TW201922633A - Glass melting furnace and method for manufacturing glass articles comprising a melting tank and a furnace throat - Google Patents

Glass melting furnace and method for manufacturing glass articles comprising a melting tank and a furnace throat Download PDF

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TW201922633A
TW201922633A TW107137482A TW107137482A TW201922633A TW 201922633 A TW201922633 A TW 201922633A TW 107137482 A TW107137482 A TW 107137482A TW 107137482 A TW107137482 A TW 107137482A TW 201922633 A TW201922633 A TW 201922633A
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glass
melting
furnace
molten glass
melting tank
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TW107137482A
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Chinese (zh)
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TWI833713B (en
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松山俊明
内田一樹
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日商Agc股份有限公司
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/26Outlets, e.g. drains, siphons; Overflows, e.g. for supplying the float tank, tweels
    • C03B5/262Drains, i.e. means to dump glass melt or remove unwanted materials
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/02Melting in furnaces; Furnaces so far as specially adapted for glass manufacture in electric furnaces, e.g. by dielectric heating
    • C03B5/027Melting in furnaces; Furnaces so far as specially adapted for glass manufacture in electric furnaces, e.g. by dielectric heating by passing an electric current between electrodes immersed in the glass bath, i.e. by direct resistance heating
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/225Refining
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/26Outlets, e.g. drains, siphons; Overflows, e.g. for supplying the float tank, tweels
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/42Details of construction of furnace walls, e.g. to prevent corrosion; Use of materials for furnace walls
    • C03B5/43Use of materials for furnace walls, e.g. fire-bricks
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B7/00Distributors for the molten glass; Means for taking-off charges of molten glass; Producing the gob, e.g. controlling the gob shape, weight or delivery tact
    • C03B7/08Feeder spouts, e.g. gob feeders
    • C03B7/088Outlets, e.g. orifice rings
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/50Glass production, e.g. reusing waste heat during processing or shaping
    • Y02P40/57Improving the yield, e-g- reduction of reject rates

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Glass Melting And Manufacturing (AREA)
  • Furnace Charging Or Discharging (AREA)
  • Glass Compositions (AREA)

Abstract

The present invention provides a glass melting furnace capable of suppressing incorporation of foreign glass into a glass article, and a method of manufacturing glass articles. The glass melting furnace 10 of the present invention is characterized in that it comprises a melting tank 20 and a furnace throat 30. The melting tank 20 is provided with a partition wall 40 and a discharge part 50, wherein the temperature T2 at which the glass is melted to have a viscosity [eta] of 102 poise is 1580 DEG C or higher, the partition wall 40 is disposed across the width direction of the melting tank 20 to block a portion of the flow of the molten glass G, the discharge part 50 is disposed on the bottom part 21 of the melting tank 20 between the furnace throat 30 and the partition wall 40 to discharge the molten glass G, and the height HS from the bottom part 21 to the lower end of the inlet of the furnace throat 30 is 20[mm] or more.

Description

玻璃熔解爐、及玻璃物品之製造方法Glass melting furnace and glass article manufacturing method

本發明係關於一種玻璃熔解爐、及玻璃物品之製造方法。The invention relates to a glass melting furnace and a method for manufacturing glass articles.

構成玻璃熔解爐之耐火物與高溫之熔融玻璃接觸而受到侵蝕,溶出至熔融玻璃。藉此,產生與熔融玻璃不同之組成、比重之異質玻璃。另一方面,與熔融玻璃接觸之部分之耐火物多使用相對於熔融玻璃之耐蝕性優異之電鑄磚。其中,氧化鋯系電鑄磚相較其他電鑄磚氧化鋯(ZrO2 )含有率高,且相較其他電鑄磚耐蝕性優異。然而,氧化鋯(ZrO2 )係玻璃組成中不包含之成分,其相較熔融玻璃之比重高,故若溶出至熔融玻璃,則助長異質玻璃之生長。若此種異質玻璃混入至最終獲得之玻璃物品中,則無法滿足所需之品質,因此引起生產良率降低之問題。The refractory constituting the glass melting furnace is in contact with the molten glass at a high temperature, is eroded, and dissolves into the molten glass. Thereby, a heterogeneous glass having a composition and specific gravity different from that of the molten glass is generated. On the other hand, many refractory parts in contact with the molten glass use electroformed bricks that are superior in corrosion resistance to the molten glass. Among them, zirconia-based electroformed bricks have a higher content of zirconia (ZrO 2 ) than other electroformed bricks, and have superior corrosion resistance compared to other electroformed bricks. However, zirconia (ZrO 2 ) is a component not included in the glass composition, and its specific gravity is higher than that of the molten glass. Therefore, if dissolved into the molten glass, the growth of heterogeneous glass is promoted. If such a heterogeneous glass is mixed into the finally obtained glass article, the required quality cannot be satisfied, thus causing a problem that the production yield is reduced.

為了不使此種異質玻璃混入至玻璃物品中,於專利文獻1中,揭示一種具備用以將異質玻璃排出至底部之玻璃排出部之玻璃熔解爐。
[先前技術文獻]
[專利文獻]
In order to prevent such a heterogeneous glass from being mixed into a glass article, Patent Document 1 discloses a glass melting furnace provided with a glass discharge section for discharging heterogeneous glass to the bottom.
[Prior technical literature]
[Patent Literature]

[專利文獻1]日本專利特開2006-62903號公報[Patent Document 1] Japanese Patent Laid-Open No. 2006-62903

[發明所欲解決之問題][Problems to be solved by the invention]

然而,僅於底部設置玻璃排出部則無法充分地抑制異質玻璃混入至玻璃物品。玻璃熔解爐內之熔融玻璃於玻璃熔解爐內一面形成循環流一面向下游側流動。於熔融玻璃之循環流較大之情形、或循環流之移動速度較快之情形時,停滯於底部之異質玻璃難以流向玻璃排出部。因此,異質玻璃混入至使熔融玻璃朝澄清槽或成形爐移送之爐喉,且於最終獲得之玻璃物品中亦會混入異質玻璃。However, the provision of the glass discharge portion only at the bottom cannot sufficiently suppress the incorporation of heterogeneous glass into the glass article. The molten glass in the glass melting furnace forms a circulating flow in the glass melting furnace and flows toward the downstream side. When the circulating flow of the molten glass is large, or when the circulating flow is moving at a high speed, it is difficult for the heterogeneous glass staying at the bottom to flow to the glass discharge portion. Therefore, the heterogeneous glass is mixed into the throat of the molten glass toward the clarification tank or the forming furnace, and the heterogeneous glass is also mixed into the finally obtained glass article.

尤其對黏度η成為102 泊之溫度T2 為1580℃以上之玻璃而言,因玻璃熔解爐內之熔融玻璃之溫度變高,故構成玻璃熔解爐之耐火物受到侵蝕,容易溶出至熔融玻璃。因此,異質玻璃混入至玻璃物品之問題顯著。Especially for the glass whose viscosity η is 10 2 poises and the temperature T 2 is 1580 ° C or higher, the temperature of the molten glass in the glass melting furnace becomes higher, so the refractory constituting the glass melting furnace is corroded and easily dissolves into the molten glass . Therefore, the problem of mixing heterogeneous glass into glass articles is significant.

本發明係鑒於上述課題而完成,其目的在於提供一種可抑制異質玻璃混入至玻璃物品之玻璃熔解爐、及玻璃物品之製造方法。
[解決問題之技術手段]
The present invention has been made in view of the above-mentioned problems, and an object thereof is to provide a glass melting furnace capable of suppressing the incorporation of heterogeneous glass into a glass article, and a method for producing a glass article.
[Technical means to solve the problem]

本發明之玻璃熔解爐之特徵在於具備:熔解槽,其將玻璃原料熔解,且使所獲得之熔融玻璃朝下游側流動;及爐喉,其與上述熔解槽連通設置,使上述熔融玻璃朝澄清槽或成形爐移送;且上述熔解槽具備間隔壁與排出部,使黏度η成為102 泊之溫度T2 為1580℃以上之玻璃熔解,上述間隔壁遍及上述熔解槽之寬度方向設置,遮擋上述熔融玻璃之流動之一部分,上述排出部設置於上述爐喉與上述間隔壁之間之上述熔解槽之底部,將上述熔融玻璃排出,自上述底部至上述爐喉之入口之下端為止之高度為20[mm]以上。The glass melting furnace of the present invention is characterized by comprising: a melting tank that melts glass raw materials and causes the obtained molten glass to flow downstream; and a furnace throat that is provided in communication with the melting tank so that the molten glass is clarified. The melting tank is provided with a partition wall and a discharge part, and the glass having a viscosity η of 10 2 poise and a temperature T 2 of 1580 ° C or higher is melted. The partition wall is provided across the width direction of the melting tank to block the above. As part of the flow of molten glass, the discharge part is disposed at the bottom of the melting tank between the furnace throat and the partition wall, and discharges the molten glass. The height from the bottom to the lower end of the entrance of the furnace throat is 20 [mm] or more.

又,本發明之玻璃物品之製造方法之特徵在於,包含熔解步驟、成形步驟、及緩冷步驟,上述熔解步驟係於熔解槽中將玻璃原料熔解,且使所獲得之熔融玻璃朝下游側流動,將黏度η成為102 泊之溫度T2 為1580℃以上之玻璃熔解,上述熔解槽具備遍及上述熔解槽之寬度方向而設置之間隔壁,進而於上述爐喉與上述間隔壁之間之上述熔解槽之底部具備排出部,上述間隔壁遮擋上述熔融玻璃之流動之一部分,上述熔融玻璃經由與上述熔解槽連通設置之爐喉而朝澄清步驟或上述成形步驟移送,上述排出部將上述熔融玻璃排出,自上述底部至上述爐喉之入口之下端為止之高度為20[mm]以上。
[發明之效果]
The method for manufacturing a glass article according to the present invention includes a melting step, a forming step, and a slow cooling step. The melting step is to melt glass raw materials in a melting tank, and to cause the obtained molten glass to flow downstream. To melt glass having a viscosity η of 10 2 poise and a temperature T 2 of 1580 ° C. or more, the melting tank is provided with partition walls provided throughout the width direction of the melting tank, and further between the furnace throat and the partition wall. The bottom of the melting tank is provided with a discharge part, and the partition wall blocks a part of the flow of the molten glass. The molten glass is transferred to the clarification step or the forming step through a furnace throat connected to the melting tank, and the discharge part transfers the molten glass. The height from the bottom to the lower end of the inlet of the furnace throat is 20 [mm] or more.
[Effect of the invention]

根據本發明之玻璃熔解爐、及玻璃物品之製造方法,可抑制異質玻璃混入至玻璃物品中。According to the glass melting furnace and the glass article manufacturing method of the present invention, it is possible to suppress the incorporation of heterogeneous glass into the glass article.

以下,使用圖式對本發明之各種實施形態進行說明。於本說明書中,表示數值範圍之「~」係指包含其前後之數值之範圍。Hereinafter, various embodiments of the present invention will be described using drawings. In this specification, "~" indicating a numerical range means a range including numerical values before and after the numerical range.

再者,各圖式之基準方向對應於符號、數字之方向。於圖式中,將XYZ座標系統表示為三維正交座標系統,將Z軸方向設為圖1~4中之上下方向,將X軸方向設為圖1、3所示之玻璃熔解爐10、110之長度方向(左右方向),將Y軸方向設為圖2、4所示之玻璃熔解爐10、110之寬度方向(左右方向)。於本說明書中,X軸方向為俯視下之熔融玻璃G之流動方向,Y軸方向與熔融玻璃G之流動方向正交。In addition, the reference directions of the drawings correspond to the directions of the symbols and numbers. In the figure, the XYZ coordinate system is represented as a three-dimensional orthogonal coordinate system, the Z-axis direction is set to the upper and lower directions in Figs. 1-4, and the X-axis direction is set to the glass melting furnace 10 shown in Figs. The length direction (left-right direction) of 110, and the Y-axis direction is the width direction (left-right direction) of the glass melting furnaces 10 and 110 shown in FIG. In this specification, the X-axis direction is the flow direction of the molten glass G in a plan view, and the Y-axis direction is orthogonal to the flow direction of the molten glass G.

又,於本說明書中,所謂上游側及下游側係相對於玻璃熔解爐10、110內之熔融玻璃G之流動方向(X軸方向)而言者,+X側為下游側,-X側為上游側。In the present specification, the upstream and downstream sides are relative to the flow direction (X-axis direction) of the molten glass G in the glass melting furnaces 10 and 110, the + X side is the downstream side, and the -X side is Upstream side.

[玻璃熔解爐]
「第一實施形態」
圖1係本發明之第一實施形態之玻璃熔解爐之於Y軸垂直面之剖視圖。圖2係本發明之第一實施形態之玻璃熔解爐之於X軸垂直面之剖視圖,且係圖1之I-I箭頭方向之剖視圖。參照圖1及圖2對本發明之玻璃熔解爐之第一實施形態進行說明。
[Glass melting furnace]
"First embodiment"
FIG. 1 is a cross-sectional view of a glass melting furnace according to a first embodiment of the present invention, taken along a vertical plane of the Y axis. FIG. 2 is a cross-sectional view of the glass melting furnace according to the first embodiment of the present invention, taken along the X-axis vertical plane, and is a cross-sectional view in the direction of arrow II in FIG. 1. A first embodiment of a glass melting furnace according to the present invention will be described with reference to FIGS. 1 and 2.

本實施形態之玻璃熔解爐10具備:熔解槽20,其將由原料供給裝置(未圖示)所供給之玻璃原料熔解,且使所獲得之熔融玻璃G朝下游側(+X側)流動;及爐喉30,其與熔解槽20連通設置,使熔融玻璃G朝澄清槽(未圖示)或成形爐(未圖示)移送。The glass melting furnace 10 according to this embodiment includes a melting tank 20 that melts glass raw materials supplied from a raw material supply device (not shown) and flows the obtained molten glass G toward the downstream side (+ X side); and The furnace throat 30 is provided in communication with the melting tank 20 so that the molten glass G is transferred to a clarification tank (not shown) or a forming furnace (not shown).

熔解槽20具備間隔壁40與排出部50,將黏度η成為102 泊之溫度T2 為1580℃以上之玻璃熔解。間隔壁40遍及熔解槽20之寬度方向(Y軸方向)而設置,遮擋熔融玻璃G之流動之一部分。排出部50設置於爐喉30與間隔壁40之間之熔解槽20之底部21,將熔融玻璃G排出。The melting tank 20 includes a partition wall 40 and a discharge section 50, and melts a glass having a viscosity T of 10 2 poise and a temperature T 2 of 1580 ° C or higher. The partition wall 40 is provided across the width direction (Y-axis direction) of the melting tank 20 and blocks a part of the flow of the molten glass G. The discharge part 50 is provided in the bottom part 21 of the melting tank 20 between the furnace throat 30 and the partition wall 40, and discharges the molten glass G.

熔解槽20於位於熔融玻璃G之上側(+Z側)之壁部具備燃燒器(未圖示),藉由使用燃料及氣體之燃燒器燃燒,將供給至熔解槽20之內部之玻璃原料熔解而獲得熔融玻璃G。燃料使用天然氣或重油,氣體使用氧氣或空氣。熔解槽20具備底部21與側壁部22,且保持熔融玻璃G。底部21及側壁部22由於內側與熔融玻璃G接觸,故由耐蝕性優異之電鑄磚形成。作為電鑄磚之例,可列舉氧化鋯系磚、氧化鋁、氧化鋯、氧化矽(AZS)系磚、及氧化鋁系磚。底部21或側壁部22亦可具備通電電極(未圖示)。通電電極藉由施加電壓而產生焦耳熱,使玻璃原料熔解而獲得熔融玻璃G。The melting tank 20 is provided with a burner (not shown) on the wall portion (+ Z side) above the molten glass G, and the glass raw material supplied to the inside of the melting tank 20 is melted by burning with a burner using fuel and gas. Thus, a molten glass G is obtained. Fuel uses natural gas or heavy oil, and gas uses oxygen or air. The melting tank 20 includes a bottom portion 21 and a side wall portion 22, and holds the molten glass G. Since the bottom portion 21 and the side wall portion 22 are in contact with the molten glass G on the inner side, they are formed of an electroformed brick having excellent corrosion resistance. Examples of electroformed bricks include zirconia-based bricks, alumina, zirconia, silica (AZS) -based bricks, and alumina-based bricks. The bottom portion 21 or the side wall portion 22 may be provided with a conducting electrode (not shown). The current-carrying electrode generates Joule heat by applying a voltage, and melts the glass raw material to obtain molten glass G.

熔解槽20與熔融玻璃G接觸,故構成熔解槽20之電鑄磚之一部分溶出至熔融玻璃G。於在熔解槽20使用包含氧化鋯(ZrO2 )之電鑄磚之情形時,比重較高之氧化鋯(ZrO2 )成分溶出至熔融玻璃G。因此,於熔解槽20之底部21附近,氧化鋯(ZrO2 )濃度較高,比重較高之異質玻璃G1滯留。Since the melting tank 20 is in contact with the molten glass G, a part of the electroformed brick constituting the melting tank 20 is dissolved into the molten glass G. When an electroformed brick containing zirconia (ZrO 2 ) is used in the melting tank 20, a zirconia (ZrO 2 ) component having a high specific gravity is eluted to the molten glass G. Therefore, in the vicinity of the bottom 21 of the melting tank 20, the heterogeneous glass G1 having a high zirconia (ZrO 2 ) concentration and a high specific gravity is retained.

將自底部21至爐喉30之入口之下端為止之高度設為HS 。高度HS 為20[mm]以上。高度HS 較佳為200[mm]以下,更佳為40~150[mm],進而較佳為60~100[mm]。藉由將高度HS 設為20[mm]以上,可抑制異質玻璃G1通過爐喉30而向下游側(+X側)流出。又,藉由將高度HS 設為200[mm]以下,可將除異質玻璃G1以外之熔融玻璃G效率良好地向相較爐喉30更靠下游側(+X側)移送。The height from the bottom 21 to the lower end of the entrance of the furnace throat 30 is set to H S. The height H S is 20 [mm] or more. The height H S is preferably 200 [mm] or less, more preferably 40 to 150 [mm], and even more preferably 60 to 100 [mm]. By setting the height H S to 20 [mm] or more, the outflow of the heterogeneous glass G1 to the downstream side (+ X side) through the furnace throat 30 can be suppressed. Further, by setting the height H S to 200 [mm] or less, the molten glass G other than the heterogeneous glass G1 can be efficiently transferred to the downstream side (+ X side) than the furnace throat 30.

如圖2所示,爐喉30與熔解槽20之寬度方向(Y軸方向)中央部連通設置。因此,熔融玻璃G之流動於寬度方向(Y軸方向)上成對稱,從而容易控制圖1所示之下游側循環流102。As shown in FIG. 2, the furnace throat 30 and the center of the width direction (Y-axis direction) of the melting tank 20 are provided in communication. Therefore, the flow of the molten glass G is symmetrical in the width direction (Y-axis direction), so that it is easy to control the downstream-side circulating flow 102 shown in FIG. 1.

間隔壁40朝相較底部21更上側(+Z側)延伸而設置,其係遮擋熔融玻璃G之下層之流動之障壁構造。間隔壁40相對於間隔壁40之上側(+Z側)、上游側(-X側)、及下游側(+X側)之熔融玻璃G分別形成前進流100、上游側循環流101、及下游側循環流102。前進流100自熔解槽20內之上游側(-X側)朝下游側(+X側)流動。上游側循環流101係於熔融玻璃G之上部朝熔解槽20內之上游側(-X側)流動、且於熔融玻璃G之下部朝熔解槽20內之下游側(+X側)流動之循環流。下游側循環流102係於熔融玻璃G之上部朝熔解槽20內之下游側(+X側)流動、且於熔融玻璃G之下部朝熔解槽20內之上游側(-X側)流動之循環流。間隔壁40藉由電鑄磚、鉑、鉑合金、銥、鉬等相對於熔融玻璃G之耐蝕性優異之材料構成。The partition wall 40 extends toward the upper side (+ Z side) from the bottom portion 21 and is a barrier structure that blocks the flow of the lower layer of the molten glass G. The partition wall 40 forms a forward flow 100, an upstream circulation flow 101, and a downstream with respect to the molten glass G on the upper side (+ Z side), the upstream side (-X side), and the downstream side (+ X side) of the partition wall 40, respectively.侧 circulation flow 102. The forward flow 100 flows from the upstream side (-X side) to the downstream side (+ X side) in the melting tank 20. The upstream-side circulation flow 101 is a circulation flowing above the molten glass G toward the upstream side (-X side) in the melting tank 20 and flowing below the molten glass G toward the downstream side (+ X side) in the melting tank 20 flow. The downstream-side circulation flow 102 is a circulation flowing above the molten glass G toward the downstream side (+ X side) in the melting tank 20 and flowing below the molten glass G toward the upstream side (-X side) in the melting tank 20 flow. The partition wall 40 is made of a material having excellent corrosion resistance to the molten glass G, such as electroformed brick, platinum, platinum alloy, iridium, and molybdenum.

排出部50設置於爐喉30與間隔壁40之間之底部21,且於底部21之下側(-Z側),具備用以排出異質玻璃G1之排出管51。藉此,可抑制滯留於相較間隔壁40更靠下游側(+X側)之異質玻璃G1朝爐喉30流出。排出管51朝相較底部21更下側(-Z側)以筒狀延伸,且Z軸垂直面之剖面為圓形,但亦可為多邊形等。排出管51亦可設置用以控制混入有異質玻璃G1之熔融玻璃G之流下量之加熱設備(未圖示)。於該情形時,排出管51為鉑或鉑合金製,且藉由設置直接通電加熱設備而可精密地控制熔融玻璃G之流下量。The discharge portion 50 is provided at the bottom portion 21 between the furnace throat 30 and the partition wall 40, and is provided below the bottom portion 21 (-Z side), and includes a discharge tube 51 for discharging the hetero glass G1. Accordingly, it is possible to suppress the outflow of the heterogeneous glass G1 remaining on the downstream side (+ X side) from the partition wall 40 toward the throat 30. The discharge tube 51 extends in a cylindrical shape toward the lower side (−Z side) than the bottom portion 21, and the cross section of the Z-axis vertical plane is circular, but may be a polygon or the like. The discharge pipe 51 may also be provided with a heating device (not shown) for controlling the flow-down amount of the molten glass G mixed with the hetero glass G1. In this case, the discharge pipe 51 is made of platinum or a platinum alloy, and the flow-through amount of the molten glass G can be precisely controlled by providing a direct current heating device.

如圖2所示,排出部50設置於熔解槽20之寬度方向(Y軸方向)中央部。排出部50中,排出管51設置於爐喉30之寬度方向(Y軸方向)內側。藉此,可有效地抑制異質玻璃G1朝爐喉30流出。As shown in FIG. 2, the discharge portion 50 is provided at the center in the width direction (Y-axis direction) of the melting tank 20. In the discharge section 50, the discharge pipe 51 is provided inside the width direction (Y-axis direction) of the furnace throat 30. Thereby, the outflow of the heterogeneous glass G1 to the furnace throat 30 can be effectively suppressed.

將爐喉30之入口與間隔壁40之間之熔解槽20所保持之熔融玻璃G之重量設為W[噸],且將1天中自爐喉30移送之熔融玻璃G之重量設為P[噸/天]。此時,本實施形態之玻璃熔解爐10較佳為滿足0.2≦W/P≦2.0。W/P更佳為0.4≦W/P≦1.2,進而較佳為0.5≦W/P≦1.0。若W/P為2.0以下,則可抑制下游側循環流102,異質玻璃G1不易被捲起,故可抑制異質玻璃G1朝爐喉30流出。又,若W/P為0.2以上,則可將除異質玻璃G1以外之熔融玻璃G效率良好地向相較爐喉30更靠下游側(+X側)移送。又,重量P較佳為20~200[噸/天]。Let the weight of the molten glass G held by the melting tank 20 between the entrance of the throat 30 and the partition wall 40 be W [ton], and let the weight of the molten glass G transferred from the throat 30 in one day be P [Tons / day]. At this time, the glass melting furnace 10 of this embodiment preferably satisfies 0.2 ≦ W / P ≦ 2.0. W / P is more preferably 0.4 ≦ W / P ≦ 1.2, and still more preferably 0.5 ≦ W / P ≦ 1.0. When W / P is 2.0 or less, the downstream-side circulating flow 102 can be suppressed, and the heterogeneous glass G1 is not easily rolled up, so that the heterogeneous glass G1 can be prevented from flowing toward the furnace throat 30. Moreover, if W / P is 0.2 or more, the molten glass G other than the heterogeneous glass G1 can be efficiently transferred to the downstream side (+ X side) compared to the furnace throat 30. The weight P is preferably 20 to 200 [tons / day].

將自底部21至熔融玻璃G之上表面為止之高度設為H0 ,將自底部21至間隔壁40之上端為止之高度設為H1 ,且將爐喉30之入口之底部與頂部之間之高度設為H2 。本實施形態之玻璃熔解爐10中,H1 /H0 較佳為滿足0.3~0.95,更佳為滿足0.5~0.95。若H1 /H0 為0.3以上,則可防止下游側循環流102變大,異質玻璃G1不易被捲起,故可抑制異質玻璃G1朝爐喉30流出。又,若H1 /H0 為0.95以下,則前進流100及下游側循環流102穩定,異質玻璃G1不易被捲起,故可抑制異質玻璃G1朝爐喉30流出。The height from the bottom 21 to the upper surface of the molten glass G is H 0 , the height from the bottom 21 to the upper end of the partition wall 40 is H 1 , and between the bottom and the top of the entrance of the furnace throat 30 The height is set to H 2 . In the glass melting furnace 10 of this embodiment, H 1 / H 0 preferably satisfies 0.3 to 0.95, and more preferably satisfies 0.5 to 0.95. When H 1 / H 0 is 0.3 or more, the downstream circulating flow 102 can be prevented from increasing, and the heterogeneous glass G1 cannot be easily rolled up. Therefore, the heterogeneous glass G1 can be prevented from flowing toward the furnace throat 30. When H 1 / H 0 is 0.95 or less, the forward flow 100 and the downstream circulating flow 102 are stable, and the heterogeneous glass G1 is not easily rolled up, so that the heterogeneous glass G1 can be prevented from flowing toward the furnace throat 30.

又,本實施形態之玻璃熔解爐10中,H2 /H0 較佳為滿足0.1~0.5。藉由使H2 /H0 為0.1~0.5,可抑制異質玻璃G1朝爐喉30流出,並且可將除異質玻璃G1以外之熔融玻璃G效率良好地向相較爐喉30更靠下游側(+X側)移送。In the glass melting furnace 10 according to this embodiment, it is preferable that H 2 / H 0 satisfy 0.1 to 0.5. By setting H 2 / H 0 to 0.1 to 0.5, the outflow of the heterogeneous glass G1 to the furnace throat 30 can be suppressed, and the molten glass G other than the heterogeneous glass G1 can be efficiently moved to the downstream side than the furnace throat 30 ( + X side) transfer.

於俯視下,將熔解槽20內之自上游端至下游端之距離設為L0 ,將自間隔壁40之下游端至熔解槽20內之下游端之距離設為L1 。本實施形態之熔解槽20中,L1 /L0 較佳為滿足0.1~0.5。藉由使L1 /L0 為0.1~0.5,可將除異質玻璃G1以外之熔融玻璃G效率良好地向下游側(+X側)移送。In a plan view, the distance from the upstream end to the downstream end in the melting tank 20 is set to L 0 , and the distance from the downstream end of the partition wall 40 to the downstream end in the melting tank 20 is set to L 1 . In the melting tank 20 of this embodiment, L 1 / L 0 preferably satisfies 0.1 to 0.5. By setting L 1 / L 0 to 0.1 to 0.5, the molten glass G other than the heterogeneous glass G1 can be efficiently transferred to the downstream side (+ X side).

如圖2所示,將熔解槽20內之寬度方向(Y軸方向)距離設為W0 ,將爐喉30之寬度方向(Y軸方向)距離設為W1 。本實施形態之玻璃熔解爐10中,W1 /W0 較佳為滿足0.03~0.3。藉由使W1 /W0 為0.03~0.3,可使除異質玻璃G1以外之熔融玻璃G效率良好地向下游側(+X側)移送。As shown in FIG. 2, the width direction (Y-axis direction) distance in the melting tank 20 is set to W 0 , and the width direction (Y-axis direction) distance of the furnace throat 30 is set to W 1 . In the glass melting furnace 10 of this embodiment, W 1 / W 0 preferably satisfies 0.03 to 0.3. By setting W 1 / W 0 to 0.03 to 0.3, the molten glass G other than the heterogeneous glass G1 can be efficiently transferred to the downstream side (+ X side).

本實施形態之玻璃熔解爐10於爐喉30之入口,熔融玻璃G之流動方向(X軸方向)之平均流速V較佳為5~15[m/h]。平均流速V[m/h]係將爐喉30之入口處之X軸垂直面之剖面積設為S[m2 ],且將熔融玻璃G之密度設為d[噸/m3 ]時,根據V=P¸(24×S×d)而算出。若平均流速V為5[m/h]以上,則可使除異質玻璃G1以外之熔融玻璃G效率良好地向相較爐喉30更靠下游側(+X側)移送。又,若平均流速V為15[m/h]以下,則可有效地抑制異質玻璃G1朝爐喉30流出。In the glass melting furnace 10 of this embodiment at the entrance of the furnace throat 30, the average flow velocity V in the flow direction (X-axis direction) of the molten glass G is preferably 5 to 15 [m / h]. The average flow velocity V [m / h] is when the cross-sectional area of the X-axis vertical plane at the entrance of the furnace throat 30 is set to S [m 2 ] and the density of the molten glass G is set to d [ton / m 3 ]. It is calculated from V = P¸ (24 × S × d). If the average flow velocity V is 5 [m / h] or more, the molten glass G other than the heterogeneous glass G1 can be efficiently transferred to the downstream side (+ X side) compared to the furnace throat 30. When the average flow velocity V is 15 [m / h] or less, the outflow of the heterogeneous glass G1 to the furnace throat 30 can be effectively suppressed.

又,關於本實施形態中使用之玻璃,為了有效地抑制異質玻璃G1之混入,黏度η成為102 泊之溫度T2 較佳為1610℃以上,更佳為1640℃以上。又,本實施形態中使用之玻璃容易熔解,故黏度η成為102 泊之溫度T2 較佳為1670℃以下。In addition, regarding the glass used in this embodiment, in order to effectively suppress the mixing of the heterogeneous glass G1, the temperature T 2 at which the viscosity η becomes 10 2 poise is preferably 1610 ° C. or more, and more preferably 1640 ° C. or more. In addition, since the glass used in this embodiment is easy to melt, the temperature T 2 at which the viscosity η becomes 10 2 poise is preferably 1670 ° C. or lower.

「第二實施形態」
圖3係本發明之第二實施形態之玻璃熔解爐之於Y軸垂直面之剖視圖。圖4係本發明之第二實施形態之玻璃熔解爐之於X軸垂直面之剖視圖,且係圖3之II-II箭頭方向之剖視圖。
"Second Embodiment"
3 is a cross-sectional view of a glass melting furnace according to a second embodiment of the present invention, taken along a vertical plane of the Y axis. FIG. 4 is a cross-sectional view of the glass melting furnace according to the second embodiment of the present invention, taken along a vertical plane of the X axis, and is a cross-sectional view taken along the arrow II-II in FIG. 3.

參照圖3及圖4對本發明之玻璃熔解爐之第二實施形態進行說明。以下,僅對與第一實施形態不同之點進行說明。第二實施形態之玻璃熔解爐110於熔解槽中具備收容部60,該點與第一實施形態之玻璃熔解爐10之構造不同。A second embodiment of the glass melting furnace according to the present invention will be described with reference to Figs. 3 and 4. Hereinafter, only points different from the first embodiment will be described. The glass melting furnace 110 according to the second embodiment includes a storage portion 60 in a melting tank, which is different from the structure of the glass melting furnace 10 according to the first embodiment.

如圖3所示,本實施形態之熔解槽120具備凹狀之收容部60,其設置於爐喉30之入口與間隔壁40之間之底部21。收容部60為箱型之形狀,其貯存熔融玻璃G。收容部60於底部設置有將熔融玻璃G排出之排出部150。凹狀之收容部60之X軸垂直面或Y軸垂直面之剖面為矩形,但亦可為正方形、半圓形、半橢圓形或圓角矩形。又,收容部60之Z軸垂直面之剖面為圓形,但亦可為正方形或矩形。As shown in FIG. 3, the melting tank 120 according to the present embodiment includes a concave receiving portion 60 provided at a bottom portion 21 between the entrance of the furnace throat 30 and the partition wall 40. The accommodating portion 60 has a box shape and stores molten glass G. The storage portion 60 is provided at the bottom with a discharge portion 150 that discharges the molten glass G. The cross section of the X-axis vertical surface or the Y-axis vertical surface of the concave receiving portion 60 is rectangular, but may also be square, semi-circular, semi-oval, or rounded rectangle. The cross section of the Z-axis vertical plane of the receiving portion 60 is circular, but may be square or rectangular.

如圖4所示,收容部60設置於熔解槽120之寬度方向(Y軸方向)中央部。收容部60之寬度相較爐喉30大,故可有效地抑制異質玻璃G1朝爐喉30流出。As shown in FIG. 4, the accommodating portion 60 is provided at the center in the width direction (Y-axis direction) of the melting tank 120. The width of the accommodating portion 60 is larger than that of the furnace throat 30, so that the outflow of the heterogeneous glass G1 toward the furnace throat 30 can be effectively suppressed.

排出部150於收容部60之底部之下側(-Z側),具備用以排出異質玻璃G1之排出管151。排出部150中,排出管之鉛直方向(Z軸方向)長度變短了收容部60之深度之量之點與第一實施形態之排出部50不同。The discharge section 150 includes a discharge pipe 151 for discharging the hetero glass G1 on the lower side (-Z side) of the bottom of the storage section 60. The discharge portion 150 differs from the discharge portion 50 of the first embodiment in that the length in the vertical direction (Z-axis direction) of the discharge tube is shorter by the depth of the receiving portion 60.

根據本實施形態之熔解槽120,可有效地抑制異質玻璃G1朝爐喉30流出。將收容部60之底部、與熔解槽20之底部21之間之距離設為高度HS1 。高度HS1 較佳為50~300[mm]。若高度HS1 為50[mm]以上,則異質玻璃G1滯留於收容部60內。又,若高度HS1 為300[mm]以下,則可抑制於收容部60內引起熔融玻璃G之循環而使異質玻璃G1朝上部流出。According to the melting tank 120 of this embodiment, the outflow of the heterogeneous glass G1 to the furnace throat 30 can be effectively suppressed. The distance between the bottom of the receiving portion 60 and the bottom 21 of the melting tank 20 is set to a height H S1 . The height H S1 is preferably 50 to 300 [mm]. When the height H S1 is 50 [mm] or more, the heterogeneous glass G1 stays in the storage portion 60. In addition, when the height H S1 is 300 [mm] or less, circulation of the molten glass G in the storage portion 60 can be suppressed, and the heterogeneous glass G1 can flow out to the upper portion.

本實施形態中,於俯視下,將收容部60之下游端與爐喉30之入口之間之流動方向(X軸方向)距離設為LS 。距離LS 較佳為0~1000[mm]。距離LS 更佳為0~500[mm],進而較佳為0~100[mm]。若距離LS 為1000[mm]以下,則可有效地抑制異質玻璃G1朝爐喉30流出。In the present embodiment, the distance in the flow direction (X-axis direction) between the downstream end of the accommodation portion 60 and the entrance of the furnace throat 30 is set to L S in a plan view. The distance L S is preferably 0 to 1000 [mm]. The distance L S is more preferably 0 to 500 [mm], and even more preferably 0 to 100 [mm]. When the distance L S is 1000 [mm] or less, the outflow of the heterogeneous glass G1 to the furnace throat 30 can be effectively suppressed.

於俯視下,將收容部60之流動方向(X軸方向)距離設為L2 。本實施形態之熔解槽120中,L2 /L1 較佳為滿足0.05~0.5。藉由使L2 /L1 為0.05~0.5,可有效地抑制異質玻璃G1朝爐喉30流出。In a plan view, the distance in the flow direction (X-axis direction) of the containing portion 60 is set to L 2 . In the melting tank 120 of this embodiment, L 2 / L 1 preferably satisfies 0.05 to 0.5. By setting L 2 / L 1 to 0.05 to 0.5, the outflow of the heterogeneous glass G1 to the furnace throat 30 can be effectively suppressed.

如圖4所示,將收容部51之寬度方向(Y軸方向)距離設為W2 。本實施形態之熔解槽120中,W2 /W1 較佳為滿足1.1~5.0。藉由使W2 /W1 為1.1~5.0,可有效地抑制異質玻璃G1朝爐喉30流出。As shown in FIG. 4, the width direction (Y-axis direction) distance of the accommodation portion 51 is W 2 . In the melting tank 120 according to this embodiment, W 2 / W 1 preferably satisfies 1.1 to 5.0. By setting W 2 / W 1 to 1.1 to 5.0, the outflow of the heterogeneous glass G1 to the furnace throat 30 can be effectively suppressed.

將收容部60內之熔融玻璃G之重量設為w[噸],且將1天中自排出部150排出之熔融玻璃G之重量設為D[噸/天]。本實施形態之玻璃熔解爐110中,較佳為滿足0.02≦w/D≦0.4。若w/D為0.02以上,則可使異質玻璃G1滯留於收容部60內,故可有效地抑制異質玻璃G1朝爐喉30流出。若w/D為0.4以下,則可抑制於收容部60內引起熔融玻璃G之循環,故可有效地抑制異質玻璃G1朝爐喉30流出。又,重量D較佳為0.5~30[噸/天]。The weight of the molten glass G in the containing portion 60 is set to w [ton], and the weight of the molten glass G discharged from the discharge portion 150 in one day is set to D [ton / day]. In the glass melting furnace 110 of this embodiment, it is preferable to satisfy 0.02 ≦ w / D ≦ 0.4. If w / D is 0.02 or more, the heterogeneous glass G1 can be retained in the accommodating portion 60, so that the heterogeneous glass G1 can be effectively prevented from flowing out of the furnace throat 30. When w / D is 0.4 or less, the circulation of the molten glass G in the containing portion 60 can be suppressed, and therefore, the outflow of the heterogeneous glass G1 to the furnace throat 30 can be effectively suppressed. The weight D is preferably 0.5 to 30 [tons / day].

以上,參照圖式對本發明之實施形態進行了詳細描述,但具體之構成並不限於上述實施形態,亦包含不脫離本發明之主旨之範圍之設計變更。As mentioned above, the embodiment of the present invention has been described in detail with reference to the drawings, but the specific configuration is not limited to the above embodiment, and also includes design changes that do not depart from the scope of the present invention.

本實施形態之玻璃熔解爐10、110藉由燃燒器加熱及電加熱而進行玻璃原料之熔解,但亦可由單獨燃燒器加熱或單獨電加熱而進行玻璃原料之熔解。The glass melting furnaces 10 and 110 of this embodiment perform melting of glass raw materials by burner heating and electric heating, but glass melting can also be performed by heating by a separate burner or electric heating alone.

本實施形態之熔解槽20、120為於俯視下之一軸方向(X軸方向)較長地延伸之矩形狀,但只要可將玻璃原料熔解,則並不限定於此。The melting tanks 20 and 120 of this embodiment are rectangular shapes extending long in one axial direction (X-axis direction) in a plan view, but the glass raw materials are not limited to this as long as they can be melted.

本實施形態中,排出部50、150設置有一處,但亦可於玻璃熔解爐10、110之長度方向(X軸方向)或寬度方向(Y軸方向)上設置有兩處以上。In this embodiment, the discharge sections 50 and 150 are provided at one place, but two or more may be provided in the length direction (X-axis direction) or the width direction (Y-axis direction) of the glass melting furnaces 10 and 110.

本實施形態中,說明了於相較底部21更上側(+Z側)延伸設置之間隔壁40之形態,但間隔壁只要將熔融玻璃G間隔開,則並不限定於此。In this embodiment, the form of the partition wall 40 extended above (+ Z side) from the bottom part 21 was demonstrated, However, if a partition wall is used to isolate molten glass G, it is not limited to this.

[玻璃物品之製造方法]
其次,對本實施形態之玻璃熔解爐10、110中使用玻璃熔解爐110製造玻璃物品之製造方法進行說明。圖5係表示本發明之第一實施形態之玻璃物品之製造方法之流程圖。
[Manufacturing method of glass articles]
Next, the manufacturing method of manufacturing glass articles using the glass melting furnace 110 among the glass melting furnaces 10 and 110 of this embodiment is demonstrated. Fig. 5 is a flowchart showing a method for manufacturing a glass article according to the first embodiment of the present invention.

本實施形態之玻璃物品之製造方法包含:將玻璃原料熔解而獲得熔融玻璃G之熔解步驟S1;去除熔融玻璃G之氣泡之澄清步驟S2;成形熔融玻璃G之成形步驟S3;及將所成形之玻璃緩冷之緩冷步驟S4。The manufacturing method of the glass article in this embodiment includes: a melting step S1 of melting glass raw material to obtain molten glass G; a clarifying step S2 of removing bubbles of the molten glass G; a forming step S3 of forming the molten glass G; and Step S4 of slow cooling of glass.

熔解步驟S1中,將玻璃原料供給至熔解槽內,加熱玻璃原料而將其熔解。將設置於玻璃熔解爐之燃燒器之火焰朝玻璃原料放射,藉此自上方加熱玻璃原料。藉由燃燒器之火焰進行加熱,並且藉由對複數個通電電極施加電壓而通電,產生焦耳熱,將玻璃原料加熱。In the melting step S1, the glass raw material is supplied into a melting tank, and the glass raw material is heated to melt it. The flame of the burner installed in the glass melting furnace is radiated toward the glass material, thereby heating the glass material from above. It is heated by the flame of the burner, and is energized by applying a voltage to a plurality of current-carrying electrodes, generating Joule heat, and heating the glass raw material.

熔解步驟S1係於熔解槽中,使熔融玻璃朝下游側流動,將黏度η成為102 泊之溫度T2 為1580℃以上之玻璃熔解。熔解槽具備遍及熔解槽之寬度方向而設置之間隔壁,進而於熔解槽之底部具備排出部。間隔壁遮擋熔融玻璃之流動之一部分。熔融玻璃經由與熔解槽連通設置之爐喉而朝澄清步驟S2移送。排出部將熔融玻璃排出。The melting step S1 is performed in a melting tank so that the molten glass flows downstream, and the glass having a viscosity η of 10 2 poise and a temperature T 2 of 1580 ° C. or more is melted. The melting tank includes a partition wall provided throughout the width direction of the melting tank, and further includes a discharge portion at the bottom of the melting tank. The partition wall blocks a part of the flow of the molten glass. The molten glass is transferred to the clarification step S2 through a furnace throat provided in communication with the melting tank. The discharge unit discharges the molten glass.

將爐喉之入口與間隔壁之間之熔解槽所保持之熔融玻璃之重量設為W[噸],且將1天中自上述爐喉移送之熔融玻璃之重量設為P[噸/天]。本實施形態之熔解步驟S1較佳為滿足0.2≦W/P≦2.0。The weight of the molten glass held by the melting tank between the entrance of the furnace throat and the partition wall is W [ton], and the weight of the molten glass transferred from the furnace throat in one day is P [ton / day]. . It is preferable that the melting step S1 in this embodiment satisfies 0.2 ≦ W / P ≦ 2.0.

本實施形態之熔解步驟S1中,將1天中自排出部排出之熔融玻璃G之重量設為D[噸/天],則重量P[噸/天]較佳為滿足0.01≦D/P≦0.2。若D/P為0.01以上,則可將異質玻璃G1自排出部50充分地排出,故可抑制異質玻璃G1朝爐喉30流出。又,若D/P為0.2以下,則可抑制由來自排出部50之熔融玻璃G之排出所導致之生產損耗。In the melting step S1 of this embodiment, the weight of the molten glass G discharged from the discharge part in one day is set to D [ton / day], and the weight P [ton / day] preferably satisfies 0.01 ≦ D / P ≦ 0.2. When D / P is 0.01 or more, the heterogeneous glass G1 can be sufficiently discharged from the discharge section 50, so that the heterogeneous glass G1 can be suppressed from flowing out to the furnace throat 30. In addition, when D / P is 0.2 or less, production loss due to discharge of the molten glass G from the discharge section 50 can be suppressed.

澄清步驟S2係將熔解步驟S1中獲得之熔融玻璃供給至澄清槽,使熔融玻璃內之氣泡浮起並去除之步驟。作為促進氣泡浮起之方法,例如有對澄清槽內減壓而消泡之方法等。The clarification step S2 is a step of supplying the molten glass obtained in the melting step S1 to a clarification tank, so as to float and remove bubbles in the molten glass. As a method for promoting the floating of the bubbles, for example, there is a method of decompressing the inside of the clarification tank to defoam.

成形步驟S3係利用設置於相較熔解槽更靠下游側之成形爐將熔融玻璃成形。緩冷步驟S4利用設置於相較成形爐更靠下游側之緩冷爐將所成形之玻璃緩冷,最終獲得玻璃物品。The forming step S3 is to form the molten glass by using a forming furnace provided on the downstream side of the melting tank. The slow-cooling step S4 uses a slow-cooling furnace provided on the downstream side of the forming furnace to slowly cool the formed glass, and finally obtains a glass article.

為了獲得作為玻璃物品之玻璃板,例如使用浮式法。浮式法係使導入至收容於浮拋窯內之熔融金屬(例如,熔融錫)上之熔融玻璃朝特定方向流動,形成帶板狀之玻璃帶之方法(成形步驟S3)。玻璃帶於在水平方向流動之過程中冷卻之後,被自熔融金屬提拉,於緩冷爐內一面搬送一面緩冷,成為板玻璃(緩冷步驟S4)。板玻璃自緩冷爐搬出之後,藉由切割機切割成特定之尺寸形狀而成為製品即玻璃板。In order to obtain a glass plate as a glass article, a float method is used, for example. The float method is a method in which a molten glass introduced into a molten metal (for example, molten tin) contained in a floating kiln flows in a specific direction to form a plate-shaped glass ribbon (forming step S3). After the glass ribbon is cooled in the process of flowing in the horizontal direction, it is pulled from the molten metal, and is slowly cooled while being transported in the slow cooling furnace to become sheet glass (slow cooling step S4). After the plate glass is carried out from the slow cooling furnace, it is cut into a specific size and shape by a cutting machine to become a glass plate, which is a product.

又,作為獲得玻璃板之其他成形方法,亦可使用熔融法。熔融法係使自流槽狀構件之左右兩側之上緣溢出之熔融玻璃沿著流槽狀構件之左右兩側面流下,於左右兩側面相交之下緣合流,藉此形成帶板狀之玻璃帶之方法(成形步驟S3)。熔融玻璃帶一面朝鉛直方向(Z軸方向)下方移動一面緩冷,成為板玻璃(緩冷步驟S4)。板玻璃藉由切割機切割成特定之尺寸形狀,成為製品即玻璃板。Moreover, as another shaping | molding method of obtaining a glass plate, the melting method can also be used. The melting method is to make molten glass overflowing from the upper edges of the left and right sides of the trough-like member flow down along the left and right sides of the trough-like member, and merge under the intersection of the left and right sides to form a plate-shaped glass ribbon Method (forming step S3). The molten glass ribbon is slowly cooled while moving downward in the vertical direction (Z-axis direction), and becomes a sheet glass (slow cooling step S4). The plate glass is cut into a specific size and shape by a cutter, and becomes a product, namely, a glass plate.

再者,本實施形態之玻璃物品之製造方法包含澄清步驟S2,但本發明之玻璃物品之製造方法亦可不包含澄清步驟。該情形時,熔融玻璃經過熔解步驟,於成形步驟中成形為玻璃帶。In addition, the manufacturing method of the glass article of this embodiment includes the clarification step S2, but the manufacturing method of the glass article of the present invention may not include the clarification step. In this case, the molten glass undergoes a melting step and is formed into a glass ribbon in a forming step.

本實施形態中使用之玻璃原料之組成並無特別限制,亦可為無鹼玻璃、鋁矽酸鹽玻璃、混合鹼系玻璃、硼矽酸玻璃、或其他玻璃之任一者。The composition of the glass raw material used in this embodiment is not particularly limited, and may be any of alkali-free glass, aluminosilicate glass, mixed alkali-based glass, borosilicate glass, or other glasses.

又,本實施形態中使用之玻璃為了可有效地抑制異質玻璃G1之混入,黏度η成為102 泊之溫度T2 較佳為1610℃以上,更佳為1640℃以上。又,本實施形態中使用之玻璃容易熔解,故黏度η成為102 泊之溫度T2 較佳為1670℃以下。In addition, in order that the glass used in this embodiment can effectively suppress the mixing of the heterogeneous glass G1, the temperature T 2 at which the viscosity η becomes 10 2 poise is preferably 1610 ° C. or more, and more preferably 1640 ° C. or more. In addition, since the glass used in this embodiment is easy to melt, the temperature T 2 at which the viscosity η becomes 10 2 poise is preferably 1670 ° C. or lower.

已對本發明詳細地、且參照特定之實施態樣進行了說明,但業者明白可不脫離本發明之精神與範圍而進行各種變更或修正。Although the present invention has been described in detail and with reference to specific implementation aspects, it is understood that various changes or modifications can be made without departing from the spirit and scope of the present invention.

本申請案基於2017年10月24日提出申請之日本專利申請2017-205301,其內容作為參照而併入至本文。
[產業上之可利用性]
This application is based on Japanese Patent Application No. 2017-205301 filed on October 24, 2017, the contents of which are incorporated herein by reference.
[Industrial availability]

所製造之玻璃物品之用途可列舉建築用、車輛用、平板顯示器用、防護玻璃罩用、及其他各種用途。The applications of the manufactured glass articles include construction, vehicles, flat panel displays, protective glass covers, and various other uses.

10‧‧‧玻璃熔解爐10‧‧‧Glass melting furnace

20‧‧‧熔解槽 20‧‧‧ melting tank

21‧‧‧底部 21‧‧‧ bottom

22‧‧‧側壁部 22‧‧‧ sidewall

30‧‧‧爐喉 30‧‧‧furnace

40‧‧‧間隔壁 40‧‧‧ partition

50‧‧‧排出部 50‧‧‧Exhaust

51‧‧‧排出管 51‧‧‧Exhaust pipe

60‧‧‧收容部 60‧‧‧ Containment Department

100‧‧‧前進流 100‧‧‧ Forward

101‧‧‧上游側循環流 101‧‧‧ upstream side circulation

102‧‧‧下游側循環流 102‧‧‧ downstream side circulation

110‧‧‧玻璃熔解爐 110‧‧‧Glass melting furnace

120‧‧‧熔解槽 120‧‧‧ melting tank

150‧‧‧排出部 150‧‧‧Exhaust

151‧‧‧排出管 151‧‧‧Exhaust pipe

G‧‧‧熔融玻璃 G‧‧‧ molten glass

G1‧‧‧異質玻璃 G1‧‧‧heterogeneous glass

H0‧‧‧高度H 0 ‧‧‧ height

H1‧‧‧高度H 1 ‧‧‧ height

H2‧‧‧高度H 2 ‧‧‧ height

HS‧‧‧高度H S ‧‧‧ height

L0‧‧‧距離L 0 ‧‧‧ distance

L1‧‧‧距離L 1 ‧‧‧ distance

L2‧‧‧距離L 2 ‧‧‧ distance

S1‧‧‧熔解步驟 S1‧‧‧ Melting step

S2‧‧‧澄清步驟 S2‧‧‧ Clarification steps

S3‧‧‧成形步驟 S3‧‧‧forming steps

S4‧‧‧緩冷步驟 S4‧‧‧ Slow cooling step

W0‧‧‧距離W 0 ‧‧‧Distance

W1‧‧‧距離W 1 ‧‧‧Distance

W2‧‧‧距離W 2 ‧‧‧Distance

圖1係本發明之第一實施形態之玻璃熔解爐之於Y軸垂直面之剖視圖。FIG. 1 is a cross-sectional view of a glass melting furnace according to a first embodiment of the present invention, taken along a vertical plane of the Y axis.

圖2係本發明之第一實施形態之玻璃熔解爐之於X軸垂直面之剖視圖,且係圖1之I-I箭頭方向之剖視圖。 FIG. 2 is a cross-sectional view of the glass melting furnace according to the first embodiment of the present invention, taken along the X-axis vertical plane, and is a cross-sectional view in the direction of arrows I-I in FIG. 1.

圖3係本發明之第二實施形態之玻璃熔解爐之於Y軸垂直面之剖視圖。 3 is a cross-sectional view of a glass melting furnace according to a second embodiment of the present invention, taken along a vertical plane of the Y axis.

圖4係本發明之第二實施形態之玻璃熔解爐之於X軸垂直面之剖視圖,且係圖3之II-II箭頭方向之剖視圖。 FIG. 4 is a cross-sectional view of the glass melting furnace according to the second embodiment of the present invention, taken along a vertical plane of the X axis, and is a cross-sectional view taken along the arrow II-II in FIG. 3.

圖5係表示本發明之第一實施形態之玻璃物品之製造方法之流程圖。 Fig. 5 is a flowchart showing a method for manufacturing a glass article according to the first embodiment of the present invention.

Claims (13)

一種玻璃熔解爐,其特徵在於具備:熔解槽,其將玻璃原料熔解,且使所獲得之熔融玻璃朝下游側流動;及爐喉,其與上述熔解槽連通設置,使上述熔融玻璃朝澄清槽或成形爐移送;且 上述熔解槽具備間隔壁與排出部,將黏度η成為102 泊之溫度T2 為1580℃以上之玻璃熔解, 上述間隔壁遍及上述熔解槽之寬度方向設置,遮擋上述熔融玻璃之流動之一部分, 上述排出部設置於上述爐喉與上述間隔壁之間之上述熔解槽之底部,將上述熔融玻璃排出, 自上述底部至上述爐喉之入口之下端為止之高度為20[mm]以上。A glass melting furnace, comprising: a melting tank that melts glass raw materials and causes the obtained molten glass to flow downstream; and a furnace throat that is provided in communication with the melting tank so that the molten glass faces a clarification tank. Or the melting furnace transfers; and the melting tank is provided with a partition wall and a discharge part, and the glass having a viscosity η of 10 2 poises and a temperature T 2 of 1580 ° C. or higher is fused, and the partition wall is provided across the width direction of the melting tank to block the melting As part of the flow of glass, the discharge part is disposed at the bottom of the melting tank between the furnace throat and the partition wall, and discharges the molten glass. The height from the bottom to the lower end of the entrance of the furnace throat is 20 [ mm] or more. 如請求項1之玻璃熔解爐,其中將上述爐喉之入口與上述間隔壁之間之上述熔解槽所保持之熔融玻璃之重量設為W[噸],且將1天中自上述爐喉移送之熔融玻璃之重量設為P[噸/天],則上述玻璃熔解爐滿足0.2≦W/P≦2.0。For example, the glass melting furnace of claim 1, wherein the weight of the molten glass held in the melting tank between the entrance of the furnace throat and the partition wall is set to W [ton], and the weight is transferred from the furnace throat in one day. If the weight of the molten glass is set to P [ton / day], then the above glass melting furnace satisfies 0.2 ≦ W / P ≦ 2.0. 如請求項1或2之玻璃熔解爐,其中上述玻璃熔解爐自上述底部至上述爐喉之入口之下端為止之高度為200[mm]以下。For example, the glass melting furnace of claim 1 or 2, wherein the height of the glass melting furnace from the bottom to the lower end of the entrance of the throat is 200 [mm] or less. 如請求項1或2之玻璃熔解爐,其中上述熔解槽具備設置於上述底部之凹狀之收容部, 上述收容部之深度為50~300[mm],且於底部設置有將上述熔融玻璃排出之排出部。For example, the glass melting furnace according to claim 1 or 2, wherein the melting tank is provided with a concave-shaped receiving part provided at the bottom, The containing portion has a depth of 50 to 300 [mm], and a discharging portion for discharging the molten glass is provided at the bottom. 如請求項4之玻璃熔解爐,其中於俯視下,上述收容部之下游端與上述爐喉之入口之間之流動方向距離為0~1000[mm]。For example, the glass melting furnace according to claim 4, wherein in a plan view, the distance between the downstream end of the containing portion and the inlet of the furnace throat is 0 to 1000 [mm]. 一種玻璃物品之製造方法,其特徵在於,包含熔解步驟、成形步驟、及緩冷步驟,且 上述熔解步驟係於熔解槽中將玻璃原料熔解,且使所獲得之熔融玻璃朝下游側流動,將黏度η成為102 泊之溫度T2 為1580℃以上之玻璃熔解, 上述熔解槽具備遍及上述熔解槽之寬度方向而設置之間隔壁,進而於上述爐喉與上述間隔壁之間之上述熔解槽之底部具備排出部,上述間隔壁遮擋上述熔融玻璃之流動之一部分, 上述熔融玻璃經由與上述熔解槽連通設置之爐喉而朝澄清步驟或上述成形步驟移送,上述排出部將上述熔融玻璃排出, 自上述底部至上述爐喉之入口之下端為止之高度為20[mm]以上。A method for manufacturing a glass article, which comprises a melting step, a forming step, and a slow cooling step, and the melting step is to melt a glass raw material in a melting tank and cause the obtained molten glass to flow to the downstream side. The glass having a viscosity η of 10 2 poises and a temperature T 2 of 1580 ° C. or more, the melting tank is provided with partition walls provided throughout the width direction of the melting tank, and further the melting tank between the furnace throat and the partition wall The bottom part is provided with a discharge part, the partition wall blocks a part of the flow of the molten glass, the molten glass is transferred to the clarification step or the forming step through a furnace throat connected to the melting tank, the discharge part discharges the molten glass, The height from the bottom to the lower end of the entrance of the furnace throat is 20 [mm] or more. 如請求項6之玻璃物品之製造方法,其中將上述爐喉之入口與上述間隔壁之間之上述熔解槽所保持之熔融玻璃之重量設為W[噸],且將1天中自上述爐喉移送之熔融玻璃之重量設為P[噸/天],則滿足0.2≦W/P≦2.0。For example, the method for manufacturing a glass article according to claim 6, wherein the weight of the molten glass held by the melting tank between the entrance of the furnace throat and the partition wall is W [ton], and the furnace is removed from the furnace in one day. The weight of the molten glass transferred by the throat is set to P [ton / day], and then 0.2 ≦ W / P ≦ 2.0 is satisfied. 如請求項6或7之玻璃物品之製造方法,其中自上述底部至上述爐喉之入口之下端為止之高度為200[mm]以下。For example, the method for manufacturing a glass article according to claim 6 or 7, wherein the height from the bottom to the lower end of the entrance of the furnace throat is 200 [mm] or less. 如請求項6或7之玻璃物品之製造方法,其中上述熔解步驟中, 於設置於上述熔解槽之底部之凹狀之收容部貯存上述熔融玻璃, 藉由設置於上述收容部之底部之排出部將上述熔融玻璃排出, 上述收容部之深度為50~300[mm]。If the method of manufacturing a glass article according to claim 6 or 7, wherein in the above melting step, The molten glass is stored in a concave receiving part provided at the bottom of the melting tank, The molten glass is discharged by a discharge portion provided at the bottom of the containing portion, The depth of the containing portion is 50 to 300 [mm]. 如請求項9之玻璃物品之製造方法,其中上述熔解步驟中,於俯視下,上述收容部之下游端與上述爐喉之入口之間之流動方向距離為0~1000[mm]。For example, the method for manufacturing a glass article according to claim 9, wherein in the above melting step, a distance in a flow direction between a downstream end of the containing portion and an inlet of the furnace throat in a plan view is 0 to 1000 [mm]. 如請求項9之玻璃物品之製造方法,其中上述熔解步驟中,將上述收容部內之熔融玻璃之重量設為w[噸],將1天中自上述排出部排出之熔融玻璃之重量設為D[噸/天],則滿足0.02≦w/D≦0.4。For example, the method for manufacturing a glass article according to claim 9, wherein in the above melting step, the weight of the molten glass in the containing part is set to w [ton], and the weight of the molten glass discharged from the discharging part in one day is set to D [Ton / day], then satisfy 0.02 ≦ w / D ≦ 0.4. 如請求項6或7之玻璃物品之製造方法,其中上述熔解步驟中,於上述爐喉之入口,上述熔融玻璃之流動方向之平均流速為5~15[m/h]。For example, the method for manufacturing a glass article according to claim 6 or 7, wherein in the melting step, the average flow velocity of the molten glass in the direction of the inlet of the furnace throat is 5 to 15 [m / h]. 如請求項7之玻璃物品之製造方法,其中於上述熔解步驟中,將1天中自上述排出部排出之熔融玻璃之重量設為D[噸/天],則上述重量P滿足0.01≦D/P≦0.2。For example, in the method for manufacturing a glass article according to claim 7, wherein in the above-mentioned melting step, the weight of the molten glass discharged from the above-mentioned discharge section in one day is set to D [ton / day], then the above-mentioned weight P satisfies 0.01 ≦ D / P ≦ 0.2.
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