間の底部21に設けられ、底部21の下側(−Z側)に、異質ガラスG1を排出するための排出管51を備える。これにより、仕切壁40より下流側(+X側)に溜まっている異質ガラスG1がスロート30へ流出することを抑制できる。排出管51は、底部21より下側(−Z側)に筒状に延び、Z軸垂直面の断面が円形であるが、多角形等であってもよい。排出管51は、異質ガラスG1が混入した溶融ガラスGの流下量を制御するための加熱設備(不図示)が設けられてもよい。この場合、排出管51は、白金又は白金合金製で、直接通電加熱設備が設けられることにより、溶融ガラスGの流下量を精密に制御することができる。   The discharge part 50 is provided in the bottom part 21 between the throat 30 and the partition wall 40, and is provided with a discharge pipe 51 for discharging the foreign glass G1 on the lower side (−Z side) of the bottom part 21. Thereby, the foreign glass G1 remaining on the downstream side (+ X side) of the partition wall 40 can be prevented from flowing out to the throat 30. The discharge pipe 51 extends cylindrically below the bottom portion 21 (−Z side), and the cross section of the Z-axis vertical plane is circular, but may be polygonal or the like. The discharge pipe 51 may be provided with a heating facility (not shown) for controlling the amount of flow of the molten glass G mixed with the foreign glass G1. In this case, the discharge pipe 51 is made of platinum or a platinum alloy, and by providing direct current heating equipment, the amount of flow of the molten glass G can be precisely controlled.

図2に示すように、排出部50は、溶解槽20の幅方向(Y軸方向)中央部に設けられる。排出部50は、排出管51がスロート30の幅方向(Y軸方向)内側に設けられる。これにより、異質ガラスG1がスロート30へ流出することを効果的に抑制できる。   As shown in FIG. 2, the discharge unit 50 is provided at the center of the dissolution tank 20 in the width direction (Y-axis direction). In the discharge unit 50, the discharge pipe 51 is provided on the inner side in the width direction (Y-axis direction) of the throat 30. Thereby, the foreign glass G1 can be effectively suppressed from flowing out to the throat 30.

スロート30の入口と仕切壁40との間における溶解槽20が保持する溶融ガラスGの重量をW[トン]、1日にスロート30から移送される溶融ガラスGの重量をP[トン/日]とする。このとき、本実施形態のガラス溶解炉10は、0.2≦W/P≦2.0を満たすことが好ましい。W/Pは、より好ましくは0.4≦W/P≦1.2、さらに好ましくは0.5≦W/P≦1.0である。W/Pが2.0以下だと、下流側循環流102が抑制され、異質ガラスG1が巻き上げられにくくなるため、異質ガラスG1がスロート30へ流出することを抑制できる。また、W/Pが0.2以上だと、異質ガラスG1を除く溶融ガラスGを効率良くスロート30より下流側(+X側)に移送させることができる。また、重量Pは、好ましくは20〜200[トン/日]である。   The weight of the molten glass G held by the melting tank 20 between the inlet of the throat 30 and the partition wall 40 is W [ton], and the weight of the molten glass G transferred from the throat 30 one day P [ton / day] I assume. At this time, it is preferable that the glass melting furnace 10 of this embodiment satisfy | fills 0.2 <= W / P <= 2.0. W / P is more preferably 0.4 ≦ W / P ≦ 1.2, still more preferably 0.5 ≦ W / P ≦ 1.0. When W / P is 2.0 or less, the downstream circulation flow 102 is suppressed, and the foreign glass G1 is less likely to be rolled up, so that the foreign glass G1 can be prevented from flowing out to the throat 30. In addition, when W / P is 0.2 or more, the molten glass G excluding the foreign glass G1 can be efficiently transferred to the downstream side (+ X side) from the throat 30. Also, the weight P is preferably 20 to 200 [tons / day].

底部21から溶融ガラスGの上面までの高さをH、底部21から仕切壁40の上端までの高さをH、スロート30の入口の底部と天部との間の高さをHとする。本実施形態のガラス溶解炉10は、H/Hが0.3〜0.95を満たしていることが好ましく、0.5〜0.95を満たしていることがより好ましい。H/Hが0.3以上だと、下流側循環流102が大きくなることを防ぐことができ、異質ガラスG1が巻き上げられにくくなるため、異質ガラスG1がスロート30へ流出することを抑制できる。また、H/Hが0.95以下だと、前進流100及び下流側循環流102が安定し、異質ガラスG1が巻き上げられにくくなるため、異質ガラスG1がスロート30へ流出することを抑制できる。 The height from the bottom 21 to the upper surface of the molten glass G is H 0 , the height from the bottom 21 to the upper end of the dividing wall 40 is H 1 , and the height between the bottom of the throat 30 and the top is H 2 I assume. Glass melting furnace 10 of the present embodiment is preferably H 1 / H 0 meets 0.3 to 0.95, and more preferably meets 0.5 to 0.95. When H 1 / H 0 is 0.3 or more, the downstream side circulation flow 102 can be prevented from becoming large, and the foreign glass G1 becomes difficult to be wound up, so that the foreign glass G1 is prevented from flowing out to the throat 30 it can. In addition, when H 1 / H 0 is 0.95 or less, the forward flow 100 and the downstream circulation flow 102 become stable, and the foreign glass G1 becomes difficult to be wound up, so that the foreign glass G1 is prevented from flowing out to the throat 30 it can.

また、本実施形態のガラス溶解炉10は、H/Hが0.1〜0.5を満たしていることが好ましい。H/Hを0.1〜0.5にすることで、異質ガラスG1がスロート30へ流出することを抑制しながら、異質ガラスG1を除く溶融ガラスGを効率良くスロート30より下流側(+X側)に移送させることができる。 The glass melting furnace 10 of the present embodiment, it is preferable that H 2 / H 0 meets 0.1-0.5. By setting H 2 / H 0 to 0.1 to 0.5, the molten glass G excluding the foreign glass G 1 is efficiently downstream of the throat 30 while suppressing the foreign glass G 1 from flowing out to the throat 30 ( Can be transported to the + X side).

平面視において、溶解槽20内の上流端から下流端までの距離をL、仕切壁40の下流端から溶解槽20内の下流端までの距離をLとする。本実施形態の溶解槽20は、L/Lが0.1〜0.5を満たしていることが好ましい。L/Lを0.1〜0.5にすることで、異質ガラスG1を除く溶融ガラスGを効率良く下流側(+X側)に移送させることができる。 In plan view, the distance from the upstream end to the downstream end in the dissolution tank 20 is L 0 , and the distance from the downstream end of the partition wall 40 to the downstream end in the dissolution tank 20 is L 1 . Dissolving tank 20 of the present embodiment, it is preferable that L 1 / L 0 meets 0.1-0.5. By setting L 1 / L 0 to 0.1 to 0.5, the molten glass G excluding the foreign glass G 1 can be efficiently transferred to the downstream side (+ X side).

図2に示すように、溶解槽20内の幅方向(Y軸方向)距離をW、スロート30の幅方向(Y軸方向)距離をWとする。本実施形態のガラス溶解炉10は、W/Wが0.03〜0.3を満たしていることが好ましい。W/Wを0.03〜0.3にすることで、異質ガラスG1を除く溶融ガラスGを効率良く下流側(+X側)に移送させることができる。 As shown in FIG. 2, the distance in the width direction (Y-axis direction) in the dissolution tank 20 is W 0 , and the distance in the width direction (Y-axis direction) of the throat 30 is W 1 . Glass melting furnace 10 of the present embodiment, it is preferable that W 1 / W 0 meets 0.03-0.3. By setting W 1 / W 0 to 0.03 to 0.3, the molten glass G excluding the foreign glass G1 can be efficiently transferred to the downstream side (+ X side).

本実施形態のガラス溶解炉10は、スロート30の入口において、溶融ガラスGの流れ方向(X軸方向)の平均流速Vが、5〜15[m/h]であることが好ましい。平均流速V[m/h]は、スロート30の入口箇所のX軸垂直面における断面積をS[m]、溶融ガラスGの密度をd[トン/m]として、V=P÷(24×S×d)で算出される。平均流速Vが5[m/h]以上だと、異質ガラスG1を除く溶融ガラスGを効率良くスロート30より下流側(+X側)に移送させることができる。また、平均流速Vが15[m/h]以下だと、異質ガラスG1がスロート30へ流出することを効果的に抑制できる。 In the glass melting furnace 10 of the present embodiment, the average flow velocity V in the flow direction (X-axis direction) of the molten glass G is preferably 5 to 15 [m / h] at the inlet of the throat 30. The average flow velocity V [m / h] is V = P ÷ (S) where S [m 2 ] is the cross-sectional area of the inlet 30 at the inlet of the throat 30 and d [t / m 3 ] is the density of the molten glass G. It is calculated by 24 × S × d). When the average flow velocity V is 5 [m / h] or more, the molten glass G excluding the foreign glass G1 can be efficiently transferred to the downstream side (+ X side) from the throat 30. Moreover, when the average flow velocity V is 15 [m / h] or less, the foreign glass G1 can be effectively suppressed from flowing out to the throat 30.

また、本実施形態で用いられるガラスは、異質ガラスG1の混入を効果的に抑制するため、粘度ηが10ポイズとなる温度Tが好ましくは1610℃以上、より好ましくは1640℃以上である。また、本実施形態で用いられるガラスは、溶解を容易にするため、粘度ηが10ポイズとなる温度Tが好ましくは1670℃以下である。 The glass used in the present embodiment, in order to effectively suppress the contamination of foreign glass G1, the temperature T 2 at which the viscosity η is 10 2 poise preferably 1610 ° C. or higher, more preferably at 1640 ° C. or higher . Further, the glass used in the present embodiment preferably has a temperature T 2 at which the viscosity η is 10 2 poise to be 1670 ° C. or less, in order to facilitate melting.

「第二実施形態」
図3は、本発明に係る第二実施形態におけるガラス溶解炉のY軸垂直面での断面図である。図4は、本発明に係る第二実施形態におけるガラス溶解炉のX軸垂直面での断面図であり、図3のII−II矢視断面図である。
"2nd embodiment"
FIG. 3 is a cross-sectional view of a glass melting furnace according to a second embodiment of the present invention taken along a plane perpendicular to the Y-axis. FIG. 4 is a cross-sectional view taken along a plane perpendicular to the X-axis of the glass melting furnace according to the second embodiment of the present invention, and is a cross-sectional view taken along the line II-II in FIG.

本発明に係るガラス溶解炉の第二実施形態について、図3及び図4を参照して説明する。以下、第一実施形態と異なる点のみ説明する。第二実施形態のガラス溶解炉110は、溶解槽に収容部60を備える点で、第一実施形態のガラス溶解炉10と構造が異なっている。   A second embodiment of a glass melting furnace according to the present invention will be described with reference to FIGS. 3 and 4. Hereinafter, only differences from the first embodiment will be described. The glass melting furnace 110 according to the second embodiment is different in structure from the glass melting furnace 10 according to the first embodiment in that the housing 60 is provided in the melting tank.

図3に示すように、本実施形態の溶解槽120は、スロート30の入口と仕切壁40との間の底部21に設けられる凹状の収容部60を備える。収容部60は、箱型の形状であり、溶融ガラスGを貯留する。収容部60は、底部に溶融ガラスGを排出する排出部150が設けられる。凹状の収容部60は、X軸垂直面又はY軸垂直面の断面が矩形であるが、正方形、半円形、半楕円形又は角丸矩形であってもよい。また、収容部60は、Z軸垂直面の断面が円形であるが、正方形又は矩形であってもよい。   As shown in FIG. 3, the dissolution tank 120 according to the present embodiment includes a concave accommodating portion 60 provided in the bottom portion 21 between the inlet of the throat 30 and the partition wall 40. The housing portion 60 has a box shape, and stores the molten glass G. The storage unit 60 is provided at the bottom with a discharge unit 150 for discharging the molten glass G. The concave housing portion 60 has a rectangular cross section in the X-axis vertical plane or the Y-axis vertical plane, but may have a square, semi-circular, semi-elliptical or rounded rectangular shape. In addition, although the cross section of the Z-axis vertical plane is circular, the housing portion 60 may be square or rectangular.

図4に示すように、収容部60は、溶解槽120の幅方向(Y軸方向)中央部に設けられる。収容部60は、スロート30よりも幅が大きいため、異質ガラスG1がスロート30へ流出することを効果的に抑制できる。   As shown in FIG. 4, the housing portion 60 is provided at the central portion in the width direction (Y-axis direction) of the dissolution tank 120. Since the housing portion 60 is larger in width than the throat 30, the outflow of the foreign glass G1 to the throat 30 can be effectively suppressed.

排出部150は、収容部60の底部の下側(−Z側)に、異質ガラスG1を排出するための排出管151を備える。排出部150は、排出管の鉛直方向(Z軸方向)長さが収容部60の深さの分だけ短くなっている点で、第一実施形態の排出部50と異なっている。   The discharge part 150 is provided with the discharge pipe 151 for discharging | emitting the foreign glass G1 in the lower side (-Z side) of the bottom part of the accommodating part 60. As shown in FIG. The discharge unit 150 is different from the discharge unit 50 of the first embodiment in that the length in the vertical direction (Z-axis direction) of the discharge pipe is shortened by the depth of the storage unit 60.

本実施形態の溶解槽120によれば、異質ガラスG1がスロート30へ流出することを効果的に抑制できる。収容部60の底部と、溶解槽20の底部21との間の距離を高さHS1とする。高さHS1は50〜300[mm]であることが好ましい。高さHS1が50[mm]以上だと、異質ガラスG1が収容部60内に溜まる。また、高さHS1が300[mm]以下だと、収容部60内で溶融ガラスGの循環が起きて異質ガラスG1が上部へ流出することを抑制できる。 According to the melting tank 120 of the present embodiment, the foreign glass G1 can be effectively suppressed from flowing out to the throat 30. The distance between the bottom of the housing portion 60 and the bottom 21 of the dissolution tank 20 is taken as a height HS1 . The height H S1 is preferably 50 to 300 [mm]. When the height H S1 is 50 [mm] or more, the foreign glass G1 is collected in the housing portion 60. In addition, when the height H S1 is equal to or less than 300 [mm], circulation of the molten glass G can occur in the housing portion 60, and the foreign glass G1 can be prevented from flowing out to the upper part.

本実施形態では、平面視において、収容部60の下流端とスロート30の入口との間の流れ方向(X軸方向)距離をLとする。距離Lは0〜1000[mm]であることが好ましい。距離Lは、より好ましくは0〜500[mm]、さらに好ましくは0〜100[mm]である。距離Lが1000[mm]以下だと、異質ガラスG1がスロート30へ流出することを効果的に抑制できる。 In the present embodiment, the distance in the flow direction (X-axis direction) between the downstream end of the housing portion 60 and the inlet of the throat 30 is L S in a plan view. The distance L S is preferably 0 to 1000 [mm]. The distance L S is more preferably 0 to 500 [mm], still more preferably 0 to 100 [mm]. When the distance L S is 1000 [mm] or less, the foreign glass G1 can be effectively suppressed from flowing out to the throat 30.

平面視において、収容部60の流れ方向(X軸方向)距離をLとする。本実施形態の溶解槽120は、L/Lが0.05〜0.5を満たしていることが好ましい。L/Lを0.05〜0.5にすることで、異質ガラスG1がスロート30へ流出することを効果的に抑制できる。 In plan view, the flow direction of the accommodating portion 60 (X-axis direction) distance and L 2. Dissolving tank 120 of the present embodiment, it is preferable that L 2 / L 1 satisfies 0.05 to 0.5. By setting L 2 / L 1 to 0.05 to 0.5, outflow of the foreign glass G 1 to the throat 30 can be effectively suppressed.

図4に示すように、収容部51の幅方向(Y軸方向)距離をWとする。本実施形態の溶解槽120は、W/Wが1.1〜5.0を満たしていることが好ましい。W/Wを1.1〜5.0にすることで、異質ガラスG1がスロート30へ流出することを効果的に抑制できる。 As shown in FIG. 4, the width direction (Y axis direction) distance of the accommodating portion 51 and W 2. Dissolving tank 120 of the present embodiment, it is preferable that W 2 / W 1 meets from 1.1 to 5.0. The outflow of the foreign glass G1 to the throat 30 can be effectively suppressed by setting W 2 / W 1 to 1.1 to 5.0.

収容部60内の溶融ガラスGの重量をw[トン]とし、1日に排出部150から排出される溶融ガラスGの重量をD[トン/日]とする。本実施形態のガラス溶解炉110は、0.02≦w/D≦0.4を満たすことが好ましい。w/Dが0.02以上だと、収容部60内に異質ガラスG1を溜めることができるため、異質ガラスG1がスロート30へ流出することを効果的に抑制できる。w/Dが0.4以下だと、収容部60内で溶融ガラスGの循環が起きることを抑制できるため、異質ガラスG1がスロート30へ流出することを効果的に抑制できる。また、重量Dは、好ましくは0.5〜30[トン/日]である。   The weight of the molten glass G in the storage unit 60 is w [ton], and the weight of the molten glass G discharged from the discharge unit 150 one day is D [ton / day]. It is preferable that the glass melting furnace 110 of this embodiment satisfy | fills 0.02 <= w / D <= 0.4. When w / D is 0.02 or more, since the foreign glass G1 can be stored in the housing portion 60, the outflow of the foreign glass G1 to the throat 30 can be effectively suppressed. When w / D is 0.4 or less, the occurrence of circulation of the molten glass G in the housing portion 60 can be suppressed, and thus the outflow of the foreign glass G1 to the throat 30 can be effectively suppressed. Also, the weight D is preferably 0.5 to 30 [tons / day].

以上、本発明の実施の形態について図面を参照して詳述したが、具体的な構成は前記実施形態に限られるものではなく、本発明の要旨を逸脱しない範囲の設計変更も含まれる。   Although the embodiments of the present invention have been described in detail with reference to the drawings, the specific configuration is not limited to the above embodiments, and design changes within the scope of the present invention are also included.

本実施形態のガラス溶解炉10,110は、バーナー加熱及び電気加熱により、ガラス原料の溶解を行っているが、バーナー加熱単独又は電気加熱単独でガラス原料の溶解を行ってもよい。   Although the glass melting furnace 10, 110 of this embodiment performs melting of the glass material by burner heating and electric heating, the glass material may be melted by burner heating alone or electric heating alone.

本実施形態の溶解槽20,120は、平面視における一軸方向(X軸方向)に長く伸びた矩形状であるが、ガラス原料を溶解できるなら、これに限定されない。   Although the dissolution tank 20, 120 of this embodiment is a rectangular shape extended long in the uniaxial direction (X-axis direction) in planar view, it is not limited to this as long as it can melt glass materials.

本実施形態では、排出部50,150は一箇所設置されているが、ガラス溶解炉10,110の長さ方向(X軸方向)又は幅方向(Y軸方向)に二箇所以上設置されてもよい。   In this embodiment, although the discharge part 50,150 is installed in one place, even if it is installed in two or more places in the length direction (X-axis direction) or the width direction (Y-axis direction) of the glass melting furnace 10,110. Good.

本実施形態では、底部21より上側(+Z側)に延在して設けられる仕切壁40の形態を説明したが、仕切壁は、溶融ガラスGを仕切るものであれば、これに限定されない。   Although the form of the partition wall 40 extended and provided in the upper side (+ Z side) from the bottom part 21 was demonstrated in this embodiment, a partition wall will not be limited to this, if it divides the molten glass G.

[ガラス物品の製造方法]
次に、本実施形態のガラス溶解炉10,110のうち、ガラス溶解炉110を用いたガラス物品の製造方法について説明する。図5は、本発明に係る第一実施形態におけるガラス物品の製造方法を示すフローチャートである。
[Method of producing glass article]
Next, the manufacturing method of the glass article using the glass melting furnace 110 among the glass melting furnaces 10 and 110 of this embodiment is demonstrated. FIG. 5 is a flowchart showing a method of manufacturing a glass article according to the first embodiment of the present invention.

本実施形態のガラス物品の製造方法は、ガラス原料を溶解して溶融ガラスGを得る溶解工程S1と、溶融ガラスGの気泡を除去する清澄工程S2と、溶融ガラスGを成形する成形工程S3と、成形されたガラスを徐冷する徐冷工程S4とを含む。   In the method of manufacturing a glass article according to the present embodiment, a melting step S1 for melting a glass raw material to obtain a molten glass G, a clarification step S2 for removing bubbles of the molten glass G, and a forming step S3 for forming the molten glass G And annealing step S4 of annealing the formed glass.

溶解工程S1は、ガラス原料を溶解槽内に供給し、ガラス原料を加熱して溶解する。ガラス溶解炉に設けられたバーナーの火炎をガラス原料に向かって放射することによって、ガラス原料を上方から加熱する。バーナーの火炎によって加熱すると共に、複数の通電電極に電圧を印加することによって通電し、ジュール熱を発生させ、ガラス原料を加熱する。   In the melting step S1, the glass material is supplied into the melting tank, and the glass material is heated and melted. The glass material is heated from above by radiating a flame of a burner provided in the glass melting furnace toward the glass material. While heating with the flame of a burner, it supplies with electricity by applying a voltage to several electricity supply electrodes, Joule heat is generated, and a glass raw material is heated.

溶解工程S1は、溶解槽において、溶融ガラスを下流側に流動させ、粘度ηが10ポイズとなる温度Tが1580℃以上のガラスを溶解する。溶解槽は、溶解槽の幅方向にわたって設けられる仕切壁を備え、さらに溶解槽の底部に排出部を備える。仕切壁は、溶融ガラスの流れの一部を遮る。溶融ガラスは、溶解槽に連通して設けられるスロートを介して、清澄工程S2に向けて移送される。排出部は、溶融ガラスを排出する。 Dissolving step S1 is in the dissolution tank, in flowing molten glass downstream, temperature T 2 at which the viscosity η is 10 2 poise dissolving 1580 ° C. or more glass. A dissolution tank is provided with the partition wall provided over the width direction of a dissolution tank, and also is equipped with the discharge part in the bottom part of a dissolution tank. The partition wall blocks part of the flow of molten glass. The molten glass is transferred toward the clarification step S2 via a throat provided in communication with the melting tank. The discharge unit discharges the molten glass.

スロートの入口と仕切壁との間における溶解槽が保持する溶融ガラスの重量をW[トン]、1日に前記スロートから移送される溶融ガラスの重量をP[トン/日]とする。本実施形態の溶解工程S1は、0.2≦W/P≦2.0を満たすことが好ましい。   The weight of the molten glass held by the melting tank between the throat inlet and the partition wall is W [ton], and the weight of the molten glass transferred from the throat on one day is P [ton / day]. The dissolution step S1 of the present embodiment preferably satisfies 0.2 ≦ W / P ≦ 2.0.

本実施形態の溶解工程S1において、重量P[トン/日]は、排出部から排出される溶融ガラスGの重量をD[トン/日]として、0.01≦D/P≦0.2を満たすことが好ましい。D/Pが0.01以上だと、異質ガラスG1を排出部50から充分に排出できるため、異質ガラスG1がスロート30へ流出することを抑制できる。また、D/Pが0.2以下だと、排出部50からの溶融ガラスGの排出による生産ロスを抑制できる。   In the melting step S1 of the present embodiment, the weight P [ton / day] is 0.01 ≦ D / P ≦ 0.2, where D [ton / day] is the weight of the molten glass G discharged from the discharge part. It is preferable to satisfy. When D / P is 0.01 or more, the foreign glass G1 can be sufficiently discharged from the discharge part 50, and therefore, the foreign glass G1 can be prevented from flowing out to the throat 30. Moreover, if D / P is 0.2 or less, the production loss by discharge of the molten glass G from the discharge part 50 can be suppressed.

清澄工程S2は、溶解工程S1で得られた溶融ガラスを清澄槽に供給し、溶融ガラス内の気泡を浮上させて除去する工程である。気泡の浮上を促進させる方法としては、例えば清澄槽内を減圧して脱泡する方法などがある。   The fining step S2 is a step of supplying the molten glass obtained in the melting step S1 to a fining tank and floating bubbles in the molten glass for removal. As a method of promoting floating of bubbles, there is, for example, a method of decompressing the inside of the clarification tank to degas.

成形工程S3は、溶解槽より下流側に設けられた成形炉で溶融ガラスを成形する。徐冷工程S4は、成形炉より下流側に設けられた徐冷炉で成形されたガラスを徐冷し、最終的にガラス物品を得る。   In the forming step S3, the molten glass is formed in a forming furnace provided downstream of the melting tank. In the slow cooling step S4, the glass formed in the slow cooling furnace provided downstream of the molding furnace is gradually cooled to finally obtain a glass article.

ガラス物品としてガラス板を得るには、例えばフロート法が用いられる。フロート法は、フロートバス内に収容される溶融金属(例えば、溶融スズ)上に導入された溶融ガラスを所定方向に流動させ、帯板状のガラスリボンとする方法である(成形工程S3)。ガラスリボンは、水平方向に流動する過程で冷却された後、溶融金属から引き上げられ、徐冷炉内で搬送されながら徐冷され、板ガラスとなる(徐冷工程S4)。板ガラスは、徐冷炉から搬出された後、切断機によって所定の寸法形状に切断され製品であるガラス板となる。   In order to obtain a glass plate as a glass article, for example, a float method is used. The float method is a method in which molten glass introduced on a molten metal (for example, molten tin) accommodated in a float bath is made to flow in a predetermined direction to form a ribbon ribbon (a forming step S3). The glass ribbon is cooled in the process of flowing in the horizontal direction, and is then pulled up from the molten metal and gradually cooled while being transported in the annealing furnace to form a sheet glass (annealing step S4). The sheet glass is taken out of the annealing furnace and then cut into a predetermined size and shape by a cutting machine to become a glass sheet which is a product.

また、ガラス板を得るのに別の成形方法として、フュージョン法を用いてもよい。フュージョン法は、樋状部材の左右両側の上縁から溢れ出した溶融ガラスを、樋状部材の左右両側面に沿って流下させ、左右両側面が交わる下縁で合わせることにより、帯板状のガラスリボンとする方法である(成形工程S3)。溶融ガラスリボンは、鉛直方向(Z軸方向)下方に移動しながら徐冷され、板ガラスとなる(徐冷工程S4)。板ガラスは、切断機によって所定の寸法形状に切断され、製品であるガラス板となる。   Moreover, you may use the fusion method as another shaping | molding method to obtain a glass plate. In the fusion method, the molten glass overflowing from the left and right upper edges of the bowl-like member is allowed to flow down along the left and right sides of the bowl-like member, and joined together at the lower edge where the left and right sides meet. This is a method of forming a glass ribbon (forming step S3). The molten glass ribbon is gradually cooled while moving downward in the vertical direction (Z-axis direction) to be a sheet glass (necessary cooling step S4). The sheet glass is cut into a predetermined size and shape by a cutting machine to become a glass sheet which is a product.

なお、本実施形態のガラス物品の製造方法は、清澄工程S2を含んでいるが、本発明のガラス物品の製造方法は、清澄工程を含んでいなくてもよい。この場合、溶融ガラスは、溶解工程を経て、成形工程でガラスリボンに成形される。   In addition, although the manufacturing method of the glass article of this embodiment contains fining process S2, the manufacturing method of the glass article of this invention does not need to include the fining process. In this case, the molten glass is formed into a glass ribbon in a forming process through a melting process.

本実施形態で用いられるガラス原料の組成には特に制約がなく、無アルカリガラス、アルミノシリケートガラス、混合アルカリ系ガラス、ホウケイ酸ガラス、又はその他のガラスのいずれであってもよい。   There is no restriction | limiting in particular in a composition of the glass-making feedstock used by this embodiment, Alkali-free glass, aluminosilicate glass, mixed alkali type glass, borosilicate glass, or any other glass may be sufficient.

また、本実施形態で用いられるガラスは、異質ガラスG1の混入を効果的に抑制できるため、粘度ηが10ポイズとなる温度Tが好ましくは1610℃以上、より好ましくは1640℃以上である。また、本実施形態で用いられるガラスは、溶解が容易になるため、粘度ηが10ポイズとなる温度Tが好ましくは1670℃以下である。 The glass used in the present embodiment, it is possible to effectively suppress the contamination of foreign glass G1, the temperature T 2 at which the viscosity η is 10 2 poise preferably 1610 ° C. or higher, more preferably at 1640 ° C. or higher . The glass used in the present embodiment, since the dissolution is facilitated, is preferably temperature T 2 at which the viscosity η is 10 2 poise is 1670 ° C. or less.

本発明を詳細に、また特定の実施態様を参照して説明したが、本発明の精神と範囲を逸脱することなく、様々な変更や修正を加えることができることは、当業者にとって明らかである。   While the invention has been described in detail and with reference to specific embodiments, it will be apparent to those skilled in the art that various changes and modifications can be made without departing from the spirit and scope of the invention.

製造されるガラス物品の用途は、建築用、車両用、フラットパネルディスプレイ用、カバーガラス用、又はその他の各種用途が挙げられる。   Applications of the manufactured glass articles include for construction, for vehicles, for flat panel displays, for cover glass, or various other applications.

10,110:ガラス溶解炉
20,120:溶解槽
21:底部
22:側壁部
30:スロート
40:仕切壁
50,150:排出部
51,151:排出管
60:収容部
100:前進流
101:上流側循環流
102:下流側循環流
G:溶融ガラス
G1:異質ガラス
10, 110: Glass melting furnace 20, 120: Dissolution tank 21: Bottom 22: Side wall 30: Throat 40: Partition wall 50, 150: Discharge part 51, 151: Discharge pipe 60: Storage part 100: Forward flow 101: Upstream Side circulation flow 102: downstream circulation flow G: molten glass G1: foreign glass

Claims (13)

ガラス原料を溶解し、得られた溶融ガラスを下流側に流動させる溶解槽と、前記溶解槽に連通して設けられ、前記溶融ガラスを清澄槽又は成形炉に向けて移送させるスロートとを備えるガラス溶解炉であって、
前記溶解槽は、仕切壁と、排出部とを備え、粘度ηが10ポイズとなる温度Tが1580℃以上のガラスを溶解し、
前記仕切壁は、前記溶解槽の幅方向にわたって設けられ、前記溶融ガラスの流れの一部を遮り、
前記排出部は、前記スロートと前記仕切壁との間における前記溶解槽の底部に設けられ、前記溶融ガラスを排出し、
前記底部から前記スロートの入口の下端までの高さが20[mm]以上であることを特徴とするガラス溶解炉。
A glass comprising: a melting tank for melting a glass raw material and causing the obtained molten glass to flow downstream, and a throat provided in communication with the melting tank for transferring the molten glass toward a clarification tank or a forming furnace A melting furnace,
The dissolving tank is provided with a partition wall, and a discharge portion, temperature T 2 at which the viscosity η is 10 2 poise by dissolving 1580 ° C. or more glass,
The partition wall is provided across the width direction of the melting tank, and blocks part of the flow of the molten glass,
The discharge unit is provided at the bottom of the melting tank between the throat and the partition wall, and discharges the molten glass.
The height from the said bottom part to the lower end of the inlet of the said throat is 20 [mm] or more, The glass melting furnace characterized by the above-mentioned.
前記ガラス溶解炉は、前記スロートの入口と前記仕切壁との間における前記溶解槽が保持する溶融ガラスの重量をW[トン]、1日に前記スロートから移送される溶融ガラスの重量をP[トン/日]として、0.2≦W/P≦2.0を満たす、請求項1に記載のガラス溶解炉。   The glass melting furnace uses the weight of molten glass held by the melting tank between the inlet of the throat and the partition wall as W [ton], and the weight of molten glass transferred from the throat daily as P [ The glass melting furnace according to claim 1, wherein 0.2 ≦ W / P ≦ 2.0 is satisfied as ton / day. 前記ガラス溶解炉は、前記底部から前記スロートの入口の下端までの高さが200[mm]以下である、請求項1または2に記載のガラス溶解炉。   The glass melting furnace according to claim 1 or 2, wherein the height of the glass melting furnace from the bottom to the lower end of the throat inlet is 200 mm or less. 前記溶解槽は、前記底部に設けられる凹状の収容部を備え、
前記収容部は、深さが50〜300[mm]であり、底部に前記溶融ガラスを排出する排出部が設けられる、請求項1〜3のいずれか1項に記載のガラス溶解炉。
The dissolution tank includes a concave receiving portion provided at the bottom,
The glass melting furnace according to any one of claims 1 to 3, wherein the storage portion has a depth of 50 to 300 mm, and a discharge portion for discharging the molten glass is provided at a bottom portion.
平面視において、前記収容部の下流端と前記スロートの入口との間の流れ方向距離が、0〜1000[mm]である、請求項4に記載のガラス溶解炉。   5. The glass melting furnace according to claim 4, wherein the flow direction distance between the downstream end of the accommodating portion and the inlet of the throat is 0 to 1000 [mm] in a plan view. 溶解工程と、成形工程と、徐冷工程とを含むガラス物品の製造方法であって、
前記溶解工程は、溶解槽において、ガラス原料を溶解させ、得られた溶融ガラスを下流側に流動させ、粘度ηが10ポイズとなる温度Tが1580℃以上のガラスを溶解し、
前記溶解槽は、前記溶解槽の幅方向にわたって設けられる仕切壁を備え、さらに前記スロートと前記仕切壁との間における前記溶解槽の底部に排出部を備え、前記仕切壁は、前記溶融ガラスの流れの一部を遮り、
前記溶融ガラスは、前記溶解槽に連通して設けられるスロートを介して、清澄工程又は前記成形工程に向けて移送され、前記排出部は、前記溶融ガラスを排出し、
前記底部から前記スロートの入口の下端までの高さが20[mm]以上であることを特徴とするガラス物品の製造方法。
A method for producing a glass article comprising a melting step, a forming step, and a slow cooling step,
The dissolution process, in the dissolution vessel to dissolve the glass raw material, in flowing molten glass obtained downstream, temperature T 2 at which the viscosity η is 10 2 poise by dissolving 1580 ° C. or more glass,
The dissolution tank includes a partition wall provided across the width direction of the dissolution tank, and further includes a discharge portion at the bottom of the dissolution tank between the throat and the partition wall, and the partition wall is formed of the molten glass Interrupt part of the flow,
The molten glass is transferred to a fining process or the forming process through a throat provided in communication with the melting tank, and the discharge unit discharges the molten glass.
The height from the said bottom part to the lower end of the entrance of the said throat is 20 [mm] or more, The manufacturing method of the glass article characterized by the above-mentioned.
前記スロートの入口と前記仕切壁との間における前記溶解槽が保持する溶融ガラスの重量をW[トン]、1日に前記スロートから移送される溶融ガラスの重量をP[トン/日]として、0.2≦W/P≦2.0を満たす、請求項6に記載のガラス物品の製造方法。   The weight of molten glass held by the melting tank between the inlet of the throat and the partition wall is W [ton], and the weight of molten glass transferred from the throat per day is P [ton / day], The manufacturing method of the glass article of Claim 6 which satisfy | fills 0.2 <= W / P <= 2.0. 前記底部から前記スロートの入口の下端までの高さが200[mm]以下である、請求項6または7に記載のガラス物品の製造方法。   The manufacturing method of the glass article of Claim 6 or 7 whose height from the said bottom part to the lower end of the entrance of the said throat is 200 [mm] or less. 前記溶解工程は、
前記溶解槽の底部に設けられる凹状の収容部で、前記溶融ガラスを貯留し、
前記収容部の底部に設けられる排出部により、前記溶融ガラスを排出し、
前記収容部は、深さが50〜300[mm]である、請求項6〜8のいずれか1項に記載のガラス物品の製造方法。
The dissolution step is
The molten glass is stored in a concave housing portion provided at the bottom of the melting tank,
The molten glass is discharged by a discharge portion provided at the bottom of the housing portion,
The manufacturing method of the glass article of any one of Claims 6-8 whose said accommodating part is 50-300 [mm] in depth.
前記溶解工程は、平面視において、前記収容部の下流端と前記スロートの入口との間の流れ方向距離が、0〜1000[mm]である、請求項9に記載のガラス物品の製造方法。   The method for producing a glass article according to claim 9, wherein, in the melting step, the distance in the flow direction between the downstream end of the storage portion and the inlet of the throat is 0 to 1000 [mm] in plan view. 前記溶解工程は、前記収容部内の溶融ガラスの重量をw[トン]、1日に前記排出部から排出される溶融ガラスの重量をD[トン/日]として、0.02≦w/D≦0.4を満たす、請求項9または10に記載のガラス物品の製造方法。   In the melting step, the weight of the molten glass in the storage unit is w [ton], and the weight of the molten glass discharged from the discharge unit in one day is D [ton / day], 0.02 ≦ w / D ≦ The manufacturing method of the glass article of Claim 9 or 10 which satisfy | fills 0.4. 前記溶解工程は、前記スロートの入口において、前記溶融ガラスの流れ方向の平均流速が、5〜15[m/h]である、請求項6〜11のいずれか1項に記載のガラス物品の製造方法。   The said melt | dissolution process manufactures the glass article of any one of Claims 6-11 whose average flow velocity of the flow direction of the said molten glass is 5-15 [m / h] in the entrance of the said throat. Method. 前記溶解工程において、前記重量Pは、1日に前記排出部から排出される溶融ガラスの重量をD[トン/日]として、0.01≦D/P≦0.2を満たす、請求項6〜12のいずれか1項に記載のガラス物品の製造方法。   In the melting step, the weight P satisfies 0.01 ≦ D / P ≦ 0.2, where D [ton / day] is the weight of the molten glass discharged from the discharge part on one day. The manufacturing method of the glass article of any one of -12.
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CN113336421A (en) * 2021-06-04 2021-09-03 河南旭阳光电科技有限公司 Glass kiln, method for discharging glass kiln and discharging system of glass kiln

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CN113336421B (en) * 2021-06-04 2023-01-06 河南旭阳光电科技有限公司 Glass kiln, method for discharging glass kiln and discharging system of glass kiln

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